Rayat Shikshan Sanstha’s

YASHAVANTRAO CHAVAN INSTITUTE OF SCIENCE, SATARA

(AUTONOMOUS)

Syllabus introduced from June, 2020

B. Sc. III. Nanoscience and Technology (Entire)

Syllabus Structure

B. Sc. III S E M E S T E R – V

Sr.

No

Course

Code

Course Title

Theory Practical

No. of

lectures

/Week

Clock

Hours/

week

Credit

s

Course Code

No. of

lectures

/Week

Clock

Hours/

Week

Credits

1 BNTT-501 Physics-IX 2 2 2 BNTP 511 LAB 1

(Physics) 5 5 2

2 BNTT-502 Physics- X 2 2 2

3 BNTT-503 Chemistry- IX 2 2 2 BNTP 512 LAB 2

(Chemistry) 5 5 2

4 BNTT-504 Chemistry- X 2 2 2

5 BNTT-505 Biotech- IX 2 2 2 BNTP 513LAB 3

(Biotechnology) 5 5 2

6 BNTT-506 Biotech- X 2 2 2

7 BNTT-507 Science at

Nanoscale I 2 2 2

BNTP 514 LAB 4

(Nano I) 5 5 2

8 BNTT-508 Science at

Nanoscale II 2 2 2

9 BNTT-509 Environmental

Nanotechnology I 2 2 2

BNTP 515 LAB 5

(Nano II) 5 5 2

10 BNTT-510

Environmental

Nanotechnology

II

2 2 2

11 BNTT-

AECC-3

Scientific Paper

Writing - - - Project 5 5 2

Total of SEM V 20 20 20 30 30 10

B. Sc. III S E M E S T E R –VI

Sr.

No

Course

Code

Course Title

Theory Practical

No. of

lectures

/Week

Clock

Hours/

week

Credits

Course Code

No. of

lectures

/Week

Clock

Hours/

Week

Credits

1 BNTT-601 Physics-XI 2 2 2 BNTP 611 LAB 1

(Physics) 5 5 2

2 BNTT-602 Physics-XII 2 2 2

3 BNTT-603 Chemistry- XI 2 2 2 BNTP 612 LAB 2

(Chemistry) 5 5 2

4 BNTT-604 Chemistry- XII 2 2 2

5 BNTT-605 Biotech- XI 2 2 2 BNTP 613 LAB 3

(Biotechnology) 5 5 2

6 BNTT-606 Biotech- XII 2 2 2

7 BNTT-607 Properties of

Nanomaterials I 2 2 2

BNTP 614 LAB 4

(Nano III) 5 5 2

8 BNTT-608 Properties of

Nanomaterials II 2 2 2

9 BNTT-609 Nano biology &

Nanomedicine I 2 2 2

BNTP 615 LAB 5

(Nano IV) 5 5 2

10 BNTT-610 Nano biology &

Nanomedicine II 2 2 2

11 BNTT-

AECC-3

Scientific Paper

Writing - - - Project 5 5 2

Total of SEM V 20 20 20 30 30 10

Total of SEM V & SEMIV 40 40 40 60 60 20

Student contact hours per week 50 hr. Total Marks for B.Sc.-III (Including Scientific Paper Writing)

:1600

Theory lectures and practical : 50 min. Total Credits for B.Sc.-III (Semester V & VI) :60

AECC3- Ability Enhancement Compulsory Course( BNTT-AECC-3 & BNTT-AECC-3 ) Scientific Paper Writing

BNTT- B. Sc. Nanoscience and Technology Entire. (for Semester V BNTT-501 to BNTT-510 and

for Semester VI BNTT-601to BNTT-610)

Course list as per enclosed Annexure. Separate passing is mandatory for Theory, Internal and Practical.

Practical Examination will be conducted at semester end for 50 Marks per DSC course (subject). Passing Criteria -

minimum40%

Semester V Sr. No Course Code Course Title Name of papers

1 BNTT-501 Physics-IX Mathematical Physics

2 BNTT-502 Physics- X Classical Mechanics, Classical

Electrodynamics and Quantum Mechanics

3 BNTT-503 Chemistry- IX Inorganic Chemistry

4 BNTT-504 Chemistry- X Organic Chemistry

5 BNTT-505 Biotech- IX Enzymology

6 BNTT-506 Biotech- X Biochemical Techniques and Bioinformatics

7 BNTT-507 Science at Nanoscale I Synthesis of Nanomaterials I

8 BNTT-508 Science at Nanoscale II Synthesis of Nanomaterials II

9 BNTT-509 Environmental

Nanotechnology I

Prevention of Pollution I

10 BNTT-510 Environmental

Nanotechnology II

Prevention of Pollution II

11 BNTT -AECC-3 Scientific Paper Writing -

12 BNTP -511-LAB-1 Physics Physical Science

13 BNTP -512-LAB-2 Chemistry Chemical Science

14 BNTP -513-LAB-3 Biotech Biotechnology

15 BNTP -514-LAB-4 Nano I Synthesis of Nanomaterials

16 BNTP -515-LAB-5 Nano II Prevention of Pollution

Semester VI Sr. No Course Code Name of course Name of papers

1 BNTT-601 Physics-XI Solid state physics

2 BNTT-602 Physics-XII Nuclear and Particle Physics

3 BNTT-603 Chemistry- XI Physical Chemistry

4 BNTT-604 Chemistry- XII Spectroscopy and Photochemistry

5 BNTT-605 Biotech- XI Molecular Biology I

6 BNTT-606 Biotech- XII Molecular Biology II

7 BNTT-607 Properties of Nanomaterials I Properties of Nanomaterials I

8 BNTT-608 Properties of Nanomaterials II Properties of Nanomaterials II

9 BNTT-609 Nano biology & Nanomedicine I Nanobiology and Nanomedicine I

10 BNTT-610 Nano biology & Nanomedicine II Nanobiology and Nanomedicine

11 BNTT -AECC-3 Scientific Paper Writing -

12 BNTP -611-LAB-1 Physics Physical Science

13 BNTP -612-LAB-2 Chemistry Chemical Science

14 BNTP -613-LAB-3 Biotech Biotechnology

15 BNTP -614-LAB-4 Nano III Properties of Nanomaterials

16 BNTP -615-LAB-5 Nano IV Nanomedicine

Paper: BNTT - 501: Physics : Mathematical Physics (Credit- 2)

Objectives:

1) To understand basic calculus for classical and quantum mechanics.

2) To study complete numbers.

3) To study infinite series for the quantum mechanical approach.

UNIT 1: Partial Differential Equation (8 hours)

Introduction to differential equations, Method of separation of variables for solving second order

partial differential equations, Form of two dimensional Laplace differential equation in Cartesian

coordinates and its solution, Three dimensional partial differential equation in Cartesian

coordinates and its solution, The differential equation of progressive wave and its solution. Practice

exercise

UNIT 2: Integral.calculaus and infinite series (6 hours)

Integration in vector field,line and surface integrals revision, double integrals,area,moments and

centers of masses,double integration in polar form. Infinite series,integral test,ratio and root

test,alternating series,power series,Taylor and Maclaurin series,fourier series. Practice exercise

UNIT 3: Complex Analysis (10 hours)

Revision of complex numbers and their graphical representation: Geometrical representation,

Equal complex numbers, Addition, Subtraction, Multiplication and Division of complex number

by geometry. Types of complex numbers, square roots of complex numbers, Logarithmic function

of complex variables, Euler’s formula, De’Moivre’s theorem, Cauchy-Riemann conditions.

UNIT 4: Matrices and Determinants. (06 hours)

Introduction, types of matrices,matrix inverse,determinants,transformation on matrices , special

matrices,symmetric asymmetric matrices,orthoganal.matrics,unitary matrices,practice exercise.

Learning Outcomes:

Students should able

1. To understand basic differentiation.

2. To understand partial differential equations used in study of classical mechanics.

3. To generalize functions and their importance with practical approach.

4. To develop better understanding of infinite series

5. To analyze its applications.

6. To understand importance of complete numbers

7. To solve problems regarding complex numbers

8. Better visualization of negative functions with complex analysis

9. To solve various problems using matrices

10. To understand different methods of solving mathematical problems.

11. To solve various differential equations and their solutions using matrices.

Reference Books

1. Advanced calculus, Robert C. Wrede, Murray Spiegel.

2. Differential Equations with Modeling Applications, Dennis G.Zill.

3. Partial Differential Equations,Gupta Malik and Mittal.

4. Differential Equations,Gupta Malik and Mittal.

5. Differential Equations,RamachandraRao,H. R. Anuradha.

6. Partial Differential Equations, N. P. Bali.

7. Differential Equations, N. Ch. S. N. Iyenger.

8. Mathematical Physics, B. S. Rajput.

9. Mathematical Methods for Physicists, Arfken, Weber, 2005, Elsevier.

10. Mathematical Methods for Scientists and Engineers, McQuarrie, 2003, Viva Books.

11. Mathematical Physics, H. K. Das, Rama Varma.

12. Essential Mathematical methods, K. F. Riley, M. P. Habson, 2011,Cambridge.

13. Mathematics for Physicists, Susan M.Lea, 2004, Thomson Books/Cole.

14. Basic training in mathematics - a fitness program for scienxe students- R. Shankar springer science

business media new york1995

15. Thomas calculus- 11 th edition - Maurice D Weir,Joel Hass,Frank R Giordano

Paper: BNTT - 502: Physics: Classical Mechanics, Classical Electrodynamics and Quantum

Mechanics (Credit- 2)

Objectives

1. To study classical mechanics and its application.

2. To understand rigid body motion.

3. To study quantum mechanical behavior of the particle .

UNIT 1: Lagrangian Formulation (8 lectures)

Constraints, Degrees of freedom, Generalized coordinates, Principle of virtual work, D’Alembert’s

principle, Lagrange’s equation from D’Alembert’s principle, Applications of Lagrange’s equation

to a particle in space, Atwood’s machine and a bead sliding on uniformly rotating wire under force

free condition.

UNIT 2: Techniques of Calculus of Variation (8 lectures)

Hamilton’s principle, Deduction of Hamilton’s principle from D’Alembert’s principle, Deduction

of Lagrange’s equation from Hamilton’s principle, Applications-shortest distance between two

points in a plane, Brachistochrone problem.

UNIT 3: Charged Particles Dynamics (6 lectures)

Poisson’s and Laplace’s equations and their physical significance, Laplace’s equation in one

dimension and its solutions, Motion of charged particle - in uniform electric field E, magnetic field

B, Crossed uniform electric field E and magnetic field B.

UNIT 4: Operators in Quantum Mechanics (08 lectures)

Definition of an operator, Position operator (x), Linear momentum operator (p), Commutation

relation in quantum mechanics, Commutation relation between x and p, Kinetic energy operator

(T), Hamiltonian operator (H), Parity operator (π), Angular momentum operator (L) – components

of angular momentum operator in Cartesian coordinate system, Ladder operators, Eigen values of

Lz and L2 (use equations for L

2 and Lz in spherical polar coordinates).

Learning Outcomes

Student should be able to

1. Understand differences between Newtonian mechanics and Lagrnagian mechanics

2. Solve problems using Lagrangian mechanis

3. Applications of Lagrangian mechanics in daily life

4. Importance of Lagrangian,Newtonian,Hamiltonian formulations

5. Solve problems related Hamiltonian principle

6. Applications of techniques of calculus of variation

7. Understand dynamical system

8. Understand motion of charge under magnetic field

9. Understand Laplace and Poissons equations

10. Use theorotical fomualtions for solving problems

11. Identify different operators and their opeations on fuction

12. Understand change in fuctions after using various operators

13. To solve problems related quantum mechanical behavior

Reference Books

1. Classical Mechanics, Goldstein Herbert, NarosaPubli./ Pearson Edu. 2018

2. Classical Mechanics, Gupta, Kumar and Sharma, Pragati Praka.2012

3. Introduction to Classical Mechanics, Nikhil Ranjan Roy, S Chand Publ. 2016

4. Introduction to Classical Mechanics,Takwale R.G., Puranik P. S.,Tata McGraw 1979

5. Classical Mechanics, Panat P.V., NarosaPubli. 2016 Atomic physics, J B Rajam S Chand

6. Concepts of Modern Physics, ArthurBeiser, McGraw Hill

7. Classical Electrodynamics, PuriS.P., Tata McGraw/Alpha Science 2011

8. Classical Electrodynamics, Jackson J. D., Wiley India , 2007

9. Electromagnetics, Laud B.B., New Age Interna. 2011

10. Modern Physics, R. Murugeshan, 1997, S. Chand and Company Ltd.

11. Atomic Physics, J B Rajam, S Chand and Co.

12. Perspectives of Modern Physics, Arthur Beiser, McGraw Hill International Editions.

13. Concepts of Modern Physics, Arthur Beiser, Ahobhit Mahajan, S. Rai Choudhury, Sixth Edition,

Tata McGraw Hill Education Private Ltd.

14. Modern Physics, S. L. Kakani and Shubhra Kulkarni, 2006, Viva books Private Ltd.

15. Modern Physics, D. L. Sehgal, K. L. Chopra and N. K. Sehgal, Reprint 1995, Sultan Chand & sons.

16. Introduction to Modern Physics, F. K. Richtmyer, E. H. Kennard, John N. Cooper, Sixth Edition,

Tata McGraw Hill Education Private Ltd

17. A Text book of Quantum Mechanics, P.M. Mathews & K. Venkatesan, 2nd Edn.,2010, Tata

McGraw Hill,

18. Quantum Mechanics, Leonard I. Schiff, 3rd

Edn. 2010, Tata McGraw Hill.

19. Quantum Mechanics Theory and Applications, A. K. Ghatak and S. Lokanathan, Third Edn.1995,

Macmillan India Ltd.

20. Quantum Mechanics Theory and applications, AjoyGhatak, S. Lokanathan, 5th

Ed,2017, Trinity.

21. Quantum Mechanics, Chatwal and Anand, Reprint 2010, Himalaya Publishing house.

Quantum Mechanics, Gupta, Kumar, Sharma, Thirtieth Edn., 2011, Jai Prakash Nath Publications.

22. Advanced Quantum Mechanics, SatyaPrakash, Reprint 2011, KedarNath Ram Nath Meerut

23. Advanced Quantum Mechanics, B. S. Rajput, Ninth Edn., 2009, Pragati Prakashan.

24. Quantum Mechanics, B. N. Srivastava, Reprint 2011, Pragati Prakashan.

BNTP-511 - Classical Mechanics, Classical Electrodynamics and Quantum Mechanics

Marks - 50 (Credits: 02)

Objective:

1. To understand practical approach to theorotical formulation

2. To study properties of atom using spectoscopy

3. To understand different softwares for solving quantum mechanical problems

PRACTICLES

1. Resonance pendulum

2. Diffraction using auxiliary slit

3. Absorption spectrum of a liquid ( KMnO4 solution)

4. Surfaces tension of mercury

5. Double pendulum

6. Measurement of BH ,Bv and theta using earth inductor

7. Electron spin resonance

8. Coupled pendulum

9. Viscosity using serles method

10. Problems on lagrangian mechanicd

a. Scilab Expt. 1 (problem from Quantum Mechanics)

b. Scilab Expt. 2 (problem from Quantum Mechanics)

Learning Outcomes

Students should be able to

1. Use various instruments

2. Apply theoretical knowledge

3. Understand effects of earths magentic field

4. To calculate quantum mechanical problems using scilab

Paper: BNTT - 503: Chemistry IX: Inorganic Chemistry (Credit- 2)

Objectives:

1) To understand the concept of acid and base.

2) To study of CFT theory.

3) To study structure of different compound.

4) To study of non aqueous solvent.

Unit I

Acids and Bases (08 lectures)

Introduction to theories of Acids and Bases-Arrhenius concept, Bronsted-Lowry concept, Lewis

Concept, Lux-Flood Concept (definition and examples), Hard and Soft Acids and Bases. (HSAB

Concept), Classification of acids and bases as hard, soft and borderline. Pearson’s HSAB concept.

Acid–Base strength and hardness-softness.Applications and limitations of HSAB principle.

Unit II (06 lectures)

Chemistry of Non aqueous Solvents

Chemistry of Non aqueous Solvents. Introduction, definition and characteristics of solvents.

Classification of solvents. Physical properties and Acid-Base reactions in Liquid Ammonia(NH3)

and LiquidSulphur Dioxide (SO2).

Unit III (08 lectures)

a) Crystal field theory (CFT)

Introduction: Shapes of d-orbitals, Basic assumptions of CFT. Crystal field splitting of d-orbitals

of metal ion in octahedral, tetrahedral, square planar complexes and John-Teller distortion.Factors

affecting the Crystal field splitting. High spin and low spin octahedral complexes w.r.t. Co (II).

Crystal Field stabilization energy (CFSE), Calculation with respect to octahedral complexes

only.Limitations of CFT.

b) Molecular orbital theory (MOT).

Introduction, MOT of octahedral complexes with sigma bonding such as [Ti(H2O)6]3+

,[CoF6]3–

,

[Co(NH3)6]3+

.Merits and demerits of MOT.

Unit IV: Coordination Chemistry Inorganic Reaction mechanism: (08 lecture)

Introduction, Classification of Mechanism: Association, dissociation, interchange and the rate

determining steps.SN1 and SN

2 reactions for inert and labile complexes. Mechanism of substitution

in cobalt (III) octahedral complexes. Trans effect and its theories. Applications of trans effect in

synthesis of Pt (II) complexes.

Learning Outcomes:

Student will able to know

1. Different acid base theory.

2. Concept of solvent.

3. CFSE enenergy of different molecules .

4. Coordination chemistry of inorganic compound.

Reference Books:

1. Inorganic Chemistry (ELBS, 3rd Edition) D. F. Shriver, P. W. Atkins, C. H.Lang Ford, Oxford University

Press, 2nd Edition.

2. Basic Inorganic Chemistry : Cotton and Wilkinson.

3. Advanced Inorganic Chemistry (4th Edn.) Cotton and Wilkinson.

4. Concepts and Models of Inorganic Chemistry : Douglas and Mc. Daniel. 3rd

Edition. John Wiley publication.

5. Structural principles in inorganic compounds. W. E. Addison.

Paper: BNTT - 504: Chemistry X: Organic Chemistry (Credit 2)

Objectives:

1) To understand the function of reagents .

2) To study of some name reaction .

3) To study of electrophilic addition of carbon carbon double and triple bond .

4) To study of bioinorganic compound, photosynthesis, nitrogen fixation.

Unit I : Reagents (08 lectures)

Preparation and Applications of following reagents.Lithium aluminium hydride LiAlH4. Raney

Nickel. Osmium tetraoxide. Selenium dioxide(SeO2). Dicyclohexyl Carbodiimide (DCC).

Diazomethane.

Unit II : Name Reactions (08 lectures)

Statement, General Reaction, Mechanism and Synthetic applications: Diels -Alder reaction.

Meerwein –Pondorff-Verley reduction.Hofmann rearrangement. Wittig reaction. Wagner-

Meerwein rearrangement. Baeyer Villiger oxidation. Problem based on above reactions.

Retrosynthesis

Introduction. Recapitulation of basics of reaction mechanism and reagents. Terms used- Target

molecule (TM), Disconnection, Synthons, Synthetic equivalence, Functional group interconversion

(FGI), one group disconnection (w. r. t. suitable examples). Retrosynthetic analysis and synthesis of

target molecules: Cinnamaldehyde, Cyclohexene,

Unit III: Electrophilic addition to >C=C< (08 lectures)

Introduction. Examples of addition reactions. Mechanism of electrophilic addition to >C=C< bond,

orientation & reactivity,Hydrohalogenation. Anti-Markovnikoff’s addition (peroxide

effect).Rearrangements (support for formation of carbocation). Addition of halogens. Addition of

water. Addition of hypohalous acids (HO-X). Hydroxylation (formation of 1,2-diols).

Hydroboration-oxidation (formation of alcohol).Hydrogenation (formation of alkane). Ozonolysis

(formation of aldehydes & ketones).

Unit IV : Electrophilic addition to Carbon-Carbon triple (−C≡C−) bond (06 lectures)

Introduction. Examples of addition reactions. Mechanism of electrophilic addition to−C≡C−bond.

Addition of halogens. Addition of halogen acids.Addition of hydrogen. Addition of water.

Formation of metal acetylides.

Learning Outcomes:

1) Preparation and Application of reagents.

2) Mechanism and application of name reaction.

3) Mechanism of electrophilic addition of carbon carbon double and triple bond.

Reference Books:

1. Instrumental methods of Chemical Analysis ‐ H. Kaur

2. Organic Chemistry –Volume I & II ‐I .L. Finar

3. Advanced Organic Chemistry – Jerry March’s & Michel B. Smith

4. Advanced Organic Chemistry, Arun Bahl, B. S. Bahl by S.Chand

5. Textbook of organic Chemistry, Raj K. Bansal By New age international publisher 5th

edition.

6. Organic Chemistry Morrison Boyd, Bhattacharjee By Pearsons publications 6th

edition.

7. Organic reaction mechanism V. K. Ahulwalia by Narosapublication.

BNTP - 512: Lab 2- Chemistry (Credit- 2)

Objectives:

1) The aim of the practical course is to provide student with the skills that will be needed in future

practical work.

2) To expose the students to the ability to perform accurate quantitative measurements with an

understanding of the theory and interpretation of experimental results, perform calculations on

these results.

Practical

INORGANIC CHEMISTRY

I ) Gravimetric Estimations (G).

N. B. Any two experiments from G1 to G3 and any oneexperiment from G4 & G6.

G1. Gravimetric estimation of iron as ferric oxide (Fe2O3 ) from the given solution

containing ferrous ammonium sulphate, copper sulphate and free sulphuric acid.

G2. Gravimetric estimation of zinc as zinc pyrophosphate from the given solution

containing zinc sulphate, ferrous ammonium sulphate and free sulphuric acid.

G3. Gravimetric estimation of barium as barium sulphate(BaSO4) from the given solution

containing barium chloride, ferric chloride and free hydrochloric acid.

G4. Gravimetric estimation of barium as barium chromate(BaCrO4) from the given solution

containing barium chloride, ferric chloride and free hydrochloric acid.

G5. Gravimetric estimation of nickel as bis (dimethylglyoximato) nickel (II) fromthe given

solution containing nickel sulphate, ferrous ammonium sulphateand free Sulphuric

acid.

G6. Gravimetric estimation of aluminium as aluminium oxinate potassium tris (8-hydroxy

quinolato) aluminium (III) from the given solution containing potash alum ,copper

sulphate and free sulphuric acid.

[For the gravimetric experiments, stock solution should be given in the range of10 to 15 cm3 and

asked to dilute to 100 cm3 (or the stock solution should be givenin the range of 20 to 30 cm

3 and

asked to dilute to 250 cm3). Use 50 cm

3 of thisdiluted solution for estimation.]

II. Inorganic Preparations (P).

N. B. At least two preparations from the following with percentage yield:

P1. Preparation of potassium trioxalato aluminate (III).

P2. Preparation of Tetra ammine copper (II) chloride.

P3. Preparation of tris(thiourea) copper (I) sulphate.

P4.Preparation of potassium trioxalato ferrate (III).

P5.Preparation of chloropenta-ammine cobalt (III) chloride.

P6. Preparation of ammonium diamminetetrathiocynatochromate (III) (Reineck’s salt).

P7. Preparation of Potassium hexa nitro coblatate (III).

P8. Preparation of ammonium trioxalato chromate (III).

P9. Preparation of hexathiourea plumbus (II) nitrate.

A) Percentage Purity

N. B. : Any onefrom the following.

V1. Determination of percentage purity of ferrous ammonium sulpahte.

V2. Determination of percentage purity of tetrammine copper (II) sulphate.

V3. Determination of percentage purity of potassium (trioxalato-aluminate) (III).

B) Analysis of Commercial Sample.

N. B. Any one from the following:

V5. Determination of percentage of Calcium in the given sample of milk powder or lime.

V6. Determination of amount of aluminum in the given solution of potash alum.

V7. Determination of titrable acidity in the given sample of milk or lassi.

V8. Determination of percentage purity of boric acid using supplied sodiumhydroxide.

(Standard succinic or oxalic acid solution to be prepared to standardise thegiven sodium

hydroxide solution.)

V9. To determine the amount of HCl in given of commercial samples.

C) Ion exchange method.

N. B. Any onefrom the following.

V10. Determination of amount of sodium present in the given solution of commonsalt

using cation exchange resin (By Acid Base titration).

V11. Determination of amount of magnesium in the given solution containing(Mg2+

and

Zn2+

) using anion exchange resin and standard solution of EDTA.

V12. Determination of amount of zinc in the given solution containing (Mg2+

andZn2+

)

using anion exchange resin and standard solution of EDTA.

Reference Books:

1. A text book of quantitative Inorganic Analysis - A. I. Vogel.

2. Text book of Quantitative Inorganic Analysis - Kolthoff and Sandell.

3. Experimental Inorganic Chemistry - Palmer W. G.

4. Advanced Practical Inorganic Chemistry - Adams and Raynor.

5. Manual in Dairy Chemistry - I.C.A.R. Sub-Committee on Diary Education.

6. Chemical methods for environmental analysis - R. Ramesh and M. Anbu.

ORGANIC CHEMISTRY

I) Qualitative analysis

Separation of binary mixture and Identification of one component.(At least 08 mixtures)

Nature 1) Solid – Solid : 4 mixtures

2) Solid – Liquid : 2 mixtures

3) Liquid – Liquid : 2 mixtures

1) Solid – SolidMixtures:

One mixture from each the following types should be given:

i) Acid+Phenol ii) Acid + Base

iii) Acid+Neutral iv) Phenol +Base

v) Phenol+Neutral vi) Base +Neutral

2) Solid – LiquidMixtures

Mixture of type Neutral + Neutral or Acid + Neutral should be given.

3) Liquid – Liquid Mixtures

Mixture of type Neutral + Neutral or Base + Neutral should be

Given. Following compounds should be used for preparation ofmixtures

i) Acids: Benzoic acid, Phthalic acid, Salicylic acid, Cinnamic acid, Aspirin, Oxalic acid. ii)

Phenols: α-naphthol, β-naphthol.

iii) Bases:o-nitroaniline, m-nitroaniline, p-nitroaniline, aniline, o-toluidine and N, N-

dimethylaniline.

iv) Neutrals: Anthracene, acetanilide, m-dintrobenzene, chloroform, carbon tetrachloride,

acetone, nitrobenzene, ethyl acetate, ethyl benzoate, bromobenzene, urea and

thiourea.

NB :

1. For Solid-Liquid and Liquid-Liquid mixtures avoid detection of type of mixture.

Instead the weightage is given to detection of nature and separation ofmixture.

2. Separation and qualitative analysis of the binary Mixtures should be carried out on

microscale using microscale kits.

II) Quantitative analysis: Organic Estimations:(Any two)

1. Estimation of sucrose

2. Saponification value of oil.

3. To determine the amount of acid and amide present in the given mixture of acid and

amide.

4. Determination of Molecular weight of monobasic/dibasic acid by volumetric method.

5. Estimation of unsaturation –to estimate the percentage purity of given olefinic

compound by brominationmethod.

Note: Double burette method should be used for titration.

III) Organic Preparations: (Any two)

1. Multicomponent reaction - Preparation of Dihydropyrimidone.

2. Radical coupling reaction - Preparation of 1,1,2 bis-2naphthol.

3. Base catalyzed Aldol condensation- Preparation of Dibenzal propanone.

4. Diels Alder reaction- Reaction between Furan and Maleic acid

5. Benzil- Benzilic acid rearrangement reaction

6. Oxidation reaction – Preparation of Methyl phenyl sulfone.

IV) Preparation of Derivatives: (Any two)

1. Picrate derivative (naphathalene and α-naphthol).

2. Iodoform(Acetone).

3. Osazone of Carbohydrates(Glucose).

4. Oxalate derivative (ofUrea).

5. Nitrate derivative of Urea

6. 2,4-Dinitro phenyl hydrazone (carbonyl compounds)

7. Oxime derivatives (carbonyl compounds)

Or

Determination of structure of organic compound from given NMR spectra.

Ethanol, Ethyl acetate, Benzyl alcohol, Propanoic acid, Butaraldehyde, Ethyl benzoate,

Isopropyl benzene, Propyl ether, n-pentane, Propene, Diethyl amine, 2-chloro butane.

NB:All preparations should be carried out by considering green Chemistry approach

1. Preparation of derivative should be carried out on small scale. The starting compound

should not be given more than one gram.

2. Calculation of percentage practical yield in preparation is must.

3. Recrystallization of crude product and its melting point.

4. The product should be confirmed byTLC.

5. Assign reactions with mechanism.

Reference books:

1. Practical Organic Chemistry by – A.I.Vogel.

2. Practical Organic Chemistry by – O. P.Agarwal

Learning outcomes:

Students will able to know

1. Alloy analysis

2. Complexometric titration

3. Determination of hardness of water and acidity of milk

Preparation of inorganic compound

Reference Books:

1. Vogel,A.I.,Tatchell,A.R.,Furnis,B.S.,Hannaford,A.J.&Smith,P.W.G., Textbook of Practical

Organic Chemistry, Prentice-Hall, 5th edition,1996

2. Mann, F.G. & Saunders, B.C. Practical Organic Chemistry Orient-Longman,1960.

3. Khosla, B. D.; Garg, V. C. & Gulati, A. Senior Practical Physical Chemistry,R. Chand

&Co.New Delhi (2011).

4. Ahluwalia,V.K.&Agarwal,R.ComprehensivePracticalOrganicChemistry,

5. Universities Press.

6. Practical Organic Chemistry by – O. P.Agarwal

Paper:BNTT -505:Biotechnology VII :Enzymology (Credit- 2)

Objectives:

1) To study structure and functions of important Enzymes.

2) To study Classificaton of Enzyme.

3) To study Kinetics of Enzymes.T

4) To Study the Concentration of Enzymes.

UNIT1: Introduction of Enzymes : (04 Lectures)

Definition, Basic terminologies, Classification, Nomenclature and Physico‐chemical properties of

enzymes, IUB system.

UNIT2: Properties of Enzymes : (06 Lectures)

Concepts of active site, binding site, enzyme‐substrate complex, activation energy, Transition State

Theory. Effects of pH , temperature and substrate concentration on enzyme activitie s.

UNIT3: Enzyme Kinetics: (10 Lectures)

Introduction: Michaelis ‐ Menten Equation‐form and derivation, steady state enzyme kinetics,

Significance of Vmax and Km.

UNIT4: Enzyme activity: (10 Lectures)

Specific activity, turnover number.

Enzyme inhibition: types of inhibitors‐competitive, non‐competitive and uncompetitive, feedback

inhibition.

Enzyme immobilization:

Types of enzyme immobilization-matrix entrapment, ionic and cross linking, column packing; Analysis of

mass transfer effects of kinetics of immobilized enzyme reactions; Analysis of Film and Pore Diffusion

Effects on Kinetics of immobilized enzyme reactions;calculation of Effectiveness Factors of immobilized

enzyme systems; Bioconversion studies with immobilized enzyme packed –bed reactors

Learning outcomes:-

1) Students will able to know functions of different Enzymes in biological system.

2) Students will able to understand Kinetics of Enzymes.

3) Students will able to know Inhibition and Immobilization.

Reference Books:

1. Lehninger’s Principles of Biochemistry by D. L. Nelson and M. M. Cox, CBS Publications,

2000.(UNIT 1, 2,3,4)

2. Biochemistry by Lubert Stryer, 4th

Edition.( UNIT 1, 2,3,4)

3. Biochemistry; Satyanarayana Chakrapani, Books & Allied Pvt Ltd( UNIT 1, 2)

Paper: BNTT -506:Biotechnology VII :Biochemical Techniques and Bioinformatics (Credit-

2)

Objectives:

1) To studythe biochemical techniques for extraction of compound.

2) To study electrophoresis for separation of Biocomponent.

3) To study Chromatoghraphic Tecniqes.

4) To Study the Bioinformatics.

5) To study of Proteomics.

6) To study of Genomics.

UNIT I : Biochemical Techniques: (08 Lectures)

Introduction: Sub‐cellular fractionation, Methods of lysis for plants, animals and microbial cells

Centrifugation: Basic principle, Types and Importance

Electrophoresis: SDS and Native PAGE, Staining techniques.

UNIT II : Chromatographic Techniques: (10 Lectures)

Ion exchange, Gel filtration chromatography, Partition chromatography, Affinity chromatography,

Paper chromatography, Thin Layer Chromatography.

Bioinformatics:

Introduction to NCBI, Biological databases, Primary and Secondary protein sequence databases

Protein sequence information, Physico‐chemical properties, Sequence alignment. Structure

visualization: Ras‐Mol.

UNIT III: Concept of nanoenzymes: (07 Lectures)

Nanozymes in bionanotechnology, Natural enzymes, artificial enzymes, nanoenzymes, Various

nanomaterial based nanoenzymes.

UNIT IV: Applications of nanoenzymes (05 Lectures)

Applications of nanoenzymes for sensing and imaging, nucleic acid sensing, as aptasensors, for

immunoassay, for detection of cells and bacteria, for imaging, Nanozymes for therapeutics,

Learning outcomes:-

1) Students will able to know techniques of Centrifugation and Electrophoresis for seperaion of

Compound.

2) Students will able to understand use of Bioinformatic.

3) Students will able to know the application of nanoenzymes.

Reference Books:

1. Lehninger’s Principles of Biochemistry by D. L. Nelson and M. M. Cox, CBS Publications,

2000.(UNIT 1, 2)

2. Biochemistry by Lubert Stryer, 4th

Edition.( UNIT 1, 2)

3. Garrett and Grisham ‐ Biochemistry 2nd Edition

4. Biochemistry by J. L.

BNTP - 513: Lab 3- Biotechnology (Credit- 2)

Objectives:

1) To study different activity of enzymes.

2) To study effect of pH and temperature.

3) To study the activity of enzymes in presence of activator and inhibitor.

4) To study comparison between nucleotide sequence.

5) To study of Rasmol to identify information of amino acid and nucleic acid.

PRACTICALS

1. Qaulitative estimation of starch by iodine and Benedict test.

2. Identification and quantitation of activity of α amylase/ β

amylase/cellulase/amyloglucosidase/invertase

3. /alkaline phosphatase

4. salivary/microbial/animal/plant source].

5. Determination of specific activity

6. Determination of activity in presence of activators.

7. Determination of activity in presence of inhibitors

8. Determination of optimum pH

9. Determination of optimum temperature

10. Determination of Km and Vmax Determination of Competitive, non‐competitive

Inhibitors.

11. Getting an amino acid sequence, nucleotide sequence and BLAST

12. Multiple sequence alignment

13. Structure analysis: secondary, tertiary and Quaternary structure, bond angle, bond length, different

interactions Ras‐Mol, Kinemag.

Learning outcomes:-

1) Students will able to know different activity of enzymes.

2) Students will able to know effect of pH and temperature.

3) Students will able to know the activity of enzymes in presence of activator and inhibitor.

4) Students will able to know comparison between nucleotide sequence.

5) Students will able to know of Rasmol to identify information of amino acid and nucleic acid.

Reference Books:

1. Practical Biochemistry: An Introductory Course by Fiona Frais.

2. Textbook of Practical Biochemistry by David Plummer.

3. Laboratory Mannual in Biochemistry by S. Jayaraman.

Paper: BNTT - 507: Science at nanoscale: Synthesis of Nanomaterials I (Credit- 2)

Objectives:

1) To study the basic knowledge of nanoscience and technology

2) To study the different types of nanomaterials

3) To study the top down method for synthesis of nanomaterials

4) To study the thin film technology.

Unit 1: Introduction to Nanoscience (8 Lectures)

Introduction to Nanoscale, Nanomaterials, Nanoscienceand Nanotechnology. Nanoscience effects:

Quantum size effects, Quantum confinement effect, Bhor exciton radius, surface area to volume

ratio etc.The development of nanoscale science: scaling up approach, scaling down approach,

Generations of nanotechnology/ Nanotechnology Timeline: Pre-18th

Century, 19th

Century,

20th

Century, 21stCentury. Nano and Nature: Lycurgus Cup, stained glass windows, Damascus saber

blades, Nanoscopic colours (Butterfly wings), Bioluminescence (fireflies), Tribology, Nano

tribology (Gecko’s Sticky Feet, Nasturtium Leaf-Lotus effect etc.) in nature

Unit 2: Classification of Nanomaterials (8 Lectures)

Classification of nanomaterials: 0D, 1D, 2D and 3D and types of nanomaterials (QDs, QW, CNT’s,

Bucky Balls, etc.) Nanocomposites: Types of nanocomposites and applications. Brief applications

of nanomaterials / Consumer products: Television, Energy, Automobile, Textile, Space, Defense

and Engineering etc.

Unit 3: Top down method:Lithography (7 Lectures)

Overview of top down nanofabrication processes. Mechanical methods: Mechanical grinding (ball

milling), Lithographic methods: Types of lithography techniques i.e. photolithography, electron

beam lithography, X-ray lithography, Nano-imprint lithography.

Unit 4: Top down method:Thin film technologies (7 Lectures)

Thin film technologies: Thermal methods: Thermal evaporation, e-beam evaporation.Plasma

methods: DC and RF Magnetron Sputtering, High-energy methods: Pulsed Laser Deposition

Physical vapor deposition method etc. Advantages and disadvantages of Top down approaches

Learning Outcomes:

1) Student will able to understand generations of nanotechnolgy.

2) Student will able to know dimensions based classification of nanomaterials.

3) Student will able to understand concept of synthesis of nanoparticles by using physical method.

4) Student will able to understand thin film technologies.

Reference Books:

1. Introduction to Nanoscience and Nanotechnology, G. Hornyak, H. Tibbals, J. data, J. Moore.

2. Nanotechnology: Principles and Practices by S. K. kulkarani

3. Nanotechnology : Technology Revolution of 21st Century by Rakesh Rathi, published by S. Chand.

4. Introduction to Nanoscience, by Stuart Lindsay.

5. Introduction to Nanomaterials and nanotechnology by Vladimir Pokropivny, RynnLohmus, Irina

Hussainova, Alex Pokropivny and Sergey Vlassov

Paper: BNTT - 508: Science at nanoscale: Synthesis of Nanomaterials II (Credit- 2)

Objectives:

1) To study the Bottom up method for nanoparticals synthesis

2) To study the basic principle of different microscopies

3) To study the application of microscopy

Unit 1: Bottom up method: Vapor – phase synthesis (9 Lectures)

Overview of bottom up nanofabrication processes.Growth mechanism: nucleation and growth of

nanomaterials: Ostwald Ripening, sintering.Vapor – phase synthesis: Chemical vapor deposition

(CVD): Types of CVD process, Atomic Layer Deposition, Molecular beam epitaxy (MBE), Inert

gas condensation, Spray Pyrolysis, Flame pyrolysis.

Unit 2: Bottom up method: Liquid-phase synthesis (9Lectures)

Liquid-phase synthesis: Colloidal methods: Metal and semiconducting nanoparticles, Solution

precipitation, Electrodeposition, Sol-gel technique: Introduction. Sol-gel process: synthesis of

Aerogel, Xerogel, sol-gel coating processes. Hydrothermal synthesis, Dip coating, spin coating,

flow coating etc. Template synthesis of nano pattering. Advantages and Disadvantages of bottom

up approaches.

Unit 3:Visualization and manipulation tools (6 Lectures)

Microscopy: Basics, Working principle and applications. Optical microscopy, Electron microscopy,

scanning electrochemical microscopy (SECM): Construction and Working principle.

Unit 4:Visualization and manipulation tools (6 Lectures)

Scanning Probe Microscope (SPM) techniques: Scanning Tunneling Microscopy (STM) and

Atomic force microscopy. Optical Tweezers: Basics, Working principles and applications.

Learning Outcomes:

1) Student will able to understand concept of growth mechanism of nanomaterials.

2) Student will able to understand bottom up methods for synthesis of nanoparticles.

3) Student will able to know microscopies.

4) Student will able to understand optical tweezers method.

Reference Books:

1. Handbook of microscopy for nanotechnologyby nan yao princeton university princeton, nj, usa

zhong lin wang.

2. Introduction to nanomaterials and nanotechnologyv. Pokropivny, r. Lohmus, i. Hussainova, a.

Pokropivny, s. Vlassov.– university of tartu.

3. Handbook of vacuum science and technology by dorothy m. Hoffman

4. Nanotechnology: Principles and Practices by S. K. kulkarani

BNTP - 514: Lab 4- Synthesis of Nanomaterials (Credit- 2)

Objectives:

1) This practical course will provide student better understanding of different techniques for

synthesis of nanoparticles

2) To gain knowledge in optimization of reaction conditions for synthesis of nanomaterial’s

Practical’s

1. Synthesis of Fe2O3 by Solvothermal method

2. Synthesis of silver nanoparticles by chemical method

3. Synthesis of TiO2 nanoparticles by using sol-gel method

4. Synthesis of Fe2O3 by sol-gel method

5. Synthesis of ZnO nanorods by hydrothermal method

6. Synthesis of Graphene oxide by modified Hummers method

7. Synthesis of Polyaniline nanofibers by CBD method

8. Electrodeposition of Cu

9. Synthesis of CdS nanoparticles by SILAR method

10. Synthesis of Nickel ferrite by hydrothermal method

11. Transparent conducting oxides by spray pyrolysis method

12. Preparation of superhydrophobic nanocoatings by spin coating method

13. Synthesis of Fe2O3 by SILAR method.

Learning Outcomes:

1) Student will able to know principle and working of various synthesis method.

2) Student will able to have an idea about the growth mechanism of nanomaterials.

3) Student will able to understanding the how to handle the synthesis methods.

Reference Book:

1. Nanotechnology: Principles and Practices by S. K. kulkarani

Paper: BNTT – 509 : Prevantion of Pollution I (Credit- 2)

Objectives:

1) To study the Bottom up method for nanoparticals synthesis

2) To study the basic principle of different microscopies

3) To study the application of microscopy

Unit 1: Water and Soil pollution (9 Lectures)

Environmental pollutants in water & soil, hazardous and toxic wastes, waste water

characteristics and parameters. Traditional water Treatment, nanomaterial Contamination in

Aqueous Environmental, Ground water pollution, sources, effects, control,

Unit 2 : Prevention and Control of Pollution: (9Lectures)

Current Nanotechnology for water treatment: Activated Carbon-A Simple Traditional

Nanotechnology, Membranes and separation Technology.

The Environment (Protection) Act, 1986, The Water (Prevention and Control of Pollution) Ac

t, 1974..

Unit 3: Water treatment: (6 Lectures)

Ground water pollution, sources, effects, control, consequences of ground water pollution.

Nanomaterials, Sources Nanoparticles in Drinking water, Domestic and industrial wastewater.

Nano‐technologies used in Water Treatments, Effluent Treatments.

Unit 4: Air pollution & Nano-toxicology : (6 Lectures)

Toxicity due to airborne Nanomaterials, Engineered nanomaterial’s in the environment and

Health Effects of Nanoparticles through Air, Absorption and pulmonary deposition of

Nanoparticles, Elimination of dusts deposited in the lungs, Nanoparticles absorption

mechanisms from air, Effects of ultrafine dusts.

Gas Separation: Advanced Membrane Technology , Chemical Sensing and Detection.

The Air (Prevention and Control of Pollution) Act, 1981

Reference Books:

1. Handbook of microscopy for nanotechnologyby nan yao princeton university princeton, nj, usa

zhong lin wang.

2. Introduction to nanomaterials and nanotechnologyv. Pokropivny, r. Lohmus, i. Hussainova, a.

Pokropivny, s. Vlassov.– university of tartu.

3. Handbook of vacuum science and technology by dorothy m. Hoffman

4. Nanotechnology: Principles and Practices by S. K. kulkarani

Paper: BNTT – 510 : Prevantion of Pollution II (Credit- 2)

Objectives:

1) To study the Bottom up method for nanoparticals synthesis

2) To study the basic principle of different microscopies

3) To study the application of microscopy

Unit 1: The Environmental and Applied Nano-Technology (9 Lectures)

Traditional Methods of Detecting, Environmental Contaminants, Type of Environmental Sensors,

Sensing of chemical pollutants (Gas sensors: Introduction),basic sensing mechanism

Unit 2: Application of TiO2 (9 Lectures)

Application of TiO2, Solar Energy and Nanotechnology, Important characteristics and

environmental applications of Mesoporous materials

Unit 3: Green Nanotechnology (6 Lectures)

Definition and principles of Green Chemistry and it’s significance, Biosynthesis of nanoparticles

from plants, fungi & microorganisms and their application. Energy efficient resources and materials

in Nanotechnology, Biological Sensors and Detectors and their applications

Future aspects and importance of Nanotechnology in environmental conservation

Unit 4: Photocatalytic degradation (6 Lectures)

Photocatalytic degradation of organic pollutants in waste water: Introduction, basic mechanism and

operating principle of photocatalysis, fabrication of TiO2 nanotubes by aqueous and non‐aqueous

electrolytes, photocatalytic activity of TiO2 nanotubes.

Introduction to biosensors: Introduction, application of TiO2 nanotubes as biosensors.

Reference Books:

1. Handbook of microscopy for nanotechnologyby nan yao princeton university princeton, nj, usa

zhong lin wang.

2. Introduction to nanomaterials and nanotechnologyv. Pokropivny, r. Lohmus, i. Hussainova, a.

Pokropivny, s. Vlassov.– university of tartu.

3. Handbook of vacuum science and technology by dorothy m. Hoffman

4. Nanotechnology: Principles and Practices by S. K. kulkarani

BNTP - 515: Lab 4- Prevention of Pollution (Credit- 2)

Objectives:

1. To study the sampling method.

2. To study the alkalinity and acidity of water sample.

3. To study the COD and BOD of water.

4. To study the hardness of some chemicals.

5. To study the properties of mineral and rocks.

PRACTICALS

1. Environmental Sampling methods and analytical preparations

2. Air pollution monitoring and analysis

3. Determination of total alkalinity and acidity of a water sample.

4. Chemical Oxygen Demand, Dissolved Oxygen and Biological Oxygen Demand

5. Total Hardness, Sulphates , Nitrates and Chlorides

6. Physical Properties of Minerals, ore and Rocks

7. Optical properties of Minerals and Study of crystal systems

8. Photogrammetry, Interpretation of Aerial Photographs / Digital Image Processing

9. Data capturing through GPS and Study of GIS softwares.

Learning outcomes:-

1) Students will able to know protection of natural source.

2) Students will able to know purification of water.

3) Students will able to know properties of minerals.

4) Students will able to know the COD and BOD of water.

Reference Books:

1. Handbook of microscopy for nanotechnologyby nan yao princeton university princeton, nj, usa

zhong lin wang.

2. Introduction to nanomaterials and nanotechnologyv. Pokropivny, r. Lohmus, i. Hussainova, a.

Pokropivny, s. Vlassov.– university of tartu.

3. Handbook of vacuum science and technology by dorothy m. Hoffman

4. Nanotechnology: Principles and Practices by S.K. Kulkarani.

Paper: BNTT - 601: Physics: Solid state physics (Credit- 2)

Objectives

1. To understand atomic stuctures

2. To understand properties of matter and its application

3. To understand band structure of solids

Unit-1 Atomic Structures. (6 lectures)

The Rutherford model of the atom,theory and conculsion,Bohr atomic model, Bohr's theory of

hydrogen atom,The hydrogen spectrum ,sommerfeld's relativistic atom model,elliptical orbits of

hydrogen,vector atom model,The Pauli's Exclusion principle.

Unit-2 Properties of matter. (8 lectures)

Introduction,lattice points amd space lattice ,crystal system, classical free electron theory of

metals,quantum theory of free electeons, classical.wave equation ,schrodingers wave equation and

its importance, electrical.conductivity from quantum

mechanical.consideration,thermal.conducyivity,magnetic properties of materials

Unit- 3. Elementary Band Theory of Solids (8 lectures)

Concept of density of states, Bloch theorem (statement only), Kroning–Penny model, Origin of

energy gap, Velocity of electrons according to band theory, Effective mass of an electron,

Distinction between metals, semiconductors and insulators, Hall Effect - Hall voltage and Hall

Coefficient.

Unit-4 Crystal imperfection (8 lectures)

Introduction, point defects,vacancies,schottky defects and frankel defects,derivation for no.of

vacancies in crystal,compositional defect,electronic defect,line imperfection,screw

disloaction,Burger vector,surface imperfections,grain boundaries,twin boundaries,stacking defects.

Learning Outcomes:

Students should be able to understand

1. various theories made by scientists to understand atomic struture

2. Experiments done by scientists to define closest stucture of atom and drawbacks of their theories

3. Use this knowledge to understand nature of atom under different circumstances.

4. Types of matter

5. Properties of matter

6. Analysing effects of pressure,temperature etc on the formation of matter and its changing

properties.

7. Solving problems related to thermal.electical properties

8. Band stuctures in solids

9. Differences between metals,semiconductor and insulators

10. Analysics hall effect.

11. Various types of imperfections in solids

12. Change in properties of solids due to defects

13. Calcualting no. Of vacancies created in solid stuctures.

Reference Books

1) Introduction to Solid State Physics, Charles Kittle, 8th

Ed.,2004,Wiley India Pvt. Ltd.

2) Elements of Solid State Physics, J.P. Srivastava, 2nd

Ed., 2006,Prenice-Hall of India

3) Introduction to Solid, Leonid V.Azaroff,2004,Tata Mc-Graw Hill

4) Solid State Physics, Neil W. Aschroft and N. David Mermin, 1976, Cengage Learning

5) Solid State Physics,Rita John,2014,Mc-Graw Hill

6) Solid State Physics, Adrianus J. Dekker, Macmillan Publishers India Ltd.

7) Solid State Physics, M.A.Wahab,3rd

Ed.,2018,Narosa Publishing House Pvt. Ltd.

8) Solid State Physics, S.O.Pillai,5th

Ed., New Age International(P) Ltd., Publishers.

9) Fundamentals of Solid State Physics, Saxena-Gupta-Saxena, (PragatiPrakashan Meerut)

10) Solid State Physics, R. L. Singhal

11) Solid State Physics, C.M. Kachhava (Tata McGraw Hill Publication)

12) Elements of X-ray diffraction, B.D.Cullity and S.Stock

B.Sc. Part-III Semester-VI

Paper: BNTT - 602: Physics: Nuclear and Particle Physics (Credit- 2)

Objectives:

1. To understand properties of nucleus.

2. To understand mechanism of particle accelerators.

3. To study nuclear detectors.

UNIT 1: General Properties of Nuclei and Nuclear Model (8 lectures)

Constituents of nucleus and their intrinsic properties, Quantitative facts about size, mass, charge

density (matter energy), binding energy, average binding energy and its variation with mass

number, Liquid drop model approach, Semi empirical mass formula, Magic numbers.

UNIT 2: Particle Accelerators (8 lectures)

Need of accelerators,Cyclotron- construction, working,theory and its limitations,Principle of phase

stable orbit, Synchrocyclotron - construction and working, Synchrotrons- electron synchrotron and

proton synchrotron, Betatron - principle, construction and workingcondition, expression of energy

gain.

UNIT 3: Nuclear Detectors (8 lectures)

Ionization chamber, Geiger Muller counter- construction, working and theory, dead time and

recoverytime, quenching mechanism, Construction of photo-multiplier tube (PMT), Scintillation

detector-principle, construction and working, Wilson cloud chamber, Semiconductor detector,

Cerenkov radiations, Cerenkov detector.

UNIT 4: Particle Physics (8 lectures)

Particle interactions, Classification of elementary particles, Symmetries and conservation laws-

energy,momentum, angular momentum and parity, Baryon number, Lepton number, Concept of

quark model.

Learning Outcomes

Students shloud be able.to understand

1. Intrinsic Nuclear properties

2. Importance of magic numbers

3. Calculate binding energy

4. Importance of particle accelerator

5. Applications of particle accelerators

6. Various types nuclear detectors

7. Use of detectors

8. Importance of detectors

9. Varous particles present in nucleus

10. Importance of nuclear particles

11. Use of nuclear particles.

Reference Books

1. Introductory Concepts of nuclear physics, Bernard L. Cohen. (Tata Mcgraw Hill, 1998).

2. Introduction to the physics of nuclei & particles, R.A. Dunlap. (Thomson Asia, 2004)

3. Introduction to Elementary Particles, D. Griffith, John Wiley & Sons

4. Quarks and Leptons, F. Halzen and A.D. Martin, Wiley India, New Delhi

5. Basic ideas and concepts in Nuclear Physics - An Introductory Approach by K. Heyde

(IOP-Institute of Physics Publishing, 2004).

6. Radiation detection and measurement, G.F. Knoll (John Wiley & Sons, 2000).

7. Theoretical Nuclear Physics, J.M. Blatt &V.F.Weisskopf (Dover Pub.Inc., 1991)

8. Nuclear Physics by John Lilley,The Manchester Physics Series – Willy

9. Nuclear Physics by S. B. Patel, New age international (p) lit. Publishers New Delhi.

10. Modern Physics by R. Murugeshan, S. Chand & company Ltd, Ram Nagar New Delhi

12. Nuclear Physics by D. C. Tayal, Himalaya Publishing house

13. Concept of modern physics by ArthirBeiser, Tata McGraw- Hill publishing company ltd. New

Delhi

14. Atomic and nuclear structure by D. K. JHA, Discovery publishing house New Delhi

15. Nuclear energy by D. K. JHA Discovery publishing house New Delhi)

16. Nuclear physics by S. N. Ghoshal , S. Chand & company Ltd, Ram Nagar New Delhi

BNTP-611 solid state physics and nuclear physics

Marks - 50 (Credits)

Objectives

1. To understand properties of solids

2. To analyse hysteresis curve

3. To understand hall effect

1. Measurement of resistivity of given thin film.using two probe.method

2. Thermal conductivity of metal using searles apparatus

3. Hysteresis using CRO

4. Surface tension of mercury

5. Study of bandgap energy using semiconductor diode

6. IV characteristics of solar cell

7. Polar graph using photocell

8. Study of temperature transducer

9. Magbetic susceptiblity

10. Hall effect

11. Determination of density and mobility of charge carriers in p- germanium

Learning outcomes

Students should be able to

1. Understand methods for analysing properties of solis

2. Measure thermal conductivity

3. Measure hall voltage and charge densoty using hall effects instrument

4. Understand effects of intensity of light on cuurent and voltage of solar cell

5. Measure magnetic susceptiblity of materials

6. Handle vaious instruments with ease

Paper : BNTT - 603: Chemistry XI: Physical Chemistry (Credit2)

Objectives:

1) To enhance student sense of enthusiasm for chemistry and to involve them in an intellectually

stimulating experience of learning in a supportiveenvironment

2) To study the properties d and f blockelement.

3) To study the all coordination theory withexample.

Unit 1: Thermodynamics (08 lectures)

Introduction.Free energy: Gibbs function (G) and Helmholtz function (A), Criteria for

thermodynamic equilibrium and spontaneity. Relation between ∆G and ∆H : Gibbs-Helmholtz

equation.Phase equilibria : Clapeyron – Clausius equation and its applications. Thermodynamics

derivation of law of mass action, Van’t – Hoff isotherm and isochore. Fugacity and activity

concepts. Partial molar quantities, Partial molar volume, Concept of chemical potential, Gibbs-

Duhem equation. Numerical problems.

Unit 2: Chemical Kinetics (08 lectures)

Introduction.Simultaneous reactions such as: Opposing reaction: (Derivation of rate equation for

first order opposed by first order expected).Side reaction.Consecutive reactions.Chain

reaction.Explosive reaction (Derivation of rate equation and Numerical problems are not expected).

Unit 3: The Solid State (06 lectures)

Introduction: Space lattice, lattice sites, lattice planes, unit cell.Laws of crystallography:

Law of constancy of interfacial angles, Law of rational indices, Law of crystal symmetry.

Weiss indices and Miller indices.Cubic lattice and types of cubic lattice, planes or faces of a simple

cubic system, spacing of lattice planes.Diffraction of X-rays, Derivation of Bragg’s

equation.Determination of crystal structure by Bragg’s method.Determination of crystal structure of

NaCl and KCl on the basis of Bragg’s equation. Numerical problems.

Unit 4 : Solutions (08 lectures)

Introduction.Ideal solutions, Raoult’s law, Vapour pressure of ideal and non ideal solutions of

miscible liquids.Composition of liquid and vapour, vapour pressure and boiling point diagrams of

miscible liquids. Distillation of miscible liquid pairs.Type I : Systems with intermediate total

vapour pressure (i.e. System in which b.p. increases regularly – Zeotropic). Type II : Systems with

a maximum in the total vapour pressure (i.e. System with a b.p. minimum – Azeotropic). Type III :

Systems with a minimum in the total vapour pressure (i.e. System with a b.p. Maximum –

Azeotropic). Solubility of partially miscible liquids. Maximum solution temperature type: Phenol –

water system.Minimum solution temperature type: Triethyl amine – water system.Maximum and

minimum solution temperature type: Nicotine – water system.Distillation of partially miscible

liquid pairs.Vapour pressure and distillation of immiscible liquids, steam distillation.

Learning Outcomes:

Students will able to know

1. General introduction of electrochemistry

2. Types of electrode

3. Concept of Gibbs and Helmhotz function

4. Geiger Nuttal relation

Reference Books

1. Textbook of Physical chemistry, P. L. Sony, O. P. Dharmarha, U.N. Das by Sultan Chand and S.

publication.

2. Principle of physical chemistryPuri Sharma, Patania by Vishal publishings. Co.44th

edition.

3. Textbook of physical chemistry, A. S. Negi, S. C. Anand New age

internationalpublishers.2nd

edition.

4. Physical chemistry, W. Atkins low pricededition.

5. Physical chemistry, G. K. Vermulapalli by Printice hall of India Pvt. Lmt eastern economyedition.

Paper: BNTT - 604: Chemistry XII: Spectroscopy and Photochemistry (Credit2)

Objectives:

1) To study of different types of spectroscopy .

2) To study of Raman spectra

3) To study of different Laws of photochemistry.

Unit 1: Spectroscopy (08 lectures)

Introduction. Electromagnetic radiation. Interaction of radiation with matter, Electromagnetic

spectrum, Energy level diagram. Electronic Spectra (UV-Vis), Modes of electronic transitions.

Rotational spectra of diatomic molecules: Rigid rotor model, moment of inertia, energy levels of

rigid rotor, selection rules, Intensity of spectral lines, determination of bond length, isotope effect,

Microwave oven. Vibrational spectra of diatomic molecules: Simple Harmonic oscillator model,

Vibrational energies of diatomic molecules, Determination of force constant, Hook’s Law for

Calculation of vibrational frequency, overtones.

Unit 2: Raman spectra: (08 lectures)

Concept of polarizability, pure rotational and pure Vibrational Raman spectra of diatomic

molecules, selection rules. Comparative study of IR and Raman spectra, rule of mutual exclusion-

CO2 molecule.

Unit 3: NMR and ESR (06 lectures)

Magnetic Resonance (NMR and ESR). Magnetic and nonmagnetic nuclei, Chemical shift:

definition, measurement, calculation, Factors affecting Chemical shift, Shielding & deshielding.

Numerical problems.

Unit 4 : Photochemistry (08 lectures)

Introduction, Difference between thermal and photochemical processes. Laws of photochemistry: i)

Grotthus - Draper law ii) Lambert law iii) Lambert – Beer’s law (with derivation) iv) Stark-

Einstein law. Quantum yield, Reasons for high and low quantum yield. Factors affecting Quantum

yield. Photosensitized reactions – Dissociation of H2, Photosynthesis. Photodimerisation of

anthracene. Jablonski diagram depicting various processes occurring in the excited state:

Qualitative description of fluorescence and phosphorescence. Chemiluminescence,

Electroluminescence and Bioluminescence. Numerical problems.

Learning Outcomes:

Students will able to know

1. Rotational spectra of diatomic molecule .

2. Comparative study of IR and Raman spectra.

3. Numerical problems related spectroscopy .

4. Jablonski diagram depicting various processes occurring in the excited state.

Reference Books:

1. Instrumental methods of chemical analysis by Chatwal andAnand,5th Edition, HimalayaPublication.

2. FundamentalsofmolecularspectroscopybyC.N.Banwell–Tata McGraw-Hill.

3. Quantum Chemistry including molecular spectroscopy by B. K.Sen,Tata Mc Graw –Hill.

4. Instrumental methods by H. Kaur.

5. Introduction of spectroscopy by Y, R. Sharma.

BNTP - 612: Lab 2- Chemistry (Credit- 2)

Objectives:

1) The aim of the practical course is the ability to perform accurate quantitative measurements with

and understanding of the theory and use contemporary chemical instrumentation, interpret

experimental result, perform the calculation these results and draw reasonably, accurateconclusion.

2) To expose the students to the ability to present scientific and technical information resulting from

laboratory experimentation in both written and oral formats.

BNTP - 612: Lab 2- Chemistry (Credit- 2)

PRACTICALS

I. Non instrumentalExperiments:

A. Any two of the following

i) PartitionLaw.

To determine the partition coefficient of CH3COOH between H2O and CCl4.

ii) Viscosity.

To determine the viscosity average molecular weight of a polymer.

iii) Adsorption.

To investigate the adsorption of oxalic acid by activated charcoal and test the validity of

Freundlich & Langmuir isotherms.

iv) Solubility.

To study the effect of addition of electrolyte (NaCl or KCl) on the solubility of Benzoic

acid at roomtemperature.

B. Chemical kinetics. (Anytwo)

1. The study of energy of activation of first order reaction i.e. hydrolysis of methyl acetate in

presence of 0.5 N HCl / 0.5 NH2SO4.

2. The study of energy of activation of second order reaction i.e. reaction

between K2S2O8 and KI (Equalconcentrations).

3. The study of energy of activation of second order reaction i.e. reaction

between K2S2O8 and KI (Unequalconcentrations).

4. Tostudythehydrolysisofmethylacetatebyusingitstwoconcentrationsinpresenceof

0.5 N HCl and hence find velocity constant of the reaction.

5. To study the effect of addition of electrolyte (KCl) on the reaction between K2S2O8 and KI

(Equal concentrations).

C. Partial molarvolume.

1. To determine the partial molar volume of ethyl alcohol in a mixture of ethyl alcohol and water

(Any seven mixtures be given).

II. Instrumental experiments

A. Potentiometry (Any two)

1. Titration of strong acid with strongalkali.

N.B.i)8to10mlof1Nacidsolutiontobegivenbyexaminerin100ml volumetric flask & student should

dilute it to 100 ml and10mlof this solution is taken fortitration.

ii) Experiment is carried out by taking pilot run from 1 to 10ml and then final runtaking 0.2 ml

reading in the range of endpoint.

2. Preparation of buffer solution and determination of their pH (Any five buffer solutions).

Theoretical calculation of pH values by using Henderson’sequation.

3. DeterminationofstandardelectrodepotentialofZn/Zn++

,Cu/Cu++

,Ag/Ag+(Anytwo).

4. Estimate the amount of Cl-, Br

- and I

- in given unknown halide mixture by titrating it

against standard AgNO3solution.

5. Titration of ferrous ammonium sulphate using K2Cr2O7 solution and to calculate redox

potential of Fe++

, Fe+++

system.

B. Conductometry (Any two).

N.B.i)8to10mlof1Nacidsolutiontobegivenbyexaminerin100ml volumetric flask & student should

dilute it to 100 ml and10mlof this solution is taken fortitration.

1. Titration of a mixture of weak acid and strong acid with strongalkali

2. To study the effect of substituent on dissociation constant of weak acid with respect to

acetic acid and monochloroacetic acid (cell constant to begiven).

N.B. Calculate K by using formula K= α2.C/1- α

3. To determine the velocity constant of hydrolysis of ethyl acetate by NaOH solution by

conduct metricmethod.

4. To determine the normality of citric acid in lemon by titrating it against standard 0.2 N

NaOH solution by conduct metricmethod.

5. To determine λ∞ of strong electrolyte (NaCl or KCl) and to verify Onsagerequation.

C. Refractometry. (Any One )

1. To determine the percentage composition of unknown mixture by(i) graphical method and

(ii) by composition law (Densities of pure liquids A & B be given).

2. To determine the molar refractivity of methyl acetate, ethyl acetate, n-hexane and carbon

tetrachloride and calculate the refraction equivalents of C, H and Clatoms.

D. Colorimetry (AnyTwo).

1. To verify Lambert – Beer’s law using CuSO4solution.

2. To estimate of Fe+++

ions by thiocynatemethod.

3. To estimate Fe+++

ions using salicylic acid by colorimetrictitration.

4. To determine the order of reaction for the oxidation of alcohol by potassium dichromate and

potassium permanganate in acidic medium colorimetrically.

E. pH – metry (AnyOne).

1. To determine the dissociation constant of monobasic acid (Aceticacid).

2. To determine the dissociation constant of dibasic acid (Malonicacid).

3. To determine hydrolysis constant of anilinehydrochloride.

Learning Outcomes:

1. Student will able to know

2. pH metric, conductometric, potentiometric titration.

3. Estimation of nitrogen, sap value of oil.

4. Estimation of glucose

5. Preparation of organic compound

Reference books

1. Svehla, G. Vogel’s Qualitative Inorganic Analysis, PearsonEducation,2012.

2. Mendham, J. Vogel’s Quantitative Chemical Analysis,Pearson,2009.

3. Khosla, B. D.; Garg, V. C. & Gulati, A. Senior Practical Physical Chemistry, R. Chand & Co.:

New Delhi(2011).

Paper:BNTT -605:Biotechnology XI :Molecular Biology I (Credit- 2)

Objectives:

1) To study structure and functions of Nucleic acid.

2) To study component of DNA replication.

3) To study the Prokaryotic replication.

4) To Study the Eukaryotic replication.

5) To study of Transcription in prokaryotic and Eukaryotic cell.

6)

UNIT1: Nucleic acid: (04 Lectures)

History, nucleic acid as genetic material. Nucleic Acid Structure and Chemistry, nitrogenous bases,

purine and pyrimidine bases Sugar–Phosphate Chain Conformations, Base Pairing, Base Stacking,

Hydrophobic and Ionic Interactions. Different forms of DNA, A form, B,form, Z form. Other

Functions of Nucleotides.

UNIT2: DNA Replication: (10 Lectures)

An Overview, Replication Forks, Role of DNA Gyrase, Semidiscontinuous Replication, RNA

Primers. Enzymes of Replication, DNA Polymerase I, DNA Polymerase III, Unwinding DNA:

Helicases and Single‐Strand Binding Protein, DNA

Ligase, Primase, Topoisomerase,

Prokaryotic Replication: Escherichia coli, Fidelity of Replication

UNIT3: Eukaryotic Replication: (08 Lectures)

The Cell Cycle, Eukaryotic Replication Mechanisms, Reverse Transcriptase, telomeres and

Telomerase. Repair of DNA, Direct Reversal of Damage, Excision Repair, Mismatch Repair, The

SOS Response, Double‐Strand Break Repair Identification of Carcinogens.

UNIT4: Transcription: (08 Lectures)

The Role of RNA in Protein Synthesis, Enzyme Induction, Messenger RNA. RNA Polymerase,

Template Binding, Chain Initiation, Chain Elongation, Chain Termination Eukaryotic RNA

Polymerases

PostTranscriptional Processing: Messenger RNA Processing, Ribosomal RNA Processing,

Transfer RNA Processing

Learning outcomes:-

1) Students will able to know structure and functions of Nucleic acid.

2) Students will able to know component of DNA replication.

3) Students will able to know the Prokaryotic replication.

4) Students will able to know the Eukaryotic replication.

5) Students will able to know of Transcription in prokaryotic and Eukaryotic cell.

Reference Books:

1. Molecular Biology of the Cell by Bruce Alberts

2. Molecular biology of the Gene by Watson

3. The Cell, a molecular approach by Cooper and Hausman

4. The Cell Biology by Gerald Karp

5. Sambrook J, Fritsch E. F. and Maniatis (1989) Molecular cloning, vol. I, II, III, 2nd

6. edition, Cold spring harbor laboratory press, New York.

7. DNA Cloning : A practical approach D.M. Glover and D.B. Hames, RL Press, Oxford,

8. 1995)

Paper: BNTT -606:Biotechnology XII :Molecular Biology II (Credit- 2)

Objectives:

1) To study the translation process.

2) To study of pst translational modification.

3) To study the process and application of PCR.

4) To Study the blotting technique for DNA and RNA seperation.

5) To study the recombinant DNA technology.

UNIT I : Translation: (08 Lectures)

The Genetic, Nature of the Code, Codons. Transfer RNA and Its Aminoacylation, Primary and

Secondary Structures of tRNA, Tertiary Structure of tRNA Aminoacyl–tRNA Synthetases, Codon–

Anticodon Interactions, Nonsense Suppression

Ribosomes and Polypeptide Synthesis: Ribosome Structure, Polypeptide Synthesis: An

Overview, Chain Initiation Chain Elongation, Translational Accuracy, Chain Termination, Protein

Synthesis Inhibitor,Antibiotics.

Control of Eukaryotic Translation: A. Regulation of eIF2, Regulation of eIF4E, mRNA

Masking and Cytoplasmic Polyadenylation, Antisense Oligonucleotides.

PostTranslational Modification: Proteolytic Cleavage, Covalent Modification, Protein Splicing:

Inteins and Exteins.

UNIT II : Nucleic Acids and Allied Techniques: (07 Lectures)

Isolation of DNA from plants, animals and microbial sources, Isolation of plasmid DNA, Agarose

gel electrophoresis

PCR,

Hybridization Methods: Probes – Labeling of probes- Radioactive and non-radioactive probes -

Detectiontechniques, Southern hybridization, Northern hybridization, Western blotting

DNA sequencing: Sanger’s method, Maxam‐Gilbert method

UNIT III: Recombinant DNA Technology: (07 Lectures)

Enzymes involved: Taq polymerase, Restriction endonucleases, Exonucleases, End modification

enzymes, Ligases

Vectors: Properties of a good vectors, Plasmids, Phages, Cosmids, Artificial vectors, Animal Virus

derived vectors

Transformation: Chemical and physical methods, Role of Agrobacteria (Ti and Ri plasmids)

Construction of cDNA libraries, Cloning libraries

Applications of Recombinant DNA Technology: Transgenics and their applications in Medicine,

Agriculture and Veterinary science

UNIT IV: (08 Lectures)

Nanoparticles for nucleic acid delivery: Nanoparticles for DNA delivery, Nanoparticles for

mRNA deliver, Nanoparticles for gene editing. Lipid-based nanoparticles, Gold nanoparticles based

delivery, Chitosan nanoparticles based delivery, solid lipid nanoparticles based delivery, composite

nanoparticles based delivery.

Learning outcomes:-

1) Students will able to know the translation process.

2) Students will able to know of post translational modification.

3) Students will able to know the process and application of PCR.

4) Students will able to know the blotting technique for DNA and RNA seperation.

5) Students will able to know the recombinant DNA technology.

Reference Books:

1. Molecular Biology of the Cell by Bruce Alberts

2. Molecular biology of the Gene by Watson

3. The Cell, a molecular approach by Cooper and Hausman

4. The Cell Biology by Gerald Karp

5. Sambrook J, Fritsch E. F. and Maniatis (1989) Molecular cloning, vol. I, II, III, 2nd

6. Genetic Engineering : An Introduction to Gene Analysis and Exploitation in Eukaryotes, S. M.

Kingsman, Blackwell Scientific Publications, Oxford, 1998.

BNTP - 613: Lab 3- Biotechnology (Credit- 2)

Objectives:

1) To study the DNA and RNA isolation from different source.

2) To study DNA amplification by PCR .

3) To study the isolation of plasmid.

4) To study isolation of protein.

5) To study of protein separation by PAGE.

PRACTICALS

1. Isolation of DNA from bacterial, plant and fungal sources

2. Quantitative estimation of DNA (spectrophotometer).

3. Separation of DNA by Agarose Gel Electrophoresis

4. Demonstration of PCR

5. Amplification of DNA by PCR

6. Preparation of competent cells

7. Plasmid Transformation in competent cells.

8. Isolation of plamids by miniprep method

9. Isolation of plamids by midiprep method.

10. Isolation of RNA

11. Isolation of proteins

12. Separation of proteins by SDS PAGE

13. Separation of proteins by Native PAGE.

14. Demonstration of DNA sequencer

Learning outcomes:-

1) Students will able to know the DNA and RNA isolation from different source.

2) Students will able to know DNA amplification by PCR .

3) Students will able to know the the isolation of plasmid.

4) Students will able to know protein separation by PAGE.

Reference Books:

1. Practical Biochemistry: An Introductory Course by Fiona Frais.

2. Textbook of Practical Biochemistry by David Plummer.

3. Laboratory Mannual in Biochemistry by S. Jayaraman.

Paper: BNTT - 607: Science at nanoscale: Properties of Nanomaterials I (Credit- 2)

Objectives:

1) To study thephysical properties of nanomaterials

2) To study the mechanical properties of nanomaterials

3) To study the electrical properties of nanomaterials

4) To study the thin film technology.

Unit 1: Physical Properties of Nanomaterials (6 Lectures)

Mechanical Characterization – Plastic deformation,Toughness,Stiffness,Ductility, modulus and

load carrying capability, fatigue – abrasion and wear resistance etc. Stress-Strain Curve. Hardness

of nanomaterials:nanoindentation. Nanomachines.

Unit 2: Mechanical properties of Nanomaterials(8 Lectures)

Mechanical properties of CNT. Micro Electromechanical Systems (MEMS), Nano

Electromechanical Systems (NEMS).Thermodynamics of Nanomaterials: Melting point and phase

transition processes at nanoscale materials. Classical thermodynamics Vs Nano thermodynamics.

Unit 3: Electronic Properties of Nanomaterials: I (7 Lectures)

Density of states of 3D, 2D, 1D and 0D dimensional nanostructures. Clusters of metals and

semiconductors, nanowires. Size-induced metal-insulator-transition (SIMIT). Electronic transport

in 1,2 and 3 dimensions. Effective mass.

Unit 4: Electronic Properties of Nanomaterials: II (9 Lectures)

Drude conduction of metals - mean free path in 3D-diffusive transport and ballistic conduction.

Coulomb blockade. Single electron transistors (SET), Tunnel diodes: Esaki tunneling diode (ETD),

Resonant tunneling diode (RTD).Fundamentals of electrical conductivity in carbon nanotubes.

CNT based transistor, electrical conductivity of nanocomposites.

Learning Outcomes:

1) Student will able to understand physical, electrical and mechanical properties of nanomaterials.

2) Student will able to know concept of density of states.

3) Student will able to understand concept of quantum confinement.

4) Student will able to understand tunnel diodes.

Reference Books:

1. Optical properties and spectroscopy of nanomaterials jinzhngzhang university of California.

2. Nanotechnology: principles and practices by s. K. Kulkarani

3. An introduction to nanoscience and nanotechnology alainnouailhat.

4. Materials science and engineeringwilliam d. Callister, jr. David g. Rethwisch

5. Microsystems and nanotechnologyzhaoyingzhouzhonglinwangliweilin

Paper: BNTT - 608: Science at nanoscale: Properties of Nanomaterials II (Credit- 2)

Objectives:

1) To study the optical properties of Nanomaterials

2) To study the magnetic properties of Nanomaterials

3) To study theoptoelectronic applications

Unit 1: Optical properties of Nanomaterials: I (9 Lectures)

Interaction of light with matter: Absorption- Emission. Direct and indirect band gap transitions,

radiative-non radiative process, photoluminescence. Surface Plasmon: Interaction of light with

metal, scattering, extinction. Difference between Surface Plasmon Resonance (SPR) and Localized

Surface Plasmon Resonance (LSPR). Origin of color generation from metal nanoparticles, Size and

Shape dependent optical properties of metal nanoparticles. Applications of nano-plasmonics.

Unit 2:Optical properties of Nanomaterials: II (8 Lectures)

Quantum dots (QDs): optical properties of QD nanomaterials. Size dependent band gap tuning:

optical absorption and optical emission. Optical properties of core-shell nanomaterials.

Optoelectronic applications of nanomaterials: detection, PV solar cells, photoelectrochemical cells,

light emitting diodes supercapacitor, batteries etc.

Unit 3: Magnetic properties of nanomaterials: I (6 Lectures)

Origin of magnetism in materials, Classification into Dia-, Para- and Ferro- magnetic materials,

Hysteresis in ferromagnetic materials, domains, soft and hard magnetic materials, Coercivity vs

particle size, Single domain particles, superparamagnetism,

Unit 4: Magnetic properties of nanomaterials: II (7 Lectures)

Exchange coupling in magnetic multilayers (RKKY Coupling), Giant Magnetoresistance (GMR),

Origin of GMR, Oscillatory exchange coupling, spin valve, Magnetic Tunnel Junction (MTJ),Spin

Field Effect Transistor (SFET).

Learning Outcomes:

1) Student will able to understand optical and magnetic properties of nanomaterials.

2) Student will able to understand concept of quantum dots.

3) Student will able to understand concept of surface plasmon resonance.

4) Student will able to know applications of nanomaterials.

Reference Books:

1. Introduction to Nanoscience and Nanotechnology, G. Hornyak, H. Tibbals, J. data, J. Moore.

2. Nanotechnology: Principles and Practices by S. K. kulkarani

3. Nanotechnology : Technology Revolution of 21st Century by Rakesh Rathi, published by S. Chand.

4. Introduction to Nanoscience, by Stuart Lindsay.

5. Introduction to Nanomaterials and nanotechnology by Vladimir Pokropivny, RynnLohmus, Irina

Hussainova, Alex Pokropivny and Sergey Vlassov

BNTP - 614: Lab 4- Properties of nanomaterials (Credit- 2)

Objectives:

1) To gain knowledge of characterization techniques

2) To study analysis of the materials by using characterization technique.

Practical

1. Structural properties of nanomaterials by XRD

2. Analysis of surface morphology by AFM

3. Photocatalytic degradation of dyes

4. Structural properties by STM

5. Quantum size effect in nanomaterials

6. Use of FT-IR for functional group identification (in CNT, graphene etc.)

7. Photoluminescence study of nanomaterials

8. Hall-effect measurement

9. Electrical resistivity of Nanorods and nanotubes

10. Size dependent Hysteresis loop study

11. Determination of crystallite size using Scherrer formula

12. Mechanical properties of nanomaterials

13. Determination of average particle size by frequency distribution curve

14. Surface area to volume ratio of nanosphere and nanowires using TEM image.

Learning Outcomes:

1) Student will able to know principle and working of various characterization techniques.

2) Student will able to have an idea about the crystal structure of materials by using XRD.

3) Student will able to understanding the structural properties by using STM.

4) Student will able to calculate the surface area of colloidal materials by using image of TEM.

Reference Books:

1. Instrumental Analysis Lab manual, M. J. Prushan. CHM 311, 2018.

Paper: BNTT – 609 : Nanobiology and Nanomedicine I (Credit- 2)

Objectives:

1. To study the nanostructure of prokaryotic and eukaryotic cell.

2. To study the intraction between Biomolecules.

3. To study the types of nanomaterials.

4. To study the functions of nanomaterials.

Unit 1: Introduction to Nanobiology and Nanomedicine (6 Lectures)

Nanobiology – Introduction. Biological Nanostructures and natural biological assemblies at

nanoscale: Bacterial S layers, phospholipid membranes, viruses, Nucleic acids, Oligosaccharides,

polysaccharides, biological polymers, Proteins. Biological nanomotors, protein assemblies: Kinesin

and dynein, cilia. Bacterial flagella: structure and function; nanomotor.

Unit 2: Ion channels (6 Lectures)

Ion channels: nanopores of high specificity. Bioinspired nanomaterials: DNA and peptide based.

Interaction between biomolecules and nanoparticle surfaces.Applications of Nanocapsules:

Nanocapsule for efficient delivary of pesticides,fertilizers and other agrochemicals, Liposomal

nanocapsules in food Science and agriculture.

Unit 3: Nanomaterials and nanoformulations (9 Lectures)

Characterization techniques for nanomaterials.Nanobioassemblies: Different types of inorganic

materials used for the synthesis of hybrid nano‐bio Assemblies. Concept of drug and

formulation/dosage form.

Unit 4: Nanobioassemblies: (9 Lectures)

Physicochemical and biological properties ofdrugs. Routes of dosage form administration.

Formulation ofnanocrystals, nanoemulsions, polymeric micelles. Introduction toliposome and

solid lipid nanoparticles (SLN). Fate of nanoformulationsin body.

.

Learning outcomes:-

1) Students will able to know natural nanopartical in organisms.

2) Students will able to know interaction between Biomolecules.

3) Students will able to know types of nanomaterials.

4) Students will able to know the functions of nanomaterials.

Reference Books:

1) Handbook of microscopy for nanotechnologyby nan yao princeton university princeton, nj, usa

zhong lin wang.

2) Introduction to nanomaterials and nanotechnologyv. Pokropivny, r. Lohmus, i. Hussainova, a.

Pokropivny, s. Vlassov.– university of tartu.

3) Handbook of vacuum science and technology by dorothy m. Hoffman

4) Nanotechnology: Principles and Practices by S. K. kulkarani.

Paper: BNTT – 610 : Nanobiology and Nanomedicine II (Credit- 2)

Objectives:

5. To study the nanodignostics.

6. To study the applications of Nanobiology.

7. To study the types of Nanodrug administration.

8. To study the nanorobots.

Unit 1: Nanomedicine : (6 Lectures)

Applications of nano in biology. Concept of disease, Cause and

molecular/cellular progression of key diseases including infectious, inherited diseases,

immunological diseases and cancer. Approach to developing nanomedicines. Various kinds of

nanosystems in use. Nanodrug administration nano‐ devices for drug delivery and theranostics.

Introduction to the potentials, applications and challenges of nanomedicine. Nanomedicine and

tissue engineering, nanobiomachines and nanorobots.

Unit 2: Nanodrug administration (6 Lectures)

Nanodrug administration nano devices for drug delivery and theranostics. Introduction to the

potentials, applications and challenges of nanomedicine. Nanomedicine and tissue engineering,

nanobiomachines and nanorobots.

Unit 3: Applications of nano in biology (9 Lectures)

Concept of disease, Cause and molecular/cellular progression of key diseases including infectious,

inherited diseases, immunological diseases and cancer. Approach to

developing nanomedicines.

Unit 4: Nanodrug administration: (9 Lectures)

Nanoparticles and quantum dots as molecular labels. Diagnostic Nanochips, lab on chips

(microfluidic technology) and microelectromechanical systems (MEMS). Biosensor and

nanobiosensor basic concepts, characterization, perception, Defferent types of nanobiosensors;

Nanobiosensors for medical diagnostics. Nanoprobes for analytical applications.

Learning outcomes:-

1) Students will able to know Diagnosis using nanomaterials.

2) Students will able to know Approach to developing nanomedicines.

3) Students will able to know tissue engineering.

4) Students will able to know the functions of nanomaterials.

Reference Books:

1) Handbook of microscopy for nanotechnologyby nan yao princeton university princeton, nj, usa

zhong lin wang.

2) Introduction to nanomaterials and nanotechnologyv. Pokropivny, r. Lohmus, i. Hussainova, a.

Pokropivny, s. Vlassov.– university of tartu.

3) Handbook of vacuum science and technology by dorothy m. Hoffman

4) Nanotechnology: Principles and Practices by S. K. kulkarani

BNTP - 615: Lab 4- Nanomedicine (Credit- 2)

Objectives:

1. To study the drug diffusion techniqe.

2. To study the formation of nanomedicine.

3. To study the types of nanomaterials.

4. To study the dissolution of tablet.

PRACTICALS

1. Collection of data on various editions of IP, gross additions and deletions per

2. edition and sources of some commonly available drugs.

3. Determination of saturation and Biopharmaceutics solubility of some drugs.

4. Determination of partition coefficient of benzoic acid between water and

benzene.

5. Preparation and evaluation of Paracetamol syrup.

6. Studies on dissolution rate of some tablet formulations.

7. Demonstration of drug diffusion in agar plate.

8. Drug diffusion through polymeric membrane using diffusion cell.

9. Determination of degree of hydrolysis of given ester.

10. Synthesis of metal nanoparticles using synthetic/green route

11. Studies on excretion of drug in urine.

12. Preparation of nanoformulation and its evaluation.

13. Demonstration of design of nanodiagnostics device.

Learning outcomes:-

1) Students will able to know preparation of nanomedicine.

2) Students will able to know about drug diffusion.

3) Students will able to know solubility of chemical compound.

4) Students will able to know the preparation of nanoformulation.

Reference Books:

1. Handbook of microscopy for nanotechnologyby nan yao princeton university princeton, nj, usa

zhong lin wang.

2. Introduction to nanomaterials and nanotechnologyv. Pokropivny, r. Lohmus, i. Hussainova, a.

Pokropivny, s. Vlassov.– university of tartu.

3. Handbook of vacuum science and technology by dorothy m. Hoffman

4. Nanotechnology: Principles and Practices by S.K. Kulkarani.

Evaluation Scheme

B. Sc. III Nanoscience and Technology

Semester V

Course Code

Name of the Course

ESE

Internal Exam

Course Code

Practical Submission

Total

ISE I

Online

Test

ISE II

Exam

Journal

Case study/

Educational

Tour/ Seminar

Day to day

Perform

ance/Project

BNTT-501 Physics-IX 40 5 5 BNTP 511

LAB 1

Physics

30

05

03

02

140 BNTT-502 Physics- X 40 5 5

BNTT-503 Chemistry- IX 40 5 5 BNTP 512

LAB 2

Chemistry

30

05

03

02

140 BNTT-504 Chemistry- X 40 5 5

BNTT-505 Biotech- IX 40 5 5 BNTP 513

LAB 3

Biotechnology

30

05

03

02

140 BNTT-506 Biotech- X 40 5 5

BNTT-507 Science at

Nanoscale I 40 5 5

BNTP 514

LAB 4

Nano I

30

05

03

02

140 BNTT-508

Science at

Nanoscale II 40 5 5

BNTT-509 Environmental

Nanotechnology I 40 5 5 BNTP 515

LAB 5

Nano II

30

05

03

02

140 BNTT-510

Environmental

Nanotechnology II 40 5 5

BNTT –

AECC-3

Scientific Paper

Writing - - - Project 50 100

Total of

SEM V

800

Semester VI

Course Code

Name of the Course

ESE

Internal Exam

Course Code

Practical Submission

Total ISE I Online

Test

ISE II

Exam

Journal

Case study/

Educational

Tour/ Seminar

Day to day

Perform

ance

BNTT-601 Physics-XI 40 5 5 BNTP 611

LAB 1

Physics

30

05

03

02

140 BNTT-602 Physics-XII 40 5 5

BNTT-603 Chemistry- XI 40 5 5 BNTP 612

LAB 2

Chemistry

30

05

03

02

140 BNTT-604 Chemistry- XII 40 5 5

BNTT-605 Biotech- XI 40 5 5 BNTP 613

LAB 3

Biotechnology

30

05

03

02

140 BNTT-606 Biotech- XII 40 5 5

BNTT-607 Properties of

Nanomaterials I 40 5 5

BNTP 614

LAB 4

Nano III

30

05

03

02

140 BNTT-608

Properties of

Nanomaterials II 40 5 5

BNTT-609 Nano biology &

Nanomedicine I 40 5 5

BNTP 615

LAB 5

Nano IV

30

05

03

02

140 BNTT-610

Nano biology &

Nanomedicine II 40 5 5

BNTT -AECC Scientific Paper

Writing - - - Project 50 100

Total of SEM

VI

800

Total of SEM

V

& VI

1600