supplemental material, tech. activity supporting doc.: exp ... · nuclear project client: division...

010001

SOUTHWEST RESEARCH INSTITUTE NUCLEAR PROJECT CLIENT: Division 20

SRR: 30576 SDG: 294954 CASE: CNWRA VTSR: April 10,2007 PROJECT# : 06002.01.242

TASK ORDER: 070410-6

f

FINAL REPORT

SOUTHWEST RESEARCH INSTITUTE 010002 SAMPLE ANALYSIS DATA SHEET

Boron

Lab Name: Southwest Research Institute

Lab Code: SwRI

Matrix: Water

Lab System ID: 294954

Method: 6010B MOD, 6020 MOD

0.441 0.2

Sample ID I C-NPCS-C1 I Client: Division 20

Date Received: 04/10/07

Project No.: 06002.01.242

SRR#: 30576

Task Order #: 070410-6

r - I Sample I Reporting I

Antimon

ICadmium I <0.0500 I 0.05 I I Calcium I <0.500 I 0.5 1

Page 1 of 10 This report may not be reproduced except in its entirety without the written approval of SwRI.

SOUTH WEST RESEARCH INSTITUTE DUPLICATE SUMMARY 010003

SamDle ID I C-NOCS-Cl I


Lab Code: SwRI

Matrix: Water

Lab System ID: 294954D


Client: Division 20


Project No.: 06002.01.242

SRR#: 30576



SOUTH WEST RESEARCH INSTITUTE MATRIX SPIKE SUMMARY

Antimony Arsenic Barium

010004

<0.200 4.96 <0.0500 20.1

0.193 20.6

Sample ID I C-NDCS-Cl I

Beryllium Bismuth Boron Cadmium Calcium Chromium Cobalt Copper Iron


<0.0500 0.501 NA NA NA NA

<0.0500 0.494 <os00 196

<0.0500 1.94 <0.0500 5.04 <0.0500 2.53 <os00 11.7

Lab Code: SwRI

Uranium I NA

Matrix: Water

NA


NA 5.00 NA 5.00 NA


NA 99.4%

NA 99.4%

NA

I Orig. Sample I Spike

Yttrium

Analysis I Result (ma) I Result ( m a ) Aluminum I <os00 I 19.4

NA NA Zinc I <o .0500 4.97

Lanthanum I NA NA Lead <0.0500 I 4.87 Lithium <0.150

<os00 <0.0500

Nickel <0.0500 4.90 Palladium NA NA

lzirconium I NA I NA

Client: Division 20


Project No.: 06002.0 1.242

SRR#: 30576


Spike I Added(mg/L) I Recovery

20.0 I 97.0% 99.2% 100.5% 102.0%

NA NA 5.00 97.4% 40.0 100.0% 200 99.0% 5.00 100.2% NA NA 5.00 98.0% NA NA NA NA 10.0 123.0% 20.0 103.5% NA NA

0.500 99.2% 100.0%

40.0 104.2% 20.0 I 105.0% NA NA NA I NA I

NA - Not Applicable. Page 3 of 10 This report may not be reproduced except in its entirety without the written approval of SwRI.

SOUTHWEST RESEARCH INSTITUTE SAMPLE ANALYSIS DATA SHEET


Lab Code: SwRI

Matrix: Water



010005 Sample ID

I C-NPCS-C~ I Client: Division 20


Project No.: 06002.01.242

SRR#: 30576



SOUTHWEST RESEARCH INSTITUTE 010006 SAMPLE ANALYSIS DATA SHEET

Sample ID I C-NPCS-C~ I


Lab Code: SwRI

Matrix: Water



Client: Division 20


Project No.: 06002.01.242

SRR#: 30576


I I Sample I Reporting I


SOUTHWEST RESEARCH INSTITUTE 0 1 0 0 0 ~

Analysis Aluminum

Arsenic Barium

Antimony

- SAMPLE ANALYSIS DATA SHEET

Sample Reporting Result ( m a ) Limit ( m a )

<OS00 0.5 <0.200 0.2 <0.0500 0.05

0.250 0.05


Lab Code: SwRI

Matrix: Water



Boron I 0.48 1

Sample ID C-NPCS-C~ 1

Client: Division 20


Project No.: 06002.01.242

SRR#: 30576


0.2

This report m

IBervllium I <0.0500 I 0.05 I IBismuth I <0.100 I 0.1 I

I <OS00 I 0.5 Calcium Chromium <0.0500 I 0.05 1 Cobalt <0.0500

<0.0500 <OS00

<0.0500 <O .05 00 <0.150

<0.0500

Palladium <0.100 Phos horus <0.200 Potassium Selenium <0.100 0.1 Silicon <OS00 Silver <0.0500 Sodium Strontium <0.0500 0.05 Sulfur Thallium <0.100 Thorium <0.150 0.15

<0.100 Titanium <0.0500 0.05 Tungsten <0.100 0.1 Uranium 4 . 2 5 Vanadium <0.0500 Yttrium <0.0500 Zinc <0.0500 Zirconium <0.0500

Page 6 of 10 lay not be reproduced except in its entirety without the written approval of SwRI.

SOUTH WEST RESEARCH INSTITUTE SAMPLE ANALYSIS DATA SHEET

Beryllium Bismuth Boron Cadmium

010008

<0.0500 0.05 <0.100 0.1

1.41 0.2 <0.0500 0.05

Sample ID I C-NpCS-C5 1


Lab Code: SwRI

Matrix: Water



Client: Division 20


Project No.: 06002.01.242

SRR#: 30576


I I Sample I Reporting I Analysis 1 Result ( m a ) I Limit ( m a ) Aluminum I <os00 I 0.5

Antimony I <0.200 I 0.2 I IArsenic I <0.0500 I 0.05 I IBarium I 0.891 I 0.05 I

Calcium <os00 Chromium <0.0500 Cobalt <0.0500

<0.0500 Iron <os00

ILanthanum I <0.0500 I 0.05 I

Silver <0.0500 Sodium Strontium <0.0500 Sulfur 29.8 Thallium <0.100

I Thorium I 10.150 I 0.15 I ITin I <0.100 I 0.1 I [Titanium I <O. 05 00 I 0.05 I

<0.100 4 . 2 5

<0.0500 <0.0500 <0.0500 <0.0500 0.05


SOUTHWEST RESEARCH INSTITUTE

Analvsis

SAMPLE ANALYSIS DATA SHEET

Sample Reporting Result ( m a ) Limit (mdL)

010069

Iron Lanthanum Lead

Sample ID I C-NpCS-C6 1

20.1 0.5 <0.0500 0.05 <0.0500 0.05

Lab Name: Southwest Research Institute Client: Division 20

Phosphorus I <0.200

Lab Code: SwRI Date Received: 04/10/07

0.2

Matrix: Water Project No.: 06002.01.242

Lab System ID: 294959 SRR#: 30576

Method: 6010B MOD, 6020 MOD Task Order #: 070410-6

1 Aluminum I C0.500 I 0.5 I Antimony I <0.200 I 0.2 Arsenic <0.0500 I 0.05 I

Lithium <0.150

<0.0500 <0.0500

Nickel <0.0500 IPalladium I <0.100 0.1

Selenium <0.100 Silicon <os00 Silver <0.0500 Sodium 18.7 Strontium <0.0500 0.05 Sulfur <os00 Thallium <o. 100 Thorium <0.150

<0.100 Titanium <0.0500 0.05

<0.100 Uranium a . 2 5 Vanadium <0.0500 Yttrium <0.0500 Zinc <0.0500

lzirconium I <0.0500 I 0.05 I Page 8 of 10

This report may not be reproduced except in its entirety without the written approval of SwRI.

SOUTHWEST RESEARCH

Analysis Aluminum

INSTITUTE 0 10010 LABORATORY CONTROL SAMPLE

Sample True Result ( m a ) Value ( m a ) Recovery

1.93 2.00 96.5%


Lab Code: SwRI

Matrix: Water

Lab System ID: LCSW-D16H1/ D25C1


Antimony Arsenic Barium Bervllium

Sample ID Lab Control I

Client: Division 20

0.493 0.500 98.6% 2.01 2.00 100.5% 2.04 2.00 102.0%

0.0503 0.0500 100.6%

Date Received: NA

Sulfur Thallium Thorium Tin Titanium Tungsten Uranium

Project No.: 06002.01.242

4.21 4.00 105.3% 2.09 2.00 104.5% NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA

SRR#: 30576

Vanadium Yttrium Zinc Zirconium


0.498 0.500 99.6% NA NA NA

0.497 0.500 99.4% NA NA NA

This report n

Bismuth Boron Cadmium 0.0497 0.0500 99.4% Calcium 20.0 98.5% Chromium 0.194 0.200 97.0% Cobalt I 0.503 I 0.500 I 100.6% Copper 0.250 0.250 100.0%

Molybdenum I NA I NA I NA Nickel I 0.489 0.500 97.8%

wRI .

SOUTHWEST RESEARCH INSTITUTE 010011 BLANK SUMMARY

B ery 1 lium Bismuth Boron

Sample ID Prep Blank I I

<0.0500 0.05 <0.100 0.1 <0.200 0.2

Lab Name: Southwest Research Institute Client: Division 20

Lanthanum Lead Lithium

Lab Code: SwRI Date Received: NA

<0.0500 0.05 <0.0500 0.05 <0.150 0.15

Matrix: Water Project No.: 06002.01.242

Phosphorus

Lab System ID: PBW-D16H1/ D25C1 SRR#: 30576

<0.200 0.2

Method: 6010B MOD, 6020 MOD Task Order #: 070410-6

Silicon Silver Sodium Strontium Sulfur Thallium

I I Sample I Reporting 1

<OS00 0.5 <0.0500 0.05

<2.50 2.5 <0.0500 0.05 <OS00 0.5 <0.100 0.1

Analysis I Result (mg/L) I Limit ( m a ) Aluminum I <OS00 I 0.5

1 Antimonv I <0.200 I 0.2 I !Arsenic I <0.0500 I 0.05 I

<OS00

Nickel <0.0500 0.05

I Potassium I <0.00200 I 0.002 I I Selenium I <0.100 I 0.1 1

I Thorium I <0.150 I 0.15 I lTin I <0.100 I 0.1 I

<0.100 Uranium 4 . 2 5 Vanadium <0.0500 Yttrium <0.0500 Zinc <0.0500 0.05 Zirconium <0.0500

This report ma

NA - Not Applicable. Page 10 of 10

.y not be reproduced except in its entirety without the wri itten app iroval of SwRI.

RAW DATA (Not Required To Be Sent to Client)

010012 SOUTHWEST RESEARCH INSTITUTE NUCLEAR PROJECT CLIENT: Division 20

SRR: 30576 SDG: 294954 CASE: CNWRA VTSR: April 10,2007 PROJECT#: 06002.01.242


Other Data

Southwest Research Institute (Division 01 QA) f

4

Content Check List for Nuclear Safety Related Projects

010013

The contents of this file may include the documentation (or only those applicable) listed below:

Final Report m . 0 7 0 y / ~ -4 / Task Orders/QPP-015

Purchase Order/Contract Agreement

r ) 4 Telephone Conversations

COC/Log-in PapenvorWLabels, Tags, etc.)

/ Copies of Log-in Book Showing Samples

fl4 Copies of Methods (If applicable)

Copies of Logbook Instruments Logs including;

0

0 f l 2) Reagent Preparation

0 3) Standard Preparation

0 J 4) Sample Calculations

0 5 ) Calculated QC samples

L/ 1) Calibration data on instruments

Any Log-in Non Conformance Sheets

fl A Certificates of Analysis for Standards

If applicable:

0 flrA Thermometer Calibrations

17 6 Pipette Calibrations

'& Balance Calibrations

hc, DI Water Verification

flL Surveillance Reports from Division 30

I certify that all applicable documents listed above are included in this file as a part of the documentation required by all Nuclear Safety Related protocol.

~ ~ ~ e v i e w r " 7 & & ~ ' Date

FRM-020 (Rev 2/June 03)

SOUTHWEST RESEARCH INSTITUTE INORGANIC DATA PACKAGE

010014 TASK ORDER: 0704 10-6

CLIENT: Division 20 SDG: 294954

PROJECT: 06002.01.242 SRR(S): 30576

DUE DATE: 05/07/07 (05/08) DATE GIVEN TO DRG: 05/02/07

FILENAME (S):Y :\METALS\REPORTS\div200704 10-6 .xls ob +.so

DRG 0 [7 w c] Client picked up report

[7 Report taken to client

0 For file only

Client specified no QC samples (see attached)

Minimum QA required, Please deliver to JoAnn

Preliminary results e-mailed to Bradley Werling ( 05/02/07 )

MAIL 0 Letter report [7 Hold for purchase order [7 Fax report once p.0. is given

0 Raw data required 0 Interoffice mail, IOCFRSO stuff

Regular mail Forms only / No raw data

c] Next day air

0 Second day air

BILLING 0 Please Bill

0 Gave Erica / Kristi / Sally info

u Paid with Check #

Daniel Ramirez

From: Sent: To: cc: Subject:

Daniel Ramirez [[email protected]] Wednesday, May 02,2007 7:13 PM Bradley A. Werling Jackie Ranger Preliminary results - 070410-6

010015

070410-6.pdf 070410-6.~l~

Bradley, Attached are the preliminary results for the six samples received on 04/10/07, placed in

The report, for Metals, is attached as an excel (070410-6.~1~) and pdf (070410-6.pdf)

Should you have any additional questions, please contact Jackie Ranger (ext. 3320).

our S R R # 30576, Task Order # 070410-6.

file.

Daniel Ramirez Southwest Research Institute Department of Analytical and Environmental Chemistry Division 01 6220 Culebra Road San Antonio, Texas 78238 Phone (210) 522.3867 Fax (210) 522.5938

1

SOUTHWEST RESEARCH INSTITUT $I10016 NUCLEAR PROJECT CLIENT: Division 20



Task Orders/Ol-QPP-O15

Southwest Research Institute

SystemID 294954 294955 294956 294957 294958 294959

Laboratory Task Order TO #: 070410-6 Revision: 0

Type Cont Matrix - Customer ID CED Method Date 02 Oct 07 1 Water C - Np CS-C 1 05 Apr 07

1 Water C-NpCS -C2 05 Apr 07 02 Oct 07 1 Cater C-NpCS-C3 ._ 05 Apr 07 02 Oct 07 1 Water C -NpCS - - C4 05 Apr 07 02 Oct 07

29 Mar 07 25 Sep 07 1 Water C-NpCS-C6 05 Apr 07 02 Oct 0 7

1 Water C - Np CS - C5

SDG: 294954 VTSR: 04/10/07 CASE: WERLING

ICPMS Method 6020 Total Metals -verify to see if ICPMS is required. Previous work needed, no mention on COC for it on this round.

SRR#’s: 30576 Client(s): Div. 20

Cnt: 6

Project@): 06002.01.242 Manager@): DAMMANN, MIKE To PM: 05/07/07

SystemID 294954 294955 294956 294957 294958 294959

To QA: 05/07/07 To Client: 05/08/07 0 1 0 0 1 7

Type Cont Matrix - Customer ID CED Method Date 02 Oct 0 7 1 Water C - Np CS-C 1 05 Apr 07

1 Water C -NpCS - C2 05 Apr 07 02 Oct 07 1 Water C ~ Np CS-C3 05 Apr 07 02 Oct 07 1 Water C-NpCS ~- -C4 05 Apr 07 02 Oct 07

C ~- -NpCS - C5 29 Mar 07 25 Sep 07 1 Water 1 Water C -NpCS __ - C6 05 Apr 07 02 Oct 07

DIVISION 20 - CNWRA. 4-WEEK TAT. Using 27-day TAT for PM/preliminary, DRG/QAU.

and ICPMS. The samples for ICP & ICPMS, 6, are listed in this task order. SEE ALSO TASK ORDER # 070410-5.

TWELVE overall samples received on 04/10/07 for ANIONS by IC and MAJOR & MINOR analysis by ICP

NOTE - Previous samples required ICPMS, no mentioned of that requirement on chain of custody.

Point of contact is BRADLEY WERLING (~6565). Send prelims to Werling, excel & pdf.

I Documents Related to this task order: 29879LCOC for SRR 305761 I Deliverables --> Hard Copy: -YES- EDD: no PDF: -YES-

This Task Order is NOT BILLED

Test: DIL-DILUTION Section: METALPREP 1 Prep, Dilution 1 Cnt: 6

Holding: 180 days from CED

Test: ICP-601OB Section: METALS

Holding: 180 days from CED - 1 ICP Method 6010B Total Metals I Cnt: 6

Test: ICPMS-6020 Section: METALS

Page 1 of 1 ver 5/25/2007

01 4PP-015 Division 01 Revision 6 June 2006

Document No.

Chemistry and Chemical Enaineerina Division

QUALITY PROJECT PLAN FOR

010018

PERFORMANCE OF CHEMICAL ANALYSES FOR COMMERCIAL NUCLEAR POWER PLANTS

WITHIN THE DEPARTMENT OF ANALYTICAL AND ENVIRONMENTAL CHEMISTRY

SOUTHWEST RESEARCH INSTITUTE Chemistry and Chemical Engineering Division 6220 CULEBRA ROAD, SAN ANTONIO, TEXAS 78238

Uncontrolled Copy CHEMISTRY AND CHEMICAL ENGINEEAWI~M~W~~ On date prillted Division 01 Quality Project Plan

Ol-QPP-015 01001 9 Division 01 Rev 6IJune 2006 Page i

QUALITY PROJECT PLAN FOR PERFORMANCE OF CHEMICAL ANALYSES FOR COMMERCIAL NUCLEAR POWER PLANTS

WITHIN THE DEPARTMENT OF ANALYTICAL AND ENVIONMENTAL CHEMISTRY

SwRl AUTHORIZATION SIGNATORIES

This is to certify that this Quality Project Plan of Southwest Research Institute (SwRI) has been reviewed and approved by the following personnel:

G;./<$&)$ DATE

+/&k i REZA K M l d (21 0) 522-241 2 DATE \ lytical and Environmental Chemistry

Southwest Research Institute Proprietary

Uncontrolled Copy Dispose of b y end of day cn date prifiled

CHEMISTRY AND CHEMICAL ENGINEERING DIVISION Division 01 Quality Project Plan

01-QPP-015 0 100 20 Division 01 Rev 6/June 2006 Page ii

TABLE OF CONTENTS

ma? 1.0 INTRODUCTION ...................................................................................................................................................... 1

2.0 SCOPE ...................................................................................................................................................................... 1

3.0 REFERENCES .......................................................................................................................................................... 1

4.0 APPLICABLE SECTIONS OF SWRI PROGRAM QUALITY PLAN (PQP-NUCLEAR) ....................................... 1

4.1 4.2 4.3 4.4 4.5 4.6 4.7 4.8 4.9 4.1 0 4.1 1 4.1 2 4.1 3 4.14

Indoctrination and Training ....................................................................................................................... 1 Qualification of Personnel ... .......... ...... ..... 2 Design Control ............... ................................................................................................. 2 Right of Access .............. ................................................................................................. 2 Control of Supplier-Generated Documents ....................... .. .... .... ... ...................................... ....... .......... 2 Acceptance of Services Only ................................................................................................................... 3

Inspection and Tes

Qua I ity Assurance 10 CFR, Part 21 ......

Handling, Storage, ...............

..................

5.0 HISTORY OF REVISIONS ....................................................................................................................................... 7


Uncontrolled Copy Dispose of by end cf drjy cn dale prir:ed 010021


01-QPP-015 Division 01 Rev 6/June 2006 Page 1 of 7

1 .o

2.0

3.0

4.0

PERFORMANCE OF CHEMICAL ANALYSES FOR COMMERCIAL NUCLEAR POWER PLANTS WITHIN THE DEPARTMENT OF ANALYTICAL AND ENVIRONMENTAL CHEMISTRY

INTRODUCTION

This Quality Project Plan (QPP) defines the Quality Assurance (QA) program requirements for personnel providing the chemical analyses for commercial nuclear power plants. Southwest Research Institute (SwRI) Program Qualify Plan (PQP-Nuclear), Nuclear Services shall implement the QA requirements. Project activities controlled by the PQP-Nuclear shall be accomplished as specified by the appropriate sections of 01 -QAP-004, Quality Assurance Plan for Analytical and Environmental Services and/or nationally recognized testing methods as specified on individual purchase orders. This QPP shall be applied to all projects initiated for nuclear utilities in the Department of Analytical and Environmental Chemistry. If, as a result of complexity, duration, or other factors, it is determined that a unique, project-specific quality plan is required, the project QAE shall notify the Project Manager and a project-specific quality plan shall be generated in accordance with SOP-014.2.1, Preparation and Revision of Documented Procedures.

SCOPE

This Quality Project Plan shall be applied to the chemical analyses performed for commercial nuclear power plants by the Department of Analytical and Environmental Chemistry within the Chemistry and Chemical Engineering Division. Although the majority of the work performed for nuclear facilities resides within the Department of Analytical and Environmental Chemistry, other departments within the division may utilize this Quality Project Plan as deemed necessary when nuclear projects are conducted.

REFERENCES

3.1 SwRI Qualify System Manual - 2000

3.2 I O CFR 50, Appendix 6, ASME NQA-1

3.3 SwRl Program Qualify Plan (PQP-Nuclear), Nuclear Services

3.4 0 1 -QAP-004, Quality Assurance Plan for Analytical and Environmental Services

APPLICABLE SECTIONS OF SWRI PROGRAM QUALITY PLAN (PQP-NUCLEAR)

4.1 Indoctrination and Training

4.1 .I Personnel performing duties affecting quality shall receive quality training to the SwRl Program Quality Plan (PQP-Nuclear), Nuclear Services prior to performing any work on projects for nuclear utilities. This training will be conducted either by Institute Quality Systems (IQS) or Division 01 Quality Assurance personnel and documentation shall be evident in the personnel training files maintained in Division


010022 Uncontrolled Copy

Dispose of by end of day on dale pricled



01 Quality Assurance. Indoctrination and training of personnel shall be conducted in accordance with SOP-OI-6.2.1, Qualification and Training.

4.1.2

4.2 Qualification of Personnel

4.2.1 Testing personnel shall be designated as qualified to perform applicable project activities as specified in SOP-01-6.2.1, Qualification and Training.

4.2.2 During the performance of each testing process, testing personnel shall have access to the necessary documented procedures, Le., QPP, QAP, Task Order, Division Quality System Standard Operating Procedures (SOPS), and applicable test/analytical procedures (TAPS) available for ready reference.

4.2.3 Any person who has not performed testing activities associated with any particular method being used for nuclear utilities projects for a period of one year shall be reevaluated prior to the conduct of the test.

4.2.4 Quality Assurance personnel witnessing the testing process for nuclear utilities shall have documented evidence of qualifications maintained by Institute Quality Systems or Division 01 Quality Assurance.

4.3 Design Control

Not applicable to activities conducted within the Department of Analytical and Environmental Chemistry.

4.4 Right of Access

4.4.1 Procurement documents shall provide for access to the suppliers’ facilities and records for surveillance, inspection, or audit by SwRl and clients.

4.4.2 Where appropriate, quality clause Q32 shall be noted on the procurement documents to indicate that right of access for inspection and surveillance of activities associated with the order shall be afforded to SwRl and clients.

4.5 Control of Supplier-Generated Documents

4.5.1 Client documents shall be controlled in accordance with SOP-OI4.2.1, Preparation and Revision of Documented Procedures. These procedures provide the requirements for the preparation, review, approval, issue, distribution, and revision of documents controlled by the Chemistry and Chemical Engineering Division.

4.5.2 Documents may be controlled as Plans or Work Instructions and shall be accessible through the Division lntranet link, Contract Requirements as PDF files.

4.5.3 Nationally recognized test methods shall be of the most current issue or as specified in the purchase order. Task orders shall identify the applicable test methods to be used on the nuclear project.



Dispose ot by end cf day cn aa!e prlrtea



4.6 Acceptance of Services Only

Not applicable to activities conducted within the Department of Analytical and Environmental Chemistry.

4.7 Commercial Grade Items

4.7.1

4.7.2

4.7.3

4.7.4

4.7.5

4.7.6

Where an item is to be incorporated into a test or deliverable to a client, and that item is not subject to design or specification requirements that are unique to nuclear facilities, used in applications other then nuclear facilities, and procured from the supplier on the specifications set forth in the manufacturers’ published product and description, the item shall be considered “commercial grade”.

Chemical reagents and standards used for testing purposes shall be ordered to specific chemical grades and certificates of analysis shall be required with each lot.

Controls for procurement planning, supplier selection, supplier performance evaluation, and acceptance of procured items and services other than chemical reagents and standards shall be as identified in SOP-01-7.4.1, Purchasing, and any referenced document within that procedure.

Receipt inspection of chemical reagents, standards, and test items for use on nuclear safety-related projects shall be performed by department personnel and documented on the SwRl Receipt Traveler or FRM-109, Item Receipt Repolt, as specified in SOP41 -8.2.4, Monitoring and Measurement. Any discrepancy such as a damaged container or container label shall be documented on the form and the client shall be contacted for disposition.

Prior or acceptance of a commercial grade item, the receipt inspection shall determine the following:

(a) Damage was not sustained during shipment;

(b) The item has satisfied the specified acceptance criteria; and

(c) Specified documentation, as applicable to the item, was received and is acceptable.

Receipt inspection of chemical reagents and standards shall also consist of verification of chemical type, grade, container integrity, certificate of analysis, and shelf life, where applicable. Upon acceptance of chemical reagents and standards, the containers shall be labeled with the following:

(a) Chemical name;

(b) Chemical grade;

(c) Lot code;


Uncontrolled Copy Dispose of i’y end of day’ on da!e pritxed


010024


(d) Date received; and

(e) Shelf life, when applicable.

4.7.7 Expired shelf life items shall not be used for testing purposes.

4.7.8 Lot codes of chemical reagents and standards used during equipment standardization and testing shall be recorded on the individual testing data sheets to provide traceability.

4.7.9 Samples supplied to SwRl for testing shall be received by the Sample Custodian and logged into the laboratory logbook. Sample documentation and sample custody shall be maintained in accordance with TAP-01-0407-001, Sample Receipt Inspection, and TAP-01-0407-035, Organic and Inorganic Sample Security.

4.7.1 0 Samples supplied to SwRl for testing shall be labeled with the following:

(a) Sample control number;

(b) Purchase order number;

(c) Purchase order line item number, as applicable;

(d) Task order number;

(e) Nuclear QA label; and

(9 Sample retention date, when applicable.

4.7.11 In the event that samples are damaged upon receipt, a Sample Discrepancy Record shall be generated from the Division Intranet.

4.7.12 The testing task order shall list the project number, tests required, test methods required, and shall be labeled Nuclear Quality.

4.7.1 3 Identification and traceability shall be maintained in accordance with SOP41 -7.5.1, Item Identification and Traceability.



Bispvie 3f by end of day cn date prtt>ied



4.8 Inspection

4.8.1 Inspection for acceptance shall be performed by qualified persons other than those who conduct or directly supervise the work being inspected.

4.8.2 Institute Quality System (IQS) personnel shall perform surveillance activities as required to ensure compliance with the contract and this Quality Project Plan. Specific areas in which IQS may perform surveillance activities include, but are not limited to, the following:

(a) Receiving inspection and labeling of chemical reagents, standards, and testing samples;

(b) Testing processes;

(c) Calibration and major equipment;

(d) Sample and record retention; and

(e) Test records

4.9 Inspection and Testing

4.9.1 Required tests for acceptance shall be conducted under appropriate environmental conditions using the tools and equipment necessary to conduct the test in a manner to fulfill test requirements and acceptance criteria.

4.9.2 Tests shall be conducted, controlled, and verified in accordance with SOP-01 -8.2.4, Monitoring and Measurement.

4.9.3 Controls for measuring and test equipment shall be as specified in SOP-01-7.6.1, Control of Measuring and Test Equipment.

4.9.4 Controls for identification, segregation, reporting, and resolution of nonconforming items and conditions shall be as specified in SOP-01-8.3.1, Nonconformance Reporting.

4.1 0 Handling, Storage, Packaging, Preservation, and Delivery

4.1 0.1 Controls for handling, storage, packaging, preservation, and delivery of items are identified in SOP-01-7.5.3, Handling, Storage, Packaging, Protection, and Delivery of Items.

4.10.2 Samples specified on the purchase order to be returned to the client shall be prepared and packaged as specified on the purchase order. Each package shall be marked legibly and indelibly with the purchase ordedrelease number and line item number(s) relevant to the package.



Dispose jai by end of day on date printed



4.1 1 Quality Assurance Records

4.1 1 .I Quality assurance records shall furnish documentary evidence that items or activities meet specified quality requirements. Documents that ensure this evidence include TAP-01-0407-014, Inventory of Case File Purges, and SOP-01- 4.2.4, Storage and Maintenance of Qualify Records. These documents and this QPP ensure that QA records shall be legible, identifiable, retrievable, and maintained in dual storage.

4.1 1.2 Records shall be traceable to associated items and activities and shall accurately reflect the work accomplished or information required.

4.11.3 Documents shall be considered valid records only if stamped, initialed or signed and dated by authorized personnel or otherwise authenticated.

4.11.4 Records of test analyses performed by the Department of Analytical and Environmental Chemistry are classified as nonpermanent and shall be retained for a minimum of five years. Nonpermanent records are those required to show evidence that an activity was performed in accordance with the applicable requirements, but need not be retained for the life of the item. Based on the use of the final data, the client shall be responsible for determining and implementing permanent storage requirements.

4.1 1.5 In order to satisfy duplicate storage requirements, one copy of the QA record shall maintained by the Project Manager in Building 70 and a separate copy shall be maintained in the Division Quality Assurance Archives in Building 201. Storage requirements shall be as stated in SOP-01-4.2.4, Storage and Maintenance of Quality Records, to ensure protection against the risk of damage or destruction.

4.12 10 CFR, Part 21

4.12.1 SwRl procurement documents shall include requirements for reporting and approving disposition of supplier nonconformances and, when required, compliance to 10 CFR, Part 21.

4.12.2 The Manager of Institute Quality Assurance or Director of Institute Quality Systems shall determine if a nonconforming condition is reportable under 10 CFR, Part 21, and initiate reporting and condition in accordance with the SwRl Operating Policies and Procedures (OPP). Safety hazards or defects that could create a substantial safety hazard shall be reported. Substantial safety hazard means a loss of safety function to the extent that there is a major reduction in the degree of protection provided to public health and safety.

4.13 Certified Test Report

The Project Manager, Division 01 QA Manager, and IQS Managemet as complying with all contractual requirements shall certify test reports. The certified test report shall reference the purchase orderhelease number, the test methods performed, and the purchase orderhelease line item number.



Dispose of by end of day on date prinlec



4.14 Valid Documents List

The Department of Analytical and Environmental Chemistry task order shall specify all applicable documents and appropriate document revision level for each document. The task order shall then serve as the Valid Documents List (VDL) for each individual project.

5.0 HISTORY OF REVISIONS

Versions 0 through 3 of this plan are maintained on record in Division 01 Quality Assurance.

Title of document changed from the Standard Project Quality Plan SPQP-CH/AN to Quality Project Pian, QPP- 015 Extensive revision to comply with Project Quality Plan PQP-Nuclear, Nuclear Services, which replaces SwRl NQAPM, Nuclear Quality Assurance Program Manual.

Revised 4.1 .I to include designated Division 01 QA staff to conduct pertinent nuclear training sessions to the SwRl Program Quality Plan (PQP-Nuclear), Nuclear Services Revised step 4.2.4 to include Division QA as an entity along with IQS, to maintain documented evidence of qualifications.

Revised 4.1 3 to include "Division 01 QA Manager" for the minimum approval signatures for test procedures for nuclear utility final test reports and to replace "Institute Quality Assurance" with "IQS Management"



PERSONNEL SIGNATURE SHEET FOR PLANS

t have read, and understand the document listed below. By affixing my signature below, I am aware that I am responsible for abiding by and following the requirements identified in the plan specified below. If I become aware of any deviations from this document, I will inform my supervisor.

DOC Number, Title, and (Rev NoNear):

QPP-015, Performance of Chemical Analyses for Commercial Nuclear Power Plants within the Department of Analytical & Environmental Chemistry (Rev 6IJuly 06)

Supervisor'slManager's Signatures The Personnel whose signatures appear above have been trained and certified in the contents of the document identified above

Printed Name Signature Date Tel EXtWISiQil

FRM-131 (Rev 3IJuly 06)

~~/~~~~~~~

010029 Southwest Research Institute

PERSONNEL SIGNATURE SHEET FOR PLANS

I have read, and understand the document listed below. By affixing my signature below, I am aware that I am responsible for abiding by and following the requirements identified in the plan specified below. I f I become aware of any deviations from this document, I will inform my supervisor.

Doc Number, Title, QPP-015, Performance of Chemical Analyses for Commercial Nulcar Power Plants and (Rev Noh‘ear): within the Dept of Analytical and Environmental Chemistry (Rev 6IJuly 06)

Printed Name Tel Extension

3a4 3-

Su pervisor’slklanager’s Signatures The Personnel whose signatures appear above have been trained and certified in the contents of the document identified obave

Printed Name Signature Date Tel Extension

FRM-131 (Rev 3IJtily 06)


PERSONNEL SIGNATURE SHEET FOR PLANS 010030

I have read, and understand the document listed below. By affixing my signature below, I am aware that I am responsible for ablding by and following the requirements identified in the plan specified below. If I become aware of any deviations from this document, I will Inform my supervisor.

Doc Number, Title, QPP-O? 5, Performance of Chemical Analyses for Commercial Nulcar Power Plants and (Rev NoNear): within the Dept of Analytical and Environmental Chemistry (Rev 6/July 06)

Supervisor’slblanager’s Signatures rhe Personnel ?hose signatures appeal- above have been trained and certified in t he contents of the document identified above

FRM-131 (Rev 3IJuly 06)


PERSONNEL SIGNATURE SHEET FOR PLANS 010031 I have read, and understand the document listed below By affixing my signature below, I am aware that I am responsible for abiding by and following the requirements identified in the plan specified below. If I become aware of any deviations from this document, I will infom my supervisor.

DOC Number. Tile, and (Rev NoNear):

QPP-015, Performance of Chemical Analyses for Commercial Nuclear Power Plants within the Department of Analytical & Environmental Chemistry (Rev 6iJuly 06)

Printed Name Signature Qh Date

/ L ” - - 3 - - o t

Supervisor‘slManager‘s Signatures The Personnel whose signatures appear above have been trained and certified in the contents of the document identified above.

Tel Extomion

FRM-131 [Rev 3/July 06)

Southwest Research Institute T4f

PERSONNEL SIGNATURE SHEET FOR PLANS Oq0032

I have read, and understand the document listed below. By affixing my signature below, I am aware that am responsible for abiding by and following the requirements identifed in the plan specified below. If I become aware of any deviations from this document, I will inform my supervisor.

Roc Number, Title, QPP-015, Performance of Chemical Analyses for Commercial Nukar Power Plants and (Rev NoNear): within the Dept of Analytical and Environmental Chemistry (Rev 6IJuly 06)

Signature

Supervisor'slManager's Signatures The Personnel whase signatures appear above have been trained and certified in the contents of the tjocumonl rdontiftcd dbove

Tel Extension

;z/c?L

F RM-131 (Rev SIJuly 06)


PERSONNEL SIGNATURE SHEET FOR PLANS 010033 f have read, and understand the document listed below. By affixing my signature below, I am aware that I am responsible for abiding by and following the requirements identified in the plan specified below. If I become aware of any deviations from this document, I will inform my supervisor.

Doc Number. Tltle, QPP-015, Performance of Chemical Analyses for Commercial Nuclear Power Plants and (Rev NoPYear). within the Department of Analytical & Environmental Chemistry (Rev 6IJuly 06)

Supervisor'slManager's Signatures The Personnel whose signatures appear above have been trained and certified in the contents of the document identified above

Name Signaturo Date Tel Extension

FRM-131 (Rev 3lJuly 06)

010034




Chain of Custody/Login Paperwork

SAMPLE LlST/CHAlN OF CUSTODY Southwest Research Institute

Chemistry and Chemical Engineering Division 6220 Culebra Road

San Antonio, Texas 78238-5166 Client Purchase Order/Other ID Site/Zone ID

Requested Turnaround: 2 Weeks

' 3 Weeks Other: Y

z ; 2 2 t a c t Dmm&hn

Date L M p p 0

Time SwRl Project#:

z ic I .OmZ d.242

Analyses equeste

Preservation a = HCI to pH <2 b = HNO3 to pH <2 c = H2SO.q to pH <2 d = NaOH to pH >I2

1 Project #06002.01.242 Case:M. Roberts VTSR :04/10/2007 Sample(s) Received Intact Temperature: 3 O0C/#O27

ntlsignature) I I

I Relinauished bv (F Sample Types: D - Duplicate ER - Equipment Rinsate ES - Environmental Sample FB - Field Blank FD - Field Duplicate MS - Matrix Spike MSD - Matrix Spike Dup TB -Trip Blank

Matrix Types: A - Air B - Biota

E - EmissionlStack L - Liquid P - Product Sd - Solid S - Soil SED -Sediment T - Tissue W - Water

D - Dust

~. &Ad z%Z&kz&P&

Received by (PrintlSignature) / Time (Signature)

Time Relinquished by (PrintlSignature)

Time 1 Time

Time

Received by (PrintlSignature)

Therm #:027

Date

WP -Wipe Temp:

Relinquished by (PrfntlSignature) Date Time Samples Disposed by:

Div 01 COC FRM-010 (Rev I/Nov 05) Page of

SAMPLE LlSTKHAlN OF CUSTODY Southwest Research Institute

Chemistry and Chemical Engineering Division 6220 Culebra Road

San Antonio, Texas 78238-5166 Client Purchase Order/Other ID Site/Zone ID

Requested Turnaround: )( 2 Weeks . 3 Weeks

Other: Y

SwRl Contact

bamnmfl

I I Date Time SwRl Project#:

243.01c70oz .D 1,242

Date Time Samples Disposed by:

c c al ._ s - -

al

I- % 'C

R c

2

l- I -

REMARKS Preservation

d = NaOH to pH >I2 e = Cool (4"C*2"C) f = Other (specify)

Project #06002.01.242 Case:M. Roberts VTSR:04/10/2Oo7 Sample(s) Received Intact Temperature: 3.O0C/#O27

I Matrix Types: A - Air B - Biota

E - Emission/Stack L - Liquid P - Product Sd - Solid S - Soil SED -Sediment T - Tissue W - Water

D - Dust

I I I I I - Relinquished by (PrintEignature) Sample Types: D - Duplicate ER - Equipment Rinsate ES - Environmental Sample FB - Field Blank FD - Field Duplicate MS - Matrix Spike MSD - Matrix Spike Dup TB - Trip Blank

Date I Time I Received by SwRl Lab: + Time Relinquished by (PrinffSignature)

Time Date Received by (PrintlSignature) Sam les Dis osed:

Time 42-7 Therm #:

Relinquished by (PrinffSignature)

Div 01 COC FRM-010 (Rev I/Nov 05) Page of

010037 Southwest Research Institute Project: 06002.01-242

Case: M. Roberts / SDG. Airbill: HAND DELIVERED

Sample Receipt: 30576 Not Present or Damaged

2. Chain of Custody L Present

1. Custody Seal

3. Sample Tags Not Present Not on COC

4. SMO Forms Not Present

Traffic Report Sample Custodian Signature:

Sample Tag Numbers

-~~ -

- - 294950 Intact Am-- ~- 294951 YES Intact

04/10/07 14 4 4 S W R m C &NpCS-C5 None ~- - 294952 YES Intact 04/10/07 14 45'00 1 SWRl COC A-!@GS-C6 -- - Nqn-e -~ 294953 YES Intact 04/1(3/07 14 45:OO 1 SWRl COC C-NpCS-C1 - ~ - - ~ None ~ - - ~ _ _ _ _ 294954 - YES Intact 04/10/07 1 4 4 a O I SWRl COC C-NpCS-C2 ~ - _ _ _ _ - None ~

294955 YES -- Intact ~

04/10/07 14 45:OO I SWRl COC C-NpCS-C3 None- -- 294956- -- YES Intact

04LI 0107 1 l 4 5 00 SWRl COC ~C-NpCS-CS - -~ None 294958 YES Intact 04/10/07 I 14 45 00 SWRl COC C-NDCS-C6 None 294959 YES Intact

04/10/07-_ 14.45.00SWRl COC C-NpCS-C4 None---- - 294957 YES Intact

Printed: 10 Apr 2007 15:07:47 page 1 of 1 ver (2/24/200

010038 Southwest Research Institute

LOG-IN CHECKLIST Sample Receipt Report No.: 30576

FRM-012 (Rev 4May 05)

010039

EPA Sample # Sample Tag # Assigned Lab #

SAMPLE LOG-IN SHEET

- -

Page 1 of 1 Log-in Date 04/10/2007

-- - ~~

Lab Name

Received G(Print Name)

~


SAS Numbe

Remarks ./̂ Condition of Sample

Shipment, etc

M. Roberts - ~- ~

Remarks 06002.01.242

I

2

3

4

5

6

7

8

9

IO

1 1

12

Custody Seal(s) Intact Prese Intact/Broken

Intact

Custody Seal Nos Intact 129495 0

+-- 294951

294952

Intact -Absent*

Present-

Chain-of Custody Records

Traffic Reports or Packing Lists Airbill

Intact

Intact A-NpCS-C6 None 294953

C-NpCS-C1 None 294954

IC-NpCS-C2 INOne 294955

1 -

~ -~

294956 t --- C-NpCS-C3 INone

Intact Airbill No HAND DELIVERED

Intact

Intact Present- Sample Tags -- - - ~

C-NpCS-C4 None

~~~~ - - - C-NpCS -C5 None

Intact Sample Tag Numbers

Intact Custody

-/Broken*/ Leaking

3.0C

@NO*

Sample Condition Intact ~- ~~

C-NpCS-C6 None 294959

Cooler Temperature

Does Information on custody records, traffic reports, and sample tags agree?

Date Received at Lab 04/10/2007

14: 45: 00 Time Received

Sample Transfer

Area # iz2-l /z-

FORM DC-1 OLM04.2

010040




Copies of Login Book

Sample Login Book Apr 10,2007

System ID I Customer ample ID 29492 1 1 M6-0714-OUT

010041

Matrix PUF

SwRl Login Area Division 1

294922

294923

294924

PUF

PUF M6-0772-IN PUF

- M6-0758-IN

M6-0758-OUT -

294925 I M6-0772-OUT PUF

System ID 294928

I 294929 I 1 1

Customer Sample ID Matrix

Sample Receipt: 30576 Project: 06002.01.242 Client: Div. 20 VTSR Time: 14:45:00 Manager: DAMMANN, MIKE I VTSR Date: Apr 10, 2007

System ID 294948

Customer Sample ID Matrix A-NpCS-C 1 Water

294949

294950

Water

A-N pCS-C3 Water -

A-NPCS-C~

Water 294951

294952

A-NpCS-C4

A-NPCS-C~

I 294955 I C-NpCS-C2 1 Water I

294953

294954

I 294956 I C-NpCS-C3 I Water I

Water C-NpCS-C1 Water

___ A- N PC S-C6

I 294957 ] C-NpCS-C4 1 Water I I 294958 I C-NpCS-C5 1 Water I I 294959 1 C-NDCS-C6 I Water I

Page Number: 61 33 (section 2 of 3) Version (5/25/2007) Printed: Jun 4 2007 12:12PM

010042




RAW DATA

7-- -1

~-

,_______ mglL 0 05

PBW-D16H1 P-1782 mglL PBW-D16H 1 1 Pd3404

~-

--

~ _ _ -

01,-

rl 0.005 0.05

0.005 0.02

0.005 0.005 0.01 0.05

0.005 0.005 0.005 0.005 0.05

0.005 0.05

0.005 0.005 0.005 0.02 0.01 0.05 0.02 0.05

0.005 0.01 0.01

0.005 0.015 0.005 0.01

0.125 0.005 0.01

0.005 0.005 0.005 0.005 0.05

0.005 0.02

0.005 0.005 0.01

mglL sigwt Dilution Calc RL 0.0153 0.2018 0.0344 0.0324

0.0004 0.0355 0.074

0.0033 0.0173

-0.0087 0.002 0.437

0.0245 0.1477

0.0025

-0.0008

-0.0007

-0.001 3 -0.053 0.0489 0.1974 0.0777 0.0979

-0.0044 -0.0029 0.0092 0.0012

-0.0605 -0.003 0.0222 1.0663

-0.0101 0.0478 -0.001 0.0009 0.0006 0.0492

1.92733 2.00785 0.00268 2.03938 0.05031

-0.00043

0.0153 0.202

0.0344 0.0324

0.0004 0.0355 0.074

0.0033 0.0173

-0.0087 0.002 0.437

0.0245 0.148

0.0025

-0.0008

-0.0007

-0.0013 -0.053 0.0489 0.197

0.0777 0.0979

-0.0044 -0.0029 0.0092 0.0012

-0.0605 -0.003 0.0222

1.07 -0.0101 0.0478 -0.001 0.0009 0.0006 0.0492

1.93 2.01

0.00268 2.04

0.0503

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I

0.05 0.5

0.05 0.2

0.05 0.05 0.1 0.5

0.05 0.05 0.05 0.05 0.5

0.05 0.5

0.05 0.05 0.05 0.2 0.1 0.5 0.2 0.5

0.05 0.1 0.1

0.05 0.15 0.05 0.1

1.25 0.05 0.1

0.05 0.05 0.05

0.005 0.05

0.005 0.02

0.005 0.005 0.01

uglml Date 0.00153 04/16/07 0.02018 04/16/07 0.00344 04/16/07 0.00324 0411 6/07

0.00004 04/16/07 0.00355 04/16/07 0.0074 04/16/07

0.00033 04/16/07 0.00173 04/16/07

0.0002 04/16/07 0.0437 04/16/07

0.00245 04/16/07 0.01477 04/16/07

0.00025 04/16/07

-0.00008 04/16/07

-0.00087 04/16/07

-0.00007 04/16/07

-0.00013 04/16/07 -0.0053 04/16/07 0.00489 04/16/07 0,01974 04/16/07 0.00777 0411 6/07 0.00979 04/16/07

-0.00044 04/16/07 -0.00029 04/16/07 0.00092 04/16/07 0.00012 04/16/07

-0.00605 04/16/07 -0.0003 04/16/07 0.00222 04/16/07 0.10663 0411 6/07

0.00478 04/16/07

0.00009 04/16/07 0.00006 04/16/07 0.0492 04/16/07

1.92733 0411 6/07 2.00785 04/16/07 0.00268 04/16/07 2.03938 04/16/07 0.05031 04/16/07

-0.00101 04/16/07

-0.0001 04/16/07

-0.00043 04/16/07

Time 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:23 18:28 18:28 18:28 18:28 18:28 18:28 18:28

div20-07041 O(6)icp

e e

Div 20 0 to#070410-6 0 06002 01.242 4

I 97 8%' 0 !

I I

_ _

105 3%

LCSW-D16H1 SI2881 mglL 0 05

LCSW-D16H1 Se196- 101 0% LCSW-D16H1 Pb220

I I I

I 104 ___c 5% -1 LCSW-D16H1 TI1908 malL I

ILCSW-Dl6H1 iMo2020 1 0.005001U I I I I _ _ Ot ~ ' 97 8%' 0 !

L-1 mglL 0005 962% 0' mglL 001 101 0% mglL 0 01 I

I I

I 104 ___c 5% -1 malL I

rl 0.05

0.005 0.005 0.005 0.005 0.05

0.005 0.05

0.005 0.005 0.005 0.02 0.01 0.05 0.02 0.05

0.005 0.01 0.01

0.005 0.025 0.005 0.01

0.125 0.005 0.01

0.005 0.005 0.005 0.005 0.05

0.005 0.02

0.005 0.005 0.01 0.05

0.005 0.005 0.005 0.005 0.05

0.005

mglL sigwt Dilution Calc RL 19.68146 19.7 0.04968 0.0497 0.50288 0.503 0.19437 0.194 0.25048 0.25 1.17832 1.18 0.00007 0.00007

19.80119 19.8 0.50262 0.503 0.00037 0.00037 0.48868 0.489 0.00189 0.00189 0.00089 0.00089 4.21288 4.21 0.49267 0.493 0.01783 0.0178 0.4809 0.481

0.00009 0.00009 0.00038 0.00038

-0.02314 -0.0231 -0.00027 -0.00027

2.02038 2.02

2.08929 2.09 0.01308 0.0131 0.49775 0.498 0.00093 0.00093

0.4971 1 0.497 -0.0004 -0.0004

-0.0008 -0.0008 -0.0065 -0.0065 -0.0045 -0.0045 0.0122 0.0122 0.4406 0.441 0.1932 0.193

0 0 0.0048 0.0048 0.1924 0.192

-0.0013 -0.0013 -0.0033 -0.0033 -0.0195 -0.0195 -0.007 -0.007 0.1165 0.117

-0.0123 -0.0123

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

0.05 0.005 0.005 0.005 0.005 0.05

0.005 0.05

0.005 0.005 0.005 0.02 0.01 0.05 0.02 0.05

0.005 0.01 0.01

0.005 0.025 0.005 0.01

0.125 0.005 0.01

0.005 0.005 0.005 0.05 0.5

0.05 0.2

0.05 0.05 0.1 0.5

0.05 0.05 0.05 0.05 0.5

0.05

uglrr Date 19.681 46 0411 6/07 0.04968 04/16/07 0.50288 04/16/07 0.19437 0411 6/07 0.25048 0411 6/07 1.17832 04/16/07 0.00007 04/16/07

19.801 19 04/16/07 0.50262 04/16/07 0.00037 0411 6/07 0.48868 04/16/07 0.00189 04/16/07 0.00089 04/16/07 4.21288 04/16/07 0.49267 0411 6/07 0.01783 04/16/07 0.4809 04/16/07

2.02038 04/16/07 0.00009 04/16/07 0.00038 0411 6/07

-0.02314 04/16/07 -0.00027 04/16/07 2.08929 04/16/07 0.01308 04/16/07 0.49775 04/16/07 0.00093 04/16/07

0.4971 1 04/16/07 -0.0004 04/16/07

-0.0008 0411 6/07 -0.00065 04/16/07 -0.00045 04/16/07 0.00122 04/16/07 0.04406 04/16/07 0.01932 04/16/07

0 04/16/07 0.00048 04/16/07 0,01924 04/16/07

-0.0001 3 04/16/07 -0.00033 04/16/07 -0.001 95 04/16/07 -0.0007 04/16/07 0.01 165 04/16/07

-0.00123 04/16/07

Time 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:28 18:33 18:33 8:33 8:33 8:33 8:33 8:33 8:33 8:33

18:33 18:33 18:33 18:33 18:33

m - Div 20 0 to#070410-6 0 06002.01.242 w d

n

rl 0.05

0.005 0.005 0.005 0.02 0.01 0.05 0.02 0.05

0.005 0.01 0.01

0.005 0.01 5 0.005 0.01

0.125 0.005 0.01

0.005 0.005 0.005 0.005 0.05

0.005 0.02

0.005 0.005 0.01 0.05

0.005 0.005 0.005 0.005 0.05

0.005 0.05

0.005 0.005 0.005 0.02 0.01 0.05

mglL sigwt 0.2616 0.262

-0.0013 -0.0013 -0.008 -0.008

-0.0069 -0.0069 -0.0333 -0.0333

-0.03 -0.03 9.5068 9.51 0.0249 0.0249 0.1875 0.188 0.0014 0.0014 0.0188 0.0188

0.0004 0.0004 -0.0008 -0.0008

-0.0441 -0.0441 -0.0059 -0.0059 -0.0022 -0.0022 -0.1373 -0.137 -0.0133 -0.0133 0.0138 0.0138

0.0062 0.0062 -0.0161 -0.0161 -0.0022 -0.0022 0.0413 0.0413

-0.0087 -0.0087 0.4402 0.44 0.1947 0.195

0 0 -0.0047 -0.0047 0.1398 0.14 -0.001 -0.001 0.0064 0.0064

-0.0161 -0.0161 -0.0012 -0.0012 0.1416 0.142

-0.0027 -0.0027 0.2842 0.284

-0.0025 -0.0025

-0.0004 -0.0004 -0.0031 -0.0031 0.0019 0.0019 0.1166 0.117

-0.0296 -0.0296 9.5343 9.53

ilution Calc RL 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

0.5 0.05 0.05 0.05 0.2 0.1 0.5 0.2 0.5

0.05 0.1 0.1

0.05 0.15 0.05 0.1

1.25 0.05 0.1

0.05 0.05 0.05 0.05 0.5

0.05 0.2

0.05 0.05 0.1 0.5

0.05 0.05 0.05 0.05

0.5 0.05

0.5 0.05 0.05 0.05 0.2 0.1 0.5

uglml Date 0.02616 04/16/07

-0.00013 04/16/07 -0.0008 04/16/07

-0.00069 0411 6/07 -0.00333 04/16/07

-0.003 04/16/07 0.95068 04/16/07 0.00249 04/16/07 0.01875 04/16/07 0.00014 04/16/07 0.00188 04/16/07

0.00004 04/16/07 -0.00008 04/16/07

-0.00441 04/16/07 -0.00059 04/16/07 -0.00022 04/16/07 -0.01 373 04/16/07 -0.001 33 04/16/07 0.00138 04/16/07

0.00062 04/16/07 -0.00025 0411 6/07

-0.00161 04/16/07 -0.00022 04/16/07 0.00413 04/16/07

0.04402 04/16/07 0.01947 04/16/07

0 04/16/07

0.01 398 0411 6/07

0.00064 04/16/07

-0.00087 04/16/07

-0.00047 04/16/07

-0.0001 04/16/07

-0.00161 04/16/07 -0.00012 04/16/07 0.01 41 6 0411 6/07

0.02842 04/16/07 -0.00027 04/16/07

-0.00004 04/16/07 -0.00031 04/16/07 0.00019 04/16/07 0.01 166 04/16/07

0.95343 04/16/07 -0.00296 04/16/07

Time 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:33 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37

<D e

Div 20 0 t0#070410-6 0 06002.01.242 rl

294954D 294954D

294954D- 294954D 2949548 Ag3280 2949548 A13082 2949548 As1 890 2949548 B 2496 #DIV/OI 2949548 2949548 2949548 2949548 294954s 29495s- 2949548- 2949548 2949548 Fe27 14

294954s 0 5 2949548

mglL 970%

1002% O!

980%i 20( 1 988%! O ! mg/L 1 0.051 1 100 -p 8%1

97 0%

1170%

1

101-2+- zi

2949548 0.2 294954s 0 1

0 2, !

2949548 103 5%

2949548 2949548 -

div20-07041 O(6)icp

rl 0.02 0.05

0.005 0.01 0.01

0.005 0.015 0.005 0.01

0.125 0.005 0.01

0.005 0.005 0.005 0.005 0.05

0.005 0.02

0.005 0.005 0.01 0.05

0.005 0.005 0.005 0.005 0.05

0.005 0.05

0.005 0.005 0.005 0.02 0.01 0.05 0.02 0.05

0.005 0.01 0.01

0.005 0.025

mglL sigwt Dilution Calc RL 0.157 0.157

0.2278 0.228 0.0004 0.0004

0.0294 0.0294 0.0005 0.0005

-0.0129 -0.0129

-0.0487 -0.0487 -0.0042 -0.0042 0.0234 0.0234 0.2175 0.218

0.0406 0.0406

0.0046 0.0046

0.4962 0.496 19.4264 19.4 20.1299 20.1 0.4387 0.439 20.579 20.6 0.5014 0.501 0.0798 0.0798

196.2759 196 0.4938 0.494 5.0376 5.04

1.944 1.94 2.5303 2.53

11.6796 11.7 0.0076 0.0076

198.1316 198 5.0118 5.01

0 0 4.9012 4.9

-0.0243 -0.0243 0.0397 0.0397

51.2072 51.2 4.9627 4.96 0.4278 0.428 4.8742 4.87

20.6814 20.7 0.0156 0.0156 0.0041 0.0041

-0.0126 -0.0126

-0.0013 -0.0013

-0.0071 -0.0071

-0.2177 -0.218

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

0.2 0.5

0.05 0.1 0.1

0.05 0.15 0.05 0.1

1.25 0.05 0.1

0.05 0.05 0.05 0.05 0.5

0.05 0.2

0.05 0.05 0.1 0.5

0.05 0.05 0.05 0.05 0.5

0.05 0.5

0.05 0.05 0.05 0.2 0.1 0.5 0.2 0.5

0.05 0.1 0.1

0.05 0.25

uglml Date 0.0157 04/16/07

0.00004 04/16/07

0.00294 04/16/07 0.00005 0411 6/07

0.02278 04/16/07

-0.00129 04/16/07

-0.00487 04/16/07 -0.00042 04/16/07 0.00234 04/16/07 0.02175 04116/07

0.00406 04/16/07

0.00046 04/16/07

0.04962 04/16/07 1.94264 04/16/07 2.01299 04/16/07 0.04387 04/16/07 2.0579 04/16/07

0.05014 04/16/07 0.00798 04/16/07

19.62759 0411 6/07 0.04938 04/16/07 0.50376 0411 6/07 0.1944 04/16/07

0.25303 04/16/07 1.16796 04/16/07 0.00076 04/16/07

19.81 316 0411 6/07 0.501 18 0411 6/07

0 04/16/07 0.49012 04/16/07

0.00397 04/16/07 5.12072 0411 6/07 0.49627 04116t07 0.04278 04/16/07 0.48742 04/16/07 2.06814 04/16/07 0.00156 04/16/07 0.00041 04/16/07

-0.00126 04/16/07

-0.00013 04/16/07

-0.00071 04/16/07

-0.00243 04/16/07

-0.02177 04/16/07

Time 18:37 18:37 18:37 18:37 18:37 18:37 18~37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:37 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42

Div 20 0 to#070410-6 a

0 06002.01.242

294954s 2949548 #DIV/O!

99.4% I 2949548 2949548 Zr3496 0.0500 U #DIv/o! mg/L 1: 1 #DIV/O! 294955 lAg3280 0.0500 U imglL 1 0.051 I l zn?osi ;~~ -T---TiT imJ

i ________-

~

I 0 5

i

2 9 4 9 5 5 294255

mglL -__

_- 294955 294955 mglL 0 5 294955 -

294955 - 294955 -- . mg/L 0 05 -

I i-

294955 ' A - 0051 I +I- 294955

~

-~

294955 -- 0 0500 U Se196 0 100 u

______________________

294955 294955

294955

rl 0.005 0.01

0.125 0.005 0.01

0.005 0.005 0.005 0.005 0.05

0.005 0.02

0.005 0.005 0.01 0.05

0.005 0.005 0.005 0.005 0.05

0.005 0.05

0.005 0.005 0.005 0.02 0.01 0.05 0.02 0.05

0.005 0.01 0.01

0.005 0.015 0.005 0.01

0.125 0.005 0.01

0.005 0.005

mglL sigwt Dilution Calc RL -0.0032 -0.0032 20.9903 21

0.516 0.516 4.9674 4.97 0.0727 0.0727

-0.0048 -0.0048 4.9724 4.97

-0.0099 -0.0099 0.0043 0.0043 0.081 8 0.081 8

-0.0191 -0.0191 0.4738 0.474 0.1861 0.186

0 0 -0.0148 -0.0148

0.17 0.17 0.0018 0.0018 0.0116 0.0116

-0.0166 -0.0166 -0.003 -0.003 0.3792 0.379 0.0097 0.0097 0.4351 0.435 0.0003 0.0003

-0.0056 -0.0056 -0.0033 -0.0033 -0.0362 -0.0362 0.0016 0.0016

10.5809 10.6 0.0964 0.0964 0.2633 0.263

-0.0035 -0.0035 -0.0064 -0.0064

0.002 0.002 0.0009 0.0009

-0.0634 -0.0634 -0.0046 -0.0046 -0.0125 -0.0125 0.4673 0.467

0.0336 0.0336

0.0124 0.0124

-0.0137 -0.0137

-0.0018 -0.0018

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

0.05 0.1

1.25 0.05 0.1

0.05 0.05 0.05 0.05 0.5

0.05 0.2

0.05 0.05 0.1 0.5

0.05 0.05 0.05 0.05 0.5

0.05 0.5

0.05 0.05 0.05 0.2 0.1 0.5 0.2 0.5

0.05 0.1 0.1

0.05 0.15 0.05 0.1

1.25 0.05 0.1

0.05 0.05

uglrnl Date -0.00032 04/16/07 2.09903 04/16/07 0.0516 04/16/07

0.49674 04/16/07 0.00727 04/16/07

0.49724 0411 6/07

0.00043 04/16/07 0.00818 04/16/07

0.04738 04/16/07 0.01861 04/16/07

0 04/16/07

0.017 04/16/07 0.00018 04/16/07 0.001 16 04/16/07

-0.00048 04/16/07

-0.00099 04/16/07

-0.001 91 0411 6/07

-0.00148 04/16/07

-0.001 66 0411 6/07 -0.0003 04/16/07 0.03792 04/16/07 0.00097 04/16/07 0.04351 04/16/07 0.00003 0411 6/07

-0.00056 04/16/07 -0.00033 04/16/07 -0.00362 04/16/07 0.00016 04/16/07 1.05809 0411 6/07 0.00964 04/16/07 0.02633 04/16/07

-0.00035 04/16/07 -0.00064 04/16/07

0.0002 04/16/07 0.00009 04/16/07

-0.00634 0411 6/07 -0.00046 04/16/07 -0.00125 04/16/07 0.04673 04/16/07

0.00336 04/16/07

0.00124 04/16/07

-0.00137 04/16/07

-0.00018 04/16/07

Time 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:42 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47 18:47

Q, e

Div 20 0 to#070410-6 0 06002.01.242 d

294956 294956

-

294956 294956 mglL 294956 - mglL 005 ~- 294956 294956

294956 294956

294956 --

2 9 4 9 5 6 - - _ _ - 0.200 u

_ -1- ~ - 0 0500 U ImgiL I 0051

294956 Sn I 899 294956 294956 Th2837 0 150 U- 294956 TI3349 -~ 294956 TI1 908 294956 294956 294956 294956 294956

0 1

- - mglL 0 05 ,- ~

294956-- Zr3496 005OOlU- mg/L 0 05 --

294957 /A93280 1 005OOiU - - ~~

294957 A13082 1 0 - U - -~ --

0 2

mglL I 0 05

div20-07041 O(6)icp

rl 0.005 0.005 0.05

0.005 0.02

0.005 0.005 0.01 0.05

0.005 0.005 0.005 0.005

0.05 0.005

0.05 0.005 0.005 0.005 0.02 0.01 0.05 0.02 0.05

0.005 0.01 0.01

0.005 0.015 0.005 0.01

0.125 0.005 0.01

0.005 0.005 0.005 0.005 0.05

0.005 0.02

0.005 0.005

mglL sigwt Dilution Calc RL -0.01 -0.01

0.0033 0.0033 0.0544 0.0544

-0.0002 -0.0002 0.4541 0.454 0.2121 0.212

0 0 0.0548 0.0548 0.1325 0.133 0.0015 0.0015 0.0096 0.0096

-0.021 1 -0.021 1 -0.0061 -0.0061 0.0006 0.0006 0.0049 0.0049 0.3596 0.36

-0.0007 -0.0007 -0.0039 -0.0039 -0.0052 -0.0052 -0.0626 -0.0626 -0.0084 -0,0084 10.1912 10.2 0.0342 0.0342 0.243 0.243

0.0338 0.0338 0.0077 0.0077 0.0006 0.0006

-0.004 -0.004

-0.0803 -0.0803 -0.0048 -0.0048 -0.0093 -0.0093 0.2222 0.222

-0.0077 -0.0077 0.0328 0.0328

0.01 18 0.01 18 -0.0024 -0.0024

-0.01 18 -0.01 18 -0.003 -0.003 0.1115 0.112 0.0181 0.0181 0.4809 0.481

0.25 0.25 0.0001 0.0001

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

0.05 0.05 0.5

0.05 0.2

0.05 0.05 0.1 0.5

0.05 0.05 0.05 0.05

0.5 0.05

0.5 0.05 0.05 0.05 0.2 0.1 0.5 0.2 0.5

0.05 0.1 0.1

0.05 0.15 0.05 0.1

1.25 0.05 0.1

0.05 0.05 0.05 0.05 0.5

0.05 0.2

0.05 0.05

uglml Date -0.001 04/16/07

0.00033 04/16/07 0.00544 04/16/07

0.04541 04/16/07 0.02121 04/16/07

0 04/16/07 0.00548 04/16/07 0.01325 04/16/07 0.00015 04/16/07 0.00096 04/16/07

-0.00002 04/16/07

-0.0021 1 04/16/07 -0.00061 04/16/07 0.00006 04/16/07 0.00049 04/16/07 0.03596 04/16/07

-0.00007 04/16/07 -0.00039 04/16/07 -0.00052 04/16/07 -0.00626 04/16/07 -0.00084 04/16/07 1.01912 04/16/07 0.00342 04/16/07 0.0243 04/16/07

0.00338 04/16/07 0.00077 04/16/07 0.00006 04/16/07

-0.0004 04/16/07

-0.00803 04/16/07 -0.00048 04/16/07 -0.00093 04/16/07 0.02222 04/16/07

0.00328 04/16/07

0.001 18 04/16/07

-0.00077 04/16/07

-0.00024 04/16/07

-0.001 18 04/16/07 -0.0003 04/16/07 0.01115 04/16/07 0.00181 04/16/07 0.04809 04/16/07

0.025 04/16/07 0.00001 04/16/07

Time 18:47 1852 1852 1852 1852 1852 1852 1852 1852 1852 1852 1852 1852 1852 1852 1852 1852 1852 1852 1852 1852 1852 1852 1852 18: 52 18:52 1852 18:52 1852 1852 18:52 1852 1852 1852 1852 1852 1852 1857 1857 1857 18:57 1857 1857

cn d' 0

Div 20 0 to#070410-6 4 06002.01.242 0

..

- 294957

rl 0.01 0.05

0.005 0.005 0.005 0.005 0.05

0.005 0.05

0.005 0.005 0.005 0.02 0.01 0.05 0.02 0.05

0.005 0.01 0.01

0.005 0.015 0.005 0.01

0.125 0.005 0.01

0.005 0.005 0.005 0.005 0.05

0.005 0.02

0.005 0.005 0.01 0.05

0.005 0.005 0.005 0.005 0.05

mglL sigwt Dilution Calc RL -0.0166 -0.0166 0.1512 0.151 0.0007 0.0007 0.013 0.013

-0.0138 -0.0138 -0.005 -0.005

-0.0156 -0.0156 -0.0014 -0.0014 0.3856 0.386 0.0009 0.0009 0.001 5 0.001 5 0.0032 0.0032 0.0874 0.0874

-0.0252 -0.0252 10.955 11 0.0552 0.0552 0.2268 0.227 0.006 0.006

0.0188 0.0188 0.0047 0.0047 0.0004 0.0004

-0.0325 -0.0325 -0.0028 -0.0028 -0.0297 -0.0297 0.2691 0.269

-0.0101 -0.0101 0.0166 0.0166

-0.0015 -0.0015 0.0036 0.0036

-0.0045 -0.0045 -0.0016 -0.0016 0.0421 0.0421 0.0183 0.0183

1.407 1.41 0.891 0.891

0 0 0.0029 0.0029 0.3024 0.302

0 0 0.0078 0.0078

-0.0198 -0.0198 -0.0054 -0.0054 -0,1193 -0.119

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

0.1 0.5

0.05 0.05 0.05 0.05 0.5

0.05 0.5

0.05 0.05 0.05 0.2 0.1 0.5 0.2 0.5

0.05 0.1 0.1

0.05 0.15 0.05 0.1

1.25 0.05 0.1

0.05 0.05 0.05 0.05 0.5

0.05 0.2

0.05 0.05 0.1 0.5

0.05 0.05 0.05 0.05 0.5

uglml Date -0.00166 04/16/07 0.01 51 2 04/16/07 0.00007 04/16/07 0.0013 04/16/07

-0.00138 04/16/07 -0.0005 04/16/07

-0.00156 04/16/07 -0.00014 04/16/07 0.03856 04/16/07 0.00009 04/16/07 0.00015 04/16/07 0.00032 04/16/07 0.00874 0411 6/07

1.0955 04/16/07 0.00552 04/16/07 0.02268 04/16/07 0.0006 04/16/07

0.00188 04/16/07 0.00047 04/16/07 0.00004 04/16/07

-0.00252 04/16/07

-0.00325 0411 6/07 -0.00028 04/16/07 -0.00297 04/16/07 0.02691 04/16/07

0.00166 04/16/07

0.00036 04/16/07

-0.001 01 0411 6/07

-0.00015 04/16/07

-0.00045 04/16/07 -0.00016 04/16/07 0.00421 04/16/07 0.00183 04/16/07 0.1407 0411 6/07 0.0891 04/16/07

0 04/16/07 0.00029 0411 6/07 0.03024 04/16/07

0 04/16/07 0.00078 04/16/07

-0.00198 04/16/07 -0.00054 04/16/07 -0.01 193 04/16/07

Time 18:57 18:57 18:57 18:57 1857 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 18:57 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02

0 an

Div 20 0 to#070410-6 0 06002.01.242 4

A

294958 !Si2881 0 881 1 0 5 I 1 ! 294958 lPb220 t- 0 0500lU 'mglL _ _ r _-- 0051 , --

0 I! 294958 iSe196 0 1001U A- mg/L 294958 Sn 1899 0 100,u ! mg/L 0 1

I , -- I

~ ~- -

- ~ ~ ~ - - - ~ ~ p

294958 Sr4215 0 0500 U mg/L 0 05 294958 Th2837 0 150U- mglL --O 15 294958 Ti3349 00500 U mg/L 0 05

- ~

- - . - 294958 - TI1 908 0 100 u mglL 0 1 294958 U-4090 1 25 U mglL 1 25 - -

294958 ~ ~ V-2924 O X O U mg/L . 0 05 294958 l - - - W 2079 . 0 100 U . mglL 0 1

~ __ ~ -

mg/L 005 294958 _ _ !Y-3710 0 0500 U

294958 jZr3496 0 0500 U I ,mg/L 0 05

294959 - - o 5ooiu 294959 As1 890 0 0500, U mg/L 0 05, _ _ 294959 8-2496 0 200 u mg/L 0 2; I I -I -

- 294959 Be3130 0 0500 - U

294959 ICd2265 0 0500 U - mglL 1 0 05 1

~ I 294958 1Zn2062 0 0500 U mg/L 005, -T----+_ i m g x - k 0 5 ' 1 - 1_

294959 -po;; t 00500/U-- j ~ mg/L 2 051- - / 1

I

I

-7 -

I I 1 -

I 294959 Ba4934 0 0500 U mg/L 0 05

294959 -85236- 0 100 u mglL ! - 0 1 294959 Ca3179 19 6 - ~. ! W L I 0 5

mglL 0 05 - --5

. -- --- __ U La3988 0.0500 294958 Mg2790 0.500 U 294958 Mn2576 0.0500 U 294958 Mo2020 0.0500 U 294958 Ni2316 0.0500 U mglL 294958 P-1782 0.200 u mglL

294958 ~ ~

294958 Pd3404 0.100 u

294958 ISb2068 ~ 0.200~U I I I 294958 .S-l820 I 29.8

rl 0.005 0.05

0.005 0.005 0.005 0.02 0.01 0.05 0.02 0.05

0.005 0.01 0.01

0.005 0.015 0.005 0.01

0.125 0.005 0.01

0.005 0.005 0.005 0.005 0.05

0.005 0.02

0.005 0.005 0.01 0.05

0.005 0.005 0.005 0.005 0.05

0.005 0.05

0.005 0.005 0.005 0.02 0.01

mglL sigw -0.0018 -0.0018 0.2428 0.243

-0.0014 -0.0014 -0.0035 -0.0035 -0.0086 -0.0086 -0.0315 -0.0315 -0.0669 -0.0669 29.8356 29.8 0.0373 0.0373 0.8811 0.881 0.006 0.006

0.0253 0.0253 0.028 0.028

0.0025 0.0025 -0.0607 -0.0607 -0.0056 -0.0056 -0.0032 -0.0032 0.2379 0.238

0.0008 0.0008

0.01 16 0.01 16

0.0053 0.0053 0.0705 0.0705 0.0236 0.0236

-0.0199 -0,0199 -0.0013 -0.0013 0.0003 0.0003 0.0686 0.0686

19.6469 19.6 0.0016 0.0016 0.0075 0.0075

-0.0185 -0.0185

-0.0036 -0.0036

-0.0149 -0.0149

-0.0096 -0.0096 -0.0004 -0.0004 20.0816 20.1 0.0099 0.0099 19.403 19.4

0 0 0.0069 0.0069 -0.003 -0.003 0.0826 0.0826 0.0274 0.0274

Dilution Cal 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

RL 0.05 0.5

0.05 0.05 0.05 0.2 0.1 0.5 0.2 0.5

0.05 0.1 0.1

0.05 0.15 0.05 0.1

1.25 0.05 0.1

0.05 0.05 0.05 0.05 0.5

0.05 0.2

0.05 0.05 0.1 0.5

0.05 0.05 0.05 0.05 0.5

0.05 0.5

0.05 0.05 0.05 0.2 0.1

uglml Date -0.0001 8 0411 6/07 0.02428 04/16/07

-0.00014 04/16/07 -0.00035 04/16/07 -0.00086 04/16/07 -0.0031 5 04/16/07 -0.00669 04/16/07 2.98356 04/16/07 0.00373 04/16/07 0.0881 1 04/16/07 0.0006 0411 6/07

0.00253 04/16/07 0.0028 0411 6/07

0.00025 04/16/07 -0.00607 04/16/07 -0.00056 04/16/07 -0.00032 04/16/07 0.02379 04/16/07

0.00008 04/16/07

0.001 16 04/16/07

0.00053 04/16/07 0.00705 04/16/07 0.00236 04/16/07

-0.00185 04/16/07

-0.00036 04/16/07

-0.00149 04/16/07

-0.001 99 0411 6/07 -0.00013 04/16/07 0.00003 04/16/07 0.00686 04/16/07 1.96469 04/16/07 0.00016 04/16/07 0.00075 04/16/07

-0.00096 04/16/07 -0.00004 04/16/07 2.00816 04/16/07 0.00099 04/16/07

1.9403 04/16/07 0 04/16/07

0.00069 04/16/07

0.00826 04/16/07 0.00274 04/16/07

-0.0003 04/16/07

Tim ! 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:02 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06

d m

Div 20 0 to#070410-6 0 06002.01.242

A

rl 0.05 0.02 0.05

0.005 0.01 0.01

0.005 0.015 0.005 0.01

0.125 0.005 0.01

0.005 0.005 0.005 0.015

mglL sigwt Dilution Calc RL 0.187

0.0362 0.024

0.0032 0.0351

-0.0042 0.001 1

-0.0631 -0.0012 0.0343 0.4654

0.0318

0.0004

0.053226566

-0.004

-0.0013

-0.0034

0.25 -1.468248647 0.015 3.955153653 0.25 19.62103135

0.015 0.048665031 0.25 148.5651339

0.25 149.0194999 0.015 39.99289315 0.25 349.0587867

0.01 5 0.018415724 0.25 162.253022

0.015 0.013346285 0.25 157.7459793

0.25 168.0072994

0.25 457.3817775

0.25 18.72467562

0.01 5 -0.002457654

0.015 -0.044875316

0.015 -0.034853291

0.015 -0.1 19929586

0.187 0.0362 0.024

0.0032 0.0351

-0.0042 0.001 1

-0.0631 -0.0012 0.0343 0.465

0.031 8

0.0004

0.0532

-0.004

-0.0013

-0.0034

-1.47 3.96 19.6

0.0487 149

149 40

349 0.0184

162 0.0133

158

168 -0.0349

457 -0.12 18.7

-0.00246

-0.0449

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

0.5 0.2 0.5

0.05 0.1 0.1

0.05 0.15 0.05 0.1

1.25 0.05 0.1

0.05 0.05 0.05 0.15 2.5

0.015 0.25 0.15 2.5

0.15 2.5

0.15 2.5

0.15 2.5

0.15 2.5

0.15 2.5

0.15 2.5

0.15 2.5

uglml Date 0.0187 04/16/07

0.00362 0411 6/07 0.0024 0411 6/07

0.00032 04/16/07 0.00351 04/16/07

0.0001 1 04/16/07 -0.00042 04/16/07

-0.00631 04/16/07 -0.00012 04/16/07 0.00343 04/16/07 0.04654 04/16/07

0.00318 04/16/07

0.00004 04/16/07

0.005322657 0411 9/07

-0.0004 04/16/07

-0.00013 04/16/07

-0.00034 0411 6/07

Time 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06 19:06

11:27AM -0.146824865 0411 9/07 1 1127 AM 3.9551 53653 0411 9/07 1 1 :30 AM 19.62103135 04/19/07 11:30AM 0.004866503 04/19/07 11:33 AM 14.85651339 04/19/07 11:33 AM

14.90194999 04/19/07 11:36AM 3.999289315 04/19/07 11:39 AM 34.90587867 04/19/07 11:39 AM 0.001841572 04/19/07 11:42AM

16.2253022 0411 9/07 1 1 :42 AM 0.001334628 04/19/07 11:45 AM 15.77459793 0411 9/07 1 1 :45 AM

16.80072994 0411 9/07 11:48 AM

45.73817775 04/19/07 11:51 AM

1.872467562 04/19/07 11 :54 AM

-0.000245765 04/19/07 1 1136 AM

-0.004487532 04/19/07 11:48 AM

-0.003485329 0411 9/07 1 1 :51 AM

-0.01 1992959 04/19/07 11 154 AM

div20-07041 O(6)icp

010052 SOUTHWEST RESEARCH INSTITUTE NUCLEAR PROJECT CLIENT: Division 20



METALS

0 200.7 TAP No. 01-0406-028 Rev3/JanO6

&OB TAP No. 01-0406-130 RevSIJan06

CI Other

ICP CAL.STD. ID'S

Std5 Std6

PROJ. NO. PROJECT TO# DATE M2lTRIX LOGBK PG

INSTRUMENT: c+a2 FILENAME: o+y$ IW

44-iG File converted to wsl? 0

TRACE METALS PREPARATORY LABORATORY DIGESTION LOG

67 006 SOUTHWEST RESEARCH INSTITUTE SAN ANTONIO, TEXAS 78228 BOOK / PAGE:

- ~~ - CLIENT(S): id 55-Q - TASK ORDER(S): !. Z ,'*~< O?&CS-6 SDG(S): 2.q @s4 -

Microwave-FusionTeflon-Rock-OTHER d ~ ~ ~ u ~ ~ L ~ Lb - MATRIX: Water&oil-Biota-Solid-Liquid-TCLP Ext-OTHER - INSTRUMENT: GFAA-ICP~P-MS-IC-FLAA-HYDRIDE-OTHER - ACID INORG #: H N O ~ # L353 HCI# 639* H2S04# HCIOP H F# H202#-- INTERNAL STD: s c Q i o P P M ~ Q i o PPM-SOURCE: =q I N O R G # . ~ ~ J X P : ~ - ~ ~ ~ A M T : B ~ Oven/Hotplate/ Block ID: p/& Temperature ("C): e/4 Time in: d?h- Timeout: &-

- - a ' A - h 3 PROJECT NO(S): d C Y Z .ai. 7 41- METHOD:3005A-3050B-3050B-7.5-30 1 OA-3020A-7760A-7740A-HC10~HC10~2SO~---

Sample Identification I I df IWT(g) ll.V.(ml) IF.V.(ml) I I I I ^ *

*40ul Li #5790 exp. 6/1/07 *40ul S #6227 exp. 1/1/08 *40uL ICAL-1 Spex#6164 exp. 10/31/07 *IOOuL Spike-I #6163 Exp.10/31/07 PBW&LCSW are prepared as 10mls 1%HN03/ 5% HCL

PREPARED BY: DATE: 4 -16-04- REVIEWED BY DATE: q- / f$7 DISPOSAL INT/DA%OC:

FRM-191 (Rev 5/Ma107)

EVOLUTION by Micro-Active Australia Pty Ltd 11:05:58 AM April 19, 2007

Keep last result visible enabled ... Starting run ... Creating high priority queue entries ... BACKGROUND CORRECTED INTENSITIES Identity 1 : BLK-SC Identity 2 : Type : STD Weight : 1.0000 Volume : 1.00 Printed : 10:59:32 AM April 19, 2007

K-766 Li670 Na589 Sc361 t l 6.5 -21.5 94.0 2147.0 1 2 19.5 -12.5 119.0 2107.0

Hean 13.0 -17.0 106.5 2127.0

XRSD 70.7 37.4 16.6 1.3 SD 9.2 6.4 17. '7 28.3

INTENSITIES Identity 1 : BLK-SC Identity 2 : Type : STD Weight : 1.0000 Volume : 1.00 Printed : l0:59:34 AH April 19, 2007

K-766 Li670 Na589 Sc361 # 1 0.0 -0.0 0.0 2147.0 P 2 0.0 -0.0 0.1 2107.0

Mean 0.0 -0.0 0.1 2127.0

XRSD 71.7 36.2 17.9 1.3 SD 0.0 0.0 0.0 28.3

BACKGROUND CORRECTED INTENSITIES Identity 1 : CLP-STD1-SC Identity 2 : Type : STD Weight : 1.0000 Volume : 1.00 Printed : 11:02:34 AM April 19, 2007

K-766 Li670 Na589 t l 2562.0 16554.0 14327. rd t 2 2544.0 16459.0 14400. (il

Mean 2553.0 16506.5 14363.5 SD 12.7 67.2 51.6 XRSD 0.5 0.4 0.4

INTENSITIES Identity 1 : CLP-STD1-SC Identity 2 : Type : STD Weight : 1.0000 Volume : 1.00 Printed : 11:02:36 AH April 19, 2007

K-766 Li678 Ne589 t 1 1.2 7. a 6.7 t 2 1.2 7. a 6. a

Mean 1.2 7.8 6. a

XRSD 0.0 0.1 0. a SD 0.0 0.0 0. x

BACKGROUND CORRECTED INTENSITIES Identity 1 : CLP-CCV-SC Identity 2 : Type : CV Weight : 1.0000 Volume : 1.00 Printed : 11:05:40 AH April 19, 2007

010055

K-766 Li670 Na589 sc Sc361 P 1 997.5 8084.0 8452. 0 2097.5 2097.5 P 2 1001.5 7896.0 a w . 0 2045.5 2045.5

I I C U I I 332.4 I Y 3 W . w O J O 4 . 3 L W / l . 3 L W /I. 3

SD 2.8 132.9 95.5 36.8 36.8 %RSD 0.3 1.7 1.1 1.8 1.8

APPARENT CONCENTRATIONS EVOLUTION by tlicro-Active Australia Pty Ltd 11:05:58 AH April 19, 2007

Identity 1 : CLP-CCV-SC Identity 2 : Type : CV Weight : 1.0000 Volume : 1.00 Printed : 11:05:40 AH April 19, 2007

K-766 Li670 Na589 sc Sc361 PPm PPm PPm P Pm

t l 19.6561 4.9715 29.6850 2097.500 98.6088 1 2 20.2442 4.9793 29.9568 2045.500 96.1566

tlean 19.9501 4.9754 29.8209 2071.500 97.3827 1.7340 SD 0.4158 0.0055 0.1922 36.770

XRSD 2.0844 0.1110 0.6445 1.775 1.7806

Checking calibration verification ... Identity 1 : CLP-CCV-SC Identity 2 : Report name Low limit Value High limit K-766 18.000 19.950 22.000 Li670 4.500 4.975 5.500 Ne589 27.000 29.821 33.000

010056

010057 EVOLUTION by Hicro-Active Australia Pty Ltd 11:15:02 AH April 19, 2007

BACKGROUND CORRECTED INTENSITIES Identity 1 : Calibration blank Identity 2 : Type : CB Weight : 1.0000 Volume : 1.00 Printed : 11:08:44 AH April 19, 2007

K-766 Li670 Na589 SC Sc361 # 1 27.0 -6.5 88.0 2127.5 2127.5 Y 2 35.0 -0.5 84.0 2096.5 2096.5

Wean 31.0 -3.5 86.0 2112.0 21 12.0 SD 5.7 4.2 2. a 21.9 21.9 XRSD 18.2 121.2 3.3 1.0 1.0

APPARENT CONCENTRATIONS Identity 1 : Calibration blank Identity 2 : Type : CB Weight : 1.0000 Volume : 1.00 Printed : 11:08:44 AH April 19, 2007

K-766 Li670 Na589 sc Sc361 PPm PPm PPm PPm

# l 0.2755 0.0064 L -0.0650 2127.500 H 100.0236 $ 2 0.4431 0.0100 L -0.0746 2096.500 98.5617

Hean 0.3593 0.0082 L -0.0698 2112.000 99.2926 SD 0.1185 0.0026 XRSD 32.9913 31.3875

Checking calibration blank ... Identity 1 : Calibration blank Report name CRDL K-766 0.250 Li670 0.010 Ne589 0.050 Sc361 0.000

0.0068 21.920 1.0337 9.7978 1.038 1.0411

Identity 2 : Value

0.359 Contaminated 0.008 -0.070 Contaminated 99.293

BACKGROUND CORRECTED INTENSITIES Identity 1 : CRI Identity 2 : Type : CV Weight : 1.0000 Volume : 1.00 Printed : 11:11:48 AH April 19, 2007

K-766 Li670 Ne589 SC Sc361 # 1 19.5 154.5 61.5 2230.0 2230.0 $ 2 1.5 150.5 61.5 2199.0 2199.0

Hean 10.5 152.5 61.5 2214.5 2214.5 SD 12.7 2.8 0.0 21.9 21.9 XRSD 121.2 1.9 0.0 1.0 1.0

APPARENT CONCENTRATIONS Identity 1 : CRI Identity 2 : Type : CV Weight : 1.0000 Volume : 1.00 Printed : 11:11:48 AH April 19, 2007

K-766 Li670 Na589 SC Sc361 PPm P Pm PPm PPm

$ 1 0.1102 0.0995 L -0.1678 2230.000 H 104.8573 # 2 L -0.2273 0.0984 L -0.1649 2199.000 H 103.3954

Mean L -0.0586 0.0989 L -0.1663 2214.500 H 104.1264 SD 0.2387 0.0008 0.0021 21.920 1.0337 XRSD 407.6039 0.7750 1.2329 0.990 0.9928

LnecKirtg caiiDration verixication ... Identity 1 : CRI Identity 2 : Report name Low limit Value High limit Li670 0.090 0.099 0.110 BACKGROUND CORRECTED INTENSITIES EVOLUTION by Micro-Active Australia Pty Ltd 11:21:28 AM April 19, 2007 010058 Identity 1 : ICSA Identity 2 : Type : INTRF Weight : 1.0000 Volume : 1.00 Printed : 11:14:50 AM April 19, 2007

K-766 Li670 Na589 sc Sc361 # 1 29.0 -27.5 55.5 2117.0 2117.0 # 2 10.0 -20.5 45.5 2086.0 2086.0

Iiean 19.5 -24.0 50.5 2101.5 2101.5 SD 13.4 4.9 7.1 21.9 21.9 XRSD 68.9 20.6 14.0 1.0 1.0

APPARENT CONCENTRATIONS Identity 1 : ICSA Identity 2 : Type : INTRF Weight : 1.0000 Volume : 1.00 Printed : 11:14:50 AM April 19, 2007

K-766 Li670 Ne589 sc Sc361 PPm PPm PPm PPm

# l 0.3177 L -0.0064 L -0.1779 2117.000 99.5284 # 2 L -0.0552 L -0.0024 L -0.2108 2086.000 98.0665

Mean 0.1312 L -0.0044 L -0.1944 2101.500 98.7975 SD 0.2636 0.0029 0.0232 21.920 1.0337 XRSD 200.8906 65.4613 11.9521 1.043 1.0463

BACKGROUND CORRECTED INTENSITIES Identity 1 : ICSAB Identity 2 : Type : ICSAB Weight : 1.0000 Volume : 1.00 Printed : 11:17:56 AH April 19, 2007

K-766 Li670 Ne589 sc Sc361 # l 41.0 1721.0 69.0 2135.0 2135.0 1 2 33.0 1688.0 71.0 2108.0 2108.0

Mean 37.0 1704.5 70.0 2121.5 2121.5 SD 5.7 23.3 1.4 19.1 19.1 XRSD 15.3 1.4 2.0 0.9 0.9

APPARENT CONCENTRATIONS Identity 1 : ICSAB Identity 2 : Type : ICSAB Weight : 1.0000 Volume : 1.00 Printed : 11:17:56 AH April 19, 2007


# l 0.5482 1.0479 L -0.1324 2135.000 H 100.3773 # 2 0.3996 1.0411 L -0.1223 2108.000 99.1040

Mean 0.4739 1.0445 L -0.1273 2121.500 99.7406 SD 0.1051 0.0049 0.0072 19.092 0.9003 XRSD 22.1748 0.4645 5.6447 0.900 0.9027

Checking interference check standard ... Identity 1 : ICSAB Identity 2 : Report name Low limit Value High limit Li670 0.800 1.045 1.200 BACKGROUND CORRECTED INTENSITIES Identity 1 : CLP-CCV-SC Identity 2 : Type : CV Weight : 1.0000 Volume : 1.00 Printed : 11:21:02 AM April 19, 2007

K -766 Li670 Na589 sc Sc361

# 1 YbY. 3 'l8Y5.5 8332.3 ZCl'/Cl. 5 ZCl'/(d. 3

t 2 981.5 7767.5 8226.5 2032.5 2032.5

Hean 975.5 7831.5 8289.5 2051.5 2051.5 SD 8.5 90.5 89.1 26.9 26.9 EVOLUTION by Hicro-Active Australia Pty Ltd 11:27:28 AH April 19, 2007

XRSD 0.9 1.2 1. 1. 1.3 1.3

APPARENT CONCENTRATIONS Identity 1 : CLP-CCV-SC Identity 2 : Type : CV Weight : 1.0000 Volume : 1.00 Printed : 11:21:02 AH April 19, 2007


t l 19.3495 4.9190 29.7185 2070.500 97.3355 # 2 19.9633 4.9297 29.8186 2032.500 95.5435

Hean 19.6564 4.9244 29.7686 2051.500 96.4395 SD 0.4340 0.0076 0.0708 26.870 1.2672 XRSD 2.2079 0.1538 0.2379 1.310 1.3139

Checking calibration verification ... Identity 1 : CLP-CCV-SC Identity 2 : Report name Low limit Value High limit

Li670 4.500 4.924 5.500 Na589 27.000 29.769 33.000 BACKGROUND CORRECTED INTENSITIES Identity 1 : Calibration blank Identity 2 : Type : CB Weight : 1.0000 Volume : 1.00 Printed : 11:24:06 AH April 19, 2007

K-766 18.000 19.656 22.000

K-766 Li670 Ne589 sc Sc361 # l 22.0 -14.0 66.5 2109.5 2109.5 1 2 35.0 -17.0 76.5 2059.5 2059.5

Hean 28.5 -15.5 71.5 2084.5 2084.5 SD 9.2 2.1 7.1 35.4 35.4 XRSD 32.3 13.7 9.9 1.7 1.7

APPARENT CONCENTRATIONS Identity 1 : Calibration blank Identity 2 : Type : CB Weight : 1.0000 Volume : 1.00 Printed : 11:24:06 AH April 19, 2007

K-766 Li670 Ne589 sc Sc361 PPm P Pm PPm P Pm

t l 0.1808 0.0017 L -0.1383 2109.500 99.1747 x 2 0.4557 L -0.0003 L -0.0964 2059.500 96.8168

Hean 0.3182 0.0007 L -0.1174 2084.500 97.9958 SD 0.1944 0.0015 0.0296 35.355 1.6673 XRSD 61.0862 209.1541 25.2577 1.696 1.7014

Checking calibration blank ... Identity 1 : Calibration blank Identity 2 : Report name CRDL Value K-766 0.250 0.318 Contaminated Li670 0.010 0.001 Na589 0.050 -0.117 Contaminated Sc361 0.000 97.996 BACKGROUND CORRECTED INTENSITIES Identity 1 : PBW-Dl6H1 Identity 2 : Type : SAHPLE Weight : 1.0000 Volume : 1.00 Printed : 11:27:08 AH April 19, 2007

0100!39

.. I Y Y Y A Y , u I.a.2-d aL JL.3301 - # l 31.5 -10.0 69.0 1955.0 1955.0 1 2 27.5 -5.0 49.0 1923.0 1923.0

Heen 29.5 -7.5 59.0 1939.0 1939.0 EVOLUTION by Hicra-Active Australia Pty Ltd 11:33:28 AH April 19, 2007

SD 2. a 3.5 14.1 22.6 22.6 XRSD 9.6 47.1 24.0 1.2 1.2

010060

APPARENT CONCENTRATIONS Identity 1 : PBW-Dl6Hl Identity 2 : Type : SAHPLE Weight : 1.0000 Volume : 1.00 Printed : ll:27:10 AH April 19, 2007


# l 0.4187 0.0037 L -0.1102 1955.000 91.8887 w 2 0.3429 0.0069 L -0.1834 1923.060 90.3796

Mean 0.3808 0.0053 L -0.1468 1939.000 91.1342 SD 0.0536 0.0023 0.0518 22.627 1.0671 XRSD 14.0879 43.0088 35.2534 1.167 1.1709

BACKGROUND CORRECTED INTENSITIES Identity 1 : LCSW-D16H1 Identity 2 : Type : SAMPLE Weight : 1.0000 Volume : 1.00 Printed : 11:30:12 AH April 19, 2007

K-766 Li670 Na589 SC Sc361 # l 964.0 6192.0 5393.5 2016.5 2016.5 # 2 934.0 5993.0 5263.5 1959.5 1959.5

1988.0 Hean 949.0 6092.5 5328.5 1988.0 SD 21.2 140.7 91.9 40.3 40.3 XRSD 2.2 2.3 1.7 2.0 2.0

APPARENT CONCENTRATIONS Identity 1 : LCSW-D16H1 Identity 2 : Type : SAHPLE Weight : 1.0000 Volume : 1.00 Printed : 11:30:12 AH April 19, 2007


# l 19.7603 3.9630 19.5783 2016.500 94.7890 1 2 19.7016 3.9473 19.6638 1959.500 92.1009

Hean 19.7309 3.9552 19.6210 1988.000 93.4449 SD 0.0416 0.0111 0.0605 40.305 1.9007 XRSD 0.2106 0.2815 0.3081 2.027 2.0341

BACKGROUND CORRECTED INTENSITIES Identity 1 : 294954 Identity 2 : Type : SAHPLE Weight : 1.0000 Volume : 1.00 Printed : 11:33:16 AH April 19, 2007

K-766 Li670 Na589 sc Sc361 # l 209.5 -8.0 4088. 5 2025.5 2025.5 # 2 210.5 -9.0 4153.5 2011.5 2011.5

Mean 210.0 -8.5 4121.0 2018.5 2018. 5 SD 0.7 0.7 46.0 9.9 9.9 XRSD 0.3 8.3 1. 1. 0.5 0.5

APPARENT CONCENTRATIONS Identity 1 : 294954 Identity 2 : Type ; SAHPLE Weight : 1.0000 Volume : 1.00 Printed : 11:33:16 AH April 19, 2007

K-766 Li670 Na589 sc Sc361 PPm PPm P Pm PPm

8 1

w 2

Hean SD EVOLUT

XRSD

4. YII4U YI. YIYI3L

4.1257 0.0045

4.1002 0.0049 0.0360 0.0005

N by Hicro-Active Austra

0.8788 9.8127

14. bU3ti L W L 3 . 3 w w Ya. L134

15.0294 2011.500 94.5532

14.8565 2018.500 94.8833 010061 0.2445 9.899 0.4668

ia Pty Ltd 11:42:58 AM April 19, 2007

1.6461 0.490 0.4920

BACKGROUND CORRECTED INTENSITIES Identity 1 : 294954D Identity 2 : Type : SAMPLE Weight : 1.0000 Volume : 1.00 Printed : 11:36:22 AH April 19, 2007

K-766 ti670 Na589 sc Sc361 # l 186.0 -12.5 4160.5 2030.0 2030.0 8 2 192.0 -20.5 4108.5 2008.0 2008.0

Hean 189.0 -16.5 4134.5 2019.0 2019.0 SD 4.2 5.7 36. & 15.6 15.6 XRSD 2.2 34.3 0.9 0.8 0.8

APPARENT CONCENTRATIONS Identity 1 : 294954D Identity 2 : Type : SAHPLE Weight : 1.0000 Volume : 1.00 Printed : 11:36:22 AH April 19, 2007


# l 3.5805 0.0024 14.9148 2030.000 95.4256 # 2 3.7476 L -0.0029 14.8891 2008.000 94.3881

Hean 3.6640 L -0.0002 14.9019 2019.000 94.9069 SD 0.1182 0.0037 0.0182 15.556 0.7336 XRSD 3.2256 1500.5430 0.1218 0.770 0.7730

BACKGROUND CORRECTED INTENSITIES Identity 1 : 294954s Identity 2 : Type : SAHPLE Weight : 1.0000 Volume : 1.00 Printed : 11:39:24 AH April 19, 2007

K-766 Li670 Ne589 sc Sc361 # 1 1135.5 6151.0 9447.5 1989.5 1989.5 # 2 1122.5 6142.0 9314.5 1977.5 1977.5

Hean 1129.0 6146.5 9381.0 1983.5 1983.5 SD 9.2 6.4 94.0 8.5 8.5 XRSD 0.8 0.1 1.0 0.4 a. 4

APPARENT CONCENTRATIONS Identity 1 : 2949546 Identity 2 : Type : SAHPLE Weight : 1.0000 Volume : 1.00 Printed : 11:39:26 AH April 19, 2007


# l 23.6413 3.9901 35.0493 1989.500 93.5157 # 2 23.5111 4.0084 34.7625 1977.500 92.9498

Hean 23.5762 3.9993 34.9059 1983.500 93.2327 SD 0.0921 0.0129 0.2028 8.485 0.4002 XRSD 0.3906 0.3234 0.5809 0.428 0.4292


K-766 Li670 Ne589 sc Sc361 # 1 227.5 -16.5 4416. S 1988.5 1988.5 w 2 211.5 -9.5 4388.5 1968.5 1968.5

Hean 219.5 -13.0 4402.5 1978.5 1978.5 SD 11.3 4.9 19.8 14.1 14.1 XRSD 5.2 38.1 0.4 0.7 0.7

EVOLUTION by Hicro-Active Australia Pty Ltd 11:51:58 AH April 19, 2007


K-766 Li670 Na589 SC Sc361 PPm PPm PPm PPm

# 1 4.5344 L -0.0004 16.1942 1988.500 93.4685 # 2 4.2427 0.0041 16.2564 1968.500 92.5253

Hean 4.3885 0.0018 16.2253 1978.500 92.9969 SD 0.2062 0.0032 0.0440 14.142 0.6669 XRSD 4.6993 171.5948 0.2712 0.715 0.7171


# l $ 2

Hean SD XRSD

APPARENT

K-766 208.0 196.0

202.0 8.5 4.2

ONCENTRAT

Li670 Na589 SC Sc361 -17.0 4351.5 2015.5 2015.5 -11.0 4359.5 2008.5 2008.5

-14.0 4355.5 2012.0 2012.0 4.2 5.7 4.9 4.9 30.3 0.1 0.2 0.2

NS Identity 1 : 294956 Identity 2 : Type : SAMPLE Weight : 1.0000 Volume ; 1.00 Printed : 11:45:32 AH April 19, 2007

K-766 Li670 Ne589 SC Sc361 PPm PPm PPm P Pm

# l 4.0651 L -0.0006 15.7317 2015.500 94.7418 $ 2 3.8300 0.0032 15.8175 2008.500 94.4117

Hean 3.9475 0.0013 15.7746 2012.000 94.5768 SD 0.1662 0.0027 0.0607 4.950 0.2334 XRSD 4.2112 201.7319 0.3848 0.246 0.2468

BACKGROUND CORRECTED INTENSITIES Identity 1 : 294957 Identity 2 : Type : SAHPLE Weight : 1.0000 Volume : 1.00 Printed ; 11:48:36 AH April 19, 2007

K-766 Li670 Na589 SC Sc361 2035.0 t l 221.0 -17.5 4670.0 2035.0

# 2 226.0 -28.5 4585.0 1985.0 1985.0

2010.0 Hean 223.5 -23.0 4627.5 2010.0 SD 3.5 7.8 60.1 35.4 35.4 XRSD 1.6 33.8 1.3 1.8 1.8


010062

K-766 Li670 Na589 sc Sc36 1 P Pm PPm PPm PPm

# l 4.2912 L -0.0008 16.7448 2035.000 95.6614 # 2 4.5112 L -0.0082 16.8566 1985.000 93.3035

~

Mean 4.4012 L -0.0045 16.8007 2010. 0uIB Y4.4824 SD 0.1556 0.0052 0.0790 35.355 1.6673 XRSD 3.5346 116.7959 0.4704 1.759 1.7647

BACKGROUND CORRECTED INTENSITIES 010063 EVOLUTION by Micro-Active AuEtralia Pty Ltd 11:58:00 AM April 19, 2007

Identity 1 : 294958 Identity 2 : Type : SAHPLE Weight : 1.0000 Volume : 1.00 Printed : 11:51:42 AM April 19, 2007

K-766 Li670 Na589 sc Sc361 t 1 531.0 -11.0 12584.0 2035.5 2035.5 1 2 534.0 -32.0 12365.0 2000.5 2000.5

Mean 532.5 -21.5 12474.5 2018.0 2018.0 SD 2.1 14.8 154.9 24.7 24.7 XRSD 0.4 69.1 1.2 1.2 1.2

APPARENT CONCENTRATIONS Identity 1 : 294958 Identity 2 : Type : SAMPLE Weight : 1.0000 Volume : 1.00 Printed : 11:51:42 AH April 19, 2007


# 1 10.6667 0.0033 45.7431 2035.500 95.6850 t 2 10.9206 L -0.0103 45.7333 2000.500 94.0344

Mean 10.7937 L -0.0035 45.7382 2018.000 94.8597 SD 0.1795 0.0096 0.0069 24.749 1.1671 'ARSD 1.6633 276.6187 0.0151 1.226 1.2304

BACKGROUND CORRECTED INTENSITIES Identity 1 : 294959 Identity 2 : Type : SAMPLE Weight : 1.0000 Volume : 1.00 Printed : 11:54:46 AX April 19, 2007

K-766 Li670 Na589 sc Sc361 # 1 102.5 -43.5 581.0 2007.0 2007.0 w 2 115.5 -25.5 616.0 1970.0 1970.0

Mean 109.0 -34.5 598.5 1988.5 1988.5 SD 9.2 12.7 24.7 26.2 26.2 XRSD 8.4 36.9 4. 1. 1.3 1.3

APPARENT CONCENTRATIONS Identity 1 : 294959 Identity 2 : Type : SAMPLE Weight : 1.0000 Volume : 1.00 Printed : 11:54:46 AM April 19, 2007


# 1 1.8825 L -0.0176 1.7859 2007.000 94.3410 t 2 2.1989 L -0.0064 1.9590 1970.000 92.5961

Mean 2.0407 L -0.0120 1.8725 1988.500 93.4685 SD 0.2238 0.0079 0.1224 26.163 1.2338 XRSD 10.9656 66.2578 6.5363 1.316 1.3200

BACKGROUND CORRECTED INTENSITIES Identity 1 : CLP-CCV-SC Identity 2 : Type : CV Weight : 1.0000 Volume : 1.00 Printed : 11:57:50 AH April 19, 2007

K-766 Li670 Ne589 sc Sc361 # l 990.5 7745.5 8253.0 2046.5 2046.5 # 2 975.5 7584.5 7993.0 2002.5 2002.5

Xeen 983.0 7665.0 8123.0 2024.5 2024.5 SD 10.6 113.8 183.8 31.1 31.1

APPARENT CONCENTRATIONS Identity 1 : CLP-CCV-SC Identity 2 : Type : CV Weight : 1.0000 Volume : 1.00 Printed : 11:57:50 AM April 19, 2007 EVOLUTION by Micro-Active Auetralia Pty Ltd 12:03:58 PM April 19, 2007

K-766 Li670 Ha589 SC Sc361 PPm PPm PPm PPm

t l 20.0091 4.8822 29.7087 2046.500 96.2037 t 2 20.1407 4.8858 29.4011 2002.500 94.1287

Mean 20.0749 4.8840 29.5549 2024.500 95.1662 SD 0.0931 0.0025 0.2175 31.113 1.4672 %RSD 0.4637 0.0515 0.7358 1.537 1.5418

Checking calibration verification ... Identity 1 : CLP-CCV-SC Identity 2 : Report name Low limit Value High limit K-766 18.000 20.075 22.000 Li670 4.500 4.884 5.500 Na589 27.000 29.555 33.000 BACKGROUND CORRECTED INTENSITIES Identity 1 : Calibration blank Identity 2 : Type : CB Weight : 1.0000 Volume : 1.00 Printed : 12:00:54 PM April 19, 2007

K-766 Li670 Na589 SC Sc361 2145.0 Y 1 26.5 -5.5 46.5 2145.0

# 2 32.5 -22.5 80.5 2097.0 2097.0

Mean 29.5 -14.0 63.5 2121.0 2121.0 SD 4.2 12.0 24.0 33.9 33.9 %RSD 14.4 85.9 37.9 1.6 1.6

APPARENT CONCENTRATIONS Identity 1 : Calibration blank Identity 2 : Type : CB Weight : 1.0000 Volume : 1.00 Printed : 12:00:54 PM April 19, 2007

K-766 Li670 Na589 SC Sc361 PPm PP* PPm PPm

t 1 0.2614 0.0070 L -0.2118 2145.000 H 100.8489 w 2 0.3930 L -0.0035 L -0.0871 2097.000 98.5852

Mean 0.3272 0.0017 L -0.1495 2121.000 99.7170 SD 0.0931 0.0074 0.0881 33.941 1.6006 %RSD 28.4494 429.0877 58.9683 1.600 1.6052

Checking calibration blank ... Identity 1 : Calibration blank Identity 2 : Report name CRDL Value K-766 0.250 0.327 Contaminated Li670 0.010 0.002 Na589 0.050 -0.149 Contaminated Sc361 0.000 99.717 BACKGROUND CORRECTED INTENSITIES Identity 1 : CRI Identity 2 : Type : CV Weight : 1.0000 Volume : 1.00 Printed : 12:03:58 PM April 19, 2007

K-766 Li670 Ne589 SC Sc361 t 1 28.0 133.5 66.5 2162.0 2162.0 t 2 27.0 132.5 32.5 2112.0 2112.0

010064

Mean 27.5 133.0 49.5 2137.0 2137.0

SD kl. 'I Io. ./ 24.10 XRSD 2.6 0.5 48.6

APPARENT CONCENTRATIONS Identity 1 : CRI Identity 2 : Type : CV EVOLUTION by Hicro-Active Australia Pty Ltd 1

33.4 1.7

:10:2

32.4 1.7

010065 PM April 19, 2007

Weight : 1.0000 Volume : 1.00

K-766 Li670 PPm PPm

Y l 0.2864 0.0898 L t 2 0.2794 0.0910 L

Mean 0.2829 0.0904 L SD 0.0049 0.0009 %RSD 1.7467 0.9951

Printed :

Na589 PPm

-0.1441 -0.2587

-0.2014 0.0811 40.2578

12:03:58 PM April 19, 2007

sc Sc361 P Pm

2162.000 H 101.6506 2112.000 99.2926

2137.000 H 100.4716 35.355 1.6673 1.654 1.6595

Checking calibration verification ... Identity 1 : CRI Identity 2 : Report name Low limit Value High limit Li670 0.090 0.090 0.110 BACKGROUND CORRECTED INTENSITIES Identity 1 : ICSA Identity 2 : Type : INTRF Weight : 1.0000 Volume : 1.00 Printed : 12:07:02 PM April 19, 2007

K-766 Li670 Na589 SC Sc361 t l 23.0 -25.0 67.0 2071.0 2071.0 Y 2 14.0 -27.0 67. Q) 2031.0 2031.0

Mean 18.5 -26.0 67.0 2051.0 2051.0 SD 6.4 1.4 0.0 28.3 28.3 XRSD 34.4 5.4 0.0 1.4 1.4

APPARENT CONCENTRATIONS Identity 1 : ICSA Identity 2 : Type : INTRF Weight : 1.0000 Volume : 1.00 Printed : 12:07:02 PM April 19, 2007


t 1 0.2091 L -8.0053 L -0.1322 2071.000 97.3591 Y 2 0.0327 L -0.0068 L -0.1274 2031.000 95.4728

Mean 0.1209 L -0.0060 L -0.1298 2051.000 96.4159 SD 0.1247 0.0011 0.0034 28.284 1.3338 XRSD 103.1582 18.4303 2.5892 1.379 1.3834

BACKGROUND CORRECTED INTENSITIES Identity 1 : ICSAB Identity 2 : Type : ICSAB Weight : 1.0000 Volume : 1.00 Printed : 12:10:06 PM April 19, 2007

K-766 Li670 Na589 sc Sc361 9 1 26.5 1688.0 45.0 2137.5 2137.5 t 2 27.5 1637.0 30.0 2074.5 2074.5

Mean 27.0 1662.5 37.5 2106.0 2106.0 SD 0.7 36.1 10. G 44.5 44.5 XRSD 2.6 2.2 28.3 2.1 2.1

APPARENT CONCENTRATIONS Identity 1 : ICSAB Identity 2 : Type : ICSAB Weight : 1.0000 Volume : 1.00 Printed : 12:10:06 PM April 19, 2007


# 1 (d. 2b3Z l . (dZbS L - ( d . Z l b 3 Zl;J./ . 3Wl H 1 W U . 4,331 # 2 0.2991 1.0261 L -0.2656 2074.500 97.5242

Mean 0.2812 1.0265 L -0.2410 2106.000 99,0097 SD 0.0254 0.0005 0.0348 44.548 2.1008 EVOLUTION by Micro-Active Australia Pty Ltd 12:16:28 PM April 19, 2007

XRSD 9.0407 0.0534 14.4236 2.115 2.1218

Checking interference check standard ... Identity 1 : ICSAB Identity 2 : Report name Low limit Value High limit Li670 0.800 1.026 1.200 BACKGROUND CORRECTED INTENSITIES Identity 1 : CLP-CCVSC Identity 2 : Type : CV Weight : 1.0000 Volume : 1.00 Printed : 12:13:14 PM April 19, 2007

K-766 Li670 Na589 sc Sc361 # 1 962.0 7732.0 8265.0 2040.5 2040.5 # 2 946.0 7618.0 8139.0 2017.5 2017.5

Mean 954.0 7675.0 8202.0 2029.0 2029.0 SD 11.3 80.6 89.1 16.3 16.3 XRSD 1.2 1.1 1.1 0.8 0.8

APPARENT CONCENTRATIONS Identity 1 : CLP-CCV-SC Identity 2 : Type : CV Weight : 1.0000 Volume : 1.00 Printed : 12:13:14 PM April 19, 2007


# l 19.4839 4.8a8i 29.8410 2040.500 95.9208 # 2 19.3769 4.8709 29.7196 2017.500 94.8361

Mean 19.4304 4.8795 29.7ao3 2029.000 95.3784 SD 0.0757 0.0121 0.0859 16.263 8.7670 XRSD 0.3895 0.2482 0.2883 0.802 0.8041

Checking calibration verification ... Identity 1 : CLP-CCV-SC Identity 2 : Report name Low limit Value High limit K-766 18.000 19.430 22.000 ti670 4.500 4.879 5.500 Na589 27.000 29.780 33.000 BACKGROUND CORRECTED INTENSITIES Identity 1 : Calibration blank Identity 2 : Type : CB Weight : 1.0000 Volume : 1.00 Printed : 12:16:18 PW April 19, 2007

K-766 Li670 Na589 sc Sc361 # 1 21.0 -1.5 31.0 2045.5 2045.5 # 2 26.0 -1.5 57.0 2020.5 2020.5

Mean 23.5 -1.5 44.0 2033.0 2033.0 SD 3.5 0.0 18.4 17.7 17.7 XRSD 15.0 0.0 41. a 0.9 0.9

APPARENT CONCENTRATIONS Identity 1 : Calibration blank Identity 2 : Type : CB Weight : 1.0000 Volume : 1.00 Printed : 12:16:18 PM April 19, 2007

# l # 2


0.1740 0.0093 L -0.2605 2045.500 96.1566 0.2829 0.0093 L -0.1631 2020.500 94.9776

010066

Mean 0.2284 0.0093 L -0.2118 2033.000 95.5671 SD 0.0770 0.0000 0.0689 17.678 0.8337 XRSD 33.7219 0.0884 32.5204 0.870 0.8723

EVOLUTION by Micro-Active Australia Pty Ltd 12:26:58 PH April 19, 2007 010067

Checking calibration blank ... Identity 1 : Calibration blank Identity 2 : Report name CRDL Value K-766 0.250 0.228 Li670 0.010 0.009 Na589 0.050 -0.212 Contaminated Sc361 0.000 95.567

200.7 TAP No. 01-0406-028 Rev3/JanO6

W B TAP No. 01-0406-130 Rev9Jan06

Other

I QCSTD.ID’s I I ICP CALSTD. I

PROJ. NO. PROJECT TO# DATE MAT= LOGBK PG

INSTRUMENT: - \ C W . 7 - FILENME: b h4(6 6

File converted to wsl?

Standardization Rpt. 04/16/07 05:07:55 PM

Method: DAILY2 Standard: blk Run Time: 04/16/07 17:03:20 010069 Elem Ag3280 A13082 As1890

SDev . o o o o . o o o o . o o o o %RSD 181.0 2.060 56.83

Avge - . 0000 . 0 0 0 5 - . 0 0 0 0 B - 2496 Ba4934 . o o o o - . 0000 . o o o o . o o o o 14.14 16.57

Be3130 .0004 . o o o o 2.641

Bi2230 - . 0000

. o o o o 98.71

#1 . o o o o . 0 0 0 5 - . 0001 # 2 - * 0001 .0005 - . 0000

. o o o o - . 0 0 0 0

.OOOl - . 0 0 0 0 .0004 .0004

- . 0000 - . 0000

Elem Ca3179 Cd2265 Co2286

SDev . o o o o . o o o o * 0000 %RSD 42.51 219.9 111.6

Avge . o o o o - . 0000 - . 0 0 0 0 Cr2677 Cu3247 . o o o o .0002 . o o o o . o o o o 1298. 6.105

Fe2714 . o o o o . O O O l 919.3

K - 7664 .0003 .OOOl 27.44

#1 . o o o o - . 0000 - . o o o o #2 . o o o o . o o o o - . 0000

- . o o o o .0002 . o o o o .0002

. o o o o - . o o o o

.0004

.0002

Elem La3988 Li6707 Mg2790

SDev . o o o o .OOOl . o o o o %RSD 437.4 10.50 931.4

Avge - . 0000 . 0 0 0 4 - . 0 0 0 0 Mn2576 Mo2020 . o o o o - . 0000 . o o o o . o o o o 59.31 103.6

Na3302 - . 0001

. o o o o 11.02

Na5889 - . 0018 .0008

47.06

#1 . o o o o . 0 0 0 5 - 0000 #2 - . 0000 .0004 - . 0000

. o o o o - . o o o o

. o o o o - . 0 0 0 0 - . 0001 - . 0001

- . 0012 - . 0024

Elem Ni2316 P - 1782 2203/1

SDev . o o o o . o o o o .OOOl %RSD 97.07 105.4 407.5

Avge - * 0000 . o o o o . o o o o 2203/2 Pd3 4 04 - . 0000 .OOOl

. o o o o .OOOl 1386. 127.4

Sb2068 - . 0010

. o o o o 1.626

S - 1820 .0002 . o o o o 19.14

#1 - . 0 0 0 0 . o o o o .OOOl #2 - . 0 0 0 0 . o o o o - . 0001

- . 0000 .0002 . o o o o . o o o o

.0002

.0002 - . 0010 - .OOlO

Elem Sc3613 1960/1 1960/2

SDev 1.57 . o o o o .OOOl %RSD 1.597 31.70 117.6

Avge 98.34 - . 0001 . o o o o Si2881 Sn1899 .0013 . o o o o .OOOl . o o o o 8.094 521.3

Sr4215 - . 0000

. o o o o 312.4

Th2837 . o o o o . o o o o 55.74

.0014 . o o o o

.0012 - . 0000 . o o o o - . o o o o

. o o o o

. o o o o #1 97.23 - * 0001 . o o o o #2 99.45 - . 0001 .OOOl

U 4090

SDev . o o o o . o o o o .0003 %RSD 24.65 1.213 49.46

Elem Ti3349 T11908 - Avge - .OOOl - . 0002 - . 0006

V 2924 W - 2079 - . 0000 .OOOl

. o o o o .OOOl 36.84 136.5

- Y - 3710 . o o o o . o o o o 17.28

Zn2062 . o o o o . o o o o 12.46

. o o o o

. o o o o ’ #I - . 0001 - .0002 - . 0004

# 2 - . 0001 - . 0002 - . 0007 - . 0000 .OOOl - . o o o o . o o o o

. o o o o

. o o o o

Elem Zr3496

SDev . o o o o Avge - . o o o o

%RSD 187.3

#I - * 0000 # 2 . o o o o

Standardization Rpt.

IntStd Mode Elem Wavlen Avge SDev %RSD

#1 #2

1 *Counts sc 3 6 1 . 3 8 4

1 5 6 1 8 . 5 7 1 . 5 8 8 3 5 1

983320

972276 994364

2 Time - - - - 1 0 0 0 0 . o o o o o o o . o o o o o o o

1 0 0 0 0 1 0 0 0 0

3 NOTUSED - - - -

0 4 / 1 6 / 0 7 0 5 : 0 7 : 5 5 PM page 2

0 1 0 0 70 7 NOTUSED

Standardization Rpt. 04/16/07 05:12:21 PM

Method: DAILY2 Standard: clp-std4 Run Time: 04/16/07 17:08:07

Elem Ag3280 As1890 2203/1 2203/2 Avge .0767 .0943 .2740 .2418 SDev .OOOl .OOOl .0042 .0014 %RSD .1633 .0797 1.541 .5719

#I . 0 7 6 6 .0943 -2769 .2408 # 2 . 0 7 6 8 .0944 .2710 .2428

Elem T11908 Avge .1699 SDev .OOOl %RSD .0787

#1 .1698 # 2 .1700

IntStd 1 2 3 4 Mode *Counts Time NOTUSED NOTUSED Elem sc Wavlen 361.384 - - Avge 1000602 10000

9411.591 . O O O O O O O - - - - SDev %RSD .9405929 . O O O O O O O - - - -

- - - - - - - - - - - - - -

- - - - 993947 10000 1007257 10000 - - - - #1

# 2

Sb2068 .1348 . 0 0 0 3 .2218

.1346

.1351

5 NOTUSED - -

1960/1 .1691 .0027 1.627

.1711

.1672

6 NOTUSED - -

Page 1

010071 1960/2 .1890 .0009 .5046

-1884 .1897

7 NOTUSED - -

Standardization Rpt. 04/16/07 05:16:06 PM Page 1

Method: DAILY2 Standard: c lp - stdl Run Time: 04/16/07 17:12:33

Elem Avge SDev %RSD

#1 #2


#1 #2

A13082 .0882 . o o o o .0069

,0882 .0882

1 *Counts sc 361.384 993242 25773.34 2.594868

1011467 975018

Ca3179 .2199 .0007 .3360

.2194

.2204


10000 10000

Fe2714 .0744 .0002 .2349

.0743

.0745

3 NOTUSED - - - - - - - - - -

- - - -

K 7664 .1867 .0006 .3097

.1871

.1863

4 NOTUSED

-

- - - - - - - - - -

- - - -

Li6707

.008 .2836

2.892 2.880

5 NOTUSED

2.886

- - - - - - - - - -

- - - -

010072 Mg2790 .0864 .0002 .1818

.0863

.0865

6 NOTUSED - - - _ - - - - - -

- - - -

Na3302 .0065 . o o o o -4438

. 0 0 6 5

.0064

7 NOTUSED - - - - - - - - - -

- - - -


Method: DAILY2 Standard: clp - std5 R u n Time: 04/16/07 17:16:18

04/16/07 05:19:46 PM

P 1782 Elem B - 2496 Bi2230 Mo2020 - Avge .1438 .0254 .2618 .0107 SDev .0002 . o o o o - 0 0 0 4 . O O O l %RSD .1629 .0433 -1684 .9480

#1 .1440 .0254 -2615 .0106 #2 .1437 .0254 -2621 .0107

Elem Ti3349 Avge 2.844 SDev . 0 0 5 %RSD .1681

#1 2.847 #2 2.840

IntStd 1 2 3 4 Mode *Counts Time NOTUSED NOTUSED Elem sc Wavlen 361.384 - - Avge SDev %RSD

- - - - - - - - - -

1050666 10000 - - - - 4 0 5 2 7 . 1 2 . O O O O O O O - - - - 3.857279 . O O O O O O O - - - -

- - - - 1079323 10000 #2 1022009 10000 - - - - #1

Si2881 .1348 . 0 0 0 6 .4826

.1352

.1343

NOTUSED - -

page 1

010073

Sn1899 Sr4215 -1226 2.490 . O O O l - 0 0 0 .0832 .0194

.1225 2.490 2.490 .1227

b NOTUSED - - - -

Standardization Rpt. 04/16/07 05:23:27 PM Page 1

Method: DAILY2 Standard: clp - std2 Run Time: 04/16/07 17:19:58

Elem Ba4934 Be3130 Cr2677 Cu3247 Avge .9535 1.352 .4100 .2883 SDev . o o o o .001 .0004 . o o o o %RSD .0020 -0469 .lo55 .0134

#1 . 9 5 3 5 1.351 .4103 .2883 #2 .9535 1.352 .4096 -2882

IntStd 1 2 3 4 Mode *Counts Time NOTUSED NOTUSED Elem sc Wavlen 361.384 - - - - - - Avge 1012105 10000 - - - - SDev 4823.882 . O O O O O O O - - - - %RSD .4766188 . O O O O O O O - - - -

- - - - - -

1015516 10000 - - - - 1008694 10000 - - - -

#1 # 2

Ni2316 .2941 .0011 -3645

.2949

.2934

6 NOTUSED - -

010074

7 NOTUSED - -

Standardization Rpt. 04/16/07 05:27:12 PM page 1

Method: DAILY2 Standard: clp - std3 Run Time: 04/16/07 17:23:39 010075 Elem Cd2265 Co2286 Mn2576 V - 2924 Zn2062 Avge .a802 .1828 .9574 .1885 -2350 SDev .0006 . O O O l . O O O l .OOOl . o o o o %RSD .0622 .0360 . 0 0 6 0 .0773 .0036

#1 .879a .1829 .9574 .1884 .2350 #2 .8806 .1828 .9574 -1886 -2350

IntStd 1 2 3 4 5 6 7 Mode *Counts Time NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Elem sc Wavlen 361.384 - - Avge 1013104 10000 SDev 4121.726 . O O O O O O O - - %RSD .4068411 . O O O O O O O - - - - - - - - - -

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -

- - - - - - - -


Method: DAILY2 Standard: clp-std6 Run Time: 04/16/07 17:27:24

~

04/16/07 05:31:15 PM

S 1820 Elem La3988 Na5889 Pd3404 - Avge .4453 .0375 .1753 .0200 SDev .0004 . 0 0 0 2 . O O O l . O O O l %RSD .0987 .5967 .0507 .2538

#1 .4450 .0376 .1753 .0200 #2 .4456 .0373 .1752 .0199

Elem Y - 3710 Zr3496 Avge .7106 1.891 SDev . O O O l . 0 0 3 %RSD .0207 .1506

#I .7107 1.889 # 2 .7105 1.893


#1 #2

1 *Counts sc 361.384 1021304 4626.600 .4530093

1024575 1018032

2 Time

- - 1 0 0 0 0 . o o o o o o o . o o o o o o o

1 0 0 0 0 1 0 0 0 0

3 4 NOTUSED NOTUSED

page 1

010076 Th2 8 3.7 U - 4090 W - 2079 . 0 9 1 5 .0594 .1509 . o o o o . o o o o . o o o o .0135 .0052 .0093

.0915 * 0594 .1509

.0915 .0594 .1509

6 NOTUSED

7 NOTUSED - -

Analysis Report QC Standard 0 4 / 1 6 / 0 7 0 5 : 3 6 : 0 3 PM Page 1

Method: DAILY2 S a m p l e N a m e : icv/ccv Run T ime : 0 4 / 1 6 / 0 7 1 7 : 3 1 : 2 8 C o m m e n t : Mode: CONC C o r r . F a c t o r : 1

E l e m U n i t s Avge S D e v %RSD

#1 #2

E r r o r s V a l u e Range

E lem U n i t s Avge SDev %RSD

#1 #2

E r r o r s V a l u e Range


#1 #2

Errors V a l u e Range


#I #2

E r r o r s Value Range

E l e m

Ag3280 PPm . 9 7 8 7 . 0 0 0 3 .0352

. 9 7 8 9

.9784

QC P a s s 1 . 0 0 0 1 0 . 0 0

Ca3179 PPm 1 9 . 8 1

. 0 4 . 1 9 5 0

1 9 . 7 9 1 9 . 8 4

QC P a s s 2 0 . 0 0 1 0 . 0 0

La3988 PPm 4 . 9 9 0

. 0 0 4 . 0 8 6 1

4 . 9 9 4 4 . 9 8 7

QC P a s s 5 . 0 0 0 1 0 . 0 0

Ni2316 PPm 4 . 9 9 0

. 0 0 4 . 0 9 0 1

4 . 9 8 7 4 . 9 9 3

QC P a s s 5 . 0 0 0 1 0 . 0 0

Sc3613

A13082 PPm 9 . 8 2 8

. 0 0 3 . 0 3 1 6

9 . 8 2 6 9 . 8 3 0

QC P a s s 1 0 . 0 0 1 0 . 0 0

Cd2265 PPm 1 . 0 0 6

. 0 0 5 . 4 5 0 9

1 . 0 0 3 1 . 0 0 9

QC P a s s 1.000 1 0 . 0 0

L i 6 7 0 7 PPm 4 . 7 2 7

. 0 1 3 . 2 7 5 5

4 . 7 3 6 4 . 7 1 8

QC Pass 5 . 0 0 0 1 0 . 0 0

P 1 7 8 2

4 . 8 2 5 .016

. 3 2 6 4

4 . 8 1 4 4 . 8 3 6

QC P a s s 5 . 0 0 0 1 0 . 0 0

1 9 6 0 / 1

PPm

As1890 PPm 5 . 0 9 9

. 0 0 9 . 1 7 4 7

5 . 0 9 3 5 . 1 0 5

QC P a s s 5 . 0 0 0 1 0 . 0 0

Co2286 PPm 5 . 1 1 8

. 0 0 8 . 1 6 0 6

5 . 1 1 2 5 . 1 2 4

QC P a s s 5 . 0 0 0 1 0 . 0 0

Mg2790 PPm 1 9 . 9 6

. 0 3 . 1 5 0 7

1 9 . 9 3 1 9 . 9 8

QC P a s s 2 0 . 0 0 1 0 . 0 0

2 2 0 3 / 1 PPm 4 . 9 4 3

. 0 0 5 . 0 9 5 5

4 . 9 3 9 4 . 9 4 6

NOCHECK

1 9 6 0 / 2

B 2496

5 . 0 1 7 . 0 1 5

. 3 0 5 5

5 . 0 0 6 5 . 0 2 8

QC P a s s 5 . 0 0 0 1 0 . 0 0

Cr2677 PPm 2 . 0 0 0

. o o o . 0 2 1 2

2 . 0 0 0 1 . 9 9 9

QC P a s s 2 . 0 0 0 1 0 . 0 0

Mn2576 PPm 1 . 0 1 9 .001

. 1 3 6 5

1 . 0 1 8 1 . 0 2 0

QC P a s s 1 . 0 0 0 1 0 . 0 0

2203 /2 PPm 4 . 9 9 5

. 0 2 0 . 3 9 7 7

5 . 0 0 9 4 . 9 8 1

NOCHECK

PPm

S i 2 8 8 1

Operator: 010077

Ba4934 PPm 1 0 . 1 9

- 0 0 .0012

1 0 . 1 9 1 0 . 1 9

QC P a s s 1 0 . 0 0 1 0 . 0 0

Cu3247 PPm 2 . 0 4 9 .001

. 0 5 7 9

2 . 0 5 0 2 . 0 4 8

QC P a s s 2 . 0 0 0 1 0 . 0 0

Mo2020 PPm 5 . 0 0 2

. 0 1 7 . 3 3 6 5

4 . 9 9 1 5 . 0 1 4

QC P a s s 5 . 0 0 0 1 0 . 0 0

Pd3404 PPm 1 . 0 1 9

. 0 0 2 . 2 2 4 2

1 . 0 1 7 1 . 0 2 0

QC P a s s 1 . 0 0 0 1 0 . 0 0

Pb2 2 0

Be3130 PPm . 9 9 3 1 . 0 0 1 2 . 1 1 7 0

. 9 9 2 3

. 9 9 3 9

QC P a s s 1 . 0 0 0 1 0 . 0 0

Fe2714 PPm 1 0 . 3 6

. 0 2 . 2 2 0 9

1 0 . 3 5 1 0 . 3 8

QC P a s s 1 0 . 0 0 1 0 . 0 0

Na3302 PPm 2 8 . 6 8

. 2 7 . 9 3 0 0

2 8 . 4 9 2 8 . 8 7

QC P a s s 3 0 . 0 0 1 0 . 0 0

S 1 8 2 0

1 . 0 4 4 . 0 1 7

1 . 5 9 0

1 . 0 5 6 1 . 0 3 3

QC P a s s 1 . 0 0 0 1 0 . 0 0

Se196

PPm

B i 2 2 3 0 PPm 5 . 1 0 2

. 0 0 4 . 0 7 6 7

5 . 1 0 5 5 . 1 0 0

QC P a s s 5 . 0 0 0 1 0 . 0 0

K 7664 PPm

4 1 7 . 9 5 .01

. 0 4 9 3

Q 1 7 . 9 4 Q 1 7 . 9 5

QC F a i l 2 0 . 0 0 1 0 . 0 0

Na5889 PPm

Q 4 9 . 8 5 .15

- 2 9 7 9

Q 4 9 . 9 5 Q 4 9 . 7 4

QC F a i l 3 0 . 0 0 1 0 . 0 0

Sb2068 PPm 1 . 0 1 2

. 0 0 4 . 4 4 2 9

1 . 0 0 9 1 . 0 1 5

QC P a s s 1 . 0 0 0 1 0 . 0 0

Sn1899

Analysis Report

Units %R Avge 100.5 SDev - 6 %RSD .5989

#I 101.0 #2 100.1

Errors NOCHECK Value Range

Elem Sr4215 Units ppm Avge 4.903 SDev . 0 0 7 %RSD .1455

#1 4.908 #2 4.898

Errors QC Pass Value 5.000 Range 10.00

Elem Y 3710 Units ppm Avge 5.086 SDev .005 %RSD .0905

#1 5.083 #2 5.090

Errors QC Pass Value 5.000 Range 10.00

QC Standard

PPm PPm 5.093 5.156 .009 .019 .1683 .3730

5.087 5.169 5.099 5.142

NOCHECK NOCHECK

Th2837 Ti3349 PPm PPm .9983 4.809 .0031 .005 .3105 .1135

1.001 4.805 .9961 4.813

QC Pass QC Pass 1.000 5.000 10.00 10.00

Zn2062 Zr3496 PPm PPm 1.024 4.953 .003 .001 .2656 -0119

1.022 4.953 1.026 4.952

QC Pass QC Pass 1.000 5.000 10.00 10.00

PPm

04/16/07 05 :36: 03 PM page 2

PPm PPm O&Q,078 5.063 4.978 5.135 5.145 .003 .012 .010 .010 .0612 .2345 .1941 .1993

5.061 4.986 5.142 5.137 5.066 4.970 5.128 5.152

QC Pass QC Pass QC Pass QC Pass 5 * 000 5.000 5.000 5.000 10.00 10.00 10.00 1 0 . 0 0

T11908 U - 4090 V - 2924 W - 2079 PPm PPm PPm PPm 5.323 1.022 5.062 1.098

. 0 0 5 .019 . o o o -002 .0993 1.829 .0078 -1782

5.062 1.096 5.327 1.009 5.320 1.036 5.063 1.099

QC Pass QC Pass QC Pass QC Pass 5.000 1.000 5.000 1.000 10.00 1 0 . 0 0 10.00 10.00

Analysis Report

I n t S t d Mode Elem Wavlen Avge SDev %RSD

#1 # 2

1 *Counts sc 3 6 1 . 3 8 4 9 8 8 4 9 8 5 9 6 6 . 5 6 7 . 6 0 3 5 9 9 3

9 9 2 7 1 7 9 8 4 2 7 9

QC Standard


1 0 0 0 0 10000

3 NOTUSED - -

0 4 / 1 6 / 0 7 0 5 : 3 6 : 0 3 PM page 3

010079 4 5 6 7 NOTUSED NOTUSED NOTUSED NOTUSED

A n a l y s i s R e p o r t B l a n k Sample 0 4 / 1 6 / 0 7 0 5 : 4 0 : 5 1 PM Page 1

O p e r a t o r : 010080 Method: DAILY2 S a m p l e N a m e : icb/ccb R u n T i m e : 0 4 / 1 6 / 0 7 1 7 : 3 6 : 1 6 C o m m e n t : Mode: CONC C o r r . F a c t o r : 1

E l e m U n i t s A v g e SDev %RSD

#1 #2

E r r o r s H i g h Low


#1 #2



#1 #2



#1 #2


Ag3280 PPm . 0 0 0 6 . 0 0 0 6 1 0 4 . 8

.0011

. 0 0 0 2

LC P a s s . 0 0 5 0 - - 0 0 5 0

C a 3 1 7 9 PPm . 0 0 1 2 . 0 0 1 6 1 3 2 . 9

- 0 0 2 3 . O O O l

LC P a s s . O S 0 0 - . 0 5 0 0

L a 3 9 8 8 PPm . 0 0 0 5 . 0 0 1 3 2 4 9 . 0

- 0 0 1 4 - . 0 0 0 4

LC P a s s . 0 0 5 0 - . 0 0 5 0

N i 2 3 1 6 PPm . 0 0 1 7 . 0 0 0 8 4 9 . 1 8

. 0 0 2 3

.0011

LC P a s s . 0 0 5 0 - . 0 0 5 0

A13082 PPm . 0 0 4 5 . 0 1 3 0 2 8 9 . 6

. 0 1 3 7 - . 0 0 4 7

LC P a s s . 0 5 0 0 - . 0 5 0 0

C d 2 2 6 5 PPm .OOOl . 0 0 0 2 1 4 9 . 0

. 0 0 0 2 - . 0 0 0 0

LC Pass . 0 0 5 0 - - 0 0 5 0

L i 6 7 0 7 PPm . O O O l . 0 0 0 2 4 0 2 . 1

. 0 0 0 2 - . 0 0 0 1

LC Pass . 0 0 5 0 - . 0 0 5 0

P 1 7 8 2

- . O l O O - 0 0 0 6

5 . 7 8 3

PPm

- . 0 0 9 6 L - . 0 1 0 4

LC Pass . O l O O - . 0 1 0 0

E l e m S c 3 6 1 3 1 9 6 0 / 1

A s 1 8 9 0 PPm . 0 0 0 5 . 0 0 1 3 2 4 9 . 5

. 0 0 1 5 - . 0 0 0 4

LC P a s s . 0 0 5 0 - . 0 0 5 0

Co2286 P P m . 0 0 0 4 . 0 0 1 2 2 7 8 . 8

. 0 0 1 2 - . 0004

LC P a s s . 0 0 5 0 - . 0 0 5 0

Mg2790 PPm . 0 0 4 0 . 0 0 6 7 1 6 8 . 3

. 0 0 8 7 - . 0 0 0 8

LC P a s s . 0 5 0 0 - . 0 5 0 0

2 2 0 3 / 1 PPm . 0 0 3 1 . 0 0 1 5 4 8 . 8 5

. 0 0 4 2 - 0 0 2 0

NOCHECK

1 9 6 0 / 2

B 2 4 9 6

. 0 1 2 9

. 0 0 4 4 3 4 . 2 8

. 0 1 6 0

. 0 0 9 8

LC P a s s . 0 5 0 0 - . 0500

C r 2 6 7 7 PPm . 0 0 0 3 . 0 0 0 9 3 1 8 . 2

. 0 0 0 9 - . 0 0 0 3

Pi%

LC P a s s . 0 0 5 0 - . 0050

Mn2576 PPm . O O O l . o o o o 5 0 . 9 8

. O O O l

. O O O l

LC P a s s . 0 0 5 0 - . 0 0 5 0

2 2 0 3 / 2 PPm . 0 0 0 8 . O O O l 8 . 1 2 0

. 0 0 0 9

. 0 0 0 8

NOCHECK

S i 2 8 8 1

B a 4 9 3 4 PPm . 0 0 0 3 . 0 0 0 2 9 1 . 2 7

. 0 0 0 4 -0001

LC P a s s . 0 0 5 0 - . 0 0 5 0

C u 3 2 4 7 PPm . 0 0 1 2 . 0 0 0 8 6 8 . 6 7

.0018

. 0 0 0 6

LC P a s s . 0 0 5 0 - . 0 0 5 0

Mo2020 PPm . 0 0 1 8 . 0 0 0 6 3 6 . 6 5

. 0 0 2 2

. 0 0 1 3

LC Pass . 0 0 5 0 - . 0 0 5 0

P d 3 4 0 4 PPm . 0 0 3 9 . 0 0 3 9 9 8 . 0 0

H . 0 0 6 7 . 0 0 1 2

LC P a s s . 0 0 5 0 - . 0 0 5 0

P b 2 2 0

B e 3 1 3 0 PPm . o o o o . O O O l 1 0 0 . 1

. O O O l

. o o o o

LC P a s s . 0 0 5 0 - . 0050

F e 2 7 1 4 PPm . 0 2 5 9 . 0 1 2 0 4 6 . 2 7

- 0 3 4 4 . 0 1 7 4

LC P a s s - 0 5 0 0 - . 0 5 0 0

Na3302 PPm

L - . 0 7 3 5 . 4 5 0 6

6 1 3 . 1

H . 2 4 5 1 L - . 3 9 2 1

LC Low . 0 5 0 0 - . 0500

S 1 8 2 0 PPm

H . 0 2 7 5 . 0 0 2 6 9 . 3 3 5

H . 0 2 5 7 H . 0 2 9 3

LC H i g h . 0 2 0 0 - . 0 2 0 0

S e 1 9 6

B i 2 2 3 0 PPm . 0 0 3 4 . 0 0 1 2 3 4 . 9 2

. 0 0 2 6

. 0 0 4 2

LC P a s s .OlOO - - 0 1 0 0

K - 7 6 6 4 PPm . 0 0 8 9 . 0 1 4 4 1 6 1 . 3

.0191 - . 0 0 1 3

LC P a s s .1000 - . 1 0 0 0

Na5889 PPm

L - . 1 4 8 3 . O O O l

. 0 7 6 8

L - . 1 4 8 2 L- . 1 4 8 4

LC Low .0500 - . 0 5 0 0

S b 2 0 6 8 PPm . 0 0 2 4 . 0 0 2 5 1 0 4 . 3

. 0 0 4 1

. 0 0 0 6

LC P a s s .OlOO - . 0 1 0 0

S n 1 8 9 9

Analysis R e p o r t Blank Sample 04/16/07 05:40:51 PM

Units A v g e S D e v %RSD

%R 99.36 3.05 3.074

PPm PPm - . 0003 - . 0027 .0094 .0021

3740. 76.92

PPm .0052 .0035 67.01

PPm .0016 . 0 0 0 6 34.57

PPm - .0019 .0045

241.1

PPm - . 0010 .0012

124.8

#1 # 2

97.21 101.5

- . 0069 - . 0041 .0064 - . 0012

.0076

.0027 .0020 .0012

L-. 0050 -0013

- . 0018 - . 0001

E r r o r s High Low

NOCHECK NOCHECK NOCHECK L C P a s s .OlOO - . 0 1 0 0

L C P a s s . 0 0 5 0 - . 0050

L C Pass .0050 - . 0050

LC P a s s .0050 - . 0050

E l e m Units A v g e S D e v %RSD

Sr4215 Th2837 Ti3349 PPm PPm .0025 .0002 .0023 .0003 93.33 132.7

T11908 V - 2924 PPm - . 0001 .0008

851.6

U 4090 - W - 2079 PPm .OOOl

PPm .0035

PPm .0361

PPm .0029

.OOOl 118.2

.0021 61.13

.0384 106.5

.OOlO 35.33

#1 #2

.0002

. o o o o .0041 .0004 . 0 0 0 8 . o o o o

.0050

.0020 .0632 .0089

.0005 - . 0007

-0022 .0036

L C Pass LC P a s s .OlOO .0050 - . 0100 - . 0 0 5 0


LC Pass .0050 - . 0 0 5 0

LC P a s s .OlOO - . 0100

L C P a s s .loo0 - . 1 0 0 0

LC P a s s .0050 - . 0050

LC P a s s .OlOO - .0100

E l e m Units A v g e S D e v %RSD

Y 3710

.0002

.0002 95.26

PPm Zn2 0 62 Zr3496 PPm PPm . o o o o .0011 .0002 .0008 6993. 70.74

#I #2

. 0 0 0 4

.OOOl . O O O l .0017 - . 0001 . 0 0 0 6


LC Pass .0050 - .0050

L C Pass LC P a s s .0050 -0050 - . 0050 - . 0050

Analysis Report


#1 #2

1 *Counts sc 3 6 1 . 3 8 4 977025 3 0 0 5 2 . 0 4 3 . 0 7 5 8 7 2

955775 998275

Blank Sample

2 3 Time NOTUSED - - - - - - - - 10000 - - . o o o o o o o - - . o o o o o o o - -

- - 10000 10000 - -

0 4 / 1 6 / 0 7 05 :40 :51 PM

4 NOTUSED

5 6 NOTUSED NOTUSED

page 3

010082 7 NOTUSED

Analysis Report QC Standard

Method: DAILY2 Sample Name: cri Run Time: 04/16/07 17:44:46 Comment : Mode: CONC Corr. Factor: 1

Elem Units Avge SDev %RSD

#1 #2

Errors Value Range


#1 #2

Errors Value Range


#1 #2

Errors Value Range


#1 #2

Errors Value Range

Elem

Ag3280 PPm .0190 .0012 6.164

.0182

.0198

QC Pass .0200 50.00

Ca3179 PPm - . 0024 .0011

44.10

- . 0017 - .0032

NOCHECK

La3988 PPm - . 0009 .0018

195.5

- . 0022 .0004

NOCHECK

Ni2316 PPm .0798 * 0002 .2539

.0800

.0797

QC Pass .0800 50.00

Sc3613

A13082 PPm .0904 .0008 .8330

.0899

.0909

QC Pass . l o o 0 50.00

Cd2265 PPm .OlOO . 0 0 0 5 4.549

.0097

.0103

QC Pass .OlOO 50.00

Li6707 PPm .0705 .0001 .1365

.0705

.0706

QC Pass . l o o 0 50.00

P 1782

.0883

.0126 14.23

.0795

.0972

QC Pass . l o o 0 50.00

1960/1

PPm

As1890 PPm .0223 .0013 5.873

.0213

.0232

QC Pass .0200 50.00

Co2286 PPm .0988 .0007 .6817

.0983

.0993

QC Pass . l o o 0 50.00

Mg2790 PPm - . 0069 .0106

154.7

- -0144 .0006

NOCHECK

2203/1 PPm .0076 .0012 15.87

.0085

.0068

NOCHECK

1960/2

04/16/07 05:49:21 PM Page 1

Operator: 010083

B 2496

.lo39

. 0 0 1 2 1.189

.lo30

.lo48

QC Pass . l o o 0 50.00

Cr2677 PPm .0183 .OOOl .2880

.0184

.0183

QC Pass .0200 50.00

Mn2576 PPm .0295 . o o o o .0821

.0295

.0295

QC Pass .0300 50.00

2203/2 PPm .0047 .OOOl 3.109

.0048

.0046

NOCHECK

PPm

Si2881

Ba4934 PPm .0207 . O O O l .4650

.0207

.0208

QC Pass .0200 50.00

Cu3247 PPm .0479 -0005 .9774

. 0 4 7 6

.0482

QC Pass .0500 50.00

Mo2020 PPm .0212 .0007 3.510

.0207

.0217

QC Pass .0200 50.00

Pd3404 PPm - . 0080 .0021

26.77

- .0065 - . 0095

NOCHECK

Pb220

Be3130 PPm .0099 . o o o o .3561

.0099

.0098

QC Pass .OlOO 50.00

Fe2714 PPm .0950 .0031 3.231

.0928

.0971

QC Pass -1000 50.00

Na3302 PPm - .3956 .0616

15.58

- .3521 - .4392

NOCHECK

S 1820

.0232

.0043 18.68

.0202

.0263

NOCHECK

PPm

Se196

Bi2230 PPm .0039 .0029 74.36

.0059

.0018

NOCHECK

K 7664 P b - . 0407 10.02

- . 0378 - . 0436 NOCHECK

.0041

Na5889 PPm - .1939 .0021

1.069

- . 1924 - .1954

NOCHECK

Sb2068 PPm .1207 .OOOl .0990

.1206

.1208

QC Pass .1200 50.00

Sn1899

Analysis Report

Units Avge SDev %RSD

#1 #2

Errors Value Range


#1 #2

Errors Value Range


#1 #2

Errors Value Range

%R 1 0 0 . 7

1 . 6 1 . 5 4 4

9 9 . 6 1 1 0 1 . 8

NOCHECK

S r 4 2 1 5 PPm . 0 2 0 5 .OOOl . 2 9 3 2

. 0 2 0 4

. 0 2 0 5

QC Pass . 0 2 0 0 5 0 . 0 0

Y 3 7 1 0

- . 0 0 0 1 . o o o o

9 . 7 0 8

- . 0 0 0 1 - . 0 0 0 1

NOCHECK

PPm

QC Standard

PPm . 0 1 1 7 - 0 0 1 5 1 2 . 9 5

. 0 1 2 8

. 0 1 0 6

NOCHECK

T h 2 8 3 7 PPm - . 0 0 1 5

. 0 0 2 9 1 8 4 . 8

. 0 0 0 5 - . 0 0 3 6

NOCHECK

Zn2 0 6 2 PPm . 0 3 9 6 . 0 0 0 3 . 7 1 0 5

. 0 3 9 8

. 0 3 9 4

QC Pass . 0 4 0 0 5 0 . 0 0

PPm . 0 1 2 2 . 0 0 3 8 3 1 . 0 2

. 0 0 9 5

. 0 1 4 9

NOCHECK

T i 3 3 4 9 PPm . 0 1 9 2 . o o o o . 1 9 4 7

. 0 1 9 2

. 0 1 9 3

QC Pass . 0 2 0 0 so. 00

Z r 3 4 9 6 PPm . 0 8 8 5 . 0 0 0 7 . 7 6 3 1

. 0 8 8 0

. 0 8 8 9

QC Pass . l o o 0 5 0 . 0 0

0 4 / 1 6 / 0 7 0 5 : 4 9 : 2 1 PM

PPm . l o 6 2 . 0 0 1 3 1 . 2 2 7

. l o 5 3

. l o 7 1

QC Pass . l o o 0 5 0 . 0 0

T 1 1 9 0 8 PPm . 0 2 0 8 . 0 0 3 1 1 4 . 7 4

. 0 2 3 0

. 0 1 8 6

QC Pass . 0 2 0 0 5 0 . 0 0

PPm . 0 0 5 7 . 0 0 0 5 8 . 6 9 6

- 0 0 6 1 . 0 0 5 4

QC Pass . 0 0 6 0 5 0 . 0 0

U 4 0 9 0

. 1 9 2 8

. 0 3 6 5 1 8 . 9 2

. 1 6 7 0

. 2 1 8 6

QC Pass . 2 0 0 0 5 0 . 0 0

PPm

PPm . 0 1 2 0 . 0 0 2 0 1 6 . 7 2

. 0 1 0 6

. 0 1 3 5

QC Pass . O l O O 5 0 . 0 0

V 2 9 2 4

. 0 9 8 4

. 0 0 0 3

. 3 2 7 1

. 0 9 8 1

. 0 9 8 6

QC Pass .1000 5 0 . 0 0

PPm

O&QO84 . 0 9 6 7 . 0 0 1 4 1 . 3 9 3

. 0 9 5 8 * 0 9 7 7

QC Pass .1000 5 0 . 0 0

W 2 0 7 9

. 0 0 4 1

. 0 0 0 4 1 0 . 6 3

PPm

. 0 0 3 7

. 0 0 4 4

NOCHECK

Analysis Report


#1 #2

1 *Counts sc 361,384 990325 15242.39 1.53913 0

979547 1001103

QC Standard


10000 1 0 0 0 0

3 NOTUSED

04/16/07 05:49:21 PM

4 NOTUSED - - - -

5 NOTUSED - - - -

6 NOTUSED _ - - -

page 3

010085 7

NOTUSED


Method: DAILY2 Sample Name: icsa Run Time: 04/16/07 17:49:33 Comment : Mode: CONC Corr. Factor: 1

Elem Ag3280 A13082 As1890 Units ppm PPm PPm Avge - . 0006 506.6 .0015 SDev . o o o o .9 .0045 %RSD .8566 .1806 303.4

#1 - . 0006 507.2 - . 0017 #2 - . 0006 506.0 .0047

Errors NOCHECK QC Pass NOCHECK Value 500.0 Range 20.00


Avge 461.8 - . 0026 .0013 SDev 1.7 . o o o o .0006 %RSD . 3 6 8 5 1.455 48.59

Units ppm PPm PPm

#1 460.6 - . 0026 .0018 #2 463 . O - . 0026 .0009

Erro r s QC Pass NOCHECK NOCHECK Value 500.0 Range 20.00

Elem La3988 Li6707 Mg2790 Units ppm PPm PPm Avge .0045 ,0004 534.4 SDev .0005 . o o o o .4 %RSD 11.35 4.523 .0757

#I .0041 .0004 534.1 #2 .0048 .0003 534.7

Errors NOCHECK NOCHECK QC Pass Value 500.0 Range 20.00

Elem Ni2316 P - 1782 2203/1

Avge .0015 .0109 .0192 SDev .0006 .0006 .0028 %RSD 39.77 5.900 14.74

Units ppm PPm PPm

#1 .0019 .0105 .0172 #2 .0011 .0114 .0212

Errors NOCHECK NOCHECK NOCHECK Value Range

Elem Sc3613 1960/1 1960/2

04/16/07 05:54:08 PM

Operator:

B 2496 Ba4934 Be3130 Bi2230

- . 0122 .0024 . 0 0 0 2 . 0 0 1 5 .0019 .OOOl . o o o o .OOlO

15.26 3.094 5.428 64.16

PPm PPm PPm PPm

- . 0108 .0024 .0002 .0022 - . 0135 .0025 .0002 .0008

NOCHECK NOCHECK NOCHECK NOCHECK

Cu3247 Fe2714 K - 7664 Cr2677 PPm PPm PPm PPm - . 0016 .0024 187.5 .0131 .0004 .0007 .4 .0186

.2063 142 . O 25.82 28.91

- . 0019 .0019 187.2 - . 0001 - . 0013 .0029 187.7 .0263

NOCHECK NOCHECK QC Pass NOCHECK 200.0 20.00

Mn2576 Mo2020 Na3302 Na5889 PPm PPm PPm PPm .0064 - .0016 .6830 - . 1295 .OOOl .0016 -3368 .0088 1.308 100.4 49.31 6.776

.0065 - . 0005 .4448 - .1233

.0064 - . 0028 .9212 - . 1357 NOCHECK NOCHECK NOCHECK NOCHECK

2203/2 Pd3404 S 1820 Sb2068

- . 0075 .0073 .0340 .0041 .0035 .0020 .0009 .0211

46.56 27.01 2.536 517.7

PPm PPm PPm PPm

- . 0050 .0059 .0346 .0190 - . 0100 .0087 .0334 - . 0108 NOCHECK NOCHECK NOCHECK NOCHECK

Si2881 Pb220 Se196 Sn1899

Analysis Report QC Standard 04/16/07 05:54:08 PM Page 2

Units Avge SDev %RSD

#I #2


E l e m Units Avge SDev %RSD

#1 #2



#I #2


%R 90.03

.83 .9180

90.62 89.45

NOCHECK

Sr4215 PPm .0157 . o o o o .1519

.0156

.0157

NOCHECK

Y 3710 PPm - . 0008

. o o o o 5.068

- . 0008 - . 0007

NOCHECK

PPm - . 0067 .0078

117.1

- .0122 - . 0011

NOCHECK

Th2837 PPm - . 0558 .0034

6.137

- . 0582 - .0534

NOCHECK

Zn2062 PPm .0063 .0017 27.55

.0075

.0051

NOCHECK

PPm - . 0047 .0072

151.8

.0003 - . 0098 NOCHECK

Ti3349 PPm - . 0006 .0002

35.39

- . 0005 - . 0008

NOCHECK

Zr3496 PPm - .0013 .0006

46.07

- . 0017 - . 0008 NOCHECK

PPm .0316 -0008 2.442

.0321

.0310

NOCHECK

T11908 PPm .0044 .0054 121.8

.0082

.0006

NOCHECK

PPm . 0 0 1 4 .0014 99.19

.0024

.0004

NOCHECK

U 4090

- . 0301 .0159

52.93

PPm

- . 0413 - . 0188 NOCHECK

PPm - . 0054 .0022

40.49

- . 0038 - . 0069 NOCHECK

V 2924 PPm - . 0016 .0004

27.50

- . 0019 - . 0013 NOCHECK

010087 PPm - . 0056 .0021

37.93

- . 0041 - . 0071 NOCHECK

W 2079

.OOOl

.0085 7038.

.0061

PPm

- . 0059 NOCHECK

Analysis Repor t QC Standard

IntStd 1 2 3 Mode *Counts Time NOTUSED Elem sc Wavlen 361.384 - - - - Avge 885346 10000 SDev 8085.059 . O O O O O O O - - %RSD .9132090 . o o o o o o o - -

- _ - -

- -

891063 1 0 0 0 0 - - #1 #2 879629 1 0 0 0 0 - -

04/16/07 0 5 : 5 4 : 0 8 PM

4 5 6 NOTUSED NOTUSED NOTUSED - - - - - -

page 3

OlOOSS 7 NOTUSED - - - -


Method: DAILY2 Sample Name: icsab Run Time: 04/16/07 17:54:20 Comment : Mode: CONC Corr. Factor: 1

Elem Ag3280 A13082 As1890

Avge 1.083 512.9 1.045 SDev . o o o .2 * 001 %RSD .0433 .0326 .1245

Units ppm PPm PPm

#1 1.082 512.8 1.046 #2 1.083 513.0 1.044

Errors QC Pass QC Pass QC Pass Value 1.000 500.0 1.000 Range 20.00 20.00 20.00


Avge 462.7 .9597 .4923 SDev 3.1 .0027 .0034 %RSD .6791 .2817 .6873

Units ppm PPm PPm

#1 465.0 .9617 .4947 #2 460.5 .9578 .4899

Errors QC Pass QC Pass QC Pass Value 500.0 1.000 .5000 Range 20.00 20.00 20.00


Avge .0037 1.218 540.2 SDev .0005 .009 1.7 %RSD 12.22 .7288 .3133

Units ppm PPm PPm

#I .0041 1.211 541.4 #2 .0034 1.224 539.0

Errors NOCHECK NOCHECK QC Pass Value 500.0 Range 20.00

Elem Ni2316 P 1782 2203/1

Avge .9432 1.019 .9823 SDev .0073 .013 .0300 %RSD .7772 1.299 3.056

Units ppm P& PPm

#1 .9484 1.010 1.004 #2 .9380 1.029 .9611

Errors QC Pass NOCHECK NOCHECK Value 1.000 Range 20.00

Elem Sc3613 1960/1 1960/2

04/16/07 05:58:57 PM Page 1

010089 Operator:

B 2496 Ba4934 Be3130 Bi2230

1.032 .5365 .4948 .0053 -004 .0023 .0014 .0048 .3951 .4228 .2932 90.43

PPm PPm PPm PPm

1.029 .5349 .4958 .0086 1.035 .5381 .4937 .0019

QC Pass QC Pass QC Pass NOCHECK 1.000 . s o 0 0 .5000 20.00 20.00 20.00

Cr2677 Cu3247 Fe2714 K - 7664 PPm PPm PPm PPm .4962 .5563 188.8 - . 0505 -0019 .0033 .5 .0268 .3733 .5924 .2534 53.01

.4975 .5539 189.1 - .0316

.4948 .5586 188.5 - .0694

QC Pass QC Pass QC Pass NOCHECK .5000 .5000 200.0 20.00 20.00 20.00

Mn2576 Mo2020 Na3302 Na5889 PPm PPm PPm PPm .SO55 1.013 .4943 - .1605 .0012 .007 .6038 .0005 .2429 .7053 122.1 .3043

.5064 1.018 .9213 - -1602

.5046 1.007 .0674 - . 1608

QC Pass QC Pass NOCHECK NOCHECK .5000 1.000 20.00 20.00

2203/2 Pd3404 S - 1820 Sb2068 PPm PPm PPm PPm .9690 - . 0016 .0274 1.053 .0076 -0063 .0177 -011 .7832 404.1 64.77 1.014

.9744 .0029 .0148 1.046

.9637 - . 0060 .0399 1.061

NOCHECK NOCHECK NOCHECK QC Pass 1.000 20.00

Si2881 Pb220 Se196 Sn1899

A n a l y s i s Report

U n i t s %R A v g e 9 2 . 4 8 SDev 2 . 0 6 %RSD 2 . 2 3 0

#1 9 1 . 0 2 #2 9 3 . 9 4

E r r o r s NOCHECK V a l u e Range

E l e m S r 4 2 1 5 Units ppm Avge 1 . 0 4 6 SDev . 0 0 4 %RSD . 3 3 6 2

#1 1 . 0 4 4 #2 1 . 0 4 9

E r r o r s QC P a s s V a l u e 1 . 0 0 0 Range 2 0 . 0 0

E l e m Y 3 7 1 0 Units ppm A v g e - . 0 0 0 9 SDev . O O O l %RSD 1 0 . 7 1

#1 - . 0 0 0 9 #2 - . 0 0 1 0

E r r o r s NOCHECK V a l u e Range

QC Standard

PPm PPm . 9 7 1 9 . 9 9 2 8 . 0 1 2 7 . 0 1 6 6 1 . 3 0 6 1 . 6 6 9

. 9 8 0 9 1 . 0 0 5

. 9 6 2 9 . 9 8 1 1

NOCHECK NOCHECK

T h 2 8 3 7 T i 3 3 4 9 PPm PPm - . 0 4 6 7 . 9 5 3 6

. 0 0 1 5 . 0 0 0 3 3 . 2 5 5 . 0 3 1 8

- . 0 4 5 6 . 9 5 3 9 - . 0 4 7 7 . 9 5 3 4

NOCHECK NOCHECK

Zn2062 Z r 3 4 9 6 PPm P P m . 9 4 3 5 . 8 9 8 1 . 0 0 6 3 . 0 0 2 4 - 6 6 2 5 . 2 6 5 1

. 9 4 7 9 . 8 9 6 5

. 9 3 9 0 . 8 9 9 8

QC P a s s QC P a s s 1 . 0 0 0 1 . 0 0 0 2 0 . 0 0 2 0 . 0 0

OlOBYQ 0 4 / 1 6 / 0 7 0 5 : 5 8 : 5 7 PM

PPm PPm PPm PPm 1 . 0 8 5 . 9 7 3 5 . 9 8 5 9 . 9 6 1 1

. o o o . 0 1 5 1 . 0 1 5 3 . 0 0 4 3 . 0 1 2 0 1 . 5 4 8 1 . 5 5 0 . 4 4 9 2

1 . 0 8 5 . 9 8 4 1 . 9 9 6 7 . 9 5 8 0 1 . 0 8 5 . 9 6 2 8 . 9 7 5 1 . 9 6 4 1

QC P a s s QC P a s s QC P a s s QC P a s s 1 . 0 0 0 1 . 0 0 0 1 . 0 0 0 2 0 . 0 0 2 0 . 0 0 2 0 . 0 0

1 . 0 0 0 2 0 . 0 0

T11908 U - 4 0 9 0 V 2924 W 2 0 7 9

1 . 0 3 4 . 9 2 3 6 . 5 0 7 2 . 0 1 0 7 . 0 0 5 - 0 5 5 6 - 0 0 0 6 . 0 0 8 0

. 4 9 8 5 6 . 0 1 5 . 1 1 9 3 7 5 . 1 5

PPm PPm PPm PPm

1 . 0 3 0 . 9 6 2 9 . 5 0 7 7 . 0 0 5 0 1 . 0 3 7 . 8 8 4 3 . 5 0 6 8 . 0 1 6 3

QC P a s s QC P a s s QC P a s s NOCHECK 1 . 0 0 0 1 . 0 0 0 . 5 0 0 0 2 0 . 0 0 2 0 . 0 0 2 0 . 0 0

Analysis Report


#1 #2

1 *Counts sc 3 6 1 . 3 8 4 9 0 9 3 9 9 2 0 3 4 6 . 2 9 2 . 2 3 7 3 3 4

895012 9 2 3 7 8 6

QC Standard


1 0 0 0 0 1 0 0 0 0

3 NOTUSED

0 4 / 1 6 / 0 7 0 5 : 5 8 : 5 7 PM

4 NOTUSED

6 NOTUSED

page 3

010091 7 NOTUSED

Analysis Report QC Standard 04/16/07 06:03:49 PM

Method: DAILY2 Sample Name: icv/cc Run Time: 04/16/07 17:59:10 Comment : Mode: CONC Corr. Factor: 1

V Operator:

Elem Ag3280 A13082 As1890

Avge .9789 9.796 5.089 SDev .0004 -008 .001 %RSD .0395 .0792 .0106

Units ppm PPm PPm B 2496

5.032 .015 .2964

PPm Ba4934 PPm 10.19

.Ol .1177

Be3130 PPm .9943 .0005 .0527

Bi2230 PPm 5.097 .003 -0571

#1 .9791 9.802 5.090 #2 .9786 9.791 5.089

5.021 5.042

10.20 10.18

.9946

.9939 5.095 5.099


QC Pass 5.000 10.00

QC Pass 10.00 10.00

QC Pass 1.000 10.00

QC Pass 5.000 10.00

Elem Ca3179 Cd2265 (32286

Avge 19.85 1.008 5.112 SDev .03 . 0 0 2 .007 %RSD .1567 .2032 .1467

Units ppm PPm PPm Cr2677 PPm 1.998 .003 .1681

Cu3247 PPm 2.057 .002 .lo41

Fe2714 PPm 10.29

.02 .1469

K 7664 PPm Q17.90

.02 .1116

#1 19.87 1.006 5.107 #2 19.83 1.009 5.117

1.996 2.001

2.059 2.056

10.28 10.30

Q17,92 Q17.89


QC Pass 2.000 10.00

QC Pass 2,000 10.00

QC Pass 10.00 10.00

QC Fail 20.00 10.00


Avge 4.993 4.738 19.96 SDev .002 -011 .03 %RSD .0340 .2341 .1750

Units ppm PPm PPm Mn2576 Mo2020

PPm 5.008 .012 .2483

Na3302 PPm 28.53

.07 .2286

Na5889 PPm 449.95

-23 .4597

PPm 1.018 .001 -1047

#1 4.994 4.746 19.94 #2 4.991 4.730 19.99

1.017 1.018

5.000 5.017

28.49 28.58

450.11 Q49.79


QC Pass 1.000 10.00

QC Pass 5.000 10.00

QC Pass 30.00 10.00

QC Fail 30.00 10.00

Elem Ni2316 P - 1782 2203/1

Avge 4.984 4.949 4.900 SDev .008 -137 .020 %RSD .1598 2.766 .4047

Units ppm PPm PPm 2203/2 PPm 4.907 .079

1.618

Pd3404 S 1820

1.043 .015

1.429

PPm Sb2068 PPm 1.007 .OOl ,1339

PPm 1.023

. 0 0 3 .2680

#1 4.989 4.852 4.886 #2 4.978 5.046 4.914

4.963 4.851

1.021 1.025

1.053 1.032

1.006 1.008

Errors QC Pass QC Pass NOCHECK Value 5.000 5.000 Range 10.00 10.00

NOCHECK QC Pass 1.000 10.00

QC Pass 1.000 10.00

QC Pass 1.000 10.00

Elem Sc3613 1960/1 1960/2 Si2881 Pb220 Se196 Sn1899

Analysis Report QC Standard 0 4 / 1 6 / 0 7 0 6 : 0 3 : 4 9 PM

010093 PPm Units

Avge SDev %RSD

%R 1 0 1 . 3

. 7 . 6 5 5 1

PPm PPm 5 . 0 4 4 5 . 0 5 3

PPm 5 . 0 7 8

. 0 0 3 . 0 6 3 9

PPm 4 . 9 0 5

. 0 4 6 . 9 4 4 5

PPm 5 . 0 5 0

. 0 6 9 1 . 3 7 1

5.151 . 0 0 4

. 0 7 5 0 . 0 2 6 .117

.5165 2 . 3 1 3

#1 # 2

1 0 1 . 8 1 0 0 . 9

5 . 0 2 6 5 .136 5 . 0 6 3 4 . 9 7 0

5 . 0 8 0 5 . 0 7 6

4 . 9 3 7 4 . 8 7 2

5 . 0 9 9 5 . 0 0 1

5 . 1 4 8 5 . 1 5 4


NOCHECK NOCHECK NOCHECK QC Pass 5 . 0 0 0 1 0 . 0 0

QC Pass 5 . 0 0 0 1 0 . 0 0

QC Pass 5 . 0 0 0 1 0 . 0 0

QC Pass 5 . 0 0 0 1 0 . 0 0

E l e m U n i t s Avge SDev % R S D

S r 4 2 1 5 PPm 4 . 9 0 2

. 0 0 4 . 0 7 5 0

T h 2 8 3 7 T i 3 3 4 9 PPm PPm . 9 9 9 3 4 . 8 0 8 . 0 0 2 2 . 0 0 4 . 2 1 6 5 . 0 8 2 2

T11908 PPm 5 . 3 1 0 .010

. 1 8 5 3

U 4 0 9 0

* 9 9 3 7 . 0 0 9 4 - 9 4 2 1

PPm V - 2 9 2 4 PPm 5 . 0 6 2

- 0 0 3 . 0 5 6 2

W 2 0 7 9

1 . 0 9 3 . 0 0 2

. 1 8 2 5

P b

#I # 2

4 . 9 0 0 4 . 9 0 5

. 9 9 7 8 4 . 8 0 5 1 . 0 0 1 4 . 8 1 0

5 . 3 0 3 5 . 3 1 7

- 9 8 7 1 1 . 0 0 0

5 . 0 6 0 5 . 0 6 4

1 . 0 9 1 1 . 0 9 4


QC Pass 5 . 0 0 0 1 0 . 0 0

QC Pass QC Pass 1 . 0 0 0 5 . 0 0 0 1 0 . 0 0 1 0 . 0 0

QC Pass 5 . 0 0 0 10.00

QC Pass 1 . 0 0 0 1 0 . 0 0

QC Pass 5 . 0 0 0 1 0 . 0 0

QC Pass 1 . 0 0 0 1 0 . 0 0


Y 3 7 1 0

5 . 0 8 4 . 0 0 4

. 0 7 9 2

P P m Zn2062 Z r 3 4 9 6 PPm PPm 1 . 0 2 1 4 . 9 7 9

. 0 0 4 . 0 0 4 . 3 6 3 6 . 0 8 5 8

#1 #2

5 . 0 8 6 5 . 0 8 1

1 . 0 1 8 4 . 9 8 2 1 . 0 2 4 4 . 9 7 6


QC Pass 5 . 0 0 0 1 0 . 0 0

QC Pass QC Pass 1.000 5 . 0 0 0 10.00 1 0 . 0 0

Analysis Report

IntStd 1 Mode *Counts Elem sc Wavlen 361.384 Avge 996429 SDev 6496.897 %RSD .6520181

QC Standard 04/16/07 06:03:49 PM

2 3 4 5 6 Time NOTUSED NOTUSED NOTUSED NOTUSED

1 0 0 0 0 - - . o o o o o o o - - . o o o o o o o - -

page 3

010094 7 NOTUSED

Method: DAILY2 Sample Name: icb/ccb Run Time: 04/16/07 18:04:01 Comment : Mode: CONC Corr. Factor: 1


#1 #2

Errors High Low


#1 #2

Errors High Low


#I #2

Errors High Low


#I # 2

Errors High Low

Ag3280 PPm .OOlO .0008 85.10

.0016

.0004

LC Pass .0050 - . 0050 Ca3179 PPm ,0019 .0004 20.31

. 0 0 2 2

.0016

LC Pass .0500 - . 0500 La3988 PPm .0012 . 0 0 0 9 74.12

.0018

.0006

LC Pass .0050 - . 0050 Ni2316 PPm .0009 . O O l O 105.1

.0002

.0016

LC Pass .0050 - . 0050

A13082 PPm .0013 .0041 315.1

.0042 - .0016

LC Pass .0500 - . 0500

Cd2265 PPm .0002 . o o o o 5.831

.0002

.0003

LC Pass .0050 - . 0050 Li6707 PPm - . 0002 -0001

53.39

- . 0001 - .0002

LC Pass . 0 0 5 0 - . 0050 P 1782

.0027

.0106 393.2

- .0048

PPm

H. 0102

LC Pass . O l O O - . O l O O

Elem Sc3613 1960/1

As1890 PPm .0016 .0006 34.16

.0020

.0012

LC Pass .0050 - .0050

Co2286 PPm .0005 .0004 82.26

.0007

. 0 0 0 2

LC Pass .0050 - .0050

Mg2790 PPm .0046 -0021 45.22

.0061

.0032

LC Pass .0500 - . 0500 2203/1 PPm .0035 .0002 6.314

.0034

.0037

NOCHECK

1960/2

B 2496

.0122 -0034 27.85

.0146

.0098

LC Pass .0500 - . 0500 Cr2677 PPm - . 0009 .0002

26.51

- . 0007 - . 0010

LC Pass

Pi%

-0050 - . 0050 Mn2576 PPm - . 0001

. o o o o 51.39

- . 0001 - . 0001 LC Pass .0050 - . 0050

2203/2 PPm - . 0014 .0003

23.00

- . 0017 - . 0012 NOCHECK

Si2881

Operator:

Ba4934 PPm .0002 .0003 218.7

. 0 0 0 4 - . 0001

LC Pass . 0 0 5 0 - . 0050

Cu3247 PPm . o o o o .0002 1238.

. 0 0 0 2 - . 0001

LC Pass .0050 - . 0050 Mo2020 PPm * 0009 . o o o o 2.894

.0009

.OOlO

LC Pass .0050 - . 0050 Pd3404 PPm .0043 .0009 20.56

.0049

.0037

LC Pass .0050 - . 0050

Be3130 PPm . o o o o . o o o o 140.6

. o o o o

. o o o o

LC Pass .0050 - -0050

Fe2714 PPm .0289 .0165 57.15

.0172

. 0 4 0 6

LC Pass .0500 - -0500

Na3302 PPm H.0604 .3888 643.9

H.3353 L- .2145

LC High .0500 - . 0500 S 1820 PPm H. 0321 .0174 54.13

.0198 H. 0444

LC High .0200 - . 0200

Pb220 Se196

~ ~~~~~~

Page 1

010095

Bi2230 PPm .0015 .0005 33.73

.0012

.0019

LC Pass -0100 - . 0100 K 7664

.0204

.0018 9.042

.0191

.0217

P b

LC Pass .1000 - . l o o 0

Na5889 PPm L-. 1864

.0030 1.589

L-. 1885 L-. 1843

LC Low .0500 - . 0500

Sb2068 PPm .0047 .0012 24.81

.0039

.0055

LC Pass .OlOO - . 0100 Sn1899

A n a l y s i s R e p o r t Blank S a m p l e 04/16/07 06:08:39 PM OlOW?! U n i t s %R

SDev . o %RSD .0468

A v g e 101.9 P P m P P m .0023 - 0 0 1 0 .0003 .0020 13.46 193.3

P P m P P m P P m P P m .0019 .0002 -0015 .0018 .0005 .0003 .0012 .0002 27.79 122.8 83.43 12.22

#1 101.9 #2 102.0

.0026 - . 0004

.0021 .0025 .0022 . o o o o -0006 .0020 .0015 .0004 .0024 .0017

E r r o r s NOCHECK H i g h Low

NOCHECK NOCHECK LC Pass LC Pass LC Pass LC Pass . O l O O . 0 0 5 0 . 0 0 5 0 . 0 0 5 0 - . 0100 - .0050 - . 0050 - . 0050

E l e m Sr4215 U n i t s p p m A v g e .0002 S D e v . 0002 % R S D 103.0

Th2837 Ti3349 T11908 U - 4090 V - 2924 W - 2079 P P m P P m - . 0027 . o o o o

P P m P P m P P m P P m .0056 .0437 - . 0009 .0029

.0011 . o o o o 40.88 168.4

.0030 .0294 . O O O l . o o o o 53.55 67.11 13.70 1.014

#1 .0003 #2 . O O O l

- . 0035 - . 0000 - . 0 0 1 9 . o o o o

.0077 .0645 - . 0008 .0029

.0035 .0230 - . 0010 .0028

Erro r s LC Pass High . 0 0 5 0 L o w - . 0 0 5 0

LC Pass LC Pass . O l O O . 0 0 5 0 - . 0 1 0 0 - . 0 0 5 0

LC Pass LC Pass LC Pass LC Pass . O l O O .loo0 .0050 .OlOO - . 0100 - . 1000 - . 0 0 5 0 - . 0100

Y 3710 E l e m - U n i t s p p m A v g e .0002 S D e v .0002 %RSD 91.91

Zn2062 Zr3496 P P m P P m - . 0001 . O O O l . O O O l .0004

52.82 603.5

#1 .0004 #2 .OOOl

- . 0001 .0004 - . 0002 - . 0002

LC Pass LC Pass . 0 0 5 0 . 0 0 5 0 - . 0050 - . 0 0 5 0

E r r o r s LC Pass H i g h . 0 0 5 0 Low - . 0 0 5 0

Analysis Report


#1 #2

1 *Counts sc 3 6 1 . 3 8 4 1 0 0 2 1 9 3 4 9 7 . 8 0 3 2 . 0 4 9 6 7 1 4

1 0 0 1 8 4 1 1 0 0 2 5 4 5

Blank Sample

2 Time - - - - 10000 . o o o o o o o . o o o o o o o

1 0 0 0 0 1 0 0 0 0

~

0 4 / 1 6 / 0 7 0 6 : 0 8 : 3 9

5 NOTUSED - -

PM page 3

010097

A n a l y s i s R e p o r t 0 4 / 1 6 / 0 7 0 6 : 13 : 2 9 PM page 1

010098 Method: DAILY2 Sample Name: LCSW-D13E1 DF5 Operator : Run T i m e : 0 4 / 1 6 / 0 7 1 8 : 0 8 : 5 1 C o m m e n t : Mode: CONC C o r r . F a c t o r : 1

E l e m Ag3280 A13082 A s 1 8 9 0 B 2 4 9 6 B a 4 9 3 4 B e 3 1 3 0 B i 2 2 3 0

A v g e . 0 2 0 9 . 7 5 5 5 . 7 6 6 4 . 0 0 5 3 . 8 3 0 8 . 0 1 9 6 . 0 0 3 0 S D e v . 0 0 0 3 . 0 0 2 7 . 0 0 0 9 . 0 0 1 3 . 0 0 0 7 . O O O l . 0 0 2 5 %RSD 1 . 6 1 0 .3543 . 1 1 9 6 2 4 . 1 2 . 0 8 5 5 . 2 4 0 1 8 2 . 3 0

U n i t s ppm PPm PPm PPm PPm PPm PPm

#1 . 0 2 0 6 . 7 5 7 4 . 7 6 5 8 . 0 0 6 2 .8313 . 0 1 9 6 . 0 0 4 7 #2 . 0 2 1 1 .7536 . 7 6 7 0 . 0 0 4 4 . 8 3 0 3 . 0 1 9 7 . 0 0 1 3

C u 3 2 4 7 F e 2 7 1 4 K 7 6 6 4 E l e m C a 3 1 7 9 C d 2 2 6 5 Co2286 C r 2 6 7 7

A v g e 3 . 9 6 3 . 0 1 9 6 . 2 0 2 1 . 0 7 9 7 . 0 9 9 4 . 4 6 1 9 2 . 4 6 5 S D e v . 0 1 3 . 0 0 0 2 .OOOl . O O l O . 0 0 0 7 - 0 4 2 6 . 0 1 7 %RSD . 3 4 0 0 . 9 4 1 0 - 0 2 6 3 1 . 2 7 2 . 6 6 2 5 9 . 2 2 9 - 6 7 6 3


#1 3 . 9 5 4 . 0 1 9 5 . 2 0 2 0 . 0 7 9 0 . 0 9 9 9 . 4 3 1 8 2 . 4 5 3 #2 3 . 9 7 3 . 0 1 9 8 . 2 0 2 1 - 0 8 0 4 . 0 9 9 0 - 4 9 2 1 2 . 4 7 7

E l e m L a 3 9 8 8 L i 6 7 0 7 Mg2790 Mn2576 Mo2020 Na3302 Na5889

A v g e . 0 0 1 4 - . 0 0 0 0 3 . 8 9 3 . 2 0 3 0 .OOOl 3 . 5 2 6 4 . 8 7 3 SDev . 0 0 0 5 .OOOl . 0 0 8 . 0 0 0 6 . 0 0 0 3 . 2 6 8 . 0 2 8 %RSD 3 6 . 0 8 3 9 9 . 5 . 2 1 2 0 . 3 1 2 9 515 .3 7 . 5 9 1 . 5 6 6 1

U n i t s ppm PPm PPm PPm P P m P P m PPm

#1 .OOlO - . 0 0 0 1 3 . 8 8 7 . 2 0 2 5 - . 0 0 0 2 3 . 3 3 6 4 . 8 9 2 #2 . 0 0 1 7 . O O O l 3 . 8 9 9 . 2 0 3 4 . 0 0 0 3 3 . 7 1 5 4 . 8 5 3

E l e m N i 2 3 1 6 P 1 7 8 2 2 2 0 3 / 1 2 2 0 3 / 2 P d 3 4 0 4 S 1 8 2 0 S b 2 0 6 8

A v g e . 1 9 8 4 . 0 0 0 5 . 1 9 6 7 . 1 9 8 2 . 0 0 6 2 . 0 2 9 0 . 2 1 4 9 SDev . 0 0 0 3 . 0 0 8 9 . 0 0 1 8 . 0 0 2 1 . 0 0 6 3 . 0 0 1 2 . 0 2 1 9 %RSD . 1 7 6 6 1 6 8 0 . . 9 3 1 2 1 . 0 4 1 1 0 1 . 7 4 . 1 2 7 1 0 . 2 0


#I . 1 9 8 1 . 0 0 6 8 . 1 9 8 0 . 1 9 6 8 . 0 0 1 7 . 0 2 8 2 . 1 9 9 4 #2 . 1 9 8 6 - . 0 0 5 8 - 1 9 5 5 . 1 9 9 7 . 0 1 0 7 - 0 2 9 9 . 2 3 0 5

E l e m S c 3 6 1 3 1 9 6 0 / 1 1 9 6 0 / 2 S i 2 8 8 1 P b 2 2 0 S e 1 9 6 S n 1 8 9 9 U n i t s %R PPm PPm PPm PPm PPm PPm A v q e 9 7 . 2 8 . 6 9 1 8 . 7 2 8 3 . 0 1 2 0 . 1 9 7 7 . 7 1 6 2 . 0 0 0 2 SD& 1 . 2 7 . 0 0 0 5 . 0 0 0 7 . 0 0 1 9 . 0 0 0 8 . 0 0 0 6 . O O l O %RSD 1 . 3 0 3 . 0 7 1 8 . 0 9 1 9 1 6 . 1 3 . 3 8 6 9 . 0 8 4 6 4 4 1 . 3

#1 9 8 . 1 8 . 6 9 2 1 . 7 2 8 8 . 0 1 3 3 . 1 9 7 2 . 7 1 6 6 . O O l O #2 9 6 . 3 8 . 6 9 1 4 . 7 2 7 9 . 0 1 0 6 . 1 9 8 3 . 7 1 5 7 - . 0 0 0 5

E l e m S r 4 2 1 5 T h 2 8 3 7 T i 3 3 4 9 T 1 1 9 0 8 U - 4 0 9 0 V - 2 9 2 4 W - 2 0 7 9 U n i t s ppm PPm PPm PPm PPm PPm PPm A v q e . 0 0 0 2 - . 0 0 2 1 - . 0 0 0 2 . 8 0 6 2 . 0 6 2 5 . 2 0 1 1 . 0 0 9 1 SD& . o o o o . 0 0 3 0 . 0 0 0 3 . 0 0 2 1 . 0 0 5 1 . O O O l - 0 0 0 2 %RSD 2 . 3 5 8 1 4 2 . 5 1 4 7 . 5 . 2 5 6 0 8 . 2 0 7 . 0 5 0 5 1 . 8 0 6

#1 . 0 0 0 2 - . 0 0 4 2 . o o o o . 8 0 7 7 . 0 5 8 9 . 2 0 1 1 . 0 0 9 0 #2 . 0 0 0 2 . o o o o - . 0 0 0 5 . 8 0 4 8 . 0 6 6 1 . 2 0 1 2 . 0 0 9 2

Analysis Report 04/16/07 0 6 : 1 3 : 2 9 PM


Y 3710

. o o o o

.OOOl 9808.

PPm Zn2062 PPm . 1 9 6 2 . 0 0 0 6 . 3 3 2 5

Zr3496 PPm .0005 . 0 0 0 8 1 6 3 . 5

#1 #2

.OOOl - . 0001

. 1 9 5 7

. 1 9 6 7 .0011 - . 0001

4 NOTUSED

6 7 NOTUSED NOTUSED


1 *Counts sc 361.384 956615 1 2 5 2 1 . 4 5 1 . 3 0 8 9 3 3

2 Time

3 NOTUSED - -

10000 . o o o o o o o . o o o o o o o

#1 #2

965469 947761

1 0 0 0 0 10000

A n a l y s i s R e p o r t 0 4 / 1 6 / 0 7 0 6 : 1 8 : 1 9 PM page 1

Operator: 010100

Method: DAILY2 Sample N a m e : CCV2 Run T i m e : 0 4 / 1 6 / 0 7 1 8 : 1 3 : 4 1 C o m m e n t : Mode: CONC C o r r . F a c t o r : 1

E l e m Ag3280 A13082 A s 1 8 9 0

A v g e - 9 7 8 2 9 . 8 3 8 5 . 0 9 1 SDev . 0 0 0 9 - 0 1 9 . 0 1 3 %RSD . 0 9 7 4 . 1 9 1 2 . 2 5 1 9

U n i t s ppm PPm PPm

#1 . 9 7 8 9 9 . 8 5 1 5 . 0 8 2 #2 . 9 7 7 6 9 . 8 2 4 5 . 1 0 0

E r r o r s LC P a s s LC P a s s LC P a s s H i g h 1 . 1 0 0 1 1 . 0 0 5 . 5 0 0 Low . g o o 0 9 . 0 0 0 4 . 5 0 0

E l e m C a 3 1 7 9 C d 2 2 6 5 Co2286

A v g e 1 9 . 9 1 1 . 0 0 9 5 . 1 2 5 SDev . 1 4 . 0 0 7 , 0 1 5 %RSD . 7 0 0 8 . 6 7 4 6 . 2 8 6 6

' U n i t s ppm PPm PPm

#1 2 0 . 0 1 1 . 0 1 4 5 . 1 3 6 #2 1 9 . 8 1 1 . 0 0 4 5 .115

E r r o r s LC P a s s LC P a s s LC P a s s H i g h 2 2 . 0 0 1 . 1 0 0 5 . 5 0 0 Low 1 8 . 0 0 . g o o 0 4 . 5 0 0

E l e m L a 3 9 8 8 L i 6 7 0 7 Mg2790 U n i t s ppm PPm PPm A v g e 4 . 9 7 5 4 . 7 1 8 2 0 . 0 0 SDev . 0 0 9 . 0 4 2 . 0 4 %RSD . 1 8 3 3 . 8 8 3 7 . 1 9 6 0

#1 4 . 9 6 9 4 . 6 8 8 2 0 . 0 2 #2 4 . 9 8 1 4 . 7 4 7 1 9 . 9 7

E r r o r s LC P a s s LC P a s s LC P a s s

Low 4 . 5 0 0 4 . 5 0 0 1 8 . 0 0 H i g h 5 . 5 0 0 5 . 5 0 0 2 2 . 0 0

E l e m N i 2 3 1 6 P - 1 7 8 2 2 2 0 3 / 1

A v g e 4 . 9 8 3 4 . 8 6 6 5 . 0 6 9 SDev . 0 3 0 . 0 8 7 . 0 4 9 %RSD . 6 0 4 8 1 . 7 8 7 . 9 7 3 4

U n i t s ppm PPm PPm

#1 5 . 0 0 4 4 . 8 0 4 5 . 1 0 4 #2 4 . 9 6 2 4 . 9 2 7 5 . 0 3 4

E r r o r s LC P a s s LC P a s s NOCHECK H i g h 5 . 5 0 0 5 . 5 0 0 Low 4 . 5 0 0 4 . 5 0 0

B 2 4 9 6 B a 4 9 3 4 Be3130 B i 2 2 3 0

5 . 0 2 0 1 0 . 1 6 . 9 9 7 4 5 . 0 7 6 . 0 4 5 . 0 4 . 0 0 4 7 . 0 2 3

. 8 9 7 8 . 4 1 8 1 . 4 6 8 3 . 4 4 9 7

PPm PPm PPm PPm

4 . 9 8 8 1 0 . 1 3 1 . 0 0 1 5 . 0 6 0 5 . 0 5 2 1 0 . 1 9 . 9 9 4 1 5 . 0 9 2

LC P a s s LC P a s s LC P a s s LC P a s s 5 . 5 0 0 1 1 . 0 0 1 . 1 0 0 5 . 5 0 0 4 . 5 0 0 9 . 0 0 0 . g o o 0 4 . 5 0 0

C r 2 6 7 7 C u 3 2 4 7 F e 2 7 1 4 K - 7 6 6 4 PPm PPm PPm PPm 2 . 0 0 1 2 . 0 5 2 1 0 . 3 5 L 1 7 . 9 0 .010 . 0 0 9 . 0 8 .10

. 5 1 4 1 .4183 . 7 9 0 8 . 5 4 9 2

2 . 0 0 9 2 . 0 4 6 1 0 . 4 1 L 1 7 . 8 3 1 . 9 9 4 2 . 0 5 9 1 0 . 2 9 L 1 7 . 9 7

LC P a s s LC P a s s LC P a s s LC Low 2 . 2 0 0 2 . 2 0 0 1 1 . 0 0 2 2 . 0 0 1 . 8 0 0 1 . 8 0 0 9 . 0 0 0 1 8 . 0 0

Mn2576 Mo2020 Na3302 Na5889 PPm PPm PPm PPm 1 . 0 2 2 5 . 0 1 0 2 8 . 5 6 H 4 9 . 7 1

. 0 0 5 . 0 1 3 . 0 5 . 4 7 . 4 7 7 2 . 2 5 7 2 . 1 8 2 5 . 9 5 1 0

1 . 0 2 5 5 . 0 2 0 2 8 . 5 2 H 4 9 . 3 7 1 . 0 1 8 5 . 0 0 1 2 8 . 6 0 H 5 0 . 0 4

LC P a s s LC P a s s LC P a s s LC H i g h 1 . 1 0 0 5 . 5 0 0 3 3 . 0 0 3 3 . 0 0 . g o o 0 4 . 5 0 0 2 7 . 0 0 2 7 . 0 0

2 2 0 3 / 2 P d 3 4 0 4 S 1 8 2 0 S b 2 0 6 8

4 . 9 6 9 1 . 0 2 5 1 . 0 4 0 1 . 0 0 5 . 1 2 0 . 0 0 5 . 0 2 3 , 0 0 2

2 . 4 0 8 . 4 6 6 4 2 . 2 2 1 - 2 2 3 0

PPm PPm PPm PPm

5 . 0 5 4 1 . 0 2 8 1 . 0 2 4 1 . 0 0 3 4 . 8 8 4 1 . 0 2 1 1 . 0 5 7 1 . 0 0 6

NOCHECK LC P a s s LC P a s s LC P a s s 1 . 1 0 0 1 . 1 0 0 1 . 1 0 0 . g o o 0 . g o o 0 . g o o 0

E l e m S c 3 6 1 3 1 9 6 0 / 1 1 9 6 0 / 2 S i 2 8 8 1 P b 2 2 0 S e 1 9 6 S n 1 8 9 9

Analysis R e p o r t 0 4 / 1 6 / 0 7 0 6 : 1 8 : 1 9 PM page 2

PPm 010101 PPm 5 . 1 4 7 5 . 1 6 1

Units %R A v g e 9 9 . 8 4 S D e v 4 . 7 2 %RSD 4 . 7 2 8

PPm 5 . 2 1 0

. 0 3 8 . 7 3 4 7

PPm 5 . 1 1 6

. 0 8 7 1 . 7 0 9

PPm 5 . 0 8 5

. 0 0 4 - 0 8 2 5

PPm 5 . 0 0 2

. 0 9 6 1 . 9 2 4

. 0 7 1 . o o o 1 . 3 8 0 . 0 0 4 0

#l 9 6 . 5 0 #2 1 0 3 . 2

5 . 2 3 7 5 .183

5 . 1 7 8 5 . 0 5 4

5 . 0 8 8 5 . 0 8 2

5 . 0 7 0 4 . 9 3 4

5 .198 5 . 1 6 1 5 . 0 9 7 5 . 1 6 0

E r r o r s NOCHECK High Low

NOCHECK NOCHECK LC Pass 5 . 5 0 0 4 . 5 0 0

LC Pass 5 . 5 0 0 4 . 5 0 0

LC Pass LC Pass 5 . 5 0 0 5 . 5 0 0 4 . 5 0 0 4 . 5 0 0

E l e m S r 4 2 1 5 Units ppm A v g e 4 . 8 8 1 S D e v . 0 0 9 %RSD . 1 8 3 3

T h 2 8 3 7 PPm . 9 9 6 2 . 0 0 1 7 . 1 7 0 1

T i 3 3 4 9 PPm 4 . 8 1 4

. o o o . 0 0 1 2

T 1 1 9 0 8 PPm 5 . 3 0 2 .011

. 2 1 6 0

U 4 0 9 0

1 . 0 5 1 . 0 3 8

3 . 5 7 2

PPm U - 2 9 2 4 W 2 0 7 9

5 , 0 6 5 1 . 0 9 2 . O l l . O O l

. 2 2 5 7 . 0 5 8 2

PPm PPm

#1 4 . 8 7 5 #2 4 . 8 8 7

4 . 8 1 4 4 . 8 1 4

5 . 2 9 4 5 . 3 1 0

1 . 0 7 8 1 . 0 2 5

5 . 0 7 3 1 . 0 9 1 5 . 0 5 7 1 . 0 9 2

. 9 9 7 4

. 9 9 5 0

E r r o r s LC Pass High 5 . 5 0 0 Low 4 . 5 0 0

LC Pass 1 . 1 0 0 . g o o 0

LC Pass 5 . 5 0 0 4 . 5 0 0

LC Pass 5 . 5 0 0 4 . 5 0 0

LC Pass 1 . 1 0 0 . g o o 0

LC Pass LC Pass 5 . 5 0 0 1 . 1 0 0 4 . 5 0 0 . g o o 0

E l e m Y 3 7 1 0 Units pPm A v g e 5 . 0 7 5 SDev .001 %RSD . 0 2 5 7

Zn2062 PPm 1 . 0 2 8

. O l O 1 . 0 1 1

Z r 3 4 9 6 PPm 4 . 9 6 7

. 0 0 3 . 0 6 0 7

#1 5 . 0 7 6 #2 5 . 0 7 4

1 . 0 3 5 1 . 0 2 0

4 . 9 6 4 4 . 9 6 9


LC Pass 1 . 1 0 0 . g o o 0

LC Pass 5 . 5 0 0 4 . 5 0 0


#I- #2

1 *Counts sc 3 6 1 . 3 8 4 9 8 1 7 1 1 4 6 4 5 8 . 3 3 4 . 7 3 2 3 8 4

9 4 8 8 6 0 1 0 1 4 5 6 2

2 Time - - - - 10000 . o o o o o o o . o o o o o o o

1 0 0 0 0 1 0 0 0 0

4

0 4 / 1 6 / 0 7 0 6 : 1 8 : 1 9 PM page 3

5 6 010102 7

Analysis Report

Method: DAILY2 Sample Name: CCB2 Run Time: 04/16/07 18:18:31 Comment : Mode: CONC Corr. Factor: 1


#I # 2

Errors High Low


#1 #2

Errors High Low


#1 #2

Errors High Low


#I #2

Errors High Low

Elem

Ag3280 PPm - . 0005 .0006

103.9

- . 0001 - . 0009

LC Pass .0050 - . 0050

Ca3179 PPm .0032 . o o o o 1.411

-0031 .0032

LC Pass .0500 - .0500

La3988 PPm . 0 0 0 2 .0011 566.9

.OOlO - . 0006

LC Pass .0050 - . 0050

Ni2316 PPm .OOOl .0002 239.5

.0002 - . 0000 LC Pass .0050 - . 0050 Sc3613

A13082 PPm - . 0052 .0002

3.260

- . 0051 - . 0053

LC Pass .0500 - . 0500

Cd2265 PPm .0002 .0002 105.7

. o o o o

.0003

LC Pass - 0 0 5 0 - . 0050 Li6707 PPm - . 0002

. o o o o 7.272

- . 0002 - . 0002 LC Pass .0050 - . 0 0 5 0

P 1782 PPm - .0030 .0026

84.22

- .0049 - . 0012 LC Pass .OlOO - . O l O O

1960/1

As1890 PPm .0004 .0004 92.17

.0007

.OOOl

LC Pass .0050 - . 0050

Co2286 PPm .0006 .0004 63.26

. 0 0 0 8

.0003

LC Pass .0050 - . 0050 Mg2790 PPm - . 0009 .0022

227.5

. 0 0 0 6 - . 0025

LC Pass .0500 - . 0500 2203/1 PPm .0034 .0018 53.73

.0021

.0046

NOCHECK

1960/2

04/16/07 06:23:09 PM Page 1

B - 2496 PPm .0104 -0041 39.55

.0133

.0075

LC Pass .0500 - . 0500 Cr2677 PPm - . 0007 .0008

113.2

- .OOOl - . 0012 LC Pass -0050 - . 0050 Mn2576 PPm - . 0001 -0002

128.2

- . 0000 - .0002

LC Pass .0050 - . 0050 2203/2 PPm - . 0008 -0005

72.20

- . 0011 - . 0004 NOCHECK

Si2881

010103 Operator :

Ba4934 PPm - . 0001 .0003

669.1

.0002 - . 0003 LC Pass .0050 - . 0050 Cu3247 PPm .0002 .OOlO 543.0

-0009 - . 0005 LC Pass .0050 - .0050

Mo2020 PPm -0013 .0012 90.58

.0021

.0005

LC Pass .0050 - . 0050

Pd3404 PPm .0017 .0026 156.8

- . 0002 .0035

LC Pass .0050 - . 0050

Be3 13 0 PPm . o o o o . o o o o 33.64

. o o o o

. o o o o

LC Pass .0050 - . 0050 Fe2714 PPm .0164 .0105 64.02

.0090

.0238

LC Pass .0500 - .0500

Na3302 PPm .0387 .1966 508.1

L-. 1003 H. 1777

LC Pass .0500 - . 0500

S 1820 PPm H. 0209 .0009 4.148

H. 0202 H. 0215

LC High .0200 - . 0200

Pb220 Se196

Bi2230 PPm .0032 .OOlO 31.45

.0039

.0025

LC Pass .OlOO - . 0100 K 7664

.0082

.0169 205.3

PPm

- . 0037 .0201

LC Pass . l o o 0 - . 1000 Na5889 PPm L- .1857

.0044 2.358

L-. 1888 L-. 1826

LC Low .0500 - . 0500

Sb2068 PPm .0056 .0019 33.83

.0043 -0070

LC Pass .OlOO - . 0100 Sn1899

Analysis Report 0 4 / 1 6 / 0 7 0 6 : 2 3 : 0 9 PM p a w 2

010104 Units Avge SDev %RSD

#1 #2



#1 #2



#1 #2


%R 1 0 5 . 1

. 5 . 4 5 7 8

1 0 4 . 7 1 0 5 . 4

NOCHECK

S r 4 2 1 5 PPm . o o o o .OOOl 1 3 9 . 4

.OOOl

. o o o o

LC Pass . 0 0 5 0 - . 0050 Y 3 7 1 0

. o o o o

. 0 0 0 3 1 6 3 7 .

. 0 0 0 2 - . 0 0 0 2

LC Pass . 0 0 5 0

PPm

- . 0 0 5 0

PPm - . 0 0 3 8 . 0 0 3 7

9 6 . 8 1

- . 0 0 6 4 - . 0 0 1 2

NOCHECK

T h 2 8 3 7 PPm - . 0 0 1 6

2 2 2 . 1

. 0 0 0 9 - . 0 0 4 2

. 0 0 3 6

LC Pass .OlOO - . 0100

Zn2 0 6 2 PPm . 0 0 0 4 . o o o o . 7 8 9 5

- 0 0 0 4 - 0 0 0 4

LC Pass . 0 0 5 0 - . 0 0 5 0

PPm - . 0 0 2 8 . 0 0 0 9

3 3 . 6 6

- . 0 0 2 1 - . 0 0 3 5

NOCHECK

T i 3 3 4 9 PPm - . 0 0 0 1

. 0 0 0 3 3 7 4 . 0

. O O O l - . 0 0 0 3

LC Pass . 0 0 5 0 - . 0 0 5 0

Z r 3 4 9 6 PPm - . 0 0 0 3

. 0 0 1 5 4 2 7 . 1

. 0 0 0 7 - . 0 0 1 4

LC Pass . 0 0 5 0 - . 0 0 5 0

PPm - . 0 0 3 7 . 0 0 1 5

4 0 . 0 1

- . 0 0 2 7 - . 0 0 4 8

LC Pass .OlOO - . 0100 T11908 PPm . 0 0 5 8 . 0 0 1 6 2 7 . 8 2

. 0 0 4 7

. 0 0 7 0

LC Pass .OlOO - . 0100

PPm . 0 0 0 6 .OOlO 1 5 4 . 4

- . 0 0 0 1 . 0 0 1 3

LC Pass . 0 0 5 0 - . 0 0 5 0

U - 4 0 9 0 PPm . 0 1 9 3 . 0 2 6 5 1 3 7 . 3

. 0 3 8 0

. 0 0 0 6

LC Pass . l o o 0 - . 1000

PPm - . 0 0 3 1

- 0 0 0 6 1 9 . 2 0

- . 0 0 3 5 - . 0 0 2 7

LC Pass . 0 0 5 0 - . 0 0 5 0

V 2 9 2 4

- . 0 0 0 1 .0011

8 9 4 . 2

. 0 0 0 7 - . 0 0 0 9

LC Pass . 0 0 5 0

Pi%

- . 0 0 5 0

PPm - . 0 0 1 5

. 0 0 0 8 5 2 . 2 5

- . 0 0 0 9 - . 0 0 2 0

LC Pass . 0050 - . 0 0 5 0

W 2 0 7 9

. 0 0 0 8

. 0 0 0 6 7 8 . 7 7

. 0 0 0 4

. 0 0 1 3

LC Pass . O l O O - . 0 1 0 0

PPm

~~ ~~ ~

Analysis Report


#I #2

1 *Counts sc 3 6 1 . 3 8 4 1 0 3 3 0 7 2 4 6 8 2 . 4 6 1 . 4 5 3 2 5 6 0

1 0 2 9 7 6 1 1 0 3 6 3 8 3

2 Time

- - 1 0 0 0 0 . o o o o o o o . o o o o o o o

1 0 0 0 0 1 0 0 0 0

0 4 / 1 6 / 0 7 0 6 : 2 3 : 0 9 P Page 3 h0105 4 5 6 7 NOTUSED NOTUSED NOTUSED NOTUSED - - - - - - - -

Analysis Report 04/16/07 06:28:00 PM Page 1

Method: DAILY2 Sample Name: PBW-D16H1 Operator: Run Time: 04/16/07 18:23:22 Comment : Mode: CONC Corr. Factor: 1

010106 Elem Ag3280 A13082 As1890 Units ppm PPm PPm Avge .0015 .0202 .0034 SDev .0015 .0092 .0007 %RSD 95.01 45.75 19.87

#I . 0 0 0 5 .0137 .0039 # 2 .0026 .0267 .0030

Errors LC Pass LC Pass LC Pass High .0050 .0500 .0050 Low - . 0050 - . 0500 - . 0050 Elem Ca3179 Cd2265 Co2286

Avge .0074 .0003 .0017 SDev . o o o o . 0 0 0 3 .0009 %RSD .1381 105.9 50.07

Units ppm PPm PPm

#1 . 0 0 7 4 . O O O l .0011 # 2 .0074 .0006 .0023

Errors LC P a s s LC Pass LC Pass High .0500 .0050 .0050 Low - .0500 - . 0050 - .0050


Avge .0025 - . 0002 .0148 SDev .0024 . o o o o .0099 %RSD 96.62 14.34 67.17

Units ppm PPm PPm

#1 .0008 - . 0001 .0078 # 2 .0041 - . 0002 .0218

Errors LC Pass LC Pass LC Pass High .0050 .0050 .0500 Low - . 0050 - . 0050 - .0500

Elem Ni2316 P - 1782 2203/1 Units ppm PPm PPm Avge - . 0001 - . 0053 - .0018 SDev .0011 . 0 0 2 0 -0008 %RSD 777.4 38.65 44.71

#1 .0006 - . 0039 - .0024 # 2 - . 0009 - . 0067 - . 0013 Errors LC Pass LC Pass NOCHECK

Low - . 0050 - . 0100 High .0050 . O l O O

Elem Sc3613 1960/1 1960/2

B 2496 Ba4934 Be3130 Bi2230

.0032 - . 0001 . o o o o .0036 -0023 .0002 . o o o o .0008 71.29 205.8 82.74 21.29

PPm PPm PPm PPm

.0041 .0049 . o o o o . O O O l .0016 - . 0002 . o o o o .0030

LC Pass LC Pass LC Pass LC Pass .0500 . 0 0 5 0 .0050 .OlOO - . 0500 - . 0050 - . 0050 - . 0100

Cr2677 Cu3247 Fe2714 K 7664

- . 0009 .0002 .0437 .0107 .0012 .0008 .0078 .0108

134.1 369.4 17.79 101.1

PPm PPm PPm PPm

- . 0000 . 0 0 0 7 .0382 .0183 - . 0017 - . 0003 .0492 .0030

LC Pass LC Pass LC Pass LC Pass .0050 .0050 .0500 . l o o 0 - . 0050 - . 0050 - . 0500 - . 1000

Mn2576 Mo2020 Na3302 Na5889 PPm PPm PPm PPm - . 0001 .0003 H.2315 L-. 1857 .0002 .0004 .0645 -0038

241.5 157.1 27.85 2.025

.OOOl .0005 H.2771 L-. 1830 - . 0002 - . 0000 H. 1859 L-. 1883

LC Pass LC Pass LC High LC Low .0050 .0050 .0500 .0500 - . 0050 - . 0050 - . 0500 - . 0500 2203/2 Pd3404 S 1820 Sb2068

.0002 .0049 .0197 .0078

.0006 .0022 .0027 .0022 273.2 44.99 13.43 28.35

PPm PPm PPm PPm

- . 0002 H. 0065 .0179 -0093 -0007 .0033 H. 0216 .0062

NOCHECK LC Pass LC Pass LC Pass .0050 .0200 . O l O O - . 0050 - . 0200 - . 0100

Si2881 Pb2 2 0 Se196 Sn1899

Analys is R e p o r t 04/16/07 06:28:00 PM page 2

010107 PPm PPm PPm PPm .0098 - . 0 0 0 4 - . 0003 .0009 .0075 .0007 .0002 .0018 76.20 158.3 54.83 190.4

U n i t s %R

S D e v .5 %RSD .4536

A v g e 102.2 PPm - . 0032 .0005

14.67

PPm .OOll . 0 0 0 5 42.24

#1 101.8 # 2 102.5

- . 0 0 3 5 - . 0029

.0015

.0008 .0045 - . 0009 - . 0002 .0022

H.0151 .OOOl - .0004 - .0003


NOCHECK NOCHECK LC P a s s L C P a s s L C P a s s L C Pass .OlOO . 0 0 5 0 .0050 .0050 - . 0100 - . 0050 - . 0050 - . 0050

E l e m Sr4215 U n i t s ppm A v g e .OOOl S D e v . O O O l %RSD 92.78

Th2837 PPm - . 0061 .0085

140.5

Ti3349 PPm - . 0003 .0003

112.9

T11908 U 4090 V 2924 W 2079

.0022 H.1066 - . 0010 .0048

.0046 .0952 . 0 0 2 0 .OOlO 207.7 89.27 193.0 22.03

PPm PPm PPm PPm

#1 . o o o o #2 .0002

- . 0 0 0 0 L - . 0121

- . 0001 - . 0005

- . 0010 .0393 .0004 .0040 .0055 H.1739 - . 0024 .0055

E r r o r s LC P a s s H i g h . 0 0 5 0 Low - .0050

L C Pass .OlOO - . 0100

L C P a s s .0050 - .0050

L C Pass L C H i g h L C P a s s LC Pass .OlOO .loo0 .0050 .OlOO - . 0100 - . 1000 - . 0050 - . 0100

E l e m Y 3710 U n i t s p P m A v g e - . 0001 S D e v .0002 %RSD 186.4

Zn2062 PPm .OOOl .OOOl 121.0

Zr3496 P P m .OOOl .OOlO 1551.

#1 . o o o o #2 - . 0002

. o o o o

.0002 .0008 - .0006

E r r o r s L C Pass H i g h .0050 Low - . 0050

L C P a s s . 0 0 5 0 - . 0 0 5 0

L C Pass .0050 - .0050

Analysis Report


#1 #2

1 2 3 *Counts Time NOTUSED sc 3 6 1 . 3 8 4 - - 1 0 0 4 4 8 4 1 0 0 0 0 - - 4 6 3 2 . 9 6 4 . O O O O O O O - - . 4 6 1 2 2 8 2 . O O O O O O O - -

- - _ - _ -

1001208 1 0 0 0 0 - - 1 0 0 7 7 6 0 1 0 0 0 0 - -

0 4 / 1 6 / 0 7 0 6 : 2 8 : 0 0 PM Page 3

4 NOTUSED

5 NOTUSED

6 010108

~ ~ ~~

A n a l y s i s Report 0 4 / 1 6 / 0 7 0 6 : 3 2 : 5 0 PM page 1

Method: DAILY2 S a m p l e N a m e : LCSW-D16H1 Run T i m e : 0 4 / 1 6 / 0 7 1 8 : 2 8 : 1 2 C o m m e n t : Mode: CONC C o r r . F a c t o r : 1


#1 # 2


#1 # 2


#1 #2


#1 # 2


#1 #2


#1 #2

Ag3280 PPm . 0 4 9 2 . 0 0 0 8 1 . 5 9 9

. 0 4 8 6

. 0 4 9 8

Ca3179 PPm 1 9 . 6 8

. 0 6 . 2 8 0 7

1 9 . 6 4 1 9 . 7 2

L a 3 9 8 8 PPm . O O O l .OOlO 1 2 0 1 .

- . 0 0 0 6 . 0 0 0 8

N i 2 3 1 6 PPm . 4 8 8 7 . 0 0 0 3 . 0 7 0 0

. 4 8 8 4

. 4 8 8 9

S c 3 6 1 3 %R 1 0 2 . 3

. 2 . 1 5 2 7

1 0 2 . 4 1 0 2 . 2

S r 4 2 1 5 PPm . 0 0 0 4 . o o o o 9 . 3 8 3

. 0 0 0 4

. 0 0 0 4

A13082 PPm 1 . 9 2 7 .001

. 0 3 3 0

1 . 9 2 7 1 . 9 2 8

C d 2 2 6 5 PPm . 0 4 9 7 . o o o o . 0 5 1 1

. 0 4 9 7

. 0 4 9 7

L i 6 7 0 7 PPm - . 0 0 0 1

. O O O l 5 8 . 4 0

- . 0 0 0 2 - . 0 0 0 1

P 1 7 8 2

. 0 0 1 9

. 0 0 4 6 2 4 2 . 9

PPm

- . 0 0 1 4 . 0 0 5 2

1 9 6 0 / 1 PPm 2 . 0 2 5

. 0 0 5 . 2 2 4 5

2 . 0 2 2 2 . 0 2 8

T h 2 8 3 7 PPm - . 0 2 3 1

. 0 0 2 7 1 1 . 4 9

- . 0 2 5 0 - . 0 2 1 3

A s 1 8 9 0 PPm 2 . 0 0 8

. 0 0 3 . 1 6 0 1

2 . 0 0 6 2 . 0 1 0

Co2286 PPm . 5 0 2 9 . O O O S . l o 2 8

. 5 0 3 3 - 5 0 2 5

Mg2790 PPm 1 9 . 8 0

.01 . 0 4 1 6

1 9 . 8 1 1 9 . 8 0

2 2 0 3 / 1 PPm . 4 7 9 0 . O O l O . 2 0 7 7

. 4 7 8 3

. 4 7 9 7

1 9 6 0 / 2 PPm 2 . 0 1 8

. 0 1 9 . 9 2 0 1

2 . 0 0 5 2 . 0 3 1

T i 3 3 4 9 PPm - . 0 0 0 3

. 0 0 0 3 1 2 2 . 5

- . 0 0 0 0 - . 0 0 0 5

B 2 4 9 6

. 0 0 2 7

.0015 5 5 . 8 2

. 0 0 3 7

. 0 0 1 6

C r 2 6 7 7 PPm . 1 9 4 4 . 0 0 0 3 . 1 5 3 4

. 1 9 4 6

. 1 9 4 2

Mn2576 PPm . 5 0 2 6 . O O O l . 0 1 3 8

. 5 0 2 7

.SO26

2 2 0 3 / 2 PPm . 4 8 1 8 . 0 0 2 7 . 5 5 9 9

. 4 7 9 9

. 4 8 3 7

S i 2 8 8 1 PPm . 0 1 7 8 . 0 0 3 4 1 9 . 3 4

. 0 1 5 4

. 0 2 0 3

T11908 PPm 2 . 0 8 9

. 0 0 6 . 2 6 9 0

2 . 0 9 3 2 . 0 8 5

P b B a 4 9 3 4 PPm 2 . 0 3 9

. o o o . 0 1 1 4

2 . 0 3 9 2 . 0 4 0

Cu3247 PPm . 2 5 0 5 . 0 0 1 9 . 7 5 2 9

. 2 5 1 8

. 2 4 9 2

Mo2020 PPm . 0 0 0 4 . O O O l 1 4 . 5 6

. 0 0 0 4 - 0 0 0 3

P d 3 4 0 4 PPm . 0 0 0 9 . 0 0 5 5 6 0 8 . 1

- . 0 0 3 0 . 0 0 4 8

P b 2 2 0 PPm . 4 8 0 9 . 0 0 2 1 . 4 4 3 1

. 4 7 9 4 - 4 8 2 4

U 4 0 9 0

. 0 1 3 1

. 0 2 8 8 2 2 0 . 3

- . 0 0 7 3 . 0 3 3 5

PPm

Operator:

Be3130 PPm . 0 5 0 3 . o o o o . 0 7 3 5

. 0 5 0 3

.OS03

F e 2 7 1 4 PPm 1 . 1 7 8

. O l O . 8 2 5 1

1 . 1 7 1 1 . 1 8 5

Na3302 PPm 1 7 . 3 8

. 2 5 1 . 4 5 9

1 7 . 2 0 1 7 . 5 5

S 1 8 2 0

4 . 2 1 3 . 0 4 0

- 9 5 4 6

4 . 2 4 1 4 . 1 8 4

S e 1 9 6 PPm 2 . 0 2 0 .014

. 6 8 7 7

2 . 0 1 1 2 . 0 3 0

V 2 9 2 4 PPm . 4 9 7 8 . 0 0 0 2 . 0 4 2 1

. 4 9 7 9

. 4 9 7 6

PPm

-

010109

B i 2 2 3 0 PPm - . 0 0 0 4 .OOOl

2 9 . 9 7

- . 0 0 0 3 - . 0 0 0 5

K 7 6 6 4

1 5 . 4 3 . 0 6

. 4 0 1 1

1 5 . 4 7 1 5 . 3 9

Na5889 PPm 3 0 . 6 7

. 18 . 5 8 2 5

3 0 . 8 0 3 0 . 5 5

S b 2 0 6 8 PPm . 4 9 2 7 . 0 0 1 5 . 3 1 0 2

- 4 9 1 6 . 4 9 3 8

S n 1 8 9 9 PPm . O O O l . 0 0 0 7 7 7 0 . 7

. 0 0 0 6

PPm

- . 0 0 0 4

W 2 0 7 9

. 0 0 0 9

. 0 0 2 5 2 7 0 . 3

- . 0 0 0 9 . 0 0 2 7

PPm

Analysis Report

Elem Y 3710 Zn2062 Zr3496 Units pPm PPm PPm Avge - .0004 .4971 - . 0008 SDev . 0 0 0 2 .0003 .0013 %RSD 58.88 .0604 159.8

04/16/07 06 : 32 : 50 PM page 2

0 1 0 1 1 ~

#1 - . 0002 .4973 .OOOl # 2 - . 0006 .4969 - . 0017 IntStd 1 2 3 4 5 6 7 Mode *Counts Time NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Elem sc Wavlen 361.384 - - Avge 1005838 10000

- - _ - _ - - - - - - - _ - - - _ - - - - - - - - - - - - - _ -

- - - - - - - - SDev 1453.104 . O O O O O O O - - %RSD .1444670 . O O O O O O O - - - - - - - - _ _

A n a l y s i s Report 0 4 / 1 6 / 0 7 0 6 : 3 7 : 3 6 PM

Method: DAILY2 Sample Name: 2 9 4 9 5 4 Run T i m e : 0 4 / 1 6 / 0 7 1 8 : 3 3 : 0 2 C o m m e n t : Mode: CONC Corr . F a c t o r : 1


#1 #2


#1 #2


#1 #2


#1 #2


#1 #2


#I #2

Ag3280 PPm - . 0007

. 0 0 1 4 2 0 9 . 1

. 0 0 0 3 - . 0 0 1 6

Ca3179 PPm . 0 1 9 2 .OG14 7 . 3 4 1

. 0 2 0 2

. 0 1 8 2

L a 3 9 8 8 PPm - . 0012

. 0 0 1 4 1 1 3 . 5

- , 0002 - . 0 0 2 2

N i 2 3 1 6 PPm - . 0 0 0 7

. 0 0 0 9 1 3 1 . 6

- . 0 0 0 0 - . G O 1 3

S c 3 6 1 3 %R 1 0 6 . 9

1 . 7 1 . 5 6 6

1 0 5 . 7 1 0 8 . 0

S r 4 2 1 5 PPm . o o o o .OOOl 1 1 0 . 2

.OOOl

. o o o o

A13082 PPm - . 0 0 0 5

. 0 0 5 6 1 2 4 7 .

. 0 0 3 5 - . 0 0 4 4

C d 2 2 6 5 PPm - . 0 0 0 1

. o o o o 2 5 . 5 0

- . 0 0 0 2 - . 0 0 0 1

L i 6 7 0 7 P P m - . 0 0 0 4 .OOOl

2 2 . 4 0

- . 0 0 0 3 - . 0 0 0 4

P 1 7 8 2

- . 0 0 3 3 . 0 2 5 9

7 7 6 . 3

. 0 1 5 0

PPm

- . 0 2 1 7

1 9 6 0 / 1 PPm . 0 0 3 8 . 0 0 4 6 1 2 3 . 0

. 0 0 7 0

. 0 0 0 5

T h 2 8 3 7 PPm - . 0 0 4 4

. 0 0 6 6 1 4 8 . 8

. 0 0 0 2 - . 0 0 9 1

A s 1 8 9 0 PPm . 0 0 1 2 . 0 0 4 5 3 6 3 . 7

. 0 0 4 4 - . 0 0 1 9

Co2286 PPm - . 0 0 0 3

1 0 2 . 7

- . 0 0 0 1 - . 0 0 0 6

. 0 0 0 3

Mg2790 PPm . 0 2 6 2 . 0 0 8 7 3 3 . 1 6

. 0 3 2 3

. 0 2 0 0

2 2 0 3 / 1 PPm . 0 0 1 3 - 0 0 1 5 1 1 9 . 5

. 0 0 0 2

. 0 0 2 4

1 9 6 0 / 2 PPm . 0 0 0 9 . 0 0 0 4 4 7 . 7 6

. 0 0 1 3

. 0 0 0 6

T i 3 3 4 9 PPm - . 0 0 0 6

. 0 0 0 5 7 8 . 8 1

- . 0 0 0 3 - . 0 0 0 9

B 2 4 9 6

. 0 4 4 1

. 0 0 2 8 6 . 2 6 1

. 0 4 6 0

. 0 4 2 1

C r 2 6 7 7 PPm - . 0 0 2 0

. 0 0 1 8 8 9 . 6 2

PPm

- . 0 0 0 7 - . 0032

Mn2576 PPm - . 0 0 0 1 .OOOl

1 0 9 . 8

- . 0 0 0 0 - . 0002

2 2 0 3 / 2 PPm - . 0004

. 0 0 0 7 1 6 7 . 5

.OOOl - . 0010

S i 2 8 8 1 PPm . 0 1 8 8 . 0 0 5 9 3 1 . 6 4

. 0 2 3 0

. 0 1 4 6

T I 1 9 0 8 PPm - . 0002

. O O l l 4 9 3 . 2

- . 0 0 1 0 . 0 0 0 6

O p e r a t o r :

B a 4 9 3 4 PPm . 0 1 9 3 . 0 0 0 4 1 . 9 5 1

. 0 1 9 6

. 0 1 9 1

C u 3 2 4 7 PPm - . 0 0 0 7

. 0 0 1 6 2 2 1 . 9

. 0 0 0 4 - . 0 0 1 8

Mo2020 PPm - . 0 0 0 8

. 0 0 0 5 6 1 . 3 7

- . 0 0 0 5 - . 0 0 1 2

P d 3 4 0 4 PPm - . 0 0 3 0

. 0 0 4 4 1 4 5 . 2

. O O O l - . 0 0 6 1

P b 2 2 0 PPm . GO01 . o o o o 1 7 . 3 4

- 0 0 0 1 . 0 0 0 2

U 4 0 9 0 PPm - . 0 1 3 7

3 9 3 . 3

. 0 2 4 5 - . 0 5 1 9

.OS40

Be3130 PPm - . 0 0 0 0

. o o o o 588.8

. o o o o - . 0 0 0 0

F e 2 7 1 4 PPm . 0 1 1 7 . 0 0 5 4 4 6 . 3 3

. 0 1 5 5

. 0 0 7 8

Na3302 PPm 1 1 . 8 6

. 4 0 3 . 3 9 7

1 2 . 1 4 1 1 . 5 7

S 1 8 2 0

. 9 5 0 7

. 0 1 2 5 1.318

. 9 5 9 5

. 9 4 1 8

S e 1 9 6 PPm . 0 0 1 9 . 0 0 1 8 9 7 . 4 3

. 0 0 3 2

. 0 0 0 6

V 2 9 2 4

PPm

P b - . 0 0 1 3

. 0 0 1 6 1 2 3 . 9

- . 0002 - . 0 0 2 5

Page 1

010111

B i 2 2 3 0 PPm . 0 0 0 5 . 0 1 2 7 2 5 9 4 .

. 0 0 9 5 - . 0 0 8 5

K 7 6 6 4

2 . 4 4 8 . 0 1 3

. 5 4 5 5

2 . 4 5 7 2 . 4 3 8

Na5889 PPm 2 0 . 1 7

. 0 4 . 1 7 3 8

2 0 . 1 5 2 0 . 2 0

S b 2 0 6 8 PPm . 0 0 2 5 .OOOl 4 . 0 7 8

. 0 0 2 6

. 0 0 2 4

S n 1 8 9 9 PPm - . 0 0 0 1

. 0 0 0 2 1 8 1 . 0

. o o o o - . 0 0 0 2

W 2 0 7 9

. 0 0 1 4

. 0 0 0 6 4 5 . 6 3

. 0 0 0 9

. 0 0 1 8

PPm

PPm

Analysis Report


#1 # 2


#1 # 2

Y 3 7 1 0 PPm - . 0 0 0 3

-

. 0 0 0 4 1 5 8 . 2

. o o o o - . 0 0 0 5

1 *Counts sc

1 0 5 0 6 7 2 1 6 4 2 2 . 5 6 1 . 5 6 3 0 5 2

3 6 1 . 3 8 4

1 0 3 9 0 6 0 1 0 6 2 2 8 5

Zn2 0 6 2 PPm . 0 0 0 6 . 0 0 0 2 2 5 . 1 4

. 0 0 0 7

. 0 0 0 5

2 Time

_ _ 1 0 0 0 0 . o o o o o o o . o o o o o o o

10000 10000

Z r 3 4 9 6 PPm - . 0016

. 0 0 2 7 1 6 4 . 5

. 0 0 0 3 - . 0 0 3 5

3 NOTUSED - -

0 4 / 1 6 / 0 7 0 6 : 3 7 : 3 6 PM page 2

010112

~ ~~~

Analysis Report

Method: DAILY2 Sample Name: 294954D Run Time: 04/16/07 18:37:48 Comment : Mode: CONC Corr. Factor: 1


#1 #2


#1 #2


#1 #2


#1 #2


#1 #2


#1 #2

Ag3280 PPm - . 0002 .0007

326.5

.0003 - . 0008

Ca3179 PPm .0140 .0008 5.659

.0145

.0134

La3988 PPm - . 0003 .OOlO

374.2

.0005 - . 0010 Ni2316 PPm .0002 .0016 807.9

.0013 - . 0009 Sc3613 %R 107.0 1.5

1.424

105.9 108.1

Sr4215 PPm .OOOl . o o o o 76.95

.OOOl

. o o o o

A13082 PPm .0041 .OOOl 2.129

.0042

.0041

Cd2265 PPm - . 0001

. o o o o 11.11

- . 0001 - . 0001 Li6707 PPm - . 0004

. o o o o 4.791

- . 0004 - . 0004 P 1782

.0117

.0110 94.14

.0194

.0039

1960/1 PPm - .0002 .0027

1551.

.0018 - .0021

Th2837 PPm - . 0049

PPm

.0057 116.3

- . 0009 - . 0089

As1890 PPm - . 0009 .0015

166.9

.0002 - . 0019

Co2286 PPm -0006 -0003 46.73

.0004 -0009

Mg2790 PPm .0284 .0057 19.93

.0324 -0244

2203/1 PPm .0002 .OOll 670.6

- .0006 .0009

1960/2 PPm - . 0019 .0006

34.64

- . 0014 - . 0023

Ti3349 PPm - . 0004 .0004

98.29

- . 0001 - . 0007

04/16/07 06:42:24 PM

B 2496

.0440

.0005 1.116

.0444

.0437

Cr2677 PPm - . 0016

PPm

.0014 87.71

- . 0006 - . 0026

Mn2576 PPm - . 0000 .OOOl

343.7

.OOOl - . 0001

2203/2 PPm - . 0000 .0036

17110.

.0025 - . 0025 Si2881 PPm .0228 .0002 .8771

.0226

.0229

TI1908 PPm .0023 .0017 73.53

.OOll

.0036

Ba4934 PPm .0195 .0002 1.159

.0196

.0193

Cu3247 PPm - . 0001 .0013

1119.

.0008 - . 0011

Mo2 02 0 PPm - . 0003

. 0 0 0 5 168.8

.OOOl - . 0007

Pd3404 PPm - . 0030 .OOOl

2.314

- . 0030 - . 0029

Pb220 PPm . o o o o .0020 4181.

.0015 - . 0014

U 4090

.0218

.0270 124.2

.0409

.0026

PPm

Operator :

Be3130 PPm - . 0000

. o o o o 36.17

- . o o o o - . 0000 Fe2714 PPm -0142 .0174 123.1

.0265

.0018

Na3302 PPm 11.93

.22 1.804

12.08 11.78

S 1820

.9534

.0224 2.345

.9376

.9692

Se196 PPm - .0013 .0013

103.5

PPm

- .0003 - .0022

V 2924 PPm - . 0013 102.0

- . 0004 - . 0022

.0013

page 1

010113

Bi2230 PPm - . 0005 .0005

113.4

- . 0001 - . 0009

K 7664

2.469 .012 .4979

2.460 2.478

Na5889 PPm 20.40

. 0 3 .1394

20.38 20.42

Sb2068 PPm .0157 .0194 123.3

.0020

.0294

Sn1899 PPm .0029 .0020 66.53

.0043

.0016

W 2079

.0041

.OOll 26.26

.0048

.0033

PPm

P b

Analysis Report

Elem U n i t s Avge SDev %RSD

#1 #2


#1 #2

Y 3710

- . 0001 .0003

214.4

PPm

.OOOl - . 0 0 0 3

1 *Counts sc 361.384 1052206 15009.76 1.426503

1041593 1062820

Zn2062 PPm . 0 0 0 5 .OOOl 33.12

.0006

.0004

2 Time

- - 10000 . o o o o o o o . o o o o o o o

10000 10000

Zr3496 PPm - .0007 .0015

215.3

.0004 - . 0018

3 NOTUSED

04/16/07 06:42:24 PM page 2

010114

Analysis Report 04/16/07 06:47:22 PM Page 1

Method: DAILY2 Sample Name: 294954s Operator: Run Time: 04/16/07 18:42:36 Comment : Mode: CONC Corr. Factor: 1


#1 #2


#1 #2


#1 #2


#I #2


#1 #2


#1 #2

Ag3280 PPm .0496 .0014 2.736

.0487

.0506

Ca3179 PPm 19.63

.05 .2346

19.60 19.66

La3988 PPm .0008 .0013 165.0

- .OOOl .0017

Ni2316 PPm .4901 .0008 .1562

.4896

.4907

Sc3613 %R 105.4

.5 .4996

105.8 105.1

Sr4215 PPm .0004 .OOOl 16.59

.0004

. 0 0 0 5

A13082 PPm 1.943 .007 .3601

1.938 1.948

Cd2265 PPm .0494 .OOOl .2331

.0493

.0495

Li6707 PPm - .0002 .OOOl

41.54

- . 0003 - . 0001 P 1782 PPm - . 0024 .0256

1051.

- . 0205 .0157

1960/1 PPm 2.051

. 0 0 3 .1252

2.053 2.049

Th2837 PPm - . 0218 .0062

28.56

- . 0262 - .0174

As1890 PPm 2.013 .OOl .0437

2.014 2.012

Co2286 PPm .SO38 .0006 .1150

.5034

.5042

Mg2790 PPm 19.81

.Ol .0683

19.80 19.82

2203/1 PPm .4858 .0014 .2886

.4848

.4867

1960/2 PPm 2.077

. o o o .0139

2.077 2.076

Ti3349 PPm - . 0003 .0005

147.3

. o o o o - . 0007

B 2496

.0439

.0026 6.023

.0457

.0420

Cr2677 PPm .1944 .0007 .3764

.1949

.1939

Mn2576 PPm * 5012 .0008 .1701

.5006

.5018

2203/2 PPm .4882 .0024 .4935

.4899

.4865

Si2881 PPm .0428 .0025 5.946

.0410

.0446

T11908 PPm 2.099 .012 .5522

2.107 2.091

PPm Ba4934 PPm 2.058 .004 .2168

2.061 2.055

Cu3247 PPm .2530 .0012 .4843

.2539

.2522

Mo2 02 0 PPm . o o o o .0003 8025.

- . 0002 .0002

Pd3404 PPm .0040 .0029 72.03

. 0 0 2 0

.0060

Pb2 2 0 PPm -4874 .0011 .2338

.4882

.4866

U 4090

-0516 -0581 112.6

.0105

.0927

PPm

010115

Be3130 Bi2230 PPm PPm .0501 .0080 .OOOl .0063 .1565 79.42

.0501 .0035

.0502 .0125

Fe2714 K - 7664 PPm PPm 1.168 19.77 -015 .02

1.298 .0976

1.157 19.76 1.179 19.78

Na3302 Na5889 PPm PPm 31.82 55.74

.3a .03 1.190 .0576

31.55 55.71 32.08 55.76

S 1820 Sb2068

5.121 .4963 .040 .0037 .7904 .7524

Pi% PPm

5.149 .4936 5.092 .4989

Se196 Sn1899 PPm PPm 2.068 .0016

* 001 .0027 .0506 169.9

2.069 - . 0003 2.067 .0035

V 2924 W - 2079

.4967 -0073 ,0005 .0013 .lo67 18.10

PPm PPm

.4971 .0063

.4964 .0082

04/16/07 06:47:22 PM Analysis Report


Y 3710 PPm - . 0005 .0003

58.00

Zn2062 PPm .4972 .0006 .1184

Zr3496 PPm - . 0010 .0014

142.9

#1 #2

- . 0003 - . 0007

.4968

.4977 . o o o o - . 0020

4 NOTUSED - -

5 NOTUSED - -

6 NOTUSED - _

7 NOTUSED - -


1 *Counts sc 361.384 1036802 5221.983 .5036628

2 Time _ _ - - 10000 . o o o o o o o . o o o o o o o

3 NOTUSED - -

#1 #2

1040494 1033109

10000 10000

A n a l y s i s Report 0 4 / 1 6 / 0 7 0 6 : 5 2 : 0 9 PM Page 1

Method: DAILY2 S a m p l e N a m e : 2 9 4 9 5 5 Run T i m e : 0 4 / 1 6 / 0 7 1 8 : 4 7 : 3 4 C o m m e n t : Mode: CONC C o r r . F a c t o r : 1

Operator: 010117

E l e m Au3280 A13082 A s 1 8 9 0 B 2 4 9 6 B a 4 9 3 4 Be3130 B i 2 2 3 0 d

U n i t s ppm PPm PPm P& PPm PPm PPm A v q e . 0 0 0 4 . 0 0 8 2 - . 0 0 1 9 . 0 4 7 4 . 0 1 8 6 . o o o o - . 0 0 1 5 SDev . 0 0 0 3 . 0 0 5 9 . 0 0 0 5 . 0 0 1 6 . 0 0 0 2 . o o o o . 0 0 5 9 %RSD 7 1 . 9 8 7 1 . 7 8 2 4 . 2 0 3 . 3 2 8 1 . 1 2 1 3 3 8 . 6 3 9 9 . 3

#1 . 0 0 0 2 . 0 0 4 0 - . 0 0 1 6 . 0 4 8 5 . 0 1 8 8 - . 0 0 0 0 . 0 0 2 7 #2 . 0 0 0 7 . 0 1 2 3 - . 0 0 2 2 . 0 4 6 3 . 0 1 8 5 . o o o o - . 0 0 5 7

E l e m C a 3 1 7 9 C d 2 2 6 5 Co2286 C r 2 6 7 7 Cu3247 F e 2 7 1 4 K - 7 6 6 4

A v g e . 0 1 7 0 . 0 0 0 2 . 0 0 1 2 - . 0 0 1 7 - . 0 0 0 3 . 0 3 7 9 2 . 7 8 2 S D e v . 0 0 2 1 . 0 0 0 2 . 0 0 0 7 . 0 0 1 6 . 0 0 0 9 . 0 3 1 1 . 0 2 7 %RSD 1 2 . 3 0 1 2 7 . 8 5 6 . 7 4 9 8 . 2 1 2 9 4 . 6 8 1 . 9 7 . 9 6 7 3


#1 . 0 1 5 5 . o o o o . 0 0 0 7 - . 0 0 0 5 . 0 0 0 3 . 0 1 5 9 2 . 7 6 3 - . 0 0 0 9 . 0 5 9 9 2 . 8 0 1 #2 . 0 1 8 5 - 0 0 0 4 . 0 0 1 6 - . 0 0 2 8

E l e m L a 3 9 8 8 L i 6 7 0 7 Mg2790 Mn2576 Mo2020 Na3302 Na5889 U n i t s ppm PPm PPm PPm PPm PPm PPm A v g e .OOlO - . 0 0 0 4 . 0 4 3 5 . o o o o - . 0 0 0 6 1 3 . 2 8 2 2 . 6 1 SDev . 0 0 0 8 - 0 0 0 1 . 0 0 7 5 . O O O l - 0 0 0 2 . 1 4 . 0 3 %RSD 8 5 . 5 6 2 1 . 5 8 1 7 . 1 8 388 .5 4 1 . 4 1 1 . 0 2 6 . 1 3 0 5

#1 . 0 0 0 4 - . 0 0 0 4 . 0 3 8 2 . O O O l - . 0 0 0 4 1 3 . 1 9 2 2 . 6 3 #2 . 0 0 1 6 - . 0 0 0 3 . 0 4 8 8 - . 0 0 0 1 - . 0 0 0 7 1 3 . 3 8 2 2 . 5 9

E l e m N i 2 3 1 6 P - 1 7 8 2 2 2 0 3 / 1 2 2 0 3 / 2 P d 3 4 0 4 S - 1 8 2 0 S b 2 0 6 8 U n i t s ppm PPm PPm PPm PPm PPm PPm A v q e - . 0 0 0 3 - . 0 0 3 6 . 0 0 2 9 - . 0 0 2 0 . 0 0 0 2 1 . 0 5 8 . 0 0 9 6 S D e v . O O O l - 0 0 9 4 . 0 0 0 2 . 0 0 1 6 . 0 0 3 1 . O O l . 0 0 2 2 %RSD 4 2 . 6 7 2 5 9 . 9 5 . 7 4 5 8 2 . 2 6 1 8 4 5 . . 0 6 6 2 2 2 . 3 2

#1 - . 0 0 0 2 . 0 0 3 0 . 0 0 2 8 - . 0 0 3 1 - . 0 0 2 0 1 . 0 5 9 . 0 0 8 1 #2 - . 0 0 0 4 - . 0 1 0 3 . 0 0 3 0 - . 0 0 0 8 . 0 0 2 3 1 . 0 5 8 . 0 1 1 2

S e 1 9 6 S n 1 8 9 9 E l e m S c 3 6 1 3 1 9 6 0 / 1 1 9 6 0 / 2 S i 2 8 8 1 P b 2 2 0 U n i t s %R PPm PPm PPm PPm PPm PPm A v g e 1 0 7 . 4 . 0 0 4 8 - . 0 0 3 4 . 0 2 6 3 - . 0 0 0 4 - . 0 0 0 6 . 0 0 0 2 SDev . 5 . 0 0 2 7 . 0 0 0 9 . 0 0 2 3 . O O l l . 0 0 0 3 . 0 0 0 6 %RSD . 4 6 4 5 5 6 . 4 1 2 6 . 4 5 8 . 7 0 2 3 2 4 . 1 4 7 . 9 1 2 9 3 . 2

#1 1 0 7 . 7 . 0 0 6 8 - . 0 0 4 0 . 0 2 4 7 - . 0 0 1 2 - . 0 0 0 4 . 0 0 0 6 #2 1 0 7 . 0 . 0 0 2 9 - . 0 0 2 8 . 0 2 8 0 . 0 0 0 5 - . 0 0 0 9 - . 0002

V 2 9 2 4 W 2 0 7 9 E l e m S r 4 2 1 5 T h 2 8 3 7 T i 3 3 4 9 T11908 U 4 0 9 0

A v g e . O O O l - . 0 0 6 3 - . 0 0 0 5 - . 0 0 1 3 . 0 4 6 7 - . 0 0 1 4 . 0 0 3 4 SDev . o o o o . 0 0 8 8 . 0 0 0 4 . 0 0 1 2 - 0 1 8 2 . 0 0 0 8 . 0 0 2 1 %RSD 3 5 . 2 3 1 3 8 . 5 8 4 . 8 1 9 9 . 0 9 3 8 . 9 0 5 6 . 2 9 6 1 . 2 6


#1 . O O O l - . 0 0 0 1 - . 0 0 0 2 - . 0004 . 0 3 3 9 - . 0 0 0 8 . 0 0 4 8 #2 . O O O l - . 0 1 2 6 - . 0 0 0 7 - . 0 0 2 1 . 0 5 9 6 - . 0 0 1 9 . 0 0 1 9

Analysis Report


#1 #2


#1 # 2

Y - 3710 PPm - . 0002

. 0002 122.7

- . 0000 - . 0003

1 *Counts sc

1055676 4953.283 .4692051

1059178 1052173

361.384

Zn2062 PPm . 0 0 1 2 . 0 0 0 5 37.10

.0009

.0016

2 Time _ - - - 10000 . o o o o o o o . o o o o o o o

10000 10000

Zr3496 PPm - . 0010 .0013

128.9

- . 0001 - . 0019

3 NOTUSED - - - - - _ _ - - -

- - - -

04/16/07 06:52:09 PM page 2

010118

A n a l y s i s Report 0 4 / 1 6 / 0 7 0 6 : 5 6 : 5 7 PM Page 1

010119 Method: DAILY2 Sample N a m e : 2 9 4 9 5 6 O p e r a t o r : Run T i m e : 0 4 / 1 6 / 0 7 1 8 : 5 2 : 2 1 C o m m e n t : Mode: CONC Corr . F a c t o r : 1

E l e m Ag3280 A13082 A s 1 8 9 0 B 2 4 9 6 B a 4 9 3 4 B e 3 1 3 0 B i 2 2 3 0

A v g e , 0 0 0 3 . 0 0 5 4 - . o o o o . 0 4 5 4 . 0 2 1 2 . o o o o . 0 0 5 5 SDev . 0 0 0 4 . 0 0 2 6 . 0 0 1 7 . 0 0 3 0 . 0 0 0 4 . o o o o . 0 0 3 5 %RSD 1 1 3 . 8 4 8 . 5 6 7 0 9 8 . 6 . 7 0 2 2 . 0 8 0 4 9 7 . 8 6 3 . 2 9


#1 . O O O l . 0 0 3 6 . 0 0 1 2 . 0 4 7 6 . 0 2 1 5 - . o o o o . 0 0 3 0 # 2 . 0 0 0 6 . 0 0 7 3 - . 0 0 1 2 . 0 4 3 3 . 0 2 0 9 . o o o o . 0 0 7 9

E l e m Ca3179 C d 2 2 6 5 Co2286 C r 2 6 7 7 Cu3247 F e 2 7 1 4 K 7 6 6 4

A v g e . 0 1 3 3 . 0 0 0 2 . O O l O - . 0 0 2 1 - . 0 0 0 6 . O O O l 2 . 6 5 4 SDev . 0 0 0 4 . 0 0 0 2 . 0 0 0 2 . 0 0 1 7 . O O l O . 0 1 1 8 . 0 0 6 %RSD 3 . 3 5 7 1 0 3 . 8 2 2 . 2 3 8 1 . 9 1 1 6 9 . 5 1 7 3 7 0 . . 2 2 2 5


#1 . 0 1 3 6 . o o o o . 0 0 0 8 - . 0 0 0 9 . O O O l . 0 0 8 4 2 . 6 5 0 # 2 . 0 1 2 9 . 0 0 0 3 .0011 - . 0 0 3 3 - . 0 0 1 4 - . 0 0 8 3 2 . 6 5 8

E l e m L a 3 9 8 8 L i 6 7 0 7 Mg2790 Mn2576 Mo2020 Na3302 Na5889

A v g e . 0 0 0 5 - . 0 0 0 5 . 0 3 6 0 - . 0 0 0 1 - . 0 0 0 4 1 2 . 7 1 2 1 . 8 8 SDev . 0 0 0 4 . o o o o . 0 0 5 3 . 0 0 0 2 . 0 0 0 4 . 3 1 . 0 6 %RSD 8 0 . 8 3 4 . 1 9 8 1 4 . 7 8 3 2 1 . 0 8 9 . 5 7 2 . 4 2 6 . 2 8 2 7


#1 . 0 0 0 2 - . 0 0 0 5 . 0 3 2 2 . O O O l - . 0 0 0 1 1 2 . 9 2 2 1 . 8 4 #2 . 0 0 0 8 - . 0 0 0 5 . 0 3 9 7 - . 0002 - . 0 0 0 6 1 2 . 4 9 2 1 . 9 2

E l e m N i 2 3 1 6 P - 1 7 8 2 2 2 0 3 / 1 2 2 0 3 / 2 P d 3 4 0 4 S 1 8 2 0 S b 2 0 6 8

A v g e - . 0 0 0 5 - . 0 0 6 3 . 0 0 0 5 - . 0 0 0 9 - . 0 0 0 8 1 . 0 1 9 - 0 0 3 4 SDev . 0 0 1 6 . 0 0 0 6 . o o o o . 0 0 0 7 . 0 0 3 5 . 0 1 2 . 0 0 1 4 %RSD 3 1 3 . 5 9 . 7 7 7 5 . 5 4 1 7 7 . 5 6 4 1 4 . 9 1 . 1 4 2 4 1 . 8 3


#1 . 0 0 0 6 - . 0 0 6 7 . 0 0 0 5 - . 0004 . 0 0 1 6 1 . 0 1 1 . 0 0 4 4 #2 - . 0 0 1 7 - . 0 0 5 8 . 0 0 0 6 - . 0014 - . 0 0 3 3 1 . 0 2 7 . 0 0 2 4

E l e m S c 3 6 1 3 1 9 6 0 / 1 1 9 6 0 / 2 S i 2 8 8 1 Pb2 2 0 S e 1 9 6 S n 1 8 9 9

A v g e 1 0 8 . 8 . 0 0 6 6 . 0 0 1 8 . 0 2 4 3 - . 0 0 0 4 . 0 0 3 4 . 0 0 0 8 SDev .1 . O O l O . 0 0 1 2 . 0 0 1 2 . 0 0 0 5 . 0 0 0 5 . 0 0 2 8 %RSD . 1 2 9 9 1 5 . 8 8 6 8 . 5 0 4 . 8 4 9 1 1 1 . 6 1 3 . 5 7 3 6 2 . 2

U n i t s %R PPm PPm PPm PPm PPm PPm

#1 1 0 8 . 7 . 0 0 5 9 - 0 0 2 6 . 0 2 3 5 - . 0 0 0 1 . 0 0 3 7 - . 0012 #2 1 0 8 . 9 . 0 0 7 3 . 0 0 0 9 . 0 2 5 1 - . 0 0 0 7 . 0 0 3 1 . 0 0 2 8

E l e m S r 4 2 1 5 T h 2 8 3 7 T i 3 3 4 9 T11908 U 4 0 9 0 V 2 9 2 4 W 2 0 7 9

A v g e .OOOl - . 0 0 8 0 - . 0 0 0 5 - . 0 0 0 9 . 0 2 2 2 - . 0 0 0 8 . 0 0 3 3 S D e v . o o o o . 0 0 5 5 . 0 0 0 4 . 0 0 3 4 . 0 1 4 6 . 0 0 1 9 . 0 0 2 2 %RSD 1 4 . 8 9 6 8 . 2 8 9 1 . 9 1 3 6 8 . 7 6 5 . 8 4 2 4 8 . 4 6 7 . 2 3

U n i t s ppm PPm PPm PPm PPm PPm P b

#1 . O O O l - . 0 0 4 2 - . 0 0 0 2 - . 0 0 3 4 . 0 1 1 9 . 0 0 0 6 . 0 0 1 7 #2 . O O O l - . 0 1 1 9 - . 0 0 0 8 . 0 0 1 5 . 0 3 2 6 - . 0 0 2 1 . 0 0 4 8

Analysis Report 0 4 / 1 6 / 0 7 0 6 : 5 6 : 5 7 PM

010120 Elem Units Avge SDev %RSD

Y 3 7 1 0

- . 0002 . 0 0 0 3

1 2 7 . 0

PPm Zn2062 PPm . 0 0 1 2 . o o o o . 2 3 2 4

Z r 3 4 9 6 PPm - . 0 0 1 2

. 0 0 2 1 1 7 3 . 1

#1 #2

- . 0 0 0 0 - . 0 0 0 5

. 0 0 1 2

. 0 0 1 2 . 0 0 0 3 - . 0 0 2 6

4 NOTUSED

5 NOTUSED

6 NOTUSED

7 NOTUSED


3 NOTUSED - -

1 * C o u n t s sc 3 6 1 . 3 0 4 1 0 6 9 8 0 6 1 2 9 6 . 1 2 7 . 1 2 1 1 5 5 3

2 Time

1 0 0 0 0 . o o o o o o o . o o o o o o o

#1 #2

10000 10000

1 0 6 8 8 9 0 1 0 7 0 7 2 3


Method: DAILY2 Sample Name: 2 9 4 9 5 7 Run T i m e : 0 4 / 1 6 / 0 7 1 8 : 5 7 : 0 9 C o m m e n t : Mode: CONC C o r r . F a c t o r : 1

E l e m Units A v g e SDev %RSD

#1 # 2


#1 #2


#1 #2


#1 # 2


#I # 2


#1 #2

A93280 PPm - . 0 0 0 3

. o o o o 9 . 8 7 9

- . 0 0 0 3 - . 0 0 0 3

Ca3179 PPm . 0 1 5 1 . 0 0 1 9 1 2 . 5 6

. 0 1 3 8

. 0 1 6 5

L a 3 9 8 8 PPm - . 0 0 0 1

. 0 0 0 4 2 5 3 . 8

- . 0 0 0 4 . O O O l

N i 2 3 1 6 PPm . 0 0 0 3 . 0 0 2 1 6 5 4 . 3

- 0 0 1 8 - . 0012

S c 3 6 1 3 %R 1 0 7 . 3

1.1 . 9 8 8 3

1 0 6 . 6 1 0 8 . 1

S r 4 2 1 5 PPm . o o o o . o o o o 1 6 . 5 0

. o o o o

. O O O l

A13082 PPm . 0 1 1 2 . 0 0 0 6 5 . 7 0 8

. 0 1 1 6

. 0 1 0 7

C d 2 2 6 5 PPm . O O O l . O O O l 7 9 . 3 7

. o o o o

. O O O l

L i 6 7 0 7 PPm - . 0 0 0 5

. o o o o 1 0 . 3 4

- . 0 0 0 5 - . 0 0 0 4

P 1 7 8 2

. 0 0 8 7

. 0 2 3 1 2 6 4 . 2

Pi%

- . 0 0 7 6 . 0 2 5 1

1 9 6 0 / 1 PPm . 0 0 7 4 . 0 0 1 6 2 1 . 7 0

. 0 0 8 6

. 0 0 6 3

T h 2 8 3 7 PPm - . 0 0 3 3

- 0 0 6 1 1 8 7 . 1

. O O l l - . 0 0 7 6

A s 1 8 9 0 PPm . 0 0 1 8 . 0 0 1 2 6 5 . 0 4

. O O l O

. 0 0 2 7

Co2286 PPm . 0 0 1 3 . 0 0 0 5 3 6 . 1 7

. O O l O

. 0 0 1 6

Mg2790 PPm . 0 3 8 6 . 0 0 3 7 9 . 7 1 2

. 0 3 5 9

. 0 4 1 2

2 2 0 3 / 1 PPm . 0 0 3 0 , 0 0 2 4 8 1 . 1 5

. 0 0 1 3

. 0 0 4 7

1 9 6 0 / 2 PPm - . 0 0 0 9

. 0 0 1 4 155 .8

. O O O l - . 0 0 1 9

T i 3 3 4 9 PPm - . 0 0 0 3

. 0 0 0 6 2 1 2 . 2

. O O O l - . 0 0 0 7

0 4 / 1 6 / 0 7 0 7 : 0 1 : 4 8 PM

B - 2 4 9 6 PPm . 0 4 8 1 . 0 0 1 4 2 . 8 0 4

. 0 4 9 0

. 0 4 7 1

C r 2 6 7 7 PPm - . 0014

. 0 0 1 9 1 3 7 . 7

- . 0 0 0 0 - . 0 0 2 7

Mn2576 PPm . O O O l . 0 0 0 3 2 6 6 . 0

. 0 0 0 3 - . 0 0 0 1

2 2 0 3 / 2 PPm - . 0 0 0 6

, 0 0 0 0 . 6 4 5 5

- . 0 0 0 6 - . 0 0 0 6

S i 2 8 8 1 PPm . 0 2 2 7 . 0 0 1 5 6 . 5 5 5

. 0 2 3 7

. 0 2 1 6

T11908 PPm - . 0 0 3 0

. 0 0 3 1 1 0 3 . 7

- . 0 0 5 1 - . 0 0 0 8

Ba4934 PPm . 0 2 5 0 . 0 0 0 3 1 . 0 9 7

. 0 2 5 2

. 0 2 4 8

Cu3247 PPm - . 0 0 0 5

. 0 0 1 6 3 1 8 . 3

. 0 0 0 6 - . 0 0 1 6

Mo2 02 0 PPm . 0 0 0 2 . 0 0 0 3 2 0 9 . 4

. 0 0 0 4 - . 0 0 0 1

P d 3 4 0 4 PPm - . 0 0 2 5

. 0 0 5 9 2 3 2 . 2

- . 0 0 6 7 - 0 0 1 6

Pb220 PPm . 0 0 0 6 . 0 0 0 8 1 3 2 . 2

. o o o o

. 0 0 1 2

U 4 0 9 0 PPm . 0 2 6 9 . 0 0 3 0 1 0 . 9 9

. 0 2 9 0

. 0 2 4 8

-

Operator:

B e 3 1 3 0 PPm . o o o o . o o o o 1 0 4 . 5

. o o o o

. o o o o

F e 2 7 1 4 PPm - . 0 0 1 6

. 0 2 2 8 1 4 6 5 .

- . 0 1 7 7 . 0 1 4 6

Na3302 PPm 1 3 . 7 8

- 1 6 1 . 1 9 3

1 3 . 6 7 1 3 . 9 0

S 1 8 2 0

1 . 0 9 6 . 0 1 7

1 . 5 7 4

1 . 0 8 3 1 . 1 0 8

S e 1 9 6 PPm . 0 0 1 9 . 0 0 1 5 7 7 . 4 3

. 0 0 2 9

. 0 0 0 9

V 2 9 2 4

- . 0 0 1 0 * 0 0 2 0

1 9 9 . 3

. 0 0 0 4

PPm

P P m

- . 0 0 2 5

Page 1

010121

B i 2 2 3 0 PPm - . 0 0 1 7

. 0 0 0 9 5 5 . 1 2

- . O O l O - . 0 0 2 3

K 7 6 6 4

2 . 8 6 7 . 0 1 9

. 6 4 6 5

2 . 8 5 4 2 . 8 8 0

Na5889 PPm 2 3 . 5 4

. 0 9 . 3 8 5 9

2 3 . 6 0 2 3 . 4 7

S b 2 0 6 8 PPm . 0 0 5 5 . 0 0 0 6 1 0 . 4 1

. 0 0 5 9

. 0 0 5 1

S n 1 8 9 9 PPm . 0 0 0 5 . 0 0 0 3 6 7 . 2 2

. 0 0 0 3

. 0 0 0 7

W 2 0 7 9

. 0 0 1 7

. 0 0 1 5 8 7 . 6 0

. 0 0 2 7

. 0 0 0 6

PPm

PPm

Analysis Report


#1 #2


Y - 3710 PPm - . 0002 .0003

194.6

.OOOl - . 0004 1 *Counts sc 361.384 1055467 10476.49 .9925932

Zn2062 PPm .0004 .OOOl 33.38

.0004

.0003

2 Time

_ _ 10000 . o o o o o o o . o o o o o o o

Zr3496 PPm - . 0005 .0018

397.1

. 0 0 0 8 - . 0017

04/16/07 07:01:48 PM

3 4 5 6 7 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED

A n a l y s i s R e p o r t 0 4 / 1 6 / 0 7 0 7 : 0 6 : 3 8 PM

Method: DAILY2 Sample N a m e : 2 9 4 9 5 8 Run T i m e : 0 4 / 1 6 / 0 7 1 9 : 0 2 : 0 0 C o m m e n t : Mode: CONC C o r r . F a c t o r : 1


#1 #2


#I #2


#I #2


#1 #2


#1 #2


#1 #2

Ag3280 PPm - . 0002

. 0 0 0 6 3 8 0 . 3

- . 0 0 0 6 . 0 0 0 3

Ca3179 PPm . 0 3 0 2 . 0 0 1 9 6 . 2 6 6

. 0 2 8 9

. 0 3 1 6

L a 3 9 8 8 PPm - . 0002 .0011

5 5 9 . 7

- . 0 0 0 9 . 0 0 0 6

N i 2 3 1 6 PPm - . 0 0 0 9

. 0 0 0 2 2 7 . 2 7

- . 0 0 0 7 - . 0 0 1 0

S c 3 6 1 3 %R 1 0 8 . 5

. 6 . 5 5 4 8

1 0 9 . 0 1 0 8 . 1

S r 4 2 1 5 PPm . 0 0 0 3 . o o o o 1 6 . 7 5

. 0 0 0 2

. 0 0 0 3

A13082 PPm . 0 0 4 2 . 0 0 8 1 1 9 1 . 9

- . 0 0 1 5 . 0 0 9 9

C d 2 2 6 5 PPm - . 0 0 0 0

. 0 0 0 3 3 2 8 8 .

- . 0 0 0 2 . 0 0 0 2

L i 6 7 0 7 P P m - . 0 0 0 4 .OOOl

2 3 . 3 1

- . 0 0 0 5 - . 0 0 0 3

P 1 7 8 2 PPm - . 0 0 3 2

. 0 1 3 7 4 3 4 . 2

- . 0 1 2 8 . 0 0 6 5

1 9 6 0 / 1 PPm . 0 0 6 0 . 0 0 5 3 8 9 . 3 4

. 0 0 9 8

. 0 0 2 2

T h 2 8 3 7 PPm - . 0 0 6 1

. 0 0 7 7 1 2 7 . 1

- . 0 0 0 6 - . 0 1 1 5

A s 1 8 9 0 PPm . 0 0 1 8 . 0 0 1 5 8 3 . 5 2

. 0 0 0 8

. 0 0 2 9

Co2286 PPm . 0 0 0 8 . 0 0 0 5 6 8 . 2 9

. 0 0 0 4

. 0 0 1 2

Mg2790 PPm . 0 2 4 3 . 0 0 5 9 2 4 . 4 4

. 0 2 0 1 , 0 2 8 5

2 2 0 3 / 1 PPm . 0 0 1 8 . 0 0 4 9 2 6 4 . 2

- . 0 0 1 6 . 0 0 5 3

1 9 6 0 / 2 PPm . 0 0 0 8 . 0 0 2 0 2 5 2 . 3

. 0 0 2 2 - . 0 0 0 6

T i 3 3 4 9 PPm - . 0 0 0 6

7 3 . 0 9

- . 0 0 0 3 - . 0 0 0 9

. 0 0 0 4

B 2 4 9 6

. 1 4 0 7 - 0 0 0 6 . 4 1 1 8

. 1 4 1 1

. 1 4 0 3

C r 2 6 7 7 PPm - . 0 0 2 0

. 0 0 1 2 6 2 . 7 0

- . 0 0 1 1 - . 0 0 2 9

PPm

Mn2576 PPm - . 0 0 0 1

. 0 0 0 2 1 3 3 . 4

- . 0 0 0 0 - . 0 0 0 3

2 2 0 3 / 2 PPm - . 0 0 0 0

. 0 0 0 5 1 3 5 7 .

- 0 0 0 3 - . 0 0 0 4

S i 2 8 8 1 PPm . 0 8 8 1 . 0 0 1 8 1 . 9 8 3

. 0 8 6 9

. 0 8 9 4

T 1 1 9 0 8 PPm - . 0 0 0 3

. 0 0 0 2 6 5 . 7 5

- . 0 0 0 5 - . 0002

Ba4934 PPm . 0 8 9 1 . 0 0 0 3 . 3 2 0 0

. 0 8 9 3

. 0 8 8 9

Cu3247 PPm - . 0 0 0 5

. 0 0 1 3 2 4 8 . 8

- 0 0 0 4 - . 0 0 1 5

Mo2020 PPm - . 0 0 0 4 .OOOl

2 3 . 0 9

- . 0 0 0 3 - . 0 0 0 4

Pd3404 PPm - . 0 0 6 7

. 0 0 6 0 8 8 . 9 4

- . 0 1 0 9 - . 0 0 2 5

P b 2 2 0 PPm . 0 0 0 6 . 0 0 1 3 2 1 4 . 7

- . 0 0 0 3 . 0 0 1 5

U 4 0 9 0

. 0 2 3 8

. 0 3 5 0 1 4 7 . 0

- . 0 0 0 9 . 0 4 8 5

P P m

Operator:

B e 3 1 3 0 PPm . o o o o . o o o o 7 3 6 . 1

- . 0 0 0 0 . o o o o

F e 2 7 1 4 PPm - . 0 1 1 9

. 0 2 2 2 1 8 6 . 0

- . 0 2 7 6 . 0 0 3 8

Na3302 PPm 4 1 . 5 5

. 4 9 1 . 1 7 6

4 1 . 2 0 4 1 . 8 9

S 1 8 2 0

2 . 9 8 4 .011

. 3 5 9 1

2 . 9 9 1 2 . 9 7 6

S e 1 9 6 PPm . 0 0 2 5 . 0 0 3 1 1 2 3 . 2

. 0 0 4 7

. 0 0 0 3

V - 2 9 2 4 P P m - . 0 0 1 9

. 0 0 1 3 6 7 . 9 6

- . 0 0 1 0 - . 0 0 2 7

PPm

Page 1

010123

B i 2 2 3 0 PPm . 0 0 0 3 . 0 0 5 9 1 9 9 1 .

- . 0 0 3 9 . 0 0 4 5

K 7 6 6 4

9 . 2 6 2 . 0 0 2

. 0 1 8 1

9 . 2 6 1 9 . 2 6 3

Na5889 PPm 7 1 . 3 8

. 2 2 . 3 0 5 1

7 1 . 5 4 7 1 . 2 3

S b 2 0 6 8 PPm . 0 0 3 7 . 0 0 2 2 5 9 . 1 5

. 0 0 2 2

. 0 0 5 3

S n 1 8 9 9 PPm . 0 0 2 8 . 0 0 0 8 2 8 . 4 9

. 0 0 3 4

. 0 0 2 2

W 2 0 7 9

.OOOl

. 0 0 0 6 6 7 2 . 1

. 0 0 0 5

PPm

PPm

- . 0 0 0 3

Analysis Report 04/16/07 07:06:38 PM


Y 3710 PPm - . 0004 -

.0003 75.25

Zn2062 PPm .0012 . 0 0 0 4 32.10

Zr3496 PPm - . 0015 .0012

80.96

#1 #2

- . 0002 - . 0006

. 0 0 0 9

.0014 - . 0006 - . 0024

4 NOTUSED

6 NOTUSED

7 NOTUSED


2 Time

3 NOTUSED

1 *Counts sc 361.384 1067248 5916.362 .5543566

10000 . o o o o o o o . o o o o o o o

#1 #2

1071432 1063065

1 0 0 0 0 1 0 0 0 0


Method: DAILY2 S a m p l e N a m e : 2 9 4 9 5 9 R u n T i m e : 0 4 / 1 6 / 0 7 1 9 : 0 6 : 5 0 C o m m e n t : Mode: CONC C o r r . F a c t o r : 1


#1 #2

E l e m U n i t s A v g e SDev % R S D

#1 #2


#1 #2


#1 #2


#I #2


#1 #2

Ag3280 PPm . 0 0 0 5 . 0 0 0 8 1 5 3 . 5

- . 0 0 0 0 .0011

Ca3179 PPm 1 . 9 6 5

. 0 0 3 . 1 7 0 0

1 . 9 6 7 1 . 9 6 2

L a 3 9 8 8 PPm .OOlO . O O l l 1 0 7 . 6

. 0 0 0 2

. 0 0 1 7

N i 2 3 1 6 PPm - . 0 0 0 3

. O O l l 3 6 5 . 4

. 0 0 0 5 - . 0 0 1 1

S c 3 6 1 3 %R 1 0 8 . 3

1 . 5 1 . 4 0 0

1 0 7 . 2 1 0 9 . 4

S r 4 2 1 5 PPm . O O O l . O O O l 5 2 . 8 8

. O O O l

. 0 0 0 2

A13082 PPm .0071 . 0 0 8 8 1 2 5 . 2

. 0 0 0 8

. 0 1 3 3

C d 2 2 6 5 PPm . 0 0 0 2 . 0 0 0 3 1 6 1 . 2

- . 0 0 0 0 . 0 0 0 3

L i 6 7 0 7 PPm - . 0 0 0 5

. o o o o 2 . 2 0 9

- . 0 0 0 5 - . 0 0 0 5

P 1 7 8 2

. 0 0 8 3

. 0 0 0 3 2 9 9 3

. 0 0 8 4

. 0 0 8 1

1 9 6 0 / 1 PPm . 0 0 3 8 . 0 0 3 4 9 0 . 8 8

. 0 0 6 2

. 0 0 1 3

T h 2 8 3 7 PPm - . 0 0 6 3 . O O l O

PPm

15.57

- . 0 0 5 6 - . 0 0 7 0

A s 1 8 9 0 PPm . 0 0 2 4 . 0 0 0 3 1 1 . 1 4

. 0 0 2 2

. 0 0 2 6

Co2286 PPm . 0 0 0 8 . O O l O 1 2 8 . 4

. O O O l

. 0 0 1 4

Mg2790 PPm 1 . 9 4 0

. 0 0 8 . 4 1 0 9

1 . 9 3 5 1 . 9 4 6

2 2 0 3 / 1 PPm . 0 0 0 3 . 0 0 4 0 1 2 4 3 .

- 0 0 3 2 - . 0 0 2 5

1 9 6 0 / 2 PPm . 0 0 3 4 . 0 0 4 6 1 3 4 . 6

. 0 0 0 2

. 0 0 6 6

T i 3 3 4 9 PPm - , 0 0 0 1 . O O O l

9 9 . 8 0

- . o o o o - . 0 0 0 2

B 2 4 9 6

- . 0 0 2 0 . 0 0 0 9

4 6 . 9 5

PPm

- . 0 0 1 3 - . 0 0 2 7

C r 2 6 7 7 PPm - . 0 0 1 0

. 0 0 0 4 3 8 . 1 4

- . 0 0 0 7 - . 0012

Mn2576 PPm - . 0000 . O O O l

1 6 1 0 0 0 .

. O O O l - . 0 0 0 1

2 2 0 3 / 2 PPm . 0 0 0 3 . O O l l 3 7 7 . 4

- . 0 0 0 5 . O O l l

S i 2 8 8 1 PPm . 0 0 2 4 . 0 0 2 0 8 2 . 7 0

. O O l O

. 0 0 3 8

T11908 PPm . 0 0 3 4 - 0 0 1 4 4 1 . 8 3

. 0 0 4 4

. 0 0 2 4

B a 4 9 3 4 PPm - . 0 0 0 1

. o o o o 3 1 . 7 9

- . 0 0 0 1 - . 0 0 0 2

C u 3 2 4 7 PPm - . o o o o

. 0 0 0 6 1 3 1 9 .

. 0 0 0 4 - . 0 0 0 5

Mo2020 PPm . 0 0 0 7 . 0 0 0 2 3 2 . 0 8

. 0 0 0 5

. 0 0 0 9

P d 3 4 0 4 PPm . 0 0 2 7 * 0 0 1 0 3 7 . 5 0

. 0 0 2 0

. 0 0 3 5

P b 2 2 0 PPm . 0 0 0 3 . 0 0 0 6 1 8 4 . 3

. 0 0 0 7 - . 0 0 0 1

U 4 0 9 0

. 0 4 6 5

. 0 4 1 0 8 7 . 9 7

. 0 1 7 6

. 0 7 5 5

PPm

Operator:

B e 3 1 3 0 PPm . o o o o . o o o o 2 3 . 7 3

. o o o o

. o o o o

F e 2 7 1 4 PPm 2 . 0 0 8

. 002 . 0 8 7 5

2 . 0 0 7 2 . 0 0 9

Na3302 PPm 1 . 6 5 6

. 0 5 6 3 . 3 6 6

1 . 6 1 7 1 . 6 9 6

S 1 8 2 0

. 0 1 8 7

. 0 0 5 2 2 7 . 9 3

. 0 2 2 4

. 0 1 5 0

S e 1 9 6 PPm - 0 0 3 5 . 0 0 1 9 5 3 . 6 5

. 0 0 2 2

. 0 0 4 9

V 2 9 2 4

PPm

PPm - . 0 0 0 4 . o o o o

1 1 . 5 6

- . 0 0 0 4 - . 0 0 0 4

page 1

010125

B i 2 2 3 0 PPm . 0 0 6 9 . 0 0 1 7 2 4 . 2 7

. 0 0 5 7

. 0 0 8 0

K 7 6 6 4

1 . 1 4 8 . 0 0 9

. 7 4 7 2

1 . 1 4 2 1 . 1 5 4

Na5889 PPm 2 . 3 1 9

. 0 1 6 . 7 0 3 3

2 . 3 0 8 2 . 3 3 1

S b 2 0 6 8 PPm . 0 0 3 6 . 0 0 4 8 1 3 2 . 7

. 0 0 7 0

. 0 0 0 2

S n 1 8 9 9 PPm - . 0 0 0 4 . O O l O

PPm

2 4 2 . 6

. 0 0 0 3 - . 0012

W 2 0 7 9

. 0 0 3 2

. 0 0 2 1 6 4 . 8 8

. 0 0 1 7

. 0 0 4 6

PPm

Analysis Report 0 4 / 1 6 / 0 7 0 7 : 1 1 : 2 8 PM Page 2

010126 Elem Units Avge SDev %RSD

Y 3710

- . 0 0 0 1 . O O O l

6 0 . 5 3

PPm Zn2062 PPm . o o o o . 0 0 0 2 4 0 6 . 7

Z r 3 4 9 6 PPm - . 0 0 0 3

. 0 0 0 6 1 7 7 . 8

#1 #2

- . 0 0 0 1 - . 0 0 0 2

- . 0 0 0 1 . 0 0 0 2

. O O O l - . 0 0 0 8

4 NOTUSED

6 NOTUSED


1 *Counts sc 3 6 1 . 3 8 4 1065052 1 4 9 3 9 . 0 5 1 . 4 0 2 6 5 9

2 Time

3 NOTUSED

5 NOTUSED

- - 1 0 0 0 0 . o o o o o o o . o o o o o o o

#1 #2

1 0 5 4 4 8 8 1 0 7 5 6 1 5

1 0 0 0 0 1 0 0 0 0

Analysis Report

Method: DAILY2 Sample Name: CCV3 Run Time: 04/16/07 19:11:40 Comment : Mode: CONC Corr. Factor: 1


#I #2

Errors High Low


#1 #2

Errors High Low


#1 #2

Errors High Low


#1 #2

Errors High Low

Elem

A93280 PPm .9800 .0006 .0620

.9804

.9795

LC Pass 1.100 .goo0

Ca3179 PPm 19.45

. 0 6 .3298

19.50 19.41

LC Pass 22.00 18.00

La3988 PPm 5.017 .012 .2327

5.008 5.025

LC Pass 5.500 4.500

Ni2316 PPm 4.958 .007 .1421

4.953 4.963

LC Pass 5.500 4.500

Sc3613

A13082 PPm 9.859 .013 .1350

9.850 9.868

LC Pass 11.00 9.000

Cd2265 PPm .9971 .OOOl .0062

.9970

.9971

LC Pass 1.100 .goo0

Li6707 PPm 4.847 .013 .2703

4.838 4.857

LC Pass 5.500 4.500

P - 1782 PPm 5.086 -031 .6047

5.107 5.064

LC Pass 5.500 4.500

1960/1

As1890 PPm 5.127 .007 .1381

5.122 5.132

LC Pass 5.500 4.500

Co2286 PPm 5.086 .006 .1183

5.090 5.082

LC Pass 5.500 4.500

Mg2790 PPm 19.76

.oo .0209

19.77 19.76

LC Pass 22.00 18.00

2203/1 PPm 4.846 .007 .1385

4.851 4.841

NOCHECK

1960/2

04/16/07 07:16:18 PM

B 2496

5.117 .026 .5179

5.099 5.136

LC Pass 5.500 4.500

Cr2677 PPm 1.980

* 001 -0590

1.981 1.979

LC Pass 2.200 1.800

Mn2576 PPm 1.013 .OOl .0543

1.013 1.012

LC Pass 1.100 .goo0

2203/2 PPm 4.993 .031 -6172

5.014 4.971

NOCHECK

PPm

Si2881

Operator:

Ba4934 PPm 10.28

.04 .3589

10.26 10.31

LC Pass 11.00 9.000

Cu3247 PPm 2 - 096 .003 -1533

2.093 2.098

LC Pass 2.200 1.800

Mo2020 PPm 4.991 .003 .0678

4.988 4.993

LC Pass 5.500 4.500

Pd3404 PPm 1.034 -003 .3330

1.036 1.032

LC Pass 1.100 .goo0

Pb220

Be3130 PPm .9815 .0013 .1279

.9824

.9806

LC Pass 1.100 .goo0

Fe2714 PPm 10.23

.04 .3760

10.25 10.20

LC Pass 11-00 9.000

Na3302 PPm 28.82

.09 .2957

28.88 28.76

LC Pass 33.00 27.00

S - 1820 PPm 1.079 .010 .8941

1.072 1.086

LC Pass 1.100 .goo0

Se196

Page 1

010127

Bi2230 PPm 5.137 .005 .0900

5.140 5.134

LC Pass 5.500 4.500

K 7664

18.51 .07

.3691

18.46 18.56

LC Pass 22.00 18.00

Na5889 PPm H50.92

.Ol .0112

H50.91 H50.92

PPm

LC High 33.00 27.00

Sb2068 PPm 1.020 .007 .7252

1.015 1.025

LC Pass 1.100 .g000

Sn1899

Analys is Report OlOY2B

04/16/07 07:16:18 PM

U n i t s A v g e SDev %RSD

%R 112.1 1.0

-9238

P P m 5.097 .001 .0267

P P m 5.264 .027 .5208

P P m 5.102 .006 .1263

P P m 4.944 .023 .4608

P P m 5.208 .019 -3596

P P m 5.116 .002 .0331

#1 #2

111.3 112.8

5.098 5.096

5.283 5.245

5.106 5.097

4.960 4.928

5.222 5.195

5.115 5.117

Errors High L o w

NOCHECK NOCHECK NOCHECK LC Pass 5.500 4.500

LC Pass 5 . 5 0 0 4.500

LC Pass 5.500 4.500

LC Pass 5.500 4.500


Sr4215 P P m 4.910 .009 .1802

Th2837 P P m .9983 .0062 ,6228

Ti3349 P P m 4.824 .004 .0907

T11908 P P m 5.327 .016 .3055

U 4090

1.047 .001 .0581

P P m V 2924

5.044 .001 .0118

P P m W 2079

1.089 .001

.1004

P P m

#1 #2

4.904 4.916

.9939 1.003

4.820 4.827

5.316 5.339

1.048 1.047

5.044 5.043

1.090 1.088

Errors H i g h L o w

LC Pass 5.500 4.500

LC Pass 1 . 1 0 0 .goo0

LC Pass 5.500 4.500

LC Pass 5.500 4.500

LC Pass 1 . 1 0 0 . g o o 0

LC Pass 5.500 4.500

LC Pass 1 . 1 0 0 .g000

E l e m U n i t s A v g e S D e v %RSD

Y 3710

5.090 .012 .2387

P P m Zn2062 P P m .9970 .0022 .2209

Zr3496 P P m 4.975 .016 .3187

#1 # 2

5.082 5.099

.9985

.9954 4.963 4.986

Errors High L o w

LC Pass 5.500 4.500

LC Pass 1.100 .goo0

LC Pass 5.500 4.500

Analysis Report


#1 #2

1 *Counts sc 361.384 1102047 10163.95 .9222794

1094860 1109234

2 Time - - - - 10000 . o o o o o o o .ooooooo

1 0 0 0 0 1 0 0 0 0

3 NOTUSED

04/16/07 07:16:18 PM

5 6

Page

014129

3


Method: DAILY2 Sample N a m e : CCB3 Run T i m e : 0 4 / 1 6 / 0 7 1 9 : 1 6 : 3 0 C o m m e n t : Mode: CONC C o r r . F a c t o r : 1

Operator:

E l e m Ag3280 A13082 A s 1 8 9 0 U n i t s ppm PPm PPm A v g e - . 0002 - . 0 0 8 2 .OOlO SDev . 0 0 0 6 . 0 0 5 9 . O O l l %RSD 2 3 0 . 1 7 2 . 1 9 1 0 9 . 4

B 2 4 9 6 B a 4 9 3 4 Be3130

. 0 0 7 0 . o o o o - . 0 0 0 0 - 0 0 2 5 . 0 0 0 2 . o o o o 3 5 . 5 9 1 0 4 4 . 3 4 . 1 0

PPm PPm PPm B i 2 2 3 0 PPm . 0 0 0 2 . 0 0 0 5 2 0 8 . 2

#1 - . 0 0 0 6 - . 0 1 2 4 . 0 0 0 2 # 2 . 0 0 0 2 - . 0 0 4 0 . 0 0 1 8

. 0 0 8 7 .OOOl - . 0 0 0 0

. 0 0 5 2 - . 0 0 0 1 - . 0000 . 0 0 0 6 - . 0 0 0 1

E r r o r s LC P a s s LC P a s s LC P a s s H i g h . 0 0 5 0 . 0 5 0 0 . 0 0 5 0 Low - . 0 0 5 0 - . 0 5 0 0 - . 0 0 5 0

LC P a s s LC P a s s LC P a s s . 0 5 0 0 . 0 0 5 0 . 0 0 5 0 - . 0 5 0 0 - . 0 0 5 0 - . 0 0 5 0

LC P a s s . O l O O - . 0 1 0 0

E l e m C a 3 1 7 9 C d 2 2 6 5 Co2286 U n i t s p p m PPm PPm A v g e - . 0 0 1 2 .OOOl - . 0 0 0 6 SDev . 0 0 1 2 . 0 0 0 2 . 0 0 0 4 %RSD 1 0 2 . 7 2 8 6 . 0 6 9 . 0 7

C r 2 6 7 7 Cu3247 F e 2 7 1 4 PPm PPm PPm - . 0 0 0 4 . 0 0 0 4 - . 0 1 3 7 . O O l O . 0 0 0 2 . 0 0 6 4

2 8 0 . 0 6 5 . 5 7 4 6 . 5 9

K 7 6 6 4 PPm - . 0 4 1 3

. 0 1 4 1 3 4 . 2 0

#1 - . 0 0 2 0 - . 0 0 0 1 - . 0 0 1 0 #2 - . 0 0 0 3 . 0 0 0 2 - . 0 0 0 3

, 0 0 0 4 . 0 0 0 5 - . 0 0 9 2 - . 0 0 1 1 . 0 0 0 2 - . 0 1 8 2

- . 0512 - . 0 3 1 3


LC P a s s LC P a s s LC P a s s . 0 0 5 0 . 0 0 5 0 . 0 5 0 0 - . 0 0 5 0 - . 0 0 5 0 - . 0 5 0 0

LC P a s s . l o o 0 - . 1 0 0 0

E l e m L a 3 9 8 8 L i 6 7 0 7 Mg2790 U n i t s ppm PPm PPm A v g e - . 0 0 0 6 - . 0 0 0 7 - . 0 0 5 9 SDev .OOlO . o o o o . 0 0 4 5 %RSD 1 5 2 . 0 6 . 5 4 9 7 6 . 8 1

Mn2576 Mo2020 Na3302 PPm PPm PPm . o o o o . 0 0 0 6 L - . 3 8 3 9 . o o o o . 0 0 0 9 . 1 1 9 6 1 4 6 . 1 1 5 2 . 6 3 1 . 1 7

Na5889 PPm

L - . 1 8 4 0 . 0 0 4 4

2 . 3 7 9

#1 - . 0 0 1 3 - . 0 0 0 7 - . 0 0 9 1 #2 . o o o o - . 0 0 0 7 - . 0 0 2 7

. O O O l . 0 0 1 2 L- . 4 6 8 5 - . 0 0 0 0 - . 0 0 0 0 L- . 2 9 9 3

L - . 1 8 7 1 L - . 1 8 0 9


LC P a s s LC P a s s LC Low . 0 0 5 0 . 0 0 5 0 - 0 5 0 0 - . 0 0 5 0 - . 0 0 5 0 - . 0 5 0 0

LC Low . 0 5 0 0 - . 0 5 0 0

E l e m N i 2 3 1 6 P 1 7 8 2 2 2 0 3 / 1 U n i t s ppm PPm PPm A v g e . 0 0 0 4 L - . 0 1 1 3 - . 0 0 2 2 SDev . 0 0 0 8 . 0 0 7 7 . 0 0 7 5 %RSD 2 3 0 . 6 6 7 . 6 9 3 3 8 . 5

2 2 0 3 / 2 P d 3 4 0 4 S 1 8 2 0

. 0 0 1 6 L- . 0 0 5 8 .0112

. 0 0 1 6 . 0 0 3 8 . 0 0 3 4 1 0 3 . 0 6 5 . 5 5 2 9 . 9 9

PPm PPm PPm S b 2 0 6 8 PPm . 0 0 3 5 . O O O l 1 . 8 5 5

#1 . 0 0 0 9 L - . 0 1 6 7 - . 0 0 7 5 #2 - . 0 0 0 2 - . 0 0 5 9 . 0 0 3 1

- 0 0 2 8 L - . 0 0 8 5 . 0 0 8 8 . 0 0 0 4 - . 0 0 3 1 . 0 1 3 5

. 0 0 3 5

. 0 0 3 4

E r r o r s LC P a s s LC Low NOCHECK

Low - . 0 0 5 0 - . 0 1 0 0 H i g h . 0 0 5 0 -0100

NOCHECK LC Low LC P a s s . 0 0 5 0 . 0 2 0 0 - . 0 0 5 0 - . 0 2 0 0

LC P a s s .OlOO - . 0 1 0 0

E l e m S c 3 6 1 3 1 9 6 0 / 1 1 9 6 0 / 2 S i 2 8 8 1 P b 2 2 0 S e 1 9 6 S n 1 8 9 9

A n a l y s i s R e p o r t 0 4 / 1 6 / 0 7 0 7 : 2 1 : 0 8 PM page 2

010131 PPm PPm PPm PPm - . 0 0 8 2 . 0 0 0 3 . 0 0 1 2 . O O l l

. 0 0 4 9 . 0 0 1 4 . 0 0 0 4 . 0 0 1 6 6 0 . 3 9 4 0 5 . 0 3 5 . 9 6 151 .5

U n i t s %R A v g e 1 1 4 . 1 SDev . 2 %RSD . 1 9 6 8

PPm . 0 0 1 4 . 0 0 3 5 2 5 4 . 3

PPm . O O l O . O O l l 1 1 1 . 0

#1 1 1 4 . 2 # 2 1 1 3 . 9

- . 0 0 1 1 . 0 0 3 9

. 0 0 1 8

. 0 0 0 2 L- . 0 1 1 7 - . 0 0 0 6 . 0 0 0 9 - * 0 0 0 1 - . 0 0 4 7 . 0 0 1 3 . 0 0 1 4 . 0 0 2 2


NOCHECK NOCHECK LC P a s s LC P a s s LC P a s s LC P a s s . O l O O . 0 0 5 0 . 0 0 5 0 . 0 0 5 0 - . 0 1 0 0 - . 0 0 5 0 - . 0050 - . 0050

E l e m S r 4 2 1 5 Units ppm A v g e . o o o o SDev . o o o o %RSD 5 4 2 . 9

T h 2 8 3 7 PPm . 0 0 2 6 . 0 0 3 4 1 3 4 . 5

T i 3 3 4 9 PPm . o o o o . O O O l 3 3 6 . 8

T11908 U 4 0 9 0 V 2 9 2 4 W 2 0 7 9

. 0 0 2 6 - . 0 0 9 1 . 0 0 0 2 . 0 0 2 8

. 0 0 2 1 . 0 2 9 1 . o o o o . 0 0 1 5 8 1 . 0 3 3 1 8 . 3 1 2 . 9 5 5 3 . 9 8

PPm PPm PPm PPm

#1 - . 0 0 0 0 #2 . o o o o

. 0 0 5 0

. O O O l . O O O l - . 0 0 0 0

. 0 0 4 0 - . 0 2 9 7 . 0 0 0 2 . 0 0 1 7

. O O l l . 0 1 1 4 . 0 0 0 2 . 0 0 3 9

E r r o r s LC P a s s H i g h . 0 0 5 0 Low - . 0 0 5 0

LC P a s s . O l O O - . 0 1 0 0

LC P a s s . 0 0 5 0 - . 0 0 5 0

LC P a s s LC P a s s LC P a s s LC P a s s . O l O O . l o o 0 . 0 0 5 0 .0100 - . 0100 - . 1000 - . 0 0 5 0 - . 0100

Y 3 7 1 0 E l e m - Units ppm A v g e .OOOl SDev . o o o o %RSD 7 . 5 5 5

Zn2 0 6 2 Z r 3 4 9 6 PPm . o o o o . 0 0 0 4 3 6 4 0 .

PPm - . 0 0 0 2 . 0 0 0 3

1 3 0 . 6

#1 . O O O l # 2 . O O O l

- . 0 0 0 4 - . 0 0 0 0

. 0 0 0 3 - . 0 0 0 3

E r r o r s LC P a s s H i g h .0050 Low - . 0050

LC P a s s .0050 - . 0 0 5 0

LC P a s s .0050 - . 0050

Analysis Report

IntStd 1 Mode *Counts Elem sc Wavlen 361.384 Avge 1121654 SDev 2122.027 %RSD .1891874

2 Time

10000 . o o o o o o o . o o o o o o o

04/16/07 07:21:08 PM

3 4 5 6 NOTUSED NOTUSED NOTUSED NOTUSED

Page 3

010132 7 NOTUSED _ _

Analysis Report 04/16/07 07:25:59 PM page 1

Method: DAILY2 Sample Name: CRI Run Time: 04/16/07 19:21:21 Comment : Mode: CONC Corr. Factor: 1

Elem Ag3280 A13082 As1890 Units ppm PPm PPm Avge .0202 .0990 .0190 SDev .0020 .0171 .0042 %RSD 9.679 17.27 22.19

#1 .0188 .0869 .0160 #2 .0216 .1111 .0220

Errors LC Pass NOCHECK LC Pass

Low .OlOO -0100 High .0300 .0300


Avge .0021 .0099 .0986 SDev .0038 .0006 .0016 %RSD 182.7 5.997 1.610

Units ppm PPm PPm

#1 - . 0006 . 0 0 9 5 .0975 #2 .0047 ,0103 .0997

Errors NOCHECK LC Pass LC Pass High .0150 .1500 Low .0050 .0500


Avge .0012 .0718 .0072 SDev .0017 . o o o o .0084 %RSD 138.5 .0562 116.9

Units ppm PPm PPm

#1 . o o o o .0718 .0012 # 2 .0024 .0718 .0131

Errors NOCHECK LC Pass NOCHECK High .1500 Low -0500

Elem Ni2316 P 1782 2203/1 Units ppm PPm PPm Avge .0790 .1135 .0091 SDev .0018 .0037 .0027 %RSD 2.220 3.287 29.19

#l .0778 .1108 .0072 #2 .0803 .1161 .0110

Errors LC Pass LC Pass NOCHECK High .1200 .1500 Low .0400 . 0 5 0 0

Operator :

010133

B 2496 Ba4934 Be3130 Bi2230

.lo42 .0212 .0097 .0019

.0027 . O O O l . O O O l .0020 2.566 .6570 .8265 103.3

PPm PPm PPm PPm

.lo23 .0211 .0097 .0005

.lo61 .0213 -0098 . 0 0 3 4

LC Pass LC Pass LC Pass NOCHECK .1500 .0300 .0150 .0500 .OlOO .0050

Cr2677 Cu3247 Fe2714 K - 7664 PPm PPm PPm PPm .0195 .0504 .1371 - .0039 .OOlO .0013 .0207 .0394 5.055 2.506 15.08 997.8

.0188 .0495 .1225 - . 0318

.0202 .0513 H. 1517 .0239

LC Pass LC Pass LC Pass NOCHECK .0300 .0750 .1500 . O l O O .0250 .0500

Mn2576 Mo2020 Na3302 Na5889 PPm PPm PPm PPm .0295 .0211 .1796 - . 1785 .0002 -0006 .0886 . O O O l .7271 3.095 49.33 .0689

.0293 .0215 .1169 - -1786

.0296 .0206 .2422 - . 1784 LC Pass LC Pass NOCHECK NOCHECK .0450 .0300 .0150 . O l O O

2203/2 Pd3404 S 1820 Sb2068

.0055 .0020 .0250 .1230

.0009 .0074 .0135 .0029 15.68 364.2 54.12 2.381

PPm PPm PPm PPm

.0061 - . 0032 .0154 .1209

.0049 .0073 -0346 .1251

NOCHECK NOCHECK NOCHECK LC Pass .1800 .0600

Elem Sc3613 1960/1 1960/2 Si2881 Pb2 2 0 Se196 Sn1899

Analysis Report 04/16/07 07:25:59 PM P a g e 2

PPm PPm PPm Q D 1 3 4 -1043 .0067 .0105 .0973

Units %R

SDev 4.1 %RSD 3.611

Avge 112.2 PPm .0089 .0017 19.68

PPm .0113 .0018 15.73

. 0 0 7 0 .0003 .0006 .0030 6.700 4.666 5.757 3.127

#1 115.1 #2 109.4

.0076

.0101 .0126 .OlOl

.0993 -0065 .0109 .0952

.lo92 .0069 .0101 .0995

Errors NOCHECK High Low

NOCHECK NOCHECK LC P a s s LC P a s s LC P a s s LC P a s s . 1 5 0 0 .0090 .0150 .1500 .0500 .0030 .0050 .0500

Elem Sr4215 Units ppm Avge .0207 SDev .O O O l %RSD .3117

Th2837 PPm . 0 0 0 6 .0004 69.93

Ti3349 PPm .0197 .0003 1.572

T11908 U 4090 U 2924 W 2079

.0244 .2430 .0996 .0042

.0006 .0495 .0016 .0020 2.622 20.39 1.600 48.32

PPm PPm PPm PPm

#I .0207 #2 -0208

.0003

.0009 .0194 .0199

.0249 .2080 .0984 .0027

.0240 .2780 .1007 .0056

Errors LC P a s s

Low . O l O O High .0300

NOCHECK LC P a s s .0300 -0100

LC P a s s NOCHECK LC P a s s NOCHECK .0300 . 1 5 0 0 . O l O O . 0 5 0 0

Elem Y 3710 Units ppm Avge .0002 SDev .0003 %RSD 163.1

Zn2062 Zr3496 PPm .0895 .0013 1.450

PPm .0390 .0008 1.947

#1 - . 0000 #2 . 0 0 0 4

.0384

.0395 .0886 .0904


LC Pass .0600 .0200

NOCHECK

Analysis Report

I n t S t d 1 Mode *Counts Elem sc Wavlen 3 6 1 . 3 8 4 Avge 1 1 0 3 6 8 8 SDev 3 9 7 4 2 . 9 4 %RSD 3 . 6 0 0 9 2 0

#1 1 1 3 1 7 9 1 # 2 1 0 7 5 5 8 6

2 Time - - _ _ 1 0 0 0 0 . o o o o o o o . o o o o o o o

1 0 0 0 0 1 0 0 0 0

3 NOTUSED - - _ _

0 4 / 1 6 / 0 7 0 7 : 2 5 : 5 9 PM Page 3

010135, 4 5 6


Method: DAILY2 Sample Name: ICSA Run Time: 04/16/07 19:26:11 Comment : Mode: CONC Corr. Factor: 1


#1 # 2

Errors High Low


#1 #2

Errors High Low


#1 #2

Errors High Low


#1 #2

Errors High Low

Elem

A93280 PPm - . 0009 .0007

80.96

- . 0014 - . 0004

NOCHECK

Ca3179 PPm 444.6 2.9

.6635

442.5 446.6

LC Pass 600.0 400.0

La3988 PPm .0047 .0002 3.782

.0048

.0046

NOCHECK

Ni2316 PPm .0027 .0005 20.21

.0023

.0031

NOCHECK

Sc3613

A13082 PPm 506.9

.7 . 1 3 0 0

506.5 507.4

LC Pass 600.0 400.0

Cd2265 PPm - . 0019 .0002

11.32

- . 0018 - .0021

NOCHECK

Li6707 PPm - .0002 .0002

72.03

- . 0003 - . O O O l

NOCHECK

P 1782

.0131

.0157 119.9

.0020

.0242

NOCHECK

PPm

1960/1

As1890 PPm .0003 .0023 677.0

.0020 - . 0013 NOCHECK

Co2286 PPm . O O l O .0004 39.41

.0007

.0012

NOCHECK

Mg2790 PPm 527.7 2.8

.5327

525.7 529.6

LC Pass 600.0 400.0

2203/1 PPm .0237 .0017 7.058

.0248

.0225

NOCHECK

1960/2

B 2496 PPm - .0164 .0005

3.172

- .0160 - .0167

NOCHECK

Cr2677 PPm - . 0008 .0018

225.3

- . 0021 .0005

NOCHECK

Mn2576 PPm .0063 . o o o o .2640

.0063

.0063

NOCHECK

2203/2 PPm - . 0100 .0028

28.32

- . 0080 - . 0120 NOCHECK

Si2881

Operator:

010136 Ba4934 PPm .0025 ,0002 8.485

.0023

.0026

NOCHECK

Cu3247 PPm .0023 .0008 37.08

.0017

.0029

NOCHECK

Mo2020 PPm - . 0029 .0024

83.85

- . 0012 - . 0046 NOCHECK

Pd3404 PPm .0034 .0095 276.2

- . 0033 .0101

NOCHECK

Pb220

Be3130 PPm . O O O l . o o o o 16.49

. O O O l

. O O O l

NOCHECK

Fe2714 PPm 184.7

.7 .3717

184.2 185.1

LC Pass 240.0 160.0

Na3302 PPm .4070 .3556 87.36

.1556 -6585

NOCHECK

S 1820

.0255 -0031 11.98

.0276

.0233

NOCHECK

PPm

Se196

Bi2230 PPm - . 0004 .0024

609.3

- . 0021 .0013

NOCHECK

K - 7664 PPm - . 0267 .0459

171.7

- . 0592 .0057

NOCHECK

Na5889 PPm - . 1555 .0139

8.934

- . 1653 - . 1457

NOCHECK

Sb2068 PPm - . 0112 .0211

187.6

.0037 - . 0261 NOCHECK

Sn1899

Analysis Report 0 4 / 1 6 / 0 7 0 7 : 3 0 : 5 0 PM page 2

PPm 01,&&37 Units Avge SDev %RSD

%R 1 0 2 . 6

1 . 0 1 . 0 2 2

PPm . 0 1 3 6 . 0 2 7 2 2 0 0 . 4

PPm - . 0138 . 0 1 9 4

1 4 0 . 6

PPm PPm . 0 2 6 1 . 0 0 1 3 - . 0 0 4 7 - . 0 0 2 9 . 0 0 1 6 . 0 0 2 4 . 0 0 3 9 . 0 0 2 3 6 . 2 1 0 1 9 4 . 1 8 2 . 9 8 7 8 . 6 8

#1 #2

1 0 3 . 3 1 0 1 . 8

- . 0 0 5 7 . o x 8

- . 0 0 0 1 - . 0 2 7 5

. 0 2 5 0 . 0 0 3 0 - . 0 0 1 9 - . 0 0 1 3

. 0 2 7 3 - . 0 0 0 5 - . 0 0 7 4 - . 0 0 4 6


NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK


S r 4 2 1 5 PPm . 0 1 5 7 . o o o o . o a 7 0

T h 2 8 3 7 PPm - . 0 3 3 2

. 0 0 4 3 1 2 . 9 9

T i 3 3 4 9 PPm - . 0 0 0 4 . O O O l

3 2 . 0 9

W 2 0 7 9 - V 2 9 2 4 T11908 U 4 0 9 0 - PPm PPm PPm PPm . 0 0 7 4 - . 0 3 2 2 - . 0 0 0 4 . 0 0 9 4 . 0 0 7 5 . 0 3 9 3 . 0 0 1 2 . 0 1 2 3 1 0 0 . 6 1 2 2 . 2 2 8 7 . 2 1 3 1 . 6

#1 #2

.0181 . 0 1 2 7 - . 0600 - . 0 0 1 3 . 0 0 2 1 - . 0 0 4 4 . 0 0 0 4 . 0 0 0 6

. 0 1 5 7

. 0 1 5 7 - . 0 3 6 2 - . 0 3 0 1

- . 0 0 0 5 - . 0 0 0 3

NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK E r r o r s High Low


Y 3 7 1 0 PPm - . 0 0 0 7

. 0 0 0 2 2 4 . 1 9

Zn2062 Z r 3 4 9 6 PPm - . 0 0 0 7

. 0 0 1 7 2 6 0 . 3

PPm - 0 0 7 4 . 0 0 0 3 3 . 6 3 2

#1 # 2

- . 0 0 0 8 - . 0 0 0 6

. 0 0 7 6

. 0 0 7 2 - . 0 0 1 9 . 0 0 0 6

NOCHECK NOCHECK NOCHECK E r r o r s High Low

~~~ ~

Analysis Report


#1 # 2

1 *Counts sc 3 6 1 . 3 8 4 1 0 0 8 7 2 0 1 0 3 3 4 . 3 6 1 . 0 2 4 5 0 3

1 0 1 6 0 2 7 1 0 0 1 4 1 2

2 Time

- - 1 0 0 0 0 . o o o o o o o . o o o o o o o

1 0 0 0 0 1 0 0 0 0

0 4 / 1 6 / 0 7 0 7 : 3 0 : 5 0 PM

4 NOTUSED - - - -

5 NOTUSED - - - -

6 NOTUSED - -

0.10138 NOTUSED


Method: DAILY2 Sample N a m e : ICSAB Run T i m e : 0 4 / 1 6 / 0 7 1 9 : 3 1 : 0 4 C o m m e n t : Mode: CONC C o r r . Factor: 1

E l e m U n i t s A v g e SDev % R S D

#1 #2



#1 #2



#1 #2



#1 #2


E l e m

Ag3280 PPm 1 . 0 9 0 .001

. 0 8 9 8

1 . 0 8 9 1 . 0 9 1

LC P a s s 1 . 2 0 0 . 8 0 0 0

C a 3 1 7 9 PPm 4 5 2 . 9

3 . 9 . 8 5 1 2

4 5 5 . 6 4 5 0 . 2

LC P a s s 6 0 0 . 0 4 0 0 . 0

L a 3 9 8 8 PPm . 0 0 4 5 . 0 0 0 6 1 3 . 6 9

. 0 0 4 9

. 0 0 4 0

NOCHECK

N i 2 3 1 6 PPm . 9 4 1 7 . 0 0 1 4 . 1 4 8 2

. 9 4 0 7

. 9 4 2 7

LC P a s s 1 . 2 0 0 . 8 0 0 0

S c 3 6 1 3

A13082 PPm 5 1 2 . 7

.1 . 0 1 1 9

5 1 2 . 7 5 1 2 . 6

LC P a s s 6 0 0 . 0 4 0 0 . 0

C d 2 2 6 5 PPm . 9 5 2 3 . 0 0 4 5 . 4 7 3 7

. 9 5 5 5

. 9 4 9 1

LC P a s s 1 . 2 0 0 . 8 0 0 0

L i 6 7 0 7 PPm

H 1 . 2 4 9 .010

.8353

H 1 . 2 4 1 H 1 . 2 5 6

LC H i g h 1 . 2 0 0 . 8 0 0 0

P 1 7 8 2 PPm 1 . 0 7 1

. 0 1 6 1 . 4 9 0

1 . 0 5 9 1 . 0 8 2

LC P a s s 1 . 2 0 0 . 8 0 0 0

1 9 6 0 / 1

-

A s 1 8 9 0 PPm 1 . 0 5 1

. 0 0 3 . 3 0 7 0

1 . 0 4 9 1 . 0 5 3

LC P a s s 1 . 2 0 0 . 8 0 0 0

Co2286 PPm . 4 9 2 0 . 0 0 1 4 . 2 9 5 5

. 4 9 3 0

. 4 9 0 9

LC P a s s . 6 0 0 0 . 4 0 0 0

Mg2790 PPm 5 3 6 . 9

2 . 6 . 4 8 6 5

5 3 8 . 7 5 3 5 . 0

LC P a s s 6 0 0 . 0 4 0 0 . 0

2 2 0 3 / 1 PPm 1 . 0 0 9

. 0 3 5 3 . 5 1 1

1 . 0 3 4 . 9 8 4 1

NOCHECK

1 9 6 0 / 2

0 4 / 1 6 / 0 7 0 7 : 3 5 : 38 PM

B 2 4 9 6

1 . 0 4 3 . 0 0 7

. 6 9 7 5

1 . 0 3 8 1 . 0 4 8

LC P a s s 1 . 2 0 0 . 8 0 0 0

C r 2 6 7 7 PPm . 4 9 2 3 . 0 0 2 5 .SO34

. 4 9 4 1

. 4 9 0 6

LC P a s s - 6 0 0 0 . 4 0 0 0

Mn2576 PPm .SO34 .0011 - 2 1 6 1

. 5 0 4 2

. 5 0 2 6

PPm

LC P a s s . 6 0 0 0 . 4 0 0 0

2 2 0 3 / 2 PPm - 9 8 4 7 . 0 0 1 3 - 1 3 4 4

. 9 8 5 6

. 9 8 3 8

NOCHECK

S i 2 8 8 1

Operator:

B a 4 9 3 4 PPm . 5 4 2 6 . 0 0 2 1 .3885

. 5 4 1 1

. 5 4 4 1

LC P a s s . 6 0 0 0 . 4 0 0 0

C u 3 2 4 7 PPm . 5 6 8 8 . 0 0 3 0 . 5 3 4 5

. 5 6 6 7

. 5 7 1 0

LC P a s s . 6 0 0 0 . 4 0 0 0

Mo2020 PPm 1 . 0 1 0 .001

. l o 8 9

1 . 0 0 9 1 . 0 1 1

LC P a s s 1 . 2 0 0 - 8 0 0 0

P d 3 4 0 4 PPm . 0 0 7 9 . 0 1 0 8 1 3 6 . 8

. 0 1 5 5

. 0 0 0 3

NOCHECK

P b 2 2 0

Be3130 PPm . 4 9 1 4 . 0 0 1 9 - 3 8 7 2

. 4 9 2 7

. 4 9 0 0

LC P a s s . 6 0 0 0 . 4 0 0 0

F e 2 7 1 4 PPm 1 8 7 . 2

. 8 . 4 0 7 9

1 8 7 . 7 1 8 6 . 6

LC P a s s 2 4 0 . 0 1 6 0 . 0

Na3302 PPm . 6 6 4 6 . 3 7 4 9 5 6 . 4 1

. 9 2 9 6

. 3 9 9 5

NOCHECK

S - 1 8 2 0 PPm - 0 4 1 9 . 0 0 2 0 4 . 7 2 6

. 0 4 0 5

. 0 4 3 3

NOCHECK

S e 1 9 6

page 1

010139

B i 2 2 3 0 PPm . 0 0 5 7 . 0 0 0 8 1 4 . 8 0

. 0 0 5 1

. 0 0 6 3

NOCHECK

K 7 6 6 4

- . 0 2 3 3 . 0 5 2 6

2 2 5 . 1

. 0 1 3 8 - . 0 6 0 5

PPm

NOCHECK

Na5889 PPm - . 1 7 3 9

. 0 0 6 2 3 . 5 6 3

- . 1 6 9 5 - . 1 7 8 3

NOCHECK

S b 2 0 6 8 PPm 1 . 0 4 2

. 0 3 2 3 . 0 9 8

1 . 0 1 9 1 . 0 6 5

LC P a s s 1 . 2 0 0 . 8 0 0 0

S n 1 8 9 9

04/16/07 07:35:38 PM Page 2 Analysis Report

010140 PPm PPm PPm PPm 1.088 .9929 1.028 .9726

Units %R

SDev 3.1 %RSD 3.146

Avge 100.0 PPm 1.042

PPm 1.021

.037 3.546

.001 .1326

.001 .0127 .013 .0014 .0673 1.279 1.286 .1443

#1 97.79 #2 102.2

1.068 1.015

1.022 1.020

1.089 1.088

1.002 .9839

1.037 1.018

.9716

.9735


NOCHECK NOCHECK NOCHECK LC P a s s 1.200 .8000

LC P a s s 1.200 .8000

LC Pass 1.200 .8000

Elem Sr4215 Units ppm Avge 1.050 SDev .005 %RSD .4528

Th2837 PPm - . 0272 .0041

15.13

T11908 Ti3349 PPm .9558 .OOOl .0058

U - 4090 V 2924

.5071

.0007

.1400

PPm W 2079

.0063

.0030 47.34

Pp” PPm 1.027

PPm .9638

.011 1.079

.0145 1.501

#1 1.047 #2 1.054

- . 0301 - . 0243

.9557

.9558 1.019 1.035

.9740

.9536 .5076 .5066

.0042

.0084

Errors LC Pass

L o w . B O O 0 High 1.200

NOCHECK LC Pass 1.200 . B O O 0

LC Pass 1.200 . g o o 0

NOCHECK LC P a s s .6000 - 4 0 0 0

NOCHECK

Elem Y 3710 Units pcm Avge - . 0006 SDev .OOOl %RSD 15.16

Zn2062 PPm .9266 .0063 .6754

Zr3496 PPm .8894 .0014 .1636

#1 - . 0006 #2 - . 0007 .9310

.9221 .8884 .8904


LC P a s s 1.200 -8000

NOCHECK

Analysis Report

IntStd 1 Mode *Counts Elem sc Wavlen 361.384 Avge 983434 SDev 30921.07 %RSD 3.144192

#1 961570 # 2 1005299

2 Time

- - 10000 . o o o o o o o . o o o o o o o

1 0 0 0 0 1 0 0 0 0

4

04/16/07 07:35:38 PM Page 3

5 6 010141 7

NOTUSED NOTUSED NOTUSED NOTUSED - - - - - - - - - - - - - - - -


Method: DAILY2 Sample Name: CCV4 Run Time: 04/16/07 19:35:50 Comment : Mode: CONC Corr. Factor: 1

Elem Ag3280 A13082 As1890 Units ppm PPm PPm Avge .9803 9.835 5.112 SDev .0016 .OOl . 0 0 6 %RSD .1644 .0112 .1130

#1 -9815 9.836 5.108 # 2 .9792 9.834 5.116

Errors LC Pass LC Pass LC Pass High 1.100 11.00 5.500 Low .goo0 9.000 4.500


Avge 19.48 1.001 5.095 SDev .03 .003 .007 %RSD .1557 .2895 .1419

Units ppm PPm PPm

#1 19.50 1.003 5.100 #2 19.46 .9992 5.090

Errors LC Pass LC Pass LC Pass High 22.00 1.100 5.500 LOW 18.00 .goo0 4.500


Avge 5.015 4.844 19.83 SDev .007 .008 .Ol %RSD .1314 .1582 .0753

Units ppm PPm PPm

#1 5.011 4.839 19.82 #2 5.020 4.849 19.84

Errors LC Pass LC Pass LC Pass

Low 4.500 4.500 18.00 High 5.500 5.500 22.00

Elem Ni2316 P 1782 2203/1

Avge 4.954 5.035 5.011 SDev . 0 0 6 .OlO .020 %RSD .1231 .1986 .4075

Units ppm PPm PPm

#1 4.950 5.042 5.026 #2 4.958 5.028 4.997

Errors LC Pass LC Pass NOCHECK High 5.500 5.500 Low 4.500 4.500

Operator:

010142

B 2496 Ba4934 Be3130 Bi2230

5.109 10.27 .9849 5.127 .018 .01 .0016 - 0 0 0

.0070 .3604 .0814 .1585

PPm PPm PPm PPm

5.096 10.26 .9860 5.127 5.122 10.27 .9838 5.126

LC Pass LC Pass LC Pass LC Pass 5.500 11.00 1.100 5.500 4.500 9.000 -9000 4.500

Cr2677 Cu3247 Fe2714 K 7664

1.980 2.092 10.24 18.44 .002 . o o o .Ol .oo .0987 .0076 .0700 .0225

PPm PPm PPm PPm

1.981 2.092 10.24 18.43 1.978 2.092 10.23 18.44

LC Pass LC Pass LC Pass LC Pass 2.200 2.200 11.00 22.00 1.800 1.800 9.000 18.00

Mn2576 Mo2020 Na3302 Na5889 PPm PPm PPm PPm 1.014 5.001 28.71 H50.92

. o o o .009 .14 .02 .0056 .1752 .4874 .0439

1.014 5.007 28.61 H50.90 1.014 4.995 28.81 H50.94

LC Pass LC Pass LC Pass LC High 1.100 5.500 33.00 33.00 .goo0 4.500 27.00 27.00

2203/2 Pd3404 S 1820 Sb2068

4.904 1.033 1.071 1.015 .052 .005 .003 .003

1.066 .5110 .2667 .2702

PPm PPm PPm PPm

1.073 1.013 4.941 1.037 4.867 1.030 1.069 1.017

NOCHECK LC Pass LC Pass LC Pass 1.100 1.100 1.100

.goo0 .goo0 .goo0

Elem Sc3613 1960/1 1960/2 Si2881 Pb220 Se196 Sn1899

Analysis Report page 2 0 4 / 1 6 / 0 7 0 7 : 4 0 : 2 5 PM

010143 Units %R Avge 1 1 0 . 7 SDev . 3 %RSD . 2 4 7 3

PPm 5 . 3 0 5

. 0 0 7 . 1 2 9 2

PPm 5 . 1 2 7

. 0 6 1 1 . 1 9 6

PPm PPm PPm PPm 5 . 0 9 4 4 . 9 4 0 5 . 1 8 6 5 . 1 2 4

. 0 0 7 . 0 4 2 . 0 4 3 .001 . 1 3 0 5 . 8 4 3 1 - 8 3 2 3 . 0 2 8 8

#I 1 1 0 . 5 #2 1 1 0 . 9

5 . 3 1 0 5 . 3 0 0

5 . 1 7 1 5 . 0 8 4

5 . 0 9 8 4 . 9 6 9 5 . 2 1 7 5 . 1 2 5 5 . 0 8 9 4 . 9 1 0 5 . 1 5 6 5 . 1 2 3


NOCHECK NOCHECK LC Pass LC Pass LC Pass LC Pass 5 . 5 0 0 5 . 5 0 0 5 . 5 0 0 5 . 5 0 0 4 . 5 0 0 4 . 5 0 0 4 . 5 0 0 4 . 5 0 0

Elem S r 4 2 1 5 Units ppm Avge 4 . 9 1 4 SDev . 0 0 5 %RSD . 0 9 6 5

T h 2 8 3 7 PPm . 9 9 6 7 . 0 0 2 7 . 2 6 8 4

T i 3 3 4 9 PPm 4 . 8 2 7

. o o o . 0 0 4 1

T 1 1 9 0 8 U - 4 0 9 0 V 2 9 2 4 W 2 0 7 9

1 . 0 8 5 5 .333 1 . 0 2 5 5 . 0 4 0 .001 . 0 1 7 . 0 0 4 . 0 0 4

. 0 2 7 3 1 . 6 6 1 . 0 7 2 5 . 3 3 0 1

PPm PPm PPm PPm

#1 4 . 9 1 1 # 2 4 . 9 1 8

. 9 9 8 6 , 9 9 4 8

4 . 8 2 7 4 . 8 2 7

5 . 3 3 2 1 . 0 3 7 5 . 0 4 2 1 . 0 8 7 1 . 0 8 2 5 . 3 3 4 1 . 0 1 3 5 . 0 3 7

E r r o r s LC P a s s High 5 . 5 0 0 Low 4 . 5 0 0

LC Pass 1.100 . g o o 0

LC Pass 5 . 5 0 0 4 . 5 0 0

LC Pass LC Pass LC Pass LC Pass 5 . 5 0 0 1.100 5 . 5 0 0 1 . 1 0 0 4 . 5 0 0 . g o o 0 4 . 5 0 0 .g000

E l e m Y 3 7 1 0 Units pPm Avge 5 . 0 8 5 SDev .001 %RSD . 0 2 0 8

Zn2062 PPm 1 . 0 0 2 .001

.lo08

Z r 3 4 9 6 PPm 4 . 9 7 5

. 0 1 2 . 2 3 3 8

#1 5 . 0 8 4 # 2 5 . 0 8 6

1.003 1.001

4 . 9 6 6 4 . 9 8 3


LC Pass 1.100 . g o o 0

LC Pass 5 . 5 0 0 4 . 5 0 0

Ana 1 ys i s


#1 #2

Report

1 *Counts sc 3 6 1 . 3 8 4 1 0 8 8 4 3 8 2 6 8 4 . 8 8 5 - 2 4 6 6 7 3 1

1 0 8 6 5 4 0 1 0 9 0 3 3 7


1 0 0 0 0 1 0 0 0 0

3 NOTUSED - -

0 4 / 1 6 / 0 7

4 5

0 7 : 4 0 : 25 PM page

010144 6 7

3


Method: DAILY2 Sample N a m e : CCB4 Run T i m e : 0 4 / 1 6 / 0 7 1 9 : 4 0 : 3 7 Comment : Mode: CONC C o r r . Factor:

E l e m U n i t s A v g e S D e v %RSD

#1 #2



#1 #2



#I #2



#1 #2


E l e m

Ag3280 PPm - . 0 0 0 5

, 0 0 0 5 1 0 1 . 2

- . 0 0 0 1 - . 0 0 0 9

LC P a s s , 0 0 5 0 - . 0 0 5 0

Ca3179 PPm * 0002 . 0 0 2 6 1 2 9 2 .

. 0 0 2 0 - . 0 0 1 6

LC P a s s . 0 5 0 0 - . 0 5 0 0

L a 3 9 8 8 PPm - . 0 0 0 7

. 0 0 1 5 2 0 4 . 3

. 0 0 0 3 - . 0 0 1 8

LC P a s s . 0 0 5 0 - . 0 0 5 0

N i 2 3 1 6 PPm - . 0 0 0 5

. O O l O 2 0 5 . 1

- .0011 . 0 0 0 2

LC P a s s . 0 0 5 0 - . 0 0 5 0

S c 3 6 1 3

A13082 PPm - . 0 0 6 6

. 0 0 2 2 3 2 . 6 0

- . 0 0 5 1 - . 0 0 8 2

LC P a s s . 0 5 0 0 - . 0 5 0 0

C d 2 2 6 5 PPm - . 0 0 0 1

. 0 0 0 2 3 5 2 . 1

. O O O l - . 0 0 0 2

LC P a s s . 0 0 5 0 - . 0 0 5 0

L i 6 7 0 7 PPm - . 0 0 0 8 . O O O l

1 6 . 8 8

- . 0 0 0 7 - . 0 0 0 9

LC P a s s . 0 0 5 0 - . 0 0 5 0

P 1 7 8 2 Pp”

H . 0 1 3 9 . 0 0 1 2 8 . 4 5 2

H . 0 1 4 7 H . 0 1 3 0

LC H i g h . O l O O - . 0 1 0 0

1 9 6 0 / 1

1

A s 1 8 9 0 PPm - .0011

. 0 0 2 2 2 0 5 . 6

. 0 0 0 5 - . 0 0 2 7

LC P a s s . 0 0 5 0 - . 0 0 5 0

Co2286 PPm . 0 0 0 2 . O O O l 5 9 . 4 8

. 0 0 0 3

. O O O l

LC P a s s - 0 0 5 0 - . 0 0 5 0

Mg2790 PPm - . 0 0 0 1

. 0 0 8 4 1 0 9 8 0 .

. 0 0 5 8 - . 0 0 6 0

LC P a s s . 0 5 0 0 - . 0 5 0 0

2 2 0 3 / 1 PPm . 0 0 3 3 . 0 0 4 2 1 2 5 . 6

. 0 0 6 3

. 0 0 0 4

NOCHECK

1 9 6 0 / 2

0 4 / 1 6 / 0 7 0 7 : 4 5 : 1 2 PM

O p e r a t o r :

010145

B 2 4 9 6

. 0 0 7 1

. 0 0 2 6 3 6 . 0 2

. 0 0 8 9

. 0 0 5 3

LC P a s s . 0 5 0 0 - . 0500

C r 2 6 7 7 PPm - . 0 0 0 7

. 0 0 0 9 1 3 8 . 6

- . 0 0 1 3 - . o o o o

LC P a s s

PPm

. 0 0 5 0 - . 0 0 5 0

Mn2576 PPm - . 0 0 0 0 . O O O l

2 2 8 6 .

- . 0 0 0 1 . O O O l

LC P a s s - 0 0 5 0 - . 0 0 5 0

2 2 0 3 / 2 PPm - . 0 0 1 8

. 0 0 0 9 4 8 . 8 0

- . 0 0 1 2 - . 0 0 2 4

NOCHECK

S i 2 8 8 1

B a 4 9 3 4 PPm . O O O l . 0 0 0 3 3 1 4 . 1

. 0 0 0 3 - . 0 0 0 1

LC P a s s . 0 0 5 0 - . 0 0 5 0

Cu3247 PPm - . 0 0 0 4

. 0 0 0 2 3 8 . 4 6

- . 0 0 0 5 - . 0 0 0 3

LC P a s s . 0 0 5 0 - . 0 0 5 0

Mo2020 PPm . 0 0 0 8 . 0 0 0 2 2 4 . 6 6

. 0 0 0 9

. 0 0 0 6

LC P a s s . 0 0 5 0 - . 0 0 5 0

Pd3404 PPm

L - . 0 0 7 8

9 . 3 5 4

L - . 0 0 7 3 L - . 0 0 8 4

LC Low - 0 0 5 0 - . 0 0 5 0

. 0 0 0 7

P b 2 2 0

Be3130 PPm - . 0 0 0 1

. o o o o 4 1 . 4 2

- . 0 0 0 0 - . 0 0 0 1

LC P a s s . 0 0 5 0 - . 0 0 5 0

F e 2 7 1 4 PPm - . 0 1 3 1

. 0 0 1 8 1 3 . 7 3

- . 0 1 1 8 - . 0 1 4 4

LC P a s s - 0 5 0 0 - . 0 5 0 0

Na3302 PPm

L- . 4 5 2 4 , 0 4 7 6

1 0 . 5 2

L- . 4 8 6 0 L- , 4 1 8 7

LC Low . 0 5 0 0 - . 0 5 0 0

S 1 8 2 0 Pp”

H . 0 2 2 7 . 0 0 3 5 1 5 . 5 7

H . 0 2 5 2 H . 0 2 0 2

LC High . 0 2 0 0 - . 0 2 0 0

S e 1 9 6

B i 2 2 3 0 PPm . 0 0 2 7 . 0 0 3 8 1 3 7 . 4

. 0 0 5 4

. O O O l

LC P a s s . O l O O - . 0 1 0 0

K 7 6 6 4

- . 0 4 9 2 . 0 0 5 5

1 1 . 2 5

PPm

- . 0 4 5 3 - . 0 5 3 1

LC P a s s .1000 - . 1 0 0 0

Na5889 PPm

L - . 1 9 3 4 . 0 0 1 3

. 6 6 0 8

L - . 1 9 2 4 L - . 1 9 4 3

LC Low . 0 5 0 0 - . 0500

S b 2 0 6 8 PPm . 0 0 1 7 . 0 0 3 0 1 7 6 . 9

- . 0 0 0 4 . 0 0 3 8

LC P a s s * 0 1 0 0 - . 0100

S n 1 8 9 9

Analys is Report 010146age

04/16/07 07:45:12 PM

Units %R A v g e 115.7 S D e v .1 %RSD .0941

P P m .0017 .0052 300.5

P P m .0011 .0034 313.2

P P m P P m PPm P P m - . 0078 - . 0001 .0013 .OOll .0037 .0020 .0040 .0006

48.07 3552. 305.6 57.85

#1 115.7 #2 115.8

- .0019 .0054

- . 0013 .0034

- . 0051 ,0013 - .0015 .0006 L - . 0104 - . 0014 .0041 .0015


NOCHECK NOCHECK LC Pass LC Pass LC Pass LC Pass .OlOO .0050 . 0 0 5 0 .0050 - . 0100 - . 0050 - . 0050 - . 0050

E l e m Sr4215 U n i t s p p m A v g e . O O O l S D e v .0002 %RSD 183.2

Th2837 P P m - . 0010 .0062

648.1

Ti3349 P P m - . 0001

. o o o o 2.114

T11908 U 4090 V 2924 W 2079

.0031 .0030 - . 0000 .0013

.0025 .0301 .OOlO -0008 79.80 1001. 8890. 65.49

P P m P P m P P m P P m

#I .0002 #2 - . 0000

- . 0053 .0034

- . 0001 - . O O O l

.0049 .0243 - . 0007 * 0019

.0014 - . 0183 .0007 .0007

E r r o r s LC Pass High . 0 0 5 0 Low - . 0 0 5 0

LC Pass .OlOO - .OlOO

LC Pass .0050 - . 0 0 5 0

LC Pass LC Pass LC Pass LC Pass . O l O O . l o o 0 .0050 .OlOO - . 0100 - . 1000 - . 0050 - . 0100

Elem Y 3710 Units p P m A v g e . O O O l S D e v . O O O l %RSD 72.73

Zn2 0 62 P P m - . 0002 .0003

108.0

Zr3496 P P m - . 0002 .0005

205.0

#1 . O O O l #2 . o o o o

- . 0001 - . 0004

- .0006 .OOOl

E r r o r s LC Pass LC Pass LC Pass High .0050 .0050 .0050 Low - . 0050 - . 0050 - .0050

Ana 1 ys i s


#1 #2

Report

1 *Counts sc 361.384 1138112 1109.451 .0974816

1137328 1138897


1 0 0 0 0 1 0 0 0 0

3

04/16/07

4 5

07:45:12 PM Page 3 010147

6

Div 20

Proj.# 06002.01 242 ~0#070410-6 qp-$ m

rl mgll sigwt Dilution Calc RL ugll Date Time 2 -0000678 -00007 1 0.002 -0 67833 04/27/07 9 56 AM 2 00165139 00165 1 0002 16.51386 04/27/07 9 5 8 A M 2 30346975 303 500 1 60 69395 04/27/07 l 0 0 0 A M 2 31 153515 31 2 500 1 62.30703 04/27/07 10 03AM 2 425745 426 500 1 85149 04/27/07 4 0 5 P M 2 98 94139 98 9 500 1 197 88278 04/27/07 lO22AM 2 34281125 3 4 3 500 1 68 56225 04/27/07 10 39AM 2 33 395135 334 500 1 66 79027 04/27/07 lO45AM

34 3 33 4 1 pp- ~

2 3546578 355 500 1 70 93156 04/27/07 lO49AM 2 16 979435 17 500 1 33 95887 04/27/07 10 51 AM 2 17690357 1 7 7 100 0 2 176 90357 04/27/07 11 04 AM

294959

i

div20-070410-6.xls

010149 0 200.8 TAP No. 01-0406-107 Rev 2/Jan 06

d 6 0 2 0 TAP No. 01 -0406-046Revl O/Jan 06

0 Other

,I.

ANALYSIS

PROJ. NO. PROJECT o ~ o o ~ - o I ‘ ~ 2 - . YZLV 28

TO# DATE

. . .

ICP-MS CALIB. STD. ID’S

so ~ - 1 ~ 4 J ST_D. 1 4mcoLt- STD. 2 STD. 3

OC STD. ID’S

ICSA ICSAB

MATRIX .LOGBK PG

Lc9,

INSTRUMENT: W, II:

Analyst: ml& 4\17\01

Quantitative Analysis - Summary Report 010150 Sample ID: S-0 Sample DateiTime: Friday, April 27, 2007 09:30:49 Sample Description: Solution Type: Standard Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K_only.mth Dataset File: C:\Elandata\DataSet\O7Apr\S-O. 1747 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary

Intensities Analyte Mass Meas. Intens. Mean Meas. Intens. RSD Blank Intensity Blank Intens. RSD r~ 39 49905 0.752 0.000

L> y 89 179684 0.896 0.000 Y-IS 89 179684 0.896 0.000

Concentration Results Analyte Mass Net Intens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit

r K 39 0.278 ugIL L> y 89 179683.682 ug/L

Y-IS 89 179683.682 100.000 0.90 0.9 %R

Page 1 Sample ID: S-0 Report DateiTime: Friday, April 27, 2007 09:31:36

Quantitative Analysis - Summary Report Sample ID: S-100 Sample Datemime: Friday, April 27, 2007 09:33:07 Sample Description: Solution Type: Standard Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\S-lOO.1748 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary

I n tens it ies Analyte Mass Meas. Intens. Mean Meas. Intens. RSD Blank Intensity Blank Intens. RSD

r~ 39 235048 1.660 0.000 L> y 89 175780 0.636 0.000

Y-IS 89 175780 0.636 0.000

Concentration Res u Its Analyte Mass Net Intens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit

r K 39 1.337 100.000 2.75 2.7 ug/L

Y-IS 89 175779.866 97.827 0.62 0.6 %R L> y 89 175779.866 ug/L

010151

_. ~ ~~ ~ - ~

Page 1 Sample ID S-100 Report Datemime Friday, April 27, 2007 09 33 54

010152 Quantitative Analysis - Summary Report Sample ID: ccv Sample Daterrime Friday, April 27, 2007 09 39 28 Sample Description Solution Type Sample Blank File Number of Replicates 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\ccv. 1749 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary

Intensities Analyte Mass Meas. Intens. Mean Meas. Intens. RSD Blank Intensity Blank Intens. RSD

r K 39 133296 1.258 0.000 L> y 89 171468 0.605 0.000

Y-IS 89 171468 0.605 0.000


r K 39 0.777 47.159 1.20 2.5 ugIL I> y 89 171467.930 ugIL

Y-IS 89 171467.930 95.428 0.58 0.6 %R

~ -~~ ~ ._ .

Page 1 Sample ID ccv Report Daterrime Friday, April 27,2007 09 40 15

Quantitative Analysis - Summary Report Sample ID: ccb Sample Datenime: Friday, April 27, 2007 09:41:45 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\ccb. 1750 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary

In tens i ties Analyte Mass Meas. Intens. Mean Meas. Intens. RSD Blank Intensity Blank Intens. RSD

r K 39 46338 0.558 0.000 L> y 89 1741 85 4.1 12 0.000

Y-IS 89 1741 85 4.1 12 0.000


r K 39 0.266 -1.076 1.17 108.5 uglL

Y-IS 89 1741 84.651 96.940 3.99 4.1 %R L> y 89 1741 84.651 uglL

010153

Page 1 Sample ID: ccb Report Datenime: Friday, April 27, 2007 09:42:32

Quantitative Analysis - Summary Report 010154 Sample ID: Irs Sample Datenime: Friday, April 27, 2007 09:44:03 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35 4\21 Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K_only.mth Dataset File: C:\Elandata\DataSet\O7Apr\lrs. 1751 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary

I n tens i ties Analyte Mass Meas. Intens. Mean Meas. Intens. RSD Blank Intensity Blank Intens. RSD

r K 39 490070 1.781 0.000 L> y 89 174297 2.513 0.000

Y-IS 89 174297 2.51 3 0.000


r K 39 2.813 239.237 6.23 2.6 uglL L> y 89 174297.276 uglL

Y-IS 89 174297.276 97.002 2.44 2.5 %R

~

Page 1 Sample ID Irs Report Datemime. Friday, April 27, 2007 09 44 52

010155 Quantitative Analysis - Summary Report

Sample ID: zzzz Sample Datenime: Friday, April 27, 2007 09:46:22 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K_only.mth Dataset File: C:\Elandata\DataSet\O7Apr\zzzz. 1752 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary

Intensities Analyte Mass Meas. Intens. Mean Meas. Intens. RSD Blank Intensity Blank Intens. RSD r~ 39 45024 0.579 0.000

L> y 89 172882 1.173 0.000 Y-IS 89 I 72882 1.173 0.000

Concentration Resu I ts Analyte Mass Net Intens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit r~ 39 0.260 -1.633 0.40 24.3 uglL

Y-IS 89 I 72881.550 96.214 1.13 1.2 %R L> y 89 172881 550 uglL

__ ___. - - - - - . . _ _ -

Page 1 Sample ID zzzz Report Datemime Friday, April 27, 2007 09 47 08

Quantitative Analysis - Summary Report 010156 Sample ID: cri I

Sample Datemime: Friday, April 27, 2007 09:48:40 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sarnple\div20-070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\cri. 1753 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 84809 0.989 0.000 L> y 89 172428 0.997 0.000

Y-IS 89 172428 0.997 0.000

Concentration Resu I ts Analyte Mass Net Intens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit

r K 39 0.492 20.210 0.72 3.6 ug/L L> y 89 172428.093 ug/L

Y-IS 89 172428.093 95.962 0.96 1.0 %R

~ _ _ -

Page 1 Sample ID cri Report Datemime Friday, April 27, 2007 09 49 30

Quantitative Analysis - Summary Report Sample ID: ccv Sample Datenime: Friday, April 27, 2007 09:51:01 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

010157


Summary


r~ 39 133338 0.641 0.000 L> y 89 170383 1.528 0.000

Y-IS 89 170383 1.528 0.000

Concentration Results Analyte Mass Net Intens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit r~ 39 0.783 47.660 1.41 3.0 ug/L

L> y 89 170383.1 97 ug/L Y-IS 89 170383.197 94.824 1.45 1.5 %R

~~ ~ ~

Page 1 Sample ID ccv Report Daterrime Friday, April 27, 2007 09 51 48


Sample ID: ccb Sample DatelTime: Friday, April 27, 2007 09:53:18 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\ccb. 1755 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\DefauIt.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 45277 0.385 0.000 L> y 89 170665 3.012 0.000

Y-IS 89 170665 3.012 0.000


r K 39 0.265 -1.161 0.78 67.6 ug/L

Y-IS 89 170664,644 94.981 2.86 3.0 %R L> y 89 170664,644 ug/L

Page 1 Sample ID: ccb Report DateiTime: Friday, April 27, 2007 09:54:05

Quantitative Analysis - Summary Report Sample ID: pbw-dZ5cl Sample Datenime: Friday, April 27, 2007 09:56:21 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20-07041 O-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\pbw-d25cl. 1756 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

4\21\07

Summary


r K 39 4671 9 0.178 0.000 L> y 89 172700 1.71 0 0.000

Y-IS 89 172700 1.71 0 0.000


r K 39 0.271 -0.678 0.48 71.3 ug/L

Y-IS 89 172700.486 96.114 1.64 1.7 %R L> y 89 172700.486 ug/L

010159

_ _ _ _ ~~ ~ _.

Page 1 Sample ID pbw-d25cl Report Daterrime Friday, April 27, 2007 09 57 09

Quantitative Analysis - Summary Report 010160 Sample ID: lcsw-d25cl Sample DateTTime: Friday, April 27, 2007 09:58:39 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\lcsw-d25cl. 1757 Tu n i ng File : c: \e la nd a t a\Tu n i ng\defa u I t. t u n Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r~ 39 771 14 1.277 0.000 L> y 89 170366 2.349 0.000

Y-IS 89 170366 2.349 0.000

Concentration Res u I ts Analyte Mass Net Intens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit r~ 39 0.453 16.514 0.63 3.8 ugIL

Y-IS 89 170366.208 94.815 2.23 2.3 %R L> y 89 170366.208 uglL

Page 1 Sample ID lcsw-d25cl Report DateTTime Friday, April 27, 2007 09 59 27

Quantitative Analysis - Summary Report Sample ID: 294954 df500 Sample Datenime: Friday, April 27, 2007 10:00:58 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\294954 df500.1758 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 170209 0.281 0.000 L> y 89 184856 0.996 0.000

Y-IS 89 184856 0.996 0.000


r K 39 0.921 60.694 0.86 1.4 uglL

Y-IS 89 184856.068 102.879 1.02 1.0 %R L> y 89 184856.068 uglL

010161

~ ~ ~

Page 1 Sample ID 294954 df500 Report Daterrime Friday, April 27, 2007 10 01 45

Quantitative Analysis - Summary Report Sample ID: 294954d df500 Sample Datenime: Friday, April 27, 2007 10:03:16 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\294954d df500.1759 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary

In tens i t i es Analyte Mass Meas. Intens. Mean Meas. Intens. RSD Blank Intensity Blank Intens. RSD

r~ 39 1721 03 1.180 0.000 L> y 89 183530 1.240 0.000

Y-IS 89 183530 1.240 0.000

Concentration Resu Its Analyte Mass Net Intens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit

r~ 39 0.938 62.307 2.06 3.3 ug/L L> y 89 183529.502 ug/L

Y-IS 89 183529.502 102.140 1.27 1.2 %R

010162

~~ _ .

Page 1 Sample ID 294954d df500 Report Daterrime Friday, April 27,2007 10 04 04


Sample ID: 294954s df500 Sample Datenime: Friday, April 27, 2007 10:05:34 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-onlymth Dataset File: C:\Elandata\DataSet\07AprP94954s df500.1760 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary

I n tens it ies Analyte Mass Meas. Intens. Mean Meas. Intens. RSD Blank Intensity Blank Intens. RSD

r K 39 194388 1.531 0.000 I> y 89 182928 1.887 0.000

Y-IS 89 182928 1.887 0.000

Concentration Res u I ts Analyte Mass Net Intens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit

39 1.063 74.1 07 2.65 3.6 uglL

Y-IS 89 182927.677 101.805 1.92 1.9 %R

r K L> y 89 1 82927.677 uglL

~ __ - __ ~ ~~ ~ -

Page 1 Sample ID. 294954s df500 Report Daterrime Friday, April 27, 2007 10.06 22

Quantitative Analysis - Summary Report Sample ID: cri Sample Datemime: Friday, April 27, 2007 10:07:53 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\cri. 1761 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 84951 0.865 0.000 L> y 89 174641 0.908 0.000

Y-IS 89 174641 0.908 0.000


39 0.486 19.699 0.71 3.6 ug/L

Y-IS 89 174641.392 97.194 0.88 0.9 %R

r K L> y 89 174641.392 ug/L

010164

~ ~

Page 1 Sample ID cri Report Datemime Friday, April 27, 2007 10 08 41

Quantitative Analysis - Summary Report Sample ID: ccv Sample Datemime: Friday, April 27, 2007 I O : 10: 12 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sarnple\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\EIandata\DataSet\07Apr\ccv. 1 762 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r~ 39 133115 0.623 0.000 L> y 89 175093 0.347 0.000

Y-IS 89 175093 0.347 0.000

Concentration Resu I ts Analyte Mass Net Intens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit r~ 39 0.760 45.539 0.54 1.2 ug/L

L> y 89 175093.493 ug/L Y-IS 89 175093.493 97.445 0.34 0.3 %R

010165

~~ ~~ ~~

Page 1 Sample ID. ccv Report Datemime. Friday, April 27, 2007 10.1 0 5 9

Quantitative Analysis - Summary Report Sample ID: ccb Sample DateKime: Friday, April 27, 2007 10:12:56 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\ccb. 1 763 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 4631 1 0.778 0.000 L> y 89 176031 1.439 0.000

Y-IS 89 176031 1.439 0.000


r K 39 0.263 -1.381 0.46 33.3 uglL L> y 89 176031.386 ug/L

Y-IS 89 176031.386 97.967 1.41 1.4 %R

010166

~- ~ ~~~- _ _ - -

Page I Sample ID ccb Report Daterrime Friday, April 27,2007 10 13 43

Quantitative Analysis - Summary Report Sample ID: 294955 df200 Sample Datemime: Friday, April 27, 2007 I O : 15.1 3 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\07AprP94955 df200.1764 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

010167

Blank Intensity Blank Intens. RSD 0.000 0.000 0.000

Concentration Results Conc. Mean Conc. SD Conc. RSD Sample Unit

108.225 3.91 3.6 ug/L L> y 89 2661 44.532 ug/L

Y-IS 89 2661 44.532 @ 8 4.15 2.8 %R

~~

Page 1 Sample ID 294955 df200 Report Datemime Friday, April 27, 2007 10'16 01

Quantitative Analysis - Summary Report Sample ID: 294956 df200 Sample Datemime: Friday, April 27, 2007 I O : 17:32 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

010168


Intensities Blank Intensity Blank Intens. RSD

0.000 0.000 0.000


106.656 2.57 2.4 ug/L 264470.574 ug/L

Y-IS 89 264470.574 1.4 %R


Quantitative Analysis - Summary Report Sample ID: 294957 df200 Sample DateiTime: Friday, April 27, 2007 I O : 1950 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

010169


Blank Intensity Blank Intens. RSD 0.000 0.000 0.000

Concentration Resu I ts Conc. Mean Conc. SD Conc. RSD Sample Unit

116.244 3.65 3.1 ug/L

0.3 %R ug/L

~~~ ~ ~~ - ~

Page 1 Sample ID. 294957 df200 Report DateiTime Friday, April 27,2007 10 20 38

Quantitative Analysis - Summary Report Sample ID: 294958 df500 Sample Datemime: Friday, April 27, 2007 10:22:09 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35


Summary


r K 39 429346 0.175 0.000 L> y 89 180862 1.767 0.000

Y-IS 89 180862 1.767 0.000

Concentration Resu Its Analyte Mass Net Intens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit

r K 39 2.374 197.883 3.70 1.9 ug/L I> y 89 180861 581 ug/L

Y-IS 89 180861.581 100.656 1.78 1.8 %R

010170

~- ~ ~~ - ~ ~~ ~- _ _



Sample ID: 294959 df200 Sample Datenime: Friday, April 27, 2007 10:24:28 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\294959 df200.1768

c

Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Intensities Blank Intensity Blank Intens. RSD

0.000 0.000 0.000

Concentration Resu I ts Conc. Mean Conc. SD Conc. RSD Sample Unit

49.635 1.43 2.9 ug/L uglL

Y-IS 89 265389.202 0.9 %R

~


Quantitative Analysis - Summary Report Sample ID: cri Sample Datenime: Friday, April 27, 2007 1026 47 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\cri. 1769 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r~ 39 85694 0.465 0.000 L> y 89 171919 2.142 0.000

Y-IS 89 171919 2.142 0.000


r~ 39 0.499 20.842 0.85 4.1 ug/L

Y-IS 89 171 91 8.583 95.678 2.05 2.1 %R L> y 89 171 91 8.583 ug/L

010172

~ ~ ~

Page 1 Sample ID cri Report Daterrime Friday, April 27, 2007 10 27 35

Quantitative Analysis - Summary Report 010173 Sample ID: ccv Sample Datenime: Friday, April 27, 2007 10:29:06 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35


Summary


r K 39 132323 1.61 5 0.000 L> y 89 174981 1.212 0.000

Y-IS 89 174981 1.212 0.000


r K 39 0.756 45.174 2.01 4.4 ug/L L> y 89 174981.225 ug/L

Y-IS 89 174981.225 97.383 1.18 1.2 %R

~~~~ ~ ~ ~- - ~

Page 1 Sample ID ccv Report Daterrime Friday, April 27, 2007 10 29 53

Quantitative Analysis - Summary Report Sample ID: ccb Sample DateITime: Friday, April 27, 2007 10:31:23 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

010174

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\ccb. 177 1 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 46694 0.560 0.000 L> y 89 178145 2.299 0.000

Y-IS 89 178145 2.299 0.000


r K 39 0.262 -1.468 0.63 43.0 uglL

Y-IS 89 1 78 1 44.9 1 5 99.144 2.28 2.3 %R L> y 89 1781 44.91 5 uglL

~

Page 1 Sample ID ccb Report Datemime Friday, April 27, 2007 10 32 10

Analyte Mass Meas. lnte Blank Intensity Blank Intens. RSD r K 39 0.000 L> y 89 0.000

Y-IS 89 0.000

Quantitative Analysis - Summary Report Sample ID: 294955 df400 Sample Datenime: Friday, April 27, 2007 10:34:08 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

010175

Sample File: C:\Elandata\Sample\div20~070410-6.sarn Method File: C:\Elandata\Method\SwRI\K-only.rnth Dataset File: C:\Elandata\DataSet\O7Apr\294955 df400.1772 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Concentration Res u Its Conc. Mean Conc. SD Conc. RSD Sample Unit

0.962 64.568 1.47 2.3 ug/L uglL 0 1.88 1.5 %R 123. 1

89 222108.570 Y-IS 89 222108.570

r K L> y

Page 1 Sample ID: 294955 df400 Report Datenime: Friday, April 27, 2007 10:34:55

Quantitative Analysis - Summary Report Sample ID: 294955 df500 Sample DateiTime: Friday, April 27, 2007 10:39:56 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

010176


Summary


r K 39 177465 1.044 0.000 L> y 89 176804 2.270 0.000

Y-IS 89 176804 2.270 0.000


r K 39 1.004 68.562 2.91 4.2 ug/L

Y-IS 89 176804,062 98.397 2.23 2.3 %R L> y 89 176804.062 ug/L

~ ~~ ~


Quantitative Analysis - Summary Report 010177

Sample ID: 294956 d f d d 5bS Sample Datemime: Friday, April 27, 2007 10:45:21 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35


Summary


r K 39 173221 2.896 0.000 L> y 89 175771 2.114 0.000

Y-IS 89 175771 2.1 14 0.000


39 0.985 66.790 1.12 1.7 uglL

Y-IS 89 175770.708 97.822 2.07 2.1 %R uglL

r K L> y 89 175770.708

~~ . _ _ ~~ ____ _~ ~- ~ _ _ _ ~ - ~ ~

Page 1 Sample ID 294956 df400 Report Datemime Friday, April 27, 2007 10 46 09

Quantitative Analysis - Summary Report Sample ID: 294957 d f F 5cc3 Sample Datenime: Friday, April 27, 2007 10:49.01 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\294957 df400.1775 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optirnize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r~ 39 ia1611 0.642 0.000 L> y 89 176509 2.592 0.000

Y-IS 89 176509 2.592 0.000


39 1.029 70.932 2.16 3.0 ugIL

Y-IS a9 176509.227 98.233 2.55 2.6 %R

r~ L> y 89 176509.227 uglL

010178

~ ~ - - ._ ~~ ~ - _ _ - Page 1 Sample ID 294957 df400 Report Daterrime Friday, April 27, 2007 10 49 48

Quantitative Analysis - Summary Report Sample ID: 294959 df@ bqb Sample Daterime: Friday, April 27, 2007 10:51:20 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

0- 4\27 107

Sample File: C:\Elandata\Sample\div20~0704IO-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\294959 df400.1776 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 114154 2.004 0.000 I> y 89 179071 0.922 0.000

Y-IS 89 179071 0.922 0.000


39 0.638 33.959 1.61 4.8 uglL L> y 89 179071.402 uglL

Y-IS 89 179071.402 99.659 0.92 0.9 %R

r K

010179

- ~ ~

Page 1 Sample ID 294959 df400 Report Daterime Friday, April 27, 2007 10 52 08

Quantitative Analysis - Summary Report Sample ID: cri Sample Datenime: Friday, April 27, 2007 10:53:39 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\cri. 1 777 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 85672 0.120 0.000 t> y 89 174171 0.758 0.000

Y-IS 89 174171 0.758 0.000


r K 39 0.492 20.21 1 0.40 2.0 uglL L> y 89 174171.355 uglL

Y-IS 89 174171.355 96.932 0.73 0.8 %R

010180

~ _ ~ _ - _ _ . -



Sample ID: ccv Sample Datenime: Friday, April 27, 2007 10:55:57 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20-07041 O-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\ccv. 1778 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 133435 1.157 0.000 L> y 89 171191 0.413 0.000

Y-IS 89 171191 0.413 0.000


r K 39 0.779 47.350 0.55 1.2 ug/L L> y 89 171 190.958 ug/L

Y-IS 89 171 190.958 95.274 0.39 0.4 %R

~ - _ _ _ ~~~ ~

Page 1 SampleID ccv Report Datemime Friday, April 27, 2007 10 56 45


Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K_only.mth Dataset File: C:\Elandata\DataSet\O7Apr\ccb. 1779 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 471 06 0.776 0.000 L> y 89 174339 1.630 0.000

Y-IS 89 174339 1.630 0.000


r K 39 0.270 -0.708 0.62 87.4 uglL

Y-IS 89 174338.858 97.025 1.58 1.6 %R L> y 89 174338.858 uglL

010182

~ ~~ ~ - ~~

Page 1 Sample ID ccb Report Daterrime Friday, April 27, 2007 10 59 02

Quantitative Analysis - Summary Report Sample ID: 294959 dfl00 Sample Datenime: Friday, April 27, 2007 11 :04:57 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

010183

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\07AprP94959 dflOO.1780 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 37081 0 5.225 0.000 L> y 89 17231 5 0.185 0.000

Y-IS 89 172315 0.1 85 0.000


r K 39 2.152 176.904 10.99 6.2 uglL

Y-IS 89 172314.671 95.899 0.18 0.2 %R L> y 89 1 723 1 4.67 1 uglL

Page 1 Sample ID: 294959 dflOO Report Datenime: Friday, April 27, 2007 11:05:45

Quantitative Analysis - Summary Report Sample ID: cri Sample Daterrime: Friday, April 27, 2007 11 :08:28 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20-07041 O-6.sam Method File: C:\Elandata\Method\SwRI\K-onlymth Dataset File: C:\Elandata\DataSet\O7Apr\cri. 1781 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r~ 39 88728 0.827 0.000 L> y 89 180786 0.554 0.000

Y-IS 89 180786 0.554 0.000

Concentration Resu I ts Analyte Mass Net Intens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit r~ 39 0.491 20.107 0.39 1.9 uglL

L> y 89 180785.752 uglL Y-IS 89 180785.752 100.613 0.56 0.6 %R

010184

- - ~~ ~~ ~~


Quantitative Analysis - Summary Report Sample ID: ccv Sample DateRime: Friday, April 27, 2007 11:10:47 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\E1andata\Samp1e\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\ccv. 1782 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r~ 39 136483 0.132 0.000 L> y 89 173251 2.180 0.000

Y-IS 89 173251 2.180 0.000

Concentration Resu I ts Analyte Mass Net Intens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit r~ 39 0.788 48.161 1.69 3.5 uglL

L> y 89 173250.546 ug1L Y-IS 89 173250.546 96.420 2.10 2.2 %R

010185

~ ~~ ~~ -~ -

Page 1 Sample ID ccv Report DateRirne Friday, April 27, 2007 11 11 34

Quantitative Analysis - Summary Report 010186

Sample ID: ccb Sample Datenime: Friday, April 27, 2007 11 :I 3:05 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35


Summary


r~ 39 48574 1.103 0.000 I> y 89 179328 1.071 0.000

Y-IS 89 179328 1.071 0.000


r K 39 0.271 -0.649 0.33 51.4 ug/L

Y-IS 89 179327.608 99.802 1.07 1.1 %R L> y 89 179327.608 ug/L

- ~

Page 1 SampleID ccb Report Daterrime Friday, April 27, 2007 11 13 51

010187

0 200.8 TAP No. 01-0406-107 Rev 2/Jan 06

d 6 0 2 0 TAP No. 01-0406-046RevlO/Jan 06 f

0 Other

ANALYSIS

k

ICP-MS CALIB. STD. ID’S

STD. 2 STD. 3

OC STD. ID’S

ICV/CCV CRI ICSA ICSAB

PROJ. NO. PROJECT TO# DATE MATRIX LLOGBK PG

INSTRUMENT: 1 FILENAME: 01 cq \ea JUW

Quantitative Analysis - Summary Report Sample ID: S-0 Sample Datenime: Friday, April 27, 2007 15:37:44 Sample Description: Solution Type: Standard Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K_only.mth Dataset File: C:\Elandata\DataSet\O7Apr\S-O. 1822 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 52703 1.207 0.000 L> y 89 170971 3.229 0.000

Y-IS 89 170971 3.229 0.000

Analyte Mass Net Intens. Mean r K 39 0.309 L> y 89 170970.697

Y-IS a9 170970.697

Concentration Res u I ts Conc. Mean Conc. SD Conc. RSD Sample Unit

uglL uglL

100.000 3.23 3.2 %R

~ _ _ ~ ___ -~ - ~

Page 1 Sample ID S-0 Report Daterrime Friday, April 27, 2007 15 38 31

Quantitative Analysis - Summary Report Sample ID: S-I00 Sample Datenime: Friday, April 27, 2007 15:40:01 Sample Description: Solution Type: Standard Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\S-lOO.1823 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 220782 1.51 3 0.000 L> y 89 170933 1.431 0.000

Y-IS 89 170933 1.431 0.000


r K 39 1.292 100.000 0.38 0.4 uglL

Y-IS 89 170932.685 99.978 1.43 1.4 %R L> y 89 170932.685 uglL

010189

~~ - - -~~~ ~~ - - -

Page 1 Sample ID S-100 Report Daterrime Friday, April 27, 2007 15 40 49

Quantitative Analysis - Summary Report 010190 Sample ID: icv Sample Datenime: Friday, April 27, 2007 1542: 19 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\icv. 1824 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary

In tens i t i es Analyte Mass Meas. Intens. Mean Meas. Intens. RSD Blank Intensity Blank Intens. RSD

r K 39 133627 1.333 0.000 L> y 89 167864 3.145 0.000

Y-IS 89 167864 3.145 0.000

Analyte Mass Net Intens. Mean r K 39 0.796 L> y 89 167863.784

Y-IS 89 167863.784


49.637 2.41 4.9 uglL ug/L

98.183 3.09 3.1 %R

~~ ~~ ~~

Page 1 Sample ID ICV

Report Daterrime Friday, April 27, 2007 15 43 07

Quantitative Analysis - Summary Report Sample ID: icb Sample Datemime: Friday, April 27, 2007 15:44:37 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K_only.mth Dataset File: C:\Elandata\DataSet\O7Apr\icb.l825 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 49499 0.407 0.000 L> y 89 173497 1.590 0.000

Y-IS 89 173497 1.590 0.000


r K 39 0.285 -2.355 0.47 19.9 ug/L L> y 89 173496.687 ug/L

Y-IS 89 173496.687 101.477 1.61 1.6 %R

010191

Page 1 Sample ID: icb Report Datemime: Friday, April 27, 2007 15:45:24

Quantitative Analysis - Summary Report 010192 Sample ID: Irs Sample DateiTime: Friday, April 27, 2007 15:52:07 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-onlymth Dataset File: C:\Elandata\DataSet\O7Apr\lrs. 1826 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 41 8806 1.626 0.000 L> y 89 170949 2.061 0.000

Y-IS 89 170949 2.061 0.000


r K 39 2.451 217.881 6.29 2.9 uglL L> y 89 170948.689 uglL

Y-IS 89 170948.689 99.987 2.06 2.1 %R

~ . ~~~ -~ ~ ~~ _ _ _ ~ -~~

Page 1 Sample ID Irs Report Datemime Friday, April 27,2007 15 52 55

Quantitative Analysis - Summary Report Sample ID: zzzz Sample Daterrime: Friday, April 27, 2007 15:54:25 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\zzzz. 1 827 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r~ 39 49444 0.378 0.000 L> y 89 173293 1.775 0.000

Y-IS 89 173293 1.775 0.000

Concentration Resu I ts Analyte Mass Net Intens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit r~ 39 0.285 -2.353 0.41 17.4 ugIL

L> y 89 173292.946 uglL Y-IS 89 173292.946 101.358 1.80 1.8 %R

010193

~ -~~ ~~ ~ ~~-

Page 1 Sample ID zzzz Report Daterrime Friday, April 27, 2007 15 55 12


010194

Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\cri. 1 828 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 84500 0.328 0.000 L> y 89 165705 2.01 6 0.000

Y-IS 89 165705 2.01 6 0.000


r K 39 0.510 20.502 0.92 4.5 ugIL L> y 89 165704,747 uglL

Y-IS 89 165704.747 96.920 1.95 2.0 %R

~

Page 1 Sample ID cri Report Daterrime Friday, April 27,2007 15 57 31

Quantitative Analysis - Summary Report Sample ID: ccv Sample Datenime: Friday, April 27, 2007 15:59:02 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20-07041 O-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\ccv. 1829 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 133868 0.916 0.000 L> y 89 168871 2.353 0.000

Y-IS 89 168871 2.353 0.000


r K 39 0.793 49.271 1.16 2.4 ugIL

Y-IS 89 168871.277 98.772 2.32 2.4 %R L> y 89 168871.277 uglL

~ ~~ -~ ~

Page 1 Sample ID ccv Report Datemime Friday, April 27, 2007 15 59 50



Summary


r K 39 46602 0.537 0.000 L> y 89 173345 1.490 0.000

Y-IS 89 173345 1.490 0.000


r K 39 0.269 -4.032 0.27 6.8 ug/L L> y 89 173344.839 ug/L

Y-IS 89 173344.839 101.389 1.51 1.5 %R

010196

Page 1 Sample ID: ccb Report Datenime: Friday, April 27, 2007 16:02:06

Quantitative Analysis - Summary Report Sample ID: 294954s df500 Sample Datenime: Friday, April 27, 2007 16:05:03 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20-07041 O-6.sam Method File: C:\EIandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\294954s df500.1831 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

010197

Summary


r K 39 197244 0.946 0.000 L> y 89 172181 1.449 0.000

Y-IS 89 1721 81 1.449 0.000


r~ 39 1.146 85.149 0.62 0.7 ug/L L> y 89 1 72 1 80.542 ug/L

1 72 1 80.542 100.708 1.46 1.4 %R Y-IS 89

~ ~~ -

Page 1 Sample ID 294954s df500 Report Daterrime Friday, April 27, 2007 16 05 51


Sample File: C:\Elandata\Sample\div20~070410-6.sam Method File: C:\Elandata\Method\SwRI\K_only.mth Dataset File: C:\Elandata\DataSet\O7Apr\cri. 1832 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 86156 0.731 0.000 I> y 89 169794 3.084 0.000

Y-IS 89 169794 3.084 0.000


r~ 39 0.508 20.258 1.24 6.1 uglL

Y-IS 89 169794.389 99.312 3.06 3.1 %R L> y 89 169794.389 ugIL

~- ~~

Page I Sample ID cri Report Daterrime Friday, April 27, 2007 16 08 10

Quantitative Analysis - Summary Report Sample ID: ccv Sample Dateflime: Friday, April 27, 2007 16:09:41 Sample Description: Solution Type: Sample Blank File: Number of Replicates: 3 Peak Processing Mode: Average Signal Profile Processing Mode: Average Dual Detector Mode: Dual Dead Time (ns): 35

Sample File: C:\Elandata\Sample\div20~0704IO-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\ccv. 1833 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r~ 39 132381 2.284 0.000 L> y 89 170207 1.506 0.000

Y-IS 89 170207 1.506 0.000


r~ 39 0.778 47.753 2.64 5.5 ug/L L> y 89 170207.1 12 ug/L

Y-IS 89 170207.1 12 99.553 1.50 1.5 %R

010199

~ ~~ ~ ~ ~~~

Page 1 Sample ID ccv Report Dateflime Friday, April 27, 2007 16 10.28


Sample File: C:\Elandata\Sample\div20-070410-6.sam Method File: C:\Elandata\Method\SwRI\K-only.mth Dataset File: C:\Elandata\DataSet\O7Apr\ccb. 1834 Tuning File: c:\elandata\Tuning\default.tun Optimization File: c:\elandata\Optimize\Default.dac Calibration File: Calibration Type: External Calibration

Summary


r K 39 46914 0.427 0.000 L> y 89 174616 1.529 0.000

Y-IS 89 174616 1.529 0.000


r K 39 0.269 -4.046 0.53 13.2 ugIL

Y-IS 89 174615.518 102.1 32 1.56 1.5 %R L> y 89 174615.518 ug/L

010200

~~- - - _. - . - - ~ - _ _ ~ ~~~ ~ _ _ _ ~ ~

Page 1 Sample ID ccb Report Daterrime Friday, April 27,2007 16 12 45