acids & bases.ppt

20
- The Strength of Acids and Alkalis -

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  • - The Strength of Acids and Alkalis -

  • Our Goals for todayTo state the uses of pH scaleTo relate pH value with acidic or alkaline properties of a substancesTo relate the concentration of hydrogen and hydroxide ions with pH valuesTo relate strong or weak acids/alkalis with the degree of ionisationTo conceptualise qualitatively strong and weak acids/alkalis.

  • What is the pH scale?The pH scale measures how acidic or basic a solution is.

  • The pH scaleThe pH scale is the concentration of hydrogen ions in a given substance.

  • Identifying Acids and BasesAcids have a pH from 0-7Lower pH value indicates a stronger acid.The lower the pH value, the higher concentration of H ions

  • Cont.Bases have a pH from 7-14Higher pH value indicates a stronger base.The higher the pH value, the higher the concentration of OH ions.

  • Did we Miss something??What happens when the pH of a substance is 7?

    Ans: A pH level of 7 indicates a Neutral Substance i.e: Water!

  • Apparatus to measure pH valuepH meterpH paper Universal Indicator

  • pH METERS

  • Universal Indicators ColorsUniversal Indicator is a mixture of different indicators which covers the full range of pH values

  • How to measure the pH value?take measurements and record the results

    [ H + ] = 10For bases

    [ H + ] = 3For acids

  • WHEN THE CONCENTRATION OF HYDROGEN IONS [H+] IN SOLUTION INCREASE SO THE pH VALUES ARE LOWER WHEN THE CONCENTRATION OF HYDROXIDE IONS [OH+] IN SOLUTION INCREASE SO THE pH VALUES ARE INCREASES

  • Concentration of acids and bases with pH values

  • Strong and Weak AcidsDepends on degree of ionisation :Complete dissociation/ ionization in water produces high concentration of H ionsPartial dissociation / ionisation in water produces low concentration of H ionsHA (aq) H+ (aq) (high) + A-(aq) HA (aq) H+ (aq) () + A-(aq)

  • Diagram of strong acid dissociation Before dissociationAfter dissociationHAHA (aq) H+ (aq) + A-(aq) H2OBackHAAAHH H+ H+ H+ H+A-A-A-A-Example ?

  • Diagram of weak acid dissociationBefore dissociationHA (aq) H+ (aq) + A-(aq) H2OBackAfter dissociationAHHHHAAAA-A-A-A- H+ H+ H+ H+Example ?

  • Strong acids definition?Weak acids definition?

  • Diagram of strong alkali dissociationBefore dissociationBOH (aq) B+ (aq) + OH-(aq) H2OAfter dissociationBackBBBB B+OHOHOHOH OH- B+ B+ B+ OH- OH- OH-

  • Diagram of weak alkali dissociationBackBefore dissociationBOH (aq) B+ (aq) + OH-(aq) H2OAfter dissociationBBBB B+OHOHOHOH OH- B+ B+ B+ OH- OH- OH-

  • Definition of strong alkali?Definition of weak alkali?

    -must consist of:1)Degree of ionisation2)Concentration of OH ions3)pH value