sds paint marker sl.250 pmuc

Quick-FDS [14990-79757-09973-011596] - 2009-01-14 - 22:09:17

SAFETY DATA SHEETSL250 PMUC

1 First edition date: 12/04/2007 91/155/EC (2001/58/EC) - ISO 11014-1Version:

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKINGProduct name: SL250 PMUC

Uses or/and applications: Industrial marking

Supplier: INTRAMAPIPA - Allée des CombesF-01150 BLYESFrancePhone: +33 (0)4 74 46 23 23Fax: +33 (0)4 74 46 23 29E-mail: [email protected]

Emergency phone number (to be used by the practising doctor):

UK - National Poisons Information Service Phone: 44 / 191 22 5131B - Centre Antipoisons Tél: 070 / 245.245

2. HAZARDS IDENTIFICATIONMost important hazards: The paint is flammable.

The polypropylene body and tip carrier, the polyethylene cap, valve and label and the polyester tip are slightly flammable.Irritating to eyes, respiratory system and skin.

Specific hazards: Possibility of eye irritation in the event of contact with the paint.The paint may cause irritation of the respiratory system and the skin.The paint may have harmful effects on aquatic organisms.

3. COMPOSITION / INFORMATION ON INGREDIENTSComponent(s) contributing to the health hazard:

• n-butyl acetate - Id No: 607-025-00-1 - CAS no: 123-86-4 - EC no: 204-658-1 Conc. wt.(%): 25 < C <= 30 - Classification: • R 10 • R 66 • R 67 • • propan-2-ol; isopropyl alcohol; isopropanol - CAS no: 67-63-0 - EC no: 200-661-7 Conc. wt.(%): 5 < C <= 10 - Classification: • F; R 11 • Xi; R 36 • R 67 • • 2-methoxy-1-methylethyl acetate - Id No: 607-195-00-7 - CAS no: 108-65-6 - EC no: 203-603-9 Conc. wt.(%): 1 < C <= 5 - Classification: • R 10 • Xi; R 36 • • benzaldehyde - Id No: 605-012-00-5 - CAS no: 100-52-7 - EC no: 202-860-4 Conc. wt.(%): 0 < C <= 1 - Classification: • Xn; R 22 •

4. FIRST AID MEASURESGeneral advice: In all cases of doubt, or when symptoms persist, seek medical attention.

Never give anything by mouth to an unconscious person.For symptom description, see item 11.

Inhalation: Remove to fresh air, keep the patient warm and at rest. If breathing is irregular or stopped, administer artificial respiration. Give nothing by mouth.If unconscious, place in the recovery position and seek medical advice.

Skin contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner.Do NOT use solvents or thinners.

Eye contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart, and seek medical advice.

Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. Drink directly plenty or water of milk.

5. FIRE-FIGHTING MEASURESSuitable extinguishing media: alcohol-resistant foam, carbon dioxide (CO2), powder water spray.

Extinguishing media which must NOT be used for safety reasons:

Do not use water jet.

Specific method(s): Cool closed containers exposed to fire with water spray.Do not allow run-off from fire fighting to enter drains or water courses.

Specific fire hazard(s): Fire will produce dense black smoke.Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required.

G.E. Conseils ® 1 / 5PAGE

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Special protective equipment for fire-fighters:

Use a self-contained breathing apparatus and also a protective suit.

6. ACCIDENTAL RELEASE MEASURESPersonal precaution(s): Evacuate personnel to a safe area.

Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in Sections 7 and 8.

Environmental precaution(s): Do not allow to enter drains or water courses.If the product enters drains or sewers the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority.Contain and collect spillages with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earthPlace in a suitable container for disposal in accordance with the waste regulations (see Section 13).

Method(s) for cleaning up: The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises:water (45% by volume), ethanol or isopropanol (50%), concentrated (d:0,880) ammonia solution (5%). A non-flammable alternative is sodium carbonate (5%) and water (95%)Add the same decontaminant to any residues and allow to stand for several days in a non-sealed container until no futher reaction occurs. Once this stage is reached, close the container and dispose of in accordance with the waste regulations (see Section 13).

7. HANDLING AND STORAGEHandling

- Precaution(s): Persons with a history of asthma, allergies or chronic or recurrent respiratory disease should only be employed in processes in which this product is used under appropriate medical supervision.Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air.Smoking, eating and drinking is prohibited in areas of storage and use.For personal protection, see Section 8.The Manual Handling Operations Regulations may apply to the handling of containers of this product. Refer to the guide weight indicated on the container when carrying out assessments.

- Technical condition(s): The product should only be used in areas from which all naked lights and other sources of ignition have been excluded.Electrical equipment should be protected to the appropriate standard.The product may charge electrostatically: use earthling leads when transferring from one container to another.Operators should wear anti-static footwear and clothing and floors should be electrically conductive.Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentrations higher than the occupational exposure limits.

- Safe handling advice(s): Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non- sparking tools should be used.Avoid skin and eye contact. Avoid inhalation of vapour and spray mist.Never use pressure to empty: the container is not a pressure vessel. Always keep in containers made of the same material as the supply container.Precautions should be taken to minimise exposure to atmospheric humidity or water as CO2 may be formed which, in closed containers can result in pressurisation.Care should be taken when re-opening partly used containers.

Storage

- Precaution(s): Observe the label precautions.No smoking. Prevent unauthorised access.

- Storage condition(s): Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight.Store at temperatures between 0°C and 25°C Containers which are opened should be properly resealed and kept upright to prevent leakage.

- Separation of incompatible product(s): Store separately from oxidising agents and strongly alkaline and strongly acidic materials., amines, alcohol's and water.

- Packaging / tank material: made of the same material as the supply container.

8. EXPOSURE CONTROLS / PERSONAL PROTECTIONEngineering measure(s): Persons with a history of asthma, allergies or chronic or recurrent respiratory disease should

only be employed in processes in which this product is used under appropriate medical supervision.Vapour exhaust preferably at emission point. Care about sufficient air renewal.


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to prevent spray mist escaping into the work area outside the spray booth. Respiratory protective equipment should be worn by spray booth operatives (see - Personal protection - below)

Control parameter(s):

- Exposure limit(s): • n-butyl acetate:VME ppm = 150 - VME mg/m³ = 713 - VLE ppm = 200 - VLE mg/m³ = 950• propan-2-ol; isopropyl alcohol; isopropanol:VME ppm = 250 - VME mg/m³ = 650• 2-methoxy-1-methylethyl acetate:VME ppm = 50 - VME mg/m³ = 275 - VLE ppm = 100 - VLE mg/m³ = 550

Alcool isopropylique : . 400 ppm - 980 mg/m3

Personal protection equipment:

- Respiratory protection: In case of insufficient ventilation wear suitable respiratory equipment.

- Hand protection: Barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred.When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. protective gloves

- Skin and body protection: Cotton or cotton/synthetic overalls or coveralls are normally suitable.

- Eye protection: Eye protection designed to protect against liquid splashes should be worn.

9. PHYSICAL AND CHEMICAL PROPERTIESGeneral information

- Physical state / form: Body: aluminiumCap : solid, made from PPHP.Tip carrier : made from polypropylene.Valve : solid, made from LDPE/HDPE.Ball point : solid, made from stainless steel.Tip : solid, made from polyester.Label : solid, made from P.E.Valve spring : solid, made from steel.Paint :

- Colour: white, yellow, red, blue, green, black.

- Odour: ester-like

Important health,safety and environmental information

- PH: 7

- Boiling point/range: Not determined.

- Flash point: 25°C

- Explosion limits: Explosive limits are unknown in literature.

- Relative density (water = 1): Not determined.

- Viscosity: Not determined.

- Water solubility: Not determined.

- Fat solubility: Not determined.

- Solvent solubility: Dilutable in esters and ketones.

10. STABILITY AND REACTIVITYStability: Stable under the recommended storage and handling conditions. (See Section 7).

Material(s) to avoid: Keep away from oxidising agents and strongly alkaline and strongly acidic materials.Uncontrolled exothermic reactions occur with amines and alcohols. The product reacts slowly with water resulting in evolution of carbon dioxide.In closed containers, pressure build up could result in distortion, blowing and in extreme cases bursting of the container.

Hazardous decomposition products: In a fire, hazardous decomposition products such as smoke, carbon monoxide. carbon dioxide and oxides of nitrogen may be produced.

11. TOXICOLOGICAL INFORMATION


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General information(s): There is no data available on the product itself.Based on the properties of isocyanate content of this product, respiratory exposure may cause acute irritation and/or sentization of the resiratory system, resulting in asthmatic symptoms, wheezing and a tightness of the chest.Sensited persons may subsequently show asthmatic symptoms when exposed to airborne concentrations of isocyanates well below the occupational exposure limit.Repeated exposure may lead to permanent respiratory disability.

Acute toxicity

- Inhalation: Exposure to organic solvent vapours may result in adverse health effects such asirritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems.. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.

- Skin contact: Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin.

- Eyes contact: Splashes in the eyes may cause irritation and reversible local damage.

- Ingestion: May cause gastrointestinal irritation, nausea, vomiting and diarrhoea.

12. ECOLOGICAL INFORMATIONGeneral information(s): There is no data available on the product itself.

The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters.

Environmental toxicity: Ecological problems are not known or expected under normal use.

Otheradverse effects

13. DISPOSAL CONSIDERATIONSWaste / unused products: Collect all waste in suitable and labelled containers and dispose according to local legislation.

Contaminated packaging: Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act.

Further Information(s):

14. TRANSPORT INFORMATIONGeneral information(s): Transport followed ADR, IMDG, IATA

UN N°: Not applicable.

15. REGULATORY INFORMATIONLabelling: .

Occupational disease chart 84 (presence of organic solvents). ..

EC number: Not applicable.

Symbol(s): None according to EC directives.

R-phrase(s): 10 Flammable.66 Repeated exposure may cause skin dryness or cracking67 Vapours may cause drowsiness and dizziness

S-phrase(s): None according to EC directives.

16. OTHER INFORMATIONItem nr 2 : R-phrase(s) R10 Flammable.

R66 Repeated exposure may cause skin dryness or crackingR67 Vapours may cause drowsiness and dizzinessR11 Highly flammable.R36 Irritating to eyes.R22 Harmful if swallowed.


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Important remarks: As the specific conditions of use of the product are outside the supplier's control,the user is responsible for ensuring that the requirements of relevant legislation are complied with.The user is always responsible for ensuring that the requirements of relevant legislation are complied with.The information contained in this safety data sheet is based on the present state of knowledge and current national legislation it provides guidance on health safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications.

Uses or/and applications: Industrial marking

Restrictions: The product should not be used for purposes other than those shown in Section 16 without first referring to the supplier and obtaining written handling instructions.

- First edition date: 12/04/2007

- Version: 1

Written by: INTRAMA - MF


sds paint marker sl.250 pmuc

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