the new coating technologies for plastics “nsc” protection glasses developed coating resin, such...
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Developed coatings agents for lens.
Served glass manufactures in Japan for more than 30years and
expanded glass business into the world.
Expanded coating business to other molded products such as Helmet
visor, Protection glasses
Developed coating resin, such as acrylic, polyurethane and inorganic
materials.
Variety of raw materials are selected carefully and then synthesized
for efficient functional coatings
Expanded coating business to film coatings for electronic materials
Various formulations are available to meet customer’s technical
requirements
NFC’s coating technologies history
Development of coatings and production and sales
Electronic industry materials
(Mobile phone, Smartphone, Computer display, TV, etc.)
Glasses
Sheets (a helmet visor, protective goggle, etc.)
Synthesis of functional materials, functional monomers,
functional development and manufacture of polymers
organic, inorganic, polymer synthesis and prescription
Key Business
1)Thermal curable coatings
・ For glazing
・ For films
・ For functional coatings
2)UV curable coatings
・ For films
・ For sheets
3)Hybrid type
Products offering
1. THERMAL CUREBLE HARD COATINGS
FOR LENS & SHEETS
CHARACTERISTICS OF NIIPPONFINE CHEMICAL
PRODUCTS
Stable performance: High abrasion resistance
Short Curing-time : 10~30minutes at 130℃
High adhesion
compatible with various plastics, metals, other substrate
Multiple functions
Capable of adding to coating layers some functions such
as antifogging, dyeing and so on
Substrate Product name Features
1.67 MR-7 ・NSC-5671 ①Disappearance of 1.60 interference fringes PU(MR-8) ・NSC-5601 insusceptible to Acryl product method 1.59 PC ・NSC-5506 ・NSC-5140/Primer ②Superior Adhesion ・NSC-5614 Boiling test 100/100 1.56 Polyurethane ・NSC-5616 Acryl ③Advanced Abrasion DAP more than 5 at 1.53 Trivex ・NSC-5613 Bayer test 1.49 CR-39 ・NSC-5150A Others ・NSC-5215 ④Excellent Weather Polarized lens ・NSC-5140 resistance ・NSC-AM-60 stable over 120hr at Stainable hard coating ・NSC-DY-106 QUV test Anti static hard coating
Functional thermal curable coatings
8
Disappearance of interference fringes
adjustment index
Refractive index can be adjusted depending on the refractive index of substrate.
Adjustable range: ~1.67
Index
Substrate 1.60
Coating layer 1.50
Index
Substrate 1.60
Coating layer 1.60
Index adjustment
NSC-5601Q
REFRACTIVE INDEX: 1.60
PENCIL HARDNESS: 3H(Polyurethane)
ABRASION(SW): 4 (very good)
ADHESION: 5 (excellent)
Bayer test : 4↑
QUV test :120hr↑
SUBSTRATE: Polyurethane
Polyacrylate
CURING CONDITION:
120℃,30mins
NSC-5613
Product name NSC-5613
Refractive index 1.53
Thickness 3 - 5 mm
Transmittance > 98%
Falling ball impact test Excellent (127 cm, 300 g)
Taber abrasion test △haze 1 % ( CS-10F wheel, 500g load, 100 cycle)
Steel wool test 4 (very good) (#0000, 500 g load, 50 time)
Bayer test 5
Crosshatch adhesion 100 / 100
Boiling water resistance Stable (100 deg. C, 30 min)
Weather resistance
QUV test (7days) Stable 168hr
Sunshine-weather meter Stable 240hr
crosshatch adhesion 100 / 100
Applied to Trivex
Advanced Adhesion, Weather resistance
NSC-5506 Advanced abrasion resistance Hard Coat for
Polycarbonate
Features : Advanced abrasion resistance, flexibility
1) ASTM D1044 500g x 100 cycles, CS10F wheels
2) Steel wool abrasion test 1kg load×100 reciprocations
3) Soaked in 100℃ of water for 30 mins.
NSC-5506 NSC-1500
NSC-5000 series flexible
Bayer abrasion test 3.9
Taber Abrasion test
(△haze%) 1) < 0.9
Abrasion2) No scratch
Adhesion 100 / 100
Adhesion
boiling water test 3) 100 / 100
Adhesion
QUV test 96 hrs. 100 / 100
Feature : high hardness & advanced abrasion resistance
Haze (%) < 0.2
Total Light Transmittance (%) > 90
Pencil hardness 1) 2H
Taber Abrasion test(△haze%) 2) < 0.2
Adhesion 100 / 100
Adhesion
boiling water test 3) 100 / 100
1) 750g load, coated on PET film.
2) ASTM D1044 500g x 100 cycles, CS10F wheels
3) Dipped in boiling water for 30 mins.
NSC-5215 High hardness / thermal curing
Feature : No interference fringe with PC lenses
Interference fringe none
Bayer abrasion test 3.1
Adhesion 100 / 100
Adhesion
boiling water test 1) 100 / 100
Adhesion
QUV test 120 hrs. 100 / 100
1) Dipped in boiling water for 30 mins.
NSC-5614
Feature : Stable after QUV test (120 hrs.)
Bayer abrasion test 4.0
Adhesion 100 / 100
Adhesion
boiling water test 1) 100 / 100
Adhesion
QUV test 120 hrs. 100 / 100
1) Dipped in boiling water for 30 mins.
NSC-5150A Weather resistance coating for CR-39 / thermal curing
NSC-DY-106 Stainable hard coating
Product name NSC-DY-106
Curing system Thermal curing
NV 32 %
Viscosity 6.0 mPa・s
Falling sand test <4
Taber abrasion test <2
Adhesion 100 / 100
Features Stainable
Advanced anti-
abrasion
Stainable hard coating Standard hard coating
0 20 40 60 80 100
Afterstaining
DY-106
Transmittance
(%)
Weather resistance
1)Prevention of coating stripping
2)UV protection
Keep substrates from yellowing and damaged.
Wavelength (nm)
Spectral transmission range of UV
Perfect UV protection less than 380nm
Tra
nsm
itta
nce
Uncoated PC lens
Weather resistance
Yellowing resistance
NSC-1550 coated
QUV test / hour
Ye
llo
w
Ind
ex
(Y
I)
Weather resistance
:UV curable hard coating
UV irradiation 72hr
Base material(PET f ilm)
Coated f ilm(conventional UVcurable coating)
Coated f ilm(NFC's weather
resistance coating)
Since the coating contains our weather resistance formulation technologies, the cured
film shows much better anti-yellowing property after irradiation of UV compared with
those of conventional UV curable coatings.
*)Upper half is covered with aluminum foil to protect against UV rays.
Polarized lens needs to be cured at low temperature due to iodine series contained in the lens.
NSC-AM60 does not cause any damage to polarized lens because it can be cured at 90℃.
Coating for polarized lens
UV light
Natural light
Glare by reflection
Polarized light filter
0
5
10
15
20
25
30
35
40
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5
T hic knes s (µm)
⊿H
a
z
e
F
a
l
l
i
n
g
s
a
n
d
t
e
s
t
NSC-1520
NSC-5501
NSC-5140
NSC-5200
Substrate
F alling s and tes t-thic knes s
relation
Thermal curing types for PC
Abrasion resistance - Coating thickness F
alli
ng
sa
nd te
st /
D
ha
ze
Thickness / mm
NSC-5501 PC lens brief thermoset test
1.5
2
2.5
3
3.5
4
1 1.5 2 2.5 5 10 30 45 60 120
Time(min)
Steel
Wool
test
110℃120℃130℃135℃NSC-1520 110℃
Handling equipment:Automatic dehydrator WS(wind speed) 3,000L/min SW test :our evaluation method♯0000 SW
PC lens quick thermal curing
NSC-5501 PC lens quick thermal curing test
Ste
el-w
oo
l h
ard
ne
ss
Handling equipment : Automatic drying machine
WS(Wind Speed) : 3,000L/min
SW test : Our evaluation method #0000 SW
Product name Features Application Curing
condition NSC-1500 for sheet PC 120゚C,1hr
NSC-1600 Stable in high temp. humid. PC 120゚C,1hr
condition, interference fringes less
NSC-5506 Advanced abrasion resistance PC 120゚C,30mins
flexible index=1.5
NSC-2000 for sheet PMMA 80゚C,2hrs
Anti-scratch
NSC-5140 Advanced abrasion resistance SEVERAL 120゚C,1hr
index=1.5 SUBSTRATE
NSC-5200 Advanced abrasion resistance SEVERAL 120゚,30mins
flexible index=1.5 SUBSTRATE
Products for thermal curable coating
Product name Features Applicable plastics
NSC-AF332 Conform to EN166/168 PC other materials
and ECE 22/05
NSC-AF301 PC other materials
Antifogging coatings
NSC-AF-332 Antifogging coating / thermal curing
One-coat type for polycarbonate
Pass the EN168 test (Antifogging and Abrasion)
Antifogging evaluation: measure with the defogging tester after the water immersion.
N-mark
K-mark (Resistance to surface damage by fine particle) : 2.7
Product
Name NSC-5140 NSC-5200
Substrate Nylon Nylon
%Solid 33% 33%
Viscosity 6.0mPa・s 10.0mPa・s
△%T(588nm) 83.0 94.3
To avoid color-dulling of dyed lenses
In the case of hard coating of dyed Nylon lenses, conventional coatings sometimes cause color-dulling
of lenses or elution of dye to the coating liquid. NFC developed an anti-color-dulling coating by our
intensive study.
Transmittance change before and after coarting
40
50
60
70
80
90
100
110
380 420 460 500 540 580 620 660 700 740 780
Wavelength/nm
TransmIttance
T%
NSC-5140コート
未コート基材
NSC-5200コート
NSC-5140
Substrate
NSC-5200
Tra
nsm
itta
nce
/
%
Wavelength / nm
Spectral reflectivity
4.5
5
5.5
6
6.5
7
7.5
8
8.5
400 450 500 550 600 650 700
Wavelength/nm
Reflectance
ratIo
%R
AR coated Uncoated
Characters aren'tclear becauselight reflects
Characters areclear
Anti-reflection coating
of
Re
fle
cta
nce
/ %
R
Wavelength / nm
Performances of
thermal curing type for PC
NSC-5000 series flexibilityTaber abrasion test piece(NSC-1520)
NSC-1520
coated
Uncoated
NSC-5501 NSC-1520 NSC-5506 NSC-1500
Water-repellentContact angle 95 Contact angle 75
Contact angle 60AntifoggingContact angle 25
Contact angle NFC can make layers that contain various types of contact angle.
High water-repellent coating can be made by using NFC’s special techniques.
Water repellent performance does not deteriorate because the water repellent
agent is incorporated into the coating layer.
Thiourethane DAP Nylon Urethane
Urethane polarized Modified Polyester
Coatings for other base materials
Antistatic coating
Containing antistatic materials, films having around 1 × 108Ω electrical surface
resistance can be obtained
1×109 Ω/cm2
more than 1×1014 Ω/cm2
Product name surface resistance Features
・NSC-AS-201 1011~12 Water resistance
・NSC-AS-202 1011~12 Water resistance
Solvent resistance
・NSC-AS-203 1011~12 Water resistance
・NSC-AS-204 109 Water resistance
Antistatic hard coatings
:Thermal curing
Product name surface resistance Features Pencil
hardness
・NSC-AS-101 1011~12 Water resistance 2H
・NSC-AS-102 1011~12 Water resistance 2H
Solvent resistance
・NSC-AS-103 1011~12 Water resistance 2H
・NSC-AS-104 109 Water resistance H
Antistatic hard coating: UV curing
2. THERMAL CURABLE HARD
COATINGS FOR FILMS
Feature of thermal curable coatings
Very short curing time
Standard curing condition at 130゚C, for 2mins
Excellent anti-scratch property
Taber abrasion test less than 2%
Low curl property
High hardness with better anti bent crack property
Easy to add further functions
Good adhesion to metal surface such as ITO films
Product name Features Applicable Pencil hardness viscosity
plastics (% solid)
・NSC-3000 Abrasion PET,TAC,PC,ITO F 23
Adhesiveness (30%)
・NSC-3010 Abrasion PET,PC H 5
Anti-scratch (26%)
・NSC-3101 Abrasion PET,TAC,ITO 2H 4
Anti-scratch (30%)
Flexible
・NSC-1700 Water & Oil PET,PC Repellent
(permanent)
Thermal curable hard coating
NSC-5125 High hardness coatings / thermal curing
39
The hardest coating of all NFC’s thermal curable
products (Pencil hardness 2H on PET film)
Advanced abrasion resistance
Properties
Pencil hardness 2H (PET film)
Adhesion 100 / 100
Water soak
adhesion* 100 / 100
Solvent resistance good
* Soaked in water at 80℃ for 30 mins, dried for 30 mins
NES-3101 PET film brief thermoset test
1.6
2
2.4
2.8
3.2
3.6
4
10秒 30秒 1分 1分30秒 2分 4分
Curing time (sec)
Steel
Wool
hardnes
110℃
120℃
130℃
140℃
10 30 60 90 120 240
Handling equipment:Automatic drying machine
WS(wind speed) 3,000L/min
SW test :our evaluation method #0000 SW
PET film : quick thermal curing
NSC-3101 PET film quick thermal curing test
Ste
el-w
oo
l h
ard
ne
ss
Product name Features Applicable Pencil viscosity
plastics hardness (% solid)
・NSC-7113 Low curl property PET,TAC film 2H 51
(55%)
・NSC-7120 High Adhesion PET,TAC film 2H 4
(55%)
・NSC-7121 High Adhesion PET,TAC film H 200
(100%)
・ NSC-7100 Hardness Sheet, film 2H 38
(80%)
・ NSC-7318 Hardness Sheet, film 4H
(60%)
3. UV CURABLE HARD COATINGS
Relationship between
thickness and pencil-hardness
Relationship between thickness and pencil-hardness
0
1
2
3
4
5
6
0 5 10 15 20
thickness(μ m)
PencIlhardness
NSC-3402
NSC-3300
NSC-3101
9H
5H
4H
3H
2H
H
100
基材:100μ mPET film
F
U
Pe
ncil
ha
rdn
ess
Substrate : 100mm PET film Thickness / mm
Product name Features Pencil viscosity
hardness (% solid)
・NSC-7101 Antifouling (oil repellant) 2H 75
finger print can be wiped off easily (80%)
・NSC-7102 Antifouling (lipophilic) 2H 6
(60%)
・NSC-7103 Flexible 2H 25
no crack after 180゚ bent (55%)
・NSC-7120 Impact resistance 2H
Functional hard coating
UV curable functionalized coating
NSC-7101/antifouling
uncoated
Coated
Finger print After wiping off/right side
Signed by permanent marker After wiping off
Since the cured film surface has oil repellant property, finger print attached on the
surface is wiped off easily.
UV curable functionalized
coating NSC-7102/antifouling
UncoatedCoated with NSC-7102
コート
Since the cured film surface has lipophilic property, finger print attached on the
surface is barely recognized.
Product name R.I. Pencil viscosity
hardness (% solid)
・NSC-7600 1.59 H 135
(60%)
・NSC-7212 1.49 2H 45
(65%)
・NSC-7500 1.36
Reflective Index
Product name Features Pencil viscosity
hardness (% solid)
・NSC-7306 Advanced weather 2H 78
resistance (50%)
・NSC-7313 Advanced weather 2H 85
resistance (50%)
(Thermal curing)
・NSC-3600 Advanced weather
resistance
Weather resistance
Spectral transmission range of UV
NSC-7302 Spectral transmission
0
20
40
60
80
100
120
300 310 320 330 340 350 360 370 380 390 400
wave length/nm
Trancemission %T T
ran
sm
issio
n /
%T
wavelength / nm
FEATURES
SUPERFICIAL INJURY AND SCRATCHES REVERT IN AN INSTANT.
Product name NSC-7700
Curing system UV
Viscosity 43.4mPa・s
NV 56%
Pencil hardness 2B(PET)
Abrasion Crack restoration nature is good (1kg load)
Adhesion 100/100
Thickness 20μm
NSC-7700
Self-healing coating
NSC-7700 Usual hard coating
4. HYBRID TYPE
Feature of hybrid type
Advanced hardness
Pencil hardness 4H
Advanced abrasion
Taber abrasion less than 1%
Multifunction
Weather resistance etc.
Pencil hardness and abrasion resistance
1
2
3
4
5
6
7
8
9
10
111 2 3 4 5
Pencil hardness
Thrmo-curable
UV-curable
Hybrid
HARDNESS
NSC-7310
Pencil hardness and abrasionA
bra
sio
n
Standard Type of Hybrids
Product name Features Applicable Pencil
plastics hardness
・NSC-7310 Hardness PET,TAC 3H
Abrasion
・NSC-7311 High hardness PET,TAC 2~3H
Tack free after heating
NSC-7322 High hardness coatings / UV curing
53
Organic-inorganic hybrid type
High hardness
Advanced abrasion resistance (Taber abrasion test : Dhaze% = 2.1 / 500g Load X 100 rotations)
Film thickness
/ mm 10 15 30 45
PC/PMMA
composite* 6H 8H 9H -
PC - F 2H 5H
* thickness of PMMA layer is 120 mm
<Pencil hardness test>
FEATURES OF COATINGS OF NFC
NFC is a world’s leading manufactures of thermal curable hard coatings.
We have been keeping majority of market share for a long time in JAPAN as well as SE ASIAN nations.
We have great deal of skill in this field based on our advanced technical background.
NFC can supply various types of UV curable hard
coatings.
NFC can supply the two different types of coatings based on the hybridization technologies of organic materials.
NFC can develop various types of coating by the
state-of-art technologies.