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Münster Symposium on

Cooperative Effects

Münster, Germany

May 4th 2012

The Collaborative Research Center(Sonderforschungsbereich) 858“Synergetic Effects in Chemistry - From Additivity towards Cooperativity“

ContactSonderforschungsbereich 858Corrensstraße 40D-48149 Münster, Germanyhttp://www.wwu.de/sfb858

Book of Abstracts

sfb858@wwu.dewww.wwu.de/sfb858

Synergetische Effektein der Chemie - von der

Additivität zur Kooperativität

SFB858

Symposium Schedule Fri May 4th 2012, Aula Schloss of the WWU Münster

Opening Adress

9:55 am Armido Studer Speaker of the SFB 858

10:00 am Shie-Ming Peng Chair: F. Ekkehardt Hahn

National Taiwan University, Taiwan

“Molecular Metal Wires and Related Molecular Materials”

11:00 am Krzysztof Matyjaszewski Chair: N. Seda Kehr

Carnegie Mellon University, Pittsburgh, USA

“Atom Transfer Radical Polymerization - From Mechanism and Synthesis to Materials and Applications”

12:00 am

Postersession

Lunch (~ 12:30 pm) Coffee Break (~ 2:00 pm)

2:30 pm Christopher A. Hunter Chair: Mark P. Waller The University of Sheffield, UK

“The Anatomy of Complex Recognition Interfaces”

3:30 pm David W. C. MacMillan Chair: Ulrich Hennecke Princeton University, USA

“Multi Catalysis in Chemical Synthesis”

4:30 pm Poster Prize Awards Closing Remarks

Poster Contributions in alphabetical order (presenting author’s surname)

Authors Institution Title

1. Jens Antony, Stefan Grimme* WWU Münster / SFB 858 Fully ab initio protein-ligand interaction energies

with dispersion corrected density functional theory

2. Lukas M. Artner, Nina Bohlke, Jens

Dernedde, Nediljko Budisa,

Christian P. R. Hackenberger*

Freie Universität Berlin Multivalent Protein Scaffolds for Lectin Binding

Studies

3. Stephan Beckendorf, Sören Asmus,

Christian Mück-Lichtenfeld, Olga

García Mancheño*

WWU Münster / SFB 858 Cooperation as key to success:

Now weak C–H∙∙∙Anion interactions can catalyze!

4. Anup Biswas, Suman De Sarkar,

Ludger Tebben, Armido Studer*

WWU Münster Enantioselective cyclopropanation of enals by

oxidative N-heterocyclic carbene catalysis

5. Roberto Blanco-Trillo, Mattias

Leven, Bernd Goldfuss*

Universität Köln Electronegativity governs enantioselectivity: Alkyl-

aryl-cross coupling with fenchol-based Palladium-

Phosphorus-Halide catalysts

6. Teerawut Bootwicha, Erli Sugiono,

Magnus Rueping*

RWTH Aachen Continuous-flow Organocatalytic Asymmetric

Hydrogenations using FTIR Inline Analysis

7. Hannah Schuster, Hanna Bruss, Rémi

Martinez, Andrey P. Antonchick,

Herbert Waldmann*

Max-Planck-Institut für

Molekulare Physiologie

Dortmund

Synthesis of the B-seco Limonoid Scaffold

8. Mark Busch, Sefer Ay, Adam Kubas,

Karin Fink, Stefan Bräse*

Karlsruhe Institute of

Technology (KIT)

Multimetallic Complexes with [2.2]Paracyclophanes

Backbone: Cooperative Effects in Catalysis

9. C. Cebrián, M. Mauro, D.

Kourkoulos, P. Mercandelli, D.

Hertel, K. Meerholz, C. A. Strassert,

L. De Cola*

WWU Münster Luminescent neutral Platinum Complexes Bearing an

asymmetric N^N^N Ligand for High-Performance

Solution-processed OLEDs

10. Xiao Yun Chen, Helmut Buschmann,

Carsten Bolm*

RWTH Aachen Bioactive Sulfoximines:

Synthesis and Properties of Dapsone analogues

11. Christian A. Citron, Nelson L. Brock,

Patrick Rabe, Jeroen S. Dickschat*

Technische Universität

Braunschweig

The Stereochemical Course and Mechanism of the

IspH Reaction

12. Soumen De, Susnata Pramanik,

Michael Schmittel*

Universität Siegen Reversible ON/OFF Nanoswitch for Organocatalysis:

Mimicking the Locking and Unlocking Operation of

CaMKII

13. Julia V. Dickschat, Slawomir Urban,

Frank Glorius*, F. Ekkehardt Hahn*

WWU Münster / SFB 858 Novel Amphiphilic Germylenes and Stannylenes and

their Reactivity

14. Arne Dickschat, Jinjun Ren, Frederik

Behrends, Wilma Pröbsting, Hellmut Eckert*, Armido Studer*

WWU Münster / SFB 858 Bifunctional Mesoporous Silica Nanoparticals utilizing

click-chemistry: A route to cooperativity

15. Hussein Ali El-Damarany,

Soumen De, Michael Schmittel*

Universität Siegen Synthesis of Molecular Tweezers as Receptors

Poster Contributions in alphabetical order (presenting author’s surname)

Authors Institution Title

16. Christina Eller, Birgit Wibbeling,

Roland Fröhlich, Gerald Kehr,

Gerhard Erker*

WWU Münster Newly Developed Sulfur-Boron Systems

17. Hugo Fanlo, Sijbren Otto* University of Groningen,

Niederlande

Substrate-Induced Catalyst Formation in Dynamic

Molecular Networks

18. Yingsheng Zhao, Siong Wan Foo,

Susumu Saito*

Nagoya University, Japan Iron/Amino Acid Catalyzed Direct N-Alkylation of

Amines with Alcohols

19. Sabrina Freye, Jakob Hey, Anna

Torras-Galán, Michael John,

Guido H. Clever*

Georg-August Universität

Göttingen

Positive Cooperativity and Allosteric Halide Binding

by an Interpenetrated Double Cage

20. Silke Frömel, Roland Fröhlich,

Constantin G. Daniliuc,

Gerald Kehr, Gerhard Erker*

WWU Münster Application of Halogenating Reagents

in FLP Chemistry

21. Daniela Fuchs, Géraldine Rousseau,

Lisa Diab, Urs Gellrich and Bernhard

Breit*

Albert-Ludwigs-Universität

Freiburg

Cooperative Supramolecular Ligand Catalysis:

Tandem Hydroformylation-Hydrogenation of

terminal Alkenes

22. Takuya Fujimoto, Michio M.

Matsushita, Kunio Awaga*

Nagoya University, Japan Octathio[8]circulene Thin-Film Transistors in Ionic

Liquids

23. Agneyo Ganguly, Yoandris del Toro

Duany, Dagmar Klostermeier*

WWU Münster / SFB 858 Selective and co-operative binding of nucleotide and

DNA co-ordinated by the latch domain guides DNA

processing by T.maritima reverse gyrase

24. Sabrina Gatzweiler, Katharina Graf,

Verena Göker, A. Stephen K.

Hashmi*

Ruprecht-Karls-Universität

Heidelberg

Dual Activation: a New Concept in Homogeneous

Gold Catalysis

25. Christoph Glotzbach, Roland

Fröhlich, Ernst-Ulrich Würthwein*,

Shohei Saito, Shigehiro Yamaguchi

WWU Münster Oxa-/Aza-Boraphenalenes A Modular Fluorescent

Oligonitrile-Boron System

26. Muxin Han, Bice He,

Guido H. Clever*

Georg-August Universität

Göttingen

Control over the Shape of Coordination Cages by

Ligand Design and Dynamics

27. Johannes Hepperle, Anna Katharina

Bier, Armido Studer*,

Anreas Greiner*

WWU Münster,

Philipps-Universität

Marburg

A New Immobilization Concept For Organocatalysts

By Functionalization Of Polymeric Nanotubes

28. Christine Hofmann,

Peter R. Schreiner*

Justus-Liebig Universität

Giessen

Stereoselective Oxidation of Alcohols using TEMPO-

Peptide catalysts

29. Waldemar Hujo, Stefan Grimme* WWU Münster / SFB 858,

Rheinische Friedrich-

Wilhelms-Universität Bonn

Accurate description of ionic liquids, weak hydrogen

bonds and thermochemistry by dispersion-corrected

density functional theory

30. Yuki Iijima, Ryo Kitaura, Katsuaki

Kawasumi, Kenichiro Itami,

Hisanori Shinohara*

Nagoya University, Japan Bottom-up Fabrication of Graphene Nanoribbons

from Halogenated Aromatic Precursors with

Dnh Symmetry

Poster Contributions in alphabetical order (presenting author’s surname)

Authors Institution Title

31. Katsuaki Kawasumi, Tomonori

Kajino, Kenji Mochida, Yasutomo

Segawa, Lawrence T. Scott,

Kenichiro Itami*

Nagoya University, Japan Direct π-extension of Polycyclic Aromatic

Hydrocarbons by C–H Functionalization

32. Kathrin Benson, J. El-Gindi, Luisa De

Cola, Hans-Joachim Galla*, Nermin

Seda Kehr*

WWU Münster / SFB 858 Cell Adhesion Behaviour on Enantiomerically

Functionalized Zeolite L Monolayers

33. Jennifer Antonia Krings, Bart Jan

Ravoo*

WWU Münster / SFB 858 Light-Responsive Self-Assembly of Silica-

Nanoparticles

34. Sadhana Kumbhar, Frank D. Fischer,

Mark P. Waller*

WWU Münster / SFB 858 Assessment of weak intermolecular interactions

across QM/MM noncovalent boundaries

35. Manik Lal Saha, Jian Fan,

Michael Schmittel*

Universität Siegen Post-Self-Assembly Functionalization of a Trigonal

Nanoprism: Construction of a Cage-like 3D

Framework and Poly-Nanocage Metallodynamer with

Three Correlated Strands

36. Stefanie C. Lange, Bart Jan Ravoo* WWU Münster / SFB 858 Dynamic and Switchable Receptors in Water

37. Matthias Leiendecker, Mahmud

Hussain, Ke Liu, Jason Law, Daisuke

Ito, Stephanie Wang, Andrew Stern,

Stephen Johnston, Gavin Dunn, Yan-

Ling Zhang, Ben Munoz, Stuart L.

Schreiber*, Alykhan Shamji

Broad Institute of

Harvard and MIT

Identification of an allele-selective, small-molecule

inhibitor of the oncogenic ketoreductase activity of

isocitrate dehydrogenase

38. Pavel Lulchev, Agneyo Ganguly,

Dagmar Klostermeier*

WWU Münster / SFB 858 Identifying key residues of functional inter-domain

interfaces and DNA-binding sites in T. maritima

reverse gyrase.

39. M. Mauro, Luisa De Cola* WWU Münster Luminescent Molecular Assemblies Based on Pt(II)

and Ir(III) Complexes

40. Stefan Minkler, Bruce Lipshutz,

Norbert Krause*

Technische Universität

Dortmund

Gold Catalysis in Micellar Systems:

Application in Natural Product Synthesis

41. Kazuhiro Mouri, Shohei Saito,

Shigehiro Yamaguchi*

Nagoya University, Japan Head-to-Tail Cyclic Thiazole Tetramers: Synthesis,

Structures, and Properties

42. Christian Mück-Lichtenfeld*,

Stefan Grimme*

WWU Münster / SFB 858,

Rheinische Friedrich-

Wilhelms-Universität Bonn

Many-body Deformation Densities provide Insight

into Cooperative Non-Covalent Binding

43. Michael E. Muratore, Masaki

Nakajima, Quentin Lefebvre,

Magnus Rueping*

RWTH Aachen Organocatalytic Carbanion Chemistry – Potassium

tert-Butoxide initiated additions of dithianes and

sulfonyl derivatives to styrenes

44. Kristine Müther, Roland Fröhlich,

Christian Mück-Lichtenfeld, Stefan

Grimme, Martin Oestreich*

Technische Universität

Berlin

Characterization of a Ferrocene-Stabilized Silicon

Cation

45. Nicole Nischan, Wiebke

Stahlschmidt, Volker Haucke,

Christian P. R. Hackenberger*

Freie Universität Berlin Chemoselective Lipidation of Azido-Polypeptides by

the Staudinger-Phosphite-Reaction: Inhibition of

Clathrin-Mediated Endocytosis

Poster Contributions in alphabetical order (presenting author’s surname)

Authors Institution Title

46. Pascal Nösel, Max M. Hansmann,

A. Stephen K. Hashmi*

Ruprecht-Karls-Universität

Heidelberg

Dual Activation: Gem-Diaurated Species as

“Instant Dual- Activation” Precatalyts

47. Nuria Ortega, Slawomir Urban,

Bernhard Beiring, Frank Glorius*

WWU Münster Ruthenium-NHC Catalyzed Highly Asymmetric

Hydrogenation of Benzofurans

48. Peter Persich, Kévin Micoine,

Alois Fürstner*

Max-Planck-Institut für

Kohlenforschung Mülheim

The Total Synthesis of Isomigrastatin

49. Markus Plois, Robert Wolf* Universität Regensburg,

WWU Münster / SFB 858

C-H Activation and H2 Fixation by Ruthenium(II)

NHC Complexes

50. Marco Potowski, Markus Schürmann,

Hans Preut, Andrey P. Antonchick,

Herbert Waldmann*

Max-Planck-Institut für

Molekulare Physiologie

Dortmund

Selective Programmed One-pot Synthesis of

Complex Molecules Bearing Eight Stereocenters

51. Helene Reeker, Norbert Krause* Technische Universität

Dortmund

Coinage Metal Catalysis in Target-Oriented

Synthesis Illustrated by the Example of a

C-Glycopyranoside

52. Matti Reißmann, André Schäfer,

Thomas Müller*

Carl von Ossietzky Universität

Oldenburg

Silyl Cationic Frustrated Lewis Pairs –

A Progress Report

53. S.B. Riese, M. Weinhart, D. Gröger,

R. Tauber, R. Haag, J. Dernedde*

Charité-Universitäts-medizin

Berlin

Modulation of L-selectin–ligand interaction via

multivalent inhibitors under flow

54. Christian Rösener, Thorsten

Holtrichter-Rößmann, Johannes

Hellmann, Roland Fröhlich, Birgit

Wibbeling, Werner Uhl*,

Ernst-Ulrich Würthwein*

WWU Münster / SFB 858 Generation of Weakly Bound Al−N Lewis Pairs

by Hydroalumination of Ynamines and the

Activation of Small Molecules:

Phenylethyne and Dicyclohexylcarbodiimide

55. Christian Rösner, Katrin

Schünemann, Carl Deutsch,

Norbert Krause*

Technische Universität

Dortmund

Towards the Total Synthesis of

(+)-Goniothalesdiol

56. Rajarshi Samanta, Jonas Lategahn,

Katharina Kulikov,

Andrey P. Antonchick*

Max-Planck-Institut für

Molekulare Physiologie

Dortmund

Organocatalytic and Metal Free Oxidative

C-H Bond Amination at Ambient Temperature

57. Soumen Kumar Samanta,

Michael Schmittel*

Universität Siegen DABCO as a Dynamic Hinge Between Cofacial

Porphyrin Panels and its Tumbling Inside a

Supramolecular Cavity

58. André Schäfer, Thomas Müller* Carl von Ossietzky Universität

Oldenburg

Silyl Cation Mediated Conversion of CO2 into

Benzoic Acid, Formic Acid and Methanol

59. P. Scharf, F. Winckler, J. Müller* WWU Münster / SFB 858 A metal-mediated base pair with a phenanthroline-

derived ligand

60. Stefanie S. Schilson, Petra Keul,

Michael Schäfers, Bodo Levkau,

Günter Haufe*

WWU Münster New Ligands for Sphingolipid Receptor Imaging

Poster Contributions in alphabetical order (presenting author’s surname)

Authors Institution Title

61. Benjamin Schinor, Günter Haufe* WWU Münster Fluorinated Tranylcypromine Analogues as New

Monoamine Oxidase Inhibitors

62. Birgitta Schirmer, Muhammad Sajid,

Annika Klose, Timothy H. Warren,

Gerhard Erker, Stefan Grimme*

WWU Münster A new persistent N-Oxyl Radical and the

Activation of SO2 – New Activation Reactions

with Frustrated Lewis Pairs

63. Ruth K. Schmidt, K. Müther, C.

Mück-Lichtenfeld, S. Grimme, M.

Oestreich*

Technische Universität Berlin The Danger of Hidden Proton Catalysis with

Strong Lewis Acids in Silylium Ion-Catalyzed

Challenging Diels-Alder Reactions

64. Markus Schmidtendorf,

F. Ekkehardt Hahn*

WWU Münster / SFB 858 Synthesis of Supramolecular Structures containing

NR,NR- and NH,Osubstituted Dicarbene Building

Blocks

65. Nils Schröder, Joanna Wencel-

Delord, Frank Glorius*

WWU Münster High Yielding, Versatile and Practical

[Rh(III)Cp*]-catalyzed ortho-bromination and

iodination of arenes

66. Sören M. M. Schuler,

Peter R. Schreiner*

Justus-Liebig Universität

Giessen

In situ generated dioxirane organocatalysts in

enantioselective epoxidation reactions

67. Zhanhu Sun, Markus Albrecht*,

Roland Fröhlich

RWTH Aachen Amide-functionalized1Quinoline Derivatives as

Receptors for Anions

68. Daniel Thiel, Jan Deska* Universität Köln A Desymmetrization/ Ring Expansion Strategy

Towards Substituted Pipecolic Acids

69. Carlos Vila, Uxue Uria,

Magnus Rueping*

RWTH Aachen Direct azidation of allylic alcohols with TMSN3

70. Raffael C. Wende, Christian E.

Müller, Radim Hrdina,

Peter R. Schreiner*

Justus-Liebig Universität

Giessen

Evolution of Asymmetric Organocatalysis –

Retrocatalysis and the Multicatalyst Approach

71. Thomas Wiegand, Hellmut Eckert*,

Olga Ekkert, Annika Klose,

Muhammad Sajid, Gerald Kehr,

Roland Fröhlich, Gerhard Erker,

Stefan Grimme

WWU Münster / SFB 858 New Insights into Frustrated Lewis Pairs by

Modern Solid-State NMR Techniques and DFT

calculations

72. Marcel Wieteck, Tobias Lauterbach,

A. Stephen K. Hashmi*

Ruprecht-Karls-Universität

Heidelberg

Dual Activation: Gold-Catalyzed Synthesis of

Dibenzopentalenes

73. Nathalie E. Wurz, Frank Glorius* WWU Münster Highly enantioselective intermolecular Stetter

reaction of simple α,β-unsaturated esters –

synthesis of α-chiral γ-ketoesters

74. Weibo Yang, Yang Yu,

A. Stephen K. Hashmi*

Ruprecht-Karls-Universität

Heidelberg

Gold(I)-Catalyzed Novel Rearrangement of 3-

Silyloxy-1,5-enynes: Synthesis of

Benzo[b]furanandBenzo[b]thiophene Derivatives