05-reazioni senza soluzioni

7/23/2019 05-Reazioni Senza Soluzioni

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COMPLETARE LE SEGUENTI REAZIONI, DEFINIRNE IL TIPO E IL NOME SPECIFICO

1.(CH3)3CCH2CH(CH3)2 + O2

calore

A + B + C

2.CH3CH2CH3 + O2

calore

A + B + C

3.

+ O2calore

A + B + C

4.ACH3CH2CH CH2 + H-I

5.

+ HCl

CH3

H

A

6.

CH2 C CHCH2CH3 + HBr

CH3

CH3

A

7.CH3CH2CH CCH2CH3 + HCl

CH3

A

8.

CH2CH3+ HBr A

9.

CH3CCH CCH2CH3 + HI

CH3

CH3

CH3

A

10.

CH2

+ HBr A


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2

11.

CH3

+ H2OH

+

A

12.

+ H2OH+ A

13.

CCl4CH3CH2CH CH2 + Br2 A

14.

H3C H

+ Br2 A

15.H H

+ Cl2H2O

A

16.

CH3

CH3

Br2A

17.

Cl2H2O

A

18.

C C

CH3CH2

CH3

CH3

H

Br2A

19.

CH2Br2

A

20.

Br2A


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3

21.

CH2 CCH3 + H2

CH3

A

22.

CH3

+ H2 A

23.

CH3 C

CH2

CH3

2H2Pt

A

24.

CH2 C

CH2CH3

CH2CH2CH3

H2Pd A

25.

CH3 CH2H2Rh

A

26.

H2Pd-C

A

27.H H

+ KMnO4dil.OH-, calore

2) H3O+ A

28.H3C H

+ OsO42) NaHSO3/H2O

A

29.

CH CH2KMnO4dil

A

30.

+ HCO

O

OH

H H

A + B


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31.CH3(CH2)7CH CH(CH2)7COOH + mCl C6H4CO

O

OH A + B

32.

C C

H CH3

CH3R C

O

O OH

A

33.

Cl2h

A

34.

35.

Br2h

CH3CH2CHCH3

CH3

A

36.

Br2h

(CH3)3CH A

37.

Cl2h

(CH3)3CH A + B

38.

perossidiCH3C

CH3

CH2 + HBr A

39.

CH3CHCH2CH=CH2 + HBr

CH3

perossidiA

40.

(CH3)2C CHCH3HBr

peross idiA

41.

HBr

ROOR A

Cl2

hCH3CH2CHCH3

CH3

A + B + C + D (INDICARE IL PRODOTTO PRINCIPALE)


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42.

OCH3

+ Br2AlBr3

A + B

43.

NO2

+ HNO3H2SO4

A

44.

COOC2H5

+ SO3

H2SO4

A

45.

O + C2H5COClAlCl3

A + B

46.

CN

SO3H

+ Cl2AlCl3 A

47.

OCH3

NO2

CH3COClAlCl3

A + B

48.

CH3

NO2

+ SO3H2SO4

A


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49.

Cl2

AlCl3

CH3

CH3

A + B

50.

CH3CH2COCl

AlCl3

CH3

CH3

A

51.

SO3

H2SO4

CH3

CH3

A

52.

OCH3

Br

CH3CH2CH(Cl)CH3

AlCl3

A + B

53.

NH2

BrHNO3

H2SO4

A + B

54.

NO2

ClSO3

H2SO4

A + B

55.

SO3H

CH3

Br2

AlCl3

A


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56.

OH

CF3

+ HNO330C

A

57.

OH

Cl

Cl

CH3Cl

AlCl3

A

58.

OH

Br

Cl2

CS2A + B

59.

OH

NO2

H2SO4 A + B

60.NaCl + CH3CH2CH2I A + B

61.CH3CH2ONa + CH2=CHCH2Cl A + B

62.

Br + NH3etanolo

A

63.

Cl + CH3CO-Na

+

Oetanolo

A + B

64.CH3CHCH2CH2Br +

CH3dimetil solfossido

NaSH A + B


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65.CH3CHCH2CH3 + CH3CH2SNa

Iacetone

A + B

66.

C I + NaCN

CH3

CH3(CH2)4CH2H

DMSOA + B

67.

CH3CH2CCH2(CH2)3CH3 + CH3CH2SNa

I

CH3

A + B

68.

Cl

CH3COO-Na+

A + B

69.H2C CCH2Br

CH3Na+-SCH3

A + B

70.CH3CH2CH2O

-Na

+ + CH3CH2CH2CH2Br A + B

71.

CH2Br + (CH3)2CHONa A + B

72.CH3CH2CH2ONa + CH3Br A + B

73.

ONa

ONa

+ 2CH3Br A

74.

NaHCH3CHCH2Cl

OH

A + B + C


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9

75.

NaHCl

H

H

OH

A + B + C

76.

NaH

Cl

H

OH

77.CH3CH2CH2Br + NaSH A + B

78.BrCH2CH2CH2CH2Br + NaSH A

79.

CH2Br + CH2SNa A + B

80.

ClCH2CH2CH(CH2)4COOC2H5 + 2C6H5CH2SH

Cl

KOHA

81.

CH2Br + NaSH A + B

82.

CH2SHNaH CH3CH2CH2Br

A B

83.

A

CN-

C6H5CH2Br

84.ACH2=CHCH2Br

CN-

85.

CH2Br + NH3(eccesso)2)NaOH

A


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86.

CH2CH2Br

NH3

2) NaOHA

87.

H2NCH32) NaOH

BKCN

CH3CH2BrHBr

CH2=CH2

A

88.

NH2

1) 2CH3Br

2) NaOHA

89.

CH3

Cl

+ KOHCH3CH2OH

A + B (INDICARE IL PRODOTTO PRINCIPALE)

90.

CH3CH2CHCHCH3

Br CH3NaOCH3

caloreA + B (INDICARE IL PRODOTTO PRINCIPALE)

91.

CH3CHCH2-C-CHCH3

CH3 Cl

CH3

CH3(CH3)3COK

caloreA + B + C (INDICARE IL PRODOTTO PRINCIPALE)

92.

CHCH3

BrKOH


93.

CH3CH-CBr

CH3CH3

CH2CH3

EtONa

caloreA + B + C (INDICARE IL PRODOTTO PRINCIPALE)


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94.

CH3CHCH2CH2CHCH2CH2Br

CH3 CH3KOH

caloreA

95.

CH3

CH3Br

CH3ONa

calore A

96.

CH2CHCHCH2CH3

Br

CH3OH-


97.

Br

CH3

Mgetere

H2OA B + C

98.CH3CHCH2CH2CH2Br + Mg

CH3etere CH3NH2A B + C

99.CH3I + Mg A B + C

Et2O CH3COOH

100.

CH3CH2CHBr

CH3Mg

etere

CH3OHB + CA

101.CH3CHCH2CH2CH2OH

Br

AMg

x

102.CH3CH2MgI + NH3 A + B

103.

CH3

OH

H2SO4, H2O

50CA + B (INDICARE IL PRODOTTO PRINCIPALE)


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104.

CH3CH2CCH3

OH

CH3

H2SO4calore

A + B (INDICARE IL PRODOTTO PRINCIPALE)

105.

CH3CH CCH2CH3

CH3 OH

CH3

H2SO4

caloreA + B + C (INDICARE IL PRODOTTO PRINCIPAL

106.

CH3CH2CHCHCH3

OH

CH3

H2SO4


107.

OH

CH3

H2SO4

caloreA

108.

CH2OHH2SO4calore

A

109.

OH

CH3

H2SO4

caloreA

110.

CH3CHCH2CH2CHCH3

OH ClH2SO4

calore A

111.

CH3

OH

HCl(gas)etere, 0C

A + B

112.

CH3COH + HBr

CH3

CH3

A + B

113.

OH + HBr A + B


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114.CH3CHCH2CH2CHCH3

OH ClHBr

A

115.

CH3(CH2)4CH2OH CrO3H3O+ A

116.

CH3(CH2)3CHOH

CH3CrO3H3O

+ A

117.CH3(CH2)4CH2OH A

PCC

118.

OH

CrO3A

119.

CH3CHCH2OH

CH3PCC

A

120.

OHNa2Cr2O7

A

121.CH3CHCH2CH2CH2CH3

OHPCC

A

122.CH3CH2OCH2CH3 + HI A + B

123.(CH3)3COCH2CH3 + HBr A + B

124.

C

O

CH3

H3C CH3

HBr A + B


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14

125.

OC(CH3)3HI

A + B

126.

CH3CH CH2 + H3O+

O

H2O A

127.

H3O+/H2O

CH3CH2C C

CH2CH3

OH H

A

128.

C6H5OH + CH2 CH2

O

H

+

A

129.

O

CH3

CH3

HClA

130.

O

H+/CH3OH

A

131.

CH3CH2CH CH2 + C2H5O-

O

A

132.

CH3CH2C CH2

O

CH3

NaOHH2O

A

133.

O

CH3O-

H2OA


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15

134.

O

CH3

CH3HS

-

H2OA

135.

CH3CH2CH2 NH2NaNO2, HCl

0CA + B + C

136.

CH3

NH2

Br2H2O

NaNO2, H2SO40-5C

H3PO2, H2O

130CA B C + D

137.

CuBrNaNO2, HCl

0-5C

CH3

NH2

A B + C

138.

CH3

NH2

HONO0-5C

H3O+, calore

A B

139.

NH2

NH2

HONO0-5C CuClA B

140.

NO2

NH2

1) HONO, 0-5C2) KI

A


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141.

NH2

I

1) HONO, 0-5C2) CuCN

A

142.

HO3S NH2HONO0-5C

C6H5OH

pH 8-10A B

143.CH3CH2CHO + NaBH4

H+

A

144.

CH3CH2CHO

H2/Pt

CH3CH2CH2OH

145.

CH3CH2CHO + C6H5MgBrH2O

H+ A + B

146.CH3CH2CHO + NaCN

H+

A

147.

C

O

H

+ CH3CH2CH2CH2NH22) H+

A + B

148.+ CH3CH2CH2CH2NH2

2) H+O

A + B

149.

+ CH3CH2CH2CH2NH22) H

+

O A + B

150.

+ H2N2) H

+

O A + B

151.

O + (CH3)2NH

CH3

2) H+

A + B


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152.

CH + (CH3)2NH

O2) H+

153.

CH2NHCH3 + O

2) H+

A

154.CH3CH2CH2CHO + H2O

H+

A + B

155.CH3CH2COCH3 + H2O

H+

A + B

156.

H+

CH + H2O

O

A + B

157.C6H5CHO + 2CH3CHCH3

OHH

+

A

158.CH3CH2CHO + HOCH2CH2OH

H+

A

159.

ONaCN

HClA

160.

CH3NH2

H+CH3CH2CCH2CH3

O

A

161.CH3CCH2CH2CH3 + HOCH2CH2CH2OH

OH

+

A

162.

C6H5CH2CHO NaBH4

H+

A


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18

163.

C6H5CH2CHOKCN

H+A

164.

C6H5CH2CHO2CH3OH

H+A

165.

C6H5CH2CHOCH3MgBr

H3O+

A

166.

PCCCH2Cl2

Br2FeBr3

Mgetere

1) HCHO2) H

+A B

C D

167.CH3CH2CHO

KMnO4diluito a freddoA

168.

C

O

H CrO3A

169.

C6H5CH2BrCN-

AH+, H2O

caloreB

170.

CH2=CHCH2Br

1) CN-

2) H+, H2O, caloreA

171.

CH3CHCH2CH2CN

CH31) LiAlH42) H2O

A

172.

C6H5COOH + CH3CH2CH2OH

H+

A + B


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19

173.CH3COOH + CH3CH2CH2CH2OH

H+

A + B

174.CH3OH + CH3CH2CH2COOH

H+

A + B

175.HOCH2CH2CH2CH2COOH

H+

A + B

176.

COOH

CH3

CH3OH

H2SO4

A + B

177.

H3C

CH3

CH3

COOH + SOCl2 A + B + C

178.

CH2

Br

COOHSO2Cl

A + B + C

179.C2H5COOH

LiAlH4A

180.

CH3COCl + H

2O A + B

181.CH3CH2COCl

H2OA + B

182.CH3COCl + CH3(CH2)2CH2OH

piridinaA + B

183.

CH3COCl + OH A + B


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184.CH3COCl

NH3A + B

185.CH3COCl + 2NH3 A + B

186.

C6H5COCl + NH2 A + B

187.

COClCH3NH2

A + B

188.

COOH

CH3

SOCl2 (C2H5)2NHA B

189.CH3COCl + CH3COONa A

190.C6H5COCl + CH3COONa A

191.CH3COCl + 2(CH3)2NH A + B

192.CH3CH2COCl + CH3OH A + B

193.

C6H5COCl + (CH3)2CHCH2OH A + B

194.C6H5COCl + (C2H5)2NH A + B

195.

CH3CH2CH2COCl + HN A + B

196.(C6H5CO)2O + 2NH3 A + B


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21

197.(CH3)2CHCH2COCCH2CH(CH3)2 + 2NH3

O O

A + B

198.(C6H5CO)2O + H2O A

199.(CH3CO)2O + CH3CH2CH2OH A + B

200.CH3CH2COCCH2CH3

O OCH3OH

A + B

201.CH3CH2COOC2H5 + CH3NH2 A + B

202.

CH3CHCH2COOCH3 +

CH3

NH2

A + B

203.

CH3CH2COOC2H5

LiAlH4

H

+

DIBAHH+

A + B

A + B

204.

CH2COOHLiAlH4

A

205.

H2C CHCHCH2COOCH3

CH3LiAlH4

H3O+

A + B

206.CH3CH2CH2CHCOOCH3

CH3LiAlH4

A + B


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22

207.

C

O

O LiAlH4A + B

208.

CH3CHCH2CH2COOCH3

CH31) DIBAH

2) H3O+

A + B

209.

CH3CH2CONH2H3O

+

H2OA + B

210.

CH3CH2CONH2 A + BOH-

H2O

211.

CONHCH2CH3NaOH

H2O

A + B

212.

CH3CH2COOC2H5H3O

+

H2OA + B

213.

CH3CH2COOC2H5OH

-

H2OA + B

214.

CH3C

O

OCH3NaOH

H2OA + B

215.CH3CH2CHO

OH-A

216.

H3C CHO + CH3CHOOH

-

A

217.CH3CH2CHO + CH3CHO

OH-

A + B + C + D


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23

218.CH3CH2CH2CHO

OH-A

219.C6H5CCH3

OOH-

A

220.

OOH

-

A

221.

CH3CHCH2CHO

CH3

OH-

A

222.

O

H3C

H3C+

CHO

OH-

A

223.

(CH3)3CCHO + CH3CCH2CHO

CH2CH3OH

-

A

224.HCHO + C6H5COCH2CH3

OH-

A

225.

2CH3CH2COOC2H51) C2H5ONa, C2H5OH

2) H+A + B

226.

C6H5CH2COOC2H5 + CH3CCOOC2H5

CH3

CH3

1) C2H5ONa, C2H5OH

2) H+A + B

227.

CH2COOCH2CH3C2H5ONa

2 A + B

228.

CH3COOEt + CH3CH2COOEt1) EtONa

2) H+A + B + C + D


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229.

CH3CH2CH2CH2CH2Br + CH2(COEt)2

O

1) NaOEt

2) H3O+, calore

A

230.

CH3CH2CH2Br + CH2(COOEt)2NaOEt

A1) NaOEt2) CH3Br

H3O+

caloreB C

231.

(CH3)2CHCH2Br + CH2(COOEt)2NaOEt

A1) NaOEt2) CH3Br

BH3O

+

caloreC

232.

CH3CH2Br + EtOCCH2CCH3

O ONaOEt H3O

+

caloreA B

233.

CH2CH2Br + EtOOCCH2COCH31) NaOEt2) H3O

+, caloreA

234.

1) NaOEt2) H3O

+, caloreCH3CHCH2Br + EtOOCCH2COCH3

CH3

A

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