acid blue 25 (1)

8/12/2019 acid blue 25 (1)

http://slidepdf.com/reader/full/acid-blue-25-1 1/124

************* MATERIAL SAFETY DATA SHEET *************

PRODUCT IDENTIFICATION

RADE NAME--------- ACID BLUE 7

HEMICAL NAME------ N/AHEMICAL FAMILY---- ACID DYESOLOR INDEX #------ ACID BLUE 7. A. S. #--------- N/AAST REVISION DATE. 4/29/2009

I. HAZARDOUS COMPONENTS

OMPONENT PERCENT ----- None

II. PHYSICAL DATA

BOILING POINT--N/A SOLUB. IN WATER--SOLUBLE IN WATER

VAPOR PRESSURE--N/A ODOR--- NONE

VAPOR DENSITY---N/A APPEARANCE--DARK POWDERVOLATILITY----- N/A SPECIFIC GRAV-- N/A

REEZE POINT--- N/A EVAP. RATE--- N/AMELTING POINT---N/A pH OF PRODUCT—N/A

V. FIRE AND EXPLOSION DATA

LASH POINT N/A

ILAMMABLE LIMITS. N/A

N CASE OF FIRE-----DRY CHEMICAL, CO2, WATER SPRAY OR REGULAR FOAM. MOVE CONTAINERS FROM FIREAREA IF YOU CAN DO IT WITHOUT RISK. APPLY COOLING WATER TO SIDES OF CONTAINERS THAT ARE EXPOSED

O FLAMES UNTIL WELL AFTER FIRE IS OUT.

8/12/2019 acid blue 25 (1)


MATERIAL SAFETY DATA SHEET (CONTINUED) **************************

V. FIRE AND EXPLOSION DATA (CONTINUED)

IRE-FIGHTING PROCEDURES----USE SELF-CONTAINED BREATHING APPARATUS TO PROTECT AGAINSTPOTENTIALLY TOXIC AND IRRITATING FUMES.

IRE AND EXPLOSION HAZARDS-----IN CASE OF FIRE OR EXPLOSION, KEEP UNNECESSARY PEOPLE AWAY.SOLTAE HAZARD AREA AND DENY ENTRY. STAY UPWIND, OUT OF LOW

AREAS, AND VENTILATE CLOSED SPACES BEFORE ENTERING.

V. REACTIVITY DATA

TABILITY------- Stable.ONDITIONS TO AVOID----- NONE KNOWN.

NCOMPATIBILITY. STRONG OXIDIZING AGENTS.

HAZARDOUS DECOMPOSITIONRODUCTS---------BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN, AND OTHER POTENATIALLY TOXICUMES.

HAZARDOUSOLYMERIZATION----- Will not Occur.

ONDITIONS TO AVOID---NONE KNOWN.

VI. HEALTH HAZARD DATA

HRESHOLD LIMIT VALUE-----NOT ESTABLISHED.

MAY CAUSE EYE & SKIN IRRITATION. DUST MAY IRRITATE THE RESPIRATORY TRACT.

HAZARD WARNINGS-----D. 0. T. NON-REGULATED SUBSTANCE.HIS PRODUCT IN ITS PRESENT STATEOSES NO THREAT TO HUMAN HEALTH OR THE ENVIRONMENT.

AGE- 2 (CONTINUED NEXT PAGE)

8/12/2019 acid blue 25 (1)



VII. EMERGENCY AND FIRST AID PROCEDURES

ROCEDURES:YES: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES.KIN: WASH WITH MILD SOAP AND WATER.F IRRITATION OCCURS GET MEDICAL ATTENTION.F CLOTHING IS CONTAMINATED, RE- MOVE AND WASH BEFORE REUSE.NHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION.NGESTION: IF CONSCIOUS, GIVE PLENTY OF WATER TO DRINK. GET MEDICAL

ATTENTION. IF UNCONSCIOUS, DO NOT GIVE ANYTHING TO DRINK.GET IMMEDIATE MEDICAL ATTENTION.

VIII. SPECIAL PROTECTION INFORMATION

ESPIRATORY. NIOSH APPROVED DUST RESPIRATOR WHEN NEEDED.

KIN-------IMPERVIOUS GLOVES AND APPROPRIATE EQUIPMENT TO PREVENT PROBABILITY OF PERSONAL CONTACT.

YES----SIDE-SHIELD SAFETY GLASSES.

VENTILATION----Local Exhaust.

THER PROTECTION--- DELUGE SAFETY SHOWER AND EYE WASH STATION SHOULD BE LOCATEI NEAR WORK AREA.


8/12/2019 acid blue 25 (1)



X. SPILL OR LEAK PROCEDURES

TEPS TO BE TAKEN:::: DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL: STOP LEAK IF YOU CAN DO IT WITHOURISK. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIALS AND PLACE INTO CONTAINERS FOR LATER

DISPOSAL. SCRUB SPILL AREA WITH DETERGENT, FLUSH WITH COPIOUS AMOUNT OF WATER.

WASTE DISPOSAL METHOD----BURY OR INCINERATE ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS.

ONTAINER REUSE METHOD----CONTAINERS SHOULD NOT BE REUSED WITHOUT PROFESSIONAL CLEANING ANDECONDITIONING.

X. PRECAUTION MEASURES

9 CFR 1910.1200 AND STATE RIGHT TO KNOW LAWS MAY DESIGNATE THIS PRODUCT AS A NUISANCE DUST. PLEASE REFERO SECTION XII OF MATERIAL SAFETY DATA SHEET FOR HANDLING INSTRUCTIONS.

XI. TRANSPORTATION INFORMATION

DOT HAZARD CLASS---- NON-HAZARDOUSROPER SHIPPING NAME----NON-HAZARDOUS MATERIAL

DOT IDENTIFICATION # …..OMMODITY CLASS---- INK MATERIAL

XII. REGULATORY INFORMATION

. A. R. A.--- NOT REPORTABLE

.S.C.A---- IN COMPLIANCE

. S. H. A. HAZARD CLASSIFICATION:ACUTE:NO CHRONIC: NO FLAMMABLE: NO REACTIVE: NO OXIDIZER: NO

HEALTH FLAMMABILITY REACTIVITY PERSONAL PROT.

H.M.I.S. CLASSIFICATION: 1 1 1 F

N.F.P.A CODES: 1 1 1 N

8/12/2019 acid blue 25 (1)


MATERIAL SAFETY DATA SHEET (END) **************************

XIII. STATES RIGHT TO KNOW LAWS

HAZARDOUS MATERIALS ** NONE***

INGREDIENTS STATE INFORMATION * * N O N E * *

***NON-HAZARDOUS MATERIALS * STATE INFORMATION::::

INGREDIENTS :::PROPRIETARY ACID DYES ::: MA. N.J, PA, CAGLAUBERS SALT 7767-86-68 MA, N.J, PA, CA

XIV. OTHER INFORMATION

ALL INFORMATION AND DATA APPEARING ON THIS M. S. D. S. ARE BELIEVED TO BE RELIABLE & ACCURATE.HOWEVER, IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SAFETY,OXICITY, AND SUITABILITY FOR HIS OWN USE OF THE PRODUCT DESCRIBED. SINCE THE ACTUAL USE BY

OTHERS IS BEYOND OUR CONTROL, NO GUARANTEE, EXPRESSED OR IMPLIED, IS MADE BY KEYCOLOUR INC,,NCORPORATED.USER ASSUMES ALL RISK AND RESPONSIBILITY.

8/12/2019 acid blue 25 (1)


MSDS 02-00021

MATERIAL SAFETY DATA SHEET

------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMENYL YELLOW RG

CHEMICAL FAMILY: ACID YELLOW 19

EMERGENCY PHONE NUMBER: CHEMTREC 800-424-9300

DATE PREPARED: DECEMBER 2009----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS----------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PELAZO DYE 12220-64-3 NOT ESTABLISHED---------------------------------------------------------------------------------------------------------------------------------------------------------------

SECTION III: HAZARDS IDENTIFICATION----------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION.

EFFECTS OF OVEREXPOSURE:EYE CONTACT: NONE IRRITATING.SKIN CONTACT: NONE IRRITATING.INHALATION: MAY BE IRRITATING.INGESTION: NOT KNOWN.CHRONIC EXPOSURE: NOT KNOWN.CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN.MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN

PRIMARY ROUTES OF ENTRY: SKIN CONTACT, EYE CONTACT AND INHALATION.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IV: FIRST AID MEASURES----------------------------------------------------------------------------------------------------------------------------------------------------------------EYE CONTACT: IMMEDIATELY FLUSH EYE WITH FLOWING WATER FOR AT LEAST 15 MINUTES, HOLDINGEYELIDS APART TO IRRIGATE THOROUGHLY. GET MEDICAL ATTENTION.

SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATIONDEVELOPS. REMOVE AND LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.

INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVEARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.

INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS ORINDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION V: FIRE FIGHTING MEASURES----------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED.LOWER EXPLOSIVE LIMIT: NOT APPLICABLE.UPPER EXPLOSIVE LIMIT: NOT APPLICABLETHERMAL DECOMPOSITION: 180CAUTOIGNITION TEMPERATURE: 360C

EXTINGUISHING MEDIA: WATER, DRY CHEMICAL, CARBON DIOXIDE, AND FOAM.

8/12/2019 acid blue 25 (1)


MSDS 02-00022

SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD BE EQUIPPED WITH SELF CONTAINEDBREATHING APPARATUS AND PROTECTIVE CLOTHING.

UNUSUAL HAZARDS: DUST AMY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THEPRESENCE OF SOURCE OF IGNITION.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VI: ACCIDENTAL RELEASE MEASURES----------------------------------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETYEQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEPPOWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS ANDFOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUSAMOUNTS OF WATER. ----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE----------------------------------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOIDPERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONSAND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY.

STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION---------------------------------------------------------------------------------------------------------------------------------------------------------------- ENGINEERING CONTROLS: LOCAL EXHAUST TO MINIMIZE EXPOSURE.

RESPIRATORY PROTECTION: IF EXPOSURE TO DUST IS LIKELY, A NIOSH APPROVED DUST RESPIRATOR ISRECOMMENDED .

EXPOSURE LIMITS: NOT ESTABLISHED.

EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES.

SKIN PROTECTION: WEAR RUBBER GLOVES.

OTHER PROTECTIVE MEASURES: WEAR APRON, COVERALLS, BOOTS AND LONG SLEEVE SHIRT TO PREVENT

SKIN CONTACT.

HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLINGTHIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, ORSMOKING, WASH HANDS AND FACE WITH SOAP AND WATER.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES---------------------------------------------------------------------------------------------------------------------------------------------------------------- APPEARANCE: YELLOW POWDER ODOR: NONESOLUBILITY IN WATER: SOLUBLEBOILING POINT: NOT APPLICABLE.MELTING POINT: 100C .PH: 7.5-9.0--------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY----------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE.

CONDITIONS TO AVOID: NONE KNOWN.

HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.

INCOMPATIBLE MATERIALS: NONE KNOWN.

8/12/2019 acid blue 25 (1)


MSDS 02-00023

HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN ANDSULFUR.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES----------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: >5000 MG/KG RABBIT, SKIN: NON IRRITANTRABBIT, EYES: NON IRRITANT.

ADDITIONAL TOXICITY DATA: SKIN SENSITIZATION: NONE KNOWN ----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XII: ECOLOGICAL INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------BACTERIAL TOXICITY (IC50): BST>300 MG/L 3 HOURSFISH TOXICITY (LC0): >1000 MG/L 48 HOURS

(LC50): >500 MG/L TROUT

----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS---------------------------------------------------------------------------------------------------------------------------------------------------------------- WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA(40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE GOVERNMENTAL REGULATIONS.

CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERALREGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED.DOT TECHNICAL NAME: NOT APPLICABLE.DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE.DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE.DOT REPORTABLE QUANTITY: NOT APPLICABLE.

DOT LABELS: NOT APPLICABLE.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDERSECTION 302 AS EXTREMELY HAZARDOUS.

SARA TITLE III SECTION 304 (CERCLA): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATEDUNDER SECTION 304 AS A HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION.

SARA TITLE III SECTION 312 HAZARD RATING:ACUTE: NOCHRONIC: NOFLAMMABILITY: NOREACTIVITY: NOPRESSURE: NO

SARA TITLE III SECTION 313: THIS PRODUCT IS NOT REPORTABLE FOR SARA 313.

TSCA: THIS PRODUCT IS REGISTERED UNDER THE REGULATIONS OF THE TOXIC SUBSTANCES CONTROL ACT(TSCA).

STATE RIGHT TO KNOW INFORMATIONINGREDIENT CAS NUMBERACID YELLOW 19 12220-64-3

8/12/2019 acid blue 25 (1)


MSDS 02-00024

-----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 1

FIRE - 1REACTIVITY - 0PERSONAL PROTECTION - E

NFPA RATING: HEALTH - 1FIRE - 1REACTIVITY - 0

- DISCLAIMER: KEYCOLOUR INC. BELIEVES ALL THE INFORMATION AND DATA GIVEN IS ACCURATE AS OFTHE DATE OF PREPARATION AND IS OFFERED IN GOOD FAITH. THIS INFORMATION IS GIVEN WITHOUTWARRANTY OR REPRESENTATION SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION.SINCE CONDITIONS OF USE ARE BEYOND OUR CONTROL, KEYCOLOUR INC. EXPRESSLY DISCLAIMS ALLLIABILITY FOR THE USE OR HANDLING OF THIS PRODUCT.------------------------------------------------------------------------------------------------------------------------------------------

8/12/2019 acid blue 25 (1)


MSDS 02-00021

MATERIAL SAFETY DATA SHEETKEYCOLOUR INC.

------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMENYL BLUE SW CRUDE

CHEMICAL FAMILY: ACID BLUE 25


DATE PREPARED: DECEMBER 2009----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTSCHEMICAL NAME CAS NUMBER % BY WT. TLV/PELANTHRAQUINONE 6408-78-2 80% NOT ESTABLISHED---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION

----------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION.

EFFECTS OF OVEREXPOSURE:EYE CONTACT: MAY BE IRRITATING.SKIN CONTACT: MAY BE IRRITATING.INHALATION: MAY BE IRRITATING.INGESTION: NOT KNOWN.CHRONIC EXPOSURE: NOT KNOWN.CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN.MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN




INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS ORINDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION V: FIRE FIGHTING MEASURES----------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED.LOWER EXPLOSIVE LIMIT: NOT APPLICABLE.UPPER EXPLOSIVE LIMIT: NOT APPLICABLEAUTOIGNITION TEMPERATURE: NOT DETERMINED.


8/12/2019 acid blue 25 (1)


MSDS 02-00022


UNUSUAL HAZARDS: DUST MAY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THEPRESENCE OF SOURCE OF IGNITION.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VI: ACCIDENTAL RELEASE MEASURES----------------------------------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETYEQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEPPOWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS ANDFOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUSAMOUNTS OF WATER. ----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE----------------------------------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOIDPERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONSAND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY.







SKIN CONTACT.

HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLINGTHIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, ORSMOKING, WASH HANDS AND FACE WITH SOAP AND WATER.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES---------------------------------------------------------------------------------------------------------------------------------------------------------------- APPEARANCE: BLUE POWDER ODOR: SLIGHT ODORSOLUBILITY IN WATER: SOLUBLEBOILING POINT: NOT APPLICABLE.MELTING POINT: NOT ESTABLISHED.--------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY----------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE.




8/12/2019 acid blue 25 (1)


MSDS 02-00023

HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN ANDSULFUR.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES----------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: NOT ESTABLISHEDRABBIT, SKIN: NOT ESTABLISHEDRABBIT, EYES: NOT ESTABLISHED, PROBABLY IRITATING.

ADDITIONAL TOXICITY DATA: NOT KNOWN.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XII: ECOLOGICAL INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------

NO INFORMATION IS CURRENTLY AVAILABLE.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS---------------------------------------------------------------------------------------------------------------------------------------------------------------- WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA(40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE GOVERNMENTAL REGULATIONS.

CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERALREGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED.DOT TECHNICAL NAME: NOT APPLICABLE.DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE.DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE.DOT REPORTABLE QUANTITY: NOT APPLICABLE.DOT LABELS: NOT APPLICABLE.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION

----------------------------------------------------------------------------------------------------------------------------------------------------------------SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDERSECTION 302 AS EXTREMELY HAZARDOUS.


SARA TITLE III SECTION 312 HAZARD RATING:ACUTE: YESCHRONIC: NOFLAMMABILITY: NOREACTIVITY: NOPRESSURE: NO



STATE RIGHT TO KNOW INFORMATIONINGREDIENT CAS NUMBERACID BLUE 25 6408-78-2

8/12/2019 acid blue 25 (1)


MSDS 02-00024

----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 2


NFPA RATING: HEALTH - 1FIRE - 1REACTIVITY – 0

-------------------------------------------------------------------------------------------------------------------------------------------DISCLAIMER: KEYCOLOUR INC. BELIEVES ALL THE INFORMATION AND DATA GIVEN IS ACCURATE AS OF THEDATE OF PREPARATION AND IS OFFERED IN GOOD FAITH. THIS INFORMATION IS GIVEN WITHOUT WARRANTYOR REPRESENTATION SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. SINCECONDITIONS OF USE ARE BEYOND OUR CONTROL, KEYCOLOUR INC. EXPRESSLY DISCLAIMS ALL LIABILITY FORTHE USE OR HANDLING OF THIS PRODUCT.

8/12/2019 acid blue 25 (1)


In U.S. Call CHEMTEL 1-800-255-3924 24 Hour Emergency Phones

Outside U.S. call CHEMTEL Collect at; 1-813-248-0585

HMIS RATINGS: HEALTH: 1 1 0 F

SECTION 1: PRODUCT IDENTIFICATION

Product I.D.: K410 Product Name: ALIZARINE BRILLANT GREEN 175% Product Description: Acid Green Colorant Powder C.I. Name: Acid Green 25 C.I. Number: 61570 Chemical Family: Anthraquinone dye CAS Number: 4403-90-1 Effective Date: July 17, 2009

SECTION 2: HAZARD IDENTIFICATION AND EMERGENCY OVERVIEW

Emergency Overview: Unprotected contact may cause eye, respiratory, skin irritation

Eye Contact: Depending on duration and personal sensitivity, unprotected contact may cause mild irritation, discomfort, redness, watering,itching or other effects. Heavy contact or for prolonged period may increase effects. Follow ALL supervisor and PersonalProtection instructions in Section 8 of this SDS.

kin Contact: Depending on degree of unprotected contact with product and individual sensitivity, may cause mild irritation to skin, redness,rash, itching, and other effects. Constant/repeated long-term contact with some powdered products may cause abrasion of skinor increase other effects. Some liquid components may be absorbed through unprotected skin causing or adding to effects.

nhalation: Depending on duration of unprotected inhalation of product, vapors, mists, aerosols or dusts may cause mild irritation of thenose, throat, lungs and mucous membranes. Effects may include shortness of breath, cough, nausea, headache or othereffects. Prolonged or heavy exposure, or heating of liquid material may increase severity of symptoms.

ngestion: Depending on amount swallowed, product can cause mild irritation of mouth, throat, esophagus, stomach, and gastrointestinaltract. Effects may include upset stomach, abdominal discomfort, nausea, vomiting, gastrointestinal disturbances, dizziness,diarrhea, or other effects. Aspiration into lungs during vomiting is an emergency and may cause lung injury and life-threateningconditions.

Medical Conditions Aggravated by Exposure:

8/12/2019 acid blue 25 (1)


SAFETY DATA SHEET (continued) Page 2 of 7

K410 ALIZARINE BRILLANT GREEN 175%

Improper protection allowing contact with vapors, mists, aerosols, liquids, splashes or dusts of product by inhalation, eyecontact, or skin contact may aggravate pre-existing conditions or diseases of the respiratory system, skin, or eyes. Individualswith above-noted conditions or known or suspected chemical sensitivities or allergies should avoid working with chemicals.

kin Sensitization: Not known to cause skin sensitization. With careful handling and when good chemical hygiene procedures are followed,

harmful effects are not expected. As a precaution against unforeseen or unexpected sensitivity or possible allergic reactions,follow ALL Personal Protection instructions in Section 8 of this SDS. Respiratory Sensitization:

Not known to cause respiratory sensitization. With careful handling and good chemical hygiene procedures being followed, noharmful effects are expected . As a precaution against unforeseen or unexpected sensitivity or possible allergic reactions,follow ALL Personal Protection instructions in Section 8 of this SDS. All PPE must be cleaned and maintained after each shift.

All exposures should be avoided. Individuals known to be, or suspected to be sensitive to chemical exposure should not workwith chemicals.

pecial Warnings: None for this material

Unusual Health Hazards:

None for this material

upplemental Hazard Information: No additional information is currently available

Notes to Physician: Treat Symptomatically based on Section 2 Hazard Warnings and Section 3 ingredients unless indicated otherwise

Cancer Information: *** Not known to contain carcinogens ***

SECTION 3: OSHA HAZARDOUS INGREDIENTS

Component Wt % OSHA - PEL ACGIH - TLV Recommended

PEL CAS Number

Acid Green 25 4403-90-1 15mg/m3 TWA Totaldust 5mg/m3

Respirable 10mg/m3 TWA Total

dust 3mg/m3Respirable

Not applicable 100.00%

1.00

Unprotected contact with ingredients listed in Section 3 may be hazardous based on OSHA 29 CFR 1910.1200 & related appendices. Components not listed arerade secrets, non-hazardous, or not reportable. This SDS is not intended to offer full disclosure, but all component information is available to medical or emergency

personnel. All hazards are based on contact exposure. Effects may be unpredictable and may vary from person to person due to individual reactions. Reducing oreliminating contact can reduce or eliminate risk. Use protective equipment and clothing in Section 8 to minimize or eliminate contact. Users are responsible forhazard determination and communication. Unless indicated otherwise, non-carcinogenic components are indicated within a 1-10% range, and investigated orpotential carcinogens within a 0.1-1% range. HMIS ratings are based on data interpretation, and vary from company to company. They are intended only for quick,general identification of the degree of potential hazards. Hazards range from 0 (Minimal) up to 4 (Severe). Consult the National Paint & Coatings Association HMISManual for detailed information on ratings. To handle material safely, consider all information in this SDS.

mportant Notice:

SECTION 4: FIRST AID INSTRUCTIONS

Immediately rinse with flowing water for at least 15 minutes while holding eyelids open. Get immediate medical attention, as aprecaution. Have a copy of this Safety Data Sheet available.

Eye Contact:

Immediately remove contaminated clothing. Wash affected area with soap and rinse with plenty of water. Get medicalattention, as a precaution. Have a copy of this Safety Data Sheet available.

Skin Contact:

8/12/2019 acid blue 25 (1)




Immediately move person to fresh air. If breathing is difficult give oxygen, call 911, calm the individual. If not breathing, call911, give artificial respiration (CPR) until medical help arrives. Have this Safety Data Sheet available.

Inhalation:

Do not induce vomiting unless directed to do so by a doctor or by other emergency medical personnel. Forced vomiting ofcertain chemicals may cause aspiration and lung damage. Have this Safety Data Sheet available.

Ingestion:

SECTION 5: FIRE FIGHTING INSTRUCTIONS

Unusual hazards: None expected

Other Hazards: None known

ypes of Extinguishers: CO2, dry chemical, foam, water fog or spray depending on type of fire

ire Fighting Directions: Wear self-contained breathing equipment and fire-proof clothing. Use water spray to cool fire exposed containers if theycannot be safely moved.

SECTION 6: ACCIDENTAL SPILL OR RELEASE INSTRUCTIONS

Special Precautions: None known. Follow general precautions shown below.

Reporting: Check the applicable RQs in Section 15

Static Discharges: IMPORTANT - FOR DYES CONTAINING FLAMMABLE SOLVENTS (Check section 3 for ingredients, section 5 or 9 for f lashpoint, section 14 for transport classification). IF FLAMMABLE, GUARD AGAINST FIRE AND EXPLOSION: Takeprecautionary measures against static discharges when cleaning up leaks or spills of combustibles, flammables and powders.Containers should be properly grounded with metal straps, cables or other appropriate means to relieve static electricity build-up or generation. IMPORTANT: When using, mixing, filling, or otherwise dispensing any types of solvents, do not allowbuildup of flammable or combustible vapors or vapor-air mixtures in confined spaces, storage tanks, or any other areas orenclosures. Totes, drums, pails, and all other containers should be completely sealed when not in use. Flammable vaporscan travel a distance to ignition sources and cause fire or explosion. Take every precaution and monitor all safety factors andsystems, including maintaining more-than-adequate air-exchange ventilation.

Environmental Protection: Immediately dike liquid spills with inert absorbent material (sand, "Oil Dry" or other commercially available spill absorbent) tocontain and soak up liquid. Prevent material from entering floor drains, sewers, or any bodies of water. For powder spills, usesweeping compound, sawdust, or other appropriate material to contain dust. If possible, recover any uncontaminatedmaterials to re-use.

Protective equipment and clothing: Wear all proper personal protective equipment and clothing to care for spill situation. See section 8 of this Safety Data Sheet.

Clean up: After containing liquid spill by diking and soaking up with inert absorbent material, place in labeled container to be sealed forproper and regulated disposal. Only the slightest residue should remain. Try to save uncontaminated material for reusewhenever possible. For powders, use sweeping compound to minimize dust and pick up as much product as possible. Donot allow liquids to seep into drains, sewers, lakes, rivers, etc. Check Sections 1 and 2 for dye description or type. Solventdye residue may be cleaned by scrubbing with detergent, depending on type. Do not add water to water-soluble dyes. Dye isconcentrated. This will increase amount of color to remove. All cleaning or scrubbing liquids used should be absorbed andplaced in labeled containers for correct disposal. Absorbent material containing solvents may release combustible orflammable vapors and should be handled accordingly, properly labeled and disposed. Check Sections 2, 5, 13 & 15 forapplicable instructions and regulations.

8/12/2019 acid blue 25 (1)




SECTION 7: HANDLING AND STORAGE

Warnings and Precautions: No special precautions anticipated. Wear all PPE in section 8 as a precaution, and avoid physical contact with material.

Personal Protection: Wear ALL proper personal protective equipment as outlined in section 8 of this SDS.

Handling, Storage & Temperature Conditions: Keep containers tightly sealed in cool & dry area, out of direct sunlight. IMPORTANT: FOR PRODUCTS LISTINGFLAMMABLE/COMBUSTIBLE SOLVENTS or LOW FLASH POINTS - GUARD AGAINST FIRE AND EXPLOSION: Storeaway from fire hazards and ignition sources, high heat, open flames, welding, hot plates, steam pipes, radiators, etc. Maintaingood ventilation. Guard against static discharges. Ground all containers before mixing or filling. Use non-sparking tools toopen, close or otherwise work with containers. Limit indoor storage to approved areas with automatic sprinklers. Vaporsexpected to be released when material is heated during process operations.

STATIC CHARGES: Take precautionary measures against static discharges when mixing, cleaning, filling or otherwisedispensing combustible or flammable liquids. Containers should be properly grounded with metal straps, cables or otherappropriate means to relieve static electricity build-up or generation.

VAPORS: IMPORTANT: DO NOT ALLOW buildup of flammable or combustible vapors or vapor-air mixtures in confinedspaces, storage tanks, or any other areas or enclosures. Totes, drums and all other containers should be completely sealedwhen not in use. Vapors can travel a distance to ignition sources and cause fire or explosion. Take every precaution andmonitor all safety factors and systems, including maintaining more-than-adequate air-exchange ventilation.

POWDERS: General precautions: Although unlikely in most instances, GUARD AGAINST DUST EXPLOSION HAZARD.Eliminate or keep dust to a minimum. Under the right conditions, high dust concentrations of certain particle sizes mixed withair in a critical ratio in the presence of an ignition source can theoretically cause a dust explosion. Be sure to PROPERLYground containers when filling, mixing or otherwise dispensing powders. KEEP WORK AREA CLEAN AND DUST-FREE.Follow all Section 8 recommendations for Exposure Controls and Personal Protection.

WATER-BASED PRODUCTS: DO NOT ALLOW TO FREEZE.

SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION

Note: Selecting protective equipment & clothing: When choosing personal protective equipment and clothing, consider each worker's environment, all chemicals beinghandled, temperature, ventilation, and all other conditions. Determination of the level of protection needed for the eyes, skinand respiratory system under working conditions is the responsibility of the product end-user or shift supervisor. SDSSections 2, 3, 8 and 11 should be consulted.

Eye protection: As a precaution, wear indirectly vented, splash-proof chemical safety goggles. When handling liquids, wear splash-proofgoggles under a clear face-shield. Face shield is not to be used without these goggles. The type or extent of protectionneeded should be determined by the product end-user or shift supervisor.

Skin Protection: Always wear impervious, chemical-resistant synthetic or rubber gloves. Check with manufacturer for best glove for thematerial being handled. Wear good quality long sleeved work shirt, coveralls, and a rubber or plastic apron. Wash handsafter handling and before eating, drinking or using restroom. Shower after each shift. Clean contaminated but reusableprotective equipment and clothing before reusing and wearing again. Discard contaminated disposable gloves and clothing.The type or extent of protection needed should be determined by the product end-user or shift supervisor.

Respiratory Protection: Depending on type of material handled and processing conditions, the appropriate NIOSH approved air-purifying organicvapor/mist respirator or dust respirator (with proper pre-filters if required) should be worn as a precaution when any inhalationcontact with product is possible. A properly selected, disposable NIOSH approved air-purifying mask may be acceptable(Check with the mask manufacturer). After each shift or when equipment becomes contaminated, clean the respirator andreplace filters in compliance with 29 CFR 1910.134. Discard disposables as often as required. The type or extent ofprotection needed should be determined by the product end-user, shift supervisor or other appropriate on-site manager.

Eye Washes and Other Protection:

8/12/2019 acid blue 25 (1)




Eye wash stations and drench showers should be located within 100 feet or 10-second walk of the work area per ANSIstandard Z358.1-1990.

Ventilation: Local exhaust or other appropriate ventilation should be used to maintain exposure limits below specified amountsrecommended by OSHA, NIOSH, or ACGIH and to draw spray, aerosol, vapors, or dusts away from workers and preventroutine inhalation. At least 10 air changes per hour are recommended for good room ventilation. IMPORTANT - GUARD

AGAINST FIRE AND EXPLOSION: When using, mixing, filling, or otherwise dispensing any types of solvents, do not allowbuildup of flammable or combustible vapors or vapor-air mixtures in confined spaces, storage tanks, or any other areas orenclosures. Totes, drums and all other containers should be completely sealed when not in use. Vapors can travel a distanceto ignition sources and cause fire or explosion. Take every precaution and monitor all safety factors and systems, includingmaintaining more-than-adequate air-exchange ventilation.

Not referenced in literature Airborne Exposure Limits:

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Flash Point: Not applicable pH: Not established % Total VOC: 0.00 % Total Solids / Non-Volatiles: 100.00

Appearance: Greenish powder Density: Not established Odor: None Freezing/Melting Point: Not established Lbs. per gallon: Not established Specific Gravity: Not established Solubility: Soluble. Test in particular applications. Other Properties: No further data Other Components: Not established Decomposition Temperature: ~ 100º C

All Data shown above are typical values, not specifications.

SECTION 10: STABILITY AND REACTIVITY

Product is expected to be stable under normal, ambient (controlled) conditions concerning heat, moisture, pressure, fire andignition hazards, and ventilation. Contact with incompatible or reactive materials may cause hazardous reactions in someproducts if indicated. Check information below.

Stability:

Hazardous Polymerization: Product will not undergo polymerization.

Conditions to Avoid:

Keep containers well sealed, avoid contact with incompatible materials, humidity or high heat

Incompatible Materials: Oxidizing & reducing agents may destroy color.

Hazardous Decomposition Products: In fire: Oxides of carbon, nitrogen sulfur, chlorine, sodium

Possible Hazard Reactions: None known

SECTION 11: TOXICOLOGICAL INFORMATION

Eye Effect Skin Effect Skin Sens Resp Sens Oral LD50 Inh LC50 Mutagen Other Info Component Other Tox

Data

Mild irritant

(Rabbit) Mild irritant

(Rabbit) No Data No Data > 10,000

mg/kg No Data No Data No Data No Data Acid Green 25

8/12/2019 acid blue 25 (1)




SECTION 12: ECOLOGICAL DATA

Other Info Other Test

Data Sewage Ecotoxicity COD Biodeg. BOD Aquatic Tox AOX Component

*** No Data *** SECTION 13: DISPOSAL AND ENVIRONMENTAL CONSIDERATION

Reclaim all uncontaminated material to reuse, recycle or otherwise rework whenever possible. Reuse of materials:

Do not release into sewers, water systems, ground systems or ecosystems without proper authorization. Contain - Do not release:

Incinerate, treat, or bury (landfill), after sampling and testing, at facility approved by applicable federal, state, and localauthorities.

Disposal Methods:

Empty containers may contain residue and/or vapors and should not be reused unless professionally cleaned andreconditioned. Crush if not cleaned, to prevent reuse.

Empty Containers:

Applicable Regulations: See Section 15 if regulated Special Instructions: See Section 15 if regulated

SECTION 14: SHIPPING AND TRANSPORTATION INFORMATION

DOT Regulations (Ground): NOT REGULATED

IATA Regulations (Air): NOT REGULATED

IMDG / IMO Regulations (Water): NOT REGULATED

SECTION 15: REGULATORY INFORMATION

FEDERAL AND STATE LISTS Component Regulatory List Weight % CAS Number

Acid Green 25 4403-90-1 No listings known to be applicable. 100.00%

SARA 311/312 Hazard Categories:

Immediate/Acute Health Hazard: YES Chronic/Delayed Hazard: NO Fire Hazard: NO Sudden Release of Pressure Hazard: NO Reactivity Hazard: NO

8/12/2019 acid blue 25 (1)




GLOBAL CHEMICAL REGISTRATION LISTINGS:

Components listed AICS (Australia): Components listed DSL (Canada): Components listed ECL (Korea): Components listed EINECS (Europe): Components listed ENCS (Japan): Components listed IECSC (China):

NZIoC (New Zealand): Components listed Components listed PICCS (Phillippines): Components listed TSCA (US):

EU Reach: Keystone has taken all relative steps to ensure REACH-Compliance. Please contact us with any REACH-Related questions.

OTHER LISTINGS: Other national or regional registrations not yet determined.

SECTION 16: OTHER INFORMATION

Reason for Revision: Format revisions Reviewed: 071709

The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee

or warranty of any kind, expressed or implied, is made with respect to the information contained herein. This Safety DataSheet was prepared to comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200, and supersedes anyprevious information. Previously dated sheets are invalid and inapplicable.

END OF SDS

Disclaimer:

8/12/2019 acid blue 25 (1)


MSDS 02-00021


----------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ----------------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMENYL BLUE 2GA CRUDE

CHEMICAL FAMILY: ANTHRAQUINONE

C.I.#: ACID BLUE 40

CAS#: 6424-85-7


DATE PREPARED: NOVEMBER 2009

----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS----------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PELACID BLUE 40 6424-85-7

NONE AS PER 29CFR PART 1910.1200. NONE UNDER TITLE III OF SARA.---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION----------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION.





INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS ORINDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION V: FIRE FIGHTING MEASURES----------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED.

8/12/2019 acid blue 25 (1)


MSDS 02-00022

LOWER EXPLOSIVE LIMIT: NOT APPLICABLE.UPPER EXPLOSIVE LIMIT: NOT APPLICABLEAUTOIGNITION TEMPERATURE: NOT DETERMINED.









OTHER PROTECTIVE MEASURES: WEAR APRON, COVERALLS, BOOTS AND LONG SLEEVE SHIRT TO PREVENTSKIN CONTACT.

HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLINGTHIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, ORSMOKING, WASH HANDS AND FACE WITH SOAP AND WATER.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES---------------------------------------------------------------------------------------------------------------------------------------------------------------- APPEARANCE: BLUE POWDER ODOR: SLIGHT ODORSOLUBILITY IN WATER: SOLUBLEBOILING POINT: NOT APPLICABLE.MELTING POINT: NOT ESTABLISHED.--------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY----------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE.


8/12/2019 acid blue 25 (1)


MSDS 02-00023



HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN ANDSULFUR.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES----------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: GREATER THAN 5000 MG/KGRABBIT, SKIN: MILDLY IRRITATINGRABBIT, EYES: MODERATELY IRRITATING.



CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERALREGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED.DOT TECHNICAL NAME: NOT APPLICABLE.DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE.DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE.

RESP. GUIDE PAGE: NOT APPLICABLE.DOT REPORTABLE QUANTITY: NOT APPLICABLE.DOT LABELS: NOT APPLICABLE.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDERSECTION 302 AS EXTREMELY HAZARDOUS.





8/12/2019 acid blue 25 (1)


MSDS 02-00024



FIRE - 1REACTIVITY - 0PERSONAL PROTECTION - F


-------------------------------------------------------------------------------------------------------------------------------------------DISCLAIMER: KEYCOLOUR INC. BELIEVES ALL THE INFORMATION AND DATA GIVEN IS ACCURATE AS OF THEDATE OF PREPARATION AND IS OFFERED IN GOOD FAITH. THIS INFORMATION IS GIVEN WITHOUT WARRANTYOR REPRESENTATION SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. SINCECONDITIONS OF USE ARE BEYOND OUR CONTROL, KEYCOLOUR INC. EXPRESSLY DISCLAIMS ALL LIABILITYFOR THE USE OR HANDLING OF THIS PRODUCT.

8/12/2019 acid blue 25 (1)


MSDS 02-00021


---------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ---------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMECID RHODAMINE B 400%

CHEMICAL FAMILY: XANTHENE


DATE PREPARED: JULY 2009 ---------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS---------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PELACID RED 52 3520-42-1 NOT ESTABLISHED---------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION---------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION.

EFFECTS OF OVEREXPOSURE:EYE CONTACT: MAY BE IRRITATING.SKIN CONTACT: MAY BE IRRITATING.INHALATION: MAY BE IRRITATING.

INGESTION: NOT KNOWN.CHRONIC EXPOSURE: NOT KNOWN.CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN.MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN

PRIMARY ROUTES OF ENTRY: SKIN CONTACT, EYE CONTACT AND INHALATION.---------------------------------------------------------------------------------------------------------------------------------------SECTION IV: FIRST AID MEASURES---------------------------------------------------------------------------------------------------------------------------------------EYE CONTACT: IMMEDIATELY FLUSH EYE WITH FLOWING WATER FOR AT LEAST 15MINUTES, HOLDING EYELIDS APART TO IRRIGATE THOROUGHLY. GET MEDICAL ATTENTION.SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. GET MEDICAL ATTENTION IFIRRITATION DEVELOPS. REMOVE AND LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOTBREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.

INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HASCONVULSIONS.---------------------------------------------------------------------------------------------------------------------------------------

8/12/2019 acid blue 25 (1)


MSDS 02-00022

SECTION V: FIRE FIGHTING MEASURES---------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED.LOWER EXPLOSIVE LIMIT: NOT APPLICABLE.UPPER EXPLOSIVE LIMIT: NOT APPLICABLEAUTOIGNITION TEMPERATURE: NOT DETERMINED. EXTINGUISHING MEDIA: WATER, DRY CHEMICAL, CARBON DIOXIDE, AND FOAM.SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD BE EQUIPPED WITH SELFCONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING.

UNUSUAL HAZARDS: DUST MAY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICALPROPORTIONS AND IN THE PRESENCE OF SOURCE OF IGNITION.---------------------------------------------------------------------------------------------------------------------------------------SECTION VI: ACCIDENTAL RELEASE MEASURES---------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATESAFETY EQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROMENTERING FLOOR DRAINS. SWEEP POWDERS CAREFULLY MINIMIZING DUSTING. SHOVELALL SPILL MATERIALS INTO DISPOSAL DRUMS AND FOLLOW DISPOSAL INSTRUCTIONS.

SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUS AMOUNTS OF WATER. ---------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE---------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CAREAND AVOID PERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TOFEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIALUSE ONLY.STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE.---------------------------------------------------------------------------------------------------------------------------------------SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION

---------------------------------------------------------------------------------------------------------------------------------------ENGINEERING CONTROLS: LOCAL EXHAUST TO MINIMIZE EXPOSURE.

RESPIRATORY PROTECTION: IF EXPOSURE TO DUST IS LIKELY, A NIOSH APPROVED DUSTRESPIRATOR IS RECOMMENDED .EXPOSURE LIMITS: NOT ESTABLISHED.EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES.SKIN PROTECTION: WEAR RUBBER GLOVES.OTHER PROTECTIVE MEASURES: WEAR APRON, COVERALLS, BOOTS AND LONG SLEEVESHIRT TO PREVENT SKIN CONTACT.

HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWERAFTER HANDLING THIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE.BEFORE EATING, DRINKING, OR SMOKING, WASH HANDS AND FACE WITH SOAP AND WATER.---------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES---------------------------------------------------------------------------------------------------------------------------------------APPEARANCE: RED POWDER ODOR: NO ODORSOLUBILITY IN WATER: SOLUBLEBOILING POINT: NOT APPLICABLE.

8/12/2019 acid blue 25 (1)


MSDS 02-00023

MELTING POINT: NOT ESTABLISHED.pH : 6.5-8.0 @ 1G/L WATER--------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY---------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE.




HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OFCARBON, NITROGEN AND SULFUR.---------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES---------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: >5000 MG/KG

RABBIT, SKIN: NOT IRRITATINGRABBIT, EYES: NOT IRRITATING

ADDITIONAL TOXICITY DATA: NONE KNOWN.---------------------------------------------------------------------------------------------------------------------------------------SECTION XII: ECOLOGICAL INFORMATION---------------------------------------------------------------------------------------------------------------------------------------

NO INFORMATION IS CURRENTLY AVAILABLE.---------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS---------------------------------------------------------------------------------------------------------------------------------------

WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUSWASTE UNDER RCRA (40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLEGOVERNMENTAL REGULATIONS.

CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSEDACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE.---------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION---------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED.DOT TECHNICAL NAME: NOT APPLICABLE.

DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE.DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE.DOT REPORTABLE QUANTITY: NOT APPLICABLE.DOT LABELS: NOT APPLICABLE.---------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION---------------------------------------------------------------------------------------------------------------------------------------

8/12/2019 acid blue 25 (1)


MSDS 02-00024

SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALSREGULATED UNDER SECTION 302 AS EXTREMELY HAZARDOUS.

SARA TITLE III SECTION 304 (CERCLA): THIS PRODUCT DOES NOT CONTAIN ANYCHEMICALS REGULATED UNDER SECTION 304 AS A HAZARDOUS SUBSTANCE FOREMERGENCY RELEASE NOTIFICATION.

SARA TITLE III SECTION 312 HAZARD RATING:

ACUTE:NO CHRONIC: YES FLAMMABILITY: NOREACTIVITY: NOPRESSURE: NO


TSCA: THIS PRODUCT IS REGISTERED UNDER THE REGULATIONS OF THE TOXIC SUBSTANCESCONTROL ACT (TSCA).

STATE RIGHT TO KNOW INFORMATIONINGREDIENT CAS NUMBERXANTHENE DYE 3520-42-1

----------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION---------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 1

FIRE - 1REACTIVITY - 0PERSONAL PROTECTION - B


-------------------------------------------------------------------------------------------------------------------------------------------DISCLAIMER: KEYCOLOUR INC. BELIEVES ALL THE INFORMATION AND DATA GIVEN ISACCURATE AS OF THE DATE OF PREPARATION AND IS OFFERED IN GOOD FAITH. THISINFORMATION IS GIVEN WITHOUT WARRANTY OR REPRESENTATION SOLELY FOR YOURCONSIDERATION, INVESTIGATION, AND VERIFICATION. SINCE CONDITIONS OF USE ARE

BEYOND OUR CONTROL, KEYCOLOUR INC. EXPRESSLY DISCLAIMS ALL LIABILITY FOR THEUSE OR HANDLING OF THIS PRODUCT.

+

8/12/2019 acid blue 25 (1)


8/12/2019 acid blue 25 (1)



------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMECID VIOLET NRR

CHEMICAL FAMILY: ANTHRAQUINONE DYE


DATE PREPARED: FEBRUARY 22, 2009----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

----------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PELACID VIOLET 76 63589-10-6 60-80% NOT ESTABLISHED---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION----------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION.

EFFECTS OF OVEREXPOSURE:EYE CONTACT: MAY BE IRRITATING.SKIN CONTACT: MAY BE IRRITATING.INHALATION: MAY BE IRRITATING.INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF GASTROINTESTINAL TRACT.CHRONIC EXPOSURE: NOT KNOWN.CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN.MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN




INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS ORINDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS.----------------------------------------------------------------------------------------------------------------------------------------------------------------

8/12/2019 acid blue 25 (1)


SECTION V: FIRE FIGHTING MEASURES----------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED.LOWER EXPLOSIVE LIMIT: NOT APPLICABLE.UPPER EXPLOSIVE LIMIT: NOT APPLICABLEAUTOIGNITION TEMPERATURE: NOT DETERMINED.



UNUSUAL HAZARDS: DUST MAY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THEPRESENCE OF SOURCE OF IGNITION.---------------------------------------------------------------------------------------------------------------------------------------------------------------- SECTION VI: ACCIDENTAL RELEASE MEASURES----------------------------------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETYEQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEPPOWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS ANDFOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUSAMOUNTS OF WATER. ----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE----------------------------------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOIDPERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONSAND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY.

STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION----------------------------------------------------------------------------------------------------------------------------------------------------------------

ENGINEERING CONTROLS: LOCAL EXHAUST TO MINIMIZE EXPOSURE.






HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLINGTHIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, ORSMOKING, WASH HANDS AND FACE WITH SOAP AND WATER.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES---------------------------------------------------------------------------------------------------------------------------------------------------------------- APPEARANCE: DARK VIOLET POWDER ODOR: NONESOLUBILITY IN WATER: 10 G/L @20C.

8/12/2019 acid blue 25 (1)


BOILING POINT: NOT APPLICABLE.MELTING POINT: NOT ESTABLISHED.--------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY----------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE.



INCOMPATIBLE MATERIALS: OXIDIZING AND REDUCING AGENTS.

HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN ANDSULFUR.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES----------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: NOT DETERMINED.RABBIT, SKIN: MAY BE IRRITATINGRABBIT, EYES: PROBABLY IRRITATING






8/12/2019 acid blue 25 (1)





STATE RIGHT TO KNOW INFORMATIONINGREDIENT CAS NUMBERACID VIOLET 76 63589-10-6----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 1



-------------------------------------------------------------------------------------------------------------------------------------------DISCLAIMER: KEYCOLOUR INC. BELIEVES ALL THE INFORMATION AND DATA GIVEN IS ACCURATE AS OF

THE DATE OF PREPARATION AND IS OFFERED IN GOOD FAITH. THIS INFORMATION IS GIVEN WITHOUT

WARRANTY OR REPRESENTATION SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION.SINCE CONDITIONS OF USE ARE BEYOND OUR CONTROL, KEYCOLOUR INC. EXPRESSLY DISCLAIMS ALLLIABILITY FOR THE USE OR HANDLING OF THIS PRODUCT.

8/12/2019 acid blue 25 (1)


For 24 hours emergency Chemtrec :: 800-424-9300



RADE NAME--------- TURQUOISE 86

HEMICAL NAME------ N/AHEMICAL FAMILY----PHTHALOCYANINE dYE. A. S. #--------- 1330-38-7AST REVISION DATE. 10/29/09


Metaphosphoric acid hexasodiumalt Content:2 %

Remarks

his product is not regulated under the OSHA hazard communication standard,9CFR1910.1200. or SARA Title III Sect. 312

II. PHYSICAL DATA


VAPOR PRESSURE--N/A ODOR--- NONEVAPOR DENSITY---N/A APPEARANCE--DARK POWDERVOLATILITY----- N/A SPECIFIC GRAV-- N/A



LASH POINT N/A


N CASE OF FIRE-----DRY CHEMICAL, CO2, WATER SPRAY OR REGULAR FOAM. MOVE CONTAINERS FROM FIRE

AREA IF YOU CAN DO IT WITHOUT RISK. APPLY COOLING WATER TO SIDES OF CONTAINERS THAT ARE EXPOSEDO FLAMES UNTIL WELL AFTER FIRE IS OUT.

Phthalocyanine dye

8/12/2019 acid blue 25 (1)







V. REACTIVITY DATA











8/12/2019 acid blue 25 (1)












cological information:

hysico-chemical eliminability : approx. 75 %Method : Iron sulphate precipitation

ish toxicity : LC50 > 100 mg/l (72 h, Leuciscus idus)Method : Range Finding Test

acteria toxicity : 1,000 mg/lNo inhibitory effects, Test method: Growth inhibition testmodified according to G. Bringmann, Gesundheitsingenieur 94,

66-369 (1973)hemical oxygen demand (COD) : 700 mg/g

emarks: Test results of an analogous product.roduct does not add to the AOX-value of the sewage. (DIN EN 1485)his product contains approx. 3,6 % complex bonded copper.he product does not release nitrogen which can contribute to eutrophication.he product contains 0,6 % phophorus as phosphate.


8/12/2019 acid blue 25 (1)


8/12/2019 acid blue 25 (1)














. A. R. A.--- REPORTABLE

ara 313his product contains the following component that is subject to the reporting requirements under0 CFR 372.ontains:

opper-Phthalocyanine-Complex Content: > 50 %Dyestuff

opper Content: 3.6 % CAS number : 7440-50-8ara 312mmediate (acute) health hazard No

Delayed (chronic) health hazard Noire hazard Noudden Release of Pressure Noeactivity No

ther regulations

No labelling is required in accordance with the EEC directives .


8/12/2019 acid blue 25 (1)












OTHERS IS BEYOND OUR CONTROL, NO GUARANTEE, EXPRESSED OR IMPLIED, IS MADE BY KEYCOLOURNCORPORATED. USER ASSUMES ALL RISK AND RESPONSIBILITY.

8/12/2019 acid blue 25 (1)


800.255.3924

________________________________________________________________________________ ____

M A T E R I A L S A F E T Y D A T A S H E E T

________________________________________________________________________________ ____

N O T E: DO NOT DETACH THIS GUIDANCE COVER SHEET FROM THE REST OF THISDOCUMENT.

This page indicates the Keycolour Trade Name and Product ID. Thisidentifying

information must be referenced when ordering products or makinginquiries.

________________________________________________________________________________ ____

A) YOUR CERTIFICATION OF COMPLIANCE UNDER FEDERAL AND STATE REGULATIONS

IMPORTANT NOTE: THIS DOCUMENT IS YOUR OFFICIAL CERTIFICATION OF COMPLIANCEas stated

in each applicable section. It is compiled in accordance with OSHA'sHazard

Communication standard (29 CFR 1910.1200), and other federal and stateregulations.

NOTE: NO ADDITIONAL COMPANY CERTIFICATION OF COMPLIANCE IS REQUIRED WHENCOMPLIANCE

IS INDICATED IN THE APPROPRIATE SECTION OF THIS DOCUMENT. To avoid use ofoutdated

information, please completely destroy ALL previously dated MSDS' that areon file.

________________________________________________________________________________ ____

B) ABOUT THE FORMAT OF THIS MATERIAL SAFETY DATA SHEET

New and updated MSDS' are presented in the ANSI Z400.1 Sixteen-sectionformat. All

available information is included in systematic updates.

________________________________________________________________________________ ____

C) ABOUT THE PURPOSE AND AVAILABILITY OF THIS DOCUMENT

Under the federal OSHA Hazard Communication Standard and some State Rightto Know

EMERGENCY PHONE: Call CHEMTEL

PRODUCT ID: K701

TRADE NAME: KEYACID VIOLET CRUDE

8/12/2019 acid blue 25 (1)


laws, employers using this product in their operation must make this MSDSavailable

to all employees handling this product in any manner. The MSDS must bereadily

available for review by all persons concerned.

This MSDS is designed to effectively communicate Health and Physical Hazardsto the material handler and all other responsible persons concerned with

Health andEnvironmental protection and regulatory compliance. Distributors receiving

this MSDSare obligated to readily provide a copy to their customers, affiliates, and

agents.

________________________________________________________________________________ ____

D) THE PRODUCT USER RESPONSIBILITY NOTICE

This type of document cannot cover all possible unique situations. It is theproduct

user's responsibility to provide a safe workplace, and to pass on allHealth, Safety

and Environmental information to all employees and customers that mayhandle this

product. Under 29 CFR 1910.1200, all product users and handlers must beinformed of

U.S. OSHA requirements, and the need to be familiar with them.

________________________________________________________________________________ ____

<<<<<<<<<< MATERIAL SAFETY DATA SHEET >>>>>>>>>>

------------------------------------------------------------------------------

EFFECTIVE DATE: 11-01-09 SUPERSEDES: PRODUCT CODE: K701

04-29-06 NONE

-------------------------------------------------------------------------------SECTION 1 CHEMICAL IDENTIFICATION

SYNONYM : ACID VIOLET 90(CHROMIUM COMPLEXED DYE)CAS NUMBER : 61916-41-4CHEMICAL FAMILY: AZO METAL COMPLEX DYE

-------------------------------------------------------------------------------SECTION 2 COMPOSITION INFORMATION ON HAZARDOUS INGREDIENTS

COMPONENT NAME CAS NUMBER PEL TLV %

ACID VIOLET 90 (CHROMIUM 61916-41-4 NE NE 85COMPLEX DYE)*

CHROMIUM* 7440-47-3 .5 MG/M3 .5 MG/M3 <3

8/12/2019 acid blue 25 (1)


(AS CR) (AS CR)

*READ SECTIONS 3 AND 11 FOR ANY ADDITIONAL HEALTH & SAFETY INFORMATION

-------------------------------------------------------------------------------SECTION 3 HAZARD IDENTIFICATION AND EMERGENCY OVERVIEW

HMIS RATINGS

HEALTH 1FLAMMABILITY 1REACTIVITY 0PROTECTION F

EMERGENCY OVERVIEW:

POSSIBLE EXPOSURES: EYES, SKIN, BREATHING DUSTS, ACCIDENTAL SWALLOWING

POSSIBLE HEALTH EFFECTS:EYE CONTACT: CAN CAUSE MODERATE IRRITATION 1SKIN CONTACT: BASED ON ANIMAL TOXICITY DATA, THIS PRODUCT IS NOT EXPECTED

TO IRRITATE, HOWEVER, PROLONGED CONTACT CAN POSSIBLY CAUSE IRRITATION 1BREATHING DUST: NE 1SWALLOWING: NE 1

SENSITIZATION: NKTARGET ORGANS: EYES, POSSIBLY SKIN

CANCER INFORMATION:PRODUCT AND COMPONENTS NOT KNOWN TO US TO BE CARCINOGENSNTP: NKIARC: NKOSHA: NR

1 PRECAUTIONS:TO HELP PROTECT YOURSELF FROM EITHER EXPECTED OR UNFORSEEN IRRITATION OR

ALLERGIC REACTIONS, WORKERS SHOULD WEAR ALL PROPERLY SELECTED PROTECTIVEEQUIPMENT AND CLOTHING AS INSTRUCTED IN SECTION 8 OF THIS MSDS. WASHHANDS AND FACE AFTER HANDLING AND BEFORE EATING, DRINKING, SMOKING OR USINGRESTROOM FACILITIES. AFTER EACH SHIFT, CLEAN ALL PROTECTIVE EQUIPMENT, WASH

ALL WORK CLOTHES, AND SHOWER. SEE SECTION 11, TOXICOLOGY INFORMATION

UNUSUAL HAZARDS: IF MIXED WITH AIR IN SUFFICIENT AMOUNTS & PROPORTIONS,ORGANIC DUSTS CAN FORM FLAMMABLE OR EXPLOSIVE DUST/AIR MIXTURES. ASPRECAUTIONS, KEEP AREAS CLEAN AND AVOID DUST BUILD-UP. HAVE PLENTY OFGOOD VENTILATION. AVOID CREATING VERY DUSTY CONDITIONS. WHEN MIXING,POURING OR PROCESSING BULK AMOUNTS OF POWDERS, GROUND ALL CONTAINERS AND

AVOID STATIC CHARGES, SPARKS, SMOKING, OPEN FLAMES, OR OTHER POSSIBLECAUSES OF FIRE OR EXPLOSION.

-------------------------------------------------------------------------------SECTION 4 FIRST AID MEASURES

EYE CONTACT: IMMEDIATELY RINSE WITH PLENTY OF CLEAN FLOWING WATER FOR 15 TO20 MINUTES, HOLDING EYELIDS OPEN TO RINSE COMPLETELY. CALL A DOCTOR,

8/12/2019 acid blue 25 (1)


AND GET MEDICAL ATTENTION IMMEDIATELY, AS A PRECAUTION.

SKIN CONTACT: REMOVE AFFECTED CLOTHING. WASH AFFECTED SKIN AREA WITH PLENTYOF SOAP AND WATER. RINSE WITH PLENTY OF WATER. WASH ALL WORK CLOTHES

BEFORE WEARING AGAIN. IF ANY REDNESS, SWELLING, ITCHING, OR PAIN OF THESKIN STARTS, SEE A DOCTOR IMMEDIATELY.

BREATHING PRODUCT DUST: MOVE PERSON TO FRESH AIR. IF PERSON IS HAVINGDIFFICULTY BREATHING, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIALRESPIRATION. GET EMERGENCY MEDICAL HELP IMMEDIATELY. CALL 911 IF AVAILABLEIN YOUR AREA, OR OTHER MEDICAL EMERGENCY NUMBER.

SWALLOWING OF PRODUCT: IF PERSON IS CONSCIOUS, GIVE WATER OR MILK TO DILUTESTOMACH CONTENTS. NEVER GIVE ANY FLUIDS OR FORCE VOMITING IF THE PERSONIS UNCONSCIOUS, OR IS HAVING CONVULSIONS, OR HAS NO GAG REFLEX. CONTACT

A DOCTOR IMMEDIATELY TO GET MEDICAL HELP, CALL 911, OR OTHER MEDICALEMERGENCY SERVICES AVAILABLE IN YOUR AREA.

-------------------------------------------------------------------------------SECTION 5 FIRE FIGHTING MEASURES

FLASH POINT : NATYPES OF EXTINGUISHERS : CO2, DRY CHEMICAL, FOAM, WATER SPRAYFIREFIGHTING DIRECTIONS: WEAR SELF-CONTAINED BREATHING APPARATUS TO PROTECT

AGAINST POSSIBLY TOXIC FUMES. WEAR FULL FIRE-PROTECTIVE CLOTHING.UNUSUAL HAZARDS : NONE KNOWN

-------------------------------------------------------------------------------SECTION 6 ACCIDENTAL SPILL OR RELEASE MEASURES

INSTRUCTIONS FOR SPILLS AND RELEASES:

WEAR A NIOSH APPROVED DUST RESPIRATOR, WITH ALL PROTECTIVE CLOTHING ANDEQUIPMENT AS DIRECTED IN SECTION 8.

CONTAIN AND CLEAN UP SPILL IMMEDIATELY. SWEEP POWDERS CAREFULLY, USING AN ABSORBENT (SWEEPING COMPOUND) TO KEEP DOWN THE DUST IN THE AREA. SCOOP

MATERIAL & ABSORBENT INTO DISPOSAL DRUM, AND SEAL.

RCRA STATUS: SEE REGULATORY INFORMATION, SECTION 15.

ENVIRONMENTAL PROTECTION: PREVENT FROM ENTERING FLOOR DRAINS OR SEWERS. DONOT RELEASE TO SEWER WITHOUT ALL PROPER GOVERNMENT AUTHORITIES PERMISSION.

CHECK SECTION 13, "DISPOSAL CONSIDERATIONS/ENVIRONMENTAL PROTECTIONPROCEDURES" FOR ANY ADITIONAL INFORMATION.

-------------------------------------------------------------------------------SECTION 7 HANDLING AND STORAGE

PROTECT PRODUCT FROM MOISTURE, STORE IN COOL, DRY PLACE UNDER LOW RELATIVEHUMIDITY, AWAY FROM EXCESSIVE HEAT. STORE IN ORIGINAL OR SIMILAR WATER-PROOF CONTAINERS. RESEAL CONTAINERS TIGHTLY AFTER EACH USE.

8/12/2019 acid blue 25 (1)


-------------------------------------------------------------------------------SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

NOTE: WHEN SELECTING PERSONAL PROTECTIVE EQUIPMENT AND CLOTHING, FOLLOW ALLMANUFACTURER SPECIFICATIONS AND RECOMMENDATIONS THAT APPLY TO YOURSPECIFIC OPERATIONS AND PROCESSING CONDITIONS. TAKE INTO CONSIDERATION

ALL CONDITIONS AND ALL CHEMICALS TO BE HANDLED OR PROCESSEDEYE PROTECTION: WEAR SPLASH-PROOF CHEMICAL SAFETY GOGGLES. CONTACT LENSES

SHOULD NOT BE WORN WHEN WORKING WITH CHEMICALS.

SKIN PROTECTION: WEAR CHEMICALLY RESISTANT RUBBER GLOVES, SELECTED WITHYOUR SPECIFIC PROCESSING CONDITIONS AND CHEMICALS TO BE HANDLED IN MIND.WEAR COVERALLS AND BOOTS TO MINIMIZE SKIN CONTACT. AS PRECAUTIONS, WASHHANDS & FACE WITH MILD SOAP & WATER BEFORE EATING, DRINKING, SMOKING, ORUSING RESTROOM. AFTER EACH SHIFT, CLEAN ALL PROTECTIVE EQUIPMENT, WASHWORK CLOTHES AND SHOWER.

LUNG, THROAT & NASAL PROTECTION: WEAR NIOSH APPROVED DUST RESPIRATOR FORYOUR PARTICULAR OPERATION AND MATERIALS BEING HANDLED.

OTHER PROTECTION: EYE WASH FOUNTAINS & DRENCH SHOWERS SHOULD BE LOCATEDWITHIN 100 FEET OR A 10 SECOND WALK OF THE WORK AREA PER ANSI Z358.1-1990

VENTILATION: LOCAL EXHAUST IS RECOMMENDED.

-------------------------------------------------------------------------------SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

DESCRIPTION : BLUISH PINK POWDER; NO ODORMELTING POINT : DECOMPOSES BEFORE MELTINGWATER SOLUBILITY : 30 G/LPH : 5.6 @ 1% SOLUTIONBULK DENSITY : NE

-------------------------------------------------------------------------------SECTION 10 STABILITY AND REACTIVITY

STABILITY : STABLECONDITIONS TO AVOID : NKHAZARDOUS POLYMERIZATION: NOT APPLICABLEINCOMPATIBLE MATERIALS : AVOID STRONG OXIDIZING & STRONG REDUCING MATERIALSHAZARDOUS DECOMPOSITION PRODUCTS: BURNING CAN PRODUCE CO, CO2, OXIDES OF

NITROGEN AND SULFUR, AND OTHER POTENTIALLY TOXIC FUMES.

-------------------------------------------------------------------------------SECTION 11 TOXICOLOGY INFORMATION

FOR C.I. ACID VIOLET 90:ORAL LD50 (RAT): > 5000 MG/KGDERMAL LD50 (RAT): NEINHALATION LC50 (RAT): NE

EYE EFFECTS (RABBIT): MODERATE IRRITANT 1

8/12/2019 acid blue 25 (1)


SKIN EFFECTS (RABBIT): NE 1BREATHING EFFECTS: NE 1

CHECK SECTION 3 FOR ANY OTHER OBSERVATIONS, EXPECTATIONS OR COMMENTS

1) AS PRECAUTIONS TO HELP MINIMIZE CONTACT, WEAR ALL PROTECTIVE EQUIPMENT &

CLOTHING AS INSTRUCTED IN THE EXPOSURE CONTROLS AND PERSONAL PROTECTIONSECTION OF THIS MSDS. SEE SECTION SECTION 8.

GENERAL PRECAUTIONS: ALWAYS PRACTICE GOOD INDUSTRIAL HYGIENE, HANDLE WITHCARE, AVOID PERSONAL CONTACT. DO NOT GET INTO EYES OR ON SKIN, DO NOTBREATHE DUST OF PRODUCT, DO NOT SWALLOW. WASH HANDS WITH SOAP AND WATER,

AND RINSE WELL AFTER HANDLING PRODUCT. SHOWER AFTER EACH SHIFT. WASH ALL WORK CLOTHING AND COMPLETELY CLEAN ALL PROTECTIVE EQUIPMENT AFTER

EACH SHIFT. READ SECTIONS 3 AND 8.

MUTAGENICITY: NK

ADDITIONAL INFORMATION: CHECK SECTION 3

MEDICAL CONDITIONS MADE WORSE BY EXPOSURE: PERSONS WITH BREATHING AND LUNGPROBLEMS CAN BE AFFECTED BY BREATHING IN ANY TYPE OF DUSTY MATERIAL.PERSONS WITH ASTHMA, ALLERGIES, OR OTHER BREATHING-RELATED PROBLEMS SHOULDSTAY AWAY FROM, NOT HANDLE, AND NOT BE EXPOSED TO ANY DUSTY PRODUCTS ORDUSTY CONDITIONS AS A PRECAUTIONARY MEASURE.

-------------------------------------------------------------------------------SECTION 12 ECOLOGICAL DATA

BOD 5: NECOD: NEFISH TOXICITY: NESEED TOXICITY: NECWA TOXIC POLLUTANTS: NKBIOLOGICAL ELIMINATION: NE

-------------------------------------------------------------------------------SECTION 13 DISPOSAL CONSIDERATIONS/ENVIRONMENTAL PROTECTION PROCEDURES

DISPOSAL METHODS:

IT IS RECOMMENDED THAT YOU SELECT AN ALTERNATIVE BELOW ACCORDING TOTHE FOLLOWING ORDER OF PREFERENCE, DEPENDING ON ENVIRONMENTAL IMPACT:

1) RECYCLE OR REWORK MATERIAL IF AT ALL POSSIBLE2) INCINERATE MATERIAL AT AN APPROVED FACILITY3) TREAT AT AN ACCEPTABLE WASTE TREATMENT FACILITY, OR MUNICIPAL WASTE

TREATMENT PLANT AFTER PROPER TESTING & APPROVAL OF WASTE SAMPLES

IF DISPOSED OF IN IT'S ORIGINAL UNUSED FORM, THIS MATERIAL SHOULD BETREATED, AND DISPOSED OF AT AN APPROVED SITE OR FACILITY, IN COMPLIANCE

WITH ALL APPLICABLE FEDERAL, STATE & LOCAL ENVIRONMENTAL REGULATIONS. YOUMUST CONTACT THE PROPER GOVERNMENT AGENCIES FOR ADDITIONAL DIRECTIONS.

8/12/2019 acid blue 25 (1)


ALL WASTE MATERIAL & WASTE WATER SHOULD BE DISPOSED OF CORRECTLY, UNDER ALL FEDERAL, STATE , CITY & COUNTY LAWS.

RCRA STATUS: SEE SECTION 15, REGULATORY INFORMATION

DO NOT RELEASE ANY CHEMICALS, DYES OR DYE SOLUTIONS INTO ANY WATERWAYS OR

SYSTEMS WITHOUT PROPER GOVERNMENT TESTING AND AUTHORIZATION.CONTAINER REUSE: AN "EMPTY" CONTAINER CAN CONTAIN PRODUCT RESIDUE, AND

SHOULD NOT BE REUSED. IF NOT PROFESSIONALLY CLEANED & RECONDITIONED,CRUSHING OR OTHER MEANS IS RECOMMENDED TO PREVENT UNAUTHORIZED REUSE

-------------------------------------------------------------------------------SECTION 14 TRANSPORT INFORMATION

DOT STATUS: NR

------------------------------------------------------------------------------SECTION 15 REGULATORY INFORMATION

AICS (Australia): ListedCAA: PRODUCT IS NOT MANUFACTURED WITH, NOR DOES IT CONTAIN CLASS I OR CLASS

II OZONE DEPLETING CHEMICALS.CAL. PROP. 65: CONTAINS THE FOLLOWING CHEMICALS KNOWN TO THE STATE OF

CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NO QUANTITATIVE DATA ISCURRENTLY AVAILABLE.

CERCLA: CONTAINS CHROMIUM COMPOUND. FOR REPORTABLE QUANTITY SEE 40 CFR 302.4CONEG-TYPICAL METALS PRESENT IN PPM:

CADMIUM NECHROMIUM NELEAD NEMERCURY NE

DSL (Canada): ListedECL (Korea): Not listedEINECS: ListedENCS (Japan): ListedFDA STATUS: NLOTHER TYPICAL DATA IN PPM: ANTIMONY NE ARSENIC NE

BARIUM NECOBALT NECOPPER NEMANGANESE NESELENIUM NESILVER NEZINC NE

RCRA: COMPOUND PER SE HAZARDOUS WASTE UNDER RCRA (40 CFR 261.24)EP TOXICITY D007 (CHROMIUM)

SARA 311/312: IMMEDIATE/ACUTE HEALTH HAZARD : YESDELAYED/CHRONIC HEALTH HAZARD : YESFIRE HAZARD : NOSUDDEN RELEASE OF PRESSURE HAZARD: NOREACTIVITY HAZARD : NO

8/12/2019 acid blue 25 (1)


SARA 313: C.I. ACID VIOLET 90 (CHROMIUM COMPLEX DYE), 85%CHROMIUM, 7440-47-3, <3%

TSCA: LISTEDUSDA: NLWHMIS: NC

-------------------------------------------------------------------------------SECTION 16 OTHER INFORMATION

V-003714-02171999-LKB

ACRONYM LIST

NA = NOT APPLICABLE TO THIS MATERIALNC = NOT CERTAIN, UNDETERMINEDND = NO DATA IS CURRENTLY AVAILABLENE = NOT ESTABLISHED, NO TESTING IS PLANNEDNH = NOT HAZARDOUS UNDER CITED REGULATIONSNK = NONE KNOWNNL = NOT LISTED OR APPROVED UNDER THESE REGULATIONSNR = NOT REGULATED OR REPORTABLE

NIOSH = NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH

THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATABELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KINDEXPRESSED OR IMPLIED, IS MADE WITH RESPECT TO THE INFORMATION CONTAINEDHEREIN. THIS MATERIAL SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THEOSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200, AND SUPERSEDES ANYPREVIOUS INFORMATION. PREVIOUSLY DATED SHEETS ARE INVALID & UNAPPLICABLE.

8/12/2019 acid blue 25 (1)


MSDS 02-00021

CHEMTREC (24HOUR) 800-424-9300

------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

------------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMECID WOOL BLUE R

CHEMICAL FAMILY: AZO


DATE PREPARED: SEPTEMBER 2009----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS----------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PELACID BLUE 92 03861-73-2 65-80% NOT ESTABLISHED---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION----------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION.

EFFECTS OF OVEREXPOSURE:EYE CONTACT: MAY BE IRRITATING.SKIN CONTACT: MAY BE IRRITATING.INHALATION: MAY BE IRRITATING.INGESTION: NOT KNOWN.CHRONIC EXPOSURE: NOT KNOWN.

CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN.MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN





8/12/2019 acid blue 25 (1)


MSDS 02-00022



UNUSUAL HAZARDS: DUST AMY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THEPRESENCE OF SOURCE OF IGNITION.---------------------------------------------------------------------------------------------------------------------------------------------------------------- SECTION VI: ACCIDENTAL RELEASE MEASURES----------------------------------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETYEQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEPPOWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS ANDFOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUSAMOUNTS OF WATER. ----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE----------------------------------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOIDPERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONSAND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY.







HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLINGTHIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, ORSMOKING, WASH HANDS AND FACE WITH SOAP AND WATER.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES---------------------------------------------------------------------------------------------------------------------------------------------------------------- APPEARANCE: DARK BLUE POWDER ODOR: NONESOLUBILITY IN WATER: SOLUBLEPH: 3.0-5.5BOILING POINT: NOT APPLICABLE.MELTING POINT: NOT ESTABLISHED.--------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY----------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE.



8/12/2019 acid blue 25 (1)


MSDS 02-00023


HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN ANDSULFUR.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES----------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: NOT ESTABLISHEDRABBIT, SKIN: NOT ESTABLISHEDRABBIT, EYES: MAY BE IRRITATING










8/12/2019 acid blue 25 (1)


MSDS 02-00024

----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH -1




8/12/2019 acid blue 25 (1)


FIRE: REACTIVITY: PERSONAL PROTECTION: HMIS RATINGS:

HEALTH: 1 1 0 F

Within U.S. Call CHEMTEL 1-800-255-3924 Outside U.S. Call Collect: CHEMTEL 1-813-248-0585


Product I.D.: K219 Product Name: ACID BLUE 113 Product Description: Powdered Acid Blue 113 C.I. Name: Acid Blue 113 C.I. Number: 26360 Chemical Family: Azo dyes CAS Number: 3351-05-1 Effective Date: September 14, 2009


Component CAS Number Wt % OSHA - PEL ACGIH - TLV Recommended

PEL

Acid Blue 113 3351-05-1 90 - 100% 15 mg/m3 TWA Totaldust 5 mg/m3

Respirable 10 mg/m3 TWA

Total dust 3 mg/m3Respirable

Not applicable


Emergency Overview: Mild to moderate eye irritant

Depending on product form and the degree and length of unprotected exposure, vapors, mists, splashes, ordusts of product or components can cause one or more of the following health effects: MILD TO MODERATEIRRITATION, discomfort, redness, watering and itching to unprotected eyes. Other effects as follows, bycomponent, ONLY apply when component is listed in Section 2: Acid Yellow 80103651: Over-exposure risksdamage to eyes. Iron Oxide: Long-term exposure can stain eyes causing "rust rings".

Eye Contact:

kin Contact:

8/12/2019 acid blue 25 (1)


MATERIAL SAFETY DATA SHEET (continued) Page 2 of 7

K219 ACID BLUE 113

NOT KNOWN OR EXPECTED to present a significant hazard to skin. However, as a precaution againstunforeseen, unexpected irritation, hypersensitivity or allergic reactions, follow ALL supervisor instructions, andSection 8 instructions for use of Personal Protective Equipment.

The hazards and health effects from UNPROTECTED INHALATION of vapors, mists or aerosols of this productHAVE NOT BEEN DETERMINED. As a precaution against the possibility of effects to existing medicalconditions, unknown irritation, hypersensitivity, allergic reactions, or other unforeseen health effects, be sure tofollow ALL supervisor instructions, AND Section 8 MSDS instructions for use of Personal Protective Equipmentand clothing when working with this product.

nhalation:

NOT EXPECTED to be a hazard with proper handling and good chemical hygiene procedures being followed.Wear appropriate, chemically impervious gloves to avoid accidental transferring and swallowing of chemicalresidue. This chemical may be a greater health hazard if swallowed deliberately, or in a large amount. In suchcases, some effects may parallel those of inhalation or skin absorption.

ngestion:

Unprotected or improperly protected exposures to (breathing) any vapors, mists, aerosols, or dusts of thisproduct or its components MAY AGGRAVATE one or more of the following pre-existing medical conditions:Respiratory (breathing related) problems (asthma, allergies, etc.), skin conditions, or disorders. kidneydisorders, liver disorders. Avoid ALL exposures. Individuals with any of the above-noted conditions, or with anyknown or suspected chemical sensitivities or allergies should avoid working with or being exposed to anychemicals.


NOT KNOWN to cause skin sensitization or allergic reactions. Harmful effects are not expected. kin Sensitization:

The possibility of respiratory sensitization caused by inhalation exposure to product dusts, vapors, mists oraerosols HAS NOT BEEN DETERMINED. As a precaution against unknown effects on existing respiratoryconditions, hypersensitivity, allergic reactions, or other unforeseen health effects, be sure to read, understandand follow all supervisor instructions, AND instructions for wearing Personal Protective Equipment and clothingin Section 8 of this MSDS. Avoid unprotected inhalation of product in any form.

Respiratory Sensitization:

upplemental Hazard Information: No additional information available

Notes to Physician: No notes available

Cancer Information: *** Not known to contain carcinogens ***


Immediately rinse with plenty of water for at least 15 minutes. Get immediate medical attention, as a precaution. Eye Contact:

Immediately remove contaminated clothing. Wash affected area with soap and rinse with plenty of water. Getmedical attention, as a precaution.

Skin Contact:

Move person to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration, and getemergency medical help immediately. Have this Material Safety Data Sheet available.

Inhalation:

8/12/2019 acid blue 25 (1)



K219 ACID BLUE 113

Do not induce vomiting unless directed to do so by emergency medical personnel. Have this Material Safety DataSheet available.

Ingestion:


lash Point: Not applicable




ire Fighting Directions: Wear self-contained breathing equipment and fire-proof clothing. Use water spray to cool fireexposed containers if they cannot be safely moved.



Static Discharges: Take precautionary measures against static discharges when mixing, filling or otherwise dispensing anypowders, combustibles, or flammable liquids. Containers should be properly grounded with metal straps, cablesor other appropriate means to relieve static electricity build-up.

Environmental Protection: Immediately dike liquid spills with inert absorbent material (sand, "Oil Dry" or other commercially available spillabsorbent) to contain and soak up liquid. Prevent material from entering floor drains, sewers, or any bodies ofwater. For powder spills, use sweeping compound, sawdust, or other appropriate material to contain dust. If

possible, recover any uncontaminated materials to re-use.

Protective equipment and clothing: Wear all proper personal protective equipment and clothing to care for spill situation. See section 8 of this MSDS.

Clean up: After containing spill by diking and soaking up with inert absorbent material, place in labeled container to besealed for proper and regulated disposal. Save uncontaminated material for reuse whenever possible. Do notallow any liquid to seep into drains, sewers, lakes, rivers, etc.


Warnings and Precautions:

No special precautions anticipated. Wear all PPE in section 8 as a precaution, and avoidphysical contact with material. Personal Protection:

Wear ALL proper personal protective equipment as outlined in section 8 of this MSDS.

Storage & Temperature Conditions: Keep conditions cool, dry, out of direct sunlight, away from high heat, with at least minimal ventilation. Protectfrom freezing.


Note: Selecting protective equipment & clothing: When choosing personal protective equipment and clothing, consider each worker environment, all chemicalsbeing handled, temperature and all other conditions.

8/12/2019 acid blue 25 (1)



K219 ACID BLUE 113

Eye protection: Always wear indirectly vented, splash-proof chemical safety goggles under a clear face-shield. Face shield is notto be used without these goggles.

Skin Protection: Always wear most impervious gloves such as nitrile or other proper chemical-resistant gloves for the job, alongwith proper coveralls, rubber or plastic apron, etc. Wash hands before eating, drinking or using restroom. Showerafter each shift. Clean contaminated protective equipment and clothing before reusing.

Respiratory Protection: Depending on materials handled, ALWAYS wear an appropriate NIOSH approved organic vapor/mist respirator,or dust respirator, with all proper filters as required whenever exposure to vapors or dusts is expected. After eachshift or when equipment becomes contaminated, clean respirator in compliance with 29 CFR 1910.134.

Eye Washes and Other Protection: Eye wash stations and drench showers should be located within 100 feet or 10-second walk of the work area per

ANSI standard Z358.1-1990. Ventilation:

Local exhaust should be used to maintain exposure limits below specified amounts recommended by OSHA,NIOSH, or ACGIH and to draw spray, aerosol, vapors, or dusts away from workers and prevent routine

inhalation. At least 10 air changes per hour are recommended for good room ventilation.

Not referenced in literature Airborne Exposure Limits:


pH: 7.5 - 9.0 @ 1 g/l H20 % Water Content: 0 % Total NonVolatiles: 100% % Total Solids: 100% % Total VOC: 0

Boiling Point:

Not applicable

Color: Blue Bulk Density (Solid): Not established Form: Powder Odor: None Specific Gravity (Liquid): Not applicable Vapor Pressure: 0 Water Solubility: 100 g/l @ 30 ºC (86 ºF) Solvent Solubility: Not applicable


The quantity of VOC's reported here is calculated based on the U.S. EPA definition. State or local definitions maydiffer. To request additional Regulatory Compliance Data, call 312-666-2015.


Product is stable under normal, ambient (controlled) conditions concerning heat, moisture, pressure, ventilationand exposure to incompatible or reactive materials.

Stability:

8/12/2019 acid blue 25 (1)



K219 ACID BLUE 113


Conditions to Avoid: Moisture in storage, high dust condition & static charges, incompatibles.

Incompatible Materials: Strong oxidizing agents, strong acids, strong bases

Hazardous Decomposition Products: In fire: Oxides of carbon, nitrogen &

sulfur

Oral LD50 (Rat): > 5000 mg/kg Eye Effects (Rabbit): Irritant Skin Effects (Rabbit): Non-irritant Mutagenicity: No data currently available Inhalation LC50 (Rat): No data currently available Skin Sensitization (Guinea Pig): No data currently available Respiratory Sensitization: No data currently available Additional Toxicity Data: No data currently available



No data currently available BOD: No data currently available COD: No data currently available Aquatic Toxicity: No data currently available Biodegradability: No data currently available Persistence: No data currently available Ecotoxicity: No additional data is available Other Data:

SECTION 13: DISPOSAL AND ENVIRONMENTAL CONSIDERATION



Incinerate, treat, or bury (landfill), after sampling and testing, at facility approved by applicable federal, state,and local authorities.

Disposal Methods:

Empty containers may contain residue and/or vapors and should not be reused unless professionally cleanedand reconditioned. Crush if not cleaned, to prevent reuse.

Empty Containers:


8/12/2019 acid blue 25 (1)



K219 ACID BLUE 113


DOT Regulations (Ground):

NOT REGULATED IATA Regulations (Air):

NOT REGULATED


Component CAS Number Regulatory List Weight % Acid Blue 113 3351-05-1 No references 90 -100%

1- CONEG 2-RCRA Hazardous Waste3-SARA 304/CERCLA Hazardous Substance 4-SARA 311/312 Hazard Categories:

Immediate/Acute Health Hazard: Delayed/Chronic Health Hazard: Fire Hazard: Sudden Release of Pressure Hazard: Reactivity Hazard:

5-SARA 313 Toxic Release Chemical 6-Clean Water Act 7-Clean Air Act 8-SOCMI Chemical 9-Ozone Depleting Chemical 10-PSM Highly Hazardous Chemical 11-FDA Status 12-WHMIS (Canada) 13-USDA Status 14-NIOSH Recommendations

15-Other Regulatory Information 16-Marine Pollutants17-State Lists CA-California Proposition 65 DE-Delaware Air Quality Management List FL-Florida Toxic Substances List MA-Massachusetts Hazardous Substance List MI-Michigan Critical Materials Register MN-Minnesota Hazardous Substances List NJ-RTK-New Jersey RTK Hazardous Substance List NJ-TCPA-New Jersey TCPA Extremely Hazardous Substance List NY-New York List of Hazardous Substances PA-Pennsylvania Hazardous Substance List WA-Washington Permissible Exposure Limits for Air Contaminates

Regulatory List Reference:


Immediate / Acute Health Hazard: Yes Chronic / Delayed Hazard: No Fire Hazard: No Sudden Release of Pressure Hazard: No Reactivity Hazard: No

NATIONAL CHEMICAL INVENTORIES:

Not yet determined AICS (Australia):

8/12/2019 acid blue 25 (1)



K219 ACID BLUE 113

Not yet determined ASIA-PAC (Asia-Pacific): Not yet determined DSL (Canada): Not yet determined ECL (Korea): Not yet determined EINECS (Europe): Not yet determined ENCS (Japan): Not yet determined IECSC (China): Not yet determined PICCS (Phillipines): Components Listed TSCA (US):

OTHER:

For additional International, Federal or State regulatory compliance information not shown: Call 312-666-2015. Supplemental Regulatory Information:


Reason for Revision: None at this time

The information and recommendations contained herein are based upon data believed to be correct. However,no guarantee or warranty of any kind, expressed or implied, is made with respect to the information containedherein. This Material Safety Data Sheet was prepared to comply with the OSHA Hazard CommunicationStandard 29 CFR 1910.1200, and supersedes any previous information. Previously dated sheets are invalidand inapplicable.

END OF MSDS

Disclaimer:

8/12/2019 acid blue 25 (1)


MSDS 02-00021


------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMENYL BRILLIANT RED B

CHEMICAL FAMILY: MONOAZO


DATE PREPARED: FEBRUARY 2010----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS----------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PELACID RED 131 70210-37-6 NOT ESTABLISHED---------------------------------------------------------------------------------------------------------------------------------------------------------------


EFFECTS OF OVEREXPOSURE:EYE CONTACT: IRRITATING.SKIN CONTACT: MAY BE IRRITATING.INHALATION: MAY BE IRRITATING.INGESTION: NOT KNOWN.CHRONIC EXPOSURE: NOT KNOWN.CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN.MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN






8/12/2019 acid blue 25 (1)


8/12/2019 acid blue 25 (1)


MSDS 02-00023

HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN ANDSULFUR.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES----------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: NOT ESTABLISHEDRABBIT, SKIN: NOT ESTABLISHEDRABBIT, EYES: NOT ESTABLISHED, PROBABLY IRRITATING.









STATE RIGHT TO KNOW INFORMATIONINGREDIENT CAS NUMBERACID RED 131 70210-37-6

8/12/2019 acid blue 25 (1)


MSDS 02-00024




DISCLAIMER: KEYCOLOUR INC. BELIEVES ALL THE INFORMATION AND DATA GIVEN IS ACCURATE AS OF THEDATE OF PREPARATION AND IS OFFERED IN GOOD FAITH. THIS INFORMATION IS GIVEN WITHOUT WARRANTYOR REPRESENTATION SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. SINCECONDITIONS OF USE ARE BEYOND OUR CONTROL, KEYCOLOUR INC. EXPRESSLY DISCLAIMS ALL LIABILITY FORTHE USE OR HANDLING OF THIS PRODUCT.

8/12/2019 acid blue 25 (1)


MSDS 02-00021


----------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ----------------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMENYL YELLOW BGT

CHEMICAL FAMILY: AZO DYE


DATE PREPARED: NOVEMBER 2009----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS----------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PEL

ACID YELLOW 135 12235-21-1 NOT ESTABLISHEDDEXTRIN 9004-53-9 3%+SODIUM CHLORIDE 7647-14-5 3%+---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION----------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION.






8/12/2019 acid blue 25 (1)


MSDS 02-00022










HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLINGTHIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, ORSMOKING, WASH HANDS AND FACE WITH SOAP AND WATER.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES---------------------------------------------------------------------------------------------------------------------------------------------------------------- APPEARANCE: YELLOW POWDER ODOR: NONESOLUBILITY IN WATER: SOLUBLEBOILING POINT: NOT APPLICABLE.MELTING POINT: NOT ESTABLISHED.EVAPORATION RATE: IS SLOWER THAN BUTYL ACETATESPECIFIC GRAVITY: 0.51pH @5.0%: 7 - 8--------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY----------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE.


8/12/2019 acid blue 25 (1)


MSDS 02-00023



HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN ANDSULFUR.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES----------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: 3000 MG/KGLC50: 200 PPM RABBIT, SKIN: IRRITATINGRABBIT, EYES: IRRITATING



CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERALREGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED.DOT TECHNICAL NAME: NOT APPLICABLE.DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE.DOT UN/NA NUMBER: NOT APPLICABLE.

PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE.DOT REPORTABLE QUANTITY: NOT APPLICABLE.DOT LABELS: NOT APPLICABLE.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDERSECTION 302 AS EXTREMELY HAZARDOUS.





8/12/2019 acid blue 25 (1)


MSDS 02-00024

STATE RIGHT TO KNOW INFORMATIONINGREDIENT CAS NUMBERACID YELLOW 135 12235-21-1DEXTRIN 9004-53-9SODIUM CHLORIDE 7647-14-5

SECTION XVI: OTHER INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 2



DISCLAIMER: KEYCOLOUR INC. BELIEVES ALL THE INFORMATION AND DATA GIVEN IS ACCURATE AS OF THEDATE OF PREPARATION AND IS OFFERED IN GOOD FAITH. THIS INFORMATION IS GIVEN WITHOUT WARRANTYOR REPRESENTATION SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. SINCECONDITIONS OF USE ARE BEYOND OUR CONTROL, KEYCOLOUR INC. EXPRESSLY DISCLAIMS ALL LIABILITYFOR THE USE OR HANDLING OF THIS PRODUCT.-------------------------------------------------------------------------------------------------------------------------------------------

8/12/2019 acid blue 25 (1)


FIRE: REACTIVITY: PERSONAL PROTECTION:



HMIS RATINGS: HEALTH: 1 1 0 F *


Product I.D.: K502 Product Name: ACID orange 144 218% Product Description: Acid Orange Colorant Powder Chemical Family: Metallized azo dye Effective Date: July 15, 2009


mergency Overview: Depending on duration and individual sensitivity, unprotected contact may cause mild eye, respiratory, skin irritation. Maycause allergic skin reactions in some sensitive individuals. May cause allergic respiratory reaction or sensitization in someindividuals.

Eye Contact: Depending on duration and personal sensitivity, unprotected contact may cause mild irritation, discomfort, redness, watering,itching or other effects. Heavy contact or for prolonged period may increase effects. Follow ALL supervisor and PersonalProtection instructions in Section 8 of this SDS.

kin Contact: Depending on amount and length of direct, unprotected contact, vapors, mists, splashes, aerosols, or dusts of product maycause varying dgrees of irritation, possible ALLERGIC REACTIONS in some individuals, redness, rash, itching, burning feeling,drying, cracking, pain, swelling, or other effects in some sensitive individuals. Prolonged or repeated contact may causeinflammation, or other effects in some persons.

nhalation: Depending on duration of unprotected inhalation of product, vapors, mists, aerosols or dusts may cause mild irritation of thenose, throat, lungs and mucous membranes, shortness of breath, sneezing, cough, runny nose, nausea, headache and othereffects. Prolonged or heavy exposure, or heating of liquid material may increase severity of symptoms.

ngestion: Depending on amount swallowed, product can cause mild irritation of mouth, throat, esophagus, stomach, and gastrointestinaltract, upset stomach, abdominal discomfort, nausea, vomiting, gastrointestinal disturbances, dizziness, diarrhea, and othereffects. Aspiration into lungs during vomiting is an emergency and may cause lung injury and life-threatening conditions. Higherdose may increase irritation and severity of symptoms.


8/12/2019 acid blue 25 (1)


8/12/2019 acid blue 25 (1)



K502 ACID orange 144 218%

Improper protection allowing contact with vapors, mists, aerosols, splashes or dusts of product by inhalation, eye contact, skincontact or swallowing may aggravate one or more of the following pre-existing medical conditions: Respiratory problems(asthma, allergies, etc.), skin conditions, eye conditions. Ingestion may have potential to aggravate kidney or liver disorders.Heavy or long-term contact may increase effects. Avoid ALL exposures. Individuals with any of the above-noted conditionsshould avoid working with chemicals.

kin Sensitization:

Not known to cause skin sensitization. With careful handling and when good chemical hygiene procedures are followed,harmful effects are not expected. As a precaution against unforeseen or unexpected sensitivity or possible allergic reactions,follow ALL Personal Protection instructions in Section 8 of this SDS.

Respiratory Sensitization: Improper protection from inhalation of product dust, mist, vapor, etc. MAY CAUSE RESPIRATORY SENSITIZATION OR

ALLERGIC REACTIONS in some individuals. Persons known to have or suspected of having chemical sensitivity or allergicreactions should avoid contact. Symptoms may include: Itching watery eyes, swelling of eyelids. sneezing, itchy, runny nose.,cough, shortness of breath, asthma-like symptoms such as tight chest, difficult breathing. It may take repeated or prolongedexposure for symptoms to appear. Reactions may be unpredictable and life-threatening for some individuals. IF SYMPTOMS

APPEAR, IMMEDIATELY remove person from contact area, GET MEDICAL HELP and follow Section 4 instructions.


Unusual Health Hazards: None for this material

upplemental Hazard Information No additional information is currently available

Notes to Physician Treat Symptomatically based on Section 2 Hazard Warnings and Section 3 ingredients unless indicated otherwise

Cancer Information:

Chemical Name CAS # WT % IARC NTP OSHA NIOSH ACGIH Cr+3 (Complexed within dyemolecule) 7440-47-3 Group 3

Unclassifiableon human

carcinogenicity

NONE NONE NONE NONE 1.20%


Component Wt % OSHA - PEL ACGIH - TLV Recommended

PEL CAS Number

Cr+3 (Complexed within dye molecule) 7440-47-3 0.5 mg/m3 TWA 0.5 mg/m3 TWA Not applicable 1.20%

Confidential Acid Orange dye

Undisclosed

Not established

Not established

Not applicable

98.80%

2.00

Unprotected contact with ingredients listed in Section 3 may be hazardous based on OSHA 29 CFR 1910.1200 & related appendices. Components not listed are tradesecrets, non-hazardous, or not reportable. This SDS is not intended to offer full disclosure, but all component information is available to medical or emergencypersonnel. All hazards are based on contact exposure. Effects may be unpredictable and may vary from person to person due to individual reactions. Reducing oreliminating contact can reduce or eliminate risk. Use protective equipment and clothing in Section 8 to minimize or eliminate contact. Users are responsible for hazarddetermination and communication. Unless indicated otherwise, non-carcinogenic components are indicated within a 1-10% range, and investigated or potentialcarcinogens within a 0.1-1% range. HMIS ratings are based on data interpretation, and vary from company to company. They are intended only for quick, generaldentification of the degree of potential hazards. Hazards range from 0 (Minimal) up to 4 (Severe). Consult the National Paint & Coatings Association HMIS Manual for

detailed information on ratings. To handle material safely, consider all information in this SDS.

mportant Notice:

8/12/2019 acid blue 25 (1)





Immediately rinse with flowing water for at least 15 minutes while holding eyelids open. Get immediate medical attention, as aprecaution.

Eye Contact:

Immediately remove contaminated clothing. Wash affected area with soap and rinse with plenty of water. Get medicalattention, as a precaution.

Skin Contact:

Immediately move person to fresh air. If breathing is difficult give oxygen, call 911, calm the individual. If not breathing, call911, give artificial respiration (CPR) until medical help arrives. Have this Material Safety Data Sheet available.

Inhalation:

Do not induce vomiting unless directed to do so by a doctor or by other emergency medical personnel. Forced vomiting ofcertain chemicals may cause aspiration and lung damage. Have this Material Safety Data Sheet available.

Ingestion:





ire Fighting Directions: Wear self-contained breathing equipment and fire-proof clothing. Use water spray to cool fire exposed containers if theycannot be safely moved.



Static Discharges: IMPORTANT - GUARD AGAINST FIRE AND EXPLOSION: Take precautionary measures against static discharges whencleaning up leaks or spills of powders, combustibles, or flammable liquids. Containers should be properly grounded withmetal straps, cables or other appropriate means to relieve static electricity build-up or generation. IMPORTANT: When using,mixing, filling, or otherwise dispensing any types of solvents, do not allow buildup of flammable or combustible vapors orvapor-air mixtures in confined spaces, storage tanks, or any other areas or enclosures. Totes, drums and all other containersshould be completely sealed when not in use. Vapors can travel a distance to ignition sources and cause fire or explosion.Take every precaution and monitor all safety factors and systems, including maintaining more-than-adequate air-exchangeventilation.

Environmental Protection: Immediately dike liquid spills with inert absorbent material (sand, "Oil Dry" or other commercially available spill absorbent) tocontain and soak up liquid. Prevent material from entering floor drains, sewers, or any bodies of water. For powder spills, usesweeping compound, sawdust, or other appropriate material to contain dust. If possible, recover any uncontaminatedmaterials to re-use.


Clean up:

8/12/2019 acid blue 25 (1)




After containing liquid spill by diking and soaking up with inert absorbent material, place in labeled container to be sealed forproper and regulated disposal. Only the slightest residue should remain. Try to save uncontaminated material for reusewhenever possible. For powders, use sweeping compound to minimize dust and pick up as much product as possible. Donot allow liquids to seep into drains, sewers, lakes, rivers, etc. Check Sections 1 and 2 for dye description or type. Solventdye residue may be cleaned by scrubbing with detergent, depending on type. Do not add water to water-soluble dyes. Dye isconcentrated. This will increase amount of color to remove. All cleaning or scrubbing liquids used should be absorbed andplaced in labeled containers for correct disposal. Absorbent material containing solvents may release combustible or

flammable vapors and should be handled accordingly, properly labeled and disposed. Check Sections 2, 5, 13 & 15 forapplicable instructions and regulations.


Warnings and Precautions: No special precautions anticipated. Wear all PPE in section 8 as a precaution, and avoid physical contact with material.

Personal Protection: Wear ALL proper personal protective equipment as outlined in section 8 of this SDS.

Handling, Storage & Temperature Conditions: Keep containers tightly sealed in cool & dry area, out of direct sunlight. IMPORTANT: FOR PRODUCTS LISTINGFLAMMABLE/COMBUSTIBLE SOLVENTS or LOW FLASH POINTS - GUARD AGAINST FIRE AND EXPLOSION: Storeaway from fire hazards and ignition sources, high heat, open flames, welding, hot plates, steam pipes, radiators, etc. Maintaingood ventilation. Guard against static discharges. Ground all containers before mixing or filling. Use non-sparking tools toopen, close or otherwise work with containers. Limit indoor storage to approved areas with automatic sprinklers. Vaporsexpected to be released when material is heated during process operations.

STATIC CHARGES: Take precautionary measures against static discharges when mixing, cleaning, filling or otherwisedispensing combustible or flammable liquids. Containers should be properly grounded with metal straps, cables or otherappropriate means to relieve static electricity build-up or generation.

VAPORS: IMPORTANT: DO NOT ALLOW buildup of flammable or combustible vapors or vapor-air mixtures in confinedspaces, storage tanks, or any other areas or enclosures. Totes, drums and all other containers should be completely sealedwhen not in use. Vapors can travel a distance to ignition sources and cause fire or explosion. Take every precaution andmonitor all safety factors and systems, including maintaining more-than-adequate air-exchange ventilation.

POWDERS: General precautions: Although unlikely in most instances, GUARD AGAINST DUST EXPLOSION HAZARD.Eliminate or keep dust to a minimum. Under the right conditions, high dust concentrations of certain particle sizes mixed withair in a critical ratio in the presence of an ignition source can theoretically cause a dust explosion. Be sure to PROPERLYground containers when filling, mixing or otherwise dispensing powders. KEEP WORK AREA CLEAN AND DUST-FREE.Follow all Section 8 recommendations for Exposure Controls and Personal Protection.

WATER-BASED PRODUCTS: DO NOT ALLOW TO FREEZE.


Note: Selecting protective equipment & clothing:

When choosing personal protective equipment and clothing, consider each worker's environment, all chemicals beinghandled, temperature, ventilation, and all other conditions. Determination of the level of protection needed for the eyes, skinand respiratory system under working conditions is the responsibility of the product end-user or shift supervisor. SDSSections 2, 3, 8 and 11 should be consulted.

Eye protection: As a precaution, wear indirectly vented, splash-proof chemical safety goggles. When handling liquids, wear splash-proofgoggles under a clear face-shield. Face shield is not to be used without these goggles. The type or extent of protectionneeded should be determined by the product end-user or shift supervisor.

Skin Protection:

8/12/2019 acid blue 25 (1)




Always wear impervious, chemical-resistant synthetic or rubber gloves. Check with manufacturer for best glove for thematerial being handled. Wear good quality long sleeved work shirt, coveralls, and a rubber or plastic apron. Wash handsafter handling and before eating, drinking or using restroom. Shower after each shift. Clean contaminated but reusableprotective equipment and clothing before reusing and wearing again. Discard contaminated disposable gloves and clothing.The type or extent of protection needed should be determined by the product end-user or shift supervisor.

Respiratory Protection: Depending on type of material handled and processing conditions, it is recommended that an appropriate NIOSH approvedorganic vapor/mist respirator, or dust respirator (with proper filters as required) be worn when exposure to product isexpected. After each shift or when equipment becomes contaminated, clean respirator and replace filters in compliance with29 CFR 1910.134. The type or extent of protection needed should be determined by the product end-user or shift supervisor.

Eye Washes and Other Protection: Eye wash stations and drench showers should be located within 100 feet or 10-second walk of the work area per ANSIstandard Z358.1-1990.

Ventilation: Local exhaust or other appropriate ventilation should be used to maintain exposure limits below specified amountsrecommended by OSHA, NIOSH, or ACGIH and to draw spray, aerosol, vapors, or dusts away from workers and preventroutine inhalation. At least 10 air changes per hour are recommended for good room ventilation. IMPORTANT - GUARD

AGAINST FIRE AND EXPLOSION: When using, mixing, filling, or otherwise dispensing any types of solvents, do not allowbuildup of flammable or combustible vapors or vapor-air mixtures in confined spaces, storage tanks, or any other areas orenclosures. Totes, drums and all other containers should be completely sealed when not in use. Vapors can travel a distanceto ignition sources and cause fire or explosion. Take every precaution and monitor all safety factors and systems, includingmaintaining more-than-adequate air-exchange ventilation.

Airborne Exposure Limits:

OTHER OEL'S NIOSH - IDLH NIOSH - REL WT % CAS # Chemical Name Not established Not established 0.5 mg/m3 TWA 7440-47-3 Cr+3 (Complexed within dye

molecule) 1.20%


Flash Point: Not established pH: ~ 5.0 % Total VOC: 0 % Total Solids / Non-Volatiles: 100 Color: Brown Density: Not established Form: Powder Odor: None Freezing/Melting Point: Not established Specific Gravity: Not established Water Solubility: Soluble. Test in specific applications and systems. Solvent Solubility: Not applicable

Other Properties: No further data Other Components: Not established Decomposition Temperature: Not Established



8/12/2019 acid blue 25 (1)




Product is expected to be stable under normal, ambient (controlled) conditions concerning heat, moisture, pressure, fire andignition hazards, and ventilation. Contact with incompatible or reactive materials may cause hazardous reactions in someproducts if indicated. Check information below.

Stability:


Conditions to Avoid: None Known Incompatible Materials:

None Known Hazardous Decomposition Products:

In fire: Oxides of carbon, nitrogen, sulfurPossible Hazard Reactions:

None known SECTION 11: TOXICOLOGICAL INFORMATION


Data

May beirritating May be

irritating No Data No Data (Rat): > 2000mg/kg No Data No Data No Data May be

respiratoryirritant

Confidential AcidOrange dye



Data

*** No Data ***




Incinerate, treat, or bury (landfill), after sampling and testing, at facility approved by applicable federal, state, and localauthorities.

Disposal Methods:

Empty containers may contain residue and/or vapors and should not be reused unless professionally cleaned andreconditioned. Crush if not cleaned, to prevent reuse.

Empty Containers:



8/12/2019 acid blue 25 (1)




DOT Regulations (Ground): NOT REGULATED

IATA Regulations (Air): NOT REGULATED

IMDG / IMO Regulations (Water): NOT REGULATED


Component Regulatory List Weight % CAS Number Cr+3 (Complexed within dye molecule) 7440-47-3 2: 5000, 8, 11: D007, 13: 0.1%, 15: DE MA MN NJ 1.20%

Confidential Acid Orange dye Undisclosed Chromium III compound (Actual Cr+3 @ <1.2%).: SARA 313: 0.1%,CERCLA Hazardous substance: RQ=5000 lbs, RCRA: D007, Statelists: DE, ID, IL, MA, MI, MN, NY,

98.80%

NOTE: When no components are shown in space above this note, no federal or state reporting requirements apply to thisproduct. When components are listed above, list numbers shown below indicate applicable regulations.*

List numbers

1-Accidental Release Substance 2-CERCLA 304 Hazardous Substance (RQ)3-Reserved4-Clean Air Act-Sec. 111 Volatile Organic Compounds (VOC) 5-Clean Air Act-Sec. 112 Haz. Air Pollutant (HAP, HAP Code) 6-Clean Air Act-Ozone Depleting Chemical (ODC) 7-Clean Water Act-RQ 8-Clean Water Act-Priority Pollutant (PP) RQ 9-Marine Pollutant (MP) 10-PSM Highly Hazardous Chemical 11-RCRA Hazardous Waste (RCRA Code) 12-SARA 302 Extremely Hazardous Substance (EHS) (RQ) 13-SARA 313 Toxic Release Inventory (TRI) (TR Conc., TR Threshold) 14-SOCMI Chemical (CAA) 15-State Lists

CA-California Proposition 65, DE-Delaware, ID-Idaho, ME-Maine, MA-Massachusetts, MI-Michigan, MN-Minnesota, NJ-RTK New Jersey Hazardous Substance List, NJ-TCPA New Jersey Extremely Hazardous Substance List, NY-New York, PA-Pennsylvania, WA-Washington, WV-West Virginia, WI-Wisconsin

16-Supplemental regulatory information (SRI)

* Numbers shown immediately after a List Number indicate additional specific information. Examples: 2: 5000 (2 = CERCLA,5000 = RQ), 11: D007 (11 = RCRA, D007 = Chromium)

Revised 011808 wln (Current list not applicable to previous Safety Data Sheets)


8/12/2019 acid blue 25 (1)


8/12/2019 acid blue 25 (1)





Immediate/Acute Health Hazard: YES Chronic/Delayed Hazard: YES Fire Hazard: NO Sudden Release of Pressure Hazard: NO

Reactivity Hazard: NO

GLOBAL CHEMICAL REGISTRATION LISTINGS

Status not determined AICS (Australia): Status not determined ASIA-PAC (Asia Pacific): Status not determined DSL (Canada): Status not determined ECL (Korea): Status not determined EINECS (Europe): Status not determined ENCS (Japan): Status not determined IECSC (China): Status not determined PICCS (Phillippines):

Components listed TSCA (US):

OTHER: No additional information applies, or no supplemental information is available at this time.


Reason for Revision: New format. General review and update. Reviewed: 071509 wln

The information and recommendations contained herein are based upon data believed to be correct. However, no guaranteeor warranty of any kind, expressed or implied, is made with respect to the information contained herein. This Material SafetyData Sheet was prepared to comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200, and supersedesany previous information. Previously dated sheets are invalid and inapplicable.

END OF MSDS

Disclaimer:

8/12/2019 acid blue 25 (1)





TRADE NAME--------- ACID BLACK 194

CHEMICAL NAME------ N/ACHEMICAL FAMILY---- ACID DYECOLOR INDEX #------ ACID BLACK 194C. A. S. #--------- 57693-14-8

AST REVISION DATE. 10/29/09


Azo Chromium Complex Dyestuff Content: >= 95 - <= 98 %

Remarks

Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticnvironment.

II. PHYSICAL DATA


VAPOR PRESSURE--N/A ODOR--- NONEVAPOR DENSITY---N/A APPEARANCE--DARK POWDERVOLATILITY----- N/A SPECIFIC GRAV-- N/A



LASH POINT N/A


N CASE OF FIRE-----DRY CHEMICAL, CO2, WATER SPRAY OR REGULAR FOAM. MOVE CONTAINERS FROM FIREAREA IF YOU CAN DO IT WITHOUT RISK. APPLY COOLING WATER TO SIDES OF CONTAINERS THAT ARE EXPOSEDTO FLAMES UNTIL WELL AFTER FIRE IS OUT.

8/12/2019 acid blue 25 (1)







V. REACTIVITY DATA

TABILITY------- Stable.CONDITIONS TO AVOID----- NONE KNOWN.




CONDITIONS TO AVOID---NONE KNOWN.


THRESHOLD LIMIT VALUE-----NOT ESTABLISHED.


HAZARD WARNINGS-----D. 0. T. NON-REGULATED SUBSTANCE.THIS PRODUCT IN ITS PRESENT STATE

OSES NO THREAT TO HUMAN HEALTH OR THE ENVIRONMENT.


8/12/2019 acid blue 25 (1)







RESPIRATORY. NIOSH APPROVED DUST RESPIRATOR WHEN NEEDED.




OTHER PROTECTION--- DELUGE SAFETY SHOWER AND EYE WASH STATION SHOULD BE LOCATEI NEAR WORK AREA.

X. Ecological information

Biodegradability : > 70 % (Colour decrease)Readily eliminable from waterMethod : Batch methodAnalysis method:, PhotometryBiodegradability :f regulations are followed when introducing effluent intoiological waste water treatment plants, no adverse effect onhe degradation activity of activated sludge is to be expected.ish toxicity : LC50 1 - 10 mg/l (96 h, Brachydanio rerio)

Method : Range Finding TestBacteria toxicity : EC50 > 1,000 mg/l (0.5 h, Pseudomonas putida)Method : OECD 209Chemical oxygen demand (COD) : 960 mg/gRemarks: Test results of a similarly composed product

roduct does not add to the AOX-value of the sewage. (DIN EN 1485)This product contains approx. 3,0 % complex bonded chromium.The product does not release nitrogen which can contribute to eutrophication.The product does not contain phosphates or organophosphorus compounds.


8/12/2019 acid blue 25 (1)




TEPS TO BE TAKEN:::: DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL: STOP LEAK IF YOU CAN DO IT WITHOURRISK. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIALS AND PLACE INTO CONTAINERS FOR LATERDISPOSAL. SCRUB SPILL AREA WITH DETERGENT, FLUSH WITH COPIOUS AMOUNT OF WATER.


ONTAINER REUSE METHOD----CONTAINERS SHOULD NOT BE REUSED WITHOUT PROFESSIONAL CLEANING ANDRECONDITIONING.

XI. PRECAUTION MEASURES


XII. TRANSPORTATION INFORMATIOND.O.T. Information

CFR UNNR: 3077 Environmentally hazardous substance, solid, n.o.s.Class: 9 PG:III

Tech. name: AZO CHROMIUM COMPLEX DYESTUFFMDG UNNR: 3077 Environmentally hazardous substance, solid, n.o.s.

Class: 9 PG:IIIEmS:F-A , S-F

ATA_C UNNR: 3077 Environmentally hazardous substance, solid, n.o.s.Class: 9 PG:III

ATA_P UNNR: 3077 Environmentally hazardous substance, solid, n.o.s.Class: 9 PG:III

XIII. REGULATORY INFORMATION

. A. R. A.--- REPORTABLEara 313

This product contains the following component that is subject to the reporting requirementsnder 40 CFR 372.ontains:

Chromium compound Content: 98 %Chromium Content: 3 % CAS number : 7440-47-3

ara 312mmediate (acute) health hazard No

Delayed (chronic) health hazard Noire hazard Noudden Release of Pressure No

Reactivity NoOther regulations

abelling in accordance with the EEC directives:Hazard symbols: N Dangerous for the environmentR51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticnvironment.61 : Avoid release to the environment. Refer to special instructions/Safety data sheets.

8/12/2019 acid blue 25 (1)








XIV. STATES RIGHT TO KNOW LAWS





XV. OTHER INFORMATION

ALL INFORMATION AND DATA APPEARING ON THIS M. S. D. S. ARE BELIEVED TO BE RELIABLE & ACCURATE.HOWEVER, IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SAFETY,TOXICITY, AND SUITABILITY FOR HIS OWN USE OF THE PRODUCT DESCRIBED. SINCE THE ACTUAL USE BYOTHERS IS BEYOND OUR CONTROL, NO GUARANTEE, EXPRESSED OR IMPLIED, IS MADE BY KEYCOLOUR,NCORPORATED. USER ASSUMES ALL RISK AND RESPONSIBILITY.

8/12/2019 acid blue 25 (1)


MSDS 02-00021


------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMENYL YELLOW A4R 280%

CHEMICAL FAMILY: AZO


DATE PREPARED: FEBRUARY 2010----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS----------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PELACID YELLOW 199 70865-20-2 NOT ESTABLISHEDGLAUBER’S SALT 7647-14-5

---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION----------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION.





INGESTION: DILUTE WITH WATER. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE VOMITING IFPATIENT IS UNCONSCIOUS OR HAS CONVULSIONS.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION V: FIRE FIGHTING MEASURES----------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED.LOWER EXPLOSIVE LIMIT: NOT APPLICABLE.UPPER EXPLOSIVE LIMIT: NOT APPLICABLEAUTOIGNITION TEMPERATURE: NOT DETERMINED.


8/12/2019 acid blue 25 (1)


MSDS 02-00022









SKIN CONTACT.

HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLINGTHIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, ORSMOKING, WASH HANDS AND FACE WITH SOAP AND WATER.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES---------------------------------------------------------------------------------------------------------------------------------------------------------------- APPEARANCE: DARK POWDER ODOR: NONESOLUBILITY IN WATER: SOLUBLEBOILING POINT: NOT APPLICABLE.MELTING POINT: NOT ESTABLISHED.--------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY----------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE.

CONDITIONS TO AVOID: STRONG OXIDIZING AGENTS.



8/12/2019 acid blue 25 (1)


MSDS 02-00023



NO SIGNIFICATN HARMFUL ENVIRONMENTAL EFFECTS ARE SHOWN.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS---------------------------------------------------------------------------------------------------------------------------------------------------------------- WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA(40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE GOVERNMENTAL REGULATIONS.







STATE RIGHT TO KNOW INFORMATIONINGREDIENT CAS NUMBER STATESACID YELLOW 199 70865-20-2 MA, NJ, PA, CAGLAUBER’S SALT 7647-14-5 MA, NJ, PA, CA

8/12/2019 acid blue 25 (1)


MSDS 02-00024




PERSONAL PROTECTION - N


8/12/2019 acid blue 25 (1)


MSDS 02-00021


----------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ----------------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMECID FLUORESCENT YELLOW AF

CHEMICAL FAMILY: COUMARIN

EMERGENCY PHONE NUMBER: 973-471-3200

DATE PREPARED: OCTOBER 28, 2005----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS----------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PEL

ACID YELLOW 250 NOT ESTABLISHED---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION----------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION.







8/12/2019 acid blue 25 (1)


MSDS 02-00022









HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLINGTHIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, ORSMOKING, WASH HANDS AND FACE WITH SOAP AND WATER.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES---------------------------------------------------------------------------------------------------------------------------------------------------------------- APPEARANCE: YELLOW POWDER ODOR: NO ODORSOLUBILITY IN WATER: SOLUBLEBOILING POINT: NOT APPLICABLE.MELTING POINT: NOT ESTABLISHED.--------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY----------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE.




8/12/2019 acid blue 25 (1)


MSDS 02-00023

HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN ANDSULFUR.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES----------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: >5000 MG/KGRABBIT, SKIN: NOT ESTABLISHEDRABBIT, EYES: IRRITATING









STATE RIGHT TO KNOW INFORMATIONINGREDIENT CAS NUMBERPROPRIETARY

8/12/2019 acid blue 25 (1)


8/12/2019 acid blue 25 (1)


800-255-3924

________________________________________________________________________________ ____


________________________________________________________________________________ ____

N O T E: DO NOT DETACH THIS GUIDANCE COVER SHEET FROM THE REST OFTHIS DOCUMENT.



________________________________________________________________________________ ____








________________________________________________________________________________ ____




________________________________________________________________________________ ____




TRADE NAME: ACID BLUE 260 CRUDE

PRODUCT ID: K260

PREPARED FOR:


8/12/2019 acid blue 25 (1)




This MSDS is designed to effectively communicate Health and Physical Hazardsto the

material handler and all other responsible persons concerned withHealth andEnvironmental protection and regulatory compliance. Distributors receiving


agents.

________________________________________________________________________________ ____







________________________________________________________________________________ ____


-------------------------------------------------------------------------------PREPARATION DATE PRODUCT ID

09-25-09 K260

-------------------------------------------------------------------------------SECTION 1 CHEMICAL IDENTIFICATION

C.I. NAME : PROPRIETARYCAS NUMBER : PROPRIETARYCHEMICAL FAMILY : ANTHRAQUINONE DYEPHYSICAL FORM : POWDER

-------------------------------------------------------------------------------SECTION 2 HAZARDOUS INGREDIENTS

NK

-------------------------------------------------------------------------------SECTION 3 HAZARD IDENTIFICATION AND EMERGENCY OVERVIEW

HMIS RATINGS

8/12/2019 acid blue 25 (1)


HEALTH 0FLAMMABILITY 1REACTIVITY 0PROTECTION F, N

EMERGENCY OVERVIEW:POSSIBLE EXPOSURES: EYES, SKIN, BREATHING DUSTS, ACCIDENTAL SWALLOWING

POSSIBLE HEALTH EFFECTS:EYE CONTACT: NOT EXPECTED TO IRRITATE 1SKIN CONTACT: NOT EXPECTED TO IRRITATE 1BREATHING DUST: NE. TAKE PRECAUTIONS. 1SWALLOWING: NE. WASH HANDS AFTER HANDLING & BEFORE EATING & DRINKING. 1

SENSITIZATION: NKTARGET ORGANS: NE

CANCER INFORMATION:PRODUCT AND COMPONENTS NOT KNOWN TO US TO BE CARCINOGENSNTP: NKIARC: NKOSHA: NR

1 PRECAUTIONS:TO HELP PROTECT AGAINST EXPECTED, OR UNFORSEEN IRRITATIONS OR REACTIONS,WEAR ALL PROPERLY SELECTED PROTECTIVE EQUIPMENT AND CLOTHING AS INSTRUCTEDIN SECTION 8 OF THIS MATERIAL SAFETY DATA SHEET. WORKERS SHOULD WASH THEIRHANDS AND FACE AFTER HANDLING AND BEFORE EATING, DRINKING, SMOKING OR USINGRESTROOM FACILITIES. AFTER EACH SHIFT, CLEAN ALL PROTECTIVE EQUIPMENT, WASH

ALL WORK CLOTHES, AND SHOWER. CHECK SECTION 11 FOR TOXICOLOGY INFORMATION.

UNUSUAL HAZARDS: IF MIXED WITH AIR IN SUFFICIENT AMOUNTS & PROPORTIONS,ORGANIC DUSTS CAN FORM FLAMMABLE OR EXPLOSIVE DUST/AIR MIXTURES. ASPRECAUTIONS, KEEP AREAS CLEAN AND AVOID DUST BUILD-UP. HAVE PLENTY OFGOOD VENTILATION. AVOID CREATING VERY DUSTY CONDITIONS. WHEN MIXING,POURING OR PROCESSING BULK AMOUNTS OF POWDERS, GROUND ALL CONTAINERS AND

AVOID STATIC CHARGES, SPARKS, SMOKING, OPEN FLAMES, OR OTHER POSSIBLECAUSES OF FIRE OR EXPLOSION.

-------------------------------------------------------------------------------SECTION 4 FIRST AID INSTRUCTIONS

EYE CONTACT: IMMEDIATELY RINSE WITH PLENTY OF CLEAN FLOWING WATER FOR ATLEAST 20 MINUTES, HOLDING EYELIDS OPEN TO RINSE COMPLETELY. CALL A DOCTOR,

AND GET MEDICAL QUICKLY, AS A PRECAUTION.

SKIN CONTACT: REMOVE AFFECTED CLOTHING. WASH AFFECTED SKIN AREA WITH PLENTYOF SOAP AND WATER. RINSE WITH PLENTY OF WATER. WASH ALL WORK CLOTHESBEFORE WEARING AGAIN. IF ANY REDNESS, SWELLING, ITCHING, OR PAIN OF THESKIN STARTS, SEE A DOCTOR QUICKLY AS A PRECAUTION.

BREATHING PRODUCT DUST: MOVE PERSON TO FRESH AIR. IF PERSON IS HAVINGDIFFICULTY BREATHING, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL

8/12/2019 acid blue 25 (1)


RESPIRATION. GET EMERGENCY MEDICAL HELP FAST. CALL 911 IF AVAILABLE INYOUR AREA. IF NOT AVAILABLE CALL ANOTHER MEDICAL EMERGENCY NUMBER.

SWALLOWING OF PRODUCT: IF CONSCIOUS, GIVE PLENTY OF WATER TO DRINK AND

GET MEDICAL HELP FAST. IF UNCONSCIOUS, DO NOT GIVE ANYTHING TO DRINKTO DRINK. CALL A DOCTOR AND GET EMERGENCY MEDICAL HELP FAST.

-------------------------------------------------------------------------------SECTION 5 FIRE FIGHTING INSTRUCTIONS

PHYSICAL HAZARDS : NKFLASH POINT : NATYPES OF EXTINGUISHERS : CO2, FOAM, DRY CHEMICAL, WATER SPRAYFIREFIGHTING DIRECTIONS: WEAR SELF-CONTAINED BREATHING APPARATUS TO PROTECT

AGAINST POSSIBLY TOXIC FUMES. WEAR FULL FIRE-PROTECTIVE CLOTHING.

-------------------------------------------------------------------------------SECTION 6 ACCIDENTAL SPILL OR RELEASE INSTRUCTIONS

WEAR A NIOSH APPROVED DUST RESPIRATOR, ALONG WITH ALL PROTECTIVE CLOTHING ANEQUIPMENT AS DIRECTED IN SECTION 8.

CONTAIN AND CLEAN UP SPILL IMMEDIATELY. SWEEP POWDERS CAREFULLY, USING AN ABSORBENT (SUCH AS SWEEPING COMPOUND) TO KEEP DOWN THE DUST IN THE AREA.

SCOOP MATERIAL & ABSORBENT INTO DISPOSAL DRUM, AND SEAL.

RCRA STATUS: SEE REGULATORY INFORMATION, SECTION 15.

ENVIRONMENTAL PROTECTION: PREVENT FROM ENTERING FLOOR DRAINS OR SEWERS. DONOT RELEASE TO SEWER OR TO ANY BODIES OF WATER OR STREAMS WITHOUT HAVINGPROPER GOVERNMENT APPROVAL AT ALL LEVELS,

SEE SECTION 13, DISPOSAL CONSIDERATIONS/ENVIRONMENTAL PROTECTION PROCEDURESFOR ANY ADITIONAL INFORMATION.

-------------------------------------------------------------------------------SECTION 7 HANDLING AND STORAGE

PROTECT PRODUCT FROM MOISTURE, STORE IN COOL, DRY PLACE UNDER LOW RELATIVEHUMIDITY, AWAY FROM EXCESSIVE HEAT. STORE IN ORIGINAL OR EQUIVALENT WATER-PROOF CONTAINERS. RESEAL CONTAINERS TIGHTLY AFTER EACH USE.

SHELF LIFE: INDEFINITE WHEN STORED CAREFULLY AS INSTRUCTED ABOVE.

-------------------------------------------------------------------------------SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

NOTE: WHEN SELECTING PERSONAL PROTECTIVE EQUIPMENT AND CLOTHING, FOLLOW ALLMANUFACTURER SPECIFICATIONS AND RECOMMENDATIONS THAT APPLY TO YOURSPECIFIC OPERATIONS AND PROCESSING CONDITIONS. TAKE INTO CONSIDERATION

ALL CONDITIONS AND ALL CHEMICALS TO BE HANDLED OR PROCESSED

EYE PROTECTION: WEAR SPLASH-PROOF CHEMICAL SAFETY GOGGLES. CONTACT LENSES

8/12/2019 acid blue 25 (1)


SHOULD NOT BE WORN WHEN WORKING WITH CHEMICALS.

SKIN PROTECTION: WEAR CHEMICALLY RESISTANT RUBBER GLOVES, SELECTED WITHYOUR SPECIFIC PROCESSING CONDITIONS AND CHEMICALS TO BE HANDLED IN MINDWEAR COVERALLS AND BOOTS TO MINIMIZE SKIN CONTACT. AS PRECAUTIONS, WASHHANDS & FACE WITH MILD SOAP & WATER BEFORE EATING, DRINKING, SMOKING, OR

USING RESTROOM. AFTER EACH SHIFT, CLEAN ALL PROTECTIVE EQUIPMENT, WASHWORK CLOTHES, AND SHOWER.

LUNG, THROAT & NASAL PROTECTION: WEAR NIOSH APPROVED DUST RESPIRATOR FORYOUR PARTICULAR OPERATION AND MATERIALS BEING HANDLED.

OTHER PROTECTION: EYE WASH FOUNTAINS & DRENCH SHOWERS SHOULD BE LOCATEDWITHIN 100 FEET OR A 10 SECOND WALK OF THE WORK AREA PER ANSI Z358.1-1990

VENTILATION: LOCAL EXHAUST IS RECOMMENDED, MECHANICAL EXHAUST ACCEPTABLE

-------------------------------------------------------------------------------SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

DESCRIPTION : BLUE POWDER; NO ODORDECOMPOSITION TEMP: NEPH : 9.0 - 10.0 @ 1 G/L WATERWATER SOLUBILITY : 10 G/L @ 30 CBULK DENSITY : NE

-------------------------------------------------------------------------------SECTION 10 STABILITY AND REACTIVITY

STABILITY : STABLECONDITIONS TO AVOID : NKHAZARDOUS POLYMERIZATION: WILL NOT OCCURINCOMPTABILE MATERIALS : NKHAZARDOUS DECOMPOSITION PRODUCTS: BURNING CAN PRODUCE OXIDES OF CARBON,

NITROGEN OR SULFUR

-------------------------------------------------------------------------------SECTION 11 TOXICOLOGY INFORMATION

ORAL LD50 (RAT): > 5000 MG/KGDERMAL LD50 (RAT): NEINHALATION LC50 (RAT): NE

EYE EFFECTS (RABBIT): NOT AN IRRITANT 1SKIN EFFECTS (RABBIT): NOT AN IRRITANT 1BREATHING EFFECTS: NE. TAKE PRECAUTIONS.

1) NOTE: ALTHOUGH THIS PRODUCT IS NOT AN IRRITANT BASED ON ANIMAL STUDIES,INDIVIDUALS CAN STILL BECOME SENSITIVE TO, OR REACT TO ANY CHEMICALS IN

ANY OF THEIR WORK AREAS. AS PRECAUTIONS, BE SURE TO WEAR ALL PROTECTIVEEQUIPMENT AND CLOTHING AS EXPLAINED IN SECTION 8 OF THIS MSDS.

GENERAL PRECAUTIONS: ALWAYS PRACTICE GOOD INDUSTRIAL HYGIENE, HANDLE WITHCARE, AVOID PERSONAL CONTACT. DO NOT GET INTO EYES OR ON SKIN, DO NOT

8/12/2019 acid blue 25 (1)


BREATHE DUST OF PRODUCT, DO NOT SWALLOW. WASH HANDS WITH SOAP AND WATER, AND RINSE WELL AFTER HANDLING PRODUCT. SHOWER AFTER EACH SHIFT. WASH ALL WORK CLOTHING AND COMPLETELY CLEAN ALL PROTECTIVE EQUIPMENT AFTER

EACH SHIFT. SEE SECTION 2.

MUTAGENICITY: NK

MORE INFORMATION: SEE SECTION 3, HAZARD IDENTIFICATION & EMERGENCY OVERVIEW

MEDICAL CONDITIONS WORSENED BY EXPOSURE: PERSONS WITH BREATHING AND LUNGPROBLEMS CAN BE AFFECTED BY BREATHING IN ANY TYPE OF DUSTY MATERIAL.PERSONS WITH ASTHMA, ALLERGIES, OR OTHER BREATHING-RELATED PROBLEMS SHOULDSTAY AWAY FROM, NOT HANDLE, AND NOT BE EXPOSED TO ANY DUSTY PRODUCTS ORDUSTY CONDITIONS AS A PRECAUTIONARY MEASURE.

-------------------------------------------------------------------------------SECTION 12 ECOLOGICAL DATA

BOD 5: 15.0 MG/GCOD: 1280.0 MG/GFISH TOXICITY: LC50 = 6 MG/L (TROUT) 48 HREFFECT ON WASTE TREATMENT BACTERIA: > 300 MG/L

ACTIVATED SLUDGE RESPIRATION INHIBITION TEST: NECWA TOXIC POLLUTANTS: NK

ADDITIONAL ENVIRONMENTAL DATA: NE

-------------------------------------------------------------------------------SECTION 13 DISPOSAL CONSIDERATIONS/ENVIRONMENTAL PROTECTION PROCEDURES

DISPOSAL METHODS:

IT IS RECOMMENDED THAT YOU SELECT AN ALTERNATIVE BELOW ACCORDING TOTHE FOLLOWING ORDER OF PREFERENCE, DEPENDING ON ENVIRONMENTAL IMPACT:

1) RECYCLE OR REWORK MATERIAL IF AT ALL POSSIBLE2) INCINERATE MATERIAL AT AN APPROVED FACILITY3) TREAT AT AN ACCEPTABLE WASTE TREATMENT FACILITY, OR MUNICIPAL WASTE

TREATMENT PLANT AFTER PROPER TESTING & APPROVAL WASTE SAMPLES.

IF DISPOSED OF IN IT'S ORIGINAL UNUSED FORM, THIS MATERIAL SHOULD BETREATED, AND DISPOSED OF AT AN APPROVED SITE OR FACILITY, IN COMPLIANCEWITH ALL APPLICABLE FEDERAL, STATE & LOCAL ENVIRONMENTAL REGULATIONS. YOUMUST CONTACT THE PROPER GOVERNMENT AGENCIES FOR ADDITIONAL DIRECTIONS.

ALL WASTE MATERIAL & WASTE WATER SHOULD BE DISPOSED OF CORRECTLY, UNDER ALL FEDERAL, STATE , CITY & COUNTY LAWS.

RCRA STATUS: CHECK SECTION 15, REGULATORY INFORMATION

DO NOT RELEASE ANY CHEMICALS, DYE, OR DYE SOLUTION INTO ANY WATERWAYS ORSEWER SYSTEMS WITHOUT PROPER GOVERNMENT PERMISSION AT ALL LEVELS.

CONTAINER REUSE: AN "EMPTY" CONTAINER CAN CONTAIN PRODUCT RESIDUE, ANDSHOULD NOT BE REUSED. IF NOT PROFESSIONALLY CLEANED & RECONDITIONED,CRUSHING OR OTHER MEANS IS RECOMMENDED TO PREVENT UNAUTHORIZED REUSE

8/12/2019 acid blue 25 (1)


-------------------------------------------------------------------------------SECTION 14 SHIPPING/TRANSPORT INFORMATION

DOT STATUS (HIGHWAY & RAIL): NR

IATA STATUS (AIR): NR------------------------------------------------------------------------------SECTION 15 REGULATORY INFORMATION

AICS (AUSTRALIA): NCCAL. PROP. 65: TO THE BEST OF OUR PRESENT KNOWLEDGE BASED ON THE INFORMATION

AVAILABLE AT THE TIME OF THIS ENTRY, WE ARE NOT AWARE OF ANY CHEMICALSPRESENT IN THIS PRODUCT THAT ARE KNOWN TO THE STATE OF CALIFORNIA TO CAUSECANCER OR REPRODUCTIVE TOXICITY.

CERCLA: NHCLEAN AIR ACT:

TITLE III-HAP'S: NKTITLE V-VOC'S: NKTITLE VI-ODC'S: NOT MANUFACTURED WITH NOR CONTAINING CLASS I OR II ODC'S

CONEG-TYPICAL METALS PRESENT IN PPM:CADMIUM NECHROMIUM NELEAD NEMERCURY NE

DSL (CANADA): NCECL (KOREA): NCEINECS (EUROPE): NCENCS (JAPAN): NCFDA STATUS: NLOTHER TYPICAL DATA IN PPM: NK

RCRA: NOT HAZARDOUS IN IT'S PURCHASED FORM. HOWEVER, UNDER RCRA, IT IS THEPRODUCT USER'S RESPONSIBILITY TO DETERMINE AT TIME OF DISPOSAL IF ANYMATERIAL CONTAINING THE PRODUCT OR DERIVED FROM THE PRODUCT IS AHAZARDOUS WASTE.

SARA 311/312: IMMEDIATE/ACUTE HEALTH HAZARD : NODELAYED/CHRONIC HEALTH HAZARD : NOFIRE HAZARD : NOSUDDEN RELEASE OF PRESSURE HAZARD: NOREACTIVITY HAZARD : NO

SARA 313: NRTSCA: COMPONENTS LISTEDUSDA: NLWHMIS: NC

-------------------------------------------------------------------------------SECTION 16 OTHER INFORMATION

ACRONYM LIST

NA = NOT APPLICABLE TO THIS MATERIALNC = NOT CERTAIN, UNDETERMINEDND = NO DATA IS CURRENTLY AVAILABLE

8/12/2019 acid blue 25 (1)


NE = NOT ESTABLISHED, NO TESTING IS PLANNEDNH = NOT HAZARDOUS UNDER CITED REGULATIONSNK = NONE KNOWN, NO INFORMATION FOUND IN DATA SEARCHSNL = NOT LISTED OR APPROVED UNDER THESE REGULATIONSNR = NOT REGULATED OR REPORTABLE

NIOSH = NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTHTHE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA

BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KINDEXPRESSED OR IMPLIED, IS MADE WITH RESPECT TO THE INFORMATION CONTAINEDHEREIN. THIS MATERIAL SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THEOSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200, AND SUPERSEDES ANYPREVIOUS INFORMATION. PREVIOUSLY DATED SHEETS ARE INVALID & UNAPPLICABLE.

8/12/2019 acid blue 25 (1)


MSDS 02-00021


------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: ACID RED 266 200%

CHEMICAL FAMILY: Acid Red 266


DATE PREPARED: DECEMBER 2009----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS----------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PELAZO DYE 57741-47-6 NOT ESTABLISHED---------------------------------------------------------------------------------------------------------------------------------------------------------------


EFFECTS OF OVEREXPOSURE:EYE CONTACT: IRRITATING.SKIN CONTACT: MAY BE IRRITATING.INHALATION: MAY BE IRRITATING.INGESTION: NOT KNOWN.CHRONIC EXPOSURE: NOT KNOWN.CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN.MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN






8/12/2019 acid blue 25 (1)


MSDS 02-00022









SKIN CONTACT.

HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLINGTHIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, ORSMOKING, WASH HANDS AND FACE WITH SOAP AND WATER.----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES---------------------------------------------------------------------------------------------------------------------------------------------------------------- APPEARANCE: POWDER ODOR: NONESOLUBILITY IN WATER: SOLUBLEBOILING POINT: NOT APPLICABLE.MELTING POINT: NOT ESTABLISHED.--------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY----------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE.




8/12/2019 acid blue 25 (1)


MSDS 02-00023










STATE RIGHT TO KNOW INFORMATIONINGREDIENT CAS NUMBERACID RED 266 57741-47-6

8/12/2019 acid blue 25 (1)


MSDS 02-00024

-----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION----------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 2




8/12/2019 acid blue 25 (1)


FIRE: REACTIVITY: PERSONAL PROTECTION:



HMIS RATINGS: HEALTH: 1 1 0 F *


Product I.D.: K301 Product Name: ACID BROWN 282 CRUDE Product Description: Acid Brown Colorant Powder

Cr+3 compound < 85% Chemical Family: Metallized azo dye Effective Date: July 3, 2009


Component CAS Number Wt % OSHA - PEL ACGIH - TLV Recommended

PEL Chromium as Cr+3 (Complexed in dye molecule) 7440-47-3 1 -10% 0.5 mg/m3 TWA 0.5 mg/m3 TWA Not applicable

1.00

UNPROTECTED CONTACT with Section 2 ingredients may be hazardous based on OSHA 29 CFR 1910.1200 & relatedappendices, unless noted otherwise for disclosure. Any not listed are confidential, non-hazardous, or below reportable limits.Confidential information is available to medical or emergency personnel. Use ALL PROTECTIVE EQUIPMENT & CLOTHING(Section 8) TO MINIMIZE or ELIMINATE CONTACT. Effects from UNPROTECTED may be unpredictable, depending onndividual reactions. End-users are responsible for hazard determination and communication.

mportant Notice:


mergency Overview: Mild eye and skin irritant. Respiratory effects not established.

Eye Contact: Depending on degree of UNPROTECTED contact, vapors, mists, aerosols, splashes, droplets or dusts ofproduct may cause health effects such as MILD IRRITATION, discomfort, redness, watering, itching, stinging.Heavy contact or for prolonged period may increase effects.

kin Contact:

8/12/2019 acid blue 25 (1)



K301 ACID BROWN 282 CRUDE

Depending on degree of UNPROTECTED contact, vapors, mists, splashes, aerosols, or dusts of product maycause health effects in SENSITIVE or SENSITIZED individuals such as IRRITATION to skin, ALLERGICREACTIONS, redness, rash, itching, burning feeling, drying, cracking, pain, swelling, or other effects.Prolonged or repeated contact may cause inflammation. Quantity absorption through skin may cause nausea,headache, or other effects.

nhalation:

UNPROTECTED breathing of product vapors, mists, aerosols or dusts may cause symptoms including MILDIRRITATION of the nose, throat, lungs and mucous membranes, shortness of breath, sneezing, coughing,runny nose, nausea, headache. Prolonged or heavy exposure, or heating of liquid material may increaseseverity of symptoms. Hazard assessment is cautious, based on component information.

ngestion: Depending on amount swallowed, product can cause health effects including MILD IRRITATION of mouth,throat, esophagus, stomach, and gastrointestinal tract, upset stomach, abdominal discomfort, nausea,vomiting, gastrointestinal disturbances, diarrhea. Higher dose may increase irritation and severity of symptoms.

Medical Conditions Aggravated by Exposure: UNPROTECTED or IMPROPERLY PROTECTED exposure to vapors, mists, aerosols, splashes or dusts of fullstrength product or its components by inhalation, eye contact, skin contact or swallowing MAY AGGRAVATEone or more of the following pre-existing medical conditions: Respiratory (breathing related) problems (asthma,allergies, etc.), skin conditions, or disorders, eye conditions or disorders, kidney disorders, liver disorders.

Avoid ALL exposures. Individuals with any of the above-noted conditions, or with any known or suspectedchemical sensitivities or allergies should avoid working with or being exposed to any chemicals.

kin Sensitization: Protect yourself and AVOID ALL EXPOSURES. As a precaution, persons known to be or suspected of beingchemically sensitive or allergic should not work with chemicals. UNPROTECTED or IMPROPERLYPROTECTED exposure to product or its components may cause SKIN SENSITIZATION OR ALLERGICREACTIONS in some individuals. Effects may include redness, swelling, itching, rash and hives. It may takerepeated or prolonged exposure to cause health effects. SENSITIZATION or ALLERGIC REACTIONS AREUNPREDICTABLE. If symptoms appear, IMMEDIATELY remove person from area of contact, follow Section 4instructions, GET MEDICAL ATTENTION.

Respiratory Sensitization: Respiratory sensitization caused by inhalation of product dust, vapors, mists or aerosols HAS NOT BEENDETERMINED. As a precaution against aggravating existing respiratory conditions, hypersensitivity, allergicreactions, or other unforeseen health effects, be sure to read, understand and follow all supervisor instructions,and instructions for wearing Personal Protective Equipment and clothing in Section 8 of this MSDS. Avoidinhalation of product in any form. ALLERGIC REACTIONS and SENSITVITY depend on the individual, andCAN BE UNPREDICTABLE.


Unusual Health Hazards: None for this material

upplemental Hazard Information: No additional information available

Notes to Physician: No notes available

8/12/2019 acid blue 25 (1)




Cancer Information:

Chemical Name CAS # WT % IARC NTP OSHA NIOSH ACGIH

Chromium as Cr+3Complexed in dye molecule) 1 - 10% 7440-47-3 Group 3

Unclassifiableon human

carcinogenicity

NONE NONE NONE NONE


Immediately rinse with plenty of water for at least 15 minutes. Get immediate medical attention, as a precaution. Eye Contact:

Immediately remove contaminated clothing. Wash affected area with soap and rinse with plenty of water. Getmedical attention, as a precaution.

Skin Contact:

Move person to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration, and getemergency medical help immediately. Have this Material Safety Data Sheet available.

Inhalation:

Do not induce vomiting unless directed to do so by emergency medical personnel. Have this Material Safety DataSheet available.

Ingestion:


lash Point: Not applicable




ire Fighting Directions: Wear self-contained breathing equipment and fire-proof clothing. Use water spray to cool fireexposed containers if they cannot be safely moved.



Static Discharges: Take precautionary measures against static discharges when mixing, filling or otherwise dispensing anypowders, combustibles, or flammable liquids. Containers should be properly grounded with metal straps, cablesor other appropriate means to relieve static electricity build-up.

Environmental Protection: Immediately dike liquid spills with inert absorbent material (sand, "Oil Dry" or other commercially available spillabsorbent) to contain and soak up liquid. Prevent material from entering floor drains, sewers, or any bodies ofwater. For powder spills, use sweeping compound, sawdust, or other appropriate material to contain dust. Ifpossible, recover any uncontaminated materials to re-use.


Clean up:

8/12/2019 acid blue 25 (1)




After containing liquid spill by diking and soaking up with inert absorbent material, place in labeled container tobe sealed for proper and regulated disposal. Only the slightest residue should remain. Try to saveuncontaminated material for reuse whenever possible. For powders, use sweeping compound to minimize dustand pick up as much product as possible. Do not allow liquids to seep into drains, sewers, lakes, rivers, etc.Check Sections 1 and 2 for dye description or type. Solvent dye residue may be cleaned by scrubbing withdetergent, depending on type. Do not add water to water-soluble dyes. Dye is concentrated. This will increaseamount of color to remove. All cleaning or scrubbing liquids used should be absorbed and placed in labeled

containers for correct disposal. Call emergency number for assistance if needed.


Warnings and Precautions: No special precautions anticipated. Wear all PPE in section 8 as a precaution, and avoidphysical contact with material.

Personal Protection: Wear ALL proper personal protective equipment as outlined in section 8 of this MSDS.

Storage & Temperature Conditions: Keep conditions cool, dry, out of direct sunlight, away from high heat, with at least minimal ventilation. Protect all

products containing water from freezing. SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION

Note: Selecting protective equipment & clothing: When choosing personal protective equipment and clothing, consider each worker environment, all chemicalsbeing handled, temperature and all other conditions.

Eye protection: Always wear indirectly vented, splash-proof chemical safety goggles under a clear face-shield. Face shield is notto be used without these goggles.

Skin Protection: Always wear most impervious gloves such as nitrile or other proper chemical-resistant gloves for the job, alongwith proper coveralls, rubber or plastic apron, etc. Wash hands before eating, drinking or using restroom. Showerafter each shift. Clean contaminated protective equipment and clothing before reusing.

Respiratory Protection: Depending on materials handled, ALWAYS wear an appropriate NIOSH approved organic vapor/mist respirator,or dust respirator, with all proper filters as required whenever exposure to vapors or dusts is expected. After eachshift or when equipment becomes contaminated, clean respirator in compliance with 29 CFR 1910.134.

Eye Washes and Other Protection: Eye wash stations and drench showers should be located within 100 feet or 10-second walk of the work area per

ANSI standard Z358.1-1990. Ventilation:

Local exhaust should be used to maintain exposure limits below specified amounts recommended by OSHA,NIOSH, or ACGIH and to draw spray, aerosol, vapors, or dusts away from workers and prevent routineinhalation. At least 10 air changes per hour are recommended for good room ventilation.

Airborne Exposure Limits:

OTHER OEL'S NIOSH - IDLH NIOSH - REL WT % CAS # Chemical Name Not established Not established 0.5 mg/m3 TWA 1 - 10% 7440-47-3 Chromium as Cr+3

(Complexed in dye molecule)


8/12/2019 acid blue 25 (1)




pH: ~ 7.5 @ 1.0% % Water Content: 0 % Total Solids / Non-Volatiles: 100 % Total VOC: 0 Color: Brown Bulk Density (Solid): Not established Form: Powder Odor: None Freezing/Melting Point: Not established Specific Gravity (Liquid): Not established Vapor Pressure: 0 Water Solubility: Soluble Solvent Solubility: Not applicable Other Properties: No further data


Any quantity of VOC's reported here is calculated based on the U.S. EPA definition. State or local definitions maydiffer. To request additional Regulatory Compliance Data, call 312-666-2015.


Product is stable under normal, ambient (controlled) conditions concerning heat, moisture, pressure, ventilationand exposure to incompatible or reactive materials.

Stability:


Conditions to Avoid: Incompatible materials, moisture

Incompatible Materials: Strong oxidizing agents, strong reducing agents

Hazardous Decomposition Products: In fire: Oxides of carbon, nitrogen, sulfur.

Possible Hazard Reactions: None known

Oral LD50 (Rat): No data currently available Eye Effects (Rabbit): No data currently available Skin Effects (Rabbit): No data currently available Mutagenicity: No data currently available Inhalation LC50 (Rat): No data currently available Skin Sensitization (Guinea Pig): No data currently available Respiratory Sensitization: No data currently available Additional Toxicity Data: No data currently available



8/12/2019 acid blue 25 (1)




No data currently available BOD: No data currently available COD: No data currently available Aquatic Toxicity: No data currently available Biodegradability: No data currently available Persistence: No data currently available Ecotoxicity: Undetermined Sewage Treatment: No additional data is available Other Data:




Incinerate, treat, or bury (landfill), after sampling and testing, at facility approved by applicable federal, state,and local authorities.

Disposal Methods:

Empty containers may contain residue and/or vapors and should not be reused unless professionally cleanedand reconditioned. Crush if not cleaned, to prevent reuse.

Empty Containers:



DOT Regulations (Ground):

NOT REGULATED

IATA Regulations (Air):

NOT REGULATED


Component Regulatory List Weight % CAS Number Chromium as Cr+3 (Complexed in dye molecule) 7440-47-3 1 - 10% 2, 8, 11: D007, 13: 0.1%, 15: DE, MA, MN, NJ, NY

NOTE: Regulations only apply when numbers listed below are shown on line(s) above this notation.Example A: 5, 8 (Indicates chemical is listed as an EPA HAP and a Marine Pollutant) Example B: 10: D007, 11: 5000 (Indicates chemical is a hazardous waste (Chromium), and is an EHS

with RQ of 5000 lbs.)

1-Accidental Release Substance 2-CERCLA 304 Hazardous Substance (RQ)3-Reserved 4-Clean Air Act-Sec. 111 Volatile Organic Compounds (VOC)

5-Clean Air Act-Sec. 112 Haz. Air Pollutant (HAP, HAP Code)


8/12/2019 acid blue 25 (1)




6-Clean Air Act-Ozone Depleting Chemical (ODC) 7-Clean Water Act-RQ 8-Clean Water Act-Priority Pollutant (PP) RQ 9-Marine Pollutant (MP) 10-PSM Highly Hazardous Chemical 11-RCRA Hazardous Waste (RCRA Code) 12-SARA 302 Extremely Hazardous Substance (EHS) (RQ)

13-SARA 313 Toxic Release Inventory (TRI) (TR Conc., TR Threshold) 14-SOCMI Chemical15-State Lists

CA-California Proposition 65 NJ-New Jersey RTK Hazardous Substance List NJ-New Jersey TCPA Extremely Hazardous Substance List

16-Supplemental regulatory information (SRI)

List revised 12/29/09 wln (Current list is not applicable to previously issued MSDS')


Immediate / Acute Health Hazard: YES Chronic / Delayed Hazard: NO Fire Hazard: NO Sudden Release of Pressure Hazard: NO Reactivity Hazard: NO

NATIONAL CHEMICAL INVENTORIES:

Not yet determined AICS (Australia): Not yet determined ASIA-PAC (Asia-Pacific): Not yet determined DSL (Canada): Not yet determined ECL (Korea):

Not yet determined EINECS (Europe): Not yet determined ENCS (Japan): Not yet determined IECSC (China): Not yet determined PICCS (Philippines): Components Listed TSCA (US):

OTHER:

For additional International, Federal or State regulatory compliance information not shown: Call 312-666-2015. Supplemental Regulatory Information:


Reason for Revision: None at this time Reviewed: wln 070306

The information and recommendations contained herein are based upon data believed to be correct. However,no guarantee or warranty of any kind, expressed or implied, is made with respect to the information containedherein. This Material Safety Data Sheet was prepared to comply with the OSHA Hazard CommunicationStandard 29 CFR 1910.1200, and supersedes any previous information. Previously dated sheets are invalidand inapplicable.

END OF MSDS

Disclaimer:

8/12/2019 acid blue 25 (1)




8/12/2019 acid blue 25 (1)


800.255.3924

________________________________________________________________________________ ____


________________________________________________________________________________ ____

N O T E: DO NOT DETACH THIS GUIDANCE COVER SHEET FROM THE REST OF THISDOCUMENT.



________________________________________________________________________________ ____








________________________________________________________________________________ ____




________________________________________________________________________________ ____




TRADE NAME: ACID RED 357 CRUDEPRODUCT ID: 601-357-80


8/12/2019 acid blue 25 (1)




This MSDS is designed to effectively communicate Health and Physical Hazardsto the

material handler and all other responsible persons concerned withHealth andEnvironmental protection and regulatory compliance. Distributors receiving


agents.

________________________________________________________________________________ ____







________________________________________________________________________________ ____


________________________________________________________________________________ __

Effective Date: 06-08-09 Supersedes: 06-10-05 Product Code: K605

________________________________________________________________________________ __

SECTION 1: <CHEMICAL IDENTIFICATION>

C.I. Name : NAC.I. Number : NACAS Number : 73507-64-9Chemical Family: Chromium Complex DyePhysical Form : Powder

________________________________________________________________________________ __

SECTION 2: <INFORMATION ON INGREDIENTS>

Component Name CAS Number PEL TLV%

8/12/2019 acid blue 25 (1)


Acid Red 357 73507-64-9 NE NE

100

________________________________________________________________________________ __

SECTION 3: <HAZARD IDENTIFICATION and EMERGENCY OVERVIEW>

HMIS Ratings: Health 1 Flammability 0 Reactivity 0Protection F,n

Emergency Overview: Irritating to eyes and skin. Ingestion may result ingastric

disturbances; inhalation may cause respiratory irritation.

Possible Exposures: Eyes, Skin, Breathing dust, Accidental swallowing

Possible Health Effects:Eye Contact: Irritating to eyesSkin Contact: Irritating to skinBreathing Dust: NE. Take precautions.Swallowing: NE. Take precautions.

Sensitization: NKTarget organs: NKCancer Information:

Product and components not known to us to be CarcinogensNTP : NK Group IARC : NK Group OSHA : NR See above

Medical conditions worsened by exposure: Persons with breathing and lungproblems can be affected by any type of dusty material. Persons with

asthma,allergies or other breathing-related problems should not handle, nor be

exposedto dusty products or dusty conditions, as a precautionary measure.

Unusual Hazards: Avoid dusting. Ground containers when dispensingproduct.

Dust can form explosive mixtures with air.

Precautions: Wear protective equipment and follow hygienicrecommendations

indicated in Section 8 of this MSDS. ________________________________________________________________________

SECTION 4: <FIRST AID INSTRUCTIONS>

Eye contact: Immediately rinse with plenty of clean flowing water for atleast 20

minutes, holding eyelids open to rinse completely. Call a doctor and get medical

help quickly, as a precaution.

8/12/2019 acid blue 25 (1)


Skin contact: Remove affected clothing, wash affected area with plenty ofsoap &

water. Rinse with plenty of water. Wash work clothes before wearingagain. If any

redness, swelling, itching or pain of skin starts, see doctor as aprecaution.

Breathing product dust: Move person to fresh air. If person hasdifficulty

breathing, give oxygen. If not breathing, give artificial respiration.Get

emergency medical help immediately. Call 911.

Swallowing: Do not induce vomiting. Flush mouth with water. Call adoctor and get

emergency medical help quickly.

________________________________________________________________________________ ___

SECTION 5: <FIRE FIGHTING INSTRUCTIONS>

Flash point : NATypes of extinguishers : Water Spray, dry chemical, CO2, foamFire-fighting directions: Wear self-contained breathing apparatus to

protectagainst possibly toxic fumes. Wear full fire-protective clothing

________________________________________________________________________________ ___

SECTION 6: <ACCIDENTAL SPILL or RELEASE INSTRUCTIONS>

Wear a NIOSH approved dust respirator, along with all protective clothingand

equipment as described in Section 8 of this MSDS. Read & follow Section8.

Contain and clean up spill immediately. Try to salvage as much clean material as

possible. Sweep powders carefully, using an absorbent (such assweeping

compound) to keep down the dust in the area. Scoop material andabsorbent into

disposal drum, seal and label.

RCRA Status: See Regulatory Information, Section 15.

Environmental protection: Prevent material from entering floor drainsor sewers.

Do not release to sewers, streams, rivers or to any other bodies of water. If

8/12/2019 acid blue 25 (1)


entry has occured or soil/vegetation has been contaminated, adviseproper

government authorities. Check Section 13, "DisposalConsiderations/Environmental

Protection Procedures" for more information.

________________________________________________________________________________ ___

SECTION 7: <HANDLING and STORAGE>

Protect product from moisture, store in cool, dry place under lowrelative

humidity, away from excessive heat. Store in original or equivalent water-proof

containers. Reseal containers tightly after each use. Keep out of directsunlight.

Avoid contact with eyes.Shelf life: Indefinite when stored carefully as instructed above.

________________________________________________________________________________ ___

SECTION 8: <EXPOSURE CONTROLS and PERSONAL PROTECTION>

Note: When selecting personal protective equipment and clothing, followall

manufacturers specifications and recommendations that apply to youroperation

and processing conditions. Take into consideration worker environmentsand all

chemicals and mixtures being handled or processed. Apply OSHA workplaceregulations in CFR Title 29 part 1910.1200, and cited and cross-

referencedregulations and standards. State and local regulations may also apply.

Eye Protection: Wear splash-proof chemical safety goggles.Precaution: Contact lenses should not be worn when working with

chemicals.

Skin Protection: Wear chemically impervious gloves, selected with yourspecific processing conditions and chemicals to be handled in mind. Wear

coverallsand boots to minimize skin contact. As precautions, wash hands and face

with mildsoap and water before eating, drinking, smoking or using restroom. After

eachshift, clean all protective equipment, wash all work clothes and shower

well.

Lung, Throat and Nasal Protection: Wear NIOSH approved dust respiratorfor your

particular operation and material being handled. Clean respirator withsoap and

water after each shift.

8/12/2019 acid blue 25 (1)


Other Protection: Eye wash fountains and drench showers should be located

within100 feet or a 10-second walk of the work area per ANSI Z358.1-1990.

Ventilation: Local exhaust is recommended.

________________________________________________________________________________ __

SECTION 9: <PHYSICAL and CHEMICAL PROPERTIES>

Description : Powder, odorlessMelting Point : NEWater Solubility: SolublepH : NEBulk density : NE% Total VOC's : 0% Non-Volatiles : 100% Water : 0

________________________________________________________________________________ __

SECTION 10: <STABILITY and REACTIVITY>

Stability : StableConditions to avoid : NKIncompatible Materials : Oxidizing and reducing agents.Hazardous decomposition products: Burning can produce oxides of carbon,

nitrogen,or other toxic or possibly harmful fumes.

________________________________________________________________________________ __

SECTION 11: <TOXICOLOGY INFORMATION>

Oral LD50 (Rat): > NEDermal LD50 (Rat): NEInhalation LC50 (Rat): NE

Eye effects (Rabbit) : Irritating to eyesSkin Effects (Rabbit): NE. Take precautions.Breathing Effects: NE. Take precautions.

General Precautions: Practice good industrial hygiene, handle with care,avoid

personal contact. Do not get in eyes or on skin, do not breathe productdust,

do not swallow. Wash hands with soap and water, and rinse well afterhandling.

Shower after each shift. Wash all work clothes and equipment after eachshift.

8/12/2019 acid blue 25 (1)


Mutagenicity: NKReproductive Effects: NK

________________________________________________________________________________

SECTION 12: <ECOLOGICAL DATA>

Mobility: Soluble in water.Pesistence and degradability: This product is not readily

biodegrageable.Other adverse effects: WGK(Germany) Water pollution class: 2-hazardous

to water(self assessment).

________________________________________________________________________________

SECTION 13: <DISPOSAL CONSIDERATIONS AND ENVIRONMENTAL PROTECTIONPROCEDURES>

Disposal Methods:

It is recommended that you select an alternative below according tothe

following order of preference, depending on environmental impact:

1) Recycle or rework material if at all possible2) Incinerate material at an approved facility3) Treat at an acceptable waste treatment facility, or municipal waste

treatment plant after proper testing & approval of waste samples.

If disposed of in original unused form, material should be treated anddisposed

of at an approved site or facility, in compliance with applicablefederal,

state & local environmental regulations. Contact proper governmentagencies

for additional directions. All waste material & waste water should bedisposed

of correctly, under all federal, state, city and county laws.

RCRA Status: See Section 15, Regulatory Information

Do not release any chemicals, dyes or other color solutions into anysewer, or

any river, stream, lake pond nor onto any other types of watercourses,

waterways, or systems without proper government permission at alllevels.

Container reuse: An "empty" container can contains product residueand should

not be reused. If not professionally cleaned and reconditioned,crushing or

8/12/2019 acid blue 25 (1)


other means is recommended to prevent unauthorized reuse.

________________________________________________________________________________

SECTION 14: SHIPPING AND TRANSPORT INFORMATION

DOT Status (Highway and rail): NRIATA Status (Air): NR

________________________________________________________________________________


AICS (Australia): ListedCal Prop. 65: To the best of present knowledge, based on information

availableon date of this entry, we are not aware of substances present in this

productlisted by California as causing cancer or reproductive toxicity.

CERCLA(40CFR 302.4): NHClean Air Act:

Title III (HAP's): NKTitle (V-VOC's): Check Sections 2, 3 and 9Title VI (ODC's): Not containing nor manufactured with class I or II

ODC's.CONEG-Typical Metals present in PPM: These figures are typical results

determined by random sample analysis and should not be construed aslimits

for this material.Cadmium : NEChromium : NE (Total including Hexavalent Cr=6)

Lead : NEMercury : NE

DSL (Canada): ListedECL (Korea): KE-20730EINECS (Europe): NCENCS (Japan): NCFDA Status: NLNEPA (China): NC

Other Typical Metals Data in PPM: NKPICCS (Philippines): ListedRCRA: Not hazardous in purchased form.SARA 311/312: Immediate/Acute Health Hazard : yes

Delayed/Chronic Health Hazard : noFire Hazard : noSudden release of pressure hazard: noReactivity Hazard : no

SARA 313: Chromium Compounds, Threshold: 1%TSCA: Listed

_______________________________________________________________________________

8/12/2019 acid blue 25 (1)


SECTION 16: <OTHER INFORMATION>

Effective date: Enter current component dataV-075330-10312001-lkbV-001099-09172002

Acronym List AICS = Australian Inventory of Chemical Substances ANSI = American National Standards Institute

CFR = Code of Federal RegulationsCERCLA = Comprehensive Environmental Responsibility, Compensation and

Liability Act (U.S. EPA)CONEG = Coalition of Northeast GovenorsCWA = Clean Water Act (U.S. EPA)DOT = Department of Transportation (U.S.A.)DSL = Domestic Substance List (Canada)ECL = Existing Chemicals List (Korea)EINECS = European Inventory of Existing Chemical Substances (European

Union)ELINCS = European Listing of Notified of Chemical Substances (European

Union)ENCS = Existing and New Chemical Substances (Japan)EPA = Environmental Protection Agency (U.S.A.)FDA = Food & Drug Administration (U.S.A.)HAP's = Hazardous Air Pollutants (U.S. EPA)IATA = International Air Transport AssociationNA = Not applicable to this materialNC = Not certain, undetermined as of this writingND = No data is currently available, user may test at own discretionNE = Not established, no testing is plannedNEPA = National Environmental Protection Agency (China)NH = Not hazardous under cited regulationsNIOSH = National Institute for Occupational Safety and HealthNK = Substance not known to be present, effect not known to be causedNL = Not listed or approved under these agencies or regulationsNR = Not regulated or reportable under applicable regulationsRCRA = Resource Conservation and Recovery Act (U.S. EPA)SARA = Superfund And Reauthorization Act (U.S. EPA)TSCA = Toxic Substance Control Act (U.S. EPA)USDA = United States Department of Agriculture

The information and recommendations contained herein are based upondata

believed to be correct. However, no guarantee or warranty of any kindexpressed

or implied, is made with respect to the information contained herein.This

Material Safety Data Sheet was prepared to comply with the OSHAHazard

Communication Standard 29 CFR 1910.1200, and supersedes any previousinformation. Previously dated sheets are invalid & inapplicable.

8/12/2019 acid blue 25 (1)


END OF MSDS

8/12/2019 acid blue 25 (1)





RADE NAME--------- ACID RED 419

HEMICAL NAME------ N/AHEMICAL FAMILY---- ACID DYESOLOR INDEX #------ ACID RED 419. A. S. #--------- N/AAST REVISION DATE. 4/29/2009


OMPONENT PERCENT ----- None

II. PHYSICAL DATA


VAPOR PRESSURE--N/A ODOR--- NONE

VAPOR DENSITY---N/A APPEARANCE--DARK POWDERVOLATILITY----- N/A SPECIFIC GRAV-- N/A



LASH POINT N/A


N CASE OF FIRE-----DRY CHEMICAL, CO2, WATER SPRAY OR REGULAR FOAM. MOVE CONTAINERS FROM FIREAREA IF YOU CAN DO IT WITHOUT RISK. APPLY COOLING WATER TO SIDES OF CONTAINERS THAT ARE EXPOSED

O FLAMES UNTIL WELL AFTER FIRE IS OUT.

8/12/2019 acid blue 25 (1)







V. REACTIVITY DATA











8/12/2019 acid blue 25 (1)













8/12/2019 acid blue 25 (1)














. A. R. A.--- NOT REPORTABLE






8/12/2019 acid blue 25 (1)










OTHERS IS BEYOND OUR CONTROL, NO GUARANTEE, EXPRESSED OR IMPLIED, IS MADE BY KEYCOLOURNC..USER ASSUMES ALL RISK AND RESPONSIBILITY.

acid blue 25 (1)

Documents