building better batteries - honeywell...tracking separator (biax) process using quality optimizer 7...
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EMEA HUG – Pulp and Paper / Continuous Web SolutionsBUILDING BETTER BATTERIESPeter DeNicola
September 25, 2019
Honeywell Confidential - © 2019 by Honeywell International Inc. All rights reserved.
LiB energy storage touches many facets of our lives
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Home / Portable Devices
• Mobile phones and tablets
• Laptop computers
• Power and garden tools
• Flashlights, landscape lighting…
Electric Industry / Grid / Off-Grid
• Wind and solar storage
• Home storage, UPS
• Battery Energy Storage Systems (BESS)
Electric Vehicles
• Hybrid and electric vehicles
• Trucks
• Light commercial vehicles, shuttle busses
• Commercial and public transportation
Industrial Applications
• Forklifts and loaders
• Construction equipment and vehicles
• Mining and marine
• Agriculture
Lithium Ion Batteries – enormous growth to meet global needs
Honeywell Confidential - © 2019 by Honeywell International Inc. All rights reserved.
By 2027, total EV battery demand will be 400GWh
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LiB Growth Requires High-Quality Manufacturing Processes
• Global demand driving new LiB plant construction
• Europe has minimal existing LiB production capacity
Honeywell Confidential - © 2019 by Honeywell International Inc. All rights reserved.
Lithium Ion Batteries are critical to Renewable-Energy Solutions
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“Look Inside” – Honeywell QCS integral to LiB ManufacturingQCS in LiB
supply chain• Aluminum rolling
mill – cathode
base
• Electro-deposited
copper film –
anode base
• Biaxial line –
separator film
QCS in LiB
manufacturing
• Anode coating
• Cathode coating
• Pressing
Note:
QCS controls
aluminum sheet
and films used in
solar panels
Honeywell Confidential - © 2019 by Honeywell International Inc. All rights reserved.
Parallel steps for anode and cathode components
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Key Steps in Battery Manufacturing
Final
Assembly
Test
Coating -
Carbon
Coating – Li
Metal Oxide
Mix
Copper foil
Electroplate
or rolling mill
Anode
coating
dual-side
Cathode
coating
dual-side
Aluminum
foil
rolling mill
Coat
drying
drying
Dry
pressing
pressing
Press
slitting
slitting
Slit
Separator
film biaxial
line
Case
Material
Separator
Ceramic
Coating
Winding and
assembly
Separator
film slitting
Critical to Quality
• Coating position
• Coating uniformity
• Coating thickness
• Separator film characteristics
Honeywell Confidential - © 2019 by Honeywell International Inc. All rights reserved.
jumbo rolls
broken down to
cell units here
Aluminum and
copper coils,
separator film
typically
manufactured
offsite and
shipped to
battery
manufacturing
plant
ANODE(-)CATHODE(+)
electrode
coating
pressing
fault detect
slitting
mixing
in b
atc
h/r
oll
un
its
SEPARATOR
ceramic coating
prep
slitting
aluminum foil copper foil
raw
ma
teria
l
Li metal oxide carbon
electrode
coating
pressing
fault detect
slitting
mixing
polymer resin
mineral oil1 2
3
fault detect
biaxial
sheet process
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7
5
6
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Aluminum foil (cathode current collector)
Fixed point MXProLine MetalsMaster with
AGC/AFC
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Copper foil (anode current collector)
Scanning measurement (deposition) or
MetalsMaster (rolling)
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Electrode coating
Subtraction-method coat weight using multiple
scanners
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Biaxial sheet process
Cast/Film measurement MXProLine with Advanced
Profile Control
4
Data historian, process & quality analytics
Tracking separator (Biax) process using Quality
Optimizer
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Ceramic coating
Measure base sheet and ceramic coating using
IR/X-ray sensors
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Pressing
Measure thickness of top/bottom coating after
calendaring
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MXProLine controls inbound metal coils, coating, pressing, and separator film
Continuous Process Through SlittingHoneywell QCS Solution
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Honeywell Confidential - © 2019 by Honeywell International Inc. All rights reserved.
Requirement Honeywell
Scan to both edges and off the edge to precisely determine edge position
for each scanner to compensate MD & CD stretch ✓
1ms sensor response time to precisely measure step change from coated
area and non-coated area ✓
Real-time direct scanner to scanner communication to keep
synchronization during total scan path including acceleration/deceleration
phases to avoid clipping and tracking problems✓
High precision head tachometer synchronization with scanner controller to
prevent position error ✓
High calibration accuracy over a wide range of measurement (no coat, +
one side ~ 100 GSM, + two sided ~ 200 GSM) ✓
Accurately measure both top and bottom coating
✓
Flexible software configuration and tuning tools to keep high performance,
can be done by customer ✓
Honeywell MXProLine QCS operating in LiB Lines since 2001
Anode and Cathode coating are critical manufacturing steps
• > 150 LiB QCS delivered
• Unique measurement and control capabilities
– Sensors
– Control applications
– Quality
– Traceability
Coated
aluminum
Cathode
Coated
copper
Anode
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Honeywell Confidential - © 2019 by Honeywell International Inc. All rights reserved.
Separator film structure critical to electron flow and battery performance
Discrete Assembly into Battery Cells
Battery Structure and Layers: Cathode, Separator, Anode
Separator
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© 2019 by Honeywell International Inc. All rights reserved.
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Typical LiB Coating Line (Anode or Cathode)
© 2019 by Honeywell International Inc. All rights reserved.
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Anode and Cathode Coating Process
Coater
Coater
Dryers
Measure
MeasureMeasure
Measure Measure
Critical to Quality: Coating Thickness, Position, Uniformity
Honeywell Confidential - © 2019 by Honeywell International Inc. All rights reserved.
Thickness Measurement Must Differentiate Coated/Uncoated Areas Precisely
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Coating Patterns Vary by Battery Application
Honeywell Confidential - © 2019 by Honeywell International Inc. All rights reserved.
MXProLine User
Engineering Station
Honeywell solution for Anode and Cathode Coating Lines
QCS Solution for Coating: MXProLine – World’s first IIoT QCS
MD /CDDamper Control
BW, Moi, Crepe, Coord. Speed
Measurement LAN
OPC-DA
Inbound
traffic ONLY
4G Router
Outbound
traffic ONLY
AMQP – Advanced
Message Queuing Protocol
Honeywell
Cloud
Secured Data
Edge Device
- Supports up to 3
Proline servers
https://qcs.demo.dev.connectedplant.honeywell.com
Operator
clients
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Honeywell Confidential - © 2019 by Honeywell International Inc. All rights reserved.
Anode and Cathode use different pressing stations for precise material control
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Pressing Station
Energy density of
electrodes is
determined by the
pressing/compaction
step which impacts
the ohmic contact
resistance and
electrochemical
impedance
Single-point
measurement
provides required
information
© 2019 by Honeywell International Inc. All rights reserved.
13
Typical Separator Film Line
Critical to Quality: Thickness and Porosity
Battery separator film is a non-conducting, porous sheet
inserted between positive and negative electrodes to provide
a chemical barrier but allow passage of electrolytes and ions.
© 2019 by Honeywell International Inc. All rights reserved.
14
Ceramic Coating Process
Critical to Quality: Coating Thickness, Position, Uniformity
MXProLine Ceramic
Thickness
Measurement
Sensor is in
development for
2020 release
Honeywell Confidential - © 2019 by Honeywell International Inc. All rights reserved.
Honeywell QCS ensures high quality LiB components critical to renewable energy growth
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Conclusion
• Demand for Lithium Ion Batteries will continue rapid growth for several years
• Major LiB Manufacturing facilities are under construction or planned, with continued CAPEX investment and expansion strategies
• Honeywell Quality Control Systems (QCS) have been solving difficult measurement and control challenges in several LiB manufacturing processes since 2001
– Aluminum and Copper base films for cathode and anode components
– Battery anode and cathode coatings measurement and control
– Pressing station thickness control
– Separator film production
– Ceramic coating (2020 introduction)
• Honeywell’s QCS 4. cloud-based solution for QCS system health and control performance compliments the on-premise control systems and provides automated monitoring and alerting for the entire enterprise