safety data sheet - acco brands · 2017. 4. 8. · safety data sheet according to hazard...

Safety Data Sheet According to Hazard Communication Standard (29 CFR 1910.1200)

Ball pen ink Black

Issue date: 01/19/2015 Version 1.0 Revision date: 01/19/2015

1. Product and Company IdentificationMaterial name

CAS #

Product code

Product useManufacturer/Supplier

Supplier:

Address:

Contact person(E-mail):

Telephone:

Fax:

Emergency telephone Number:

2. Hazards identificationGHS classification

Physical hazards

Health hazards Category 4

Category 2

Category1

Ball pen ink Black

See section 3

-

Not available.

ACCO BRANDS AUSTRALIA

2 Coronation Avenue, Kings Park, NSW 2148

[email protected]

(02) 9695 2500

(02) 9695 2500

Not classified

Acute toxicity- Oral

skin corrosion/irritation

skin sensitisation

serious eye damage/eye irritation Category1

specific target organ toxicity after single exposure Category 3

Environmental hazards hazardous to the aquatic environment- CHRONIC Category 1

GHS label elements Hazard Pictograms

Signal word Danger

Hazard statement Harmful if swallowed

Causes skin irritation

May cause an allergic skin reaction

Causes serious eye damage

May cause respiratory irritation

Very toxic to aquatic life with long lasting effects

Precautionary statement Prevention Avoid breathing dust/fume/gas/mist/vapours/spray.

Wash hands thoroughly after handling.

Do not eat, drink or smoke when using this product.

Use only outdoors or in a well-ventilated area.

Material name: Ball pen ink Black MSDS US Version #:1.0 Revision date:01-19-2015. Issue date:01-19-2015. 1 / 7

Contaminated work clothing should not be allowed out of the workplace.

Avoid release to the environment.

Wear protective gloves/protective clothing/eye protection/face protection.

Response IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

IF ON SKIN: Wash with plenty of soap and water.

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for

breathing.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

Immediately call a POISON CENTER or doctor/physician.

Call a POISON CENTER or doctor/physician if you feel unwell.

Rinse mouth.

If skin irritation occurs: Get medical advice/attention.

If skin irritation or rash occurs: Get medical advice/attention.

Take off contaminated clothing and wash before reuse.

Wash contaminated clothing before reuse.

Collect spillage.

Storage Store in a well-ventilated place. Keep container tightly closed.

Store locked up.

Disposal Dispose of contents/container in according with local regulation.

3. Composition / Information on IngredientsComponents CAS# Percent

Solvent black 46 65113-55-5 30%

Benzyl alcohol 100-51-6 25%

2-Phenoxy Ethanol 122-99-6 20%

Keton resin 25054-06-2 14%

Epoxy resin 24969-06-0 6%

Triethanolamine 102-71-6 4%

Phosphoric acid ester 90506-69-7 1%

4. First Aid MeasuresFirst aid procedures

Eye contact Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

Skin contact Wash thoroughly with soap and water.

Inhalation If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel.

Ingestion Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel.

Notes to physician Treat symptoms.

5. Fire Fighting MeasureMaterial name: Ball pen ink Black MSDS US Version #:1.0 Revision date:01-19-2015. Issue date:01-19-2015. 2 / 7

Flammable properties This product is non-flammable.

Extinguishing media

Suitable extinguishing media Water, dry extinguishing media, carbon dioxide, alcohol resistant foams.

Unsuitable extinguishing media Direct water stream.

Firefighting equipment/instructions In the event of fire, wear self-contained breathing apparatus.

Hazardous combustion products None Special hazards caused by the substance.

6. Accidental Release MeasuresPersonal precautions Ensure good ventilation/exhaustion at the workplace.

Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.

Methods for cleaning up For large amounts: Pump off product. For residues: Pick up with suitable absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Dispose of absorbed material in accordance with regulations.

7. Handling and StorageHandling Prevent contact with air/oxygen (formation of peroxide). General Handling: Do not

swallow. Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling. Keep container closed. Use with adequate ventilation.

Storage Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. Exposure Controls / Personal ProtectionOCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes US ACGIH Threshold

Limit Values (TLV) Triethanolamine Triethanolamine 5 mg/m3 Not Available Not Available TLV® Basis:

Eye & skin irr; BEIA

EMERGENCY LIMITS Ingredient Material name TEEL-1 TEEL-2 TEEL-3 Benzyl alcohol Benzyl alcohol 30 ppm 49 ppm 49 ppm

2-Phenoxy Ethanol Phenoxyethanol, 2-; (Phenyl cellosolve) 20 ppm 20 ppm 44 ppm triethanolamine Triethanolamine; (Trihydroxytriethylamine) 15 mg/m3 51 mg/m3 1100 mg/m3

Ingredient Original IDLH Revised IDLH

Solvent black 46 Not Available Not Available

Benzyl alcohol Not Available Not Available

2-Phenoxy Ethanol Not Available Not Available

Keton resin Not Available Not Available

Epoxy resin Not Available Not Available

Triethanolamine Not Available Not Available

Phosphoric acid ester Not Available Not Available


Personal protective equipment

Eye / face protection Safety glasses with side shields. Chemical goggles.

Skin protection Wear chemical protective gloves, e.g. PVC.

Respiratory protection Wear appropriate protective mask.

General hygiene

considerations

Wash hands, forearms and face thoroughly after handling chemical products, before eating,

smoking and using the lavatory and at the end of the working period.

9. Physical & Chemical PropertiesAppearance

Physical state Liquid

Form Liquid

Color Black

Odor Not available

Odor threshold Not available

pH Not available

Vapor pressure 0.014 hPa( 20 °C) ( CAS#122-99-6)

Vapor density Not available

Boiling point 244.3 °C ( CAS#122-99-6)

Melting point/Freezing point 11.8 °C ( CAS#122-99-6)

Solubility (water) 24.2 g/L( 20.7 °C pH=5.5) ( CAS#122-99-6)

Specific gravity Not available

Relative density 1.11( 20 °C) ( CAS#122-99-6)

Density Not available

Flash point 126 °C ( CAS#122-99-6)

Flammability limits in air, upper, %by volume Not available

Flammability limits in air, lower, % by volume Not available

Auto-ignition temperature 475 °C ( CAS#122-99-6)

VOC Not available

Percent volatile Not available

Other data

Viscosity 19 mPa s (dynamic)(40.5 °C) ( CAS#122-99-6)

Partition coefficient(log Pow) 1.2 (23 °C) ( CAS#122-99-6)

Decomposition temperature > 350 °C( CAS#122-99-6)

Surface tension 70.7 mN/m( CAS#122-99-6)

10. Chemical Stability & Reactivity InformationChemical stability Material is stable under normal conditions.

Conditions to avoid Incompatible materials.

Incompatible materials Strong acids. Strong bases. Strong oxidizers.

Hazardous decomposition products Not available.

Possibility of hazardous reactions No dangerous reactions known.

11. Toxicological Information


Toxicokinetics, metabolism and distribution: Non-human toxicological data: Not available

Information on toxicological effects: Acute toxicity:

2-Phenoxy Ethanol (CAS#122-99-6)

LD50(Oral, Rat): 1850 mg/kg bw LD50(Dermal, Rabbit): Not available LC50(Inhalation, Rat): > 1000 mg/m³ airBenzyl alcohol (CAS#100-51-6)LD50(Oral, Rat): 1620 mg/kg bw LD50(Dermal, Rabbit): Not available LC50(Inhalation, Rat): > 4178 mg/m³ air 4hSolvent black46 (CAS#65113-55-5)LD50(Oral, Rat): > 2000 mg/kg bwLD50(Dermal, Rabbit): > 2000 mg/kg bwLC50(Inhalation, Rat): Not available

Skin corrosion/Irritation: Causes skin irritation.

Serious eye damage/irritation: Causes serious eye damage.

Respiratory or skin sensitization: May cause an allergic skin reaction.

Germ cell mutagenicity: Not classified

Carcinogenicity: Not classified

Reproductive toxicity: Not classified

STOT- single exposure: May cause respiratory irritation.

STOT-repeated exposure: Not classified

Aspiration hazard: Not classified

12. Ecological InformationToxicity:2-Phenoxy Ethanol (CAS#122-99-6)

Acute toxicity Time Species Method Evaluation Remarks

LC50 344 mg/L 96h Fish OECD 203 N/A N/A

EC50 > 500 mg/L 48h Daphnia OECD 202 N/A N/A

EC50 > 500 mg/L 72h Algae OECD 201 N/A N/A

Benzyl alcohol (CAS#100-51-6)



EC50 230 mg/L 48h Daphnia OECD 202 N/A N/A

EC50 770 mg/L 72h Algae OECD 201 N/A N/A

Solvent black46 (CAS#65113-55-5)


LC50 N/A 96h Fish OECD 203 N/A N/A

EC50 0.011 mg/L 48h Daphnia OECD 202 N/A N/A

EC50 0.0034 mg/L 72h Algae OECD 201 N/A N/A

Persistence and degradability: Not available. Material name: Ball pen ink Black MSDS US Version #:1.0 Revision date:01-19-2015. Issue date:01-19-2015. 5 / 7

Bioaccumulative potential: Not available.

Mobility in soil: Not available.

Results of PBT&vPvB assessment: Not available.

Other adverse effects: Very toxic to aquatic life with long lasting effects.

13. Disposal ConsiderationsDisposal instructions Dispose of contents/container in accordance with local/regional/national/international

regulations.

Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after

container is emptied.

14. Transport InformationDOT

Basic shipping requirements:

UN number 3082

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S(Solvent black46)

Hazard class 9

Packing group Ⅲ

Environmental hazards Yes

IATA

UN number 3082

UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S(Solvent black46)

Transport hazard class(es) 9

Packing group Ⅲ

IMDG

UN number 3082

UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S(Solvent black46)

Transport hazard class(es) 9

Packing group Ⅲ

Environmental hazards Yes

15. Regulatory InformationSafety, health and environmental regulations/legislation specific for the substance or mixture:

Solvent black 46 (65113-55-5) is found

on the following regulatory lists

"US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory"

Benzyl alcohol(100-51-6) is found on the

following regulatory lists


2-Phenoxy Ethanol(122-99-6) is found on

the following regulatory lists


Keton resin (25054-06-2) is found on the



Epoxy resin(24969-06-0) is found on the



Triethanolamine (102-71-6) is found on "US ACGIH Threshold Limit Values (TLV)",


the following regulatory lists "US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory"

Phosphoric acid ester(90506-69-7) is

found on the following regulatory lists

"Not Applicable"

16. Other InformationHMIS®ratings Health: 2

Flammability: 1

Physical hazard: 0

NFPA ratings Health: 2 Flammability: 1

Instability: 0

Disclaimer The information in the sheet was written based on the best knowledge and experience currentlyavailable.

Issue date 01-19-2015


Safety Data Sheet According to Hazard Communication Standard (29 CFR 1910.1200)

Ball pen ink Blue

Issue date: 01/19/2015 Version 1.0 Revision date: 01/19/2015

1. Product and Company IdentificationMaterial name

CAS #

Product code

Product useManufacturer/Supplier

Supplier(Manufacturer):

Address:

Contact person(E-mail):

Telephone:

Fax:

Emergency telephone Number:

2. Hazards identificationGHS classification

Physical hazards

Health hazards Category 4

Category 2

Category 1

Category 2

Environmental hazards

Ball pen ink Blue

See section 3

-

Not available.

ACCO BRANDS AUSTRALIA

2 Coronation Avenue, Kings Park, NSW 2148

[email protected]

(02) 9695 2500

(02) 9695 2500

Not classified

Acute toxicity- Oral

skin corrosion/irritation

Skin sensitization

serious eye damage/eye irritation

Not classified

GHS label elements Hazard Pictograms

Signal word Warning

Hazard statement Harmful if swallowed

Causes skin irritation

May cause an allergic skin reaction

Causes serious eye irritation

Precautionary statement Prevention Avoid breathing dust/fume/gas/mist/vapours/spray.

Wash hands thoroughly after handling.

Do not eat, drink or smoke when using this product.

Contaminated work clothing should not be allowed out of the workplace.

Wear protective gloves/protective clothing/eye protection/face protection.

Response IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

IF ON SKIN: Wash with plenty of soap and water.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

Material name: Ball pen ink Blue MSDS US Version #:1.0 Revision date:01-19-2015. Issue date:01-19-2015. 1 / 7

present and easy to do. Continue rinsing.

Rinse mouth.

If skin irritation occurs: Get medical advice/attention.

If eye irritation persists: Get medical advice/attention.

Take off contaminated clothing and wash before reuse.

Wash contaminated clothing before reuse.

Storage Not applicable.

Disposal Dispose of contents/container in according with local regulation.

3. Composition / Information on IngredientsComponents CAS# Percent

2-Phenoxy Ethanol 122-99-6 25%

Benzyl alcohol 100-51-6 15%

BX 147-14-8 15%

Solvent blue 4 6786-83-0 15%

1,2-propanediol 4254-14-2 10%

Keton resin 25054-06-2 10%

Castor oil resin 66070-88-0 5%

Triethanolamine 102-71-6 4%

Phosphoric acid ester 90506-69-7 1%

4. First Aid MeasuresFirst aid procedures

Eye contact Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

Skin contact Wash thoroughly with soap and water.

Inhalation If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel.

Ingestion Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel.

Notes to physician Treat symptoms.

5. Fire Fighting MeasureFlammable properties This product is non-flammable.

Extinguishing media

Suitable extinguishing media Water, dry extinguishing media, carbon dioxide, alcohol resistant foams.

Unsuitable extinguishing media Direct water stream.

Firefighting equipment/instructions In the event of fire, wear self-contained breathing apparatus.

Hazardous combustion products None Special hazards caused by the substance.

6. Accidental Release MeasuresPersonal precautions Ensure good ventilation/exhaustion at the workplace.

Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface


waters/groundwater.

Methods for cleaning up For large amounts: Pump off product. For residues: Pick up with suitable absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Dispose of absorbed material in accordance with regulations.

7. Handling and StorageHandling Prevent contact with air/oxygen (formation of peroxide). General Handling: Do not

swallow. Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling. Keep container closed. Use with adequate ventilation.

Storage Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. Exposure Controls / Personal ProtectionOCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes US ACGIH Threshold

Limit Values (TLV) Triethanolamine Triethanolamine 5 mg/m3 Not Available Not Available TLV® Basis:

Eye & skin irr; BEIA

US OSHA Permissible Exposure Levels (PELs)

- Table Z1

BX Copper - Fume / Copper

0.1 mg/m3 / 1 mg/m3

Not Available Not Available (as Cu) / (as Cu);Dusts and mists

EMERGENCY LIMITS Ingredient Material name TEEL-1 TEEL-2 TEEL-3

Benzyl alcohol Benzyl alcohol 30 ppm 49 ppm 49 ppm 2-Phenoxy Ethanol Phenoxyethanol, 2-; (Phenyl cellosolve) 20 ppm 20 ppm 44 ppm

triethanolamine Triethanolamine; (Trihydroxytriethylamine) 15 mg/m3 51 mg/m3 1100 mg/m3

Ingredient Original IDLH Revised IDLH

2-Phenoxy Ethanol Not Available Not Available

Benzyl alcohol Not Available Not Available

BX Not Available Not Available

Solvent blue 4 Not Available Not Available

1,2-propanediol Not Available Not Available

Keton resin Not Available Not Available

Castor oil resin Not Available Not Available

Triethanolamine Not Available Not Available

Phosphoric acid ester Not Available Not Available

Personal protective equipment

Eye / face protection Safety glasses with side shields. Chemical goggles.

Skin protection Wear chemical protective gloves, e.g. PVC.

Respiratory protection Wear appropriate protective mask.


General hygiene

considerations

Wash hands, forearms and face thoroughly after handling chemical products, before

eating, smoking and using the lavatory and at the end of the working period.

9. Physical & Chemical PropertiesAppearance

Physical state Liquid

Form Liquid

Color Blue

Odor Not available

Odor threshold Not available

pH Not available

Vapor pressure 0.014 hPa( 20 °C) ( CAS#122-99-6)

Vapor density Not available

Boiling point 244.3 °C ( CAS#122-99-6)

Melting point/Freezing point 11.8 °C ( CAS#122-99-6)

Solubility (water) 24.2 g/L( 20.7 °C pH=5.5) ( CAS#122-99-6)

Specific gravity Not available

Relative density 1.11( 20 °C) ( CAS#122-99-6)

Density Not available

Flash point 126 °C ( CAS#122-99-6)

Flammability limits in air, upper, %by volume Not available

Flammability limits in air, lower, % by volume Not available

Auto-ignition temperature 475 °C ( CAS#122-99-6)

VOC Not available

Percent volatile Not available

Other data

Viscosity 19 mPa s (dynamic)(40.5 °C) ( CAS#122-99-6)

Partition coefficient(log Pow) 1.2 (23 °C) ( CAS#122-99-6)

Decomposition temperature > 350 °C( CAS#122-99-6)

Surface tension 70.7 mN/m( CAS#122-99-6)

10. Chemical Stability & Reactivity InformationChemical stability Material is stable under normal conditions.

Conditions to avoid Incompatible materials.

Incompatible materials Strong acids. Strong bases. Strong oxidizers.

Hazardous decomposition products Not available.

Possibility of hazardous reactions No dangerous reactions known.

11. Toxicological Information

Toxicokinetics, metabolism and distribution:Non-human toxicological data: Not available

Information on toxicological effects: Acute toxicity:

2-Phenoxy Ethanol (CAS#122-99-6)


LD50(Oral, Rat): 1850 mg/kg bw LD50(Dermal, Rabbit): Not available LC50(Inhalation, Rat): > 1000 mg/m³ airBenzyl alcohol (CAS#100-51-6) LD50(Oral, Rat): 1620 mg/kg bw LD50(Dermal, Rabbit): Not available LC50(Inhalation, Rat): > 4178 mg/m³ air 4hTriethanolamine (CAS#102-71-6) LD50(Oral, Rat): 6400 mg/kg bw LD50(Dermal, Rabbit): > 2000 mg/kg bwLC50(Inhalation, Rat): Not available

Skin corrosion/Irritation: Causes skin irritation.

Serious eye damage/irritation: Causes serious eye irritation.

Respiratory or skin sensitization: May cause an allergic skin reaction.

Germ cell mutagenicity: Not classified

Carcinogenicity: Not classified

Reproductive toxicity: Not classified

STOT- single exposure: Not classified

STOT-repeated exposure: Not classified

Aspiration hazard: Not classified

12. Ecological InformationToxicity:2-Phenoxy Ethanol (CAS#122-99-6)



EC50 > 500 mg/L 48h Daphnia OECD 202 N/A N/A

EC50 > 500 mg/L 72h Algae OECD 201 N/A N/A

Benzyl alcohol (CAS#100-51-6)



EC50 230 mg/L 48h Daphnia OECD 202 N/A N/A


Triethanolamine (CAS#102-71-6)



EC50 609.88 mg/L 48h Daphnia OECD 202 N/A N/A


Persistence and degradability: Not available.

Bioaccumulative potential: Not available.

Mobility in soil: Not available.

Results of PBT&vPvB assessment: Not available.

Other adverse effects: No known significant effects or critical hazards.


13. Disposal ConsiderationsDisposal instructions Dispose of contents/container in accordance with local/regional/national/international

regulations.

Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after

container is emptied.

14. Transport InformationDOT

Basic shipping requirements:

UN number Not regulated

Proper shipping name Not regulated

Hazard class Not regulated

Packing group Not regulated

Environmental hazards No

IATA


UN proper shipping name Not regulated

Transport hazard class(es) Not regulated


IMDG


UN proper shipping name Not regulated

Transport hazard class(es) Not regulated


Environmental hazards No

15. Regulatory InformationSafety, health and environmental regulations/legislation specific for the substance or mixture:

2-Phenoxy Ethanol(122-99-6) is found on



Benzyl alcohol(100-51-6) is found on the



BX (147-14-8) is found on the following

regulatory lists

"US - Idaho - Limits for Air Contaminants",

"US - Hawaii Air Contaminant Limits",

"US -Washington Toxic air pollutants and their ASIL, SQER and de minimis emission values",

"US Toxic Substances Control Act (TSCA) -Chemical Substance Inventory"

Solvent blue 4 (6786-83-0) is found on



1,2-propanediol (4254-14-2) is found on


"US ATSDR Minimal Risk Levels for Hazardous Substances (MRLs)",

"US - Washington Toxic air pollutants and their ASIL,SQER and de minimis emission values",

"US Spacecraft Maximum Allowable Concentrations (SMACs) for Airborne Contaminants",

"US Toxic Substances Control Act (TSCA) -Chemical Substance Inventory"

Keton resin (25054-06-2) is found on the "US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory"



Castor oil resin (66070-88-0) is found on



Triethanolamine (102-71-6) is found on


"US ACGIH Threshold Limit Values (TLV)",


Phosphoric acid ester (90506-69-7) is

found on the following regulatory lists

"Not Applicable"

16. Other InformationHMIS®ratings Health: 1

Flammability: 1

Physical hazard: 0

NFPA ratings Health: 1 Flammability: 1

Instability: 0

Disclaimer The information in the sheet was written based on the best knowledge and experience currentlyavailable.

Issue date 01-19-2015


Safety Data Sheet (SDS)According to Commission Regulation (EU) No 453/2010

Version number 1 Printing date 27.03.2012 Revision date 27.03.2012

DR

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier

· Product name: Ballpen inks green· Registration number: No registration number is given yet for this product.

· 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Used to ballpen inks.Use advised against: No information available.

· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:

ACCO BRANDS AUSTRALIA Address: 2 Coronation Avenue, Kings Park, NSW 2148Email: [email protected]: (02) 9695 2500

· 1.4 Emergency telephone number +86-512-63331385

2 SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008 [CLP]

Acute Tox. 4 H302 Harmful if swallowed.

Eye Irrit. 2 H319 Causes serious eye irritation.

· Classification according to Directive 67/548/EEC [DSD] or Directive 1999/45/EC [DPD]Xn; R20/22Xi; R36

· Classification system:The classification is according to the latest editions of the EU-lists, and extended by company and literature data.

· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008 [CLP]

The product is classified and labelled according to the CLP regulation.· Hazard pictogram(s):

GHS07

· Signal word: Warning(Contd. on page 2)



DR

Product name: Ballpen inks green

· Hazard statement(s):H302 Harmful if swallowed.H319 Causes serious eye irritation.

· Precautionary statements:P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P280 Wear protective gloves/protective clothing/eye protection/face protection. P264 Wash thoroughly after handling. P270 Do no eat, drink or smoke when using this product.

(Contd. of page 1)

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. P337+P313 If eye irritation persists: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

· 2.3 Other hazards No information available.· Results of PBT and vPvB assessment:· PBT: Not applicable.· vPvB: Not applicable.

3 SECTION 3: Composition/information on ingredients

· 3.1 Chemical characterization: Mixtures· Description:Product: consisting of the following components.

Ingredient name CAS No. EC No. Concentration (%) Solvent yellow19 10343-55-2 233-747-8 20

Basic blue 7 2390-60-5 219-232-0 10 Benzyl alcohol 100-51-6 202-859-9 25

2-Phenoxyethanol 122-99-6 204-589-7 20Epoxy resin 24969-06-0 - 6Keton resin 25054-06-2 - 14

Triethanolamine 102-71-6 203-049-8 4Phosphoric acid ester 90506-69-7 291-933-4 1

(Contd. on page 3)



DR


(Contd. of page 2)

· Dangerous components:

CAS: 100-51-6 EINECS: 202-859-9

Benzyl alcohol Xn R20/22

25%

Acute Tox. 4, H302; Acute Tox. 4, H332 CAS: 122-99-6 EINECS: 204-589-7

2-PhenoxyethanolXn R22; Xi R36

20%

Acute Tox. 4, H302; Eye Irrit. 2, H319CAS: 2390-60-5 EINECS: 219-232-0

[4-[4-(diethylamino)-alpha-[4-(ethylamino)-1-naphthyl]benzylidene]cyclohexa-2,5-dien-1-ylidene]diethylammonium chloride T R25

10%

Acute Tox. 3, H301 · Additional information: For the wording of the listed risk phrases refer to section 16.

4 SECTION 4: First aid measures

· 4.1 Description of first aid measures· General information: In all cases of doubt, seek medical attention.· Following inhalation:

Not expected to become a significant inhalation hazard under normal conditions of use. In case of accident byinhalation, supply fresh air and to be sure call for a doctor.

· Following skin contact: Immediately wash with water and soap and rinse thoroughly.· Following eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.· Following ingestion: Induce vomiting, if person is conscious. Seek medical help.· Information for doctor: Treat symptomatically and supportively.

· 4.2 Most important symptoms and effects, both acute and delayed No information available.

· 4.3 Indication of any immediate medical attention and special treatment needed No information available.

5 SECTION 5: Firefighting measures

· 5.1 Extinguishing media· Suitable extinguishing agents: CO2, dry chemical powder, water spray.· Unsuitable extinguishing agents: No information available.

· 5.2 Special hazards arising from the substance or mixtureFormation of toxic gases is possible during heating or in case of fire.In case of fire, the following can be released:

(Contd. on page 4)

DR

Page 4




Carbon monoxide (CO) Carbon dioxide Other irritating and toxic gases.

· 5.3 Advice for firefighters· Protective equipment:

Wear self-contained respiratory protective device.Wear suitable protective clothing and eye/face protection.

(Contd. of page 3)

6 SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency proceduresRefer to Section 8 for personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition.Evacuate personnel to safe areas.

· 6.2 Environmental precautionsDo not allow product to reach sewage system or any water course.Inform respective authorities in case of seepage into water course or sewage system.

· 6.3 Methods and material for containment and cleaning upAbsorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).Dispose contaminated material as waste according to item 13.

· 6.4 Reference to other sectionsSee Section 7 for information on safe handling.See Section 8 for information on personal protection equipment.See Section 13 for disposal information.

7 SECTION 7: Handling and storage

· 7.1 Handling· Precautions for safe handling:

Handle in accordance with good industrial hygiene and safety practice. Use personal protective equipment as required.Do not get in eyes, on skin, or on clothing. Wash thoroughly after handling. Use this material with adequateventilation.

· Information about fire - and explosion protection:Keep ignition sources away - Do not smoke.The product is not explosive.

(Contd. on page 5)

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(Contd. of page 4)

· 7.2 Conditions for safe storage, including any incompatibilitiesStore in cool, dry and well-ventilated place. Store away from incompatible materials.

· 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.

8 SECTION 8: Exposure controls/personal protection

· Information about design of technical facilities:Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposurelimits.

· 8.1 Control parameters

· Ingredients with limit values that require monitoring at the workplace:

100-51-6 Benzyl alcohol (25%)

WEEL (USA) 44 mg/m³, 10 ppm

102-71-6 2,2',2''-nitrilotriethanol (4%)

TLV (USA) 5 mg/m³

· Additional information: The lists valid during the making were used as basis.

· 8.2 Exposure controls· Appropriate engineering controls:

Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposurelimits. Ensure adequate ventilation.

· Respiratory protection: Suitable respiratory protective device recommended.· Skin protection:

Protective gloves

· Material of gloves:The selection of the suitable gloves does not only depend on the material, but also on further marks of quality andvaries from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of theglove material can not be calculated in advance and has therefore to be checked prior to the application.

· Penetration time of glove material:The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.

(Contd. on page 6)

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· Eye and face protection:

Tightly sealed goggles

· Body protection: Protective work clothing

(Contd. of page 5)

9 SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties· Appearance:

Form: Liquid Colour: Green

· Odour: Odourless

· pH-value: Not determined. · Melting point/Melting range: Not determined. · Boiling point/Boiling range: Not determined.

· Flash point: Not determined.

· Flammability (solid, gaseous): Not applicable.

· Auto-Ignition temperature: Not determined.

· Decomposition temperature: Not determined.

· Self-igniting: Product is not selfigniting.

· Danger of explosion: Product does not present an explosion hazard.

· Vapour pressure: Not determined.

· Density: Not determined. · Evaporation rate: Not determined.

· Solubility in/Miscibility with:Water: Not miscible or difficult to mix.

· Partition coefficient (n-octanol/water): Not determined.· 9.2 Additional information No further relevant information available.

(Contd. on page 7)

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(Contd. of page 6)

10 SECTION 10: Stability and reactivity

· 10.1 Reactivity Stable under recommended storage and handling conditions (see section 7, handling and storage).

· 10.2 Chemical stability Stable under normal conditions of use, storage and transport.· Thermal decomposition/conditions to be avoided: No decomposition if used according to specifications.

· 10.3 Possibility of hazardous reactions No dangerous reactions known.

· 10.4 Conditions to avoid Strong heating, fire. Incompatible materials.

· 10.5 Incompatible materialsStrong acids, strong bases or strong oxidizing agents.Base metals.

· 10.6 Hazardous decomposition productsCarbon monoxideOther irritating and toxic gases.

11 SECTION 11: Toxicological information

· Acute toxicity: No data available.

· LD/LC50 values relevant for classification:

100-51-6 Benzyl alcohol

Oral

Dermal

LD50

LD50

1230 mg/kg (rat)

2000 mg/kg (rabbit)

122-99-6 2-Phenoxyethanol

Oral

Dermal

LD50

LD50

1260 mg/kg (rat)

5000 mg/kg (rabbit)

102-71-6 2,2',2''-nitrilotriethanol

Oral

Dermal

LD50

LD50

4920 mg/kg (rat)

> 2000 mg/kg (rabbit)

· Skin corrosion/irritation: No irritant effect.· Serious eye damage/irritation: Cause serious eye irritation.· Respiratory or skin sensitization: No sensitizing effects known.· Specific target organ system toxicity: No information available.

(Contd. on page 8)

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(Contd. of page 7) · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction): No information available.

12 SECTION 12: Ecological information

· 12.1 Toxicity

· Acquatic toxicity:


EC50 - Crustacea

EC50 - Algae

LC50 - Fish

> 500 mg/L/48h mg/L/48h (Daphnia magna)

> 500 mg/L/72 h mg/L/48h (Desmodesmus subspicatus (green algae))

220 - 460 mg/L/48h (Leuciscus idus (Golden orfe))


LC50 - Fish

EC50 - Crustacea

IC50 - Algae

450 - 1000 mg/L mg/L/48h (Lepomis macrochirus)

609,88 mg/L/48h mg/L/48h (Daphnia magna)

216 mg/L/72h mg/L/48h (Desmodesmus subspicatus (green algae))


EC50 - Algae

EC50 - Crustacea

LC50 - Fish

700 mg/L/72h mg/L/48h (Pseudokirchneriella Subcatitata)

230 mg/L/48h mg/L/48h (Daphnia magna)

460 mg/L/96h mg/L/48h (Pimephales promelas (fathead minnow))

· 12.2 Persistence and degradability No further relevant information available.

· 12.3 Bioaccumulative potential No further relevant information available.

· 12.4 Mobility in soil No further relevant information available.

· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.

· 12.6 Other adverse effects No information available.

13 SECTION 13: Disposal considerations

· 13.1 Waste treatment methods· Recommendation:

Must not be disposed together with household garbage. Do not allow product to reach sewage system.(Contd. on page 9)

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(Contd. of page 8)

· Uncleaned packaging:· Recommendation: Disposal must be made according to official regulations.

14 SECTION 14: Transport information

· 14.1 Land transport· ADR/RID class: Not regulated.· UN-Number: Not applicable.

· 14.2 Maritime transport· IMDG Class: Not regulated. · UN Number: Not applicable. · Marine pollutant: No

· 14.3 Air transport· ICAO/IATA Class: Not regulated.· UN/ID Number: Not applicable.

· 14.4 Environmental hazards: Not applicable.

· 14.5 Special precautions for user Not applicable.

· 14.6 Transport/Additional information: Not dangerous according to the above specifications.

15 SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixtureEU Regulation:Authorisations: No information available.Restrictions on use: No information available.Regulatory information

CAS No. EU (EINECS)

US (TSCA)

Japan (ENCS)

Canada (DSL/ NDSL)

Austrlia (AICS)

Korea (ECL)

China (IECSC)

10343-55-2 Listed Listed Listed NDSL Listed Listed Listed 2390-60-5 Listed Listed Listed DSL Listed Listed Listed 100-51-6 Listed Listed Listed DSL Listed Listed Listed 122-99-6 Listed Listed Listed DSL Listed Listed Listed

24969-06-0 Not listed Listed Not listed DSL Listed Listed Listed 25054-06-2 Not listed Listed Not listed DSL Listed Listed Listed

102-71-6 Listed Listed Listed DSL Listed Listed Listed 90506-69-7 Listed Not listed Not listed Not listed Not listed Not listed Listed

(Contd. on page 10)

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(Contd. of page 9)

· 15.2 Chemical safety assessment A Chemical Safety Assessment has not been carried out.

16 SECTION 16: Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

· Relevant phrases:R20/22: Harmful by inhalation and if swallowed.R25: Toxic if swallowed.R36: Irritating to eyes.H301: Toxic if swallowed.H332: Harmful if inhaled.

· Training hints: Provide adequate information, instruction and training for operators.

· Department issuing SDS: Centre Testing International· Contact us: [email protected]· Date issuing SDS: March 26, 2012· Sources:

ESIS: European chemical Substances Information System.GESTIS-database: Information system on hazardous substances of the German Social Accident Insurance.ECHA's public database with information on registered substances.Provided by company

Safety Data Sheet (SDS) According to Commission Regulation (EU) No 453/2010


DR

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier

· Product name: Ballpen inks Red· Registration number: No registration number is given yet for this product.

· 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Used to ballpen inks.Use advised against: No information available.

· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:

ACCO BRANDS AUSTRALIA Address: 2 Coronation Avenue, Kings Park, NSW 2148Email: [email protected]: (02) 9695 2500

· 1.4 Emergency telephone number +86-512-63331385

2 SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008 [CLP]

STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.

Acute Tox. 4 H302 Harmful if swallowed.

Eye Irrit. 2 H319 Causes serious eye irritation.

· Classification according to Directive 67/548/EEC [DSD] or Directive 1999/45/EC [DPD]Xn; R22R33Xi; R36

· Classification system:The classification is according to the latest editions of the EU-lists, and extended by company and literature data.

· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008 [CLP]

The product is classified and labelled according to the CLP regulation.· Hazard pictogram(s):

GHS07 GHS08

(Contd. on page 2)

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Product name: Ballpen inks Red

· Signal word: Warning · Hazard statement(s):

H302 Harmful if swallowed. H319 Causes serious eye irritation. H373 May cause damage to organs through prolonged or repeated exposure.

· Precautionary statements: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P280 Wear protective gloves/protective clothing/eye protection/face protection. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P270 Do no eat, drink or smoke when using this product.

(Contd. of page 1)

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P330 Rinse mouth. P337+P313 If eye irritation persists: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

· 2.3 Other hazards No information available. · Results of PBT and vPvB assessment: · PBT: Not applicable. · vPvB: Not applicable.

3 SECTION 3: Composition/information on ingredients

· 3.1 Chemical characterization: Mixtures · Description: Product: consisting of the following components.

Ingredient name CAS No. EC No. Concentration (%) Solvent res49 509-34-2 208-096-8 30

Benzyl alcohol 100-51-6 202-859-9 20 2-Phenoxyethanol 122-99-6 204-589-7 25

Epoxy resin 24969-06-0 - 6 Keton resin 25054-06-2 - 14

Triethanolamine 102-71-6 203-049-8 4 Phosphoric acid ester 90506-69-7 291-933-4 1

(Contd. on page 3)



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(Contd. of page 2)

· Dangerous components:

CAS: 100-51-6 EINECS: 202-859-9

Benzyl alcohol Xn R20/22

20%

Acute Tox. 4, H302; Acute Tox. 4, H332 CAS: 122-99-6 EINECS: 204-589-7

2-Phenoxyethanol Xn R22; Xi R36

25%

Acute Tox. 4, H302; Eye Irrit. 2, H319 CAS: 509-34-2 EINECS: 208-096-8

3',6'-bis(diethylamino)spiro[isobenzofuran-1(3H),9'-[9H]xanthene]-3-one Xn R22 R33

30%

STOT RE 2, H373; Acute Tox. 4, H302 · Additional information: For the wording of the listed risk phrases refer to section 16.

4 SECTION 4: First aid measures

· 4.1 Description of first aid measures · General information: In all cases of doubt, seek medical attention. · Following inhalation:

Not expected to become a significant inhalation hazard under normal conditions of use. In case of accident by inhalation, supply fresh air and to be sure call for a doctor.

· Following skin contact: Immediately wash with water and soap and rinse thoroughly. · Following eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. · Following ingestion: Induce vomiting, if person is conscious. Seek medical help. · Information for doctor: Treat symptomatically and supportively.

· 4.2 Most important symptoms and effects, both acute and delayed No information available.

· 4.3 Indication of any immediate medical attention and special treatment needed No information available.

5 SECTION 5: Firefighting measures

· 5.1 Extinguishing media · Suitable extinguishing agents: CO2, dry chemical powder, water spray. · Unsuitable extinguishing agents: No information available.

(Contd. on page 4)

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(Contd. of page 3)

· 5.2 Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. In case of fire, the following can be released: Carbon monoxide (CO) Carbon dioxide Other irritating and toxic gases.

· 5.3 Advice for firefighters · Protective equipment:

Wear self-contained respiratory protective device. Wear suitable protective clothing and eye/face protection.

6 SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures Refer to Section 8 for personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas.

· 6.2 Environmental precautions

Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system.

· 6.3 Methods and material for containment and cleaning up

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13.

· 6.4 Reference to other sections

See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

7 SECTION 7: Handling and storage

· 7.1 Handling · Precautions for safe handling:

Handle in accordance with good industrial hygiene and safety practice. Use personal protective equipment as required. Do not get in eyes, on skin, or on clothing. Wash thoroughly after handling. Use this material with adequate ventilation.

· Information about fire - and explosion protection: Keep ignition sources away - Do not smoke.

(Contd. on page 5)

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The product is not explosive.

· 7.2 Conditions for safe storage, including any incompatibilities

Store in cool, dry and well-ventilated place. Store away from incompatible materials.

(Contd. of page 4)

· 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.

8 SECTION 8: Exposure controls/personal protection

· Information about design of technical facilities: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.

· 8.1 Control parameters

· Ingredients with limit values that require monitoring at the workplace:

100-51-6 Benzyl alcohol (25%)

WEEL (USA) 44 mg/m³, 10 ppm

102-71-6 2,2',2''-nitrilotriethanol (4%)

TLV (USA) 5 mg/m³

· Additional information: The lists valid during the making were used as basis.

· 8.2 Exposure controls · Appropriate engineering controls:

Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Ensure adequate ventilation.

· Respiratory protection: Suitable respiratory protective device recommended. · Skin protection:

Protective gloves

· Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.

· Penetration time of glove material: The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.

(Contd. on page 6)

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· Eye and face protection:

Tightly sealed goggles

· Body protection: Protective work clothing

(Contd. of page 5)

9 SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties · Appearance:

Form: Liquid Colour: Red

· Odour: Odourless

· pH-value: Not determined. · Melting point/Melting range: Not determined. · Boiling point/Boiling range: Not determined.

· Flash point: Not determined.

· Flammability (solid, gaseous): Not applicable.

· Auto-Ignition temperature: Not determined.

· Decomposition temperature: Not determined.

· Self-igniting: Product is not selfigniting.

· Danger of explosion: Product does not present an explosion hazard.

· Vapour pressure: Not determined.

· Density: Not determined. · Evaporation rate: Not determined.

· Solubility in/Miscibility with:

Water: Not miscible or difficult to mix.

· Partition coefficient (n-octanol/water): Not determined. · 9.2 Additional information No further relevant information available.

(Contd. on page 7)

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(Contd. of page 6)

10 SECTION 10: Stability and reactivity

· 10.1 Reactivity Stable under recommended storage and handling conditions (see section 7, handling and storage).

· 10.2 Chemical stability Stable under normal conditions of use, storage and transport. · Thermal decomposition/conditions to be avoided: No decomposition if used according to specifications.

· 10.3 Possibility of hazardous reactions No dangerous reactions known.

· 10.4 Conditions to avoid Strong heating, fire. Incompatible materials.

· 10.5 Incompatible materials

Strong acids, strong bases or strong oxidizing agents. Base metals.

· 10.6 Hazardous decomposition products

Carbon monoxide Other irritating and toxic gases.

11 SECTION 11: Toxicological information

· Acute toxicity: No data available.

· LD/LC50 values relevant for classification:


Oral

Dermal

LD50

LD50

1230 mg/kg (rat)

2000 mg/kg (rabbit)


Oral

Dermal

LD50

LD50

1260 mg/kg (rat)

5000 mg/kg (rabbit)


Oral

Dermal

LD50

LD50

4920 mg/kg (rat)

> 2000 mg/kg (rabbit)

· Skin corrosion/irritation: No irritant effect. · Serious eye damage/irritation: Cause serious eye irritation. · Respiratory or skin sensitization: No sensitizing effects known. · Specific target organ system toxicity: No information available.

(Contd. on page 8)

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(Contd. of page 7) · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction): No information available.

12 SECTION 12: Ecological information

· 12.1 Toxicity

· Acquatic toxicity:


EC50 - Crustacea

IC50 - Algae

LC50 - Fish

> 500 mg/L/48h mg/L/48h (Daphnia magna)

> 500 mg/L/72 h mg/L/48h (Desmodesmus subspicatus (green algae))

220 - 460 mg/L/48h (Leuciscus idus (Golden orfe))


LC50 - Fish

EC50 - Crustacea

IC50 - Algae

450 - 1000 mg/L mg/L/48h (Lepomis macrochirus)

609,88 mg/L/48h mg/L/48h (Daphnia magna)

216 mg/L/72h mg/L/48h (Desmodesmus subspicatus (green algae))


EC50 - Algae

EC50 - Crustacea

LC50 - Fish

700 mg/L/72h mg/L/48h (Pseudokirchneriella Subcatitata)

230 mg/L/48h mg/L/48h (Daphnia magna)

460 mg/L/96h mg/L/48h (Pimephales promelas (fathead minnow))

· 12.2 Persistence and degradability No further relevant information available.

· 12.3 Bioaccumulative potential No further relevant information available.

· 12.4 Mobility in soil No further relevant information available.

· 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.

· 12.6 Other adverse effects No information available.

13 SECTION 13: Disposal considerations

· 13.1 Waste treatment methods · Recommendation:

Must not be disposed together with household garbage. Do not allow product to reach sewage system. (Contd. on page 9)

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(Contd. of page 8)

· Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations.

14 SECTION 14: Transport information

· 14.1 Land transport · ADR/RID class: Not regulated. · UN-Number: Not applicable.

· 14.2 Maritime transport · IMDG Class: Not regulated. · UN Number: Not applicable. · Marine pollutant: No

· 14.3 Air transport · ICAO/IATA Class: Not regulated. · UN/ID Number: Not applicable.

· 14.4 Environmental hazards: Not applicable.

· 14.5 Special precautions for user Not applicable.

· 14.6 Transport/Additional information: Not dangerous according to the above specifications.

15 SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation: Authorisations: No information available. Restrictions on use: No information available. Regulatory information

(Contd. on page 10)

CAS No. EU (EINECS)

US (TSCA)

Japan (ENCS)

Canada (DSL)

Austrlia (AICS)

Korea (ECL)

China (IECSC)

509-34-2 Listed Listed Listed Listed Listed Listed Listed 100-51-6 Listed Listed Listed Listed Listed Listed Listed 122-99-6 Listed Listed Listed Listed Listed Listed Listed

24969-06-0 Not listed Listed Not listed Listed Listed Listed Listed 25054-06-2 Not listed Listed Not listed Listed Listed Listed Listed

102-71-6 Listed Listed Listed Listed Listed Listed Listed 90506-69-7 Listed Not listed Not listed Not listed Not listed Not listed Listed

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· 15.2 Chemical safety assessment A Chemical Safety Assessment has not been carried out.

16 SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

· Relevant phrases: R20/22: Harmful by inhalation and if swallowed. R33: Danger of cumulative effects. R36: Irritating to eyes. H332: Harmful if inhaled.

· Training hints: Provide adequate information, instruction and training for operators.

· Department issuing SDS: Centre Testing International · Contact us: [email protected] · Date issuing SDS: March 26, 2012 · Sources:

ESIS: European chemical Substances Information System. GESTIS-database: Information system on hazardous substances of the German Social Accident Insurance. ECHA's public database with information on registered substances. Provided by company

mailto:[email protected]�

safety data sheet - acco brands · 2017. 4. 8. · safety data sheet according to hazard...

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