safety data sheet according to osha hazard …

SAFETY DATA SHEETAccording to OSHA Hazard Communication Standard, 29 CFR1910.1200

Version 1.5 Revision Date: 12/31/2015 Print Date: 01/01/2016

SECTION 1. IDENTIFICATION

Product name : Shell Gadus S2 V220 2

Schindler ElevatorGadus Grease S2 V220 2

Part# 994436

Product code : 001D8451

Manufacturer or supplier's details

Manufacturer/Supplier

SDS RequestCustomer Service

Shell Oil Products USPO Box 4427Houston TX 77210-4427USA(+1)877-276-7285

Emergency telephone numberSpill Information : 877-504-9351Health Information : 877-242-7400

Recommended use of the chemical and restrictions on useRecommended use : Automotive and industrial grease.

SECTION 2. HAZARDS IDENTIFICATION

GHS ClassificationNot a hazardous substance or mixture.

GHS Label elementHazard pictograms : No Hazard Symbol required

Signal word

Hazard statements

Precautionary statements

No signal word

PHYSICAL HAZARDS:Not classified as a physical hazard under GHS criteria.HEALTH HAZARDS:Not classified as a health hazard under GHS criteria.ENVIRONMENTAL HAZARDS:Not classified as an environmental hazard under GHS criteria.

Prevention:No precautionary phrases.

Response:No precautionary phrases.

Storage:No precautionary phrases.Disposal:No precautionary phrases.

Other hazards which do not result in classificationProlonged or repeated skin contact without proper cleaning can clog the pores of the skin result-ing in disorders such as oil acne/folliculitis.

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Used grease may contain harmful impurities.High-pressure injection under the skin may cause serious damage including local necrosis.Not classified as flammable but will burn.

The classification of this material is based on OSHA HCS 2012 criteria.

Under normal conditions of use or in a foreseeable emergency, this product does not meet thedefinition of a hazardous chemical when evaluated according to the OSHA Hazard Communica-tion Standard, 29 CFR 1910.1200.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature A lubricating grease containing highly-refined mineral oils andadditives.The highly refined mineral oil contains <3% (w/w) DMSO-extract, according to IP346.

Hazardous componentsChemical NameZinc alkyl dithiophosphate

SynonymsPhosphorodithioicacid, O,O-di-C1-14-alkyl esters, zincsalts

CAS-No.68649-42-3

Concentration (%)1 - 2.4

SECTION 4. FIRST-AID MEASURES

General advice

If inhaled

In case of skin contact

In case of eye contact

If swallowed

Most important symptomsand effects, both acute anddelayed

Not expected to be a health hazard when used under normalconditions.

No treatment necessary under normal conditions of use.If symptoms persist, obtain medical advice.

Remove contaminated clothing. Flush exposed area with wa-ter and follow by washing with soap if available.If persistent irritation occurs, obtain medical attention.

When using high pressure equipment, injection of productunder the skin can occur. If high pressure injuries occur, thecasualty should be sent immediately to a hospital. Do not waitfor symptoms to develop.Obtain medical attention even in the absence of apparentwounds.

Flush eye with copious quantities of water.If persistent irritation occurs, obtain medical attention.

In general no treatment is necessary unless large quantitiesare swallowed, however, get medical advice.

Oil acne/folliculitis signs and symptoms may include formationof black pustules and spots on the skin of exposed areas.Ingestion may result in nausea, vomiting and/or diarrhoea.Local necrosis is evidenced by delayed onset of pain and

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Protection of first-aiders

Immediate medical attention,special treatment

tissue damage a few hours following injection.

When administering first aid, ensure that you are wearing theappropriate personal protective equipment according to theincident, injury and surroundings.

Treat symptomatically.

High pressure injection injuries require prompt surgical inter-vention an d possibly steroid therapy, to minimise tissue dam-age and loss of function.Because entry wounds are small and do not reflect the seri-ousness of the underlying damage, surgical exploration todetermine the extent of involvement may be necessary. Localanaesthetics or hot soaks should be avoided because theycan contribute to swelling, vasospasm and ischaemia. Promptsurgical decompression, debridement and evacuation of for-eign material should be performed under general anaesthet-ics, and wide exploration is essential.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Unsuitable extinguishingmedia

Specific hazards during fire-fighting

Specific extinguishing meth-ods

Special protective equipmentfor firefighters

Foam, water spray or fog. Dry chemical powder, carbon diox-ide, sand or earth may be used for small fires only.

Do not use water in a jet.

Hazardous combustion products may include:A complex mixture of airborne solid and liquid particulates andgases (smoke).Carbon monoxide may be evolved if incomplete combustionoccurs.Unidentified organic and inorganic compounds.

Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment.

Proper protective equipment including chemical resistantgloves are to be worn; chemical resistant suit is indicated iflarge contact with spilled product is expected. Self-ContainedBreathing Apparatus must be worn when approaching a fire ina confined space. Select fire fighter's clothing approved torelevant Standards (e.g. Europe: EN469).

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec-tive equipment and emer-gency procedures

Environmental precautions

Avoid contact with skin and eyes.

Use appropriate containment to avoid environmental contami-nation. Prevent from spreading or entering drains, ditches or

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rivers by using sand, earth, or other appropriate barriers.

Methods and materials for : Prevent from spreading or entering into drains, ditches or riv-containment and cleaning up ers by using sand, earth, or other appropriate barriers.

Additional advice For guidance on selection of personal protective equipmentsee Chapter 8 of this Safety Data Sheet.For guidance on disposal of spilled material see Chapter 13 ofthis Safety Data Sheet.

SECTION 7. HANDLING AND STORAGE

Technical measures

Precautions for safe handling

Avoidance of contact

Use local exhaust ventilation if there is risk of inhalation ofvapours, mists or aerosols.Use the information in this data sheet as input to a risk as-sessment of local circumstances to help determine appropri-ate controls for safe handling, storage and disposal of thismaterial.

Avoid prolonged or repeated contact with skin.Avoid inhaling vapour and/or mists.When handling product in drums, safety footwear should beworn and proper handling equipment should be used.Properly dispose of any contaminated rags or cleaning mate-rials in order to prevent fires.

Strong oxidising agents.

StorageOther data

Packaging material

Container Advice

: Keep container tightly closed and in a cool, well-ventilatedplace.Use properly labeled and closable containers.

Store at ambient temperature.

: Suitable material: For containers or container linings, use mildsteel or high density polyethylene.Unsuitable material: PVC.

: Polyethylene containers should not be exposed to high tem-peratures because of possible risk of distortion.

SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Components with workplace control parameters

Components

Oil mist, mineral

CAS-No.

Not Assigned

Value type(Form ofexposure)TWA ((inhal-

Control parame-ters / Permissibleconcentration5 mg/m3

Basis

US. ACGIH

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able frac-tion))(Mist) 5 mg/m3

ThresholdLimit ValuesOSHA TRANS

Biological occupational exposure limits

No biological limit allocated.Monitoring Methods

Monitoring of the concentration of substances in the breathing zone of workers or in the generalworkplace may be required to confirm compliance with an OEL and adequacy of exposure con-trols. For some substances biological monitoring may also be appropriate.Validated exposure measurement methods should be applied by a competent person and sam-ples analysed by an accredited laboratory.Examples of sources of recommended exposure measurement methods are given below or con-tact the supplier. Further national methods may be available.National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methodshttp://www.cdc.gov/niosh/Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methodshttp://www.osha.gov/Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substanceshttp://www.hse.gov.uk/Institut fur Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA), Germanyhttp://www.dguv.de/inhalt/index.jspL'lnstitut National de Recherche et de Securite, (INRS), France http://www.inrs.fr/accueil

Engineering measures : The level of protection and types of controls necessary willvary depending upon potential exposure conditions. Selectcontrols based on a risk assessment of local circumstances.Appropriate measures include:Adequate ventilation to control airborne concentrations.

Where material is heated, sprayed or mist formed, there isgreater potential for airborne concentrations to be generated.

General Information:Define procedures for safe handling and maintenance ofcontrols.Educate and train workers in the hazards and controlmeasures relevant to normal activities associated with thisproduct.Ensure appropriate selection, testing and maintenance ofequipment used to control exposure, e.g. personal protectiveequipment, local exhaust ventilation.Drain down system prior to equipment break-in or mainte-nance.Retain drain downs in sealed storage pending disposal orsubsequent recycle.Always observe good personal hygiene measures, such aswashing hands after handling the material and before eating,drinking, and/or smoking. Routinely wash work clothing andprotective equipment to remove contaminants. Discard con-taminated clothing and footwear that cannot be cleaned.Practice good housekeeping.

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Due to the product's semi-solid consistency, generation ofmists and dusts is unlikely to occur.

Personal protective equipmentRespiratory protection

Hand protectionRemarks

Eye protection

Skin and body protection

Protective measures

No respiratory protection is ordinarily required under normalconditions of use.In accordance with good industrial hygiene practices, precau-tions should be taken to avoid breathing of material.If engineering controls do not maintain airborne concentra-tions to a level which is adequate to protect worker health,select respiratory protection equipment suitable for the spe-cific conditions of use and meeting relevant legislation.Check with respiratory protective equipment suppliers.Where air-filtering respirators are suitable, select an appro-priate combination of mask and filter.Select a filter suitable for the combination of organic gasesand vapours [Type A/Type P boiling point >65°C (149°F)].

Where hand contact with the product may occur the use ofgloves approved to relevant standards (e.g. Europe: EN374,US: F739) made from the following materials may providesuitable chemical protection. PVC, neoprene or nitrile rubbergloves Suitability and durability of a glove is dependent onusage, e.g. frequency and duration of contact, chemical re-sistance of glove material, dexterity. Always seek advice fromglove suppliers. Contaminated gloves should be replaced.Personal hygiene is a key element of effective hand care.Gloves must only be worn on clean hands. After usinggloves, hands should be washed and dried thoroughly. Appli-cation of a non-perfumed moisturizer is recommended.For continuous contact we recommend gloves with break-through time of more than 240 minutes with preference for >480 minutes where suitable gloves can be identified. Forshort-term/splash protection we recommend the same, butrecognize that suitable gloves offering this level of protectionmay not be available and in this case a lower breakthroughtime maybe acceptable so long as appropriate maintenanceand replacement regimes are followed. Glove thickness is nota good predictor of glove resistance to a chemical as it isdependent on the exact composition of the glove material.Glove thickness should be typically greater than 0.35 mmdepending on the glove make and model.

If material is handled such that it could be splashed into eyes,protective eyewear is recommended.

Skin protection is not ordinarily required beyond standardwork clothes.It is good practice to wear chemical resistant gloves.

Personal protective equipment (PPE) should meet recom-mended national standards. Check with PPE suppliers.

Environmental exposure controls

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General advice Take appropriate measures to fulfill the requirements of rele-vant environmental protection legislation. Avoid contaminationof the environment by following advice given in Chapter 6. Ifnecessary, prevent undissolved material from being dis-charged to waste water. Waste water should be treated in amunicipal or industrial waste water treatment plant beforedischarge to surface water.Local guidelines on emission limits for volatile substancesmust be observed for the discharge of exhaust air containingvapour.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Colour

Odour

Odour Threshold

pH

Drop point

Initial boiling point and boilingrange

Flash point

Evaporation rate

Flammability (solid, gas)

Upper explosion limit

Lower explosion limit

Vapour pressure

Relative vapour density

Relative density

Semi-solid at ambient temperature.

brown

Slight hydrocarbon

Data not available

Not applicable

180 °C / 356 TMethod: IP 396

Data not available

>=180°C/>=356°FMethod: ASTM D92

Data not available

Data not available

Typical 10%(V)

Typical 1 %(V)

< 0.5 Pa (20 °C / 68 °F)estimated value(s)

> 1 estimated value(s)

0.900(15°C/59°F)

Density 900 kg/m3(15.0 °C / 59.0 °F)Method: Unspecified

Solubility(ies)Water solubility

Solubility in other solvents

negligible

Data not available

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Partition coefficient: n- : Pow: > 6(based on information on similar products)octanol/water

Auto-ignition temperature : >320 °C / 608 °F

ViscosityViscosity, dynamic : Data not available

Viscosity, kinematic : Not applicable

Conductivity : This material is not expected to be a static accumulator.

Decomposition temperature : Data not available

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : Stable.

Possibility of hazardous reac- : Reacts with strong oxidising agents,tions

Conditions to avoid : Extremes of temperature and direct sunlight.

Incompatible materials : Strong oxidising agents.

Hazardous decomposition : Hazardous decomposition products are not expected to formproducts during normal storage.

SECTION 11. TOXICOLOGICAL INFORMATION

Basis for assessment : Information given is based on data on the components andthe toxicology of similar products.Unless indicated otherwise,the data presented is representative of the product as awhole, rather than for individual component(s).

Information on likely routes of exposureSkin and eye contact are the primary routes of exposure although exposure may occur followingaccidental ingestion.

Acute toxicity

Product:Acute oral toxicity : LD50 (rat): > 5,000 mg/kg

Remarks: Expected to be of low toxicity.

Acute inhalation toxicity : Remarks: Not considered to be an inhalation hazard undernormal conditions of use.

Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kgRemarks: Expected to be of low toxicity:

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Skin corrosion/irritation

Product:Remarks: Expected to be slightly irritating., Prolonged or repeated skin contact without propercleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis.

Serious eye damage/eye irritation

Product:Remarks: Expected to be slightly irritating.

Components:Zinc alky) dithiophosphate:Remarks: Based on available data, the classification criteria are not met.

Respiratory or skin sensitisation

Product:Remarks: Not expected to be a skin sensitiser.

Germ cell mutagenicity

Product:: Remarks: Not considered a mutagenic hazard.

Carcinogenicity

Product:Remarks: Not expected to be carcinogenic.

Remarks: Product contains mineral oils of types shown to be non-carcinogenic in animal skin-painting studies., Highly refined mineral oils are not classified as carcinogenic by the Internation-al Agency for Research on Cancer (IARC).

Reproductive toxicity

Product:

Remarks: Not expected to impair fertility., Not expected to bea developmental toxicant.

STOT - single exposure

Product:Remarks: Not expected to be a hazard.

STOT - repeated exposure

Product:

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Remarks: Not expected to be a hazard.

Aspiration toxicity

Product:Not considered an aspiration hazard.

Further information

Product:Remarks: Used grease may contain harmful impurities that have accumulated during use. Theconcentration of such harmful impurities will depend on use and they may present risks to healthand the environment on disposal., ALL used grease should be handled with caution and skincontact avoided as far as possible.

Remarks: High pressure injection of product into the skin may lead to local necrosis if the prod-uct is not surgically removed.

Remarks: Slightly irritating to respiratory system.

SECTION 12. ECOLOGICAL INFORMATION

Basis for assessment

Ecotoxicity

Product:Toxicity to fish (Acute toxici-ty)

Toxicity to daphnia and otheraquatic invertebrates (Acutetoxicity)

Toxicity to algae (Acute tox-icity)

Toxicity to fish (Chronic tox-icity)

Toxicity to daphnia and otheraquatic invertebrates (Chron-ic toxicity)

Toxicity to bacteria (Acute

Ecotoxicological data have not been determined specificallyfor this product.Information given is based on a knowledge of the componentsand the ecotoxicology of similar products.Unless indicated otherwise, the data presented is representa-tive of the product as a whole, rather than for individual com-ponent^). (LL/EL/IL50 expressed as the nominal amount ofproduct required to prepare aqueous test extract).

Remarks: Expected to be practically non toxic:LL/EL/IL50>100mg/l

Remarks: Expected to be practically non toxic:LL/EL/IL50>100mg/l

Remarks: Expected to be practically non toxic:LL/EL/IL50 > 100 mg/l

Remarks: Data not available



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toxicity)

Persistence and degradability

Product:Biodegradability : Remarks: Expected to be not readily biodegradable.

Major constituents are expected to be inherently biodegrada-ble, but contains components that may persist in the environ-ment.

Bioaccumulative potential

Product:Bioaccumulation Remarks: Contains components with the potential to bioac-

cumulate.

Mobility in soil

Product:Mobility Remarks: Semi-solid under most environmental conditions.

If it enters soil, it will adsorb to soil particles and will not bemobile.

Remarks: Floats on water.

Other adverse effectsno data available

Product:Additional ecological infor-mation

Product is a mixture of non-volatile components, which are notexpected to be released to air in any significant quantities.Not expected to have ozone depletion potential, photochemi-cal ozone creation potential or global warming potential.

Poorly soluble mixture.May cause physical fouling of aquatic organisms.

Mineral oil is not expected to cause any chronic effects toaquatic organisms at concentrations less than 1 mg/l.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methodsWaste from residues

Contaminated packaging

Recover or recycle if possible.It is the responsibility of the waste generator to determine thetoxicity and physical properties of the material generated todetermine the proper waste classification and disposal meth-ods in compliance with applicable regulations.Do not dispose into the environment, in drains or in watercourses

Dispose in accordance with prevailing regulations, preferably

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to a recognized collector or contractor. The competence ofthe collector or contractor should be established beforehand.Disposal should be in accordance with applicable regional,national, and local laws and regulations.

Local legislationRemarks : Disposal should be in accordance with applicable regional,

national, and local laws and regulations.

SECTION 14. TRANSPORT INFORMATION

National Regulations

US Department of Transportation Classification (49 CFR Parts 171-180)

Not regulated as a dangerous good

International Regulation

IATA-DGRNot regulated as a dangerous good

IMDG-CodeNot regulated as a dangerous good

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Pollution categoryShip typeProduct nameSpecial precautions

Special precautions for user

Not applicableNot applicableNot applicableNot applicable

Remarks : Special Precautions: Refer to Chapter 7, Handling & Storage,for special precautions which a user needs to be aware of orneeds to comply with in connection with transport.

Additional Information : MARPOL Annex 1 rules apply for bulk shipments by sea.

SECTION 15. REGULATORY INFORMATION

California Prop 65 : This product does not contain any chemicals known to Stateof California to cause cancer, birth defects, or any other re-productive harm.

The components of this product are reported in the following inventories:EINECS : All components listed or polymer exempt.

TSCA : All components listed.

DSL : All components listed.

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SECTION 16. OTHER INFORMATION

Further informationNFPA Rating (Health, Fire, Reac- 0, 1, 0tivity)

A vertical bar (|) in the left margin indicates an amendment from the previous version.Abbreviations and Acronyms : The standard abbreviations and acronyms used in this docu-

ment can be looked up in reference literature (e.g. scientificdictionaries) and/or websites.

ACGIH = American Conference of Governmental IndustrialHygienistsADR = European Agreement concerning the InternationalCarriage of Dangerous Goods by RoadAICS = Australian Inventory of Chemical SubstancesASTM = American Society for Testing and MaterialsBEL = Biological exposure limitsBTEX = Benzene, Toluene, Ethylbenzene, XylenesCAS = Chemical Abstracts ServiceCEFIC = European Chemical Industry CouncilCLP = Classification Packaging and LabellingCOG = Cleveland Open-CupDIN = Deutsches Institut fur NormungDMEL = Derived Minimal Effect LevelDNEL = Derived No Effect LevelDSL = Canada Domestic Substance ListEC = European CommissionEC50 = Effective Concentration fiftyECETOC = European Center on Ecotoxicology and Toxicolo-gy Of ChemicalsECHA = European Chemicals AgencyEINECS = The European Inventory of Existing CommercialChemical SubstancesEL50 = Effective Loading fiftyENCS = Japanese Existing and New Chemical SubstancesInventoryEWC = European Waste CodeGHS = Globally Harmonised System of Classification andLabelling of ChemicalsIARC = International Agency for Research on CancerI ATA = International Air Transport AssociationIC50 = Inhibitory Concentration fiftyIL50 = Inhibitory Level fiftyIMDG = International Maritime Dangerous GoodsINV = Chinese Chemicals InventoryIP346 = Institute of Petroleum test method N° 346 for thedetermination of polycyclic aromatics DMSO-extractablesKECI = Korea Existing Chemicals InventoryLC50 = Lethal Concentration fiftyLD50 = Lethal Dose fifty per cent.LL/EL/IL = Lethal Loading/Effective Loading/Inhibitory loadingLL50 = Lethal Loading fiftyMARPOL = International Convention for the Prevention of

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Pollution From ShipsNOEC/NOEL = No Observed Effect Concentration / No Ob-served Effect LevelOEJHPV = Occupational Exposure - High Production VolumePBT = Persistent, Bioaccumulative and ToxicPICCS = Philippine Inventory of Chemicals and ChemicalSubstancesPNEC = Predicted No Effect ConcentrationREACH = Registration Evaluation And Authorisation OfChemicalsRID = Regulations Relating to International Carriage of Dan-gerous Goods by RailSKIN_DES = Skin DesignationSTEL = Short term exposure limitTRA = Targeted Risk AssessmentTSCA = US Toxic Substances Control ActTWA = Time-Weighted AveragevPvB = very Persistent and very Bioaccumulative

Revision Date : 12/31/2015

This information is based on our current knowledge and is intended to describe the product forthe purposes of health, safety and environmental requirements only. It should not therefore beconstrued as guaranteeing any specific property of the product.

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safety data sheet according to osha hazard …

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