safety data sheets — april 1, 2016 - pestgon sds.pdf · important disclosure – please read...

3612 Ocean Ranch Blvd

Oceanside, CA 92056

Cell 760801.7572 • Office 877724.8100Office Fax: 866.724.8282

Pestgon

Website: www.pestgon.com E-mail: [email protected]

Did you know…Pestgon has a termite divison:

PestgonTermiteCall toll-free

877.499.7378for an inspection

Safety Data Sheets — April 1, 2016Important Disclosure.................................................................................................................... Page 2Advion Cockroach Gel Bait ..................................................................................................Pages 3-9Avert Dry Flowable .............................................................................................................Pages 10-16Avitrol ..................................................................................................................................... Pages 17-27Bedlam Plus ......................................................................................................................... Pages 28-36CB-80 ...................................................................................................................................... Pages 37-45Contrac .................................................................................................................................. Pages 46-49Deadline MP ......................................................................................................................... Pages 50-57Delta Dust ............................................................................................................................. Pages 58-68Demand CS ........................................................................................................................... Pages 69-77Eco PCO ACU ....................................................................................................................... Pages 78-86Endzone ................................................................................................................................. Pages 87-93Essentria IC3 ......................................................................................................................Pages 94-100Final .....................................................................................................................................Pages 101-104Fumitoxin Tablets ...........................................................................................................Pages 105-119InVict Xpress Granular Bait ...................................................................................... Pages 120-127Martin’s Gopher Bait 50............................................................................................. Pages 128-132Maxforce FC Magnum ................................................................................................ Pages 133-141Maxforce Fly Spot Bait ............................................................................................... Pages 142-151Maxforce Granular Fly Bait ....................................................................................... Pages 152-161Niban FG ........................................................................................................................... Pages 162-167Onslaught FastCap ....................................................................................................... Pages 168-176Phantom ........................................................................................................................... Pages 177-187Precor 2000 Plus ........................................................................................................... Pages 188-196Precor IGR ........................................................................................................................ Pages 197-204PTB Phantom Pressurized.......................................................................................... Pages 205-216 Purge III ............................................................................................................................ Pages 217-225Pyrethrin Fogger ........................................................................................................... Pages 226-234Pyrocide 300 ................................................................................................................... Pages 235-242RCO Omega Gopher Grain Bait ............................................................................... Pages 243-250Talstar PL .......................................................................................................................... Pages 251-258 Termidor SC ..................................................................................................................... Pages 259-267Terro PCO ......................................................................................................................... Pages 268-273Wasp Freeze .................................................................................................................... Pages 274-286 ZP Rodent Oat Bait ...................................................................................................... Pages 287-290

Important Disclosure – Please read carefully – RETAIN FOR YOUR FILES — 4/1/2016 RIGHT TO KNOW: Prior to application of pesticides to your property, State law requires that you be given the following information:

CAUTION - PESTICIDES ARE TOXIC CHEMICALS. Structural Pest Control Operators are licensed and regulated by the Structural Pest Control Board and apply pesticides which are registered and approved for use by the California Department of Food and Agriculture and the United States Environmental Protection Agency. Registration is granted when the state finds that, based on existing scientific evidence, there are no appreciable risks if proper use conditions are followed or that the risks are outweighed by the benefits. The degree of risk depends upon the degree of exposure; so exposure should be minimized. If, within 24 hours following application, you experience symptoms similar to common seasonal illnesses comparable to the flu, contact your physician or poison control center (800-876-4766) and your pest control operator immediately. If rodenticide ingestion occurs, you may experience symptoms of mild shock/bleeding, an anticoagulant reaction.

For further information, contact any of the following:

Service Information: Pest Control Operator 877-724-8100, Pestgon Incorporated

Health Information: County Health Department Riverside 951-358-5000

Orange 714-834-4722

Los Angeles 213-250-8055

San Bernardino 800-442-2283

San Diego 619-692-8499

Application Information: County Ag Commissioner Riverside 951-955-3000

Orange 714-955-0100

Los Angeles 626-575-5466

San Bernardino 909-387-2115

San Diego 858-694-8980

Regulatory Information: Structural Pest Control Board 2005 Evergreen St., Ste 1500, Sacramento, CA 95825 • 916.561.8708

TERMS AND NOTICES: The total amount of this contract for any and all pest management service work is due and payable upon receipt of each billing invoice. Only target pests checked on the original contract are included in the Regular Scheduled Service (RSS). Should Pestgon Incorporated fail to comply with specifications of the service contract, they shall be given a thirty (30) day written notice to comply and render satisfactory service, and if, at the end of such thirty-day notice, unsatisfactory conditions persist, customer reserves the right to cancel the contract without further notice. In any case, either party shall give written notice thirty (30) days prior to cancellation date.

SERVICE GUARANTEE: The PESTGON INCORPORATED Service Guarantee is a promise to retreat target pests during the term of the service contract, not a guarantee of efficacy or safety. If necessary, PESTGON INCORPORATED agrees to call back during the Service Guarantee period unless otherwise noted and provide retreat service at no extra charge. After the SG period, it will be understood by both parties that target pests are controlled and any other pest management services are chargeable to the customer. Charges for Regular Scheduled Service shall continue uninterrupted by the Service Guarantee unless otherwise agreed. Upon being instructed or advised, either in writing or orally, if the customer fails to make proper preparations and/or corrections for pest management service, Pestgon Incorporated cannot assure satisfactory service and the Service Guarantee will be void.

RESPONSIBILITY: Customer agrees to inform PESTGON INCORPORATED of any allergic or pregnant persons occupying the premises prior to any indoor treatment and PESTGON agrees to make reasonable effort to inquire. PESTGON shall take every reasonable precaution to use pest control products labeled to provide the maximum safety required by the United States Environmental Protection Agency in order to protect persons, pets and plants. However, PESTGON is not responsible for their health or wellbeing. Customer agrees to follow all precautionary instructions, written or oral, and to hold pest control operator harmless from any and all claims, damages and expenses arising out of pests and/or pest management services pursuant to this contract.

PRIME CONTRACT: In compliance with the Structural Pest Control Board, the California Department of Food and Agriculture and the United States Environmental Protection Agency, this document, even as an addendum, is the prime contract for pest control services by and between PESTGON INCORPORATED and the owners and authorized agents of the property herein addressed. Consent by the Owner (s) or authorized agent (s) and performance by PESTGON of any part of this contract binds this contractual agreement and its terms as the prime contract. No other contractual agreement, attachments or addendum shall have any force to precede, prevail, invalidate, impair or negate this prime contract and its terms. Any changes to this contractual agreement shall be only by written agreement, which is and shall be expressly understood to be an addendum hereto. In case any one or more of the parts or provisions of this contractual agreement shall be invalid, illegal or unenforceable in any respect, the validity, legality and enforceability of the remaining parts and provisions contained herein shall not be in any way invalidated, negated, affected or impaired thereby.

PESTICIDE DISCLOSURE NOTICE: California law (8538 Business & Professions Code and 1940.4 California Code of Regulations) requires that we provide you with a pesticide disclosure notice and the following chemical information prior to our initial pest control service. Property Managers, please notify your tenants that there will be ongoing pest control performed on the exterior common areas. If we treat the interior of a unit, we will leave a copy of this pesticide disclosure notice inside the unit for the tenant.

CHEMICAL INFORMATION AND APPLICATION RATES PER EPA LABEL INSTRUCTIONS: Advion Cockroach Gel Bait = 0.6% Indoxacarb (S-Enantiomer) EPA 352-652 Avert Dry Flowable = 0.050% Abamectin B1, EPA 499-294 Avitrol = 0.5% 4-Aminopyridine, EPA-11649-4 Bedlam Plus Insecticide = 0.4% 3-phenoxybenzyl-(1RS, 3RS, 1RS, 3SR)-2, 2-dimethyl-3-(2- methylprop-1-enyl) cycloproposanecarboxylate, 1.0% N-Ocyl bicycloheptene dicarboximide, Imicloprid 0.05%, EPA 1021-2569 CB-80 = 0.5% Pyrethrins, EPA-9444-175 Contrac Rodent Bait = 0.005% Bromadiolone, EPA-12455-79 Deadline M-Ps Snail Bait = 4% Metaldehyde, EPA-64864-38 Delta Dust = 0.05% Deltamethrin, EPA-432-772 Demand CS = 0.06% Lambda-Cyhalothrin, EPA-100-1066 EcoPCO ACU = 0.1% 2-Phenethyl Propionate, EPA 67425-14-655 Endzone = 4.4% AceTamiprid EPA-8033-114-279 Essentria IC3 Insect Concentrate = Rosemary Oil 10%, Geraniol 5%, Wintergreen Oil 37%, White Mineral Oil 40%, Vanilin 3%, EPA Exempt Final All-Weather Blox = .005% Brodifacoum , EPA12455-89 Fumitoxin = 55% Aluminum Phosphide, EPA-72959-1-5857 InVict Express Granular Bait, Imidacloprid 0.5%, EPA 73079-14 Martins Gopher Grain Bait 50 = 0.5% Strychnine Alkaloid, EPA-53883-23 Maxforce FC Magnum=.05% Fipronl, 432-1460 Maxforce Fly Spot Bait = 10% Imidacloprid, 1-[6-Chloro-3-pyridinyl)methyl], 0.1% Z-9-Tricosene, EPA 432-1455 Niban = 0.5% Orthoboric Acid, EPA-64405-2 Maxforce Granular Fly Bait = Imidacloprid, 1-[(g-chloro-3-pyridinyl)methyl]-N nitro-2-imidazolidin-imine_0.5%

Z-9-Tricosene_0.1% EPA-432-1375 Niban = 0.5% Orthoboric Acid, EPA-64405-2 Onslaught FastCap Spider & Scorpion Insecticide = 6.40% Esfenvalerate, 1.60% Prallethrin, 8.0% PiperonylButoxide, EPA-1021-2574 Phantom Insecticide = 21.45% Chlorfenapyr, EPA-241-392 Precor 2000 Plus = 0.085% Methoprene, 0.35% pemethrin, 0.3% Phenothrin, 2% N-octylbicycloheptene, dicarboximide, 1.4% Piperonyl butoxide, EPA 2724-490 Precor Plus IGR = 1.2% [S]-Methoprene EPA2724-352 PTB Phantom II Pressurized = 0.5% ChlorFenapyr.4-bromo-2(4-chlorophenyl)-1-(eThoxymethyl)-5-(trifluorometh- yl)-1H-Pyrrole-3-Caronitrile, EPA-499-548 Purge III Insecticide = 0.975% Pyrethrins, 1.950% Piperonyl Butoxide, 3.05% N-octylbicyclopheptene, EPA 279-3388 Pyrethrin Fogger = 0.5% Pyrethrins, 1% Piperonyl Butoxide, technical, 1% N-OctylBicyclohepteneDicarboximide, EPA 11623-GA-1 Pyrocide 300 = 3.0% Pyrethrins - 6.0% *Piperonyl butoxide, Technical ** 9.57% N-Octly bicychloheptene dicabonximide, EPA-1021-1177 RCO Omega Gopher Grain Bait = 0.5% Strychnine Alkaloid, EPA-5042-32 Talstar PC Granular, 0.2 Bifenthrin, EPA 279-3168 Termidor SC = 9.1% Fipronil, EPA 7969-210 Terro PCO Liquid Ant Bait Stations = 5.40% Sodium Tetraborate Decahydrate (Borax) EPA-149-8-64405 Wasp-Freeze = 0.129% Allethrin, EPA-499-362 ZP Rodent Bait = 2% Zinc Phosphide, EPA-12455-17

Pestgon Incorporated, 3612 Ocean Ranch Blvd, Oceanside, CA 92056-2669 • 877-724-8100 www.pestgon.com • [email protected]

Return to Index...

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

DuPont™

Advion® Cockroach Gel Bait

Version 2.2 Revision Date 10.11.2010 Ref.130000029437

1/7

This SDS adheres to the standards and regulatory requirements of the European Union and may not meet the regulatory requirements in other countries.

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product information

Product name : DuPont™

Advion® Cockroach Gel Bait

Synonyms : B12141924

Use of the Substance/Mixture

: Biocidal product

Company : DuPont de Nemours South Africa (Pty) Ltd 34 Whiteley Road Block B, 1st Floor Melrose Arch South Africa

Telephone : +27 11 218 8600

Telefax : +27 11 218 8664

Emergency telephone number

: +27 (0)83 123 3911

E-mail address : [email protected]

2. HAZARDS IDENTIFICATION

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Avoid treating areas that are easily accessible to children and pets.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No. EC-No. Registration number

Classification Concentration [%]

Indoxacarb (S-Enantiomer) 173584-44-6 T; R25R43N; R50/53

0,6

For the full text of the R-phrases mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice : Never give anything by mouth to an unconscious person.

Inhalation : No hazards which require special first aid measures. Is not considered a potential route of exposure. Consult a physician if necessary.

Skin contact : No hazards which require special first aid measures. Wash with water and soap as a precaution. In the case of skin irritation or allergic reactions see a

Return to Index....


DuPont

™ Advion

® Cockroach Gel Bait

Version 2.2

Revision Date 10.11.2010 Ref.130000029437

2/7

physician.

Eye contact

: No hazards which require special first aid measures. Hold eye open and rinse slowly and gently with water for 15-20 minutes. If eye irritation persists, consult a specialist.

Ingestion

: No hazards which require special first aid measures. Do not induce vomiting without medical advice. Rinse mouth with water. Consult a physician if necessary.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment., Water, Water spray, Foam, Dry chemical, Carbon dioxide (CO2),

Extinguishing media which shall not be used for safety reasons

: High volume water jet, (contamination risk),

Specific hazards during fire fighting

: Not a fire or explosion hazard.

Special protective equipment for fire-fighters

: Wear self-contained breathing apparatus and protective suit.

Further information

: Prevent fire extinguishing water from contaminating surface water or the ground water system. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

(on small fires) If area is heavily exposed to fire and if conditions permit, let fire burn itself out since water may increase the area contaminated. Prevent fire extinguishing water from contaminating surface water or the ground water system.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

: Use personal protective equipment. Refer to protective measures listed in sections 7 and 8.

Environmental precautions

: Use appropriate container to avoid environmental contamination. Prevent further leakage or spillage. Do not allow material to contaminate ground water system. Do not flush into surface water or sanitary sewer system. Local authorities should be advised if significant spillages cannot be contained. If the spill area is porous, the contaminated material must be collected for subsequent treatment or disposal. If the product contaminates rivers and lakes or drains inform respective authorities.

Methods for cleaning up

: Clean-up methods - small spillage For small spills, use cloth or paper towels and place collected material and towels in appropriate container for disposal.

Clean-up methods - large spillage Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up or vacuum up


DuPont

™ Advion


Version 2.2


3/7

spillage and collect in suitable container for disposal. Flush away traces with water.

Additional advice

: Dispose of in accordance with local regulations.

7. HANDLING AND STORAGE

Handling

Advice on safe handling

: Before using, read the product bulletin. Wear personal protective equipment. Do not get in eyes or mouth or on skin. Do not store or consume food, drink or tobacco in areas where they may become contaminated with this material. Wash hands before breaks and immediately after handling the product. Close container after each use. For personal protection see section 8.

Advice on protection against fire and explosion

: Do not apply this product around electrical equipment due to the possibility of shock hazard.

Storage

Requirements for storage areas and containers

: Store in original container. Keep in properly labelled containers. Keep tightly closed in a dry and cool place. Store in a place accessible by authorized persons only. Keep out of the reach of children. Keep away from food, drink and animal feedingstuffs.

Advice on common storage

: No special restrictions on storage with other products.

Storage temperature

: > 3 °C

Other data

: Stable under recommended storage conditions.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment

Respiratory protection : No personal respiratory protective equipment normally required.

Hand protection : Material: Protective gloves The suitability for a specific workplace should be discussed with the producers of the protective gloves.

Eye protection

: Safety glasses with side-shields conforming to EN166

Hygiene measures

: Regular cleaning of equipment, work area and clothing. Contaminated work clothing should not be allowed out of the workplace. Avoid prolonged contact with eyes, skin and clothing. When using do not eat, drink or smoke. Wash hands before breaks and immediately after handling the product. Keep away from food, drink and animal feedingstuffs. For environmental protection remove and wash all contaminated protective equipment before re-use. Dispose of rinse water in accordance with local and national regulations.

Protective measures : No PPE is specified however, avoid contact with skin, eyes, and clothing.


DuPont

™ Advion


Version 2.2


4/7

9. PHYSICAL AND CHEMICAL PROPERTIES

Form

: gel,

Colour

: light tan,

Odour

: slight,

pH

: 5,4 at 10 g/l ( 25 °C), Method: CIPAC MT 75

Flash point

: > 100 °C

Flammability (solid, gas)

: Does not sustain combustion.

Oxidizing properties

: The product is not oxidizing.

Explosive properties

: Not explosive

Density

: 1,123 g/cm3 at 22 °C

10. STABILITY AND REACTIVITY

Conditions to avoid

: Temperature : < 3 °C Protect from frost.

Materials to avoid

: No materials to be especially mentioned.

Hazardous reactions

: None reasonably foreseeable. No dangerous reaction known under conditions of normal use. Stable at normal temperatures and storage conditions.

11. TOXICOLOGICAL INFORMATION

Acute oral toxicity

: LD50/ rat: > 5 000 mg/kgMethod: OECD Test Guideline 425 (Data on the product itself) Information source: Internal study report

Acute inhalation toxicity

• Indoxacarb (S-Enantiomer)

: LC50/ 4 h/ rat female: 4,2 mg/l

Acute dermal toxicity

: LD50/ rat 5 000 mg/kg Method: OECD Test Guideline 402 (Data on the product itself) Information source: Internal study report

Skin irritation

: rabbit Result: No skin irritation Method: OECD Test Guideline 404 (Data on the product itself) Information source: Internal study report

Eye irritation

: rabbit Result: No eye irritation Method: OECD Test Guideline 405 (Data on the product itself) Information source: Internal study report


DuPont

™ Advion


Version 2.2


5/7

Sensitisation

: Local lymph node test mouse Result: Animal test did not cause sensitization by skin contact. Method: OECD Test Guideline 429 (Data on the product itself) Information source: Internal study report

Mutagenicity assessment Indoxacarb (S-Enantiomer) : Tests on bacterial or mammalian cell cultures did not show mutagenic effects.,

Did not cause genetic damage in animals. Carcinogenicity assessment


: Did not show carcinogenic effects in animal experiments.

Toxicity to reproduction assessment


: Animal testing did not show any effects on fertility.

12. ECOLOGICAL INFORMATION

Elimination information (persistence and degradability) Biodegradability

: Not readily biodegradable. Estimation based on data obtained on active ingredient.

Bioaccumulation

: This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).

Toxicity to fish


: LC50 / 96 h/ Oncorhynchus mykiss (rainbow trout) : 0,65 mg/l

Aquatic toxicity


: / EC50/ 48 h/ Daphnia magna (Water flea): 0,256 mg/l

Chronic toxicity to fish


: Early Life-Stage/ NOEC/ 90 d/ Oncorhynchus mykiss (rainbow trout): 0,15 mg/l Method:

Chronic toxicity to aquatic Invertebrates


: / NOEC/ 21 d/ Daphnia magna (Water flea): 1 mg/l

Further information on ecology

Additional ecological information

: No data is available on the product itself. Do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the mean high


DuPont

™ Advion


Version 2.2


6/7

water mark.

13. DISPOSAL CONSIDERATIONS

Product

: Do not contaminate ponds, waterways or ditches with chemical or used container. Wastes resulting from the use of this product must be disposed of on site or at an approved waste disposal facility. In accordance with local and national regulations.

Contaminated packaging

: Dispose of in accordance with local regulations.

14. TRANSPORT INFORMATION

Further information : Not dangerous goods in the meaning of ADR/RID, ADNR, IMDG-Code,

ICAO/IATA-DGR

15. REGULATORY INFORMATION

Labelling according to EC Directives

Hazardous components: Indoxacarb (S-Enantiomer) R-phrase(s) : R52/53 Harmful to aquatic organisms, may cause long-term adverse

effects in the aquatic environment.

S-phrase(s) : S 2 Keep out of the reach of children.

S13 Keep away from food, drink and animal feedingstuffs. S35 This material and its container must be disposed of in a safe

way. S46 If swallowed, seek medical advice immediately and show this

container or label.

Special labelling of certain mixtures

: To avoid risks to man and the environment, comply with the instructions for use.

Sensitising components contains:

Indoxacarb (S-Enantiomer)

Indoxacarb, (R-enantiomer)

May produce an allergic reaction.

16. OTHER INFORMATION

Text of R-phrases mentioned in Section 3

R25 Toxic if swallowed. R43 May cause sensitization by skin contact.


DuPont

™ Advion


Version 2.2


7/7

R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Further information

Before use read DuPont's safety information., Take notice of the directions of use on the label. ® Registered trademark of E.I. du Pont de Nemours and Company

Significant change from previous version is denoted with a double bar.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The above information relates only to the specific material(s) designated herein and may not be valid for such material(s) used in combination with any other materials or in any process or if the material is altered or processed, unless specified in the text.

Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 1/7Version: 3.2 (30472240/SDS_CPA_US/EN)

1. Product and Company Identification

24 Hour Emergency Response Information Company BASF CORPORATION 100 Campus Drive Florham Park, NJ 07932, USA

CHEMTREC: 1-800-424-9300 BASF HOTLINE: 1-800-832-HELP

Registrant: Whitmire Micro-Gen Research Laboratories, Inc. 3568 Tree Court Industrial Blvd. St. Louis, MO 63122

Substance number: 000000396123 Synonyms: Abamectin B1

2. Hazards Identification

Emergency overview

CAUTION: KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. HARMFUL IF SWALLOWED. HARMFUL IF INHALED. HARMFUL IF ABSORBED THROUGH SKIN. Avoid inhalation of dusts. Avoid contact with the skin, eyes and clothing. Wash thoroughly after handling.

See Product Label for additional precautionary statements.

State of matter: solid Colour: brown Odour: mild

Potential health effects

Primary routes of exposure: Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases.

Acute toxicity: Relatively nontoxic after single ingestion. Slightly toxic after short-term skin contact.

Irritation / corrosion: May cause slight but temporary irritation to the eyes. Contact may result in skin irritation.

Return to Index....


Sensitization: Skin sensitizing effects were not observed in animal studies.

3. Composition / Information on Ingredients

CAS Number Content (W/W) Chemical name 71751-41-2 0.05 % Abamectin 99.05 % Proprietary ingredients

4. First-Aid Measures

General advice: First aid providers should wear personal protective equipment to prevent exposure. Remove contaminated clothing. Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or physician for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. If inhaled: Remove the affected individual into fresh air and keep the person calm. If on skin: Rinse skin immediately with plenty of water for 15 - 20 minutes. If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing. If swallowed: Have person sip a glass of water if able to swallow. Do not induce vomiting. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Note to physician Treatment: Treat symptomatically.

5. Fire-Fighting Measures

Flash point: Substance/product is non-flammable. Suitable extinguishing media: dry powder, carbon dioxide, water spray Hazards during fire-fighting: carbon monoxide, carbon dioxide, If product is heated above decomposition temperature, toxic vapours will be released. The substances/groups of substances mentioned can be released in case of fire. Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not allow to enter drains or waterways.


6. Accidental release measures

Personal precautions: Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment. Environmental precautions: Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water. A spill of or in excess of the reportable quantity requires notification to state, local and national emergency authorities. This product is not regulated by CERCLA ('Superfund'). Cleanup: Dike spillage. Sweep/shovel up. Avoid raising dust. Use wet cleaning methods when applicable. Place into suitable containers for reuse or disposal in a licensed facility. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal.

7. Handling and Storage

Handling

General advice: RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect against heat. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Provide means for controlling leaks and spills. Follow label warnings even after container is emptied. The substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment. Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition.

Storage

General advice: Keep only in the original container in a cool, dry, well-ventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protect against contamination. The authority permits and storage regulations must be observed. Storage incompatibility: General advice: Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials. Storage stability: May be kept indefinitely if stored properly. If an expiry date is mentioned on the packaging/label this takes priority over the statements on storage duration in this safety data sheet.

8. Exposure Controls and Personal Protection

Users of a pesticidal product should refer to the product label for personal protective equipment requirements.


Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment.


RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS: Respiratory protection: Wear respiratory protection if ventilation is inadequate. Breathing protection if breathable aerosols/dust are formed. Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards. Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit. General safety and hygiene measures: RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice. Personal protective equipment should be decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift. No eating, drinking, smoking or tobacco use at the place of work. Keep away from food, drink and animal feeding stuffs.

9. Physical and Chemical Properties

Form: powder Odour: mild Colour: brown pH value: 4.9 ( 1 %(m)) Melting point: not applicable Boiling point: not applicable Relative density: 0.619 ( 23 °C) Bulk density: 672.8 kg/m3 Vapour density: not determined Solubility in water: insoluble

10. Stability and Reactivity

Conditions to avoid: Avoid all sources of ignition: heat, sparks, open flame. Avoid prolonged storage. Avoid electro-static discharge. Avoid contamination. Avoid prolonged exposure to extreme heat. Avoid extreme temperatures. This product may form an explosive mixture if: 1. the dust is suspended in the atmosphere as a dust cloud AND 2. the concentration of the dust is above the lower explosion limit (LEL) AND 3. the limiting oxygen concentration (LOC) is exceeded. Substances to avoid: caustics


Hazardous reactions: The product is chemically stable. No hazardous reactions when stored and handled according to instructions. Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. To avoid thermal decomposition, do not overheat. Corrosion to metals: Corrosive effects to metal are not anticipated. Oxidizing properties: Not an oxidizer.

11. Toxicological information

Acute toxicity Oral: Type of value: LD50 Species: rat (male/female) Value: > 5,000 mg/kg (other) Inhalation: Type of value: LC50 Not inhalable due to the physico-chemical properties of the product. Dermal: Type of value: LD50 Species: rabbit (male/female) Value: > 2,000 mg/kg (other) Irritation / corrosion Skin: Species: rabbit Result: non-irritant Method: Primary skin irritation test Eye: Species: rabbit Result: non-irritant Method: Primary eye irritation test May cause slight irritation to the eyes. Genetic toxicity Information on: Abamectin Results from a number of mutagenicity studies with microorganisms, mammalian cell culture and mammals are available. Taking into account all of the information, there is no indication that the substance is mutagenic. ---------------------------------- Carcinogenicity Information on: Abamectin


In long-term studies in rats and mice in which the substance was given by feed, a carcinogenic effect was not observed. ---------------------------------- Reproductive toxicity Information on: Abamectin The results of animal studies suggest a fertility impairing effect with high doses. ---------------------------------- Development: Information on: Abamectin Causes developmental effects in animals at high, maternally toxic doses. ----------------------------------

12. Ecological Information Fish Information on: Abamectin Acute: Oncorhynchus mykiss/LC50 (96 h): 0.0036 mg/l ---------------------------------- Aquatic invertebrates Information on: Abamectin Acute: Daphnia magna/EC50 (48 h): 0.00034 mg/l ---------------------------------- Aquatic plants Information on: Abamectin Toxicity to aquatic plants: OECD Guideline 201 static green algae/EC50 (72 h): > 6.1 mg/l ---------------------------------- Not readily biodegradable (by OECD criteria). ----------------------------------

13. Disposal considerations

Waste disposal of substance: Pesticide wastes are regulated. If pesticide wastes cannot be disposed of according to label instructions, contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Container disposal: Rinse thoroughly at least three times (triple rinse) in accordance with EPA recommendations. Consult state or local disposal authorities for approved alternative procedures such as container recycling. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers.

14. Transport Information

Reference Bill of Lading


15. Regulatory Information

Federal Regulations Registration status: Chemical TSCA, US blocked / not listed Crop Protection TSCA, US released / exempt EPCRA 311/312 (Hazard categories): Acute; Chronic

16. Other Information

Refer to product label for EPA registration number. Recommended use: insecticide We support worldwide Responsible Care® initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products.

MSDS Prepared by: BASF NA Product Regulations [email protected] MSDS Prepared on: 2011/07/18 IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET

US EPA Reg No. 11649-4: CD PCPA Reg. No. 12098US EPA Reg No. 11649-6: CD PCPA Reg. No. 12095US EPA Reg No. 11649-7: CD PCPA Reg. No. 12096

Return to Index

May be harmful if swallowed.

1. PRODUCT AND COMPANY IDENTIFICATION

Product identifier Product Name: Bedlam PLUS®EPA Registration Number: 1021-2569

Other means of identification Part Code: 29511

Recommended use of the chemical and restrictions on use: Recommended Use: A Liquefied Aerosol Insecticide Spray.

Details of the supplier of the safety data sheet

Telephone Number: (800) 645-6466, or (763) 544-0341e-Mail Address: [email protected]

Emergency telephone numbers: 24 Hour TRANSPORTATION Emergency: CHEMTREC®: (800) 424-9300International: (703) 527-3887

24 Hour MEDICAL Emergency: SafetyCall®: (888) 740-8712, or (952) 852-9509

Comments: MGK® Hours of operation are 8:00 am to 4:30 pm CST, 14:00 to 22:30 GMT.For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day to(888) 740-8712, or (952) 852-9509.


Classification

OSHA Regulatory Status:This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).

Acute toxicity - Inhalation (Dusts/Mists) Category 4Skin sensitization Category 1

Label elements Emergency Overview

_____________________________________________________________________________________________

Page 1 / 9

Revision Date: 30-Oct-2015 Version: 1

Manufacturer Address:McLaughlin Gormley King Company8810 10th Avenue NorthMinneapolis, MN 55427

FAX #:(763) 544-6437

WARNING

SAFETY DATA SHEET

Flammable aerosol

Hazard statements

Issue Date: 30-Oct-2015

Category 2Gases under pressure Liquefied gas

Return to Index...

_____________________________________________________________________________________________

Precautionary Statements - Prevention:P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smokingP211 - Do not spray on an open flame or other ignition sourceP251 - Pressurized container: Do not pierce or burn, even after useP261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP271 - Use only outdoors or in a well-ventilated areaP272 - Contaminated work clothing should not be allowed out of the workplaceP280 - Wear protective gloves

Precautionary Statements - Response:P321 - Specific treatment (see Section 4/ First Aid).P302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP363 - Wash contaminated clothing before reuseP304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP312 - Call a POISON CENTER or doctor/physician if you feel unwell

Precautionary Statements - Storage:P410 + P403 - Protect from sunlight. Store in a well-ventilated placeP411 - Do not expose to temperatures exceeding 122 °F (50 °C)

Precautionary Statements - Disposal:P501 - Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC):Do not use this product in or on electrical equipment due to the possibility of shock hazard.

3. COMPOSITION/ INFORMATION ON INGREDIENTS

Chemical Name CAS No Weight-%d-Phenothrin (SUMITHRIN®) 26002-80-2 0.40

MGK®-264 Insecticide Synergist (n-Octylbicycloheptene dicarboximide)

113-48-4 1.00

Imidacloprid 138261-41-3 0.05Isobutane 75-28-5 5<--->15 *

*The exact percentage (concentration) of composition has been withheld as a trade secret.

_____________________________________________________________________________________________

Page 2 / 9

Revision Date: 30-Oct-2015Bedlam PLUS®

H280 - Contains gas under pressure; may explode if heated

Odor: Slight , Sweet - SolventAppearance: Milky white / Milkyyellow (Aerosol Non-volatiles)

Physical state: Aerosol -Compressed liquefied gas.

_____________________________________________________________________________________________

Comments: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications.


Aspiration pneumonia hazard:

Description of first aid measures:

Eye contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Removecontact lenses, if present, after the first 5minutes, then continue rinsing eye. Call apoison control center or doctor for treatment advice.

Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for15-20 minutes. Call a poison control centeror doctor for treatment advice.

Ingestion: If swallowed, IMMEDIATELY call a poison control center or doctor for treatmentadvice. Have person sip a glass of water if able to swallow. Do not induce vomitingunless told to do so by a poison control center or a doctor. Never give anything bymouth to an unconscious person.

Inhalation: Remove affected person to fresh air. If person is not breathing, call 911 or anambulance, then give artificialrespiration, preferably mouth-to-mouth if possible.Call a poison control center or doctor for further treatment advice.

Self-protection of the FirstResponder:

Remove all sources of ignition. Use personal protective equipment as required.

Note to physicians: For skin effects, a highly efficient therapeutic agent for Pyrethrin/ Pyrethroidexposure is topical application of tocopherol acetate (Vitamin E).


Suitable extinguishing mediaUse extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media:Caution: Use of water spray when fighting fire may be inefficient.

Hazardous combustion products: Carbon monoxide, Carbon dioxide (CO2).

Specific hazards arising from the chemicalNo information available.

Explosion data Sensitivity to Mechanical Impact: None.Sensitivity to Static Discharge: None.

Protective equipment and precautions for firefighters:In the event of fire and/or explosion do not breathe fumes.

Chronic Hazard Star Legend * = Chronic Health Hazard_____________________________________________________________________________________________

Page 3 / 9

HMIS

NFPA

Health hazards 1 *

Bedlam PLUS®

Flammability 4 Physical hazards 0 Personal protectionX

Health hazards 2

Revision Date: 30-Oct-2015

Flammability 4 Instability 0 Physical andChemical Properties*

_____________________________________________________________________________________________


Personal precautions, protective equipment and emergency procedures

Personal precautions: Remove all sources of ignition. Evacuate personnel to safe areas. Ensureadequate ventilation, especially in confined areas. Keep people away from andupwind of spill/leak. Use personal protective equipment as required.

Environmental precautions: Prevent further leakage or spillage if safe to do so. Prevent product from enteringdrains. See Section 12 for additional ecological information.

Methods and material for containment and cleaning up

Methods for containment: Prevent further leakage or spillage if safe to do so. Cover powder spill with plasticsheet or tarp to minimize spreading. Dike far ahead of liquid spill for later disposal.

Methods for cleaning up: Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,universal binder, sawdust). Pick up and transfer to properly labeled containers.Soak up with inert absorbent material.


Precautions for safe handling

Advice on safe handling: Ensure adequate ventilation, especially in confined areas. Keep away from heat,sparks, flame and other sources of ignition (i.e., pilot lights, electric motors andstatic electricity). Take precautionary measures against static discharges. Usespark-proof tools and explosion-proof equipment. All equipment used whenhandling the product must be grounded. Use with local exhaust ventilation. Usepersonal protective equipment as required. Do not breathedust/fume/gas/mist/vapors/spray. Avoid contact with eyes. Avoid breathing vaporsor mists. Contents under pressure. Do not puncture or incinerate cans. Do notstick pin or any other sharp object into opening on top of can. For moreinformation, see product label.

Conditions for safe storage, including any incompatibilities

Storage Conditions: Keep tightly closed in a dry and cool place. Keep in properly labeled containers.Keep containers tightly closed in a cool, well-ventilated place. For moreinformation, see product label.

8. EXPOSURE CONTROLS/ PERSONAL PROTECTION

Control parameters

Exposure Guidelines: This product, as supplied, does not contain any hazardous materials withoccupational exposure limits established by the region specific regulatory bodies.

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Supplier OELIsobutane 75-28-5

STEL: 1000 ppm - TWA: 800 ppmTWA: 1900 mg/m3

-

NIOSH IDLH Immediately Dangerous to Life or Health

Appropriate engineering controls

_____________________________________________________________________________________________

Page 4 / 9

Bedlam PLUS® Revision Date: 30-Oct-2015

_____________________________________________________________________________________________

Engineering Controls: Safety showersEyewash stationsVentilation systems

Individual protection measures, such as personal protective equipment

Eye/face protection: Tight sealing safety goggles. Face protection shield.

Skin and body protection: Wear protective gloves and protective clothing.

Respiratory protection: If exposure limits are exceeded or irritation is experienced, NIOSH/MSHAapproved respiratory protection should be worn. Positive-pressure supplied airrespirators may be required for high airborne contaminant concentrations.Respiratory protection must be provided in accordance with current localregulations.

General HygieneConsiderations:

When using do not eat, drink or smoke. Regular cleaning of equipment, work areaand clothing is recommended.


Information on basic physical and chemical properties:

Physical state: Aerosol - Compressed liquefied gas.

Other Information:

Density: 1.00 g/cm3 @ 20.0 °C (Aerosol Non-volatiles)_____________________________________________________________________________________________

Page 5 / 9

Bedlam PLUS®

Upper flammability limit (UEL): No information available

pH: 5.3

Lower flammability limit (LEL): No information available

Odor threshold:

Vapor pressure: No information available

@ 5% in H2O. Test was performed on aerosolNon-Volatile's. .

No information available

Vapor density: No information available

Melting point / freezing point: No information available

Specific Gravity: No information available

Appearance:

Water solubility: No information available

Milky white / Milky yellow (Aerosol Non-volatiles)

Partition coefficient; n-Octanol/Water:


Boiling point / boiling range: No information available

Color (Gardner Scale):

Autoignition temperature: No information available


Decomposition temperature: No information available

Flash point:

Kinematic viscosity: No information available

> 93.3 °C / > 200.0 °F


Dynamic viscosity: 5.33 cPs @ 21.1°C.

Tag Closed Cup; Test was performed onaerosol Non-Volatile's;

Test was performed on aerosol Non-Volatile's..

Refractive Index: No information available

Odor: Slight , Sweet - Solvent

Property:

Evaporation rate: No information available

Values:

Flammability (solid, gas): No information available

_____________________________________________________________________________________________

VOC Content (%): 12.9

Miscibility/ Solubility: Water: Partially miscibleAlcohol Partially miscibleAromatic solvents: Partially misciblePetroleum distillates: Partially miscible


Reactivity

Chemical stabilityStable under recommended storage conditions.

Possibility of Hazardous ReactionsNone under normal processing.

Hazardous polymerization: Hazardous polymerization does not occur.

Conditions to avoidHeat, flames and sparks.

Incompatible materials:Incompatible with strong acids and bases. Incompatible with oxidizing agents.

Hazardous Decomposition ProductsCarbon monoxide, Carbon dioxide (CO2).


Numerical measures of toxicity - Product Information

Oral LD50 >5,000 mg/kg (rat)Dermal LD50 >5,000 mg/kg (rabbit)Inhalation LC50 >2.09 mg/L (rat; 4 hours)

Eye contact: Non-irritating to eyes. (rabbit).Skin Contact: Slightly irritating. (rabbit).Skin Irritation Index: 0.8

Sensitization: Positive. (guinea pig).

Comment: Some of the above toxicity data was bridged from the insecticide concentrate, thatis used in manufacturing this end-use product.

Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listedby OSHA, IARC or NTP.

Reproductive toxicity: No information available.Developmental Toxicity No information available.

Teratogenicity: No information available.STOT - single exposure: No information available.STOT - repeated exposure: No information available.

Chronic toxicity: Avoid repeated exposure.Target Organ Effects: Central nervous system.

_____________________________________________________________________________________________

Page 6 / 9


No data available

Bedlam PLUS®

_____________________________________________________________________________________________


Ecotoxicity:

Persistence and degradabilityNo information available.

BioaccumulationNo information available.

Chemical Name Partition coefficient; n-Octanol/ Water:d-Phenothrin (SUMITHRIN®)

26002-80-26.8

Isobutane 75-28-5

2.88

Other adverse effects: No information available

Environmental hazards (EPA):Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unlessin accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and thepermitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product tosewer systems without previously notifying the local sewage treatment plant authority. For guidance contact yourState Water Board or Regional Office of the EPA.


Waste treatment methods

Disposal of wastes: Disposal should be in accordance with applicable regional, national and local lawsand regulations. For more information, see product label.

Contaminated packaging: For more information, see product label.


DOT (Department of Transportation)

UN/ID Number: UN1950Proper Shipping Name: Aerosols, non-flammableHazard Class: 2.2

Air (IATA/ ICAO) UN/ID Number: UN1950Proper Shipping Name: Aerosols, non-flammableHazard Class: 2.2

Vessel (IMO/ IMDG)

UN/ID Number: UN1950Proper Shipping Name: Aerosols, non-flammableHazard Class: 2.2


_____________________________________________________________________________________________

Page 7 / 9


_____________________________________________________________________________________________

US Federal Regulations

SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does notcontain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of FederalRegulations, Part 372

SARA 311/312 Hazard Categories

Acute health hazard NoChronic Health Hazard YesFire hazard NoSudden release of pressure hazard YesReactive Hazard No

CWA (Clean Water Act)This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR122.21 and 40 CFR 122.42)

CERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under theComprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the SuperfundAmendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at thelocal, regional, or state level pertaining to releases of this material

US State Regulations:

California Proposition 65:This product does not contain any Proposition 65 chemicals

U.S. EPA Label Information:

EPA Registration Number: 1021-2569

Difference between SDS and EPA (FIFRA) Pesticide label:This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subjectto certain labeling requirements under federal pesticide law. These requirements differ from the classification criteriaand hazard information required for Safety Data Sheets (SDS), and for workplace labels of non-pesticide chemicals.The pesticide label also includes other important information, including directions for use. The hazard informationrequired on the pesticide label is reproduced below:

Precautionary Statements:

International:TSCA Does not complyDSL/NDSL Does not complyEINECS/ELINCS Does not complyENCS Does not complyIECSC CompliesKECL Does not complyPICCS Does not complyAICS Does not comply

_____________________________________________________________________________________________

Page 8 / 9


_____________________________________________________________________________________________

Legend:TSCA - United States Toxic Substances Control Act Section 8(b) InventoryDSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances ListEINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified ChemicalSubstancesENCS - Japan Existing and New Chemical SubstancesIECSC - China Inventory of Existing Chemical SubstancesKECL - Korean Existing and Evaluated Chemical SubstancesPICCS - Philippines Inventory of Chemicals and Chemical SubstancesAICS - Australian Inventory of Chemical Substances

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION.

SDS Prepared By: Troy Azzivitto, MGK® Chemistry Department.e-Mail Address: [email protected]

Disclaimer: The data contained herein are based on information currently available toMcLaughlin Gormley King Company and,to the best of our knowledge, areaccurate and based on sound expert opinion. Our statements herein, however, arenot to betaken as a warranty or representation for which McLaughlin Gormley KingCompany assumes legal responsibility.

End of Safety Data Sheet.

_____________________________________________________________________________________________

Page 9 / 9

Revision Date:30-Oct-2015


Revision Note:- New SDS.- GHS - Classification.

Issue Date:30-Oct-2015

Bedlam PLUS®

SAFETY DATA SHEETCB-80 Insecticide

SDS # : 6545-ARevision date: 2015-04-13

Format: NAVersion 1.01


Product Identifier

Product Name CB-80 Insecticide

Other means of identification

Product Code(s) 6545-A

Synonyms Pyrethrins and Pyrethroids, Pyrethrum PIPERONYL BUTOXIDE:Butylcarbityl(6-propylpiperonyl) ether, 1,3-Benzodioxole,5-[[2-(2-butoxyethoxy)ethoxy]methyl]-6-propyl-

Active Ingredient(s) Piperonyl Butoxide, Pyrethrins

Recommended use of the chemical and restrictions on use

Recommended Use: Insecticide

Restrictions on Use: Use as recommended by the label

Manufacturer Address FMC Corporation1735 Market StreetPhiladelphia, PA 19103(215) 299-6000 (General Information)[email protected] (E-Mail General Information)

Emergency telephone number For leak, fire, spill or accident emergencies, call:1 800 / 424 9300 (CHEMTREC - U.S.A.)1 703 / 527 3887 (CHEMTREC - Collect - All Other Countries)Medical Emergencies:1 800 / 331-3148 (PROSAR - U.S.A. & Canada)1 651 / 632-6793 (PROSAR - All Other Countries - Collect)


Classification

OSHA Regulatory Status

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200)

Acute toxicity - Inhalation (Dusts/Mists) Category 4Serious eye damage/eye irritation Category 2Skin sensitization Category 1Specific target organ toxicity (single exposure) Category 3Aspiration toxicity Category 1

Page 1 / 9

Flammable Aerosols Category 2

Return to Index...

CB-80 InsecticideSDS # : 6545-A

Revision date: 2015-04-13Version 1.01

GHS Label elements, including precautionary statements

EMERGENCY OVERVIEW

Precautionary Statements - PreventionP261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP272 - Contaminated work clothing should not be allowed out of the workplaceP210 - Keep away from heat/sparks/open flames/hot surfaces. - No smokingP211 - Do not spray on an open flame or other ignition sourceP251 - Do not pierce or burn, even after useP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/ attentionP302 + P352 - IF ON SKIN: Wash with plenty of water and soapP333 + P313 - If skin irritation or rash occurs: Get medical advice/ attentionP363 - Wash contaminated clothing before reuseP304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathingP312 - Call a POISON CENTER or doctor if you feel unwellP301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctorP331 - Do NOT induce vomiting

Precautionary Statements - StorageP405 - Store locked upP403 + P233 - Store in a well-ventilated place. Keep container tightly closedP410 + P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F

Precautionary Statements - DisposalP501 - Dispose of contents/ container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) No hazards not otherwise classified were identified.

Other Information May be harmful if swallowedHarmful to aquatic life with long lasting effects


Chemical name CAS-No Weight %Piperonyl butoxide 51-03-6 4

Pyrethrins 8003-34-7 0.5

Danger

Hazard StatementsH304 - May be fatal if swallowed and enters airwaysH313 - May be harmful in contact with skinH317 - May cause an allergic skin reactionH319 - Causes serious eye irritationH332 - Harmful if inhaledH335 - May cause respiratory irritationH336 - May cause drowsiness or dizziness

Page 2 / 9



1,1-Difluoroethane 75-37-6 65-75Isopropanol 67-63-0 10-15

Petroleum distillates, hydrotreated light 64742-47-8 5-15

Synonyms are provided in Section 1.


Eye Contact Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Removecontact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poisoncontrol center or doctor for further treatment advice.

Skin Contact Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20minutes. Call a poison control center or doctor for further treatment advice.

Inhalation Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificialrespiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor forfurther treatment advice.

Ingestion Immediately call a poison control center or doctor. Do not induce vomiting unless told to doso by a poison control center or doctor. Do not give any liquid to the person. Do not inducevomiting or give anything by mouth to an unconscious person.

Most important symptoms andeffects, both acute and delayed

Central nervous system effects.

Indication of immediate medicalattention and special treatmentneeded, if necessary

Treat symptomatically. Contains petroleum distillate. May pose an aspiration pneumoniahazard.


Suitable Extinguishing Media Foam. Carbon dioxide (CO2). Dry chemical. Water spray.

Specific Hazards Arising from theChemical

Contents under pressure.

Explosion data Sensitivity to Mechanical Impact Not sensitive.Sensitivity to Static Discharge Not sensitive.

Protective equipment andprecautions for firefighters

Isolate fire area. Evaluate downwind. In the event of fire, wear self contained breathingapparatus.


Personal Precautions Isolate and post spill area. Remove all sources of ignition. Ventilate the area. Wear suitableprotective clothing, gloves and eye/face protection. For personal protection see section 8. Ifventilation is not possible wear full protection suit and chemical protective equipment.

Other For further clean-up instructions, call FMC Emergency Hotline number listed in Section 1"Product and Company Identification" above.

Environmental Precautions See Section 12 for additional Ecological Information.

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Transfer damaged cartridges or cans to containers for later disposal. Clean and neutralizespill area, tools and equipment by washing with bleach water and soap. Waste must beclassified and labeled prior to recycling or disposal. Dispose of waste as indicated inSection 13. Rinsate may be disposed at a waste water treatment plant.

Page 3 / 9




Handling Do not contaminate other pesticides, fertilizers, water, food, or feed by storage or disposal.BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperaturesover 130°F. Do not open by force or throw into fire even after use. Do not spray on flamesor red-hot objects.

Storage Keep in a dry, cool and well-ventilated place. Keep away from open flames, hot surfacesand sources of ignition. Keep out of reach of children and animals. Keep/store only inoriginal container.

Incompatible products Strong oxidizing agents. Bases. Powdered earth metals.


Control parameters

Chemical name ACGIH TLV OSHA PEL NIOSH MexicoPyrethrins 8003-34-7

TWA: 5 mg/m3 TWA: 5 mg/m3 IDLH: 5000 mg/m3

TWA: 5 mg/m3Mexico: TWA 5 mg/m3

Mexico: STEL 10 mg/m3

Isopropanol 67-63-0

STEL 400 ppmTWA: 200 ppm

TWA: 400 ppmTWA: 980 mg/m3

IDLH: 2000 ppmTWA: 400 ppm

TWA: 980 mg/m3

STEL: 500 ppmSTEL: 1225 mg/m3

Mexico: TWA 400 ppmMexico: TWA 980 mg/m3

Mexico: STEL 500 ppmMexico: STEL 1225

mg/m3

Chemical name British Columbia Quebec Ontario TWAEV AlbertaPyrethrins 8003-34-7

TWA: 5 mg/m3 TWA: 5 mg/m3 TWA: 5 mg/m3 TWA: 5 mg/m3

Isopropanol 67-63-0

TWA: 200 ppmSTEL: 400 ppm



TWA: 200 ppmSTEL: 400 ppm



Petroleum distillates,hydrotreated light

64742-47-8

TWA: 200 mg/m3

Skin- - -


Engineering measures Apply technical measures to comply with the occupational exposure limits. When working inconfined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable forbreathing and wear the recommended equipment.


Eye/Face Protection If there is a potential for exposure to particles which could cause eye discomfort, wearchemical goggles.

Skin and Body Protection Wear long-sleeved shirt, long pants, socks, and shoes.

Hand Protection Protective gloves

Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approvedrespiratory protection should be worn. Respiratory protection must be provided inaccordance with current local regulations.

Hygiene measures Clean water should be available for washing in case of eye or skin contamination. Washskin prior to eating, drinking, chewing gum or using tobacco. Shower or bathe at the end ofworking. Remove and wash contaminated clothing before re-use. Launder work clothingseparately from regular household laundry.

Page 4 / 9



General information If the product is used in mixtures, it is recommended that you contact the appropriateprotective equipment suppliers These recommendations apply to the product as supplied


Information on basic physical and chemical properties

Appearance yellow, Aerosolized liquidPhysical State Liquid AerosolColor YellowOdor PyrethrinsOdor threshold No information availablepH No information availableMelting point/freezing point Not applicableBoiling Point/Range No information availableFlash point 14.4 °C / 58 °F (Flame extension 5" - no flashback)Evaporation Rate No information availableFlammability (solid, gas) No information availableFlammability Limit in Air

Upper flammability limit: No information availableLower flammability limit: No information available

Vapor pressure No information availableVapor density No information availableDensity 7.29 lb/galSpecific gravity 0.8746Water solubility No information availableSolubility in other solvents No information availablePartition coefficient No information availableAutoignition temperature No information availableDecomposition temperature No information availableViscosity, kinematic No information availableViscosity, dynamic No information availableExplosive properties No information availableOxidizing properties No information availableMolecular weight No information availableBulk density No information available


Reactivity None under normal use conditions.

Chemical Stability Stable under recommended storage conditions.

Possibility of Hazardous Reactions None under normal processing.

Hazardous polymerization Hazardous polymerization does not occur.

Conditions to avoid Keep away from open flames, hot surfaces and sources of ignition.

Incompatible materials Strong oxidizing agents. Bases. Powdered earth metals.

Hazardous Decomposition Products Carbon oxides (COx), Hydrogen fluoride, Carbonyl fluoride.


Product Information

LD50 Oral 2,370 mg/kg (rat)LD50 Dermal > 2000 mg/kg (rabbit)LC50 Inhalation 2.5 mg/L (rat)

Eye Contact Slightly or non-irritating (rabbit)Skin Contact Slightly or non-irritating (rabbit)

Page 5 / 9



Sensitization Sensitizer.

Information on toxicological effects

Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.Intentional misuse by deliberately concentrating and inhaling contents may be harmful orfatal.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Mutagenicity Piperonyl butoxide ether may affect mammalian liver microsomal detoxification enzymes.n-Octyl bicycloheptene dicarboximide was negative in a chromosome aberration assay,

Carcinogenicity Not recognized as carcinogenic by Research Agencies (IARC, NTP, OSHA, ACGIH).Reproductive toxicity No information available.Developmental toxicity Isopropanol has been reported to cause teratogenicity in laboratory animals.STOT - single exposure Not classified.STOT - repeated exposure Not classified.Target organ effects Mice fed 0.3 or 0.9% piperonyl butoxide in the diet for 20 days had increased liver weight

and other signs of liver toxicity. Male rats given up to 2.4% of piperonyl butoxide in the dietfor up to 12 weeks had clinical and histologic signs of liver damage; the highest dose groupshowed preneoplastic changes, including enlargement of hepatocyte nuclei andmultinucleated cells. Kidney damage was also seen.

Aspiration hazard No information available.Chemical name ACGIH IARC NTP OSHA

Piperonyl butoxide 51-03-6

Group 3

Isopropanol 67-63-0

Group 3


Ecotoxicity

Piperonyl butoxide (51-03-6)Active Ingredient(s) Duration Species Value UnitsPiperonyl Butoxide LC50 Fish 3.94 ppm

LD50 Bee 25 µg/beeLD50 Bobwhite quail >2250 mg/kgLD50 Mallard duck >5620 ppm

Persistence and degradability No information available.

Bioaccumulation No information available.


Waste disposal methods Improper disposal of excess pesticide, spray mixture, or rinsate is prohibited. If thesewastes cannot be disposed of by use according to label instructions, contact appropriatedisposal authorities for guidance.

Contaminated Packaging Containers must be disposed of in accordance with local, state and federal regulations.Refer to the product label for container disposal instructions.


DOT

Page 6 / 9



UN/ID no 17 oz. Container: UN195013 lb. Cylinder: UN1954

Proper Shipping Name 17 oz. Container: Consumer Commodity13 lb. Cylinder: Compressed gas, flammable, n.o.s. (1,1-Difluoroethane, Isopropyl alcohol)

Hazard class 17 oz. Container: ORM-D13 lb. Cylinder: 2.1

TDG UN/ID no 17 oz. Container: UN1950

13 lb. Cylinder: UN1954Proper Shipping Name 17 oz. Container: Aerosols

13 lb. Cylinder: Compressed gas, flammable, n.o.s. (1,1-Difluoroethane, Isopropyl alcohol)Hazard class 2.1

ICAO/IATA UN/ID no 17 oz. Container: ID8000

13 lb. Cylinder: UN 1954Proper Shipping Name 17 oz. Container: Consumer Commodity

13 lb. Cylinder: Compressed gas, flammable, n.o.s. (1,1-Difluoroethane, Isopropyl alcohol)Hazard class 17 oz. Container: 9

13 lb. Cylinder: 2.1IMDG/IMO

UN/ID no 17 oz. Container: UN195013 lb. Cylinder: UN1954

Proper Shipping Name 17 oz. Container: Aerosols13 lb. Cylinder: Compressed gas, flammable, n.o.s. (1,1-Difluoroethane, Isopropyl alcohol)

Hazard class 2.1

15. REGULATORY INFORMATIONU.S. Federal Regulations

SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemicalor chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:

SARA 311/312 Hazard Categories Acute health hazard YesChronic health hazard YesFire hazard YesSudden release of pressure hazard NoReactive Hazard No

Clean Water ActThis product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21and 40 CFR 122.42):

Chemical name CWA - ReportableQuantities

CWA - Toxic Pollutants CWA - PriorityPollutants

CWA - HazardousSubstances

Pyrethrins 8003-34-7

1 lb

CERCLAThis material, as supplied, contains one or more substances regulated as a hazardous substance under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):

Chemical name Hazardous Substances RQs Extremely HazardousSubstances RQs

RQ


1 lb RQ 1 lb final RQRQ 0.454 kg final RQ

FIFRA Information

Page 7 / 9



This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labelingrequirements under federal pesticide law. These requirements differ from the classification criteria and hazard informationrequired for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information asrequired on the pesticide label:

CAUTIONContains petroleum distillates. Causes moderate eye irritation. Harmful if swallowed, inhaled, or absorbed through skin.Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.

US State Regulations

California Proposition 65This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations

This product does not contain any substances regulated by state right-to-know regulations

International Inventories

Component TSCA(UnitedStates)

DSL(Canada)

EINECS/ELINCS

(Europe)

ENCS(Japan)

China(IECSC)

KECL(Korea)

PICCS(Philippines)

AICS(Australia)

Piperonyl butoxide 51-03-6 ( 4 )

X X X X X X X X

Pyrethrins 8003-34-7 ( 0.5 )

X X X X X X

1,1-Difluoroethane 75-37-6 ( 65-75 )

X X X X X X X X

Isopropanol 67-63-0 ( 10-15 )

X X X X X X X X

Petroleumdistillates,

hydrotreated light 64742-47-8 ( 5-15 )

X X X X X X X X

Mexico - Grade Serious risk, Grade 3

WHMIS Hazard Class A - Compressed gasesB5 - Flammable aerosolD1B - Toxic materialsD2B - Toxic materials


Revision date: 2015-04-13Revision note Format Change

NFPA Health Hazards 2 Flammability 3 Instability 0 Special Hazards -

HMIS Health Hazards 2 Flammability 3

Page 8 / 9

Physical hazard 0 Personal Protection X



DisclaimerFMC Corporation believes that the information and recommendations contained herein (including data and statements)are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OFMERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATIONPROVIDED HEREIN. The information provided herein relates only to the specified product designated and may not beapplicable where such product is used in combination with any other materials or in any process. Use of this product isregulated by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in amanner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of FMCCorporation, FMC corporation expressly disclaims any and all liability as to any results obtained or arising from any useof the products or reliance on such information.

Prepared By:FMC Corporation

FMC Logo - Trademark of FMC Corporation

© 2015 FMC Corporation. All Rights Reserved.End of Safety Data Sheet

Page 9 / 9

Trade Name: Contrac All-Weather Blox Date Created: January 2015 Supplier: Bell Laboratories, Inc. Page 1 of 4

CONTRAC®ALL-WEATHER BLOX SAFETY DATA SHEET ACCORDING TO REGULATION: OSHA

Hazard Communication Standard 29 CFR 1910.1200 DATE OF ISSUE: January 2015

PREPARED BY: CAR

1. PRODUCT AND COMPANY IDENTIFICATIONProduct Identifier: CONTRAC® ALL-WEATHER BLOX EPA Registration Number: 12455-79 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Anticoagulant Rodenticide - Ready to use Uses advised against: Use only for the purpose described above

MANUFACTURER/SUPPLIER: Bell Laboratories, Inc. 3699 Kinsman Blvd. Madison, WI 53704, USA Email: [email protected] Phone: 608-241-0202 Medical or Vet Emergency: 877-854-2494 or 952-852-4636 Spill or Transportation Emergency: 800-424-9300 (CHEMTREC)

2. HAZARD IDENTIFICATIONClassification according to Regulation OSHA 1910.1200(d): Not classified

See Section 15 for information on FIFRA applicable safety, health, and environmental classifications.

3. COMPOSITION/INFORMATION ON INGREDIENTSComponent CAS No. % By weight

Bromadiolone [3-[3-(4’-Bromo-[1,1’-biphenyl]-4-yl)-3-hydroxy-1-phenylpropyl]-4-hydroxy-2H-1-benzopyran-2-one]

28772-56-7 0.005%

Inert and Non-Hazardous Ingredients Proprietary 99.995%

4. FIRST AID MEASURESDescription of first aid measures Ingestion: Call physician or emergency number immediately. Have person sip a glass of water if able to swallow. Do not induce vomiting unless instructed by physician. Inhalation: Not applicable. Eye contact: Hold eye open and rinse slowly with water for 15 – 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. If irritation develops, obtain medical assistance. Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. If irritation develops, obtain medical assistance. Most important symptoms and effects, both acute and delayed Ingestion of excessive quantities may cause nausea, vomiting, loss of appetite, extreme thirst, lethargy, diarrhea, bleeding. Advice to physician: If ingested, administer Vitamin K1 intramuscularly or orally as indicated for bishydroxycoumarin overdoses. Repeat as necessary as based upon monitoring of prothrombin times. Advice to Veterinarian: For animals ingesting bait and/or showing poisoning signs (bleeding or elevated prothrombin times), give Vitamin K1. If needed, check prothrombin times every 3 days until values return to normal (up to 30 days). In severe cases, blood transfusions may be needed.

Return to Index


5. FIRE-FIGHTING MEASURES Extinguishing media Suitable Extinguishing Media: water, foam or inert gas. Unsuitable Extinguishing Media: None known. Special hazards arising from the mixture: High temperature decomposition or burning in air can result in the formation of toxic gases, which may include carbon monoxide and traces of bromine and hydrogen bromide. Advice for firefighters: Wear protective clothing and self-contained breathing apparatus.

6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Gloves should be worn when handling the bait. Collect spillage without creating dust. Environmental precautions: Do not allow bait to enter drains or water courses. Where there is contamination of streams, rivers or lakes contact the appropriate environment agency. Methods and materials for containment and cleaning up For Containment: Sweep up spilled material immediately. Place in properly labeled container for disposal or re-use. For Cleaning Up: Wash contaminated surfaces with detergent. Dispose of all wastes in accordance with all local, regional and national regulations. Reference to other sections: Refer to Sections 7, 8 & 13 for further details of personal precautions, personal protective equipment and disposal considerations.

7. HANDLING AND STORAGE Precautions for safe handling: Do not handle the product near food, animal foodstuffs or drinking water. As soon as possible, wash hands thoroughly after applying bait and before eating, drinking, chewing gum, using tobacco, or using the toilet. Conditions for safe storage, including any incompatibilities: Store only in original container in a cool, dry place, inaccessible to pets and wildlife. Do not contaminate water, food or feed by storage or disposal. Keep containers closed and away from other chemicals.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION Established Limits

Component OSHA ACGIH Other Limits Bromadiolone Not Established Not Established Not Established

Appropriate Engineering Controls: Not required Occupational exposure limits: Not established Personal Protective Equipment: Respiratory protection: Not required Eye protection: Not required Skin protection: Shoes plus socks, and waterproof gloves. Hygiene recommendations: Wash thoroughly with soap and water after handling.


9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties

Appearance/Color: Blue wax block Odor: Sweet grain-like Odor Threshold: Not applicable, odor not associated with a hazardous material. pH: Not applicable, Contrac All-Weather Blox is not dispersible with water. Melting point: Not applicable to rodenticide bait Boiling point: Not applicable to rodenticide bait Flash point: Not applicable, Contrac All-Weather Blox does not contain components classified as flammable. Evaporation rate: Not applicable, Contrac All-Weather Blox is a solid. Upper/lower flammability or explosive limits:

Not applicable, Contrac All-Weather Blox does not contain components classified as flammable or explosive.

Vapor Pressure: Vapor Density:

Not applicable to rodenticide bait NA: Contrac All-Weather Blox is a solid

Relative Density: 1.13 g/mL @ 20°C Solubility (water): Not water soluble Solubility (solvents): Not applicable to rodenticide bait Partition coefficient: n-octanol/water:

Not applicable to rodenticide bait

Auto-ignition temperature: Not applicable, Contrac All-Weather Blox does not contain components classified as flammable. Decomposition temperature: Not applicable to rodenticide bait Viscosity: Not applicable, Contrac All-Weather Blox is not a liquid.

10. STABILITY AND REACTIVITY Reactivity: Stable when stored in original container in a cool, dry location. Chemical stability: Stable when stored in original container in a cool, dry location. Possibility of hazardous reactions: Refer to Hazardous decomposition products Conditions to avoid: Avoid extreme temperatures (below 0°C or above 40°C). Incompatible materials: Avoid strongly alkaline materials. Hazardous decomposition products: High temperature decomposition or burning in air can result in the formation of toxic gases, which may include carbon monoxide and traces of bromine and hydrogen bromide.

11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute Toxicity LD50, oral (ingestion): >5000 mg/kg (rats) (Bromadiolone Rat LD50 oral: 0.70 mg/kg bw). LD50, dermal (skin contact): > 5001 mg/kg (rats) (Bromadiolone rabbit LD50 dermal: 1.71 mg/kg bw). LC50, inhalation: Contrac All-Weather Blox is a wax block and therefore exposure by inhalation is not relevant. Skin corrosion/irritation: Not irritating to skin. Serious eye damage/Irritation: Not irritating to eyes. Respiratory or skin sensitization: Dermal sensitization: Not a Sensitizer (Guinea pig maximization test). Germ cell mutagenicity: Contrac All-Weather Blox contains no components known to have a mutagenetic effect. Carcinogenicity: Contrac All-Weather Blox contains no components known to have a carcinogenetic effect.

Components NTP IARC OSHA Bromadiolone Not listed Not listed Not listed

Reproductive Toxicity: Contrac All-Weather Blox: No data Aspiration Hazard: Not applicable. Contrac All-Weather Blox is a wax block. Target Organ Effects: Reduced blood clotting ability.

12. ECOLOGICAL INFORMATION Ecotoxicity Effects: This product is extremely toxic to fish, birds and other wildlife. Dogs and predatory and scavenging mammals and birds might be poisoned if they feed upon animals that have eaten this bait. Do not apply this product directly to water or to areas where surface water is present or to intertidal areas below the mean high water mark. Runoff also may be hazardous to aquatic organisms in water adjacent to treated areas. Do not contaminate water when disposing of equipment wash water or rinsate. Persistence and degradability: Contrac All-Weather Blox is inherently biodegradable. Bioaccumulative potential: Not determined for Contrac All-Weather Blox. Bromadiolone water solubility is extremely low (< 0.1mg/l). Mobility in Soil: Not determined for Contrac All-Weather Blox. Mobility of bromadiolone in soil is considered to be limited. Other adverse effects: None.


13. DISPOSAL CONSIDERATIONS Do not contaminate water, food or feed by storage or disposal. Pesticide Storage: Store only in original container in a cool, dry place inaccessible to children and pets. Keep containers closed and away from other chemicals. Pesticide Disposal: Wastes resulting from the use of this product may be placed in trash or delivered to an approved waste disposal facility. Container Handling: Non-refillable container. Do not reuse or refill this container. [Plastic:] Offer for recycling or reconditioning; or puncture and dispose of in a sanitary landfill; or by incineration. In most states, burning is not allowed. [Paper:] Dispose of empty container by placing in trash, at an approved waste disposal facility or by incineration. In most states, burning is not allowed.

14. TRANSPORT INFORMATION UN number: Not regulated UN proper shipping name: Not regulated Transport hazard class(es): Not regulated Packing group : Not regulated Environmental Hazards DOT Road/Rail: Not considered hazardous for transportation via road/rail. DOT Maritime: Not considered hazardous for transportation by vessel. DOT Air: Not considered hazardous for transportation by air. Freight Classification: LTL Class 60 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code: Not applicable Special precautions for user: None

15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture: FIFRA: This pesticide product is regulated by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The safety, health, environmental, and hazard information required on the pesticide label is listed below and reflected throughout this SDS. The pesticide label also includes other important information, including directions for use. Signal Word: CAUTION Precautionary Statements: Contains the anticoagulant Bromadiolone which may cause bleeding if ingested. Harmful if swallowed or absorbed through the skin. Keep away from children, domestic animals and pets. Do not get in eyes, on skin or on clothing. Potential Health Effects: Eye Contact: May cause irritation Skin Contact: Non-irritating to the skin Ingestion: Harmful if swallowed TSCA: All components are listed on the TSCA Inventory or are not subject to TSCA requirements CERCLA/SARA 313: Not listed CERCLA/SARA 302: Not listed

16. OTHER INFORMATION For additional information, please contact the manufacturer noted in Section 1.

NFPA Health: 1 (caution) Flammability: 0 (will not burn) Reactivity: 0 (stable) Specific Hazard: None HMIS Health: 2 (moderate) Flammability: 0 (minimal) Reactivity: 0 (minimal) Protective Equipment: B

Disclaimer: The information provided in this Safety Data Sheet has been obtained from sources believed to be reliable. Bell Laboratories, Inc. provides no warranties; either expressed or implied, and assumes no responsibility for the accuracy or completeness of the data contained herein. This information is offered for your consideration and investigation. The user is responsible to ensure that they have all current data, including the approved product label, relevant to their particular use.

SAFETY DATA SHEET

1. Identification

Product identifier Deadline Bullets®


SDS number 305

QAD Number 11578

Synonym(s) Deadline® M-Ps™ * Deadline® T&O * Deadline® M-Ps™ Mini Pellets * Deadline® Ornamental

Recommended use Mollusicide

Recommended restrictions Keep out of the Reach of Children!Keep away from dogs!

5481-511

Product registration number

EPA

5481-507

Pest Control Products Act(Canada)

WHMIS: 26650

Manufacturer/Importer/Supplier/Distributor information

Manufacturer

AMVAC Chemical Corporation

Address

Los Angeles, CA 90023 USA

4100 E Washington Blvd

Company name

Website

Telephone AMVAC Chemical Corp 323-264-3910

AMVAC Chemical Corp 323-268-1028 (FAX)

Emergency phone number Medical 888-681-4261

CHEMTREC® (USA+Canada) 800-424-9300

Product Use 888-462-6822

CHEMTREC® (Outside USA) +1-703-527-3887

E-mail

www.Amvac-Chemical.com

[email protected]

2. Hazard(s) identification

Not classified.Physical hazards

Category 4Acute toxicity, inhalationHealth hazards

Category 2BSerious eye damage/eye irritation

Category 2Reproductive toxicity

Not classified.Environmental hazards

Not classified.OSHA defined hazards

Label elements

Signal word Warning

Hazard statement Causes eye irritation.

Precautionary statement

Prevention Wash hands thoroughly after handling.

Response If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present andeasy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Storage Store away from incompatible materials.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

1 / 8

Material name: Deadline Bullets®

11578 Version #: 01 Issue date: 04-08-2015

SDS US

Return to Index

Hazard(s) not otherwiseclassified (HNOC)

None known.

Supplemental information United States Environmental Protection Agency Labeling Requirements: This chemical is apesticide product registered by the United States Environmental Protection Agency and is subjectto certain labeling requirements under federal pesticide law. These requirements differ from theclassification criteria and hazard information required for safety data sheets (SDS), and forworkplace labels of non-pesticide chemicals. The hazard information required on the pesticidelabel is reproduced below. The pesticide label also includes other important information, includingdirections for use.

HAZARDS TO HUMANS AND DOMESTIC ANIMALS.

CAUTION. Harmful if swallowed. Avoid breathing dust. May cause eye irritation. Avoid contactwith eyes, skin, and clothing. This pesticide may be fatal to children and dogs or other animals ifeaten. Keep out of reach of children and pets, poultry and livestock. Keep children, dogs andother pets out of treated areas.

ENVIRONMENTAL HAZARDS

For terrestrial uses, do not apply directly to water, or to areas where surface water is present or tointertidal areas below the mean high water mark. Do not contaminate water when disposing ofequipment washwater or rinsate.

3. Composition/information on ingredients

Mixtures

CAS number %Common name and synonymsChemical name

MixtureOther components 96

108-62-3Metaldehyde 4

4. First-aid measures

Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen orartificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance.Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or otherproper respiratory medical device. Call a POISON CENTER or doctor/physician if you feel unwell.

Skin contact Take off contaminated clothing and wash before reuse. Wash off immediately with plenty of water.If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse.

Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Continue rinsing. Removecontact lenses, if present and easy to do. Call a physician or poison control center immediately.

Ingestion Call a physician or poison control center immediately. Rinse mouth. Drink 1 or 2 glasses of water.Do not induce vomiting without advice from poison control center. Have physician determine ifpatient’s condition allows induction of vomiting or evacuation of stomach. Never give anything bymouth to a victim who is unconscious or is having convulsions.

Most importantsymptoms/effects, acute anddelayed

Based on animal toxicity information for metaldehyde, it is anticipated that this material would beharmful upon ingestion and that direct contact may elicit mild eye and skin irritation. Overexposureto metaldehyde may cause excessive salivation, vomiting, nausea, acetonuria (odor of acetone onbreath), convulsions, increased body temperature, depression of medullary respiratory andvasomotor control centers and coma. May be fatal. [Note: Because of the low amounts ofmetaldehyde in the product, it is unlikely the victim can be exposed to sufficient quantities ofmetaldehyde to have coma or death induced.] Overexposure may aggravate preexisting conditionsassociated with the kidney, liver, and brain.

Indication of immediatemedical attention and specialtreatment needed

According to manufacturer of Metaldehyde Technical communication , gastric lavage with a 2.5%solution of sodium bicarbonate-powdered charcoal and prevention of acidosis by sodiumbicarbonate may be needed. Administration of Diazepam or Clonidine 20 minutes after ingestion of1000 mg/kg of Metaled by mice delayed the onset of symptoms and reduced mortality. This isequivalent to 0.6 lb of product ingested for a 10 kg child. Therefore, Diazepam and Clonidine maybe appropriate antidotes to reduce the symptomatology of Metaldehyde ingestion. For acuteinhalation overexposure, the patient should be monitored as respiratory failure may occur 24 to 48hours after exposure.

General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. In the case of accident or if you feel unwell, seek medical advice immediately(show the label where possible).

5. Fire-fighting measures

Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).

2 / 8



SDS US

Unsuitable extinguishingmedia

None known.

Specific hazards arising fromthe chemical

During fire, gases hazardous to health may be formed.

Special protective equipmentand precautions for firefighters

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire fightingequipment/instructions

In the event of fire, cool tanks with water spray. Water runoff can cause environmental damage.

General fire hazards May form combustible dust concentrations in air.


Personal precautions,protective equipment andemergency procedures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out oflow areas. Wear appropriate personal protective equipment. Do not touch damaged containers orspilled material unless wearing appropriate protective clothing. Ventilate closed spaces beforeentering them. Local authorities should be advised if significant spillages cannot be contained. Forpersonal protection, see section 8 of the SDS/SDS.

Methods and materials forcontainment and cleaning up

Stop the flow of material, if this is without risk, to prevent entry into waterways, sewer, basementsor confined areas. Collect spillage. Prevent entry into waterways, sewer, basements or confinedareas. Following product recovery, flush area with water. For waste disposal, see section 13 of theSDS.

Environmental precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquaticenvironment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoiddischarge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Keep out of the reach of children. Keep away from food, drink and animal feedstuffs. Minimize dustgeneration and accumulation. Avoid breathing dust. Use only outdoors or in a well-ventilated area.Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Wear appropriatepersonal protective equipment recommended in section 8. Wash thoroughly after handling. Washcontaminated clothing before reuse. Observe good industrial hygiene practices. Avoid release tothe environment. Do not empty into drains.

Conditions for safe storage,including any incompatibilities

Keep container tightly closed. Store in a cool, dry place out of direct sunlight. Store in awell-ventilated place.

8. Exposure controls/personal protection

Occupational exposure limits

US. ACGIH Threshold Limit Values

ValueMaterial Type

TWA 0.5 mg/m3Deadline Bullets®

Biological limit values No biological exposure limits noted for the ingredient(s).

Exposure guidelines Dust exposure limit.

Appropriate engineeringcontrols

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level.


Eye/face protection Wear safety glasses with side shields (or goggles). Wear a full-face respirator, if needed.

Skin protection

Hand protection To prevent skin contact use suitable protective gloves.

Other Wear suitable protective clothing.

Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.

Thermal hazards Not applicable.

General hygieneconsiderations

Always observe good personal hygiene measures, such as washing after handling the materialand before eating, drinking, and/or smoking. Routinely wash work clothing and protectiveequipment to remove contaminants.

9. Physical and chemical properties

Appearance Red, blue or buff colored pellet

Physical state Solid.

3 / 8



SDS US

Form Pellets.

Color Red, blue or buff.

Odor Aldehyde odor

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Initial boiling point and boilingrange

Not available.

Flash point Not available.

Evaporation rate Not available.

Flammability (solid, gas) Not available.

Upper/lower flammability or explosive limits

Flammability limit - lower(%)

Not available.

Flammability limit - upper(%)

Not available.

Explosive limit - lower (%) Not available.

Explosive limit - upper (%) Not available.

Vapor pressure 1.90E+00 mm Hg @ 24°C (active ingredient).

Vapor density 6.06 (air = 1).

Relative density Not available.

Solubility(ies)

Solubility (water) 0.2 g/l @ 17°C for active ingredient.

Auto-ignition temperature Not available.

Decomposition temperature Not available.

Viscosity Not available.

Other information

Bulk density 24 - 45 lb/ft3

Specific gravity 0.4 - 0.72

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability Material is stable under normal conditions.

Possibility of hazardousreactions

Hazardous polymerization does not occur.

Conditions to avoid Avoid conditions which create dust. Contact with incompatible materials. Avoid heat, sparks, openflames and other ignition sources.

Incompatible materials Strong oxidizing agents.

Hazardous decompositionproducts

Acetaldehyde can be formed by decomposition of Metaldehyde. Decomposition by burning mayresult in carbon monoxide and other toxic fumes and vapors of unknown composition.


Information on likely routes of exposure

Inhalation Prolonged inhalation may be harmful.

Skin contact Slight skin irritant.

Eye contact Causes mild eye irritation.

Ingestion However, ingestion is not likely to be a primary route of occupational exposure.

4 / 8



SDS US

Symptoms related to thephysical, chemical andtoxicological characteristics

Exposed individuals may experience eye tearing, redness, and discomfort. Based on animaltoxicity information for metaldehyde, it is anticipated that this material would be harmful uponingestion and that direct contact may elicit mild eye and skin irritation. Overexposure tometaldehyde may cause excessive salivation, vomiting, nausea, acetonuria (odor of acetone onbreath), convulsions, increased body temperature, depression of medullary respiratory andvasomotor control centers and coma. May be fatal. [Note: Because of the low amounts ofmetaldehyde in the product, it is unlikely the victim can be exposed to sufficient quantities ofmetaldehyde to have coma or death induced.]


Acute toxicity Causes mild eye irritation.

Test ResultsProduct Species

Deadline Bullets®

Dermal

Acute

LD50 Rabbit > 5050 mg/kg (EPA Tox Cat IV).

Inhalation

LC50 Rat > 2.48 mg/l, 4 hours (EPA Tox Cat IV).

Oral

* Estimates for product may be based on additional component data not shown.

LD50 Rat > 5000 mg/kg (EPA Tox Cat IV).

Skin corrosion/irritation Causes slight skin irritation.

Irritation Corrosion - SkinDeadline Bullets® , (EPA Tox Cat IV).

Result: Slightly irritating

Serious eye damage/eyeirritation

Causes mild eye irritation.

Eye / Kay and Calandra class - IntactDeadline Bullets® , (EPA Tox Cat iV).

Result: Mild irritant.

Respiratory or skin sensitization

Respiratory sensitization Not a respiratory sensitizer.

Skin sensitization This product is not expected to cause skin sensitization.

SensitizationDeadline Bullets® Result: Not a skin sensitizer.

Species: Guinea pig

Germ cell mutagenicity No evidence of mutagenicity with in vitro testing. No data available to indicate product or anycomponents present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity Acetaldehyde, a decomposition product of Metaldehyde, has been listed as carcinogenic in theIARC monographs and by the NTP. Acetaldehyde is present at less than 0.01% in the product.None of the components found in appreciable quantities has been found to be carcinogenic byIARC, NTP, or OSHA.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Reproductive toxicity No evidence of reproductive toxicity has been observed. No evidence of teratogenicity inlaboratory animals.

Specific target organ toxicity -single exposure

Not classified.

Specific target organ toxicity -repeated exposure

Not classified.

Aspiration hazard Not an aspiration hazard.

Chronic effects Overexposure may aggravate preexisting conditions associated with the kidney, liver, and brain.

12. Ecological information

Ecotoxicity No information is available about the potential of this material to produce adverse environmentaleffects. This product may be fatal to dogs, other pests, and wild animals if eaten. May be toxic towater inhabitants. Do not contaminate water bodies.

5 / 8



SDS US

Persistence and degradability No data is available on the degradability of this product.

Bioaccumulative potential

Mobility in soil No data available.

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.


Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site according to allapplicable regulations. Dispose of contents/container in accordance with all applicablelocal/regional/national/international regulations.

Local disposal regulations Dispose in accordance with all applicable regulations.

Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the wastedisposal company.

Waste from residues / unusedproducts

Dispose of in accordance with all applicable regulations. Empty containers or liners may retainsome product residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposalaccording to all applicable regulations. Since emptied containers may retain product residue,follow label warnings even after container is emptied.

14. Transport information

DOT

Not regulated as dangerous goods.

IATA


IMDG


Not established.Transport in bulk according toAnnex II of MARPOL 73/78 andthe IBC Code

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200. This product is registered under EPA/FIFRA Regulations. It is aviolation of Federal Law to use this product in any manner inconsistent with its labeling. Read andfollow all label directions. This product is excluded from listing requirements under EPA/TSCA.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Metaldehyde (CAS 108-62-3) Listed.

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No

SARA 302 Extremely hazardous substance

Not listed.

SARA 311/312 Hazardouschemical

Yes

SARA 313 (TRI reporting)

Not regulated.

6 / 8



SDS US

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

Safe Drinking Water Act(SDWA)

Not regulated.

US state regulations

US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)

Not listed.

US. Massachusetts RTK - Substance List

Metaldehyde (CAS 108-62-3)

US. New Jersey Worker and Community Right-to-Know Act


US. Pennsylvania Worker and Community Right-to-Know Law


US. Rhode Island RTK

Not regulated.

US. California Proposition 65

California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to containany chemicals currently listed as carcinogens or reproductive toxins.


Country(s) or region Inventory name On inventory (yes/no)*

NoCanada Domestic Substances List (DSL)

NoCanada Non-Domestic Substances List (NDSL)

NoUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).

16. Other information, including date of preparation or last revision

Issue date 04-08-2015

References ACGIH®: American Conference of Governmental Industrial Hygienists CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act

EPA: Environmental Protection Agency FIFRA: Federal Insecticide, Fungicide, and Rodenticide Act

IARC: International Agency for Research on Cancer NTP: National Toxicology Program

OSHA: Occupational Safety and Health Agency SARA: Superfund Amendments and Reauthorization Act TSCA: Toxic Substances Control Act

DOT: Department of Transportation IMDG: International Maritime Dangerous Goods

IATA: International Air Transport Association

Version # 01

Further information Not available.

HMIS® ratings Health: 2*Flammability: 0Physical hazard: 0

NFPA ratings Health: 2Flammability: 0Instability: 0

7 / 8



SDS US

Disclaimer AMVAC Chemical Corporation cannot anticipate all conditions under which this information and itsproduct, or the products of other manufacturers in combination with its product, may be used. It isthe user’s responsibility to ensure safe conditions for handling, storage and disposal of theproduct, and to assume liability for loss, injury, damage or expense due to improper use. Thisinformation is provided for the limited guidance to the user. While AMVAC believes that theinformation is, as of the date hereof, reliable, it is the user’s responsibility to determine thesuitability of the information for its purposes. The user is advised not to construe the informationas absolutely complete since additional information may be necessary or desirable whenparticular, exceptional, or variable conditions or circumstances exist (like combinations with othermaterials), or because of applicable regulations. No express or implied warranty of merchantabilityor fitness for a particular purpose or otherwise is made hereunder with respect to the informationor the product to which the information relates.

©2015 AMVAC Chemical Corporation. All Rights Reserved. AMVAC, Deadline, Deadline Bullets,Deadline M-Ps, and the Beaker Logo are trademarks owned by AMVAC Chemical Corporation.Chemtrec is a trademark of the American Chemistry Council, Inc. HMIS is a trademark of theAmerican Coatings Association. NFPA is a trademark of the National Fire Protection Association,Inc. ACGIH is a trademark of the American Conference of Governmental Industrial Hygienists.

Revision Information Product and Company Identification: SynonymsComposition / Information on Ingredients: IngredientsPhysical & Chemical Properties: Multiple PropertiesToxicological Information: Toxicological Property DataTransport Information: Proper Shipping Name/Packing GroupRegulatory Information: United StatesHazReg Data: North AmericaGHS: Classification

8 / 8



SDS US

Bayer Environmental ScienceSAFETY DATA SHEET

DELTADUST® INSECTICIDE 1/11 Version 4.0 / USA Revision Date: 10/06/2015 102000004846 Print Date: 10/07/2015

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifier

Trade name DELTADUST® INSECTICIDE

Product code (UVP) 05952247

SDS Number 102000004846

EPA Registration No. 432-772

Relevant identified uses of the substance or mixture and uses advised against

Use Insecticide

Restrictions on use See product label for restrictions.

Information on supplier

Supplier Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC 27709 United States

Responsible Department Email: [email protected]

Emergency telephone no.

Emergency Telephone Number (24hr/ 7 days)

1-800-334-7577

Product Information Telephone Number

1-800-331-2867

SECTION 2: HAZARDS IDENTIFICATION

Classification in accordance with regulation HCS 29CFR §1910.1200 This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Other hazards No other hazards known.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Component Name CAS-No. Concentration % by weight Deltamethrin 52918-63-5 0.05 Crystalline quartz (respirable) 14808-60-7 2.50 Calcium carbonate 1317-65-3 95.4

Return to Index

Bayer Environmental Science

SAFETY DATA SHEET


SECTION 4: FIRST AID MEASURES

Description of first aid measures

General advice When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment.

Inhalation Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately.

Skin contact Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately.

Eye contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately.

Ingestion Call a physician or poison control center immediately. Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Do not leave victim unattended.

Most important symptoms and effects, both acute and delayed

Symptoms To date no symptoms are known.

Indication of any immediate medical attention and special treatment needed

Treatment Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. There is no specific antidote.

SECTION 5: FIREFIGHTING MEASURES

Extinguishing media

Suitable Carbon dioxide (CO2), Dry chemical, Foam, Water

Unsuitable None known.

Advice for firefighters


Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing.

Further information Keep out of smoke. Fight fire from upwind position. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses. Contain the spread of the fire-fighting media.

Flash point not applicable

Autoignition temperature no data available


SAFETY DATA SHEET


Lower explosion limit not applicable

Upper explosion limit not applicable

Explosivity

no data available

Dust explosion class no data available

SECTION 6: ACCIDENTAL RELEASE MEASURES


Precautions Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled product or contaminated surfaces.

Methods and materials for containment and cleaning up

Methods for cleaning up Avoid dust formation. Sweep up or vacuum up spillage and collect in suitable container for disposal. Clean contaminated floors and objects thoroughly, observing environmental regulations.

Additional advice Use personal protective equipment. Do not allow to enter soil, waterways or waste water canal.

Reference to other sections Information regarding safe handling, see section 7. Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE


Advice on safe handling Handle and open container in a manner as to prevent spillage. Maintain exposure levels below the exposure limit through the use of general and local exhaust ventilation.

Hygiene measures Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics.

Remove Personal Protective Equipment (PPE) immediately after handling this product. Before removing gloves clean them with soap and water. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing.



Store in a cool, dry place and in such a manner as to prevent cross contamination with other crop protection products, fertilizers, food, and feed. Store in original container and out of the reach of children, preferably in a locked storage area.


SAFETY DATA SHEET


SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components CAS-No. Control parameters Update Basis Deltamethrin 52918-63-5 0.02 mg/m3

(TWA)

OES BCS*

Crystalline quartz (respirable) (Respirable fraction.)

14808-60-7 0.025 mg/m3 (TWA)

02 2012

ACGIH

Crystalline quartz (respirable) (Respirable dust.)

14808-60-7 0.05 mg/m3 (REL)

2010

NIOSH


14808-60-7 0.1 mg/m3 (TWA)

1989

OSHA Z1A


14808-60-7 0.1 mg/m3 (TWA)

06 2008

TN OEL

Crystalline quartz (respirable)

14808-60-7 0.27ug/m3 (AN ESL)

03 2014

TX ESL

Crystalline quartz (respirable)

14808-60-7 14ug/m3 (ST ESL)

03 2014

TX ESL


14808-60-7 0.1 mg/m3 (TWA PEL)

08 2010

US CA OEL

Crystalline quartz (respirable) (Total dust.)

14808-60-7 0.3 mg/m3 (TWA PEL)

08 2010

US CA OEL

Crystalline quartz (respirable) (Respirable.)

14808-60-7 0.1 mg/m3 (TWA)

2000

Z3

Crystalline quartz (respirable) (Total dust.)

14808-60-7 0.3 mg/m3 (TWA)

2000

Z3

Crystalline quartz (respirable) (Respirable.)

14808-60-7 2.4millions of particles per cubic foot of air

(TWA)

2000

Z3

Calcium carbonate (Respirable.)

1317-65-3 5 mg/m3 (REL)

2010

NIOSH

Calcium carbonate (Total)

1317-65-3 10 mg/m3 (REL)

2010

NIOSH

Calcium carbonate (Respirable fraction.)

1317-65-3 5 mg/m3 (PEL)

02 2006

OSHA Z1

Calcium carbonate (Total dust.)

1317-65-3 15 mg/m3 (PEL)

02 2006

OSHA Z1

Calcium carbonate 1317-65-3 5 mg/m3 1989 OSHA Z1A


SAFETY DATA SHEET


(Respirable fraction.) (TWA) Calcium carbonate (Total dust.)

1317-65-3 15 mg/m3 (TWA)

1989

OSHA Z1A

Calcium carbonate (Total dust.)

1317-65-3 15 mg/m3 (TWA)

06 2008

TN OEL

Calcium carbonate (Respirable fraction.)

1317-65-3 5 mg/m3 (TWA)

06 2008

TN OEL

Calcium carbonate 1317-65-3 5ug/m3 (AN ESL)

03 2014

TX ESL

Calcium carbonate 1317-65-3 50ug/m3 (ST ESL)

03 2014

TX ESL

*OES BCS: Internal Bayer CropScience "Occupational Exposure Standard"

Exposure controls

Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply.

Respiratory protection When respirators are required, select NIOSH approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industry recommendations.

Hand protection Chemical resistant nitrile rubber gloves

Eye protection Safety glasses or Goggles

Skin and body protection Wear long-sleeved shirt and long pants and shoes plus socks.

General protective measures Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and warm/tepid water. Keep and wash PPE separately from other laundry.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance white

Physical State powder

Odor weak characteristic

Odour Threshold no data available

pH no data available

Vapor Pressure no data available

Vapor Density (Air = 1) no data available

Bulk density ca. 55.5 lb/ft³(loose)


SAFETY DATA SHEET


Evapouration rate not applicable

Boiling Point not applicable Melting / Freezing Point not applicable

Water solubility soluble

Minimum Ignition Energy no data available

Decomposition temperature

no data available

Partition coefficient: n-octanol/water

no data available

Viscosity not applicable





Explosivity no data available

Dust explosion class no data available

SECTION 10: STABILITY AND REACTIVITY

Reactivity

Thermal decomposition no data available

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous reactions

No hazardous reactions known.

Conditions to avoid no data available

Incompatible materials Strong acids

Hazardous decomposition products

no data available

SECTION 11: TOXICOLOGICAL INFORMATION Exposure routes Skin contact, Eye contact

Immediate Effects


SAFETY DATA SHEET


Skin May be harmful if absorbed through skin.


Acute oral toxicity LD50 (rat) > 5,050 mg/kg

Acute inhalation toxicity LC50 (rat) > 26.1 mg/l Exposure time: 4 h Determined in the form of dust.

LC50 (rat) > 100 mg/l Exposure time: 1 h Determined in the form of dust. Extrapolated from the 4 hr LC50.

Acute dermal toxicity LD50 (rabbit) > 2,020 mg/kg

Skin irritation No skin irritation (rabbit)

Eye irritation No eye irritation (rabbit)

Sensitisation Non-sensitizing. (guinea pig)

Assessment repeated dose toxicity

Deltamethrin caused neurobehavioral effects and/or neuropathological changes in animal studies. The toxic effects of Deltamethrin are related to transient hyperactivity typical for pyrethroid neurotoxicity.

Assessment mutagenicity

Deltamethrin was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.

Assessment carcinogenicity

Deltamethrin was not carcinogenic in lifetime feeding studies in rats and mice.

ACGIH

Crystalline quartz (respirable) 14808-60-7 Group A2

NTP

Crystalline quartz (respirable) 14808-60-7

IARC

Deltamethrin 52918-63-5 Overall evaluation: 3 Crystalline quartz (respirable) 14808-60-7 Overall evaluation: 1

OSHA

None.

Assessment toxicity to reproduction

Deltamethrin did not cause reproductive toxicity in a two-generation study in rats.

Assessment developmental toxicity

Deltamethrin caused developmental toxicity only at dose levels toxic to the dams. The developmental effects seen with Deltamethrin are related to maternal toxicity.


SAFETY DATA SHEET


Further information

Only acute toxicity studies have been performed on the formulated product. The non-acute information pertains to the active ingredient(s).

SECTION 12: ECOLOGICAL INFORMATION

Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)) 0.00091 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient deltamethrin.

Toxicity to aquatic invertebrates

EC50 (Daphnia magna (Water flea)) 0.00056 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient deltamethrin.

Toxicity to aquatic plants EC50 (Algae) > 9.1 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient deltamethrin.

Biodegradability Deltamethrin: not rapidly biodegradable

Koc Deltamethrin: Koc: 10240000

Bioaccumulation Deltamethrin: Bioconcentration factor (BCF) 1,400 Does not bioaccumulate.

Mobility in soil Deltamethrin: Immobile in soil

Environmental precautions Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Apply this product as specified on the label.

SECTION 13: DISPOSAL CONSIDERATIONS


Product Pesticide, spray mixture or rinse water that cannot be used according to label instructions may be disposed of on site or at an approved waste disposal facility.

Follow advice on product label and/or leaflet.

Contaminated packaging Triple rinse containers. Dispose of empty container in a sanitary landfill or by incineration, or, if

allowed by State/Provincial and local authorities, by burning. If burned, stay out of smoke. Follow advice on product label and/or leaflet.


SAFETY DATA SHEET


RCRA Information Characterization and proper disposal of this material as a special or

hazardous waste is dependent upon Federal, State and local laws and are the user's responsibility. RCRA classification may apply.

SECTION 14: TRANSPORT INFORMATION 49CFR Not dangerous goods / not hazardous material IMDG UN number 3077 Class 9 Packaging group III Marine pollutant YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,

N.O.S. (DELTAMETHRIN MIXTURE) IATA UN number 3077 Class 9 Packaging group III Environm. Hazardous Mark YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,

N.O.S. (DELTAMETHRIN MIXTURE ) This transportation information is not intended to convey all specific regulatory information relating to this product. It does not address regulatory variations due to package size or special transportation requirements. Freight Classification: INSECTICIDES OR FUNGICIDES, N.O.I., OTHER THAN

POISON

SECTION 15: REGULATORY INFORMATION

EPA Registration No. 432-772 US Federal RegulationsTSCA list Crystalline quartz (respirable) 14808-60-7 Calcium carbonate 1317-65-3 US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section 302 - Notification and Information None. SARA Title III - Section 313 - Toxic Chemical Release Reporting None.


SAFETY DATA SHEET


US States Regulatory ReportingCA Prop65 This product contains a chemical known to the State of California to cause cancer.Crystalline quartz (respirable) 14808-60-7 This product does not contain any substances known to the State of California to cause reproductive harm. US State Right-To-Know Ingredients Crystalline quartz (respirable) 14808-60-7 MN Calcium carbonate 1317-65-3 MN Canadian Regulations Canadian Domestic Substance List None. Environmental CERCLA None. Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None. EPA/FIFRA Information: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information required on the pesticide label: Signal word: Caution!

Hazard statements: May be harmful if absorbed through skin.

Avoid contact with skin, eyes and clothing. Wash thoroughly with soap and water after handling.

SECTION 16: OTHER INFORMATION

Abbreviations and acronyms 49CFR Code of Federal Regulations, Title 49 ACGIH US. ACGIH Threshold Limit Values CAS-Nr. Chemical Abstracts Service number EINECS European inventory of existing commercial substances ELINCS European list of notified chemical substances IARC US. IARC Monographs on Occupational Exposures to Chemical Agents IATA International Air Transport Association IMDG International Maritime Dangerous Goods


SAFETY DATA SHEET


N.O.S. Not otherwise specified NTP US. National Toxicology Program (NTP) Report on Carcinogens OECD Organization for Economic Co-operation and Development TDG Transportation of Dangerous Goods TWA Time weighted average UN United Nations WHO World health organisation

NFPA 704 (National Fire Protection Association): Health - 1 Flammability - 0 Instability - 0 Others - none

HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 0 Flammability - 0 Physical Hazard - 0 PPE -

0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Reason for Revision: The following sections have been revised: Section 15: Regulatory information. Revision Date: 10/06/2015 This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer.

Safety Data Sheet

1/28/2015

6/12/2015

Replaces:

Date:

DEMAND® CS Insecticide

1. PRODUCT IDENTIFICATION

A12690A

Use: Insecticide

Product identifier on label: DEMAND® CS Insecticide

Manufacturer: Syngenta Crop Protection, LLC

Post Office Box 18300

Greensboro NC 27419

Manufacturer Phone: 1-800-334-9481

Emergency Phone: 1-800-888-8372

Product No.:


Warning

Classifications:

Signal Word (OSHA):

May cause an allergic skin reactionHazard Statements:

Harmful if inhaled

May cause respiratory irritation

May cause drowsiness or dizziness

May cause damage to organs

Inhalation: Category 4

Skin Sensitizer: Category 1B

Specific Target Organ Toxicity: Repeated Category 2

Specific Target Organ Toxicity: Drowsiness Category 3

Specific Target Organ Toxicity: Respiratory Irritation Category 3

Precautionary Statements: Do not breathe mist, vapors, spray.

Use only outdoors or in a well-ventilated area.

Contaminated work clothing must not be allowed out of the workplace.

Wear protective gloves, protective clothing, eye protection.

If on skin: Wash with plenty of soap and water.

If skin irritation or rash occurs: Get medical advice.

If inhaled: Remove person to fresh air and keep comfortable for breathing.

Call a poison center, doctor or Syngenta if you feel unwell.

See Section 4 First Aid Measures.

Wash contaminated clothing before reuse.

Hazard Symbols:

Page 1 of 9

Return to Index

Safety Data Sheet

1/28/2015

6/12/2015

Replaces:

Date:


Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications.


Chemical Name ConcentrationCommon Name CAS Number

Xylene Xylene 1330-20-7 <1%

1,2,4-Trimethylbenzene 1,2,4-Trimethylbenzene 95-63-6 <2.5%

Cumene Cumene 98-82-8 <1%

1,2-Propanediol Propylene Glycol 57-55-6 Trade Secret

Petroleum Solvent Petroleum Solvent 64742-95-6 Trade Secret

Other ingredients Other ingredients Trade Secret >85.8%

[1a(S*),3a(Z)]-cyano(3-phenoxyphenyl)methyl-3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethylcyclopropanecarboxylate

Lambda-Cyhalothrin 91465-08-6 9.7%


Have the product container, label or Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for treatment.

If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment advice. Do not give any liquid to the person. Do not induce vomiting unless told to do so after calling 800-888-8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person.

If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice.

If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice.

If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call Syngenta (800-888-8372), a poison control center or doctor for further treatment advice.

Ingestion:

Eye Contact:

Skin Contact:

Inhalation:

Indication of immediate medical attention and special treatment needed:

Most important symptoms/effects:

There is no specific antidote if this product is ingested.

Treat symptomatically.

Persons suffering a temporary allergic reaction may respond to treatment with antihistamines or steroid creams and/or systemic steroids.

Allergic skin reaction

Drowsiness or dizziness

Respiratory irritation

May cause temporary itching, tingling, burning or numbness of exposed skin, called paresthesia.

Other Hazard Statements:

Store locked up.

Dispose of contents and container in accordance with local regulations.

Page 2 of 9

Safety Data Sheet

1/28/2015

6/12/2015

Replaces:

Date:


Skin contact paresthesia effects (itching, tingling, burning or numbness) are transient, lasting up to 24 hours. Treat symptomatically.Contains petroleum distillate - vomiting may cause aspiration pneumonia.

5. FIRE FIGHTING MEASURES

Suitable (and unsuitable) extinguishing media:

Specific Hazards:

Special protective equipment and precautions for firefighters:

Use dry chemical, foam or CO2 extinguishing media. If water is used to fight fire, dike and collect runoff.

During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.

Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion.


Personal precautions, protective equipment, and emergency procedures:

Methods and materials for containment and cleaning up:

Follow exposure controls/personal protection outlined in Section 8.

Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions in Protective Equipment Section. Cover entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent (e.g. commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition.


Precautions for safe handling:

Conditions for safe storage, including any incompatibilities:

Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling.

Store locked up.


THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION AND PACKAGING OF THIS PRODUCT.

FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL.

Occupational Exposure Limits:

Chemical Name OtherOSHA PEL ACGIH TLV Source

Xylene 100 ppm TWA 100 ppm TWA; 150 ppm STEL

100 ppm TWA NIOSH

1,2,4-Trimethylbenzene Not Established 25 ppm TWA 25 ppm TWA NIOSH

Cumene 50 ppm TWA (skin) 50 ppm TWA Not Established Not Applicable

Page 3 of 9

Safety Data Sheet

1/28/2015

6/12/2015

Replaces:

Date:


Ingestion:

Eye Contact:

Skin Contact:

Inhalation:

Appropriate engineering controls:Use effective engineering controls to comply with occupational exposure limits (if applicable).

Individual protection measures:

Propylene Glycol Not Established Not Established 10 mg/m³ TWA AIHA

Petroleum Solvent Not Established Not Established 100 mg/m³ (19 ppm) TWA

Manufacturer

Other ingredients Not Applicable Not Applicable Not Applicable Not Applicable

Lambda-Cyhalothrin Not Established Not Established 0.04 mg/m³ TWA (skin)

Syngenta

Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling.

Where eye contact is likely, use chemical splash goggles.

Where contact is likely, wear chemical-resistant gloves (such as barrier laminate, butyl rubber, nitrile rubber or Viton), coveralls, socks and chemical-resistant footwear. Stringent housekeeping measures are necessary to prevent translocation of the material from contaminated work surfaces to uncontaminated surfaces (railings, doors, etc.). Unprotected contact with such translocated material can result in paresthesia effects (see Section 11).

A combination particulate/organic vapor respirator should be used until effective engineering controls are installed to comply with occupational exposure limits, or until exposure limits are established. Use a NIOSH approved respirator with an organic vapor (OV) cartridge or canister with any R, P or HE filter.

Use a self-contained breathing apparatus in cases of emergency spills, when exposure levels are unknown, or under any circumstances where air-purifying respirators may not provide adequate protection.

Slight odor/typical aromatic solvent

Off-white liquid


Vapor Pressure:

Solubility (ies):

pH: 7.3 (1% w/w dilution in deionized water)

Odor:

Appearance:

212 °F

Not Applicable

Initial boiling point and boiling range:

Melting point/freezing point:

Odor Threshold: Not Available

Not Available

Flammability: Not Applicable

> 212°F (Setaflash)Flash Point (Test Method):

Flammable Limits (% in Air):

Vapor Density:

Relative Density:

Not AvailablePartition coefficient: n-octanol/water:

1.036 @ 68°F (20°C)

Not Available

Lambda-Cyhalothrin 1.5 x 10(-9) mmHg @ 68°F (20°C)

Lambda-Cyhalothrin 0.004 mg/l

Page 4 of 9

Safety Data Sheet

1/28/2015

6/12/2015

Replaces:

Date:


Not AvailableAutoignition Temperature:

Not AvailableDecomposition Temperature:

Not AvailableViscosity:

NoneOther:

Incompatible materials:

Possibility of hazardous reactions: Will not occur.

Chemical stability: Stable under normal use and storage conditions.


None known.Hazardous Decomposition Products:

Reactivity: Not reactive.

Conditions to Avoid: None known.

None known.


Numerical measures of toxicity (acute toxicity/irritation studies (finished product))

Chronic/Subchronic Toxicity Studies

Carcinogenicity

Ingestion:

Dermal:

Inhalation:

Eye Contact:

Skin Contact:

Skin Sensitization:

Oral (LD50 Rat) :

Non-Irritating (Rabbit)

Practically Non-Irritating (Rabbit)

A weak skin sensitizer in animal tests.

Dermal (LD50 Rat) :

Inhalation (LC50 Rat) :

> 5000 mg/kg body weight

> 2000 mg/kg body weight

> 4.62 mg/l

Reproductive/Developmental Effects

Likely routes of exposure:

Health effects information

Symptoms of exposure:

Delayed, immediate and chronic effects of exposure:

Lambda-Cyhalothrin : Reversible paresthesia (abnormal skin sensation).Reversible clinical signs of neurotoxicity in mammals.

Lambda-Cyhalothrin : Not a developmental or reproductive toxicant.

Dermal, Inhalation

Drowsiness or dizziness, Respiratory irritation

Allergic skin reaction, Drowsiness or dizziness, Respiratory system effects, Paresthesia

Page 5 of 9

Safety Data Sheet

1/28/2015

6/12/2015

Replaces:

Date:


Carcinogenicity

Toxicity of Other Components

Target Organs

Other Toxicity InformationIn humans, contact with exposed skin may result in temporary itching, tingling, burning or numbness, called paresthesia. The effect may result from splash, aerosol, or hot vapor contact, or transfer to the face from contaminated gloves and hands. The symptoms normally disappear within 24 hours. Face and genital areas are especially susceptible to this effect. Paresthesia involving the face is also known as "subjective facial sensation" or SFS.

Active Ingredients

Inert Ingredients

Lambda-Cyhalothrin : No treatment-related tumors in rats or mice.

Inhalation of 1,2,4-trimethylbenzene at high concentrations can cause central nervous system depression, respiratory tract irritation, asphyxiation, cardiac stress and coma. Effects of chronic exposure to this solvent can include blood disorders (anemia, leukopenia) and kidney or liver damage.

1,2,4-Trimethylbenzene

Exposure to cumene vapors may cause irritation to eyes, skin, and respiratory tract. Cumene may also cause headaches, dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects. Prolonged exposure to high concentrations (>100 PPM) may result in liver, kidney or lung damage.

Cumene

Not ApplicableOther ingredients

The supplier reports that high vapor/aerosol concentrations (> 1000 ppm) are irritating to the eyes and the respiratory tract, may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects.

Petroleum Solvent

Reported to cause central nervous system depression (anesthesia, dizziness, confusion), headache and nausea. Also, eye irritation may occur with lacrimation but no residual discomfort or injury. Prolonged contact to skin may cause mild to moderate irritation and possible allergic reactions. Chronic dietary exposure caused kidney and liver injury in experimental animals.

Propylene Glycol

Inhalation of xylene at high concentrations can cause central nervous system depression, respiratory tract irritation, asphyxiation, cardiac stress and coma.

Xylene

Lambda-Cyhalothrin : Liver, nervous system

1,2,4-Trimethylbenzene: CNS, liver, kidney, blood, respiratory tract, skin, eye

Cumene: Skin, eye, liver, respiratory tract, kidney, CNS

Other ingredients: Not Applicable

Petroleum Solvent: Eye, respiratory tract, CNS

Chemical Name NTP/IARC/OSHA Carcinogen

Xylene IARC Group 3

1,2,4-Trimethylbenzene No

Cumene No

1,2-Propanediol No

Petroleum Solvent No

Other ingredients No

[1a(S*),3a(Z)]-cyano(3-phenoxyphenyl)methyl-3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethylcyclopropanecarboxylate

No

Page 6 of 9

Safety Data Sheet

1/28/2015

6/12/2015

Replaces:

Date:


Propylene Glycol: CNS, kidney, liver

Xylene: CNS, respiratory tract, skin


Environmental Fate

Eco-Acute Toxicity

The information presented here is for the active ingredient, lambda-cyhalothrin. Not persistent in soil or water. Immobile in soil. Sinks in water (after 24 h).

Lambda-Cyhalothrin :

Lambda-Cyhalothrin :Fish (Rainbow Trout) 96-hour LC50 0.19 ppb

Bird (Mallard Duck) LD50 Oral > 3950 mg/kg

Invertebrate (Water Flea) 48-hour EC50 0.04 ppb


Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, state, and federal health and environmental regulations.

Characteristic Waste: Not Applicable

Listed Waste: Not Applicable

Disposal:


DOT Classification

Ground Transport - NAFTAContainers < 450 liters: Not regulatedContainers > 450 liters:Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Lambda-Cyhalothrin)Hazard Class or Division: Class 9Identification Number: UN 3082Packing Group: PG III

CommentsWater Transport - InternationalProper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Lambda-Cyhalothrin), Marine PollutantHazard Class or Division: Class 9Identification Number: UN 3082Packing Group: PG III

Air TransportProper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Lambda-Cyhalothrin)Hazard Class or Division: Class 9Identification Number: UN 3082Packing Group: PG III

Page 7 of 9

Safety Data Sheet

1/28/2015

6/12/2015

Replaces:

Date:



RCRA Hazardous Waste Classification (40 CFR 261):

Not Applicable

TSCA Status:

Exempt from TSCA, subject to FIFRA

EPCRA SARA Title III Classification:

Section 311/312 Hazard Classes:

Section 313 Toxic Chemicals:

CERCLA/SARA 304 Reportable Quantity (RQ):

Report product spills > 520 gal. (based on xylene [RQ = 100 lbs.] content in the formulation)

Pesticide Registration:

This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:

EPA Registration Number(s):

100-1066

Acute Health Hazard

Chronic Health Hazard

Xylene <1% (CAS No. 1330-20-7)

1,2,4-Trimethylbenzene <2.5% (CAS No. 95-63-6)

Cumene <1% (CAS No. 98-82-8)

Caution: Harmful if absorbed through skin. Avoid breathing spray mist or vapor. Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after handling, and before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove contaminated clothing and wash before reuse. Prolonged or frequently repeated skin contact may cause allergic skin reactions in some individuals.

1

00

1

2


NFPA Hazard Ratings

7/14/1999

1/28/20156/12/2015

Health:

Flammability:

Instability:

Replaces:

Original Issued Date:

Revision Date:

The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein.

HMIS Hazard Ratings

Health:

Flammability:

Reactivity:

0 Minimal1 Slight2 Moderate3 Serious4 Extreme

C,SSyngenta Hazard Category:

2, 4, 11Section(s) Revised:

* Chronic

2

For non-emergency questions about this product call:

1-800-334-9481

Page 8 of 9

Safety Data Sheet

1/28/2015

6/12/2015

Replaces:

Date:


Page 9 of 9

United States (US)According to: OSHA 29 CFR 1910.1200 HCS

Safety Data Sheet

Section 1: Identification

Product identifierProduct Name • EcoPCO ACU InsecticideSynonyms • EPA Reg. No.: 8945959Product Description • Colorless aerosol spray.

Relevant identified uses of the substance or mixture and uses advised againstRecommended use • Insecticide.Restrictions on use • KEEP OUT OF THE REACH OF CHILDREN. Keep away from heat, sparks and

flames. Do not take internally. Avoid contact with eyes and skin. Avoid inhalation of vapors or fumes.

Details of the supplier of the safety data sheetManufacturer • Central Garden & Pet Company

1501 E. Woodfield Road, Suite 200W Schaumburg, IL 60173 United States www.zoecon.com

Emergency telephone numberManufacturer • 17035273887 CHEMTREC Outside North America Collect Calls AcceptedManufacturer • 18004249300 CHEMTRECManufacturer • 18002487763

Section 2: Hazard Identification

Classification of the substance or mixtureOSHA HCS 2012 • Aspiration 1

Flammable Aerosols 2 Skin Irritation 2 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects Eye Irritation 2A

Label elementsOSHA HCS 2012

DANGER

EcoPCO ACU InsecticideEcoPCO ACU InsecticideEcoPCO ACU InsecticideEcoPCO ACU Insecticide

Preparation Date: 10/July/2015Preparation Date: 10/July/2015Preparation Date: 10/July/2015Preparation Date: 10/July/2015Revision Date: 10/July/2015Revision Date: 10/July/2015Revision Date: 10/July/2015Revision Date: 10/July/2015

Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012

Page 1 of 9Page 1 of 9Page 1 of 9Page 1 of 9

Return to Index...

Hazard statements • Flammable aerosol May be fatal if swallowed and enters airways Causes skin irritation May cause drowsiness or dizziness Causes serious eye irritation

Precautionary statementsPrevention • Avoid breathing dust, fume, gas, mist, vapours and/or spray.

Keep away from heat, sparks, open flames and/or hot surfaces. No smoking. Pressurized container: Do not pierce or burn, even after use. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Use only outdoors or in a wellventilated area. Do not spray on an open flame or other ignition source.

Response • IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment, see supplemental first aid information in Section 4 First Aid Measures. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Storage/Disposal • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50ºC/122ºF. Store in a wellventilated place. Keep container tightly closed.

Other hazardsOSHA HCS 2012 • Under United States Regulations (29 CFR 1910.1200 Hazard Communication

Standard), this product is considered hazardous.

Section 3 Composition/Information on Ingredients

Substances

• Material does not meet the criteria of a substance.

Mixtures

CompositionChemical Name Identifiers %2Phenethyl Propionate CAS:122703 0.1% Benzyl alcohol CAS:100516 4% Distillates (petroleum), hydrotreated light CAS:64742478 75.9% Propane CAS:74986 14% Other ingredients NDA 6%





Section 4: FirstAid Measures

Description of first aid measuresInhalation • IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for

breathing. Call a poison control center or doctor if you feel unwell. Skin • IF ON SKIN: Wash skin with soap and water. If skin irritation occurs: Get medical

advice/attention. Eye • IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,

if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Ingestion • IF SWALLOWED: Immediately call a poison control center or doctor. Do NOT induce vomiting.

Most important symptoms and effects, both acute and delayed• Aspiration hazard, may cause dizziness or drowsiness if vapor is inhaled, causes skin irritation, causes serious eye irritation. Refer to Section 11 Toxicological Information.

Indication of any immediate medical attention and special treatment neededNotes to Physician • Treat symptomatically and supportively. May present an aspiration hazard.

Section 5: FireFighting Measures

Extinguishing mediaSuitable Extinguishing Media • Use CO2, dry chemical, or foam. Unsuitable Extinguishing Media

• Water is unsuitable for use on burning material but may be used to cool containers exposed to heat.

Firefighting Procedures • Do not allow fire fighting water to escape into waterways or sewers. Flammable aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards. Move containers from fire area if you can do it without risk. Ventilate closed spaces before entering. Do not breathe gas/fumes/vapor/spray.

Special hazards arising from the substance or mixtureUnusual Fire and Explosion Hazards

• Containers may explode when heated. Flammable aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards. Flammable; may be ignited by heat, sparks or flames. At temperatures above 130°F, container may rupture.

Hazardous Combustion Products

• Carbon monoxide and carbon dioxide.

Advice for firefighters• Wear positive pressure selfcontained breathing apparatus (SCBA).

Section 6 Accidental Release Measures

Personal precautions, protective equipment and emergency proceduresPersonal Precautions • Approach leaking or punctured pressurized containers cautiously. Isolate leaking

container from all sources of ignition. Ventilate the area before entry. Avoid breathing fumes.

Emergency Procedures • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Ventilate closed spaces before entering. Avoid unnecessary personnel and equipment traffic in the spill area.

Environmental precautions





• Avoid run off to waterways and sewers.

Methods and material for containment and cleaning upContainment/Cleanup Measures

• SMALL SPILLS: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Do not flush to sewer or allow to enter waterways.

Section 7 Handling and Storage

Precautions for safe handlingHandling • Keep away from fire No Smoking. Contents under pressure, do not crush, puncture

or incinerate. Exposure to temperatures above 130ºF may cause bursting. Avoid contact with skin, eyes, and clothing. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco.

Conditions for safe storage, including any incompatibilitiesStorage • Keep away from fire, sparks and heated surfaces. Store in cool, dry area, inaccessible

to children. Store locked up. Keep container tightly closed and do not store above 130°F(55°C). Ventilate enclosed areas. NFPA Aerosol Classification: Level 1.

Incompatible Materials or Ignition Sources

• Oxidizing agents. Heat, sparks, open flame.

Section 8 Exposure Controls/Personal Protection

Control parametersExposure Limits/Guidelines • No data available.

Exposure Limits/GuidelinesResult ACGIH NIOSH OSHA

Propane (74986) TWAs

1000 ppm TWA (listed under Aliphatic hydrocarbon gases: Alkane C14)

1000 ppm TWA; 1800 mg/m3 TWA 1000 ppm TWA; 1800 mg/m3 TWA

Exposure Limits Supplemental

ACGIH •Propane (74986): TLV Basis Critical Effects: (asphyxia (See Appendix F: Minimal Oxygen Content))

Exposure controlsEngineering Measures/Controls

• Use adequate ventilation to remove vapors (fumes, dust etc)

Personal Protective EquipmentPictograms •

Respiratory • Follow the OSHA respirator regulations found in 29 CFR 1910.134. Use a NIOSH/MSHA approved respirator if exposure limits are exceeded or symptoms are experienced.

Eye/Face • Wear safety goggles.Hands • Impervious gloves.Skin/Body • If prolonged exposure is anticipated, it is recommended for handlers to wear

appropriate clothing to prevent skin contact. Environmental Exposure Controls

• Refer to Section 13 Disposal Considerations.





Section 9 Physical and Chemical Properties

Information on Physical and Chemical PropertiesMaterial Description Physical Form Aerosol Appearance/Description Colorless aerosol spray.

Color Colorless liquid in container / colorless aerosol when discharged.

Odor Very faint, almost odorless.

Aerosol Type Spray Odor Threshold No data availableGeneral Properties

Boiling Point No data available Melting Point/Freezing Point 17ºF (8ºC)

Decomposition Temperature No data available pH No data available

Specific Gravity/Relative Density 0.76 0.8 Bulk Density No data available

Water Solubility No data available Viscosity No data availableExplosive Properties No data available Volatility Vapor Pressure No data available Vapor Density 5.26 Air=1

Evaporation Rate Less than nbutyl acetate

Flammability Flash Point No data available UEL No data availableLEL No data available Autoignition No data available

Heat of Combustion (ΔHc) 11.3 kJ/g Flame Extension

>43 cm (>17 in)Flammability (solid, gas) Flammable aerosol. Environmental Octanol/Water Partition coefficient No data available

Section 10: Stability and Reactivity

Reactivity• Nonreactive

Chemical stability• Stable

Possibility of hazardous reactions• Flammable, aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards.

Conditions to avoid• Keep away from fire. Heat, sparks, open flame. Excessive heat. Strong oxidizers.

Incompatible materials• Store away from oxidizers.

Hazardous decomposition products• None. However, as with any organic material, combustion will product carbon dioxide and possibly carbon monoxide.





Section 11 Toxicological Information


GHS Properties Classification

Acute toxicityOSHA HCS 2012 • Acute Toxicity Dermal Classification criteria not met; Acute Toxicity Inhalation Classification criteria not met; Acute Toxicity Oral Classification criteria not met

Aspiration Hazard OSHA HCS 2012 • Aspiration 1

Carcinogenicity OSHA HCS 2012 • Classification criteria not met

Germ Cell Mutagenicity OSHA HCS 2012 • Classification criteria not met

Skin corrosion/Irritation OSHA HCS 2012 • Skin Irritation 2

Skin sensitization OSHA HCS 2012 • Classification criteria not met

STOTRE OSHA HCS 2012 • Classification criteria not met

STOTSE OSHA HCS 2012 • Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects

Toxicity for Reproduction OSHA HCS 2012 • Classification criteria not met

Respiratory sensitization OSHA HCS 2012 • Classification criteria not met

Serious eye damage/Irritation OSHA HCS 2012 • Eye Irritation 2A

Route(s) of entry/exposure • Inhalation, Skin, Eye, Ingestion.Potential Health EffectsInhalationAcute (Immediate) • May affect the central nervous system. Symptoms may include dizziness or

drowsiness.Chronic (Delayed) • No data available.

SkinAcute (Immediate) • Causes skin irritation.Chronic (Delayed) • No data available.

EyeAcute (Immediate) • Causes serious eye irritation.Chronic (Delayed) • No data available.

IngestionAcute (Immediate) • Aspiration Hazard may be fatal if swallowed and enters airways.Chronic (Delayed) • No data available.

OtherChronic (Delayed) • None known.

Mutagenic Effects • No data available.Carcinogenic Effects • No data available.

Reproductive Effects • No data available.

Section 12 Ecological Information

Toxicity





• No data available

Persistence and degradability• No data available.

Bioaccumulative potential• No data available.

Mobility in Soil• No data available.

Other adverse effects• No data available.

Ecological Fate • No data available.

Section 13 Disposal Considerations

Waste treatment methodsProduct waste • Do not puncture or incinerate. If partly filled: Call your local solid waste agency for

disposal instructions. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.

Packaging waste • If empty: Place in trash or offer for recycling if available. Do not puncture or incinerate. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.

Section 14 Transport Information

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Environmental hazards

DOT UN1950 Aerosols 2.1 Not Applicable Not Applicable

IMO/IMDG UN1950 Aerosols 2.1 Not Applicable Not Applicable

IATA/ICAO UN1950 Aerosols, flammable 2.1 Not Applicable Not Applicable

Special precautions for user • None specified.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code


Other information• No data available.

IMO/IMDG • No data availableIATA/ICAO • No data available

Key to abbreviations= N/A = Not applicable.

Section 15 Regulatory Information

Safety, health and environmental regulations/legislation specific for the substance or mixtureSARA Hazard Classifications • Acute





FIFRA – Pesticide LabelingThis chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of nonpesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. CAUTION

Hazard Statements • Keep out of reach of children. Precautionary Statements •

Hazards to Humans and Domestic Animals

• PRECAUTIONARY STATEMENTS Hazards to Humans & Domestic Animals CAUTION Causes moderate eye irritation. Avoid contact with eyes or clothing. Wear safety glasses, safety goggles, or face shield. Wash Thoroughly with soap and water after handling and before eating, drinking, chewing gum or using tobacco.

First Aid • IF IN EYES: Hold eye open and rinse slowly and gently with water for 1520 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Note to Physician: Contains petroleum distillate vomiting may cause aspiration pneumonia.

Environmental Hazards • For terrestrial uses: Do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwaters or rinsate.

Physical or Chemical Hazards

• Flammable. Contents under pressure. Keep away from fire, sparks, and heated surfaces. Do not puncture or incinerate container. Exposure to temperatures above 130°F may cause bursting.

InventoryComponent CAS TSCA

Benzyl alcohol 100516 Yes

Distillates (petroleum), hydrotreated light

64742478 Yes

Propane 74986 Yes

2Phenethyl Propionate 122703 Yes

United StatesEnvironment

U.S. RCRA (Resource Conservation & Recovery Act) List for Hazardous Constituents

• Propane 74986 Not Listed • 2Phenethyl Propionate 122703 Not Listed • Distillates (petroleum), hydrotreated light 64742478 Not Listed • Benzyl alcohol 100516

U.S. RCRA (Resource Conservation & Recovery Act) TSD Facilities Ground Water Monitoring

• Propane 74986 Not Listed • 2Phenethyl Propionate 122703 Not Listed • Distillates (petroleum), hydrotreated light 64742478 Not Listed • Benzyl alcohol 100516

Section 16 Other Information





Last Revision Date • 10/July/2015Preparation Date • 10/July/2015Disclaimer/Statement of Liability

• The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE.





SAFETY DATA SHEETEndZone Insecticide Sticker

SDS # : 7110-1-ARevision date: 2015-04-13

Format: NAVersion 1


Product Identifier

Product Name EndZone Insecticide Sticker


Product Code(s) 7110-1-A

Synonyms ACETAMIPRID:(E)-1-(6-chloro-3-pyridylmethyl)-N-nitroimidazolidin-2-ylideneamine;(2E)-1-[(6-chloro-3-pyridinyl)methyl]-N-nitro-2-imidazolidinimine

Active Ingredient(s) Acetamiprid

Chemical Family Neonicotinoid


Recommended Use: Pesticide





Classification



Acute toxicity - Oral Category 4


Page 1 / 7

Return to Index...

EndZone Insecticide StickerSDS # : 7110-1-A

Revision date: 2015-04-13Version 1

EMERGENCY OVERVIEW

Precautionary Statements - PreventionP264 - Wash face, hands and any exposed skin thoroughly after handlingP270 - Do not eat, drink or smoke when using this productP301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwellP330 - Rinse mouth



Other Information No information available


Chemical Family Neonicotinoid.

Chemical name CAS-No Weight %Acetamiprid 135410-20-7 4.4





Inhalation Not applicable.

Ingestion Call a poison control center or doctor immediately for treatment advice Have person sip aglass of water if able to swallow. Do not induce vomiting unless told to do so by a poisoncontrol center or doctor Never give anything by mouth to an unconscious person


None known.



Warning

Hazard StatementsH302 - Harmful if swallowed

Page 2 / 7




Suitable Extinguishing Media Carbon dioxide (CO2). Foam. Water spray. Dry powder.


Not flammable



Wear self-contained breathing apparatus and protective suit.


Personal Precautions Isolate and post spill area. Wear suitable protective clothing, gloves and eye/faceprotection. For personal protection see section 8.



Methods for Containment Sweep up and shovel into suitable containers for disposal.

Methods for cleaning up Clean and neutralize spill area, tools and equipment by washing with bleach water andsoap. Absorb rinsate and add to the collected waste. Waste must be classified and labeledprior to recycling or disposal. Dispose of waste as indicated in Section 13.


Handling Do not contaminate other pesticides, fertilizers, water, food, or feed by storage or disposal.


Incompatible products None known


Control parameters

This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the regionspecific regulatory bodies





Skin and Body Protection Wear suitable protective clothing. Protective shoes or boots.


Page 3 / 7





General information If the product is used in mixtures, it is recommended that you contact the appropriateprotective equipment suppliers



Appearance Clear, Rectangular stripPhysical State SolidColor ClearOdor NeutralOdor threshold No information availablepH 6.86Melting point/freezing point Not applicableBoiling Point/Range No information availableFlash point Not applicableEvaporation Rate No information availableFlammability (solid, gas) No information availableFlammability Limit in Air


Vapor pressure No information availableVapor density No information availableDensity No information availableSpecific gravity No information availableWater solubility No information availableSolubility in other solvents No information availablePartition coefficient No information availableAutoignition temperature No information availableDecomposition temperature No information availableViscosity, kinematic No information availableViscosity, dynamic No information availableExplosive properties No information availableOxidizing properties No information availableMolecular weight No information availableBulk density 1.271 lb/cu ft


Reactivity Not applicable




Conditions to avoid Excessive heat

Incompatible materials None known.

Hazardous Decomposition Products None known based on information supplied.


Page 4 / 7



Product Information

LD50 Oral Acetamiprid: 146 -217 mg/kg (rat)LD50 Dermal Acetamiprid: > 2000 mg/kg (rat)

Sensitization Non-sensitizer.


Symptoms None known.


Chronic toxicity Acetamiprid: Prolonged exposure in animal studies caused nonspecific toxicity observed asdecreases in body weight and food consumption.

Mutagenicity Acetamiprid. Not genotoxic in animal studiesCarcinogenicity Acetamiprid: No evidence of carcinogenicity from animal studies.Neurological effects Acetamiprid: Caused clinical signs of neurotoxicity (decreased locomotor activity, tremors)

in animal studies.Reproductive toxicity Acetamiprid: Reductions in pup weight, litter size, viability and weaning indices; delay in

sexual maturity endpoints.Developmental toxicity Acetamiprid: Not teratogenic in animal studies.STOT - single exposure Not classified.STOT - repeated exposure Not classified.Target organ effects Acetamiprid: No specific target organ toxicity; the liver effects were considered an adaptive

response to chemicals rather than frank toxicity.Neurological effects Acetamiprid: Caused clinical signs of neurotoxicity (decreased locomotor activity, tremors)

in animal studies.Aspiration hazard No information available.


Ecotoxicity

Acetamiprid (135410-20-7)Active Ingredient(s) Duration Species Value UnitsAcetamiprid 72 h EC50 Algae >98.3 mg/L

96 h LC50 Fish >100 mg/L48 h LC50 Crustacea 49.8 mg/L21 d NOEC Fish 19.2 mg/L21 d NOEC Crustacea 5 mg/L

Persistence and degradability Acetamiprid: Non-persistent. Does not readily hydrolyze. Not readily biodegradable.

Bioaccumulation Acetamiprid: The substance does not have a potential for bioconcentration.

Mobility Acetamiprid: Moderately mobile. Has some potential to reach groundwater.




Page 5 / 7




DOT This material is not a hazardous material as defined by U.S. Department of Transportationat 49 CFR Parts 100 through 185.

TDG Not regulatedICAO/IATA Not regulatedIMDG/IMO Not regulated


SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories Acute health hazard NoChronic health hazard NoFire hazard NoSudden release of pressure hazard NoReactive Hazard No

Clean Water ActThis product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42)

CERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this material

FIFRA InformationThis chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labelingrequirements under federal pesticide law. These requirements differ from the classification criteria and hazard informationrequired for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information asrequired on the pesticide label:

CAUTIONHarmful if swallowed or absorbed through the skin. Do not let children handle stickers. Do not handle stickers with wet hands.This product is toxic to wildlife. This product is very toxic to bees.




This product does not contain any substances regulated by state right-to-know regulations


Page 6 / 7




DSL(Canada)

EINECS/ELINCS

(Europe)

ENCS(Japan)

China(IECSC)

KECL(Korea)

PICCS(Philippines)

AICS(Australia)

Acetamiprid 135410-20-7 ( 4.4 )

X X

Mexico - Grade Slight risk, Grade 1

WHMIS Hazard Class Non-controlled









Page 7 / 7



Safety Data Sheet


Product identifierProduct Name l Essentria IC3 Insect ConcentrateSynonyms l 100208730; 674610Product Description l Clear, light brown liquid.

Relevant identified uses of the substance or mixture and uses advised againstRecommended use l Insecticide.Restrictions on use l KEEP OUT OF THE REACH OF CHILDREN. Avoid contact with eyes, skin and

clothing. Do not use or store near heat or open flame. Do not take internally. When used indoors, ensure adequate ventilation.

Details of the supplier of the safety data sheetManufacturer l Central Garden & Pet Company

1501 E. Woodfield Road, Suite 200W Schaumburg, IL 60173 United States

Emergency telephone numberManufacturer (Transportation) l 17035273887 CHEMTREC Outside North America Collect Calls AcceptedManufacturer (Transportation) l 18004249300 CHEMTRECManufacturer l 18002487763


Classification of the substance or mixtureOSHA HCS 2012 l Acute Toxicity Oral 4

Aspiration 1 Flammable Liquids 4 Reproductive Toxicity 1B Serious Eye Damage 1 Skin Irritation 2 Skin Sensitization 1 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects


DANGER

Essentria IC3 Insect ConcentrateEssentria IC3 Insect ConcentrateEssentria IC3 Insect ConcentrateEssentria IC3 Insect Concentrate

Preparation Date: 26/January/2015Preparation Date: 26/January/2015Preparation Date: 26/January/2015Preparation Date: 26/January/2015Revision Date: 26/January/2015Revision Date: 26/January/2015Revision Date: 26/January/2015Revision Date: 26/January/2015



Return to Index

Hazard statements l Causes serious eye damage Causes skin irritation Harmful if swallowed May be fatal if swallowed and enters airways May cause an allergic skin reaction May cause drowsiness or dizziness Combustible liquid May damage fertility or the unborn child.

Precautionary statementsPrevention l Wash thoroughly after handling.

Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Avoid breathing dust, fume, gas, mist, vapors and/or spray. Keep away from heat, sparks, open flames and/or hot surfaces. No smoking. Avoid contact during pregnancy/while nursing. Do not eat, drink or smoke when using this product. Use only outdoors or in a wellventilated area. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.

Response l IF ON SKIN: Wash with plenty of soap and water. Specific treatment, see supplemental first aid information. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison control center or doctor if you feel unwell. IF exposed or concerned: Get medical advice/attention. In case of fire: Use appropriate media CO2, Dry chemical, Foam for extinction.

Storage/Disposal l Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Store locked up. Store in a wellventilated place. Keep container tightly closed.

Other hazardsOSHA HCS 2012 l Under United States Regulations (29 CFR 1910.1200 Hazard Communication



Substances

l Material does not meet the criteria of a substance.

Mixtures

CompositionChemical Name Identifiers %Rosemary oil CAS:8000257 10%





Geraniol CAS:106241 5% Wintergreen Oil CAS:68917759 37% White mineral oil CAS:8042475 40% Vanillin CAS:121335 3% Other ingredients NDA 5%


Description of first aid measuresInhalation l IF INHALED: If breathing is difficult, remove person to fresh air and keep at rest in a

position comfortable for breathing. Call a poison control center or doctor for further treatment advice.

Skin l IF ON SKIN: Wash with plenty of soap and water. If irritation or rash occurs, get medical advice/attention. Take off contaminated clothing and wash before reuse.

Eye l IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Ingestion l IF SWALLOWED: Immediately call a poison control center or doctor. Aspiration hazard if swallowed, do NOT induce vomiting.

Most important symptoms and effects, both acute and delayedl Aspiration hazard; eye irritant, skin irritant, may cause an allergic skin reaction in individuals with a sensitivity to Wintergreen Oil or Geraniol, harmful if swallowed, may damage fertility or the unborn child. Refer to Section 11 Toxicological Information.

Indication of any immediate medical attention and special treatment neededNotes to Physician l Treat symptomatically and supportively.


Extinguishing mediaSuitable Extinguishing Media l Use foam, carbon dioxide, or dry chemical. Unsuitable Extinguishing Media

l Do not use water. May spread fire.

Firefighting Procedures l Do not allow fire fighting water to escape into waterways or sewers. Ventilate closed spaces before entering. Do not breathe gas/fumes/vapor/spray. Do not use direct stream of water. A direct stream of water may spread fire. Eliminate ignition sources.


l Combustible liquid. Containers may explode when heated. Liquid will float and may reignite on surface of water.


l Carbon dioxide, carbon monoxide, smoke, fumes, and unburned hydrocarbons and terpenes.

Advice for firefightersl Wear positive pressure selfcontained breathing apparatus (SCBA).


Personal precautions, protective equipment and emergency proceduresPersonal Precautions l Ventilate enclosed areas. Wear appropriate personal protective equipment, avoid

direct contact. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep all sources of ignition away.





Emergency Procedures l ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Ventilate closed spaces before entering.

Environmental precautionsl No data available


l Absorb spills with an inert material, clay granules or other inert absorbent material and put in container for disposal.


Precautions for safe handlingHandling l Keep away from fire No Smoking. Avoid breathing fumes. Use only in well ventilated

areas. Wear appropriate personal protective equipment, avoid direct contact. Conditions for safe storage, including any incompatibilitiesStorage l Store locked up. Store in a cool/lowtemperature, wellventilated dry place away from

heat and ignition sources. Keep from freezing. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F


l Heat, sparks, open flame. Oxidizing agents.


Control parametersExposure Limits/Guidelines l No data available.


l Use adequate ventilation to remove vapors (fumes, dust, etc.)

Personal Protective EquipmentPictograms l

Respiratory l In case of insufficient ventilation, wear suitable respiratory equipment.Eye/Face l Wear chemical splash safety goggles.Hands l Wear appropriate gloves.Skin/Body l Wear full body suit.

Environmental Exposure Controls

l While specific data regarding toxicity to fish or other aquatic organisms is not available for this product, care should always be taken to prevent pesticides from entering aquifers.


Information on Physical and Chemical PropertiesMaterial Description Physical Form Liquid Appearance/Description Clear, light brown liquid.Color Light brown. Odor Faint minty.Odor Threshold No data available General Properties Boiling Point No data available Melting Point No data available





Decomposition Temperature No data available pH No data available

Specific Gravity/Relative Density 0.985g/ml Density No data available

Water Solubility Not soluble Viscosity No data available

Critical Temperature No data available Volatility Vapor Pressure No data available Vapor Density No data availableEvaporation Rate No data available Flammability Flash Point 145 F(62.7778 C) UEL No data availableLEL No data available Autoignition No data availableFlammability (solid, gas) No data available Environmental Octanol/Water Partition coefficient No data available


Reactivityl Nonreactive under normal handling and storage conditions.

Chemical stabilityl Stable

Possibility of hazardous reactionsl Hazardous polymerization will not occur.

Conditions to avoidl Direct sunlight. Do not freeze. Excessive heat >110°F. Heat, sparks, open flame, other ignition sources, and oxidizing conditions.

Incompatible materialsl Heat, strong acids, strong bases and oxidizing agents.

Hazardous decomposition productsl Carbon dioxide, carbon monoxide, smoke, fumes, and unburned hydrocarbons and terpenes.




Acute toxicityOSHA HCS 2012 • Acute Toxicity Dermal Classification criteria not met; Acute Toxicity Inhalation Classification criteria not met; Acute Toxicity Oral 4



Germ Cell Mutagenicity OSHA HCS 2012 • Not classified data lacking


Skin sensitization OSHA HCS 2012 • Skin Sensitizer 1







Toxicity for Reproduction OSHA HCS 2012 • Toxic to Reproduction 1B


Serious eye damage/Irritation OSHA HCS 2012 • Serious Eye Damage 1

Potential Health EffectsInhalationAcute (Immediate) l May cause drowsiness and dizziness.Chronic (Delayed) l No data available

SkinAcute (Immediate) l May cause an allergic reaction in individuals with a sensitivity to Wintergreen oil or

Geraniol. Causes skin irritation.Chronic (Delayed) l No data available

EyeAcute (Immediate) l Causes serious eye damage.Chronic (Delayed) l No data available

IngestionAcute (Immediate) l Aspiration hazard small amounts of liquid aspirated into the lungs during ingestion or

from vomiting may cause chemical pneumonitis or pulmonary edema. Harmful if swallowed.

Chronic (Delayed) l No data available

Reproductive Effects l Laboratory experiments have shown teratogenic effects.


Toxicityl No data available

Persistence and degradabilityl No data available

Bioaccumulative potentiall No data available.

Mobility in Soill No data available

Other adverse effects


Waste treatment methodsProduct waste l Dispose of content and/or container in accordance with local, regional, national, and/or

international regulations. Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Do not contaminate water by disposal.

Packaging waste l Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. See product label for disposal instructions.






UN number

UN proper shipping name Transport hazard class(es)

Packing group


DOT None Not Regulated N/A N/A N/A

IMO/IMDG None Not Regulated N/A N/A N/A

IATA/ICAO UN3334 Aviation regulated liquid, n.o.s. (rosemary oil) 9 III N/A

Special precautions for user l None specified.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

l No data available

Other informationIMO/IMDG l No data availableIATA/ICAO l No data available

Key to abbreviationsN/A = Not applicable.


Safety, health and environmental regulations/legislation specific for the substance or mixtureSARA Hazard Classifications l Not regulated


Geraniol 106241 Yes

Rosemary oil 8000257 Yes

Vanillin 121335 Yes

White mineral oil 8042475 Yes

Wintergreen Oil 68917759 Yes


Last Revision Date l 26/January/2015Preparation Date l 26/January/2015Disclaimer/Statement of Liability

l The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE.





Trade Name: Final All-Weather Blox Date Created: January 2015 Supplier: Bell Laboratories, Inc. Page 1 of 4

FINAL®ALL-WEATHER BLOX SAFETY DATA SHEET ACCORDING TO REGULATION: OSHA


PREPARED BY: CAR

1. PRODUCT AND COMPANY IDENTIFICATIONProduct Identifier: FINAL® ALL-WEATHER BLOX EPA Registration Number: 12455-89 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Anticoagulant Rodenticide - Ready to use Uses advised against: Use only for the purpose described above





Brodifacoum [3-[3-(4'-Bromo-[1,1'-biphenyl]-4-yl)-1,2,3,4-tetrahydro-1-naphthalenyl]-4-hydroxy-2H-1-benzopyran-2-one]

56073-10-0 0.005%


4. FIRST AID MEASURESDescription of first aid measures Ingestion: Call physician or emergency number immediately. Have person sip a glass of water if able to swallow. Do not induce vomiting unless instructed by physician. Inhalation: Not applicable. Eye contact: Hold eye open and rinse slowly with water for 15 – 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. If irritation develops, obtain medical assistance. Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. If irritation develops, obtain medical assistance. Most important symptoms and effects, both acute and delayed Ingestion of excessive quantities may cause nausea, vomiting, loss of appetite, extreme thirst, lethargy, diarrhea, bleeding. Advice to physician: If ingested, administer Vitamin K1 intramuscularly or orally as indicated for bishydroxycoumarin overdoses. Repeat as necessary as based upon monitoring of prothrombin times. Advice to Veterinarian: For animals ingesting bait and/or showing poisoning signs (bleeding or elevated prothrombin times), give Vitamin K1. If needed, check prothrombin times every 3 days until values return to normal (up to 30 days). In severe cases, blood transfusions may be needed.

Return to Index...


5. FIRE-FIGHTING MEASURES Extinguishing media Suitable Extinguishing Media: water, foam or inert gas. Unsuitable Extinguishing Media: None known. Special hazards arising from the mixture: High temperature decomposition or burning in air can result in the formation of toxic gases, which may include carbon monoxide and traces of bromine and hydrogen bromide. Advice for firefighters: Wear protective clothing and self-contained breathing apparatus.

6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Gloves should be worn when handling the bait. Collect spillage without creating dust. Environmental precautions: Do not allow bait to enter drains or water courses. Where there is contamination of streams, rivers or lakes contact the appropriate environment agency. Methods and materials for containment and cleaning up For Containment: Sweep up spilled material immediately. Place in properly labeled container for disposal or re-use. For Cleaning Up: Wash contaminated surfaces with detergent. Dispose of all wastes in accordance with all local, regional and national regulations. Reference to other sections: Refer to Sections 7, 8 & 13 for further details of personal precautions, personal protective equipment and disposal considerations.



Component OSHA ACGIH Other Limits Brodifacoum Not Established Not Established Not Established

Appropriate Engineering Controls: Not required Occupational exposure limits: Not established Personal Protective Equipment: Respiratory protection: Not required Eye protection: Not required Skin protection: Shoes plus socks, and waterproof gloves. Hygiene recommendations: Wash thoroughly with soap and water after handling.



Appearance/Color: Red wax block Odor: Sweet grain-like Odor Threshold: Not applicable, odor not associated with a hazardous material. pH: Not applicable, Final All-Weather Blox is not dispersible with water. Melting point: Not applicable to rodenticide bait Boiling point: Not applicable to rodenticide bait Flash point: Not applicable, Final All-Weather Blox does not contain components classified as flammable. Evaporation rate: Not applicable, Final All-Weather Blox is a solid. Upper/lower flammability or explosive limits:

Not applicable, Final All-Weather Blox does not contain components classified as flammable or explosive.


Not applicable to rodenticide bait NA: Final All-Weather Blox is a solid



Auto-ignition temperature: Not applicable, Final All-Weather Blox does not contain components classified as flammable. Decomposition temperature: Not applicable to rodenticide bait Viscosity: Not applicable, Final All-Weather Blox is not a liquid.

10. STABILITY AND REACTIVITY Reactivity: Stable when stored in original container in a cool, dry location. Chemical stability: Stable when stored in original container in a cool, dry location. Possibility of hazardous reactions: Refer to Hazardous decomposition products Conditions to avoid: Avoid extreme temperatures (below 0°C or above 40°C). Incompatible materials: Avoid strongly alkaline materials. Hazardous decomposition products: High temperature decomposition or burning in air can result in the formation of toxic gases, which may include carbon monoxide and traces of bromine and hydrogen bromide.

11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute Toxicity LD50, oral (ingestion): >5001 mg/kg (rats) (Brodifacoum rat LD50 oral: 0.490 mg/kg bw). LD50, dermal (skin contact): > 5001 mg/kg (rats) (Brodifacoum rabbit LD50 dermal: 4.185 mg/kg bw). LC50, inhalation: Final All-Weather Blox is a wax block and therefore exposure by inhalation is not relevant. Skin corrosion/irritation: Not irritating to skin. Serious eye damage/Irritation: Not irritating to eyes. Respiratory or skin sensitization: Dermal sensitization: Not a Sensitizer (Guinea pig maximization test). Germ cell mutagenicity: Final All-Weather Blox contains no components known to have a mutagenetic effect. Carcinogenicity: Final All-Weather Blox contains no components known to have a carcinogenetic effect.

Components NTP IARC OSHA Brodifacoum Not listed Not listed Not listed

Reproductive Toxicity: Final All-Weather Blox: No data Aspiration Hazard: Not applicable. Final All-Weather Blox is a wax block. Target Organ Effects: Reduced blood clotting ability.

12. ECOLOGICAL INFORMATION Ecotoxicity Effects: This product is extremely toxic to fish, birds and other wildlife. Dogs and predatory and scavenging mammals and birds might be poisoned if they feed upon animals that have eaten this bait. Do not apply this product directly to water or to areas where surface water is present or to intertidal areas below the mean high water mark. Runoff also may be hazardous to aquatic organisms in water adjacent to treated areas. Do not contaminate water when disposing of equipment wash water or rinsate. Persistence and degradability: Final All-Weather Blox is inherently biodegradable. Bioaccumulative potential: Not determined for Final All-Weather Blox. Brodifacoum water solubility is extremely low (< 0.1mg/l). Mobility in Soil: Not determined for Final All-Weather Blox. Mobility of brodifacoum in soil is considered to be limited. Other adverse effects: None.




15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture: FIFRA: This pesticide product is regulated by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The safety, health, environmental, and hazard information required on the pesticide label is listed below and reflected throughout this SDS. The pesticide label also includes other important information, including directions for use. Signal Word: CAUTION Precautionary Statements: Contains the anticoagulant Brodifacoum which may cause bleeding if ingested. Harmful if swallowed or absorbed through the skin. Keep away from children, domestic animals and pets. Do not get in eyes, on skin or on clothing. Potential Health Effects: Eye Contact: May cause irritation Skin Contact: Non-irritating to the skin Ingestion: Harmful if swallowed TSCA: All components are listed on the TSCA Inventory or are not subject to TSCA requirements CERCLA/SARA 313: Not listed CERCLA/SARA 302: Not listed




/15 Safety Data Sheet (SDS)

OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.

Printing date 04/02/2015 Reviewed on 04/02/2015

40.1.6

· Product identifier· Trade name: Fumitoxin® Tablets - U.S. EPA Reg. No. 72959-1; Fumitoxin® Pellets - U.S. EPA Reg. No.

72959-2 · Relevant identified uses of the substance or mixture and uses advised against· Product description Fumigant for Insect & Rodent Control· Application of the substance / the mixtureFumigants used to treat raw agricultural commodities, processed foods, non-food commodities and rodentburrows.

· Details of the supplier of the safety data sheet· Manufacturer/Supplier:DEGESCH America, Inc.153 Triangle Dr.P.O. Box 116Weyers Cave, VA 24486 USATelephone: (540) 234-9281 / 800-330-2525Telefax: (540) [email protected]

· Emergency telephone number:For human or animal emergencies: 1-800-308-4856 (Rocky Mountain Poison and Drug Center)For all other chemical emergencies: 1-800-424-9300 (Chemtrec)Emergency and Information - DEGESCH America, Inc.: (540) 234-9281 / 800-330-2525

· Classification of the substance or mixture

GHS02 Flame

Water-react. 1 H260 In contact with water releases flammable gases which may ignite spontaneously.

GHS06 Skull and crossbones

Acute Tox. 2 H300 Fatal if swallowed. Acute Tox. 2 H330 Fatal if inhaled.

GHS05 Corrosion

Eye Dam. 1 H318 Causes serious eye damage.

GHS09 Environment

Aquatic Acute 1 H400 Very toxic to aquatic life.

GHS07

(Contd. on page 2)

* 2 Hazard(s) identification

* 1 Identification

Return to Index...

http://www.degeschamerica.com/

mailto:[email protected]

40.1.6

Page 2/15 Safety Data Sheet (SDS)



Trade name: Fumitoxin® Tablets - U.S. EPA Reg. No. 72959-1; Fumitoxin® Pellets - U.S. EPA Reg. No. 72959-2

Skin Irrit. 2 H315 Causes skin irritation.

· Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).

· Hazard pictograms

GHS02 GHS05 GHS06 GHS09

· Signal word Danger

· Hazard-determining components of labeling: Aluminum Phosphide Ammonium Carbamate

· Hazard statements In contact with water releases flammable gases which may ignite spontaneously. Fatal if swallowed or if inhaled. Causes skin irritation. Causes serious eye damage. Very toxic to aquatic life.

· Precautionary statements Keep away from any possible contact with water, because of violent reaction and possible flash fire. Do not breathe dust/fume/gas/mist/vapors/spray. Wear respiratory protection. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. If swallowed: Immediately call a poison center/doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see supplementary first aid instructions on this Safety Data Sheet). IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If skin irritation occurs: Get medical advice/attention. In case of fire: Use for extinction: CO2, sand, extinguishing powder. If on skin: Wash with plenty of water. Collect spillage. Take off contaminated clothing and wash it before reuse. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a dry place. Store in a closed container. Dispose of contents/container in accordance with local/regional/national/international regulations.

· Unknown acute toxicity: 10.3 percent of the mixture consists of ingredient(s) of unknown toxicity.

(Contd. on page 3)

40.1.6





· Classification system: · NFPA ratings (scale 0 - 4)

Health = 4 Fire = 4 Reactivity = 2

The substance demonstrates unusual reactivity with water.

· HMIS-ratings (scale 0 - 4)

Health = *4 Fire = 4 Reactivity = 2

· Other hazards None known

· Chemical characterization: Mixtures · Description: Mixture of substances listed below with nonhazardous additions.

· Dangerous Components: CAS: 20859-73-8 RTECS: BD 1400000

Aluminum Phosphide 55% Water-react. 1, H260; Acute Tox. 2, H300; Aquatic Acute 1,

H400 CAS: 1111-78-0 Ammonium Carbamate Proprietary%

Eye Dam. 1, H318; Acute Tox. 4, H302; Skin Irrit. 2, H315; Aquatic Acute 3, H402

RTECS: BD 1200000 Proprietary 5-10% STOT SE 3, H335

Proprietary 2-12% Skin Irrit. 2, H315; STOT SE 3, H335; Eye Irrit. 2B, H320

· Additional information: Fumitoxin Tablets and Fumitoxin Pellets react with water to produce phosphine (hydrogen phosphide, PH3, CAS No. 7803-51-2) as shown in Equation 1. Fumitoxin products are formulated with 55% aluminum phosphide and also contains ammonium carbamate (AC) and inert ingredients. Ammonium carbamate decomposes to liberate ammonia (CAS No. 7664-41-7) and carbon dioxide (CAS No. 124-38-9) as shown in Equation 2.

1) AlP + 3H2O ---> Al(OH)3 + PH3 2) NH2COONH4 ---> 2NH3 + CO2

· Description of first aid measures · General information: Symptoms of overexposure are headache, dizziness, nausea, difficult breathing, vomiting, and diarrhea. In ALL cases of overexposure, get medical attention immediately. Take victim to a doctor or emergency treatment facility. Have product container label or applicator's manual with you when calling a poison control center, doctor, or when going for treatment.

(Contd. on page 4)

* 4 First-aid measures

* 3 Composition/information on ingredients

4 4 2

—W

HEALTH *4

FIRE 4

REACTIVITY 2

40.1.6





· After inhalation: Get exposed person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth to mouth, if possible. Contact a poison control center or doctor for treatment advice.

· After skin contact: Take off contaminated clothing immediately. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.

· After eye contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. Call a poison control center or doctor for treatment advice.

· After swallowing: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not give anything by mouth to an unconscious person. Do not induce vomiting unless told to by a poison control center or doctor.

· Information for doctor: · Most important symptoms and effects, both acute and delayed Aluminum phosphide fumigant products react with moisture from the air, acids and many other liquids to release phosphine gas (hydrogen phosphide, PH3). Mild exposure by inhalation causes malaise (indefinite feeling of sickness), headache, ringing in the ears, fatigue, nausea and pressure in the chest which is relieved by removal to fresh aid. Moderate poisoning causes weakness, vomiting, pain just above the stomach, chest pain, diarrhea and dyspnea (difficulty breathing). Symptoms of severe poisoning may occur within a few hours to several days resulting in pulmonary edema and may lead to dizziness, cyanosis, unconsciousness, and death.

· Indication of any immediate medical attention and special treatment needed No further relevant information available.

· Extinguishing media · Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water. · For safety reasons unsuitable extinguishing agents: Water · Special hazards arising from the substance or mixture Phosphine (hydrogen phosphide, PH3)-air mixtures at concentrations above the LEL of 1.8% v/v (18,000 ppm) may ignite spontaneously. Ignition of high concentrations of phosphine gas (hydrogen phosphide, PH3) can product a very energetic reaction. Explosions can occur under these conditions and may cause severe personal injury. Never allow the buildup of phosphine gas (hydrogen phosphide, PH3) to exceed explosive concentrations. Open containers of metal phosphides in open air only and never in a flammable atmosphere. Do not confine spent or partially spent dust from metal phosphide fumigants as the slow release of phosphine gas (hydrogen phosphide, PH3) from these materials may result in the formation of an explosive atmosphere. Spontaneous ignition may occur if large quantities of aluminum phosphide are piled in contact with liquid water. This is particularly true if quantities of these materials are placed in an environment which can provide partial confinement of the hydrogen phosphide gas liberated by hydrolysis.

If incinerated, product will release the following toxic materials: Oxides of aluminum, magnesium, phosphorous, nitrogen (NOx), carbon, phosphine gas (hydrogen phosphide, PH3), ammonia and phosphoric acid.

· Advice for firefighters Aluminum phosphide is not flammable by itself. However, it reacts readily with water to produce phosphine gas (hydrogen phosphide, PH3) which may ignite spontaneously in air at concentrations above its LEL of 1.8% v/v (18,000 ppm). The UEL of phosphine gas (hydrogen phosphide, PH3) is unknown.

(Contd. on page 5)

* 5 Fire-fighting measures

40.1.6





· Protective equipment: As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent), and full protective gear to prevent contact with skin and eyes. Wear a NOISH/MSHA approved full-face gas mask – phosphine gas canister combination may be used at levels up to 15 ppm or following manufacturers’ use conditions instructions for escape. Above 15 ppm or in situations where the phosphine gas concentration is unknown, a NIOSH/MSHA approved SCBA must be worn.

· Personal precautions, protective equipment and emergency procedures Respiratory protection will most likely be required during cleanup of spilled aluminum phosphide fumigants. If the concentration of phosphine (hydrogen phosphide, PH3) is unknown, NIOSH/MSHA approved SCBA or its equivalent must be worn. Full-face gas mask canister combinations may only be worn at concentrations no higher than 15 ppm.

· Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system.

· Methods and material for containment and cleaning up: If possible, dispose of spilled material by use according to label instructions. Freshly spilled material which has not been contaminated by water or foreign matter may be placed into original or other gas-tight containers. Punctured flasks, pouches or containers may be temporarily repaired using aluminum tape. If the age of the spill is unknown or if the product has been contaminated with soil, debris, water, etc., gather up the spillage in small open buckets having a capacity no larger than about 1 gallon. Do not add more than about 1 to 1.5 kg (2 to 3 lbs.) to a bucket. If on-site wet-deactivation is not feasible, transport the uncovered buckets in open vehicles to a suitable area. Small amounts of spillage, from about 4 to 8 kg (9 to 18 lbs.) may be spread out over the ground in an open area to be deactivated by atmospheric moisture. Alternatively, spilled aluminum phosphide fumigants may be deactivated by the wet method as described in the following:

Wet Deactivation of Spilled Fumitoxin Products: 1. Deactivating solution is prepared by adding the appropriate amount of low sudsing detergent to water in a drum or other suitable container. A 2% solution or 4 cups of detergent in 30 gallons is suggested. The container should be filled with deactivating solution to within a few inches of the top. 2. The material is added slowly to the deactivating solution and stirred so as to thoroughly wet all of the product. This should be carried out in open air and respiratory protection may be required. At no time should the deactivation drum be covered. 3. No more than about 45 to 50 lbs. of Fumitoxin should be added to 15 gallons of water-detergent mixture. Products may ignite during wet deactivation if they are allowed to float to the surface. Add weights or otherwise ensure that products stay submerged until deactivation is completed. 4. Allow the mixture to stand, with occasional stirring, for about 36 hours. The resultant slurry of dust or packaged product will then be safe for disposal. 5. Dispose of the slurry of deactivated material, with or without preliminary decanting, at a sanitary landfill or other suitable site approved by local authorities. Where permissible, this slurry may be poured into a storm sewer or out onto the ground.

· Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

· Handling: · Precautions for safe handling Store in a cool, dry place in tightly closed containers.

(Contd. on page 6)

* 7 Handling and storage

* 6 Accidental release measures

40.1.6





· Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Protect from heat. Keep protective respiratory device available.

· Conditions for safe storage, including any incompatibilities Store away from water, acids, bases, strong oxidizing agents and strong reducing agents.

· Storage: · Requirements to be met by storerooms and receptacles: Store products in a locked, dry, well-ventilated area away from heat. Post as a pesticide storage area. Do not store in buildings inhabited by humans or domestic animals.

· Information about storage in one common storage facility: Not required. · Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well-sealed containers.

· Specific end use(s) No further relevant information available.

· Additional information about design of technical systems: No further data; see section 7.

· Control parameters All ventilation should be designed in accordance with OSHA standard (29 CFR 1910.94). Use local exhaust at filling zones and where leakage and dust formation is probable. Use mechanical (general) ventilation for storage areas. Use appropriate ventilation as required to keep Exposure Limits in Air below TLV & PEL limits.

· Components with occupational exposure limits: 20859-73-8 Aluminum Phosphide REL

TLV

Long-term value: 2 mg/m³ as Al Long-term value: 1* mg/m³ as Al;*as respirable fraction

Proprietary PEL

REL

TLV

Long-term value: 15*; 15** mg/m³ *Total dust; ** Respirable fraction Long-term value: 10* 5** mg/m³ as Al*Total dust**Respirable/pyro powd./welding f. Long-term value: 1* mg/m³ as Al; *as respirable fraction

Proprietary TLV Long-term value: 10 mg/m³ 7803-51-2 phosphine PEL REL

TLV

Long-term value: 0.4 mg/m³, 0.3 ppm Short-term value: 1 mg/m³, 1 ppm Long-term value: 0.4 mg/m³, 0.3 ppm Short-term value: (1.4) mg/m³, (1) ppm Long-term value: (0.42) mg/m³, (0.3) NIC-0.1 ppm Ceiling limit value: NIC-0.5 ppm

(Contd. on page 7)

* 8 Exposure controls/personal protection

40.1.6





7664-41-7 ammonia, anhydrous PEL REL

TLV

Long-term value: 35 mg/m³, 50 ppm Short-term value: 27 mg/m³, 35 ppm Long-term value: 18 mg/m³, 25 ppm Short-term value: 24 mg/m³, 35 ppm Long-term value: 17 mg/m³, 25 ppm

· Additional information: The lists that were valid during the creation were used as basis.

· Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing and wash before reuse. Wash hands before breaks and at the end of work. Avoid contact with the skin. Avoid contact with the eyes and skin.

· Breathing equipment: Respiratory protection will most likely be required while using aluminum phosphide fumigants. If the concentration of phosphine (hydrogen phosphide, PH3) is unknown, NIOSH/MSHA approved SCBA or its equivalent must be worn. Full-face gas mask canister combinations may only be worn at concentrations no higher than 15 ppm.

· Protection of hands:

Protective gloves

Wear dry gloves of cotton or other material if contact with tablets, pellets, or dust is likely. Gloves should remain dry after use. Aerate gloves and other clothing that may be contaminated in a well-ventilated area prior to laundering.

· Material of gloves Dry gloves of cotton or other material. · Penetration time of glove material The exact break-through time has to be determined and observed by the manufacturer of the protective gloves.

· Eye protection: Not required.

· Information on basic physical and chemical properties · General Information · Appearance:

Form: Solid Color: Greenish-gray

· Odor: Garlic, carbide or decaying fish · Odor threshold: Not determined.

· pH-value: Not applicable.

· Change in condition Melting point/Melting range: AlP = > 1000 °C (AlP = > 1832 °F) (PH3 = -133.5 °C) Boiling point/Boiling range: AlP = > 1000 °C (AlP = > 1832 °F) (PH3 = -87.7 °C)

· Flash point: Not determined

(Contd. on page 8)

* 9 Physical and chemical properties

40.1.6





· Flammability (solid, gaseous): Contact with water or acids liberates extremely flammable gases.

· Ignition temperature: Not determined

· Decomposition temperature: Decomposes at ambient conditions when moisture is present.

· Auto igniting: Spontaneously flammable in air.

· Danger of explosion: Not determined.

· Explosion limits: Lower: 1.8% Vol % (for PH3) Upper: Not established Vol % (for PH3)

· Vapor pressure: AlP = 0 mm Hg PH3 = 40 mm Hg @ -129.4 °C AC = 100 mm Hg @ 26.7 °C

· Density @ 20 °C (68 °F): AlP = 2.85 g/cm³ (AlP = 23.783 lbs/gal) (PH3 = 1.17 g/cm³) · Relative density Not determined. · Vapor density Not applicable. · Evaporation rate Not applicable.

· Solubility in / Miscibility with Water: AlP = Insoluble, reacts

PH3 = 26 cc in 100 ml at 17 °C AC = Very soluble, reacts

· Partition coefficient (n-octanol/water): Not determined.

· Viscosity: Dynamic: Not applicable. Kinematic: Not applicable.

· Solvent content: Solids content: 100.0 %

· Other information No further relevant information available.

· Reactivity No further relevant information available. · Chemical stability Products are stable to most chemical reactions, except for hydrolysis. Products will react with moist air, liquid water, acids and some other liquids to produce toxic and flammable phosphine (hydrogen phosphide, PH3) gas.

· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions Contact with water releases flammable gases. Contact with water releases toxic gases.

· Conditions to avoid: Avoid prolonged exposure to air. · Incompatible materials: Water, acids, bases, strong oxidizing agents and strong reducing agents. · Hazardous decomposition products: Oxides of aluminum, phosphorous, nitrogen (NOx), magnesium, carbon, phosphine gas (hydrogen phosphide, PH3), ammonia and phosphoric acid.

· Additional information: Phosphine (hydrogen phosphide, PH3) gas may react with certain metals and cause corrosion, especially at higher temperatures and relative humidity. Metals such as copper, brass and other copper alloys, and

(Contd. on page 9)

* 10 Stability and reactivity

40.1.6





precious metals such as gold and silver are susceptible to corrosion by phosphine. Small electric motors, smoke detectors, brass sprinkler heads, batteries and battery chargers, fork lifts, temperature monitoring systems, switching gears, communication devices, computers, calculators and other electrical equipment may be damaged by this gas. Phosphine (hydrogen phosphide, PH3) will also react with certain metallic salts and, therefore, sensitive items such as photographic film, some inorganic pigments, etc., should not be exposed.

· Information on toxicological effects · Acute toxicity:

· LD/LC50 values that are relevant for classification: 20859-73-8 Aluminum Phosphide Oral LD50 0.4 mg/kg (rat) 1111-78-0 Ammonium Carbamate Oral Inhalative

LD50 LC50/96 hours

1470 mg/kg (rat) 37 mg/l (Trout)

7803-51-2 phosphine Inhalative LC50/1 h 180 ppm (rat) 7664-41-7 ammonia, anhydrous Oral Inhalative

LD50 LC50/4 h

350 mg/kg (rat) 2000 mg/l (rat)

· Primary irritant effect: · on the skin: May be irritating. Irritant to skin and mucous membranes.

· on the eye: Direct contact may cause eye irritation. Strong irritant with the danger of severe eye injury. Causes serious eye irritation.

· Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant Very toxic

· Carcinogenic categories · IARC (International Agency for Research on Cancer) None of the ingredients are listed.

Group 1 - Carcinogenic to humans Group 2A - Probably carcinogenic to humans Group 2B - Possibly carcinogenic to humans Group 3 - Not classifiable as to its carcinogenicity to humans Group 4 - Probably not carcinogenic to humans

· NTP (National Toxicology Program) None of the ingredients are listed.

· OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients are listed.

(Contd. on page 10)

* 11 Toxicological information

40.1.6





· Toxicity · Aquatic toxicity: Avoid release into the environment. Runoff from fire control or dilution water may cause pollution.

1111-78-0 Ammonium Carbamate EC50 129.1 mg/l (Green algae)

63 mg/l (Water flea) · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Ecotoxical effects: · Remark: Very toxic for fish · Additional ecological information: · General notes: Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Very toxic for aquatic organisms

· Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available.

· Waste treatment methods · Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. When being disposed of, spilled or partially reacted Fumitoxin products are considered hazardous wastes under existing Federal Regulations. If properly exposed, the grayish-white residual dust after a fumigation will not be a hazardous waste and normally contains only a very small amount of unreacted aluminum phosphide. This waste will be safe for disposal. However, the spent residual dust from incompletely exposed Fumitoxin products may require special care. Triple rinse tablet and pellet flasks and stoppers with water. Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local authorities. Rinsate may be disposed of in a storm sewer, sanitary landfill or by other approved procedures. Or, it is permissible to remove lids and expose empty flasks to atmospheric conditions until the residue in the flasks is reacted. Then puncture and dispose of in a sanitary landfill or other approved site, or by other procedures approved by state and local authorities. Some local and state waste disposal regulations may vary from the following recommendations. Disposal procedures should be reviewed with appropriate authorities to ensure compliance with local regulations. Contact your State Pesticide or Environmental Control Agency or Hazardous Waste Specialist at the nearest EPA Regional Office for guidance.

1. Confinement of partially spent residual materials, as in a closed container, or collection and storage of large quantities of dust may result in a fire or explosion hazard. Small amounts of phosphine (hydrogen phosphide, PH3) may be given off from unreacted aluminum phosphide, and confinement of the gas may result in a flash. 2. In open areas, small amounts of spent residual dust or spent packaged products may be disposed of on site by burial or by spreading over the land surface away from inhabited buildings. 3. Residual dust from Fumitoxin products may also be collected and disposed of at a sanitary landfill, or other

(Contd. on page 11)

* 13 Disposal considerations

* 12 Ecological information

40.1.6





approved sites or by other procedures approved by Federal, State or Local authorities. 4. From 3 to 5 kg (7 to 10 lbs.) of spent dust from 2 to 3 flasks of Fumitoxin may collected for disposal in a 1-gallon bucket. Larger amounts, up to about one-half case, may be collected in burlap, cotton or other types of porous cloth bags for transportation in an open vehicle to the disposal site. Do not collect dust from more than 7 flasks of tablets, 10 flasks of pellets (about 11 kg or 25 lbs.) in a single bag. Do not pile cloth bags together. Do not use this method for partially spent or "green" dust. Caution: Do not collect dust in large drums, dumpsters, plastic bags or other containers where confinement may occur.

· Uncleaned packagings: · Recommendation: Triple rinse tablet and pellet flasks and stoppers with water and then offer for recycling or reconditioning; or puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local authorities.

· UN-Number · DOT, ADR, IMDG, IATA UN1397 · UN proper shipping name · DOT Aluminum phosphide · ADR UN1397 Aluminum phosphide, ENVIRONMENTALLY

HAZARDOUS · IMDG ALUMINIUM PHOSPHIDE, MARINE POLLUTANT · IATA ALUMINIUM PHOSPHIDE · Transport hazard class(es) · DOT

· Class 4.3 Substances which, in contact with water, emit flammable

gases · Label 4.3, 6.1

· ADR

· Class 4.3 (WT2) Substances which, in contact with water, emit

flammable gases · Label 4.3, 6.1

· IMDG


gases (Contd. on page 12)

* 14 Transport information

40.1.6





· Label 4.3/6.1

· IATA


gases · Label 4.3 (6.1) · Packing group · DOT, ADR, IMDG, IATA I · Environmental hazards: Product contains environmentally hazardous substances:

Aluminum Phosphide · Special marking (ADR): Symbol (fish and tree) · Special precautions for user Warning: Substances which, in contact with water, emit

flammable gases · Danger code (Kemler): 462 · EMS Number: F-G,S-N · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.

· Transport/Additional information: · DOT · Quantity limitations On passenger aircraft/rail: Forbidden

On cargo aircraft only: 15 kg

· ADR · Excepted quantities (EQ) Code: E0

Not permitted as Excepted Quantity

· IMDG · Limited quantities (LQ) 0 · Excepted quantities (EQ) Code: E0

Not permitted as Excepted Quantity · UN "Model Regulation": UN 1397 , Aluminum phosphide, ENVIRONMENTALLY

HAZARDOUS, 4.3, 6.1, I

· Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara

· Section 355 (extremely hazardous substances): 20859-73-8 Aluminum Phosphide

· Section 313 (Specific toxic chemical listings): 20859-73-8 Aluminum Phosphide

Proprietary Proprietary

· TSCA (Toxic Substances Control Act): 20859-73-8 Aluminum Phosphide

(Contd. on page 13)

* 15 Regulatory information

40.1.6





Proprietary Proprietary Proprietary

· Proposition 65

· Chemicals known to cause cancer: None of the ingredients are listed.

· Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed.

· Chemicals known to cause reproductive toxicity for males: None of the ingredients are listed.

· Chemicals known to cause developmental toxicity: None of the ingredients are listed.

· Carcinogenic categories

· EPA (Environmental Protection Agency) Proprietary D, I, II

· TLV (Threshold Limit Value established by ACGIH) Proprietary A4

· NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients are listed.

· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).

· Hazard pictograms

GHS02 GHS05 GHS06 GHS09

· Signal word Danger

· Hazard-determining components of labeling: Aluminum Phosphide Ammonium Carbamate

· Hazard statements In contact with water releases flammable gases which may ignite spontaneously. Fatal if swallowed or if inhaled. Causes skin irritation. Causes serious eye damage. Very toxic to aquatic life.

· Precautionary statements Keep away from any possible contact with water, because of violent reaction and possible flash fire. Do not breathe dust/fume/gas/mist/vapors/spray. Wear respiratory protection. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Wash thoroughly after handling. Do not eat, drink or smoke when using this product.

(Contd. on page 14)

40.1.6





If swallowed: Immediately call a poison center/doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see supplementary first aid instructions on this Safety Data Sheet). IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If skin irritation occurs: Get medical advice/attention. In case of fire: Use for extinction: CO2, sand, extinguishing powder. If on skin: Wash with plenty of water. Collect spillage. Take off contaminated clothing and wash it before reuse. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a dry place. Store in a closed container. Dispose of contents/container in accordance with local/regional/national/international regulations.

· National regulations: The product is subject to be labeled according with the prevailing version of the regulations on hazardous substances.

· State Right to Know CAS: 20859-73-8 RTECS: BD 1400000

Aluminum Phosphide 55% Water-react. 1, H260; Acute Tox. 2, H300; Aquatic Acute 1,

H400 CAS: 1111-78-0 Ammonium Carbamate Proprietary%

Eye Dam. 1, H318; Acute Tox. 4, H302; Skin Irrit. 2, H315; Aquatic Acute 3, H402

RTECS: BD 1200000 Proprietary 5-10% STOT SE 3, H335

Proprietary 2-12% Proprietary 2-12%

Skin Irrit. 2, H315; STOT SE 3, H335; Eye Irrit. 2B, H320 All ingredients are listed.

· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as of the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied and shall not establish a legally valid contractual relationship. It is the responsibility of the user to determine applicability of this information and the suitability of the material or product for any particular purpose.

· Date of preparation / last revision 04/02/2015 / - · Abbreviations and acronyms:

ADR: The European Agreement concerning the International Carriage of Dangerous Goods by Road ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent

(Contd. on page 15)

16 Other information

40.1.6





LD50: Lethal dose, 50 percent Water-react. 1: Substances and Mixtures which, in contact with water, emit flammable gases, Hazard Category 1

Acute Tox. 2: Acute toxicity, Hazard Category 2 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 Eye Irrit. 2B: Serious eye damage/eye irritation, Hazard Category 2B STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1 Aquatic Acute 3: Hazardous to the aquatic environment - AcuteHazard, Category 3

· * Data compared to the previous version altered. SDS created by MSDS Authoring Services www.msdsauthoring.com (877) 204-9106

http://www.msdsauthoring.com/

Safety Data SheetInVict™ Xpress™ Granular Bait Release Date: 5/15/2015

Print Date: 5/28/2015 Version 1.0

Rockwell - RP0011

Page 1 of 8

______________________________________________________________________________________________

1. PRODUCT IDENTIFICATION

1.1. Product Identifiers

Product name : InVict™ Xpress™ Granular Bait

1.2. Other Means of Identification

Product synonyms : InVict™ Blitz™ Ant Granules

1.3. Recommended Uses/Restrictions to Use

Uses : 0.5% imidacloprid granular bait for control of various pest species per label

Restrictions : See product label for details

1.4. Supplier Details

Company : Rockwell Labs Ltd

1257 Bedford Avenue

North Kansas City, MO 64116-4308

USA

Telephone : 1 816-283-3167

1.5. Emergency Contact

Outside normal business hours

Emergency Phone # : 1 800-424-9300 (USA & Canada)

1 703-527-3887 (Outside USA & Canada)

_______________________________________________________________________________________


2.1. Classification of Substance or Mixture

none

2.2. GHS label elements, including precautionary statements

Pictogram(s) none

Signal word none

Hazard statement(s)

none

Precautionary statement(s)

none

2.3. Other hazards which do not result in classification

Imidacloprid is a neurotoxin that when consumed in sufficient quantities can

have adverse effects up to and including death. This product contains a low

Return to Index...

Safety Data Sheet

InVict™ Xpress™ Granular Bait Release Date: 5/15/2015 Print Date: 5/28/2015

Version 1.0

Rockwell - RP0011

Page 2 of 8

concentration of imidacloprid and normal use should not result in significant

occupational hazard.

__________________________________________________________________________


3.1. Substances

Not applicable

3.2. Mixtures

Hazardous component(s) or components of note:

Chemical Identity

Contains (% w/w)

CAS-No.

Hazard Classification

Imidacloprid 0.5 138261-41-3 none

_______________________________________________________________________________________


4.1. Description of first aid measures

General advice

Consult a physician or poison control center. Provide this safety data sheet to medical personnel. Move out of

hazardous areas.

If inhaled

Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration,

preferably mouth to mouth if possible. Call a poison control center or doctor for further treatment advice.

In case of skin contact

Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison

control center or doctor for treatment advice.

In case of eye contact

Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after

the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.

If swallowed

Call a poison control center or doctor for treatment advice. Have person sip a glass of water if able to swallow.

Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by

mouth to an unconscious person.

4.2. Most important symptoms and effects, both acute and delayed

Imidacloprid may cause drowsiness, dizziness, vomiting, disorientation, and fever with ingestion of more than an

incidental amount.

4.3. Indication of any immediate medical attention and special treatment needed, if necessary

See section 4.2.

_______________________________________________________________________________________


5.1. Extinguishing media

Suitable extinguishing media: use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2. Specific hazards arising from the chemical

Safety Data Sheet


Version 1.0

Rockwell - RP0011

Page 3 of 8

Oxides of carbon, nitrogen, and sulfur.

5.3. Special protective equipment and precautions for fire fighters

Wear self contained breathing apparatus for firefighting if deemed necessary.

Additional information: none.

5.4. Further information

No data available

_______________________________________________________________________________________


6.1. Personal precautions, protective equipment and emergency procedures

Avoid contact with spilled product and contaminated surfaces. Evacuate personnel to safe areas during

emergencies. For safe handling instructions see section 7. For proper PPE see section 8.

6.2. Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not allow release directly to water, to areas where surface

water is present or to intertidal areas below the mean high-water mark.

6.3. Methods and materials for containment and cleaning up

Sweep up any spilled material and dispose of according to instructions in section 13. Wash contaminated surfaces

with soap and water.

_______________________________________________________________________________________


7.1. Precautions for safe handling

Handle in accordance with good industrial hygiene practices. Wash hands thoroughly with soap and water after

use and before eating, drinking, chewing gum, using tobacco, or using the toilet. For additional precautions see

section 2.2

7.2. Conditions for safe storage, including any incompatibilities

Store in a dry place. Store in original container. Do not store where children or animals may gain access.

_______________________________________________________________________________________


8.1. Control parameters

Components with workplace parameters

Component CAS-No. Value Control

parameters Basis

none ----- ----- ----- -----

8.2. Appropriate engineering controls

Ensure relevant engineering controls are employed to prevent exceeding threshold values for the listed control

parameters in section 8.1.

8.3. Individual protection measures, such as personal protective equipment

In normal use and handling conditions refer to the product label for required PPE. In all other cases the

following recommendations would apply.

Eye/face protection

Safety Data Sheet


Version 1.0

Rockwell - RP0011

Page 4 of 8

Safety glasses or other similar eye protection conforming to ANSI Z87.1 standards recommended when handling

product.

Skin protection

Chemical resistant nitrile rubber or similarly compatible gloves recommended when handling product. Dispose

of contaminated gloves after use in accordance with applicable local and state regulations. Wash exposed skin

with soap and water immediately. Wash all contaminated clothing prior to reuse.

Respiratory protection

Not required under normal use conditions. Particulate respirator recommended when risk assessment show need

for air-purifying respirators.

Thermal hazards

None known

_______________________________________________________________________________________


9.1. Information on basic physical and chemical properties

Appearance; Opaque, yellow beige granule

Odor; Oily/fishy

Odor threshold; No data available

pH; 7.63 @ 1% in water (23.4 ºC)

Melting point/freezing point; No data available

Initial boiling point and boiling range;

No data available

Flash point; No data available

Evaporation rate; No data available

Flammability (solid, gas); No data available

Upper/lower flammability or explosive limits;

No data available

Vapor pressure; No data available

Vapor density; No data available

Relative density; 0.4085 g/ml

Solubility; Partially soluble in water

Partition coefficient: n-octanol/water;

No data available

Auto-ignition temperature; No data available

Decomposition temperature; No data available

Safety Data Sheet


Version 1.0

Rockwell - RP0011

Page 5 of 8

Viscosity; No data available

9.2. Additional Information

No data available

_______________________________________________________________________________________


10.1. Reactivity

No data available

10.2. Chemical stability

Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

No data available

10.4. Conditions to avoid

Exposure to excessive heat.

10.5. Incompatible materials

Strong oxidizing agents. Strong reducing agents.

10.6. Hazardous decomposition products

Other decomposition products – no data available

In the event of a fire: see Section 5

_______________________________________________________________________________________


11.1. Information on toxicological effects

Acute Toxicity

LD50 Oral – Rat – > 5000 mg/kg

LD50 Dermal – Rat – > 5000 mg/kg

LD50 Inhalation – no data available

Skin corrosion/irritation

Skin – Rabbit

Results: not irritating to skin

(OECD Test Guideline 404)

Serious eye damage/irritation

Eye – Rabbit

Results: minimal eye irritation

(OECD Test Guideline 405)

Respiratory or skin sensitization

Not a known sensitizer

Germ cell mutagenicity

Not a known mutagen

Carcinogenicity

IARC: No component of this product presents at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Safety Data Sheet


Version 1.0

Rockwell - RP0011

Page 6 of 8

ACGIH: No component of this product presents at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by ACGIH.

NTP: No component of this product presents at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by NTP.

OSHA: No component of this product presents at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by OSHA.

Reproductive toxicity

No data available

Specific target organ toxicity – single exposure

Imidacloprid is a neurotoxin that when consumed in sufficient quantities can have adverse effects up to and

including death. This product contains a low concentration of imidacloprid and normal use should not result in

significant occupational hazard.

Specific target organ toxicity – repeated exposure

No data available

Aspiration hazard

No data available

11.2. Other information

No data available

_______________________________________________________________________________________


12.1. Toxicity

Toxicity to fish no data available

Toxicity to daphnia no data available

and other aquatic

invertebrates

12.2. Persistence and degradability

No data available

12.3. Bioaccumulative potential

No data available

12.4. Mobility in soil

No data available

12.5. Other adverse effects

No data available

_______________________________________________________________________________________


13.1. Disposal Methods.

The best disposal method is to use the entire product per label directions. If it is necessary to dispose of unused

material then follow the label instructions and relevant local, state and federal waste disposal guidelines.

Product Disposal:

Do not contaminate water, food or feed by storage or disposal.

Safety Data Sheet


Version 1.0

Rockwell - RP0011

Page 7 of 8

Packaging Disposal:

If empty: Place in trash or offer for recycling if available. If partly filled: Call your local solid waste agency or 1-

800-CLEANUP which is managed as a public-private partnership.

_______________________________________________________________________________________


DOT

Not dangerous goods

IMDG

Not dangerous goods

IATA

Not dangerous goods

______________________________________________________________________________________________


This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain

labeling requirements under federal pesticide law. These requirements differ from the classification criteria and

hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following

is the hazard information as required on the pesticide label:

KEEP OUT OF THE REACH OF CHILDREN

CAUTION

Causes moderate eye irritation.

Avoid contact with eyes or clothing.

Wash hands thoroughly with soap and water after use and before eating, drinking, chewing gum, using tobacco,

or using the toilet.

This pesticide is highly toxic to birds and aquatic invertebrates.

Do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean

high water mark.

To protect the environment, do not allow pesticide to enter or run off into storm drains, drainage ditches, gutters

or surface waters.

SARA 302 Components

No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components

This material does not contain any chemical components with known CAS numbers that exceed the threshold

(De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards

Acute Health Hazard (Imidacloprid)

California Proposition 65 Components

This product does not contain any chemicals known to the state of California to cause cancer, birth defects, or

reproductive harm.

Safety Data Sheet


Version 1.0

Rockwell - RP0011

Page 8 of 8

TSCA

All components of this product are listed, exempted, or excluded from listing on the U.S. Toxic Substances

Control Act chemical substance inventory.

_______________________________________________________________________________________


Acronyms and abbreviations used

LD50 Lethal Dose, 50%

OECD Organization for Economic Cooperation and Development

IARC International Agency for Research on Cancer

ACGIH American Conference of Industrial Hygienists

NTP National Toxicology Program

OSHA Occupational Safety and Health Administration

DOT Department of Transportation

IMDG International Maritime Dangerous Goods

IATA International Air Transport Association

SARA Superfund Amendments and Reauthorization Act

TSCA Toxic Substances Control Act

CAS-No. Chemical Abstract Services - Number

PPE Personal Protective Equipment

HMIS Hazardous Materials Identification System

NFPA National Fire Protection Association

PPM Parts Per Million

Hazard Rating System Crossover

HMIS Rating NFPA Rating

Health Hazard: 1 Health Hazard: 1

Flammability: 0 Flammability: 0

Reactivity: 0 Reactivity: 0

Preparation information

Prepared by: Rockwell Labs Ltd

Version: 1.0

Revision Date: May 15, 2015

Reason for revision: none

Notice to Reader: The information provided in this Safety Data Sheet has been obtained from sources believed

to be reliable. Rockwell Labs Ltd provides no warranties, express or implied, and assumes no responsibility for

the accuracy and completeness of the data contained herein. The customer assumes all responsibility for safety

and use not in accordance with label instructions. The product names are trademarks of Rockwell Labs Ltd.

SAFETY DATA SHEET Martin’s Gopher Bait 50

Page 1 of 5

1. IDENTIFICATION

Product name: Martin’s Gopher Bait 50 Product type: Strychnine treated grain bait EPA Registration No.: 53883-23 Chemical name of active ingredient(s): Quinclorac: 3,7-dichloro-8-quinolinecarboxylic acid Manufacturer/Registrant: Control Solutions, Inc.

5903 Genoa-Red Bluff Pasadena, TX 77507

For fire, spill, and/or leak emergencies, contact Chemtrec: Phone: 1-800-424-9300 For medical emergencies and health and safety inquiries, contact Safety Call:

Phone: 1-866-897-8050

Poison Control Center Phone: 1-800-222-1222

2. HAZARDS IDENTIFICATIONS

OSHA HCS CLASSIFICATION (29 CFR 1910.1200)

Acute Toxicity:

Acute oral Acute dermal

Acute inhalation

Eye irritation

Skin irritation

Skin Sensitization

Category 4 NC NC 2B 2 1B

NC: Not classified

SIGNAL WORD: WARNING

HAZARD STATEMENTS:

- Harmful is swallowed Cause eye irritation

- Cause skin irritation

- May cause skin reaction

PICTOGRAM:

PRECAUTIONARY STATEMENTS:

- Wash hand thoroughly after handling. Do not eat, drink or smoke when using this product. Ifswallowed: Call a poison center or a doctor if you feel unwell. Rinse mouth.

- Wash hands thoroughly after handling. If in eyes: rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritationpersists: get medical advice.

- Wash hand thoroughly after handling. Wear protective gloves. If on skin: wash with plenty ofwater. If skin/irritation occurs: Get medical advice. Take off contaminated clothing and wash itbefore reuse.

- Avoid breathing dust, fume or gas. Contaminated work clothing must not be allowed out of theworkplace. Wear protective gloves. If on skin: wash with plenty of water. If skin irritation orrash occurs: get medical advice. Wash contaminated clothing before reuse.

Contact Safety Call® International for emergency medical treatment at (866) 897-8050.

Return to Index...


Page 2 of 5


COMMON NAME CAS NO. % OSHA PEL

ACGIH TLV OTHER

NTP/IARC/OSHA (Carcinogen)

Strychnine 57-24-9 0.5 0.15 mg/m3 NE NE NA Calcium carbonate (Limestone)

1317-65-3 1.34 15 mg/m3 NE NE NA

Grain Dust None >1% 10 mg/m3 NE NE NA NE=Not established; NA=Not applicable.


FIRST AID IF SWALLOWED: • Call a physician or poison control center immediately.

• If less than ten (10) minutes have passed since poison was taken, give1 or 2 glasses of water and induce vomiting by touching back of throat with finger. Repeat until vomit fluid is clear. Have patient lie down in quiet, darkened room and keep warm and quiet.

• If person is unconscious, do not give anything by mouth and do no induce vomiting.

• Do not give anything by mouth to an unconscious person. IF INHALED: • Remove victim to fresh air. If not breathing, give artificial respiration. Get

medical attention. IF IN EYES: • Hold eyelids open and flush with steady, gentle stream of water for 15 minutes.

Get medical attention. IF ON SKIN: • Wash with plenty of soap and water. Get medical attention. NOTE TO PHYSICIAN: (A) Administer 100% oxygen by positive pressure to provide as much pulmonary gas exchange as possible despite seizures. (B) Administer ANTICONVULASANT DRUGS intravenously to control convulsions. NOTICE: It may be difficult of impossible to stop the seizure activity without stopping respiration. Be prepared to maintain pulmonary ventilation mechanically. Tracheotomy may be necessary if seizures are prolonged.

Have the product container or label with you when calling a poison control center or doctor, or going for treatment. In case of a medical emergency call SafetyCall® at (866) 897-8050.


FLASH POINT: Non-flammable FLAMMABLE LIMITS: Not available. EXTINGUISHING MEDIA: Water spray, CO2, foam, dry chemical.

UNUSUAL FIRE, EXPLOSION HAZARDS: Not known.

FIRE-FIGHTING PROCEDURES: Wear full-faced self-contained breathing apparatus along with full protective gear.

HAZARDOUS DECOMPOSITION PRODUCTS: Only when heated.


ACTION TO TAKE FOR SPILLS/LEAKS: Do not allow bait to be exposed on soil surface. Do not contaminate water by cleaning of equipment or disposal of wastes. Sweep up all spilled bait carefully and bury.


PRECAUTIONS TO BE TAKEN IN HANDLING: Keep out of reach of children, pets and domestic animals. Convulsion poison. Poisonous if swallowed. This bait may cause an allergic reaction. Do not breathe dust. Do not get in eyes, on skin or on clothing. Do not contaminate feed and foodstuffs. Wash arms, hands and face with germicidal soap and Water after using and before eating or accepting anything by mouth or smoking. All spilled bait must be cleaned up immediately.


Page 3 of 5

PRECAUTIONS TO BE TAKEN IN STORAGE: Store in original container in a dry place inaccessible to children and pets, under lock and key. Do not store near heat or flame. Do not store near food or feeds. Do not stack pallets more than two (2) high.

STORAGE TEMPERATURE (MIN/MAX): Normal ambient temperatures.


THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION, PACKAGING AND USE OF THIS PRODUCT.

FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL.

SKIN PROTECTION: Long-sleeve shirt, long pants, shoes plus socks and rubber or water gloves.

EYE PROTECTION: Not required.

RESPIRATOR REQUIREMENTS: For most conditions, no respiratory protection required.

VENTILATION: Whenever possible, adequate ventilation should be used to minimize the need for personal protective equipment. Local exhaust required. Do not stand down wind.

ADDITIONAL PROTECTIVE MEASURES: Follow manufacturer’s instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry.

USER SAFETY RECOMMENDATIONS: Users Should:

• Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. • Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean

clothing. • Remove PPE immediately after handling this product. Wash the outside of gloves before

removing. As soon as possible, wash thoroughly and change into clean clothing.

EXPOSURE GUIDELINES: Refer to Section 3. ENGINEERING CONTROLS: Local exhaust required. Do not stand down wind.


APPEARANCE: Green colored, milo with crystalline-alkaloid coating ODOR: No odor pH: 6.95 (5% solution) FLASH POINT: Non-flammable SPECIFIC GRAVITY: 42 lbs./cu. ft. VISCOSITY: Not available


STABILITY: Stable under normal conditions. CONDITIONS TO AVOID: Spilling and heating. HAZARDOUS DECOMPOSITION PRODUCTS: Only when heated. HAZARDOUS POLYMERIZATION: May occur.


ACUTE TOXICITY/IRRITATION STUDIES: Acute Oral LD50 (Rat): 659 mg/kg (Highly toxic convulsive poison) Acute Dermal LD50 (Rabbit): > 2,000 mg/kg Acute Inhalation LC50 (Rat): None expected but dust may cause mild irritation of nasal mucous membranes. Eye Irritation: May cause irritation Skin Irritation: May cause irritation


Page 4 of 5

Dermal Sensitization: May cause an allergic reaction

REPRODUCTIVE/DEVELOPMENTAL EFFECTS: No information available

CHRONIC/SUBCHRONIC TOXICITY STUDIES: No information available

MUTAGENICITY: No information available


ENVIRONMENTAL HAZARDS: This product is toxic to fish, birds, and other wildlife. Do not allow bait to be exposed on soil surface. Do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water by cleaning of equipment disposal of wastes.

ECOTOXICITY: (Strychnine technical): Northern bobwhite quail 8-d NOEC: 3,536 ppm Mallard duck 8-day NOEC : 212 ppm Rainbow trout 96-h LC50 : 2.3 mg/L Bluegill sunfish 96-h LC50 : 0.76 mg/L Daphnia magna 48-h EC50 : 10 mg/L

ENVIRONMENTAL FATE: (Strychnine technical)

When released into the soil, this material has the potential to photolyze on soil surfaces. Volatilization and chemical hydrolysis are not expected to be important fate processes. When released into water, this material has the potential to photolyze. Volatilization, chemical hydrolysis and bioaccumulation in aquatic organisms are not expected.


PESTICIDE DISPOSAL: Pesticide, spray mixture or rinse water that cannot be used according to label instructions must be disposed of at or by an approved waste disposal facility.

CONTAINER DISPOSAL: Dispose of product containers, waste containers, and residues according to label instructions and local, state, and federal health and environmental regulations.


DOT CLASSIFICATION:

Not Regulated.

INTERNATIONAL TRANSPORTATION: Not Regulated.


FIFRA INFORMATION: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information for safety data sheet, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label.

POISON

DANGER Convulsive Poison. Fatal if swallowed if swallowed.

SARA TITLE III CLASSIFICATION: Section 302: Strychnine (CAS# 57-24-9) TPQ 100 lbs. (lower threshold); 10,000 lbs. TPQ (upper

thresh old) Section 311/312: Acute health hazard (immediate)

Chronic health hazard (delayed) Section 313: Strychnine (CAS# 57-24-9)

CA PROPOSITION 65: Not applicable


Page 5 of 5

CERCLA RQ: Strychnine (CAS# 57-24-9) RQ= 10 lbs. (4.54 kg)

RCRA CLASSIFICATION: Under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste.

TSCA STATUS: The ingredients of this product are listed on the TSCA inventory or are exempt.


HAZARD RATINGS NFPA HMIS HEALTH: 3 3 0 MINIMAL

FLAMMABILITY: 0 0 1 SLIGHT REACTIVITY: 0 0 2 MODERATE

3 HIGH 4 SEVERE

MSDS DATE: 2-28-2013. Supersedes version dated 12-06-2006. Changes made to all sections.

The information and recommendations contained herein are based upon data believed to be correct. However, no warranty of any kind, expressed or implied, is made with respect to the information contained herein.


MAXFORCE® FC MAGNUM ROACH KILLER BAIT GEL 1/9 Version 2.0 / USA Revision Date: 11/06/2014102000015432 Print Date: 11/06/2014


Product identifier

Trade name MAXFORCE® FC MAGNUM ROACH KILLER BAIT GEL


SDS Number 102000015432



Use Insecticide


Information on manufacturer

Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC 27709 United States



1-800-334-7577 (24 hours/day)


1-800-331-2867

SDS Information or Request [email protected]


Classification in accordance with regulation HCS 29CFR §1910.1200 This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Other hazards No particular hazards known.


Hazardous Component Name CAS-No. Concentration % by weight Fipronil 120068-37-3 0.05

Return to Index...


SAFETY DATA SHEET

MAXFORCE® FC MAGNUM ROACH KILLER BAIT GEL 2/9 Version 2.0 / USA Revision Date: 11/06/2014 102000015432 Print Date: 11/06/2014









Symptoms The following symptoms may occur:, Restlessness, Anxiety, Tremors


Treatment Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. There is no specific antidote.


Extinguishing media

Suitable Dry chemical, Foam, Water, Carbon dioxide (CO2)

Unsuitable None known. Special hazards arising from the substance or mixture

Dangerous gases are evolved in the event of a fire.



In the event of fire and/or explosion do not breathe fumes. Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing.

Further information Keep out of smoke. Fight fire from upwind position. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses.


SAFETY DATA SHEET


Flash point no data available


Lower explosion limit no data available

Upper explosion limit no data available

Explosivity

not applicable





Methods for cleaning up Collect and transfer the product into a properly labelled and tightly closed container. Clean contaminated floors and objects thoroughly, observing environmental regulations.





Advice on safe handling Product will stain porous surfaces. Use only in area provided with appropriate exhaust ventilation.


Do not use this product in or on electrical equipment due to the possibility of shock hazard.

Hygiene measures Remove Personal Protective Equipment (PPE) immediately after handling this product. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing.

Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics.



SAFETY DATA SHEET



Keep out of reach of children and animals. Keep away from direct sunlight. Keep containers tightly closed in a dry, cool and well-ventilated place.


Control parameters

Components CAS-No. Control parameters Update Basis Fipronil (Particulate.)

120068-37-3 50ug/m3 (ST ESL)

02 2013

TX ESL

Fipronil (Particulate.)

120068-37-3 5ug/m3 (AN ESL)

02 2013

TX ESL

Fipronil 120068-37-3 0.035 mg/m3 (TWA)

OES BCS*

Sucrose 57-50-1 10 mg/m3 (TWA)

02 2012

ACGIH

Sucrose (Respirable.)

57-50-1 5 mg/m3 (REL)

2010

NIOSH

Sucrose (Total)

57-50-1 10 mg/m3 (REL)

2010

NIOSH

Sucrose (Total dust.)

57-50-1 15 mg/m3 (PEL)

02 2006

OSHA Z1

Sucrose (Respirable fraction.)

57-50-1 5 mg/m3 (PEL)

02 2006

OSHA Z1


57-50-1 5 mg/m3 (TWA)

1989

OSHA Z1A


57-50-1 15 mg/m3 (TWA)

1989

OSHA Z1A


57-50-1 5 mg/m3 (TWA)

06 2008

TN OEL


57-50-1 15 mg/m3 (TWA)

06 2008

TN OEL

Sucrose (Particulate.)

57-50-1 50ug/m3 (ST ESL)

02 2013

TX ESL

Sucrose (Particulate.)

57-50-1 5ug/m3 (AN ESL)

02 2013

TX ESL

No control parameters known.


Exposure controls


Respiratory protection Respiratory protection is not required under anticipated circumstances of exposure.


SAFETY DATA SHEET



Eye protection Safety glasses with side-shields




Appearance light brown

Physical State gel

Odor characteristic


pH no data available



Specific Gravity no data available

Evapouration rate no data available

Boiling Point no data available Melting / Freezing Point no data available

Water solubility soluble

Minimum Ignition Energy not applicable


not applicable


not applicable

Viscosity 40,000 - 115,000 cps at 25 °C

Flash point no data available


Lower explosion limit no data available

Upper explosion limit no data available

Explosivity not applicable


SAFETY DATA SHEET



Reactivity

Thermal decomposition not applicable

Chemical stability Stable under normal conditions.


No dangerous reaction known under conditions of normal use.

Conditions to avoid Extremes of temperature and direct sunlight. Exposure to moisture.

Incompatible materials Strong oxidizing agents, Strong bases, Strong acids


No decomposition products expected under normal conditions of use.

SECTION 11: TOXICOLOGICAL INFORMATION Exposure routes Eye contact, Skin Absorption, Skin contact, Ingestion

Immediate Effects

Eye Moderate eye irritation.

Skin Harmful if absorbed through skin.



Acute inhalation toxicity no data available

Acute dermal toxicity LD50 (rat) > 5,000 mg/kg

Skin irritation Slight irritation (rabbit)

Eye irritation Minimally irritating. (rabbit)

Sensitisation Non-sensitizing. (guinea pig)


Fipronil caused specific target organ toxicity in experimental animal studies in the following organ(s): liver. Fipronil caused neurobehavioral effects and/or neuropathological changes in animal studies.

Assessment Mutagenicity

Fipronil was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.

Assessment Carcinogenicity

Fipronil caused an increased incidence of tumours in rats in the following organ(s): Thyroid. The mechanism that triggers tumours in rodents and the type of tumours observed are not relevant to humans.


SAFETY DATA SHEET


ACGIH

None.

NTP

None.

IARC

None.

OSHA

None.


Fipronil caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to the parent animals. The reproduction toxicity seen with Fipronil is related to parental toxicity.


Fipronil did not cause developmental toxicity in rats and rabbits.

Further information

Acute toxicity studies have been bridged from a similar formulation(s). Only acute toxicity studies have been performed on the formulated product.


Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)) 0.25 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient fipronil.


EC50 (Daphnia magna (Water flea)) 0.19 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient fipronil.

Toxicity to aquatic plants EC50 (Scenedesmus subspicatus) 0.068 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient fipronil.

Biodegradability Fipronil: ; not rapidly biodegradable

Koc Fipronil: Koc: 427 - 1278

Bioaccumulation Fipronil: Bioconcentration factor (BCF) 321; Does not bioaccumulate.

Mobility in soil Fipronil: Slightly mobile in soils

Environmental precautions Do not allow to get into surface water, drains and ground water. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Apply this product as specified on the label.


SAFETY DATA SHEET




Product It is best to use all of the product in accordance with label directions. If it is necessary to dispose of unused product, please follow container label instructions and applicable local guidelines.

Never place unused product down any indoor or outdoor drain.

Contaminated packaging Do not re-use empty containers. Place empty container in trash. Follow advice on product label and/or leaflet.

RCRA Information Characterization and proper disposal of this material as a special or hazardous waste is dependent upon Federal, State and local laws and are the user's responsibility. RCRA classification may apply.

SECTION 14: TRANSPORT INFORMATION According to national and international transport regulations this material is not classified as dangerous goods / hazardous material. SECTION 15: REGULATORY INFORMATION

EPA Registration No. 432-1460 US Federal RegulationsTSCA list None. US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section 302 - Notification and Information None. SARA Title III - Section 313 - Toxic Chemical Release Reporting None. US States Regulatory ReportingCA Prop65 This product does not contain any substances known to the State of California to cause cancer. This product does not contain any substances known to the State of California to cause reproductive harm. US State Right-To-Know Ingredients None. Canadian Regulations Canadian Domestic Substance List None.


SAFETY DATA SHEET


Environmental CERCLA None. Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None. EPA/FIFRA Information: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information required on the pesticide label: Signal word: Caution!

Hazard statements: Harmful if absorbed through skin.

Moderate eye irritation. Avoid contact with skin, eyes and clothing. Wash thoroughly with soap and water after handling.




0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Reason for Revision: Revised according to the current OSHA Hazard Communication Standard (29CFR1910.1200) Revision Date: 11/06/2014 This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer.


MAXFORCE® FLY SPOT BAIT 1/10 Version 1.0 / USA Revision Date: 08/15/2014102000027252 Print Date: 02/09/2015


Product identifier

Trade name MAXFORCE® FLY SPOT BAIT


SDS Number 102000027252



Use Insecticide






1-800-334-7577 (24 hours/day)


1-800-331-2867



Classification in accordance with regulation HCS 29CFR §1910.1200 This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Other hazards No particular hazards known.


Hazardous Component Name CAS-No. Concentration % by weight Imidacloprid 138261-41-3 10.00

Return to Index


SAFETY DATA SHEET

MAXFORCE® FLY SPOT BAIT 2/10 Version 1.0 / USA Revision Date: 08/15/2014 102000027252 Print Date: 02/09/2015









Symptoms If large amounts are ingested, the following symptoms may occur:

Dizziness, Abdominal pain, Nausea


Treatment There is no specific antidote. Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended.


Extinguishing media

Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable High volume water jet Special hazards arising from the substance or mixture

In the event of fire the following may be released:, Hydrogen chloride (HCl), Hydrogen cyanide (hydrocyanic acid), Carbon monoxide (CO), Nitrogen oxides (NOx)



In the event of fire and/or explosion do not breathe fumes. In the event of fire, wear self-contained breathing apparatus.

Further information Keep out of smoke. Fight fire from upwind position. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses.


SAFETY DATA SHEET



Autoignition temperature 345 °C / 653 °F



Explosivity

Not explosive 92/69/EEC, A.14 / OECD 113





Methods for cleaning up Avoid dust formation. Sweep up or vacuum up spillage and collect in suitable container for disposal. Clean contaminated floors and objects thoroughly, observing environmental regulations.





Advice on safe handling Use only in area provided with appropriate exhaust ventilation.

Hygiene measures Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics.




Store in a cool, dry place and in such a manner as to prevent cross contamination with other crop protection products, fertilizers, food, and feed. Store in original container and out of the reach of children, preferably in a locked storage area.


SAFETY DATA SHEET


Advice on common storage Keep away from food, drink and animal feedingstuffs.


Control parameters

Components CAS-No. Control parameters Update Basis Imidacloprid 138261-41-3 5ug/m3

(AN ESL) 07 2011

TX ESL

Imidacloprid 138261-41-3 50ug/m3 (ST ESL)

07 2011

TX ESL

Imidacloprid 138261-41-3 0.7 mg/m3 (TWA)

OES BCS*

Synthetic amorphous silica 112926-00-8 6 mg/m3 (REL)

2010

NIOSH

Synthetic amorphous silica 112926-00-8 6 mg/m3 (TWA)

1989

OSHA Z1A

Synthetic amorphous silica 112926-00-8 6 mg/m3 (TWA)

06 2008

TN OEL

Synthetic amorphous silica (Particulate.)

112926-00-8 2ug/m3 (AN ESL)

02 2013

TX ESL

Synthetic amorphous silica (Particulate.)

112926-00-8 27ug/m3 (ST ESL)

02 2013

TX ESL

Synthetic amorphous silica 112926-00-8 20millions of particles per cubic foot of air

(TWA)

2000

Z3

Synthetic amorphous silica 112926-00-8 0.8 mg/m3 (TWA)

2000

Z3

Sucrose 57-50-1 10 mg/m3 (TWA)

02 2012

ACGIH

Sucrose (Respirable.)

57-50-1 5 mg/m3 (REL)

2010

NIOSH

Sucrose (Total)

57-50-1 10 mg/m3 (REL)

2010

NIOSH


57-50-1 15 mg/m3 (PEL)

02 2006

OSHA Z1


57-50-1 5 mg/m3 (PEL)

02 2006

OSHA Z1


57-50-1 5 mg/m3 (TWA)

1989

OSHA Z1A


57-50-1 15 mg/m3 (TWA)

1989

OSHA Z1A


57-50-1 5 mg/m3 (TWA)

06 2008

TN OEL


57-50-1 15 mg/m3 (TWA)

06 2008

TN OEL

Sucrose 57-50-1 50ug/m3 02 2013 TX ESL


SAFETY DATA SHEET


(Particulate.) (ST ESL) Sucrose (Particulate.)

57-50-1 5ug/m3 (AN ESL)

02 2013

TX ESL


Exposure controls








Appearance white to beige

Physical State granular



pH 4.5 - 6.5 at 1 % (23 °C) (CIPAC D water (342ppm))



Specific Gravity no data available


Boiling Point not applicable

Melting / Freezing Point 181 °C / 357.8 °F

Water solubility dispersible



> 420 °C , Heating rate: 0.5 K/min


SAFETY DATA SHEET



no data available



Autoignition temperature 345 °C / 653 °F



Explosivity Not explosive 92/69/EEC, A.14 / OECD 113

Other information Further safety related physical-chemical data are not known.


Reactivity

Thermal decomposition > 420 °C, Heating rate: 0.5 K/min

Self heating not self-heating



No hazardous reactions when stored and handled according to prescribed instructions.

Conditions to avoid Extremes of temperature and direct sunlight.

Incompatible materials no data available



SECTION 11: TOXICOLOGICAL INFORMATION Exposure routes Ingestion, Skin contact, Eye contact

Immediate Effects

Eye May cause mild irritation to eyes.

Ingestion Harmful if swallowed.


Acute oral toxicity LD 50 cut-off (rat) > 5,000 mg/kg


SAFETY DATA SHEET


Acute inhalation toxicity ATE (rat) > 5 mg/l

Exposure time: 4 h calculated ATE – acute toxicity estimate

Acute dermal toxicity ATE (rat) > 5,000 mg/kg Calculation method ATE – acute toxicity estimate


Eye irritation Minimally irritating. (rabbit)

Sensitisation Non-sensitizing. (guinea pig) OECD Test Guideline 406, Magnusson & Kligman test


Imidacloprid did not cause specific target organ toxicity in experimental animal studies.


Imidacloprid was not mutagenic or genotoxic based on the overall weight of evidence in a battery of in vitro and in vivo tests.


Imidacloprid was not carcinogenic in lifetime feeding studies in rats and mice.

ACGIH

None.

NTP

None.

IARC

None.

OSHA

None.


Imidacloprid caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to the parent animals. The reproduction toxicity seen with Imidacloprid is related to parental toxicity.


Imidacloprid caused developmental toxicity only at dose levels toxic to the dams. The developmental effects seen with Imidacloprid are related to maternal toxicity.

Further information

Acute toxicity studies have been bridged from a similar formulation(s). The non-acute information pertains to the active ingredient(s).


SAFETY DATA SHEET



Toxicity to fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 211 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient imidacloprid.


EC50 (Water flea (Daphnia magna)) 85 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient imidacloprid.

EC10 (Chironomus riparius (non-biting midge)) 2,09 µg/l Exposure time: 28 d The value mentioned relates to the active ingredient imidacloprid.

Toxicity to aquatic plants EC50 (Desmodesmus subspicatus) > 10 mg/l Growth rate; Exposure time: 72 h The value mentioned relates to the active ingredient imidacloprid.

Biodegradability Not applicable for this mixture.

Bioaccumulation Not applicable for this mixture.

Mobility in soil Not applicable for this mixture.


No other effects to be mentioned.

Environmental precautions Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Do not apply this product or allow it to drift to blooming crops or weeds if bees are visiting the treatment area. Apply this product as specified on the label.



Product Pesticide, spray mixture or rinse water that cannot be used according to label instructions may be disposed of on site or at an approved waste disposal facility.

Contaminated packaging Do not re-use empty containers. Completely empty container into application equipment, then dispose of

empty container in a sanitary landfill, by incineration or by other procedures approved by state/provincial and local authorities.

If burned, stay out of smoke. Follow advice on product label and/or leaflet.


SAFETY DATA SHEET


RCRA Information Characterization and proper disposal of this material as a special or

hazardous waste is dependent upon Federal, State and local laws and are the user's responsibility. RCRA classification may apply.


N.O.S. (IMIDACLOPRID MIXTURE) IATA UN number 3077 Class 9 Packaging group III Environm. Hazardous Mark YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,

N.O.S. (IMIDACLOPRID MIXTURE ) This transportation information is not intended to convey all specific regulatory information relating to this product. It does not address regulatory variations due to package size or special transportation requirements. SECTION 15: REGULATORY INFORMATION

EPA Registration No. 432-1455 US Federal RegulationsTSCA list None. US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section 302 - Notification and Information None. SARA Title III - Section 313 - Toxic Chemical Release Reporting None. US States Regulatory ReportingCA Prop65 This product does not contain any substances known to the State of California to cause cancer. This product does not contain any substances known to the State of California to cause


SAFETY DATA SHEET


reproductive harm. US State Right-To-Know Ingredients None. Canadian Regulations Canadian Domestic Substance List None. Environmental CERCLA None. Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None. EPA/FIFRA Information: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information required on the pesticide label: Signal word: Caution!

Hazard statements: Harmful if swallowed.





0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Reason for Revision: New Safety Data Sheet. Revision Date: 08/15/2014 This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer.


MAXFORCE® GRANULAR FLY BAIT 1/10 Version 1.0 / USA Revision Date: 09/05/2014102000027208 Print Date: 02/09/2015


Product identifier

Trade name MAXFORCE® GRANULAR FLY BAIT


SDS Number 102000027208



Use Insecticide






1-800-334-7577 (24 hours/day)


1-800-331-2867



Classification in accordance with regulation HCS 29CFR §1910.1200 This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Other hazards Dust may form explosive mixture in air.


Hazardous Component Name CAS-No. Concentration % by weight Imidacloprid 138261-41-3 0.50 2,6-Di-tert-butyl-4-methylphenol 128-37-0 >=0.10 – <0.25

Return to Index


SAFETY DATA SHEET

MAXFORCE® GRANULAR FLY BAIT 2/10 Version 1.0 / USA Revision Date: 09/05/2014 102000027208 Print Date: 02/09/2015









Symptoms If large amounts are ingested, the following symptoms may occur:

Dizziness, Abdominal pain, Nausea

Symptoms and hazards refer to effects observed after intake of significant amounts of the active ingredient(s).


Treatment There is no specific antidote. Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended.


Extinguishing media

Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable High volume water jet Special hazards arising from the substance or mixture

Dangerous gases are evolved in the event of a fire.



Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing.


SAFETY DATA SHEET


Further information Keep out of smoke. Fight fire from upwind position. Do not allow run-off

from fire fighting to enter drains or water courses.





Explosivity

no data available



Precautions Keep unauthorized people away. Isolate hazard area. Avoid dust formation. Avoid contact with spilled product or contaminated surfaces.


Methods for cleaning up Avoid dust formation. Use mechanical handling equipment. Clean contaminated floors and objects thoroughly, observing environmental regulations. Keep in suitable, closed containers for disposal.




Advice on safe handling Avoid dust formation. Use only in area provided with appropriate exhaust ventilation. For personal protection see section 8.


Dust may form explosive mixture in air. Take measures to prevent the build up of electrostatic charge. Keep away from heat and sources of ignition.

Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics.




SAFETY DATA SHEET



Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a place accessible by authorized persons only. Keep away from direct sunlight.


Control parameters

Components CAS-No. Control parameters Update Basis Imidacloprid 138261-41-3 5ug/m3

(AN ESL) 07 2011

TX ESL

Imidacloprid 138261-41-3 50ug/m3 (ST ESL)

07 2011

TX ESL

Imidacloprid 138261-41-3 0.7 mg/m3 (TWA)

OES BCS*

2,6-Di-tert-butyl-4-methylphenol (Inhalable fraction and vapor.)

128-37-0 2 mg/m3 (TWA)

02 2012

ACGIH

2,6-Di-tert-butyl-4-methylphenol

128-37-0 10 mg/m3 (REL)

2010

NIOSH


128-37-0 10 mg/m3 (TWA)

1989

OSHA Z1A


128-37-0 10 mg/m3 (TWA)

06 2008

TN OEL

2,6-Di-tert-butyl-4-methylphenol (Particulate.)

128-37-0 50ug/m3 (ST ESL)

02 2013

TX ESL

2,6-Di-tert-butyl-4-methylphenol (Particulate.)

128-37-0 5ug/m3 (AN ESL)

02 2013

TX ESL


128-37-0 10 mg/m3 (TWA PEL)

02 2012

US CA OEL


Exposure controls






SAFETY DATA SHEET





Appearance light red

Physical State granular



pH 5.5 - 6.5 at 1 % (23 °C) (deionized water)




Boiling Point not applicable Melting / Freezing Point 180 - 182 °C / 356 - 359.6 °F



no data available


not applicable






Explosivity no data available

Other information Further safety related physical-chemical data are not known.


Reactivity

Thermal decomposition no data available



SAFETY DATA SHEET



No hazardous reactions when stored and handled according to prescribed instructions.

Conditions to avoid Extremes of temperature and direct sunlight.

Incompatible materials Store only in the original container.



SECTION 11: TOXICOLOGICAL INFORMATION Exposure routes Eye contact, Skin contact, Inhalation, Ingestion

Immediate Effects

Eye Causes eye irritation.

Skin May cause slight irritation. Harmful if absorbed through skin.

Ingestion Harmful if swallowed.

Inhalation Harmful if inhaled.



Acute inhalation toxicity no data available

During intended and foreseen applications, no respirable aerosol is formed.

Acute dermal toxicity LD50 (rat) > 2,000 mg/kg


Eye irritation No eye irritation (rabbit)

Sensitisation Non-sensitizing. (guinea pig) OECD Test Guideline 406, Magnusson & Kligman test


Imidacloprid did not cause specific target organ toxicity in experimental animal studies.


Imidacloprid was not mutagenic or genotoxic based on the overall weight of evidence in a battery of in vitro and in vivo tests.


Imidacloprid was not carcinogenic in lifetime feeding studies in rats and mice.

ACGIH

2,6-Di-tert-butyl-4-methylphenol 128-37-0 Group A4


SAFETY DATA SHEET


NTP

None.

IARC

2,6-Di-tert-butyl-4-methylphenol 128-37-0 Overall evaluation: 3

OSHA

None.


Imidacloprid caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to the parent animals. The reproduction toxicity seen with Imidacloprid is related to parental toxicity.


Imidacloprid caused developmental toxicity only at dose levels toxic to the dams. The developmental effects seen with Imidacloprid are related to maternal toxicity.

Further information

Only acute toxicity studies have been performed on the formulated product. The non-acute information pertains to the active ingredient(s).


Toxicity to fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 211 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient imidacloprid.


EC50 (Water flea (Daphnia magna)) 85 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient imidacloprid.

EC10 (Chironomus riparius (non-biting midge)) 2,09 µg/l Exposure time: 28 d The value mentioned relates to the active ingredient imidacloprid.

Toxicity to aquatic plants EC50 (Desmodesmus subspicatus) > 10 mg/l Growth rate; Exposure time: 72 h The value mentioned relates to the active ingredient imidacloprid.

Biodegradability Imidacloprid: ; not rapidly biodegradable

Koc Imidacloprid: Koc: 225

Bioaccumulation Imidacloprid: ; Does not bioaccumulate.

Mobility in soil Imidacloprid: Moderately mobile in soils


No other effects to be mentioned.


SAFETY DATA SHEET


Environmental precautions Do not allow to get into surface water, drains and ground water.



Product Dispose in accordance with all local, state/provincial and federal regulations.

Contaminated packaging Do not re-use empty packagings. Completely empty container into application equipment, then dispose of

empty container in a sanitary landfill, by incineration or by other procedures approved by state/provincial and local authorities.

If burned, stay out of smoke. Follow advice on product label and/or leaflet.

RCRA Information Characterization and proper disposal of this material as a special or hazardous waste is dependent upon Federal, State and local laws and are the user's responsibility. RCRA classification may apply.


N.O.S. (IMIDACLOPRID MIXTURE) IATA UN number 3077 Class 9 Packaging group III Environm. Hazardous Mark YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,

N.O.S. (IMIDACLOPRID MIXTURE ) This transportation information is not intended to convey all specific regulatory information relating to this product. It does not address regulatory variations due to package size or special transportation requirements. Freight Classification: INSECTICIDES OR FUNGICIDES, N.O.I., OTHER THAN

POISON


SAFETY DATA SHEET


SECTION 15: REGULATORY INFORMATION

EPA Registration No. 432-1375 US Federal RegulationsTSCA list 2,6-Di-tert-butyl-4-methylphenol 128-37-0 US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section 302 - Notification and Information None. SARA Title III - Section 313 - Toxic Chemical Release Reporting None. US States Regulatory ReportingCA Prop65 This product does not contain any substances known to the State of California to cause cancer. This product does not contain any substances known to the State of California to cause reproductive harm. US State Right-To-Know Ingredients 2,6-Di-tert-butyl-4-methylphenol 128-37-0 CA, MN Canadian Regulations Canadian Domestic Substance List None. Environmental CERCLA None. Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None. EPA/FIFRA Information: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information required on the pesticide label: Signal word: Caution!

Hazard statements: Harmful if swallowed, inhaled or absorbed through the skin.



SAFETY DATA SHEET





0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Reason for Revision: New Safety Data Sheet. Revision Date: 09/05/2014 This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer.

Return to Index

For the control of crickets, cockroaches, silverfish, ants (except fire ants) and earwigs. FOR BOTH INTERIOR AND EXTERIOR USE

ACTIVE INGREDIENT: Orthoboric Acid ..................................................... 5.0% OTHER INGREDIENTS ........................................ 95.0% TOTAL ................................................................. 100.0%

EPA Reg. No. 64405-2 EPA Est. 64405-TN-1

PRECAUTIONARY STATEMENTS Hazards to Humans & Domestic Animals

CAUTION: Harmful if absorbed through skin. Causes moderate eye irritation. Avoid contact with skin, eyes or clothing.

Personal Protective EquipmenT (PPE) Applicators and handlers must wear: Long-sleeved shirt and long pants; waterproof gloves; and shoes plus socks. Follow manufacturer’s instructions for cleaning/ maintaining PPE. If no such instructions for washables are given, use detergent and hot water.

User Safety Recommendations Users should: • Wash hands before eating, drinking, chewing gum, using

tobacco or using the toilet. • Remove clothing immediately if pesticide gets inside;

then thoroughly wash and put on clean clothing. • Immediately remove PPE after handling this product.

Wash the outside of gloves before removing. As soon as possible, thoroughly wash and change into clean clothing.

Environmental Hazards Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwaters or rinsate.

DIRECTIONS FOR USE It is a violation of Federal law to use this product in a

manner inconsistent with its labeling.

General Information This product is a ready-to-use, weather/moisture resistant bait that controls and kills ants (except fire ants), cock-roaches, crickets, earwigs and silverfish specifically: Ants: Argentine, carpenter, thief, pharaoh, little black, pavement, odorous house and crazy ants. Cockroaches: Asian, American, brown, brown-banded, smokybrown, German and oriental cockroaches. Crickets: Camel, house, field and mole crickets. European Earwigs. Do not contaminate this product with other pesticides. If this product becomes contaminated with another pesticide it will lose its effectiveness. Do not apply directly to food and avoid contamination of feed and foodstuff. In commercial food handling facilities, cover or remove any food during application. In food handling and other areas, bait may be placed in removable bait stations. Always record the number and location of bait stations. This product is designed to be used as a residual treatment in an Integrated Pest Management program incorporating good sanitation practices. This product may be applied in appropriate areas with a power duster (except in California). Consult equipment manufacturer for recom-mended settings. Keep children and pets out of treatment area until application has been completed. Do not treat pets with this product. Avoid over-application around ornamental plants and fish ponds. Do not apply this product in combination with fertilizers, other pesticides or other biologically-active materials.

Application Instructions Exterior Baiting to Control and Kill Ants (Except Fire Ants), Including Carpenter Ants, Around Apartment Buildings, Food Processing Plants, Garages, Homes, Hospitals, Hotels, Kennels, Motels, Pet Stores, Public

First Aid

If in Eyes

• Hold eye open and rinse slowly and gently with water for 15 - 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes.

• Call a poison control center or doctor for treatment advice.

If on Skin

• Take off contaminated clothing. • Immediately rinse with plenty of water for

15 – 20 minutes. • Call a poison control center or doctor for

treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. You may also contact 1-800-424-9300 for emergency medical treatment information.

KEEP OUT OF REACH OF CHILDREN CAUTION

& Private Institutions, Recreational Vehicles, Res-taurants, Schools, Supermarkets and Warehouses: Treat exterior perimeter areas of structure in a band 2 to 4 feet wide at a rate of 6 ounces per 100 square feet. Also apply product in a 2- to 4-foot band around all trees, stumps, firewood piles and other locations where car-penter ants may nest. If the nest is located in a hollow tree or stump, apply 1/2 to 1 ounce of product directly into the cavity. Apply along ant trails and in areas where ant activity has been noted. To Control and Kill Ants (Except Fire Ants), Cock-roaches, Crickets, Earwigs and Silverfish Within and Around the Exterior of Structures Such as Apartment Buildings, Food Processing Plants (Non-Food Areas), Garages, Homes, Hospitals, Hotels, Kennels, Motels, Pet Stores, Public & Private Institutions, Recreational Vehicles, Restaurants (Non-Food Areas), Schools, Sewers, Stores, Supermarkets and Warehouses: Apply at a rate of 6 ounces or 1 1/4 cups per 100 square feet of surface area. Spread evenly in crawl spaces, attics, drop ceilings and cellars with dirt or gravel floors. Concentrate application in areas where insect activity is most prevalent. In attics, be sure to apply in eaves and access drains. In warehouses, garages and basements, concentrate appli-cation along walls and baseboards. This product may also be applied in inaccessible areas such as cracks and crevices where insects may hide. Any bait visible after application must be brushed into cracks and crevices or removed. Apply in pits of elevator, dumbwaiter and trash chute shafts. Apply under and behind pallets and boxes in storerooms. Bait may also be placed in removable bait stations in areas accessible to insects but inaccessible to children and pets. Always record the location and number of bait stations. Regularly inspect bait stations and replace bait as needed. In sewers, apply along ledges and around manhole entrances. Treat exterior perimeter building walls in a band approximately 2 feet wide and scatter bait in flower beds, leaf litter, wood piles, trash cans and refuse areas. Reapply as necessary. To Control and Kill Ants (Except Fire Ants), Cockroaches, Crickets, Earwigs and Silverfish in Aircraft, Apartment Buildings, Boats, Buses, Fac-tories, Food Handling Establishments, Food Pro-cessing Plants, Garages, Grocery Stores, Homes, Hospitals, Hotels, Industrial Plants, Kennels, Libraries, Markets, Military Bases, Mobile Homes, Motels, New Construction, Nursing Homes, Offices, Pet Stores, Private & Public Institutions, Recreational Vehicles, Restaurants, Schools, Sewers, Ships, Supermarkets, Theaters, Trains, Trucks, Utilities, Warehouses, Yachts, and Zoos: Food area application limited to only crack and crevice treatment. Apply only in areas inaccessible to children and pets. Avoid contamination of feed and foodstuffs. Apply by scattering/dusting under and behind refrigerator, cooler, stove, sink, dishwasher, washing machine and dryer tubs; counters; into openings around drains, water pipes and electrical conduits; and in cracks and crevices along baseboards and corners of cabinets, counter tops, cupboards, and closets. Remove all lower drawers in kitchen and bathroom cabinets,

bedroom dressers and chests of drawers, then scatter/dust in drawer wells. Bait may also be applied into and around areas of insect infestation of above-ground trans-formers, in-ground utility boxes, pedestal boxes and vending machines. Any bait visible after application must be brushed into cracks and crevices or removed. Reapply as necessary. Bait may also be placed in removable bait stations in areas accessible to insects but inaccessible to children and pets. Always record the location and number of bait stations. Regularly inspect bait stations and replace bait as needed. Crack and Crevice Applications in Aircraft, Apartment Buildings, Boats, Buses, Factories, Food Handling Establishments, Food Processing Plants, Garages, Grocery Stores, Homes, Hospitals, Hotels, Industrial Plants, Kennels, Libraries, Markets, Military Bases, Mobile Homes, Motels, New Construction, Nursing Homes, Offices, Pet Stores, Private & Public Institu-tions, Recreational Vehicles, Restaurants, Schools, Sewers, Ships, Supermarkets, Thea-ters, Trains, Trucks, Utilities, Warehouses, Yachts and Zoos: Crack and crevice applications may be made using most types of dust applicators. A bellows type duster works best. Insert stem into gaps, cracks and crevices and apply 2 to 6 puffs per lineal foot, depending upon the severity of the infestation. Any bait visible after application must be brushed into cracks and crevices or removed. Drill small holes to gain access into wall voids and under cabinets. This product may also be applied in appropriate areas with a power duster (except in California). Consult equipment manufacturer for recommended settings. Application Sites and Directions: 1. Apply under and behind appliances in kitchens,

bathrooms and utility rooms (remove kick plates if possible).

2. Kitchen and bathroom cabinets and vanities often have a space between the floor and the bottom drawer or cabinet. If a gap exists along the top of the kickplate, dust this product into the void area. If no gaps are present, drill a small hole every two feet along the kickplate, drilling at least one hole under each cabinet, and apply this product through the holes.

3. Apply in voids around plumbing pipes behind water heaters and under sinks in kitchens, bath-rooms, showers and utility rooms. Pull back escutcheon plates around pipes to allow access to the void.

4. Remove electrical wall socket and switch covers and dust product around boxes and into voids. Do not apply product directly into electrical switch and outlet boxes.

5. Cracks or spaces between the wall and doorframes, cabinets, counter tops, molding or baseboards provide excellent hiding places for roaches and ants. Dust a small amount of this product into these areas wherever possible.

6. Apply under and behind vending machines. If access can be gained to the interior of the machine, apply around the interior base, being careful not to contaminate any foodstuffs.

To Control and Kill Cockroaches, Crickets, Ants, Earwigs and Silverfish in Federally-Inspected (USDA)

Meat and Poultry Plants: For application only in inedible product areas and non-processing areas as a crack and crevice treatment. Apply to cracks and crevices in areas such as around base-boards and in closets; beneath cabinets and appliances, in and around waste containers and into openings around drains, water pipes and electrical conduits. Any bait visible after application must be brushed into cracks and crevices or removed. Avoid contamination of feed and food stuffs. Bait stations may be used. Always record the number and location of bait stations. Regularly inspect bait stations and replace bait as needed. This product is best used as a supplemental residual treatment preceded by approved spray and good sanitation practices.

STORAGE AND DISPOSAL Do not contaminate water, food or feed

by storage or disposal. Pesticide Storage: Store in a dry place. Do not store where children or animals may gain access. Pesticide Disposal: Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Container Disposal: Non-refillable container; do not reuse or refill this container. Completely empty container then offer for recycling, if available; otherwise dispose of empty container in a sanitary landfill or by incineration.

WARRANTY DISCLAIMER To the extent not prohibited by applicable law, Manu-facturer warrants that this product conforms to the chemical description on the label and is reasonably fit for the purposes stated on the label when used in strict accordance with the directions, subject to the inherent risks set forth below. To the extent not prohibited by applicable law, MANUFACTURER MAKES NO OTHER EXPRESS OR IMPLIED WARRANTY OF MERCHANT-ABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER EXPRESS OR IMPLIED WARRANTY.

Inherent Risks of Use The directions for use are believed to be adequate and must be carefully followed. It is impossible to eliminate all

risks associated with use of this product. Lack of performance or other unintended consequences may result because of such factors as use of the product contrary to label instructions, abnormal conditions, the presence of other materials, climatic conditions or the manner of application, all of which are beyond the control of the Manufacturer. To the extent not prohibited by applicable law, the buyer/user assumes all such risks.

Limitation of Remedies To the extent not prohibited by applicable law the exclusive remedy for losses or damages resulting from this product (including claims based on contract, negligence, strict liability or other legal theories) shall be limited to, at Manufacturer’s election, one of the following:

1. Refund of purchase price paid by buyer or user for product bought, or

2. Replacement of amount of product used. To the extent not prohibited by applicable law: a) Manufacturer shall not be liable for losses or damages resulting from handling or use of this product unless Manufacturer is promptly notified of such loss or damage in writing; and b) TO THE EXTENT NOT PROHIBITED BY APPLICABLE LAW, IN NO CASE SHALL MANUFAC-TURER BE LIABLE FOR CONSEQUENTIAL OR INCI-DENTAL DAMAGES OR LOSSES, INCLUDING WITHOUT LIMIT, HEALTH RELATED DAMAGES OR INJURIES. The terms of this Warranty Disclaimer and Limitation of Remedies cannot be varied by any written or verbal statements or agreements. No employee or sales agent of Manufacturer or the seller is authorized to vary or exceed the terms of this Warranty Disclaimer or Limitation of Remedies in any manner. It is not intended that this product be used to practice any applicable patent, whether mentioned or not, without pro-curement of a license, if necessary, from the owner, following investigation by the user.

100 Nisus Drive • Rockford, TN 37853 • (800) 264-0870

Niban-FG and Nisus Corporation are trademarks or registered trademarks of Nisus Corporation. ©2015 Nisus Corporation #NFG- SL-0315a-SAL020515

SAFETY DATA SHEET

Health Emergencies: INFOTRAC® (800) 535-5053

1. PRODUCT AND COMPANY INFORMATION Product Identity: Niban-FG® Fine Granular Bait Recommended use of the chemical and restrictions on use: A weather/moisture resistant bait to kill and control ants (except fire ants), carpenter ants, cockroaches, crickets, mole crickets, earwigs, silverfish, snails, and slugs. Read and understand the entire label before using. Use only according to label directions. It is a violation of Federal law to use this product in a manner inconsistent to label directions. Manufacturer: Nisus Corporation 100 Nisus Drive Rockford, TN 37853 Telephone: Phone: (800) 264-0870 Fax: (865) 577-5825 Emergency Phone: 800-535-5053 (INFOTRAC) SDS Date of Preparation: 01/12/16

2. HAZARDS IDENTIFICATION GHS Classification:

Physical Health Environment

Not Hazardous

Acute Toxicity Oral Category 4 Specific Target Organ Toxicity – Repeat Exposure Category 2

Aquatic Acute Toxicity Category 3

GHS Label Elements: TE None Required Statements of Hazard Precautionary Statements None Required None Required


Component CAS No. Amount

Boric Acid 10043-35-3 5%

Non-Hazardous Ingredient Proprietary 95%

The exact formulation is being withheld as a trade secret.

4. FIRST AID MEASURES Eye: Flush victim's eyes with large quantities of water, while holding the eyelids apart. Get medical attention if irritation develops or persists. Skin: Wash skin thoroughly with soap and water. Get medical attention if irritation develops. Remove and launder clothing before re-use. Ingestion: Do not induce vomiting unless directed to do so by a medical professional. Get medical attention for large ingestions or if symptoms develop or if you feel unwell. Inhalation: Remove victim to fresh air. If breathing is difficult or irritation persists, get medical attention. Most important Symptoms: May cause eye and skin irritation. Inhalation of dust may cause mild mucous membrane and respiratory irritation. Harmful if swallowed. Repeated ingestion may cause kidney damage. Indication of immediate medical attention/special treatment: Immediate medical attention is required for large ingestions.

5. FIRE FIGHTING MEASURES Suitable (and Unsuitable) Extinguishing Media: Use media appropriate for surrounding fire. Specific hazards arising from the chemical: Fine particles may present an explosion hazard if suspended in air. Burning may produce carbon monoxide and carbon dioxide.

Special Protective Equipment and Precautions for Fire-Fighting Instructions: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing. Contain runoff.

6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment, and Emergency Procedures: Wear appropriate protective clothing as described in Section 8. Do not apply directly to water or contaminate water. Methods and Materials for Containment and Cleaning Up: Collect and place in appropriate containers for disposal. Avoid generating dust. Clean spill area thoroughly. Prevent spill from entering sewers and watercourses. Report releases as required by local, state and federal authorities.

7. HANDLING AND STORAGE Precautions for Safe Handling: Avoid contact with the eyes, skin and clothing. Avoid breathing dusts. Wear protective clothing and equipment as described in Section 8. Wash thoroughly with soap and water after handling. Remove contaminated clothing immediately and wash before reuse. Remove PPE immediately after handling. Wash thoroughly after using and change into clean clothing. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. Keep containers closed when not in use. Refer product label for additional information on use and handling. Nonrefillable container. Do not reuse containers. Product residues in empty containers can be hazardous. Follow all SDS precautions when handling empty containers. Conditions for Safe Storage, Including Any Incompatibilities: Store in a dry area away from incompatible materials. Do not store where children or animals may gain access.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines:

Boric Acid 2 mg/m3 TWA ACGIH TLV (inhalable) 6 mg/m3 STEL ACGIH TLV (inhalable)

Engineering Controls: Use with adequate ventilation to maintain exposure levels below the occupational exposure limits. Refer product label for additional information. Respiratory Protection: In operations where exposure levels are exceeded, a NIOSH approved respirator with dust/mist cartridges appropriate for the form and concentration of the contaminants should be used. Selection and use of respiratory equipment must be in accordance with OSHA 1910.134 and good industrial hygiene practice. Refer to the product label for additional information. Skin Protection: Use gloves for normal application of this product. Eye Protection: Wear safety glasses to prevent eye contact. Other: Wear long-sleeve shirts, long pants, socks and shoes when using this product. Suitable washing facilities should be available in the work area.

9. PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Brown, granular particles with no odor. Physical State: Granular particles Odor Threshold: Not established Vapor Density: Not determined Initial Boiling Point/Range: Not determined Solubility In Water: Not soluble Vapor Pressure: Negligible Relative Density: 0.62 of water Evaporation Rate: N/A Melting/Freezing Point: N/A pH: N/A Percent Volatile: Minimal Octanol/Water Coefficient: N/A Solubility: Not soluble Decomposition Temperature: N/A Viscosity: N/A Flammability (solid, gas): Fine dust may form explosive mixtures in air Flashpoint: >451°F (233°C) TOC Autoignition Temperature: None Flammable Limits: LEL: Not determined UEL: N/A

10. STABILITY AND REACTIVITY Reactivity: Not normally reactive Chemical Stability: Stable under normal storage and handling conditions. Possibility of Hazardous Reactions: None known. Conditions to Avoid: Avoid generating fine dust. Incompatible Materials: None known Hazardous Decomposition Products: When heated to decomposition emits carbon monoxide and carbon dioxide.

11. TOXICOLOGICAL INFORMATION HEALTH HAZARDS: Ingestion: May be harmful if large quantities are ingested. Inhalation: Inhalation of dust may cause irritation of the nose, throat and upper respiratory tract. Eye: May cause slight irritation. Skin: Not expected to cause irritation. Chronic: Borates have been shown to have some chronic toxicity in animals fed high doses, but this has not been found in humans. Sensitization: This material is not expected to cause sensitization. Carcinogenicity: None of the components is listed as a carcinogen or suspected carcinogen by IARC, NTP or OSHA. Germ Cell Mutagenicity: No data available Reproductive Toxicity: Borates have been found to have some reproductive toxicity in animals, but this has not been found in humans. Numerical Measures of Toxicity: Product Toxicity Data: Oral rat LD50: >5000 mg/kg; Dermal rabbit LC50: >5050 mg/kg

12. ECOLOGICAL INFORMATION This product breaks down naturally in the environment to provide organic matter and boron micro nutrients. Boron occurs naturally in sea water at an average concentration of 5 mg B/l and fresh water at 1 mg B/l or less. In dilute aqueous solutions the predominant boron species present is undissociated boric acid. Ecotoxicity: EC10 Green Algae: 24 mg B/l; LC50 Daphnia magna: 530 mg B/l/96 hr; LC50 Dab: 74 mg B/l/48hr; LC50 Rainbow Trout: 88 mg B/l/24hr; LC50 Goldfish: 71 mg B/l/72hr Persistence and Degradability: Boron is naturally occurring and ubiquitous in the environment. Niban-FG decomposes in the environment to natural borate. Bioaccumulative Potential: Not determined. Mobility in Soil: Boric acid is soluble in water and is leachable through normal soil. Other Adverse Effects: Some plants are sensitive to boron. This product is designed to be used for certain types of insects. Use product only as directed on the label. See product label for full instructions and restrictions on use.

13. DISPOSAL CONSIDERATION Dispose in accordance with local, state and federal environmental regulations. Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high-water mark. Do not contaminate water when disposing of equipment washwaters or rinsate. Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Non-refillable container: do not reuse or refill this container. Completely empty container into application equipment, then offer for recycling, if available; otherwise dispose of empty container in a sanitary landfill or by incineration. For guidance contact your state water board or regional office of the EPA.

14. TRANSPORTATION INFORMATION DOT Hazardous Materials Description: Not Regulated Sea Transport IMDG, not classified as dangerous Air Trasnport IATA/ICAO, not classified as dangerous

15. REGULATORY INFORMATION This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. FIFRA Labeling:

Niban-FG Fine Granular Bait EPA Reg. No. 64405-2

Keep Out of Reach of Children CAUTION

PRECAUTIONARY STATEMENTS Hazards to Humans & Domestic Animals

Caution: Harmful if absorbed through skin. Causes moderate eye irritation. Avoid contact with skin, eyes or clothing. CERCLA: This product is not subject to reporting under CERCLA. Some states have more stringent reporting requirements. Report all spills in accordance with local, state, and federal regulations. SARA Hazard Category (311/312): Not hazardous SARA 313: This product contains the following chemicals subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): None EPA TSCA Inventory: This product is regulated under FIFRA, thus exempt.

16. OTHER INFORMATION NFPA Rating: Health = 0 Flammability = 0 Instability = 0 HMIS Rating: Health = 1 Flammability = 0 Physical Hazard = 0 SDS Revision History: 01/07/14: New SDS 01/12/16: Revised

WARRANTY DISCLAIMER The information, data and recommendations contained herein are believed to be accurate but may not be all inclusive and should only be used as a guide. The information is furnished upon the condition that the person receiving it shall make his own determination of the suitability of the product for his particular use and on condition that they assume the risk of the use thereof. With respect to this publication and the product related thereto, unless otherwise expressly provided by Manufacturer in writing, MANUFACTURER MAKES NO EXPRESS OR IMPLIED WARRANTY OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER EXPRESS OR IMPLIED WARRANTY.

Remedy/Liability Limits The exclusive remedy for losses or damages resulting from this publication or the related product (including claims based on contract, negligence, strict liability or other legal theories) shall be limited to, at Manufacturer’s sole election, one of the following:


2. Replacement of amount of product used. Manufacturer shall not be liable for losses or damages resulting from use of this publication or handling or use of this product, IN NO CASE SHALL MANUFACTURER BE LIABLE FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OR LOSSES, INCLUDING WITHOUT LIMIT, HEALTH RELATED DAMAGES OR INJURIES. The terms of this Warranty Disclaimer and Remedy/Liability Limits cannot be varied by any written or verbal statements or agreements. No employee or sales agent of Manufacturer or the seller is authorized to vary or exceed the terms of this Warranty Disclaimer or Limitation of Remedies in any manner.

100 Nisus Drive • Rockford, TN 37853 USA • (800) 264-0870

Niban-FG and Nisus Corporation are registered trademarks of Nisus Corporation. ©2016 Nisus Corporation• #NB-SDS-011216a

SAFETY DATA SHEET

Issue Date: 22-Sep-2015 Revision Date: 22-Sep-2015 Version: 1


Product identifier Product Name: Onslaught® FastCap Spider & Scorpion InsecticideEPA Registration Number: 1021-2574

Other means of identification Part Code: 2964

Recommended use of the chemical and restrictions on use: Recommended Use: Insecticide.


Telephone Number: (800) 645-6466, or (763) 544-0341e-Mail Address: [email protected]

Emergency telephone numbers: 24 Hour TRANSPORTATION Emergency: CHEMTREC®: (800) 424-9300International: (703) 527-3887

24 Hour MEDICAL Emergency: SafetyCall®: (888) 740-8712, or (952) 852-9509

Comments: MGK® Hours of operation are 8:00 am to 4:30 pm CST, 14:00 to 22:30 GMT.For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day to(888) 740-8712, or (952) 852-9509.


Classification

OSHA Regulatory Status:This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).

Acute toxicity - Oral Category 4Acute toxicity - Inhalation (Dusts/Mists) Category 4Skin corrosion/irritation Category 2

Label elements Emergency Overview

Manufacturer Address:McLaughlin Gormley King Company8810 10th Avenue NorthMinneapolis, MN 55427

_____________________________________________________________________________________________

FAX #:(763) 544-6437

WARNING

Page 1 / 9

Hazard statements

Return to Index...

_____________________________________________________________________________________________Onslaught® FastCap Spider & Scorpion Insecticide Revision Date: 22-Sep-2015

Precautionary Statements - Prevention:P261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP270 - Do not eat, drink or smoke when using this productP271 - Use only outdoors or in a well-ventilated areaP264 - Wash hands thoroughly after handlingP280 - Wear protective gloves

Precautionary Statements - Response:P321 - Specific treatment (see Section 4/ First Aid).P302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 - Take off contaminated clothing and wash before reuseP304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP312 - Call a POISON CENTER or doctor/physician if you feel unwellP301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

Precautionary Statements - Storage:P405 - Store locked upP403 + P233 - Store in a well-ventilated place. Keep container tightly closed

Precautionary Statements - Disposal:P501 - Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC):Do not use this product in or on electrical equipment due to the possibility of shock hazard.

3. COMPOSITION/ INFORMATION ON INGREDIENTS

Chemical Name CAS No Weight-%Esfenvalerate 66230-04-4 6.40

Prallethrin (ETOC®) 23031-36-9 1.60Piperonyl Butoxide (PBO) 51-03-6 8.00

Petroleum distillates, hydrotreated light 64742-47-8 < 10 *

*The exact percentage (concentration) of composition has been withheld as a trade secret.

Comments: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications.


_____________________________________________________________________________________________

Appearance: cream , light yellow /brown

Page 2 / 9

Physical state: Liquid Odor Slight - Sweet


Aspiration pneumonia hazard:

Description of first aid measures:

Eye contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Removecontact lenses, if present, after the first 5minutes, then continue rinsing eye. Call apoison control center or doctor for treatment advice.

Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for15-20 minutes. Call a poison control centeror doctor for treatment advice.

Ingestion: If swallowed, IMMEDIATELY call a poison control center or doctor for treatmentadvice. DO NOT give any liquid to the person. Do not induce vomiting unless toldto do so by a poison contol center or a doctor. Never give anything by mouth to anunconscious person.

Inhalation: Remove affected person to fresh air. If person is not breathing, call 911 or anambulance, then give artificialrespiration, preferably mouth-to-mouth if possible.Call a poison control center or doctor for further treatment advice.

Self-protection of the FirstResponder:

Use personal protective equipment as required.

Note to physicians: For skin effects, a highly efficient therapeutic agent for Pyrethrin/ Pyrethroidexposure is topical application of tocopherol acetate (Vitamin E).


Suitable extinguishing mediaUse extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media:Caution: Use of water spray when fighting fire may be inefficient.

Hazardous combustion products: Carbon monoxide, Carbon dioxide (CO2), Hydrogen cyanide.

Specific hazards arising from the chemicalIn the event of fire and/or explosion do not breathe fumes. May cause sensitization by inhalation and skin contact.Thermal decomposition can lead to release of irritating and toxic gases and vapors.

Explosion data Sensitivity to Mechanical Impact: None.Sensitivity to Static Discharge: None.

Protective equipment and precautions for firefighters:As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent)and full protective gear.

Chronic Hazard Star Legend * = Chronic Health Hazard


NFPA Health hazards 1 Flammability 1 Instability 0

_____________________________________________________________________________________________

Physical andChemical Properties-

HMIS Health hazards 1 Flammability 1

Page 3 / 9

Physical hazards 0 Personal protectionX



Personal precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment asrequired. Evacuate personnel to safe areas. Keep people away from and upwindof spill/leak.

Environmental precautions: Prevent entry into waterways, sewers, basements or confined areas. Do not flushinto surface water or sanitary sewer system. Prevent further leakage or spillage ifsafe to do so. Prevent product from entering drains. See Section 12 for additionalecological information.


Methods for containment: Prevent further leakage or spillage if safe to do so.

Methods for cleaning up: Cover liquid spill with sand, earth or other non-combustible absorbent material.Cover powder spill with plastic sheet or tarp to minimize spreading. Pick up andtransfer to properly labeled containers. Soak up with inert absorbent material. Damup.



Advice on safe handling: Avoid contact with skin, eyes or clothing. Wash contaminated clothing beforereuse. Do not eat, drink or smoke when using this product. Use personalprotective equipment as required. Do not breathedust/fume/gas/mist/vapors/spray. Use with local exhaust ventilation. For moreinformation, see product label.


Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Keep out of thereach of children. Keep containers tightly closed in a cool, well-ventilated place.Keep in properly labeled containers. For more information, see product label.

8. EXPOSURE CONTROLS/ PERSONAL PROTECTION

Control parameters

Exposure Guidelines: This product, as supplied, does not contain any hazardous materials withoccupational exposure limits established by the region specific regulatory bodies.

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Supplier OELPetroleum distillates,

hydrotreated light 64742-47-8

- - - TWA: 100 ppmTWA: 525 mg/m3


Engineering Controls:

_____________________________________________________________________________________________

Safety showersEyewash stationsVentilation systems


Page 4 / 9

Eye/face protection: Tight sealing safety goggles. Face protection shield.


Skin and body protection: Wear protective gloves and protective clothing.

Respiratory protection: If exposure limits are exceeded or irritation is experienced, NIOSH/MSHAapproved respiratory protection should be worn. Positive-pressure supplied airrespirators may be required for high airborne contaminant concentrations.Respiratory protection must be provided in accordance with current localregulations.

General HygieneConsiderations:

When using do not eat, drink or smoke. Wash contaminated clothing before reuse.Regular cleaning of equipment, work area and clothing is recommended.


Information on basic physical and chemical properties:

Physical state: Liquid

Other Information:

Density: 1.011 g/cm3 @ 20.0 °CVOC Content (%): 2.5

Miscibility/ Solubility: Water: ImmiscibleAlcohol ImmiscibleAromatic solvents: ImmisciblePetroleum distillates: Immiscible


Appearance: cream , light yellow / brownOdor Slight - SweetOdor threshold: No information availableColor (Gardner Scale): No information available

Property: Values:pH: 6.9 @ 5% in H2O. .Melting point / freezing point: No information availableBoiling point / boiling range: No information availableFlash point: > 93.3 °C / > 200.0 °F Tag Closed Cup;

Evaporation rate: No information availableFlammability (solid, gas): No information availableUpper flammability limit (UEL): No information availableLower flammability limit (LEL): No information availableVapor pressure: No information availableVapor density: No information availableSpecific Gravity: No information availableWater solubility: No information availablePartition coefficient; n-Octanol/Water:


Autoignition temperature: No information availableDecomposition temperature: No information availableKinematic viscosity: No information available

_____________________________________________________________________________________________

Dynamic viscosity: 1,446 cPs @ 21.3°C. .Refractive Index:

Page 5 / 9



Reactivity

Chemical stabilityStable under recommended storage conditions.

Possibility of Hazardous ReactionsNone under normal processing.

Hazardous polymerization: Hazardous polymerization does not occur.

Conditions to avoidExtremes of temperature and direct sunlight.

Incompatible materials:Incompatible with strong acids and bases. Incompatible with oxidizing agents.

Hazardous Decomposition ProductsCarbon monoxide, Carbon dioxide (CO2), Hydrogen cyanide.


Numerical measures of toxicity - Product Information

Oral LD50 1,750 mg/kg (rat)Dermal LD50 >5,000 mg/kg (rabbit)Inhalation LC50 >2.04 mg/L (rat; 4 hours)

Eye contact: Slightly irritating. Irritation clearing in 72 hours. (rabbit).Skin Contact: Moderate irritation at 72 hours. (rabbit).Skin Irritation Index: 2.4

Sensitization: Negative. (guinea pig).

Piperonyl Butoxide:Carcinogenicity/ Oncogenicity:

Marginally higher incidences of benign liver tumors in mice were observedfollowing lifetime high dose exposures to PBO. The significance of theseobservations is questionable and under review. The doses at which tumors wereobserved for PBO greatly exceeded potential human exposure from labeled uses.Doses at which these effects were observed greatly exceeded anticipated humandietary intake. At anticipated dietary exposure levels, it is highly unlikely that thisproduct will result in carcinogenic effects.

Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listedby OSHA, IARC or NTP.

Reproductive toxicity: No information available.Developmental Toxicity No information available.

Teratogenicity: No information available.STOT - single exposure: No information available.STOT - repeated exposure: No information available.

Chronic toxicity: Repeated contact may cause allergic reactions in very susceptible persons. Avoidrepeated exposure.

_____________________________________________________________________________________________


Ecotoxicity:

Page 6 / 9

No data available


Persistence and degradabilityNo information available.

BioaccumulationNo information available.

Chemical Name Partition coefficient; n-Octanol/ Water:Prallethrin (ETOC®)

23031-36-94.49

Other adverse effects: No information available

Environmental hazards (EPA):Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unlessin accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and thepermitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product tosewer systems without previously notifying the local sewage treatment plant authority. For guidance contact yourState Water Board or Regional Office of the EPA.



Disposal of wastes: Disposal should be in accordance with applicable regional, national and local lawsand regulations. For more information, see product label.

Contaminated packaging: For more information, see product label.


DOT (Department of Transportation)

Proper Shipping Name: Insecticides, Insect or Animal Repellent, LiquidHazard Class: Non-Hazardous

Air (IATA/ ICAO) Proper Shipping Name: Insecticides, Insect or Animal Repellent, LiquidHazard Class: Non-Hazardous

Vessel (IMO/ IMDG) Not available



SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product containsa chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of FederalRegulations, Part 372

_____________________________________________________________________________________________

Chemical Name SARA 313 - Threshold Values %Piperonyl Butoxide (PBO) - 51-03-6 1.0

Page 7 / 9


SARA 311/312 Hazard Categories

Acute health hazard YesChronic Health Hazard NoFire hazard NoSudden release of pressure hazard NoReactive Hazard No

CWA (Clean Water Act)This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR122.21 and 40 CFR 122.42)

CERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under theComprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the SuperfundAmendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at thelocal, regional, or state level pertaining to releases of this material

US State Regulations:

California Proposition 65:This product does not contain any Proposition 65 chemicals

U.S. EPA Label Information:

EPA Registration Number: 1021-2574

Difference between SDS and EPA (FIFRA) Pesticide label:This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subjectto certain labeling requirements under federal pesticide law. These requirements differ from the classification criteriaand hazard information required for Safety Data Sheets (SDS), and for workplace labels of non-pesticide chemicals.The pesticide label also includes other important information, including directions for use. The hazard informationrequired on the pesticide label is reproduced below:

Signal word: CAUTION

Precautionary Statements:

International:TSCA Does not complyDSL/NDSL Does not complyEINECS/ELINCS Does not complyENCS Does not complyIECSC Does not complyKECL Does not complyPICCS Does not complyAICS

_____________________________________________________________________________________________

Does not comply

Legend:

Page 8 / 9

TSCA - United States Toxic Substances Control Act Section 8(b) InventoryDSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List


EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified ChemicalSubstancesENCS - Japan Existing and New Chemical SubstancesIECSC - China Inventory of Existing Chemical SubstancesKECL - Korean Existing and Evaluated Chemical SubstancesPICCS - Philippines Inventory of Chemicals and Chemical SubstancesAICS - Australian Inventory of Chemical Substances

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION.

SDS Prepared By: Troy Azzivitto, MGK® Chemistry Department.e-Mail Address: [email protected]

Disclaimer: The data contained herein are based on information currently available toMcLaughlin Gormley King Company and,to the best of our knowledge, areaccurate and based on sound expert opinion. Our statements herein, however, arenot to betaken as a warranty or representation for which McLaughlin Gormley KingCompany assumes legal responsibility.

_____________________________________________________________________________________________

End of Safety Data Sheet.

Issue Date:22-Sep-2015

Page 9 / 9

Revision Date:22-Sep-2015

Revision Note:- New SDS.- GHS - Classification.

Safety Data Sheet PHANTOM TERMITICIDE/INSECTICIDERevision date : 2014/09/29 Page: 1/11Version: 7.0 (30128307/SDS_CPA_US/EN)

1. Identification

Product identifier used on the label

PHANTOM TERMITICIDE/INSECTICIDE Recommended use of the chemical and restriction on use Recommended use*: insecticide

* The “Recommended use” identified for this product is provided solely to comply with a US Federal requirement and is notpart of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty,express or implied, including by incorporation into or reference in the seller's sales agreement.


Company: BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA

Telephone: +1 973 245-6000


CHEMTREC: 1-800-424-9300 BASF HOTLINE: 1-800-832-HELP (4357)

Other means of identification Substance number: 62151 EPA Register number: 241-392Molecular formula: C(15) H(11 ) Br Cl F(3) N(2) OChemical family: pyrrole derivativeSynonyms: chlorfenapyr


According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

Classification of the product

Acute Tox. 3 (Inhalation - vapour) Acute toxicity Acute Tox. 4 (oral) Acute toxicity

Label elements

Return to Index...

Safety Data Sheet PHANTOM TERMITICIDE/INSECTICIDE Revision date : 2014/09/29 Page: 2/11Version: 7.0 (30128307/SDS_CPA_US/EN)

Pictogram:

Signal Word: Danger Hazard Statement: H331 Toxic if inhaled. H302 Harmful if swallowed. Precautionary Statements (Prevention): P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe mist or vapour. P270 Do not eat, drink or smoke when using this product. P264 Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): P311 Call a POISON CENTER or doctor/physician. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for

breathing. P301 + P330 IF SWALLOWED: rinse mouth. Precautionary Statements (Storage): P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection

point. Hazards not otherwise classified Labeling of special preparations (GHS): The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 1 - 3 % dermal The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 0 - 2 % oral The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 10 - 12 % Inhalation - vapour The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 10 - 12 % Inhalation - mist According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Emergency overview CAUTION: HARMFUL IF SWALLOWED. HARMFUL IF INHALED. HARMFUL IF ABSORBED THROUGH SKIN. MAY CAUSE EYE IRRITATION. KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. Do not get in eyes, on skin, or on clothing. Avoid inhalation of mists/vapours.



According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 CAS Number Content (W/W) Chemical name 122453-73-0 21.45 % Chlorfenapyr According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 CAS Number Content (W/W) Chemical name 122453-73-0 21.45 % Chlorfenapyr 57-55-6 7.5 % Propylene glycol 70.97 % Proprietary ingredients


Description of first aid measures General advice: First aid providers should wear personal protective equipment to prevent exposure. Remove contaminated clothing. Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or physician for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. If inhaled: Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary. If on skin: Rinse skin immediately with plenty of water for 15 - 20 minutes. If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing. If swallowed: Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to by a poison control center or doctor. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Indication of any immediate medical attention and special treatment needed Note to physician Antidote: No known specific antidote. Treatment: Treat symptomatically.



Extinguishing media Suitable extinguishing media: foam, dry powder, carbon dioxide, water spray Special hazards arising from the substance or mixture Hazards during fire-fighting: carbon monoxide, carbon dioxide, hydrogen bromide, hydrochloric acid, Hydrofluoric acid, hydrogen fluoride, halogenated hydrocarbons, nitrogen dioxide, Hydrocarbons, If product is heated above decomposition temperature, toxic vapours will be released. The substances/groups of substances mentioned can be released if the product is involved in a fire. Advice for fire-fighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not allow to enter drains or waterways. Do not decontaminate personnel or equipment, or handle broken packages or containers without appropriate personal protective equipment.


Personal precautions, protective equipment and emergency procedures Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment. Environmental precautions Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water. Methods and material for containment and cleaning up Dike spillage. Pick up with suitable absorbent material. Place into suitable containers for reuse or disposal in a licensed facility. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal.


Precautions for safe handling RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product for Agricultural Use Requirements in accordance with the EPA Worker Protection Standard 40 CFR part 170. Ensure adequate ventilation. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect contents from the effects of light. Protect against heat. Protect from air. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Avoid aerosol formation. Avoid dust formation. Provide means for controlling leaks and spills. Do not return residues to the storage containers. Follow label warnings even after container is emptied. The


substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment. Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Sources of ignition should be kept well clear. Avoid extreme heat. Keep away from oxidizable substances. Electrical equipment should conform to national electric code. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition. Conditions for safe storage, including any incompatibilities Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials. Further information on storage conditions: Keep only in the original container in a cool, dry, well-ventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protect against contamination. The authority permits and storage regulations must be observed. Protect from temperatures below: 0 °C The product can crystallize below the limit temperature. Protect from temperatures above: 40 °C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.

8. Exposure Controls/Personal Protection

Users of a pesticidal product should refer to the product label for personal protective equipment requirements. Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment.

Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS: Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) TC23C Chemical/Mechanical type filter system to remove a combination of particles, gas and vapours. For situations where the airborne concentrations may exceed the level for which an air purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions. Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards. Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.


Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit. General safety and hygiene measures: Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice. Personal protective equipment should be decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift. No eating, drinking, smoking or tobacco use at the place of work. Keep away from food, drink and animal feeding stuffs.


Form: suspension Odour: sweetish Odour threshold: Not determined since toxic by inhalation. Colour: white to light brown pH value: approx. 6.9 ( 2 %(m), 20 °C) Freezing point: approx. 0 °C ( 1,013.3 hPa) Information applies to the

solvent. Boiling point: approx. 100 °C ( 1,013 mbar) Information applies to the

solvent. Flash point: (ASTM D93) No flash point -

Measurement made up to the boiling point.

Flammability: not flammable Autoignition: not applicable Vapour pressure: approx. 23.3 hPa ( 20 °C) Information applies to the

solvent. Density: approx. 1.11 -

1.16 g/cm3 ( 20 °C)

Vapour density: not applicable Partitioning coefficient n-octanol/water (log Pow):

not applicable

Thermal decomposition: carbon monoxide, carbon dioxide, hydrogen bromide, hydrochloric acid, Hydrofluoric acid, hydrogen fluoride, halogenated hydrocarbons, nitrogen dioxide, Hydrocarbons Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released.

Viscosity, dynamic: approx. > 1 mPa.s

( 20 °C)

Solubility in water: dispersible Molar mass: 407.6 g/mol Evaporation rate: not determined Other Information: If necessary, information on other physical and chemical

parameters is indicated in this section.


Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals:


Corrosive effects to metal are not anticipated. Oxidizing properties: not fire-propagating Not an oxidizer. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions The product is chemically stable. No hazardous reactions if stored and handled as prescribed/indicated. Conditions to avoid 183 degrees Celsius Disregard of the conditions mentioned may result in undesirable decomposition reactions. Incompatible materials strong oxidizing agents Hazardous decomposition products Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off. Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide, hydrogen bromide, hydrochloric acid, Hydrofluoric acid, hydrogen fluoride, halogenated hydrocarbons, nitrogen dioxide, Hydrocarbons Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released.


Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Slightly toxic after single ingestion. Slightly toxic after short-term inhalation. Slightly toxic after short-term skin contact. Oral Type of value: LD50 Species: rat (male/female) Value: 560 - 567 mg/kg Inhalation Type of value: LC50 Species: rat (male) Value: 2.284 mg/l (calculated)


Exposure time: 1 h Type of value: LC50 Species: rat (female) Value: > 6.4 mg/l (calculated) Exposure time: 1 h Dermal Type of value: LD50 Species: rabbit Value: > 2,000 mg/kg Irritation / corrosion Assessment of irritating effects: May cause slight irritation to the skin. May cause slight but temporary irritation to the eyes. Skin Species: rabbit Result: non-irritant Eye Species: rabbit Result: non-irritant Sensitization Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. modified Buehler test Species: guinea pig Result: Skin sensitizing effects were not observed in animal studies. Method: OECD Guideline 406 Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. No substance-specific organtoxicity was observed after repeated administration to animals. Genetic toxicity Information on: Chlorfenapyr Assessment of mutagenicity: No mutagenic effect was found in various tests with microorganisms and mammalian cell culture. The substance was not mutagenic in a test with mammals. ---------------------------------- Carcinogenicity Assessment of carcinogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no indication of a carcinogenic effect. Reproductive toxicity Assessment of reproduction toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of animal studies gave no indication of a fertility impairing effect. Teratogenicity


Assessment of teratogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals. Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Medical conditions aggravated by overexposure Individuals with pre-existing diseases of the respiratory system, skin or eyes may have increased susceptibility to excessive exposures.

12. Ecological Information

Toxicity Aquatic toxicity Assessment of aquatic toxicity: Very toxic (acute effect) to fish. Very toxic (acute effect) to aquatic invertebrates. Acutely toxic for aquatic plants. Toxicity to fish LC50 (96 h) 0.0239 mg/l, Oncorhynchus mykiss (Flow through.) Aquatic invertebrates EC50 (48 h) 0.012 mg/l, Daphnia magna (static) Aquatic plants EC50 (72 h) 4.09 mg/l, Selenastrum capricornutum (OECD Guideline 201) Assessment of terrestrial toxicity Acutely very toxic to terrestrial organisms. Bioaccumulative potential Assessment bioaccumulation potential The product has not been tested. The statement has been derived from the properties of the individual components. Additional information Other ecotoxicological advice: The ecological data given are those of the active ingredient.


Waste disposal of substance: Pesticide wastes are regulated. Improper disposal of excess pesticide, spray mix or rinsate is a violation of federal law. If pesticide wastes cannot be disposed of according to label instructions, contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.


Container disposal: Rinse thoroughly at least three times (triple rinse) in accordance with EPA recommendations. Consult state or local disposal authorities for approved alternative procedures such as container recycling. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers. RCRA: This product is not regulated by RCRA.


Land transport USDOT

Not classified as a dangerous good under transport regulations

Sea transport IMDG Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Marine pollutant: YES Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (contains CHLORFENAPYR 24%)

Air transport IATA/ICAO

Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (contains CHLORFENAPYR 24%)


Federal Regulations Registration status: Chemical TSCA, US blocked / not listed Crop Protection TSCA, US released / exempt EPCRA 311/312 (Hazard categories): Acute; State regulations State RTK CAS Number Chemical name PA 57-55-6 Propylene glycol


NFPA Hazard codes: Health : 2 Fire: 1 Reactivity: 1 Special: Labeling requirements under FIFRA This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label. CAUTION: HARMFUL IF SWALLOWED. HARMFUL IF INHALED. HARMFUL IF ABSORBED THROUGH SKIN. May cause moderate but temporary irritation to the eyes. KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. Do not get in eyes, on skin, or on clothing.

Avoid inhalation of mists/vapours.


SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2014/09/29 We support worldwide Responsible Care® initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products.

IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET

ᄞ


Safety Data Sheet


Product identifierProduct Name • Precor 2000 Plus Premise SpraySynonyms • 100517677; 3006018; 3006301; 3006302; EPA Reg. No.: 2724490; RF9910 AerosolProduct Description • Clear to white aerosol spray.

Relevant identified uses of the substance or mixture and uses advised againstRecommended use • Insecticide.Restrictions on use • Keep out of the reach of children. Avoid contact with skin, eyes and clothing. Keep

away from heat, sparks and flame. Do not allow product to enter drain or any body of water.

Details of the supplier of the safety data sheetManufacturer • Wellmark International


Emergency telephone numberManufacturer • 18002487763 Manufacturer (Transportation) • 18004249300 CHEMTRECManufacturer (Transportation) • 17035273887 CHEMTREC Outside North America Collect Calls Accepted



Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects Flammable Aerosols 2 Skin Irritation 2 Skin Sensitization 1


DANGER

Precor 2000 Plus Premise SprayPrecor 2000 Plus Premise SprayPrecor 2000 Plus Premise SprayPrecor 2000 Plus Premise Spray




Return to Index...

Hazard statements • May cause drowsiness or dizziness May be fatal if swallowed and enters airways Flammable aerosol Causes skin irritation May cause an allergic skin reaction

Precautionary statementsPrevention • Use only outdoors or in a wellventilated area.

Avoid breathing dust, fume, gas, mist, vapors and/or spray. Keep away from heat, sparks, open flames and/or hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash thoroughly after handling. Wear protective gloves. Contaminated work clothing should not be allowed out of the workplace.

Response • IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison control center or doctor if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.

Storage/Disposal • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Store locked up. Store in a wellventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50ºC/122ºF.




Substances

• Material does not meet the criteria of a substance according to United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS)

Mixtures

CompositionChemical Name Identifiers %(s)Methoprene CAS:65733166 0.085% Permethrin CAS:52645531 0.35% Piperonyl butoxide CAS:51036 1.75% Phenothrin CAS:26002802 0.3% NOctyl Bicyloheptene Dicarboximide CAS:113484 1.75% Distillates (petroleum), hydrotreated light CAS:64742478 14% Ethoxylated nonylphenol, branched CAS:68412544 1.8% 2Pyrrolidinone, 1octyl CAS:2687947 0.4%





Propane CAS:74986 7.08% Butane CAS:106978 6.92% Other ingredients NDA 65.565%


Description of first aid measuresInhalation • IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for

breathing. Call a poison control center or doctor if you feel unwell. Skin • IF ON SKIN: Wash with plenty of soap and water. If irritation or rash occurs, get

medical advice/attention. Eye • IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,

if present and easy to do. Continue rinsing. Get medical attention if symptoms occur. Ingestion • IF SWALLOWED: Aspiration hazard do NOT induce vomiting. Call a poison control

center or doctor immediately for treatment advice. Most important symptoms and effects, both acute and delayed

• Aspiration hazard, may cause dizziness or drowsiness if inhaled, causes skin irritation, may cause an allergic reaction in individuals with a sensitivity to piperonyl butoxide and/or noctyl bicycloheptene dicarboximide. Refer to Section 11 Toxicological Information.

Indication of any immediate medical attention and special treatment neededNotes to Physician • Contains petroleum distillate vomiting may cause aspiration pneumonia. Treat

symptomatically and supportively.


Extinguishing mediaSuitable Extinguishing Media • LARGE FIRE: Water spray, fog or regular foam.

SMALL FIRES: Dry chemical, CO2, water spray or regular foam. Unsuitable Extinguishing Media

• Avoid heavy hose streams.

Firefighting Procedures • Flammable aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards. As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions.


• At temperatures above 130°F, container may rupture. Flammable aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards.


• Thermal degradation may produce oxides of carbon, oxides of nitrogen and/or volatile hydrocarbon vapors.



Personal precautions, protective equipment and emergency proceduresPersonal Precautions • Approach leaking or punctured pressurized containers cautiously. Isolate leaking

container from all sources of ignition. Avoid breathing fumes. Ventilate enclosed areas. Emergency Procedures • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate





area). Avoid unnecessary personnel and equipment traffic in the spill area. Turn off electric power to area. Stay upwind. Ventilate closed spaces before entering. Do not allow runoff into water, storm drains or drainage ditches.

Environmental precautions• Avoid run off to waterways and sewers.


• Keep away from fire, sparks and heated surfaces. SMALL SPILLS: Take up with sand or other noncombustible absorbent material and place into containers for later disposal.


Precautions for safe handlingHandling • Do not use or store near heat or open flame. Do not smoke while using this product.

Contents under pressure, do not crush, puncture or incinerate. Avoid breathing fumes. Conditions for safe storage, including any incompatibilitiesStorage • Store in a cool, dry place. Keep out of reach of children. Keep away from sources of

ignition – No Smoking. Store locked up. Store in a wellventilated place. Keep container tightly closed. Keep at a temperature not exceeding 122°F (50°C). Keep from freezing.


• Heat, sparks, open flame.


Control parametersExposure Limits/Guidelines

Result ACGIH NIOSH OSHA

Butane (106978)

STELs 1000 ppm STEL Not established Not established

TWAs Not established 800 ppm TWA; 1900 mg/m3 TWA Not established

Propane (74986) TWAs

1000 ppm TWA (listed under Aliphatic hydrocarbon gases: Alkane C14)

1000 ppm TWA; 1800 mg/m3 TWA 1000 ppm TWA; 1800 mg/m3 TWA


• Use adequate ventilation to remove vapors (fumes, dust etc)


Respiratory • In case of insufficient ventilation, wear suitable NIOSH approved respiratory protection.Eye/Face • Wear safety glasses.Hands • Impervious gloves. Some materials that are chemical resistant to this product are

Barrier Laminate, Nitrile Rubber, Neoprene Rubber or Viton. Skin/Body • It is recommended for handlers to wear appropriate clothing to prevent skin contact

including long sleeves, long pants, socks and shoes. Environmental Exposure Controls

• Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways.






Information on Physical and Chemical PropertiesMaterial Description Physical Form Aerosol Appearance/Description White to clear aerosol spray.Color White to clear. Odor No data available.Aerosol Type Spray Odor Threshold No data availableGeneral Properties Boiling Point No data available Melting Point/Freezing Point No data availableDecomposition Temperature No data available Heat of Decomposition No data availablepH No data available Specific Gravity/Relative Density No data availableWater Solubility No data available Viscosity No data availableVolatility Vapor Pressure No data available Vapor Density No data availableEvaporation Rate No data available VOC (Wt.) No data availableVOC (Vol.) No data available Flammability Flash Point Not relevant UEL No data availableLEL No data available Heat of Combustion (ΔHc) 6.98 kJ/gFlame Extension 1 in Flammability (solid, gas) Flammable aerosol.Environmental Octanol/Water Partition coefficient No data available


Reactivity• Nonreactive under normal handling and storage conditions.

Chemical stability• Stable under normal temperatures and pressures.

Possibility of hazardous reactions• Flammable, aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards.

Conditions to avoid• Heat, sparks, open flame. Excess heat.

Incompatible materials• Heat, strong acids, strong bases and oxidizing agents.

Hazardous decomposition products• Hazardous decomposition may occur when heated producing oxides of carbon and nitrogen, volatile hydrocarbon vapors.


Information on toxicological effectsCAS





Precor 2000 Plus Premise Spray NDA

Acute Toxicity: Ingestion/OralRat LD50 • >5000 mg/kg 14 Day(s); InhalationRat LC50 • >2.12 mg/L 4 Hour(s); SkinRabbit LD50 • >5050 mg/kg 24 Hour(s); Irritation: EyeRabbit • Mild irritation; SkinRabbit • Moderate irritation


Acute toxicityOSHA HCS 2012 • Acute Toxicity Dermal Classification criteria not met; Acute Toxicity Inhalation Classification criteria not met; Acute Toxicity Oral Classification criteria not met





Skin sensitization OSHA HCS 2012 • Skin Sensitizer 1





Serious eye damage/Irritation OSHA HCS 2012 • Classification criteria not met

Potential Health EffectsInhalationAcute (Immediate) • May cause drowsiness and dizziness.Chronic (Delayed) • No data available

SkinAcute (Immediate) • Causes skin irritation. May cause an allergic reaction in individuals with a sensitivity to

piperonyl butoxide and/or noctyl bicycloheptene dicarboximide.Chronic (Delayed) • No data available.

EyeAcute (Immediate) • Under normal conditions of use, no health effects are expected.Chronic (Delayed) • No data available

IngestionAcute (Immediate) • Aspiration Hazard may be fatal if swallowed and enters airways.Chronic (Delayed) • No data available


ToxicityComponent CAS Data

(s)Methoprene (0.085%) 65733166

Crustacea: NOEC Crustacea Mysid shrimp 0.014 mg/L [Chronic]; 96 Hour(s) LC50 Crustacea Mysid shrimp 0.11 mg/L [Acute]; 48 Hour(s) LC50 Crustacea Daphnia magna 0.36 mg/L [Acute]; Fish: 96 Hour(s) LC50 Fish Rainbow Trout 0.76 mg/L [Acute]; 96 Hour(s) LC50 Fish Blue Gill >0.37 mg/L [Acute]; NOEC Fish Fathead minnow 0.048 mg/L [Chronic]

Crustacea: NOEC Crustacea Daphnia magna 0.000039 mg/L [Chronic]; NOEC Crustacea Mysid shrimp 0.000011 mg/L [Chronic]; LC50 Crustacea Hexagenia bilineuta 0.0001 mg/L [Acute]; 96 Hour





Permethrin (0.35%) 52645531 (s) LC50 Crustacea Mysid shrimp 0.000019 mg/L [Acute]; Fish: 96 Hour(s) LC50 Fish Blue gill 0.00079 mg/L [Acute]; 96 Hour(s) LC50 Fish Atlantic silverside 0.0022 mg/L [Acute]; NOEC Fish Fathead minnow 0.0003 mg/L [Chronic]; NOEC Fish Sheepshead minnow 0.00083 mg/L [Chronic]

Piperonyl butoxide (1.75%) 51036

Crustacea: LC50 Crustacea Gammarus fasciatus (amphipod) 0.51 mg/L [Acute]; LC50 Crustacea Mysid shrimp 0.49 mg/L [Acute]; NOEC Crustacea Daphnia magna 0.03 mg/L [Chronic]; Fish: LC50 Fish Rainbow Trout 1.9 mg/L [Acute]; LC50 Fish Sheephead minnow 3.94 mg/L [Acute]; NOEC Fish Fathead minnow 0.04 mg/L [Chronic]

Phenothrin (0.3%) 26002802

Crustacea: NOEC Crustacea Daphnia magna 0.00047 mg/L [chronic]; 48 Hour(s) LC50 Crustacea Daphnia magna 0.0044 mg/L [acute]; 96 Hour(s) LC50 Crustacea Mysid shrimp 0.000025 mg/L [acute]; Fish: 96 Hour(s) LC50 Fish Rainbow trout 0.0027 mg/L [acute]; 96 Hour(s) LC50 Fish Blue gill 0.0158 mg/L [acute]; NOEC Fish Rainbow trout 0.0011 mg/L [chronic]

NOctyl Bicyloheptene Dicarboximide (1.75%) 113484 Crustacea: 48 Hour(s) LC50 Crustacea Daphnia magna 2.3 mg/L [Acute];

Fish: LC50 Fish 1.42.4 mg/L [Acute]

Persistence and degradability• No data available

Bioaccumulative potential• No data available

Mobility in Soil• No data available

Other adverse effectsPotential Environmental Effects

• No data available.


Waste treatment methodsProduct waste • Dispose of content and/or container in accordance with local, regional, national, and/or

international regulations. Do not allow entry into storm drains, drainage ditches, gutters or surface waters.

Packaging waste • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Do not puncture or incinerate.


UN number



Packing group


DOT UN1950 Aerosols (contains Phenothrin) 2.1 Not Applicable Marine Pollutant

IMO/IMDG UN1950 Aerosols (contains Phenothrin) 2.1 Not Applicable Marine Pollutant

IATA/ICAO UN1950 Aerosols, flammable 2.1 Not Applicable Not Applicable



Other informationIMO/IMDG • No data availableIATA/ICAO • No data available







Safety, health and environmental regulations/legislation specific for the substance or mixtureSARA Hazard Classifications • Acute, SARA Title III Section 313


Precautionary Statements • KEEP OUT OF THE REACH OF CHILDREN. Hazards to Humans and

Domestic Animals• HAZARDS TO HUMANS AND DOMESTIC ANIMALSCAUTION: Avoid contact with skin or clothing. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.

First Aid • IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 1520 minutes. Call a poison control center or doctor for treatment advice. IF SWALLOWED: Immediately call a poison control center or doctor for treatment advice. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give ANY liquid to the person. Do not give anything by mouth to an unconscious person. Note to Physician: Contains petroleum distillate vomiting may cause aspiration pneumonia.


• Contents under pressure. Do not use or store near open flame. Do not puncture or incinerate container. Exposure to temperatures above 130°F may cause bursting.


(s)Methoprene 65733166 No

2Pyrrolidinone, 1octyl 2687947 Yes

Butane 106978 Yes


64742478 Yes

NOctyl Bicyloheptene Dicarboximide

113484 No

Permethrin 52645531 No

Phenothrin 26002802 No

Ethoxylated nonylphenol, branched

68412544 Yes

Piperonyl butoxide 51036 Yes

Propane 74986 Yes





United StatesEnvironment

U.S. CERCLA/SARA Section 313 Emission Reporting

• Ethoxylated nonylphenol, branched 68412544 Not Listed • Propane 74986 Not Listed • Butane 106978 Not Listed • (s)Methoprene 65733166 Not Listed

• Permethrin 52645531 1.0 % de minimis concentration

• Distillates (petroleum), hydrotreated light 64742478 Not Listed • 2Pyrrolidinone, 1octyl 2687947 Not Listed

• Piperonyl butoxide 51036 1.0 % de minimis concentration

• NOctyl Bicyloheptene Dicarboximide 113484 Not Listed

• Phenothrin 26002802 1.0 % de minimis concentration









Safety Data Sheet


Product identifierProduct Name • Zoecon Precor IGR ConcentrateSynonyms • 10290A; 37190B; 37740C; EPA Reg. No.: 2724352; Zoecon RF291 Emulsifiable

ConcentrateProduct Description • Very light strawcolored, transparent liquid.

Relevant identified uses of the substance or mixture and uses advised againstRecommended use • Insect growth regulator.Restrictions on use • KEEP OUT OF THE REACH OF CHILDREN. Avoid contact with eyes, skin and

clothing. Do not use or store near heat or open flame. Do not take internally. Avoid inhalation of vapors or fumes.

Details of the supplier of the safety data sheetManufacturer • Wellmark International


Emergency telephone numberManufacturer • 18002487763 Manufacturer (Transportation) • 18004249300 CHEMTRECManufacturer (Transportation) • 17035273887 CHEMTREC Outside North America Collect Calls Accepted



Flammable Liquids 4 Eye Mild Irritation 2B Skin Irritation 2 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects


DANGER

Zoecon Precor IGR ConcentrateZoecon Precor IGR ConcentrateZoecon Precor IGR ConcentrateZoecon Precor IGR Concentrate




Return to Index...

Hazard statements • Causes skin irritation May be fatal if swallowed and enters airways Combustible liquid Causes eye irritation May cause drowsiness or dizziness

Precautionary statementsPrevention • Wash thoroughly after handling.

Wear protective gloves/protective clothing/eye protection/face protection. Avoid breathing dust, fume, gas, mist, vapors and/or spray. Use only outdoors or in a wellventilated area. Keep away from flames and hot surfaces. No smoking.

Response • IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. In case of fire: Use appropriate media Foam, water, dry chemical or C02. for extinction. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison control center or doctor if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Storage/Disposal • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Store in a wellventilated place. Keep cool. Store locked up. Keep container tightly closed.




Substances

• Material does not meet the criteria of a substance.

Mixtures

CompositionChemical Name Identifiers %(s)Methoprene CAS:65733166 1.2% Distillates (petroleum), hydrotreated light CAS:64742478 78.72% Poly(oxy1,2ethanediyl), alpha(dodecylphenyl)omegahydroxy CAS:9014920 <= 16.6% Other ingredients NDA > 3%






Description of first aid measuresInhalation • IF INHALED: If breathing is difficult, remove person to fresh air and keep at rest in a

position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.

Skin • IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.

Eye • IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Ingestion • IF SWALLOWED: Immediately call a poison control center or doctor. Aspiration hazard if swallowed, do NOT induce vomiting.

Most important symptoms and effects, both acute and delayed• Aspiration hazard, causes skin irritation, causes eye irritation, may cause dizziness or drowsiness if inhaled. Refer to Section 11 Toxicological Information.

Indication of any immediate medical attention and special treatment neededNotes to Physician • Contains petroleum distillate vomiting may cause aspiration pneumonia. Treat

symptomatically and supportively.


Extinguishing mediaSuitable Extinguishing Media • LARGE FIRE: Water spray, fog or regular foam.

SMALL FIRES: Dry chemical, CO2, water spray or regular foam. Unsuitable Extinguishing Media

• Avoid heavy hose streams.

Firefighting Procedures • LARGE FIRES: Move containers from fire area if you can do it without risk. Stay upwind. Ventilate closed spaces before entering. Do not breathe gas/fumes/vapor/spray.


• Combustible liquid. Containers may explode when heated. Liquid will float and may reignite on surface of water.


• Combustible liquid may produce carbon dioxide and/or carbon monoxide.



Personal precautions, protective equipment and emergency proceduresPersonal Precautions • Do not walk through spilled material. Ventilate enclosed areas. Wear appropriate

personal protective equipment, avoid direct contact. Emergency Procedures • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate

area). Ventilate closed spaces before entering. Avoid release into the environment. Environmental precautions

• LARGE SPILLS: Prevent entry into waterways, sewers, basements or confined areas.






Containment/Cleanup Measures

• All equipment used when handling the product must be grounded. Stop leak if you can do it without risk. SMALL SPILLS: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Use appropriate Personal Protective Equipment (PPE)


Precautions for safe handlingHandling • Keep away from fire No Smoking. Avoid breathing fumes. Use only in well ventilated

areas. Wear appropriate personal protective equipment, avoid direct contact.Conditions for safe storage, including any incompatibilitiesStorage • Store locked up. Store in a cool/lowtemperature, wellventilated dry place away from

heat and ignition sources. Keep from freezing. Do not store at temperatures exceeding 130°F. Keep container tightly closed.


• Heat, sparks, open flame.

Other Information• See product label for additional information.


Control parametersExposure Limits/Guidelines • No data available.


• Use adequate ventilation to remove vapors (fumes, dust, etc.)


Respiratory • In case of inadequate ventilation, avoid breathing vapors or mist, wear a NIOSH approved chemical cartridge respirator with organic vapor cartridges and a pesticide prefilter.

Eye/Face • Wear chemical splash safety goggles.Hands • Wear appropriate gloves.Skin/Body • If prolonged exposure is anticipated, it is recommended for handlers to wear

appropriate clothing to prevent skin contact.Environmental Exposure Controls

• Refer to Section 13 Disposal Considerations.

Other Information• See product label for additional information.


Information on Physical and Chemical PropertiesMaterial Description Physical Form Liquid Appearance/Description Very light straw, transparent liquid.Color Very light straw, transparent. Odor Faint aliphatic.





Odor Threshold No data available General Properties Boiling Point No data available Melting Point/Freezing Point No data available

Decomposition Temperature No data available pH 4.92 (10% in Type 1 Water)

Specific Gravity/Relative Density 0.82 (6.8 lb/gal) Water Solubility Insoluble

Viscosity < 100 Centipoise (cPs, cP) or mPas Volatility Vapor Pressure No data available Vapor Density No data availableEvaporation Rate No data available Flammability

Flash Point 196°F (91°C) UEL No data available

LEL No data available Autoignition No data availableFlammability (solid, gas) No data available Environmental Octanol/Water Partition coefficient No data available


Reactivity• Nonreactive under normal handling and storage conditions.

Chemical stability• Stable

Possibility of hazardous reactions• Hazardous polymerization will not occur.

Conditions to avoid• Direct sunlight. Do not freeze. Excessive heat >130°F. Heat, sparks, open flame, other ignition sources, and oxidizing conditions. Strong oxidizers.

Incompatible materials• Store away from oxidizers.

Hazardous decomposition products• Carbon dioxide and possibly carbon monoxide.


Information on toxicological effectsCAS

Zoecon Precor IGR Concentrate NDA

Acute Toxicity: Ingestion/OralRat LD50 • >5100 mg/kg; InhalationRat LC50 • 5.37 mg/L 4 Hour(s); SkinRabbit LD50 • >2100 mg/kg; Irritation: EyeRabbit • Mild irritation; SkinRabbit • Moderate irritation


Acute toxicityOSHA HCS 2012 • Acute Toxicity Dermal Classification criteria not met; Acute Toxicity Inhalation Classification criteria not met; Acute Toxicity Oral





Classification criteria not met





Skin sensitization OSHA HCS 2012 • Classification criteria not met





Serious eye damage/Irritation OSHA HCS 2012 • Eye Mild Irritation 2B

Potential Health EffectsInhalationAcute (Immediate) • May cause drowsiness and dizziness.Chronic (Delayed) • No data available

SkinAcute (Immediate) • Causes skin irritation.Chronic (Delayed) • No data available

EyeAcute (Immediate) • Causes eye irritation.Chronic (Delayed) • No data available

IngestionAcute (Immediate) • Aspiration hazard small amounts of liquid aspirated into the lungs during ingestion or

from vomiting may cause chemical pneumonitis or pulmonary edema.Chronic (Delayed) • No data available


ToxicityComponent CAS Data

(s)Methoprene (1.2%) 65733166

Crustacea: NOEC Crustacea Mysid shrimp 0.014 mg/L [Chronic]; 96 Hour(s) LC50 Crustacea Mysid shrimp 0.11 mg/L [Acute]; 48 Hour(s) LC50 Crustacea Daphnia magna 0.36 mg/L [Acute]; Fish: 96 Hour(s) LC50 Fish Rainbow Trout 0.76 mg/L [Acute]; 96 Hour(s) LC50 Fish Blue Gill >0.37 mg/L [Acute]; NOEC Fish Fathead minnow 0.048 mg/L [Chronic]

Persistence and degradability• No data available.

Bioaccumulative potential• No data available.

Mobility in Soil• No data available

Other adverse effectsPotential Environmental Effects

• No data available.






Waste treatment methodsProduct waste • Dispose of content and/or container in accordance with local, regional, national, and/or

international regulations. Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Never place unused product down any indoor or outdoor drain.

Packaging waste • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. See product label for disposal instructions.


UN number



Packing group


DOT 1268 Petroleum distillates, n.o.s. 3 III Not Applicable

IMO/IMDG 1268 Petroleum distillates, n.o.s. 3 III Not Applicable

IATA/ICAO 1268 Petroleum distillates, n.o.s. 3 III Not Applicable



Other informationIMO/IMDG • No data availableIATA/ICAO • No data available



Safety, health and environmental regulations/legislation specific for the substance or mixtureSARA Hazard Classifications • Acute


Precautionary Statements • KEEP OUT OF THE REACH OF CHILDREN. Hazards to Humans and

Domestic Animals• HAZARDS TO HUMANS AND DOMESTIC ANIMALS CAUTION: Harmful if absorbed through the skin. Causes moderate eye irritation. Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after handling.

First Aid • Call a poison control center or doctor immediately for treatment advice. If in eyes • Hold eye open and rinse slowly and gently with water for 1520 minutes. • Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. If on





skin or clothing • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 1520 minutes. NOTE TO PHYSICIAN: This product contains petroleum distillates. If swallowed: Immediately call a poison control center or doctor. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give any liquid to the person. Do not give anything by mouth to an unconscious person.


• Combustible. Do not use or store near heat or open flame


(s)Methoprene 65733166 No


64742478 Yes

Poly(oxy1,2ethanediyl), alpha(dodecylphenyl)omegahydroxy

9014920 Yes








Safety Data SheetPTB PHANTOM PRESSURIZEDRevision date : 2015/12/04 Page: 1/12 Version: 5.0 (30468750/SDS_CPA_US/EN)

1. Identification


PTB PHANTOM PRESSURIZEDRecommended use of the chemical and restriction on use Recommended use*: insecticide

* The “Recommended use” identified for this product is provided solely to comply with a Federal requirement and is not part ofthe seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express orimplied, including by incorporation into or reference in the seller's sales agreement.



Telephone: +1 973 245-6000



Other means of identification Substance number: 383799 EPA Registration number: 7969-285 Molecular formula: C15 H11 Br Cl F3 N2 O Chemical family: pyrrole derivative Synonyms: chlorfenapyr




Flam. Liq. 1 Flammable liquids Aquatic Acute 1 Hazardous to the aquatic environment - acute Aquatic Chronic 1 Hazardous to the aquatic environment - chronic

Label elements

Return to Index...

Safety Data Sheet PTB PHANTOM PRESSURIZED Revision date : 2015/12/04 Page: 2/12 Version: 5.0 (30468750/SDS_CPA_US/EN)

Pictogram:

Signal Word: Danger Hazard Statement: H224 Extremely flammable liquid and vapour. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Precautionary Statements (Prevention): P210 Keep away from heat, hot surfaces, sparks, open flames and other

ignition sources. No smoking. P280 Wear protective gloves and eye/face protection. P273 Avoid release to the environment. P243 Take precautionary measures against static discharge. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P242 Use only non-sparking tools. Precautionary Statements (Response): P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.

Rinse skin with water/shower. P391 Collect spillage. P370 + P378 In case of fire: Use water spray, dry powder, foam or carbon dioxide for

extinction. Precautionary Statements (Storage): P403 + P235 Store in a well-ventilated place. Keep cool. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection

point. Hazards not otherwise classified Labeling of special preparations (GHS): The product contains fluorinated greenhouse gases according to regulation (EC) No 517/2014. The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 12 % Inhalation - vapour The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 12 % Inhalation - mist According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Emergency overview CAUTION: KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. Avoid contact with the skin, eyes and clothing. Avoid inhalation of mists/vapours.


Wash thoroughly after handling.


According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 CAS Number Weight % Chemical name 122453-73-0 0.5 % Chlorfenapyr 64742-47-8 < 10.0% Distillates (petroleum), hydrotreated light 67-64-1 < 15.0% Acetone 68476-40-4 < 15.0% Hydrocarbons, C3-4 811-97-2 < 75.0% HFC-134A According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 CAS Number Weight % Chemical name 122453-73-0 0.5 % Chlorfenapyr 64742-47-8 < 10.0% Distillates (petroleum), hydrotreated light 67-64-1 < 15.0% Acetone 68476-40-4 Hydrocarbons, C3-4 811-97-2 HFC-134A >= 75.0% Proprietary ingredients


Description of first aid measures General advice: First aid providers should wear personal protective equipment to prevent exposure. Remove contaminated clothing. Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or physician for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. If inhaled: Remove the affected individual into fresh air and keep the person calm. If on skin: Wash thoroughly with soap and water. If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing. If swallowed: Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting. Have person sip a glass of water if able to swallow. Most important symptoms and effects, both acute and delayed Symptoms: No significant reaction of the human body to the product known. Indication of any immediate medical attention and special treatment needed


Note to physician Antidote: No known specific antidote. Treatment: Treat symptomatically.


Extinguishing media Suitable extinguishing media: foam, dry powder, carbon dioxide, water spray Special hazards arising from the substance or mixture Hazards during fire-fighting: carbon monoxide, carbon dioxide, nitrogen dioxide, nitrogen oxide, Hydrogen chloride, hydrogen fluoride, hydrogen bromide, halogenated hydrocarbons, Hydrocarbons, If product is heated above decomposition temperature, toxic vapours will be released. The substances/groups of substances mentioned can be released in case of fire. Advice for fire-fighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not allow to enter drains or waterways.


Personal precautions, protective equipment and emergency procedures Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment. Environmental precautions Do not discharge into the subsoil/soil. Contain contaminated water/firefighting water. Methods and material for containment and cleaning up Dike spillage. Pick up with suitable absorbent material. Place into suitable containers for reuse or disposal in a licensed facility. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal.


Precautions for safe handling RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product for Agricultural Use Requirements in accordance with the EPA Worker Protection Standard 40 CFR part 170. Ensure adequate ventilation. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect contents from the


effects of light. Protect against heat. Protect from air. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Provide means for controlling leaks and spills. Do not return residues to the storage containers. Follow label warnings even after container is emptied. The substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment. Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Sources of ignition should be kept well clear. Avoid extreme heat. Keep away from oxidizable substances. Electrical equipment should conform to national electric code. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition. Conditions for safe storage, including any incompatibilities Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials. Further information on storage conditions: Keep only in the original container in a cool, dry, well-ventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protect against contamination. The authority permits and storage regulations must be observed. Protect from temperatures above: 40 °C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.


Users of a pesticidal product should refer to the product label for personal protective equipment requirements. Components with occupational exposure limits Acetone OSHA PEL PEL 1,000 ppm 2,400 mg/m3 ; STEL value

1,000 ppm 2,400 mg/m3 ; TWA value 750 ppm 1,800 mg/m3 ;

ACGIH TLV TWA value 250 ppm ; STEL value 500 ppm ; Distillates (petroleum), hydrotreated light

ACGIH TLV TWA value 200 mg/m3 Non-aerosol (total

hydrocarbon vapor); Application restricted to conditions in which there are negligible aerosol exposures. Skin Designation Non-aerosol (total hydrocarbon vapor); The substance can be absorbed through the skin.


Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS:


Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. For situations where the airborne concentrations may exceed the level for which an air purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions. Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards. Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit. General safety and hygiene measures: Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice. Personal protective equipment should be decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift. No eating, drinking, smoking or tobacco use at the place of work. Keep away from food, drink and animal feeding stuffs.


Form: liquid, under pressure Odour: strong, of acetone Odour threshold: Not determined due to potential health hazard by inhalation. Colour: amber, cloudy pH value: approx. 7 - 9

( 5 %(m), approx. 25 °C)

Melting point: The product has not been tested. Boiling point: approx. -12 °C

Information applies to the solvent.

Flash point: approx. -104 °C Information applies to the propellant.

Flammability: Extremely flammable. Flammability of Aerosol Products:

0 cm no flashback

(ASTM D 3065)

Lower explosion limit: 1.9 %(V) Information applies to the solvent.

Upper explosion limit: 13.3 %(V) Information applies to the solvent.

Vapour pressure: approx. 2000 hPa ( 21 °C) Information applies to the solvent.

Density: approx. 0.8 g/cm3 ( 20 °C)

Vapour density: not applicable


Thermal decomposition: carbon monoxide, carbon dioxide, nitrogen dioxide, nitrogen oxide, Hydrogen chloride, hydrogen fluoride, hydrogen bromide, halogenated hydrocarbons, Hydrocarbons Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released.

Viscosity, dynamic: 2.5 mPa.s ( 26 °C)

Solubility in water: miscible Evaporation rate: not applicable Other Information: If necessary, information on other physical and chemical



Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: Corrosive effects to metal are not anticipated. Oxidizing properties: Not an oxidizer. Based on its structural properties the product is not classified as oxidizing. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions The product is chemically stable. Hazardous polymerization will not occur. No hazardous reactions if stored and handled as prescribed/indicated. Conditions to avoid Avoid all sources of ignition: heat, sparks, open flame. Avoid prolonged storage. Avoid electro-static discharge. Avoid contamination. Avoid prolonged exposure to extreme heat. Avoid extreme temperatures. Incompatible materials strong oxidizing agents Hazardous decomposition products Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off. Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide, nitrogen dioxide, nitrogen oxide, Hydrogen chloride, hydrogen fluoride, hydrogen bromide, halogenated hydrocarbons, Hydrocarbons Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released.


Primary routes of exposure


Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic by inhalation. Virtually nontoxic after a single skin contact. Oral Type of value: LD50 Species: rat (female) Value: > 5,000 mg/kg Inhalation Type of value: LC50 Species: rat (male/female) Value: > 5.2 mg/l Exposure time: 4 h Dermal Type of value: LD50 Species: rat (male/female) Value: > 5,000 mg/kg Irritation / corrosion Assessment of irritating effects: May cause slight irritation to the skin. May cause slight but temporary irritation to the eyes. Skin Species: rabbit Result: non-irritant Eye Species: rabbit Result: non-irritant Sensitization Assessment of sensitization: There is no evidence of a skin-sensitizing potential. Buehler test Species: guinea pig Result: Non-sensitizing. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: Acetone Assessment of repeated dose toxicity: The substance may cause damage to the testes after repeated ingestion of high doses, as shown in animal studies. The substance may cause damage to the hematological system after repeated ingestion of high doses. The substance may cause damage to the kidney after repeated ingestion of high doses, as shown in animal studies. ----------------------------------


Genetic toxicity Assessment of mutagenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Mutagenicity tests revealed no genotoxic potential. Carcinogenicity Assessment of carcinogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no indication of a carcinogenic effect. Reproductive toxicity Assessment of reproduction toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: chlorfenapyr Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility impairing effect. Information on: Acetone Assessment of reproduction toxicity: As shown in animal studies, the product may cause damage to the testes after repeated high exposures that cause other toxic effects. ---------------------------------- Teratogenicity Assessment of teratogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals. Other Information Misuse can be harmful to health. Symptoms of Exposure No significant reaction of the human body to the product known. Medical conditions aggravated by overexposure Individuals with pre-existing diseases of the respiratory system, skin or eyes may have increased susceptibility to excessive exposures.


Toxicity Aquatic toxicity Assessment of aquatic toxicity: Very toxic (acute effect) to aquatic organisms. Toxicity to fish Information on: chlorfenapyr LC50 (96 h) 0.00744 mg/l, Oncorhynchus mykiss ---------------------------------- Aquatic invertebrates


Information on: chlorfenapyr EC50 (96 h) 0.00203 mg/l, Mysidopsis bahia (Directive 84/449/EEC, C.2) ---------------------------------- Aquatic plants Information on: chlorfenapyr EC50 (72 h) 0.132 mg/l, Desmodesmus subspicatus ---------------------------------- Assessment of terrestrial toxicity Acutely very toxic to terrestrial organisms. Additional information Other ecotoxicological advice: The ecological data given are those of the active ingredient. Do not release untreated into natural waters.


Waste disposal of substance: Pesticide wastes are regulated. Improper disposal of excess pesticide, spray mix or rinsate is a violation of federal law. If pesticide wastes cannot be disposed of according to label instructions, contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Container disposal: Consult state or local disposal authorities for approved alternative procedures such as container recycling. Do not reuse empty containers. RCRA: This product is not regulated by RCRA.



Hazard class: 2.2 ID number: UN 1950 Hazard label: 2.2, EHSM Proper shipping name: AEROSOLS

Sea transport IMDG Hazard class: 2.2 ID number: UN 1950 Hazard label: 2.2, EHSM Marine pollutant: YES Proper shipping name: AEROSOLS



Hazard class: 2.2 ID number: UN 1950 Hazard label: 2.2 Proper shipping name: AEROSOLS, NON-FLAMMABLE Further information DOT: This product may be classified as ORM-D (Consumer Commodity) or Limited Quantity. After 12/31/2020, ORM-D will not apply.


Federal Regulations Registration status: Crop Protection TSCA, US released / exempt Chemical TSCA, US blocked / not listed EPCRA 311/312 (Hazard categories): Acute; Chronic CERCLA RQ CAS Number Chemical name 5000 LBS 67-64-1 Acetone State regulations State RTK CAS Number Chemical name PA 67-64-1

64742-47-8 Acetone Distillates (petroleum), hydrotreated light

MA 67-64-1 64742-47-8

Acetone Distillates (petroleum), hydrotreated light

NJ 67-64-1 64742-47-8

Acetone Distillates (petroleum), hydrotreated light

CA Prop. 65: There are no listed chemicals in this product. NFPA Hazard codes: Health : 1 Fire: 1 Reactivity: 1 Special: Labeling requirements under FIFRA This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label. CAUTION: KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. Avoid contact with the skin, eyes and clothing.


Avoid inhalation of mists/vapours. Wash thoroughly after handling.




SAFETY DATA SHEETPURGEÒ III INSECTICIDE


Format: NAVersion 1


Product Identifier

Product Name PURGEÒ III INSECTICIDE



Synonyms PIPERONYL BUTOXIDE: Butylcarbityl(6-propylpiperonyl) ether, 1,3-Benzodioxole,5-[[2-(2-butoxyethoxy)ethoxy]methyl]-6-propyl-; N-OCTYL BICYCLOHEPTENEDICARBOXIMIDE: N-(2-ethylhexyl)-5-norbornene-2,3-dicarboximide;N-(2-ethylhexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide; Pyrethrins

Active Ingredient(s) Piperonyl Butoxide, n-Octyl bicycloheptene dicarboximide, Pyrethrins







Classification



Acute toxicity - Inhalation (Dusts/Mists) Category 4Aspiration toxicity Category 1



Page 1 / 9

Gases Under Pressure Compressed Gas

Return to Index...

PURGEÒ III INSECTICIDESDS # : 6586-A


EMERGENCY OVERVIEW

Precautionary Statements - PreventionP261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ sprayP210 - Keep away from heat/sparks/open flames/hot surfaces. - No smokingP211 - Do not spray on an open flame or other ignition sourceP251 - Do not pierce or burn, even after useP304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathingP312 - Call a POISON CENTER or doctor if you feel unwellP301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctorP331 - Do NOT induce vomiting

Precautionary Statements - StorageP405 - Store locked upP410 + P403 - Protect from sunlight. Store in a well-ventilated placeP412 - Do not expose to temperatures exceeding 50 °C/ 122 °F



Other Information No information available.


Chemical name CAS-No Weight %Piperonyl butoxide 51-03-6 1.95

n-Octyl bicycloheptene dicarboximide 113-48-4 3.05Pyrethrins 8003-34-7 0.975

1,1-Difluoroethane 75-37-6 40-50Petroleum distillates, hydrotreated light 64742-47-8 30-40Petroleum gases, liquified, sweetened 68476-86-8 10-20



Danger

Hazard StatementsH304 - May be fatal if swallowed and enters airwaysH332 - Harmful if inhaledPhysical HazardsH223 - Flammable aerosolH280 - Contains gas under pressure; may explode if heated

Page 2 / 9





Inhalation Move to fresh air. If person is not breathing, call 911 (within the U.S. and Canada) or anambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call apoison control center or doctor for further treatment advice.





Contains petroleum distillate. Vomiting may cause aspiration pneumonia. Treatsymptomatically.











Environmental Precautions Keep people and animals away from and upwind of spill/leak. Keep material out of lakes,streams, ponds, and sewer drains.





Page 3 / 9






Control parameters








64742-47-8

TWA: 200 mg/m3

Skin- - -






Hand Protection Rubber/latex/neoprene or other suitable chemical resistant gloves.






Appearance Clear, Aerosolized liquidPhysical State Liquid AerosolColor ClearOdor No information availableOdor threshold No information availablepH No information availableMelting point/freezing point Not applicableBoiling Point/Range No information availableFlash point > 85 °C / > 185 °F (8-inch Flame Extension)Evaporation Rate No information availableFlammability (solid, gas) No information available

Page 4 / 9



Flammability Limit in AirUpper flammability limit: No information availableLower flammability limit: No information available

Vapor pressure No information availableVapor density No information availableDensity 6.9 lb/galSpecific gravity No information availableWater solubility No information availableSolubility in other solvents No information availablePartition coefficient No information availableAutoignition temperature No information availableDecomposition temperature No information availableViscosity, kinematic No information availableViscosity, dynamic No information availableExplosive properties No information availableOxidizing properties No information availableMolecular weight No information availableBulk density No information available


Reactivity None under normal use conditions.




Conditions to avoid Keep away from open flames, hot surfaces and sources of ignition.


Hazardous Decomposition Products Carbon oxides (COx), Hydrogen fluoride, Carbonyl fluoride.


Product Information

LD50 Oral 2140 mg/kg (rat)LD50 Dermal > 2000 mg/kg (rabbit)LC50 Inhalation 2.5 mg/L (rat)

Eye Contact Slightly or non-irritating (rabbit)Skin Contact Slightly or non-irritating (rabbit)Sensitization Non-sensitizing




Mutagenicity Piperonyl butoxide ether may affect mammalian liver microsomal detoxification enzymes.n-Octyl bicycloheptene dicarboximide was negative in a chromosome aberration assay,

Carcinogenicity Not recognized as carcinogenic by Research Agencies (IARC, NTP, OSHA, ACGIH).Reproductive toxicity No information available.STOT - single exposure Not classified.STOT - repeated exposure Not classified.

Page 5 / 9



Target organ effects Mice fed 0.3 or 0.9% piperonyl butoxide in the diet for 20 days had increased liver weightand other signs of liver toxicity. Male rats given up to 2.4% of piperonyl butoxide in the dietfor up to 12 weeks had clinical and histologic signs of liver damage; the highest dose groupshowed preneoplastic changes, including enlargement of hepatocyte nuclei andmultinucleated cells. Kidney damage was also seen.

Aspiration hazard Potential for aspiration if swallowed. May be fatal if swallowed and enters airways.Chemical name ACGIH IARC NTP OSHA


Group 3


Ecotoxicity









DOT USDOT is requiring that products formerly classified as "Consumer Commodity, ORM-D"transition to "Limited Quantity" by 12/31/2020. During the transition period the 49CFRcarton shipping marks may be Consumer Commodity (old) or Limited Quantity Diamond(new). Please prepare shipping documents to match the carton mark.

Packaging Type 7.3 oz ContainersProper Shipping Name Consumer commodityHazard class ORM-D

TDG UN/ID no UN1950Proper Shipping Name AerosolsHazard class 2.1Description UN1950, Aerosols (1-1-Difluroethane, Isopropyl alcohol), 2.1

ICAO/IATA UN/ID no ID8000Proper Shipping Name Consumer commodityHazard class 9

IMDG/IMO UN/ID no UN1950

Page 6 / 9



Proper Shipping Name AerosolsHazard class 2.1EmS No. F-D, S-UDescription UN1950, Aerosols (1-1-Difluoroethane, Isopropyl alcohol), 2.1



Chemical name CAS-No Weight % SARA 313 - ThresholdValues %

Piperonyl butoxide - 51-03-6 51-03-6 1.95 1.0

SARA 311/312 Hazard Categories Acute health hazard YesChronic health hazard YesFire hazard YesSudden release of pressure hazard NoReactive Hazard No






1 lb



RQ




CAUTIONContains petroleum distilliate. Harmful if absorbed through the skin.




Page 7 / 9



Chemical name New Jersey Massachusetts PennsylvaniaPiperonyl butoxide

51-03-6X


X X X

1,1-Difluoroethane 75-37-6

X X



DSL(Canada)

EINECS/ELINCS

(Europe)

ENCS(Japan)

China(IECSC)

KECL(Korea)

PICCS(Philippines)

AICS(Australia)

Piperonyl butoxide 51-03-6 ( 1.95 )

X X X X X X X X

n-Octylbicycloheptenedicarboximide

113-48-4 ( 3.05 )

X X X X X X

Pyrethrins 8003-34-7 ( 0.975 )

X X X X X X

1,1-Difluoroethane 75-37-6 ( 40-50 )

X X X X X X X X


hydrotreated light 64742-47-8 ( 30-40

)

X X X X X X X X

Petroleum gases,liquified, sweetened 68476-86-8 ( 10-20

)

X X X X X X X

Mexico - Grade Moderate risk, Grade 2

CANADA

WHMIS Hazard Class A - Compressed gasesB5 - Flammable aerosolD2B - Toxic materials





Page 8 / 9








Page 9 / 9

SAFETY DATA SHEETPyrethrin Fogger


Format: NAVersion 1.01


Product Identifier

Product Name Pyrethrin Fogger



Synonyms (Z)-(S)-2-methyl-4-oxo-3-(penta-2,4-dienyl)cyclopent-2-enyl(1R,3R)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate5-[2-(2-butoxyethoxy)ethoxymethyl]-6-propyl-1,3-benzodioxole;5-[[2-(2-butoxyethoxy)ethoxy]methyl]-6-propyl-1,3-benzodioxole N-(2-ethylhexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide;2-(2-ethylhexyl)-3a,4,7,7a-tetrahydro-4,7-methano-1H-isoindole-1,3(2H)-dione

Active Ingredient(s) Pyrethrins, Piperonyl Butoxide, n-Octyl bicycloheptene dicarboximide (MGK264)

Chemical Family Pyrethrins







Classification



Acute toxicity - Inhalation (Dusts/Mists) Category 4

Page 1 / 9

Return to Index...

Pyrethrin FoggerSDS # : 6597-A


Skin sensitization Category 1


EMERGENCY OVERVIEW

Precautionary Statements - PreventionP261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ sprayP272 - Contaminated work clothing should not be allowed out of the workplaceP280 - Wear protective glovesP210 - Keep away from heat/sparks/open flames/hot surfaces. - No smokingP211 - Do not spray on an open flame or other ignition sourceP251 - Do not pierce or burn, even after useP302 + P352 - IF ON SKIN: Wash with plenty of water and soapP333 + P313 - If skin irritation or rash occurs: Get medical advice/ attentionP363 - Wash contaminated clothing before reuseP304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathingP312 - Call a POISON CENTER or doctor if you feel unwell

Precautionary Statements - StorageP410 + P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F



Other Information No information available


Chemical Family Pyrethrins.

Chemical name CAS-No Weight %n-Octyl bicycloheptene dicarboximide 113-48-4 1.0

Piperonyl butoxide 51-03-6 1.0Pyrethrins 8003-34-7 0.5Propane 74-98-6 10-20Butane 106-97-5 5-10

Petroleum distillates, hydrotreated light 64742-47-8 5-10Isobutane 75-28-5 5-10


Danger

Hazard StatementsH317 - May cause an allergic skin reactionH332 - Harmful if inhaledPhysical HazardsH222 - Extremely flammable aerosolH229 - Pressurized container: May burst if heated

Page 2 / 9










None known.

















Page 3 / 9







Control parameters





Propane 74-98-6

TWA: 1000 ppm TWA: 1000 ppmTWA: 1800 mg/m3

IDLH: 2100 ppmTWA: 1000 ppm

TWA: 1800 mg/m3

-

Isobutane 75-28-5

STEL 1000 ppm - TWA: 800 ppmTWA: 1900 mg/m3

-



Propane 74-98-6

TWA: 1000 ppm TWA: 1000 ppmTWA: 1800 mg/m3

TWA: 1000 ppm TWA: 1000 ppm


64742-47-8

TWA: 200 mg/m3

Skin- - -

Isobutane 75-28-5

TWA: 1000 ppm - TWA: 800 ppm TWA:1000 ppm

-










Page 4 / 9





Appearance No information availablePhysical State AerosolColor No information availableOdor Slight PyrethrinsOdor threshold No information availablepH 7.0Melting point/freezing point Not applicableBoiling Point/Range No information availableFlash point 2.8-3.3 °C / 37-38 °FEvaporation Rate No information availableFlammability (solid, gas) No information availableFlammability Limit in Air


Vapor pressure No information availableVapor density No information availableDensity 8 lb/galSpecific gravity No information availableWater solubility Soluble in waterSolubility in other solvents No information availablePartition coefficient No information availableAutoignition temperature No information availableDecomposition temperature No information availableViscosity, kinematic No information availableViscosity, dynamic No information availableExplosive properties No information availableOxidizing properties No information availableMolecular weight No information availableBulk density No information available


Reactivity Not applicable




Conditions to avoid Keep away from open flames, hot surfaces and sources of ignition


Hazardous Decomposition Products Carbon dioxide (CO2). Carbon monoxide (CO).


Product Information

LD50 Oral > 5000 mg/kgLD50 Dermal > 5000 mg/kgLC50 Inhalation > 2.11 mg/L 4 hr

Serious eye damage/eye irritation Slightly or non-irritating (rabbit).Skin corrosion/irritation Slightly or non-irritating (rabbit).Sensitization Sensitizer.

Page 5 / 9






Mutagenicity Piperonyl butoxide ether may affect mammalian liver microsomal detoxification enzymes.n-Octyl bicycloheptene dicarboximide was negative in a chromosome aberration assay,.

Carcinogenicity Not recognized as carcinogenic by Research Agencies (IARC, NTP, OSHA, ACGIH).Reproductive toxicity No information available.STOT - single exposure Not classified.STOT - repeated exposure Not classified.Target organ effects Mice fed 0.3 or 0.9% piperonyl butoxide in the diet for 20 days had increased liver weight

and other signs of liver toxicity. Male rats given up to 2.4% of piperonyl butoxide in the dietfor up to 12 weeks had clinical and histologic signs of liver damage; the highest dose groupshowed preneoplastic changes, including enlargement of hepatocyte nuclei andmultinucleated cells. Kidney damage was also seen.



Group 3


Ecotoxicity









DOT USDOT is requiring that products formerly classified as "Consumer Commodity, ORM-D"transition to "Limited Quantity" by 12/31/2020. During the transition period the 49CFRcarton shipping marks may be Consumer Commodity (old) or Limited Quantity Diamond(new). Please prepare shipping documents to match the carton mark.

Proper Shipping Name Consumer commodityHazard class ORM-D

TDG

Page 6 / 9



UN/ID no UN1950Proper Shipping Name AerosolsHazard class 2.1Description UN1950, Aerosols, 2.1

ICAO/IATA UN/ID no ID8000Proper Shipping Name Consumer commodityHazard class 9

IMDG/IMO UN/ID no UN1950Proper Shipping Name AerosolsHazard class 2EmS No. F-D, S-UDescription UN1950, Aerosols, 2.1




Piperonyl butoxide - 51-03-6 51-03-6 1.002 1.0

SARA 311/312 Hazard Categories Acute health hazard YesChronic health hazard YesFire hazard NoSudden release of pressure hazard NoReactive Hazard No






1 lb



RQ




CAUTIONProlonged or frequently repeated skin contact may cause allergic reactions in some individuals.

Page 7 / 9






Chemical name New Jersey Massachusetts PennsylvaniaPiperonyl butoxide

51-03-6X


X X X

Propane 74-98-6

X X X

Isobutane 75-28-5

X X X



DSL(Canada)

EINECS/ELINCS

(Europe)

ENCS(Japan)

China(IECSC)

KECL(Korea)

PICCS(Philippines)

AICS(Australia)

n-Octylbicycloheptenedicarboximide

113-48-4 ( 1.0 )

X X X X X X

Piperonyl butoxide 51-03-6 ( 1.0 )

X X X X X X X X

Pyrethrins 8003-34-7 ( 0.5 )

X X X X X X

Propane 74-98-6 ( 10-20 )

X X X X X X X X


hydrotreated light 64742-47-8 ( 5-10 )

X X X X X X X X

Isobutane 75-28-5 ( 5-10 )

X X X X X X X X

WHMIS Hazard Class A - Compressed gasesB5 - Flammable aerosol


NFPA/HMIS Ratings Legend * - Chronic hazard



HMIS Health Hazards 1* Flammability 4

Page 8 / 9








Page 9 / 9

SAFETY DATA SHEET (GHS)

Date Issued : 10/6/2015

MSDS No : PYROCIDE300

Date-Revised : 10/6/2015

Revision No : 1

PYROCIDE® 300


PRODUCT NAME: PYROCIDE® 300

PRODUCT DESCRIPTION: An Insecticide for Indoor Use as a ULV, Space, Area, Contact Spray, or Thermal Fog.

PRODUCT CODE: 5628, EPA REG. NO. : 1021-1177

ACTIVE INGREDIENT(S): Pyrethrins; Piperonyl Butoxide; MGK®-264 (N-Octyl Bicycloheptene Dicarboximide)

MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS

McLaughlin Gormley King Company

8810 10th Avenue North

Minneapolis, MN 55427

Emergency Phone: 1(888) 740-8712

Alternate Emergency Phone: 1(952) 852-9509

Product Stewardship: 1(800) 645-6466

E-Mail: [email protected]

FOR TRANSPORTATION:

CHEMTREC® U.S. and CANADA:1(800) 424-9300

CHEMTREC® All Other Areas:1(703) 527-3887

COMMENTS: MGK® Hours of operation are 8:00 am to 4:30 pm CST, 14:00 to 22:30 GMT.

For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day to 1-888-740-8712 or 1-952-852-9509 outside of

the U.S.A.


GHS CLASSIFICATIONS

Health:

Skin Sensitization, Category 1

Aspiration Hazard, Category 1

Environmental:

Acute Hazards to the Aquatic Environment, Category 1

Chronic Hazards to the Aquatic Environment, Category 1

Physical:

Flammable Liquids, Category 4

GHS LABEL

Exclamation

mark

(GHS 07)

Health

hazard

(GHS 08)

Environment

(GHS 09)

SIGNAL WORD: DANGER

HAZARD STATEMENTS

H304: May be fatal if swallowed and enters airways.

H317: May cause an allergic skin reaction.

H400: Very toxic to aquatic life.

Page 1 of 8

Return to Index...





Revision No : 1

PYROCIDE® 300

H410: Very toxic to aquatic life with long lasting effects.

H227: Combustible liquid.

PRECAUTIONARY STATEMENT(S)

Prevention:

P202: Do not handle until all safety precautions have been read and understood.

P210: Keep away from heat/sparks/open flames/hot surfaces. – No smoking.

P240: Ground/bond container and receiving equipment.

P241: Use explosion-proof electrical/ventilating/lighting equipment.

P243: Take precautionary measures against static discharge.

P264: Wash hands, face, and any exposed skin thoroughly after handling.

P272: Contaminated work clothing should not be allowed out of the workplace.

P280: Wear protective gloves/protective clothing/eye protection/face protection.

Response:

P321: Specific treatment (see Section 4/ First Aid).

P302+P352: IF ON SKIN: Wash with plenty of soap and water.

P333+P313: If skin irritation or rash occurs: Get medical advice/attention.

P362: Take off contaminated clothing and wash before reuse.

P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P331: Do NOT induce vomiting.

P370+P378: In case of fire: Use CO2, dry chemical, or foam for extinction.

Storage:

P405: Store locked up.

P404: Store in a closed container.

P403+P235: Store in a well-ventilated place. Keep cool.

Disposal:

P501: Dispose of contents/container to an approved waste disposal plant.

COMMENTS: This material is considered hazardous by the 2012 OSHA Hazard Communication Standard [29 CFR 1910.1200],

and the G.H.S.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical Name Wt.% CAS

Pyrethrins 3 8003-34-7

Piperonyl Butoxide 6 51-03-6

MGK®-264 (N-Octyl Bicycloheptene Dicarboximide) 9.57 113-48-4

Petroleum Distillates 50 - 75 64742-47-8

COMMENTS: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications.


EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5

minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.

SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center

Page 2 of 8





Revision No : 1

PYROCIDE® 300

or doctor for treatment advice.

INGESTION: If swallowed, IMMEDIATELY call a poison control center or doctor for treatment advice. DO NOT give any liquid to

the person. Do not induce vomiting unless told to do so by a poison contol center or a doctor. Never give anything by mouth to

an unconscious person.

INHALATION: Remove affected person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial

respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice.

NOTES TO PHYSICIAN: Contains Pyrethrins and Petroleum Distillates-vomiting may pose an aspiration pneumonia hazard.

For skin effects, a highly efficient therapeutic agent for Pyrethrin exposure is topical application of Tocopherol Acetate (Vitamin

E).


FLAMMABLE CLASS: OSHA-COMBUSTIBLE LIQUID

EXTINGUISHING MEDIA: Foam, carbon dioxide or dry chemical.

HAZARDOUS COMBUSTION PRODUCTS: Under fire conditions this product will support combustion and may decompose to

give off toxic gases such as carbon monoxide, carbon dioxide, and nitrogen oxides.

FIRE FIGHTING PROCEDURES: Treat as an oil fire. Use a full-faced self-contained breathing apparatus along with full protective

gear. Keep nearby containers and equipment cool with a water stream.

SENSITIVE TO STATIC DISCHARGE: Yes, use proper bonding and/or grounding procedures.


SMALL SPILL: Shut off ignition sources. Stop release, if possible without risk. Dike or contain release, if possible, and if

immediate response can prevent further damage or danger. Isolate and control access to the release area. Take actions to

reduce vapors. Absorb with appropriate absorbent. Clean spill area of residues and absorbent.

LARGE SPILL: Shut off ignition sources. Stop release, if possible without risk. Dike or contain release, if possible, and if

immediate response can prevent further damage or danger. Isolate and control access to the release area. Take actions to

reduce vapors. Collect product into drums, etc. via drains, pumps, etc. Absorb with appropriate absorbent. Clean spill area of

residues and absorbent.

ENVIRONMENTAL PRECAUTIONS

WATER SPILL: Contains Pyrethrins, which are toxic to fish and other aquatic invertebrates. Contaminated absorbent and wash

water should be disposed of according to local, state, and federal regulations.


GENERAL PROCEDURES: Do not use or store near heat, sparks, open flame, or any other ignition sources.

HANDLING: Mixers, loaders, and other handlers:

Wear a long-sleeved shirt and long pants, shoes and socks.

Wear chemical-resistant gloves such as Barrier Laminate, Neoprene Rubber, Nitrile Rubber, or Viton.

Applicators using a high-pressure hand-wand in an enclosed-area must also wear the following additional PPE:

A MSHA/ NIOSH-approved respirator with a dust/ mist filter with MSHA/ NIOSH approval number prefix TC-21C, or any R, P or

HE filter.

Page 3 of 8





Revision No : 1

PYROCIDE® 300

Applicators using hand-held foggers in an enclosed-area must also wear the following additional PPE:

Wear a MSHA/ NIOSH-approved respirator, such as a half-face, full-face, or hood-style NIOSH-approved respirator with a dust/

mist filtering cartridge (MSHA/ NIOSH approval number prefix TC-21C), or a canister approved for pesticides (MSHA/ NIOSH

approval number prefix TC-14G), or a cartridge or canister with any N, R, P or HE filter.

Do not contaminate water, food or feedstuffs by storage, handling, or disposal.

READ AND OBSERVE ALL PRECAUTIONS AND INSTRUCTIONS ON THE PRODUCT LABEL.

STORAGE: Store in a cool, dry, well-ventilated place. Keep container closed. Do not use or store near heat, sparks, open flame,

any ignition sources, or near strong acids, bases, and oxidizers. Always store pesticides in the original container. Store away

from food and pet-food.

KEEP OUT OF REACH OF CHILDREN.

ELECTROSTATIC ACCUMULATION HAZARD: This product contains petroleum distillates for which there is potential for the

accumulation of static electricity. Consideration should be given to bonding and grounding of equipment during loading,

unloading, and transfer of this product.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE GUIDELINES

OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)

EXPOSURE LIMITS

OSHA PEL ACGIH TLV SupplierOEL

Chemical Name ppm mg/m3 ppm mg/m3 ppm mg/m3

Pyrethrins TWA 5 5

Piperonyl Butoxide TWA None None None

MGK®-264 (N-Octyl Bicycloheptene Dicarboximide) TWA None None None

Petroleum Distillates TWA None None 152 [1] 1200 [1]

OSHA TABLE COMMENTS:

1. Based on total hydrocarbon composition.

ENGINEERING CONTROLS: Ventilate treatment area thoroughly before re-entry.

PERSONAL PROTECTIVE EQUIPMENT

EYES AND FACE: Take prudent precautions to avoid contact with eyes.

SKIN: Wear chemical-resistant gloves such as Barrier Laminate, Neoprene Rubber, Nitrile Rubber, or Viton, and wear

protective clothing.

RESPIRATORY: Applicators using a high-pressure hand-wand in an enclosed-area must also wear the following additional

PPE:

A MSHA/ NIOSH-approved respirator with a dust/ mist filter with MSHA/ NIOSH approval number prefix TC-21C, or any N, R,

P or HE filter.

Applicators using hand-held foggers in an enclosed-area must also wear the following additional PPE:

Wear a MSHA/ NIOSH-approved respirator, such as a half-face, full-face, or hood-style NIOSH-approved respirator with a

Page 4 of 8





Revision No : 1

PYROCIDE® 300

dust/ mist filtering cartridge (MSHA/ NIOSH approval number prefix TC-21C), or a canister approved for pesticides (MSHA/

NIOSH approval number prefix TC-14G), or a cartridge or canister with any N, R, P or HE filter.

PROTECTIVE CLOTHING: Wear a long-sleeved shirt and long pants, shoes and socks.

WORK HYGIENIC PRACTICES: DO NOT SMOKE, EAT, OR DRINK, OR APPLY COSMETICS IN WORK AREA!

Wash promptly if skin becomes contaminated. Wash at the end of each work shift and before eating, smoking, or using the

toilet.


PHYSICAL STATE: Liquid

ODOR: Strong solvent-odor.

APPEARANCE: Dark, amber-colored liquid.

COLOR: 8.5 on Gardner Scale

pH: Not Applicable; Product not intended to be diluted in water.

FLASHPOINT AND METHOD: 83.3°C (182°F) TAG Closed Cup

VAPOR DENSITY: Heavier than air.

FREEZING POINT: Not Determined

SOLUBILITY IN WATER: Immiscible in water.

SPECIFIC GRAVITY: 0.827 (Water = 1) at 20°C (68°F)

VISCOSITY #1: 10.5 cPs at 24.5°C (76.1°F)

(VOC): < 6.000 %


STABLE: Yes

HAZARDOUS POLYMERIZATION: No

CONDITIONS TO AVOID: Not compatible with strong acids or bases. Not compatible with strong oxidizers.


ACUTE

DERMAL LD50: > 2.0 gm/kg

Notes: Albino rabbit.

ORAL LD50: > 5.0 gm/kg

Notes: Albino rat.

INHALATION LC50: > 8.40 mg/L

Notes: Rats exposed for 4 hours to test atmosphere. The Acute Inhalation LC50 of this material places it in EPA Toxic

Category IV.

EYE EFFECTS: Irritation clearing in 24 hours.

SKIN EFFECTS: Slight irritation at 72 hours. Irritation Index = 0.96

SENSITIZATION: When applied dermally to albino guinea pigs, this product appears to be a dermal sensitizer.

COMMENTS: None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC,

Page 5 of 8





Revision No : 1

PYROCIDE® 300

NTP, OSHA or ACGIH as being carcinogens.

Marginally higher incidences of benign liver tumors in mice were observed following lifetime high dose exposures to PBO. The

significance of these observations is questionable and under review. The doses at which tumors were observed for PBO greatly

exceeded potential human exposure from labeled uses. Doses at which these effects were observed greatly exceeded

anticipated human dietary intake. At anticipated dietary exposure levels, it is highly unlikely that this product will result in

carcinogenic effects.


ECOTOXICOLOGICAL INFORMATION: Do not discharge effluent containing this product into lakes, streams, ponds, estuaries,

oceans or other waters, unless in accordance with the requirements of a National Pollutant Discharge Elimination System

(NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing

this product into sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact

your State Water Board or Regional Office of the EPA.


DISPOSAL METHOD: To avoid wastes, use all materials in the containers by application according to label directions. If wastes

cannot be avoided, offer remaining product to a waste disposal facility or pesticide disposal program (NOTE: such programs are

often run by state or local governments, or by industry).

EMPTY CONTAINER: Non-refillable container. DO NOT reuse or refill this container.

Triple-rinse container (or equivalent) promptly after emptying. Then, offer for recycling if available, or puncture and dispose of

container in a sanitary landfill.

Triple-rinse as follows for containers less than < 5 gallons (< 18.9 L) or less: Empty the remaining contents into application

equipment or a mix-tank and drain for 10 seconds after the flow begins to drip. Fill the container 1/4 full with water and re-cap.

Shake for 10 seconds. Pour rinsate into application equipment or a mix-tank or store rinsate for later use or disposal. Drain for

10 seconds after the flow begins to drip. Repeat this procedure two more times.

Triple-rinse as follows for containers greater than > 5 gallons (> 18.9 L): Empty the remaining contents into application

equipment or a mix-tank. Fill the container 1/4 full with water. Replace and tighten closures. Tip container on its side and roll

back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the container on its end and tip it back and forth

several times. Turn the container over onto its other end and tip it back and forth several times. Empty the rinsate into

application equipment or a mix-tank or store rinsate for later use or disposal. Repeat this procedure two more times.

RCRA/EPA WASTE INFORMATION: This product contains the following RCRA/CERCLA Hazardous wastes/substances:

Component, RCRA ID#, CERCLA RQ:

Pyrethrins, N/A, 1 Lb.


DOT (DEPARTMENT OF TRANSPORTATION)

PROPER SHIPPING NAME: UN3082, Environmentally Hazardous Substance, Liquid, N.O.S., RQ (Pyrethrins)

PRIMARY HAZARD CLASS/DIVISION: 9

PACKING GROUP: III

REPORTABLE QUANTITY (RQ) UNDER CERCLA: 1 Lb. (Pyrethrins/ Pyrethrum)

Page 6 of 8





Revision No : 1

PYROCIDE® 300

OTHER SHIPPING INFORMATION: This product is not regulated as a hazardous material by the DOT in quantities less than <

33.3 Lbs.

Shipping name for quantities less than < 33.3 Lbs. : Insecticides, Insect or Animal Repellents, Liquid, N.O.S.

AIR (ICAO/IATA)

SHIPPING NAME: UN3082, Environmentally Hazardous Substance, Liquid, N.O.S., RQ (Pyrethrins)

PRIMARY HAZARD CLASS/DIVISION: 9

PACKING GROUP: III

VESSEL (IMO/IMDG)

SHIPPING NAME: Not Available


UNITED STATES

SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)

FIRE: Yes PRESSURE GENERATING: No REACTIVITY: No ACUTE: Yes

313 REPORTABLE INGREDIENTS:

COMPONENT, CAS#, Max %

Piperonyl Butoxide, 000051-03-6, > 1.0%

302/304 EMERGENCY PLANNING

EMERGENCY PLAN: There are no SARA Title III Section 302 extremely hazardous substances present in this formulation

(40 CFR 355).

See Section 13 of this MSDS for the components that are subject to emergency requirements under CERCLA Section

103(a)(40 CFR 302.4).

TSCA (TOXIC SUBSTANCE CONTROL ACT)

TSCA STATUS: All chemical substances found in this product comply with the Toxic Substances Control Act's inventory

reporting requirements.

REGULATIONS

STATE REGULATIONS:

VOLATILE ORGANIC COMPOUNDS (VOC):

This product contains less than 6% VOC’s.

CALIFORNIA PROPOSITION 65: This product DOES NOT contain any known ingredients for which the State of California has

found to cause cancer, birth defects, or other reporoductive harm, which requires a warning under the statute.

FIFRA (FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT):

NOTE: This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain

labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information

required for Safety Data Sheets, and for workplace labels of non-pesticide chemicals. The following is the hazard information as

required on the pesticide label:

CAUTION. Harmful if swallowed or absorbed through the skin. Contains petroleum distillates - Vomiting may cause aspiration

pneumonia. Avoid contact with skin, eyes, and clothing. Prolonged or frequently repeated skin contact may cause allergic reactions in

Page 7 of 8





Revision No : 1

PYROCIDE® 300

some individuals.


REVISION SUMMARY: This MSDS replaces the 10/6/2015 MSDS. Revised: Section 9: COLOR.

HMIS RATING

HEALTH 2

FLAMMABILITY 2

PHYSICAL HAZARD 1

PERSONAL PROTECTION

HMIS RATINGS NOTES: We assign HMIS ratings to this product based on the hazards of its ingredients(s). Since the customer is

most aware of the applications and conditions of use, he or she must ensure that the proper Personal Protective Equipment is

provided, consistent with the information contained in Section's 2, 7, and 8 of this MSDS.

COMMENTS: The data contained herein are based on information currently available to McLaughlin Gormley King Company and,

to the best of our knowledge, are accurate and based on sound expert opinion. Our statements herein, however, are not to be

taken as a warranty or representation for which McLaughlin Gormley King Company assumes legal responsibility.

MSDS Prepared by T. Azzivitto

Page 8 of 8

Safety Data Sheet RCO Omega Gopher Bait

SDS Revision Date: 04/28/2015

Page 1 of 8

1. Identification

1.1. Product identifier Product Identity RCO Omega Gopher BaitAlternate Names USEPA Reg # 5042-32

1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use See Technical Data Sheet. Application Method See Technical Data Sheet.

1.3. Details of the supplier of the safety data sheet Company Name RCO International, Inc.

P.O. Box 191Harrisburg, OR 97446

Emergency CHEMTREC (USA) (800) 424-9300Customer Service: RCO International, Inc. (541) 995-7799

2. Hazard(s) identification

2.1. Classification of the substance or mixture Acute Tox. 4;H302 Harmful if swallowed. Acute Tox. 3;H311 Toxic in contact with skin.

2.2. Label elements Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows.

Danger H302 Harmful if swallowed. H311 Toxic in contact with skin.

[Prevention]: P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product.

Return to Index...



Page 2 of 8

P280 Wear protective gloves / eye protection / face protection. [Response]: P301+312 IF SWALLOWED: Call a POISON CENTER or doctor / physician immediately. P302+352 IF ON SKIN: Wash with plenty of soap and water. P322 Specific measures (see information on this label). P330 Rinse mouth. P361 Remove / Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. [Storage]: P405 Store locked up. [Disposal]: P501 Dispose of contents / container in accordance with local / national regulations.

3. Composition/information on ingredients There are no ingredients in this product which are in a concentration above the GHS cutoff. Contains active ingredient Strychnine (CAS Number 57-24-9) at 0.5%

4. First aid measures

4.1. Description of first aid measures General In all cases of doubt, or when symptoms persist, seek medical attention.

Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give

artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth.

Eyes Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and seek medical attention.

Skin Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognized skin cleanser.

Ingestion If less than ten (10) minutes have passed since the poison was taken, give or 2 glasses of water and induce vomiting by touching back of the throat with finger. Repeat until vomit fluid is clear. Have patient lie down in a quiet, darkened room and keep him warm and quiet. If person is unconscious, do not give anything by mouth and do not induce vomiting.

4.2. Most important symptoms and effects, both acute and delayed Overview DANGER:

Convulsive Poison! Fatal if swallowed or inhaled. Harmful if absorbed through skin. Do not get in eyes or on clothing. Avoid contact with skin. Do not breathe dust. Do not apply this product in a way that will contact any person or pet. Wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove contaminated clothing and wash clothing before reuse.



Page 3 of 8

Note to Physician: A. Administer 100% OXYGEN by positive pressure to provide as much pulmonary gas exchange as possible, despite seizures. B. Administer ANTICONVULSANT DRUGS intravenously to control convulsions. NOTICE: It may be difficult or impossible to stop the seizure activity without stopping respiration. Be prepared to maintain pulmonary ventilation mechanically. Tracheotomy may be necessary if seizures are prolonged. See section 2 for further details.

Skin Toxic in contact with skin. Ingestion Harmful if swallowed.

5. Fire-fighting measures

5.1. Extinguishing media Recommended extinguishing media; alcohol resistant foam, CO2, powder, water spray. Do not use; water jet. 5.2. Special hazards arising from the substance or mixture Hazardous decomposition: No hazardous decomposition data available. 5.3. Advice for fire-fighters When heated, strychnine emits highly toxic fumes, thus firefighters must wear self-contained breathing apparatus. ERG Guide No. ----

6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Put on appropriate personal protective equipment (see section 8). 6.2. Environmental precautions This product is toxic to fish, birds and other wildlife. Do not allow bait to be exposed on soil surface. Do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water by cleaning or equipment, or disposal of wastes. Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. 6.3. Methods and material for containment and cleaning up Sweep up spilled materials completely and either use according to label directions or take to an approved pesticide disposal site in a sealed container. Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spilled bait, or reinstate is a violation of Federal law. If these wastes cannot be disposed of by label instructions, contact your State Pesticide or Environment Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.



Page 4 of 8

7. Handling and storage

7.1. Precautions for safe handling Non-refillable container. Do not reuse or refill this container. Offer to recycling, if available. Completely empty bag by shaking and tapping sides and bottom to loosen clinging particles. Empty residue into application equipment. Then dispose of bags in a sanitary landfill or by incineration if allowed by state and local authorities. See section 2 for further details. - [Prevention]: 7.2. Conditions for safe storage, including any incompatibilities Handle containers carefully to prevent damage and spillage. Incompatible materials: No data available. Store only in original container, in a dry place inaccessible to children, pets and domestic animals. See section 2 for further details. - [Storage]: 7.3. Specific end use(s) Keep away from children and pets.

8. Exposure controls and personal protection 8.1. Control parameters There are no ingredients in this product which are in a concentration above the GHS cutoff. Contains active ingredient Strychnine (CAS Number 57-24-9) at 0.5% Strychnine has an OSHA PEL of 0.15 mg/m3 (TWA) and ACGIH TLV of 0.15 mg/m3 (TWA) 8.2. Exposure controls Respiratory If workers are exposed to concentrations above the exposure limit they must use the

appropriate, certified respirators. MSHA/NIOSH approval # prefix TC-21C or NIOSH w/ N,P,R,HE filter.

Eyes Safety Goggles Skin Wear love sleeved shirts, pants, shoes with socks, and rubber gloves. Engineering Controls Provide adequate ventilation. Where reasonably practicable this should be achieved by the

use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn.

Other Work Practices Follow manufacturer’s instructions for cleaning and maintaining PPE. If there are no such instructions, use detergent and hot water. Keep and wash PPE separately from other laundry Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.

See section 2 for further details. - [Prevention]:



Page 5 of 8

9. Physical and chemical properties Appearance Green Solid Odor Slight smell of anise oil Odor threshold Not Measured pH Not Measured Melting point / freezing point Not Measured Initial boiling point and boiling range 518F Flash Point Not Measured Evaporation rate (Ether = 1) Not Measured Flammability (solid, gas) Not Applicable Upper/lower flammability or explosive limits Lower Explosive Limit: Not Measured Upper Explosive Limit: Not Measured Vapor pressure (Pa) Not Measured Vapor Density Not Measured Specific Gravity Not Measured Solubility in Water Insoluble Partition coefficient n-octanol/water (Log Kow) Not Measured Auto-ignition temperature Not Measured Decomposition temperature Not Measured Viscosity (cSt) Not Measured Bulk Density 5.5 lbs/gal 9.2. Other information No other relevant information.

10. Stability and reactivity 10.1. Reactivity Hazardous Polymerization will not occur. 10.2. Chemical stability Stable under normal circumstances. 10.3. Possibility of hazardous reactions No data available. 10.4. Conditions to avoid Excessive heat and open flame. 10.5. Incompatible materials Compatible with most materials. 10.6. Hazardous decomposition products May occur when bait is heated or burned.



Page 6 of 8

11. Toxicological information Acute toxicity There are no ingredients in this product which are in a concentration above the GHS cutoff. Contains active ingredient Strychnine (CAS Number 57-24-9) at 0.5% Strychnine has an oral LD50 of 16 mg/kg (rat) The lethal dose to man is 30-60 mg/kg of strychnine, equivalent to one gram of bait per kilogram of body weight. Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate). Classification Category Hazard Description Acute toxicity (oral) 4 Harmful if swallowed. Acute toxicity (dermal) 3 Toxic in contact with skin. Acute toxicity (inhalation) --- Not Applicable Skin corrosion/irritation --- Not Applicable Serious eye damage/irritation --- Not Applicable Respiratory sensitization --- Not Applicable Skin sensitization --- Not Applicable Germ cell mutagenicity --- Not Applicable Carcinogenicity --- Not Applicable Reproductive toxicity --- Not Applicable STOT-single exposure --- Not Applicable STOT-repeated exposure --- Not Applicable Aspiration hazard --- Not Applicable

12. Ecological information 12.1. Toxicity The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and GHS and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 3 for details Aquatic Ecotoxicity There are no ingredients in this product which are in a concentration above the GHS cutoff. Contains active ingredient Strychnine (CAS Number 57-24-9) at 0.5% Strychnine is expected to be very toxic to aquatic and terrestrial life. The LC50/96 hour values for fish are less than 1 mg/l



Page 7 of 8

12.2. Persistence and degradability There is no data available on the preparation itself. 12.3. Bioaccumulative potential Not Measured 12.4. Mobility in soil No data available. 12.5. Results of PBT and vPvB assessment This product contains no PBT/vPvB chemicals. 12.6. Other adverse effects No data available.

13. Disposal considerations 13.1. Waste treatment methods Observe all federal, state and local regulations when disposing of this substance.

14. Transport information This product is not regulated by DOT; Freight Class Number is 77.5.

15. Regulatory information Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected

regulations are represented. Toxic Substance Control Act ( TSCA)

All components of this material are either listed or exempt from listing on the TSCA Inventory.

WHMIS Classification D1B

US EPA Tier II Hazards Fire: No Sudden Release of Pressure: No Reactive: No Immediate (Acute): Yes Delayed (Chronic): No EPCRA 311/312 Chemicals and RQs: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. EPCRA 302 Extremely Hazardous: Strychnidin-10-one



Page 8 of 8

EPCRA 313 Toxic Chemicals: Strychnidin-10-one Proposition 65 - Carcinogens (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Developmental Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Female Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Male Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. N.J. RTK Substances (>1%) : To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Penn RTK Substances (>1%): Soybean oil

16. Other information The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders. The full text of the phrases appearing in section 3 is: Not Applicable

This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not applicable.

End of Document

SAFETY DATA SHEETTALSTAR® PL GRANULAR INSECTICIDE


Format: NAVersion 2


Product Identifier

Product Name TALSTAR® PL GRANULAR INSECTICIDE



Synonyms BIFENTHRIN: (2-methyl[1,1'-biphenyl]-3-yl)methyl3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethylcyclopropanecarboxylate (CAS name);2-methylbiphenyl-3-ylmethyl(Z)-(1RS)-cis-3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethylcyclopropanecarboxylate(IUPAC name)

Active Ingredient(s) Bifenthrin

Chemical Family Pyrethroid Pesticide


Recommended Use: Insecticide, Miticide





Classification



Carcinogenicity Category 1ASpecific target organ toxicity (single exposure) Category 1Specific target organ toxicity (repeated exposure) Category 1

Page 1 / 8

Return to Index...

TALSTAR® PL GRANULAR INSECTICIDESDS # : 1686-A



EMERGENCY OVERVIEW

Precautionary Statements - PreventionP201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP281 - Use personal protective equipment as requiredP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP270 - Do not eat, drink or smoke when using this productPrecautionary Statements - ResponseP321 - Specific treatment (see .? on this label)P308 + P311 - IF exposed or concerned: Call a POISON CENTER or doctor

Precautionary Statements - StorageP405 - Store locked up



Other Information Very toxic to aquatic life with long lasting effects


Chemical Family Pyrethroid Pesticide.

Chemical name CAS-No Weight %Bifenthrin 82657-04-3 0.2

crystalline silica, quartz 14808-60-7 >80





Danger

Hazard StatementsH350 - May cause cancerH370 - Causes damage to organsH372 - Causes damage to organs through prolonged or repeated exposure

Page 2 / 8




Ingestion Call a poison control center or doctor immediately for treatment advice Have person sip aglass of water if able to swallow. Do not induce vomiting unless told to do so by a poisoncontrol center or doctor. Do not give anything by mouth to an unconscious person.




Treat symptomatically. This product is a pyrethroid. If large amounts have been ingested,milk, cream, and other digestible fats and oils may increase absorption and so should beavoided.


Suitable Extinguishing Media Use CO2, dry chemical, or foam.


Powdered material may form explosive dust-air mixtures



As in any fire, wear self-contained breathing apparatus and full protective gear.


Personal Precautions Isolate and post spill area. Remove all sources of ignition. Ventilate the area. Wear suitableprotective clothing, gloves and eye/face protection. For personal protection see section 8.



Methods for Containment Use a wet sweeping compound or water to prevent dust formation.

Methods for cleaning up Sweep up and shovel into suitable containers for disposal. Clean and neutralize spill area,tools and equipment by washing with bleach water and soap. Absorb rinsate and add to thecollected waste. Waste must be classified and labeled prior to recycling or disposal.Dispose of waste as indicated in Section 13.


Handling Do not contaminate other pesticides, fertilizers, water, food, or feed by storage or disposal.

Storage Keep in a dry, cool and well-ventilated place. Keep away from open flames, hot surfacesand sources of ignition. Keep out of reach of children and animals. Store in originalcontainer.

Incompatible products None known


Control parameters

Page 3 / 8



Chemical name ACGIH TLV OSHA PEL NIOSH Mexicocrystalline silica, quartz

14808-60-7TWA: 0.025 mg/m3 See note IDLH: 50 mg/m3

TWA: 0.05 mg/m3Mexico: TWA 0.1 mg/m3

Chemical name British Columbia Quebec Ontario TWAEV Albertacrystalline silica, quartz

14808-60-7TWA: 0.025 mg/m3 TWA: 0.1 mg/m3 TWA: 0.10 mg/m3 TWA: 0.025 mg/m3












Appearance Light tan to tan , GranulesPhysical State SolidColor cream to tanOdor Slight MustyOdor threshold No information availablepH 6.8-7.1Melting point/freezing point Not applicableBoiling Point/Range No information availableFlash point Not applicableEvaporation Rate No information availableFlammability (solid, gas) No information availableFlammability Limit in Air


Vapor pressure No information availableVapor density No information availableDensity 1.39 lb/ft3

Specific gravity No information availableWater solubility No information availableSolubility in other solvents No information availablePartition coefficient No information availableAutoignition temperature No information availableDecomposition temperature No information availableViscosity, kinematic No information availableViscosity, dynamic No information availableExplosive properties No information available

Page 4 / 8



Oxidizing properties No information availableMolecular weight No information availableBulk density 50-53 lb/ft3


Reactivity None under normal use conditions




Conditions to avoid Excessive heat. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible materials None known.

Hazardous Decomposition Products Carbon oxides (COx), Hydrogen chloride, Hydrogen fluoride.


Product Information

LD50 Oral > 5000 mg/kg (rat)LD50 Dermal > 2000 mg/kg (rabbit)LC50 Inhalation No information available

Serious eye damage/eye irritation Non-irritating. Product dust may cause mechanical eye irritation.Skin corrosion/irritation Non-irritating.Sensitization Non-sensitizer.


Symptoms Large doses of bifenthrin ingested by laboratory animals produced signs of toxicity includingconvulsions, tremors and bloody nasal discharge.


Chronic toxicity Bifenthrin: Long-term exposure caused neurotoxicity (tremors and impaired gait) in the earlyexposure in animal studies, but tremors disappeared with continued exposure.

Mutagenicity Bifenthrin: Not genotoxic in laboratory studies.Carcinogenicity Bifenthrin: Weak treatment-related response for liver adenocarcinomas and benign bladder

tumors (lesion) in male mice. This product contains crystalline silica (quartz) in anon-respirable form. Inhalation of crystalline silica is unlikely to occur from exposure to thisproduct. However, if granules are pulverized or crushed into a fine, respirable powder, silicaexposure via inhalation is probable.

Neurological effects Bifenthrin: Causes clinical signs of neurotoxicity (tremors, impaired gait, excessivesalivation) following acute or subchronic exposure. Tremors disappeared with continuedexposure.

Reproductive toxicity Bifenthrin: No toxicity to reproduction in animal studies.Developmental toxicity Bifenthrin: Not teratogenic in animal studies.STOT - single exposure Not classified.STOT - repeated exposure Not classified.Target organ effects Bifenthrin: Central Nervous System.

Neurological effects Bifenthrin: Causes clinical signs of neurotoxicity (tremors, impaired gait, excessivesalivation) following acute or subchronic exposure. Tremors disappeared with continuedexposure.


crystalline silica, quartz 14808-60-7

A2 Group 1 Known X

Page 5 / 8




Ecotoxicity

Bifenthrin (82657-04-3)Active Ingredient(s) Duration Species Value UnitsBifenthrin 96 h LC50 Fish 0.1 µg/L

72 h EC50 Algae 0.822 mg/L48 h EC50 Crustacea 0.11 µg/L21 d NOEC Fish 0.012 µg/L21 d NOEC Crustacea 0.0013 µg/L

Persistence and degradability Bifenthrin: Moderately persistent. Does not readily hydrolyze. Not readily biodegradable.

Bioaccumulation Bifenthrin: The substance has a potential for bioconcentration.

Mobility Bifenthrin: Immobile. Not expected to reach groundwater.





DOT This material is not a hazardous material as defined by U.S. Department of Transportationat 49 CFR Parts 100 through 185.

TDG UN/ID no UN3077Proper Shipping Name Environmentally hazardous substance, solid, n.o.s.Hazard class 9Packing Group IIIMarine Pollutant Bifenthrin.Description UN3077, Environmentally hazardous substance, solid, n.o.s. (bifenthrin), 9, PGIII, Marine

Pollutant

ICAO/IATA UN/ID no UN3077Proper Shipping Name Environmentally hazardous substance, solid, n.o.s.Hazard class 9Packing Group IIIDescription UN3077, Environmentally hazardous substance, solid, n.o.s. (bifenthrin), 9, PGIII, Marine

PollutantIMDG/IMO

UN/ID no UN3077Proper Shipping Name Environmentally hazardous substance, solid, n.o.s.Hazard class 9Packing Group IIIEmS No. F-A, S-FMarine Pollutant BifenthrinDescription UN3077, Environmentally hazardous substance, solid, n.o.s. (bifenthrin), 9, PGIII, Marine

Pollutant

Page 6 / 8






Bifenthrin - 82657-04-3 82657-04-3 0.2 1.0

SARA 311/312 Hazard Categories Acute health hazard YesChronic health hazard YesFire hazard NoSudden release of pressure hazard NoReactive Hazard No

Clean Water ActThis product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42)

CERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this material


CAUTIONHarmful if absorbed through skin.This pesticide is extremely toxic to fish and aquatic invertebrates.


California Proposition 65This product contains the following Proposition 65 chemicals:.

Chemical name California Prop. 65crystalline silica, quartz - 14808-60-7 Carcinogen


Chemical name New Jersey Massachusetts PennsylvaniaBifenthrin

82657-04-3X

crystalline silica, quartz 14808-60-7

X X X


Page 7 / 8




DSL(Canada)

EINECS/ELINCS

(Europe)

ENCS(Japan)

China(IECSC)

KECL(Korea)

PICCS(Philippines)

AICS(Australia)

Bifenthrin 82657-04-3 ( 0.2 )

X X X

crystalline silica,quartz

14808-60-7 ( >80 )

X X X X X X X X

Mexico - Grade Moderate risk, Grade 2

WHMIS Hazard Class D2A - Very toxic materials


*Indicates a chronic health hazard.







HMIS Health Hazards 2* Flammability 0

Page 8 / 8


Safety Data Sheet TERMIDOR 9.1% SC. Revision date : 2013/10/31 Page: 1/9Version: 4.1 (30357978/SDS_CPA_US/EN)

1. Product and Company Identification

Company BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA

24 Hour Emergency Response Information CHEMTREC: 1-800-424-9300 BASF HOTLINE: 1-800-832-HELP (4357)

Substance number: 000000256709 Molecular formula: C12 H4 Cl2 F6 N4 O S Chemical family: phenyl pyrazole Synonyms: fipronil


Emergency overview

CAUTION: HARMFUL IF SWALLOWED. HARMFUL IF ABSORBED THROUGH SKIN. HARMFUL IF INHALED. Causes eye irritation. Do not get in eyes, on skin, or on clothing. Do not breathe vapours/mists. Wash thoroughly after handling.

See Product Label for additional precautionary statements.

State of matter: liquid Colour: beige Odour: characteristic

Potential health effects

Primary routes of exposure: Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases.

Acute toxicity: Slightly toxic after single ingestion. Slightly toxic after short-term skin contact. Slightly toxic after short-term inhalation.

Irritation / corrosion: May cause slight irritation to the skin. May cause moderate but temporary irritation to the eyes.

Sensitization:

Return to Index...


Skin sensitizing effects were not observed in animal studies. Medical conditions aggravated by overexposure: Individuals with pre-existing diseases of the respiratory system, skin or eyes may have increased susceptibility to excessive exposures. Signs and symptoms of overexposure: CNS stimulation, tremors, convulsions All injection injuries must be treated as potential threats to the future viability of the hand, foot, or limb. Injection wounds containing dirt, leather, product or other infectious detritus should be considered dangerous to the viability of the hand, foot or limb. Surgical exploration and debridement may be required. Potential environmental effects Aquatic toxicity: Very toxic (acute effect) to aquatic organisms. Terrestrial toxicity: With high probability not acutely harmful to terrestrial organisms.


CAS Number Content (W/W) Chemical name 120068-37-3 9.1 % fipronil 57-55-6 3.0 % Propylene glycol 87.9 % Proprietary ingredients


General advice: First aid providers should wear personal protective equipment to prevent exposure. Remove contaminated clothing. Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or physician for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. If inhaled: Remove the affected individual into fresh air and keep the person calm. If on skin: Rinse skin immediately with plenty of water for 15 - 20 minutes. If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing. If swallowed: Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting. Have person sip a glass of water if able to swallow. Note to physician Antidote: No known specific antidote. Treatment: Treat symptomatically. Anticonvulsant therapy as routinely administered to

humans. Based on animal studies diazepam and phenobarbital prevented convulsions. Due to the slow elimination of the active compound and its metabolites, the treatment must be continued for several days, gradually decreasing the dose of anticonvulsant based on the clinical response.



Flash point: > 206.96 °F Autoignition: Information applies to the solvent. not

applicable Lower explosion limit: As a result of our experience with this

product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use.

Upper explosion limit: As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use.

Self-ignition temperature: not self-igniting Suitable extinguishing media: foam, dry powder, carbon dioxide, water spray Hazards during fire-fighting: carbon monoxide, carbon dioxide, hydrogen fluoride, Hydrogen chloride, nitrogen oxides, sulfur oxides, acid halides If product is heated above decomposition temperature, toxic vapours will be released. The substances/groups of substances mentioned can be released if the product is involved in a fire. Protective equipment for fire-fighting: Wear self-contained breathing apparatus and chemical-protective clothing. Further information: In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.


Personal precautions: Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment. Environmental precautions: Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water. Cleanup: Dike spillage. Pick up with suitable absorbent material. Place into suitable containers for reuse or disposal in a licensed facility. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal.


Handling

General advice: RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product for Agricultural Use Requirements in accordance with the EPA Worker Protection


Standard 40 CFR part 170. Ensure adequate ventilation. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect contents from the effects of light. Protect against heat. Protect from air. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Avoid aerosol formation. Avoid dust formation. Provide means for controlling leaks and spills. Do not return residues to the storage containers. Follow label warnings even after container is emptied. The substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment. Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Sources of ignition should be kept well clear. Avoid extreme heat. Keep away from oxidizable substances. Electrical equipment should conform to national electric code. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition.

Storage

General advice: Keep only in the original container in a cool, dry, well-ventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protect against contamination. The authority permits and storage regulations must be observed. Storage incompatibility: General advice: Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials. Temperature tolerance Protect from temperatures below: 0 °C Changes in the properties of the product may occur if substance/product is stored below indicated temperature for extended periods of time. Protect from temperatures above: 40 °C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.

8. Exposure Controls and Personal Protection

Users of a pesticidal product should refer to the product label for personal protective equipment requirements. Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment.


RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS: Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. For situations where the airborne concentrations may exceed the level for which an air purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions. Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards.


Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit. General safety and hygiene measures: Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice. Personal protective equipment should be decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift. No eating, drinking, smoking or tobacco use at the place of work. Keep away from food, drink and animal feeding stuffs.


Form: suspension Odour: characteristic Colour: beige pH value: 7.2 ( 10 g/l) onset of boiling: approx. 100 °C ( 1,013 hPa) Information applies to the

solvent. Vapour pressure: approx. 23.3 hPa ( 20 °C) Information applies to the solvent. Density: 1.06 g/cm3 ( 20 °C) Vapour density: not determined Partitioning coefficient n-octanol/water (log Pow):

not applicable

Viscosity, dynamic: approx. 1,600 - 1,850 mPa.s

( 21.6 °C)

Solubility in water: dispersible Molar mass: 437.15 g/mol


Conditions to avoid: Avoid all sources of ignition: heat, sparks, open flame. Avoid prolonged storage. Avoid electro-static discharge. Avoid contamination. Avoid prolonged exposure to extreme heat. Avoid extreme temperatures. Substances to avoid: strong oxidizing agents Hazardous reactions: The product is chemically stable. Hazardous polymerization will not occur. No hazardous reactions if stored and handled as prescribed/indicated. Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off. Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide, nitrogen oxide, Hydrogen chloride, hydrogen fluoride, Sulphur dioxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. If product is heated above decomposition temperature hazardous fumes may be released. Corrosion to metals: Corrosive effects to metal are not anticipated.


Oxidizing properties: Not an oxidizer.

not fire-propagating


Acute toxicity Oral: Type of value: LD50 Species: rat Value: 1,999 mg/kg Inhalation: Type of value: LC50 Species: rat Value: > 1.7 mg/l Exposure time: 4 h Type of value: LC50 Species: rat Value: 6.8 mg/l (calculated) Exposure time: 1 h Dermal: Type of value: LD50 Species: rat Value: > 2,000 mg/kg Irritation / corrosion Skin: Species: rabbit Result: Slightly irritating. Eye: Species: rabbit Result: Slightly irritating. Sensitization: Species: guinea pig Skin sensitizing effects were not observed in animal studies. Genetic toxicity Information on: fipronil Results from a number of mutagenicity studies with microorganisms, mammalian cell culture and mammals are available. Taking into account all of the information, there is no indication that the substance is mutagenic. ---------------------------------- Carcinogenicity Information on: fipronil In long-term studies in rats the substance induced thyroid tumors. In long-term studies in rodents exposed to high doses, a tumorigenic effect was found; however, these results are thought to be due to a rodent-specific liver effect that is not relevant to humans. ---------------------------------- Reproductive toxicity Information on: fipronil


Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals. ---------------------------------- ----------------------------------

12. Ecological Information Fish Acute: Brachydanio rerio/LC50 (96 h): 3.89 mg/l Aquatic invertebrates Acute: Daphnia pulex/EC50 (48 h): 0.2 mg/l Aquatic plants Information on: fipronil Toxicity to aquatic plants: green algae/EC50 (96 h): 0.068 mg/l Common duckweed/EC50 (336 h): > 0.160 mg/l green algae/EC50 (120 h): > 0.140 mg/l Algae/EC50 (120 h): > 0.170 mg/l Algae/EC50 (120 h): > 0.120 mg/l ---------------------------------- Non-Mammals Information on: fipronil Other terrestrial non-mammals: Honey bee/LD50 (48 d): 0,00593 ug/bee (contact) Honey bee/LD50 (48 d): 0,00417 ug/bee (oral) ---------------------------------- Degradability / Persistence Biological / Abiological Degradation Evaluation: Not readily biodegradable (by OECD criteria). Other adverse effects: The ecological data given are those of the active ingredient. Do not release untreated into natural waters.


Waste disposal of substance: Pesticide wastes are regulated. Improper disposal of excess pesticide, spray mix or rinsate is a violation of federal law. If pesticide wastes cannot be disposed of according to label instructions, contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Container disposal: Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product. Rinse thoroughly at least three times (triple rinse) in accordance with EPA recommendations. Consult state or local disposal authorities for approved alternative procedures such as container recycling. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers. RCRA:


This product is not regulated by RCRA.



Not classified as a dangerous good under transport regulations

Sea transport IMDG

Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Marine pollutant: YES Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

(contains FIPRONIL 9%)


Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

(contains FIPRONIL 9%)


Federal Regulations Registration status: Chemical TSCA, US blocked / not listed Crop Protection TSCA, US released / exempt OSHA hazard category: Acute target organ effects reported; Chronic target organ effects reported EPCRA 311/312 (Hazard categories): Acute; Chronic State regulations State RTK CAS Number Chemical namePA 57-55-6 Propylene glycol


Refer to product label for EPA registration number.


Recommended use: insecticide NFPA Hazard codes: Health : 2 Fire: 1 Reactivity: 1 Special: We support worldwide Responsible Care® initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products.

SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2013/10/31 IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET

Return to Index...

TERRO®-PCO Liquid Ant Bait

For Control of Sweet Eating Ants • Contains Borax • No Unpleasant Odors • Use Indoors • Use Outdoors • Attracts Ants Fast

Active Ingredient:

Sodium Tertaborate Decahydrate (Borax)............................................... 5.40% Other Ingredients+................................................................................. 94.60% Total ........................................................................................................ 100.00%

EPA Reg. No. 149-8-64405 EPA Est. 149-MO-1

Keep Out of Reach of Children CAUTION

DIRECTIONS FOR USE

It is a violation of Federal law to use this product in a manner inconsistent with its labeling.

FOR USE IN AND AROUND: Homes, Hospitals, Restaurants, Apartments, Grocery Stores, Institutional Buildings, Schools, Cafeterias, Warehouses, Storage Areas, Food Processing Plants, Mobile Homes, Boats, Military Bases, Theaters, Nursing Homes and on Military, Commercial and Cruise Ships. ATTRACTS AND KILLS ALL COMMON HOUSEHOLD ANTS INCLUDING: Argentine ants, Ghost ants, Cornfield ants, Pavement ants, Acrobat ants, White-footed ants, Little black ants, Odorous house ants, Crazy ants, Big-headed ants and other sweet-eating ants. DO NOT USE in edible product areas of food handling establishments, restaurants or other areas where food is commercially prepared or processed. Do not use in serving areas while food is exposed. Avoid contamination of feed and foodstuffs. Place bait in areas inaccessible to children and pets. TERRO®-PCO Liquid Ant Bait can be diluted with water to obtain a 1% or 2% solution of Borax. Such a dilution is helpful when you plan on using a substantial volume of TERRO®-PCO Liquid Ant Bait in a baiting program designed to control very large multi-queen and multi-colony ant infestations. 1% Dilution: 1 part TERRO®-PCO Liquid Ant Bait to 5 parts water. Mix thoroughly.

2% Dilution: 1 part TERRO®-PCO Liquid Ant Bait to 2 parts water. Mix thoroughly. COMMON DILUTlONS 1% Dilut ion TERRO + WATER = FINISHED PRODUCT 5 fl. oz. + 25 fl. oz. = 1 Quart (approximately)

20 fl. oz. + 100 fl. oz. = 1 Gallon (approximately) 1 gallon + 5 gallons = 6 gallons

2% Dilut ion TERRO + WATER = FINISHED PRODUCT 10 fl. oz. + 20 fl. oz. = 1 Quart (approximately) 42 fl. oz. + 84 fl. oz. = 1 Gallon (approximately) 1 gallon + 2 gallons = 3 gallons

USING TERRO®-PCO LIQUID ANT BAIT IN BAIT STATIONS: Apply the 1% or 2% TERRO®-PCO Liquid Ant Bait solution using bait stations designed to hold liquid bait. This product will work well in most bait stations such as those made by B&G, Kness, and Whitmire Micro-Gen. Follow directions included with the bait stations to obtain best results.

Storage and Disposal STORAGE: Store in a cool dry place. Do not store where children or animals may gain access. DISPOSAL: I f empty: Do not reuse this container. Place in trash or offer for recycling if available. I f part ly f i l led: Call your local solid waste agency for disposal instructions. Never place unused product down any indoor or outdoor drain.

Distr ibuted by:

100 Nisus Drive, Rockford, TN 37853 • (800) 264-0870

Made in the U.S.A. Terro is registered trademark of Senoret Chemical Company, Nisus is a registered trademark of Nisus Corporation.

©2010 Nisus Corporation. #TGAL-SL-0710

TERRO P

®P-PCO

Liquid Ant Bait Stations

Pre-Filled – Ready-to-Use No Drips, Spill or Mess For Control of Sweet Eating Ants

Active Ingredient: Sodium Tetraborate Decahydrate (Borax) ..... 5.40% Other Ingredients .............................................. 94.60% Total..................................................................100.00% EPA Reg. No. 149-8-64405 EPA Est. 64405-TN-1

KEEP OUT OF REACH OF CHILDREN CAUTION

DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. FOR USE IN AND AROUND: Homes, Hospitals, Restaurants, Apartments, Grocery Stores, Institutional Buildings, Schools, Cafeterias, Warehouses, Storage Areas, Food Processing Plants, Mobile Homes, Boats, Military Bases, Theaters, Nursing Homes and on Military, Commercial and Cruise Ships. ATTRACTS AND KILLS ALL COMMON HOUSEHOLD ANTS INCLUDING: Argentine ants, Ghost ants, Cornfield ants, Pavement ants, Acrobat ants, White-footed ants, Little black ants, Odorous house ants, Crazy ants, Big-headed ants and other sweet-eating ants. TerroP

®P-PCO Liquid Ant Bait now comes as an easy-to-

use, pre-filled liquid ant bait. Ants will enter, feed and return to the nest where they will pass on the TerroP

®P-PCO Liquid Ant Bait to the rest of the colony.

1. Break pre-filled baits apart from the plastic

frame. 2. Hold bait upright and cut off colored section. 3. Place baits, label side up, near ant trails or close

to where ants are numerous. Place additional baits anywhere ants may enter the home. For best results, use seven baits to ensure sufficient supply for the ants.

4. Monitor regularly for activity but do not interfere with the ants or baits. Replace with additional baits when first set is depleted.

5. Once ants are controlled, replace baits every three months to keep ants from returning.

DO NOT USE in edible product areas of food handling establ ishments, restaurants or other areas where food is commercial ly prepared or processed. Do not use in serving areas while food is exposed. Avoid contamination of feed and foodstuffs. Place bait in areas inaccessible to chi ldren and pets.

STORAGE AND DISPOSAL STORAGE: Store in a cool dry place. Do not store

where children or animals may gain access.

DISPOSAL: I f empty: Do not reuse this container. Place in trash or offer for recycling if available. I f part ly f i l led: Call your local solid waste agency for disposal instructions. Never place unused product down any indoor or outdoor drain.

Distributed by:

100 Nisus Drive Rockford, TN 37853

800-264-0870

Terro is a registered trademark of Senoret Chemical Company, Inc.

Nisus is a registered trademark of Nisus Corporation. ©2010 Nisus Corporation #TBS-SL-1006a

SAFETY DATA SHEET

Health Emergencies: INFOTRAC® (800) 535-5053

1. PRODUCT AND COMPANY INFORMATION Product Identity: Terro® PCO Recommended use of the chemical and restrictions on use: Insecticide - Crawling Bug - Non-Aerosol Distributed by: Nisus Corporation 100 Nisus Drive Rockford, TN 37853 Telephone: Phone: (800) 264-0870 Fax: (865) 577-5825 Emergency Phone: 800-535-5053 (INFOTRAC) SDS Date of Preparation: 01/12/16

2. HAZARDS IDENTIFICATION GHS Classification:

Health Reproductive Toxicity Category 1B

GHS Label Elements: TE

Signal Word: Danger! Statements of Hazard May damage fertility or the unborn child Precautionary Statements Obtain special instructions before use Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant


Component CAS No. Amount

Sucrose 57-50-1 40-70%

Sodium borate 1303-96-4 3-7%

The exact formulation is being withheld as a trade secret. 4. FIRST AID MEASURES General Advice : Show this safety data sheet to the doctor in attendance. Eye Contact: Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician. Skin Contact: Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician.

Inhalation: Remove to fresh air. If symptoms persist, call a physician. Ingestion : Do NOT induce vomiting. Drink plenty of water. If symptoms persist, call a physician. Most important Symptoms: No information available Notes to Physician Treat symptomatically.

5. FIRE FIGHTING MEASURES Suitable Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media: CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical No information available. Hazardous Combustion Products Carbon oxides. Explosion Data Sensitivity to Mechanical Impact: No. Sensitivity to Static Discharge: No. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with eyes. Environmental Precautions: Refer to protective measures listed in Sections 7 and 8. Methods and Materials for Containment and Cleaning Up: Prevent further leakage or spillage if safe to do so. Pick up and transfer to properly labeled containers.


STORAGE AND DISPOSAL: Do not contaminate water, food, or feed by storage and disposal. STORAGE: Store in a cool dry place. Do not store where children or animals may gain access. PESTICIDE DISPOSAL AND CONTAINER HANDLING: Non-refillable Container: Do not reuse or refill this container. If empty: Place in trash or offer for recycling if available. If partly filled: Call your local solid waste agency for disposal instructions. Never place unused product down any indoor or outdoor drain.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines:

Chemical Name ACGIH TLV OSHA PEL NIOSH

IDLH

Sucrose 57-50-1

TWA: 10 mg/m3

TWA: 15 mg/m3 total

dust TWA: 5 mg/m3

respirable fraction

(vacated) TWA: 15

mg/m3 total dust

TWA: 10 mg/m3

total dust

TWA: 5 mg/m3 respirable dust

(vacated) TWA: 5 mg/m3

respirable fraction

Sodium borate

1303-96-4

STEL: 6 mg/m3 inhalable fraction TWA: 2 mg/m3 inhalable fraction

(vacated) TWA: 10 mg/m3

TWA: 5 mg/m3

ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health Engineering Measures: Showers, Eyewash stations, Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection: No special protective equipment required. Skin and Body Protection: Wear protective gloves and protective clothing. Respiratory Protection: No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Wash hands before breaks and immediately after handling the product.


Appearance And Odor: Clear liquid with sweet odor Physical State: Liquid Odor Threshold: No information available Vapor Density: No data available Initial Boiling Point/Range: No data available Solubility In Water: 100% Vapor Pressure: No data available Evaporation Rate: No data available Melting/Freezing Point: No data available pH: 7.75 Percent Volatile: >89% average as water and other volatiles Decomposition Temperature: No data available Viscosity: No data available Flammability (solid, gas): No data available Flashpoint: 100°C (212°F) Autoignition Temperature: No data available Flammable Limits: LEL: No data available UEL: No data available

10. STABILITY AND REACTIVITY Reactivity: No data available Chemical Stability: Stable under normal storage conditions. Possibility of Hazardous Reactions: Not under normal processing. Conditions to Avoid: None known based on information supplied. Incompatible Materials: None known based on information supplied. Hazardous Decomposition Products: Carbon oxides. Hazardous Polymerization: Hazardous polymerization does not occur.

11. TOXICOLOGICAL INFORMATION Product does not present an acute toxicity hazard based on known or supplied information. Ingestion: Specific test data for the substance or mixture is not available Inhalation: Specific test data for the substance or mixture is not available Eye: Specific test data for the substance or mixture is not available Skin: Specific test data for the substance or mixture is not available Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

Sodium borate 1303-96-4 2403 mg/kg ( Rat ) > 2000 mg/kg

( Rabbit )

> 2.03 mg/L ( Rat ) 4 h

Information on toxicological effects Symptoms: No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization: No information available. Mutagenic Effects: No information available Carcinogenicity: The table below indicates whether each agency has listed any ingredient as a carcinogen.

Chemical Name ACGIH IARC NTP OSHA Sodium borate 1303-96-4

Group 2A X

IARC (International Agency for Research on Cancer) Group 2A - Probably Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present

Reproductive Toxicity: Contains a known or suspected reproductive toxin. STOT - single exposure: No information available. STOT - repeated exposure: No information available. Chronic Toxicity: No known effect based on information supplied. Contains a known or suspected carcinogen. Contains a known or suspected reproductive toxin. Possible risk of irreversible effects. Target Organ Effects: Reproductive System. Eyes. Respiratory system. Skin. Kidney. Testes. Aspiration Hazard: No information available.

Numerical measures of toxicity Product Information The following values are calculated based on chapter 3.1 of the GHS document

ATEmix (oral) 44,500.00 mg/kg

12. ECOLOGICAL INFORMATION Ecotoxicity: The environmental impact of this product has not been fully investigated. Persistence and Degradability No information available. Bioaccumulation No information available Other adverse effects No information available.

13. DISPOSAL CONSIDERATION Disposal methods: This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.

Contaminated Packaging: Dispose of contents/containers in accordance with local regulations. California Hazardous Waste Codes 232

This product contains one or more substances that are listed with the State of California as a hazardous waste.

Chemical Name California Hazardous Waste

Sodium borate 1303-96-4 Toxic

14. TRANSPORTATION INFORMATION DOT/TDG/MEX/ICAO/IATA/IMDG/IMO/RID/ADR: Not Regulated

15. REGULATORY INFORMATION International Inventories TSCA: Complies DSL: All components are listed either on the DSL or NDSL. TSCA: United States Toxic Substances Control Act Section 8(b) Inventory

DSL/NDSL: Canadian Domestic Substances List/Non-Domestic Substances List


SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories Acute Health Hazard: No Chronic Health Hazard: Yes Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No

CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material


California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations

Chemical Name

New Jersey Massachusetts Pennsylvania Rhode

Island Illinois

Supplier Trade Secret X X

Sodium borate 1303-96-4 X X X X

EPA Pesticide Registration Number 149-8-64405

International Regulations

Mexico National occupational exposure limits

Component Carcinogen Status Exposure Limits Sucrose

57-50-1 ( 40 - 70 ) Mexico: TWA 10 mg/m3 Mexico: STEL 20 mg/m3

Sodium borate 1303-96-4 ( 3 - 7 ) Mexico: TWA 5 mg/m3

Mexico - Occupational Exposure Limits - Carcinogens

Canada

WHMIS Hazard Class D2A - Very toxic material

This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazards information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use.

16. OTHER INFORMATION NFPA Rating: Health = 1 Flammability = 0 Instability = 0 HMIS Rating: Health = 1* Flammability = 0 Physical Hazard Personal Protection= X *Chronic Health Hazard SDS Revision History: 05/01/15: New SDS

01/12/16: Revised WARRANTY DISCLAIMER

The information, data and recommendations contained herein are believed to be accurate but may not be all inclusive and should only be used as a guide. The information is furnished upon the condition that the person receiving it shall make his own determination of the suitability of the product for his particular use and on condition that they assume the risk of the use thereof. With respect to this publication and the product related thereto, unless otherwise expressly provided by Manufacturer in writing, MANUFACTURER MAKES NO EXPRESS OR IMPLIED WARRANTY OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER EXPRESS OR IMPLIED WARRANTY.

Remedy/Liability Limits The exclusive remedy for losses or damages resulting from this publication or the related product (including claims based on contract, negligence, strict liability or other legal theories) shall be limited to, at Manufacturer’s sole election, one of the following:


2. Replacement of amount of product used. Manufacturer shall not be liable for losses or damages resulting from use of this publication or handling or use of this product, IN NO CASE SHALL MANUFACTURER BE LIABLE FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OR LOSSES, INCLUDING WITHOUT LIMIT, HEALTH RELATED DAMAGES OR INJURIES. The terms of this Warranty Disclaimer and Remedy/Liability Limits cannot be varied by any written or verbal statements or agreements. No employee or sales agent of Manufacturer or the seller is authorized to vary or exceed the terms of this Warranty Disclaimer or Limitation of Remedies in any manner.

100 Nisus Drive • Rockford, TN 37853 USA • (800) 264-0870

Terro and Nisus Corporation are trademarks or registered trademarks of Nisus Corporation. ©2016 Nisus Corporation• #TR-SDS-011216a

Safety Data Sheet WASP FREEZE INSECTICIDERevision date : 2014/10/13 Page: 1/13Version: 4.0 (30472285/SDS_CPA_US/EN)

1. Identification


WASP FREEZE INSECTICIDE Recommended use of the chemical and restriction on use Recommended use*: insecticide

* The “Recommended use” identified for this product is provided solely to comply with a US Federal requirement and is notpart of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty,express or implied, including by incorporation into or reference in the seller's sales agreement.



Telephone: +1 973 245-6000



Registrant: Whitmire Micro-Gen Research Laboratories, Inc. 3568 Tree Court Industrial Blvd. St. Louis, MO 63122

Other means of identification Substance number: 413973 EPA Register number: 499-362Synonyms: d-trans Allethrin + phenothrin




Flam. Aerosol 1 Flammable aerosol

Return to Index...

Safety Data Sheet WASP FREEZE INSECTICIDE Revision date : 2014/10/13 Page: 2/13Version: 4.0 (30472285/SDS_CPA_US/EN)

Label elements Pictogram:

Signal Word: Danger Hazard Statement: H222 Extremely flammable aerosol. Precautionary Statements (Prevention): P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use. Precautionary Statements (Storage): P410 + P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/

122°F. According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Emergency overview CAUTION: KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. HARMFUL IF SWALLOWED. HARMFUL IF INHALED. HARMFUL IF ABSORBED THROUGH SKIN. Avoid inhalation of mists/vapours. Avoid contact with the skin, eyes and clothing. Wash thoroughly after handling. Flammable Liquid Aerosol container contains flammable gas under pressure.


According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 CAS Number Content (W/W) Chemical name 28057-48-9 0.129 % d-trans Allethrin 26002-80-2 0.12 % Phenothrin 64742-47-8 > 10.0 % Distillates (petroleum), hydrotreated light Carbon dioxide, liquid According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 CAS Number Content (W/W) Chemical name 28057-48-9 0.129 % d-trans Allethrin 26002-80-2 0.12 % Phenothrin 64742-47-8 > 10.0 % Distillates (petroleum), hydrotreated light Carbon dioxide, liquid >= 85.0 % Proprietary ingredients



Description of first aid measures General advice: First aid providers should wear personal protective equipment to prevent exposure. Remove contaminated clothing. Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or physician for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. If inhaled: Remove the affected individual into fresh air and keep the person calm. If on skin: Rinse skin immediately with plenty of water for 15 - 20 minutes. If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing. Wash affected eyes for at least 15 minutes under running water with eyelids held open. If swallowed: Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting. Have person sip a glass of water if able to swallow. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Hazards: Vomiting may cause aspiration pneumonia due to the ingredients. Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Aspiration of this product during induced emesis can result in lung

injury. If evacuation of stomach contents is considered necessary, use method least likely to cause aspiration, such as gastric lavage after endotracheal intubation.


Extinguishing media Suitable extinguishing media: foam, dry powder, carbon dioxide Special hazards arising from the substance or mixture Hazards during fire-fighting: carbon monoxide, carbon dioxide,


The substances/groups of substances mentioned can be released in case of fire. Aerosol container contains flammable gas under pressure. Risk of explosion at excessive temperatures. carbon monoxide, carbon dioxide, The substances/groups of substances mentioned can be released in case of fire. Advice for fire-fighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not allow to enter drains or waterways. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. In case of fire and/or explosion do not breathe fumes. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. Keep containers cool by spraying with water if exposed to fire.


Personal precautions, protective equipment and emergency procedures Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment. Environmental precautions Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water. A spill of or in excess of the reportable quantity requires notification to state, local and national emergency authorities. This product is not regulated by CERCLA ('Superfund'). Methods and material for containment and cleaning up Dike spillage. Pick up with suitable absorbent material. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal.


Precautions for safe handling RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect against heat. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Provide means for controlling leaks and spills. Follow label warnings even after container is emptied. The substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment. Protection against fire and explosion:


Aerosol container contains flammable gas under pressure. The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition. No special precautions necessary. The substance/product is non-combustible. Product is not explosive. Conditions for safe storage, including any incompatibilities Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials. Further information on storage conditions: Protect containers from physical damage. Store in a cool, dry, well-ventilated area. Avoid all sources of ignition: heat, sparks, open flame. Storage stability: May be kept indefinitely if stored properly. If an expiry date is mentioned on the packaging/label this takes priority over the statements on storage duration in this safety data sheet. Protect from temperatures above: 130 °F Explosive at or above indicated temperature.


Users of a pesticidal product should refer to the product label for personal protective equipment requirements. Components with occupational exposure limits

OSHA PEL PEL 5,000 ppm 9,000 mg/m3 ; TWA value 10,000 ppm 18,000 mg/m3 ; STEL value 30,000 ppm 54,000 mg/m3 ;

Carbon dioxide, liquid

ACGIH TLV TWA value 5,000 ppm ; STEL value 30,000 ppm ;

Distillates (petroleum),

hydrotreated light ACGIH TLV TWA value 200 mg/m3 Non-aerosol (total hydrocarbon vapor); Application restricted to conditions in which there are negligible aerosol exposures. Skin Designation Non-aerosol (total hydrocarbon vapor); The substance can be absorbed through the skin.


Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS: Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. For situations where the airborne concentrations may exceed


the level for which an air purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions. Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards. Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit. General safety and hygiene measures: RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Store work clothing separately.


Form: liquid Odour: solvent-like Odour threshold: Not determined due to potential health

hazard by inhalation. Colour: pale yellow, clear pH value: of low solubility, not applicable pour point: -50 °C Flash point: 73 - 95 °C Information applies to the solvent. Flammability: not readily

ignited (calculated)

NFPA 30B flammability: Level 3 Aerosol

Lower explosion limit: 0.8 %(V) Information applies to the solvent. Upper explosion limit: 6 %(V) Information applies to the solvent. Autoignition: approx. 225 °C Information applies to the solvent. Vapour pressure: approx. 6895

hPa (approx. 19 °C)

Density: approx. 0.80 g/cm3

( 20 °C)

Vapour density: not applicable Partitioning coefficient n-octanol/water (log Pow):

not applicable

Thermal decomposition: carbon monoxide, carbon dioxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. To avoid thermal decomposition, do not overheat.

not determined Viscosity, dynamic: not determined Solubility in water: sparingly soluble Evaporation rate: not applicable Other Information: If necessary, information on other physical and chemical




Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: Corrosive effects to metal are not anticipated. Oxidizing properties: Based on its structural properties the product is not classified as oxidizing. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions The product is chemically stable. Conditions to avoid Avoid all sources of ignition: heat, sparks, open flame. Avoid prolonged storage. Avoid electro-static discharge. Avoid contamination. Avoid prolonged exposure to extreme heat. Avoid extreme temperatures. Incompatible materials No substances known that should be avoided. Hazardous decomposition products Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off. Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. To avoid thermal decomposition, do not overheat. not determined


Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Relatively nontoxic after single ingestion. Slightly toxic after short-term skin contact. Oral Type of value: LD50 Species: rat


Value: > 5,000 mg/kg Inhalation Type of value: LC50 Species: rat Value: > 5.2 mg/l Exposure time: 4 h The product has not been tested. The statement has been derived from the properties of the individual components. Dermal Type of value: LD50 Species: rabbit Value: > 2,000 mg/kg Irritation / corrosion Assessment of irritating effects: Contact may result in eye irritation. May cause moderate irritation to the skin. Skin Species: rabbit Result: Slightly irritating. Eye Result: Slightly irritating. Sensitization Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. Species: guinea pig Result: Non-sensitizing. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. No substance-specific organtoxicity was observed after repeated administration to animals. Genetic toxicity Assessment of mutagenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Mutagenicity tests revealed no genotoxic potential. Carcinogenicity Assessment of carcinogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: bioallethrin Assessment of carcinogenicity: Indication of possible carcinogenic effect in animal tests. A clear indication of an increased risk of cancer in humans has so far not been shown. Information on: d-phenothrin Assessment of carcinogenicity: Not likely to be carcinogenic to humans (US EPA 2005 Guidelines). ---------------------------------- Reproductive toxicity


Assessment of reproduction toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of animal studies gave no indication of a fertility impairing effect. Teratogenicity Assessment of teratogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals. Other Information Misuse can be harmful to health. Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known.


Toxicity Aquatic toxicity Assessment of aquatic toxicity: Acutely toxic for fish. The product has not been tested. The statement has been derived from the properties of the individual components. Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Toxicity to fish Information on: bioallethrin LC50 9,9 µg/l, Salvelinus namaycush (Flow through.) The ecological data given are those of the active ingredient. Information on: d-phenothrin LC50 (96 h) 0.0027 mg/l, Oncorhynchus mykiss Information on: Distillates (petroleum), hydrotreated light LL50 (96 h) 2 - 5 mg/l, Oncorhynchus mykiss (OECD Guideline 203, semistatic) The product has low solubility in the test medium. A saturated solution has been tested. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Nominal values (confirmed by concentration control analytics) ---------------------------------- Aquatic invertebrates Information on: bioallethrin LC50 (96 h) 0.0356 mg/l, Daphnia magna (Flow through.) Information on: d-phenothrin (96 h) > 300 mg/l, Daphnia magna Information on: Distillates (petroleum), hydrotreated light EL50 (48 h) 1.4 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)


The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. A saturated solution has been tested. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. ---------------------------------- Aquatic plants Information on: Distillates (petroleum), hydrotreated light EL50 (72 h) 1 - 3 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201, static) The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. A saturated solution has been tested. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. No observed effect concentration (72 h) 1 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201, static) The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. A saturated solution has been tested. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. ---------------------------------- Persistence and degradability Assessment biodegradation and elimination (H2O) The product has not been tested. The statement has been derived from the properties of the individual components. Assessment biodegradation and elimination (H2O) Information on: Distillates (petroleum), hydrotreated light Not readily biodegradable (by OECD criteria). Inherently biodegradable. ---------------------------------- Bioaccumulative potential Assessment bioaccumulation potential The product has not been tested. The statement has been derived from the properties of the individual components. Bioaccumulation potential Information on: Distillates (petroleum), hydrotreated light No data available. ---------------------------------- Mobility in soil Assessment transport between environmental compartments No data available. Additional information Other ecotoxicological advice: Do not discharge product into the environment without control.



Waste disposal of substance: Pesticide wastes are regulated. Improper disposal of excess pesticide, spray mix or rinsate is a violation of federal law. If pesticide wastes cannot be disposed of according to label instructions, contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Must be sent to a suitable incineration plant, observing local regulations. Container disposal: Do not cut, puncture, crush, or incinerate empty aerosol containers. Consult state or local disposal authorities for approved alternative procedures such as container recycling. Empty aerosol cans may meet the definition of RCRA D003. Consult local and/or regional EPA for further guidance. Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.



Hazard class: 2.1 ID number: UN 1950 Hazard label: 2.1 Proper shipping name: AEROSOLS

Sea transport IMDG Hazard class: 2.1 ID number: UN 1950 Hazard label: 2.1, EHSM Marine pollutant: YES Proper shipping name: AEROSOLS (contains KEROSENE (PETROLEUM), D-TRANS

ALLETHRIN)


Hazard class: 2.1 ID number: UN 1950 Hazard label: 2.1 Proper shipping name: AEROSOLS, FLAMMABLE (contains KEROSENE (PETROLEUM),

D-TRANS ALLETHRIN) Further information DOT: This product may be classified as ORM-D (Consumer Commodity) or Limited Quantity. After 12/31/2020, ORM-D will not apply.


Federal Regulations Registration status:


Crop Protection TSCA, US released / exempt Chemical TSCA, US blocked / not listed EPCRA 311/312 (Hazard categories): Acute; Fire; Sudden release of pressure State regulations State RTK CAS Number Chemical name NJ 26002-80-2 Phenothrin MA, NJ, PA 64742-47-8 Distillates (petroleum), hydrotreated light MA, NJ, PA Carbon dioxide, liquid NFPA Hazard codes: Health : 1 Fire: 2 Reactivity: 1 Special: Labeling requirements under FIFRA This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label. CAUTION: KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. HARMFUL IF SWALLOWED. HARMFUL IF INHALED. HARMFUL IF ABSORBED THROUGH SKIN. Avoid inhalation of mists/vapours.

Avoid contact with the skin, eyes and clothing. Wash thoroughly after handling. Flammable Liquid Aerosol container contains flammable gas under pressure.



Trade Name: ZP Rodent Oat Bait AG Date Created: January 2015 Supplier: Bell Laboratories, Inc. Page 1 of 4

ZP®RODENT OAT BAIT AG™ SAFETY DATA SHEET ACCORDING TO REGULATION: OSHA


PREPARED BY: CAR

1. PRODUCT AND COMPANY IDENTIFICATIONProduct Identifier: ZP® RODENT OAT BAIT AG™ EPA Registration Number: 12455-102 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Acute Rodenticide - Ready to use – Restricted Use Uses advised against: Use only for the purpose described above





Zinc Phosphide 1314-84-7 2.0%


4. FIRST AID MEASURESDescription of first aid measures Ingestion: Call physician or emergency number immediately. Do not drink water. Do not give anything by mouth or induce vomiting unless instructed by physician. Inhalation: Move person to fresh air. If not breathing, call an ambulance, then give artificial respiration, preferably mouth to mouth, if possible. Eye contact: Hold eye open and rinse slowly with water for 15 – 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. If irritation develops, obtain medical assistance. Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. If irritation develops, obtain medical assistance. Most important symptoms and effects, both acute and delayed Ingestion of excessive quantities may cause nausea, abdominal pain, tightness in the chest, eye irritation, or weakness. Advice to physician: There is no specific antidote. Probable mucosal damage may contradict the use of gastric lavage. Sodium bicarbonate can be given orally to neutralize the stomach acidity. The stomach and intestinal tract can be evacuated, oxygen administered and cardiac and circulatory stimulants given. Advice to Veterinarian: For animals ingesting bait and/or showing poisoning signs, induce vomiting by using hydrogen peroxide. Sodium bicarbonate can be given orally to neutralize the stomach acidity. The stomach and intestinal tract can be evacuated, oxygen administered and cardiac and circulatory stimulants given.

Return to Index...


5. FIRE-FIGHTING MEASURES Extinguishing media Suitable Extinguishing Media: Dry chemical, soda ash, sand, or inert gas. Unsuitable Extinguishing Media: Avoid water or foam as they may form phosphine gas upon contact with zinc phosphide. Special hazards arising from the mixture: High temperature decomposition or burning in air can result in the formation of toxic or flammable gases, which may include flammable phosphine gas, oxides of phosphorus, and zinc. Advice for firefighters: Wear protective clothing and self-contained breathing apparatus. Fight fire upwind and evacuate downwind as appropriate.

6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Gloves, long sleeve shirt, long pants, shoes, and socks should be worn when handling the bait. Collect spillage without creating dust. Environmental precautions: Do not allow bait to enter drains or water courses. Where there is contamination of streams, rivers or lakes contact the appropriate environment agency. Methods and materials for containment and cleaning up For Containment: Carefully sweep up spilled material immediately. Avoid contact with dust. Place in properly labeled container for disposal or re-use. For Cleaning Up: Wash contaminated surfaces with detergent. Dispose of all wastes in accordance with all local, regional and national regulations. Reference to other sections: Refer to Sections 7, 8 & 13 for further details of personal precautions, personal protective equipment and disposal considerations.



Component OSHA ACGIH Other Limits Zinc Phosphide Not Established Not Established Not Established

Appropriate Engineering Controls: Not required Occupational exposure limits: Not established Personal Protective Equipment: Respiratory protection: Persons loading pellets or baits into aircraft or mechanical ground equipment and persons loading/applying with a hand-pushed or hand-held equipment, such as a push-type spreader or cyclone spreader, must wear a dust/mist filtering respiration (MSHA/NIOSH approval number prefix TC-21C or a NIOSH-approved respirator with a R, P, or HE filter). Eye protection: Protective eyewear. Skin protection: Gloves, long sleeve shirt, long pants, shoes, and socks should be worn when handling the bait. Hygiene recommendations: Keep and wash PPE separately from other laundry. Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash hands thoroughly after applying bait and before eating, drinking, chewing gum, using tobacco or using the toilet, and change into clean clothing.



Appearance/Color: Grey oat groat Odor: Garlic-like Odor Threshold: Not applicable, odor not associated with a hazardous material. pH: Not applicable, ZP Rodent Oat Bait AG is not dispersible with water. Melting point: Not applicable to rodenticide bait Boiling point: Not applicable to rodenticide bait Flash point: Not applicable, ZP Rodent Oat Bait AG does not contain components classified as flammable. Evaporation rate: Not applicable, ZP Rodent Oat Bait AG is a solid. Upper/lower flammability or explosive limits:

Not applicable, ZP Rodent Oat Bait AG does not contain components classified as flammable or explosive.


Not applicable to rodenticide bait NA: ZP Rodent Bait Oat AG is a solid



Auto-ignition temperature: Not applicable, ZP Rodent Oat Bait AG does not contain components classified as flammable. Decomposition temperature: Not applicable to rodenticide bait Viscosity: Not applicable, ZP Rodent Oat Bait AG is not a liquid.

10. STABILITY AND REACTIVITY Reactivity: Stable when stored in original container in a cool, dry location. Chemical stability: Stable when stored in original container in a cool, dry location. Possibility of hazardous reactions: Refer to Hazardous decomposition products Conditions to avoid: Avoid extreme temperatures (below 0°C or above 40°C). Incompatible materials: Avoid water, acidic materials. Hazardous decomposition products: Avoid exposure to acidic conditions, light, heat, and extreme humidity. Exposure to acidic conditions may result in the liberation of flammable phosphine gas. Oxides of zinc and phosphide.

11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute Toxicity LD50, oral (ingestion): >2000 mg/kg (rats) (Zinc phosphide Rat LD50 oral: 21.0 mg/kg bw). LD50, dermal (skin contact): > 5001 mg/kg (rats) (Zinc phosphide rabbit LD50 dermal: 2000 - 5000 mg/kg bw). LC50, inhalation: ZP Rodent Oat Bait AG is an oat groat and therefore exposure by inhalation is not relevant. Skin corrosion/irritation : Not irritating to skin. Serious eye damage/Irritation: Slight eye irritation potential Respiratory or skin sensitization: Dermal sensitization: Not a Sensitizer (Guinea pig maximization test). Germ cell mutagenicity: ZP Rodent Oat Bait AG contains no components known to have a mutagenetic effect. Carcinogenicity: ZP Rodent Oat Bait AG contains no components known to have a carcinogenetic effect.

Components NTP IARC OSHA Zinc Phosphide Not listed Not listed Not listed

Reproductive Toxicity: ZP Rodent Oat Bait AG: No data Aspiration Hazard: Not applicable. ZP Rodent Oat Bait AG is an oat groat. Target Organ Effects: None

12. ECOLOGICAL INFORMATION Ecotoxicity Effects: This product is extremely toxic to fish, birds and other wildlife. Dogs and predatory and scavenging mammals and birds might be poisoned if they feed upon animals that have eaten this bait. Do not apply this product directly to water or to areas where surface water is present or to intertidal areas below the mean high water mark. Runoff also may be hazardous to aquatic organisms in water adjacent to treated areas. Do not contaminate water when disposing of equipment wash water or rinsate. Persistence and degradability: ZP Rodent Oat Bait AG is inherently biodegradable. Zinc phosphide rapidly decomposes in water. Bioaccumulative potential: Not determined for ZP Rodent Oat Bait AG. Zinc phosphide water solubility is extremely low (< 0.1mg/l). Mobility in Soil: Not determined for ZP Rodent Oat Bait AG. Mobility of zinc phosphide in soil is considered to be limited. Other adverse effects: None.




15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture: FIFRA: This pesticide product is regulated by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The safety, health, environmental, and hazard information required on the pesticide label is listed below and reflected throughout this SDS. The pesticide label also includes other important information, including directions for use. Signal Word: CAUTION Precautionary Statements: Contains phosphine producing active ingredient, zinc phosphide. Harmful if swallowed or inhaled. Keep away from children, domestic animals and pets. Do not get in eyes, on skin or on clothing. Potential Health Effects: Eye Contact: May cause irritation Skin Contact: Non-irritating to the skin Ingestion: Harmful if swallowed TSCA: All components are listed on the TSCA Inventory or are not subject to TSCA requirements CERCLA/SARA 313: Not listed CERCLA/SARA 302: Not listed




safety data sheets — april 1, 2016 - pestgon sds.pdf · important disclosure – please read...

Documents