vapor-liquid equilibrium data collection · c4h11n d i eth ylam i ne c6h6 ben le ne c6h14 hhane...

J. Gmehling

U. Onken

W. Arlt

VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION

Aliphatic Hydrocarbons

c4-c6

Chemistry Data Series

Vol. I, Part 6a

Published by DECHEMA Deutsche Gesellschaft fur Chemisches Apparatewesen

Editors: Dieter Behrens, Reiner Eckermann

' ,,

Vapor-Liquid Equilibrium Data Collection

6a


C4-Ce

Tables and diagrams of data for binary and

multicomponent mixtures up to moderate pressures.

Constants of correlation equations for computer use.

J. Gmehling, U. Onken, W. Arlt

Lehrstuhl Technische Chemie 8 (Prof. Dr. U. Onken)

Universitat Dortmund

© 1980 DECHEMA Deutsche Gesellschaft fiir Chemisches Apparatewesen

6000 FrankfurtiMain, Federal Republic of Germany

ISBN 3-921 567-30-0

All rights reserved

No part of this work may be reproduced or used in any form or by any means - graphic, electronic, or mechanical, including photocopying, recording, or taping, or information storage and retrieval systems·- without written permission of the publishers.

Printed by Schon & Wetzel GmbH, Frankfurt/Main, F. R. Germany

·' '

6a


C4-Cs

1 ,3-Butadiene

Butane

i-Butene

1-Butene

Cyclohexane

Cyclohexene

Cyclopentadiene

Cyclopentane

2,2-Dimethylbutane

2,3-Dimethylbutane

Hexane

1-Hexene

Isoprene

Systems with:

2-Methylbutane

2-Methyl-1-butene

2-Methyl-2-butene

Methylcyclopentane

2-Methylpentane

3-Methylpentane

2-Methyl-1-pentene

4-Methyl-1-pentene

Neopentane

trans-1 ,3-Pentadiene

Pentane

1-Pentene

Vinyl acetylene

VI

SUBJECTS OF VOLUME I

The table lists the parts of Volume I already publ'ished or being in preparation.

Subtitle Vol. I, Part

Aqueous-Organic Systems 1 published Supplement 1 1a in prep.

Organic Hydroxy Compounds Alcohols 2a published Alcohols and Phenols 2b published Supplement 1 2c ,in prep.

Aldehydes, Ketones, Ethers 3/4 published

Esters and Carboxylic Acids 5 in prep.

Aliphati.c Hydrocarbons 6a published 6b published

Aromatic Hydrocarbons 7 in prep.

Halogen, Nitrogen, Sulfur and other Compounds

I 8 in prep.

VII

AUTHORS' PREFACE

Continuing the publication of our Vapor-Liquid Equilibrium Data Collection we are presenting Part 6, subdivided into Parts 6a and 6b. Completion of Part 5 has been postponed, because in correlating systems containing carboxylic acids we also intend to include vapor phase non-ideality for more than one associating component in a system; programming of this calculation procedure has not yet been finished.

From Part 5 onwards, parameters of activity coefficient equations are also given for "incomplete" x-y data (isothermal without P, resp. isobaric without T). In these cases, equilibrium ratios y/x have been used in the objective function for parameter optimization. A further additional information in the tables from Part 5 onwards concerns incomplete isothermal x-y data; here the result of the consistency test by method 2 (area test of Redlich and Kister) is given.

We again express our thanks to the great number of colleagues who have supported our efforts by supplying VLE data from their laboratories. On this occasion we should like to repeat our plea to all workers in the field of vapor-liquid equilibrium to send us reprints of new experimental results.

·

Special thanks are due to Dipi.-Phys. G. Schwichtenberg, head of the computer center of the University of Dortmund, and to his staff, especially to H. Forster and U. Liebegut, for their co-operation. We are also grateful to Dr. R. Eckermann (DECHEMA, Frankfurt/M.) for his efforts in editing the data collection.

Finally, we wish to thank all members of our team who helped in the preparation of Part 6 of the VLE Data Collection; these are: Mrs. U. Arlt, Dipl.-lng. P. Grenzheuser, Miss G. Hennig, W. Kirchhoff, Dipl.-lng. B. Kolbe, Mrs. S. Koort, Mrs. L. Kunzner, Dr. G. Nocon.

Dortmund, January 1980

Ulfert On ken Ji.irgen Gmehling Wolfgang Arlt

VIII

PREFACE OF EDITORS

Subjects of this series are the physical and thermodynamic property data of chemical compounds and mixtures essentially for the fluid state covering PVT data, heat capacity, enthalpy, and entropy data, phase equilibrium data, transport and interfacial tension data.

The main purpose is to prov·ide chemists and engineers with data for process design and development. For computer based calculations in process design appropriate correlation methods and accurate data must be used. These are only in some cases available in the open literature. For that reason the most urgent requirement regard!ing the publication of data is to offer classified and critically evaluated data, thus giving an impression which of them are reliable or not. This will be the goal of the series.

DECHEMA gives the opportun:ity to authors especially from universities to

publish not only their theoretical results, but also their measured or compiled data, most often a large amount, that would otherwise never have been published.

The work of Dr. Gmehling, Prof. Onken and Dipi.-Chem. Arlt on vapor-liquid equilib�ia which was supported by the Federal Ministry of Research and Technology and DECHEMA has been very fruitful; in particular, it led to an extension of the UNIFAC method, The authors have produced what is probably the largest collection of vapor-liquid equil.ibrium data that is today available with evaluation programs and experimental data.

We present the evaluation of this material in several parts of the first volume of the series. We hope that this gives particularly the users an instrument that will allow them to solve their problems considerably more easily and quickly than before.

Frankfurt/Main, January 1980 Dieter Behrens Reiner Eckermann

Subjects of Volume I

CONTENTS Vol. I, Part 6a

IX

VI

Authors' Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . VII

Preface of Editors . . . . . . . • . . . . . • . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . VIII

Contents Volume I, Part 6a . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . IX

Contents Volume I, Part 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XI

Contents Volume I, Part 2a . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XII

Contents Volume I, Part 2b . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XIII

Contents Volume I, Parts 3+4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XV

Guide to Tables . . . . . . • . • . . . . . . • • • . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XVII

List of Symbols .................................................. XXVII

References . . . . . . . . . . . . . . . • . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XXIX

Data Tables

Binary Systems ............................................. .

Vinylacetylene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . • . . .

1 ,3-Butadiene . . . . . . . . . • . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

1-Butene ................................................. .

lsobutene

Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Cyclopentadiene ......................................... .

Isoprene ................................................. .

trans-1 ,3-Pentadiene . . . . . . . . . . • . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Cyclopentane . . . . . . . • . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

2-Methyl-1-butene ......................................... .

2-Methyl-2-butene ......................................... .

1-Pentene ............................................... .

2-Methylbutane ........................................... .

Neopentane

1

1

1

3

17

18

19

36

38 57

60

77

79

85

86

90

Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100

Cyclohexene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 128

Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139

1-Hexene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 340

Methylcyclopentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 361

2-Methyl-1-pentene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 376

4-Methyl-1-pentene

2,2-Dimethylbutane

378

381

X

2,3-Dimethylbutane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 387

Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 398

2-Methylpentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 619 3-Methylpentane

Ternary Systems ................................ . ............ .

Cyclopentadiene

Isoprene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Cyclohexene ............................................. .

Cyclohexane ............................................. .

1-Hexene ...................................... . .......... .

Methylcyclopentane ....................................... .

Hexane

626

631

631

632

634

636

651

652

659

Appendix A: Pure Component Parameters ......................... . 667

Formula Index of Systems ....................................... .

Alphabetical Index of Systems ................................... .

673

681

1ST COf\PON£ NT

C4H 4

C4H6

C4H8

C4�8

673

Formula Index of Systems

R=RECOMMENDED VALUES

2ND COMPONENT

V INYLACETY LE N F

C6Hb BENZENE

C8H1t P•XYLENE

1,3-BUTADIEN£.

CCL4 TETRACHLOROMlTHANE

CH2CL2 DICHLOROM ETHANE

CH3N02 NITROMETHANE

CS 2 CARBON DIS ULFIDE

C4H5CL 2-CHLOR0-1,3-BUTAOIENE

C4H8 1-BUTENE

C4H18 BUTANE

C6H6 BENZENE

C8H8 S TYRENE

1-BUTENE

C4H1e B UTANf.

I S OBUTENE

CSHS ISOPRENE

BUTANE

CHSN METHYLAMINE

C2H5Cl E THYL CHLORIDE

C2H5D2N N·DEUTEROETHY LAI· IN E

C2H7N ETHYLAMINE

C4F8 PERFLUOROCYCLOBUTANE

C5H1? PENTANE

HEX ANE

3RO COMPONENT 4TH COHPONE�T

PAGE

6

8• 10 1t

11- 13

14

15- 16

17

is

19- 2f

2 2

23- 27

28

29

31- 35 = ====:===�=======�========c== ===�===============c================ =========== =========== ==================

'

CS� 6 CYCLOPENTADIENE

C5HS IS OPRENE 36

C5H11 2-�ET HYL-2-BUTENf 631

CSH 10 2-METHYL-2 -BUTlH 3 7

C51i8 I S OPRENE

CH3N(l2 NITROMETHANE 38

C2H3N A CETON ITR !lE 39- 4e

C5H1t 2 -METHYL- 2-SUTENf 632-633

674


C%8

CSH 8

C5H1�

C5H1�

C5H1�

C5H1�

CSH12

C 2H 60S

C3H7NO

C5H8

C5H10

C5H1e

C5H1t

C 5H 12

C2H60S

CCl4

CHCl3

CS2

C2CL4

C3H8S

C6H6

C6H 14

C 10H 18

C1eH18

CH3N02

C5H1t

CH3N02

C2H3N

ISOPRENE

DIM ET HVLSU lf OXIDE

N,N-DIMETHYLFORMAHIDE

TR-1,3-PENTAOI�NE

2-HETHY L-1 -BUTENE

2-HETHYL-2-BUTENE

3-METHY L-1-BUTENE

2-METHYLBUTANE

TR-1,3-PENTAOI�NE

OIMETHYLSUlfOXIOE

CYClOPENTANE

TETRACHLOROMETHANE

CHLOROFORM

CARBON DISULFIOE

TETRACHLOROETHYlENE

2-PROPANETHIOl

BENZENE

2,3-DIMETHYLBUTANE

CIS-DECAHYORONAPHTHALENE

THA-DECAHYORONAPHTHAL ENE

2-HETHYL-1-BUTENE

NITROMETHANE

2-HETHYL-2-BUTENE

2-METHYL-2-BUTENE

NITROMETHANE

ACE TON ITR ILE

41- 4 3

44

45

46- 47

48- 53

54- 55

56

57- 59

6e- 61

62

63- 66 6�

67

68

69- 73

75

76

71

78

19

81- 82

C3H7NO N,N-DIMETHYLFOR�AMIDE 83 -------------------------------- ---------------------------------------------------------C5H1 2 2-HETHY LBUTANE 84

1-P ENTENE

C2H 3N ACETONITR !LE 85

2-METHY LBUTANE

CS2 CARBON DISULFIOE 86-87

C2H 3N ACETONITRILE 88

C3H7NO N,N-DIMETH YLFDR�AMIOE 89

C5H1? NE OPE NTANE

C4H12SI TETRAMETHYLSILANE

C5H1 2 PENTANE

C5H17. PENTANE

CH?.CL2 D I CHLOROMETHANE

C2H3N A C ETON IT RILE

C3H3N ACRYLONITRILE

C 3H8S 1-PROPANETHIOL

C5H11BP PENTYL BROMIDE

C6H6 B ENZENE

C6H12 C YC LOHEXANE

METHYL CY CLOPlNTANE

C6H14 H EXAN E

C7H14 METHY LCY CL OHlXANE

C7H 1 6 J!EPTANE

C6HH CY CLOHEXEN E

C CL4 TETRA CHLOROMETHANE

C2H4CL7. 1,2-D I C HLOROETHANE

C6H6 BENZENE ·

C6H12 CYCLOHEXANE

C6H12 CY CLOHEXANE

CCL4 TETR A CHLOROMETHANE

CHCLF2 CHLORODIFLUOROMETHANE

C H3N02 N ITROMETHANE

CS2 CARBON DISULFIDE

C2 HCL3 TRI CHLOROETHYLENE

C2HCL 5 PENTA CHLO�OETHANE

C2H4 BR 2 1,2-DIBROMOETHANE

C2H4CL 2 1,2-DI C HLOROETHANE

C 2H 5NO N _,.ET HYLFORMAI< I DE

C3H3NS TH IAZOLE

C4H4S THIOPHENE

C4H9N PYRROLI DINE

C�H 5N PYRIDINE

675


9t- 94

95- 99

1U

1e1-H2

115

116-113

114-118

119

12t-121

122-123

124-125

126-127

128

129

C6H1Z CYC LOHEX ANE 634-635

C6H6 BENZENE

C6H6 BENZENl

13t-136 136

137-138

139-15t 15t

151-152

636

153-154

155

637-638

157

158-163 16 3 R

164-165

166

167

168-17f 17t

171-182

676


C6�12

C6H1?

C 5H 11 N

CM6

CY CLOHEXANE

PIPERIDINE

HEXAFLUOROBENZENE

1�3-185

185

186-191

1 91 R

=��-------�=��=��:�:��:--------------------------------------------------��=��= C6H5RR BROHOBENZENE 196-211

C6H5 CL CHLOROBENZEN(

C6H5N02 NITROBENZENE

C6H6 BENZENE

C6H7N ANILINE

C6H11CL CHLOROCYCLOHEXANE

C6H1? HETHYL C Y CLOPENTANE

C 6H1 3N CYCLOHEXYLA�INE

C6H13N HEXA�ETHYL ENEIHINE

C6H 14 DIHETHY LBUTANE

C 6H14 HEX AN E

C7HA TOLUENE

C7H9N HETHYLANILINE

C7H14 HETHYLCY CLOHEXANE

C7H 15N N-HETHYL CY CLOHEXYLAMINE

C7H16 HEPTANE

C7H16 TRIHElHYLBUTANE

C8HH ETHYLBENZENE

C8HH 0-XYLENE

M-XYLENE

C8HH P-XYLENE

C8H16 1-0CTENE

C �H18 O CTANE

C8H18 2,2,4-TRIHETHYLPENTANE

C12H?6 DODE CANE

C 16H34 HEXADE CANE

c ?eH42 EI COUNE

1-HEXENE

C CL4 TETRACHLOROMETHANE

C6H7N ANI LINE

C6 H14 HEXANE

C7H8 TOLUENE

C7H16 HEPTANE

212

2f3

214-241 l4t-2 41

639

6 41-647

6 48

242-257 257

258-261

262

26 3-2 69

271-271

272

273-277 277 R

278-291

6 49-651

292-29 4

295

296-299 299

3U-316 3t6

3t7

H8-31t

3 1 1-3 12

. 313-314

315-318_

31 9

321-323

324-329 329

334-336

337-339

C6H1? 1-HEXENE

C 2CL � T ETRACHLOROETHYLENE

C2HCL3 TRICHLOROETHY L E NE

C2H2 CL4 1,1,2,2-TETRACHLOROET�ANE

C2H3CL3 1,1,1-TRICHLOROfTHANE

C2H3CL3 1,1,2-TRICHlOROETHANE

C3�5 CL3 1,2,3-TRICHLOROPROPANE

C3H7BR PROPY l BROM I Of

C4H11N BUTYLAMINE

C4H11N D I ETH YlAM I NE

C6H6 BEN lE NE

C6H1 4 HHANE

C6H15N DIISDPROPYLAMINE

C6H15N OIPROPYLAMINE

C6H 15N HEX YL AMINE

C6H15N TRIETHYLAMINE

C7H8 TOLUENE

C6H12 HETHYLCYClOPENTANE

CCl4 TETRACHLOROHETHANE

C3H8S 1-PROPANETHIO L

C6H6 BENZENE

C6H14 HEX AN E

C7H8 TOLUENE

C6H1? 2-METHYl-1-PENTENE

C 6 H6 BENZENE

C6H12 4-METHYL-1-PENTENE

C6H6 BENZENE

C6H11.. 2 ,2-DIMETHYLBUTANE

C CL4 T ETRACHLOROMETHANE

C6H6 BENZENE

C6H14 HEXANE

C16H34 HEX ADECANE

C6H11. 2 ,3-DIMETHYLBUTANE

CCL4 TEfRACHLOROHET�ANE

677


C6H14 HEXANE

C6H1 4 HfXANE

341

34l

343

344

345

34 6

651

347

348

349

35t

351-353 353

354

355

356

357

358-36t

361

363-368 368 R

652-658

369-374

375

376-377

37a-3ae

381

382-384

385

386

387

678


C6H11. 2,3-DIMETHYLBUTANE

CHCL3 CHLOROFORM

C6H6 BENZENE 391-393

C6H14 HEX AN E 394

C7H14 CYCLOHEPTANE 395

C8H 16 CYCLOOCTANE 396

C16H34 HEXADECANE 397 ===============================::z::::az==:::u:::::::z::::z:::caaa:C:�::a::::a:z::::ca:cs:::::zazci::accca:aaa:::

CCL4

CD31

CD5N

CHBR3

CHCL3

CH2D3N

CH3D2N

CH5N

C2Cl4

C2D7N

C2HCL3

C2HD6N

C2H2Cl4

C2H3C l3

C2H3Cl3

C2H5D2N

C2H51

C2H5N02

C2H6DN

C 2H7N

C2H7N

C3H5CL3

C3H7N02

C3 H7N02

C3 H8S

C3H9N

C3H9N

C4H11N

C4H11N

HnANE

TETRA CHlOROMETHANE

TRIDEUTEROIODIDE

PERDEUTEROMETHYLAMINE

TR IBROMOME THAN£

CHLOROFORM

TRIDEUTEROMETHYLAMINE

N ,N-DEUTEROMETHYLAHINE

METHYLAMINE

TETRACHLOROETHYLENE

PERDEUTERODIMETHYLAMINE

TRICHlOROETHYLENE

HEXAD�UTERODIMETHYLAMINE

1,1,2,2-TETRACHlOROElHANE

1,1,1-TRICHLOROETHANE

1,1,2-TRICHlOROETHANE

N ,N-DEUT EROETHY lAII IN E

ETHYl IODIDE

NITROETHANE

N-DEUTERODIMETHYLAHINE

Dl� ETHYL AMINE

ETHYLAMINE

1,2,3-TRICHlOROPROPANE

1-NITROPROPAN E

2-NITROPROPAN E

1-PROPANETHIOL

PROPYlAMINE

TRIMETHYLAMINE

BUTYLAMINE

DIETHYlAMINE

398-413

414-419

411-419

421-422

433 -437

438-442

443-452

453

454-461

462-463

464-471

473

474

475-478

479-481

481-483 483

484-491

491-513

514-517

518

519

511

51 1

512-514

515-517

518

519 -------------------------------------------�---------------------------------------------

C6 F6 HEXAF LUOROBENZENE 521-52 1

679


================== ===========================================s===========================================

C6 H14

C6H14

C6H1A

HEXANE

CM14 PERFLUOROHEXAH

C6H3 CL� 1,2, 4-T RICHLOROBENZENE

C6H5CL CHLOROBENZENE

C6H5N02 NITROBENZENE

C6H6 BENZENE

C6H7N ANILINE

C6H12 METHYLCYCLOPENTANE

C6H14 2-MET HY LPE NTANE

C6H14 3-HE THYLPENTA NE

C6H15N DIISOPROPYL�HINE

C6H15N DIPROPYLAM INE

C6H15N HEXYLAMINE

C 6H 15N TRIETHYLAMINE

C7H8 TOLUENE

C7H14 METHYLCYCLOHEX ANE

C7H16 HEPTANE

C8H1t P-X YLENE

C8H18 OCT ANE

C16H34 HEX ADECANE

2-HETHYLPE NT ANE

CCL4 TETRACHLOROMETHANE

C6H6 BENZENE

C7H8 TOLUENE

C 6H11 P-XYLENE

522-5l5 525

526 -527

528-53f

659-661

531-5 33

534-'559 559

66 2-663

664-665

561-581

581

582

583

584

5.85

586-589

5 9 1

591-595

596-597

598-616

617-618

619-613

614-618

619

C2H5N02 NITROHHANE 621 ---------------------------------� -------------------------------------------------------

C3H8S 1-PROPANETH I OL 6 21

C6H6 BENZENE 622-624

C16H34 HEXADECANE 625

3-METHY LPENTANE

CCL4 TETRA CHLOROMETHANE 626

C7H8 TOLUENE 627-629

C16H34 HEXADECANE 63e

681

Alphabetical Index of Systems

================================================================================================· ·=======

1ST Cf•f!rO�� NT 2ND COMPON�NT 3PD COMPONE.N T 4TH CO�PONENT

PAGE

=========================================================================================== ==============

1 ,3-Pl TADJEtH

BUTA�l

1-BUTENE

CYCL�HXAN£

C4H6

BENZENE C6H6

BUTANE C 4H 1e

1 -BUTENE C4H 8

CARBON DISULFIDE CSZ

14

11- 13

8- , . ,.

--------------------------------------------------------------------·------------

�-CHLOR0-1,3-BUTADIENE C4H5CL

Dl CHLOROMETHANE CH 2C l2

N ITRDMETHANE C H3 N 02

STTREN E C8H8

TETRACHLOROMETHANE CCL4

C4H1f

N -DEUTEROETHYLAMINE C2H502N

ETHYLAMINE C2H7N

ETHYL CHLORIDE C2H5Cl

H EX AN E C6H 14

4

15- 16

23- 27

28

22

31- 3 5 --------------------------------------- ----------------------------------�------

METH YL AMIN E C H5N 19- 21

PENTANE C5H1Z -------------------------------------------------------�------------------------

PERFLUOROCYCLOBUTANE C4F8

C4H8

BUT ANE C4H 1t

C6H12

ANILINE C6 H 7N

BENZENE C6H6

BROMOBENZENE C6H58R

CARBON OISUlfiDE CS 2

CH LOROBENZENE C6H5Cl

CHLOR OCY CLOHEX ANE C6H11Cl

CHLOROOIFLUOROMETHANE CHCLF2

CYCLOHEX HAM I NE C6 H 13N

1,2-0IBROMOETHANE C2H4BR2

AN I LINE C 6H 7N

HEXANE C6H 14

TOLUENE C7H8

29

17

242-257 257

214-241 24 1 -241 R

639

64t-647

648

196-2e1

153-154

,2t2

258-261

151-152

263-269

157

682


:=================================================================================================a======

CYCLN·� XANl C6H12

1,2-DICHLOROETHANE C2H4CL2

DIMETHYL BUTANE C6H14

DODECANE C12H26

EICOSANE C2eH42

ETHYlBENlENE C8H11

HEPTANE C7H16

HEXADECANE C16HH

HEXAFLUOROBE NZENE C6F6

HEXAME THYLENEIMIN E C6H 1 3N

HE X AN E C6 H14

HETHYlANI LINE C7H9N

HETHYLCYCLOHEXANE C7H14

N-HETHYLCYC LOHEXYLAHINE C7H15N

METHYLCYCLOPENTANE C6H12

N-METHYLFORMAHIDE C2H5NO

NITROBE NZENE C6 H5N02

NITROHETHANE CH3N02

OCTANE CBH18

1-0CTENE C8H16

PENTACHLOROE THANE C 2H C l5

PERFLUOROCYCLOHEXANE C6F12

PIPE RIDINE C5 H11N

PYRIDINE C5H5N

PYRROLIDINE C 4 H9N

TETRACHLOROHETHANE CC L4

TH IAZOLE C3H3NS

THIOPHE NE C4H4S

TOLUE NE C7H8

TRICHLOROETHYlENE C2HCl3

TR I HE THYLBUTANE C 7H 1 6

2,2,4-TRIHFTHYLPENTANE C8H18

M-XYLEN E C8H1f

0-XYlENE C8 H1e

C@H1f

BENZENE C6H6

HE PTAH C7Hf6

BENZENE C6H6

158-163 163 R

Z72

H7-H9

3J8-31J

3 U•H6 . 3J6

334-336

186 -191 191 R

Z7J-271

273-277 277

292-294

295

296-299 299

26 2

164-465

2J3

636

3 2J -323

319

156

192-19 5

183•185 185 R

171-18 2

139•15e 15J

166

167

Z78-291

649-65f

155.

637-638

317

324-329 329

313-314

311-312

315-318

C Y CL�IIEXEH

CYCLOPlNTADIFNE

CYCLflPlNTAIIE

2, 2-� tnETH Y LBUTA NE

2, 3-� 11 ETHllfUTANF

C6 H 1 f

BE N ZENE C6H6

CYCLOHEX ANE C6H12

1,2-DICHLOROETHAN£ C2 H 4 CL 2

TETRACHLOROMETHANl CCL4

C5H6

ISOP RE NE C5H8

2-METHYL-2-BUTENE C5H1t

C5H1f

BENZ ENE C6H6

CARBON DISULFIDE csz

CHLOROFORM C HCL3

CI�-DECAHYDRONAPHTHALENE C1fH18

TRA-DECA HYDRONAPHTHALENE C1tH18

2, 3- D IMETHYLBUTANE C6H14

2-PROPANETHIOL C3H8S

TETRACHLOROETHYLENE C2Cl4

TETRACHLOROMETHANE CCL4

C6H 1 4

BENHNE C6H6

HE X ADEC ANE C1 6H34

HEXANE C6H14

TETRACHLOROMETHA�E CC L4

C6H14

BENZEN E C6H6

CHLOROFORM CHCL 3

C YCLOHEPTAN E C7H14

CYCLOOCTANE C8H16

HEXI\DECANE C1 6H34

HXANE C6H 14

TETRACHLOROMETHANE CC L 4

C6H14

ANILINE C6H7N

683


CYCLOHEXAN E C6H1?

2-HETHYL-2-BUTENE C5H1f

13f-136

136

H7-138

129

634-6:55

1 28

36

631

H

6 9- 73

63- 66

66

62

75

76

74

68

67

6t- 61

382-384

386

385

381

391-393

388-Hf 39t

395

396

397

394

387

56t-S8f

684


�===============================�=s======================================================================

HEX A� l C6HH

B£NZENE C6H6

BUTY LA HI NE C4 H11N

CHLOROBENZENE c 6H se L

CHLO ROfORM CH CL3

N-DEUTFRODI�ETHYLAHINE C2H60N

N,N-OEUTEPOETHYLAMINE C2H5D2N

N,N-DEUTEROMETHYLAMINE CH3D2N

DIETHYLAMINE C4H11 N

DIISOPROPYLAMINE C6Hl5N

OIMETHYLAM INE C2H7N

DIPROPYLAMINE C6H15N

ETHYL AMI NE C2H7N

£THYL I ODIDE C2H51

HEPTAN£ C7 H16

HEXADE CANE C16H34

HEXADEUTERODIMETHYL-AMINE C2HD6N

IIEXAF LUO ROBENZENE

HEXYLAHINE

METHYLAMINE

METHYLCYCLOHEXANE

METHYLCY CLOPENTANE

2-METH YLPE NTANE

3-HETHYLPENTANE

NITROBENZENE

NITRO£THANE

1-NITROPROPANE

2 -N ITR OPROPAN E

O CTANE

PEROEUTERODIMETHYLAMINE

C6F6

C6H15N

CH5N

C7H14

C6H12

C6H14

C6H 1 4

C6H5N0 2

C2H5N02

C3H7N02

C3H7N02

C8H 18

C2 D7N

PEROEUTERO�ETHYLAMINE CD5N

PERF LUOROHEKANE C6F14

1-PROP ANETHIOL C3H8S

PROPY �AMINE C3H9N

1,1,2,Z-TETRA CHLOROETHANE C2HZ CL4

TETRA CHLOROETHYLENE C2CL4

TOLUENE C7H8

P- X YLENE C8H1t

BENZENE C6H6

534-559

559 R

662-663

664 - 665

518

659-661

423-432

432 R

475-478

438-442

519

584

491-513

585

514-517

479-481

598-616

614-618

464-471

52e-5l1

586-589

443-452

596-597

581

582

583

531-533

481-483

483

519

511

619-613

454-4 61

41t-419

522-525

525

511

512-514

472

45 3

685


: :::::::::: :::;::::::::: :::::: :::::::::: :::::::::::::::::::::::::::::: :::::::::::::::::: �== ::::::.;: ::::::::::::::::::::::::::::::: :::::::::::::::::::::: Z ::: ::: :::::::::::::: IC: :::::::::::::::::::::::: :::::::::::::=::::::::::::: ::::::::::::::::::z=:::=-z::::::;z::: ZE ::::::::::1:1:::

H�XA�E

TETRACHLOROMETHANl CCL4

TOLUENl C7H8

TRIBROHOMETHANE CHBR3

1,7,4-TRICHLOROBENZENE C6H3CL3

1,1,1-TRICHLOROETHANE C2HHL3

1,1,2-TkiCHLOROETHANE C2H3CL 3

TRICHLOROETHYLEN[ C2HCL3

1,2,3-TRICHLOROPROPAN� C3 H5C L3

TRIDEUTEROIODIDE C�31

TRIDEUTEROMETHYLA�INE CH2D3N

TR lE THYLAM INE C6H15N

TRII"ETHYLAMINE C3H9N

P-XYLENE C8HU

1-HEX ENE C6H12

8[NHNE C6H6

BUTYLAMINE C4H11N

DIETHYLAMINE C4H11N

DIISOPROPYLAHINE C6H15N

DIPROPYUMINE C6H15N

HEX ANE C6H14

HEXYLAMINE C6H15N

PROPYL BROMIDE C3H 7BR

1,1,7.,2-TETRACHLOROETHANE C2H2CL4

TETRACHLOROEThYLENE C2CL4

TETRACHLOROMETHANE CC L4

TOLUENE C7H8

1,1,1-TRICHLOROETHANE C2H3Cl3

1,1,2-TRICHLOROETHANE C2H3CL3

TR ICH LOR OETHYLENl C2HCL3

TR lE THYLAMINE C6H15N

HEXANE C6H14

591-595

42•-422

526-527

473

474

518

414-419

433-437

591

515-517

617-618

351

348

349

354

355

351-353 . 35 3

356

3 47

343

341

341

358-361

344

345

342

651

357 ====================

·=====================================================================================

IS�BI'TEJ;E C4H8

ISOPRENE C5H8 18

)SOPPEtfE C5 H8

ACETONITRILE C2H3N 39- 41

Z-HETHYl-2-&UTENE C5H1t 632-633

686


===============================z=====a==================•=================x============================= =

ISOf·PF.Il[

2-tll T\! YLBUTANE

2-METtiYL-1-BUTENE

2-HETHYL-2-BUTENE

METHYLCYCLOPENTANE

:!-rtl THY LPENTANE

C5H8

----------------------------------� ---------------------------------------------N,N-DIHETHYLFOR�AMIOF

O!METHYLSULFOXIDE

2-HETHYLBUTANE

2-�ETHYL-1-BUTENE

2-HETHYL-2-BUTENE

3-METHYL-1-BUTENE

NITROHETHANE

TR-1,3-PENTADIENE

ACETONITRILE

CARBON OISULFIOE

N,N-OIHETHYLFORHAMIOE

2-METHYL-2-BUTENE

NITROMETHANE

ACETONITRILE

N,N-DIMETHYLFORHA�IOE

2-METHYLBUHNE

NITROHETHANE

BENZENE

HXANE

1-PROPANETHIOL

TETRACHLOROHETHANE

TOLUENE

BENZEH

HEXAOECANE

NITROETHANE

1-PROPAHTH I Ol

TETRACHLOROMETHANE

C3H7�0

C2H60S

C5H12

C5H10

C 5H 11

C5HU

CH3N02

CSH8

C5H12

C2H3N

CS2

C3H 7NO

C5H1t

C5H1t

CH3N02

C5H1t

C2H3N

C3H7NO

C5H12

CH3N02

C6H12

C6 HI>

�EXANE

C6H14

C3H8S

CCL4

C7H8

CtH14

C6H6

C16H34

C 2H5N02

C3H8S

CCL4

C6H14

44

41- 43

56

46- 47

48- 53

54- 55

38

45

88 .

86-87

89

78

77

si- 8 2

8 3

84

79

363-368

368

652-658

369-374

.!62

361

375

622-624

625

62t

621

619

2-RlT�Y L-1-PfNTENE

4-METHYL-1-PENTENF

NEOPf NT AN£

TR-1.3-PENTADIEN£

PENT AM

1-PENTE NE

VINYLhtETYLf.N£

C6H14

687


HEXADECANE C1 � H34 631

- -------------------------------------------------------------- --- --------- -----

TETRACHLOROMETHA�£ CCL4 626

TOLUENE C7H8 627-629

C6H12

BEN ZENE C6H6 376-377

C6H12

BENZENf C 6 H6

C5H12

PENTANE C5H12 95- 99

TETRAHETHYLSILANE C4H12 SI 91- 94

C5H6

D!METHYL SULFOXIDE C2H60S 57- 59

C5H1 2

ACETONITRILE C2 H3 N 1t1-1t2

ACRYLONITRILE C3H3N 1t3-114

----------------------------------------------------------- ---------------------BENZENE C6H6 114-118

CYCLOHHAN£ C6H12 119

------------------------------------------- -------------------------------------DICHLOROMETHANE CH2CL2 1U --------------- ------------------------------------------ ----------- ------------HEPTANE C7H16 126-127

HEX ANE C6H14 122-123

METHYLCYCLOHEXANE C7H14 124-125

METHYLCYCLOPENTANE C6H12 121-121

PENTYL BROMIDE C5H118R 1t6-113 --------------------------------------------------------------------------------

1-PROPANETHIOL C3H8S 115

C5HH

ACETONITRILE C2�3N 85

C4H4

B EN ZENE C6H6

P-XYLENE CRH11

vapor-liquid equilibrium data collection · c4h11n d i eth ylam i ne c6h6 ben le ne c6h14 hhane...

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