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The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory Energy Technology Centre 1 1 Solander Science Park (2nd floor)

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Page 1: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

The ETC Bioenergy Laboratory

Chemrec

DP1

Smurfit Kappa

Kraftliner

ETC Bioenergy

Laboratory

Energy Technology Centre1

1

Solander Science

Park (2nd floor)

Page 2: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Pre- treatment of biomass

Henry HedmanEnergitekniskt Centrum

HighBio seminar 2009-05-12 Luleå, Sweden

Energy Technology Centre2

Page 3: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

AGENDA

• Why pre-tretment of biomass• Charactarization of biomass• Different applications and technologies• Torrefaction, hammermills• Futher work

Energy Technology Centre3

Page 4: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Why pre-tretment of biomass

• Making a homogenius feedstook, size, form,,,• Changing structure in wood, hemicellulosa,

celluloosa, hydrophobe• Different applications combustion or gasification• Higher pressure, different levels of oxidant• Feeding systems, powder, slurry• Different gasification processes

Energy Technology Centre4

• Different gasification processes - Slagging, (needs additives)- Non- slagging

Page 5: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Technologies in Highbio project

• Systems for feeding biomass to high pressures- Powder form, lockhoppers- Slurry, pump systems

1 Torrefaction process2 New type of milling process shearing (patented)

compared to traditional hammer mill

Energy Technology Centre5

2 New type of milling process shearing (patented) compared to traditional hammer mill

3 Pyrolysis oil

Page 6: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Methods to characterize biomass

• Moisture content, ash content, density• Particle size distribution• Particle form, microscope• Valuting, bridging• Chemical analyzis• Combustion tests measuring deposits, slagg,

gasues, dust and particles

Energy Technology Centre6

• Combustion tests measuring deposits, slagg, gasues, dust and particles

Page 7: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Light microscope

Bark (pellets) after milling Stem wood (pellets) after milling

Energy Technology Centre7

Bark (pellets) after milling Stem wood (pellets) after milling

Dry wood chips after milling

Page 8: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Valut and bridging

Energy Technology Centre8

Flowability test

Page 9: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Feeding and combustion tests

Energy Technology Centre9

Page 10: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Torrefaction

• Breaking the wood structure regarding to decomposition

• Hemicellulosa, volotiles mainly acetic acid and water small amounts of methanol, acetone and fenol

• Making a hydrophobe product• Slurry pump technology

Energy Technology Centre10

• Slurry pump technology• Low milling energy

Page 11: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Torrefaction

• Around 30 scientific papers about torrefaction• A gap between current litterature regarding

combustion properties of torrefact material (Bridgman 2007)

• Comersial processes long ago • New plants in Ö-vik ”BioEndev” in Sweden 2010• Also a new plant in Holland

Energy Technology Centre11

• Also a new plant in Holland

Page 12: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Torrefaction stages

Energy Technology Centre12

Page 13: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Mass and energy balance

Torrefaction gases 0.3M |

Energy Technology Centre13

Torrefaction

250-300°C

Torrefied Biomass

0.7M | 0.9E 1M | 1E

Page 14: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Milling electric power consumption

Energy Technology Centre14

Page 15: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Hammer mill

60

80

100

120

En

erg

y c

on

su

mp

tio

n (

kW

/to

n)

Energy consumption (kW/ton)

Energy Technology Centre15

0

20

40

60

Bark Dry wood chips Stem wood pellets Torrefaction

Fuel type

En

erg

y c

on

su

mp

tio

n (

kW

/to

n)

Energy consumption (kW/ton)

Page 16: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Slurry feeding

Pump system

Energy Technology Centre16

Page 17: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Wood powder + water around 22 % biomassWood powder + vegetable oil around 27 % biomassWood powder + Methanol around 30 % biomass

Coal powder + water around 78 % biomass

Mix of wood and coal in not better!!!!

Slurry trials

Energy Technology Centre17

Trials with torrefacted material will be performed soon at ETC

Page 18: Smurfit Kappa Kraftliner ETC Bioenergy Laboratory … · The ETC Bioenergy Laboratory Chemrec DP1 Smurfit Kappa Kraftliner ETC Bioenergy Laboratory ... • Different gasification

Further work

• Torrefaction studies literature and lab trials slurry pumping

• Rotary valves and lock hoppers in lab• Using of different biomass feed stocks

(autumn 2009) using additives• New technology regarding milling (shearing)

Energy Technology Centre18

• New technology regarding milling (shearing)• Pyrolysis oil