Thermodynamics IIAP Physics

Could This Happen? Could all the air in a box rush to one side of

the box leaving a vacuum in the other side?

Will heat flow spontaneously from a cold object to a hot object?

Nature’s processes have preferred directions

Direction is important in Thermodynamic processes

Reversible vs. Irreversible ProcessesREVERSIBLEA reversible process is a transition from

one state of a thermodynamic system to another, during which the system is always very close to a state of mechanical and thermal equilibrium (including uniform temperature and pressure)

In other words…a small change in the system that can be reversed.

Ex. a gas that expands slowly and adiabatically can be compressed slowly and adiabatically by a small increase in pressure

IRREVERSIBLEA process that despite

any small change in conditions cannot be reversed.

Ex. Conversion of work to heat by friction

Heat EnginesA device that converts heat partly into work or

mechanical energy.

In a heat engine a quantity of matter, called the working substance, inside the engine undergoes addition and subtraction of heat, expansion and compression, and sometimes, a phase change.

Ex. of Heat Engines Working Substance

Heat EnginesThe simplest engines to analyze are those that have a working

substance which undergoes a cyclic process.Cyclic process a sequence of processes that eventually leaves the substance in

the same state as it started when a cycle is complete the system starts and ends with the same

internal energyCycleAbsorb Heat at High Temp. Do Work Discard Heat at Low

Temp.

Heat EnginesInternal Energy doesn’t change after a cycle.

WQU 0WQ

WWQ

WQQQ CH

Fuel ConsumptionA gasoline engine in a large truck takes in 2500 J of heat and

delivers 500 J of mechanical work per cycle. The heat is obtained by burning gasoline with heat of combustion Lc = 5.0 x 104 J/g.

a) What is the thermal efficiency of this engine?b) How much heat is discarded in each cycle?c) How much gasoline is burned during each cycle?d) If the engine goes through 100 cycles per second, what is

its power output in watts? In horsepower? [1hp = 746 W]e) How much gasoline is burned per second? per hour?

The Otto Cycleidealized model of the thermodynamic processes in a

gasoline engine

idealized model of the thermodynamic processes in a gasoline engine

The Otto Cycle

The Diesel Cycle idealized model of the

thermodynamic processes in a diesel engine

there are no spark plugs for ignition in a diesel engine

the fuel is injected just before the power stroke

the fuel ignites spontaneously from the high temperature developed during the adiabatic compression

Pros Cons

Refrigeratorheat engine operating in

reverse take heat from a cold place

(inside the fridge) and expel it to a warmer place (outside the fridge)

I thought heat didn’t flow from cold to hot?!?!...well it doesn’t…to move heat from cold to hot requires some work!

Refrigeration Process1. The compressor takes in the refrigerant fluid (working substance) and

compresses it adiabatically (this requires work)2. The refrigerant is then sent to the condenser coil at high temperature3. Heat transfers from the hot refrigerant to the surroundings (outside the

fridge) which partially condenses the fluid4. Refrigerant fluid expands

adiabatically into the evaporator (the expansion valve controls this). The expansion cools the fluid enough so that it is colder than the inside of the fridge.

5. The fluid is then transferred into the fridge where it absorbs the heat from the inside of the fridge and partially vaporizes

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Don’t Write This

Air Conditioners & Heat Pumps Air conditioners operate the

same as a refrigerator Difference – inside of

room/building is like the inside of fridge;outside of fridge is now outside of room/building

Heat Pumps are similar to anair conditioner exceptthey’re backwards.

2nd Law of Thermodynamics (2LT)2LT for EnginesIt is impossible for any system

to undergo a process in which it absorbs heat from a reservoir at a single temperature and converts the heat completely into mechanical work with the system ending in the same state in which it began.

A 100% efficient engine does not exist.

2nd Law of Thermodynamics (2LT)2LT for RefrigeratorsIt is impossible for any

process to have as its sole result the transfer of heat from a cooler object to a hotter object.

It is impossible to have a workless refrigerator.

How Efficient Can An Engine Be?2LT – No engine is 100% efficient

In 1824 Sadi Carnot (a French engineer) determined the hypothetical maximum possible efficiency for an engine based on the 2LT.

Carnot CycleTo maximize efficiency we must avoid irreversible

processes.

Heat flow as a result of a temperature difference is an irreversible process.

To avoid this irreversible process the only time that heat can flow must be during an isothermal process.

Carnot Cycle1. Isothermal

Expansion (a b) (Heat Absorbed)

2. Adiabatic Expansion(b c)

3. Isothermal Compression(c d)(Heat Released)

4. Adiabatic Compression (d a)

W is the work done by the system

Thermal Efficiency of Carnot Cycle

The thermal efficiency of a Carnot Engine is dependent only on the absolute temperature (temperature in Kelvin) of the heat reservoirs.

A Carnot EngineA Carnot engine takes 200o J of heat from a reservoir at 500 K, does some work, and discards some heat to a reservoir at 350 K.a) What is the engine’s efficiency?b) How much work does it do?c) How much heat is discarded by the engine?

EntropyA quantitative measure of disorder. Nature (irreversible processes) tends towards randomness

(disorder). No process is possible in which the total entropy decreases

when all systems taking part in the process are included.

Reversible ProcessesChange in Entropy is the heat transferred

divided by the absolute temperature (Kelvin).Thermo Process

Heat (Q)

Entropy

Isothermal Q = -WIsobaric Q = ΔU -

WIsochoric Q = ΔUAdiabatic Q = 0

Entropy