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A Study of Underground Stormwater Detention Chambers and the Creation of the Model for Underground Detention of Sediment by Nicholas David McIntosh A thesis submitted in conformity with the requirements for the degree of Master of Applied Science Graduate Department of Civil Engineering University of Toronto © Copyright by Nicholas David McIntosh 2015

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A Study of Underground Stormwater Detention Chambers and

the Creation of the Model for Underground Detention of

Sediment

by

Nicholas David McIntosh

A thesis submitted in conformity with the requirements

for the degree of Master of Applied Science

Graduate Department of Civil Engineering

University of Toronto

© Copyright by Nicholas David McIntosh 2015

II

A Study of Underground Stormwater Detention Chambers and

the Creation of the Model for Underground Detention of

Sediment

Nicholas David McIntosh

Master of Applied Science

Graduate Department of Civil Engineering

University of Toronto

2015

Abstract

This thesis investigates the hydraulic and runoff treatment capabilities of Underground

Stormwater Detention Chambers (USDC) and compares them to stormwater management ponds,

the industry standard system for runoff detention and treatment. Runoff characteristics were

monitored at a USDC in Markham, Ontario. Characteristics include: total suspended solids,

turbidity, nutrients, metals, bacteria, temperature, and hydrocarbons. The Model for

Underground Detention of Sediment (MUDS) was created to predict the removal of suspended

solids by a USDC. The results indicate that the Markham USDC meets all provincial hydraulic

requirements and most water quality requirements. Also, the Markham USDC provides

equivalent or improved level of service compared to stormwater management ponds for runoff

treatment in most cases. MUDS was proven capable of accurately predicting USDC hydraulics

and suspended solids removal for both event based and continuous based simulations.

III

Acknowledgments

I would first like to thank Dr. Drake for her invaluable advice and guidance throughout the

preparation of this thesis. I would like to thank Jason Spencer (Con Cast Pipe), and Dean Young

and Tim Van Seters (Toronto and Region Conservation Authority) for answering my questions

and providing many helpful suggestions. Thanks and appreciation is also extended to Mark

Hummel and Jacob Kloeze (TRCA) for their field work. Lastly, I would like to thank my wife,

Ali, and parents, David and Brenda, for supporting and encouraging me throughout the years.

IV

Table of Contents

Acknowledgments ........................................................................................................................................ III

Table of Contents ......................................................................................................................................... IV

List of Tables ............................................................................................................................................... VI

List of Figures ............................................................................................................................................. VII

List of Symbols ............................................................................................................................................ IX

Chapter 1 Introduction .................................................................................................................................. 1

Chapter 2 Relevant Literature ....................................................................................................................... 6

2.1 Urbanization and Stormwater Management............................................................................................ 6

2.2 Stormwater Management Pond Pollutant Characteristics ....................................................................... 9

2.2.1 Total Suspended Solids .................................................................................................................... 9

2.2.2 Nutrients ......................................................................................................................................... 12

2.2.3 Heavy Metals ................................................................................................................................. 16

2.2.4 Temperature ................................................................................................................................... 20

2.2.5 First Flush ...................................................................................................................................... 21

2.2.6 Winter Conditions .......................................................................................................................... 22

2.3 Modeling of Stormwater Management Ponds....................................................................................... 23

2.3.1 K-C Decay Rate Model .................................................................................................................. 23

2.3.2 Sedimentation ................................................................................................................................ 24

2.3.3 Probabilistic ................................................................................................................................... 27

2.4 Summary ............................................................................................................................................... 28

Chapter 3 Methodology .............................................................................................................................. 30

3.1 Field Site ............................................................................................................................................... 30

3.2 Monitoring ............................................................................................................................................ 34

3.3 Water Quality Analysis ......................................................................................................................... 36

3.4 Modeling ............................................................................................................................................... 37

3.4.1 Hydraulics ...................................................................................................................................... 38

3.4.2 Particle Tracking ............................................................................................................................ 39

3.4.3 Pollutant Removal .......................................................................................................................... 41

3.4.5 SWMM Modeling .......................................................................................................................... 45

3.5 Summary ............................................................................................................................................... 48

Chapter 4 Water Quality Results ................................................................................................................ 50

4.1 Total Suspended Solids and Turbidity .................................................................................................. 51

4.2 Nutrients ................................................................................................................................................ 53

V

4.3 Metals .................................................................................................................................................... 56

4.4 Bacteria ................................................................................................................................................. 61

4.5 Temperature .......................................................................................................................................... 63

4.6 Hydrocarbons ........................................................................................................................................ 65

4.7 Vertical Profiles .................................................................................................................................... 67

4.8 Summary ............................................................................................................................................... 70

Chapter 5 Model Development and Results ............................................................................................... 73

5.1 SWMM Calibration and Validation ...................................................................................................... 75

5.2 Particle Removal Assessment ............................................................................................................... 80

5.2.1 Sensitivity Analysis ....................................................................................................................... 84

5.3 Markham USDC MUDS Simulations ................................................................................................... 85

5.3.1 Design Storm Simulation ............................................................................................................... 85

5.3.2 Continuous Simulation (May - Nov) ............................................................................................. 87

5.3.3 Seasonal Simulations ..................................................................................................................... 89

5.3.4 Sizing Simulations ......................................................................................................................... 90

5.4 Summary ............................................................................................................................................... 92

Chapter 6 Conclusions and Recommendations ........................................................................................... 95

6.1 Conclusions ........................................................................................................................................... 95

6.1.1 Objective 1 ..................................................................................................................................... 95

6.1.2 Objective 2 ..................................................................................................................................... 97

6.1.3 Objective 3 ..................................................................................................................................... 98

6.2 Recommendations for Future Research ................................................................................................ 99

6.2.1 Water Quality ................................................................................................................................. 99

6.2.2 Modeling ...................................................................................................................................... 100

6.2.3 USDC Design in Ontario ............................................................................................................. 101

References ................................................................................................................................................. 102

Appendix A: Layout of MUDS Interface ................................................................................................. 106

Appendix B: Removal Percentage Calculation ......................................................................................... 107

Appendix C: Hydrograph and Depth Figures of Storms used for Validation and Calibration of the SWMM

Model ........................................................................................................................................................ 113

VI

List of Tables

Table 1: TSS Removal Percentage by SWM .............................................................................................. 12 Table 2: Median Total and Soluble Phosphorus, Ammonia and Nitrate/Nitrite Concentrations by Land

Use .............................................................................................................................................................. 15 Table 3: Summary of Nitrogen and Phosphorus Transformations and Removal Mechanisms .................. 15 Table 4: Nutrient Removal Efficiency by SWM Ponds .............................................................................. 16 Table 5: Common Sources of Metal in Urban Runoff (Shaver et al., 2007) .............................................. 17 Table 6: Typical Levels of Metals Found in Stormwater Runoff (µg/L) .................................................... 17 Table 7: Percent Reduction in Metals after Removal of Various Particle Sizes ......................................... 18 Table 8: Percent Removal of Metals by SWM ........................................................................................... 19 Table 9: Metals Provincial Water Quality Requirements ........................................................................... 19 Table 10: Distribution of Event Constituents (EMC) ................................................................................. 28 Table 11: DoubleTrapTM Monitoring Equipment Properties and Purpose .................................................. 34 Table 12: Outflow Equations ...................................................................................................................... 38 Table 13: Particle Tracking Equations (Takamatsu et al., 2010) ................................................................ 40 Table 14: SWMM Subcatchment Properties .............................................................................................. 48 Table 15: SWMM Land Type Roughness and Storage .............................................................................. 48 Table 16: SWMM Conduit Properties ........................................................................................................ 48 Table 17: Sampled Storm Event Hydrologic Parameters ........................................................................... 50 Table 18: Summary of TSS EMC and Turbidity ........................................................................................ 51 Table 19: Summary of TSS and Turbidity Statistical Analysis .................................................................. 51 Table 20: Percent Removal of TSS and Turbidity ...................................................................................... 52 Table 21: Summary of Nutrient EMC ......................................................................................................... 54 Table 22: Summary of Nutrient Statistical Analysis................................................................................... 55 Table 23: Summary of Metals EMC ........................................................................................................... 57 Table 24: Summary of Metals Statistical Analysis ..................................................................................... 59 Table 25: Percent Removal of Metals ......................................................................................................... 61 Table 26: Summary of Bacteria EMC ......................................................................................................... 61 Table 27: Summary of Bacteria Statistical Analysis................................................................................... 62 Table 28: Number of Hydrocarbon Samples below the MDL .................................................................... 65 Table 29: Summary of Hydrocarbon Removal ........................................................................................... 66 Table 30: Hydrocarbon Provincial Water Quality Requirements ............................................................... 67 Table 31: Minimum Acceptable Dissolved Oxygen Concentration in Rivers for the Protection of Aquatic

Life (Canadian Council of Ministers of the Environment, 2015) ............................................................... 69 Table 32: Summary of Calibration and Validation Events ......................................................................... 73 Table 33: MUDS Input Values ................................................................................................................... 74 Table 34: Raw Inflow and Outflow Data Summary ................................................................................... 79 Table 35: TRCA and Average Monitored Storm PSD................................................................................ 82 Table 36: Assessment of Particle Removal Summary ................................................................................ 84 Table 37: Seasonal and Overall TSS Removal Simulation Results ............................................................ 89 Table 38: Summary of Forebay and Residence Time Significance Tests ................................................... 97

VII

List of Figures

Figure 1: StormTrap Cell Top and Bottom - Con Cast Pipe Facilities June 4, 2014 .................................... 2 Figure 2: StormTrap Rebar Cage (Left), Cell Mold (right) - Con Cast Pipe Facilities June 4, 2014 ........... 3 Figure 3: StormTrap Cell in Mold (left) with Manhole Styrofoam (right) - Con Cast Pipe Facilities June 4,

2014 .............................................................................................................................................................. 4 Figure 4: StormTrap after Concrete Pouring (left) Mold Covered by a Tarp (right) - Con Cast Pipe

Facilities June 4, 2014 ................................................................................................................................... 4 Figure 5: Pre vs. Post-Urbanization Hydrographs ........................................................................................ 6 Figure 6: Median Stormwater TSS Concentrations from NSQD ................................................................ 10 Figure 7: Structure With/Without Baffling ................................................................................................. 12 Figure 8: 25/50 M(V) Curve ....................................................................................................................... 22 Figure 9: Particle Sedimentation Paths ....................................................................................................... 26 Figure 10: DoubleTrapTM Location and Service Area ................................................................................ 31 Figure 11: DoubleTrapTM Site and Monitoring Boxes (Left), Construction Zone South of the

DoubleTrapTM (Right) (June 23, 2014) ....................................................................................................... 31 Figure 12: Parkland Surrounding the DoubleTrapTM (June 23, 2014) ........................................................ 32 Figure 13: DoubleTrapTM Monitoring Equipment and Dimensions ........................................................... 33 Figure 14: DoubleTrapTM Dimensions (Side) ............................................................................................. 33 Figure 15: As Built DoubleTrapTM with Individual Cells ........................................................................... 33 Figure 16: Particle Size Distribution (AZO Materials, 2007) ..................................................................... 41 Figure 17: Flocculent Settling Column Test (Viessman & Hammer, 1985) ............................................... 42 Figure 18: Potential Particle Entry Paths .................................................................................................... 43 Figure 19: Flocculent Settling Removal Calculation Example: .................................................................. 43 Figure 20: Model Particle Paths .................................................................................................................. 44 Figure 21: SWMM Model Study Area Map ............................................................................................... 47 Figure 22: Box plots of Suspended Solids and Turbidity ........................................................................... 51 Figure 23: TSS VS Turbidity: Inlet (Right), Hatch 2 and Outlet (Left)...................................................... 53 Figure 24: Box Plots of Nitrogen Species ................................................................................................... 54 Figure 25: Box Plots of Phosphorus Species .............................................................................................. 55 Figure 26: Box Plots of Monitored Metals ................................................................................................. 57 Figure 27: Box Plots of Monitored Bacteria ............................................................................................... 62 Figure 28: YSI Temperature Results .......................................................................................................... 63 Figure 29: Box Plots of Hydrocarbons ....................................................................................................... 66 Figure 30: Depth Profile Results ................................................................................................................. 68 Figure 31: Measured and Modeled Outflow Comparison ........................................................................... 75 Figure 32: Calibration Height and Flow Results ........................................................................................ 76 Figure 33: October 16 Outflow Modeling .................................................................................................. 77 Figure 34: October 16 Depth Modeling ...................................................................................................... 77 Figure 35: October 20 Outflow Modeling .................................................................................................. 77 Figure 36: October 20 Depth Modeling ...................................................................................................... 78 Figure 37: USDC Peak Flow Reduction ..................................................................................................... 79 Figure 38: First Flush Ratio Calibration Example ...................................................................................... 81 Figure 39: TRCA and Average Monitored Storm PSD .............................................................................. 82 Figure 40: Assessment of Particle Removal Results................................................................................... 83 Figure 41: Sensitivity Analysis Results ...................................................................................................... 84 Figure 42: 5 Year Storm Hydrographs ........................................................................................................ 86

VIII

Figure 43: 10 Year Storm Hydrographs ...................................................................................................... 86 Figure 44: Hydrographs for Continuous Simulation ................................................................................... 87 Figure 45: Modeled Depth for Continuous Simulation............................................................................... 88 Figure 46: July to August Simulation Hydrograph ..................................................................................... 90 Figure 47: July to August New Area Hydrographs ..................................................................................... 91 Figure 48: Reduced Catchment Area with TRCA PSD Hydrographs ........................................................ 92

IX

List of Symbols

A Drainage Area (L2) Qr Surface runoff (L3/T)

Af Effective flow area (L2) RTRM Relative thermal resistance to mixing

(-) Ao Orifice area (L2)

B(t) Width at time t (L) RFraction Fraction of particles removed in a

particle wave (-) b First flush coefficient (-)

C Concentration (M/L3) rA Reaction rate (M/L3∙T)

CA Concentration of a pollutant in a

SWM pond (M/L3)

S Surface slope (-)

SA Surface area (L2)

CAo Concentration of a pollutant as it

enters a SWM pond (M/L3)

t time (T)

tf Time for a particle to travel through

the USDC (T) Cd Orifice loss coefficient (-)

Cin Concentration flowing in (M/L3) tlarger Time for the larger particle of two to

reach the bottom of a USDC (T) Cout Concentration flowing out (M/L3)

c Runoff coefficient (-) tsmaller Time for the smaller particle of two to

reach the bottom of a USDC (T) d Orifice diameter (L)

dp Particle diameter (L) V Volume (L3)

F Flow rate (L3/T) Vs Settling velocity of a particle (L/T)

g Gravitational constant (L/T2) Vsc Critical settling velocity (L/T)

Ho Depth of water above midpoint of

orifice (L)

Vsegment Settling velocity of the segment

between two particle sizes (L/T)

Hw Depth of water above the orifice

invert (L)

X Cumulative Volume/Total Volume (-)

x(t) Horizontal position at time t (L)

h Height (L) Y Cumulative mass/Total Mass (-)

hexit Particle exit height (L) Yimean Mean of observed data for the

constituent being evaluated (any units) hini Particle entry height (L)

h(t) Depth of water at time t (L) Yiobs The ith observation for the constituent

being evaluated (any units) hp(t) Depth of a particle at time t (L)

i Rainfall intensity (L/T) Yisim The ith simulated value for the

constituent being evaluated (any units) j Order of a reaction for decay rates (-)

k Decay rate constant (-) y(t) Vertical position at time t (L)

L Pathlength (L) Δh Change in height (L) MFraction Fraction of the total mass of

pollutants attributed to a wave of

particles (-)

Δt Change in time (T)

η Filling ratio of relative depth (-)

μ Dynamic viscosity of a substance

(M/L∙T) n Number of samples taken (-)

nr Manning's roughness coefficient (-) ρs Particle density (M/L3)

P Wetted perimeter (L) ρw Water density (M/L3)

Q Flow rate (L3/T) ρz1 Water density at depth z1 (M/L3)

Qin Flow rate in (L3/T) ρz2 Water density at depth z2 (M/L3)

Qout Flow rate out (L3/T) ρ4 Water density at 4oC (M/L3)

Qp Peak discharge (L3/T) ρ5 Water density at 5oC (M/L3)

1

Chapter 1 Introduction

Underground stormwater detention chambers (USDC) are a novel technology for the

detention and treatment of stormwater runoff; therefore, there is little information available to

accurately predict contaminant removal in the Ontario hydrology and climate. Stormwater

management (SWM) ponds have been the most widely employed management practice in urban

drainage in Ontario for over 40 years (Marsalek et al., 2003). SWM ponds share many similar

features to USDC: both of these stormwater treatment technologies detain runoff with a

permanent pool and an orifice which restricts flow to a set maximum; they both have

sedimentation forebays just after their inlets to capture larger particles which are brought in by

runoff; and both are end-of-pipe systems.

Despite their similarities, there are several key differences between SWM ponds and

USDC which prevent research conducted on SWM ponds from being directly applied to USDC.

1. SWM ponds use a combination of plant species and settling to remove nutrients

and metals from runoff. Also, bacteria present in SWM ponds are deactivated by

sunlight exposure. USDC are dark and unvegetated so pollutant removal

mechanisms are limited to physical processes such as sedimentation.

2. Winter has a significant effect on SWM ponds, such as thermal stratification and a

reduction in dissolved oxygen concentration, its effects on USDC are unknown.

3. The various concrete structures within the USDC change the flow path of the

water significantly, which causes turbulence and may or may not assist in the

removal of contaminants. In SWM ponds the flow hydraulics are assumed to be

very simple and is usually assumed to have a constant speed and direction.

2

4. USDC are not open to the environment so they are not affected by solar radiation.

Therefore, the thermal issues with SWM ponds, such as elevated effluent

temperature and thermal gradients, may be avoided.

All of these factors combine such that the conditions within a USDC are unique and so

must be researched as a separate entity to the SWM pond.

The specific USDC monitored for this project is a StormTrap-DoubleTrapTM unit

produced by Con Cast Pipe. A significant economic advantage of the StormTrap system is the

dynamic behavior in which a system can be designed. Each StormTrap is built from various

types of cells in order to create an individual and tailored design for the site. An example of one

of these cells is shown in Figure 1. The cells are attached in such a way that they direct and store

runoff as required by the engineer.

Figure 1: StormTrap Cell Top and Bottom - Con Cast Pipe Facilities June 4, 2014

Each cell is constructed from a rebar cage that is encased in concrete. Rebar is welded

together on site by hand with the exception of the top/bottom grate, which has a much denser

mesh than the pillars. Clamps are installed in the top of the rebar cage for moving the finished

product. Figure 2 (left) shows a standard rebar cage. The cages are placed inside of a mold with

3

sides that open and close to allow placement of the cage and removal of the finished cell half

(Figure 2 (right)). The molds are coated in a form release agent so that the finished cell can be

removed easily after curing.

Figure 2: StormTrap Rebar Cage (Left), Cell Mold (right) - Con Cast Pipe Facilities June

4, 2014

After the rebar cages are installed, the doors are closed and a high slump concrete is

discharged into the mold. The high slump allows for the concrete to spread easily in and around

the rebar cage and results in a smooth finish for an aesthetic appearance. Manholes can be

installed in the top of a cell by placing a Styrofoam cylinder on top of the rebar cage then

pouring concrete around it. After the concrete has cured, the Styrofoam is removed and a

manhole is placed into the hole that is left. Before and after photos of the concrete pouring

process can be seen in Figure 3 and Figure 4 (left). Following the pouring process, the mold is

covered by a tarp; this tarp holds in steam that is pumped in (Figure 4 (right)). The steam keeps

the concrete moist and regulates the temperature inside the tarp to assist the curing process which

takes 12 hours.

4

Figure 3: StormTrap Cell in Mold (left) with Manhole Styrofoam (right) - Con Cast Pipe

Facilities June 4, 2014

Figure 4: StormTrap after Concrete Pouring (left) Mold Covered by a Tarp (right) - Con

Cast Pipe Facilities June 4, 2014

USDC are an appealing design option for municipalities considering stormwater

management plans because the land on which the system resides can be restored to be used for

alternative purposes, such as parkland, and there is no risk of pedestrians falling in to open water

as with SWM ponds. However, with the strict water quality laws in place for stormwater runoff

treatment, it is risky for engineering consultants to include a newer and less studied technology

in stormwater management designs. A general estimate of cost for a StormTrap is approximately

$250/ m3 for the material and freight, and $50/ m3 for the installation with 500 mm of cover

(Gross, 2015). With more research and design tools available, USDC can be better compared

against other stormwater management technologies and used with greater confidence.

5

The purpose of this research is to gain an understanding of how a USDC acts in an

Ontario climate. Research objectives are to:

1. Identify the stormwater treatment capabilities of underground stormwater

detention chambers using on-site monitoring.

2. Compare the runoff treatment from underground stormwater detention chambers

to stormwater management ponds.

3. Create a model that predicts the removal of contaminants in underground

stormwater detention chambers.

The thesis consists of six chapters, they are structured as follows:

Chapter 1 (Introduction): Introduces thesis topic, outlines objectives, and presents the thesis

structure.

Chapter 2 (Relevant Literature): Presents relative background theory on the removal of

pollutants in SWM ponds and techniques used for modeling this removal.

Chapter 3 (Methodology): Outlines the characteristics of the monitoring site, the equipment

used for monitoring, and how the model was constructed.

Chapter 4 (Water Quality Results): Discusses the results of the site runoff analysis and

compares them to standard SWM pond removal capabilities.

Chapter 5 (Model Results): Discusses the calibration and validation of the SWMM model

hydraulics and hydrology, the assessment of the pollutant removal modeling, and the results of

several simulations.

Chapter 6 (Conclusions and Recommendations): Presents conclusions of the thesis research and

discusses future research directions and recommendations.

Appendix A: Presents the layout of the MUDS Interface as of April 2015.

Appendix B: Provides an explanation of the calculation for removal efficiency by MUDS.

Appendix C: Presents hydrograph and depth figures of storms used for validation and

calibration of the SWMM model.

6

Chapter 2 Relevant Literature

2.1 Urbanization and Stormwater Management

Stormwater management is a key issue in the design of urban infrastructure. Sustained

increases in urbanization have resulted in large-scale replacement of pervious land by impervious

surfaces, which reduces infiltration rates and available surface storage (Natarajan and Davis,

2010). Due to these changes, a larger proportion of urban precipitation becomes runoff. Runoff is

removed from the immediate area through storage and conveyance infrastructure where it is

directed to a nearby water body. Examples of pre- and post-urbanization hydrographs that show

the discharge rate from a watershed can be seen in Figure 5. The pre-urbanization hydrograph

has a significantly smaller peak discharge and the total volume of runoff is far less so there is

less risk of flooding the river or catch basin that is accepting flow from the area.

Figure 5: Pre vs. Post-Urbanization Hydrographs

This phenomenon can be explained simply by using a standard engineering equation for

calculating runoff, the Rational Equation:

7

𝑄𝑝 = 𝑐𝑖𝐴 (1)

where Qp is the peak discharge, c is the runoff coefficient, i is the rainfall intensity, and A is the

drainage area. As an area becomes more impervious, the coefficient c approaches 1, which

results in a larger peak discharge. There are several issues associated with an increased peak

discharge which include: increased flow volumes through rivers; increased flow rates in rivers;

increased duration of high volume and flow rate; and increased frequencies of high runoff events

(Shaver et al., 2007). This results in physical damage to waterways and aquatic habitats by

eroding the soil which supports aquatic plants and shapes the watercourse. A loss of aquatic

plants removes the food source for aquatic organisms and erosion expands the flow channel

increasing flow rates which makes flooding downstream more common (Shaver et al., 2007).

Urban floods occur when the peak discharge exceeds the capacity of the natural and municipal

systems. Depending on the severity of the storm there is potential for significant damage to

property, or even loss of life. For example, a storm which occurred in Toronto in 2013 resulted in

$65 million in damage (National Post, 2014). A stormwater management system will inevitably

fail, but the robustness of the design determines how often it fails and how costly each failure is.

Municipal systems are generally designed for 5-10 year return period events.

Increased runoff volumes are not the only threat to waterways; pollutants which are

prominent in urban areas are transported to receiving water bodies during runoff events.

Pollutants are deposited on impervious surfaces through human activities and atmospheric

deposition; during a runoff event, these pollutants are transported from the surface into the runoff

which then flows into the receiving water body. This process is commonly referred to as non-

point source pollution which is defined as, “having loadings which are discontinuous in time,

frequently not concentrated in a single location, and highly responsive to climate conditions,”

8

(Thomson et al., 1997). The specific types, sources, and environmental issues associated with

stormwater pollutants are explored further in Section 2.2.

The necessity for flow and pollutant control resulting from increased stormwater runoff

has led to the creation of several technologies. These include: coalescing plate separators; dry

detention ponds; wet ponds; constructed wetlands; grassed channels; vegetated filter strips;

porous pavement; and bioretention filters. For a complete explanation of how each of these

technologies function and what they are designed for as well as several more technologies, refer

to Greater Vancouver Sewerage and Drainage District (1999).

The treatment capability of a technology is generally measured using the removal

efficiency term for which there is three ways to define: direct ratio, event mean concentration

(EMC) efficiency, and mass load efficiency (He et al., 2014).

1. Direct Ratio Method:

𝑅𝑒𝑚𝑜𝑣𝑎𝑙 (%) =

1

𝑛∑ 100 ∗

𝐶𝑖𝑛 − 𝐶𝑜𝑢𝑡

𝐶𝑖𝑛𝑛

(2)

Assumptions and limitations of this approach include:

n is the number of samples taken

Cin/Cout are the concentration in/out

Assumes measured concentrations are from the same well mixed source (rarely

occurs under environmental sampling conditions)

Does not account for flow

2. Event Mean Concentration:

𝑅𝑒𝑚𝑜𝑣𝑎𝑙 (%) =

∑ 𝐶𝑖𝑛𝑖𝑛𝑖𝑛𝑖𝑛𝑖𝑛

−∑ 𝐶𝑜𝑢𝑡𝑗

𝑛𝑜𝑢𝑡𝑗

𝑛𝑜𝑢𝑡

∑ 𝐶𝑖𝑛𝑖𝑛𝑖𝑛𝑖

𝑛𝑖𝑛

(3)

9

Assumptions and limitations of this approach include:

Calculated by averaging the inflow and outflow concentration across the storm

event

Does not account for flow

3. Mass Load Efficiency:

𝑅𝑒𝑚𝑜𝑣𝑎𝑙 (%) =

∑ 𝛥𝑡𝑖 ∗ 𝑄𝑖𝑛𝑖 ∗ 𝐶𝑖𝑛𝑖𝑖 − ∑ 𝛥𝑡𝑗 ∗ 𝑄𝑜𝑢𝑡𝑗 ∗ 𝐶𝑜𝑢𝑡𝑗𝑗

∑ 𝛥𝑡𝑖 ∗ 𝑄𝑖𝑛𝑖 ∗ 𝐶𝑖𝑛𝑖𝑖 (4)

Assumptions and limitations of this approach include:

Conserves total particle mass

Accounts for varying flow

Preferred choice for calculating removal efficiency since it uses conservation of

mass

While these methods are widely used and accepted, there are several issues with the

percent removal efficiency concept. For example, if a treatment technology is tested using a very

polluted sample, then the removal efficiency may be large even if the outlet concentration is still

high. Removal efficiencies do not guarantee that the effluent will not harm aquatic organisms.

Also, even in systems with a short residence time, particle concentrations at the inlet and outlet

may not be closely related (He et al., 2014); particles from previous storm events are present in

the storage and can interfere with the analysis of pollutants from the current storm.

2.2 Stormwater Management Pond Pollutant Characteristics

2.2.1 Total Suspended Solids Total suspended solids (TSS) is a crucial characteristic of runoff. It encompasses not

only clay, sand, and gravel particles which are washed away during runoff events, but also the

10

particulate forms of nutrients, heavy metals, and organics. Sources of TSS in runoff include

construction activities, road sanding/salting, decaying organic matter, metallic dust from car

brakes or engines, and erosion (International Stormwater BMP Database, 2011a). The amount of

TSS which may be present during a runoff event depends on the land use characteristics. The

National Stormwater Quality Database (NSQD) studied this phenomenon and the results can be

seen in Figure 6 (International Stormwater BMP Database, 2011a).

Figure 6: Median Stormwater TSS Concentrations from NSQD

Due to the strong correlation between TSS and other pollutant concentrations, it is

frequently used as an indicator parameter to characterize overall water quality. The broad range

of pollutants which are part of TSS make it strongly correlated with: biochemical oxygen

demand (BOD) - the amount of dissolved oxygen required by organic organisms and increases as

more nutrients are available for reproduction; chemical oxygen demand (COD) – the amount of

dissolved oxygen consumed by contaminants which cannot be oxidized biologically; and heavy

metals such as lead, zinc and copper (Martino et al. 2011). Excessive sediment can adversely

impact aquatic life, source waters for drinking water supply, and water bodies used for

11

recreational activities. The negative effects of excess nutrients and metals are described in

sections 2.2.2 and 2.2.3 respectively.

In stormwater detention systems, suspended solids are removed solely by providing time

for particles to settle (Nix et al., 1988; Jayanti and Narayanan 2004). A detention system is

designed such that particles with a settling velocity greater than the terminal settling velocity –

the settling velocity of the smallest diameter particle which is 100% removed for a given design

event - are removed (Jayanti and Narayanan, 2004). The Ontario Ministry of Environment and

Climate Change (MOECC) defines enhanced protection by a stormwater treatment facility as

having achieved a long-term average removal of 80% suspended solids and by maintaining

maximum flow rates below or equal to pre-development values for storms with design return

periods ranging from 2 to 100 years (Ontario Ministry of Environment, 2003). To obtain the 80%

removal criteria, a sufficient volume must be provided so that, for the given design flow rate, the

particulates have time to settle before exiting the system. The ideal design of a detention facility

is long and thin; this prevents any potential short circuiting by pollutants to ensure that runoff is

treated for the designed length of time. Short circuiting can occur in detention facilities that are

too wide which results in poorer than expected performance. Baffling (Figure 7) is also installed

in cases where a high length to width ratio can not be obtained.

12

Figure 7: Structure With/Without Baffling

Standard TSS removal rates by SWM ponds can be found in Table 1 below. Included in

the table are several sources such as the International Stormwater BMP Database (2011a) and

Shaver et al. (2007) which have summarized data from numerous studies across the United

States of America. Overall, SWM ponds are a reliable way to achieve significant TSS removal in

ranges that achieve enhanced protection under MOECC standards; however, they must be

properly designed and maintained.

Table 1: TSS Removal Percentage by SWM

Source TSS % Removal

International Stormwater BMP Database, 2011a 80

Shaver et al., 2007 50-90

Greater Vancouver Sewerage and Drainage District, 1999 77

House et al., 1993 88

Stormwater Assessment Monitoring and Performance Program, 2005 81-92

Wu et al.,1996 62-93

Pitt, 2003 70-90

2.2.2 Nutrients When designing for stormwater treatment systems, nutrients (nitrogen and phosphorus)

must be adequately removed to maintain a healthy aquatic environment. While these are

13

generated in natural environments and are necessary for the health and growth of aquatic

organisms, excessive loadings of nitrogen and phosphorus from urban stormwater runoff can

have serious repercussions. With an increased concentration of nutrients, there is a greater

potential for eutrophication of the receiving water body. This process results in the rapid

production and decay of organic matter and ultimately in anaerobic conditions and the mass

mortality of organisms (Hu, 2001). Furthermore, as eutrophication progresses there is potential

for aquatic species imbalances, public health threats, and a decline in resource value. As of 2010

over 14,000 water bodies across the United States of America were listed as impaired for

nutrients, organic enrichment, algal growth, and/or ammonia (International Stormwater BMP

Database, 2010).

The effects of eutrophication on ecosystems are not limited to small lakes and rivers but

can even have a significant effect on the Great Lakes. In 2011, Lake Erie experienced its largest

algal bloom in history due to problems with phosphorus enrichment from rural and urban

sources; this resulted in impaired water quality, and impacts on ecosystem health, drinking water

supplies, fisheries, recreation, tourism, and property values (International Joint Commission,

2013). Similar issues as those in Lake Erie have also been found in Lake Simcoe, Ontario

(Environment Canada, 2014). Both urban and rural activities have contributed to the increase of

nutrients in rivers and lakes, some examples include: agriculture, fertilization of lawns and fields,

treated sewage effluent, septic systems, combined sewer overflows, sediment erosion, and

animal waste.

Total phosphorus (TP) and total nitrogen (TN) are present as both soluble and dissolved

forms in stormwater runoff; these phases of nutrients can be further divided. Particulate phase

phosphorus is composed of bacteria, algae, detritus, zooplankton and inorganic particulates such

14

as silt and clay (Shaver et al., 2007). Dissolved phosphorus can be divided into soluble reactive

phosphorus (SRP) and soluble unreactive phosphorus (SUP). SRP is comprised of

orthophosphates and is available for uptake by plants, algae, and microorganisms whereas SUP

is primarily comprised of polyphosphates and various organic compounds not available for

uptake (Shaver et al., 2007). Nitrogen found in stormwater runoff is comprised of nitrate, nitrite,

and total kjeldahl nitrogen (TKN) which is the sum of ammonia, organic, and reduced nitrogen

(United States Environmental Protection Agency, 2015). Vaze and Chiew (2004) found that 85%

of TP and TN are attached particles less than 300µm in diameter. Vaze and Chiew (2004) also

observed that 60% of TP are attached to particles ranging between 11 and 150 µm in diameter;

the majority of TN was also in this range of particles but the fraction was much more variable.

Therefore, by removing suspended particles with diameters of 300 µm and smaller from

stormwater, it will simultaneously proveide water quality treatment for TSS and nutrients. The

dissolved component for TN and TP in urban runoff can range from 20-50% and 20-30%

respectively, this fraction of nutrients is not affected by sedimentation processes (Vaze & Chiew,

2004).

A 2003 study by the Water Environment Research Federation (WERF) found that by

removing TP and phosphate particles with diameters greater than 20, 5, and 0.45µm,

approximately 70, 80, and 90% of the particles were removed, respectively. Median

concentrations of total and soluble phosphorus, ammonia, and nitrate and nitrite based on land

use were found by the NSQD and the National Urban Runoff Program (NURP); these can be

seen in Table 2 below (International Stormwater BMP Database, 2010).

15

Table 2: Median Total and Soluble Phosphorus, Ammonia and Nitrate/Nitrite

Concentrations by Land Use

Source Residential Mixed Commerical Open Space/Non-Urban

NSQD

TP (mg/L) 0.17 - 0.11 0.13

Ammonia (mg/L 0.32 - 0.50 0.18

Nitrate and Nitrite (mg/L) 0.60 - 0.60 0.59

NURP

TP (mg/L) 0.38 0.26 0.20 0.12

Soluble P (mg/L) 0.14 0.056 0.08 0.026

The removal and transformation mechanisms for the various forms of nitrogen and

phosphorus have been summarized in Table 3 and were adapted from the International

Stormwater BMP Database (2010).

Table 3: Summary of Nitrogen and Phosphorus Transformations and Removal

Mechanisms

Species Transformation and Removal Mechanisms

Particulate Phosphorus Physical separation (filtration and sedimentation)

Orthophosphates Adsorption/precipitation onto soil

Plant and microbial uptake

Nitrogenous Organic

Solids

Physical separation (filtration and sedimentation)

Ammonification (transform via microbial decomposition to NH4

Nitrate (NO3)

Plant uptake

Denitrification (removal via biological reduction to N2 gas and

volatilization)

Ammonia (NH4+, NH3)

Volatilization

Nitrification (transform via biological oxidation to NO3 via NO2)

The MOECC developed general guidelines for concentrations of ammonia and total

phosphorus (TP) to prevent aesthetic and water quality deterioration. For un-ionized ammonia, a

guideline of 20µg/L was set (Ministry of Environment and Energy, 1994). For TP, the guidelines

recommended are 10µg/L for a high level of protection against aesthetic deterioration, 20µg/L to

avoid nuisance concentrations of algae in lakes, and 30µg/L to prevent excessive plant growth in

rivers and streams (Ministry of Environment and Energy, 1994).

16

Removal efficiency of SWM ponds for nutrients in stormwater runoff are shown in Table

4. There is a wide range in removal efficiency. This is most likely due to variations in local

conditions such as vegetation type and quantity, and the dissolved fraction of nutrients.

Table 4: Nutrient Removal Efficiency by SWM Ponds

Source TN TKN

Nitrite +

Nitrate Nitrate TP

TSP

(Soluble) DP

Ortho-

PO4

International

Stormwater BMP

Database, 2010

27 15 62

59

45 64

Shaver et al., 2007 30

50

Greater Vancouver

Sewerage and

Drainage District,

1999

30

24 47 51

House et al., 1993

38 65

38

Stormwater

Assessment

Monitoring and

Performance Program,

2005

42-87

Wu et al., 1996

21-32

36-45

Pitt, 2003 60-70

60-70

2.2.3 Heavy Metals In urban environments, heavy metals originate primarily from automobiles and exposure

of building materials to rain; if a metal is naturally abundant then it may be present in stormwater

due to soil erosion and weathering. Treated wood, tires, and atmospheric deposition are also

common sources of metals (International Stormwater BMP Database, 2011b). A summary of the

sources of several common metals are shown in Table 5. Metal concentrations in stormwater

runoff have been found to be 10-100 times the average concentration in sanitary effluent water

(Sansalone and Cristina, 2004). As of 2011, over 7,400 water bodies in the United States of

America are listed as impaired due to metals (USEPA, 2015).

17

Table 5: Common Sources of Metal in Urban Runoff (Shaver et al., 2007)

Metal Source

Copper

Building materials

Paints and wood preservatives

Algaecides

Brake pads

Zinc

Galvanized metals

Paints and wood preservatives

Roofing and gutters

Tires

Lead

Gasoline

Paint

Batteries

Chromium Electro-plating

Paints and preservatives

Cadmium Electro-plating

Paints and preservatives

Heavy metals have been associated with many illnesses in humans and have strict

concentration guidelines in wastewater and drinking water treatment. However, there are no

MOECC requirements for treatment of heavy metals in stormwater runoff. While this water is

treated prior to distribution in drinking water systems to prevent human illness, it still poses a

risk to aquatic ecosystems as the metals can bioaccumulate in organisms, which has adverse

effects (Center for Hazardous Substance Research, 2009). Typical levels of metals that are found

in stormwater runoff can be seen in Table 6 which was adapted from Shaver et al. (2007).

Table 6: Typical Levels of Metals Found in Stormwater Runoff (µg/L)

Metal Stormwater Median

(90th Percentile)a

Mean

(sd)b

Median (Cov)

Urban

Stormwaterc

Range for

Highway

Runoffd

Range for

Parking lot

Runoffe

Arsenic N/A 5.9 (2.8) 3.3 (2.42) 0-58 N/A

Cadmium N/A 1.1 (0.7) 1.0 (4.42) 0-40 0.5-3.3

Chromium N/A 7.2 (2.8) 7.0 (1.47) 0-40 1.9-10

Copper 34 (93) 33 (19) 16.0 (2.24) 22-7033 8.9-78

Lead 144 (350) 70 (48) 15.9 (1.89) 73-1780 10-59

Mercury N/A N/A 0.2 (1.17) 0-0.322 N/A

Nickel N/A 10 (2.8) 9.0 (2.08) 0-53.3 2.1-18

Silver N/A N/A 3.0 (4.63) N/A N/A

Zinc 160 (500) 215 (141) 112.0 (4.59) 56-929 51-960

Sources of Research Cited by Shaver et al. 2007: aUSEPA, 1983. bSchiff et al., 2001. cPitt et al., 2002. dBarrett et al., 1998. eTiefenthaler et al., 2001

18

Metals can occur in particulate, dissolved, or colloidal forms; however, a great proportion

is bound to particles (Li et al., 2005). For example, in a study by the United States Geological

Survey (2011), 74% of total metal load in Wisconsin storm sewers was in particulate form

(United States Geological Survey, 2011). Particulate-bound pollutants are predominately

attached to smaller particles, and particles less than 25µm in diameter can represent around 90%

of the total surface area (Pettersson, 2002). Particle phases of some metal elements such as

copper and nickel will increase with sample holding time as they tend to precipitate out of their

dissolved form (Li et al., 2008).

Metals which are in their precipitate form can be removed through sedimentation and/or

filtration; the dissolved fraction can be removed through sorption and precipitation processes.

WERF (2005) determined the percent removal of various metals after the removal of several

particle sizes, this is summarized in Table 7.

Table 7: Percent Reduction in Metals after Removal of Various Particle Sizes

Metal Particle Size (µm)

>20 >5 >1 >0.45

Cadmium 20 22 22 22

Copper 26 34 34 37

Lead 41 62 76 82

Iron 52 63 95 97

Zinc 64 70 70 72

Chromium 69 81 82 84

Approximate removal efficiencies of metals in SWM ponds are shown in Table 8. As can

be seen, the physical processes which remove particulates from stormwater runoff also remove

significant portions of metals. However, the most effective method for removing metals from

runoff is removing the various sources from which it originates. The MOECC has several

provincial water quality requirements for metals, those being monitored are listed in Table 9;

these drinking water quality standards.

19

Table 8: Percent Removal of Metals by SWM

Source Total

Arsenic

Total

Cadmium

Total

Chromium

Total

Copper

Total

Iron

Total

Lead

Total

Nickel

Total

Zinc

International

Stormwater

BMP Database,

2011b

23 33 60 40 76 70 53 62

Greater

Vancouver

Sewerage and

Drainage

District, 1999

24

57

73

51

Stormwater

Assessment

Monitoring and

Performance

Program, 2005

10-67

70-87

Wu et al., 1996

52-87

32-80

Table 9: Metals Provincial Water Quality Requirements

Metal Provincial Water Quality Requirement (μg/L) Aluminum *(Interim) 75 Antimony *(Interim) 20

Arsenic 100 Barium N/A

Beryllium Hardness < 75 mg/L - 11 Hardness > 75 mg/L - 1100

Boron 200

Cadmium *(Interim) Hardness 0-100 mg/L - 0.1 Hardness > 100 mg/L - 0.5

Chromium 1 hexavalent, 8.9 trivalent Cobalt 0.9 Copper 5

Iron 300

Lead *(Interim) Hardness < 30 mg/L - 1

Hardness 30-80 mg/L - 3 Hardness > 80 mg/L - 5

Manganese N/A Molybdenum *(Interim) 40

Nickel 25 Selenium 100

Silver 0.1 Strontium N/A

Thallium *(Interim) 0.3 Titanium N/A

Uranium *(Interim) 5 Vanadium *(Interim) 6

Zinc *(Interim) 20

20

2.2.4 Temperature The thermal properties of an aquatic system are generally determined by local

environmental and weather conditions, such as heat from the overlying air, solar radiation, and

heated urban runoff (Song et al., 2013). SWM ponds consistently produce thermally enriched

effluent due to prolonged exposure to solar radiation during detention and runoff that underwent

heat exchange with impervious surfaces. As the effluent enters a receiving water body it can

cause damage to local ecosystems. For example, increases in stream temperature can negatively

impact behaviour, metabolism, reproduction, growth, and vulnerability to disease in various

Trout species (Jones, 2008).

Thermal stratification – when a relationship exists between the depth and temperature of

water – has been observed in SWM ponds (Jones, 2008). This is due to extended detention times

and solar radiation heating the surface of the pond. Strong stratification can slow or prevent the

exchange of materials between the surface and bottom waters. Song et al. (2013) studied thermal

stratification patterns in urban ponds and found that concentrations of dissolved oxygen were

consistently higher in the surface relative to bottom waters and higher concentrations of

suspended solids, TP, and particulate nutrients were in bottom waters. Differences in TP and

particulate phosphorus were strongly related to stratification intensity, but differences in total

dissolved phosphorus concentrations were significantly related to the duration of stratification

rather than intensity. If thermal stratification occurs in a USDC, it may act similarly to SWM

ponds.

USDC are a potential mitigation to elevated runoff temperatures. Natarajan and Davis

(2010) studied a USDC in Maryland and showed that its outflow temperatures were more

uniform compared to the runoff. The USDC achieved a mean reduction in temperature of 1.6oC

during July, and its mean outflow temperature was only 19.7oC. This reduction in temperature

21

was attributed to the cooler ambient air temperatures in a USDC and the lack of solar radiation.

Accordingly, the USDC did not have a cooling effect on runoff at lower temperatures. The

thermal effects of USDC was not reported.

2.2.5 First Flush The first flush of contaminants from the beginning of a storm event delivers a high

concentration or mass of pollutants into the receiving water body (Sansalone and Cristina, 2004).

In some cases, the stormwater runoff pollution in first flush can be comparable to or greater than

sewage pollution (Martino et al., 2011). Although the potential for occurrence of first flush is

widely recognized there is no unified definition but many have been proposed (Hallberg, 2006).

For example, Bertrand-Krajewski et al. (1998) propose a 30/80 first flush definition where 80%

of the pollutants from a runoff event occur in the first 30% of flow into a facility; but 20/80 and

25/50 definitions have also been proposed by Stahre and Urbonas (1990) and Wanielista and

Yousef (1993) respectively. Designing for, or enhancing, the treatment of first flush runoff can

improve the overall performance of a treatment facility (Li et al., 2008).

There are two ways of determining whether a first flush has occurred; mass-based and

concentration-based methods (Sansalone and Cristina, 2004). The mass-based method is defined

by the following formula:

Cumulative Mass (t)

Total Mass>

Cumulative Volume (t)

Total Volume (5)

This method is particularly appealing as it can be interpreted graphically with ease, using

a mass-volume (M(V)) curve, and it can be used to compare storms on a similar scale regardless

of storm length (Figure 8). M(V) curves have been shown to fit well with the following formula:

𝑌 = 𝑋𝑏 (6)

22

where Y is the Cumulative Mass/Total Mass and X is the Cumulative Volume/Total Volume

(Bertrand-Krajewski et al., 1998). Higher values of b indicate a higher first flush effect

(Sansalone and Cristina, 2004).

Figure 8: 25/50 M(V) Curve

The concentration based method is not so mathematically straightforward, but is instead a

set of conditions which suggest a first flush has occurred. First, there must be a high initial

concentration followed by a rapid concentration decline. Subsequently, there is a relatively low

and constant concentration.

2.2.6 Winter Conditions

During the winter, pollutant load increases dramatically; this is due to the use of de-icing

agents which increase the chloride and TDS concentrations (Hallberg, 2006, Marsalek et al.,

2003). Studded tires which are used during the winter also contribute to larger TDS

concentrations as they increase the wear on asphalt pavement (Hallberg, 2006).

Marsalek et al. (2003) noted several characteristics in SWM ponds that occur through the

winter. The ice layer which seperates the pond water from the air caused the water to lag air

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

0 0.2 0.4 0.6 0.8 1

Y:

Cu

mu

lati

ve M

ass/

To

tal M

ass

X: Cumulative Volume/ Total Volume

23

temperature by 3-4 days, the amplitude for water temperature was 4.4oC less than air

temperature, and fluctuations in daily water temperature were 1/3 that of the air temperature.

Marsalek et al. also observed that the dissolved oxygen (DO) concentration decreased to 0 from

mid-December to mid-January, this is undesireable because a lack of DO can lead to the

mortality of aquatic organisms and plants. Lastly, density stratification occurred due to thermal

stratification and chemical stratification by dissolved solids (particularly chloride) (Marsalek et

al., 2003).

2.3 Modeling of Stormwater Management Ponds

SWM and the USDC use similar removal processes to treat pollutants in stormwater

runoff. Therefore, many of the models that have been developed for SWM ponds and

sedimentation tanks can be applied or modified to simulate the removal of pollutants in USDC.

2.3.1 K-C Decay Rate Model The K-C model has been shown to be applicable for vegetated and non-vegetated ponds

(Wong et al., 2006). Reactor kinetics which are prominent in water and wasterwater treatment

processes are used to create the decay rate formula (Equation 7).

𝑟𝐴 =

𝑑𝐶

𝑑𝑡= −𝑘𝐶𝐴

𝑛

(7)

The reaction rate (rA) is defined as the change in concentration of the pollutant over time

(mg/L∙s), k is a decay rate constant which is specific to the pollutant, and CA is the concentration

of the pollutant in the SWM pond (mg/L). The value of n defines the order of the reaction (eg.

first order, second order) with higher orders decaying at faster rates.

Conceptually, a stormwater pond will follow plug-flow reactor (PFR) mechanics.

However this condition rarely, if ever, occurs in the field as some degree of mixing is always

24

present. A continuously stirred tank reactor (CSTR) matches the flow conditions through a pond

well (Wong et al., 2006). The equations for PFR and CSTR reactor mechanics can be seen in

formulas 8 and 9, respectively.

𝑃𝐹𝑅 𝑉

𝐹= ∫

𝑑𝐶𝐴

𝑟𝐴

𝐶𝐴

𝐶𝐴0

(8)

𝐶𝑆𝑇𝑅

𝑉

𝐹=

𝐶𝐴 − 𝐶𝐴0

𝑟𝐴 (9)

where V is the volume (m3), F is the flowrate (m3/s), and CAo is the concentration of the pollutant

as it enters (mg/L). While the PFR calculates the concentration at each time increment, the

effluent from a CSTR is based solely on its intial concentration. Depending on its design, a

SWM pond lies somewhere between PFR and CSTR flow conditions, so a number of CSTRs can

be used in series to predict correct effluent concentrations. This is accomplished by taking the

concentration exiting the previous CSTR and using it as the intial concentration in the next

CSTR. As the number of CSTRs approaches infinity the effluent concentration will equal that

calculated by the PFR equation. First order decay can be applied to TSS, TP, TN, BOD, and

Turbidity (Wong et al., 2006). However, TSS has also been modeled using second order decay

(Zawilski and Sakson, 2008).

2.3.2 Sedimentation Modeling sedimentation is more physically based compared to the previous K-C method.

The principles of sedimentation through gravity has been well studied as it is one of the primary

seperation processes used to treat water and wastewater (Jayanti and Narayanan, 2004). There

are four distinct classes of sedimentation:

1. Discrete Particle Settling: particles settle without interference from nearby particles.

25

2. Flocculent Settling: particles collide and adhere to one another increasing the settling

velocity

3. Hindered (or Zone) Settling: particles settle as a extremely high concentration layer

which has a single settling velocity

4. Compression Settling: particles that have settled to the bottom are compressed by

gravity.

In SWM ponds, sedimentation can be modeled using discrete particle settling, as no

flocculating agents are added to induce flocculent or hindered settling, and compression settling

has no effect on the effluent pollutant concentration. Fine suspended particles can flocculate of

their own accord, but will break up under certain flow conditions (Krishnappan & Marsalek,

2002); so, it is not a mechanism that can be reliably modeled and may overpredict removal

efficiency.

The removal efficiency is determined by ascertaining the critical settling velocity, which

is the flow rate divided by the SWM pond surface area. All particles with diameters larger than

the particle with a settling velocity equal to the critical settling velocity are fully removed. Some

of the smaller particles will settle while others flow out of the system; this depends on their

elevation after they enter the SWM pond and have been subject to turbulent mixing. The fraction

which is removed is directly proportional to their settling velocity divided by the critical settling

velocity. Figure 9 shows the potential paths a particle can take in a settling tank. V1 represents

the path of a particle with the terminal settling velocity, V2 has a settling velocity greater than

V1, and V3 has a settling velocity less than V1. If V3 entered at a higher elevation then the

particle would have exited the system.

26

Figure 9: Particle Sedimentation Paths

Stokes’ law (Equation 10) is commonly used to describe the settling velocity of a discrete

spherical particle for a given diameter and particle density:

𝑉𝑠 =

1

18

𝜌𝑠 − 𝜌𝑤

µ 𝑔𝑑𝑝

2

(10)

where ρs is the particle density (kg/m3), ρw is the water density (kg/m3), µ is the dynamic

viscosity of the fluid (Pa∙s), g is the gravitational constant (m/s2), and dp is the diameter of the

particle (m).

There are several assumptions in Stokes’ Law which may affect the accuracy. Firstly, the

velocity is heavily dependent on the density of the particle and this has an effect on the removal

efficiency; the lower the density, the lower the removal efficiency (Takamatsu et al., 2006). The

specific gravity of most soils and rocks typical in runoff is 2.65 (Freeze and Cherry, 1979).

However, Karamalegos (2006) reported that particles with diameters less than 75 µm had

average densities ranging from 0.81 g/cm3 to 2.80 g/cm3. Due to the variability in density,

Stokes’ law may over predict the removal efficiency of a sedimentation tank. The density of

particles has a significant effect on removal efficiency especially below 2 g/cm3 (Takamatsu et

al., 2010). Secondly, there is high variability in particle size distributions between and within a

site as well as over time. Variability between samples collected from a single site can often be

greater than the variability between samples collected from different sites (Toronto and Region

Conservation Authority, 2012a). Therefore, accurately and consistently predicting sedimentation

27

on a storm-by-storm basis is challenging. In Ontario, the Toronto and Region Conservation

Authority (2012a) have found that SWM pond samples collected throughout the Greater Toronto

Area often have finer particle size distributions than those collected in many other cold climate

jurisdictions. Lastly, the shape of the particles are unlikely to be spherical which is a basic

assumption of Stokes’ Law. Particle shape can range so any random particle may fall slower or

faster than a perfect sphere; therefore, this assumption is least likely to have a significant effect

on average settling velocity prediction.

Takamatsu et al. (2010) produced a sedimentation model which uses Stokes’ Law in

combination with the hydraulics of a dry stormwater pond (no permanent pool). This “pathline”

model tracks the location in the x and y direction of particles of a given diameter through a storm

event. Takamatsu et al. (2010)'s model consistently underestimated the removal efficiency of the

dry pond but only by a few percent.

2.3.3 Probabilistic Many runoff event properties can be described using probability distributions due to their

stochastic nature. The EMC of various pollutants are often described using a log-normal

distribution (Strecker et al., 2001, Buren et al., 1997, German and Svensson, 2002). However,

effluent concentrations have also been shown to follow normal distributions (Buren et al., 1997).

Table 10, which was adapted from Buren et al. (1997), shows the distributions associated with

various pollutants. EMC have been correlated with pollutant concentration in pond sediment

(German and Svensson, 2002). Particle size distributions in runoff and settling velocities for a

specific particle diameter can alse be described by log-normal distributions (Takamatsu et al.,

2006, Li et al.,2008).

28

Adams and Papa (2000), and Loganathan et al. (1985) have produced probabilistic

models to describe hydraulic and hydrologic processes of stormwater retention and detention

systems. These models provide a range of possibilities that a system may experience but cannot

predict results on a storm-by-storm basis.

Table 10: Distribution of Event Constituents (EMC)

Pollutant Source

Parking lot Creek inflow Pond Outflow

Constituent PL W2 PL W2 PL W2

TSS

TDS

COD

Chloride

TP

Sol. P

Sulphate

Ammonia

Sol. TKN -

Tot. TKN -

Oil & Gr

Phenol - -

-

Copper - -

-

Zinc - -

-

Normal PL – Results interpreted from a probability plot

Log-Normal

W2- Results from 95% acceptance Cramer-Von

Mises tests

Either

Neither -

2.4 Summary

The chapter above explains the necessity for controlling and treating runoff in an urban

environment. Preventing damage to receiving water bodies through high flow rates, high runoff

volumes, and the subsequent release of pollutants is essential to prevent damage to aquatic

environments. Furthermore, stormwater management systems assist in the prevention of

29

flooding, erosion, and damage to source waters which can have negative effects on health, safety,

and the local economy (Shaver et al., 2007).

The chapter describes common pollutants found in urban runoff including their sources

and the effectiveness of treatment by SWM ponds. TSS is an important factor for ensuring a

stormwater management system has been properly designed, it is often used as an indicator

parameter to assess overall water quality and compare removal processes. In Ontario, SWM

ponds are often designed with the intention of removing 80% of TSS which is the standard for

enhanced protection under MOECC standards (Ontario Ministry of Environment, 2003). Other

water quality characteristics that are commonly studied include the concentrations of nutrients,

metals, and temperature at the inlet and outlet of stormwater management systems; excessive

levels of any of these pollutants can cause severe damage to aquatic environments (International

Joint Commission, 2013).

The chapter also summarizes the common methods for modeling the removal of

pollutants by SWM ponds and settling tanks including the direct ratio method, event mean

concentrations, and mass load efficiencies. Removal of suspended sediments in a SWM pond can

be simulated using K-C decay models, sedimentation, or probabilistic models. Modeling the

process of sedimentation through physically based data is a straightforward and accurate method.

The literature presented in this chapter are applied in the following chapters to determine

the hydraulic and water treatment performance of the Markham UDSC. Conceptual and

theoretical models presented from this chapter are applied in the methodology discussed in

Chapter 3 to develop, test and apply MUDS using water quality data collected from the

Markham USDC

30

Chapter 3 Methodology

3.1 Field Site

The specific USDC monitored for this project services the South Unionville Square

development in the City of Markham, Ontario (Figure 10). The drainage area serviced by the

DoubleTrapTM is a new 5.24 hectare commercial and residential mixed-use development and is

one of the first in Ontario to feature such a system (Toronto and Region Conservation Authority,

2012b). The DoubleTrapTM was installed in July 2010 but was not connected to its full drainage

area until late 2011. One small section located immediately south of the DoubleTrapTM, across

South Unionville Avenue, remained under construction during this study. Sediment wash-off

from the construction site into the DoubleTrapTM was not a concern because little to no runoff

was expected because there was abundant surface storage in this area. Additionally, the site

occupied only a small portion of the total catchment area (6%).

Originally, a SWM pond was planned to control runoff, but was replaced with a

DoubleTrapTM in 2010 in order to double the available parkland. The DoubleTrapTM receives

runoff from the catchment and wastewater from a splash pad in the park. Several boxes which

contain monitoring equipment and prevent the public from accessing the system’s hatches are the

only indications that a USDC is installed on the site. Additional photos of the park, surrounding

area, and the remaining construction zone are shown in Figure 11 and Figure 12.

31

Figure 10: DoubleTrapTM Location and Service Area

Figure 11: DoubleTrapTM Site and Monitoring Boxes (Left), Construction Zone South of

the DoubleTrapTM (Right) (June 23, 2014)

32

Figure 12: Parkland Surrounding the DoubleTrapTM (June 23, 2014)

Figure 13 and Figure 14 show the various dimensions of the USDC. The DoubleTrapTM

has an approximate 1,200 m2 footprint, a maximum height of 3.4 m, and side lengths of 51.5 m

and 23.1 m. A permanent pool of 1,475 m3 is provided for water treatment, and an extended

storage volume of 1,143 m3 allows for a 25 mm storm to drain over 24 hours. A 1,200 mm pipe

at a height of 1.39 m relative to the bottom of the USDC directs runoff from the stormwater

sewer into the system. A 120 mm orifice plate installed in a 300 mm pipe drains water from the

system during a storm event; the maximum design flow rate is 0.03 m3/s which corresponds to

the preconstruction flow for a 5-year return period storm event. Two 525 mm overflow pipes are

installed and have a maximum flow rate of 1.39 m3/s. The 300 mm and 525 mm pipes are

installed at heights of 1.39 m and 2.45 m, respectively, relative to the bottom of the USDC.

Figure 15 shows the USDC as it has been built as well as its individual cells.

33

Figure 13: DoubleTrapTM Monitoring Equipment and Dimensions

Figure 14: DoubleTrapTM Dimensions (Side)

Figure 15: As Built DoubleTrapTM with Individual Cells

34

3.2 Monitoring

Monitoring was conducted by Toronto and Region Conservation Authority (TRCA)

technicians from May 2014 to early December 2014. The monitored water quality parameters

include: TSS, nutrients, metals, oil and grease, chloride, bacteria, turbidity, temperature, DO and

conductivity. The location of the various samplers and monitoring equipment is shown in Figure

13 with an explanation of each sensor in Table 11. Precipitation measurements were taken at

Milne Dam in the City of Markham, which is three kilometers east of the site (Figure 10). Flow-

weighted composite samples were collected and sent for water quality analyses at a MOECC lab.

The Hobo Water Level Logger and YSI monitors were positioned 0.04 m above the bottom of

the USDC. Data from the MOECC lab and monitoring equipment was sent to the University of

Toronto for processing and analysis.

Table 11: DoubleTrapTM Monitoring Equipment Properties and Purpose

Parameter Equipment Frequency Accuracy

Water Quality

ISCO Auto-samplers coupled

with water level sensors to

trigger start and end of

sampling

All storm events that

generate enough flow to

trigger the sampler

Water Level HOBO Water Level Logger Continuous measurements

at 5 minute intervals ± 3 mm

Temperature Hobo Water Level Logger Continuous measurements

at 5 minute intervals

±0.44o

(from 0 o to 50 oC)

Turbidity YSI monitors Continuous measurements

at 5 minute intervals

± 2% of reading or

0.3 NTU, whichever

is greater

Flow Rate/Volume ISCO ultrasonic water level

sensor attachment

Continuous measurements

at 5 minute intervals

± 0.03 m/s

(-1.5 to 1.5 m/s)

±2% of reading (1.5

to 6.1 m/s)

Conductivity/

Temperature

Profiles

Probe lowered to regular depth

intervals

Four profiles conducted

during summer and winter

seasons

Precipitation

0.2 mm Four season (heated)

tipping bucket precipitation

gauge

Continuous measurements

at 5 minute intervals

35

Hydraulic and water quality data collection was scheduled to begin in early May, but was

delayed due to construction and clean out activities. The parkland which houses the Markham

USDC remained under construction throughout May, and the permanent pool of the USDC

contained a significant amount of construction sediment that had eroded and washed off from the

surrounding area. Under these conditions, any data collected would be an inappropriate

representation of the hydraulics and treatment capability of the catchment and USDC. The

excessive sediment loads caused by the construction activities as well as the sediment already

present in the USDC permanent pool generated much higher pollutant concentrations than

typical urban runoff. By May 29th the park was finished, the USDC was emptied and cleaned so

useful data could start being collected.

The cleaning of the USDC required the permanent pool to be emptied. Afterwards, the

permanent pool filled gradually with runoff. Until June 21st, any runoff that occurred would not

generate outflow since the permanent pool needed to be refilled by runoff in the catchment.

Closely following the resumption of outflow, the orifice plate was clogged by garbage. This

interfered with the outflow measurements causing them to vary widely over short periods and not

be easily predicted by hydraulic equations. The orifice plate was unclogged on July 10th allowing

several storms to be monitored successfully until, on July 27th, the orifice plate was clogged

again. This was the final time that clogging occurred during the monitoring period, and was

remedied on August 12th.

In mid-August the Town of Markham installed a splashpad at the park which had an

outlet leading to the inlet of the USDC. On several occasions, the splashpad was observed

flowing during storm events. The inflow hydrograph for the model was generated using SWMM

so it can only account for flows due to rainfall, making accurately predicting the outflow difficult

36

due to the unknown splashpad flow rate. This was also causing issues with sample collection as

the ISCO sampler at the inlet would activate due to the splashpad flow and capture water that

was previously in the municipal water system instead of runoff from the catchment. To account

for these issues, a flowmeter was installed in the piping leading from the splashpad to the USDC

inlet and the sampling tube of the ISCO sampler was moved further up the stormsewer system

where it would not receive flow from the splashpad. The splashpad was shut down on September

17th.

Monitoring continued until December 2nd when the equipment was removed for the

winter. There were no issues gathering hydraulic data until this point. However, the turbidity

meters malfunctioned in November with the YSI monitor near Hatch 1 providing negative values

until November 10th, and the YSI monitor near Hatch 5 providing negative or unreasonably low

values until November 24th. For this reason water quality could not be modeled for the storm

events that occurred in November but could still be used for hydraulic calibration.

During the monitoring phase it was also discovered that the Markham USDC had been

overdesigned. Originally the USDC was supposed to accept runoff from close to 8 hectares but a

section of the catchment area was excluded later, so it only receives runoff from a 5.24 hectare

catchment. Therefore, the USDC should perform above expectations for storms that would cause

a failure to occur for a more optimally designed USDC.

3.3 Water Quality Analysis

Descriptive statistics such as: range, average, median, and standard deviation, were

calculated. Statistical analyses were used to determine whether the average concentration of a

given pollutant changed to a 95% significance level (p<0.05). Paired t-tests were performed to

compare the average EMC of pollutants observed at the inlet, Hatch 2, and outlet. Paired t-tests

37

operate under the assumption that the data is represented by a normal distribution, in order to

ascertain the distribution of data for each pollutant, the EPA's statistical software ProUCL 5.0

was utilized. If the data was not normally distributed it was transformed using conversion

formulae specific to the actual distribution. Paired t-tests were performed with the transformed

data set to determine statistical significance.

3.4 Modeling

This section presents the methodologies used by The Model for Underground Detention

of Sediment (MUDS) to predict TSS removal efficiency of a USDC. The basic mathematical and

physical principles that govern the hydraulics, particle tracking, and pollutant removal are

discussed. A summary of a Storm Water Management Model (SWMM) that was also created to

estimate inflows to the Markham USDC is also included.

MUDS was constructed by Nicholas McIntosh at the University of Toronto in 2014, it

utilizes Excel’s interface combined with the Visual Basic compiler that is accessible through

Excel’s Macro function. MUDS is designed to simulate the hydraulics and pollutant removal of a

USDC regardless of location and layout. The required input parameters are: an inflow

hydrograph; timestep length; USDC dimensions; the particle size distribution (d10 – d90) and

density of pollutants in runoff; water density and dynamic viscosity; and the first flush

pollutant/flow proportion. These parameters are used to calculate the outflow hydrograph and

TSS removal efficiency. The large number of variables makes MUDS versatile for a broad range

of design applications. Runoff inflows to the Markham DoubleTrapTM could not be directly

monitored because the stormwater inlet and outlet are at the same elevation; therefore, the inlet

water levels fluctuate with the active storage inside the Markham USDC which can cause

backwater conditions at the inlet. As a result, inflow hydrographs were generated by creating a

38

SWMM model which was calibrated and validated for the Markham USDC catchment (Section

3.4.5). A diagram of MUDS’ layout is included in Appendix A.

3.4.1 Hydraulics The flow of water into and out of a USDC can be described by a continuity equation:

𝑑𝑆(𝑡)

𝑑𝑡= 𝑄𝑖𝑛(𝑡) − 𝑄𝑜𝑢𝑡(𝑡)

(11)

where Qin and Qout are the flow in and out of the USDC (m3/s), S is the storage in the USDC

(m3), and t is the time (s). As a rectangular reservoir system, the change in storage (dS) is

expressed solely in a change in water height (dS = SA*dh) where SA is the surface area (m2), and

h is the water height (m). The continuity equation can be further expressed as:

𝑑ℎ(𝑡)

𝑑𝑡=

1

𝑆𝐴(𝑄𝑖𝑛(𝑡) − 𝑄𝑜𝑢𝑡(𝑡))

(12)

Outflow is calculated using a circular sharp-crested weir equation developed by

Vatankhah (2010) for partially-full flow conditions and using a full orifice flow equation for full

flow conditions (Table 12).

Table 12: Outflow Equations

Condition Equations Terms

Partially Full

Flow

(Vatankhah,

2010)

𝜂 =𝐻𝑤

𝑑 (13)

η- filling ratio or

relative depth

Hw- depth of water

above the orifice invert

(m)

d- orifice diameter (m)

Cd- Orifice loss

coefficient

Q- flow out of orifice

(m3/s)

𝐶𝑑 =0.728 + 0.240𝜂

1 + 0.668√𝜂 (14)

𝑄 = 0.3926𝐶𝑑√2𝑔𝐻32𝑑𝜂

12(√1 − 0.2200𝜂

+ √1 − 0.7730𝜂 ) (15)

Full Orifice

Flow

(Chin, 2013) 𝑄 = 𝐶𝑑𝐴√2𝑔𝐻𝑜 (16)

Ho- depth of water

above midpoint of

orifice (m)

g- gravitational constant

(m/s2)

A- orifice area (m2)

39

The partially full flow is significantly influenced by the ratio of depth above the orifice

invert to the diameter of the orifice (η). As the depth increases, the loss coefficient (Cd) – the

fraction of energy transferred to the water after passing through an orifice – decreases and the

outflow increases; Cd for full orifice flow in a circular orifice has a value of approximately 0.6

(Brater et al., 1996).

Modeled outflows are compared against the measured data using the Nash-Sutcliffe

efficiency (NSE) equation:

NSE = 1 − [∑ (𝑌𝑖

𝑜𝑏𝑠 − 𝑌𝑖𝑠𝑖𝑚)

2ni=1

∑ (𝑌𝑖𝑜𝑏𝑠 − 𝑌𝑖

𝑚𝑒𝑎𝑛)2n

i=1

] (17)

where Yiobs is the ith observation for the constituent being evaluated, Yi

sim is the ith simulated value

for the constituent being evaluated, Yimean is the mean of observed data for the constituent being

evaluated, and n is the total number of observations. NSE is commonly used as a normalized

statistic that determines the relative magnitude of the residual variance and indicates how well a

plot of observed versus simulated data fits the 1:1 line (Moriasi et al., 2007). NSE values range

from -∞ to 1.0 with 1.0 being the optimal value.

3.4.2 Particle Tracking The particle tracking equations developed by Takamatsu et al. (2010) are used to

determine the sizes of particles that are removed from runoff for a given storm event. A

particle’s position is determined using the equations outlined in Table 13.

The x and y position of a given particle are simply the summation of the velocities in the

x and y direction multiplied by the time step length. In MUDS, the initial height of a particle is

always assumed to be the depth of water at the time the particle entered the USDC.

40

Table 13: Particle Tracking Equations (Takamatsu et al., 2010)

Particle

Position Equations Terms

Horizontal

𝑥(𝑡) = ∫(

𝐿 − 𝑥(𝑡)𝐿

) (𝑄𝑖𝑛(𝑡) − 𝑄𝑜𝑢𝑡(𝑡)) + 𝑄𝑜𝑢𝑡(𝑡))𝑑𝑡

𝐵 ∗ ℎ(𝑡)

𝑡

𝑡𝑖𝑛

(18)

t- time (s)

L- path length from inlet to

outlet (m)

x(t)- horizontal position at t

(m)

B- Average width

h(t)- depth of water at t (m)

Vertical 𝑦(𝑡) = ∫𝑑ℎ(𝑡)

𝑑𝑡

𝑦(𝑡)𝑑𝑡

ℎ(𝑡)−

(𝜌𝑠 − 𝜌)𝑔𝑑𝑠2𝑑𝑡

18µ

𝑡

𝑡𝑖𝑛

(19)

y(t)- vertical position at t (m)

ρs- density of particles

(Kg/m3)

ρ- density of water (Kg/m3)

μ- Dynamic viscosity of

water (N·s/m2)

ds- diameter of particle (m)

g - gravitational constant

(m/s2)

MUDS only accepts the entry of an average width (B) since the variability in USDC

design would require complex additional user input, USDC can have varying widths around

baffled sections. The user also inputs a pathlength which when combined with the average width

simplifies the calculations such that MUDS interprets the USDC as a long tunnel as opposed to a

complex winding structure.

Vertical velocity is a combination of the vertical movement of the water surface in the

USDC and the settling velocity of the particle. Settling velocity is calculated using Stokes’ law.

The change in height of the particle due to the effect of the change in height of the water surface

is calculated by linearly interpolating from the bottom of the USDC to the water surface; so, if

the particle is at the water surface it moves with the surface, and if it is halfway between the

bottom and the surface it moves half that of the surface. This is a simple approach to attempt to

replicate the complicated turbulent flow mechanisms within a USDC, based on the results of

Takamatsu et al. (2010) this assumption provides adequate results.

41

3.4.3 Pollutant Removal MUDS uses hydraulic and particle tracking equations outlined in the previous sections to

determine how particles move through the USDC. This section describes the theory behind the

calculation of overall TSS removal efficiency after the simulation has finished.

One of the required inputs for MUDS is the particle size distribution of the pollutants in

the runoff. As can be seen in Figure 16, the distribution is represented by values denoted by d10

to d90; these values are the diameters of the particles for which x% by mass of the particles have

a smaller diameter (e.g. if the d90 is 50 µm then the remaining 90% of the particles by mass have

a diameter smaller than 50 µm). Therefore, these dx values represent thresholds where, if that

particle size is removed, then x% of particles by mass have been removed from the runoff. At

each timestep where there is flow into the USDC, a wave of particles with the specified

distribution is released and tracked as it progresses through the structure.

Figure 16: Particle Size Distribution (AZO Materials, 2007)

Figure 16 shows a standard particle size distribution chart. The y-axis is cumulative finer

volume percent; one of the assumptions of MUDS is that all particles have a constant density so

42

the cumulative percent finer is interchangeable with cumulative mass percent. The user can use a

particle size distribution found using samples from the intended USDC site or select a particle

size distribution associated with the land-use type such as those from the Toronto and Region

Conservation Authority (2012a) or the International Stormwater BMP database (2011a).

In wastewater sedimentation systems, a settling column test is frequently used to

calculate removal efficiency under flocculent settling conditions and requires graphical

interpretation. A polluted water sample is placed in a column that has testing taps at various

heights, an initial TSS measurement is taken at the start of the test, and samples are taken at each

tap at specific time intervals. Based on the ratio of the TSS at any given time to the initial TSS,

the removal percentage of particulates can be determined at any height and time (Agrawal &

Bewtra, 1985). Figure 17 shows the results of a flocculent settling column test.

Figure 17: Flocculent Settling Column Test (Viessman & Hammer, 1985)

Removal percentage lines can be drawn by plotting out the removal percentage vs. depth

and time. However, this removal percentage is based on the assumption that all particles enter

and stay at the top of the settling structure. In actuality, suspended particles can spread across the

43

entire depth due to turbulent mixing, so the actual removal percentage is higher than estimated

values (Figure 18).

Figure 18: Potential Particle Entry Paths

Figure 19: Flocculent Settling Removal Calculation Example:

Adapted from (Viessman & Hammer, 1985)

The actual removal percentage can be calculated graphically (Figure 19). Figure 19

provides an example of a tank with a fixed residence time of 24 minutes and a depth of 7 feet; at

this depth at a time of 24 minutes, 45% of the particles have been fully removed. Next, the point

where the time between removal percentage lines is equal is found to determine the average

settling velocity of that section. In the example above for the section between the 45% and 60%

lines, the average settling velocity is 3.4 feet per 24 minutes. The ratio of the settling velocity

and the critical settling velocity is multiplied against the section size it is representing to find the

percent of pollutants that entered the tank low enough to be removed. Since the velocities are

44

calculated over the same time the ratio of depths can be used instead. The total removal of the

tank in the example is calculated below.

𝑅 = 45% +𝑉1

𝑉𝑐𝐶1 + ⋯ +

𝑉𝑛

𝑉𝑐𝐶𝑛

𝑅 = 45% +3.4

7(60 − 45) +

1.3

7(75 − 60) +

0.4

7(100 − 75)

𝑅 = 56.4%

In MUDS it is assumed that the overall settling paths of these particles are linear instead

of curved since settling conditions are discrete, not flocculent. This assumption allows removal

percentages to be calculated using trigonometry rather than graphically; for a full derivation of

how removal percentages are calculated in MUDS refer to Appendix B. It is important to note

that the settling paths of the particles are still calculated using the equations provided in Section

3.4.1 but the overall settling velocity for determining removal is calculated assuming linearity.

Figure 20 shows how the particle paths are interpreted by the model for calculating the removal

percentage of a wave of particles.

Figure 20: Model Particle Paths

MUDS includes two more important assumptions. Firstly, the hydraulic model finishes

executing when the outflow is less than 0.1 L/s so any particles that remain suspended inside are

45

assumed to settle (100% removal). Secondly, if the d90 particle size of a wave has a final vertical

position greater than zero when that wave reaches the outlet, then removal of that wave is also

zero. The overall removal efficiency of an entire storm is governed by the following equation:

𝑅𝑒𝑚𝑜𝑣𝑎𝑙 (%) = ∑ 𝑅𝐹𝑟𝑎𝑐𝑡𝑖𝑜𝑛 ∗ 𝑀𝐹𝑟𝑎𝑐𝑡𝑖𝑜𝑛 ∗ 100 (20)

where RFraction is the fraction of pollutants removed in a specific particle wave, and MFraction is the

fraction of the total mass of pollutants attributed to the wave of particles.

The mass fraction of a pollutant is calculated using concepts discussed in Section 2.2.5.

The user enters the first flush ratio which allows for the variable b to be calculated using

equation 6; b can then be used to develop an M(V) curve that describes how pollutants are

released as runoff is received by the USDC. The following equation governs the calculation of

mass fraction:

𝑀𝐹𝑟𝑎𝑐𝑡𝑖𝑜𝑛 = 𝑋𝑡𝑏 − 𝑋𝑡−1

𝑏 (21)

𝑀𝐹𝑟𝑎𝑐𝑡𝑖𝑜𝑛 = [

∑ 𝑄𝑖𝑛 ∗ 𝛥𝑡𝑡𝑛=1

∑ 𝑄𝑖𝑛 ∗ 𝛥𝑡𝑛𝑛=1

]

𝑏

− [∑ 𝑄𝑖𝑛 ∗ 𝛥𝑡𝑡−1

𝑛=1

∑ 𝑄𝑖𝑛 ∗ 𝛥𝑡𝑛𝑛=1

]

𝑏

(22)

where Qin is the flow in to the USDC at timestep t (m3/s), and Δt is the timestep length (s).

Summing the product of the mass fraction of each wave and its respective removal percentage

gives the total percent of pollutants removed by mass.

3.4.5 SWMM Modeling The Storm Water Management Model (SWMM) was used to generate the inflow

hydrographs for the Markham USDC. SWMM is a physically based water quality and

hydrological simulation model used primarily for urban areas (DeMartino et al., 2011). Each

46

subcatchment surface is treated as a nonlinear reservoir where inflow is generated by

precipitation and upstream catchments, and outflow is simulated as infiltration, evaporation, and

surface runoff. Surface runoff occurs when the maximum depression storage in a subcatchment

is exceeded (Environmental Protection Agency SWMM 5.1 a, 2015). Runoff flow rate is

governed by Manning’s equation (Equation 23).

𝑄 =𝐴

53 ∗ 𝑆

12

𝑛 ∗ 𝑃23

(23)

where Q is the surface runoff (m3/s), A is the effective flow area (m2), S is the surface slope, n is

the Manning's roughness coefficient, and P is the wetted perimeter (m).

Flow through the sewer system is routed using the kinematic wave model which solves

the mass and momentum continuity equations in each conduit. This method assumes that the

slope of the water surface is equal to the slope of the conduit. The maximum flow that can be

conveyed by a conduit is the full normal flow value; any excess is either lost from the system or

can pond at the inlet node and be introduced as capacity becomes available. This method cannot

account for backwater effects, entrance/exit losses, flow reversal, or pressurized flow

(Environmental Protection Agency SWMM 5.1 b, 2015).

The subcatchment characteristics were determined using information from previous

OTTHYMO modeling conducted by Masongsong Associates Engineering Limited (Masongsong

Associates Engineering Limited, 2008) as well as on-site observations. A diagram of the

subcatchments and conduits is shown in Figure 21. A comparison between Figure 10 and Figure

21 shows where the subcatchments are located within the service area of the USDC.

47

Figure 21: SWMM Model Study Area Map

Subcatchment and conduit properties are described in Table 14, Table 15, and Table 16.

Each conduit was circular in shape and the Manning’s roughness coefficient in each was

assumed to be 0.012 because they are composed of concrete.

48

Table 14: SWMM Subcatchment Properties

Catchment Area

(ha)

Catchment

Width (m)

Slope

(%)

Impervious

Surface (%) Outlet

Sub1 (Residential) 2.27 100 0.5 35 J1

Sub2 (Road) 0.15 20 0.5 80 J3

Sub3 (Road/depressed grassy area) 0.7 30 0.5 20 J5

Sub4 (Road) 0.5 25 0.5 95 J8

Sub5 (Road) 0.22 25 1 95 J11

Sub6 (Road/construction area) 0.64 40 0.5 20 J10

Sub7 (Parkland) 0.77 40 0.5 0 J10

Table 15: SWMM Land Type Roughness and Storage

Land Type Roughness Coefficient Storage Depth (mm)

Impervious 0.013 2

Pervious 0.25 4

Pervious w/ Construction 0.25 100

Table 16: SWMM Conduit Properties

Conduit Inlet Outlet Max

Depth(m) Length (m)

C1 J1 J3 0.75 28

C2 J3 J5 0.825 110

C3 J5 J6 0.9 20

C4 J6 J8 0.9 23

C5 J11 J8 0.45 15.5

C6 J8 J10 1.2 30

C7 J10 Out1 1.2 10

3.5 Summary

The chapter above outlines the characteristics of the monitoring site as well as the

dimensions of the studied USDC. The USDC is located in the South Unionville Square

development in the City of Markham, Ontario. The type of USDC installed is a StormTrap-

DoubleTrapTM, it services a new 5.24 hectare commercial and residential mixed-use

development. The Markham USDC is designed to allow a maximum design flow rate of 0.03

m3/s to accommodate a 5-year return period storm event and maintain preconstruction flow. It is

49

also designed to achieve enhanced protection for the removal of TSS under MOECC standards

(80%).

Monitoring was conducted by the TRCA from May 2014 to early December 2014. A

water quality sampler was installed to take samples of stormwater at the inlet, Hatch 2, and outlet

during storm events. The captured samples were sent to the MOECC lab to determine the

concentration of pollutants. Several other monitoring devices were installed to assist with the

modeling process and ensure that the Markham USDC was meeting hydraulic requirements and

for other water characteristics of interest; these include: water level sensors, temperature sensors,

turbidity sensors, and a flow rate sensor located at the outlet. Conductivity and temperature

vertical profiles were to be conducted during the summer and winter seasons. Due to various

issues, consistent monitoring could not begin until the beginning of September. Statistical

analysis was used to determine whether significant changes in concentration of pollutants

occurred between the monitored points.

The mechanics of MUDS were explained for the calculation of hydraulics, tracking of

particles, and the removal of particles. MUDS accounts for partially full, and full orifice flow;

results of modeled flow rate are compared to measured flow rate using the NSE equation.

Particles are tracked in the vertical and horizontal dimensions as they progress through the

USDC. As each wave of particles reaches the outlet, the fraction of particles removed from the

wave is calculated. When MUDS has finished running, the final removal percentage of particles

is calculated. A SWMM model was also developed to model the hydrology of the site catchment,

it creates inflow hydrographs which are required for MUDS to function.

The methodology presented in this chapter is applied in the following chapters to

determine the hydraulic and water treatment performance of the Markham USDC as well as to

calibrate and validate the SWMM model and verify the particle removal function in MUDS. In

the following chapter, the results for the monitored water quality parameters are discussed.

50

Chapter 4 Water Quality Results

Throughout the monitoring phase, samples were collected by the TRCA from seven

storm events at the inlet and eight storm events at Hatch 2 and the outlet. The events at the inlet

occurred on: July 9th, August 11th, 16th, September 2nd, 5th, 21st, and October 3rd; the additional

sample for Hatch 2 and the outlet was captured on June 25th. The sample captured on July 9th at

the inlet was not used in the analysis because it had an extremely TSS EMC compared to the

other samples which suggests it was from another source; since this is the time around where the

splashpad was turned on it is likely that splashpad water was captured, rather than stormwater

runoff. A summary of key hydrological parameters for each storm is shown in Table 17.

Table 17: Sampled Storm Event Hydrologic Parameters

Event

Date

Duration

(hrs)

Depth

(mm)

Max Intensity

(mm/hr)

Average Intensity

(mm/hr)

Preceding Dry

Days

Jun-25 2.42 28.2 74.4 11.3 <1

Jul-09 2.58 17.2 40.8 6.5 <1

Aug-11 4.42 19.2 28.8 4.3 6

Aug-16 9.75 4.8 7.2 0.6 4

Sep-02 3.00 26.6 67.2 8.6 10

Sep-05 11.75 42.6 79.2 3.6 3

Sep-21 2.83 21 52.8 7.2 <1

Oct-03 2.83 7 9.6 2.4 12

The IDF curves generated by the IDF Curve Lookup tool produced by Ministry of

Transportation (2013) show that the sampled storms are frequently occurring events that were

within the design capacity of the Markham USDC (return period ≤ 2 years).

ProUCL 5.0 was utilized to determine the statistical distribution of the sampled

pollutants. It was found that all pollutants followed log-normal distributions. In order to perform

paired t-tests the data was transformed such that it could be represented by a normal distribution.

51

4.1 Total Suspended Solids and Turbidity

A summary of TSS and turbidity data is shown in Table 18 with box plots of each

following in Figure 22. Table 19 summarizes whether TSS and turbidity are removed

significantly between the monitored points using a paired t-test.

Table 18: Summary of TSS EMC and Turbidity

Figure 22: Box plots of Suspended Solids and Turbidity

Table 19: Summary of TSS and Turbidity Statistical Analysis

Pollutant Paired T-Test Results (p<0.05)

Inlet - Hatch 2 Hatch 2 - Outlet Inlet - Outlet

TSS

Turbidity

Significant Decrease Significant Increase No Significance

As stormwater progresses through the USDC, particles are steadily removed. This

observation agrees with the theoretical concept that with greater residence time more particles

are removed. With the exception of one event (September 2nd), the concentration leaving the

outlet was below 100 mg/L. The September 2nd event had high intensity rainfall over a short

period of time which would result in increased pollutant concentration in the runoff and less

residence time in the USDC. The range of values at the outlet appears to be much more

consistent than at the inlet, which suggests that the pollutants at the outlet are fines that will not

Range Avg Med Std dev Range Avg Med Std dev Range Avg Med Std dev

Total Suspended Solids mg/L 109 - 783 293 195.5 260 24.6 - 421 136 106.8 128 4.5 - 174 52.3 42.6 53.94

Turbidity FTU 80 - 776 312 236 268 31.9 - 470 143 109.5 139 5.87 - 251 70.3 52 78.74

Pollutant UnitsInlet Hatch 2 Outlet

52

settle regardless of detention time. The average removal of suspended solids by the USDC was

82%, therefore it achieves enhanced protection under MOECC standards. With this removal rate

the USDC is achieving similar removal as compared to a SWM pond (Refer to Table 1). A

higher removal rate was expected but the very fine PSD of the catchment area will make it

difficult to remove suspended solids from the runoff by sedimentation alone regardless of the

treatment approach (SWM ponds or USDC).

Table 19 shows that there was a statistically significant difference in the averages in all

cases except for turbidity between the inlet and Hatch 2; while there is a noticeable difference in

average turbidity in this section, there is not enough data to confirm that the forebay significantly

decreases turbidity. Based on Table 20, the forebay appears to remove just over half of the TSS

and turbidity present at the inlet, and the particles are reduced again by just over half while

traversing the permanent pool. Therefore, the forebay cannot solely be relied on to remove

particles from runoff: the permanent pool is an essential part of the treatment process.

Table 20: Percent Removal of TSS and Turbidity

Pollutant Fraction of Pollutants Removed (%)

Inlet - Hatch 2 Hatch 2 - Outlet Inlet - Outlet

TSS 53.6 28.5 82.1

Turbidity 54.2 23.3 77.5

Lab testing at the University of Toronto was conducted to determine a relationship

between the TSS and turbidity at the USDC site. A storm event that occurred on October 3rd

provided sufficient volumes to conduct these tests. The ISCO samplers at the inlet, Hatch 2, and

the outlet each supplied 24 samples. Tests were conducted following ASTM D5907-13 and

ASTM D7725-12 standard protocol for TSS and turbidity, respectively.

Turbidity was analyzed using a VWR Scientific 66120-200 Turbidity Meter with

resolutions of 0.01 (0-20 NTU) and 0.1 (0-200 NTU). Some samples required dilution since the

53

unit can only read turbidity values up to 200 NTU. This was accounted for when calculating the

actual turbidity of the sample.

The results of the TSS and turbidity testing are shown in Figure 23 below. Different

TSS-Turbidity correlations were required for the different sampling locations within the USDC.

Ideally more than one event would be used to establish this relationship but due to limitations in

monitoring time this was not possible.

Figure 23: TSS VS Turbidity: Inlet (Right), Hatch 2 and Outlet (Left)

YSI’s installed in the USDC recorded turbidity every five minutes, so this relationship

allows for a much more accurate measurement of TSS as a storm event progresses compared to

the flow-weighted ISCO samples. The flow rate measurements at the outlet combined with the

modeled inflow and the TSS concentrations allows for the use of the mass load efficiency

equation from Section 2.1. Subsequently, the removal efficiency for each observed storm event

can now be compared with the prediction from MUDS (Section 5.2).

4.2 Nutrients

A summary of all nutrients measured is shown in Table 21 with box plots of each

following in Figure 24 and Figure 25. Table 22 summarizes whether a given nutrient is removed

significantly between the monitored points using a paired t-test.

y = 0.6176xR² = 0.8025

0

200

400

600

800

1000

0 500 1000 1500 2000

Turb

idit

y (N

TU)

Total Suspended Solids (mg/L)Inlet

y = 0.5119xR² = 0.9087

y = 0.0562xR² = 0.2126

0

20

40

60

80

100

120

0 50 100 150 200

Turb

idit

y (N

UT)

Total Suspended Solids (mg/L

Hatch 2 Outlet

54

Table 21: Summary of Nutrient EMC

Figure 24: Box Plots of Nitrogen Species

Range Avg Med Std dev Range Avg Med Std dev Range Avg Med Std dev

Nitrogen; ammonia + ammonium mg/L 0.1 - 1.9 0.50 0.24 0.67 0.06 - 0.30 0.19 0.208 0.09 0.06 - 0.26 0.18 0.1815 0.06

Nitrogen; nitrite mg/L 0.04 - 0.14 0.07 0.0605 0.04 0.04 - 0.20 0.08 0.0535 0.05 0.02 - 0.21 0.06 0.047 0.06

Nitrogen; nitrate + nitrite mg/L 0.07 - 0.77 0.49 0.549 0.25 0.51 - 1.3 0.81 0.8195 0.25 0.47 - 1.1 0.70 0.6645 0.21

Nitrogen; total mg/L 0.76 - 17.8 3.99 1.145 6.79 0.9 - 4.3 1.69 1.285 1.15 0.85 - 2.4 1.38 1.16 0.58

Nitrogen; total Kjeldahl mg/L 0.15 - 17.5 3.55 0.86 6.85 0.13 - 3.5 0.96 0.58 1.06 0.14 - 1.8 0.74 0.585 0.51

Phosphorus; phosphate mg/L 0.05 - 1.1 0.31 0.12 0.44 0.02 - 0.15 0.08 0.07255 0.04 0.03 - 0.15 0.08 0.0755 0.04

Phosphorus; total mg/L 0.14 - 1.2 0.42 0.29 0.40 0.02 - 0.26 0.15 0.1285 0.08 0.07 - 0.19 0.12 0.111 0.04

Inlet Hatch 2 OutletUnitsPollutant

55

Figure 25: Box Plots of Phosphorus Species

Table 22: Summary of Nutrient Statistical Analysis

Pollutant Paired T-Test Results (p<0.05)

Inlet - Hatch 2 Hatch 2 - Outlet Inlet - Outlet

Nitrogen; ammonia + ammonium

Nitrogen; nitrite

Nitrogen; nitrate + nitrite

Nitrogen; total

Nitrogen; total Kjeldahl

Phosphorus; phosphate

Phosphorus; total

Significant Decrease Significant Increase No Significance

No significant removal was observed for all nitrogen parameters. Analysing nitrogen by

its components yields some interesting results. The spread in concentration of observed ammonia

and ammonium was reduced, however the average change in concentration is insignificant. The

concentration of nitrite, and nitrate and nitrite fluctuate throughout the USDC but overall, change

is also insignificant. It is expected that the concentrations of ammonia, ammonium, and nitrite

will decrease and nitrate will increase, but there are not enough samples to confirm this with

statistics. The data suggests that the oxidation of ammonia may occur within the USDC either by

nitrifying bacteria or through natural processes. The median value at the outlet of ammonia and

ammonium is 181 μg/L, using the tables found in Ministry of Environment and Energy (1994)

56

the concentration of un-ionized ammonia is 0.25 μg/L which meets the MOECC guideline (20

μg/L).

Both total phosphorus and phosphate were significantly reduced between the USDC inlet

and outlet. For total phosphorus, the removal percentage was either above those in the literature

or toward the higher end of the ranges listed (Table 4). Therefore, the Markham USDC provided

equivalent or superior removal of phosphorus compared to a SWM pond. The majority of

phosphorus was removed before exiting the forebay suggesting that a large portion was in a

particulate form. The median concentration at the outlet for total phosphorus was 111 µg/L

which lies above the limit for preventing excessive plant growth in rivers and streams (30 µg/L).

With a maximum design flow rate of 0.03 m3/s, the ammonia, ammonium, and total

phosphorus values would be diluted once outflow enters the Rouge River, which has an average

annual flowrate of 1.6 m3/s (Environment Canada Data Explorer, 2012). The flow rate in the

river during a storm event would also be larger, so the pollutants would be even further diluted

and less of a risk to the environment.

4.3 Metals

The summary of all monitored metals that had median inlet concentrations above the

minimum detection limit (MDL) are shown in Table 23 with box plots of each following in

Figure 26. Table 24 summarizes whether a given metal is removed significantly between the

monitored points using a paired t-test.

57

Table 23: Summary of Metals EMC

Figure 26: Box Plots of Monitored Metals

Range Avg Med Std dev Range Avg Med Std dev Range Avg Med Std dev

Aluminum ug/L 1200 - 7760 2740 1955 2490 364 - 2350 1120 925.5 622 126 - 1470 646 601 446

Antimony ug/L 0.3 - 0.6 0.47 0.5 0.10 0.4 - 0.7 0.51 0.5 0.12 0.4 - 3.9 1.06 0.7 1.16

Arsenic ug/L 0.6 - 1.5 1.00 1.05 0.32 0.8 - 1.2 1.04 1.05 0.14 0.7 - 1.3 0.90 0.8 0.19

Barium ug/L 28.7 - 135 62.8 53.2 38.24 31.4 - 68.8 46.3 46.45 11.33 23.5 - 44.7 32.1 32 6.55

Boron ug/L 23 - 36 30.3 31 4.76 30 - 58 40.6 41 8.67 25 - 44 35.4 35.5 7.03

Cobalt ug/L 1.1 - 5.4 2.22 1.7 1.63 0.5 - 2.5 1.13 0.9 0.62 0.2 - 1.3 0.63 0.65 0.35

Copper ug/L 6.7 - 22.6 14.6 13.75 6.06 6.5 - 10.3 7.78 7.55 1.24 4 - 8.4 6.44 6.85 1.57

Iron ug/L 870 - 8000 2450 1575 2748 400 -1660 920 780 416 110 - 1030 520 560 313

Lead ug/L 2.7 - 12.7 5.30 4.15 3.76 1.4 - 5.6 2.71 2.35 1.38 0.3 - 3.3 1.43 1.35 0.88

Manganese ug/L 76.4 - 393 175 137.2 120 39 - 283 113 91.5 74.78 10.8 - 130 46.4 41.4 37.44

Nickel ug/L 2.3 - 11.3 4.50 3.35 3.40 2.0 - 4.2 2.69 2.3 0.91 0.9 - 2.2 1.63 1.75 0.48

Strontium ug/L 126 - 281 208 201.5 58.14 223 - 379 286 274.5 48.74 158 - 303 226 220 45.64

Titanium ug/L 11.1 - 19.7 14.5 13.9 3.09 7.7 - 17.3 11.7 11.25 3.33 4.2 - 21.5 10.2 10.1 5.29

Vanadium ug/L 3.3 - 14.6 6.00 4.6 4.28 1.9 - 4.9 3.09 3 1.00 0.9 - 4.8 2.40 2.5 1.32

Zinc ug/L 16.2 - 106 45.3 35.25 32.00 14.5 - 37.5 21.7 20.55 7.11 6.5 - 21.3 13.0 12.85 5.13

OutletPollutant Units

Inlet Hatch 2

58

Figure 26: Box Plots of Monitored Metals (Continued)

59

Figure 26: Box Plots of Monitored Metals (Continued)

Table 24: Summary of Metals Statistical Analysis

Pollutant Paired T-Test Results (p<0.05)

Inlet - Hatch 2 Hatch 2 - Outlet Inlet - Outlet

Aluminum

Antimony

Arsenic

Barium

Boron

Cobalt

Copper

Iron

Lead

Manganese

Nickel

Strontium

Titanium

Vanadium

Zinc

Significant Decrease Significant Increase No Significance

60

All of these metals were significantly reduced between the inlet and outlet, with the

exception of antimony, which significantly increased, and boron, arsenic, and strontium, which

were unaffected. Compared to the removal percentages cited in Section 2.2.3, the removal of

metals by the Markham USDC are either greater or within the same range of previously

published SWM pond studies (Table 8); the only exception is arsenic. Therefore, the Markham

USDC proved treatment either equivalent or superior for the removal of the metals with the

exception of arsenic. The notable metals with large inflow concentrations are aluminum and iron

which have median inflow concentrations of 1.955 and 1.575 mg/L, respectively. For

comparison, the United States Environmental Protection Agency has secondary drinking water

standards of 0.2 mg/L and 0.3 mg/L for aluminum and iron respectively (US EPA, 2015). At the

outlet, the majority of metals are meeting the provincial water quality requirements listed in

Table 9 with only aluminum, copper, and iron exceeding the required concentrations.

Boron and strontium were found to significantly increase in concentration after exiting

the forebay. These metals have been known to increase in concentration when draining through

permeable pavement, so the increase may be due to contact with the concrete structure (Toronto

and Region Conservation Authority, 2012c). The effectiveness of the permanent pool and the

forebay are inconsistent between metals, with significant removal and percent removal being

dependant on the individual metal (Table 25). This result is sensible since the association with

various particle sizes and dissolved portion is dependent on the individual metal.

61

Table 25: Percent Removal of Metals

Pollutant Fraction of Pollutants Removed (%)

Inlet - Hatch 2 Hatch 2 - Outlet Inlet - Outlet

Aluminum 59.1 17.3 76.4

Antimony -9.8 -117.9 -127.7

Arsenic -3.8 13.8 10.0

Barium 26.4 48.9 22.5

Boron -33.9 17.3 -16.6

Cobalt 49.2 22.6 71.8

Copper 46.8 9.2 56.0

Iron 62.4 16.4 78.8

Lead 49.1 24.1 73.2

Manganese 35.2 38.2 73.4

Nickel 40.3 23.6 63.9

Strontium -37.4 28.6 -8.8

Titanium 19.2 10.4 29.6

Vanadium 48.5 11.5 60.0

Zinc 52.2 19.1 71.3

4.4 Bacteria

A summary of all bacteria measured is shown in Table 26 below with box plots of each

following in Figure 27. Table 27 summarizes whether a given bacteria is removed significantly

between the monitored points using a paired t-test. One less sample was analysed for bacteria,

the August 16th event was not captured.

Table 26: Summary of Bacteria EMC

Range Avg Med Std dev Range Avg Med Std dev Range Avg Med Std dev

Escherichia coli c/100mL 64 - 7600 3480 3000 3398 4 - 6300 1330 130 2285 3.3 - 1400 446 220 544

Fecal streptococcus c/100mL 140 - 9100 3980 2800 4167 4 -2800 935 940 993.07 10 - 2600 641 380 899

Pseudomonas aeruginosa c/100mL 660 - 8300 2750 1400 3169 4 - 8300 1430 360 3038 20 - 720 246 170 222

Inlet Hatch 2 OutletPollutant Units

62

Figure 27: Box Plots of Monitored Bacteria

Table 27: Summary of Bacteria Statistical Analysis

Pollutant Paired T-Test Results (p<0.05)

Inlet - Hatch 2 Hatch 2 - Outlet Inlet - Outlet

Escherichia coli

Fecal streptococcus

Pseudomonas aeruginosa

Significant Decrease Significant Increase No Significance

For each bacteria the USDC removes a large fraction on average of those that entered the

inlet; however, the large range of values at all points in the USDC result in E. coli as the sole

bacteria significantly removed on average. At the outlet, the median concentration of E. coli was

212 c/100mL; this is above the maximum acceptable concentration for beach water in Ontario

which is 100 c/100 mL (City of Toronto, 2015). The median inflow and outflow concentrations

63

of E. coli in a wetland basin/retention pond is 869 and 196 c/100 mL, respectively (International

Stormwater BMP Database, 2014). This concentration is within the same range as those

measured at the Markham USDC outlet.

Reduced concentrations between the inlet and outlet suggest that the conditions inside of

USDC are not conducive to the reproduction of bacteria. This is most likely due to the

consistently cold water (Section 4.5) and ambient air temperature. Bacteria are also removed

from the water through sedimentation since they are predominantly attached to particles that

enter during a storm event. An overall removal percentage for each bacteria is difficult to

guarantee since the concentrations at all measured points are highly variable.

4.5 Temperature

The temperature in the USDC was recorded using a YSI monitor at Hatch 1 and a HOBO

Water Temperature Data Logger at Hatch 5; these were located approximately 0.04 m above the

bottom of the USDC, the results are shown in Figure 28 below. The gap in recorded inlet data

between October 24th and November 11th was caused by a temporary malfunction of the YSI

sensor.

Figure 28: YSI Temperature Results

0

5

10

15

20

25

30

01-06-14 01-07-14 31-07-14 30-08-14 29-09-14 29-10-14 28-11-14

Tem

per

ature

(⁰C

)

Inlet Outlet

1

64

As can be seen, the temperature at the outlet of the USDC is consistently less than what is

entering the inlet throughout the entire monitoring period. At the outlet, the temperature

increases steadily from 8oC to its highest around 13oC in October. The low temperatures at the

beginning of June correspond to the period when the permanent pool was refilling following the

Markham USDC cleaning on May 29th. The temperature begins to decrease as the year

progresses into November. The inlet temperature varies significantly more than the outlet. This is

due to storm events bringing heated runoff from impervious surfaces into the USDC. The cooler

ambient air temperature in the USDC then begins to cool the permanent pool that remains after

the event. The sensors at Hatch 1 and 5 recorded average temperatures of 14.5 and 12.5oC at the

inlet and outlet respectively. The temperature of the outflow eliminates the release of thermally

enriched runoff and it poses no threat to organisms in coldwater streams (Chu et al., 2009). It is

unclear whether the splashpad has an effect on the inflow temperature, but it follows the same

patterns as before the splashpad was activated so whatever effect it has is minimal.

The time period noted by circle 1 in Figure 28 experienced a sharp drop and rise in the

inlet temperature, and a sharp drop in the outlet temperature. The drop was caused by a storm on

November 24th that occurred during the night. Instead of being warmed by the impervious

surfaces, the runoff entered the USDC at a cold temperature. The permanent pool remained cool,

but the forebay pool temperature was increased as the ambient air temperature increased

throughout the day.

The USDC studied by Natarajan and Davis (2010) had an average outflow temperature

during July of 19.7 oC which is significantly more than the Markham USDC (11.4 oC). Natarajan

and Davis (2010) saw a mean reduction in temperature of 1.6oC and the Markham USDC on

average achieved a 3.5oC reduction. One possible reason for this discrepancy was that Natarajan

65

and Davis were studying a detention system that was composed of 6-122 cm interconnected

storage pipes with limited storage and detention. Therefore, the system had a shorter time for

cooling the stormwater and a smaller volume of cool stored water that would buffer some of the

elevated temperature runoff. Also, the inflow temperature is much higher for Natarajan and

Davis (mean of 21.7oC) while the Markham USDC inflow temperature was 14.9oC. The runoff

temperature combined with the small storage volume would result in stored water heating

quickly, and any cooling would be dependant on the ambient air temperature.

The HOBO temperature sensor took measurements not at the outlet, but towards the

bottom of the USDC, so there is the potential that a temperature gradient was occurring.

However, of the four temperature profiles conducted (discuessed further in Section 4.7), there is

little temperature gradient within the USDC. To better confirm this, additional profiles are still

needed through the summer months.

4.6 Hydrocarbons

Significance tests could not be conducted on several hydrocarbons since the minimum

detection limit (MDL) was too high. Therefore, removal of hydrocarbons could not be

determined. The number of samples below the MDL for each hydrocarbon is shown in Table 28.

The box plots were created using the MDL values (10 ng/L) from the results. A summary of all

monitored hydrocarbons that had inlet concentrations above the MDL are shown in Table 29

below with box plots of each following it in Figure 29.

Table 28: Number of Hydrocarbon Samples below the MDL

Hydrocarbon Number of Samples Below MDL

Inlet Hatch 2 Outlet

Phenanthrene 1/6 3/8 8/8

Fluoranthene 1/6 3/8 7/8

Pyrene 1/6 4/8 7/8

Napthalene 1/6 6/8 8/8

Fluorene 0/6 6/8 6/8

66

Table 29: Summary of Hydrocarbon Removal

Figure 29: Box Plots of Hydrocarbons

Range Avg Med Std dev Range Avg Med Std dev Range Avg Med Std dev

Phenanthrene ng/L Trace - 66 33.3 22.5 23.17 Trace - 25 16.8 17.5 6.32 Trace - - -

Fluoranthene ng/L Trace - 110 42.2 33.5 34.53 Trace - 48 22.5 16.5 16.05 Trace - 12 - - -

Pyrene ng/L Trace - 93 33.8 25 29.65 Trace - 36 17.6 12.5 11.01 Trace - 11 - - -

Naphthalene ng/L Trace - 20 14.0 12.5 3.74 Trace - 20 - - - Trace - - -

Fluorene ng/L 12 - 30 19.8 18 6.82 Trace - 26 - - - Trace - 22 - - -

UnitsInlet Hatch 2 Outlet

Pollutant

67

Lowering the MDL would have a more profound effect on those hydrocarbons with inlet

concentrations already close to the MDL, such as napthalene and fluorene. Unless a more

accurate test is conducted, the actual removal efficiency of hydrocarbons by USDC cannot be

determined. However, all of the concentrations at the outlet of the detected hydrocarbons are

below the provincial water quality requirements, with the exception of fluoranthene, which has a

requirement below the MDL. Each hydrocarbon and its associated requirement are listed in

Table 30.

Table 30: Hydrocarbon Provincial Water Quality Requirements

Hydrocarbon Provincial Water Quality

Requirement (μg/L)

Phenanthrene 0.03

Fluoranthene 0.0008

Pyrene N/A

Napthalene 7

Fluorene 0.2

Using the available data, the USDC appears to consistently remove a large portion of the

hydrocarbons after they pass through the forebay, only phenanthrene is significantly removed by

the forebay.

4.7 Vertical Profiles

Four vertical profiles of water quality have been taken since the USDC was installed at

the Markham site. Two of the profiles were taken before the cleaning of the USDC. The results

of the profile measurements are shown in Figure 30.

68

Figure 30: Depth Profile Results

Figure 30: Depth Profile Results (Continued)

The temperature and dissolved oxygen (DO) plots show that there is some stratification

occurring in the USDC (different values at different depths). Even though there is only a slight

decrease in temperature between the water surface and the bottom. There is a dramatic drop in

the DO saturation and concentration; this is suggestive of the presence of a thermocline which is

“the region in a thermally stratified body of water which separates warmer surface water from

cold deep water and in which temperature decreases with depth” (Merriam Webster, 2015).

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

0 5 10 15D

ep

th (

m)

Temperature C°

Jan 9/14 Mar 10/14

Dec 2/14 Feb 18/15

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

0 10 20 30

De

pth

(m

)

TDS (g/L)

Jan 9/14 Mar 10/14

Dec 2/14 Feb 18/15

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

0 20 40 60 80

De

pth

(m

)

Dissolved Oxygen Saturation (%)

Jan 9/14 Mar 10/14

Dec 2/14 Feb 18/15

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

0 5 10 15D

ep

th (

m)

Dissolved Oxygen Concentration (mg/L)

Jan 9/14 Mar 10/14

Dec 2/14 Feb 18/15

69

Thermoclines prevent the mixing of surface waters with those below, which induces a sharp

gradient in the DO concentration. The lack of mixing can also be a barrier to particle settling.

The relative thermal resistance to mixing (RTRM) was calculated as follows (Song, et al.,

2013):

RTRM =

(𝜌𝑧2 − 𝜌𝑧1)

(𝜌4 − 𝜌5) (23)

where ρ4 and ρ5 are the water densities at 4 and 5oC (kg/m3), and ρz1 and ρz2 are the water

densities at the water depths z1 and z2 respectively (kg/m3). The RTRM in the USDC ranged

from -2.42 to 1.88 which is much lower than the average in the SWM ponds monitored by Song

et al. (2013) which ranged from 63.2 to 218. Therefore, the thermal stratification that is

occurring is to a much lesser degree than that of SWM ponds. However; the profiles by Song et

al. (2013) were conducted during the summer months while the ones at the Markham site were

solely taken during the winter.

The minimum acceptable concentration for dissolved oxygen concentration is variable

depending on the type of river, the values are shown in Table 31. Based on the two profiles taken

after the USDC cleaning (December 2nd and February 18th), the water in the USDC is below the

minimum acceptable DO concentration for protection of aquatic organisms at all depths. To gain

a better understanding of USDC thermal and DO stratification, more profiles should be taken

during the summer months and when storm events occur.

Table 31: Minimum Acceptable Dissolved Oxygen Concentration in Rivers for the

Protection of Aquatic Life (Canadian Council of Ministers of the Environment, 2015)

River Biota Concentration (mg/L)

Warm water: early life stages 6.0

Warm water: other life stages 5.5

Cold water: early life stages 9.5

Cold water: other life stages 6.5

70

The total dissolved solids (TDS) profile returned results as expected. A slight increase in

TDS at the bottom of the USDC would occur since all of the solids that were removed from

runoff settle to the bottom. The profiles taken on January 9th and March 10th 2014 have far

different results than the other two; these were taken before the USDC was cleaned, so there was

a high concentration of TDS in the permanent pool. Therefore, those profiles are not

representative of a USDC under working conditions.

4.8 Summary

The chapter discussed the results of the site runoff analysis and compared them to

standard SWM pond removal capabilities. Of the captured samples, six at the inlet and eight at

the outlet were usable. The sampled storm were deemed to be frequently occurring events (return

period ≤ 2 years) and so were within the design capacity of the Markham USDC.

TSS and turbidity were significantly removed by the Markham USDC. An 82.1% TSS

removal was achieved, therefore the Markham USDC achieved enhanced protection (80% TSS

removal) and is equivalent to SWM ponds for the removal of TSS. Lab testing was performed to

develop a relationship between turbidity and TSS, this relationship will be used to convert

turbidity measurements to TSS and then compare the measured TSS removal in a storm to the

modeled removal by MUDS.

No significant removal was observed for nitrogen parameters, a decrease in total nitrogen

occurs in SWM ponds and so was expected to occur in the Markham USDC. A decrease in

average concentration did occur but was not large enough to declare with statistical significance.

Phosphorus was significantly removed, the change in concentration was either equivalent or

greater than SWM ponds found in the literature. The effluent met the MOECC guideline for un-

71

ionized ammonia (20 μg/L) but not the total phosphorus guideline for preventing excessive plant

growth in rivers and streams (30 µg/L)

All metals were significantly removed between the inlet and outlet, with the exception of

antimony, arsenic, boron, and strontium. Of those removed, the change in concentration is either

greater or within the same range as SWM ponds found in the literature. A possible explanation

for the increase in concentration of some metals is extended contact time with concrete in the

USDC; the specific metals have been known to increase in concentration when draining through

permeable pavement (Toronto and Region Conservation Authority, 2012c). The concentrations

of metals in the effluent are meeting provincial water quality requirements other than aluminum,

copper, and iron.

Large ranges in values were found for each bacteria at all monitored points. The observed

concentrations are suggestive of a reduction in concentration but an overall removal percentage

is difficult to guarantee due to the high variability. Reduced concentrations between the inlet and

outlet suggest the conditions inside the Markham USDC are not conducive to the production of

bacteria. The median concentration of E. coli was above the maximum acceptable concentration

for beach water in Ontario.

Temperature was monitored from the beginning of June to the beginning of December.

Average temperature at Hatch 1 and Hatch 5 (inlet and outlet) were 14.5 and 12.5oC respectively.

The average decrease in temperature was expected due to the literature and known conditions of

the Markham USDC; this is an advantage over SWM ponds which are known to release elevated

temperature effluent. The temperature of the Markham USDC effluent poses no threat to

organisms in coldwater streams (Chu et al., 2009)

72

Statistical analysis of hydrocarbons could not be conducted due to a large number of non-

detects at Hatch 2 and the outlet. The observed concentrations are suggestive of a reduction in

concentration of hydrocarbons, the actual amount cannot be calculated. All of the concentrations

of measured hydrocarbons are below the provincial water quality requirement except

fluoranthene which has a requirement below the MDL.

Four vertical profiles were conducted during the winter months. Observing the

temperature and DO plots show that there is some stratification occurring in the Markham

USDC. The water in the Markham USDC is below the minimum acceptable DO concentration at

all depths. TDS concentration increases with depth as expected. The following chapter will

discuss the development of the SWMM model and MUDS and the results obtained through

performing simulations.

73

Chapter 5 Model Development and Results

Due to the various issues with clogging and the splashpad, as mentioned in

Section 3.1, only storms from September onwards were utilized for calibration and validation of

the SWMM model. A summary of key hydrological parameters for each storm is shown in Table

32. Assessment of MUDS was conducted using the storms listed in Table 32 with the exception

of those in November due to malfunctions with the turbidity meters at that time. The values used

for SWMM calibration and validation and in MUDS’ pollutant removal assessment are listed in

Table 33.

Table 32: Summary of Calibration and Validation Events

Event

Date

Duration

(hrs)

Depth

(mm)

Max

Intensity

(mm/hr)

Average Intensity

(mm/hr)

Preceding

Dry Days

Sep-02 3.0 26.6 67.2 8.6 10

Sep-05 11.8 42.6 79.2 3.6 3

Sep-10 10.8 25 16.8 2.3 4

Sep-13 4.5 2.8 4.8 0.6 2

Sep-15 3.4 3.2 4.8 0.9 2

Sep-21 2.8 21 52.8 7.2 <1

Oct-03 2.8 7 9.6 2.4 12

Oct-06 26.0 13.2 9.6 0.5 2

Oct-15 5.3 6.6 4.8 1.2 8

Oct-16 5.8 19.2 33.6 3.3 <1

Oct-20 12.6 9.6 7.2 0.8 4

Nov-06 9.8 5.8 4.8 0.6 2

Nov-17 5.1 8 4.8 1.5 6

Nov-24 6.8 18.6 12 2.7 2

74

Table 33: MUDS Input Values

USDC Property Value

Surface Area (m2) 854

Average Width (m) 12

Height to Outlet Orifice Invert (m) 1.38

Orifice Diameter (m) 0.15

Starting Height (m) 1.38

Starting Outflow (m3/s) 0

Pathlength (m) 80

Particle Density (kg/m3) 2650

Particle Size Distribution

d10 (μm) 0.8

d20 (μm) 1.2

d30 (μm) 1.6

d40 (μm) 2.2

d50 (μm) 3.1

d60 (μm) 4.5

d70 (μm) 6.6

d80 (μm) 10.6

d90 (μm) 19.2

First Flush Ratio (Pollutant Mass/Volume)

Percentage of Pollutants 50

Percentage of Flow 50

Overflow Outlets

Height to Outlet Orifice Invert 1 (m) 2.45

Orifice Diameter 1 (m) 0.525

Height to Outlet Orifice Invert 2 (m) 2.45

Orifice Diameter 2 (m) 0.525

Water Properties

Density (kg/m3) 998.21

Dynamic Viscosity (kg/m∙s) 0.001002

75

5.1 SWMM Calibration and Validation

Calibration of the SWMM model began by comparing the outflow calculated, using the

measured depth and the equations in Table 12, against measured outflow data for monitored

storms. One such comparison is shown in Figure 31. The NSE equation (Equation 17), was used

to determine what orifice diameter and orifice height provided the most accurate flow prediction.

Ideally, the orifice diameter and height from the design documents would be used, but there were

complications that required these numbers to be adjusted. Following the orifice plate clogging

event from late July to mid-August, when some leaking occurred around the plate, the model

orifice diameter was increased from 0.12 to 0.15 m in order to better simulate measured flow

rates. If the calculated outflow was not responding to the depth as predicted then that event was

not used for calibration or validation. The comparison was also used to determine whether there

was an issue with the orifice plate so that it could be remedied as soon as possible.

Figure 31: Measured and Modeled Outflow Comparison

Following the comparison of measured and modeled outflows, the rainfall data for each

storm was entered into the SWMM model and an inflow hydrograph to the USDC was

generated. These data were entered MUDS to predict outflows and water depths throughout the

storm event. The orifice diameter and depth values from the first comparison were used by

MUDS and the outputs were compared against the measured data using the NSE equation.

1400

1500

1600

1700

1800

0

5

10

15

20

25

30

02-09-14 03-09-14 04-09-14D

ep

th (

mm

)

Flo

w R

ate

(L/

s)

Q Measured Q Modeled USDC Depth

76

A total of 12 storms were used for calibration of the SWMM model. The subcatchment

parameters that were calibrated were the depth of storage for impervious and pervious surfaces,

and the percent of impervious surface area. A baseflow parameter was also adjusted for the

September 2nd, 5th, 10th, 13th, and 15th storms to account for flow from the splashpad, the average

of the first 10 timesteps of the measured flow before a storm event were used as the baseflow.

Figure 32 shows the results for the depth and outflow following calibration. The median

NSE values were 0.52 and 0.49 respectively. With the exception of two events (Oct 15th and Nov

17th), the calibration storms remained within satisfactory to good prediction range (0.36-0.75) as

recommended by Moriasi et al. (2007). The model overpredicted the flow rates for the Oct 15th

and Nov 17th event by a large proportion of the measured flow rate; however, the measured flow

rates are very low with the maximum rate being 2.2 and 2.4 L/s respectively. Therefore, the

apparently poor accuracy based on the NSE value is misleading since the model only

overestimated by 1 - 2 L/s.

Figure 32: Calibration Height and Flow Results

-5

-4

-3

-2

-1

0

1

2

Height Flow

NSE

Val

ue

77

Two storms, (Oct 16th and 20th) were used for validation of the SWMM model. The

measured versus modeled outflow and depth for each storm event are shown in Figure 33 to

Figure 36. The flow and depth figures for the storms used for calibration are included in

Appendix C.

Figure 33: October 16 Outflow Modeling

Figure 34: October 16 Depth Modeling

Figure 35: October 20 Outflow Modeling

0

0.02

0.04

0.06

0.08

0.1

0

5

10

15

20

0 2 4 6 8 10 12 14 16 18 20

Infl

ow

(m

3 /s)

Ou

tflo

w (

L/s)

Time (h)

NSE = 0.52

Qout Measured Qout Modeled Qin Modeled

1.34

1.44

1.54

1.64

0 2 4 6 8 10 12 14 16 18 20

De

pth

(m

)

Time (h)

NSE = 0.36

Depth Measured Depth Modeled

0

0.005

0.01

0.015

0.02

0

1

2

3

4

5

0 5 10 15 20 25 30 35 40 45

Infl

ow

(m

3 /s)

De

pth

(m

)

Time (h)

NSE = 0.46

Qout Measured Qout Modeled Qin Modeled

78

Figure 36: October 20 Depth Modeling

The outflow NSE values are close to the median of the calibration storm events but the

depth NSE values are much lower than expected. This is possibly due to differences in localized

rainfall between the monitoring site and the USDC catchment area, which are roughly 3 km

apart. This discrepancy is quite obvious when examining the October 16th storm which has a

brief intense spike in inflow with no outflow registered on the monitoring devices. Either the rain

that caused this spike did not occur at the USDC site or it was part of the second inflow spike.

Smaller spatial variations in rainfall may have occurred in the October 21st storm but to a much

lesser degree, since the flow rates resulting from this storm were also smaller.

In general, the modeled outflow and depth followed similar temporal patterns and slopes

relative to the measured data, with variations in quantity largely being responsible for low NSE

values. These variations were less severe in storms that solicited higher inflow rates since the

differences in local rainfall intensity would not have as large an effect on inflow rates. For

example, a difference in modeled to measured flow of 3 m3/s when the modeled value is 27 m3/s

does not have as severe an effect as a 3 m3/s difference when the modeled value is 10 m3/s. The

storm on October 16th was exceptional in that there was a localized intense downpour at the

1.34

1.36

1.38

1.4

1.42

1.44

0 5 10 15 20 25 30 35 40 45

De

pth

(m

)

Time (h)

NSE = 0.01

Depth Measured Depth Modeled

79

rainfall monitoring site that was not experienced at all at the USDC site. Table 34 summarizes

the modeled inflow and outflow data generated by the SWMM model and MUDS.

Table 34: Raw Inflow and Outflow Data Summary

Event Date SWMM Peak

Inflow (L/s)

MUDS Peak

Outflow (L/s)

SWMM Avg

Inflow (L/s)

MUDS Avg

Outflow (L/s)

Sep-02 216.7 26.7 6.1 6.2

Sep-05 269.1 27.4 9.1 9.1

Sep-10 59.5 24.1 6.1 6.1

Sep-13 6.6 5.2 2.7 2.7

Sep-15 7.5 6.2 2.7 2.7

Sep-21 175.1 15.5 4.1 4.1

Oct-03 14.7 3.6 1.0 1.0

Oct-06 28.5 7.3 0.8 0.9

Oct-15 10.5 2.2 1.1 1.1

Oct-16 87.0 13.6 5.2 5.0

Oct-20 16.8 3.3 1.0 1.0

Nov-06 9.9 2.3 0.9 0.9

Nov-17 11.1 2.4 1.6 1.5

Nov-24 46.1 16.6 3.3 3.4

Analysis was conducted on the reduction in peak flow achieved by the USDC. The peak

inflow generated by the SWMM model was compared against the peak outflow generated by the

MUDS for each storm; Figure 37 was generated using this data.

Figure 37: USDC Peak Flow Reduction

The peak flow was reduced significantly for all modeled events. The mean and median

peak flow reductions were 66 and 78% respectively. Lower values were due to very low peak

80

inflow rates and so the USDC could not reduce the outflow much further. The highest outflow of

the modeled events was 27.4 m3/s from the September 5th storm with a peak inflow of 269.1

m3/s. The average inflow and outflow rates were equivalent across the same timeframe

regardless of the decrease in peak flow. Therefore, the flow is released across a longer

timeframe.

5.2 Particle Removal Assessment

Assessment of MUDS’ particle removal model was conducted by comparing the modeled

removal to the mass load efficiency calculated from turbidity and flow data. The mass load

efficiency (Equation 4) requires inflow, outflow, and TSS concentration data for each time step

in order to estimate the fraction of pollutants removed. The concentration of TSS was determined

using the TSS to turbidity relationship presented in Section 4.1. The accuracy of the inflow

hydrograph generated by the SWMM model was highly variable and was considered an

ineffective tool to assess removal efficiency. Instead, the inflow hydrograph for each storm was

generated by performing a mass balance on the measured outflow hydrograph; the mass balance

equation is shown below.

𝑄𝑖𝑛 − 𝑄𝑜𝑢𝑡 =

𝛥ℎ ∗ 𝑆𝐴

𝛥𝑡 (25)

where Qin and Qout is flow in and out of the USDC (m3/s), Δh is change in height over time (m),

SA is surface area of the USDC (m2), and Δt is time over which the change in height occurs (s).

The various monitoring devices installed at the Markham USDC provided data for all the

variables in Equation 24 so an inflow hydrograph was easily generated. In the cases where the

mass balance resulted in a negative inflow, a value of zero was used instead since a negative

flow through the inlet is physically impossible. This situation occurs when there is a decrease in

81

height that is too large to be explained by the measured outflow, so mathematically there must be

flow out of the inlet; the discrepancy is most likely due to errors in measured outflow, depth,

and/or surface area. The generated inflow hydrograph was then entered in MUDS and

simulations were run to predict the particle removal percentage for several storm events.

In general, the accuracy of the flow and height prediction improved compared to the

results using SWMM inflow hydrographs. This method was most effective for storms with large

flow rates. Storms with flow rates below 5 m3/s were more affected by the replacement of

negative inflow with zero. In the cases where the accuracy of the new outflow hydrograph was

worse than the one from the SWMM model, the SWMM model outflow hydrograph was used for

pollutant removal assessment.

The first flush ratio for each storm was calculated by plotting the measured cumulative

mass/total mass against the inflow hydrographs cumulative volume/total volume. This graph was

compared against one where the cumulative mass/total mass was calculated using Equation 6

where the value of b was input by the user. The best fitting first flush ratio was determined using

the NSE equation (Equation 17). An example of this comparison is shown in Figure 38.

Figure 38: First Flush Ratio Calibration Example

PSD were determined by the MOECC lab, where water quality testing was conducted.

The average PSD across all sampled storms was used to run MUDS. This is shown in Table 33.

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cu

mu

lati

ve M

ass/

Tota

l Mas

s

Cumulative Volume/Total Volume

Measured Calculated

82

The PSD for this catchment is very fine compared to the mixed-residential PSD found by the

Toronto and Region Conservation Authority (2012a). Therefore, particles in runoff from the

Markham catchment area are expected to take longer to settle and to be more difficult to remove

compared to “typical” Toronto catchments. Consequently, lower removal rates of TSS are

expected from the Markham USDC. The TRCA PSD and average PSD across monitored storms

is provided in Table 35, with a graphical representation following in Figure 39.

Table 35: TRCA and Average Monitored Storm PSD

Particle

Diameter TRCA

Average

Monitored Storm

d10 (μm) 3.4 0.8

d20 (μm) 5.8 1.2

d30 (μm) 7.8 1.6

d40 (μm) 10.2 2.2

d50 (μm) 12.5 3.1

d60 (μm) 16.2 4.5

d70 (μm) 19.8 6.6

d80 (μm) 26.2 10.6

d90 (μm) 46.7 19.2

Figure 39: TRCA and Average Monitored Storm PSD

When conducting the assessment of the MUDS particle removal predicion, preliminary

monitored removal rates calculated using the real-time turbidity measurements were returning

consistently lower values than those of the model. Upon closer inspection it was found that a

0

20

40

60

80

100

0 10 20 30 40 50

Pe

rce

nt

Smal

ler

Than

Particle Diameter (μm)

TRCA Average Monitored Storm

83

baseflow of TSS was exiting the USDC and influencing pollutant removal rates. Storms which

had lower concentrations of TSS in the inflow were most affected by the baseflow since it is a

larger fraction of the inflow TSS compared to those storms with high TSS runoff. The baseflow

is caused by those particles remaining from previous storms, which are either incapable of

settling or did not have sufficient time to settle. In order to ascertain the single event removal, the

baseflow TSS for each storm was determined and subtracted from the pollutants entering and

exiting the USDC.

The results of the particle removal assessment for MUDS are shown in Figure 40 with a

summary of the raw data following in Table 36. Removal percentages between the measured and

the modeled results were consistently within a few percent of each other following the removal

of the baseflow with one exception; the September 13-14 event had poor flow prediction and

very low concentrations of TSS at the inlet and outlet leading to an inaccurate prediction.

Figure 40: Assessment of Particle Removal Results

0.1

1

10

100

Dif

fere

nce

Bet

wee

n M

easu

red

an

d

Mo

del

ed P

arti

cle

Rem

ova

l (%

)

84

Table 36: Assessment of Particle Removal Summary Storm Event Modeled Particle Removal Measured Particle Removal

September 2-4 100 97.1

September 5-7 100 95.3

September 10-12 100 95.1

September 13-14 100 62.0

September 15-16 100 95.3

September 21-22 100 98.1

October 3-4 100 99.8

October 6-9 100 99.5

October 15-16 100 96.2

October 16-17 100 99.7

October 20-21 100 99.7

The storms used for assessment all resulted in a predicted removal of 100% of the

particles; therefore, the flow rates and lengths of the storms were not large enough to move

particles from the inlet to the outlet in a single event. While this is problematic for assessing the

accuracy of removal in larger storms, the results do match well with the monitored events after

removing the baseflow from the measured values.

5.2.1 Sensitivity Analysis Sensitivity analysis was conducted on the variables that govern particle removal in

MUDS. The results are shown in Figure 41. The July to August time period was selected for

sensitivity simulations.

Figure 41: Sensitivity Analysis Results

65

70

75

80

85

90

-20% -10% Zero 10% 20%

Par

ticl

e R

em

ova

l Eff

icie

ncy

(%

)

Particle Density USDC Surface Area

85

The original values for particle density, surface area, and length used by MUDS (Table

33) were scaled by -20, -10, 10, and 20% to determine what effect they had on the TSS removal

percent. The length appears to have the largest effect on particle removal. This is intuitive, since

the pathlength of the particle is directly related to how long it has to settle in the USDC. The

surface area has the least effect; it indirectly changes the particle removal by altering the

hydraulics of the USDC.

The three properties all follow linear trends within this ±20% range. The +10% length

value is the only exception. The cause of this discrepancy is most likely due to assumptions

made by MUDS, in particular, the assumption explained in Appendix B – B.4 where the particle

exit height is greater than entry height; this situation may occur several times during the July to

August time period as there are storms which cause a large increase in depth very quickly. If a

large mass of pollutants are present at the very end of the USDC, then they will exit at a height

greater than the entry height which will provide a more conservative removal percentage than

what is actually occurring. Sensitivity analysis of the pathlength was conducted again using the

September – November time period. It was found to follow a linear trend which reinforces the

conclusion that the non-linear trend is a highly situational error based on MUDS’ assumptions.

5.3 Markham USDC MUDS Simulations

5.3.1 Design Storm Simulation In order to determine how well the USDC performs under extreme conditions, two design

storms were simulated with MUDS. Five and ten year storm events with rainfall duration of 2

hours were used; this corresponds to average rainfall intensities of 17.3 mm/hr and 20.2 mm/hr,

respectively (Ministry of Transportation, 2013). The five and ten year events are common design

criteria for quantity control for Ontario municipalities and a 2 hour storm period was selected to

86

test the most extreme conditions for five and ten year storms. For the purposes of this thesis, the

return period of a storm is defined using the average rainfall intensity across a storm event. The

rainfall intensities were assumed to be constant over two hours and were input to the SWMM

model to develop an inflow hydrograph. A first flush ratio of 80/30 was used to predict a highly

concentrated release of pollutants. The designed outlet diameter of 0.12 m was used instead of

the 0.15 m for calibration and validation to evaluate how the USDC acts under designed

conditions. The outflow and inflow hydrographs are shown in Figure 42 and Figure 43.

Figure 42: 5 Year Storm Hydrographs

Figure 43: 10 Year Storm Hydrographs

The peak flow was reduced substantially. The 10 year return period event outflow is well

below the maximum design outflow of 30 L/s, which was the outflow for a 5 year return period

storm. Therefore, the Markham USDC exceeds all hydraulic expectations for reducing peak

0

20

40

60

80

100

120

0 5 10 15 20 25 30

Flo

wra

te (

L/s)

Time (h)

Qout

Qin

0

20

40

60

80

100

120

140

0 5 10 15 20 25 30

Flo

wra

te (

L/s)

Time (h)

Qout

Qin

87

outflow. The model also predicted that 100% of particles would be removed from the runoff

regardless of the extreme conditions. However, the high removal efficiency and peak flow

reduction of the Markham USDC under extreme conditions will undoubtedly be influenced by its

oversizing.

5.3.2 Continuous Simulation (May - Nov) Continuous modeling was conducted to determine how well the USDC removed particles

over several seasons. Rain data gathered at the Milne Dam site during the monitoring period

(May 1st, 2014 – November 30th, 2014) was entered into the SWMM model, and the inflow

hydrograph generated to MUDS. A first flush ratio of 50/50 was used for even distribution of

particles across the entire simulation period. MUDS was designed to be an event-based model, so

the first flush ratio is intended to be used on a per-storm basis, not across an entire year, using a

50/50 first flush releases the particles at a constant rate. The results of the continuous simulation

are shown in Figure 44 and Figure 45.

Figure 44: Hydrographs for Continuous Simulation

88

Figure 45: Modeled Depth for Continuous Simulation

The USDC remained within the hydraulic design parameters (outflow < 30 L/s) for all

storms with the exception of the event that occurred on August 1st, which has an outflow of just

over 200 L/s. Other storms have maximum inflow rates that approach the August 1st storm, but

the outflow does not scale the same way because of the initial conditions of the USDC and the

storm volume. The key difference is the depth in the USDC; the August 1st storm raises the

USDC depth to above the invert depth of the overflow pipes (2.45 m), which causes a severe

increase in the outflow. Using the IDF Curve Lookup tool from the Ministry of Transportation

(2013), the August 1st storm has a 13 year return period, which lies outside the design criteria for

the Markham USDC (5 year return period). Therefore, the Markham USDC is performing to its

design standards for hydraulics.

The overall removal efficiency predicted by MUDS was 81.5%. This matches very

closely with the water quality samples returned from the MOECC labs, which had an average

suspended solids removal of 82%. Therefore, MUDS accurately predicted the removal of

particles in USDC on both an event and continuous basis. In order to more accurately gauge

MUDS' continuous simulation ability, more rain and suspended solids data is required.

89

5.3.3 Seasonal Simulations MUDS was also run to determine how well the USDC removes particles on a seasonal

basis. Three time periods were selected: May-June, July-August, and September-November. The

results of the simulations are presented in Table 37.

Table 37: Seasonal and Overall TSS Removal Simulation Results

Modeled Time Particle Removal

Efficiency (%)

May – June 98.4

July – August 77.8

September -

November 95.1

May - November 81.5

The USDC is able to provide enhanced protection under MOECC standards (80% TSS

removal) except for July-August where it is slightly below the requirement. This makes sense by

examining Figure 45, which shows that this was also the period when the USDC was at the

greatest depth and correspondingly experienced the largest volumes of inflow. Larger volumes

flowing into the USDC lead to longer drainage time and consequently a higher probability that

particles which entered during the storm event or are already present in the USDC will reach the

outlet before settling.

The seasonal rainfall characteristics are an important factor to consider when designing a

USDC. While the Markham USDC achieves an overall removal of 81.5%, the July to August

time period does not meet the enhanced protection standard. If it is required that the USDC

achieve this standard at all times, then an overall removal is irrelavent and the designer should

instead focus on this critical time period where there is a combination of high inflow rates and

large inflow volumes.

Comparing the August 1st storm in Figure 46 to the same storm in Figure 44 shows that

there is a difference of around 70 L/s for the maximum inflow and 90 L/s for the maximum

90

outflow. Similar changes can also be observed in the other simulated storms. A change in the

inflow can only be explained by the conditions in the SWMM model, which in turn effects the

outflow. Investigating the runoff values calculated by SWMM revealed that each subcatchment

was releasing more runoff during the continuous simulation. The source of this error could not be

determined. The removal efficiency using the inflow and outflow rates from the May-November

simulation would most likely be lower than what was found using the July-August simulation.

Figure 46: July to August Simulation Hydrograph

5.3.4 Sizing Simulations Finally, MUDS was used to compare how well runoff would have been treated from the

Markham catchment area if the USDC had been sized for the correct catchment area (5.24 ha),

rather than the original area (7.97 ha). The surface area, average width, and length of the USDC

were reduced by the same factor as the contributing area, to roughly 65.7% (5.24/7.97) of the

original value. MUDS was run using these new values to determine if the USDC still meets the

hydraulic and runoff treatment requirements. The July-August time period was used to develop

the inflow hydrograph to determine the performance under the most intense rainfall conditions.

91

Figure 47: July to August New Area Hydrographs

The results of the simulation are shown in Figure 47. The changes have a profound effect

on the outflow rates calculated by the USDC. This change most notably occurrs in the August 1st

event where the outflow increases from the original July-August simulation (120 L/s) to just

under 200 L/s. The other storms remain under the hydraulic requirements. The reduction in

length and width drastically reduces the removal efficiency of suspended solids, the new USDC

achieves a removal of 51.2% compared to the original 77.8%.

Another simulation was run with the mixed commercial-residental PSD found by the

Toronto and Region Conservation Authority (2012a). This is shown in Table 35. While the

outflow hydrograph remains the same, the removal efficiency of suspended solids improves from

51.2% to 67.1% with the new PSD. This value is still well below the requirments for enhanced

protection under MOECC standards, indicating that a USDC can not be simply scaled based on

the catchment area. An iterative process is required to determine the appropriate dimensions for

the chamber.

This process was performed using the July-August time period to determine what

dimensions would be needed for the USDC for the reduced catchment area (5.24 ha) and the

TRCA PSD. Surface area, width, and length were all reduced to 80% and 85% of their original

values, resulting in a TSS removal efficiency of 79.1% and 84% respectively. Therefore, a

92

USDC with 85% of the original USDC properties is required for enhanced protection. The

hydraulic results are shown in Figure 48. These would be the required USDC measurements to

achieve enhanced protection during the worst time period of the year. Performing this process

using the May-November inflow hydrographs would likely result in a smaller USDC being

necessary.

Figure 48: Reduced Catchment Area with TRCA PSD Hydrographs

5.4 Summary

The chapter discussed the calibration and validation of the SWMM model hydraulics and

hydrology, the assessment of the pollutant removal modeling, and the results of several

simulations by MUDS. Due to various issues with clogging and the splashpad, only storms from

September onwards were utilized for the modeling process.

The SWMM model was calibrated and validated to ensure adequate simulation of the

hydraulics of the Markham USDC catchment. The NSE equation was used to compare measured

and modeled values. It was found that the SWMM model was more accurate for storms with

larger flow rates, NSE values for smaller flow rate storms were disproportionately affected by

small differences in modeled flow rate. Localized variations in rainfall may be partially

responsible for errors since the Markham USDC and rainfall monitoring site were 3 km apart.

The median modeled outflow and depth were within satisfactory to good prediction range (0.36 –

0.75) as recommended by Moriasi et al. (2007). Analyzing the hydraulic data revealed that the

93

Markham USDC reduced peak flow significantly for all modeled events. The mean and median

peak flow reductions were 66.1 and 77.6% respectively.

Assessment of MUDS’ particle removal model was conducted by comparing the modeled

removal to the mass load efficiency calculated from turbidity and flow data. First flush ratio was

determined on a per storm basis using measured turbidity data and the average PSD across

monitored storm was used. Removal percentages between the measured and modeled results

were consistently within a few percent of each other with one exception. The modeled storms

were not large enough to move particles from the inlet to outlet in a single event; however, the

results show that MUDS is accurate for predicting the removal of contaminants on an event

basis.

Several simulations were performed to determine the treatment and hydraulic capability

of the Markham USDC. A 5 and 10 year storm were input to the SWMM model to develop

inflow hydrographs, a first flush ratio of 80/30 was used to predict a highly concentrated release

of pollutants. Peak flows for both storms were below the maximum design outflow of 30 L/s and

no particles from the storm escaped over the duration of the event. Therefore, the Markham

USDC is performing above its design capacity for hydraulics and removal of TSS.

Continuous modeling was conducted to determine the accuracy of MUDS over an

extended time period and how well the Markham USDC removed particles over several seasons.

Rain data gathered at the Milne Dam site during the monitoring period was input to the SWMM

model. The Markham USDC met the hydraulic requirements except on one occasion where a

12.9 year storm occurred, this is beyond the design capacity of the Markham USDC and so is an

acceptable failure. MUDS predicted a removal efficiency of 81.5% which matches very closely

94

with the water quality results (82.1%). Therefore, MUDS is accurate for both event based and

continuous based modeling simulations.

Seasonal simulations were performed to determine whether the time of year has an effect

on USDC performance. The Markham USDC was found to perform worse during the July-

August time period, it was unable to achieve enhanced protection during this simulation. The

poorer performance during this time period was expected as the summer is when more and

higher intensity storms occur.

Finally, sizing simulations were performed on the Markham USDC, it was originally

designed for a 7.97 ha catchment but the contributing area was reduced to 5.24 ha after

installation. MUDS was used to determine the appropriate size by scaling the surface area, width,

and pathlength equally by the ratio of the areas (5.24/7.97). The predicted removal percentage

was 51.2%, the poor performance may have been due to the very find PSD of the Markham site.

Replacing the PSD with one found in the literature resulted in a removal of 67.1%. The surface

area, width, and pathlength were scaled equally to determine the size required for enhanced

protection. The parameters were scaled to 85% of their original values to achieve enhanced

protection; therefore, USDC cannot be scaled by catchment area, they require iterative use of

MUDS to determine appropriate sizing. The conclusions and recommendations from the work on

this thesis are discussed in the following chapter.

95

Chapter 6 Conclusions and Recommendations

6.1 Conclusions

The purpose of this research was to gain an understanding of how a USDC acts in an

Ontario climate. In the following sections, conclusions which address the research objectives will

be discussed. In summary, the research objectives were to:

1. Identify the stormwater treatment capabilities of USDC using on-site monitoring

2. Compare the runoff treatment from USDC to SWM ponds

3. Create a model that predicts the removal of contaminants in USDC

6.1.1 Objective 1 The stormwater treatment capabilities of a newly constructed StormTrap-DoubleTrapTM

were studied using field monitoring equipment installed in Markham, Ontario. This includes

ISCO samplers at the inlet, Hatch 2, and outlet, and YSI monitors at the inlet and outlet.

Monitoring and maintenance was performed by TRCA technicians from May-December 2014.

Samples were captured by the ISCO samplers during storm events; of those, six at the inlet and

eight at Hatch 2 and the outlet were used for water quality analysis. The Markham USDC was

found to provide peak flow reduction and water quality benefits for many monitored pollutants.

1. The USDC achieved an overall 82% removal efficiency of TSS which meets

enhanced protection requirements under MOECC standards (80% removal).

2. The average un-ionized ammonia concentration of 0.25 μg/L was below the MOECC

guideline of 20 μg/L, but total phosphorus far exceeded its guideline (30 μg/L) with

an average concentration of 111 μg/L.

96

3. All monitored metals achieved the provincial water quality requirements for

maximum allowable concentration (MAC) with the exception of aluminum, copper,

and iron.

4. The concentration of E. coli decreased significantly from the inlet to outlet, but the

median E. coli concentration of 212 c/100mL was greater than the MAC for beach

water in Ontario (100 c/100mL).

5. Temperatures were reduced significantly, with an average at the inlet and outlet of

14.5 and 12.5 oC, respectively.

6. Hydrocarbons were also removed very well, with few samples testing above the

MDL. All hydrocarbons met the provincial water quality requirements with the

exception of fluorene, which has a requirement below the lab MDL.

7. Several depth profile measurements taken showed that there was a slight temperature

gradient and a dissolved oxygen gradient between the surface and bottom of the

USDC.

Statistical analysis was performed to ascertain where the majority of removal was

occurring in the USDC for each individual pollutant. Understanding this assists in the design

process by determining whether the key design factor is the forebay or permanent pool. The

results for pollutants which were significantly removed are summarized in Table 38.

97

Table 38: Summary of Forebay and Residence Time Significance Tests

Pollutant Paired T-Test Results (p<0.05)

Inlet - Hatch 2 Hatch 2 - Outlet Inlet - Outlet

Total Suspended Solids

Turbidity

Nitrogen; ammonia + ammonium

Nitrogen; nitrate + nitrite

Nitrogen; total

Nitrogen; total Kjeldahl

Phosphorus; phosphate

Phosphorus; total

Aluminum

Antimony

Arsenic

Barium

Boron

Cobalt

Copper

Iron

Lead

Manganese

Nickel

Strontium

Titanium

Vanadium

Zinc

Phenanthrene N/A N/A N/A

Fluoranthene N/A N/A N/A

Pyrene N/A N/A N/A

Napthalene N/A N/A N/A

Fluorene N/A N/A N/A

Escherichia coli

Fecal streptococcus

Pseudomonas aeruginosas

Significant Decrease Significant Increase No Significance

6.1.2 Objective 2 The results of the pollutant removal analysis were MUDS compared against SWM ponds

to determine whether USDC provide an equivalent level of treatment. Values were taken from

various sources in the literature.

1. The removal of TSS by USDC was found to be equivalent to that of SWM ponds.

98

2. Phosphorus removal was either above or equivalent to listed removal rates in SWM

ponds.

3. The removal of metals by USDC are either greater or within the same range of

previously published studies with the exception of arsenic.

4. Effluent concentrations of E. coli were roughly equivalent to SWM ponds.

5. Runoff temperature was significantly reduced between the inlet and outlet whereas

SWM ponds consistently release water at an elevated temperature.

Overall, USDC have exhibited pollutant removal efficiencies at a greater or equivalent

level as SWM ponds.

6.1.3 Objective 3 The Model for Underground Detention of Sediment (MUDS) was developed by Nicholas

McIntosh at the University of Toronto. It has shown to be an accurate model for the prediction of

hydraulics and TSS removal for both event and continuous-based modeling. A sensitivity

analysis was performed on the suspended solids removal and it was found that changes in

particle pathlength have the greatest effect on removal percentage. MUDS was also used to

determine seasonal and particle size distribution effects on USDC performance. The findings of

the modeling process are as follows:

1. The Markham USDC remained beneath the required outflow rate of 30 L/s for 5 and

10 year storms with periods of 2 hours. The removal percentage for these storm

events was 100%.

2. Under continuous simulation from May - November the Markham USDC removed

81.5% of particles. There was one failure event where the outflow exceeded 30 L/s,

but this was during a 13 year return period storm which is outside the design capacity

of the USDC.

99

3. Seasonal simulations revealed that the worst performance by the Markham USDC

(77.8% removal efficiency) took place in the July-August time period.

4. An iterative process was conducted using MUDS to determine the USDC dimensions

for the Markham USDC using the final catchment area and the TRCA mixed

commercial-residential particle size distribution. A USDC with 85% of the original

Markham USDC dimensions would provide enhanced protection. This process also

revealed that USDC could not be linearly scaled based on the catchment area.

6.2 Recommendations for Future Research

Through this study the treatment capability of a USDC has been determined, however

this process has also highlighted several areas in which more research is needed. In the following

sections, recommendations for future research are presented for the categories water quality,

modeling, and USDC design in Ontario.

6.2.1 Water Quality Throughout this study, the gathering and analysis of samples was largely successful.

Only for a few parameters were there issues with gathering data. The analysis of the removal of

hydrocarbons was made impossible by the MDL set by the MOECC laboratories. Some of the

samples at the inlet, and the majority of those at Hatch 2 and the outlet, were below the lab MDL

so statistical analysis could not be performed. While the reduction in hydrocarbon concentration

is a good indication of the USDC treating hydrocarbons well, until more accurate tests are

performed the actual removal efficiency can not be determined. Additional water quality samples

are also required to better identify trends in the removal of pollutants by USDC. A sample size of

only eight events is not large enough to identify small changes in concentration as being

statistically significant.

100

Further research is also required on vertical profiles taken in USDC to determine the

existence and extent of thermal and dissolved oxygen stratification during the summer months.

The summer is when the USDC will be most active, so it is important to determine the

characteristics of the water being released during that time. If there is thermal stratification

during the summer, this may bring into question the thermal benefits provided by USDC. The

strong stratification of dissolved oxygen may also be different in the summer months since the

USDC will be receiving more inflow and so will be more turbulent.

The long term performance of USDC must also be studied. This monitoring program

took place over a single year, in order to ascertain the treatment capability of USDC over it's

lifetime a long term study should be conducted. This would also assist in determining the long

term maintenance requirements for sediment and debris cleanout. Extended monitoring can also

be used to determine whether the accumulation of sediment has an effect on the hydraulics or

treatment process of USDC.

6.2.2 Modeling Additional data is required to confirm the accuracy of MUDS for event and continuous

based simulation. For event-based simulations, larger events that result in particles flowing from

the inlet to the outlet in a single event are required before a non-100% removal will occur. For

continuous based, more data available for conducting simulations will increase the confidence in

prediction accuracy. Extended study of USDC may also reveal that accommodations must be

made for the accumulation of sediment and hydraulic losses.

The TSS removal simulated by MUDS could be expanded to include the removal of

pollutants strongly associated with TSS such as nutrients and metals. This also requires more

101

data, as the relationships between dissolved and particle fractions are complex and dependant on

the individual pollutant.

6.2.3 USDC Design in Ontario Through the course of the monitoring program it has become apparent that orifice plates

are not a practical solution to flow rate management on their own. The orifice plate installed on

the Markham USDC site clogged twice in quick succession due to plastic bags entering the

system with runoff. The clogging disrupted flow through the USDC and caused damage to the

orifice plate, resulting in noticeable leaking and a higher flow rate than designed. Without the

ongoing monitoring program, the clogging would not have been noticed and likely would have

persisted until the next maintenance period.

There are several solutions to preventing orifice clogging in SWM ponds such as a

submerged reverse-slope pipe, a trash rack, and a perforated pipe with wire cloth and stone

jacket (Greater Vancouver Sewerage and Drainage District, 1999). The most practical solution

would be to place a finely meshed grate across the opening from the forebay to the permanent

pool. The mesh would be sized such that any object small enough to pass through would not clog

the orifice plate. This solution would prevent any disruption to flow through the USDC and

miscellaneous garbage and debris would be confined to the forebay but adds another component

to the maintenance of USDC.

102

References

Adams, & Papa. (2000). Urban Stormwater Management Planning with Analytical Probabilistic Models. Chichester: John Wiley & Sons Ltd.

Agrawal, & Bewtra. (1985). Modified Approach to Evaluate Column Test Data. Journal of Environmental Engineering, 111(2): 231-234.

AZO Materials. (2007). Effect of Particle Size on The Taste, Texture and Manufacture of Chocolate Products, Particle Size Analysis Using The Micrometics DigiSizer.

Barrett, Irish, Malina, & Charbeneau. (1998). Characterization of Highway Runoff in Austin, Texas. Journal of Environmental Engineerin, 124: 131-137.

Bertrand-Krajewski, Chebbo, & Saget. (1998). Distribution of Pollutant Mass Vs. Volume in Stormwater Discharges and the First Flush Phenomenon. Water Resources, 32(8): 2341-2356.

Brater, King, Lindell, & Wei. (1996). Handbook of Hydraulics for the Solution of Hydraulic Engineering Problems 7th Edition. McGraw-Hill.

Buren, Watt, & Marsalek. (1997). Application of the Log-Normal and Normal Distributions to Stormwater Quality Parameters. Water Resources, 31(1): 95-104.

Canadian Council of Ministers of the Environment. (2015, April 2). Water Quality for the protection of Aquatic Life. Retrieved from Canadian Council of Ministers of the Environment: http://st-ts.ccme.ca/en/index.html?lang=en&factsheet=154#aql_fresh_concentration

Center for Hazardous Substance Research. (2009). Human Health Effects of Heavy Metals. Environmental Science and Technology Briefs for Citizens, 1-6.

Chin. (2013). Water-Resources Engineering. New Jersey: Pearson Education, Inc. Chu, Jones, Piggott, & Buttle. (2009). Evaluation of a Simple Method to Classify the Thermal

Characteristics of Streams Using a Nomogram of Daily Maximum Air and Water Temperatures. North American Journal of Fisheries Management, 29: 1605-1619.

City of Toronto. (2015, January). About Toronto Beaches Water Quality. Retrieved from toronto.ca: http://www.toronto.ca/health/swimsafe/beaches_about.htm

DeMartino, DePaola, Fontant, Marini, & Ranucci. (2011). Pollution Reduction in Receivers: Storm-Water Tanks. Journal of Urban Planning and Development, 137: 29-38.

Environment Canada. (2014, 02 10). Reducing Phosphorus Loads to Lake Simcoe. Retrieved from Environment Canada: http://www.ec.gc.ca/indicateurs-indicators/default.asp?lang=en&n=90435A23-1

Environment Canada Data Explorer. (2012, Nov 15). Environment Canada. Environmental Protection Agency SWMM 5.1 a. (2015). Surface Runoff. In E. P. Agency, EPA SWMM

Help. Environmental Protection Agency SWMM 5.1 b. (2015). Kinematic Wave Routing. In E. P. Agency, EPA

SWMM Help. Freeze, & Cherry. (1979). Groundwater. Englewood Cliffs, N.J.: Prentice-Hall. German, & Svensson. (2002). The Relation Between Stormwater and Sediment Quality in Stormwater

Ponds. Urban Drainage. Greater Vancouver Sewerage and Drainage District. (1999). Best Management Practices Guide for

Stormwater. Gross, D. (2015, April 17). General Sales Manager for Special Projects - StormTrap. (N. McIntosh,

Interviewer) Hallberg. (2006). Suspended Solids and Metals in Highway Runoff-Implications for Treatment Systems.

KTH Architecture and the Built Environment.

103

He, Rochfort, & McFadyen. (2014). Potential Errors and Error Proagation in Methods Used to Determine Particle Removal Efficiency. Journal of Environmental Engineering, 140: 06014002-1 - 06014002-5.

House, Waschbusch, & Hughes. (1993). Water Quality of an Urban Wet Detention Pond in Madison, Wisconsin, 1987-88. U.S. Geological Survey.

Hu. (2001). The Influence of Drainage Canal Discharge on Eutrophication in the St. Lucie Estuary, Florida. World Water Congress.

International Joint Commission. (2013). Lake Erie Ecosystem Priority: Scientific Findings and Policy Recommendations to Reduce Nutrient Loadings and Harmful Algal Blooms.

International Stormwater BMP Database. (2010). International Stormwater Best Management Practices (BMP) Database Pollutant Category Summary: Nutrients.

International Stormwater BMP Database. (2011a). International Stormwater Best Management Practices (BMP) Database Pollutant Category Summary: Solids (TSS, TDS and Turbidity).

International Stormwater BMP Database. (2011b). International Stormwater Best Management Practices (BMP) Database Pollutant Category Summary: Metals.

International Stormwater BMP Database. (2014). Internation Stormwater Best Management Practices (BMP) Database Pollutant Category Statistical Summary Report: Solids, Bacteria, Nutrient, and Metals.

Jayanti, & Narayanan. (2004). Computational Study of Particle-Eddy Interaction in Sedimentation Tanks. Journal of Environmental Engineering, 130: 37-49.

Jones. (2008). Effect of Urban Stormwater BMPs on Runoff Temperature in Trout Sensitive Regions. 11th International Conference on Urban Drainage, (pp. 1-10). Edinburgh.

Karamalegos, Barrett, Lawler, & Malina. (2006). Particle Size Distribution of Highway Runoff and Modification Through Stormwater Treatment. Austin: Center for Research in Water Resources.

Krishnappan, & Marsalek. (2002). Transport Characteristics of Fine Sediments From an On-Stream Stormwater Management Pond. Urban Water, 4: 3-11.

Li, Kang, Lau, Kayhanian, & Stenstrom. (2008). Optimization of Settling Tank Design to Remove Particles and Metals. Journal of Environmental Engineering, 134: 885-894.

Li, L., Kayhanian, & Stenstrom. (2005). Particle Size Distribution in Highway Runoff. Journal of Environmental Engineering, 131: 1267-1276.

Loganathan, Delleur, & Segara. (1985). Planning Detention Storage for Stormwater Management. Journal of Water Resources Planning and Management, 111: 382-398.

Marsalek, Watt, Marsalek, & Anderson. (2003). Winter Operation of an On-Stream Stormwater Management Pond. Water Science and Technology, 48(9): 133-143.

Martino, Paola, Fontana, Marini, & Ranucci. (2011). Pollution Reduction in Receivers: Storm-Water Tanks. Journal of Urban Planning and Development, 137: 29-38.

Masongsong Associates Engineering Limited. (2008). South Unionville Square Town of Markham Functional Servicing Report. Mansongson Associates Engineering Limited.

Merriam Webster. (2015, 03 03). Dictionary Thermocline. Retrieved from www.merriam-webster.com: http://www.merriam-webster.com/dictionary/thermocline

Ministry of Environment and Energy. (1994). Water Management Policies, Guidelines, Provincial Water Quality Objectives of the Ministry of Environment and Energy. Queen's Printer Ontario.

Ministry of Transportation. (2013, September 11). IDF Curve Lookup Online Tool. Ontario, Canada. Moriasi, Arnold, Liew, Bingner, Harmel, & Veith. (2007). Model Evaluation Guidelines for Systematic

Quantification of Accuracy in Watershed Simulations. American Society of Agricultural and Biological Engineer, 885-900.

Natarajan and Davis. (2010). Thermal Reduction by an Underground Storm-Water Detention System. Journal of Environmental Engineering, 136: 520-526.

104

National Post. (2014, January 8). Toronto ice storm cost expected to soar to $106-million, as extreme weather costs city $171-million in 2013. Retrieved from news.nationalpost.com: http://news.nationalpost.com/2014/01/08/toronto-ice-storm-cost-expected-to-soar-to-106-million-as-extreme-weather-costs-city-171-million-in-2013/

Nix, Heaney, & Huber. (1988). Suspended Solids Removal in Detention Basins. Journal of Environmental Engineering, 114: 1331-1343.

Ontario Ministry of Environment. (2003). Stormwater Management Planning and Design Manual. Queen's Printer for Ontario.

Pettersson. (2002). Characteristics of Suspended Particles in a Small Stormwater Pond. Global Solutions for Urban Drainage (pp. 1-12). Portland, Oregon: American Society of Civil Engineers.

Pitt. (2002). Receiving Water Impacts Associated with Urban Runoff. In Hoffman, Rattner, Burton, & Cairns, Handbook of Ecotoxicology, 2nd Edition. NY: CRC Press.

Pitt. (2003). The Design, Use, and Evaluation of Wet Detention Ponds for Stormwater Quality Management. Department of Civil Engineering, University of Alabama.

Sansalone and Cristina. (2004). First Flush Concepts for Suspended and Dissolved Solids in Small Impervious Watersheds. Journal of Environmental Engineering, 130: 1301-1314.

Schiff, Bay, & Diehl. (2003). Stormwater Toxicity in Chollas Creek and San Diego Bay, California. Environmental Monitoring and Assessment, 81: 119-132.

Shaver, Horner, Skupien, May, & Ridley. (2007). Fundamentals of Urban Runoff Management: Technical and Institutional Issues. U.S. Environmental Protection Agency.

Song, Xenopoulos, Buttle, Marsalek, Wagner, Pick, & Frost. (2013). Thermal Stratification Patterns in Urban Ponds and Their relationships with Vertical Nutrient Gradients. Journal of Environmental Management, 127: 317-323.

Stahre, & Urbonas. (1990). Stormwater Detention. New Jersey: Prentice Hall, Inc. Stormwater Assessment Monitoring and Performance Program. (2005). Synthesis of Monitoring Studies

Conducted Under the Stormwater Assessment Monitoring and Performance Program. Toronto and Region Conservation Authority.

Strecker, Quigley, Urbonas, Jones, & Clary. (2001). Determing Urban Storm Water BMP Effectiveness. Journal of Water Resources Planning and Management, 127: 144-149.

Takamatsu, Barrett, & Charbeneau. (2006). Modeling of Sedimentation in Stormwater Detention Basins. Water Environment Foundation.

Takamatsu, Barrett, & Charbeneau. (2010). Hydraulic Model for Sedimentation in Storm-Water Detention Basins. Journal of Environmental Engineering, 136: 527-534.

Thomson, McBean, Snodgrass, & Mostrenko. (1997). Sample Size Needs for Characterizing Pollutant Concentrations in Highway Runoff. Journal of Environmental Engineering, 123: 1061-1065.

Tiefenthaler, Schiff, & Bay. (2001). Characteristics of Parking Lot Runoff Produced by Simulated Rainfall. Southern California Coastal Water Research Project.

Toronto and Region Conservation Authority. (2012a). Characterization of Particle size Distributions of Runoff from High Impervious Urban Catchments in the Greater Toronto Area.

Toronto and Region Conservation Authority. (2012b). Memorandum: Proposed surface water monitoring program for the South Unionville Square DoubleTrap performance evaluation.

Toronto and Region Conservation Authority. (2012c). Evaluation of Permeable Pavements in Cold Climates. Vaughan: Toronto and Region Conservation Authority.

United States Environmental Protection Agency. (2015, April 18). Total Nitrogen. Retrieved from www.epa.gov: http://www.epa.gov/region9/water/tribal/training/pdf/TotalNitrogen.pdf

United States Geological Survey. (2011). Characterizing the Size Distribution of Particles in Urban Stormwater by Use of Fixed-Point Sample-Collection Methods. Virginia: United States Geological Survey.

105

US EPA. (2015, February 17). Drinking Water Contaminants. Retrieved from United States Environmental Protection Agency: http://water.epa.gov/drink/contaminants/#two

USEPA. (1983). Results of the Nationwide Urban Runoff Program PB 84- 185552. Washington, DC. USEPA. (2015, March 24). Watershed Assessment, Tracking & Environmental Results. Retrieved from

iaspub.epa.gov: http://iaspub.epa.gov/waters10/attains_nation_cy.control?p_report_type=T USGS. (2006, September 27). USGS Water-Quality Information. Retrieved from water.usgs.gov:

http://water.usgs.gov/owq/FieldManual/Chapter6/conversion.html Vatankhah. (2010). Flow Measurement Using Circular Sharp-Crested Weirs. Flow Measurement and

Instrumentation, 21: 118-122. Vaze, & Chiew. (2004). Nutrient Loads Associated With Different Sediment Sizes in Urban Stormwater

and Surface Pollutants. Journal of Environmental Engineering, 130: 391-396. Viessman, & Hammer. (1985). Water Supply and Pollution Control. New York: Harper & Row. Wanielista, & Yousel. (1993). Stormwater Management. New York: John Wiley and Sons. Water Environment Research Federation. (2003). Metals Removal Technologies for Urban Stormwater.

Alexandra, VA: Water Environment Federation. Water Environment Research Federation. (2005). Critical Assessment of Stormwater Treatment Controls

and Control Selection Issues. Alexandria, VA: Water Environment Federation. Wong, Fletcher, & Duncan. (2006). Modelling Urban Stormwater treatment-A Unified Approach.

Ecological Engineering, 27(1): 58-70. Wu, Holman, & Dorney. (1996). Systematic Evaluation of Pollutant Removal by Urban Wet Detention

Ponds. Journal of Environmental Engineering, 122: 983-988. Zawilski, & Sakson. (2008). Modelling of Detention-Sedimentation Basins for Stormwater Treatment

Using SWMM Software. 11th Internation Conference on Urban Drainage, (pp. 1-10). Edinburgh.

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Appendix A: Layout of MUDS Interface

The layout below (Appendix Figure A 1) includes sample values in each of the cells

required for MUDS to run and an example of the removal percentage output.

Appendix Figure A 1: Layout of MUDS Interface

t (s) Qin (m3/s) delta t (s) Tank Dimensions h(t) Qout(t) Qout L/s Removal (%)= 82.62389039

0.00 300 SA (m2) = 854 1.38 0 0

300.00 Width (m) = 12

Baseflow Height to Outlet Orifice Invert (m) = 1.38

0 Orifice Diameter (m) = 0.12

Starting Height (m) 1.38

Starting Qout (m3/s) 0

Length (m) 80

Particle Density (Kg/m3) 2650

Particle Size Distribution

d10 (um) 0.8

d20 (um) 1.2

d30 (um) 1.6

d40 (um) 2.2

d50 (um) 3.1

d60 (um) 4.5

d70 (um) 6.6

d80 (um) 10.6

d90 (um) 19.2

First Flush Ratio (Pollutant Mass/Volume)

Percentage of Pollutants 50

Percentage of Flow 50

Overflow Outlets

Number 4

Height to Outlet Orifice Invert 1 (m) = 2.448

Orifice Diameter 1 (m) = 0.525

Height to Outlet Orifice Invert 2 (m) = 2.448

Orifice Diameter 2 (m) = 0.525

Height to Outlet Orifice Invert 3 (m) = 2.448

Orifice Diameter 3 (m) = 0.525

Height to Outlet Orifice Invert 4 (m) = 2.448

Orifice Diameter 4 (m) = 0.525

Water Density (Kg/m3) = 998.21

Water Dynamic Viscosity (Kg/m·s)) = 0.001002

Q Calculation Progress

Treatment Calculation Progress

107

Appendix B: Removal Percentage Calculation

As explained in Section 3.4.3, users are prompted to enter a particle size distribution

before running MUDS. These particle sizes represent thresholds, if a particle size settles to the

bottom of the USDC then a known percentage of TSS has been removed (e.g. if the d50 particle

has settled then 50% of TSS has been removed). MUDS tracks waves of particles as they

progress through the USDC, Appendix Figure B 1 represents how MUDS interprets the tracking

information calculated for each particle wave where hini is the initial height (m), and tf is the time

the particle wave exited the USDC (s). When visualizing the settling paths of these threshold

particle sizes, the settling paths can be interpreted as lines of removal (e.g. the d40 settling path

represents the 60% line of removal). The particles are divided into 10% segments by the lines of

removal.

Appendix Figure B 1: MUDS Settling Path Prediction

The settling velocity of a particle diameter can be determined using the following

equation:

𝑉𝑠 =

ℎ𝑖𝑛𝑖

𝑡𝑓 (B1)

108

The height of the particle at each point in time (hp(t)) can then be determined using this

simple equation of a line:

ℎ𝑝(𝑡) = −𝑉𝑠 ∗ 𝑡 + ℎ𝑖𝑛𝑖 (B2)

Rearranging for time yields equation B3:

𝑡 =

ℎ𝑝(𝑡) − ℎ𝑖𝑛𝑖

−𝑉𝑠=

ℎ𝑖𝑛𝑖 − ℎ𝑝(𝑡)

𝑉𝑠 (B3)

Not all threshold particle sizes reach the bottom of the USDC before reaching the outlet,

when this occurs there is a partial removal of the particles in the segment between the larger

threshold particle size that settled out and the one that did not. An average settling velocity for

the segment must be calculated to determine how much of the segment is removed. One of the

conditions to calculate this partial removal is that the difference between one line of removal

(e.g. 40%) to the time to finish must be equal to the difference between the next line (e.g. 50%)

at the same height. This is represented by the lines labeled a and b in Appendix Figure B 1, and

by the following equations:

𝑎 = 𝑏 (B4)

𝑡𝑓 − 𝑡𝑎 = 𝑡𝑏 − 𝑡𝑓 (B5)

Rearranging yields:

2𝑡𝑓 = 𝑡𝑏 + 𝑡𝑎 (B6)

This equation can be combined with the equation B3:

𝑡𝑎 =ℎ𝑖𝑛𝑖 − ℎ𝑝

𝑉𝑠𝑎 𝑡𝑏 =

ℎ𝑖𝑛𝑖 − ℎ𝑝

𝑉𝑠𝑏

𝑡𝑎 + 𝑡𝑏 =

ℎ𝑖𝑛𝑖 − ℎ𝑝

𝑉𝑠𝑎+

ℎ𝑖𝑛𝑖 − ℎ𝑝

𝑉𝑠𝑏 (B7)

109

𝑡𝑎 + 𝑡𝑏 =𝑉𝑠𝑎(ℎ𝑖𝑛𝑖 − ℎ𝑝) + 𝑉𝑠𝑏(ℎ𝑖𝑛𝑖 − ℎ𝑝)

𝑉𝑠𝑎 ∗ 𝑉𝑠𝑏

Where hp is the height at which a = b. Substituting using equation B6:

2𝑡𝑓 =

(ℎ𝑖𝑛𝑖 − ℎ𝑝)(𝑉𝑎 + 𝑉𝑏)

𝑉𝑠𝑎 ∗ 𝑉𝑠𝑏 (B8)

Finally, the height at which a = b can be calculated by rearranging:

ℎ𝑝 = ℎ𝑖𝑛𝑖 −

2𝑡𝑓 ∗ 𝑉𝑠𝑎 ∗ 𝑉𝑠𝑏

𝑉𝑠𝑎 + 𝑉𝑠𝑏 (B9)

The removal percentage of a segment attributed to the total removal of a wave is the ratio

of the settling velocity of the segment to the critical settling velocity for that wave times the

percentage that segment represents (10%)

𝑅𝐹𝑟𝑎𝑐𝑡𝑖𝑜𝑛 =

𝑉𝑠𝑒𝑔𝑚𝑒𝑛𝑡

𝑉𝑠𝑐∗ (𝑑𝑖𝑓𝑓 𝑖𝑛 %) (B10)

The settling velocity of the segment is calculated using equation B11:

𝑉𝑠𝑒𝑔𝑚𝑒𝑛𝑡 =

ℎ𝑖𝑛𝑖 − ℎ𝑝

𝑡𝑓 (B11)

Substituting with equation B9:

𝑉𝑠𝑒𝑔𝑚𝑒𝑛𝑡 =ℎ𝑖𝑛𝑖 − ℎ𝑖𝑛𝑖 +

2𝑡𝑓 ∗ 𝑉𝑎 ∗ 𝑉𝑏

𝑉𝑎 + 𝑉𝑏

𝑡𝑓

𝑉𝑠𝑒𝑔𝑚𝑒𝑛𝑡 =

2𝑉𝑎 ∗ 𝑉𝑏

𝑉𝑎 + 𝑉𝑏 (B12)

Making a final substitution yields the equation for the removal percentage of a segment

attributed to the total removal of a particle wave:

𝑅𝐹𝑟𝑎𝑐𝑡𝑖𝑜𝑛 =

2𝑉𝑎 ∗ 𝑉𝑏

(𝑉𝑎 + 𝑉𝑏) ∗ 𝑉𝑠𝑐∗ (𝑑𝑖𝑓𝑓 𝑖𝑛 %) (B13)

The critical settling velocity of the particle wave is calculated using equation B14:

110

𝑉𝑠𝑐 =

ℎ𝑖𝑛𝑖

𝑡𝑓 (B14)

There are special conditions where different removal percentage equations are applied.

These include: (1) removal of particles with settling velocity greater than the critical settling

velocity, this can have any value and is not limited to groupings of 10% (values can be 57%,

44%, etc.); (2) removal of particles left over in a ten percent group after calculating removal of

particles with Vs > Vsc (e.g. for 57% fully removed some fraction of the 3% remaining is

partially removed); (3) the fraction of particles removed with particle diameters smaller than the

d10; (4) when a particle group has a height at the outlet that is greater than the height at which it

entered the USDC, this can occur during high intensity and volume storm events cause the water

surface to rise quickly far above the outlet. The calculations for these situations are explained in

sections B.1 – B.4.

B.1 Particles with Vs > Vsc

MUDS begins by determining the smallest particle size that reached the bottom of the

USDC. Every particle larger than this has been fully removed, for example if a d50 is the smallest

particle size to reach the bottom of the USDC before the wave reaches the outlet then 50% of the

particles have been fully removed. The segment between the smallest to be removed and the next

smallest is divided by the critical settling velocity particle path. Therefore, a portion of the

segment is fully removed and a portion only has partial removal. The percentage of particles

fully removed between the smallest to be removed and the next smallest is calculated by linearly

interpolating between the time it takes the larger particle to reach the bottom, the time for a

particle settling at the critical settling velocity, and the time for the smaller particle to reach the

bottom.

111

𝑅𝐹𝑟𝑎𝑐𝑡𝑖𝑜𝑛 =

𝑡𝑓 − 𝑡𝑙𝑎𝑟𝑔𝑒𝑟

𝑡𝑠𝑚𝑎𝑙𝑙𝑒𝑟 − 𝑡𝑙𝑎𝑟𝑔𝑒𝑟∗ (10%) (B15)

Where RFraction is the removal percentage, tf is the time for the particle wave to reach the

outlet (s), tlarger is the time for the larger particle to reach the bottom of the USDC (s), and tsmaller

is the time for the smaller particle (s). The value for tlarger is tracked by MUDS, but tsmaller is

calculated using equation B16.

𝑡𝑠𝑚𝑎𝑙𝑙𝑒𝑟 =

ℎ𝑖𝑛𝑖

𝑉𝑠=

ℎ𝑖𝑛𝑖 ∗ 𝑡𝑓

ℎ𝑖𝑛𝑖 − ℎ𝑒𝑥𝑖𝑡 (B16)

Where hexit is the height at which the particle size exits the USDC. Appendix Figure B 2

shows how MUDS interprets these values.

Appendix Figure B 2: MUDs Interpretation of tlarger and tsmaller

B.2 Partial Removal of Particles after Fully Removed is Determined

The partial removal of the remaining portion of the segment that was not fully removed

in the calculation in Section B.1 is calculated using equation B13, but the value for Vsc is used in

place of Va. To determine what portion of the segment was not fully removed, another linear

interpolation is performed. The final equation for the removal of this segment of the particles is

shown in equation B17.

112

𝑅𝐹𝑟𝑎𝑐𝑡𝑖𝑜𝑛 =

2𝑉𝑠𝑐 ∗ 𝑉𝑏

(𝑉𝑠𝑐 + 𝑉𝑏) ∗ 𝑉𝑠𝑐∗

𝑡𝑠𝑚𝑎𝑙𝑙𝑒𝑟 − 𝑡𝑓

𝑡𝑠𝑚𝑎𝑙𝑙𝑒𝑟 − 𝑡𝑙𝑎𝑟𝑔𝑒𝑟∗ (10 %) (B17)

B.3 Removal of Particles between d10 and d0

It is assumed that the diameter of particles for the smallest 10 percent in the particle size

distribution can be linearly interpolated between the d10 and zero. Therefore, the average settling

velocity for those particles is the settling velocity of the d10 divided by two. The formula for the

removal of this section is presented in equation B18.

𝑅𝐹𝑟𝑎𝑐𝑡𝑖𝑜𝑛 =

h𝑖𝑛𝑖 − ℎ𝑒𝑥𝑖𝑡

2𝑡𝑓 ∗ 𝑉𝑠𝑐∗ (10 %) (B18)

B.4 Particle Exit Height is Greater than Entry Height

This situation can occur during high intensity and volume storm events that cause the

water level to rise quickly far above the outlet, and results in MUDS interpreting the particle

group as having a negative settling velocity. If a particle size has a negative settling velocity it is

assumed that none of the particles between that particle size and the next largest are removed by

the USDC. While this is not strictly true it is an assumption that gives a more conservative

answer for particle removal.

This circumstance can also effect the removal calculation in Section B.1, a particle size

may settle to the bottom but the next smallest may still exit at a height greater than the entry

height given the right conditions. If this occurs, it is assumed that there is no partial removal of

the 10% section and only the particles with diameters larger than the last to settle are fully

removed. For example, if the d50 is removed but the d40 exits at a height greater than the entry

height then only 50% of that wave is removed.

113

Appendix C: Hydrograph and Depth Figures of Storms used for

Validation and Calibration of the SWMM Model

September 2nd Hydrographs and Depth

0

2

4

6

8

10

12

140

60

120

180

240

300

360

0

21

00

42

00

63

00

84

00

10

50

0

12

60

0

14

70

0

16

80

0

18

90

0

21

00

0

23

10

0

25

20

0

27

30

0

29

40

0

31

50

0

33

60

0

35

70

0

37

80

0

39

90

0

42

00

0

44

10

0

46

20

0

48

30

0

50

40

0

52

50

0

54

60

0

56

70

0

58

80

0

60

90

0

Rai

nfa

ll (m

m/5

min

)

Flo

wra

te (

L/s)

Time (s)

NSE = 0.90

Rainfall Qin Modeled Qout Measured Qout Modeled

0

2

4

6

8

10

121.34

1.44

1.54

1.64

1.74

1.84

1.94

2.04

0

21

00

42

00

63

00

84

00

10

50

0

12

60

0

14

70

0

16

80

0

18

90

0

21

00

0

23

10

0

25

20

0

27

30

0

29

40

0

31

50

0

33

60

0

35

70

0

37

80

0

39

90

0

42

00

0

44

10

0

46

20

0

48

30

0

50

40

0

52

50

0

54

60

0

56

70

0

58

80

0

60

90

0

Rai

nfa

ll (m

m/5

min

)

Dep

th (

m)

Time (s)

NSE = 0.92

Rainfall Depth Monitored Depth Modeled

114

September 5th Hydrographs and Depth

0

2

4

6

8

10

12

140

60

120

180

240

300

360

420

480

26

40

0

28

80

0

31

20

0

33

60

0

36

00

0

38

40

0

40

80

0

43

20

0

45

60

0

48

00

0

50

40

0

52

80

0

55

20

0

57

60

0

60

00

0

62

40

0

64

80

0

67

20

0

69

60

0

72

00

0

74

40

0

76

80

0

79

20

0

81

60

0

84

00

0

86

40

0

88

80

0

91

20

0

93

60

0

96

00

0

Rai

nfa

ll (m

m/5

min

)

Flo

wra

te (

L/s)

Time (s)

NSE = 0.84

Rainfall Qin Modeled Qout Measured Qout Modeled

0

2

4

6

8

10

121.34

1.44

1.54

1.64

1.74

1.84

1.94

2.04

26

40

0

28

80

0

31

20

0

33

60

0

36

00

0

38

40

0

40

80

0

43

20

0

45

60

0

48

00

0

50

40

0

52

80

0

55

20

0

57

60

0

60

00

0

62

40

0

64

80

0

67

20

0

69

60

0

72

00

0

74

40

0

76

80

0

79

20

0

81

60

0

84

00

0

86

40

0

88

80

0

91

20

0

93

60

0

96

00

0

Rai

nfa

ll (m

m/5

min

)

Dep

th (

m)

Time (s)

NSE = 0.86

Rainfall Depth Measured Depth Modeled

115

September 10th Hydrographs and Depth

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

10

2

4

6

8

10

0

30

00

60

00

90

00

12

00

0

15

00

0

18

00

0

21

00

0

24

00

0

27

00

0

30

00

0

33

00

0

36

00

0

39

00

0

42

00

0

45

00

0

48

00

0

51

00

0

54

00

0

57

00

0

60

00

0

63

00

0

66

00

0

69

00

0

72

00

0

75

00

0

78

00

0

81

00

0

84

00

0

87

00

0

90

00

0

93

00

0

96

00

0

Rai

nfa

ll (m

m/5

min

)

Flo

wra

te (

L/s)

Time (s)

NSE = 0.45

Rainfall Qin Modeled Qout Measured Qout Modeled

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

11.4

1.405

1.41

1.415

1.42

1.425

0

30

00

60

00

90

00

12

00

0

15

00

0

18

00

0

21

00

0

24

00

0

27

00

0

30

00

0

33

00

0

36

00

0

39

00

0

42

00

0

45

00

0

48

00

0

51

00

0

54

00

0

57

00

0

60

00

0

63

00

0

66

00

0

69

00

0

72

00

0

75

00

0

78

00

0

81

00

0

84

00

0

87

00

0

90

00

0

93

00

0

96

00

0

Rai

nfa

ll (m

m/5

min

)

Dep

th (

m)

Time (s)

NSE = 0.53

Rainfall Depth Measured Depth Modeled

116

September 15th Hydrographs and Depth

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

1.8

20

2

4

6

8

10

0

30

00

60

00

90

00

12

00

0

15

00

0

18

00

0

21

00

0

24

00

0

27

00

0

30

00

0

33

00

0

36

00

0

39

00

0

42

00

0

45

00

0

48

00

0

51

00

0

54

00

0

57

00

0

60

00

0

63

00

0

66

00

0

69

00

0

72

00

0

75

00

0

78

00

0

81

00

0

84

00

0

87

00

0

90

00

0

93

00

0

96

00

0

Rai

nfa

ll (m

m/5

min

)

Flo

wra

te (

L/s)

Time (s)

NSE = 0.39

Rainfall Qin Modeled Qout Measured Qout Modeled

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

1.8

21.39

1.395

1.4

1.405

1.41

1.415

1.42

1.425

1.43

1.435

04

20

08

40

01

26

00

16

80

02

10

00

25

20

02

94

00

33

60

03

78

00

42

00

04

62

00

50

40

05

46

00

58

80

06

30

00

67

20

07

14

00

75

60

07

98

00

84

00

08

82

00

92

40

09

66

00

10

08

00

10

50

00

10

92

00

11

34

00

11

76

00

12

18

00

12

60

00

13

02

00

13

44

00

Rai

nfa

ll (m

m/5

min

)

Dep

th (

m)

Time (s)

NSE = 0.75

Rainfall Depth Measured Depth Modeled

117

September 22nd Hydrographs and Depth

0

1

2

3

4

5

6

7

8

9

100

50

100

150

200

250

300

350

0

30

00

60

00

90

00

12

00

0

15

00

0

18

00

0

21

00

0

24

00

0

27

00

0

30

00

0

33

00

0

36

00

0

39

00

0

42

00

0

45

00

0

48

00

0

51

00

0

54

00

0

57

00

0

60

00

0

63

00

0

66

00

0

69

00

0

72

00

0

75

00

0

78

00

0

81

00

0

84

00

0

87

00

0

90

00

0

93

00

0

96

00

0

Rai

nfa

ll (m

m/5

min

)

Flo

wra

te (

L/s)

Time (s)

NSE = 0.69

Rainfall Qin Modeled Qout Measured Qout Modeled

0

1

2

3

4

5

6

7

8

9

101.35

1.4

1.45

1.5

1.55

1.6

1.65

1.7

0

30

00

60

00

90

00

12

00

0

15

00

0

18

00

0

21

00

0

24

00

0

27

00

0

30

00

0

33

00

0

36

00

0

39

00

0

42

00

0

45

00

0

48

00

0

51

00

0

54

00

0

57

00

0

60

00

0

63

00

0

66

00

0

69

00

0

72

00

0

75

00

0

78

00

0

81

00

0

84

00

0

87

00

0

90

00

0

93

00

0

96

00

0

Rai

nfa

ll (m

m/5

min

)

Dep

th (

m)

Time (s)

NSE = 0.88

Rainfall Depth Measured Depth Modeled

118

October 3rd Hydrographs and Depth

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

1.8

20

2

4

6

8

10

12

14

16

18

20

0

30

00

60

00

90

00

12

00

0

15

00

0

18

00

0

21

00

0

24

00

0

27

00

0

30

00

0

33

00

0

36

00

0

39

00

0

42

00

0

45

00

0

48

00

0

51

00

0

54

00

0

57

00

0

60

00

0

63

00

0

66

00

0

69

00

0

72

00

0

75

00

0

78

00

0

81

00

0

84

00

0

87

00

0

90

00

0

93

00

0

96

00

0

Rai

nfa

ll (m

m/5

min

)

Flo

wra

te (

L/s)

Time (s)

NSE = 0.45

Rainfall Qin Modeled Qout Measured Qout Modeled

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

1.8

21.35

1.36

1.37

1.38

1.39

1.4

1.41

1.42

1.43

1.44

1.45

0

30

00

60

00

90

00

12

00

0

15

00

0

18

00

0

21

00

0

24

00

0

27

00

0

30

00

0

33

00

0

36

00

0

39

00

0

42

00

0

45

00

0

48

00

0

51

00

0

54

00

0

57

00

0

60

00

0

63

00

0

66

00

0

69

00

0

72

00

0

75

00

0

78

00

0

81

00

0

84

00

0

87

00

0

90

00

0

93

00

0

96

00

0

Rai

nfa

ll (m

m/5

min

)

Dep

th (

m)

Time (s)

NSE = 0.45

Rainfall Depth Measured Depth Modeled

119

October 6th Hydrographs and Depth

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

1.8

20

5

10

15

20

25

30

35

40

45

50

08

10

01

62

00

24

30

03

24

00

40

50

04

86

00

56

70

06

48

00

72

90

08

10

00

89

10

09

72

00

10

53

00

11

34

00

12

15

00

12

96

00

13

77

00

14

58

00

15

39

00

16

20

00

17

01

00

17

82

00

18

63

00

19

44

00

20

25

00

21

06

00

21

87

00

22

68

00

23

49

00

24

30

00

25

11

00

25

92

00

Rai

nfa

ll (m

m/5

min

)

Flo

wra

te (

L/s)

Time (s)

NSE = 0.88

Rainfall Qin Modeled Qout Measured Qout Modeled

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

1.8

21.35

1.37

1.39

1.41

1.43

1.45

1.47

1.49

1.51

1.53

07

80

01

56

00

23

40

03

12

00

39

00

04

68

00

54

60

06

24

00

70

20

07

80

00

85

80

09

36

00

10

14

00

10

92

00

11

70

00

12

48

00

13

26

00

14

04

00

14

82

00

15

60

00

16

38

00

17

16

00

17

94

00

18

72

00

19

50

00

20

28

00

21

06

00

21

84

00

22

62

00

23

40

00

24

18

00

24

96

00

Rai

nfa

ll (m

m/5

min

)

Dep

th (

m)

Time (s)

NSE = 0.72

Rainfall Depth Measured Depth Modeled

120

October 15th Hydrographs and Depth

0

0.2

0.4

0.6

0.8

1

1.20

2

4

6

8

10

12

14

16

02

40

04

80

07

20

09

60

01

20

00

14

40

01

68

00

19

20

02

16

00

24

00

02

64

00

28

80

03

12

00

33

60

03

60

00

38

40

04

08

00

43

20

04

56

00

48

00

05

04

00

52

80

05

52

00

57

60

06

00

00

62

40

06

48

00

67

20

06

96

00

72

00

07

44

00

76

80

0

Rai

nfa

ll (m

m/5

min

)

Flo

wra

te (

L/s)

Time (s)

NSE = -1.96

Rainfall Qin Modeled Qout Measured Qout Modeled

0

0.2

0.4

0.6

0.8

1

1.21.35

1.37

1.39

1.41

1.43

1.45

0

24

00

48

00

72

00

96

00

12

00

0

14

40

01

68

00

19

20

02

16

00

24

00

02

64

00

28

80

03

12

00

33

60

0

36

00

0

38

40

04

08

00

43

20

0

45

60

04

80

00

50

40

05

28

00

55

20

05

76

00

60

00

06

24

00

64

80

06

72

00

69

60

0

72

00

0

74

40

07

68

00

Rai

nfa

ll (m

m/5

min

)

Dep

th (

m)

Time (s)

NSE = -0.17

Rainfall Depth Measured Depth Modeled

121

October 16th Hydrographs and Depth

0

1

2

3

4

5

60

20

40

60

80

100

120

140

160

180

0

21

00

42

00

63

00

84

00

10

50

0

12

60

0

14

70

0

16

80

0

18

90

0

21

00

0

23

10

0

25

20

0

27

30

0

29

40

0

31

50

0

33

60

0

35

70

0

37

80

0

39

90

0

42

00

0

44

10

0

46

20

0

48

30

0

50

40

0

52

50

0

54

60

0

56

70

0

58

80

0

60

90

0

63

00

0

65

10

0

Rai

nfa

ll (m

m/5

min

)

Flo

wra

te (

L/s)

Time (s)

NSE = 0.52

Rainfall Qin Modeled Qout Measured Qout Modeled

0

1

2

3

4

5

61.35

1.4

1.45

1.5

1.55

0

21

00

42

00

63

00

84

00

10

50

0

12

60

0

14

70

0

16

80

0

18

90

0

21

00

0

23

10

0

25

20

0

27

30

0

29

40

0

31

50

0

33

60

0

35

70

0

37

80

0

39

90

0

42

00

0

44

10

0

46

20

0

48

30

0

50

40

0

52

50

0

54

60

0

56

70

0

58

80

0

60

90

0

63

00

0

65

10

0

Rai

nfa

ll (m

m/5

min

)

Dep

th (

m)

Time (s)

NSE = 0.36

Rainfall Depth Measured Depth Modeled

122

October 20th Hydrographs and Depth

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

1.8

20

5

10

15

20

25

0

48

00

96

00

14

40

0

19

20

0

24

00

0

28

80

0

33

60

0

38

40

0

43

20

0

48

00

0

52

80

0

57

60

0

62

40

0

67

20

0

72

00

0

76

80

0

81

60

0

86

40

0

91

20

0

96

00

0

10

08

00

10

56

00

11

04

00

11

52

00

12

00

00

12

48

00

12

96

00

13

44

00

13

92

00

14

40

00

14

88

00

Rai

nfa

ll (m

m/5

min

)

Flo

wra

te (

L/s)

Time (s)

NSE = 0.46

Rainfall Qin Modeled Qout Measured Qout Modeled

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

1.8

21.35

1.37

1.39

1.41

1.43

1.45

0

48

00

96

00

14

40

0

19

20

0

24

00

0

28

80

0

33

60

0

38

40

0

43

20

0

48

00

0

52

80

0

57

60

0

62

40

0

67

20

0

72

00

0

76

80

0

81

60

0

86

40

0

91

20

0

96

00

0

10

08

00

10

56

00

11

04

00

11

52

00

12

00

00

12

48

00

12

96

00

13

44

00

13

92

00

14

40

00

14

88

00

Rai

nfa

ll (m

m/5

min

)

Dep

th (

m)

Time (s)

NSE = 0.01

Rainfall Depth Measured Depth Modeled

123

November 6th Hydrographs and Depth

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

1.8

20

2

4

6

8

10

12

14

0

27

00

54

00

81

00

10

80

0

13

50

0

16

20

0

18

90

0

21

60

0

24

30

0

27

00

0

29

70

0

32

40

0

35

10

0

37

80

0

40

50

0

43

20

0

45

90

0

48

60

0

51

30

0

54

00

0

56

70

0

59

40

0

62

10

0

64

80

0

67

50

0

70

20

0

72

90

0

75

60

0

78

30

0

81

00

0

Rai

nfa

ll (m

m/5

min

)

Flo

wra

te (

L/s)

Time (s)

NSE = 0.72

Rainfall Qin Modeled Qout Measured Qout Modeled

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

11.35

1.36

1.37

1.38

1.39

1.4

1.41

1.42

0

27

00

54

00

81

00

10

80

0

13

50

0

16

20

0

18

90

0

21

60

0

24

30

0

27

00

0

29

70

0

32

40

0

35

10

0

37

80

0

40

50

0

43

20

0

45

90

0

48

60

0

51

30

0

54

00

0

56

70

0

59

40

0

62

10

0

64

80

0

67

50

0

70

20

0

72

90

0

75

60

0

78

30

0

81

00

0

Rai

nfa

ll (m

m/5

min

)

Dep

th (

m)

Time (s)

NSE = 0.21

Rainfall Depth Measured Depth Modeled

124

November 17th Hydrographs and Depth

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

1.8

20

2

4

6

8

10

12

14

0

21

00

42

00

63

00

84

00

10

50

0

12

60

0

14

70

0

16

80

0

18

90

0

21

00

0

23

10

0

25

20

0

27

30

0

29

40

0

31

50

0

33

60

0

35

70

0

37

80

0

39

90

0

42

00

0

44

10

0

46

20

0

48

30

0

50

40

0

52

50

0

54

60

0

56

70

0

58

80

0

60

90

0

63

00

0

65

10

0

Rai

nfa

ll (m

m/5

min

)

Flo

wra

te (

L/s)

Time (s)

NSE = -0.32

Rainfall Qin Modeled Qout Measured Qout Modeled

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

11.35

1.37

1.39

1.41

1.43

1.45

0

21

00

42

00

63

00

84

00

10

50

0

12

60

0

14

70

0

16

80

0

18

90

0

21

00

0

23

10

0

25

20

0

27

30

0

29

40

0

31

50

0

33

60

0

35

70

0

37

80

0

39

90

0

42

00

0

44

10

0

46

20

0

48

30

0

50

40

0

52

50

0

54

60

0

56

70

0

58

80

0

60

90

0

63

00

0

65

10

0

Rai

nfa

ll (m

m/5

min

)

Dep

th (

m)

Time (s)

NSE = -4.3

Rainfall Depth Measured Depth Modeled

125

November 24th Hydrographs and Depth

0

0.5

1

1.5

2

0

10

20

30

40

50

60

70

80

0

27

00

54

00

81

00

10

80

0

13

50

0

16

20

0

18

90

0

21

60

0

24

30

0

27

00

0

29

70

0

32

40

0

35

10

0

37

80

0

40

50

0

43

20

0

45

90

0

48

60

0

51

30

0

54

00

0

56

70

0

59

40

0

62

10

0

64

80

0

67

50

0

70

20

0

72

90

0

75

60

0

78

30

0

81

00

0

83

70

0

Rai

nfa

ll (m

m/5

min

)

Flo

wra

te (

L/s)

Time (s)

NSE = 0.50

Rainfall Qin Modeled Qout Measured Qout Modeled

0

0.5

1

1.5

2

1.35

1.4

1.45

1.5

1.55

1.6

1.65

1.7

0

27

00

54

00

81

00

10

80

0

13

50

0

16

20

0

18

90

0

21

60

0

24

30

0

27

00

0

29

70

0

32

40

0

35

10

0

37

80

0

40

50

0

43

20

0

45

90

0

48

60

0

51

30

0

54

00

0

56

70

0

59

40

0

62

10

0

64

80

0

67

50

0

70

20

0

72

90

0

75

60

0

78

30

0

81

00

0

83

70

0

Rai

nfa

ll (m

m/5

min

)

Dep

th (

m)

Time (s)

NSE = 0.52

Rainfall Depth Measured Depth Modeled