safety data sheet - dijf55il5e0d1.cloudfront.net · cdn 70% ipa / 30% di h2o section 4. first aid...

CDN 70% IPA / 30% DI H2O

Solid.

GHS product identifier

Other means ofidentification

Product type

Section 1. Identification

CDN PW70, CDN 200; 70% IPA / 30% DI H2O

SAFETY DATA SHEET

Product code

Identified uses

Emergency telephonenumber (with hours ofoperation)

Supplier's details

Compliant SDS for GHS: HazCom 2012 / United States; WHMIS 2015 / Canada; NMX-R-019-SCFI-2011 / Mexico


Section 3. Composition/information on ingredientsThere are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are

classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Wash out mouth with water. Remove victim to fresh air and keep at rest in a positioncomfortable for breathing. If material has been swallowed and the exposed person isconscious, give small quantities of water to drink. Stop if the exposed person feels sickas vomiting may be dangerous. Do not induce vomiting unless directed to do so bymedical personnel. If vomiting occurs, the head should be kept low so that vomit doesnot enter the lungs. Get medical attention. If necessary, call a poison center orphysician. Never give anything by mouth to an unconscious person. If unconscious,place in recovery position and get medical attention immediately. Maintain an openairway.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lowereyelids. Check for and remove any contact lenses. Continue to rinse for at least 20minutes. Get medical attention.

Flush contaminated skin with plenty of water. Get medical attention if symptoms occur.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If itis suspected that fumes are still present, the rescuer should wear an appropriate maskor self-contained breathing apparatus. Get medical attention. If necessary, call apoison center or physician.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

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Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if largequantities have been ingested or inhaled.

Description of necessary first aid measures

Specific treatments : No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness anddizziness.

Can cause central nervous system (CNS) depression.:Ingestion

Skin contact : No known significant effects or critical hazards.

Causes serious eye irritation.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness

No known significant effects or critical hazards.


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Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

Potential acute health effects

Indication of immediate medical attention and special treatment needed, if necessary

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Section 4. First aid measuresProtection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is

suspected that fumes are still present, the rescuer should wear an appropriate mask orself-contained breathing apparatus.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Move containers from fire area if this can be done without risk. Use water spray to keepfire-exposed containers cool.

Hazardous thermaldecomposition products

Specific hazards arisingfrom the chemical

Decomposition products may include the following materials:carbon dioxidecarbon monoxide

Flammable solid.

Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protectiveequipment for fire-fighters

Use dry chemical, CO2, water spray (fog) or foam.

Extinguishing media

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Do not use water jet or water-based fire extinguishers.

Suitable extinguishingmedia

:

Unsuitable extinguishingmedia

:

Special protective actionsfor fire-fighters

:

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

:

: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Shut off all ignition sources. No flares, smoking or flames in hazard area.Provide adequate ventilation. Wear appropriate respirator when ventilation isinadequate. Put on appropriate personal protective equipment.

Inform the relevant authorities if the product has caused environmental pollution (sewers,waterways, soil or air).

Methods and materials for containment and cleaning up

For non-emergencypersonnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information inSection 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Place spilled material in designated, labelled waste container. Dispose via a licensedwaste disposal contractor.

:Spill

Section 7. Handling and storage

Precautions for safe handling

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Section 7. Handling and storage

Advice on generaloccupational hygiene

Conditions for safe storage,including anyincompatibilities

Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. See also Section 8 for additional information on hygienemeasures.

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilatedarea, away from incompatible materials (see Section 10) and food and drink. Storelocked up. Eliminate all ignition sources. Separate from oxidizing materials. Keepcontainer tightly closed and sealed until ready for use. Do not store in unlabeledcontainers. Use appropriate containment to avoid environmental contamination.

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Protective measures Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoidcontact with eyes, skin and clothing. Use only with adequate ventilation. Do not enterstorage areas and confined spaces unless adequately ventilated. Keep in the originalcontainer or an approved alternative made from a compatible material, kept tightlyclosed when not in use. Store and use away from heat, sparks, open flame or any otherignition source. Use only non-sparking tools. Empty containers retain product residueand can be hazardous. Do not reuse container.

:

Section 8. Exposure controls/personal protection

Control parameters

Occupational exposure limits

Ingredient name

Isopropyl alcohol ACGIH TLV (United States, 3/2015).

STEL: 400 ppm 15 minutes.TWA: 200 ppm 8 hours.

NIOSH REL (United States, 10/2013).STEL: 1225 mg/m³ 15 minutes.STEL: 500 ppm 15 minutes.TWA: 980 mg/m³ 10 hours.TWA: 400 ppm 10 hours.

OSHA PEL (United States, 2/2013).TWA: 980 mg/m³ 8 hours.TWA: 400 ppm 8 hours.

OSHA PEL 1989 (United States, 3/1989).

TWA: 400 ppm 8 hours.TWA: 980 mg/m³ 8 hours.STEL: 500 ppm 15 minutes.STEL: 1225 mg/m³ 15 minutes.

Exposure limits

Canada

Occupational exposure limits

Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations

Isopropyl alcohol US ACGIH 3/2015 200 - - 400 - - - - -AB 4/2009 200 492 - 400 984 - - - -BC 2/2015 200 - - 400 - - - - -ON 7/2015 200 - - 400 - - - - -QC 1/2014 400 983 - 500 1230 - - - -

TWA (8 hours) STEL (15 mins) Ceiling

United States

Mexico

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Section 8. Exposure controls/personal protection

Hand protection

Recommended: Vapor respirator.

Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary. Considering the parameters specified by the glove manufacturer, checkduring use that the gloves are still retaining their protective properties. It should benoted that the time to breakthrough for any glove material may be different for differentglove manufacturers.

Recommended: Safety glasses.Eye/face protection

Respiratory protection :

:

:

Body protection Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist beforehandling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothingshould include anti-static overalls, boots and gloves.

:

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation.

Appropriate engineeringcontrols

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proofventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Ensurethat eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Skin protection

Other skin protection : Appropriate footwear and any additional skin protection measures should be selectedbased on the task being performed and the risks involved and should be approved by aspecialist before handling this product.

Ingredient name

Isopropyl alcohol NOM-010-STPS (Mexico, 9/2000).

LMPE-CT: 1225 mg/m³ 15 minutes.LMPE-CT: 500 ppm 15 minutes.LMPE-PPT: 980 mg/m³ 8 hours.LMPE-PPT: 400 ppm 8 hours.

Exposure limits

Section 9. Physical and chemical properties

Physical state Solid. [Solid containing liquid (prewetted wiper)]

Rubbing alcohol.Odor

pH

White substrate with colorless liquid.Color

Not available.

Not available.Odor threshold

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Appearance

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Section 9. Physical and chemical propertiesMelting point

Vapor pressure

Relative density

Vapor density

Solubility in water

Not available.

Not available.

Not available.

Not available.

Insoluble in the following materials: cold water and hot water.

Evaporation rate Not available.

Auto-ignition temperature

Flash point

399°C (750.2°F)

Closed cup: 20°C (68°F)

Not available.

Viscosity Not available.

Partition coefficient: n-octanol/water

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Boiling point : Not available.

Flammability (solid, gas) : Highly flammable in the presence of the following materials or conditions: open flames,sparks and static discharge and shocks and mechanical impacts.

Lower and upper explosive(flammable) limits

: Lower: 2%Upper: 12.7%

Decomposition temperature : Not available.

Section 10. Stability and reactivity

Hazardous decompositionproducts

Conditions to avoid Avoid all possible sources of ignition (spark or flame).

Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.

The product is stable.Chemical stability

Highly reactive or incompatible with the following materials: oxidizing materials.

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:

:

Incompatible materials :

Possibility of hazardousreactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Information on toxicological effects

Acute toxicity

Product/ingredient name Result Species Dose Exposure

Irritation/Corrosion

Product/ingredient name Result Score Exposure ObservationSpecies

Isopropyl alcohol LD50 Dermal Rabbit 12800 mg/kg -LD50 Oral Rat 5000 mg/kg -

Isopropyl alcohol Eyes - Severe irritant Rabbit - 100 mg -Skin - Mild irritant Rabbit - 500 mg -Eyes - Moderate irritant Rabbit - 24 hours 100 mg -Eyes - Moderate irritant Rabbit - 10 mg -

Sensitization

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Carcinogenicity

Mutagenicity

Teratogenicity

Reproductive toxicity

Information on the likelyroutes of exposure

Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness anddizziness.

Can cause central nervous system (CNS) depression.:Ingestion

Skin contact : No known significant effects or critical hazards.

Causes serious eye irritation.:Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness



:

:

:

Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

Delayed and immediate effects and also chronic effects from short and long term exposure

: Dermal contact. Eye contact. Inhalation. Ingestion.

Potential acute health effects

Short term exposure

There is no data available.




Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Name Category

Aspiration hazard

Route ofexposure

Target organs

Isopropyl alcohol Category 3 Not applicable. Narcotic effects



Classification

Product/ingredient name

Isopropyl alcohol None. 3 - A4 - -

ACGIH EPA NIOSHNTPIARCOSHA

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No known significant effects or critical hazards.General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Potential chronic health effects

Numerical measures of toxicity

Oral 7692.3 mg/kg

Route ATE value

Acute toxicity estimates

Potential immediateeffects

: No known significant effects or critical hazards.

Potential delayed effects : No known significant effects or critical hazards.

Potential immediateeffects

: No known significant effects or critical hazards.

Long term exposure

Potential delayed effects : No known significant effects or critical hazards.

Section 12. Ecological information

LogPow BCF Potential

Bioaccumulative potential

Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

Toxicity

Product/ingredient name SpeciesResult Exposure

Persistence and degradability

Soil/water partitioncoefficient (KOC)

: No data available.

Mobility in soil

Isopropyl alcohol Acute LC50 1400000 to 1950000 µg/L Marine water Crustaceans - Crangon crangon 48 hoursAcute LC50 4200 mg/L Fresh water Fish - Rasbora heteromorpha 96 hours


Isopropyl alcohol 0.05 - low

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Section 15. Regulatory information

The following components are listed: Isopropyl alcohol

No products were found.

Massachusetts :

SARA 313

Product name CAS number %

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall includecopying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

Isopropyl alcohol 67-63-0 70

Isopropyl alcohol 67-63-0 70

Form R - Reportingrequirements

Supplier notification

California Prop. 65

DEA List I Chemicals(Precursor Chemicals)

: Not listed

DEA List II Chemicals(Essential Chemicals)

: Not listed

New York : None of the components are listed.

New Jersey : The following components are listed: Isopropyl alcohol

Pennsylvania : The following components are listed: Isopropyl alcohol

State regulations

SARA 302/304

SARA 304 RQ : Not applicable.

Composition/information on ingredients

SARA 311/312

Classification : Fire hazardImmediate (acute) health hazard

Isopropyl alcohol 70 Yes. No. No. Yes. No.

Name % Firehazard

Suddenrelease ofpressure

Reactive Immediate(acute)healthhazard

Delayed(chronic)healthhazard

Composition/information on ingredients

No products were found.

Canada

Canadian lists

The following components are listed: Isopropyl alcoholCanadian NPRI :

Canada inventory : All components are listed or exempted.

CEPA Toxic substances : None of the components are listed.

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safety data sheet - dijf55il5e0d1.cloudfront.net · cdn 70% ipa / 30% di h2o section 4. first aid...

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