Arkema New High Performance Long Chain Polyamide 10.10

Rilsan ® TMNO TLD

2

Castor seeds

Castor

HARVESTING

GRINDING

Long Chain PAPA11

MONOMER SYNTHESIS

Castor oil

Synthesis of Arkema PA10.10

Long Chain PA10.10

POLYMERIZATION

100%100%

Bio-based degree: carbon from castor plants

Rilsan T: Arkema new 100% bio-based long chain Polyamide

From monomer to polymer: all in Arkema, high quality guarantee

3

PA 10.10 General Property vs Other PAs

Water absorbance

Barrier Properties

Density

PA

11

Ch

ain

Len

gth

PA66

PA610

PA612

PA1010 PA1012

PA12

Polar Fluids Resistance

Flexibility

Hydrolysis Resistance

� PA10.10: bridge gap between PA6.10/PA6.12 & PA11/PA12

/PA6

4

Density

1

1.02

1.04

1.06

1.08

1.1

1.12

1.14

1.16

PA6 PA610 PA612 PA1010 PA1012 PA12 PA11

(g/c

m3)

PA 10.10 Physical Property vs Other PAs

0

0.5

1

1.5

2

2.5

3

3.5

4

0 2000 4000 6000 8000 10000 12000 14000Mo

istu

re u

pta

ke

(%

)

immersion time in water (hrs)

Moisture uptake

PA6.10

PA6.12

PA10.10

PA10.12

PA12

PA11

Immersion in distillation water under room temperature

5

600

1100

1600

2100

2600

3100

3600

170 180 190 200 210 220 230 240 250 260 270 280

Melting Point °C

Ten

sil

e M

od

ulu

s (

MP

a)

PA6.10

PA6.12

PA10.10PA12

PA10.12

PA11

PA6

PA6.6

600

1100

1600

2100

2600

3100

3600

170 180 190 200 210 220 230 240 250 260 270 280

Melting Point °C

Ten

sil

e M

od

ulu

s (

MP

a)

PA6.10

PA6.12

PA10.10PA12

PA10.12

PA11

PA6

PA6.6

PA10.10 Mechanical Properties

Tensile modulus (23℃, 50% RH) vs melting point

400

600

800

1000

1200

1400

1600

1800

2000

170 180 190 200 210 220 230

PA6.10

PA6.12

PA10.10PA12

PA10.12

PA11

400

600

800

1000

1200

1400

1600

1800

2000

170 180 190 200 210 220 230

PA6.10

PA6.12

PA10.10PA12

PA10.12

PA11

6

Physical Properties

� Density Rilsan T>Rilsan>Rilsamid

� Tm Rilsan T>Rilsan > Rilsamid, thus for short term heat resistance Rilsan T is best

� Rilsan ®TMNO TLD has similar color as Rilsan, Rilsamid natural color grade

Physical Property Rilsan® TMNO TLD Rilsan® BMNO TLD Rilsamid® AMNO TLD

Density (g/cm3) 1.04 1.03 1.02

Melting point (℃℃℃℃) 202 189 178

L/a/b 90/0.5/6 85/0.4/6 85/0.9/3

YI 13 13 8

Shrinkage* (MD/TD, 0 hr) 0.9/1.0 0.8/0.8 0.8/0.9

Shrinkage* (MD/TD, 24 hrsunder 23℃℃℃℃ 50% humidity)

1.1/1.2 1.0/1.0 0.9/1.0

* 100×100×1 mm plate, mold temperature: 40℃

7

Rheology Properties

Rheology Property Rilsan® TMNO TLD Rilsan® BMNO TLD Rilsamid® AMNO TLD

MFI (g/10min,

2.16kg @230℃℃℃℃)25 27 46

MVI (cm3/10min,

2.16kg @230℃℃℃℃)28 30 50

� Good flowability of Rilsan® TMNO TLD

8

Mechanical & Ageing Properties

Mechanical Property* Rilsan® TMNO TLD Rilsan® BMNO TLDRilsamid® AMNO

TLD

Tensile modulus (MPa) 1400 1320 1230

Elongation (%) >200 >200 >200

Stress at yield (MPa) 45 41 38

Flexural modulus (MPa) 1100 1140 N/A

Charpy impact (kJ/m2)

Unnotched 23℃ NB NB NB

Unnotched -30℃ NB NB NB

� Rilsan® TMNO TLD has similar mechanical properties as Rilsan and Rilsamid

� Rilsan® TMNO TLD has similar heat ageing resistance as Rilsan and Rilsamid **

* Sample conditioned 15 days at 23℃/ 50% humidity

** Based on 150℃, dumbbell tensile test results

9

Rilsan ® TMNO TLD applications

General injection applications

Process abilityDimensional StabilityGood heat & impact resistance100% bio-based

Process abilityColoring AbilitySuitable for laser marking

Laser marking

Cable coating

Good processablity for coating Good cold resistanceGood impact resistance

10

Applications in Auto/Industrial MarketsExample of Homologation

Grade: Rilsan ® TMNO TLD

Application: Car control cable coating

Status: Commercial

Customer: Chinese car cable maker

Features:

Excellent processability

Excellent cold resistance compared to competitor grade

Excellent heat resistance

11

Conclusions – Rilsan® T MNO TLD

Arkema’s new PA10.10 heat and light stabilized grade

Suitable for molding and extrusion

Low density, low moisture uptake, good processing workability, high heat ageing and impact resistance

Ideal materials for Automotive, Industrial applications

Production & supply from Asia