publications (as of apr. 3, 2019)kuchem.kyoto-u.ac.jp/orgchem/yorimitsu_lab/publication... · 2019....

Publications (as of Apr. 3, 2019)

Original Papers

(307) “Annulative Synthesis of Thiazoles and Oxazoles from Alkenyl Sulfoxides and

Nitriles via Additive Pummerer Reaction” Mitsuki Hori, Keisuke Nogi, Aiichiro

Nagaki, and Hideki Yorimitsu, Asian J. Org. Chem. 2019, 8, in press (DOI:

10.1002/ajoc.201900169).

(306) “Sulfoxide-Directed Iterative Assembly into Oligoarenes” Tomoyuki Yanagi,

Keisuke Nogi, and Hideki Yorimitsu, Synlett 2019, 30, in press (DOI:

10.1055/s-0037-1611767).

(305) “Palladium-Catalyzed Amination of Aryl Sulfides and Sulfoxides with

Azaarylamines of Poor Nucleophilicity” Ramendra Pratap and Hideki Yorimitsu,

Synthesis 2019, 51, in press (DOI: 10.1055/s-0037-1611732).

(304) “Four-Component Coupling Strategy for 2,3,4-Trisubstituted

3,4-Dihydroquinoline” Hiroki Yamagishi, Shun Tsuchiya, Hayate Saito, Keisuke

Nogi, Jun Shimokawa, and Hideki Yorimitsu, Heterocycles 2019, 99, in press

(DOI: 10.3987/COM-18-S(F)24).

(303) “Palladium-Catalyzed Alkoxycarbonylation of Arylsulfoniums” Hiroko Minami,

Keisuke Nogi, and Hideki Yorimitsu, Org. Lett. 2019, 21, in press (DOI:

10.1021/acs.orglett.9b00067).

(302) “Photoredox-Catalyzed Site-Selective α-C(sp3)–H Alkylation of Primary Amine

Derivatives” Melissa A. Ashley, Chiaki Yamauchi, John C. K. Chu, Shinya

Otsuka, Hideki Yorimitsu, and Tomislav Rovis, Angew. Chem. Int. Ed. 2019, 58,

4002–4006 (DOI: 10.1002/anie.201812227); Angew. Chem. 2019, 131,

4042–4046 (DOI: 10.1002/ange.201812227).

(301) “Photoredox-Catalyzed Alkenylation of Benzylsulfoniums” Shinya Otsuka,

Keisuke Nogi, Tomislav Rovis, and Hideki Yorimitsu, Chem. Asian J. 2019, 14,

532–536 (DOI: 10.1002/asia.201801732).

(300) “Annulative Synthesis of Benzofurans from General Alkenyl Sulfoxides and

Phenols via Pummerer/Sigmatropic Cascade” Mitsuki Hori, Tomoyuki Yanagi,

Kei Murakami, Keisuke Nogi, and Hideki Yorimitsu, Bull. Chem. Soc. Jpn. 2019,

92, 302–311 (DOI: 10.1246/bcsj.20180321).

(299) “Iridium-catalyzed Hydroarylation of Glycals: Ligand-controlled Stereoselective

Synthesis of α- and β-C-glycosyl Arenes” Kana Sakamoto, Masaki Nagai,

Yusuke Ebe, Hideki Yorimitsu, and Takahiro Nishimura, ACS Catal. 2019, 9,

1347–1352 (DOI: 10.1021/acscatal.8b04686).

(298) “Carbon Materials with Zigzag and Armchair Edges” Yasuhiro Yamada, Miki

Kawai, Hideki Yorimitsu, Shinya Otsuka, Motoharu Takanashi,andSatoshi Sato,

ACS Appl. Mater. Interfaces 2018, 10, 40710–40739 (DOI:

10.1021/acsami.8b11022).

(297) “Intramolecular Desulfitative Coupling: Nickel-Catalyzed Transformation of

Diaryl Sulfones into Biaryls via Extrusion of SO2” Fumiya Takahashi, Keisuke

Nogi, and Hideki Yorimitsu, Org. Lett. 2018, 20, 6601–6605 (DOI:

10.1021/acs.orglett.8b02972).

(296) “Sigmatropic Dearomatization/Defluorination Strategy for C–F Transformation:

Synthesis of Fluorinated Benzofurans from Polyfluorophenols” Koichi Okamoto,

Mitsuki Hori, Tomoyuki Yanagi, Kei Murakami, Keisuke Nogi, and Hideki

Yorimitsu, Angew. Chem. Int. Ed. 2018, 57, 14230–14234 (DOI:

10.1002/anie.201809035); Angew. Chem. 2018, 130, 14426–14430 (DOI:

10.1002/ange.201809035).

(295) “Cobalt-Catalyzed Reduction of Aryl Sulfones to Arenes by Means of

Alkylmagnesium Reagents” Jun-ichi Fukuda, Keisuke Nogi, and Hideki

Yorimitsu, Asian J. Org. Chem. 2018, 7, 2049–2052 (DOI:

10.1002/ajoc.201800473).

(294) “Synthesis of 4-aryl- and 4-acyl-1,3-dithiole-2-thiones via deprotonative

zincation of 1,3-dithiole-2-thione” Shinya Otsuka and Hideki Yorimitsu,

Heteroatom Chem. 2018, 29, e21432 (DOI: 10.1002/hc.21432).

(293) “Copper-Catalyzed Ring-Opening Silylation of Benzofurans with Disilane”

Hayate Saito, Keisuke Nogi, and Hideki Yorimitsu, Angew. Chem. Int. Ed. 2018,

57, 11030–11034 (DOI: 10.1002/anie.201806237); Angew. Chem. 2018, 130,

11196–11200 (DOI: 10.1002/ange.201806237).

(292) “Macroscopically Anisotropic Structures Produced by Light-induced

Solvothermal Assembly of Porphyrin Dimers” Yasuyuki Yamamoto, Yushi

Nishimura, Shiho Tokonami, Norihito Fukui, Takayuki Tanaka, Atsuhiro Osuka,

Hideki Yorimitsu, and Takuya Iida, Sci. Rep. 2018, 8, No. 11108 (DOI:

10.1038/s41598-018-28311-2 or https://rdcu.be/3nrz).

(291) “Palladium-Catalyzed Mizoroki-Heck-Type Alkenylation of

Monoaryldialkylsulfoniums” Daisuke Uno, Hiroko Minami, Shinya Otsuka,

Keisuke Nogi, and Hideki Yorimitsu, Chem. Asian J. 2018, 13, 2397–2400

(DOI: 10.1002/asia.201800489).

(290) “Palladium-Catalyzed Insertion of Isocyanides into the C-S Bonds of Heteroaryl

Sulfides” Shinya Otsuka, Keisuke Nogi, and Hideki Yorimitsu, Angew. Chem.

Int. Ed. 2018, 57, 6653–6657 (DOI: 10.1002/anie.201802369); Angew. Chem.

2018, 130, 6763–6767 (DOI: 10.1002/ange.201802369).

(289) “Palladium-catalyzed Homo-coupling of Heteroarylsulfoniums via

Borylation/Suzuki-Miyaura Coupling Sequence” Hiroko Minami, Keisuke Nogi,

and Hideki Yorimitsu, Heterocycles 2018, 97, 998–1007 (DOI:

10.3987/COM-18-S(T)78).

(288) “Sigmatropic Rearrangements of Hypervalent-Iodine-Tethered Intermediates for

the Synthesis of Biaryls” Mitsuki Hori, Jing-Dong Guo, Tomoyuki Yanagi,

Keisuke Nogi, Takahiro Sasamori, and Hideki Yorimitsu, Angew. Chem. Int. Ed.

2018, 57, 4663–4667 (DOI: 10.1002/anie.201801132); Angew. Chem. 2018, 130,

4753–4757 (DOI: 10.1002/ange.201801132).

(287) “Palladium-Catalyzed Amination of Aryl Sulfoxides” Yuto Yoshida, Shinya

Otsuka, Keisuke Nogi, and Hideki Yorimitsu, Org. Lett. 2018, 20, 1134–1137

(DOI: 10.1021/acs.orglett.8b00060).

(286) “Iridium-Catalyzed Hydroarylation of Conjugated Dienes via π-Allyliridium

Intermediates” Midori Nagamoto, Hideki Yorimitsu, and Takahiro Nishimura,

Org. Lett. 2018, 20, 828–831 (DOI: 10.1021/acs.orglett.7b03969).

(285) “Room temperature stable film formation of π-conjugated organic molecules on

3d magnetic substrate” Eiichi Inami, Mikio Shimasaki, Hideki Yorimitsu, and

Toyo Kazu Yamada, Sci. Rep. 2018, 8, No. 353 (DOI:

10.1038/s41598-017-18605-2).

(284) “Palladium-Catalyzed Borylation of Aryl Sulfoniums with Diborons” Hiroko

Minami, Shinya Otsuka, Keisuke Nogi, and Hideki Yorimitsu, ACS Catal. 2018,

8, 579–583 (DOI: 10.1021/acscatal.7b03841).

(283) “Palladium-Catalyzed Arylation of Benzylic C-H Bonds of Azaarylmethanes

with Aryl Sulfides” Ke Gao, Keita Yamamoto, Keisuke Nogi, and Hideki

Yorimitsu, Synlett 2017, 28, 2956–2960 (DOI: 10.1055/s-0036-1589098).

(282) “C–S Bond Alkynylation of Diaryl Sulfoxides with Terminal Alkynes by Means

of a Palladium-NHC Catalyst” Yuto Yoshida, Keisuke Nogi, and Hideki

Yorimitsu, Synlett 2017, 28, 2561–2564 (DOI: 10.1055/s-0036-1591676).

(281) “Hydroxoiridium-Catalyzed Hydroarylation of Alkynes and Bicycloalkenes with

N-Sulfonylbenzamides” Midori Nagamoto, Jun-ichi Fukuda, Miyuki Hatano,

Hideki Yorimitsu, and Takahiro Nishimura, Org. Lett. 2017, 19, 5952–5955


(280) “Nickel-Catalyzed Cross-Coupling Reaction of Aryl Sulfoxides with Arylzinc

Reagents: When the Leaving Group is an Oxidant” Keita Yamamoto, Shinya

Otsuka, Keisuke Nogi, and Hideki Yorimitsu, ACS Catal. 2017, 7, 7623–7628

(DOI: 10.1021/acscatal.7b02347).

(279) “Manganese-Catalyzed Ring Opening of Benzofurans and Its Application to

Insertion of Heteroatoms into the C2–O Bond” Shun Tsuchiya, Hayate Saito,

Keisuke Nogi, and Hideki Yorimitsu, Org. Lett. 2017, 19, 5557–5560 (DOI:

10.1021/acs.orglett.7b02660).

(278) “Regioselective C-H Sulfanylation of Aryl Sulfoxides by Means of

Pummerer-Type Activation” Hitomi Kawashima, Tomoyuki Yanagi, Chien-Chi

Wu, Keisuke Nogi, and Hideki Yorimitsu, Org. Lett. 2017, 19, 4552–4555 (DOI:

10.1021/acs.orglett.7b02147).

(277) “Robust Palladium-Catalyzed Arylation of Catalyst-Poisoning ortho-Sulfanyl

Aryl Halides with Tetraarylborates and Its Application to Synthesis of

π-Extended Dibenzothiophenes” Dhananjayan Vasu, Jan Niklas Hausmann,

Hayate Saito, Tomoyuki Yanagi, Hideki Yorimitsu, and Atsuhiro Osuka, Asian J.

Org. Chem. 2017, 6, 1390–1393 (DOI: 10.1002/ajoc.201700323).

(276) “Iridium-catalyzed sp3 C–H Alkylation of 3-Carbonyl-2-(alkylamino)pyridines

with Alkenes” Masaki Nagai, Midori Nagamoto, Takahiro Nishimura, and

Hideki Yorimitsu, Chem. Lett. 2017, 46, 1176–1178 (DOI: 10.1246/cl.170373).

(275) “Rh/Cu-cocatalyzed Ring-opening Diborylation of Dibenzothiophenes for

Aromatic Metamorphosis via Diborylbiaryls” Hayate Saito, Keisuke Nogi, and

Hideki Yorimitsu, Chem. Lett. 2017, 46, 1122–1125 (DOI: 10.1246/cl.170415).

(274) “Palladium-Catalyzed Double Borylation of Diaryl Sulfoxides with Diboron”

Hayate Saito, Keisuke Nogi, and Hideki Yorimitsu, Synthesis 2017, 49,

4769–4774 (DOI: 10.1055/s-0036-1588848).

(273) “Iridium-Catalyzed Intramolecular Oxidative Cyclization of Alkenamides and

Alkenoic Acids” Midori Nagamoto, Takahiro Nishimura, and Hideki Yorimitsu,

Synthesis 2017, 49, 4272–4282 (DOI: 10.1055/s-0036-1588435).

(272) “Hydroxoiridium-Catalyzed Hydroalkylation of Terminal Alkenes with Ureas

via C(sp3)–H Bond Activation” Daisuke Yamauchi, Takahiro Nishimura, and

Hideki Yorimitsu, Angew. Chem. Int. Ed. 2017, 56, 7200–7204 (DOI:

10.1002/anie.201702169); Angew. Chem. 2017, 129, 7306–7310.

(271) “Iridium-Catalyzed Cleavage of C–O Bonds Using Alcohols as Reducing

Reagents” Yuta Hibe, Yusuke Ebe, Takahiro Nishimura, and Hideki Yorimitsu,

Chem. Lett. 2017, 46, 953–955 (DOI: 10.1246/cl.170239).

(270) “Iridium-Catalyzed Regio- and Enantioselective Hydroarylation of Alkenyl

Ethers by Olefin Isomerization” Yusuke Ebe, Mitsuki Onoda, Takahiro

Nishimura, and Hideki Yorimitsu, Angew. Chem. Int. Ed. 2017, 56, 5607–5611

(DOI: 10.1002/anie.201702286); Angew. Chem. 2017, 129, 5699–5703.

(269) “Palladium-Catalyzed Cross-Coupling of Aryl Chlorides with Arylsilatranes”

Yutaro Yamamoto, Alexandre Baralle, Anaïs Godefroy, Kei Murakami, Hideki

Yorimitsu, and Atsuhiro Osuka, Heterocycles 2017, 95, 568–574 (DOI:

10.3987/COM-16-S(S)21).

(268) “Aromatic Metamorphosis of Dibenzofurans into Triphenylenes Starting with

Nickel-Catalyzed Ring-Opening C-O Arylation” Yuto Kurata, Shinya Otsuka,

Norihito Fukui, Keisuke Nogi, Hideki Yorimitsu, and Atsuhiro Osuka, Org. Lett.

2017, 19, 1274–1277 (DOI: 10.1021/acs.orglett.6b03861).

(267) “Asymmetric hydroarylation of vinyl ethers catalyzed by a hydroxoiridium

complex: azoles as effective directing groups” Daisuke Yamauchi, Takahiro

Nishimura, and Hideki Yorimitsu, Chem. Commun. 2017, 53, 2760–2763 (DOI:

10.1039/C7CC00238F).

(266) “Synthesis of Dibenzophospholes from Dibenzothiophene Dioxides and

Phenylphosphine by Twofold SNAr Reactions” Mitsuki Onoda, Yoshinari

Koyanagi, Hayate Saito, M. Bhanuchandra, Yoshihiro Matano, and Hideki

Yorimitsu, Asian J. Org. Chem. 2017, 6, 257–261 (DOI:

10.1002/ajoc.201600612).

(265) “Base-Free Palladium-Catalyzed Hydrodechlorination of Aryl Chlorides with

Pinacol Borane” Yutaro Yamamoto, Keisuke Nogi, Hideki Yorimitsu, and

Atsuhiro Osuka, ChemistrySelect 2017, 2, 1723–1727 (DOI:

10.1002/slct.201700189).

(264) “Highly planar diarylamine-fused porphyrins and their remarkably stable radical

cations” Norihito Fukui, Wonhee Cha, Daiki Shimizu, Juwon Oh, Ko Furukawa,

Hideki Yorimitsu, Dongho Kim, and Atsuhiro Osuka, Chem. Sci. 2017, 8,

189–199 (DOI: 10.1039/C6SC02721K).

(263) “meso-meso Linked Diarylamine-Fused Porphyrin Dimers” Norihito Fukui,

Hideki Yorimitsu, and Atsuhiro Osuka, Chem. Eur. J. 2016, 22, 18476–18483

(DOI: 10.1002/chem.201604301).

(262) “Nickel-Catalyzed Boron Insertion into the C2–O Bond of Benzofurans” Hayate

Saito, Shinya Otsuka, Keisuke Nogi, and Hideki Yorimitsu, J. Am. Chem. Soc.

2016, 138, 15315–15318 (DOI: 10.1021/jacs.6b10255).

(261) “Metal-Free Approach to Biaryls from Phenols and Aryl Sulfoxides by

Temporarily Sulfur-Tethered Regioselective C–H/C–H Coupling” Tomoyuki

Yanagi, Shinya Otsuka, Yuko Kasuga, Keisuke Fujimoto, Kei Murakami,

Keisuke Nogi, Hideki Yorimitsu, and Atsuhiro Osuka, J. Am. Chem. Soc. 2016,

138, 14582–14585 (DOI: 10.1021/jacs.6b10278).

(260) “Pictet-Spengler Synthesis of Quinoline-Fused Porphyrins and

Phenanthroline-Fused Diporphyrins” Ke Gao, Norihito Fukui, Seok Il Jung,

Hideki Yorimitsu, Dongho Kim, and Atsuhiro Osuka, Angew. Chem. Int. Ed.

2016, 55, 13038–13042 (DOI: 10.1002/anie.201606293); Angew. Chem. 2016,

128, 13232–13236.

(259) “Asymmetric Cyclization of N-Sulfonyl Alkenyl Amides Catalyzed by

Iridium/Chiral Diene Complexes” Midori Nagamoto, Tomoyuki Yanagi,

Takahiro Nishimura, and Hideki Yorimitsu, Org. Lett. 2016, 18, 4474–4477


(258) “Selective H/D Exchange at Vinyl and Methylidene Groups with D2O Catalyzed

by an Iridium Complex” Miyuki Hatano, Takahiro Nishimura, and Hideki

Yorimitsu, Org. Lett. 2016, 18, 3674–3677 (DOI: 10.1021/acs.orglett.6b01721).

(257) “Pd-NHC-Catalyzed Alkynylation of General Aryl Sulfides with Alkynyl

Grignard Reagents” Alexandre Baralle, Hideki Yorimitsu, and Atsuhiro Osuka,

Chem. Eur. J. 2016, 22, 10768–10772 (DOI: 10.1002/chem.201602315).

(256) “Base-Free Palladium-Catalyzed Borylation of Aryl Chlorides with Diborons”

Yutaro Yamamoto, Hiroshi Matsubara, Hideki Yorimitsu, and Atsuhiro Osuka,

ChemCatChem 2016, 8, 2317–2320 (DOI: 10.1002/cctc.201600456).

(255) “Palladium-Catalyzed ipso-Borylation of Aryl Sulfides with Diborons” M.

Bhanuchandra, Alexandre Baralle, Shinya Otsuka, Keisuke Nogi, Hideki

Yorimitsu, and Atsuhiro Osuka, Org. Lett. 2016, 18, 2966–2969 (DOI:

10.1021/acs.orglett.6b01305).

(254) “Spontaneous Formation of an Air-Stable Radical upon the Direct Fusion of

Diphenylmethane to a Triarylporphyrin” Kenichi Kato, Wonhee Cha, Juwon Oh,

Ko Furukawa, Hideki Yorimitsu, Dongho Kim, and Atsuhiro Osuka, Angew.

Chem. Int. Ed. 2016, 55, 8711–8714 (DOI: 10.1002/anie.201602683); Angew.

Chem. 2016, 128, 8853–8856.

(253) “Porphyrin Analogues of Trityl Cations and Anions” Kenichi Kato, Woojae Kim,

Dongho Kim, Hideki Yorimitsu, and Atsuhiro Osuka, Chem. Eur. J. 2016, 22,

7041–7045 (DOI: 10.1002/chem.201600473).

(252) “Triphenylsilane-fused Porphyrins” Kenichi Kato, Jun Oh Kim, Hideki

Yorimitsu, Dongho Kim, and Atsuhiro Osuka, Chem. Asian J. 2016, 11,

1738–1746 (DOI: 10.1002/asia.201600424).

(251) “Asymmetric Alkylation of N-Sulfonylbenzamides with Vinyl Ethers via C–H

Bond Activation Catalyzed by Hydroxoiridium/Chiral Diene Complexes”

Miyuki Hatano, Yusuke Ebe, Takahiro Nishimura, and Hideki Yorimitsu, J. Am.

Chem. Soc. 2016, 138, 4010–4013 (DOI: 10.1021/jacs.6b01591).

(250) “Regioselective phenylene-fusion reactions of Ni(II)-porphyrins controlled by an

electron-withdrawing meso-substituent” Norihito Fukui, Seung-Kyu Lee,

Kenichi Kato, Daiki Shimizu, Takayuki Tanaka, Sangsu Lee, Hideki Yorimitsu,

Dongho Kim, and Atsuhiro Osuka, Chem. Sci. 2016, 7, 4059–4066 (DOI:

10.1039/C5SC04748J).

(249) “α-Arylation of Ketimines with Aryl Sulfides at a Low Palladium Catalyst

Loading” Ke Gao, Hideki Yorimitsu, and Atsuhiro Osuka, Angew. Chem. Int. Ed.


4649–4652.

(248) “Directly Diphenylborane-fused Porphyrins” Keisuke Fujimoto, Juwon Oh,

Hideki Yorimitsu, Dongho Kim, and Atsuhiro Osuka, Angew. Chem. Int. Ed.


3248–3251.

(247) “Computational Picture of Silyl Transfer from Silylsilatranes to Arylpalladium

Chloride” Jing-Dong Guo, Takahiro Sasamori, Yutaro Yamamoto, Hiroshi

Matsubara, Shigeru Nagase, and Hideki Yorimitsu, Bull. Chem. Soc. Jpn. 2016,

89, 192–194 (DOI: 10.1246/bcsj.20150343).

(246) “Synthesis of Spirocyclic Diarylfluorenes by One-pot Twofold SNAr Reactions

of Diaryl Sulfones with Diarylmethanes” M. Bhanuchandra, Hideki Yorimitsu,

and Atsuhiro Osuka, Org. Lett. 2016, 18, 384–387 (DOI:

10.1021/acs.orglett.5b03384).

(245) “Base-Free Palladium-Catalyzed Cross-Coupling of Arylsulfonium Salts with

Sodium Tetraarylborates” Dhananjayan Vasu, Hideki Yorimitsu, and Atsuhiro

Osuka, Synthesis 2015, 47, 3286–3291 (DOI: 10.1055/s-0035-1560476).

(244) “Palladium-Catalyzed Zinc-Amide-Mediated C–H Arylation of Fluoroarenes

and Heteroarenes with Aryl Sulfides” Shinya Otsuka, Hideki Yorimitsu, and

Atsuhiro Osuka, Chem. Eur. J. 2015, 21, 14703–14707 (DOI:

10.1002/chem.201502101).

(243) “Peripherally Silylated Porphyrins” Kenichi Kato, Keisuke Fujimoto, Hideki

Yorimitsu, and Atsuhiro Osuka, Chem. Eur. J. 2015, 21, 13522–13525 (DOI:

10.1002/chem.201502563).

(242) “Transition-Metal-Free Synthesis of Carbazoles and Indoles by an SNAr-based

“Aromatic Metamorphosis” of Thiaarenes” M. Bhanuchandra, Kei Murakami,

Dhananjayan Vasu, Hideki Yorimitsu, and Atsuhiro Osuka, Angew. Chem. Int.

Ed. 2015, 54, 10234–10238 (DOI: 10.1002/anie.201503671); Angew. Chem.

2015, 127, 10372–10376.

(241) “Porphyrinylboranes Synthesized via Porphyrinyllithiums” Keisuke Fujimoto,

Hideki Yorimitsu, and Atsuhiro Osuka, Chem. Eur. J. 2015, 21, 11311–11314

(DOI: 10.1002/chem.201502215).

(240) “β,β-Diborylated Subporphyrinato Boron(III) Complexes as Useful Synthetic

Precursors” Masaaki Kitano, Yasuhiro Okuda, Eiji Tsurumaki, Takayuki Tanaka,

Hideki Yorimitsu, and Atsuhiro Osuka, Angew. Chem. Int. Ed. 2015, 54,

9275–9279 (DOI: 10.1002/anie.201503530); Angew. Chem. 2015, 127,

9407–9411.

(239) “Palladium-Assisted “Aromatic Metamorphosis” of Dibenzothiophenes into

Triphenylenes” Dhananjayan Vasu, Hideki Yorimitsu, and Atsuhiro Osuka,

Angew. Chem. Int. Ed. 2015, 54, 7162–7166 (DOI: 10.1002/anie.201501992);

Angew. Chem. 2015, 127, 7268–7272. (238) “The Influence of Source Molecule Structure on Low Temperature Growth of

Nitrogen-doped Graphene” Tokio Katoh, Gaku Imamura, Seiji Obata, M.

Bhanuchandra, Graeme Copley, Hideki Yorimitsu, and Koichiro Saiki, Phys.

Chem. Chem. Phys. 2015, 17, 14115–14121 (DOI: 10.1039/c5cp02032h).

(237) “meso,β-Oligohaloporphyrins as Useful Synthetic Intermediates of

Diphenylamine-Fused Porphyrin and meso-meso β-β Doubly Butadiyne-Bridged

Diporphyrin” Norihito Fukui, Hideki Yorimitsu, and Atsuhiro Osuka, Angew.

Chem. Int. Ed. 2015, 54, 6311–6314 (DOI: 10.1002/anie.201501149); Angew.

Chem. 2015, 127, 6409–6412.

(236) “Palladium-Catalyzed Amination of Aryl Sulfides with Aliphatic Amines” Ke

Gao, Hideki Yorimitsu, and Atsuhiro Osuka, Eur. J. Org. Chem. 2015,

2678–2682 (DOI: 10.1002/ejoc.201500226).

(235) “Dimeric 1:2 Adduct of b,b’-Bis(diphenylphosphino)porphyrin with Silver(I) Chloride” Keisuke Fujimoto, Hideki Yorimitsu, and Atsuhiro Osuka, J.

Porphyrins Phthalocyanines 2015, 19, 171–174 (DOI:

10.1142/S1088424615500078).

(234) “Nickel–NHC-Catalyzed Cross-Coupling of 2-Methylsulfanylbenzofurans with

Alkyl Grignard Reagents” Alexandre Baralle, Shinya Otsuka, Vincent Guérin,

Kei Murakami, Hideki Yorimitsu, and Atsuhiro Osuka, Synlett 2015, 26,

327–330 (DOI: 10.1055/s-0034-1378914).

(233) “Activator-Free Palladium-Catalyzed Silylation of Aryl Chlorides with

Silylsilatrane: Smooth Transmetalation Promoted by Acid-Base Interaction

between Chlorine and Silicon” Yutaro Yamamoto, Hiroshi Matsubara, Kei

Murakami, Hideki Yorimitsu, and Atsuhiro Osuka, Chem. Asian J. 2015, 10,

219–224 (DOI: 10.1002/asia.201402595).

(232) “Palladium-Catalyzed [3+2] Annulation of meso-Bromoporphyrins with

Silylacetylenes and Desilylation of 8a-Silyl-7,8-Dehydropurpurin” Norihito

Fukui, Seiji Arai, Hiroshi Shinokubo, Hideki Yorimitsu, and Atsuhiro Osuka,

Heterocycles 2015, 90, 252–260 (DOI: 10.3987/COM-14-S(K)15).

(231) “Two-Step, Practical, and Diversity-Oriented Synthesis of Multisubstituted

Benzofurans from Phenols through Pummerer Annulation Followed by

Cross-coupling” Kei Murakami, Hideki Yorimitsu, and Atsuhiro Osuka, Bull.

Chem. Soc. Jpn. 2014, 87, 1349–1366 (DOI: 10.1246/bcsj.20140241).

(230) “Synthesis of meso-Heteroatom-substituted Subporphyrins” Masaaki Kitano,

Daiki Shimizu, Takayuki Tanaka, Hideki Yorimitsu, and Atsuhiro Osuka, J.

Porphyrins Phthalocyanines 2014, 18, 659–665 (DOI:

10.1142/S1088424614500394).

(229) “Palladium-Catalyzed Cross-Coupling of Unactivated Aryl Sulfides with

Arylzinc Reagents under Mild Conditions” Shinya Otsuka, Daishi Fujino, Kei

Murakami, Hideki Yorimitsu, and Atsuhiro Osuka, Chem. Eur. J. 2014, 20,

13146–13149 (DOI: 10.1002/chem.201404380).

(228) “Palladium-Catalyzed Amination of Aryl Sulfides with Anilines” Tomohiro

Sugahara, Kei Murakami, Hideki Yorimitsu, and Atsuhiro Osuka, Angew. Chem.

Int. Ed. 2014, 53, 9329–9333 (DOI: 10.1002/anie.201404355); Angew. Chem.

2014, 126, 9483–9487.

(227) “Practical, Modular, and General Synthesis of Benzofurans through Extended

Pummerer Annulation/Cross-coupling Strategy” Kei Murakami, Hideki

Yorimitsu, and Atsuhiro Osuka, Angew. Chem. Int. Ed. 2014, 53, 7510–7513

(DOI: 10.1002/anie.201403288); Angew. Chem. 2014, 126, 7640–7643.

(226) “Efficient Synthesis and Versatile Reactivity of Porphyrinyl Grignard Reagents”

Keisuke Fujimoto, Hideki Yorimitsu, and Atsuhiro Osuka, Eur. J. Org. Chem.

2014, 4327–4334 (DOI: 10.1002/ejoc.201402391).

(225) “Regiocontrolled Palladium-Catalyzed Arylative Cyclizations of Alkynols”

Daishi Fujino, Hideki Yorimitsu, and Atsuhiro Osuka, J. Am. Chem. Soc. 2014,

136, 6255–6258 (DOI: 10.1021/ja5029028).

(224) “Synthesis of 7,8-Dehydropurpurin Dimers and Their Conversion to

Conformationally Constrained b-to-b Vinylene-Bridged Porphyrin Dimers”

Norihito Fukui, Hideki Yorimitsu, Jong Min Lim, Dongho Kim, and Atsuhiro

Osuka, Angew. Chem. Int. Ed. 2014, 53, 4395–4398 (DOI:

10.1002/anie.201400632); Angew. Chem. 2014, 126, 4484–4487.

(223) “Control of the Conformational Dynamics of meso-meso Vinylene-bridged

Zn(II) Porphyrin Dimers through Diamine Coordination” Minjung Son, Young

Mo Sung, Sumito Tokuji, Norihito Fukui, Hideki Yorimitsu, Atsuhiro Osuka, and

Dongho Kim, Chem. Commun. 2014, 50, 3078–3080 (DOI:

10.1039/c4cc00126e).

(222) “Excited-State Electronic Couplings in a 1,3-Butadiyne-Bridged Zn(II)Porphyrin

Dimer and Trimer” Sangsu Lee, Heejae Chung, Sumito Tokuji, Hideki Yorimitsu,

Atsuhiro Osuka, and Dongho Kim, Chem. Commun. 2014, 50, 2947–2950 (DOI:

10.1039/c4cc00063c).

(221) “Facile Preparation of β-Haloporphyrins as Useful Precursors of β-Substituted

Porphyrins” Keisuke Fujimoto, Hideki Yorimitsu, and Atsuhiro Osuka, Org. Lett.

2014, 16, 972–975 (DOI: 10.1021/ol4037049).

(220) “Synthesis and Catalytic Activities of Porphyrin-based PCP Pincer Complexes”

Keisuke Fujimoto, Tomoki Yoneda, Hideki Yorimitsu, and Atsuhiro Osuka,

Angew. Chem. Int. Ed. 2014, 53, 1127–1130 (DOI: 10.1002/anie.201308551);

Angew. Chem. 2014, 126, 1145–1148.

(219) “Palladium-Catalyzed Tetraarylation of 5,15-Dialkylporphyrins with Aryl

Bromides” Yutaro Yamamoto, Sumito Tokuji, Takayuki Tanaka, Hideki

Yorimitsu, and Atsuhiro Osuka, Heterocycles 2014, 88, 223–231 (DOI:

10.3987/COM-13-S(S)5).

(218) “Amination of meso-Bromoporphyrins and 9-Haloanthracenes with

Diarylamines Catalyzed by a Pd-PEPPSI Complex” Yuko Suzuki, Norihito

Fukui, Kei Murakami, Hideki Yorimitsu, and Atsuhiro Osuka, Asian J. Org.

Chem. 2013, 2, 1066–1071.

(217) “meso–meso-Linked Subporphyrin Dimer” Masaaki Kitano, Jooyoung Sung,

Kyu Hyung Park, Hideki Yorimitsu, Dongho Kim, and Atsuhiro Osuka, Chem.

Eur. J. 2013, 19, 16523–16527.

(216) “Practical and Scalable Syntheses of Substituted Ketene Dithioacetal

Monoxides” Kei Murakami, Hideki Yorimitsu, and Atsuhiro Osuka, Bull. Chem.

Soc. Jpn. 2013, 86, 1193–1195 (Erratum: Bull. Chem. Soc. Jpn. 2014, 87, 441).

(215) “Oxidative Fusion Reactions of meso-(Diarylamino)porphyrins” Norihito Fukui,

Won-Young Cha, Sangsu Lee, Sumito Tokuji, Dongho Kim, Hideki Yorimitsu,

and Atsuhiro Osuka, Angew. Chem. Int. Ed. 2013, 52, 9728−9732; Angew. Chem.

2013, 125, 9910−9914.

(214) “Demetalation of Metal Porphyrins via Magnesium Porphyrins by Reaction with

Grignard Reagents” Kei Murakami, Yutaro Yamamoto, Hideki Yorimitsu, and

Atsuhiro Osuka, Chem. Eur. J. 2013, 19, 9123–9126.

(213) “TIPS-TTF as a Precursor for Low-Symmetry TTF Derivatives: Steric

Protection Strategy in the Regioselective C-H Modification of TTF” Ryota Ueno,

Daishi Fujino, Hideki Yorimitsu, and Atsuhiro Osuka, Chem. Eur. J. 2013, 19,

7156–7161.

(212) “Copper-Catalyzed Extended Pummerer Reactions of Ketene Dithioacetal

Monoxides with Alkynyl Sulfides and Ynamides with an Accompanying

Oxygen Rearrangement” Kei Murakami, Junichi Imoto, Hiroshi Matsubara,

Suguru Yoshida, Hideki Yorimitsu, and Koichiro Oshima, Chem. Eur. J. 2013, 19,

5625–5630.

(211) “Direct Arylation of Porphyrin with p-Extended Aryl Bromides under

Ligand-Free Fagnou-Hartwig Conditions” Yutaro Yamamoto, Sumito Tokuji,

Takayuki Tanaka, Hideki Yorimitsu, and Atsuhiro Osuka, Asian J. Org. Chem.

2013, 2, 320–324.

(210) “Homoconjugation in Diporphyrins: Excitonic Behaviors in Singly and Doubly

Linked Zn(II)porphyrin Dimers” Min-Chul Yoon, Sangsu Lee, Sumito Tokuji,

Hideki Yorimitsu, Atsuhiro Osuka, and Dongho Kim, Chem. Sci. 2013, 4,

1756–1764.

(209) “Direct Arylation of meso-Formyl Porphyrin” Sumito Tokuji, Hiroyuki Awane,

Hideki Yorimitsu, and Atsuhiro Osuka, Chem. Eur. J. 2013, 19, 64−68.

(208) “Preferential Formation of Cyclic Trimers by Palladium-Catalyzed Oxidative

Coupling of 2,18-Diethynylporphyrins” Sumito Tokuji, Hideki Yorimitsu, and

Atsuhiro Osuka, Angew. Chem. Int. Ed. 2012, 51, 12357–12361; Angew. Chem.

2012, 124, 12523–12527.

(207) “Synthesis of a Library of Fluorescent 2-Aryl-3-trifluoromethylnaphthofurans

from Naphthols by Using a Sequential Pummerer Annulation/Cross-coupling

Strategy and Their Photophysical Properties” Yuuya Ookubo, Atsushi Wakamiya,

Hideki Yorimitsu, and Atsuhiro Osuka, Chem. Eur. J. 2012, 18, 12690–12697.

(206) “Synthesis of 1,2-Disubstituted Cyclopentenes by Palladium-Catalyzed Reaction

of Homopropargyl-Substituted Dicarbonyl Compounds with Organic Halides via

5-endo-dig Cyclization” Daishi Fujino, Hideki Yorimitsu, and Atsuhiro Osuka,

Org. Lett. 2012, 14, 2914–2917.

(205) “Effective meso-Fabrications of Subporphyrins” Masaaki Kitano, Shin-ya

Hayashi, Takayuki Tanaka, Hideki Yorimitsu, Naoki Aratani, and Atsuhiro

Osuka, Angew. Chem. Int. Ed. 2012, 51, 5593–5597; Angew. Chem. 2012, 124,

5691–5695.

(204) “Palladium-Catalyzed Alkynylthiolation of Alkynes with

Triisopropylsilylethynyl Sulfide” Masayuki Iwasaki, Daishi Fujino, Tatsuya

Wada, Azusa Kondoh, Hideki Yorimitsu, and Koichiro Oshima, Chem. Asian J.

2011, 6, 3190–3194.

(203) “Rearrangements of a [36]Octaphyrin Triggered by Nickel(II) Metalation:

Metamorphosis to a Directly meso-β-Linked Diporphyrin” Yasuo Tanaka,

Hirotaka Mori, Taro Koide, Hideki Yorimitsu, Naoki Aratani, and Atsuhiro

Osuka, Angew. Chem. Int. Ed. 2011, 50, 11460–11464; Angew. Chem. 2011, 123,

11662–11666.

(202) “Palladium-Catalyzed β-Selective Direct Arylation of Porphyrins” Yu

Kawamata, Sumito Tokuji, Hideki Yorimitsu, and Atsuhiro Osuka, Angew.

Chem. Int. Ed. 2011, 50, 8867–8870; Angew. Chem. 2011, 123, 9029–9032.

(201) “Straightforward access to aryl-substituted tetrathiafulvalenes by

palladium-catalysed direct C–H arylation and their photophysical and

electrochemical properties” Yukihiro Mitamura, Hideki Yorimitsu, Koichiro

Oshima, and Atsuhiro Osuka, Chem. Sci. 2011, 2, 2017–2021.

(200) “Bis(cyclopentadienyldicarbonyliron) as a Convenient Carbon Monoxide Source

in Palladium-Catalyzed Carbonylative Coupling of Aryl Iodides with Amines,

Alcohols, and Thiols” Ryotaro Nakaya, Hideki Yorimitsu, and Koichiro Oshima,

Chem. Lett. 2011, 40, 904–906.

(199) “(1-Alkynyl)dicarbonylcyclopentadienylirons as Electron-Rich Alkynes in

Organic Synthesis: BF3-Mediated [2+2] Cycloaddition/Ring-Opening Providing

(2-Alkenyl-1-imino)irons” Ryotaro Nakaya, Shigeo Yasuda, Hideki Yorimitsu,

and Koichiro Oshima, Chem. Eur. J. 2011, 17, 8559–8561.

(198) “Synthesis of Alkylidenecyclopropanes by Palladium-Catalyzed Reaction of

Propargyl-Substituted Malonate Esters with Aryl Halides by

Anti-Carbopalladation Pathway” Daishi Fujino, Hideki Yorimitsu, and Koichiro

Oshima, J. Am. Chem. Soc. 2011, 133, 9682–9685.

(197) “New Synthetic Strategy for Diporphyrins: Pinacol Coupling–Rearrangement”

Sumito Tokuji, Chihiro Maeda, Hideki Yorimitsu, and Atsuhiro Osuka, Chem.

Eur. J. 2011, 17, 7154–7157. (196) “Palladium(II)-Triggered Rearrangement of Heptaphyrins to N-Confused

Porphyrins” Tomoki Yoneda, Shohei Saito, Hideki Yorimitsu, and Atsuhiro

Osuka, Angew. Chem. Int. Ed. 2011, 50, 3475−3478; Angew. Chem. 2011, 123,

3537−3540.

(195) “Allyl-, Allenyl-, and Propargyl-Transfer Reactions through Cleavage of C–C

Bonds Catalyzed by an N-Heterocyclic Carbene/Copper Complex: Synthesis of

Multisubstituted Pyrroles” Masahiro Sai, Hideki Yorimitsu, and Koichiro

Oshima, Angew. Chem. Int. Ed. 2011, 50, 3294–3298; Angew. Chem. 2011, 123,

3352–3356.

(194) “Cobalt-Catalyzed Addition of Styrylboronic Acids to 2-Vinylpyridine

Derivatives” Tsuneyuki Kobayashi, Hideki Yorimitsu, and Koichiro Oshima,

Chem. Asian J. 2011, 6, 669–673.

(193) “Intermolecular Reductive Radical Addition to

2-(2,2,2-Trifluoroethylidene)-1,3-dithiane 1-Oxide: Experimental and

Theoretical Studies” Ryota Nakayama, Hiroshi Matsubara, Daishi Fujino,

Takayuki Kobatake, Suguru Yoshida, Hideki Yorimitsu, and Koichiro Oshima,

Org. Lett. 2010, 12, 5748–5751.

(192) “Palladium-Catalyzed Addition of Silyl-Substituted Chloroalkynes to Terminal

Alkynes” Tatsuya Wada, Masayuki Iwasaki, Azusa Kondoh, Hideki Yorimitsu,

and Koichiro Oshima, Chem. Eur. J. 2010, 16, 10671–10674.

(191) “Synthesis of 3-Trifluoromethylbenzo[b]furans from Phenols via Direct Ortho

Functionalization by Extended Pummerer Reaction” Takayuki Kobatake, Daishi

Fujino, Suguru Yoshida, Hideki Yorimitsu, and Koichiro Oshima, J. Am. Chem.

Soc. 2010, 132, 11838–11840.

(190) “Palladium-Catalyzed Intramolecular Carboacetoxylation of

4-Pentenyl-Substituted Malonate Esters with Iodobenzene Diacetate” Daishi

Fujino, Hideki Yorimitsu, and Koichiro Oshima, Chem. Asian J. 2010, 5,

1758–1760.

(189) “Silver-Catalyzed Coupling Reactions of Alkyl Halides with Indenyllithiums”

Hidenori Someya, Hideki Yorimitsu, and Koichiro Oshima, Tetrahedron 2010,

66, 5993−5999.

(188) “Cobalt-Catalyzed Benzylzincation of Alkynes” Kei Murakami, Hideki

Yorimitsu, and Koichiro Oshima, Chem. Eur. J. 2010, 16, 7688−7691.

(187) “Rhodium-Catalyzed Arylzincation of Terminal Allenes Providing Allylzinc

Reagents and Its Application to Versatile Three-component Coupling Reaction”

Yuji Yoshida, Kei Murakami, Hideki Yorimitsu, and Koichiro Oshima, J. Am.

Chem. Soc. 2010, 132, 8878–8879.

(186) “Palladium-Catalyzed Allylation of Aryl Halides with Homoallyl Alcohols

Bearing a Trisubstituted Double Bond: Application to Chirality Transfer from

Hydroxylated Carbon to Benzylic One” Ryota Wakabayashi, Daishi Fujino,

Sayuri Hayashi, Hideki Yorimitsu, and Koichiro Oshima, J. Org. Chem. 2010, 75,

4337–4343.

(185) “Silver-Catalyzed Benzylation and Allylation of Tertiary Alkyl Bromides with

Organozinc Reagents” Yukihiro Mitamura, Yoshihiro Asada, Kei Murakami,

Hidenori Someya, Hideki Yorimitsu, and Koichiro Oshima, Chem. Asian J. 2010,

5, 1487−1493.

(184) “Arylation of Styrenes with Aryliron Complexes [CpFe(CO)2Ar]” Shigeo

Yasuda, Hideki Yorimitsu, and Koichiro Oshima, Organometallics 2010, 29,

2634−2636.

(183) “Nickel-Catalyzed Arylative Ring-Opening of 3-Methylenecycloalkane-1,1-

dicarboxylates” Yuto Sumida, Hideki Yorimitsu and Koichiro Oshima, Org. Lett.

2010, 12, 2254–2257.

(182) “Synthesis of 2-Indolylphosphines by Palladium-Catalyzed Annulation of

1-Alkynylphosphine Sulfides with 2-Iodoanilines” Azusa Kondoh, Hideki

Yorimitsu, and Koichiro Oshima, Org. Lett. 2010, 12, 1476–1479.

(181) “Reaction of 2-(2,2,2-Trifluoroethylidene)-1,3-dithiane 1-Oxide with Ketones

under Pummerer Conditions and Its Application to the Synthesis of

Trifluoromethyl-Substituted Five-Membered Heteroaromatics” Takayuki

Kobatake, Suguru Yoshida, Hideki Yorimitsu, and Koichiro Oshima, Angew.


(180) “Radical Additions of Arenethiols to Ynamides for the Selective Synthesis of

N-[(Z)-2-(Arylsulfanyl)-1-alkenyl]amides” Akinori Sato, Hideki Yorimitsu, and

Koichiro Oshima, Bull. Korean Chem. Soc. 2010, 31, 570–576.

(179) “Silver-Catalyzed Diallylation and Dibenzylation of gem-Dibromoalkanes with

Grignard Reagents” Yukihiro Mitamura, Hidenori Someya, Hideki Yorimitsu,

and Koichiro Oshima, Synlett 2010, 309−312.

(178) “Synthesis of Functionalized Aryliron Complexes [CpFe(CO)2Ar] by

Copper-Mediated Transmetalation between [CpFe(CO)2I] and Aryltin Reagents”

Shigeo Yasuda, Hideki Yorimitsu, and Koichiro Oshima, Organometallics 2010,

29, 273−274.

(177) “Tin-Hydride-Mediated Radical Addition of Alkyl Halides to

2-Methylene-1,3-Dithiane Monoxide as a Ketene Equivalent” Suguru Yoshida,

Hideki Yorimitsu, and Koichiro Oshima, Heterocycles 2010, 80, 259–267.

(176) “Radical Addition of Polyhaloalkanes to 2-Ethynyl-4,4,5,5-tetramethyl-1,3,2-

dioxaborolane” Tatsuya Wada, Yuto Sumida, Azusa Kondoh, Hideki Yorimitsu,

and Koichiro Oshima, Bull. Chem. Soc. Jpn. 2009, 82, 1433−1435.

(175) “Palladium-Catalyzed Preparation of Silyl Enolates from α,β-Unsaturated

Ketones or Cyclopropyl Ketones with Hydrosilanes” Yuto Sumida, Hideki

Yorimitsu, and Koichiro Oshima, J. Org. Chem. 2009, 74, 7986–7989.

(174) “Palladium-Catalysed Arylative Cyclisation of N-Allylacetamides with Aryl

Halides Yielding Benzyl-Substituted Oxazolidines” Daishi Fujino, Sayuri

Hayashi, Hideki Yorimitsu, and Koichiro Oshima, Chem. Commun. 2009,

5754–5756.

(173) “Synthesis of Aziridines by Palladium-Catalyzed Reactions of Allylamines with

Aryl or Alkenyl Halides: Evidence of Intramolecular syn-Carboamination

Pathway” Sayuri Hayashi, Hideki Yorimitsu, and Koichiro Oshima, Angew.


(172) “Copper-Catalyzed Allylation of Alkyl Halides with Allylic Grignard Reagents”

Masahiro Sai, Hideki Yorimitsu, and Koichiro Oshima, Bull. Chem. Soc. Jpn.

2009, 82, 1194–1196.

(171) “Synthesis of Aryliron Complexes [CpFe(CO)2Ar] by Palladium-Catalyzed

Reactions of [CpFe(CO)2I] with Arylzinc, -Boron, or -Indium Reagents” Shigeo

Yasuda, Yoshihiro Asada, Hideki Yorimitsu, and Koichiro Oshima, Materials

2009, 2, 978–991.

(170) “Use of Aryliron Complexes [CpFe(CO)2Ar] as Arylcarbonyl Cation

Equivalents in the Reactions with Organolithium Reagents to Yield Ketones”

Shigeo Yasuda, Hideki Yorimitsu, and Koichiro Oshima, Organometallics 2009,

28, 4872−4875.

(169) “Synthesis of (1-Alkynyl)dicarbonylcyclopentadienyliron Complexes by

Palladium-catalyzed Sonogashira-type Carbon–Iron Bond Formation” Ryotaro

Nakaya, Shigeo Yasuda, Hideki Yorimitsu, and Koichiro Oshima, Tetrahedron

Lett. 2009, 50, 5274−5276.

(168) “Copper-Catalyzed Arylation of Chlorosilanes with Grignard Reagents” Eiji

Morita, Kei Murakami, Masayuki Iwasaki, Koji Hirano, Hideki Yorimitsu, and

Koichiro Oshima, Bull. Chem. Soc. Jpn. 2009, 82, 1012−1014.

(167) “Synthesis of (2-Arylethylidene)cyclobutanes by Palladium-Catalyzed Reactions

of Aryl Halides with Homoallyl Alcohols Bearing a Trimethylene Group at the

Allylic Position” Masayuki Iwasaki, Hideki Yorimitsu, and Koichiro Oshima,

Synlett 2009, 2177−2179.

(166) “Palladium-Catalyzed (N-Oxido-2-pyridinyl)methyl Transfer from

2-(2-Hydroxyalkyl)pyridine N-Oxide to Aryl Halides via β-Carbon Elimination”

Takafumi Suehiro, Takashi Niwa, Hideki Yorimitsu, and Koichiro Oshima,

Chem. Asian J. 2009, 4, 1217−1220.

(165) “Cobalt-Catalyzed Isomerization of 1-Alkenes to (E)-2-Alkenes with

Dimethylphenylsilylmethylmagnesium Chloride and Its Application to the

Stereoselective Synthesis of (E)-Alkenylsilanes” Tsuneyuki Kobayashi, Hideki

Yorimitsu, and Koichiro Oshima, Chem. Asian J. 2009, 4, 1078–1083.

(164) “Palladium-catalyzed Mizoroki-Heck Reactions of 2-Methylene-1,3-dithiane

1-Oxide with Aryl Iodides” Eiji Morita, Masayuki Iwasaki, Suguru Yoshida,

Hideki Yorimitsu, and Koichiro Oshima, Chem. Lett. 2009, 38, 624–625.

(163) “Cobalt-Catalyzed Arylzincation of Alkynes” Kei Murakami, Hideki Yorimitsu,

and Koichiro Oshima, Org. Lett. 2009, 11, 2373–2375.

(162) “Carbon-Carbon Bond Formations at the Benzylic Positions of

N-Benzylxanthone Imines and N-Benzyldi-1-naphthyl Ketone Imine” Takashi

Niwa, Takafumi Suehiro, Hideki Yorimitsu, and Koichiro Oshima, Tetrahedron

2009, 65, 5125–5131.

(161) “Silver-Catalyzed Cross-Coupling Reactions of Alkyl Bromides with Alkyl or

Aryl Grignard Reagents” Hidenori Someya, Hideki Yorimitsu, and Koichiro

Oshima, Tetrahedron Lett. 2009, 50, 3270–3272.

(160) “2-(2,2,2-Trifluoroethylidene)-1,3-dithiane Monoxide as a

Trifluoromethylketene Equivalent” Suguru Yoshida, Hideki Yorimitsu, and

Koichiro Oshima, Org. Lett. 2009, 11, 2185–2188.

(159) “Atom-transfer Radical Addition of α-Iodo Esters to 1-Alkynyl Sulfides” Junichi

Imoto, Akinori Sato, Hideki Yorimitsu, and Koichiro Oshima, Chem. Lett. 2009,

38, 462–463.

(158) “Nickel-Catalyzed Borylation of Cyclopropyl Ketones with

Bis(pinacolato)diboron to Synthesize 4-Oxoalkylboronates” Yuto Sumida,

Hideki Yorimitsu, and Koichiro Oshima, J. Org. Chem. 2009, 74, 3196–3198.

(157) “Palladium-catalyzed 1-Methylene-2-propenylation Reactions of Aryl Bromides

with 3,4-Alkadien-1-ols via Carbon-Carbon Bond Cleavage for the Synthesis of

2-Aryl-1,3-butadiene Derivatives” Junichi Imoto, Sayuri Hayashi, Koji Hirano,

Hideki Yorimitsu, and Koichiro Oshima, Bull. Chem. Soc. Jpn. 2009, 82,

393−400.

(156) “Synthesis of Prenylarenes and Related (Multisubstituted Allyl)arenes from Aryl

Halides and Homoallyl Alcohols via Palladium-Catalyzed Retro-Allylation”

Masayuki Iwasaki, Hideki Yorimitsu, and Koichiro Oshima, Bull. Chem. Soc.

Jpn. 2009, 82, 249−253.

(155) “Synthesis of Epoxides by Palladium-Catalyzed Reactions of Tertiary Allyl

Alcohols with Aryl or Alkenyl Halides” Sayuri Hayashi, Hideki Yorimitsu, and

Koichiro Oshima, J. Am. Chem. Soc. 2009, 131, 2052−2053.

(154) “Palladium-Catalyzed Benzylic Direct Arylation of Benzyl Sulfones with Aryl

Halides” Takashi Niwa, Hideki Yorimitsu, and Koichiro Oshima, Tetrahedron

2009, 65, 1971–1976.

(153) “Radical Addition of Alkyl Halides to 2-Methylene-1,3-dithiane Monoxide as a

Ketene Equivalent” Suguru Yoshida, Hideki Yorimitsu, and Koichiro Oshima,

Chem. Lett. 2009, 38, 248–249.

(152) “Zinc-Catalyzed Nucleophilic Substitution Reaction of Chlorosilanes with

Organomagnesium Reagents” Kei Murakami, Hideki Yorimitsu, and Koichiro

Oshima, J. Org. Chem. 2009, 74, 1415–1417.

(151) “Regio- and Stereoselective Synthesis of

(E)-1-Aryl-1-thio-2-thiophosphinylethene Derivatives via a Radical Process”

Akinori Sato, Hideki Yorimitsu, and Koichiro Oshima, Tetrahedron 2009, 65,

1553–1558.

(150) “Regio- and Stereoselective Radical Additions of Thiols to Ynamides” Akinori

Sato, Hideki Yorimitsu, and Koichiro Oshima, Synlett 2009, 28–31.

(149) “Synthesis of Functionalized Aryliron Complexes by Palladium-Catalyzed

Transmetalation between [CpFe(CO)2I] and Arylzinc or Arylboron Reagents”

Yoshihiro Asada, Shigeo Yasuda, Hideki Yorimitsu, and Koichiro Oshima,

Organometallics 2008, 27, 6050–6052.

(148) “Cobalt-Catalyzed Cross-Coupling Reactions of Aryl Bromides with Alkyl

Grignard Reagents” Hiroyuki Hamaguchi, Minoru Uemura, Hiroto Yasui,

Hideki Yorimitsu, and Koichiro Oshima, Chem. Lett. 2008, 37, 1178–1179.

(147) “Palladium-Catalyzed Benzylic Arylation of N-Benzylxanthone Imine” Takashi

Niwa, Hideki Yorimitsu, and Koichiro Oshima, Org. Lett. 2008, 10, 4689–4691.

(146) “Nickel-Catalyzed Borylative Ring Opening Reaction of Vinylcyclopropanes

with Bis(pinacolato)diboron Yielding Allylic Boronates” Yuto Sumida, Hideki


(145) “2-Alkylidene-1,3-Dithiane Monoxides as Activated Alkenes in

Rhodium-Catalyzed Addition Reaction of Arylboronic Acids” Suguru Yoshida,

Hideki Yorimitsu, and Koichiro Oshima, Heterocycles 2008, 76, 679−688.

(144) “Synthesis of Bulky Arylphosphanes by Rhodium-Catalyzed Formal [2 + 2 + 2]

Cycloaddition Reaction and Their Use as Ligands” Takayuki Kobatake, Azusa

Kondoh, Suguru Yoshida, Hideki Yorimitsu, and Koichiro Oshima, Chem. Asian

J. 2008, 3, 1613−1619.

(143) “Cobalt-Catalyzed Regioselective Dehydrohalogenation of Alkyl Halides with

Dimethylphenylsilylmethylmagnesium Chloride” Tsuneyuki Kobayashi,

Hirohisa Ohmiya, Hideki Yorimitsu, and Koichiro Oshima, J. Am. Chem. Soc.

2008, 130, 11276–11277.

(142) “Synthesis of Aryliron Complexes by Palladium-Catalyzed Transmetalation

between [CpFe(CO)2I] and Aryl Grignard Reagents and Their Chemistry

Directed toward Organic Synthesis” Shigeo Yasuda, Hideki Yorimitsu, and

Koichiro Oshima, Organometallics 2008, 27, 4025–4027.

(141) “Nickel-Catalyzed Cross-Coupling Reactions of Alkyl Aryl Sulfides and

Alkenyl Alkyl Sulfides with Alkyl Grignard Reagents by Using

(Z)-3,3-Dimethyl-1,2-bis(diphenylphosphino)but-1-ene as Ligand” Shigenari

Kanemura, Azusa Kondoh, Hideki Yorimitsu, and Koichiro Oshima, Synthesis

2008, 2659−2664.

(140) “Silver-Catalyzed Transmetalation between Chlorosilanes and Aryl and Alkenyl

Grignard Reagents for Synthesis of Tetraorganosilanes” Kei Murakami, Koji

Hirano, Hideki Yorimitsu, and Koichiro Oshima, Angew. Chem. Int. Ed. 2008, 47,

5833–5835; Angew. Chem. 2008, 120, 5917–5919.

(139) “Regio- and Stereoselective Hydroamidation of 1-Alkynylphosphine Sulfides

Catalyzed by Cesium Base” Azusa Kondoh, Hideki Yorimitsu, and Koichiro

Oshima, Org. Lett. 2008, 10, 3093–3095.

(138) “Nickel-Catalyzed Carboxylation of Organozinc Reagents with CO2” Hidenori

Ochiai, Minsul Jang, Koji Hirano, Hideki Yorimitsu, and Koichiro Oshima, Org.

Lett. 2008, 10, 2681–2683.

(137) “Extended Pummerer Reaction of Arylketene Dithioacetal Monoxides with

Aromatic Compounds by Means of Trifluoromethanesulfonic Anhydride”

Suguru Yoshida, Hideki Yorimitsu, and Koichiro Oshima, Chem. Lett. 2008, 37,

786–787.

(136) “Copper-Catalyzed Reaction of Alkyl Halides with Cyclopentadienylmagnesium

Reagent” Masahiro Sai, Hidenori Someya, Hideki Yorimitsu, and Koichiro

Oshima, Org. Lett. 2008, 10, 2545–2547.

(135) “Palladium-Catalyzed Formal Cycloaddition of Silacyclobutanes with Enones:

Synthesis of Eight-Membered Cyclic Silyl Enolates” Koji Hirano, Hideki


(134) “Synthesis of Arylallenes by Palladium-Catalyzed Retro-Propargylation of

Homopropargyl Alcohols” Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, and

Koichiro Oshima, J. Am. Chem. Soc. 2008, 130, 5048–5049.

(133) “Nickel-Catalyzed Allylation of Allyl Carbonates with Homoallyl Alcohols via

Retro-Allylation Providing 1,5-Hexadienes” Yuto Sumida, Sayuri Hayashi, Koji

Hirano, Hideki Yorimitsu, and Koichiro Oshima, Org. Lett. 2008, 10,

1629–1632.

(132) “Regio- and Stereoselective Additions of Diphenyldithiophosphinic Acid to

N-(1-Alkynyl)amides and 1-Alkynyl Sulfides” Shigenari Kanemura, Azusa

Kondoh, Hiroto Yasui, Hideki Yorimitsu, and Koichiro Oshima, Bull. Chem. Soc.

Jpn. 2008, 81, 506−514.

(131) “Rhodium-Catalyzed Reaction of 1-Alkynylphosphines with Water Yielding

(E)-1-Alkenylphosphine Oxides” Azusa Kondoh, Hideki Yorimitsu, and

Koichiro Oshima, Bull. Chem. Soc. Jpn. 2008, 81, 502−505.

(130) “Intermolecular Radical Addition of Alkylthio- and Arylthiodiphenylphosphines

to Terminal Alkynes” Tatsuya Wada, Azusa Kondoh, Hideki Yorimitsu, and


(129) “Generation of Rhodium Enolates via Retro-aldol Reaction and Its Application

to Regioselective Aldol Reaction” Kei Murakami, Hirohisa Ohmiya, Hideki

Yorimitsu, and Koichiro Oshima, Tetrahedron Lett. 2008, 49, 2388–2390.

(128) “Silylcupration and Copper-Catalyzed Carbomagnesiation of Ynamides:

Application to Aza-Claisen Rearrangement” Hiroto Yasui, Hideki Yorimitsu, and

Koichiro Oshima, Bull. Chem. Soc. Jpn. 2008, 81, 373–379.

(127) “Silver-Catalyzed Benzylation and Allylation Reactions of Tertiary and

Secondary Alkyl Halides with Grignard Reagents” Hidenori Someya, Hirohisa

Ohmiya, Hideki Yorimitsu, and Koichiro Oshima, Org. Lett. 2008, 10, 969–971.

(126) “Vanadium-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Aryl

Grignard Reagents” Shigeo Yasuda, Hideki Yorimitsu, and Koichiro Oshima,

Bull. Chem. Soc. Jpn. 2008, 81, 287–290.

(125) “Synthetic Application of Intramolecular Cyanoboration on the Basis of

Removal and Conversion of a Tethering Group by Palladium-Catalyzed

Retro-Allylation” Toshimichi Ohmura, Tomotsugu Awano, Michinori Suginome,

Hideki Yorimitsu, and Koichiro Oshima, Synlett 2008, 423–427.

(124) “Cp*Li as a Base: Application to Palladium-Catalyzed Cross-Coupling Reaction

of Aryl-X or Alkenyl-X (X = I, Br, OTf, ONf) with Terminal Acetylenes”

Minoru Uemura, Hideki Yorimitsu, and Koichiro Oshima, Tetrahedron 2008, 64,

1829–1833.

(123) “Rhodium-Catalyzed Allylation of Aldehydes with Homoallyl Alcohols via

Retro-Allylation Followed by Isomerization into Saturated Ketones with

Conventional or Microwave Heating” Yuto Sumida, Yuko Takada, Sayuri

Hayashi, Koji Hirano, Hideki Yorimitsu, and Koichiro Oshima, Chem. Asian J.

2008, 3, 119–125.

(122) “Regio- and Stereoselective Hydrothiolation Reactions of Ynamides with

Diphenyldithiophosphinic Acid: Straightforward Synthesis of Ketene N,S-Acetal

Derivatives” Hiroto Yasui, Hideki Yorimitsu, and Koichiro Oshima, Chem. Lett.

2008, 37, 40–41.

(121) “Synthesis of β,γ–Unsaturated Ketones from Acid Chlorides through

Carbon–Pentamethylcyclopentadienyl Bond Formation and Cleavage” Minoru

Uemura, Masayuki Iwasaki, Eiji Morita, Hideki Yorimitsu, and Koichiro

Oshima, Bull. Chem. Soc. Jpn. 2007, 80, 2400–2405.

(120) “Synthesis of Benzo[b]thiophenes by Cyclization of Arylketene Dithioacetal

Monoxides under Pummerer-like Conditions” Suguru Yoshida, Hideki Yorimitsu,


(119) “O-Alkyl S-3,3-Dimethyl-2-oxobutyl Dithiocarbonates as Versatile Sulfur Transfer Agents in Radical Csp3–H Functionalization” Akinori Sato, Hideki

Yorimitsu, and Koichiro Oshima, Chem. Asian J. 2007, 2, 1568–1573.

(118) “Nickel-Catalyzed β-Boration of α,β-Unsaturated Esters and Amides with

Bis(pinacolato)diboron” Koji Hirano, Hideki Yorimitsu, and Koichiro Oshima,

Org. Lett. 2007, 9, 5031–5033.

(117) “Efficient Aerobic Oxidation of Phosphines, Phosphites, and Sulfides by Using

Trialkylborane” Kosuke Motoshima, Akinori Sato, Hideki Yorimitsu, and


(116) “Microwave-Assisted Palladium-Catalyzed Direct Arylation of 1,4-Disubstituted

1,2,3-Triazoles with Aryl Chlorides” Masayuki Iwasaki, Hideki Yorimitsu, and

Koichiro Oshima, Chem. Asian J. 2007, 2, 1430–1435.

(115) “Synthesis of (Arylalkenyl)silanes by Palladium-Catalyzed Regiospecific and

Stereoselective Allyl Transfer from Silyl-Substituted Homoallyl Alcohols to

Aryl Halides” Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, and Koichiro


(114) “Cobalt-Catalyzed Sequential Cyclization/Cross-Coupling Reactions of

6-Halo-1-hexene Derivatives with Grignard Reagents and Their Application to

the Synthesis of 1,3-Diols” Hidenori Someya, Hirohisa Ohmiya, Hideki

Yorimitsu, and Koichiro Oshima, Tetrahedron 2007, 63, 8609–8618.

(113) “Nickel-catalyzed Carbometalation Reactions of

[2-(1-Propynyl)phenyl]methanol with 1-Alkenylmagnesium Reagents” Kei

Murakami, Hirohisa Ohmiya, Hideki Yorimitsu, and Koichiro Oshima, Chem.

Lett. 2007, 36, 1066–1067.

(112) “Zirconocene-Catalyzed Alkylative Dimerization of 2-Methylene-1,3-dithiane

via a Single Electron Transfer Process to Provide Symmetrical

vic-Bis(dithiane)s” Suguru Yoshida, Hideki Yorimitsu, and Koichiro Oshima, J.

Organomet. Chem. 2007, 692, 3110–3114.

(111) “Rhodium-Catalyzed Addition of Arylboronic Acids to

2-Methylene-1,3-dithiane Monoxide” Suguru Yoshida, Hideki Yorimitsu, and

Koichiro Oshima, Synlett 2007, 1622–1624.

(110) “Palladium-Catalyzed Direct Arylation of Aryl(azaaryl)methanes with Aryl

Halides Providing Triarylmethanes” Takashi Niwa, Hideki Yorimitsu, and


(109) “Synthesis of Bulky Phosphines by Rhodium-Catalyzed Formal [2 + 2 + 2]

Cycloaddition Reactions of Tethered Diynes with 1-Alkynylphosphine Sulfides”

Azusa Kondoh, Hideki Yorimitsu, and Koichiro Oshima, J. Am. Chem. Soc. 2007,

129, 6996–6997.

(108) “Plugging and Unplugging Holes of Single-Wall Carbon Nanohorns” Ryota

Yuge, Masako Yudasaka, Jin Miyawaki, Yoshimi Kubo, Hiroyuki Isobe, Hideki

Yorimitsu, Eiichi Nakamura, Sumio Iijima, J. Chem. Phys. C 2007, 111,

7348–7351.

(107) “Nickel-Catalyzed Regio- and Stereoselective Silylation of Terminal Alkenes

with Silacyclobutanes: Facile Access to Vinylsilanes from Alkenes” Koji Hirano,

Hideki Yorimitsu, and Koichiro Oshima, J. Am. Chem. Soc. 2007, 129,

6094–6095.

(106) “Rhodium-Catalyzed Allyl Transfer from Homoallyl Alcohols to Acrylate

Esters via Retro-allylation” Minsul Jang, Sayuri Hayashi, Koji Hirano, Hideki


(105) “Microwave-Assisted Palladium-Catalyzed Allylation of Aryl Halides with

Homoallyl Alcohols via Retro-Allylation” Masayuki Iwasaki, Sayuri Hayashi,

Koji Hirano, Hideki Yorimitsu, and Koichiro Oshima, Tetrahedron 2007, 63,

5200–5203.

(104) “Carbocupration of 1-Alkynylphosphines Followed by Trapping with

Electrophiles” Shigenari Kanemura, Azusa Kondoh, Hideki Yorimitsu, and


(103) “Chromium-Catalyzed Arylmagnesiation of Alkynes” Kei Murakami, Hirohisa

Ohmiya, Hideki Yorimitsu, and Koichiro Oshima, Org. Lett. 2007, 9,

1569–1571.

(102) “N-Heterocyclic Carbene Ligands in Cobalt-Catalyzed Sequential

Cyclization/Cross-Coupling Reactions of 6-Halo-1-hexene Derivatives with

Grignard Reagents” Hidenori Someya, Hirohisa Ohmiya, Hideki Yorimitsu, and


(101) “Nickel-Catalyzed 1,4-Addition of Trialkylboranes to α,β-Unsaturated Esters:

Dramatic Enhancement by Addition of Methanol” Koji Hirano, Hideki


(100) “Pd(OAc)2/P(cC6H11)3-Catalyzed Allylation of Aryl Halides with Homoallyl

Alcohols via Retro-Allylation” Masayuki Iwasaki, Sayuri Hayashi, Koji Hirano,


4463–4469.

(99) “Copper-catalyzed anti-Hydrophosphination Reaction of 1-Alkynylphosphines

with Diphenylphosphine Providing (Z)-1,2-Diphosphino-1-alkenes” Azusa

Kondoh, Hideki Yorimitsu, and Koichiro Oshima, J. Am. Chem. Soc. 2007, 129,

4099–4104.

(98) “Palladium-Catalyzed anti-Hydrothiolation of 1-Alkynylphosphines” Azusa

Kondoh, Hideki Yorimitsu, and Koichiro Oshima, Org. Lett. 2007, 9,

1383–1385.

(97) “Palladium-Catalyzed 2-Pyridylmethyl Transfer Reactions from

2-(2-Pyridyl)ethanol Derivatives to Organic Halides Involving

Chelation-Assisted Cleavage of Unstrained Csp3-Csp3 Bonds” Takashi Niwa,

Hideki Yorimitsu, and Koichiro Oshima, Angew. Chem. Int. Ed. 2007, 46,

2643–2645; Angew. Chem. 2007, 119, 2697–2699.

(96) “Synthesis and Bio-imaging of Positron-emitting 15O-Labeled

2-Deoxy-D-glucose of Two-minute Half-life” Hideki Yorimitsu, Yoshihiro

Murakami, Hiroyuki Takamatsu, Shintaro Nishimura, and Eiichi Nakamura,

Chem. Asian J. 2007, 2, 57–65.

(95) “Transformations of N-Allyl-N-(phenylethynyl)arenesulfonamides into

2,2-Disubstituted 4-Pentenenitriles through Aza-Claisen Rearrangement That

Follows Carbomagnesiation” Hiroto Yasui, Hideki Yorimitsu, and Koichiro

Oshima, Chem. Lett. 2007, 36, 32–33.

(94) “Synthesis of β,γ-Unsaturated Ketones by Allylation of

Pentamethylcyclopentadienyl Ketones Followed by Removal of

Pentamethylcyclopentadiene” Masayuki Iwasaki, Eiji Morita, Minoru Uemura,


(93) “Gallium-Mediated Allyl Transfer from Bulky Homoallyl Alcohol to Aldehydes

or Alkynes: Control of Dynamic σ-Allylgalliums Based on Retro-allylation

Reaction” Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, and Koichiro Oshima,

J. Organomet. Chem. 2007, 692, 505–513.

(92) “Synthesis of Cp*CH2PPh2 and Its Use as a Ligand for Nickel-Catalysed

Cross-Coupling Reaction of Alkyl Halides with Aryl Grignard Reagents”

Minoru Uemura, Hideki Yorimitsu, and Koichiro Oshima, Chem. Commun. 2006,

4726–4728.

(91) “A New Approach to 4-Aryl-1,3-butanediols by Cobalt-Catalyzed Sequential

Radical Cyclization/Arylation Reaction of Silicon-Tethered 6-Iodo-1-hexene

Derivatives” Hidenori Someya, Azusa Kondoh, Akinori Sato, Hirohisa Ohmiya,


(90) “Alkylation of Aldehydes with Trialkylboranes in Water” Koji Hirano, Hideki

Yorimitsu, and Koichiro Oshima, Adv. Synth. Catal. 2006, 348, 1543–1546.

(89) “Cobalt-catalyzed Allylzincations of Internal Alkynes” Hiroto Yasui, Toshihiro

Nishikawa, Hideki Yorimitsu, and Koichiro Oshima, Bull. Chem. Soc. Jpn. 2006,

79, 1271–1274.

(88) “Isomerization of Alkynes to 1,3-Dienes under Rhodium or Palladium

Catalysis” Hiroto Yasui, Hideki Yorimitsu, and Koichiro Oshima, Synlett 2006,

1783–1785.

(87) “Cobalt-mediated Cross-coupling Reactions of Primary and Secondary Alkyl

Halides with 1-Trimethylsilylethenyl- and 2-Trimethylsilylethynylmagnesium

Reagents” Hirohisa Ohmiya, Hideki Yorimitsu, and Koichiro Oshima, Org. Lett.

2006, 8, 3093–3096.

(86) “Cobalt-Catalyzed Trimethylsilylmethylmagnesium-Promoted Radical

Alkenylation of Alkyl Halides: A Complement to the Heck Reaction” Walter

Affo, Hirohisa Ohmiya, Takuma Fujioka, Yousuke Ikeda, Tomoaki Nakamura,

Hideki Yorimitsu, Koichiro Oshima, Yuki Imamura, Tsutomu Mizuta, Katsuhiko

Miyoshi, J. Am. Chem. Soc. 2006, 128, 8068–8077.

(85) “Rhodium-Catalyzed Allyl Transfer from Homoallyl Alcohols to Aldehydes via

Retro-allylation Followed by Isomerization into Ketones” Yuko Takada, Sayuri

Hayashi, Koji Hirano, Hideki Yorimitsu, and Koichiro Oshima, Org. Lett. 2006,

8, 2515–2517.

(84) “In Vivo Magnetic Resonance Imaging of Single-Walled Carbon Nanohorns by

Labeling with Magnetite Nanoparticles” Jin Miyawaki, Masako Yudasaka,

Hideto Imai, Hideki Yorimitsu, Hiroyuki Isobe, Eiichi Nakamura, and Sumio

Iijima, Adv. Mater. 2006, 18, 1010–1014.

(83) “Radical Phosphination of Organic Halides and Alkyl

Imidazole-1-carbothioates” Akinori Sato, Hideki Yorimitsu, and Koichiro


(82) “Three-step α-Acylation of (E)-Cinnamate Esters with Inversion of

Stereochemistry through Formation and Cleavage of

Carbon–Pentamethylcyclopentadienyl Bonds” Minoru Uemura, Hideki

Yorimitsu, and Koichiro Oshima, Chem. Lett. 2006, 35, 408–409.

(81) “Pentamethylcyclopentadienide in Organic Synthesis: Nucleophilic Addition of

Lithium Pentamethylcyclopentadienide to Carbonyl Compounds and

Carbon–Carbon Bond Cleavage of the Adducts Yielding the Parent Carbonyl

Compounds” Minoru Uemura, Kazunari Yagi, Masayuki Iwasaki, Kenichi

Nomura, Hideki Yorimitsu, and Koichiro Oshima, Tetrahedron 2006, 62,

3523–3535.

(80) “Synthesis of Ultrafine Gd2O3 Nanoparticles Inside Single-Wall Carbon

Nanohorns” Jin Miyawaki, Masako Yudasaka, Hideto Imai, Hideki Yorimitsu,

Hiroyuki Isobe, Eiichi Nakamura, and Sumio Iijima, J. Phys. Chem. B 2006, 110,

5179–5181.

(79) “Synthesis of Coordinatively Unsaturated Cobalt(II)-Alkyl Complexes Bearing

Phosphorus-Bridged [1.1]Ferrocenophanes” Yuki Imamura, Tsutomu Mizuta,

Katsuhiko Miyoshi, Hideki Yorimitsu, and Koichiro Oshima, Chem. Lett. 2006,

35, 260–261.

(78) “Palladium-Catalyzed Stereo- and Regiospecific Allylation of Aryl Halides with

Homoallyl Alcohols via Retro-Allylation: Selective Generation and Use of

σ-Allylpalladium” Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, and Koichiro


(77) “Cobalt(diamine)-catalyzed Cross-coupling Reaction of Alkyl Halides with

Arylmagnesium Reagents: Stereoselective Constructions of Arylated

Asymmetric Carbons and Application to Total Synthesis of AH13205” Hirohisa

Ohmiya, Hideki Yorimitsu, and Koichiro Oshima, J. Am. Chem. Soc. 2006, 128,

1886–1889.

(76) “Nickel-Catalyzed Reactions of Silacyclobutanes with Aldehydes: Ring Opening

and Ring Expansion Reaction” Koji Hirano, Hideki Yorimitsu, and Koichiro

Oshima, Org. Lett. 2006, 8, 483–485.

(75) “Nucleophilic Aromatic Substitution Reaction of Nitroarenes with Alkyl- or

Arylthio Groups in Dimethyl Sulfoxide by Means of Cesium Carbonate” Azusa

Kondoh, Hideki Yorimitsu, and Koichiro Oshima, Tetrahedron 2006, 62,

2357–2360.

(74) “Cobalt-Catalyzed Cross-coupling Reactions of Alkyl Halides with Aryl

Grignard Reagents and Their Application to Sequential Radical

Cyclization/Cross-coupling Reactions” Hirohisa Ohmiya, Katsuyu Wakabayashi,

Hideki Yorimitsu, and Koichiro Oshima, Tetrahedron 2006, 62, 2207–2213.

(73) “Cobalt- and Rhodium-Catalyzed Cross-coupling Reaction of Allylic Ethers and

Halides with Organometallic Reagents” Hiroto Yasui, Keiya Mizutani, Hideki

Yorimitsu, and Koichiro Oshima, Tetrahedron 2006, 62, 1410–1415.

(72) “Chlorodimethylaluminum-Promoted Nucleophilic Addition of Lithium

Pentamethylcyclopentadienide to Aliphatic Aldehydes and DDQ-Mediated

Carbon-Carbon Bond Cleavage of the Adducts Providing the Parent Aldehydes”

Minoru Uemura, Hideki Yorimitsu, and Koichiro Oshima, Tetrahedron Lett.

2006, 47, 163–166.

(71) “1,2-Migration of Phosphorus-Centered Anions on Ate-type Copper Carbenoids

and Its Application for the Synthesis of New Potent Phosphine Ligands” Junichi

Kondo, Hidenori Someya, Hidenori Kinoshita, Hiroshi Shinokubo, Hideki


(70) “Nickel-Catalyzed Alkylation of Aldehydes with Trialkylboranes” Koji Hirano,

Hideki Yorimitsu, and Koichiro Oshima, Org. Lett. 2005, 7, 4689–4691.

(69) “Controlling the Incorporation and Release of C60 in Nanometer-Scale Hollow

Spaces inside Single-Wall Carbon Nanohorns” Ryota Yuge, Masako Yudasaka,

Jin Miyawaki, Yoshimi Kubo, Toshinari Ichihashi, Hideto Imai, Eiichi

Nakamura, Hiroyuki Isobe, Hideki Yorimitsu, and Sumio Iijima, J. Phys. Chem.

B 2005, 109, 17861–17867.

(68) “Stereoselective Hydrothiolation of Alkynes Catalyzed by Cesium Base: Facile

Access to (Z)-1-Alkenyl Sulfides” Azusa Kondoh, Kazuaki Takami, Hideki

Yorimitsu, and Koichiro Oshima, J. Org. Chem. 2005, 70, 6468–6473.

(67) “Gallium-Mediated Allyl Transfer from Bulky Homoallylic Alcohol to

Aldehydes via Retro-allylation: Stereoselective Synthesis of Both erythro- and

threo-Homoallylic Alcohols” Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu,


(66) “Nickel-Catalyzed Cross-Coupling Reaction of Aryl Halides with Allylic

Zirconium Reagents Generated in situ from Zirconocene(alkene) Complexes”

Koji Hirano, Kazuya Fujita, Hideki Yorimitsu, and Koichiro Oshima, Synlett

2005, 1787–1788.

(65) “Pentamethylcyclopentadienide in Organic Synthesis: Nucleophilic Addition of

Lithium Pentamethylcyclopentadienide to Aromatic Aldehydes and

Carbon-Carbon Bond Cleavage of the Adducts Affording the Parent Aldehydes”

Kazunari Yagi, Hideki Yorimitsu, and Koichiro Oshima, Tetrahedron Lett. 2005,

46, 4831–4833.

(64) “A New Method for the Synthesis of Acyltitanium Complexes and Their

Application to Copper-Mediated Acylmetallation of Carbon-Carbon Multiple

Bonds in Aqueous Media” Zhenfu Han, Takuma Fujioka, Shin-ichi Usugi,

Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima, Org. Biomol. Chem.

2005, 3, 1622–1623.

(63) “Regio- and Stereoselective Approach to 1,2-Di- and 1,1,2-Trisilylethenes by

Cobalt-Mediated Reaction of Silyl-Substituted Dibromomethanes with

Silylmethylmagnesium Reagents” Hirohisa Ohmiya, Hideki Yorimitsu, and

Koichiro Oshima, Angew. Chem. Int. Ed. 2005, 44, 3488–3490; Angew. Chem.

2005, 117, 3554–3556.

(62) “Ultra-rapid Synthesis of 15O-Labeled 2-Deoxy-D-glucose for Positron Emission

Tomography (PET)” Hideki Yorimitsu, Yoshihiro Murakami, Hiroyuki

Takamatsu, Shintaro Nishimura, and Eiichi Nakamura, Angew. Chem. Int. Ed.

2005, 44, 2708–2711; Angew. Chem. 2005, 117, 2768–2771.

(61) “Cobalt-Catalyzed Syn-Hydrophosphination of Alkynes” Hirohisa Ohmiya,

Hideki Yorimitsu, and Koichiro Oshima, Angew. Chem. Int. Ed. 2005, 44,

2368–2370; Angew. Chem. 2005, 117, 2420–2422.

(60) “Radical Allylation, Vinylation, Alkynylation, and Phenylation Reactions of

α-Halo Carbonyl Compounds with Organoboron, Organogallium, and

Organoindium Reagents” Kazuaki Takami, Shin-ichi Usugi, Hideki Yorimitsu,

and Koichiro Oshima, Synthesis 2005, 824–839.

(59) “Synthesis of (E)-1,2-Diphosphanylethene Derivatives from Alkynes by Radical

Addition of Tetraorganodiphosphane Generated In Situ” Akinori Sato, Hideki

Yorimitsu, and Koichiro Oshima, Angew. Chem. Int. Ed. 2005, 44, 1694–1696;

Angew. Chem. 2005, 117, 1722–1724.

(58) “Phosphorus-Bridged [1.1]Ferrocenophane with syn and anti Conformations”

Tsutomu Mizuta, Yuki Imamura, Katsuhiko Miyoshi, Hideki Yorimitsu, and

Koichiro Oshima, Organometallics 2005, 24, 990–996.

(57) “Cobalt-Mediated Mizoroki-Heck-Type Reaction of Epoxide with Styrene”

Yousuke Ikeda, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima,

Adv. Synth. Catal. 2004, 346, 1631–1634.

(56) “Boron Trifluoride-Mediated Alkylation of Diphenylphosphine with tert-Alkyl

Fluoride” Koji Hirano, Hideki Yorimitsu, and Koichiro Oshima, Org. Lett. 2004,

6, 4873–4875.

(55) “Radical Alkenylation of α-Halo Carbonyl Compounds with Alkenylindiums”

Kazuaki Takami, Hideki Yorimitsu, and Koichiro Oshima, Org. Lett. 2004, 6,

4555–4558.

(54) “Cobalt-Catalyzed Cross-coupling Reactions of Alkyl Halides with Allylic and

Benzylic Grignard Reagents and Their Application to Tandem Radical

Cyclization/Cross-coupling Reaction” Hirohisa Ohmiya, Takashi Tsuji, Hideki

Yorimitsu, and Koichiro Oshima, Chem. Eur. J. 2004, 10, 5640–5648.

(53) “Development of Radical Reactions with Zirconocene Complexes as Electron

Transfer Reagents” Kazuya Fujita, Hideki Yorimitsu, and Koichiro Oshima, Bull.

Chem. Soc. Jpn. 2004, 77, 1727–1736.

(52) “Cobalt-Catalyzed Cross-coupling Reaction of Chloropyridines with Grignard

Reagents” Hirohisa Ohmiya, Hideki Yorimitsu, and Koichiro Oshima, Chem.

Lett. 2004, 33, 1240–1241.

(51) “Cobalt-Catalyzed Regio- and Stereoselective Allylzincation of

1-Phenyl-1-alkynes” Toshihiro Nishikawa, Hideki Yorimitsu, and Koichiro

Oshima, Synlett 2004, 1573–1574.

(50) “Cobalt-Catalyzed Allylic Substitution Reaction of Allylic Ethers with Phenyl

and Trimethylsilylmethyl Grignard Reagents” Keiya Mizutani, Hideki Yorimitsu,

and Koichiro Oshima, Chem. Lett. 2004, 33, 832–833.

(49) “Selective Deposition of a Gadolinium(III) Cluster in a Hole Opening of

Single-wall Carbon Nanohorn” Ayako Hashimoto, Hideki Yorimitsu, Kumiko

Ajima, Kazutomo Suenaga, Hiroyuki Isobe, Jin Miyawaki, Masako Yudasaka,

Sumio Iijima, and Eiichi Nakamura, Proc. Nat. Acad. Sci. USA 2004, 101,

8527–8530.

(48) “Transformation of Zirconocene–Olefin Complexes into Zirconocene Allyl

Hydride and Their Use as Dual Nucleophilic Reagents: Reactions with Acid

Chloride and 1,4-Diketone” Kazuya Fujita, Hideki Yorimitsu, Hiroshi

Shinokubo, and Koichiro Oshima, J. Am. Chem. Soc. 2004, 126, 6776–6783.

(47) “Direct Preparation of Allylic Zirconium Reagents from Zirconocene–Olefin

Complexes and Alkenes” Kazuya Fujita, Hideki Yorimitsu, Hiroshi Shinokubo,

and Koichiro Oshima, J. Org. Chem. 2004, 69, 3302–3307.

(46) “Boron Trifluoride-catalyzed Reaction of Alkyl Fluoride with Silyl Enolate,

Allylsilane, and Hydrosilane” Koji Hirano, Kazuya Fujita, Hideki Yorimitsu,

Hiroshi Shinokubo, and Koichiro Oshima, Tetrahedron Lett. 2004, 45,

2555–2557.

(45) “Disulfidation of Alkynes and Alkenes with Gallium Trichloride” Shin-ichi

Usugi, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima, Org. Lett.

2004, 6, 601–603.

(44) “Synthesis of Cyclopropanes via Iodine-Magnesium Exchange between

3-Iodomethyl-1-oxacyclopentanes and Organomagnesium Reagents” Takashi

Tsuji, Tomoaki Nakamura, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro

Oshima, Tetrahedron 2004, 60, 973–978.

(43) “Synthesis of Fullerene Glycoconjugates through Sulfide Connection in

Aqueous Media” Hiroyuki Isobe, Hiroko Mashima, Hideki Yorimitsu, and Eiichi

Nakamura, Org. Lett. 2003, 5, 4461–4463.

(42) “Triethylborane-Mediated Hydrogallation and Hydroindation: Novel Access to

Organogalliums and Organoindiums” Kazuaki Takami, Satoshi Mikami, Hideki

Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima, J. Org. Chem. 2003, 68,

6627–6631.

(41) “Triethylborane-Induced Radical Reactions with Gallium- and Indium

Hydrides” Kazuaki Takami, Satoshi Mikami, Hideki Yorimitsu, Hiroshi

Shinokubo, and Koichiro Oshima, Tetrahedron 2003, 59, 6627–6635.

(40) “Triethylborane-Induced Radical Reaction of Alkynylgallium with α-Halo

Carbonyl Compounds” Shin-ichi Usugi, Hideki Yorimitsu, Hiroshi Shinokubo,

and Koichiro Oshima, Bull. Chem. Soc. Jpn. 2002, 75, 2687–2690.

(39) “Cobalt-Catalyzed Coupling Reaction of Alkyl Halides with Allylic Grignard

Reagents” Takashi Tsuji, Hideki Yorimitsu, and Koichiro Oshima, Angew. Chem.,

Int. Ed. Engl. 2002, 41, 4137–4139; Angew. Chem. 2002, 114, 4311–4313.

(38) “Triethylborane-Induced Radical Reaction of Gallium Enolates with α-Halo

Esters” Shin-ichi Usugi, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro

Oshima, Bull. Chem. Soc. Jpn. 2002, 75, 2049–2052.

(37) “Trans-Hydrometalation of Alkynes by a Combination of InCl3 and DIBAL-H:

One-Pot Access to Functionalized (Z)-Alkenes” Kazuaki Takami, Hideki


(36) “Palladium-Catalyzed Coupling Reaction of Alkenylgalliums with Aryl Halides”

Satoshi Mikami, Hideki Yorimitsu, and Koichiro Oshima, Synlett 2002,

1137–1139.

(35) “Cobalt-Catalyzed Intramolecular Heck-type Reaction of 6-Halo-1-Hexene

Derivatives” Takuma Fujioka, Tomoaki Nakamura, Hideki Yorimitsu, and


(34) “Cobalt-Catalyzed Heck-type Reaction of Alkyl Halides with Styrenes” Yousuke

Ikeda, Tomoaki Nakamura, Hideki Yorimitsu, and Koichiro Oshima, J. Am.

Chem. Soc. 2002, 124, 6514–6515.

(33) “Triethylborane-Induced Radical Reactions in Ionic Liquids” Hideki Yorimitsu

and Koichiro Oshima, Bull. Chem. Soc. Jpn. 2002, 75. 853–854.

(32) “Radical Addition of α-Halo Ester to Homoallylic Gallium or Indium Species:

Formation of Cyclopropane Derivatives” Shin-ichi Usugi, Takayuki Tsuritani,

Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima, Bull. Chem. Soc.

Jpn. 2002, 75. 841–845.

(31) “Radical Addition to (2,3-Epoxy-4-pentenyloxy)trialkylsilanes Yielding

α,β-Unsaturated Aldehydes via Carbon-Carbon Bond Cleavage” Shinobu Tanaka,

Tomoaki Nakamura, Hideki Yorimitsu, and Koichiro Oshima, Synlett 2002,

569–572.

(30) “Radical Cyclization Reaction with a Zirconocene-Olefin Complex as an

Efficient Single Electron Transfer Reagent” Kazuya Fujita, Hideki Yorimitsu,

and Koichiro Oshima, Synlett 2002, 337–339.

(29) “Allylation of Carbonyl Compounds with Allylic Gallium Reagents” Takashi,

Tsuji, Shin-ichi Usugi, Hideki Yorimitsu, Hiroshi Shinokubo, Seijiro Matsubara,

and Koichiro Oshima, Chem. Lett. 2002, 31, 2–3.

(28) “Conversion of Acid Chloride into Homoallylic Alcohol via Allylic C–H Bond

Activation of Alkene with a Zirconocene Complex” Kazuya Fujita, Hideki

Yorimitsu, Hiroshi Shinokubo, Seijiro Matsubara, and Koichiro Oshima, J. Am.

Chem. Soc. 2001, 123, 12115–12116.

(27) “Nucleophilic Addition of Tri-2-furylgermane to Aldehydes and α,β-Unsaturated

Carbonyl Compounds in the Presence of a Catalytic Amount of Base” Tomoaki

Nakamura, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima,

Tetrahedron 2001, 57, 9827–9836.

(26) “Triethylborane-Induced Bromine Atom-Transfer Radical Addition in Aqueous

Media: Study of the Solvent Effect in Radical Addition Reaction” Hideki

Yorimitsu, Hiroshi Shinokubo, Seijiro Matsubara, Koichiro Oshima, Kiyoyuki

Omoto and Hiroshi Fujimoto, J. Org. Chem. 2001, 66, 7776–7785.

(25) “Radical Addition of 2-Iodoalkanamide or 2-Iodoalkanoic Acid to Alkenes with

a Water-Soluble Radical Initiator in Aqueous Media: Facile Synthesis of

γ-Lactones” Hideki Yorimitsu, Katsuyu Wakabayashi, Hiroshi Shinokubo, and


(24) “Radical Addition of Triphenylgermane to Vinyloxiranes: Its Application to

Synthesis of 4-Vinyltetrahydro-2-furanones” Shinobu Tanaka, Tomoaki

Nakamura, Hideki Yorimitsu, Hiroshi Shinokubo, Seijiro Matsubara, and

Koichiro Oshima, Synlett 2001, 1278–1280.

(23) “Et3B-Induced Hydrogermylation of Alkenes and Silyl Enol Ethers” Shinobu

Tanaka, Tomoaki Nakamura, Hideki Yorimitsu, Hiroshi Shinokubo, and

Koichiro Oshima, C. R. Acad. Chim. Ser. II C 2001, 4, 461–470.

(22) “Palladium-Catalyzed Cross-Coupling Reaction of Organoindiums with Aryl

Halides in Aqueous Media” Kazuaki Takami, Hideki Yorimitsu, Hiroshi

Shinokubo, Seijiro Matsubara, and Koichiro Oshima, Org. Lett. 2001, 3,

1997–1999.

(21) “Triethylborane-induced Radical Allylation of α-Halo Carbonyl Compounds

with Allylgallium Reagent in Aqueous Media” Shin-ichi Usugi, Hideki


(20) “Triethylborane-Induced Radical Reactions with Gallium Hydride Reagent

HGaCl2” Satoshi Mikami, Kazuya Fujita, Tomoaki Nakamura, Hideki Yorimitsu,

Hiroshi Shinokubo, Seijiro Matsubara, and Koichiro Oshima, Org. Lett. 2001, 3,

1853–1855.

(19) “Cobalt-Catalyzed Tandem Radical Cyclization and Cross Coupling Reaction:

Its Application to Benzyl-Substituted Heterocycles” Katsuyu Wakabayashi,


5374–5375.

(18) “Reduction of Organic Halides with Tri-2-Furylgermane: Stoichiometric and

Catalytic Reaction” Tomoaki Nakamura, Hideki Yorimitsu, Hiroshi Shinokubo

and Koichiro Oshima, Bull. Chem. Soc. Jpn. 2001, 74. 747–752.

(17) “Triethylborane-Induced Radical Reaction with Schwartz Reagent” Kazuya

Fujita, Tomoaki Nakamura, Hideki Yorimitsu, and Koichiro Oshima, J. Am.

Chem. Soc. 2001, 123, 3137–3138.

(16) “Iodotrimethylsilane-Induced Cyclization of 6-Alkynal Acetals” Kazuaki

Takami, Hideki Yorimitsu, Hiroshi Shinokubo, Seijiro Matsubara, and Koichiro

Oshima, Synlett 2001, 293–295.

(15) “Radical Reaction by a Combination of Phosphinic Acid and a Base in Aqueous

Media” Hideki Yorimitsu, Hiroshi Shinokubo and Koichiro Oshima, Bull. Chem.

Soc. Jpn. 2001, 74, 225–235.

(14) “Powerful Solvent Effect of Water in Radical Reaction. Triethylborane-Induced

Atom Transfer Radical Cyclization in Water” Hideki Yorimitsu, Tomoaki

Nakamura, Hiroshi Shinokubo, Koichiro Oshima, Kiyoyuki Omoto and Hiroshi

Fujimoto, J. Am. Chem. Soc. 2000, 122, 11041–11047.

(13) “Radical Cyclization of N-Allyl-2-halo Amide in Water” Katsuyu Wakabayashi,

Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima, Bull. Chem. Soc.

Jpn. 2000, 73, 2377–2378.

(12) “Et3B-Induced Hydrogermylation of Alkenes and Silyl Enol Ethers” Shinobu

Tanaka, Tomoaki Nakamura, Hideki Yorimitsu, Hiroshi Shinokubo, and


(11) “Intramolecular Aryl Migration from Tin to Carbon via a Radical

Atom-Transfer Process” Katsuyu Wakabayashi, Hideki Yorimitsu, Hiroshi

Shinokubo and Koichiro Oshima, Org. Lett. 2000, 2, 1899–1901.

(10) “A Highly Effective Aldol Reaction Mediated by Ti(O-n-Bu)4/t-BuOK

Combined Reagent” Zhenfu Han, Hideki Yorimitsu, Hiroshi Shinokubo and

Koichiro Oshima, Tetrahedron Lett. 2000, 41, 4415–4418.

(9) “Radical Cyclization Reaction Using a Combination of Phosphinic Acid and a

Base in Aqueous Ethanol” Hideki Yorimitsu, Hiroshi Shinokubo and Koichiro

Oshima, Chem. Lett. 2000, 29, 104–105.

(8) “Reduction of Organic Halides with Tri-2-Furanylgermane: Stoichiometric and

Catalytic Reaction” Tomoaki Nakamura, Hideki Yorimitsu, Hiroshi Shinokubo

and Koichiro Oshima, Synlett 1999, 1415–1416.

(7) “Transformation of Tetrahydropyranyl Ether of Allylic Alcohols into

7-Octene-1,5-diol by Means of Trialkylmanganate” Toshihiro Nishikawa,

Tomoaki Nakamura, Hirotada Kakiya, Hideki Yorimitsu, Hiroshi Shinokubo and


(6) “Radical Addition of 2-Iodoalkanamide or 2-Iodoalkanoic Acid to Alkenols

Using a Water-Soluble Radical Initiator in Water. A Facile Synthesis of

γ-Lactones” Hideki Yorimitsu, Katsuyu Wakabayashi, Hiroshi Shinokubo and


(5) “Triethylborane-Induced Radical Addition of Halogenated Compounds to

Alkenes and Alkynes in Water” Tomoaki Nakamura, Hideki Yorimitsu, Hiroshi

Shinokubo and Koichiro Oshima, Synlett 1998, 1351–1352.

(4) “Triethylborane-Mediated Atom Transfer Radical Reaction in Water” Hideki

Yorimitsu, Tomoaki Nakamura, Hiroshi Shinokubo and Koichiro Oshima, J. Org.

Chem. 1998, 63, 8604–8605.

(3) “Manganese-catalyzed Phenylation of Acetylenic Compounds with a Phenyl

Grignard Reagent” Hideki Yorimitsu, Jun Tang, Kenji Okada, Hiroshi

Shinokubo and Koichiro Oshima, Chem. Lett. 1998, 27, 11–12.

(2) “Generation of Allylic Manganates from Trimethylmanganate and Allylic

Stannanes and Their Reactions with Epoxides” Jun Tang, Hideki Yorimitsu,

Hirotada Kakiya, Rie Inoue, Hiroshi Shinokubo and Koichiro Oshima,

Tetrahedron Lett. 1997, 38, 9019–9022.

(1) “Selectivity in Organic Group Transfer in Reactions of Mixed

Diorganomanganese(II) and Triorganomanganate(II) with 2-Cyclohexen-1-one

or Cyclohexanecarbaldehyde” Hideki Yorimitsu, Yasuhiro Hayashi, Jun Tang,

Hiroshi Shinokubo and Koichiro Oshima, Bull. Chem. Soc. Jpn. 1997, 70,

2297–2300.

Reviews, Accounts, Books, Essay, etc.

59. 「なぜナニ化学クイズショー（関西版）」依光英樹, 化学と教育 2019, 67, in

press.

58. “Catalytic Inter- and Intramolecular Coupling of Aryl Sulfones” Fumiya

Takahashi, Keisuke Nogi, and Hideki Yorimitsu, Phosphorus, Sulfur, Silicon

2019, 194, in press (DOI: 10.1080/10426507.2019.1603232).

57. “Editorial Board Focus: Professor Hideki Yorimitsu (Kyoto University, Japan)”

Synform 2019, (3), A39–A40 (DOI: 10.1055/s-0037-1609828).

56. “フローマイクロ合成が可能にする新規プメラー型反応 (New

Pummerer-Type Reaction Attainable in Flow Microreactor)” 柳智征, 依光英樹,

月刊ファインケミカル 2018, 47 (12), 24–29.

55. “Recent development of ortho-C–H functionalization of aryl sulfoxides through

[3,3] sigmatropic rearrangement” Tomoyuki Yanagi, Keisuke Nogi, and Hideki

Yorimitsu, Tetrahedron Lett. 2018, 59, 2951–2959 (DOI:

10.1016/j.tetlet.2018.06.055).

54. “C–S Bond Activation” Shinya Otsuka, Keisuke Nogi, and Hideki Yorimitsu,

Top. Curr. Chem. 2018, 376, No. 13 (DOI: 10.1007/s41061-018-0190-7 or

https://rdcu.be/Lc6r).

53. “Smith Organic Chemistry, 5th ed., Japanese Translation, Vol. 2” Koichiro

Oshima, Kazuhiko Takai, Hiroshi Shinokubo, and Hideki Yorimitsu, Trans.;

Hisashi Yamamoto and Koichiro Oshima, Trans. Eds.; Kagaku Dojin, Kyoto,

2018.

52. “Smith Organic Chemistry, 5th ed., Japanese Translation, Vol. 1” Koichiro



2017.

51. 「パラジウム触媒が導く新規メタラート転位」野木馨介, 依光英樹, 化学

2017, 72 (10), 66–67.

50. “Cascades of Interrupted Pummerer Reaction-Sigmatropic Rearrangement”

Hideki Yorimitsu, Chem. Rec. 2017, 17, 1156–1167 (DOI:

10.1002/tcr.201700017).

49. “Embedding heteroatoms: an effective approach to create porphyrin-based

functional materials” Norihito Fukui, Keisuke Fujimoto, Hideki Yorimitsu, and

Atsuhiro Osuka, Dalton Trans. 2017, 46, 13322–13341 (DOI:

10.1039/c7dt02815f).

48. 「斬新な化学反応を求めて」依光英樹, JST News, JST, 2017, Oct. 10–11.

47. “Dibenzothiophene 5,5-dioxide” M. Bhanuchandra and Hideki Yorimitsu, In

Electronic Encyclopedia of Reagents for Organic Synthesis (2nd Update), Leo A.

Paquette, Philip L. Fuchs, David Crich, and Gary A. Molander, Eds.; John Wiley

and Sons, 2017, DOI: 10.1002/047084289X.rn02046.

46. “Aromatic metamorphosis: conversion of an aromatic skeleton into a different

ring system” Keisuke Nogi and Hideki Yorimitsu, Chem. Commun. 2017, 53,

4055–4065 (DOI: 10.1039/C7CC00078B).

45. 「二次元大型原子層分子の精密有機合成」依光英樹，CSJカレントレビュ

ー25 二次元物質の科学，戸部義人，斉木幸一朗，川俣純，西原寛編，

化学同人, 2017, Chapter 14.

44. “Cross-coupling of Aryl Sulfides Powered by N-Heterocyclic Carbene Ligands”

Ke Gao, Shinya Otsuka, Alexandre Baralle, Keisuke Nogi, Hideki Yorimitsu,

Atsuhiro Osuka, J. Synth. Org. Chem. Jpn. 2016, 74, 1119–1127 (DOI:

10.5059/yukigoseikyokaishi.74.1119).

43. “Aromatic Metamorphosis of Dibenzothiophenes” Hideki Yorimitsu,

Dhananjayan Vasu, M. Bhanuchandra, Kei Murakami, Atsuhiro Osuka, Synlett

2016, 27, 1765–1774 (DOI: 10.1055/s-0035-1561617).

42. “Trimethylsilylmethylmagnesium Chloride” Ke Gao and Hideki Yorimitsu, In

Electronic Encyclopedia of Reagents for Organic Synthesis (2nd Update), Leo A.


and Sons, 2016, DOI: 10.1002/047084289X.rt322.pub3.

41. “Author Profile Hideki Yorimitsu” Angew. Chem. Int. Ed. 2016, 55, 480; Angew.

Chem. 2016, 128, 490 (DOI: 10.1002/anie.201508279).

40. “Catalytic Retro-allylation and Deallylation” Hideki Yorimitsu, In Cleavage of

Carbon–Carbon Single Bonds by Transition Metals; Masahiro Murakami and

Naoto Chatani Eds.; Wiley-VCH: Weinheim, 2016, Chapter 5.

39. 「コバルト」依光英樹，有機合成実験法ハンドブック第二版, 有機合成化

学協会編, 丸善, 2015, 19.3.4節.

38. “Discrete Atomic Layers at the Molecular Level” Hideki Yorimitsu and M.

Bhanuchandra, J. Phys. Soc. Jpn. 2015, 84, 121016-1–16 (DOI:

10.7566/JPSJ.84.121016).

37. 「OMCOS-18」依光英樹， Organometallic News, 2015, 105.

36. 「最先端有機金属化学を駆使した π 電子系分子の創出」依光英樹，大須

賀篤弘, Organometallic News, 2015, 48–53.

35. “Heteroatom-stabilized Allylic Anions” Hideki Yorimitsu and Koichiro Oshima,

In Comprehensive Organic Synthesis II, Paul Knochel, Gary Molander, Koichi

Mikami, Eds.; Elsevier: Oxford, UK, 2014, Vol. 2, Chapter 2.4.

34. “Homolytic Substitution at Phosphorus for C–P Bond Formation in Organic

Synthesis” Hideki Yorimitsu, Beilstein J. Org. Chem. 2013, 9, 1269–1277.

33. “Organometallic Approaches for Direct Modification of Peripheral C-H Bonds

in Porphyrin Cores” Hideki Yorimitsu and Atsuhiro Osuka, Asian J. Org. Chem.

2013, 2, 356−373.

32. “Synthesis of Heteroaromatic Compounds by Newly Extended Pummerer

Reactions” Hideki Yorimitsu, J. Synth. Org. Chem., Jpn. 2013, 71, 341−354.

31. “Recent Advances in Transition-metal-catalyzed Intermolecular

Carbomagnesiation and Carbozincation” Kei Murakami and Hideki Yorimitsu,

Beilstein J. Org. Chem. 2013, 9, 278–302.

30. “Smith Organic Chemistry, 3rd ed., Japanese Translation, Vol. 2” Koichiro



2013.

29. “Smith Organic Chemistry, 3rd ed., Japanese Translation, Vol. 1” Koichiro



2012.

28. “Direct Multiple Arylation of Functional Aromatics” Hideki Yorimitsu and

Atsuhiro Osuka, Low Temperatures and Materials Sciences (Kyoto University),

2012, 20, 9−17.

27. 「白浜温泉での国際会議」依光英樹, 化学と工業, 2012, 65, 337.

26. 「HTSで幸運をたぐり寄せる?」依光英樹, Organometallic News, 2012, 26.

25. “Transition Metals and Radicals” Hideki Yorimitsu, In Encyclopedia of Radicals

in Chemistry, Biology and Materials, Chryssostomos Chatgilialoglu and Armido

Studer, Eds.; John Wiley & Sons: Chichester, UK, 2012, Vol. 1, Chapter 35.

24. “Free Radical Reactions” Hideki Yorimitsu and Koichiro Oshima, In Science of

Synthesis: Water in Organic Synthesis, Shu Kobayashi, Ed.; Thieme: 2012, Vol.

2011/7, Chapter 5.8.

23. “The Chemistry of Organomanganese Ate Complexes” Hideki Yorimitsu and

Koichiro Oshima, In The Chemistry of Organomanganese Compounds, Ilan

Marek and Zvi Rappoport, Eds.; John Wiley & Sons: Chichester, UK, 2011,

Chapter 10.

22. “Alkyl Grignard Reagents (Update)” Hideki Yorimitsu, In Science of Synthesis,

Kazuaki Ishihara, Ed.; Thieme: 2011, Volume 7. Chapter 7.6.10.9.

21. “Aryl Grignard Reagents (Update)” Hideki Yorimitsu, In Science of Synthesis,

Kazuaki Ishihara, Ed.; Thieme: 2011, Volume 7. Chapter 7.6.5.6.

20. “SYNTHESIS OF TETRAORGANOSILANES: (CHLOROMETHYL)-

DIMETHYLPHENYLSILANE” Kei Murakami, Hideki Yorimitsu, Koichiro

Oshima, Jane Panteleev, and Mark Lautens, Org. Synth. 2010, 87, 178−183.

19. “1-Alkynylphosphines and Their Derivatives as Key Starting Materials in

Creating New Phosphines” Azusa Kondoh, Hideki Yorimitsu, and Koichiro

Oshima, Chem. Asian J. 2010, 5, 398−409.

18. “Metal-Mediated Retro-Allylation of Homoallyl Alcohols for Highly Selective

Organic Synthesis” Hideki Yorimitsu and Koichiro Oshima, Bull. Chem. Soc.

Jpn. 2009, 82, 778–792.

17. “Tri-2-furanylgermane” Hideki Yorimitsu and Koichiro Oshima, In Electronic

Encyclopedia of Reagents for Organic Synthesis, Leo A. Paquette, Philip L.

Fuchs, David Crich, and Gary A. Molander, Eds.; John Wiley & Sons, 2008,

DOI: 10.1002/047084289X.rn01083; Encyclopedia of Reagents for Organic

Synthesis, 2nd Edition, Leo A. Paquette, Philip L. Fuchs, David Crich, and Gary

A. Molander, Eds.; John Wiley and Sons, 2009, Vol. 13, 10147–10148.

16. “Nickel-Catalysed Reactions with Trialkylboranes and Silacyclobutanes” Koji

Hirano, Hideki Yorimitsu, and Koichiro Oshima, Chem. Commun. 2008,

3234−3241.

15. “Selective Reactions Based on Retro-allylation of Homoallyl Alcohols” Hideki

Yorimitsu and Koichiro Oshima, J. Synth. Org. Chem., Jpn. 2008, 66, 332−343.

14. “Bis(bicyclo[2.2.1]hepta-2,5-diene)dichlorodirhodium” Hideki Yorimitsu and

Koichiro Oshima, In Electronic Encyclopedia of Reagents for Organic Synthesis

(Update), Leo A. Paquette, Philip L. Fuchs, David Crich, and Gary A. Molander,

Eds.; John Wiley & Sons, 2008, DOI: 10.1002/047084289X.rb105;

Encyclopedia of Reagents for Organic Synthesis, 2nd Edition, Leo A. Paquette,

Philip L. Fuchs, David Crich, and Gary A. Molander, Eds.; John Wiley and Sons,

2009, Vol. 2, 844–847.

13. “1,1-Dimethylsilacyclobutane” Koji Hirano, Hideki Yorimitsu, and Koichiro

Oshima, In Electronic Encyclopedia of Reagents for Organic Synthesis, Leo A.


& Sons: 2008, DOI: 10.1002/047084289X.rn00813; Encyclopedia of Reagents

for Organic Synthesis, 2nd Edition, Leo A. Paquette, Philip L. Fuchs, David

Crich, and Gary A. Molander, Eds.; John Wiley and Sons, 2009, Vol. 6

4296–4297.

12. “The Chemistry of Organomagnesium Ate Complexes” Hideki Yorimitsu and

Koichiro Oshima, In The Chemistry of Organomagnesium Compounds

(Chemistry of Functional Groups), Zvi Rappoport and Ilan Marek, Eds.; John

Wiley & Sons: 2008, Chapter 18.

11. “Development of New Methods for the Synthesis of Phosphine Ligands” Hideki

Yorimitsu and Koichiro Oshima, Japanese Scientific Monthly 2008, 61, 7–12.

10. “Product Class 10: O/O Acetals: With Functionalization Attached to the Acetal

Carbon” Hideki Yorimitsu and Koichiro Oshima, In Science of Synthesis, Stuart

L. Warriner, Ed.; Thieme: 2007, Volume 29. Chapter 29.10, pp. 691–706.

9. “N,N-Dichlorobenzenesulfonamide” Hideki Yorimitsu and Koichiro Oshima, In

Electronic Encyclopedia of Reagents for Organic Synthesis, Leo A. Paquette,

Philip L. Fuchs, David Crich, and Gary A. Molander, Eds.; John Wiley and

Sons: 2007, DOI: 10.1002/047084289X.rn00718; Encyclopedia of Reagents for

Organic Synthesis, 2nd Edition, Leo A. Paquette, Philip L. Fuchs, David Crich,

and Gary A. Molander, Eds.; John Wiley and Sons, 2009, Vol. 5, 3296–3297.

8. “Trimethylsilylmethylmagnesium Chloride” Hideki Yorimitsu and Koichiro

Oshima, In Electronic Encyclopedia of Reagents for Organic Synthesis (Update),

Leo A. Paquette, Philip L. Fuchs, David Crich, and Gary A. Molander, Eds.;

John Wiley and Sons, 2007, DOI: 10.1002/047084289X.rt322; Encyclopedia of

Reagents for Organic Synthesis, 2nd Edition, Leo A. Paquette, Philip L. Fuchs,

David Crich, and Gary A. Molander, Eds.; John Wiley and Sons, 2009, Vol. 13,

10402–10407.

7. “New Synthetic Reactions Catalyzed by Cobalt Complexes” Hideki Yorimitsu

and Koichiro Oshima, Pure Appl. Chem. 2006, 78, 441–449.

6. 「酸素−15標識糖の超高速合成とその応用〜時間との究極の戦い」依光英

樹，村上佳裕，西村伸太郎，中村栄一, 化学と生物 2005, 43, 731–733.

5. “Recent Rapid Progress in Asymmetric Allylic Substitutions Catalyzed by Chiral

Copper Complexes” Hideki Yorimitsu and Koichiro Oshima, Angew. Chem. Int.

Ed. 2005, 44, 4435–4439; Angew. Chem. 2005, 117, 4509–4513.

4. “Recent Advances in the Use of Tri(2-furyl)germane, Triphenylgermane and

Their Derivatives in Organic Synthesis” Hideki Yorimitsu and Koichiro Oshima,

Inorg. Chem. Commun. 2005, 8, 131–143.

3. “Innovative Reactions Mediated by Zirconocene” Kazuya Fujita, Hideki

Yorimitsu, and Koichiro Oshima, Chem. Rec. 2004, 4, 110–119.

2. “Synthetic Radical Reactions in Aqueous Media” Hideki Yorimitsu, Hiroshi

Shinokubo, and Koichiro Oshima, Synlett 2002, 674–686.

1. “Radical Chain Reactions: Organoborane Initiators” Hideki Yorimitsu and

Koichiro Oshima, In Radicals in Organic Synthesis; Renaud, P.; Sibi, M. Eds.;

Wiley-VCH: 2001, Vol. 1. Chapter 1.2.

Patents

VII. “Contrast Medium” Sumio Iijima, Jin Miyawaki, Masako Yudasaka, Eiichi

Nakamura, Hiroyuki Isobe, Hideki Yorimitsu, and Hideto Imai, Jpn. Tokkyo

Koho 2011, JP 4822702.

VI. “Substance-Containing Carbon Nanohorn Composite Having Polyamine Plug

and Process for Producing the Same” Ryota Yuge, Hideki Yorimitsu, Masako

Yudasaka, and Sumio Iijima, PCT Int. Appl. 2008, WO 2008004532.

V. “Carbon Campsite Inclusion with Cap Effect and Manufacturing Method”

Sumio Iijima, Masako Yudasaka, Hitoshi Miyawaki, Ryota Yuge, Hideki

Yorimitsu, Hiroyuki Isobe, Eiichi Nakamura, Jpn. Kokai Tokkyo Koho 2008, JP

2008001570.

IV. “Carbon Nanohorn Complex Having Substance Encapsulated Therein and

Method Producing the Same” Ryota Yuge, Masako Yudasaka, Sumio Iijima, and

Hideki Yorimitsu, PCT Int. Appl. 2007, WO 2007091663.

III. “Contrast Medium” Sumio Iijima, Jin Miyawaki, Masako Yudasaka, Eiichi

Nakamura, Hiroyuki Isobe, Hideki Yorimitsu, and Hideto Imai, PCT Int. Appl.

2006, WO 2006068294.

II. “Preparation of Carbohydrate Compounds Having Five Sugar Moieties, Their

Use as Receptor Inhibitors, Fullerene Derivatives Having Organosulfur Groups,

and Preparation of Sulfide Group-Containing Fullerene Derivatives” Eiichi

Nakamura, Hiroyuki Isobe, and Hideki Yorimitsu, Jpn. Kokai Tokkyo Koho 2005,

JP 2005112816.

I. “Preparation of 15O-Labeled Monosaccharides Useful for Positron Emission

Tomography” Eiichi Nakamura, Shintaro Nishimura, Yoshihiro Murakami, and

Hideki Yorimitsu, PCT Int. Appl. 2005, WO 2005105708.

publications (as of apr. 3, 2019)kuchem.kyoto-u.ac.jp/orgchem/yorimitsu_lab/publication... · 2019....

Documents