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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION III

Environmental Sciences Center 701 Mapes Road

Fort Meade, Maryland 20755-6350

DATE

FROM

TO

January 29, 2009

SUBJECT: Region m Data QA Review

Khin-Caio Thaung ^ ^ ' Region m ESAT RPO (3EA21)

Robert Kelly Regional Project Manager (3HS32)

Attached is tihie inorganic data validation report for the Twin City tU'\^\ » ^ T**" Co xfoHy 6»<i_ (Case #: 38123; SDG#: MCOl 14, MCOl 18) completed by the Region m Environmental Services Assistance Team (ESAT) contractor under the direction of Region IQ EAID.

If you have any questions regarding this review, please call me at (410) 305-2743.

Attachments

cc: Gene Nance (Tech Law, Inc.)

TO File #: 0014 TDF#: 01007

%^ Printed on 100% recycled/recyclable paper with 100% post-consumer fiber and process chlorinefree. Customer Service Hotline: 1-800-438-2474

AR100002

Lockheed Martin Enterprise Solutions & Services ESAT Region 3 US EPA Environmental Science Center 701 Mapes Road Ft. Meade, MD 20755-5350 Telephone 410-305-3037 Facsimile 410-305-3597

LOG as H e e D MA«7sea~^ We never forget who we 're working for

Date:

Subject:

From:

^

To:

January 13,2009

Inorganic Data Validation (IM2 Level) Case: 38123 SDGs: MCOl 14, MCOl 18 Site : Twin City Metal and Iron Company, Inc.

Kurt Roby 0 -Inorganic Data Reviewer

Mahboobeh Mecanic P^P^ Senior Oversight Chemist

Khin-Cho Thaung ESAT Region 3 Project Officer

OVERVffiW

Case 38123, Sample Delivery Groups (SDGs) MCOl 14 and MCOl 18, consisted of twenty-foiu- (24) soil samples and one (1) field blank analyzed for total metals by ICP-AES and for mercury (Hg) by cold vapor technique. The sample set included three (3) field duplicate pairs. Samples were analyzed by ChemTech Consulting Group (CHEM) according to Contract Laboratory Program (CLP) Statement of Work (SOW) ILM05.4 through the Routine Analytical Services (RAS) program.

SUMMARY

Data were validated according to Region DI Modifications to the National Functional Guidelines for Inorganic Data Review, Level IM2. Areas of concern with respect to data usability are listed below.

Data in this case have been impacted by outliers present in field and laboratory blanks as well as ICP serial dilution and matrix spike analyses. Details of these outliers are discussed under "Minor Problems," specific samples affected are outlined in *Table 1 A" and qualified analytical results for all samples are summarized on the Data Summary Forms (DSFs).

AR100003

of3

MINOR PROBLEMS

Continuing calibration (CCB) and field (FB) blanks had reported results greater than the Method Detection Limits (MDLs) for the analytes listed below. Positive results for these analytes in affected samples which are less than five times (<5X) the blank concentrations may be biased high and have been quaUfied "B" on the DSFs.

SDG Blank Affected Analytes MCOl 14 FB Sodium (Na)

MCOl 18 CCB Aluminum (Al), iron (Fe), magnesium (Mg), potassium (K), thallium (Tl)

FB Na

Percent differences (%Ds) in the ICP serial dilution analyses were outside the control limit (>10%) for the analytes listed below. Positive results for these analytes in affected samples are estimated due to possible matrix interferences and have been qualified'T' on the DSFs.

SDG Analvte(s^ MCOl 14 Al, chromium (Cr), cobalt (Co), copper (Cu), lead (Pb), nickel (Ni), zinc (Zn)

MCOl 18 Al, Co, Cu, Pb, Zn

Matrix spike recoveries were low (<75% but >30%) for silver (Ag) in both SDGs. Low recoveries may be attributed to matrix interferences or analyte lost during the digestion process. Positive results for Ag in affected samples may be biased low and are qualified "L" unless superseded by 'T ' on the DSFs. Quantitation limits for Ag in affected samples may be biased low and have been quaUfied "UL" on the DSFs.

NOTES

The concentration of several analytes exceeded the calibration range in the initial analysis for the samples listed below. These samples were re-analyzed to bring the concentration of the analytes within the calibration range. Results for these analytes were reported fifom the diluted analyses and annotated with (+) or (++) symbols on the DSFs by the reviewer.

Sample(s) MC0125, MC0131, MC0138, MC0139

MC0136

MC0137

MC0125, MC0126, MC0140

MC0124

Dilution 4X

lOX

4X

lOX

lOX

Analvtefs) Fe

Fe,Pb

Al, calcium (Ca), Fe

Pb

Fe

AR100004

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Reported results between MDLs and Contract Required Quantitation Limits (CRQLs) were quaUfied "J" unless superseded by "B" on the DSFs.

Reported results for field duplicate pairs MCOl 16/MCOl 17, MC0132/MC0142 and MC0134/MC0141 were within 35% RPD, +2XCRQL for all analytes except the following:

MCOl 16/MCOl 17 Ca, manganese (Mn)

MC0132/MC0142 Ca, Pb, Mg

MCOl 34/MC0141 Arsenic (As), chromium (Cr), Fe

Data for Case 38123, SDGs MCOl 14 and MCOl 18, were reviewed in accordance with the National Functional Guidelines for Evaluating Inorganic Analyses with Modifications for use within Region DI.

ATTACHMENTS

INFORMATION REGARDING REPORT CONTENT

Table 1A is a summary of quaUfiers qipUed to the laboratory-generated results during data validation.

Table lA Summary of qualifiers on data summary forms after data validation Table IB Codes used in comments colxmin of Table 1A Appendix A Glossary of Data Qualifier Codes Appendix B Data Summary Form(s) Appendix C Chain of Custody Records Appendix D Laboratory Case Narrative

DCN: 38123 MCOl 14 118

AR100005

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TABLE lA SUMMARY OF QUALIFIERS ON DATA SUMMARY

FORM AFTER DATA VALIDATION

Case 38123, SDG MCOl 14

ANALYTE

. Al

Cr

Co

Cu

Pb

Ni

Ag

SAMPLES AFFECTED

All samples

All samples

AU samples

All samples

AU samples

All samples

AU samples except MC0134, MC0137, MC0138, MC0139, MC0141,MC0142

POSITIVE VALUES

L

NON-DETECTED VALUES

UL

BUS

Low

COMMENTS*

ISD (12%)

ISD(11%)

ISD (19%)

ISD (17%)

ISD (21%)

ISD (16%)

MSL(41%)

Na

Zn

MCOl 34, MCOl 37, MC0138,MC0139, MC0141,MC0142

AU samples except MCOl 37

All samples

B

>MDL<CRQL MSL(41%)

High FB(511Jug/L)

ISD (18%)

See explanation of comments in Table IB

AR100006

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TABLElA SUMMARY OF QUALIFIERS ON DATA SUMMARY

FORM AFTER DATA VALIDATION

Case 38123, SDG MCOl 18

NON-POSmVE DETECTED

ANALYTE SAMPLES AFFECTED VALUES VALUES BIAS COMMENTS*

Al MC0123,MC0124, J . ISD (11%)

MC0125,MC0126

MCOl 18 B High CCB (46.555 J ug/L)

Co MC0123, MC0124, J ISD (11%) MC0125, MC0126

Cu MC0123,MC0124, J ISD (14%)

MC0125, MC0126

B High CCB (52.320 J ug/L)

J ISD (18%)


L UL Low MSL(42%)


B High FB (511 J ug/L)


J ISD (17%)

Fe

Pb

Mg

Ag

K

Na

Tl

Zn

MCOl 18

MC0123, MC0124, MC0125, MC0126

MCOl 18

MC0123, MC0124, MC0125, MC0126

MCOl 18

MC0123, MC0124, MC0125, MC0126

MCOl 24

MC0123, MC0124, MC0125, MC0126

See explanation of comments in Table IB

AR100007

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TABLE IB CODES USED IN COMMENTS COLUMN

ISD = Percent differences (%Ds) in the ICP serial dilution analysis were outside the control limit (>10%) [%Ds are in parenthesis]. Positive results are estimated.

MSL = Matrix spike recoveries were low (<75% but >30%) [percent recoveries are in parenthesis]. Positive results and quantitation limits may be biased low.

>MDL<CRQL = Reported results are greater than MDL but less than CRQL and are considered estimated.

FB = Field blank had a result >MDL [result is in parenthesis]. Positive results which are <5X the blank concentration may be biased high.

CCB = Continuing caUbration blanks had results >MDLs [results are in parenthesis]. Positive resiilts which are <5X the blank concentrations may be biased high.

AR100008

Appendix A

Glossary of Data Qualifier Codes

AR100009

GLOSSARY OF DATA QUALIFIER CODES aNORGANIC)

CODES RELATED TO IDENTIFICATION (confidence concerning presence or absence of analytes):

U = Not detected. The associated number indicates approximate sample concentration necessary to be detected.

(NO CODE) = Confirmed identification.

B = Not detected substantially above the level reported in laboratory or field blanks.

R = UnreUable resiUt. Analyte may or may not be present in the sample. Supporting data necessary to confirm result.

CODES RELATED TO QUANTITATION (can be used for both positive results and sample quantitation limits):

J = Analyte Present. Reported value may not be accurate or precise.

K = Analyte present. Reported value may be biased high. Actual value is expected to be lower.

L = Analyte present. Reported value may be biased low. Actual value is expected to be higher.

UJ = Not detected, quantitation limit may be inaccurate or imprecise.

UL = Not detected, quantitation Umit is probably higher.

OTHER CODES

Q = No analytical result.

AR100010

Appendix B

Data Summary Forms

AR100011

DATA SUMMARY FORM: INORGANIC Page 1 of 6

Case #: 38123

S i te :

Lab . :

SDG:MC0114

TWIN CITY IRON & METAL CO INC

CHEM

Number of Soil Samples : 20

Number of Water Samples: 0

Sample Number:

Sampling Locat ion:

Reld Q C :

Matr ix:

Un i ts :

Date Sampled :

Time Sampled :

%SolJds:

Dilution Factor:

ANALYTE

ALUMINUM

ANTIMCihJY

ARSENIC

BARIUM

BERYLLIUM

CADMiuK»i">:'r^'; ;:':••

CALCIUM

•eHf^jiiHuiiA:;:";-';^;-.^

COBALT

• 6 6 ^ ( * E R - • • • • : ! ; - • : , ; : ; : • • • •

IRON

k E A D - :••••'

MAGNESIUM

MANGANESE

MERCURY

NjCKEL.

POTASSIUM

SELENIUM

SILVER

, SOOHiM

THALLIUM

VANADiUIW

ZINC

CRQL

20

6

1

20

0.5

6.5

500

i 5

2.5

10

1

500

i.5 0.1

• 4

500

|-.:''3.S':.;

1

•N-SOO :

2.5

• • . • • • s ' .

6

MC0114

SD01

Soil

mg/Kg

12/9«008

10:09

74.5

1.0

Result

8420

6.8

113

0.92

0.41

11700

• 1 8 3 • ••

12.7

; 8.3

17100

28.6

4560

2190

•• : - 6 . 7 . " '

367

; -.

f - •• . 1 0 4 - :

• -29,3^.

22.9

Rag

J

J

:•!" J

? ! :'•

J

^J. "• J

[•;•••.-::/

UL

[«• . . ;

• • • • • ' • ' •

J

MC0115

SD02

Soil

mg/Kg

12/9/2008

10:33

71.5

1.0

Result

6730

3.2

8.6

430

0.70

5.1

41800

r.'"-"20i3'-:

9.1

[ .. 16V."

18800

6/7

3070

401

1 0.081

'•• : - : i 3 i 8 :

440

:•• : . : ^ - i 2 4 : - ^

; - • : . • • • - 2 0 3 ; -

202

Rag

J

J

'J ' " : ! :

J

•s-y .

J

J

r j . •.

J

,UL

SvV

• • • ' •

J

MCOl 16 1 SD03

Dup.ofMC0117

Soil

mg/Kg

12««008

11:10

87.1

1.0

Result

3860

5.1

2Jf3

0.44

0:42

57200

••"./i&s-i

6.2

r •: "•i'*-i ' 14600

:: 23.4 ••

2650

j : . . 5 1 1 - :

0.067

• • . • • S A

263

j: •-."•• vs&e;::-

;• • ; ' - : ' l&^3. - ' : : :

60.8

Rag

J

:.."' J

\ i •

i : < > : ' J

[ i i ' "

J

J

N' '• !J

JUL p;>;

J

MCOl 17

SD04

Dup.o fMC0116

Soil

mg/Kg

12/9/2008

11:15

88.0

1.0

(Result

4380

4.2

181

0.51

647

33800

\..- m 7.5

[ • •• - 1 5 . 5 ••

11600

21.6

2620

327

5 . 6 ••

305 • j : . : - : - .-. :. :.::;:?

;.>••• / • • • 57 .9 . : - ^

[ •• • i i t i . 2 . ;

45.0

Flag

J

J

J

M--' J

| j ' '

J

: J . •

J

UL

: « : • • ; • ;

J

MC0127

SS09

Soil

mg/Kg

12/9/2008

15:43

58.2

1.0

Result

6290

2;4

8.4

484

0.69

0.87

51100

•V19.2.

i - : •.- .24.3-:

24400

• • • ' 2 1 4 .•

4180

239

0.076

I 9.4 I 705

k": •• 413 .:

•;.••••• : - 2 3 . 3 - ' '

291

Flag

J

J

J

\ j

J

k ' •'

i j

J

J

J

UL

j 'B- •

J

CRQL = Contract Required Quantitation Limit

To calculate sample quantitation limits: (CRQL * Dilution Factor) / (%Solids/100)

SEE NARRATIVE FOR CODE DEFINITIONS

Revised 09/99

AR100012


Case #: 38123

S i te :

Lab . :

S D G : MCOl 14

TWIN CITY IRON & METAL CO INC -

CHEM

1 Sample Number :

Sampling Locat ion:

Reld Q C :

Matr ix:

Un i ts :

Date Sampled :

1 Time Sampled :

%Sol ids :

1 Dilution Factor:

1 ANALYTE ]

• ' / l i J j g l iUM"^ :

ANTIMONY

/«»$^NiC

BARIUM

Bfei*YUJUM

CADMIUM

CALCJUM 1

CHROMIUM

1 GOBALt

I COPPER

liRON

j*LEAD

MAGNlEStUM

MANGANESE

MERCURY

1 NICKEL

1 POTASSIUM

1 SELENIUM

S I L \ ^

1 SODIUM

T i M L t t i i M

VANADIUM

l .^ l^ ja- : . :• ••.,••

CRQL

::^:/2Q.:;

6

- • : - . - l '

20

:;. • a ^ ' '

0.5

sm 1

; . - • • • • • 5 " "

2.5

10 1

':. 500

1.5

0.1

4

1>:-S^^:

3.5

f;-.; -V-il:-:-

500

\l W^ ^ 5

6

MC0128 j

SSI 3

Soil

mg/Kg

12/9/2008

15:33

77.9

1.0

Result!

r / •msQ4 5.4 j

•• • • ^ • l i . r ' j

364

; : • • • • • • • • C L S S i -

1.4

:• . .14200.

34.2

p ••:-'t4;&-;-

47.8

[•-, • 3 0 ^ - '

i 1260

1940

867

0.11

14.8

• • • : - 7 9 9 . :

77.4

38.9

Flag

• J - -

J

J

M. •

J

J

J

J

[UL

B

[4..J:

MC0129

SS14

Soil

mg/Kg

12/9^2008

15:26

80.4

1.0

Result

• • ' . • ' ^ E » ' .

2.9

• • ld : t -

343

0;87--

1.2

[ 9 0 8 0 0

37.4

[:; . i 1:2.2 :•

36.5

232(k>

554

I 4260

598

0.-11

10.1

•• •• • • . 5 7 7 -

76.0

34.5

k-rm.

Rag

; : j : : • ; :

J

J

\ : i : : J

J

• J

J

[•'t

":oL

B

y ^

MCOl 30

SSI 5

Soil

mg/Kg

12/9/2008

15:31

67.2

1.0

Resul

f-""'::$m-:\ 1 1-9 ; : ; • ; • • • • • • : - ; . 8 i ; 4 ' :

329

[:•• • • - p ^ ; :

1.2

( 2ea» I 27.1

I ; 1M ': I 33.3

•••^2(E«flOH

317

. • 3370-

561

0.12 "

10.4

;.• . • • 7 3 0 ;

62.6

27.8

\uK.^ :m-

Flag

iP J

^Jr:-1

J

' ^ / • • • :

J

J

[ • • J -

J

U • ^

[tIL- •

B

' •

^2iL^

MCOl 31 1

SSI 6

Soil

mg/Kg

12/9/2008

15:20

67.7

1.0/4.0 .

Result!

r;;-v2o«io:: 26.5

••-• • •• a s a ^

975

•• :pi27

164

i'.'. - • • 9 « » 110

\^ ••• - . l i T - ' 1

3600

h..i5iono*j 5920 j

[• 7n t 1 1610

1.1

1 107

•.- t I l iO- :

.•:•• 9 . 6 • • '

172 [ • • ' . '

37.9

Flag

W-:

• J- '

J

M" ; J

J

J

i t - : B

y^;.;

MCOl 32 1

SSI 7

Dup.ofMC0142

Soil

mg/Kg

12ra/2008

15:08

85.6

1.0 j

Result

r---mn:] 7.9

• 1 0 : 1 - ;

147

0.61-.

2.0

'• ^ e o q . 1

38.6 1

i'v • i f r i ' /

83.4

' i ^ o o

1680

[ 7320

470

0.12- :

10.4 v o l '•

68.2

•

25.8

L...:.:.:..M-.

Flag

m'

4 . .

J

i ' j - ' J

J

J

kJ

| t )L .

[B

b f - ;




Revised 09/99

' + " = Result reported from the diluted analysis.

AR100013


Case #: 38123

Site:

Lab.:

SDG:MC0114


CHEM

1 Sample Number:

Sampling Location:

Reld QC:

Matrix:

Units:

I3ate Sampled:

Time Sampled:

%Soliris: 1 Dilution Factor:

ANALYTE 1

ALUMINUM

• : y ! f j * j i ^ ^ i.:. .--..r.••:•:::::•::

ARSENIC

: : : B / i i l ? { p ( 4 - : ( : ; ; : , . • ."•• :• ' • ;•• : ,•••• .•

BERYLLIUM

::eAl#yj«; ^ ^ ^ ^ CALCIUM

I c f i f i i ^ ..::.••;.;•..- j

COBALT

r o b p p E R ^ •• ••• •

1 IRON

p t E M - ^ 4 ^ :•:••••"••

1 MAGNESIUM

MANQANESE

MERCURY

NICKEL

1 POTASSIUM ^ L B « U M

j SILVER ;.;S0t«UMl

1 THALLIUM [ v / W A D f t J M 1 ZINC

CRQL

20

;v-':-:6M

1

;;• • • ^ • • 2 0 : ]

0.5

; : • • ; • : • • ; # ; ;

500

'MM 5

;•• ;--2;$:i -1

10

'MM. • 500

[•• - 1 . 5 •

0.1

•• - . • • 4 .

500

[:••-. ••3:5'

1

km-: 2.5

• - • ' • • * • •

6

MCOl 33 ] SSI 8

Soil

mg/Kg

12/9/2008

15:23

75.2

1.0

Resultl

9570

5':-:'.-':-M 15.9

;•••••"• ^ m i \

0.83

• i ^ r ' • > • • • • - ^ - ^

26800

tMm^l 13.2

'M - \ 38900

^ ^ • • • ' • i m - - ^

3230

„ 1090 •.

0.20

[•". ' • . i * '8 :

1 ^

[;•: M A J B ':

^ • • • • • • 4 i ; 6 - :

1 313

Rag]

J 1

:J'-

<y/ .

U-:-J

m:-iiJ/i}:

f;J •

UL

B •. •

| j

MC0134

SSI 9

Dup.ofMCOUl

Soil

mg/Kg

12/9/2008

15:03

63.3

1.0

Result!

9830

4':V'.:-W-. 15.1

•:•;:••: • • 3 t 6 : '

0.77

^i'---::lM'-42300

tl:'.-x0: 29.4

k/'-'-i'i^ j 33600

f!••,-• i i z a •-

3020

371

0.45

. 23^3 •

934

0.21

[-:'.•.: ^iis': '

M'..'W:' \ 415

Flag

•'.. MX ^

J

IsZ J

;il-; :

:¥;-:

M ' •

M J

|i:i.i:

K-j!

1J

MCOl 35 1

SS25

Soil

mg/Kg

12/9/2008

14:58

63.0

1.0

Result!

12400

fe--' -WA::- ]

33.8

• ^s?o; 1 0.52

M :.--':1p-- j 51800

[ • • " ^ • • • • ' : ' ' : ' ^ * i f - ;

20.1

[••••••• i m ' i 78800

p•••^•1#t>:^'

11400

• . 1020 • 3.8

• •• M ^

1240

2.4

.•;.:• : • ' : ; 1 * * ^

\M' :m ' \ 2590

Flag]

J J

J

W"' J

W^ •: [

\^'- '.

}jiM.

[ y - • • • • : • • • : • •

L

li-:J;

: • • ? ' • i v

[ j

MCOl 36 1

SS29

Soil

mg/Kg

12/S/2008

14:32

78.7

1.0/10

Resutl

6490

• ' • # • ' ;

70.6

. 170: ]

0.15 1

%'•••• ^ m i

7050

M:-Jm4'.'i 13.0

• • m

169000 +

f:-.tmm:* \ 1 2250

:. ':956 1

1 1.1

;••••• •• ' 7 * ^ 2 : •

456

3.8

l-:::;--':::;-; :; I

fMM^ I 652

Flag

J

J

'iM' J

? • > • • •:

W::. '•

p-r M L .

m^

| j

MCOl 37 1

SS31

Soil

mg/Kg 1

12/9/2008 1

14:39

69.5 1.0/4.0 1

Result 1 126000 +

" m i ; 20.4

:./ -. m i 0.45

ii'i-:.-.: m 173000 +

M"'''W-19.1

^ • ' ' * ^

112000 +

p: M ^ '• 6010

843

6.5

72i5-

471

0.28

;., •• y ^ m t ' :

. . ' • • • • < ^ ' ^ . ;

1 3410

Flag]

7 j

J 1

pi J

"J

J

•:>

J

J

M..

J 1 CRQL = Contract Required Quantitation Umit



Revised 09/99

'+" = Result reported from the diluted analysis.

AR100014


Case #: 38123

S i te :

Lab . :

SDG:MC0114


CHEM

1 Sample Number:

Sampling Locat ion:

Field Q C :

Matr ix:

Un i ts :

Date Sampled :

Time Sampled :

%Sol ids :

1 Dilution Factor:

ANALYTE 1

y M : ( 3 i i * i f i i M . ^ - ••• •;

A N T I M O N Y

• • A P i S E N I d - • • • ; • • • • • • ••••• -• . :

1 BARIUM r B f e i m i u u M . . ••..•;. '.•;•':'1

CADMIUM

CAifSluM-;- • • . • ; , • ] 1 CHROMIUM 1 r - G ^ ^ j M i T ^ ' - ' - • ; • • : !

1 COPPER

iRbN |*LEAD

KM^NisSuM MANGANESE

;ilV#K3il^'-^ NICKEL

POTASSIUM.

SELENIUM

SILVER

SODIUM

TMALUUM

VANADIUM

• . . Z I N C . . . , , v . - . . ...:., •.•-... . • • - . :

CRQL]

-\m-l 6

• ' I -

20

r:'-.o.5.- 0.5

i' W ; 1

: : : . • • . : $ :

2.5

• • . : • : • • • f 6 ••

1

R SOO:; 1 1.5

MHA ': 4

- 5 0 0 •

3.5

' '' 500

[• 2^5. • 5

! : . • • • • . 6 ;

MCOl 38 1 SS32

Soil

mg/Kg

12ra«008

14:48

62.9

1.0/4.0

Resultj

t ' - ' '••sm"--] 37.5

32.6' •

482

. P;22. :'

75.9

•i-. - . - a ^ : : ]

106

f ? • • ^ • ^ ^ ^ :;

646

145OO0>

11400

]'••• • • 2 7 0 I J .

I 1080

I • 0 0 ' ! 106

: 651 ;

. 0.73-

108

24.3

k ..- :-iW: ;

Flag

^4 ••

M- :

: • • • . • • • .• : •

J

M: - '-•

J

J

J.

-J

J-

B

\ i .

MC0139 ]

SS33

Soil

mg/Kg

12/9/2008

15:16

72.0

1.0/4.0

Resul^

v:--:-i(im* 98.5

••39;9 1 462

[:• OA* 14.5

•;:'•.-'. iKw»;

142

• ^ • • ^ • • • • • " i ' 6 ^ ^ ' : :

1170

i 134000 + 17200

.. .4340 •

1250

'o.e^ 87.5

877

0.72

87.6

36.4

I...... - mir:

Rag

W]

••.J: '..

J

i ^ " •

J

J

J

J .

B

U-l:

MCOl 40 ]

SS34

Son mg/Kg

12/9/2008

15:55

63.5

1.0/10 !

Result!

.- •• - ' m i i j h ]

657

m 254

04^ \ 13.4

t : " - ' ^ • : \ 224

! • : • . • • • • : * # ;

i 1880

I 6 7 ^ 124000 +

[ •1410-: '

759

- • . . • l i ^

76.7

T^J .

4.4

•- • • • • . 4 . 2 - :

1 ^^

1 38.0

I.;-: ':.$m-

Rag

W.- :

J

I M • J

J

; - . •

J

U - •• •

J

p : • ••

B

M

m i

MC0141 1

SS59

Dup.ofMC0134

Soil

mg/Kg

12^^008

15:06

61.2

1.0

Resu^

f-.yitsm-:-10.1

• " • • •• ^ 2 3 : 1 '1

317

':':. ^ 10.9

;•••••• ^ ^ i s m '

56.5

:;::..: •::.-;2g;S^:

150

t 5S0dO ;

1330

i:' 2Q:eo 524

i o ;^ 1 25.6

905 •

- 0.3Q

121

• •

51.0

Flag

: ;n[: : : ; :

. ! • ••'

[ • • • - •

J

p.' •' '

J

J

J

•

J -

B

k'

MC0142 I SS67

Dup.ofMC0132 1 Soil 1 mg/Kg 1 12«/2008

15:10

87.1

1.0 1 Result

[•••• • • S K © : - :

10.8

1^9- I 151

\ 0.-54 •!

2.8

]•:• •.761:Q6:-;

36.9 i::.:-::.:-.-.^9;7-:!

110

I ^ 6 0 2420

22000

486

0.15

12.5

999

OiZI ^

90.1

33.1

Rag]

f T l

J

1 J

W-J

J

J

\ j

B

b.;;. 1 CRQL = Contract Required Quantitation Limit

To calculate sample quantitation limits: (CRQL * Dilution Factor) / (%Sonds/100)

SEE NARRATIVE FOR CODE DERNITIONS

Revised 09/99

"+" = Result reported from the diluted analysis.

AR100015


Case #: 38123

Site:

Lab.:

SDG:MC0118


CHEM

Number of Soil Samples : 4

Number of Water Samples: 1

Sample Number:

Sampling Location:

Mafaix:

Units:

Date Sampled:

Time Sampled:

%Sonds: Dilution Factor:

ANALYTE

ALUMINUM

A«T«lpiNY .

ARSENIC

•iBAi^iigi^--:-

BERYLLIUM

CADMIUM CALCIUM

CHROMIUM

COBALT

COPPER

IRON

*LEAP

MAGNESIUM

MANQANFSF

MERCURY

Ni6<FK

POTASSIUM

setetyftOM

SILVER

•soDttjM.-:,: •••,•• •

T H A U I U M

yfAfifibmiA ZINC

CRQL

20

X - : . ' M ' ' 1

• • - • • • i o r

0.5

• : ; - . .0 t5. . -

500

1

5

2.6

10

1

500

15 0.1

- • M ' 500

•; ' 3 ^ - ^

1

- ^ Sfifii:-:

2.5

: : • : : • • : 5 V - :

6

MC0123

SS100

Soil

mg/Kg

12«/2008

16:22

73.9 1.0

Result

7530

• • • 1 > 2 - : ;

6.6

279

0.66

o i 2 21400

17.6

8.0

31.3 18000

281

7240

440

0.075

•;7.o.;.

624 • ' • ;

::."•..••..;.." . " i 7 a : i

^ ' : - ' - ^ \ . 67.4

Rag

J

: j - ; . .

J

J

4:) .

:J-l:-

J

; • • " • . - * . •

J

UL

i-l

J

MC0124

SS02

Soil

mg/Kg

^2JS/2O0a

16:11

68.3 1.0/10

Result

1750

i6^:i)

665

93:3

79,7

6190

272

24.1

484

420000 +

4630

903

1960

0.99

209

325

V : ' • ' : • • . • • • • • : •

•;: " ^ • • • • i 2 i ; ' : ^ .

1.1

1:-. ••••] . i 0 : ' 2560

Rag

J

J

J

J

J

UL

% • ' •

B

J

MCOl 25

SS06

Soil

mg/Kg

12/9C008

16:05

66.8

1 . 0 / 4 . 0 / 1 0

Result

25300 : • ; • - • • . m . ]

240

• . •: 3 6 ^ . ,

0 .41

2<fcp

18600

200

10.7

2S«}

125000 +

122000++

1790

1010

1.3

86;b 727

• f W 4.0

:•• ;i52:::i:

: • ' i m : : : 2630

Flag

J

J

J

• • > • ••

J

' ! • . • .

J

: ' . ' . • ' ;

L

m , . . . . . : . •

J

MCOl 26

SS08

Soil

mg/Kg

12/9/2008

15:48

65.2 1 .0 /10

Result

44200

V •••.••••• • : ^ : & 7 5 J V ;

250

••:.--" '3to.-

1.1

•34^4 :•;

4650

139

11.9

,mio 72600

116000 +

1310

739

1.4

8a2 744

-:••:•• y i ^ i

2.9

• - m n

••,-: • . m s V ;

1800

Flag

J

J

4

J

J • • • . • • ' • T >

L

^ f :•••••!

J

Result

• •

M v -

Rag




Revised 09/99

"+" = Result reported from ttie diluted analysis

'++' = Result reported from the lurttier diluted analysis

AR100016


Case #: 38123

Site:

Lab.:

SDG: MCOl 18


CHEM

1 Sample Number:

Sampling Location:

Field QC:

Matrix:

Units:

Date Sampled:

Time Sampled: 1 Dilution Factor:

ANALYTE

ALUMINUM

ANTIMONY

•ARSENIC

BARIUM

BERYLLIUM

•CADMIUM

CALCIUM

•CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MEROJFtY

•NICKEL

POTASSIUM

SELENIUM

SILVEFI

SODIUM

THALLIIJM

VANADIUM

1 ZINC

CRQL

200

60

10

200

5

5

5000

10

i 60

25

100

10

5000

15

0.2

40

5(»0

35

Id-

5000

[-: • 25

50

1 :•:•:•:: : 6 Q . :

MCOl 18

FB-01

Reld Blanl(

Water

ug/L

12/9/2008

14:11 1.0

Resul

13.8

1900

2.4

49.3

102

1.6

139

511

• .. ..-..: 5,0

Rag

B

M

J

B

B

J

B

J

1J ...

Result Flag Result Flag Result Rag Result Flag

CRQL = Contract Required Quantitation Limit 'Action Level Exists

To calculate sample quantitation limits: (CRQL * Dilution Factor)


Revised 09/99

AR100017

Appendix C

Chain of Custody Records

AR100018

& I E P ^ USEPA Contract LabonBtory Program «2ri«.nrt |no,gantc Tratnc Report & Chain of Custody Record

n««la<i3

PMjBOtCOdt! AcoountCodsi

cencuBio: SpiniD:

WBHmalBMK

nro]MtLMd«R

AcfTon: 6«ni|>1lnflCoi

3

2O0ffT03N302l}C6CO3ENR800

VA0(»465797S

EM Twin a m Iron and Mstal/VA

MIctel leDal lnmdro Rfltnwal Action

TACiiLow, Ino.

Dctattilppodi 12/10/2088

C»fldvN«im: FedEx

AWdH: 880971549722

ShQipad I K ChaAiTeeh CoMuWng Qtaup(CHEMEO) 264 ShBineW Street MountalntliteNJ 07092 (9fia)7M-6800

Case No: DAS No:

38123

Chain of Cuatady Record

FUnnqu!*b»d By (D tH/nnn)

^ Jt?K IXit,.Ctr/iLQL

Samgibr . Spnttin: /O^'*^—"^—

I

RflcdvadBy (Dal»/Tlint}

3

3 : INOROMflC SAMPLE No.

umau ocNcr l i ra

ANDLYSar TlfflNAMUD

TMNoJ PREURVATBffilBgtlM

afMTm LOCAIKN

«UMPl£OOltECr DAC/TME

ORQANIC SAMPLE No. IVPB

N9

M M

K9 O e 09

MC0123

tytC0124

iMcoiza

MC0126

MC0127

MCdl28

8i>ll/S«dtin«nl/ Oeine Nance

SoiVSedtoisntf Gene Nance

SolVSecHment/ GansNcKioB

SoiVSedlinent/

SolVSedlment/ GeneNflRoe

Son/SedlmanV Gene Nance

UO

IJQ

UQ

UQ

UG

UG

Me|als(8)(14]

Meiab(SM14)

Ma)ato<S)(14)

llMata(8)(14)

Uetgl8<!S){14}

Metftl«(S)(14>

73S<lo»On1y)(1)

73J0oeOn1y)l1)

741 (Ice Only) (1)

742(loeOniy)(1)

744{ lceOnW<l )

7 4 6 ( I C S O B W < 1 )

SS100

£602

$soe

$808

SSM

$813

Sii2mzao6

8:12^S/200e

S: 12/9/2008

S: 12W/2008

S:12/6/2(»8

S: 12/00008

16:22

18:11

1&05

1&46

15:43

1633

L a b Q C

CO

O

s o

o a

eMpmantftfOn* Coniiiiefe7N

8«nipl*(i}to<»a luw l forlabenteiy QC:

MC0123

AnldWonal 8Mnpl>r8l{tnatui«|a): Chain orCuatodySeai NumlwK

AnalydBKsy:

NMah (8) - Hg. ICP M d E H T S p C P T ^ Ceii«*iiiniiani L«Law,tt''ljo«iiflyM9tBn,H«HI(^ TypcilDttlBiwtei OompOBlle'iC.Gisb"0

TRl Number: 3-532217917-121^)8-0005 PR provldss pnttntnaty rewlb. Raipwita for imBnilnaiy TMBtts wffl (ncTMM anaiyOnl {mat*. - - J ^ — . . . . . « — , . • • . . - « ^ » . ^ . r r t » « » -MV in tu^uu iua iUu fn , nn*(nn VA.90491.3400Piuina703/264-^8F«x703/264.9222

SMpoMirtlDed7

REGION COPY F»G.1J04} P f l g s l O f l

AR100019

& P P / k ^SEPA Contract Laboratory Program Inorganic Ttafftc Report & Chain of Custody Heoord

Case No:

O A S N o :

36123

»0

o o

so

ffflglon:

Pni]«etCod«i AeuunlCode; CEBCU8 ro:

SpilllD:

StteNBfflBfStatai

PnlMdMflaK

Acttoii:

aompilnfl C«:

CT4433 2OP0TO3N3a2tX%CO3ENR8DO

VAD034S57S78

EN t v A n Cities Iron and MaiaUVA

MtPfteHeOaUessandro Removal Action Teclilaw, Inc.

Data Shipped: 12/1(M2008

CinlarNanu: FedEx AMIIh 888371540711

SMppadto: CheBfTeohConeultins Group (CHEMED) 284 Sfieffleld Street MeunlahBldeNJ 07082 {9I»8} 789-8000

Chvin Of Casfeody Reoord

Raltoqulahad By (D«tB;TiRi«}

' - t f ^ U ^ . yi>-/0V(i^<:>

^A^,.— RaoslvfittQy (Oate/Tlma)

INORGANIC SAMPLE K o .

MAINDO 8«i ima

MC0114

h a » i i 8

MC0116

MC0117

MC0118

MC0f19

MC0120

MC012-1

MC0122

SedlDianl / Gene Npnoe

SadimenV Gene Nance

Sediment/ Gene Nance

Sediment/ Gene Nance

Sui faoe Water/ Gene Nance

Sinfaoe Water / Gene Nance

Surface Water/ QtnaNanoe

SuffacaWetei/ Gene Nance

Surface Water/ Gene Nanco

cwc/ TYPE

L/G

UQ

L/Q

UQ

UG

UQ

L/0

UG

fmysB TUmWOUND

lAONoJ tt&BtilKTNBWtM

STAimi lOCAIKM

»MUOOU£Cr DAIS/rWE

ORQANIC SAMPLE NOL

OC TVpa

Me)ele(8)(14)

MatBlB^SH14)

MBial8(8H14)

Me1al»(8)(14]

MBtBlB(W)(14>

IUBlai8(W)<14]

Metals (W) (14)

Metd8(W)(14)

AA8lab(VV)<14}

esr (Ice Only) (1)

e9^{lcePn1y)t1)

70t (Joe Only) (1)

703((oeOidy)(1}

717(HN03)(1)

7 1 8 ( H N 0 3 ) { 1 )

710(HNO3).720{HNO3), 721(HN03)(3)

730{HNO3)(1)

7»(HN03){1)

6002

8D03

$004

FB-01

SW01

8WD2

SWD3

SW04

8:12^12008 10:09

8: 12AI2008 10:33

S: i2f8/2MB 11:10

S: i2maooB l i ne

S: 12/ftf200B 14:11

S: 12/9/2008 10:04

8: 12/»200S 10:22

S: 12/9/2008 10:66

8:12/S/2008 11:00

LebQC

Field Duplicate of SD03

Field Blank

LabOC

Field Duplicate o f S W 0 3

o I

-H m C-) I—

§

-a

o o

8h1pn«itforOiBa Comgitala^N

Sen.,. . . J to f t vuBadro r la to ra to j yQC:

MCQ11B, MC0120

AddWonal Sampler 8lgaatura(s);

Typi/OMjjnafe: C o T n p v ^ a C . Q r a ^ ' G

I S

AnalyatoK«y: Conoantrafloa: L -Lew.MoLowMadi i im.HaHlg i i

MetBlB (S) « H B . ICP M ^ t f a by lUH-AbS. Mfetett (VW) «• V d , V i P K i m t U M ' - m - A i t?a l-d H& R H f c . a ; c / ^ > K . ^ '

PR Number: $.532217917-121008-0003 ' PR provtdas prellmlnaiy raasttt. Raquaata f v pi«Untnaiy resalla wi l l ( p a w s t anatjflicsl oqatt. " — • " - " - " - " I - ManaiMwanJ Offlce, 2000 Edmund fHalley D r „ Reston, VA . 20191-3400 Pfcone 703/264-8348 f a x 703/284-8222 F2WHJ« P a g e 1 o f 1

AR100020

o l-»

M

ro o e

(-' OS

O

oe

o o

^B'A Ragira:

PnilactCoda;

AceountCede:

OERCUS IS:

Spin ID:

SlaNemBfStaia!

Project UBibr :

AtSoiK

SampllnsCoi

U^PA Contract Laboratory Program Inorganic nvffie Report & Chain of Custody Record

CT4433 2099T03N302DO6O03ENR80O

VADO346S7fi70

EN

Twin ClUefi Iron and U e l a W A

MIe)ie])eDties»andio Removal Aotkm

TaohLaw, ino.

iNOROANIC SAMPLE No. SMPLR TIPS

I II I I I i I »

ANM.Y8W lURNAROlMD

OateShlppadi 12/(0/2008

OatilBrHcmK FedEx 8883 7164 0798

ChemTeoh Conswltlns GJOUp(CKEMED} 284 8he l fe ld8 i ieBt Moin iatns ldeNJ070S2 (008)789-8900

C98sNo:

QASNo:

38123

Choln vS CuBtody Record

Stlppadto;

TAQNft/ mEsonAmErBoiiNa

Rallnqulal^tf 9 f (Dalai Tlma)

' . ^ , f ; t ' / 0 . <j/r4<e

Samptor SiTiatuB;

RaealvedBy (Data/Time]

STAWN LOOAHOM

SAMiUOOlIECT OAis/me

ORGANIC SAMPLE No.

QC T V P »

MC0129

MC0130

M00131

IM00132

MC0133

MC0134

MC0135

MC0136

MC0137

MC0138

MC0139

8olV8ei>lment/ OeneNpnoe

SoH^Sedlmant/ Gene Nance

SoK/Sadlmeid/ Gene l48r>oe

BoWSedltnent/ Gene Npnee

Soll/SedlmenV Gene Nance

SoD/SeiQment/ Gene Nanee

SolVSedlmenl/ Gene Nanoe

8oD/8ed9ment/ Gene N{moe

S ^ f i e d i m a n l / Gene Nanoe

SoWSedlmsnt/ GeneNpnoe

SolVSedlmwt/ Gene Nance

1X3

UG

UG

UQ

\JQ

I/O

UG

UG

UG

UO

UG

Me|alB(8»(14>

Melals (8) (14}

MBtBla{S)(14}

MetalB(S)<14)

Metals <8) (1^

MetfB(8M14)

Metals (8) (14)

Me]al8($}(14)

M8tsls(6K14}

Ma(Bte{8)(14)

Melals (B) (14)

M i l i c e O r t W u T

749 (toe Only) (1)

780 (ioe Only) (1)

762(loeOnV)(1)

7S8a>»OnV)<1)

764 aoa Only) (1)

TEW (lee Only) (1)

798 (ioe Only) (1)

7B8(loeOft^)<1>

769(lceOnty>(1)

7eg (Ice Only) (1)

8S14

S818

8816

8S17

8818

$819

8628

8831

8832

8833

8:12«/20O8

8:12/9/2008

8:12^S/200B

8: •t2/ft/2()08

8:12^/2008

S: 12^12006

6: 12/9/2008

S:12«2008

8:12ffli/200B

8: 120/2008

8: 12/9/2008

15:28

16:31

15:20

15:08

15:23

16:03

14:58

14:SZ

14:89

14:45

15:18

Ub'diC

I

¥ TA S

r s j

Sh^tn tAuCim Coniplibfr

Sampte^ltotwnaadfBrlaMnitwyCKir

MC0I29

AddHtorad Sampler SfanabraO): Cliain ef CiMtmtir Saa] Niimben

AnalyabKay;

Metals (S)<'H5, ICP

CoDWntnrflon: La Low. M - LcmMedlDm. H aHlgti

Mdiaii'byicwfcy • " — 1VP«A>e>lon<K-' Cam|»osil»<'C,Omb'>0 SblpHMntlBBd?

FR Number: 3-532217917-121003-0000 PR provldaa pTalimlnary reaiiRa, Requarte for piailmlnBiy iwuBa WIS Iwraaaa ansiyttcsl oeala. - -.-. . . . « , , . « , « « » n , « n » rtflten 3000 EttmundHaRay Dr., R w l o n . VA. 28191-3400 Pliona 703084-9348 Fax 703/284-9222 m u m Pafle1of2

AR100021

09

00

& E P A ^^^^'' ^^ntract Laboratory Program ^K^L^t^r\ inpigaiilc frafflc Report & Chain of Custody Record

CaseKo:

OASNo:

36123 K Ra^oo:

PnlaotCoila:

Account CBd«i

0ERCUaiI>i

SpWIDl

SHtNAiiMttMi:

?iip|ectLMdar.

Acdon:

Bamplino C K

CT4433 2009T03N302QCeC03ENRS0O

VAD034fi67S79

EN

T\vln Ctdet Iran and tfelal/VA

Michelle fiailMsandro Removal At l ien

TechLaiw, Inc.

Dalattilppetf! W1QQ008

CanlerName: FedEx

AHWili e6837154«799

Sh^padfo: ChemTeoh ConstilUng Group (PHEMED) 2848faeineld8tn«f MomitalnsldeNiJ 07092 (908) 789-8900

C h a i n o f C a s l o d y R e c o r d

Ral^qulaliadBy (Data/Time)

^ > ? ^ f - ^ f;>r'/<>'^f/<^<.-

SignatiBK ^ h ^ — RecelvadBy {Oate/Hm*]

o

INORGANIC SAMPLE No.

IKfRDU StMPUR

exm TYPE

ANN.Y8Sf TUMAROUW

TAeNo; naSRWIHEraottaa

BIATHN IOCAHON

suffiuoouEcr nATE/TME

ORGANIC SAMPLE No.

QC IVpa

MC0140

MO0141

MC0142

Sog/Sodlment/ Gene Nance

SoBSedinani/ Gene Nanoe

SoUSedinen)/ Gene Nanoe

UQ

UG

UQ

Metato(81(14)

Metals (8) (14)

Melals (3) (14)

761(106 Only) p )

762 (Ice Only) (1)

784 (Ice Only) (1)

8834 S: 12W2(»8 1S:6«

£839 S: 12/9/2O08 15:06

SS67 S: 12flV20aS 15:10

Field Duplicate of 8S19

Field OupRoate of S817

•v

e o r o

o

OS

o oe

StttpoiHttforCaas OampMafY

Sampltw t f i iB u u d for iationttoiy OC:

MC012S

/MdWenal SamplvSljiaalunfi): C halB of CuatMly SssI Himdur:

AnaiyaiaKayi

MelslB (8 )« No, ICP M i S T W ^ B P ^ ^

Conoentiattm: LaLow,iUI>'Lo««todIvn,K>Klah lyp^'DMlgnaie: Campo t fa 'COnboQ

TR Number: 3.532217917-121008-000$ PR oravldie DnNmloanr naauRe. Ra«uaats Air pretlnilaBir raauva WW pieiaaa»ana|y|lcal ooatt.

SMpmantlesd?

j R.PGIOW COPY

aWKIAa P a n a 4 n r 9

AR100022

U.S. EPA Region III Analytical Request Form Revision 10.06

5^/^3

ASQAB USE ONLY RAS# DAS# NSFW

CT4433 Analytical TAT

14 DAYS

Date: 11/29/08 Site Activity: Sampling Assessment

Site Name; Twin City Metal and Iron CO.INC. Street Address: 1000 Fairview Street

City: Bristol State: VA Latitude: Longitude:

Program: Superfimd Acct. #: 2009 T03N302DC6C03ENRS00 CERCLIS #: VAD034557579

Site ID: 03 EN Spill ID: Operable Unit:

Site Specific QA Plan Submitted: D N O I^Yes I Title: Sampling QA/QC Woric Plan Date Approved:

EPA Project Leader: Robert F. Kelly Phone#: 215-814-3268 Cell Phone #: 215-266-7456 E-mail: Kelly.robertj@epa,gov

Request Preparer: Gene Nance Phone#: 740-867-0968 Cell Phone #: 304-830-1442 E-mail: [email protected]

Site Leader: Michelle Dallessandro Phone#: 304-230-1230 Cell Phone #: 304-830-1444 E-mail: [email protected]

Contractor: TechLaw, Inc. EPACO/PO: Murray/Wodarczyk

^Samples 24 . ^ Matrix: soil/sediment Parameter: TAL ICP-AES Total Metals+Hg CJiG^ Method: ILM05.4 ICP-AES a ^ ' ^ g /

^Samples 5 Matrix: surface water Parameter: TAL ICP-MS Total Metals+Hg Method: ILM05.4 ICP-MS M f ^ .2-

^Samples 5 Matrix: surface water Parameter: Al, Ca, Fe, Mg, Na, K Methoi ILM05.4 ICP-AES vf!?-> #Samples ^, Matrix: Water (QC-rinsate) Parameter: TAL ICP-AES Total Metals+Hg Method: ILM05.4 ICP-AES

^Samples 10 Matrix: soil/sedimetit Parameter: PCBs (Aroclors) mAsh Method: SOMO 1.2 - r i V£i_

^Samples 5 Matrix: surface water Parameter: PCBs (Aroclors) Method SOMO 1.2 " . '1^1^^^ '

^Samples Matrix: Parameter: Method:

/^Samples Matrix: Parameter: Method:

^Samples Matrix: Parameter: Method:

Ship Date From: December 10,2008 Ship Date To: December 11,2008 Org. Validation Level M3 Inorg. Validation Level IM2

Unvalidated Data Requested: D No | ^ Yes If Yes, TAT Needed: ^ 14days D 7days D 72hrs D 48hrs D 24hr5 D Other (Specify) J ^ ^ . ^ j ^ / j J

^ Validated Data Package Due: Q 42 days IS! 30 days Q 21days D 14 days Q Other (Specify)

Electronic Data Deliverables Required: Q No I 3 Yes (EDDs will be provided in Region 3 EDD Format)

Special Instructions: Surface vfater samples for TAL ICP-MS metals and Al, Ca, Fe, Mg, Na, K analyses will be collected in one sample bottle under the assumption that they will be assigned to the same laboratory. TAL for ICP-MS metals and ICP-AES metals and TCL for PCB (Aroclors) are attached. Quality Assurance Project Plan (QAPP) For START Sampling Activities Submitted To U S EPA Region III.

AR100023

mailto:[email protected]


"Dallessandro, Michelle" To Judy Snyder/ESC/R3/USEPA/US@EPA <Mdallessandro@TechLawln ..,, ^ „ „ „ _ ^. c.com> ' Nance, Gene <[email protected]>

01/08/200911:12 AM ^ ' ^ Subject FW: duplicate pairs for Twin Cities Iron and Metal Site case

number 38123

History: i ^ jh is message has been fonwarded.

sorry, forgot the blank:

C0118 and MC0118

lab QC (MS/MSD):

C0120 MC0115 MC0120 MC0123 C0H5 CO 12 9 MC0129

Michelle Dallessandro, Project Manager 131 Peninsula Street, Suite B Wheeling, WV 25003 (304) 830-1444 (mobile) (304) 230-1230 (office) (304) 232-5006 (fax) mdallessandro®techlawinc.com

From: Dallessandro, Michelle Sent: Thu 08-Jan-09 11:04 To: snyder.j udy®epamai1.epa.gov Cc: Nance, Gene Subject: duplicate pairs for Twin Cities Iron and Metal Site case number 38123

C0121/C0122 (SURFACE WATER) MC0116/MC0117 (SEDIMENT) MC0121/MC0122 (SURFACE WATER) C0116/C0117 (SEDIMENT) C0132/C0142 (SOIL/SEDIMENT) MC0132/MC0132 (SOIL/SEDIMENT) MC0134/MC0141 (SOIL/SEDIMENT)

Michelle Dallessandro, Project Manager 131 Peninsula Street, Suite B Wheeling, WV 26003 (304) 830-1444 (mobile) (304) 230-1230 (office) (304) 232-5006 (fax) mdallessandro®techlawinc.com

AR100024


'Dallessandro, Michelle' To Judy Snyder/ESC/R3/USEPA/US@EPA <Mdalless8ndro@TechLawln ,^, ^ . ^ ^ .^ ,_, CQQ,„» cc Nance, Gene" <[email protected]>

01/08/200911:04 AM ^ ^ Subject duplicate pairs for Twin Cities Iron and Metal Site case

number 38123

History: i ^ jh is message has been forwarded.

C0121/C0122 (SURFACE WATER) MC0116/MC0117 (SEDIMENT) MC0121/MC0122 (SURFACE WATER) C0116/C0117 (SEDIMENT) C0132/C0142 (SOIL/SEDIMENT) MC0132/MC0132 (SOIL/SEDIMENT) MC0134/MC0141 (SOIL/SEDIMENT)

Michelle Dallessandro, Project Manager 131 Peninsula Street, Suite B Wheeling, WV 26003 (304) 830-1444 (mobile) (304) 230-1230 (office) (304) 232-5006 (fcuc) mdallessandroQtechlawinc.com

AR100025


i-abo

Appendix D

AR100026

SDG MCOl 14

AR100027

USEPA - CLP

COVER PAGE

Lab Name CHEMTECH CONSULTING GROUP Contract: EPW08065

Lab Code: CHEM Case No.: 38123 NRASNo.:

SOW No.: ILM05.4

EPA Sample No.

MC0114 MCOl 15 MCOl 16 MCOl 17 MC0127 MC0128 MCOl 29 MC0129D MC0129S MC0130 MC0131 MC0132 MCOl 33 MC0134 MC0135 MCOl 36 MC0137 MC0138 MC0139 MC0140 MC0141 MC0142

Were ICP-AES and ICP-MS interelement corrections ^plied?

Were ICP-AES and ICP-MS background corrections applied? If yes, were raw data generated before application of background corrections?

SDG No.: MCOl 14

Lab Sample ID

Z5830-17 Z5830-18 Z5830-19 Z5830-20 Z5830-21 Z5830-22 Z5830-O1 Z5830-02 Z5830-03 Z5830-04 Z5830-05 Z5830-06 Z5830-07 Z5830-08 Z5830-09 Z5830-10 Z5830-11 Z5830-12 Z5830-13 Z5830-14 Z5830-I5 Z5830-16

ICP-AES ICP-MS

(Yes/No) YES

(Yes/No) YES

(Yes/No) NO

Lx>mmeius: THE "E" QUALIFIERS ON FORM I AND VIII FOR ALUMINUM. CHROMIUM,COBALT. COPPER. LEAD. NICKEL AND ZINC INDICATE CHEMICAL OR PHYSICAL INTERFERENCE EFFECTS. WHICH WERE SUSPECTED DURING THOSE ELEMENTS'

I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in diis hardcopy data package and in the computer-readable data submitted on diskette (or via an alternate means of electronic transmission, if approved in advance by IJSEPA) has been authorized by the Laboratory Manager or Ae Manager's designee, as verified by ttie following signature.

Signature:

Date:

Name: PARVEEN HASAN

Title: EPA PROJECT MANAGER

COVER PAGE ILM05.4

AR100028

CHEMTECH 284 Sheffield Street Mountainside, NJ 07092

SDG NARRATIVE

USEPA SDG#MC0114 CASE # 38123 CONTRACT # EPW08065 LAB NAME: CHEMTECH CONSULTING GROUP LAB CODE: CHEM CHEMTECH PROJECT #Z5830

A. Number of Samples and Date of Receipt

20 Soil Samples were delivered to the laboratory intact on 12/11/08, 12/11/08& 12/11/08.

B. Parameters

Test requested for ICP Metals CLP Full (by ICP-AES) & Hg.

C. Cooler Temp

Indicator Bottle: Presence/Absence Cooler: S^C, 3''C & 4°C.

D. Detail Documentation (related to Sample Handling Shipping, Analytical Problem, Temp of Cooler etc):

E. Corrective Action taken for above:

F. Analytical Techniques:

All analyses were based on CLP Methodology by method ILM05.4

AR100029


G. Calculation:

Calculation example for ICP-AES Soil Sample:

Conversion of Results from mg/L or ppm to mg/kg (Dry Weight Basis):

Results reported in Mg/Kg = (Result in mg/L or ppm for ICP-AES) X 1000 X Fraction of % Solid (100/ % Solid) X Dilution Factor (if any) X Fraction of Sample Amount Taken in ICP-Soil Prep.

Example of Fraction of Sample Amount Taken in ICP-AES Soil Prep = 1/10 (1.0 XIO or 0.50 X 20) (if 1.0 g of sample taken during Digestion and the Final Volume was made to 100 ml or 0.5 g to

Final Volume 50ml)

Or

Example of Fraction of Sample Amount Taken in ICP-AES Soil Prep = 1/10.2 (1.02 X 10 or 0.51X20) (if 1.02 g of sample taken during Digestion and the Final Volume was made to 100 ml or 0.51 g

to Final Volume 50ml)

Etc.

Calculation example for Hg Soil Sample:

Conversion of Results from ppb to mg/kg (Dry Weight Basis):

Results reported in Mg/Kg = (Result in ppb for Hg) X Fraction of % Solid (100/ % Solid) X Dilution Factor (if any) X Fraction of Sample Amount Taken in Prep.

Example of Fraction of Sample Amount Taken in Hg Soil Prep =1 /2 (0.2 X 10) (if 0.2 g of sample taken during Digestion and the Fmal Volume was made to 100 ml)

Or

Example of Fraction of Sample Amount Taken in Hg Soil Prep =1 /2 .1 (0.21 X 10) (if 0.21 g of sample taken during Digestion and the Final Volume was made to 100 ml)

Etc.

AR100030


H. QA/QC

Calibrations met requirements. Interference check met requirements. Blank analyses did not indicate any presence of contamination. Laboratory Control sample was writhin control limits. Spike sample did meet requirements except for the Silver. Duplicate sample did meet requirements. Serial Dilutioo did meet requirements except for the Aluminum, Chix)niium, Cobalt, Copper, Lead, Nickel & Zinc.

1 certify that the data package is in compliance v^th the terms and conditions of the contract both technically and for completeness, for other than tiie conditions detailed above. Release of the data contained in this hard copy data package has been audiorized by the Laboratory Director or his designee, as verified by the following signature.

Name: Parveen Hasan

Title: Project Manager

AR100031

CHEMTECH

QC: \jg>42iO<S7 PERCENT SOLIDS

:^5"^30

25830-01 Z5830-02 Z5830-03 Z5830-04 Z6830-05 Z5830-06 Z5830-07 Z5830-08 Z5630-09 Z5830.10 Z5830-11 Z583G-12 Z5830-13 Z5830-14 Z5830-15 Z5830-16 Z5830-17 Z5830-18 Z5830-19 Z5830-20 Z5830-21 Z5830-22 BLANK BLANK

MC0129 MC0129D MC0129S MC0130 MC0131 MC0132 iWC0133 MC0134 MC0135 MCOl 36 MC0137 MC0138 WIC0139 MC0140 W1C0141 MC0142 MCOl 14 MC0115 MC0116 MC0117 MC0127 MC0128 DISH DISH

10 11 12 13 14 16 16 17 18 19 20 21

1.19 1.17

NR 1.17 1.17 1.2

1.16 1.18 1.18 1.18 1.17 1.17 1.17 1.17 1.18 1.17 1.18 1.18 1.16

8.84 8.7

NR 8.9

8.62 9,01 8.88 8.93

8.83 8.73

NR

8.82 8.94 9.04 8.86 8.84

8.61

1.19

22 81 82

1.18 1.18 1.17 1.18

8.96 8.94 8.81 1.17 1.18

7.34 718

6.36 6.21 7.88 6.96 6.08 6.08 7.2

6.42

NR

6.76 8.16 5.88 7.85

6.49 7.69 8.02 5.69 7,12 1.17 1.18

80.4 79.9

67.2 67.7 86.6 75.2 63.3 63.0 78.7 69.5 62.9 72.0 63.5 61.2 87,1 74,5 71.5 87.1 88.0 58.2 77.9 0.0 0,0

DATE; \ 2 . ANALYST;

to OVEN TEMP: 1 ^ y ^ ^

TIME IN: t2. |J7/oR ^ ^Bo iM TIME GUTUSSpSl'^' ^ * ^^

AR100032

SDG MCOl 18

AR100033

USEPA - CLP

COVER PAGE

Lab Name CHEMTECH CONSULTING GROUP Contract: EPW08065

Lab Code: CHEM Case No.: 38123 NRASNo.:

SOW No.: ILM05.4

EPA Sample No.

MCOl 18 MCOl 23 MC0123D MC0123S MCOl 24 MC0I25 MCOl 26

SDG No.: MCOl 18

Lab Sample ID

Z5831-07 Z5831-01 Z5831-02 Z5831-03 Z5831-04 Z5831-05 Z5831-06

(Yes/No)

(Yes/No)

(Yes/No)

ICP-AES

YES

YES

NO

ICP-MS

Were ICP-AES and ICP-MS interelement corrections applied?

Were ICP-AES and ICP-MS background corrections applied? If yes, were raw data generated before application of background corrections?

Comments: THE "E" QUALIFIERS ON FORM I AND VIII FOR ALUMINUM. COBALT. COPPER. LEAD AND ZINC INDICATE CHEMICAL OR PHYSICAL INTERFERENCE EFFECTS. WHICH WERE SUSPECTED DURING THOSE ELEMENTS' ANALYSES ONLY.

I certitS' that this data package is in compliance with the terms and co iditions of the contract both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package and in the computer-readable data submitted on diskette (or via an altemate means of electronic transmission, if approved in advance by USEPA) has been authorized by the Laboratory Manager or the Manager's designee, as verified by the following signature.

Signature:

Date:

Name: PARVEEN HASAN

Title: EPA PROJECT MANAGER

COVER PAGE ILM05.4

AR100034


SDG NARRATIVE

USEPA SDG # MCOl 1 8 CASE # 38123 CONTRACT # EPW08065 LAB NAME: CHEMTECH CONSULTING GROUP LAB CODE: CHEM CHEMTECH PROJECT #Z5831

A. Number of Samples and Date of Receipt

04 Soil & 01 Water Samples were delivered to the laboratory intact on 12/11/08 & 12/11/08.

B. Parameters

Test requested for ICP Metals CLP Full (by ICP-AES) & Hg.

C. Cooler Temp

Indicator Bottle: Presence/Absence Cooler: 4°C & 3°C

D. Detail Documentation (related to Sample Handling Shipping, Analytical Problem, Temp of Cooler etc):

Issue 1: Samples MCOl 15, -123, and -129 are designated as laboratorj- QC on the TR/COC for the 24 soil samples received on 12/10/08. The laboratorj' would like to select samples MC0123 and MC0129 as laboratory QC and disregard sample MCO115 as laboratory QC.

Issue 2: The laboratory received 5 water samples on 12/10/08 that list the sample matrix as Surface Water and lists the analyses as ICP-AES (Al, Ca, Fe, Mg, K, Na) and ICP-MS Metals/Hg; however, sample MCOl 18 has a station location of FB-01. which the laboratory believes is a field blank sample. The Case is scheduled for five water samples for ICP-AES (Al, Ca, Fe, Mg. K., Na) and ICP-MS Metals/Hg analysis and one water sample for ICP-AES TM/Hg analysis. The laboratorj' would like to confirm tliat sample MCOl 18 is a field blank sample and should only perform the ICP-AES TM/Hg analysis instead of the ICP-AES (Al, Ca, Fe, Mg, K. Na) and ICP-MS Metals/Hg analysis.

AR100035


E. Corrective Action taken for above:

Resolution 1: In accordance with previous direction fi-om Region 3, the laboratory will select one of the designated samples per matrix for laboratory QC. The laboratory will note the issue in the Case/SDG Narrative, notify the SMO coordinator of the sample selected for laboratory QC, and proceed with the analysis of the sjimples.

Resolution 2: Per Region 3, the laboratory's proposed actions are acceptable. Sample MCOl 18 is a field blank sample and the laboratory should perform the requested ICP-AES TM/Hg analysis on the sample. The laboratory will note the issue in the Case/SDG Narrative and proceed with the analysis of the samples.

F. Analytical Techniques:

All analyses were based on CLP Methodology by method ILM05.4

G. Calculation:

Calculation example fo r ICP-AES Soil Sample:

Conversion of Results from mg/L or ppm to mgilcg (Drj' Weight Basis):

Results reported in Mg,/Kg = (Result in mg/L or ppm for ICP-AES) X 1000 X Fraction of % Solid (100/ % Solid) X Dilution Factor (if any) X Fraction of Sample Amount Taken in ICP-Soil Prep.

Example of Fraction of Sample Amount Taken in ICP-AES Soil Prep = 1/10 (1.0 XIO or 0.50 X 20) ' (if 1.0 g of sample taken during Digestion and the Final Volume was made to 100 ml or 0.5 g to

Final Volume 50ml)

Or

Example of Fraction of Sample Amount Taken in ICP-AES Soil Prep = 1/10.2 (1.02 X 10 or 0 .51X20) (if 1.02 g of sample taken during Digestion and the Final Volume was made to 100 ml or 0.51 g

to Final Volume 50ml)

Etc..

AR100036


Calcitlation example for ICP-AES Water Sample:

Results reported in Ug/L = Results in ppm X 1000 X Dilution Factor (if any) X Fraction of Sample Amount Taken in ICP Water- Prep

Fraction of Sample Amount Taken in ICP Water- Prep = 100/100 or 50/50 =1 (if 100 ml Initial Volume taken and Final Volume was made to 100 ml or 50 ml Initial Volume and Final Volume made to 50 ml in ICP-AES Water Digestion procedure)

Calculation example for Hg Soil Sample:

Conversion of Results from ppb to mg/kg (Dry Weight Basis):

Results reported in Mg/Kg = (Result in ppb for Hg) X Fraction of % Solid (100/ % Solid) X Dilution Factor (if any) X Fraction of Sample Amount Taken in Prep.

Example of Fraction of Sample Amount Taken in Hg Soil Prep = 1 / 2 (0.2 X 10) (if 0.2 g of sample taken during Digestion and the Final Volume was made to 100 ml)

Or

Example of Fraction of Sample Amount Taken in Hg Soil Prep = 1 / 2 . 1 (0.21 X 10) (if 0.21 g of sample taken during Digestion and the Final Volume was made to 100 ml)

Etc.

Calculation example for Hg Water Sanyfle:

Results reported in Ug/L = Results in ppb X Dilution Factor (if any) X Fraction of Sample Amount Taken in Water Hg-Prep.

Fraaion of Sample Amount Taken in Water Hg-Prep = 100/100 =1 (if 100 nil Initial Volume taken and made it to Final Volume as 100 ml)

AR100037


H. QA/ QC

Calibrations met requirements. Interference check met requirements. Blank analyses did not indicate any presence of contamination. Laboratory Control sample was within control limits. Spike sample did meet requirements except for the Silver. Duplicate sample did meet requirements. Serial Dilution did meet requirements except for the Aluminum, Cobalt, Copper, Lead & Zinc.

I certify that the data package is in compliance with the tenns and conditions of the contract both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratorj' Director or his designee, as verified by the following signature.

Name: Parveen Hasan

Title: Project Manager

AR100038

CHEMTECH

QC: U g > 4 a o ^ 7 >.!.•• . • I . J ' J J . i l l . 1 , l | . . i . W ... . 1 . . .

PERCENT SOLIDS ANALYST:.

z^^^ i DATE:4:aJi5ic5 ' ' " V "

W

Z5831-01 Z5831-02 Z5831-03 25831-04 Z5831-06 Z5831.06 BLANK

MCOl 23 MC0123D MC0123S MC0124 MC0125 MC0126 DISH 81

1.17 1.19

NR 1.18 1.19 1.18 1.17

8.86 9.03

NR 9.06 8.82 8.67 1.17

6.85 7.04

NR 6.66 6.28 6:06 1.17

'%^MM

73.9 74.7

NR 68.3 66.8 65.2

0.0

CO

o

OVEN TEMP TIMEIN:__UJ

\OUO

TIMEOUT; t X f e b ^ 7/0F9:

6^ 12(D^M

AR100039

Snehal Mehta

From: Walsh, Colin [[email protected]] Sent: Thursday. December 18, 2008 8:28 AM To: Snehal Mehta Cc: parveen; [email protected]; [email protected]; [email protected];

[email protected] Subject: Region 03 | Case 38123 | Lab CHEM | Issue Documentation j FINAL Attachments: Case-38123-SoilandWater.pdf

Snehal,

***Summary Start*** -Insufficient/inappropriate designation of laboratory QC-Issue 1: Samples MC0115, -123, and -129 are designated as laboratory QC on the TR/COC for the 24 soil samples received on 12/10/08. The laboratory would like to select samples MC0123 and MC0129 as laboratory QC and disregard sample MC0115 as laboratory QC. Resolution 1: In accordance with previous direction from Region 3, the laboratory will select one of the designated samples per matrix for laboratory QC. The laboratory will note the issue in the Case/SDG Narrative, notify the SMO coordinator of the sample selected for laboratory QC, and proceed with the analysis of the samples. SMO will note that the laboratory selected samples MC0123 and MC0129 as laboratory QC and disregarded sample MC0115 as laboratory QC.

-Discrepancies with tags, jars, and/or TR/COC-Issue 2: The laboratory received 5 water samples on 12/10/08 that list the sample matrix as Surface Water and lists the analyses as ICP-AES (Al, Ca, Fe, Mg, K, Na) and ICP-MS Metals/Hg; however, sample MC0118 has a station location of FB-01, which the laboratory believes is a field blank sample. The Case is scheduled for five water samples for ICP-AES (Al, Ca, Fe, Mg, K, Na) and ICP-MS Metals/Hg analysis and one water sample for ICP-AES TM/Hg analysis. The laboratory would like to confirm that sample MC0118 is a field blank sample and should only perform the ICP-AES TM/Hg analysis instead of the ICP-AES (Al, Ca, Fe, Mg, K, Na) and ICP-MS Metals/Hg analysis. Resolution 2: Per Region 3, the laboratory's proposed actions are acceptable. Sample MC0118 is a field blank sample and the laboratory should perform the requested ICP-AES TM/Hg analysis on the sample. The laboratory will note the issue in the Case/SDG Narrative and proceed with the analysis of the samples. ***Summary End***

Please let me know if you have any further questions or problems.

Thanks,

Colin

Col in G. Walsh Environmental Coordinator - Region 3 CSC

15800 Conference Center Drive^ Chanti.ilyj VA 29151 Civil Division | (p) 703-818-4544 | (f) 703-818-4602 | [email protected] | www.csc.com

Original Message From: Slizys.Dan|aepamail.epa.gov [mailto:[email protected]] Sent: Thursday, December 18, 2008 8:21 /\M To: Walsh, Colin

236 AR100040







http://www.csc.com


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