safety data sheets - douglas county, wi

Safety Data SheetsHHS 4th Floor

HHS 4th Floor

02/29/2016

Safety Data Sheet Index

Binder: HHS 4th Floor - HHS 4th Floor

096-000 106-97-8 Norazza, Inc. 05/05/2015 3

CARPET STAIN REMOVER Spartan Chemical Company, Inc. 01/22/2015 8

Clorox Commercial Solutions Green Works 99%Naturally Derived General Purpose Cleaner -Ready-to-Use Solution - 1:48 from Concentrate

Clorox Professional ProductsCompany

05/23/2015 14

Comet Deodorizing Cleanser with Chlorinol Procter & Gamble Professional 06/12/2015 23

Disinfecting Multi-Surface Cleaner Seventh Generation Inc 05/28/2015 30

Expo White Board Cleaner Newell Rubbermaid 08/05/2015 36

Fabuloso Pro APC Cleaner Lavender Colgate-Palmolive Company 44

Febreze Air Effects - Sun Baked Procter & Gamble 02/24/2015 53

Goo Gone Spray Gel Goo Gone 08/14/2014 60

Lemon SHine Furnature Polish Nyco Products Company 08/16/2005 66

MURPHY OIL SOAP WOOD CLEANERSPRAY RTU

Colgate-Palmolive Company 05/22/2015 68

Office Max Compressed Gas Duster 75-37-6 Falcon Safety Products, Inc 04/28/2015 75

PLEDGE FURNITURE CLEANER & POLISHWITH NATURAL ORANGE OIL

S.C. Johnson and Son, Limited 05/21/2014 83

PURELL Hand Sanitizing Wipes GOJO Industries, Inc. 03/30/2015 91

Sani-Cloth HB Germicidal Disposable Wipe Professional DisposablesInternational, Inc. NP Nice Pak

105

SHINE M UP AEROSOLSAMPLE, CAN CL CERTIFIED LABS - DIVISION OFNCH CORPORATION

11/18/2009 111

Static Free Hand Guard CHEMTRONICS 05/18/2015 115

ULTRA MARK ICELAND DAWN Mohawk Finishing ProductsDivision of RPM Wood FinishesGroup, Inc.

07/04/2015 126

Product Name CAS Number Manufacturer Version Date Page

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of 4 SDS for: 2914011

Printed: 5/5/2015

SAFETY DATA SHEET This document is not intended for general distribution.

It can be used as the basis for a general distribution document if appropriate changes are made to the identification

section.

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: 096-000 Product Code: 2914011 Chemical Name: Endust for Electronics Screen & Electronics Cleaner 8oz Details of the supplier of the safety data sheet:

This Safety Data Sheet has been updated in accordance with the Global Harmonized System (GHS) Manufacturer/Supplier:

Norazza, Inc. 3938 Broadway St Buffalo NY 14227 US Supplier Phone Number: Contact Phone 716-706-1160

Emergency telephone number: 800-255-3924 International +01-813-248-0585

Product Use: Anti-static cleaner for electronic equipment

2. HAZARDS IDENTIFICATION

CLASSIFICATION

Flammable aerosol 2

Gas under pressure Liquefied gas

SIGNAL WORD: Warning


of 4 SDS for: 2914011

Printed: 5/5/2015

Hazard Statements

Flammable aerosol

Contains gas under pressure; may explode if heated

Precautionary Statements

Keep away from heat/sparks/open flames/hot surfaces – No smoking

Do not spray on an open flame or other ignition source

Pressurized container – Do not pierce or burn, even after use

Protect from sunlight. Store in a well ventilated place

Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No. Percent

WATER 7732-18-5 97.00

BUTANE 106-97-8 1.90

4. FIRST AID MEASURES

INHALATION: Remove to fresh air. Administer oxygen if needed. Apply artificial respiration if breathing has stopped

. Get medical attention.

EYE CONTACT: Wash immediately with large volumes of fresh water for at least 15 minutes . Get medical attention.

SKIN CONTACT: Wipe off with a towel. Wash with soap and water. Get medical attention if irritation persists.

INGESTION: Not a likely route of exposure.

Most important symptoms/effects, acute and delayed: Repeated exposure may cause skin dryness or cracking.

May cause drowsiness or dizziness.

Indication of immediate medical attention and special treatment needed: None known.

5. FIRE FIGHTING MEASURES

Suitable and unsuitable extinguising media: Foam, Alcohol foam, CO2, Dry chemical, Water fog . Water spray

may be ineffective.

Specific hazards arising from the chemical: Closed containers may explode from internal pressure build-up when

exposed to extreme heat and discharge contents. Liquid content of container will support combustion.

Overexposure to decomposition products may cause a health hazard. Symptoms may not be readily apparent.

Obtain medical attention. Hazardous decomposition products include carbon dioxide, carbon monoxide, and other

toxic fumes

Special equipment and precautions for fire-fighters: Water may be used to cool containers to prevent pressure

build-up and explosion when exposed to extreme heat. Wear goggles and use self-contained breathing apparatus . If

water is used, fog nozzles are preferred.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures: Avoid breathing vapors. Ventilate

area. Remove all sources of ignition.


of 4 SDS for: 2914011

Printed: 5/5/2015

Methods and materials for containment and cleaning up: Clean up with absorbent material and place in closed

containers for disposal.

7. HANDLING AND STORAGE

Precautions for safe handling: Do not puncture or incinerate (burn) cans. Do not stick pins, nails, or any other

sharp objects into opening on top of can. Do not spray in eyes. Do not take internally. See product label for

additional information.

Conditions for safe storage, including any incompatibilities: Store and use in cool, dry, well-ventilated areas .

Do not store above 120 F.

8. EXPOSURE CONTROL/PERSONAL PROTECTION

Chemical Name / CAS No. OSHA Exposure Limits ACGIH Exposure Limits Other Exposure Limits

WATER

7732-18-5

Not established Not established

BUTANE

106-97-8

Not established TWA: 1000 ppm

Appropriate engineering controls: Ventilation should be sufficient to prevent inhalation of any vapors . General

dilution and/or local exhaust ventilation in volume to keep PEL/TLV of most hazardous ingredient below acceptable

limit and well below stated limit.

Individual protection measures:

Respiratory protection: None under normal use. Avoid breathing vapors. In restricted areas , use approved

chemical/mechanical filters designed to remove a combination or particles and vapor. In confined areas, use an

approved air line respirator or hood. Self-contained breathing apparatus is required for vapor concentrations above

PEL/TLV limits.

Protective gloves: None under normal use. Use solvent-resistant for prolonged or repeated contact.

Eye protection: None under normal use. However, use of safety glasses with splash guards or full face shield

should be used if indicated.

Other protective clothing or equipment: None under normal use. However, use of solvent- resistant aprons or other

clothing is recommended. Eye washes and safety showers in the workplace are recommended.

SHOWERS IN THE WORKPLACE ARE RECOMMENDED.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Aerosol product

Vapor Pressure: Not determined

Vapor Density: Heavier than air

Density: 0.985259828

Freezing point: Not determined

Boiling point: N/A

Evaporation rate: Slower than ether

Explosive Limits: Not determined

Auto ignition temperature: Not determined

Viscosity: Not determined


of 4 SDS for: 2914011

Printed: 5/5/2015

Odor: Pleasant

Odor threshold: Not determined

pH: Not determined

Melting point: Not determined

Solubility: Not determined Flash

point: Not determined

Flammability: Level 1 Aerosol

Partition coefficient (n- Not determined

octanol/water):

Decomposition temperature: Not determined

10. STABILITY AND REACTIVITY

Reactivity: Not reactive under normal conditions of use.

Chemical stability: Stable under normal storage and handling conditions.

Possibility of hazardous reactions: None known.

Incompatible materials:

No data

Hazardous decomposition products:

No data

11. TOXICOLOGICAL INFORMATION

Long-term toxicological studies have not been conducted for this product.

12. ECOLOGICAL INFORMATION

Long-term ecological studies have not been conducted for this product.

13. DISPOSAL CONSIDERATIONS


of 4 SDS for: 2914011

Printed: 5/5/2015

Dispose of in accordance with local, state, and federal regulations. Before attempting clean up, refer to other sections

this document for hazard cautionary information.

14. TRANSPORT INFORMATION

By land: DOT Proper Shipping Name: None required per 49 CFR 173 .306(i) for products that conform to the Limited

Quantity provisions. Commodity shipping description: Cleaning Compound, NOI

By water: DOT & IMDG Proper Shipping Name: UN1950, Aerosols, 2 .1, LTD QTY

By air: DOT & IATA Proper Shipping Name: UN1950, Aerosols, flammable, 2 .1, LTD QTY (packing instruction Y203

applies)

15. REGULATORY INFORMATION

All ingredients are either listed on the TSCA inventory or are exempt .

16. OTHER INFORMATION

Date revised: 2015-05-05

Date Printed: 2015-05-05

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE. HOWEVER, NO

WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THE DATA OR THE RESULTS TO BE

OBTAINED FROM THE USE THEREOF. BECAUSE THE INFORMATION CONTAINED HEREIN MAY BE APPLIED

UNDER CONDITIONS BEYOND OUR CONTROL, WE ASSUME NO RESPONSIBILITY FOR ITS USE.

Revision 0


Revision Date: 22-Jan-2015

Safety Data SheetSpartan Chemical Company, Inc.


Product Identifier Product Name: CARPET STAIN REMOVERProduct Number: 6374Recommended Use: Cleaning agentUses Advised Against: For Industrial and Institutional Use Only

Manufacturer/Supplier: Spartan Chemical Company, Inc.1110 Spartan DriveMaumee, Ohio 43537 USA800-537-8990 (Business hours)www.spartanchemical.com

24 Hour Emergency Phone Numbers:Medical Emergency/Information: 888-314-6171Transportation/Spill/Leak: CHEMTREC 800-424-9300


GHS ClassificationSerious Eye Damage/Eye Irritation: Category 2A

GHS Label Elements Signal Word: Danger

Hazard Statements: Causes serious eye irritationExtremely flammable aerosol.Contains gas under pressure; may explode if heated

Precautionary Statements: Prevention: Wash hands and any exposed skin thoroughly after handling.

Wear eye / face protectionKeep away from heat/sparks/open flames/hot surfaces. — No smokingDo not spray on an open flame or other ignition sourcePressurized container: Do not pierce or burn, even after useIntentional misuse by deliberately concentrating and inhaling contents may be harmful orfatal.

Response:-Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.-Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information.

Storage: Protect from sunlight. Do not expose to temperatures exceeding 122°F (50°C) Store in awell-ventilated place

Disposal: Not Applicable

_____________________________________________________________________________________________

Flammable Aerosols Category 1Gases Under Pressure

Page 1 / 6

Liquefied gas

Symbols:


www.spartanchemical.com

www.spartanchemical.com

_____________________________________________________________________________________________6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015

Hazards Not Otherwise Classified: Not Applicable

Other Information: • May cause skin irritation.• May be harmful if swallowed.• Inhalation of vapors or mist may cause respiratory irritation.• Keep out of reach of children.


Chemical Name CAS No Weight-%water 7732-18-5 60-100

2-butoxyethanol 111-76-2 5-10isopropanol 67-63-0 1-5

propane 74-98-6 1-5N-butane 106-97-8 1-5

Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret.


-Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present andeasy to do. Continue rinsing. If eye irritation persists: Get medical attention.

-Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention.-Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a

poison control center or physician if you feel unwell.-Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious

person. Get medical attention if you feel unwell.Note to Physicians: Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media: Water spray (fog), FoamSpecific Hazards Arising from theChemical:

Extremely flammable aerosol. Exposure to high temperature may cause containers to burst.Bursting aerosol containers may be propelled from fire at high speed.

Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors.

Protective Equipment andPrecautions for Firefighters:

Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and fullprotective gear. Water may be used to cool closed containers to prevent pressure build-upand possible auto ignition or explosion when exposed to extreme heat.


Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water.Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with

non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite)and place in container for disposal according to local / national regulations (see Section 13).

_____________________________________________________________________________________________


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Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Intentional misuseby deliberately concentrating and inhaling contents may be harmful or fatal. Keep awayfrom heat/sparks/open flames/hot surfaces. — No smoking. Wash thoroughly afterhandling.



Storage Conditions: NFPA 30B Level 1 Aerosol. Do not store in direct sunlight or above 122 F° / 50 C°.Exposure to high temperature may cause containers to burst. Keep out of the reach ofchildren.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits: .Chemical Name ACGIH TLV OSHA PEL NIOSH2-butoxyethanol

111-76-2TWA: 20 ppm TWA: 50 ppm

TWA: 240 mg/m3

(vacated) TWA: 25 ppm(vacated) TWA: 120 mg/m3

(vacated) S*S*

IDLH: 700 ppmTWA: 5 ppm

TWA: 24 mg/m3

isopropanol 67-63-0

STEL: 400 ppmTWA: 200 ppm

TWA: 400 ppmTWA: 980 mg/m3


(vacated) STEL: 500 ppm(vacated) STEL: 1225 mg/m3


TWA: 980 mg/m3

STEL: 500 ppmSTEL: 1225 mg/m3

propane 74-98-6

TWA: 1000 ppm TWA: 1000 ppmTWA: 1800 mg/m3



TWA: 1800 mg/m3

N-butane 106-97-8

TWA: 1000 ppm (vacated) TWA: 800 ppm(vacated) TWA: 1900 mg/m3


Engineering Controls: Provide good general ventilation.If work practices generate dust, fumes, gas, vapors or mists which expose workers tochemicals above the occupational exposure limits, local exhaust ventilation or otherengineering controls should be considered.

Personal Protective Equipment Eye/Face Protection:

_____________________________________________________________________________________________

Wear splash goggles.Skin and Body Protection: Not required with expected use.Respiratory Protection:

Page 3 / 6

Not required with expected use.If occupational exposure limits are exceeded or respiratory irritation occurs, use of aNIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section3 should be considered.

General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling.See 29 CFR 1910.132-138 for further guidance.




Reactivity: This material is considered to be non-reactive under normal conditions of use.Chemical Stability: Stable under normal conditions.Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage.Conditions to Avoid: Extremes of temperature and direct sunlight.Incompatible Materials: Strong oxidizing agents. Strong acids.Hazardous DecompositionProducts:

May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors.


Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation.Symptoms of Exposure:-Eye Contact: Pain, redness, swelling of the conjunctiva and blurred vision.-Skin Contact: Drying of the skin.-Inhalation: Nasal discomfort and coughing.-Ingestion: Pain, nausea, vomiting and diarrhea.Immediate, Delayed, Chronic EffectsProduct Information: Data not available or insufficient for classification.

Target Organ Effects: -Eyes. Respiratory System. -Skin. Blood. Central nervous system. hematopoietic system.kidney. Liver,

Numerical Measures of ToxicityThe following acute toxicity estimates (ATE) are calculated based on the GHS document..ATEmix (oral): 4331 mg/kgATEmix (dermal): 11323 mg/kgATEmix (inhalation-gas): 10511385ATEmix (inhalation-dust/mist): 23.1 mg/lATEmix (inhalation-vapor): 22.9 mg/l

Component Acute Toxicity InformationChemical Name Oral LD50 Dermal LD50 Inhalation LC50

water 7732-18-5

> 90 mL/kg ( Rat ) Not Available Not Available


Appearance/Physical State: AerosolColor: WhiteOdor: solventpH: 10.0-11.0Melting Point / Freezing Point: No information available.Boiling Point / Boiling Range: 100 °C / 212 °F (Product without propellant)Flash Point: < -18 °C / < 0 °F (Propellant-estimated)Evaporation Rate: <1 (Butyl acetate = 1)Flammability (solid, gas) No information available.Upper Flammability Limit: No information available.Lower Flammability Limit: No information available.Vapor Pressure: No information available.Vapor Density: No information available.Specific Gravity: 0.96 (Product without propellant)Solubility(ies): No information available.

_____________________________________________________________________________________________

Partition Coefficient: No information available.Autoignition Temperature: No information available.

Page 4 / 6

Decomposition Temperature: No information available.Viscosity: No information available.



2-butoxyethanol 111-76-2

= 470 mg/kg ( Rat ) = 2270 mg/kg ( Rat ) = 220 mg/kg (Rabbit )

= 2.21 mg/L ( Rat ) 4 h = 450 ppm( Rat ) 4 h

isopropanol 67-63-0

= 4396 mg/kg ( Rat ) = 12800 mg/kg ( Rat ) = 12870mg/kg ( Rabbit )

= 72.6 mg/L ( Rat ) 4 h

propane 74-98-6

Not Available Not Available = 658 mg/L ( Rat ) 4 h

N-butane 106-97-8

Not Available Not Available = 658 mg/L ( Rat ) 4 h

Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA.


EcotoxicityChemical Name Algae/Aquatic Plants Fish Toxicity to

MicroorganismsCrustacea

2-butoxyethanol 111-76-2

Not Available 1490: 96 h Lepomismacrochirus mg/L LC50

static 2950: 96 h Lepomismacrochirus mg/L LC50

Not Available 1698 - 1940: 24 h Daphniamagna mg/L EC50 1000: 48

h Daphnia magna mg/LEC50

isopropanol 67-63-0

1000: 96 h Desmodesmussubspicatus mg/L EC50

1000: 72 h Desmodesmussubspicatus mg/L EC50

9640: 96 h Pimephalespromelas mg/L LC50

flow-through 11130: 96 hPimephales promelas mg/LLC50 static 1400000: 96 hLepomis macrochirus µg/L

LC50

Not Available 13299: 48 h Daphnia magnamg/L EC50

Persistence and Degradability: No information available.Bioaccumulation: No information available.

Other Adverse Effects: No information available.


Disposal of Wastes: Dispose of in accordance with federal, state and local regulations.Contaminated Packaging: Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with

federal, state and local regulations.


DOT: UN/ID No: UN1950Proper Shipping Name: AerosolsHazard Class: 2.1Special Provisions: This product meets the exception requirements of section 49 CFR 173.306 as a limited

quantity and may be shipped as a limited quantity.


TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory)All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances.

SARA 313This product contains the following listed substances:2-butoxyethanol

_____________________________________________________________________________________________

CAS No 111-76-2 applies to R-(OCH2CH2)n-OR', where n = 1, 2, or 3, R=Alkyl C7 or less, or R = Phenyl or Alkyl substitutedphenyl, R' = H or Alkyl C7 or less, or OR' consisting of Carboxylic acid ester, Sulfate, Phosphate, Nitrate, or Sulfonate, ChemicalCategory N230

SARA 311/312 Hazard Categories

Page 5 / 6

Acute Health Hazard: Yes



Chronic Health Hazard: NoFire Hazard: NoSudden release of pressure hazard: YesReactive Hazard: No

California Proposition 65This product contains the following Proposition 65 chemicals

Chemical Name California Proposition 65formaldehyde - 50-00-0 Carcinogen

WARNING: This product contains a chemical known to the State of California to cause cancer.


Revision Date: 22-Jan-2015Reasons for Revision: No information available.

Disclaimer:The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and beliefat the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Theinformation relates only to the specific material designated and may not be valid for such material used in combinationwith any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

NFPA Health Hazards: 2

_____________________________________________________________________________________________

Flammability: 1 Instability: 0 Special: N/AHMIS

Page 6 / 6

Health Hazards: 2 Flammability: 2 Physical Hazards: 2


SAFETY DATA SHEET

Issuing Date May 23, 2015

Revision Date New

Revision Number 0

Page 1 / 9

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Clorox Commercial Solutions® Green Works® 99% Naturally Derived General

Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Other means of identification Synonyms None Recommended use of the chemical and restrictions on use Recommended use Ready-to-use general purpose cleaner dilution from the Clorox® EZ Dilute™ system Uses advised against No information available Details of the supplier of the safety data sheet Supplier Address Clorox Professional Products Company 1221 Broadway Oakland, CA 94612 Phone: 1-510-271-7000

Emergency telephone number Emergency Phone Numbers For Medical Emergencies call: 1-800-446-1014

For Transportation Emergencies, call Chemtrec: 1-800-424-9300


Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate

Revision Date New

Page 2 / 9

2. HAZARDS IDENTIFICATION Classification This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). GHS Label elements, including precautionary statements

Emergency Overview

This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).

Appearance Clear,

colorless-to-very-light green

Physical State Thin liquid

Odor Lemon

Precautionary Statements - Prevention None Precautionary Statements - Response None Precautionary Statements - Storage None Precautionary Statements - Disposal None Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 0.3% of the mixture consists of ingredient(s) of unknown toxicity Other information May cause slight eye irritation. Interactions with Other Chemicals No information available.


This product contains no substances that at their given concentrations are considered to be hazardous to health.



Revision Date New

Page 3 / 9

4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Hold eye open and rinse slowly and gently with water for 15–20 minutes. If present, remove

contact lenses after the first 5 minutes of rinsing, then continue rinsing eye. Call a poison control center or doctor for further treatment advice.

Skin Contact Rinse skin with plenty of water. If irritation persists, call a doctor. Inhalation Move to fresh air. If breathing problems develop, call a doctor. Ingestion Drink a glassful of water. Call a doctor or poison control center. Most important symptoms and effects, both acute and delayed Most Important Symptoms and Effects

May cause slight eye irritation.

Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical Hazardous Combustion Products Oxides of carbon. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge No. Protective equipment and precautions for firefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protectivegear.



Revision Date New

Page 4 / 9

6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with eyes. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental Precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary

treatment facility in advance to assure ability to process washed-down material.

7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with

eyes, skin, and clothing. Do not eat, drink, or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Keep containers tightly closed. Incompatible Products None known.


Control parameters Exposure Guidelines This product does not contain any ingredients with occupational exposure limits that are at

concentrations below their cut-off values/concentrations and that contribute to the hazard classification of the product.

Appropriate engineering controls Engineering Measures Showers

Eyewash stations Ventilation systems

Individual protection measures, such as personal protective equipment Eye/Face Protection No special protective equipment required. Skin and Body Protection No special protective equipment required. Respiratory Protection No protective equipment is needed under normal use conditions. If irritation is experienced,

ventilation and evacuation may be required. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.



Revision Date New

Page 5 / 9

9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Thin liquid Appearance Clear

Odor Lemon Color Colorless-to-very- light green

Odor Threshold No information available Property Values

Remarks/ Method pH 6 - 9

None known Melting/freezing point No data available

None known Boiling point / boiling range No data available

None known Flash Point No data available

None known Evaporation rate No data available

None known Flammability (solid, gas) No data available

None known Flammability Limits in Air

Upper flammability limit No data available

None known Lower flammability limit No data available

None known Vapor pressure No data available

None known Vapor density No data available

None known Specific Gravity ~1.0

None known Water Solubility Complete

None known Solubility in other solvents No data available

None known Partition coefficient: n-octanol/water No data available

None known Autoignition temperature No data available

None known Decomposition temperature No data available

None known Kinematic viscosity No data available

None known Dynamic viscosity No data available

None known Explosive Properties Not explosive Oxidizing Properties No data available Other Information Softening Point No data available VOC Content (%) No data available Particle Size No data available Particle Size Distribution No data available

10. STABILITY AND REACTIVITY Reactivity No data available.

Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None known. Conditions to avoid None known. Incompatible materials None known. Hazardous Decomposition Products None known.



Revision Date New

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11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Exposure to vapor or mist may cause slight respiratory tract irritation Eye Contact May cause slight irritation. Skin Contact May cause slight irritation. Ingestion Ingestion of liquid may cause slight irritation to mucous membranes and gastrointestinal tract. Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Ethanol 64-17-5

- - 125 mg/L (Rat, 4 h)

Information on toxicological effects Symptoms May cause slight redness and tearing of eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Ethanol has been shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage.

Chemical Name ACGIH IARC NTP OSHA

Ethanol 64-17-5

A3 Group 1 Known X

ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen

IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans

NTP (National Toxicology Program) Known - Known Carcinogen

OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present

Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity Contains a known or suspected carcinogen. Ethanol has been shown to be carcinogenic in

long-term studies only when consumed as alcoholic beverage. Contains a known or suspected reproductive toxin. Ethanol has been shown to be a reproductive toxin only when consumed as an alcoholic beverage. May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Repeated abuse can have long-term health effects.

Target Organ Effects Eyes, blood, central nervous system (CNS), liver, reproductive system, respiratory system.



Revision Date New

Page 7 / 9

Aspiration Hazard Not an aspiration hazard. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS documentNo information available.

12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated.

Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to MicroorganismsDaphnia Magna (Water

Flea)

Ethanol 64-17-5

LC50: 12.0 - 16.0 mL/L (96 h static) Oncorhynchus mykissLC50: 13400 - 15100 mg/L

(96 h flow-through) Pimephales promelas

LC50: > 100 mg/L (96 h static) Pimephales promelas

EC50 = 34634 mg/L 30 min EC50 = 35470 mg/L 5 min

LC50: 9268 - 14221 mg/L (48h ) Daphnia magna

EC50: 10800 mg/L (24 h ) Daphnia magna

EC50: 2 mg/L (48 h Static) Daphnia magna

Persistence and DegradabilityNo information available. Bioaccumulation

Chemical Name Log Pow Ethanol 64-17-5

-0.32

Other adverse effects No information available.

13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations. Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations.


DOT Not regulated. TDG Not regulated. ICAO Not regulated. IATA Not regulated IMDG/IMO Not regulated



Revision Date New

Page 8 / 9

15. REGULATORY INFORMATION Chemical Inventories TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt

from listing. DSL/NDSL All components are on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. US State Regulations California Proposition 65 This product contains the following Proposition 65 chemical. Ethyl alcohol is only a considered a Proposition 65 developmental and cancer hazard when it is ingested as an alcoholic beverage.

Chemical Name California Proposition 65 Ethanol 64-17-5

Developmental Cancer

U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Ethanol 64-17-5

X

International Regulations Canada WHMIS Hazard Class Not controlled.



Revision Date New

Page 9 / 9

16. OTHER INFORMATION NFPA

Health Hazard 0

Flammability 0

Instability 0

Physical and Chemical Hazards -

HMIS

Health Hazard 0

Flammability 0

Physical Hazard 0

Personal Protection -

Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501

Preparation/Revision Date May 23, 2015 Revision Note Reference

New INT0049

General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.



1. IDENTIFICATION

Product Name Comet� Deodorizing Cleanser with Chlorinol�

Product Code(s) 3-10

Product ID: 97086927_PROF_NG

Product Type: Finished Product - Professional Use Only

Recommended Use Hard Surface Cleaner

Restrictions on Use Do not mix with other cleaning products or chemicals as irritating fumes may be formed.

Manufacturer Procter & Gamble Professional2 P&G PlazaCincinnati, Ohio 45202

Procter & Gamble Inc.P.O. Box 355, Station AToronto, ON M5W 1C5

1-800-332-7787

E-mail Address [email protected]

Emergency Telephone Transportation (24 HR)CHEMTREC - 1-800-424-9300(U.S./ Canada) or 1-703-527-3887Mexico toll free in country: 800-681-9531

2. HAZARD IDENTIFICATION

This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:.

Hazard Category Eye Damage / Irritation Category 2B

Page 1 / 7

Hazard pictograms None

Issuing Date: 12-Jun-2015

Precautionary Statements -Prevention

Wash hands thoroughly after handlingDo not mix with other cleaning products or chemicals as irritating fumes may be formed

Signal Word WARNING

Revision Date: 12-Jun-2015

Precautionary Statements -Response

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsingIf eye irritation persists: Get medical advice/attentionIF SWALLOWED:Drink 1 or 2 glasses of water

SAFETY DATA SHEET

Version 1

Hazard Statements Causes eye irritation



Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation


First aid measures for different exposure routes

Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists.

Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists.

Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately ifsymptoms occur.

Inhalation Move to fresh air. If symptoms persist, call a physician.

Most important symptoms/effects,acute and delayed

None under normal use conditions.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to Physician Treat symptomatically.


Suitable extinguishing media Dry chemical, CO 2, alcohol-resistant foam or water spray.

Unsuitable Extinguishing Media None.

Special hazard None known.

Special protective equipment forfire-fighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH(approved or equivalent) and full protective gear.

Specific hazards arising from thechemical

None.

Page 2 / 7


Precautionary Statements -Disposal

Dispose of contents/container in accordance with local regulation

Precautionary Statements -Storage

None

97086927_PROF_NG - Comet� Deodorizing Cleanser withChlorinol�

Hazards not otherwise classified(HNOC)

None

Chemical Name Synonyms Trade Secret CAS-No Weight %Limestone - No 1317-65-3 40 - 100

Sodium carbonate - No 497-19-8 5 - 10Symclosene - No 87-90-1 1 - 5

Benzenesulfonic acid,mono-C10-16-alkyl derivs., sodium

salts

- No 68081-81-2 1 - 5



Personal precautions, protective equipment and emergency procedures

Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing.

Advice for emergency responders Use personal protective equipment as required.

Methods and materials for containment and cleaning up

Methods for containment Prevent dust cloud. Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Sweep up and shovel into suitable containers for disposal. Dispose of in accordance withlocal regulations.


Precautions for safe handling

Advice on safe handling Use personal protective equipment as required. Keep container closed when not in use.Never return spills in original containers for re-use. Keep out of the reach of children.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible products Do not mix with other cleaning products or chemicals as irritating fumes may be formed.


Control parameters

Exposure Guidelines .

Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PELLimestone 1317-65-3 TWA: 15 mg/m3 total dust

TWA: 5 mg/m3 respirablefraction

(vacated) TWA: 15 mg/m3

total dust(vacated) TWA: 5 mg/m3

respirable fraction

Mexico: TWA 10 mg/m3

Mexico: STEL 20 mg/m3

Chemical Name CAS-No Alberta Quebec Ontario TWAEV British ColumbiaLimestone 1317-65-3 TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3

TWA: 3 mg/m3

STEL: 20 mg/m3

No relevant exposure guidelines for other ingredients

Exposure controls

Engineering Measures Distribution, Workplace and Household Settings:Ensure adequate ventilation

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Where reasonably practicable this should be achieved by the use of local exhaustventilation and good general extraction

Personal Protective Equipment

Page 3 / 7

Revision Date: 12-Jun-201597086927_PROF_NG - Comet� Deodorizing Cleanser withChlorinol�


Eye Protection Distribution, Workplace and Household Settings:No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Use appropriate eye protection

Hand Protection Distribution, Workplace and Household Settings:No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Protective gloves

Skin and Body Protection Distribution, Workplace and Household Settings:No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Wear suitable protective clothing

Respiratory Protection Distribution, Workplace and Household Settings:No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):In case of insufficient ventilation wear suitable respiratory equipment


Physical State @20°C solidAppearance whiteOdor PineOdor threshold No information available

Oxidizing properties These substances will accelerate burning when involved in a fire.VOC Content (%) Products comply with US state and federal regulations for VOC content in consumer

products.


Reactivity None under normal use conditions.

Page 4 / 7

No information available

Lower Flammability Limit No information available

Values

Vapor pressure No information available

Boiling point/boiling range

Vapor density




Relative density No information available

Note

Water solubility

Flash point

15%Solubility in other solvents


No information availablePartition coefficient: n-octanol/waterNo information available

pH value

Autoignition temperature

Evaporation rate

No information available .Decomposition temperature


No information available .Viscosity of Product No information available

11.5

Flammability (solid, gas)

Property


(as 1% solution)

Flammability Limits in Air

Melting/freezing point

Upper flammability limit




Stability Stable under normal conditions.

Hazardous polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

Conditions to Avoid None under normal processing.

Materials to avoid Do not mix with other cleaning products or chemicals as irritating fumes may be formed.

Hazardous Decomposition Products None under normal use.


Product Information Information on likely routes of exposure

Inhalation No known effect.Skin contact No known effect.Ingestion No known effect.Eye contact Irritating to eyes.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Acute toxicity No known effect.Skin corrosion/irritation No known effect.Serious eye damage/eye irritation Irritating to eyes.Skin sensitization No known effect.Respiratory sensitization No known effect.Germ cell mutagenicity No known effect.Neurological Effects No known effect.Reproductive toxicity No known effect.Developmental toxicity No known effect.Teratogenicity No known effect.STOT - single exposure No known effect.STOT - repeated exposure No known effect.Target Organ Effects No known effect.Aspiration hazard No known effect.Carcinogenicity No known effect.

Component Information

Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 InhalationSodium carbonate 497-19-8 2800 mg/kg bw > 2000 mg/kg bw (US EPA

16 CFR 1500.40)-


Ecotoxicity

The product is not expected to be hazardous to the environment.

Persistence and degradability No information available.

Bioaccumulative potential No information available.

Mobility No information available.



Page 5 / 7




Waste treatment

Waste from Residues / UnusedProducts

Disposal should be in accordance with applicable regional, national and local laws andregulations.

Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws andregulations.

California Hazardous Waste Codes(non-household setting)

331


DOT Not regulated

IMDG Not regulated

IATA Not regulated

15. REGULATORY INFORMATIONU.S. Federal Regulations

SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

CERCLAThis material, as supplied, contains one or more substances regulated as a hazardous substance under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):

Chemical Name CAS-No HazardousSubstances RQs

Extremely HazardousSubstances RQs

CERCLA/SARA 302TPQ

Piperidine 110-89-4 - 1000 lb 1000 lb

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air ActAmendments of 1990.

Clean Water ActThis product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42)

California Proposition 65This product is not subject to warning labeling under California Proposition 65.

U.S. State Regulations (RTK)

Chemical Name CAS-No New JerseyLimestone 1317-65-3 X

Symclosene 87-90-1 X

Chemical Name CAS-No PennsylvaniaLimestone 1317-65-3 X

Symclosene 87-90-1 X

Page 6 / 7




International Inventories

United StatesAll intentionally-added components of this product(s) are listed on the US TSCA Inventory.

CanadaThis product is in compliance with CEPA for import by P&G.

LegendTSCA - United States Toxic Substances Control Act Section 8(b) InventoryCEPA - Canadian Environmental Protection Act


HMIS Ratings Health hazard 2Flammability 0Physical hazard 0

Health hazard 2Flammability 0Instability 0

Issuing Date: 12-Jun-2015Revision Date: 12-Jun-2015DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of itspublication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any other materials or in any process, unlessspecified in the text

End of SDS

Page 7 / 7




28 May 2015

aqua (water) diluent 7732-18-5 Not applicable

thymol (a component of thyme oil) antimicrobial active 8007-46-3 0.05% 980 mg/kgOther ingredients: . 99.95% .

Ingredient Function CAS Number Concentration1 LD502

Active ingredient . .

Eyes Minimal eye irritant category IV

Regardless of hazard classification, Seventh Generation discloses all intentionally added ingredients and, if applicable incidental ingredients ≥1% on the consumer product label.

Section 3: Composition, Information on Ingredients


Emergency Overview No symptoms or effects under normal use. May cause slight irritation of eyes, skin or respiratory tract.

This product is not considered hazardous under the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).This product is not considered hazardous under the WHMIS 2015.

Classification

U.S.

Canada

Section 2: Hazards Identification

APERSONAL PROTECTION

Not determined

Hazardous Materials Identification System (HMIS) Rating

0

0

0PHYSICAL HAZARDS

FLAMMABILITY

Skin Slight dermal irritant category IV. Non-sensitizer.Ingestion May cause transient gastrointestinal irritation.

HEALTHLegend: 4-Severe, 3-Serious, 2-Moderate, 1-Slight, 0-Minimal

Inhalation May cause slight irritation.Hazards not otherwise identified None known

Percent ingredients with unknown acute toxicity 0% of the product consists of ingredients of unknown acute oral toxicity. Refer to Section 3.

SAFETY DATA SHEET

National Fire Protection Association (NFPA) Rating

Botanical Disinfecting Multi-Surface CleanerHard Surface Disinfecting and Cleaning

Seventh Generation, Inc.60 Lake Street, Burlington, VT 05401, USA

This Safety Data Sheet (SDS) is intended to provide product information for workplaces, emergency personnel and other situations where there is potential for longer exposure or exposure to larger quantities of product. For consumer use, applicable precautionary information is provided on the product label. This SDS is designed to cover both U.S. and Canadian requirements. Differences between U.S. and Canadian requirements are noted where applicable.

Issue date

Emergency Telephone Number U.S. Canada1-800-211-42791-800-255-3924 (ChemTel)

Monday -Friday 8 am - 5 pm ET (except holidays)Outside these hours

Address

Restrictions on Use Follow directions on the product label

Section 1: Identification of Product and Company

Product NameSynonymsProduct Use

Manufacturer Name

Disinfecting Multi-Surface Cleaner

FM000054-00.2

Page 1 of 6


SAFETY DATA SHEET

Safe HandlingHousehold Setting Use as directed on product label.Industrial Setting Wear appropriate personal protective equipment (refer to section 8).

Section 7: Handling and Storage

Section 6: Accidental Release Measures

Personal Precautions

Protective Equipment and Precautions for FirefightersFire fighters should wear full protective clothing and self contained breathing apparatus as for surrounding fire.

Suitable Extinguishing Media As appropriate for surrounding fire. Use water, dry chemical, carbon dioxide or foam.

Unsuitable Extinguishing Media Not available.

Most important symptoms and effects Acute exposure may result in eye irritation.

Specific Hazards arising from the chemical mixture Not available.Hazardous Combustion Products Not available.

Section 4: First Aid Measures

*Lemongrass Citrus Scent: cymbopogon nardus (citronella) oil, cymbopogon schoenanthus (lemongrass) oil. Citral is a component of these essential oils. 1 Where ranges are shown, the exact concentration has been withheld as a trade secret. 2 LD50 Acute oral toxicity (rat) – This is a value provided by the raw material supplier or scientific literature. It is not a value generated by Seventh Generation by testing using rats. Seventh Generation uses alternative, non-animal based methods and scientific literature to determine the safety classification of our products and their ingredients.

sodium citrate water softener 6132-04-3 6730 mg/kg

essential oils* fragrance mixture >5000 mg/kgoriganum vulgare (oregano) oil fragrance 8007-11-2 1850 mg/kg

copper sulfate pentahydrate (bluestone) water mineralizer 7758-99-8 300 mg/kg

citric acid water softener 77-92-9 3000 mg/kg

sodium lauryl sulfate cleaning agent 151-21-3 ≤1% 1288 mg/kg

Eye ContactHold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Call a doctor or poison control center for treatment advice.

Section 5: Fire Fighting Measures

Skin Contact Rinse thoroughly with water if skin contact occurs. Call a physician if irritation develops or persists.

IngestionHave person sip a glass of water if able to swallow. Do not induce vomiting unless told to by a doctor or poison control center. Do not give anything to an unconscious person.

Inhalation Remove to fresh air. If breathing is affected, call a physician.Notes to Physician Treat symptomatically.

Industrial Setting Wear appropriate personal protective equipment (refer to Section 8).Environmental Precautions Avoid entry into lakes, streams, ponds or public waterways.Methods for Containment and Cleaning Up

Household SettingSmall spills and leaks may be cleaned up and disposed of in normal household trash or diluted and disposed of via sewer.

Industrial Setting

Before attempting clean up, refer to hazard data given. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labeled containers. Prevent extremely large spills from entering sewers or waterways. Dispose in accordance with all applicable local, state, and federal regulations.

Page 2 of 6


SAFETY DATA SHEET

Possibility of Hazardous Reactions None known.

Household SettingIn general, cleaning products should not be mixed with other household chemicals, unless specifically provided for in the use directions.

Section 10: Stability and Reactivity

Industrial Setting None known.Hazardous Decomposition Products None known.

Conditions to Avoid None known.Incompatible Materials

VOC (weight %) Not available.

Partition Coefficient: n-octanol/water Not available.Viscosity Not available.

Vapor Density (Air = 1) Not available.Solubility in Water Soluble

Specific Gravity (H2O = 1) 1.00-1.02Relative Density Not available.

Lower Explosive Limit (LEL) Not applicable.Vapor Pressure (mmHg) Not available.

Evaporation Rate As per water.Upper Explosive Limit (UEL) Not applicable.

Flash Point Not available. Aqueous Solution.

Freezing Point As per water.Initial Boiling Point and Boiling Range As per water.

pH 4.0 - 5.0Melting Point As per water.

Odor Scented. Characteristic of the ingredientsOdor Threshold Not available.

Color Colorless (water-white)Clarity Clear

Physical State Liquid.

Section 9: Physical and Chemical Properties

Eye Protection Goggles or other protective eye wear may be worn for protection. Skin Protection Gloves may be worn for protection. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Safe Storage

KEEP OUT OF REACH OF CHILDREN AND PETS.Nonrefillable container. Store airtight at room temperature in original container and keep container closed when not in use.Avoid freezing.

Storage Incompatibilities None known.

Industrial Setting Respiratory Protection None required under normal conditions. General ventilation required.

Exposure Limits None known.Engineering Controls Not applicable.Personal Protective Equipment (PPE)

Household Setting No special precautions necessary as long as product is used as directed.

Section 8: Exposure Controls, Personal Protection

Reactivity None known.Chemical Stability Stable.

Page 3 of 6


SAFETY DATA SHEET

Washington Hazardous Waste Code WT02

Industrial Setting

When disposed as waste in its original form, this product is not considered hazardous waste under Federal regulations, however regulations may vary by state or province and may designate it as hazardous waste. Check with your local waste and waste water authorities. We are aware of the following state waste classifications:

California Hazardous Waste Code 232 Connecticut Hazardous Waste Code CT04 Michigan Liquid Waste Code 029L Vermont Hazardous Waste Code VT06

Product WasteAny disposal must be in compliance with applicable local, state, provincial and federal laws and regulations.

Household Setting Product residues in the bottle may be discarded in trash, or diluted with water and disposed via sewer.

Compatible with septic systems.

Section 13: Disposal Considerations

Environmental Fate No adverse effects expected.

Bioaccumulative Potential Not applicable.Mobility in Soil Not available.

Ecotoxicity Not available.Persistence and Degradability Meets requirements for ready biodegration based on OECD 301B.

Section 12: Ecological Information

Target Organ Effects Not expected to have chronic health effects.

Not expected to have chronic health effects.Reproductive EffectsTeratogenicity Not expected to have chronic health effects.Mutagenicity Not expected to have chronic health effects.

NTP No Ingredients ListedIARC No Ingredients ListedOSHA No Ingredients Listed

Carcinogenicity Not expected to have chronic health effects.

Not expected to have chronic health effects.

SensitizationDoes not indicate a potential for allergic contact sensitization, based on Human Repeat Insult Patch Test (HRIPT).

Skin Contact Non to slight dermal irritant category IV, based on ingredients and in-vitro data.Component Information Refer to section 3 for ingredient LD50 (acute oral).

Effects of Acute Exposure

Section 11: Toxicological Information

Oral Toxicity LD50 >5000 mg/kg, calculated based on ingredients.Dermal Toxicity LD50 >5000 mg/kg, calculated based on ingredients.Inhalation Toxicity >20 mg/L/4h, based on ingredients.

Eye Contact

Potential Route(s) of Exposure Eyes. Skin. Ingestion.

Minimal eye irritant category IV, based on ingredients and in-vitro data.

Effects of Chronic Exposure

Page 4 of 6


SAFETY DATA SHEET

Offer empty container for recycling. If recycling is not available, discard in trash.

Prepared by Seventh Generation Inc.Issuing Date 28 May 2015

Section 16: Other Information

Health Canada Registration Number DIN 02415070

Right to KnowRegardless of hazard classification, Seventh Generation discloses all intentionally added ingredients and, if applicable incidental ingredients ≥1% on the product label. Please refer to Section 3. of this SDS for ingredient listing.

OtherFragrances used in this product comply with applicable International Fragrance Association (IFRA) guidance.

California Prop 65 This product is not subject to the labeling requirements of California’s Proposition 65.

California Air Resources Board (CARB) Meets applicable California Air Resource Board requirements for consumer products.

Canada

Domestic Substances List (DSL)This product complies with the inventory requirements under Canada’s Domestic Substances List (DSL) or Non-Domestic Substances List (NDSL) or is otherwise in compliance with the New Substances Notification (NSN) regulations or exemptions.

Toxic Substances Control Act (TSCA) This product complies with the inventory requirements of the U.S. Toxic Substances Control Act (TSCA).

U.S.

EPA Registration Number 84683-3-86066California DPR Registration Number 84683-3-ZA-86066

Section 15: Regulatory Information

IATA (Air Transport) Not regulated.IMDG (Marine Transport) Not regulated.

U.S. States (Surface Transport)

Not regulated as finished product.

Regulated in some states if the product is disposed of in its original form as waste by commercial users/handlers. Refer to Section 13. for applicable state waste codes.

Canadian TDG (Surface Transport) Not regulated.

U.S. DOT (Surface Transport) Not regulated.

Section 14: Transport Information

Empty Packaging

Revision Date 28 May 2015

Please note: This product is manufactured and marketed for consumer use and should be used as directed on the product label for the intended purpose. Seventh Generation warrants that this product conforms to our standard specification when released to the market and when used according to directions. To the best of our knowledge, the information contained herein is accurate. However, we do not assume any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of the suitability of any product is the sole responsibility of the user. All products may present unknown hazards and should be used with requisite caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Other abbreviations used in this document:

Revision Note Revised format as per OSHA 2012 and WHMIS 2015.

Page 5 of 6


SAFETY DATA SHEET


DOT – (U.S.) Department of TransportationEPA – (U.S.) Environmental Protection AgencyIARC – International Agency for Research on CancerNTP – (U.S. Department of Health and Human Services) National Toxicology ProgramOSHA – (U.S.) Occupational Safety and Health AdministrationTDG – (Canadian) Transport of Dangerous GoodsWHMIS – (Canadian) Workplace Hazardous Materials Information System

Page 6 of 6


Expo White Board Cleaner

CHEMTREC (U.S. and Canada) 1-800-424-9300

SAFETY DATA SHEET

Product name

Emergency telephone number (with hours of operation)

Section 1. Identification:

:

Manufacturer : Newell Rubbermaid3500 Lacey Road, 10th FloorDowners Grove, IL 60515USA800-323-0749 or 630-829-2500

Material uses : Cleaning solutions.

Section 2. Hazards identification

Not classified.Classification of the substance or mixture

:

Signal word : Not applicable

Hazard statements : No known significant effects or critical hazards.

Precautionary statements

Prevention : Not applicable.

Response : Not applicable.

Storage : Not applicable.

Disposal : Not applicable.

GHS label elements

General : Read label before use. If medical advice is needed, have product container or label at hand.

OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product.

Hazards not otherwise classified

: None known.

Section 3. Composition/information on ingredients

3-butoxypropan-2-ol 2 - 5 5131-66-8

Ingredient name CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Substance/mixture : Mixture

Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 1/8




Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

:

:

:

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Description of necessary first aid measures

Specific treatments : No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

No specific data.

:

:

:

Eye contact : No specific data.

Potential acute health effects

See toxicological information (Section 11)


Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:carbon dioxidecarbon monoxide

In a fire or if heated, a pressure increase will occur and the container may burst.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

:

:

:

None known.

Suitable extinguishing media

:

Unsuitable extinguishing media

:

Special protective actions for fire-fighters

:




Section 6. Accidental release measures

Environmental precautions


Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

:

: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill :

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :


For non-emergency personnel

For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage,including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

:

:

Protective measures Put on appropriate personal protective equipment (see Section 8).:


None.

Section 8. Exposure controls/personal protection

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Control parameters

Individual protection measures

Occupational exposure limits





Hand protection

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Eye/face protection

Respiratory protection :

:

:

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

:

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Skin protection

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid.

Not available.

Not available.

Not available.

Not available.

Not available.

Not available.Odor

pH

Clear.Color

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Not available.

Not available.

Not available.

Viscosity Not available.

Not available.Odor threshold

Partition coefficient: n-octanol/water

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

Appearance

Boiling point : Not available.

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

: Not available.

Burning rate Not applicable.:

Burning time : Not applicable.

SADT Not available.:

Decomposition temperature : Not available.

Solubility in water : Not available.




Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid No specific data.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

No specific data.

:

:

:

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Acute toxicity

3-butoxypropan-2-ol LD50 Dermal Rabbit 3100 mg/kg -

Product/ingredient name Result Species Dose Exposure

Carcinogenicity

No known significant effects or critical hazards.

Mutagenicity


Teratogenicity


Reproductive toxicity


Irritation/Corrosion


Sensitization


Information on the likely routes of exposure

Delayed and immediate effects and also chronic effects from short and long term exposure

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)



Aspiration hazard


Information on toxicological effects

: Not available.

Potential immediate effects

: Not available.

Short term exposure

Potential delayed effects : Not available.





No known significant effects or critical hazards.General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Potential chronic health effects

Numerical measures of toxicity

Dermal 63798.6 mg/kg

Route ATE value

Acute toxicity estimates


: Not available.

Long term exposure


Section 12. Ecological information

LogPow BCF Potential

Bioaccumulative potential

Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

3-butoxypropan-2-ol 1.2 - low

Toxicity


Persistence and degradability


Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

:Disposal methods




Section 14. Transport information

-

-

-

-

-

-

-

Not regulated.

-

-

Not regulated. Not regulated.

- - -

DOT Classification

IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

Special precautions for user

No. No. No.

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

:

TDG Classification

Not regulated.

-

-

-

No.

-

Mexico Classification

Not regulated.

-

-

-

No.

-

Section 15. Regulatory informationU.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted.

SARA 311/312

Classification : Not applicable.

3-butoxypropan-2-ol 2 - 5 Yes. No. No. Yes. No.

Name % Fire hazard

Sudden release of pressure

Reactive Immediate (acute)health hazard

Delayed (chronic)health hazard

Composition/information on ingredients

The following components are listed: Propylene glycol butyl ether

Not controlled under WHMIS (Canada).

None of the components are listed.

Canada

WHMIS (Canada)

Canadian lists

Canadian NPRI

CEPA Toxic substances :

:

:

Canada inventory : All components are listed or exempted.

This product does not contain Chemicals known to State of California to cause cancer, birth defects, or reproductive harm.

California Prop. 65

Section 16. Other informationHistory

Date of issue/Date of revision

Version

Prepared by

Date of previous issue

:

:

:

:

8/5/2015

No previous validation

1

Product Safety.




Section 16. Other information

Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of knowledge and on national and community regulations. The mixture must not be used for other uses than those specified in section 1 without having first obtained written handling instructions. It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations. The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture and not as a guarantee of the properties thereof.

Indicates information that has changed from previously issued version.

Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientUN = United Nations



NA

FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015

1 / 9

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name

: FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER

Product code : 200000038598

: B02703630000

Manufacturer or supplier's details Company : Colgate-Palmolive Co

300 Park Avenue New York, NY 10022

Telephone : US: Consumer Affairs - 1-800-468-6502

Emergency telephone number

: For emergencies involving spill, leak, fire, exposure or acci-dent call CHEMTREC (24hr) at (800) 424-9300 or (703) 527-3887.

Medical Emergency (24HR):

For MEDICAL EMERGENCIES involving this product call: (888) 489-3861

Recommended use of the chemical and restrictions on use Recommended use

: Formulated all purpose cleaner for household use.

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview Appearance

liquid

Colour

purple

GHS Classification Skin irritation

: Category 2

Eye irritation

: Category 2A

Skin sensitisation

: Category 1

GHS Label element Hazard pictograms

:

Signal word : Warning


NA


2 / 9

Hazard statements

: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation.


: Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear eye protection/ face protection. P280 Wear protective gloves. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ atten-tion. P362 Take off contaminated clothing and wash before reuse. Disposal: P501 Dispose of contents/ container to an approved waste dis-posal plant.

Potential Health Effects Inhalation

: No adverse effects due to inhalation are expected.

Skin

: May cause skin irritation upon prolonged contact.

Eyes

: Causes eye irritation on direct contact.

Ingestion

: May be harmful if swallowed in large quantities.

Aggravated Medical Condi-tion

: None known.

Carcinogenicity: IARC

No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH

No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino-gen by ACGIH.

OSHA

No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino-gen by OSHA.

NTP

No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen


NA


3 / 9

by NTP.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components Chemical Name CAS-No. Concentration (%) (C10-C16) Alkylbenzenesulfonic acid 68584-22-5 >= 1 - < 5

SECTION 4. FIRST AID MEASURES

If inhaled

: Remove victim to fresh air. Get medical attention, if symp-toms persist.

In case of skin contact

: Flush skin with large amounts of water. If irritation develops and persists, get medical attention.

In case of eye contact

: Flush eyes with water at least 15 minutes. Get medical atten-tion if eye irritation develops or persists.

If swallowed

: Drink 8 ounces of clear water. Get medical attention.

Most important symptoms and effects, both acute and delayed

: Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.

SECTION 5. FIREFIGHTING MEASURES


: Use water spray, alcohol-resistant foam, dry chemical or car-bon dioxide.

Hazardous combustion prod-ucts

: No hazardous combustion products are known

Special protective equipment for firefighters

: Self-contained breathing apparatus and full protective clothing should be worn when fighting chemical fires.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec-tive equipment and emer-gency procedures

: Use personal protection recommended in Section 8 of the SDS.


: Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of wa-ter.

SECTION 7. HANDLING AND STORAGE


NA


4 / 9

Conditions for safe storage

: Store at controlled room temperature at 20-25°C (68-77°F).

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters Contains no substances with occupational exposure limit values.

Engineering measures : In an industrial work environment, no special precautions or control measures are required.

Personal protective equipment Respiratory protection

: No personal respiratory protective equipment normally re-quired.

Protective measures

: In an industrial work environment, if a splash is likely, chemi-cal goggles may be needed. Prolonged skin contact may require protective gloves. For consumer use, no unusual precautions are necessary.

Hygiene measures

: In an industrial work environment, avoid eye and prolonged skin contact.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

: liquid

Colour

: purple

pH

: 7

Flash point

: No data available

SECTION 10. STABILITY AND REACTIVITY

Possibility of hazardous reac-tions

: Hazardous polymerisation does not occur.

Incompatible materials

: Strong oxidizing agents


: None known.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity Not classified based on available information.


NA


5 / 9

Product: Acute oral toxicity

: Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method

Acute inhalation toxicity

: Acute toxicity estimate : > 10 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method

Components: (C10-C16) Alkylbenzenesulfonic acid: Acute oral toxicity

: LD50 (Rat): 1,460 mg/kg Method: No information available.


: LC50 (Rabbit): > 1.9 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403

Acute dermal toxicity

: LD50 (Rabbit): > 5,000 mg/kg Method: OECD Test Guideline 402

Skin corrosion/irritation Causes skin irritation.

Components: (C10-C16) Alkylbenzenesulfonic acid: Result: Corrosive after 1 to 4 hours of exposure

Serious eye damage/eye irritation Causes serious eye irritation.

Components: (C10-C16) Alkylbenzenesulfonic acid: Result: Irreversible effects on the eye

Respiratory or skin sensitisation Skin sensitisation: May cause an allergic skin reaction. Respiratory sensitisation: Not classified based on available information.

Components: (C10-C16) Alkylbenzenesulfonic acid: Exposure routes: Inhalation Remarks: No data available Exposure routes: Dermal Result: May cause sensitisation by skin contact.

Germ cell mutagenicity Not classified based on available information.


NA


6 / 9

Carcinogenicity Not classified based on available information.

Reproductive toxicity Not classified based on available information.

STOT - single exposure Not classified based on available information.

STOT - repeated exposure Not classified based on available information.

Aspiration toxicity Not classified based on available information.

Further information

Product: Remarks: This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the SDS.

SECTION 12. ECOLOGICAL INFORMATION

The product has not been tested as a whole for environmental toxicity. However, environmental infor-mation on the ingredients in this product have been reviewed by the Environmental, Health and Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This evalua-tion is based on available information on individual ingredients, interactions of ingredients, and similar ingredients. Biodegradability claims are supported by data on ingredients (i.e., surfactants are biode-gradable) or testing conducted on the final product (i.e., This product is biodegradable).

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods Waste from residues : Any disposal practice must be in compliance with local, state

and federal laws and regulations (contact local or state envi-ronment agency for specific rules). Do not dump in sewers, any body of water or on the ground.

SECTION 14. TRANSPORT INFORMATION

DOT : Not regulated. TDG : Not regulated. IATA : Not regulated.


NA


7 / 9

IMDG : Not regulated.

International Regulation

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.

National Regulations

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

Components CAS-No. Component RQ (lbs)

Calculated product RQ (lbs)

Sulfuric Acid 7664-93-9 1000 * Sulfuric Acid 7664-93-9 100 *

*: Calculated RQ exceeds reasonably attainable upper limit.

SARA 304 Extremely Hazardous Substances Reportable Quantity



Sulfuric Acid 7664-93-9 1000 *

*: Calculated RQ exceeds reasonably attainable upper limit. SARA 302

: No chemicals in this material are subject to the reporting re-quirements of SARA Title III, Section 302.

SARA 313

: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489).

Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Ta-ble 116.4A: SODIUM HYDROXIDE 1310-73-2 Sulfuric Acid SULFURIC ACID The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: SODIUM HYDROXIDE 1310-73-2


NA


8 / 9

Sulfuric Acid SULFURIC ACID This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307

Massachusetts Right To Know Sulfuric Acid SULFURIC

ACID

Pennsylvania Right To Know WATER Water 2-PHENOXYETHANOL 122-99-6 SODIUM HYDROXIDE 1310-73-2 Sulfuric Acid SULFURIC

ACID

New Jersey Right To Know WATER Water PROPYLENE GLYCOL PROPYL ETHER 1569-01-3 (C10-C16) Alkylbenzenesulfonic acid 68584-22-5

California Prop 65 : This product does not contain any chemicals known to State

of California to cause cancer, birth defects, or any other re-productive harm.

The components of this product are reported in the following inventories: TSCA

: All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory.

Inventories

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)


NA


9 / 9

SECTION 16. OTHER INFORMATION

Further information NFPA: HMIS III:

Disclaimer: The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or im-plied, as to the accuracy, reliability or completeness of the information and assumes no re-sponsibility for injury, damage or loss resulting from the use of the material.

Flammability

Hea

lth

Instability

1 1

0

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

1 0

2

Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic


SAFETY DATA SHEET

Issuing Date: 24-Feb-2015 Revision Date: 24-Feb-2015 Version 1

1. IDENTIFICATION

Product Name Febreze Air Effects - Sun Baked

Product ID: 92351338_RET_NG

Product Type: Finished Product - Consumer (Retail) Use Only

Recommended Use Air freshener

Restrictions on Use Safe to use around dogs and cats. As with other care products, not for use around birds.

Synonyms Febreze Air Effects - Summer Fruit Bouquet (92351338_A_RET_NG)Febreze Air Effects - Seaside Spring & Escape (92351338_B_RET_NG)Febreze Air Effects - Wintry Mint (96892319_RET_NG)Febreze Air Effects - Pumpkin Bliss (92350451_RET_NG)Febreze Air Effects - Pumpkin Harvest 92350451_A_RET_NG)Febreze Air Effects - Vanilla Latte (92350912_RET_NG)Febreze Air Effects - Pumpkin Harvest (92350912_A_RET_NG)Febreze Air Effects - Fluffy Vanilla (92350912_B_RET_NG)Febreze Air Effects - Cozy Vanilla Sugar (92350912_C_RET_NG)Febreze Air Effects - Morning Herbs & Mist (92351003_RET_NG)Febreze Air Effects - Turquoise Sea & Shimmer (92351003_A_RET_NG)Febreze Air Effects - New Zealand Springs (92351003_B_RET_NG)

Manufacturer PROCTER & GAMBLE - Fabric and Home Care Division. Ivorydale Technical Centre.5289 Spring Grove Avenue, Cincinnati, Ohio 45217-1087 USA

E-mail Address [email protected]

Emergency Telephone Transportation (24 HR)CHEMTREC - 1-800-424-9300(U.S./ Canada) or 1-703-527-3887Mexico toll free in country: 800-681-9531

2. HAZARD IDENTIFICATION

"Consumer Products", as defined by the US Consumer Product Safety Act and which are used as intended (typical consumerduration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR 1910.1200). This SDS is beingprovided as a courtesy to help assist in the safe handling and proper use of the product.

This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:.

Not Classified.

Hazard Statements None

Hazard pictograms None

Page 1 / 7


92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015


Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation


First aid measures for different exposure routes

Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists.

Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists.

Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately ifsymptoms occur.

Inhalation Move to fresh air. If symptoms persist, call a physician.

Most important symptoms/effects,acute and delayed

None under normal use conditions.


Notes to Physician Treat symptomatically.


Suitable extinguishing media Dry chemical, CO 2, alcohol-resistant foam or water spray. Dry chemical. Alcohol-resistantfoam.

Unsuitable Extinguishing Media None.

Special hazard None known.

Special protective equipment forfire-fighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH(approved or equivalent) and full protective gear.

Specific hazards arising from thechemical

None.

Precautionary Statements -Prevention

None

Precautionary Statements -Response

None

Precautionary Statements -Storage

None

Precautionary Statements -Disposal

None

Hazards not otherwise classified(HNOC)

None

Chemical Name Synonyms Trade Secret CAS-No Weight %Ethanol

Page 2 / 7

- No 64-17-5 1 - 5





Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing.

Advice for emergency responders Use personal protective equipment as required.

Environmental precautions Keep out of waterways. Do not discharge product into natural waters without pre-treatmentor adequate dilution.


Methods for containment Absorb with earth, sand or other non-combustible material and transfer to containers forlater disposal. Prevent product from entering drains. Prevent further leakage or spillage ifsafe to do so.

Methods for cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,earth, diatomaceous earth, vermiculite) and place in container for disposal according tolocal / national regulations (see section 13).



Advice on safe handling Use personal protective equipment as required. Keep container closed when not in use.Never return spills in original containers for re-use. Keep out of the reach of children.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible products None known.

Aerosol Classification Level 1


Control parameters

Exposure Guidelines .

Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PELEthanol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm

TWA: 1900 mg/m3

(vacated) TWA: 1000 ppm(vacated) TWA: 1900

mg/m3

Mexico: TWA 1000 ppmMexico: TWA 1900 mg/m3

Chemical Name CAS-No Alberta Quebec Ontario TWAEV British ColumbiaEthanol 64-17-5 TWA: 1000 ppm

TWA: 1880 mg/m3


STEL: 1000 ppm STEL: 1000 ppm

No relevant exposure guidelines for other ingredients

Page 3 / 7

Exposure controls

Engineering Measures Distribution, Workplace and Household Settings:Ensure adequate ventilation

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Where reasonably practicable this should be achieved by the use of local exhaustventilation and good general extraction




Eye Protection Distribution, Workplace and Household Settings:No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Use appropriate eye protection

Hand Protection Distribution, Workplace and Household Settings:No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Protective gloves

Skin and Body Protection Distribution, Workplace and Household Settings:No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Wear suitable protective clothing

Respiratory Protection Distribution, Workplace and Household Settings:No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):In case of insufficient ventilation wear suitable respiratory equipment


Physical State @20°C AerosolAppearance clearOdor ScentedOdor threshold No information available

VOC Content (%) Products comply with US state and federal regulations for VOC content in consumerproducts.


Property Values Note pH value 4.7 - 5.3Melting/freezing point No information availableBoiling point/boiling range No information availableFlash point 51.6 - 60 °C / 125 - 140 °FEvaporation rate No information availableFlammability (solid, gas) No information availableFlammability Limits in AirUpper flammability limit No information availableLower Flammability Limit No information available

Vapor pressure No information availableVapor density No information availableRelative density 0.987 - 1.0Water solubility No information availableSolubility in other solvents No information availablePartition coefficient: n-octanol/waterNo information availableAutoignition temperature No information available .Decomposition temperature No information available .Viscosity of Product No information available

Page 4 / 7



Reactivity None under normal use conditions.

Stability Stable under normal conditions.

Hazardous polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

Conditions to Avoid None under normal processing.

Materials to avoid None in particular.

Hazardous Decomposition Products None under normal use.


Product Information Information on likely routes of exposure

Inhalation No known effect.Skin contact No known effect.Ingestion No known effect.Eye contact No known effect.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Acute toxicity No known effect.Skin corrosion/irritation No known effect.Serious eye damage/eye irritation No known effect.Skin sensitization No known effect.Respiratory sensitization No known effect.Germ cell mutagenicity No known effect.Neurological Effects No known effect.Reproductive toxicity No known effect.Developmental toxicity No known effect.Teratogenicity No known effect.STOT - single exposure No known effect.STOT - repeated exposure No known effect.Target Organ Effects No known effect.Aspiration hazard No known effect.Carcinogenicity No known effect.


Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 InhalationEthanol 64-17-5 10470 mg/kg bw (OECD

401)> 15800 mg/kg bw (Rabbit) 116.9 mg/L air (//OECD

403)


Ecotoxicity

The product is not expected to be hazardous to the environment.

Persistence and degradability No information available.

Bioaccumulative potential No information available.

Mobility No information available.

Page 5 / 7





Waste treatment

Waste from Residues / UnusedProducts

Aerosol cans, when disposed as waste, are regulated as D003 reactive hazardous waste insome States because of their potential to explode when heated. Check with your Stateenvironmental agency for guidance.

Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws andregulations.

California Hazardous Waste Codes(non-household setting)

331


DOT UN no UN1950UN Proper shipping name AerosolsDescription UN1950, Aerosols, 2.2 , Ltd. Qty.Hazard Class 2.2Emergency Response GuideNumber

126

IMDG UN Number UN1950UN Proper shipping name AerosolsDescription UN1950, Aerosols, 2.2 , Ltd. Qty.Transport hazard class(es) 2.2EmS-No F-D, S-U

IATA UN no UN1950UN Proper shipping name Aerosols, non-flammableDescription UN1950, Aerosols, non-flammable, 2.2 , Ltd. Qty.Hazard Class 2.2ERG Code 2LIATA comment Can also be shipped as ID8000 Consumer Commodity

15. REGULATORY INFORMATIONU.S. Federal Regulations

SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

CERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this material

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air ActAmendments of 1990.

Page 6 / 7

Clean Water ActThis product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42)



California Proposition 65This product is not subject to warning labeling under California Proposition 65.Ethanol is only a considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage.

U.S. State Regulations (RTK)

Chemical Name CAS-No New JerseyEthanol 64-17-5 X

Chemical Name CAS-No MassachusettsEthanol 64-17-5 X

Chemical Name CAS-No PennsylvaniaEthanol 64-17-5 X

Dipropylene Glycol 25265-71-8 X

International Inventories

United StatesAll intentionally-added components of this product(s) are listed on the US TSCA Inventory.

CanadaThis product is in compliance with CEPA for import by P&G.

Legend TSCA - United States Toxic Substances Control Act Section 8(b) InventoryCEPA - Canadian Environmental Protection Act


Issuing Date: 24-Feb-2015Revision Date: 24-Feb-2015DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of itspublication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any other materials or in any process, unlessspecified in the text

Page 7 / 7

End of SDS


Form N051 Page 1

5332 Dansher Road Countryside, Illinois 60525

MATERIAL SAFETY DATA SHEET

Revision Date: 8/16/2005 MSDS No: N-051 Emergency Phones: 708-579-8100 (NYCO) 800-424-9300 (CHEMTREC) PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations.

SECTION I - PRODUCT IDENTITY PRODUCT NAME: Lemon Shine Furnature Polish Formula: Lemon oil and silicone emulsion with hydrocarbon propellant for use on furnature Chemical Type: Lemon oil and silicone emulsion

HMIS RATINGS

Health = 1 (Slight) Flammability = 2 (Moderate)

Reactivity = 0 (Minimal) Protection = A (Safety Glasses)

SECTION II - HAZARDOUS INGREDIENTS

CARCINOGEN PERCENT TLV (OSHA,TP,IARC) Propane 1-5% 1000 ppm No CAS No. 74-98-6 n-Butane 1-5% 600 ppm No CAS No. 106-97-8

SECTION III - CHEMICAL AND PHYSICAL

Appearance and Odor: Lemon Odor, Cone Spray Boiling Point: N/A Evaporation Rate (Ether = 1): <1 Melting Point: N/A pH: 10.0-11.0 Spec. Gravity (H20 = 1): <1 Water Solubility: 10% Vapor Density (Air = 1): >1 Vapor Pressure (psig): 117 @ 130F

SECTION IV - FIRE AND EXPLOSION HAZARDS

Aerosol Flammability: Product is not required to be labeled as flammable as described in 16 CFR 1500.3 and 1500.45. Flash Point (Method): <0F (Propellant) None even until boiling (Conc) Explosion Limits: Upper: 9.5 Lower: 1.9 Extinguishing Media: Carbon Dioxide, foam and/or dry chemical may be used. Special Firefighting Procedures and Hazards: Containers should be cooled with water to prevent vapor pressure build up. Use equipment or

shielding, as required, to protect personnel from bursting, rupturing or venting containers. Unusual Fire and Explosion Hazards: At evelated temperatures (over 54C or 130F) containers exposed to direct flame or heat contact should be

cooled with water to prevent weakening or container structure.

SECTION V - REACTIVITY INFORMATION

Stable: Unstable:

Precautions: Incompatibility: Avoid heat, open flame and oxidizing agents.

Hazardous Decomposition Products: Carbon Monoxide in small amounts and additional toxic chemicals may be formed in small amounts Conditions to Avoid: Do not store above 54C or 130F. Keep away from heat, direct sunlight, open flames or sparks. Dropping of containers may cause bursting. Hazardous Polymerization: Occurs: Does Not Occur:


Form N025 Page 2

SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical

attention. Skin: Remove contaminated clothing. Flush skin with water followed by washing with soap and water. If irritation occurs, get

medical attention. Do not use clothing until cleaned. Eyes: Flush eyes with plents of water for 15 minutes while holding eye lids wide open. Get medical attention if irritation persists. Ingestion: Get medical attention. Most likely routes of entry: Inhilation, eyes, and skin

Other Important Medical or Precautionary Information: None

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Remove all sources of ignition and ventilate area. Soak up spill wiht an inert absorbent and place into a designed disposal container. Consult local regulatory agency for proper disposition of material. Storage and Handling: Avoid breathing vapor. Keep away from heat and flame. Use with adequate ventilation. Do not puncture or incinerate containers. Do not expose to direct sunlight or store at temperatures above 130F (54C). Store as level 1 Aerosol (NFPA 30B) Waste Disposal: Do not puncture or incinerate containers. When contents are depleted continue to depress button until all gass is expelled. Dispose of container in acordance with local, state, and federal regulations. Empty Containers: Dispose in accordance with local, state, and federal regulations. Other Precautions: Please read and follow the directions on the product label; THey are your best guide to using this product in the most effective way, and give the necessary safety precautions to protect you health.

SECTION VIII - REGULATORY INFORMATION Respiratory Protection: None required if good ventilation is maintained. If exposure exceeds occupational exposure limits (Sect. II), use a NIOSH

approved repirator to prevent overexposure. Ventilation: General ventilation is adequate under normal conditions. Mechanical ventilation is optional. Protective Gloves: Chemical resistant gloves are recommended - consult glove manufacturer to determine the proper type for a specific operation.

Eye Protection: Chemical safety glasses are recommended.

Other Protective Clothing or Equipment: Wear impervious clothing to prevent skin contact.

Work/Hygienic Practices: Ensure stict sanityar conditions are conformed to when working around chemicals. Protective clothing and equipment

should be in accordance with 29 CFR 1910.132 and 1910.133.

Reportable for SARA Title III, S.313 (Form R):

The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, NYCO Products Company cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use.


NA

MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015

1 / 7

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name

: MURPHY OIL SOAP WOOD CLEANER SPRAY RTU

Product code : 200000041735

: B02955850000

Manufacturer or supplier's details Company : Colgate-Palmolive Co

300 Park Avenue New York, NY 10022

Telephone : US: Consumer Affairs - 1-800-468-6502


: For emergencies involving spill, leak, fire, exposure or acci-dent call CHEMTREC (24hr) at (800) 424-9300 or (703) 527-3887.

Medical Emergency (24HR):

For MEDICAL EMERGENCIES involving this product call: (888) 489-3861

Recommended use of the chemical and restrictions on use Recommended use

: Formulated all purpose cleaner for household use.


Emergency Overview Appearance

liquid

Colour

orange

GHS Classification Not a hazardous substance or mixture.

GHS Label element Not a hazardous substance or mixture.

Potential Health Effects Inhalation

: No adverse effects due to inhalation are expected.

Skin

: May cause skin irritation upon prolonged contact.

Eyes

: Causes eye irritation on direct contact.

Ingestion

: May be harmful if swallowed in large quantities.

Aggravated Medical Condi- : None known.


NA


2 / 7

tion

Carcinogenicity: IARC

No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH

No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino-gen by ACGIH.

OSHA

No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino-gen by OSHA.

NTP

No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.


Hazardous components No hazardous ingredients


If inhaled

: Remove victim to fresh air. Get medical attention, if symp-toms persist.


: Flush skin with large amounts of water. If irritation develops and persists, get medical attention.


: Flush eyes with water at least 15 minutes. Get medical atten-tion if eye irritation develops or persists.

If swallowed

: Drink 8 ounces of clear water. Get medical attention.

SECTION 5. FIREFIGHTING MEASURES


: Use water spray, alcohol-resistant foam, dry chemical or car-bon dioxide.


: No hazardous combustion products are known


: Self-contained breathing apparatus and full protective clothing should be worn when fighting chemical fires.


NA


3 / 7


Personal precautions, protec-tive equipment and emer-gency procedures

: Use personal protection recommended in Section 8 of the SDS.


: Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of wa-ter.



: Store at controlled room temperature at 20-25°C (68-77°F).


Components with workplace control parameters Contains no substances with occupational exposure limit values.

Engineering measures : In an industrial work environment, no special precautions or control measures are required.

Personal protective equipment Respiratory protection

: No personal respiratory protective equipment normally re-quired.

Protective measures

: In an industrial work environment, if a splash is likely, chemi-cal goggles may be needed. Prolonged skin contact may require protective gloves. For consumer use, no unusual precautions are necessary.

Hygiene measures

: In an industrial work environment, avoid eye and prolonged skin contact.


Appearance

: liquid

Colour

: orange

pH

: 10.0

Flash point

: > 100 °C

Density

: 1.0 g/cm3


NA


4 / 7



: Hazardous polymerisation does not occur.


: Strong oxidizing agents


: None known.


Acute toxicity Not classified based on available information.

Product: Acute oral toxicity

: Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method

Skin corrosion/irritation Not classified based on available information.

Serious eye damage/eye irritation Not classified based on available information.

Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information.

Germ cell mutagenicity Not classified based on available information.

Carcinogenicity Not classified based on available information.

Reproductive toxicity Not classified based on available information.

STOT - single exposure Not classified based on available information.

STOT - repeated exposure Not classified based on available information.

Aspiration toxicity Not classified based on available information.

Further information

Product: Remarks: This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available


NA


5 / 7

safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the SDS.


The product has not been tested as a whole for environmental toxicity. However, environmental infor-mation on the ingredients in this product have been reviewed by the Environmental, Health and Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This evalua-tion is based on available information on individual ingredients, interactions of ingredients, and similar ingredients. Biodegradability claims are supported by data on ingredients (i.e., surfactants are biode-gradable) or testing conducted on the final product (i.e., This product is biodegradable).


Disposal methods Waste from residues : Any disposal practice must be in compliance with local, state

and federal laws and regulations (contact local or state envi-ronment agency for specific rules). Do not dump in sewers, any body of water or on the ground.


DOT : Not regulated. TDG : Not regulated. IATA : Not regulated. IMDG : Not regulated.


Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.

National Regulations


EPCRA - Emergency Planning and Community Right-to-Know Act





NA


6 / 7

FORMALDEHYDE 50-00-0 100 *

*: Calculated RQ exceeds reasonably attainable upper limit.




FORMALDEHYDE 50-00-0 100 *

*: Calculated RQ exceeds reasonably attainable upper limit. SARA 302

: No chemicals in this material are subject to the reporting re-quirements of SARA Title III, Section 302.

SARA 313


Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489).

Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Ta-ble 116.4A: SODIUM HYDROXIDE 1310-73-2 FORMALDEHYDE 50-00-0 The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: SODIUM HYDROXIDE 1310-73-2 FORMALDEHYDE 50-00-0 This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307

Massachusetts Right To Know FORMALDEHYDE 50-00-0 HYDROGEN PEROXIDE 7722-84-1

Pennsylvania Right To Know WATER Water SODIUM HYDROXIDE 1310-73-2

New Jersey Right To Know WATER Water Sodium tallate 61790-45-2

California Prop 65 : This product does not contain any chemicals known to State

of California to cause cancer, birth defects, or any other re-productive harm.

The components of this product are reported in the following inventories:


NA


7 / 7

TSCA

: All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory.

Inventories

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) In accordance with OSHA 29 CFR 1910.1048 formaldehyde is not listed in Section 3 of this MSDS, however, formaldehyde is regulated by State and Federal regulations at varying concen-trations. State and Federal information can be found above in Section 15.


Further information NFPA: HMIS III:

Disclaimer: The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or im-plied, as to the accuracy, reliability or completeness of the information and assumes no re-sponsibility for injury, damage or loss resulting from the use of the material.

Flammability

Hea

lth

Instability

2 1

0

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

1 0

2



Safety Data Sheet Office Max Compressed Gas Duster

Section 1. Identification

Product Identifier Office Max Compressed Gas DusterSynonyms OM96090, OM96091, OM96092, OM04736, OM04737Manufacturer Stock Numbers

N/A

Product Cas 75-37-6 Recommended use Dust RemovalUses advised against Use Only as Directed - Read label instructions carefully. Keep out of reach of

children. Intentional misuse by deliberately concentrating and/or inhaling contents may be fatal.

Manufacturer Contact

Address Falcon Safety Products, Inc. 25 ImClone Drive Branchburg, NJ, 08876 USA

Phone Emergency Phone Fax

(908) 707-4900 (800) 498-7192 N/A

Section 2. Hazards Identification

Classification FLAMMABLE GASES - Category 2 GASES UNDER PRESSURE - Compressed gas

Signal Word WarningPictogram

Hazard Statements Contains gas under pressure; may explode if heated

Flammable gas Precautionary Statements

Response Eliminate all ignition sources if safe to do so. Leaking gas fire: Do not extinguish, unless leak can be stopped safely.

Prevention Do not spray on an open flame or other ignition source. Keep away from heat. Pressurized container: Do not pierce or burn, even after use.

Storage Protect from sunlight. Store in a well-ventilated place. Store at temperatures not exceeding 120 degrees F/49 degrees C

Disposal N/A

Page 1 of 8 of 132Page 75 of 132Page 75 of 132Page 75 of 132


General Keep out of reach of children Ingredients of unknown toxicity

0%

Hazards not Otherwise Classified

N/A

No Data Available

Section 3. Ingredients

CAS Ingredient Name Weight % 75-37-6 Ethane, 1,1-difluoro- 100 %

Section 4. First-Aid Measures

General Advice Never give anything by mouth to an unconscious person. When symptoms persist or in all cases of doubt, seek medical advice.

Inhalation Remove from exposure, lie down. Move to fresh air. Keep patient warm and at rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention.

Skin Take off all contaminated clothing immediately. Flush area with lukewarm water. Do not use hot water. If frostbite has occurred, call a physician.

Eye Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention.

Ingestion Is not considered a potential route of exposure.Most important symptoms/effects, acute and delayed

Anaesthetic effects: light-headedness, irregular heartbeat with a strange sensation in the chest, heart thumping, apprehension, feeling of fainting, dizziness or weakness.

Protection of First-aiders If potential for exposure exists refer to Section 8 for specific personal protective equipment.

Notes to Physician Because of possible disturbances of cardiac rhythm catecholamine drugs, such as epinephrine, which may be used in situations of emergency life support, should be used with special caution.


Section 5. Fire Fighting Measures

Suitable Extinguishing Media

Water spray, water fog, dry chemical, alcohol resistant foam, carbon dioxide (CO2)

Unsuitable Extinguishing Media

No applicable data available.

Specific Hazards Flammable. This substance's fire decomposition by-products will include hydrofluoric acid and possibly carbonyl flouride. Avoid contact with these materials, which are toxic and irritating. Evacuate personnel immediately in the event of a fire involving this substance. Vapors may form explosive mixtures with air. Vapors are heavier than air and may spread along floors. Vapors or gases may travel considerable distances to ignition source and flash back.


Use personal protective equipment. Wear neoprene gloves during cleaning up work after a fire. Exposure to decompositon products may be a hazard to health.

Further Information Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Cool containers/tanks with water spray.

Section 6. Accidental Release Measures

NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up.

Safeguards (Personnel) Evacuate personnel to safe areas. Ventilate the area. Refer to protective measures listed in sections 7 and 8.

Spill Clean-up If this product is spilled and not recovered, or is recovered as a waste for treatment and disposal, the CERCLA Reportable Quantity is 100 lbs. (release of an Unlisted Hazardous Waste with the Characteristic of Ignitability). Evaporates. Ventilate area using forced ventilation, especially low or enclosed places where heavy vapors might collect.

Accidental Release Measures

Wear self-contained breathing apparatus (SCBA).

Section 7. Handling and Storage

Handling (Personnel) Avoid breathing vapors or mist. Avoid contact with skin, eyes and clothing. Provide sufficient air exchange and/or exhaust in work rooms. For personal protection see section 8. Handle in accordance with good industrial hygiene and safety practice.

Handling (Physical Aspects) Vapors are heavier than air and may spread along floors. Vapors may form flammable mixture with air. The product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropirate standard. No sparking tools should be used. Take measures to prevent the build up of electrostatic charge. Keep away from open flames, hot surfaces and sources of ignition. When using DO NOT SMOKE. Do not use in areas where vapors may accumulate such as paper shredders.

Dust Explosion class Not applicableStorage Keep container tightly closed and in a dry, well-ventilated location. Store in original

container. The product has an indefinite shelf life when stored properly. Storage Period Recommended shelf life - 10 years provided product is stored in a dry location as

directed.Storage Temperature Do not expose to temperatures above 120 degrees F (49 degrees C) as

overheating could cause can to burst. DO NOT leave in direct sunlight or enclosed vehicle.


Section 8. Exposure Controls/Personal Protection

Occupational Exposure Limits

Ingredient Name ACGIH TLV OSHA PEL STEL

Ethane, 1,1-difluoro- N/A N/A N/A


N/A

Engineering controls Ensure adequate ventilation, especially in confined areas. Use respiratory protection if needed.

Eye/Face Protection Wear safety glasses with side shields. Direct contact with liquid may cause frostbite.

Respiratory Protection For rescue use self-contained breathing apparatus. Vapors are heavier than air and can cause suffication by reducing oxygen available for breathing.

Skin and body protection As required by employer code. If there is risk of skin contact, wear protective clothing, gloves, etc. Direct contact with liquid can cause frostbite.

General Hygiene Considerations

Handle in accordance with good industrial hygiene and safety practices.


Section 9. Physical and Chemical Properties

Physical State GasColor ClearOdor slight, ether-

likeOdor Threshold No applicable

data availableSolubility Water -

SlightlyPartition coefficient Water/n-octanol N/AVOC% N/AViscosity No applicable

data availableSpecific Gravity 0.91Density lbs/Gal 0.9Pounds per Cubic Foot N/AFlash Point <-58°F (<-50°

C)FP Method N/APh NeutralMelting Point No applicable

data availableBoiling Point -13 °F (-25 °

C) Boiling Range N/ALEL 3.9UEL 16.9Evaporation Rate No applicable

data availableFlammability FlammableDecomposition Temperature N/AAuto-ignition Temperature No applicable

data availableVapor Pressure 5,960 KPa at

77F (25C)Vapor Density 2.4 at 77F

(25C) (Air=1)

Section 10. Stability and Reactivity

Reactivity Stable under recommended storage conditions.Chemical Stability The product is chemically stable under recommended storage conditions.Conditions to Avoid Aerosol containers are unstable at temperatures above 120 degrees F/49 degrees

CIncompatible Materials Incompatible products include Alkali metals, Alkaline earth metals, powdered

metals, powdered metal salts.Hazardous Decomposition Products

Decomposition products are hazardous. This material can be decomposed by high temperatures (open flames, glowing metal surfaces, etc.) forming hydrofluoric acid and possibly carbonyl fluoride.


Section 11. Toxicological Information

Component Analysis - LC50 1,1-Difluoroethane - > 64000 ppm ratComponent analysis - Oral LD50

1,1-Difluoroethane - 1500 mg/kg rat

Effects of Acute Exposure - Eye

Contact with liquid may cause frostbite

Effects of Acute Exposure - Skin

Contact with liquid may cause frostbite

Effects of Acute Exposure - Inhalation

Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effect (headaches, dizziness). Vapors may cause dizziness or suffocation.

Effects of Acute Exposure - Ingestion

Not a normal route of exposure

Sensitization Non-hazardous by WHMIS/OSHA criteria.Carcinogenicity Not classifiable as a human carcinogen. Animal testing did not show carcinogenic

effects. None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, or OSHA as a carcinogen.

Mutagenicity Animal testing did not show any mutagenic effects. Did not cause genetic damage in cultured bacterial cells. Tests on mammalian cell cultures showed mutagenic effects.

Reproductive Toxicity No toxcicity to reproduction. Animal testing showed no reproductive toxicity.Teratogenicity Animal testing showed no developmental toxicity.Further Information Cardiac sensitization threshold limit: 405000 mg/m3

Section 12. Ecological Information

Aquatic Toxicity 1,1-Difluoroethane 96 h LC50 : Fish 295.78 mg/l 96 h EC50 : Algae 47.76 mg/l 48 h EC50 : Daphnia (water flea) 146.7 mg/l

Section 13. Disposal

Waste Disposal Methods Comply with applicable Federal, State/Provincial and Local Regulations. May be a RCRA Hazardous waste due to the ignitability characteristic. Do not puncture or incinerate container.

Contaminated Packaging Not Available


Section 14. Transport Information

UN Number 1030UN Proper Shipping Name 1,1-DifluoroethaneDOT Classification 2.1Packing Group N/APackaging Exceptions Note: Falcon Safety Products has been granted a DOT special permit. A copy of

DOT Special Permit SP-11516 can be obtained by calling Falcon Safety Products, Inc. at 908-707-4900.

Transportation of Dangerous Goods (TDG - Canada)

Proper Shipping name: 1,1-Difluoroethane Hazard Class: 2.1 UN number: 1030 Packaging Exceptions: Limited quantity (containers up to 125mL)

IATA/ICAO (Air) Proper Shipping Name: 1,1-Difuoroethane. Hazard Class: 2.1. UN Number: 1030. Maximum Net Quantity Packaging: Cargo Aircraft only - 150 kg maximum (forbidden on passenger aircraft). Maximum Net Quantity packaging cargo only: 150 kg.

IMDG (Marine Transport) Proper Shipping Name: 1,1-DIFLUOROETHANE. Hazard Class: 2.1. UN Number: 1030.

Additional Information TDG Canada: Falcon Safety Products has been granted Equivalency Certificate SU 9211 (ren. 1) by the TCSS, TDGD to offer for transport by road, rail and marine.

Section 15. Regulatory Information

Canadian Federal Regulations

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations.

WHMIS Status ControlledWHMIS Classification Class A - Compressed Gas, Class B - Division 1 - Flammable GasTSCA On the inventory, or in compliance with the inventory.SARA 313 Regulated Chemical(s)

This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

US Federal Regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

NJ Right to Know Regulated Chemical(s)

Substances on the New Jersey Workplace Hazardous Substance List present at a concentration of 1% or more (0.1% for substances identified as carcinogens, mutagens or teratogens): 1,1-Difluoroethane.

California Prop. 65 This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm.

Canada Domestic Substances List (DSL)

This product is listed on the DSL inventory list and complies with the inventory requirements administered by the governing country.


Section 16. Other Information

Revision Date 4/28/2015

Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document.

Prepared By Falcon Safety Products, Inc. 908-707-4900


Material Safety Data Sheet

according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL

Version 2.0 Print Date 05/22/2014

Revision Date 05/21/2014 MSDS Number 350000017409

1/8


Product information

Trade name : PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL

Use of the Substance/Mixture

: Furniture Polish/Cleaner

Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1


: 24 Hour Transport & Medical Emergency Phone (866) 231-5406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666


Emergency Overview Appearance / Odor : yellow / liquid / pleasant

Immediate Concerns

: Caution Avoid contact with skin, eyes and clothing. May be harmful if swallowed.

Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion.

Eyes : May cause:

Mild eye irritation

Skin : Prolonged or repeated contact may dry skin and cause irritation.

Inhalation : Excessive exposures may affect human health, as follows: Inhalation may cause central nervous system effects.

Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Aspiration hazard if swallowed - can enter lungs and cause damage.

Aggravated Medical Condition

: Persons with pre-existing skin disorders may be more susceptible to irritating effects.







2/8


Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table:

Chemical Name CAS-No. Weight percent

Hydrocarbons, C16-C20, n-alkanes, isoalkanes, cyclics, <2% aromatics

64742-46-7 30.00 - 60.00

White Mineral Oil, (Petroleum)

8042-47-5 30.00 - 60.00

Citrus, Extract 94266-47-4 1.00 - 5.00

For additional information on product ingredients, see www.whatsinsidescjohnson.com.


Eye contact : Rinse with plenty of water. Get medical attention if irritation develops and persists.

Skin contact : Rinse with plenty of water. Get medical attention if irritation develops and persists.

Inhalation : Remove to fresh air. If breathing is affected, get medical attention.

Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.

5. FIREFIGHTING MEASURES


: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Specific hazards during firefighting

: Container may melt and leak in heat of fire.

Further information : Fight fire with normal precautions from a reasonable distance.

Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus.

Flash point : 102 °C







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215.6 °F Method: Tag Closed Cup (TCC)

Lower explosion limit : Note: not applicable

Upper explosion limit : Note: not applicable


Personal precautions : Material can create slippery conditions.

Personal precautions : No special precautions required.

Environmental precautions : Outside of normal use, avoid release to the environment.

Methods for cleaning up : Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Dike large spills. Clean residue from spill site.


Handling

Advice on safe handling : Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS.

Advice on protection against fire and explosion

: Normal measures for preventive fire protection.

Storage

Requirements for storage areas and containers

: Keep container closed when not in use. Keep in a dry, cool and well-ventilated place.


Occupational Exposure Limits

Components CAS-No. mg/m3

ppm

Non-standard

units

Basis

White Mineral Oil, (Petroleum)

8042-47-5 5 mg/m3

-

-

ACGIH TWA

Personal protective equipment







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Respiratory protection

No personal respiratory protective equipment normally required.

Hand protection

: No special requirements.

Eye protection

No special requirements.

Skin and body protection

: No special requirements.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.


Form : liquid

Color : yellow

Odor : pleasant

pH : not applicable

Boiling point : no data available

Freezing point : no data available

Flash point : 102 °C 215.6 °F Method: Tag Closed Cup (TCC)

Evaporation rate : no data available

Flammability (solid, gas) : Does not sustain combustion.

Lower explosion limit : not applicable

Upper explosion limit : not applicable

Vapour pressure : no data available

Density : 0.8424 g/cm3 at 40 °C

Water solubility : negligible

Viscosity, dynamic : 24 mPa.s at 40 °C







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Viscosity, kinematic : 28.5 mm2/s at 40 °C

Volatile Organic Compounds Total VOC (wt. %)*

: 1.1 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations


Conditions to avoid : Direct sources of heat.

Materials to avoid : Strong oxidizing agents

Materials to avoid : None known.


: Thermal decomposition can lead to release of irritating gases and vapours.

Hazardous reactions : Stable under recommended storage conditions.


Acute oral toxicity : LD50 Calculated > 5,000 mg/kg

Acute inhalation toxicity : no data available

Acute dermal toxicity : no data available

Chronic effects Carcinogenicity : no data available

Mutagenicity : None Anticipated Reproductive effects : no data available

Teratogenicity : no data available







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Sensitisation : Substance is not a sensitizer.


Ecotoxicity effects : no data available


Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist.


Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport

U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Sea transport

IMDG: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Air transport

ICAO/IATA: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None.


Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.







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Notification status : All ingredients of this product comply with the New Substances

Notification requirements under the Canadian Environmental Protection Act (CEPA).

California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65.

Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.


HMIS Ratings

Health 1

Flammability 1

Reactivity 0

NFPA Ratings

Health 1

Fire 1

Reactivity 0

Special -

This information is being provided in accordance with Occupational Safety and Health Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS) regulations. The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use.

Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.

Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)







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SAFETY DATA SHEET

PURELL® Hand Sanitizing Wipes

Version 1.0

Revision Date: 03/30/2015

MSDS Number: 80013-00001

Date of last issue: - Date of first issue: 03/30/2015

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SECTION 1. IDENTIFICATION

Product name

: PURELL® Hand Sanitizing Wipes

Manufacturer or supplier's details

Company name of supplier

: GOJO Industries, Inc.

Address

: One GOJO Plaza, Suite 500 Akron OH 44311

Telephone

: 1 (330) 255-6000

Emergency telephone

: 1-800-424-9300 CHEMTREC

Recommended use of the chemical and restrictions on use

Recommended use

: Hand Sanitizer

Restrictions on use

: This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.


GHS Classification

Flammable liquids

: Category 3

Eye irritation

: Category 2A

GHS Label element

Hazard pictograms

:

Signal Word

: Warning

Hazard Statements

: H226 Flammable liquid and vapor. H319 Causes serious eye irritation.


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: Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards

Vapors may form explosive mixture with air.


Substance / Mixture

: Mixture

Hazardous ingredients

Chemical Name CAS-No. Concentration (%)

Ethanol 64-17-5 >= 10 - < 20

Benzethonium chloride 121-54-0 >= 0.1 - < 1


General advice

: In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.

If inhaled

: If inhaled, remove to fresh air. Get medical attention if symptoms occur.


: Wash with water and soap as a precaution. Get medical attention if symptoms occur.


: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn.


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Get medical attention.

If swallowed

: If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.

Most important symptoms and effects, both acute and delayed

: Causes serious eye irritation.

Protection of first-aiders

: First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.

Notes to physician

: Treat symptomatically and supportively.

SECTION 5. FIRE-FIGHTING MEASURES


: Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2)


: High volume water jet

Specific hazards during fire fighting

: Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health.


: Carbon oxides

Specific extinguishing methods

: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.


: In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.



: Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations.

Environmental precautions : Discharge into the environment must be avoided.


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Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.


: Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.


Technical measures

: See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.

Local/Total ventilation

: Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation.

Advice on safe handling

: Avoid inhalation of vapor or mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container tightly closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment.


: Keep in properly labeled containers. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition.

Materials to avoid

: Do not store with the following product types: Strong oxidizing agents


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Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases


Ingredients with workplace control parameters

Ingredients CAS-No. Value type (Form of exposure)

Control parameters / Permissible concentration

Basis

Ethanol 64-17-5 TWA 1,000 ppm 1,900 mg/m3

NIOSH REL

TWA 1,000 ppm 1,900 mg/m3

OSHA Z-1

STEL 1,000 ppm ACGIH

Hazardous components without workplace control parameters

Ingredients CAS-No.

Benzethonium chloride 121-54-0

Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation.

Personal protective equipment

Respiratory protection

: General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection.

Hand protection Material : Impervious gloves Material : Flame retardant gloves


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Remarks

: Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday.

Eye protection

: Wear the following personal protective equipment: Safety goggles

Skin and body protection

: Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).

Hygiene measures

: Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.


Appearance

: impregnated cloth

Color

: colorless, clear, cloudy

Odor

: citrus

Odor Threshold

: No data available

pH

: 4.0 - 7.5

Melting point/freezing point

: No data available

Initial boiling point and boiling range

: No data available

Flash point

: 37.8 °C

Evaporation rate

: No data available

Flammability (solid, gas)

: Not applicable

Upper explosion limit

: No data available

Lower explosion limit

: No data available

Vapor pressure

: No data available

Relative vapor density : No data available


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Density

: 0.9780 g/cm3

Solubility(ies) Water solubility

: soluble


: Not applicable

Autoignition temperature

: No data available

Decomposition temperature

: The substance or mixture is not classified self-reactive.

Viscosity Viscosity, kinematic

: No data available

Explosive properties

: Not explosive

Oxidizing properties

: The substance or mixture is not classified as oxidizing.


Reactivity

: Not classified as a reactivity hazard.

Chemical stability

: Stable under normal conditions.


: Flammable liquid and vapor. Vapors may form explosive mixture with air. Can react with strong oxidizing agents.

Conditions to avoid

: Heat, flames and sparks.


: Oxidizing agents


: No hazardous decomposition products are known.


Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact

Acute toxicity

Not classified based on available information.

Product:

Acute oral toxicity

: Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method


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Ingredients:

Ethanol: Acute oral toxicity

: LD50 (Rat): > 5,000 mg/kg


: LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor

Benzethonium chloride: Acute oral toxicity

: LD50 (Rat): 295 mg/kg Method: OECD Test Guideline 401

Skin corrosion/irritation


Product:

Result: No skin irritation

Ingredients:

Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Benzethonium chloride: Species: Rabbit Result: Corrosive after 1 to 4 hours of exposure

Serious eye damage/eye irritation

Causes serious eye irritation.

Ingredients:

Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405

Respiratory or skin sensitization

Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information.

Product:

Assessment: Does not cause skin sensitization.

Ingredients:

Ethanol: Test Type: Local lymph node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative Benzethonium chloride:


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Test Type: Magnusson-Kligman-Test Routes of exposure: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative

Germ cell mutagenicity


Ingredients:

Ethanol: Genotoxicity in vitro

: Test Type: In vitro mammalian cell gene mutation test Result: negative

Genotoxicity in vivo

: Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative

Benzethonium chloride: Genotoxicity in vitro

: Test Type: Bacterial reverse mutation assay (AMES) Result: negative

Carcinogenicity


Ingredients:

Benzethonium chloride: Species: Rat Application Route: Skin contact Exposure time: 2 Years Result: negative IARC

No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

OSHA

No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino-gen by OSHA.

NTP

No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.



Ingredients:

Ethanol: Effects on fertility

: Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion


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Method: OECD Test Guideline 416 Result: negative

STOT-single exposure


STOT-repeated exposure


Repeated dose toxicity

Ingredients:

Ethanol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y

Aspiration toxicity



Ecotoxicity

Ingredients:

Ethanol: Toxicity to fish

: LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h

Toxicity to algae

: EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)

: NOEC (Daphnia magna (Water flea)): 9.6 mg/l Exposure time: 9 d

Toxicity to bacteria

: EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h

Benzethonium chloride: Toxicity to fish

: LC50 (Oncorhynchus mykiss (rainbow trout)): 1.15 mg/l Exposure time: 96 h Method: OECD Test Guideline 203

Toxicity to daphnia and other aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): 0.22 mg/l Exposure time: 48 h Method: OECD Test Guideline 202


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Toxicity to algae

: EC50 (Pseudokirchneriella subcapitata (green algae)): 0.12 mg/l Exposure time: 72 h Method: OECD Test Guideline 201

M-Factor (Acute aquatic tox-icity)

: 1

Toxicity to bacteria

: EC50: 35.70 mg/l Exposure time: 3 h Method: OECD Test Guideline 209


Ingredients:

Ethanol: Biodegradability

: Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d

Benzethonium chloride: Biodegradability

: Result: Not readily biodegradable. Biodegradation: 0 % Exposure time: 28 d Method: OECD Test Guideline 301B


Ingredients:

Ethanol: Partition coefficient: n-octanol/water

: log Pow: -0.35

Benzethonium chloride: Partition coefficient: n-octanol/water

: log Pow: 1.08

Mobility in soil

No data available

Other adverse effects

No data available


Disposal methods

Waste from residues : Dispose of in accordance with local regulations.

Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum.


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UNRTDG Not regulated as a dangerous good

IATA-DGR Not regulated as a dangerous good

IMDG-Code Not regulated as a dangerous good

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not applicable for product as supplied.

Domestic regulation

49 CFR Not regulated as a dangerous good


EPCRA - Emergency Planning and Community Right-to-Know


This material does not contain any components with a CERCLA RQ.


This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards

: Fire Hazard Acute Health Hazard

SARA 302

: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313


US State Regulations

Pennsylvania Right To Know

Water 7732-18-5 70 - 90 %

Ethanol 64-17-5 10 - 20 %

Propan-2-ol 67-63-0 0.1 - 1 %

New Jersey Right To Know

Water 7732-18-5 70 - 90 %

Ethanol 64-17-5 10 - 20 %

D-Glucitol, ethoxylated 53694-15-8 1 - 5 %


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California Prop 65 This product does not contain any chemicals known to the

State of California to cause cancer, birth, or any other reproductive defects.

The ingredients of this product are reported in the following inventories:

REACH

: All ingredients (pre-)registered or exempt.

TSCA

: All chemical substances in this product are either listed on the TSCA Inventory or are in compliance with a TSCA Inventory exemption.

DSL

: All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL).

AICS

: All ingredients listed or exempt.

Inventories

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)


Further information

NFPA: HMIS III:

Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-

its for Air Contaminants ACGIH / STEL : Short-term exposure limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour

workday during a 40-hour workweek OSHA Z-1 / TWA : 8-hour time weighted average

Flammability

Health

Insta

bility

2

2

0

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

2

0

2



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Sources of key data used to compile the Material Safety Data Sheet

: Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen-cy, http://echa.europa.eu/

Revision Date

: 03/30/2015

The information provided in this Safety Data Sheet is correct to the best of our knowledge, in-formation and belief at the date of its publication. The information is designed only as a guid-ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provid-ed relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un-less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in-cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. US / Z8


#19617 Page: 1 of 6 Issue date 11-February-2015

SAFETY DATA SHEET

1. Product and Company Identification

Product identifier Sani-Cloth HB Germicidal Disposable Wipe SDS0042

Other means of identification Not available

Recommended use Hard, Nonporous Surface Disinfectant

Recommended restrictions For Professional and Hospital Use

Manufacturer/Importer/Supplier/Distributor information

Manufacturer

Company name

Address

Professional Disposables International, Inc.

Two Nice-Pak Park,

Orangeburg, NY 10962-1376

Telephone 1-845-365-1700 (M-F 9am - 5pm)

Emergency phone number 1-800-999-6423

2. Hazards Identification

Physical hazards

Health hazards


OSHA defined hazards

Label elements

Hazard symbol

Not classified.

Not classified.

Not determined.

Not classified.

None.

Signal word None.

Hazard statement The mixture does not meet the criteria for classification.

Precautionary statement

Prevention Observe good industrial hygiene practices.

Response Wash hands after handling.

Storage Store away from incompatible materials.

Disposal Dispose of waste and residues in accordance with local authority requirements.

Hazard(s) not otherwise

classified (HNOC) None known.

Supplemental information Not applicable.

3. Composition/Information on Ingredients

Mixtures

Chemical name Common name and synonyms

CAS number %

Benzyl-C12-18-alkyldimethyl ammonium chlorides

Quaternary ammonium compounds, C12-14-alkyl[(ethylphenyl)methyl]di methyl, chlorides

68391-01-5

85409-23-0

0.07

0.07

4. First Aid Measures

Inhalation Not a normal route of exposure.

Skin contact If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control centre or doctor for treatment advice. Have the product container or label with you when calling a poison control center or doctor, or going for treatment.



Eye contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if

present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.

Ingestion Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention.

Most important

symptoms/effects, acute and

delayed

Indication of immediate

medical attention and special

treatment needed

Direct contact with eyes may cause temporary irritation.

Treat patient symptomatically.

General information If you feel unwell, seek medical advice (show the label where possible). Show this safety data

sheet to the doctor in attendance. Avoid contact with eyes, skin and clothing. Keep out of reach of children.

5. Fire Fighting Measures

Suitable extinguishing media Treat for surrounding material.

Unsuitable extinguishing

media

Specific hazards arising from

the chemical

Special protective equipment

and precautions for firefighters

Fire-fighting

equipment/instructions

None known.

Firefighters should wear a self-contained breathing apparatus.

Firefighters should wear full protective clothing including self contained breathing apparatus.

In the event of fire, cool product with water spray.

Specific methods Cool product exposed to flames with water until well after the fire is out.

General fire hazards No unusual fire or explosion hazards noted.

6. Accidental Release Measures

Personal precautions,

protective equipment and

emergency procedures

Methods and materials for

containment and cleaning up

Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the SDS.

Prevent entry into waterways, sewers or confined areas. Pick up and discard towel. For waste disposal, see section 13 of the SDS.

Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and Storage

Precautions for safe handling Use good industrial hygiene practices in handling this material. Do not reuse towelette. Do not reuse the empty container. When using do not eat or drink.

Conditions for safe storage,

including any incompatibilities

Store in a closed container away from incompatible materials. Store away from incompatible materials (see Section 10 of the SDS). Keep out of reach of children.

8. Exposure Controls/Personal Protection

Occupational exposure limits No exposure limits noted for ingredient(s).

Biological limit values No biological exposure limits noted for the ingredient(s).

Exposure guidelines This material does not have established exposure limits.

Appropriate engineering

controls

Ensure adequate ventilation.

Individual protection measures, such as personal protective equipment

Eye/face protection Wear gear as deemed necessary. Follow label directions.

Skin protection

Hand protection Wear as deemed necessary, follow label directions.

Other As required by employer code.

Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator.

Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene

considerations

Handle in accordance with good industrial hygiene and safety practice. Washing with soap and water after use is recommended as good hygienic practice to prevent possible eye irritation from hand contact. When using do not eat or drink.



9. Physical and Chemical Properties

Appearance Liquid saturated on wipe

Physical state Solid.

Form Liquid saturated on wipe

Color White

Odor Mild quat

Odor threshold Not available.

pH 10.75 (liquid)

Melting point/freezing point Not available.

Initial boiling point and boiling

range

Not available.

Pour point Not available.

Specific gravity 1.0027 g/mL (liquid)

Partition coefficient

(n-octanol/water)

Not available.

Flash point > 212.0 °F (> 100.0 °C) Tag Closed Cup (Liquid)


Flammability (solid, gas) Not applicable.

Upper/lower flammability or explosive limits

Flammability limit - lower

(%)

Flammability limit - upper

(%)

Not available.

Not available.

Explosive limit - lower (%) Not available.

Explosive limit - upper (%) Not available.

Vapor pressure Not available.

Vapor density Not available.

Relative density Not available.

Solubility(ies) Wipe is not soluble

Auto-ignition temperature Not available.

Decomposition temperature Not available.


10. Stability and Reactivity

Reactivity May react with incompatible materials.

Possibility of hazardous

reactions

Hazardous polymerization does not occur.

Chemical stability Stable under recommended storage conditions.

Conditions to avoid Avoid temperatures exceeding the flash point. Do not mix with other chemicals.

Contact with incompatible materials.

Incompatible materials Acids. Oxidizers. Caustics.

Hazardous decomposition

products

May include and are not limited to: Oxides of carbon. Chloride compounds Ammonia.

11. Toxicological Information

Information on likely routes of exposure

Ingestion Not applicable under normal conditions of use.

Inhalation Health injuries are not known or expected under normal use.

Skin contact Prolonged skin contact may cause skin irritation.

Eye contact Health injuries are not known or expected under normal use.

Symptoms related to the

physical, chemical and

toxicological characteristics

Symptoms may include stinging, tearing, redness, swelling of the eyes, and blurred vision. Symptoms may include redness, drying, defatting and cracking of the skin. Symptoms may include stomach distress, nausea or vomiting.


Acute toxicity



Components Species

Benzyl-C12-18-alkyldimethyl ammonium chlorides (CAS 68391-01-5)

Acute

Dermal

LD50 Rat

Inhalation

LC50 Not available

Oral

LD50 Mouse

Test Results

2000 mg/kg

1420 mg/kg

150 mg/kg

Rat 240 mg/kg

Quaternary ammonium compounds, C12-14-alkyl[(ethylphenyl)methyl]dimethyl, chlorides (CAS 85409-23-0)

Acute

Dermal

LD50 Not available

Inhalation

LC50 Not available

Oral

LD50 Rat 300 - 2000 mg/kg

Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.

Exposure minutes Not available.

Erythema value Not available.

Oedema value Not available.

Serious eye damage/eye

irritation

Direct contact with eyes may cause temporary irritation.

Corneal opacity value Not available.

Iris lesion value Not available.

Conjunctival reddening

value

Not available.

Conjunctival oedema value Not available.

Recover days Not available.

Respiratory or skin sensitization

Respiratory sensitization Not available.

Skin sensitization This product is not expected to cause skin sensitization.

Germ cell mutagenicity Non-hazardous by OSHA criteria.

Carcinogenicity Non-hazardous by OSHA criteria.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Reproductive toxicity Non-hazardous by OSHA criteria.

Specific target organ toxicity -

single exposure

Specific target organ toxicity -

repeated exposure

Not classified.

Not classified.

Aspiration hazard Not classified.

Chronic effects Non-hazardous by OSHA criteria.

Further information This product has no known adverse effect on human health.

12. Ecological Information

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the

possibility that large or frequent spills can have a harmful or damaging effect on the environment. See below

Persistence and degradability No data is available on the degradability of this product.

Bioaccumulative potential No data available.

Mobility in soil No data available.

Mobility in general Not available.



Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal Considerations

Disposal instructions Dispose of used towelette in trash. Do not flush in toilet.

Local disposal regulations Dispose in accordance with all applicable regulations.

Hazardous waste code This product is not a hazardous waste.

Waste from residues / unused

products

Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Contaminated packaging Empty packaging may be disposed in trash.

14. Transport Information

U.S. Department of Transportation (DOT)

Not regulated as dangerous goods.

15. Regulatory Information

US federal regulations This product is NOT known to be a "Hazardous Chemical" as defined by the OSHA Hazard

Communication Standard, 29 CFR 1910.1200.

This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use.

PRECAUTIONARY STATEMENTS: Hazard to humans and domestic animals. CAUTION: Causes moderate eye irritation. Harmful if absorbed through skin. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or tobacco. Remove contaminated clothing and wash before reuse.

EPA Reg. # 61178-4-9480 EPA Est. # 9480-NY-1.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Not listed.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No

SARA 302 Extremely No

hazardous substance

SARA 311/312 Hazardous No

chemical

SARA 313 (TRI reporting)

Not regulated.

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

Safe Drinking Water Act

(SDWA)

Food and Drug

Administration (FDA)

Not regulated.

Not regulated.

US state regulations This product is not subject to warning labeling under the California Proposition 65 regulation.

US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance

Not listed.



US - Texas Effects Screening Levels: Listed substance

Benzyl-C12-18-alkyldimethyl ammonium chlorides (CAS 68391-01-5)

US. Massachusetts RTK - Substance List

Not regulated.

US. Pennsylvania RTK - Hazardous Substances

Not regulated.

US. Rhode Island RTK

Not regulated.

Listed.

Country(s) or region Inventory name On inventory (yes/no)*

United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)

16. Other Information

Yes

LEGEND

Severe 4

Serious 3

Moderate 2

Slight 1

Minimal 0

HEALTH / 1

0 FLAMMABILITY 0

1 0 PHYSICAL HAZARD 0

PERSONAL X

PROTECTION

Disclaimer The information in the sheet was written based on the best knowledge and experience currently

available. Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document.

Issue date 11-February-2015

Further information For any questions surrounding this SDS, please contact the supplier/manufacturer listed on the first page of the document.

It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Not for use on skin. Not a baby wipe. For use on hard surfaces only.

Revision 0. Bulk Liquid # 4BQ08401.

Other information This Safety Data Sheet was prepared to comply with the current OSHA Hazard Communication

Standard (HCS) adoption of the Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

Prepared by Dell Tech Laboratories, Ltd. Phone: (519) 858-5021


Material Safety Data Sheet: SHINE M UP AEROSOLSAMPLE, CAN CLSupercedes Date 02/23/2006 Issuing Date 11/18/2009

1. PRODUCT AND COMPANY IDENTIFICATION Product Name SHINE M UP AEROSOLSAMPLE, CAN CL Product Code 5056Recommended Use Cleaning agent Chemical Nature AerosolInformation on Manufacturer Emergency Telephone Number CERTIFIED LABS, DIV. OF NCH CORP. CHEMTREC ® 800-424-9300BOX 152170 IRVING, TEXAS 75015


Emergency Overview CAUTION

May be harmful if inhaledMay cause skin irritationMay cause eye irritation

May be harmful if swallowedContents under pressure

Color Off -white Physical State Liquid Odor AmmoniacalPotential Health Effects Principle Route of Exposure Skin contact, Eye contact, Inhalation.Primary Routes of Entry InhalationAcute Effects Eyes May cause eye irritation. Skin May cause skin irritation. Inhalation May cause irritation of respiratory tract. Inhalation may cause central nervous system effects. Symptoms and signs include

headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea.Chronic Toxicity Occupational health effects due to inhalation of mineral dusts incorporating crystalline silica (quartz, cristobalite, tridymite), crystalline

silicates (kaolin, talc) graphite or coal, Kidney injury may occur, May cause cancer after repeated inhalation of spray or dust.Target Organ Effects Eyes, Skin, Respiratory system, Central nervous system, Heart, Liver, Kidney, Lungs.Aggravated Medical Conditions Respiratory disorders, Skin disorders, Liver disorders, Kidney disorders, Heart disease.Potential Environmental Effects See Section 12 for additional Ecological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Component CAS-NoCrystalline Silica (Quartz) 14808-60-7

Propane 74-98-6Butane 106-97-8

Ammonium tallate 68132-50-3

4. FIRST AID MEASURES General Advice Avoid contact with skin, eyes, and clothing. Avoid breathing vapors, mist, or gas.Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if irritation develops and persists.Skin Contact Wipe up with absorbent material (e.g. cloth, fleece). Wash off immediately with plenty of water. Get medical attention if irritation

develops and persists. Wash contaminated clothing before re-use.Inhalation If inhaled, remove to fresh air. Get medical attention if symptoms occur.Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention if symptoms occur.Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES Flash Point >212°F/>100°C Method Seta closed cupAutoignition Temperature No information available.

Flammability Limits in Air % Propellant. Upper 1.8 Lower 9.5Suitable Extinguishing MediaFoam. Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.Specific Hazards Arising from the ChemicalSolvent vapors are heavier than air and may spread along floors. Vapors may ignite and explode. Material can create slippery conditions. Flame extension: 0 inches / 0 cm and Burnback: 0 inches / 0 cm.Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.Aerosol Level (NFPA 30B) - 1NFPA Health 2 Flammability 1 Instability 0HMIS Health 2 Flammability 1 Instability 0

6. ACCIDENTAL RELEASE MEASURES Personal Precautions Avoid contact with skin, eyes, and clothing. Remove all sources of ignition.Environmental Precautions Prevent further leakage or spillage if safe to do so.

Page 1 / 4 of 132Page 111 of 132Page 111 of 132Page 111 of 132

Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13).

Methods for Cleaning Up Pick up and transfer to properly labeled containers.Neutralizing Agent Not applicable.

7. HANDLING AND STORAGE Handling Avoid contact with skin, eyes, and clothing. Avoid breathing dust/fume/gas/mist/vapours/spray. Contents under pressure. Do not

puncture.Storage Keep in a dry, cool and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition.Storage Temperature Minimum 35°F/2°C Maximum 120°F/49°CStorage Conditions Indoor X Outdoor Heated Refrigerated

8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines

Component ACGIH TLV OSHA PEL NIOSHCrystalline Silica (Quartz) TWA: 0.025 mg/m3 No data available IDLH: 50 mg/m3 TWA: 0.05 mg/m3

Propane TWA: 1000 ppm TWA: 1800 mg/m3 TWA: 1000 ppm IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3

Butane TWA: 1000 ppm No data available TWA: 1900 mg/m3 TWA: 800 ppm

Ammonium tallate No data available No data available No data available Engineering Measures Ensure adequate ventilation, especially in confined areas.Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin Protection For prolonged or repeated contact, use protective gloves Respiratory Protection In case of inadequate ventilation wear respiratory protection.General Hygiene Considerations Ensure that eyewash stations and safety showers are close to the workstation location. Wash contaminated clothing before re-use.

9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Viscosity ViscousColor Off -white Odor AmmoniacalAppearance Opaque pH @10% -10Specific Gravity 1.180 Evaporation Rate 12.3 (Butyl acetate=1)Percent Volatile (Volume) 76.4 VOC Content (%) 6.5VOC Photoreactive (Y/N) Yes Vapor Pressure 136.9 mmHg @ 70 °FVapor Density 1.3 (Air = 1.0) Solubility Completely solubleBoiling Point/Range 212°F/100°C

10. STABILITY AND REACTIVITY Chemical Stability Stable under normal conditions. Hazardous polymerization does not occur.Conditions to Avoid Heat, flames, and sparks.Incompatible Products Oxidizing agents, Acids, Highly halogenated compounds, Fluorinated hydrocarbons.Hazardous Decomposition Products Carbon oxides, Nitrogen oxides (NOx).Possibility of Hazardous Reactions Dangerous fumes form when mixed with other products. Chlorine.

11. TOXICOLOGICAL INFORMATION Product Information No information available.

Component Information Acute toxicity

Component LD50 Oral LD50 Dermal LC50 Inhalation Draize Test OtherCrystalline Silica (Quartz) 500 mg/kg ( Rat ) no data available no data available no data available no data available

Propane no data available no data available 658 mg/L ( Rat ) 4 h no data available no data availableButane no data available no data available 658 mg/L ( Rat ) 4 h no data available no data available

Ammonium tallate no data available no data available no data available no data available no data available Chronic Toxicity

Component Mutagenicity Sensitization Developmental Toxicity Reproductive Toxicity Target Organ Effects

Crystalline Silica (Quartz) no data available no data available no data available no data available eyes, respiratory system (in animals: lung cancer)

Propane no data available no data available no data available no data available CNSButane no data available no data available no data available no data available CNS

Ammonium tallate no data available no data available no data available no data available no data available Carcinogenicity

Component ACGIH IARC NTP OSHA OtherCrystalline Silica (Quartz) A2 Group 1 Known X not applicable

Propane not applicable not applicable not applicable not applicable not applicableButane not applicable not applicable not applicable not applicable not applicable

Ammonium tallate not applicable not applicable not applicable not applicable not applicable

5056 - SHINE M UP AEROSOLSAMPLE, CAN CL5056 - SHINE M UP AEROSOLSAMPLE, CAN CL5056 - SHINE M UP AEROSOLSAMPLE, CAN CL5056 - SHINE M UP AEROSOLSAMPLE, CAN CL Issuing Date 18-Nov-2009Issuing Date 18-Nov-2009Issuing Date 18-Nov-2009Issuing Date 18-Nov-2009


12. ECOLOGICAL INFORMATION Product Information No information available.


Component Toxicity to Algae Toxicity to Fish Microtox Water Flea log PowCrystalline Silica (Quartz) no data available no data available no data available no data available N/A

Propane no data available no data available no data available no data available 2.3Butane no data available no data available no data available no data available 2.89

Ammonium tallate no data available no data available no data available no data available N/A Persistence and Degradability No information available.Bioaccumulation No information available.Mobility No information available.

13. DISPOSAL CONSIDERATIONS Product Disposal Dispose of in accordance with local regulations.Container Disposal Contents under pressure. Do not puncture. Empty remaining contents. Empty containers should be taken for local recycling, recovery

or waste disposal.

14. TRANSPORT INFORMATION DOT DOT Proper Shipping Name Consumer commodity Hazard Class ORM-D Description Consumer commodity ,ORM-D TDG Proper shipping name Aerosols Hazard Class 2.1 UN-No UN1950 Description AEROSOLS,2.1,UN1950, LTD QTY ICAO UN-No UN1950 Proper Shipping Name Aerosols Hazard Class 2.1 Shipping Description Aerosols,UN1950, LTD QTY IATA UN-No UN1950 Proper Shipping Name Aerosols, flammable Hazard Class 2.1 ERG Code 10L Shipping Description UN1950,Aerosols, flammable,2.1, LTD QTY IMDG/IMO Proper Shipping Name Aerosols Hazard Class 2 UN-No UN1950 EmS No. F-D, S-U Shipping Description UN1950, Aerosols,2, LTD QTY

15. REGULATORY INFORMATION Inventories TSCA CompliesDSL Complies U.S. Federal Regulations SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization

Acute Health Hazard

Yes

Chronic Health Hazard

Yes

Fire Hazard

No

Sudden Release of Pressure Hazard

Yes

Reactive Hazard

No

CERCLA

Component Hazardous Substances RQs CERCLA EHS RQs

Crystalline Silica (Quartz) Not applicable Not applicable

Propane Not applicable Not applicable



Butane Not applicable Not applicable

Ammonium tallate Not applicable Not applicable

Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard ClassA Compressed gases, D2A Very toxic materials.

16. OTHER INFORMATION Prepared By Dan HollasSupercedes Date 02/23/2006Issuing Date 11/18/2009Reason for Revision No information available.Glossary No information available.List of References. No information available.CERTIFIED LABS, DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended use, storage or disposal of the product. The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.



Static Free™ Hand Guard™

Antistatic agents

Liquid.

Chemtrec - 1-800-858-4043CANTUC (Canadian Transportation): (613) 996-6666Emergency phone: (800) 858-404324/7

SAFETY DATA SHEET

GHS product identifier

Other means of identification

Product type

Emergency telephone number (with hours of operation)

Section 1. Identification:

:

:

:

Supplier's details : Chemtronics8125 Cobb Center DriveKennesaw, GA 30152

Tel. 770-424-4888 or toll free 800-645-5244


Relevant identified uses of the substance or mixture and uses advised against

Not applicable.

Section 2. Hazards identification

Not classified.Classification of the substance or mixture

:

Signal word : No signal word.

Hazard statements : No known significant effects or critical hazards.


Prevention : Not applicable.

Response : Not applicable.

Storage : Not applicable.

Disposal : Not applicable.

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 82.5%

OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product.

Hazards not otherwise classified

: None known.


Other means of identification

: Antistatic agents

CAS number : Not applicable.

Substance/mixture

Product code : C805

CAS number/other identifiers

: Mixture

Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 1/11




stearic acid 1 - 5 57-11-4glycerol 1 - 2 56-81-5octadecan-1-ol 1 - 2 112-92-5

Ingredient name CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.


Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

:

:

:

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48 hours.

Description of necessary first aid measures

Specific treatments : No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Harmful if swallowed.:Ingestion


May cause eye irritation.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion


Adverse symptoms may include the following:nausea or vomitingdiarrhea

No specific data.

:

:

:

Eye contact : Adverse symptoms may include the following:irritationrednesswatering


See toxicological information (Section 11)





Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxides

In a fire or if heated, a pressure increase will occur and the container may burst.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.


Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

:

:

:

None known.


:


:

Special protective actions for fire-fighters

:

Section 6. Accidental release measures

Environmental precautions


Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

:

: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill :

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :


For non-emergency personnel

For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Section 7. Handling and storage

Advice on general occupational hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

:

Protective measures Put on appropriate personal protective equipment (see Section 8).:





Section 7. Handling and storageConditions for safe storage,including any incompatibilities

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

:

glycerol OSHA PEL (United States, 2/2013). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dustOSHA PEL 1989 (United States, 3/1989). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 10 mg/m³ 8 hours. Form: Total dust


Ingredient name Exposure limits

Hand protection

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Eye/face protection

Respiratory protection :

:

:

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

:

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Control parameters

Individual protection measures

Occupational exposure limits

Skin protection

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.




Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid. [Viscous liquid.]

0°C (32°F)

1

Not available.

Not available.

Not available.

Pleasant.Odor

pH

White.Color


Auto-ignition temperature

Flash point

Not available.

Not available.

Not available.

7.2


Not available.Odor threshold


:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

Appearance

Boiling point : 100°C (212°F)

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

: Not available.

Decomposition temperature : Not available.

Section 10. Stability and reactivity


Conditions to avoid No specific data.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

No specific data.

:

:

:

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.


Acute toxicity

stearic acid LD50 Dermal Rabbit >5 g/kg -LD50 Oral Rat 4600 mg/kg -

glycerol LD50 Oral Rat 12600 mg/kg -octadecan-1-ol LD50 Oral Rat >5000 mg/kg -

Product/ingredient name Result Species Dose Exposure

Irritation/Corrosion






Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.


Not available.

stearic acid Skin - Mild irritant Human - 72 hours 75 milligrams Intermittent

-

Skin - Moderate irritant Rabbit - 24 hours 500 milligrams

-

glycerol Eyes - Mild irritant Rabbit - 24 hours 500 milligrams

-

Skin - Mild irritant Rabbit - 24 hours 500 milligrams

-

octadecan-1-ol Eyes - Mild irritant Rabbit - 24 hours 100 milligrams

-

Skin - Mild irritant Man - 48 hours 30 Percent

-

Skin - Mild irritant Rabbit - 24 hours 500 milligrams

-

Product/ingredient name Result Score Exposure Observation

Sensitization

Not available.

Species

Information on the likely routes of exposure

Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Harmful if swallowed.:Ingestion


May cause eye irritation.:Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact


No specific data.

:

:

Eye contact : Adverse symptoms may include the following:irritationrednesswatering

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Not available.

Not available.

Aspiration hazard

Not available.

: Not available.






Not available.

No known significant effects or critical hazards.General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Ingestion Adverse symptoms may include the following:nausea or vomitingdiarrhea

:

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Oral 26833.3 mg/kgDermal 58333.3 mg/kg

Route ATE value

Acute toxicity estimates


: Not available.

Short term exposure



: Not available.

Long term exposure


Section 12. Ecological information

LogPow BCF Potential


Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

stearic acid 8.23 238 to 288 lowglycerol -1.76 - lowoctadecan-1-ol 7.4 - high

Toxicity

Not available.


Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Not available.




Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

:Disposal methods

Section 14. Transport information

-

-

-

-

-

-

-

Not regulated.

-

-

Not regulated. Not regulated.

- - -

DOT Classification

IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information


Special precautions for user

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

No. No. No.

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

: Not available.

:

TDG Classification

Not regulated.

-

-

-

No.

-

ADR/RID

Not regulated.

-

-

-

No.

-

Mexico Classification

Not regulated.

-

-

-

No.

-

Section 15. Regulatory informationU.S. Federal regulations :

Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)

: Not listed

Clean Air Act Section 602 Class I Substances

: Not listed

Clean Air Act Section 602 Class II Substances

: Not listed

DEA List I Chemicals (Precursor Chemicals)

: Not listed

TSCA 8(a) CDR Exempt/Partial exemption: Not determined

Commerce control list precursor: 2,2',2''-nitrilotriethanol

Not determined.




Section 15. Regulatory information

The following components are listed: TRIETHANOLAMINE; GLYCERINE MIST

WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer.

Massachusetts :

retinyl palmitate Yes. No. No. No.

Ingredient name Cancer Reproductive No significant risk level

Maximum acceptable dosage level

California Prop. 65

DEA List II Chemicals (Essential Chemicals)

: Not listed

New York : None of the components are listed.

New Jersey : The following components are listed: TRIETHANOLAMINE; ETHANOL, 2,2',2"-NITRILOTRIS-; GLYCERIN; 1,2,3-PROPANETRIOL; PROPYLENE GLYCOL; 1,2-PROPANEDIOL

Pennsylvania : The following components are listed: ETHANOL, 2,2',2"-NITRILOTRIS-; 1,2,3-PROPANETRIOL; 1,2-PROPANEDIOL

State regulations

SARA 302/304

SARA 304 RQ : Not applicable.

No products were found.


SARA 311/312

Classification : Not applicable.

stearic acid 1 - 5 Yes. No. No. Yes. No.glycerol 1 - 2 No. No. No. Yes. No.octadecan-1-ol 1 - 2 No. No. No. Yes. No.

Name % Fire hazard

Sudden release of pressure

Reactive Immediate (acute)health hazard

Delayed (chronic)health hazard


International regulations

Chemical Weapon Convention List Schedules I, II & III Chemicals

Montreal Protocol (Annexes A, B, C, E)

Not listed.

Stockholm Convention on Persistent Organic Pollutants

Not listed.

Rotterdam Convention on Prior Inform Consent (PIC)

Not listed.

Triethanolamine Schedule III Listed

Ingredient name List name Status

UNECE Aarhus Protocol on POPs and Heavy Metals

Not listed.

International lists

National inventory

Australia : All components are listed or exempted.

Canada : All components are listed or exempted.

China : All components are listed or exempted.




Section 15. Regulatory informationEurope : Not determined.

Japan : Not determined.

Republic of Korea : Not determined.

Malaysia : Not determined.

New Zealand : All components are listed or exempted.

Philippines : All components are listed or exempted.

Taiwan : Not determined.


5/18/2015.

History

Date of printing

Date of issue/Date of revision

Version

Date of previous issue

:

:

:

:

Indicates information that has changed from previously issued version.

References : Not available.

Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations

5/18/2015.

No previous validation.

1

Hazardous Material Information System (U.S.A.)

0

0

0

00

0

National Fire Protection Association (U.S.A.)

Health

Special

Instability/Reactivity

Flammability

Health

Flammability

Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.





To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Notice to reader



Date Printed: 7/4/2015 Product: M282-3928

Safety Data Sheet

1. Identification

Product Information: M282-3928

Product Name: ULTRA® MARK ICELAND DAWN

Recommended Use: Surface Preparation or Protection

Mohawk Finishing Products

Division of RPM Wood Finishes Group, Inc.

22 South Center Street

Hickory, NC 28602

USA

Supplied by:

Company Phone No: (800) 522-8266

Emergency Phone No. CHEMTREC: (800) 424-9300

(703) 527-3887 (Collect calls are accepted)International Emergency No. CHEMTREC:

2. Hazards Identification

GHS Classification

Carc. 1B, Eye Dam. 1, Flam. Liq. 2, Muta. 1B, Skin Irrit. 2

Symbol(s) of Product

Signal Word

Danger

GHS HAZARD STATEMENTS

Flammable Liquid, category 2 H225 Highly flammable liquid and vapour.

Skin Irritation, category 2 H315 Causes skin irritation.

Serious Eye Damage, category 1 H318 Causes serious eye damage.

Germ Cell Mutagenicity, category 1B H340 May cause genetic defects.

Carcinogenicity, category 1B H350 May cause cancer.

GHS LABEL PRECAUTIONARY STATEMENTS

P202 Do not handle until all safety precautions have been read and understood.

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No

smoking.

P233 Keep container tightly closed.

P264 Wash hands thoroughly after handling.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Page 1 / 7



P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with

water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P310 Immediately call a POISON CENTER or doctor/physician.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

GHS SDS PRECAUTIONARY STATEMENTS

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/ equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

3. Composition/Information on ingredients

Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements

ethanol 64-17-5 40-55 GHS02 H225

butanol 71-36-3 10-25 GHS02-GHS05-

GHS07

H226-302-315-318-332-335-336

pm acetate 108-65-6 10-25 GHS02-GHS07 H226-332

titanium dioxide 13463-67-7 2.5-10 No Information No Information

isopropanol 67-63-0 1.0-2.5 GHS02-GHS07 H225-302-319-336

carbon black 1333-86-4 1.0-2.5 GHS02 H251

aliphatic hydrocarbons 8052-41-3 0.1-1.0 GHS08 H304-340-350-372

aliphatic petroleum distillates 64742-88-7 0.1-1.0 GHS06-GHS08 H304-331-372

ethylbenzene 100-41-4 0.1-1.0 GHS02-GHS07-

GHS08

H225-304-332-373

The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section.

4. First-aid Measures

FIRST AID - EYE CONTACT: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and

easy to do. Continue rinsing.

FIRST AID - SKIN CONTACT: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If

skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse.

FIRST AID - INGESTION: IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF exposed or if you feel unwell: Call a POISON

CENTER or doctor/physician.

FIRST AID - INHALATION: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable

for breathing. IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician.

5. Fire-fighting Measures

SPECIAL FIREFIGHTING PROCEDURES: Evacuate all persons from the fire area to a safe location. Move non-burning material, as

feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while

extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly

Page 2 / 7



decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use

water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish

a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the

accumulation of an explosive vapor-air mixture after the initial fire is extinguished.

FIREFIGHTING EQUIPMENT: This is a NFPA/OSHA Class 1B or less flammable liquid. Follow NFPA30, Chapter 16 for fire

protection and fire suppression. Use a dry chemical, carbon dioxide, or similar ABC fire extinguisher for incipeint fires. Water may be

used to cool and prevent rupture of containers that are exposed to heat from fire.

6. Accidental Release Measures

ENVIRONMENTAL MEASURES: No Information

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Follow personal protective equipment recommendations

found in Section VIII. Personal protective equipment needs must be evaluated based on information provided on this sheet and the

special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred,

and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits.

Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled

product to enter public drainage system or open waterways.

7. Handling and Storage

HANDLING: Avoid inhalation and contact with eyes, skin, and clothing. Wash hands thoroughly after handling and before eating or

drinking. In keeping with safe handling practices, avoid ignition sources (smoking, flames, pilot lights, electrical sparks); ground and

bond containers when transferring the material to prevent static electricity sparks that could ignite vapor and use spark proof tools

and explosion proof equipment. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder,

drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Any of these actions can

potentially cause an explosion that may lead to injury.

STORAGE: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials.

8. Exposure Controls/Personal Protection

Ingredients with Occupational Exposure Limits

Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING

ethanol N.D. 1000 ppm 1000 ppm N.D.

butanol 20 ppm N.D. 100 ppm N.D.

pm acetate N.D. N.D. N.D. N.D.

titanium dioxide 10 mg/m3 N.D. 15 mg/m3 N.D.

isopropanol 200 ppm 400 ppm 400 ppm N.D.

carbon black 3 mg/m3 N.D. 3.5 mg/m3 N.D.

aliphatic hydrocarbons 100 ppm N.D. 500 ppm N.D.

aliphatic petroleum distillates N.D. N.D. N.D. N.D.

ethylbenzene 20 ppm N.D. 100 ppm N.D.

Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation

Sk = Skin Sensitizer N.E. = Not Established N.D. = Not Determined

Personal Protection

RESPIRATORY PROTECTION: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be

permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.

Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is

potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying

Page 3 / 7



respirators may not provide adequate protection.

SKIN PROTECTION: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as

appropriate.

EYE PROTECTION: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is

possible due to splashing or spraying of material.

OTHER PROTECTIVE EQUIPMENT: No Information

HYGIENIC PRACTICES: It is good practice to avoid contact with the product and/or its vapors, mists or dust by using

appropriate protective measures. Wash thoroughly after handling and before eating or drinking.

9. Physical and Chemical Properties

Colored Liquid LIQUIDAppearance: Physical State:

Moderately Strong Alcohol Not determinedOdor: Odor Threshold:

0.916 Not determinedDensity, g/cm3: pH:

Not determined Not determinedFreeze Point, °F: Viscosity:

Not determinedPartition Coefficient, n-octanol/

water: Not determinedSolubility in Water:

Not determined Not determinedDecomposition temperature, °F: Explosive Limits, %:

> 100 °F 55 ° FBoiling Range, °F: Flash Point, °F:

Supports Combustion Not determinedCombustibility: Auto-Ignition Temperature, °F:

Faster than Diethyl Ether Not determinedEvaporation Rate: Vapor Pressure, mmHg:

Not determinedVapor Density:

N.I. = No Information

10. Stability and reactivity

STABILITY: Stable under normal conditions.

CONDITIONS TO AVOID: Heat, flames and sparks.

INCOMPATIBILITY: Acids, Bases, Oxidizing agents

HAZARDOUS DECOMPOSITION PRODUCTS: Not determined.

Page 4 / 7



11. Toxicological information

Practical Experiences

EMERGENCY OVERVIEW: No Information

EFFECT OF OVEREXPOSURE - EYE CONTACT: No Information

EFFECT OF OVEREXPOSURE - INGESTION: No Information

EFFECT OF OVEREXPOSURE - INHALATION: No Information

EFFECT OF OVEREXPOSURE - SKIN CONTACT: No Information

CARCINOGENICITY: May cause cancer.

This product contains Titanium Dioxide, which is listed by IARC as possibly carcinogenic to

humans (Group 2B). This listing is based on inadequate evidence of carcinogenicity in humans

and sufficient evidence in experimental animals. This classification is relevant when exposed

to titanium dioxide in dust or powder form only, including cured product that is subject to

sanding, grinding, cutting, or other surface preparation activities.

PRIMARY ROUTE(S) OF ENTRY:

Eye Contact, Skin Contact

Acute Toxicity Values

The acute effects of this product have not been tested. Data on individual components are tabulated below

CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50

64-17-5 ethanol 7060 mg/kg Rat N.I. 124.7 mg/L Rat

71-36-3 butanol 700 mg/kg Rat 3402 mg/kg Rabbit 8000 mg/l Rat

108-65-6 pm acetate 8532 mg/kg Rat >5000 mg/kg Rabbit >20 mg/L

13463-67-7 titanium dioxide >10000 mg/kg Rat >10000 mg/kg Rabbit >20 mg/l

67-63-0 isopropanol 1870 mg/kg Rat 4059 mg/kg Rabbit 72.6 mg/L Rat

1333-86-4 carbon black >5000 mg/kg Rat >3000 mg/kg Rabbit >20 mg/l

8052-41-3 aliphatic hydrocarbons >5000 mg/kg Rat >3160 mg/kg Rat 21 mg/L Rat

64742-88-7 aliphatic petroleum distillates >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat

100-41-4 ethylbenzene 3500 mg/kg Rat 15400 mg/kg Rabbit 17.2 mg/L Rat

N.I. = No Information

12. Ecological information

ECOLOGICAL INFORMATION: Ecological evaluation of this material has not been performed; however, do not allow the product to

be released to the environment without governmental approval/permits.

13. Disposal Information

Product

DISPOSAL METHOD: Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material,

contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations.

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Follow personal protective equipment recommendations

found in Section VIII. Personal protective equipment needs must be evaluated based on information provided on this sheet and the

special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred,

Page 5 / 7



and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits.

Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled

product to enter public drainage system or open waterways.

14. Transport Information

SPECIAL TRANSPORT PRECAUTIONS: No Information

DOT: CONSUMER COMMODITY

IATA: ID8000, CONSUMER COMMODITY, 9

IMDG: LIMITED QUANTITY UN1263

15. Regulatory Information

U.S. Federal Regulations:

CERCLA - SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the

Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to

meet the following categories:

Fire Hazard, Acute Health Hazard, Chronic Health Hazard

SARA SECTION 313

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the

Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

Chemical Name CAS-No.

butanol 71-36-3

isopropanol 67-63-0

TOXIC SUBSTANCES CONTROL ACT

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from

the United States:

No TSCA components exist in this product.

U.S. State Regulations:

CALIFORNIA PROPOSITION 65 CARCINOGENS

WARNING: This product contains a chemical known to the State of California to cause cancer.

CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS

WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductiveharm.

Page 6 / 7



16. Other Information

5/16/2015Supersedes Date:Revision Date: 7/4/2015

Reason for revision: Product Composition Changed

Datasheet produced by: Regulatory Department

HMIS Ratings:

Health: 2 Flammability: 3 Reactivity: 0 Personal Protection: X

Volatile Organic Compounds, gr/ltr: 683

Text for GHS Hazard Statements shown in Section 3 describing each ingredient:

H225 Highly flammable liquid and vapour.

H226 Flammable liquid and vapour.

H251 Self-heating: may catch fire.

H302 Harmful if swallowed.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H331 Toxic if inhaled.

H332 Harmful if inhaled.

H335 May cause respiratory irritation.

H336 May cause drowsiness or dizziness.

H340 May cause genetic defects.

H350 May cause cancer.

H372 Causes damage to organs through prolonged or repeated exposure.

H373 May cause damage to organs through prolonged or repeated exposure.

Icons for GHS Pictograms shown in Section 3 describing each ingredient:

GHS02

GHS05

GHS06

GHS07

GHS08

The information on this sheet corresponds to our present knowledge. It is not a specification and it does not guarantee specific

properties. The information is intended to provide general guidance as to health and safety based upon our knowledge of the

handling, storage, and use of the product. It is not applicable to unusual or non-standard uses of the product where instructions

and recommendations are not followed.

Page 7 / 7


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