semspub.epa.gov · case narrative this technical report submitted by etc corporation contains the...

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TECHNICAL MEMORANDUM NO. 2

APPENDIX F

Results of Analyses of Soil Samples Collected from Wells P-2A and LW-4

Volume I: Well P-2A

L

r

I

L

I

I R E. LaMoreaux & Associates

Technical Report

for

CITY DISPOSAL CORP. LANDFILL

Chain of Custody D»t» Required tor ETC Data Management Summary Reports

- •• -' '•• -:-;tS|B2l2,CA»2S3 . 'WMI 405

No.f/apseo s

Company Facility Sample Point Date Time Hours \

Lr

L

LLI

Swep T Dav is

Pr e s i d e n f

CASE NARRATIVE

This technical report submitted by ETC Corporation contains theanalytical results and required deliverables for the samplesidentified as follows:

ETC ID CLIENT ID ETC IP CLIENT IDCA0212 S P2A CA0253 X TRIPBLANK

During the preparation and analysis of these samples, the followingwas observed:

VOLATILES; Tetrahydrofuran was not spiked into the standardsolutions for the five point calibration or the calibration checkduring analysis. However, a qualitative search was performed forthis sample which did not detect Tetrahydrofuran.

ACID/BASE/NEUTRAL: Variable Matrix Spike and Matrix SpikeDuplicate recoveries have been manually verified and may beattributed to the large final volume and matrix interference.

PESTICIDE/PCS: Surrogate recoveries outside of QC limits may be dueto matrix interference. Surrogate recoveries are advisory only.

Spike recoveries for the Matrix Spike and Matrix Spike Duplicateoutside of QC limits may be due to matrix interference.

The sample was quantitated from the primary analysis. In theprimary analysis, alpha-BHC, beta-BHC, delta-BHC, gamma-BHC,Endrin, ODD and Endosulfan sulfate failed percent differencecriteria in the standard at the end of the sequence. Samples ofinterest were not analyzed after the standard not meeting criteria.

In the confirmation analysis, Methoxyclor failed percent differencecriteria in the middle of the sequence... M tibn.wja'L'ir -ivi ?require confirmation in the sample.

Release of the data contained in this hardcopy data package hasbeen authorized by the following signature.

07Ken/Hebel DalzfeVide President of Operations

ETC

CASE NARRATIVE

ETC

METHODOLOGY

ETC

METHODOLOGY

FOR

CLP ANALYSIS OF ORGANICS

The determination of the organics is performed according to USEPAContract Laboratory Program(CLP) Protocol. These methods arepublished in the Statement of Work, "Organic Analysis,Multi-Media Multi-Concentration", 7/87 revisiion.

4

METHODOLOGY

CLP ANALYSIS OF METALS

The determination of metals is performed according to USEPAContract Laboratory Program(CLP) Protocol. These methods arepublished in the Statement of Work, "Inorganic Analysis,Multi-Media Multi-Concentration", SOW 7/87.

Antimony, Arsenic, Lead, Selenium and Thallium are analyzed bygraphite furnace atomic absorption. Potassium is determined byflame atomic absorption and Mercury by cold vapor atomicabsorption.

The remaining analytes are determined by inductively coupledplasma emission spectrometry.

ETC

VOLATILES

ETC

QC SUMMARY

UIAIFP Ull lr t l ILt-. SUk'WGl-.rtTb Rh CGUt- KY

Lab Name: t-~TC Corp . I L a b o r a t o r y l . nn t ra r t :

Lab Code: Case Nn . : SrtS Nr, . : SI Hi Nn

EPrt i siSAMPLE NO . i(i UL J *

- = = = = = = = = = = = 1= = - = = =Uc.''0i4uju i n IBQCx'UlJ14U 1 11LICrtlJ2'7?U 1 V<7QC7UH14U 1 71? *i.:«ui/"7?us i in 3CttU2193UR 1 104

11111111111111111111

sv(.HhB Mf======

1 1 211>

V2VVvv

1 1) u

S'-CDCE J#

1 1 UllJ/VISHv99v

1 1 1 HI- K 1 U 1 1III IT 1

110IJ1IJ0

U I02

II1?060>OB119101. I121}14I1?16I/'IBIV2 u2122232421?26'i7282V3U

page 1 of

51 11UD = loluene-r lB52 ( Hf-8 ) = Bromn f 1 uo robenzene53 (DUE) = 1 ,2-Uich 1 o r oe t h*ne-c14

IJC L in I fSCHH-3 'I Ij )(.86- lib )(/6-114)

# Column to be used to flag recovery values* Ualues outside UC l i m i t sD Surrogates d i l u t e e ) out

I I UUrt -1 1,'B./

8

2BSOIL VOLATILE SURROGATE RECOVERY

Lab Name: ETC Corp. I Laboratory Contract:

Lab Code: Case No.: SAS No.:

Level : CLOU/NED )LOUJ

SDG No,

ERASAMPLE NO.

QC70011VQC70011VBJ1630VCA0212VSCA0212VCA0212URBJ1630VSBJ1630VRQC70011VCA0742VCA0744V

SI(TOD*

971111039210982921001049693

S2(BFB)#

110109114113105107108106988688

S3(DCE)*

1151151029811491104106107104101

.

OTHER TOTOUT

00000000000

010203040506070809101112131415161718192021222324252627282930

page 1 of

51 l TOD -52 CBFB) -53 (DCE) -

Toluene-dSBromofluorobenzenel,2-Dichloroethane-d4

QC LIMITS(81-117)(74-121)(70-121)

Column to be used to flagValues outside QC l i m i t sSurrogates di l u t e d out

9

recovery values

FORM I I VOA -2 1 '87 Rev

UULA1ILE MATRIX SP I Kb.''MAT R I X SPIKh Dl IHL 1 i.:Al t R

Lab Name: tTC Lorp. I Laboratory Lon I- rar t: :

Lab Code: Case No.: SAS Nn . : Si Hi Nn . :

M a t r i x Spike - EHA Sample No.: L;AU'X.53US

: CUMHIJI IND

1 f 1-0 ich loroe t hene1 T r i ch 1 oroe t hene;_ benzene

To 1 ueneCh lorobenzene

!

1 SHlKt1 ADOtf)1 Cur jX I ')

= = = | . = _„<*,=

\ 5U . II 111!1 511.0 II IJ1 'r- It . II II II1 511 . OH II1 •-> IJ . U IJ IJ1

SAMHl ri:UNi.:fcNl RAT ION

( ugXL )

U. UUU

L'I . n u uU . LI 1 1 1 1o . u u oII . U U I J

MS 1CUNI..:fcN 1 RAT I UN 1

(unXLii 1

*1 . X21? 1311.7X0 1J 4 . 8 M X 13 6 . 6 > U 1* (S . 1 4 * 1

1

MS l i.|i: i% i L 1 M i Ts l

RKC * wt-.r. . 1

A J * J - J 41? 16? * xi-iyfiiXU * X 6 - J X X I7} » X6-li)t> 1X2 * 1 X^- 1 ^IJ 1

1 1

,

CUMHOUNU

i 1 . 1-Dich loroe theneTr ich lo roe theneBenzene

1 To 1 ueneCh 1 o robenzene

SHIKh 1 MSDrtUDtl J 1 UJNI»I 1 WA 1 [UN'. uqXL) 1 CugXL. )

511 . OUIJ 1 36 . 65H^U . UUIJ 1 55 . «645U . UUU 1 411 . 36*MJ . UUU 1 44. 25 15 I I . O U O 1 42.747

1

MSI.)"l!

RrC *

-., •

X2SIH985

1% i iji: L

PHD # i RHD

1 5 * 1 1 415 * 1 J '11 9 * 1 1 31 X * 1 1 *

1

Ml IS

R^ C .

n 1 - J 45

X I - '1 '.-' 1 1X6-12XX o L .' ^

•' y" ~ • 1 / 1 1

Column to be used to f laq

Jalue* outside of l i m i t s

and RHD values w i t h an asterisk

'HD: 4 out of ^ outside l i m i t spike Ween <..' ens.-: 4 out of I.IJ outside l i m i t s

nmme n t s:

rURM I I 1 ULIA -1 .1/8 X

10

76SOIL UQLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOUERY

Lab Name: ETC Corp. I Laboratory Contract:

Lab Code: Case No.: • SAS No.: SOG No.:

M a t r i x Spike - EPA Sample No.: CA0212US Le ve 1 : C LOU/MED '> LOW

COMPOUND

1 .1-DichloroetheneTr ich loroetheneBenzeneTo lueneCh lorobenzene

SPIKEADDED(ug/Kg )

50. 00050. 00050. 00050. 00050. 000

SAMPLECONCENTRAT

tug/kg )

0. 0000. 0000.0000.0000. 000

1 MSI ON (CONCENTRATION

1 Cug/Kgi

1 33.8931 40.6611 40.6~7>1 34.3061 43.2301

MS%

REC

68fii816987

I QC(LIMITS

#1 REC.

159-172162-137166-142159-139160-1331

COMPOUND

1 . 1-DichloroetheneTr ich loroetheneBenzeneTo 1 ueneCh lorobenzene

SPIKEADDED(.ug/Kg )

50. 00050. 00050.00050. 00050. 000

MSD 1CONCENTRAT I ON 1

( ug/Kg .1 1

29.641 133.914 135.098 129.406 137.094 1

1

MSD 1 1\ 1 Ji 1

REC #! RPD #i............. |.

59 1 13 168 1 18 170 1 15 159 A* 15 '74 1 15 1

1

1QC LIMITS 1RPD 1 REC. 1

22 159-172124 162-137!21 166-142121 159-139121 160-1331

1 1

# Column to be used to flag recovery and RPD values with an asterisk

* Ualues outside of l i m i t s

RPD: 0 out of 5 outside l i m i t sSpike Recove ry: O/if ou t of 10 outside l i m i t s

Comments: _____

FORM I I I UOA -2 1/87 Rev.

11

4AUULATILt Ml- I HUD Bl ANK SI IMMAWY

Lab Name: K !~C Corp.

Lab Code: Case No

Lab F i l e ID: ) \.:.

Date Analyzed

M a t r i x : I s o i l / w a t e r ) UIA I HK

Inst rument ID: GL/MS C

THIS METHUD HLANK APPL 1H S IU I HE hULLMUJiNG SAMPLES, MS AND

i.jnn t r an t :

SAS No . : SI)!.-; No . :

Lab Samp I e I U : ULVll IJ ] 4U

"I i me «n* lyzed : \<*> 50

1 : ( I nuix'rn«rl ) LI IUI

i EPA i LrtH i LAH i1 SAMPLE NU. 1 SAMPLE ID 1 FILE. IU 11............. |.»». = » »...»„.. ).....««....... |

01 1 1 rAMl'^^U 1 >L6>41ll'2 1 1 1031 1 1U4 1 1 1M1- 1 1 1116 I 1 1U / 1 1 1IIH 1 1 1tiy i i ii u i i iill i i1^1 i i1 31 i i141 1 1i1? i i i161 1 11 /I 1 1i a i i iIV I I I'I U 1 1 1211 1 1V.'J 1 1 I2 .* 1 1 1241 1 121? 1 1 12r, I I I

2 / 1 1 128 1 I 12V 1 I 1.Mil I 1

1" 1 MK 1ANALY/fc U 1

2 1.1 > 6

nmm^n t s:

i -=i q e 1 o fiu ULIA

12

4AUGLA'llLE Mr THUD Bl ANK SUMMARY

Lab Name: ETL. Corp. Con t-r art:

Lab Code: Case Nn.: SAb Nn.:

Lab F i I « ID: >C6>47

D*te Analyzed Ob -'"2 U /8V

M a t r i x : (so i l /uia t e r > UA I E K

Instrument ID: GC./Mb C

THIS MFTHUD BLANK AHHLH-S ID I HE HJLI. UUHNb bAMHLhS, Mb AND MbU:

SDG Nn. :

Lab S^mp ! e ID: IJC/ ' I IM I 4U

l i m e Ana lysed : 1'".

I ^V-IP I : ( I owXmed ) I I.IUI

01D20>U4ObU60-'HHOvin111^1*J 4I1?161 /'1HIV2U21222*2421?262/282v*U

EHASAMPLE NIJ.

LAHSAMPl.t ID

CA02?:5USCAOV7>UH

LAHFILE ID

X'ir, *4H>l .6 >4V

1 1 MtANALYZED

1 3 '/1 4V y

nmrnen t s:

age 1 ofiu UUA i/a/

13

4AVOLATILE METHOD BLANK SUMMARY

Lab Name: ETC Corp.

Lab Code: Case No.:

Lab Fi l e ID: >D6535

Date Analyzed 05/20/89

Matrix: (soil/water) SOIL

Instrument ID: GC/MS D

THIS METHOD BLANK APPLIES TO,THE FOLLOWING SAMPLES, MS AND MSD:

Cont rac t :

SAS No.: SDG No.:

Lab Sample ID: QC70011U

Time Analyzed: 1412

Leve 1 : ( low/med ) LQUI

Commen t s:

010203040506070809101112131415161718192021222324252627282930

EPASAMPLE NO.

LABSAMPLE ID

CA0742UCA0744Y

LABFILE ID

>D6536>D6537

TIMEANALYZED

15291619

page 1 of iFORM IV UOA 1/87

•VOLATILE ORGANIC GC--T1S TUN IMG AMD ;IAS5CALIBRATION - BROMOFLUOROBENZEME (BFB.'

Lab Name:ETC Corp. I Laboratory Contract:

Lao Code: Case No.: SA5 No.: SDG No.:

Lab File ID: XC6270 BFB Injection Da t e : 05 -• io/ S'-

Instrument ID: GC-'MS C BFB I n j e c t i o n Time:0955

Ma t r i x : '. so i 1-'wa t e r ) WATER Leve 1 : ' 1 ow>'med ) LOLJ Co 1 umn : i. pac^ -- cap

Im -•' e

50759596173174175176177

ION ABUNDANCE CRITERIA

15. 0 - 40. 0% of mass 9530.0 - 60.0% of mass 95Base peak, 100% relative abundance5.0 - 9.0% of mass 95Less than 2.0% of mass 174Greater than 50.0% of mass 955.0 - 9.0% of mass 174Greater than 95.0%. but less than 101.0% of mass5.0 - 9.0% of mass 17o

S RELnTIUE I1 ABUNDANCE I

1 24.7i 52. 01100.0I S.Ii o.o c1 91.21 6.5',

1741 37.3 t1 6.2 C1

1111

0. OU 11

7.1)11Q5 . 7 ) 1 I7.1)21

11-Ualue is % mass 17-4 2-Ualue is % mass 176

THIS TUNE nPPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, HND STANDARD'

0102Q3040506O"703O'51011;2171-*1 CA. -

lo] -L3i ?••i |T

2 1^ •"!

ERASAMPLE NO.

LAB i LAB 1 DATE I TIMESAMPLE ID 1 FILE ID 1 ANAL VIED 1 ANALYZED

= «, = ..»,»« = = »= | =,, = »« = = , = = = = = !=, = = = = =. = = =!= = = =«=« = = = = =

QC70012US 1 >C6271 1 05-' ID ••"39 1 1142QC70012'.)S 1 -C6272 i 05," 10- 3'' i 123-*QC70012US 1 >C6273 ! 05 -'iD /a* | 132&QC70012US 1 .-C6274 i G5/16--3* ' 1-*19QC70GUS 1 >C6275 1 05, -16/89 1 1511

1 i i1 1 11 ! '1 1 11 i !1 1 11 : I1 1 1I ! i1 1 ii 1 !1 1 1! 1 i1 > :i i II i ii I :

paq* FORM '.> UQA16

5AUOLATILE ORGANIC GC/MS TUNING AND MAS';CALIBRATION - BROMOFLUOROBENZENE '.BFB;

Lab Name: ETC CORP

Lab Code: _____

Lab F i l e ID: >C6330

Case No.:

Con tract :

SAS No.: SDG No.:

BFB Injection Date: 05/19/89

;____ SFB Injection time: 08:58

Ma t r i x : C s o i 1 /wa t e r ) U/A 7S&. Leve 1 : ( 1 o w/nrted ) Lold Co 1 umn: Cpack/cap) pack

I n s t r u me n t ID.:

m/e

5075959617?1741751761"7

11 ION ABUNDANCE CRITERIA]= = = = = = = = = = =.=« = = = = =::» = »= = = = = = = = = = = = = = = = = = = = = = = = = = :« = = » = = =

1 15-40% of mass 95------------------------------ — ---1 30-60% of mass 95-- ——— _ _ _ _ _ _ _ _ _ _ — _ — ___ — _ _ _ _ — ___1 Base peak, 10 OS relative abundance------------------1 C^ LJUr' J-lf" rt-^t^— OC^

1 Less than 2% of mass 174--------------- — __-____----1 Greater than 50 'i of mass 95-------------------------1 5-9% of mass 174--- — - ———— _ —— - — -_ —— —— — ———— ---1 95-101% of mass 174-------_--__---------------------1 5-9% of mass 176------------------------------------1

% RELATIVEABUNDANCE

O (1 Q

53.3100.08 s,

0. OC 0.093.37. 1 ( 7.6

O Q <-. t O _t 1

6 . 7 C 7.5

1I

-= 1I1I1

) 1 11

) 1 1i I \V2 !

11-Ualue is % mass 174 2-Ualue is % mass 176

THIS TUNE APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:

0102030-i050607OP09101112131-4

15161718192021

l =I

EPASAMPLE NO.

LABSAMPLE ID

A6 70oi<4 1/£Ac7t>l>m-vcAa<t*r\/

LABFILE ID

> C 6$ 3 }> £ f, *J3-

•? C. / 3 J \

DATEANALYZED

0S//1/tf

—ir->L-

TIME IANALYZED I= = = = = = = = = |

to; 1 1 i/[. '-a- I/ i - /D I

IiI!IIIIIIIIIIIIIII

paqe i- °* f- FGRM U UOA 17 1x87 REU

5 AUOLATILE ORGANIC GC.-T1S TUNING AND MASSCALIBRATION - BROMOFLUOPOBENZENE ;SFB)

Lafc Name: ETC CORH

Lab Code: _____. Case No. :

Con trac t :.

SAS No.: SDG No. :.

Lab F i l e ID: ~> Co7^-

Instrument ID.: __ cMa t r i x : ( so i 1 /uia t e r )

• BFB I n j e c t i o n Date: 05--'20--'S9

SFB I n j e c t i o n t i m e : 0^:55

Leve 1 : ( 1 ow/med ) L SMJ Co 1 umn : t pack--'cap > pack

m/e

5075o cO JL

I ~*"

174175176177


15-4054 of mass 95-----------------------------------30-60?i of mass 95-----------------------------------3ase peak, 10 OS r e l a t i v e abundance------------------5- 'i of mass 95-------------------------------------Less than 2% of mass 174----------------------------Greater than 50% of mass 95-------------------------5-'?% of mass 174------------------------------------9^-101'i of mass 174---------------------------------5-'?% of mass 176 ------------------------------------

S RELAn

ABUNC'i-

oo •»

49.2i U 0 . 06.60. 0(,

QQ r\7. Q(

36.415.9C

' I 'JEHi^JCE

0.0)1

~? O 1 '

O ~ ? I l l

6.9i !•

1-Ua'lue is >t mass 'i">4 l-'Oa'iue is S mas^s 'i -b

THIS TUNh APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS;

1 EPA

i SAMPLE NO.i = = = = = = = = = = = =

01 102 i03 10« :0 5 1On 1

0 7 1

Ot: i09 11 0 !

11 11 • ' 1

13 1141

15 116 l171It: i; 9 i

20 121122 l

LABSAMPLE I D

£c ?voi<lc£&c ~?ooi(J.UZAozsiVS£>4nijrj Vtf-

1

LABFILE ID

> C 6?4-6' C £*<t~l

7 C £34S>:> r /J34-7

DATE 1 TIME 1ANALYZED 1 ANALYZED l. = = :, = :.*.:,:, = :.=:= = = = = |

Affal '81 | / C - : a < ? iI 1 0 : .1 S~ 1

1 / 3 - -3~ ) :^ 1 y 4 : a 7 l

l l1 11 iI :l :l il il iil ii ;I !l :1 ll il l1 !

1 1

page o f FORM 'J 'JOA l-'S

18

5HUOLATILE ORGANIC GCxMS TUNING AND MASSCALIBRATION - BROMOFLUOROBENZENE CBFB)

Lab Name:ETC Corp. Contract:______

Lab Code: _____ Case No.: ____ SAS No.: _____

Lab File ID: >D6510 . BFB Injection Da t e: 05x18/89

Instrument ID: GCXMS____ BFB Injection Time:2006

Mat r ix : (soi I/water ) SOT\._, Leve 1 : C lowXmed ) LOW Co lumn : (pack/cap ) PACK

SDG No.:

m/e

50759596173174175176177


15.0 - 40.0% of mass 9530.0 - 60. OS of mass 95Base peak, 100S relative abundance5.0 - 9. OS of mass 95Less than 2 . OS of mass 174Greater than 50. OS of mass 955.0 - 9. OS of mass 174Greater than 95. OS, but less than 101. OS of mass 1745.0 - 9. OS of mass 176

S RELATIUEABUNDANCE

32.358.8

100.05.80.0 ( 0.0)193.46.9 ( 7.4)192.8 ( 99.3)18.2 ( 8.9)2

1-Ualue is \ mass 174 2-Ualue is S mass 176


page

ERASAMPLE NO.

LABSAMPLE ID

LABFILE ID

I DATEI ANALYZED

TIME IANALYZED I

0102030405060708091011121314151617ia19202122

QC70011USQC70011USQC70011USQC70011USQC70011USQC70011U

>D6511>D6512>D6513>D6514>D6515>D6516

•

05x18x8905x18x8905x18x8905x18x8905x19x8905x19x89

204921372224231200000048

of I FORM U UOA 1---87 Re*.19

5AVOLATILE ORGANIC GC/MS TUNING AND MASSCALIBRATION - BROMOFLUOROBENZENE IBFB)



Lab File ID: >D6517 BFB Injection Date:05/19/89

Instrument ID: GC/MS____ BFB Injection Time:Q94l

Mat P ix : (so i I/water ) S< i! L- LeveI:(1ow/med) LOUi Co lumn :( pack/cap ) ?ACK

SDG No.:

m/e

507595°,^173174175176177

11 ION ABUNDANCE CRITERIA

1 15.0 - 40. OS of mass 951 30.0 - 60. OS of mass 951 Base peak, 100S relative abundancei, 1.0, - 9 ,QX a€ m«A 951 Less than 2 . OS of mass 1741 Greater than 50. OS of mass 95I 5.0 - 9. OS of mass 1741 Greater than 95. OS, but less than 101. OS of mass 1741 5.0 - 9. OS of mass 1761

\ RELATIVE -ABUNDANCE

24.858. 1100.07.60.0 (

98.98.2 (

0.0)1

8.3)196.6 ( 97. 7U5.8 ( 5.9)2

1-Ualue is \ mass 174 2-Ualue is S mass 176

THIS TUNE APPLIES TO THE FOLLOW ING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:

01020304050607080910111213141516171819202122

EPASAMPLE NO.

LABSAMPLE ID

QC70011UQC70011USBJ1630UCA0212USCA0212UCA0212URBJ1630USBJ1630YR

LABFILE ID

>D6519>D6520>D6522>D6523>C6525>C6526>C6527>C6528

DATEANALYZED

05/19/8905/19/8905/19/8905/19/8905/19/8905/19/8905/19/8905/19/89

TIMEANALYZED

11411230143115201739182719142002

page V ot- FORM U UOA 1''87 Rev,

5AUOLATILE ORGANIC GC/MS TUNING AND MASSCALIBRATION - BROMOFLUORGBENZENE CBFB)



Lab File ID: >D6532 BFB Injection Da t e: 05/2 G''89

Instrument ID: GC/MS____ BFB Injection Time:0949

Mat r ix : (so i 1/water ) Sol U Leve 1 : ( 1 ow/med ) LOW Co lumn : C pack/cap ) "PACK

3DG No.:

m/e

50759596173174175176177


15.0 - 40. OX of mass 9530.0 - 60.0% of mass 95Base peak, 100S relative abundance5.0 - 9. OS of mass 95Less than 2.05* of mass 174Greater than 50.0% of mass 955.0 - 9.0% of mass 174Greater than 95.0%, but less than 101.0% of mass 1745.0 - 9.0% of mass 176

% RELATIUEABUNDANCE

28.456.7100.07.31.1 ( 1.3)1

89.47.2 ( 8.0)1

86.8 ( 97.0)15.2 ( 6.0)2

1-Ualue is % mass 174 2-Ualue is % mass 176


01020304050607080910111213141516171819202122

EPASAMPLE NO.

LABSAMPLE ID

QC70011USQC70011UCA0742UCA0744U

LABFILE ID

>C6533>D6535>D6536>D6537

DATEANALYZED05/20/8905/20/8905/20/8905/20/89

TIMEANALYZED

1031141215291619

page of I FORM O UOA 1--87 Rev.

ETC

SAMPLE DATA

22

1AUOLHTILE ORGAN ICS ANALYSIS DnTA SHEET

ERA SHMPLE NO.

Lab Name: ETC Corp.

Lab Code: Case No. :

Con tract

SAS No. SDG No

M a t r i x : C so i 1 --'wa t e r ) SOIL

Sample wt/'^ols 5.0 (g.'mL) G

Level: UoWmed) LOW

Ji Moisture: not dec.

Column: (.pack/cap) PACK

Lab Sample ID:

Lab F i l e ID: >C6525

Date Received: OS/ 3/

Date Analyzed: 05/19/89

D i l u t i o n Factor: 1

CAS NO. COMPOUNDCONCENTRATION UNITS:(uq/L or uq/Kg) UG/KG

74-87-3---------Chloromet hane____________74-8?-9---------Bromome thane_____________7?_01-4---------Uinyl Chloride___________75-00-3---------Chloroethane_____________75-09-2---------Methylene Chloride_______67-64-l---------rtcetone__________________75-15-0---------Carbon Disulfide_________75-75-4---------1,1-Dichloroethene_______75-34-3---------1,1-Dichloroe thane_______540-59-0 — --———1, 2-Dichlorethene (total ).67-66-3---------Ch1oroform_______________107-06-2--------1,2-Dichloroethane_______78-93-3---------2-Butanone_______________71-55-6---------1,1,1-Trichloroet hane____56-27-5---------Carbon Tetrachloride_____108-05-4--------Uiny1 Acetate____________75-27-4---------Bromodichloromet hane_____78-87-5---------l,2-Dichloropropane______10061-01-5------Cis-1,3-Dichlorop ropene__79-01-6---------Trichloroethene__________124-48-l--------Dibromochloromet hane_____79-00-5---------l,l,2-Trichloroethane____71-43-2---------Benzene_________________1 006 1 -02-6------trans-1,3-Dichloropropene.7I?-25-2---------Bromot:or m________________108-10-1--------4-Methyl-2-Pentanone_____591-78-6--------2-Hexanone_______________127-18-4--------Tetrachloroethene________79-?4-5---------l,l,2,2-Tetrachloroethane_108-88-3--------To luene__________________108-90-7--------Chlorobenzene____________100-41-4--------Ethyl benzene_____________100-42-5--------Styrene__________________1330-20-7——————Xylene (total )__________

I 10I 10I 10I 10I 10113151515151515I 101515I 10151515151515151515I 10I 1015151515151515

23FORM I UOA

Q

IIDIUIUID

IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUI

1/87 Rev.

VC* 2

6-66-60T

tztrrmv tatmMoYT

IEVOLATILE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

TENTATIVELY

Lab Name: tTC C^(^>Lab Code: Case No.

Matrix: (soil/water) $ar<-

Sample vt/vol: 6 (

Level: (low/med) L.OW

% Moisture: not dec.

Column: (pack/cap) PAcK

IDENTIFIED COMPOUNDS | |1 1Contract : | i

: SAS NO. : SDG No. :

Lab Saaple ID: Cj^o.2.|£Ly

«/BL) <£? Lab File ID: > c dfS^SDate Received: oe/is/s^

Date Analyzed: o-s//^y^9

Dilution Factor: [

Nuaber TIC* found:CONCENTRATION UNITS:(ug/L or uq/Kq)

CAS NUMBER

1.2.3.4.5.6.7.8.9-

10.11.12.13.14.15.16.YJ.18.19.20.21.22.23.24.25.26.27.28.29.30.

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REFERENCE STflNDBPD 'SPECTRUM; n 14 •' Ett: Pfc

1 100k

111

SAMPLE

!ii 42

!1

•SAMPLEi F 1 1 * fj Bpt fib

! 4*

1

~ i * 9 7 T ar q * t p « f « r 4 r, c « ~, p * .: t - *0009 Npri MOM

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SPECTRUM ^ BACKGROUND SUBTRACTED*

.1 1

- i 3? '/ xJ1,-,],! .ii, ,/, , . ;Afj ft^ l£0 loO cO?

SPECTRUM • UNALTEPED.1

C652E cIFB'VOfi 5. 19 39 D CfleeiiV ,aV78eil ,i : :Mo .5 , ,69643

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£59 [

i , ''*-*

Scan ££9i9 . '? 8 rn in.:

(-180r

£59 [ |

£40

Data F i l e : Cc. = 2?: : JOName: 2 I F3 • UGn ? I1? -'S'5 DM i sc : C.H02 12',' , QU^Q 0 11 , '=.: : Mb , ?•Quan r Time: 3° 0?19 IS : 2 0Injected at: 3* 0 ?i Q 1 : 3 9

Compound Mo: "Co mpo u n d Name : HC e to neScan Murnber : 22°Re tent i on T i rue : 9 . 9S m i n .Quan • lot-, : 43 . 0 •urea : °Oo7Concentration: 62.6° NGq-'-.-'a 1 ue : ^2

Quant Output r i l e : 'D* F 2 5: :US

Quant ID File: IDlOlo::USuast Calibration: S90?l° 1?:01

29

Film >C65£3 SirSxVCS 3'"13x8? u CSSSlcV ,aV73611 ,3 i i?16 ,G , , 3c«n 78p!s fib 9999 SUB NRtt 1.27 ain.

11086-1"

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Data File: >C6?2?::UOName: 2IFBX'.'QA 5x19x99 DM:sc Data: CAQ212'J,QU700H ,S: : M6 ,5 , ,RT (rnin): 1.77Scan: 7Area: 1?7/15?19 Rank: 1Semi-quantitative Cone (uncorrected): 9 0.7? NGSemi-quantitative Cone C corrected ): 1989.1? ugxkgCalculated uaing !atd: Bromochloromethane g 12.99 minutes

No PBM hits for this scan.

30

IPUOLATUE UWi-iANir.S ANALYSIS DA I A SHkt f

EHA SAMPLE NU.

Lab Name: ETC Corp.

Lab Code: Case No.:

Matrix: (soil/water) UAVbW

Sample wt/vol: b.O (g/mL) ML

Level: (loui/medJ Li IUI

X Moisture: not dec.

Column: (pack, /cap) PACK

CAS NL). CUMHUIJND

Contract: I___

SAS No . : SDL^ No . :

Lab Samp Ie ID:

Lab F i l e ID: >C6.*41

Uate Weneivnd:

L)a t e Ana 1 yzed :

L) i I u t ion Factor: 1

CUNCEN1kAl1GN UNITS:(ug/L or ng/KgJ Ula/L

74-87-3---------Ch1oromethane____________74-H 3- v------_--b)romome t hane_____________75-01-4-——----Uinyl Chloride___________/"7-00-J---------Ch loro«t hane_____________75-09-2---------Methylene Chloride_______(S7-64- l---------Ac«tonff____________________75-15-Q---------Carbon Disu1fide_________75-35-4---------1,1-Dichlornet hene_______7H-34-3--———--1,1-Uichloroethane_______540-'?9-0--------1 ,2 - [) i c h lorethene ( tota 1 ).67-66-3---------Chloroform_______________107-116-2- — -----1 ,2-Uinh I o roe than*_______7K-93-3---------2-But anone_______________71-55-6---- — ---1 ,1 , 1- l> ichloroethane____56-^5-5---------Carbon Tet rachlor i de_____I I.I8-H5-4--- — ---Uinyl Acetat«____________7*?-27-4---------blromnd i ch 1 o rome t han»_____78-87-5--------- 1 ,'i'-Dich ] oropropanw______10061-01-5--—--cis-1,3-Uichloroprop-ne__79-01-6--- —— --- ("rich loroethene__________124-48-l--------Dibromochlorom*thane_____79-UO-1?--- ——— --1,1,2- I r ichlorowthane____71-43-2 — — - —— -benzene_________________10061-02-6------trans-l,*-Uichloropropp!ne.75 - 2 *» - 2 - - - - — — - - - H r o mn f o r m________________108-10-1--- —— --4-Methy l-'^-Hentanon-_____591-78-6--------2-Hexanone_______________127-18-4--------letrachloro«thene________79-34-5---------l,l,2I_-1etrarhloroethane.1M8-H8-3----- — -lo luene_________________inn-90-7--———-Chlorobenzene____________

100-42-5--———-Styrene__________________1330-70-7——————Xylene t tota 1 )__________

I D1 I)1(11 II

<?1 Ub«?b*>bb1Ub"•>J IIb••>b

bbb^'I U1 Ubb•?b•?b"9

F I I K M 1o

1/H/

VOUTILf IFA SAIOU NO.

colon i

109-99-9 Tetrahydrofuran.

^-gV/i/.j*?'

I gJ-/v?AP7

1/S7 Mv.

32

/—v

Lab Name:,Lab Code:

IEVOLATILE ORGANXCS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS

Contract:.SAS No.:

EPA SAMPLE NO.

Case No.: SDG No.:

Matrix: (soil/vater) yjArtft.

Sample wt/vol: S fq/BL) ML

Lav«l: (low/mad)

% Moistura: not dae.Coluan: (pack/cap) PACK

Number TIC» found: I

Lab Sample ID:

Lab Pila ID:Data Racaivad:

Data Analyzed:Dilution Factor:

CONCENTIUTION UNITS:(ug/L or uq/Kq) < /c

CAS NUMBER

1.2.3.4.5.6.7.t.9.

10.11.12.13.14.15.\A^17.It.19.20.21.22.23.24.25.26.27.28.29.30.

•

COMPOUND NAME

£a*£er»\ 0/Jtnfi'*&

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RT

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EST. CONC.

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FOXN Z VOA-TIC33

1/17 Rev.

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138888-

120008-

100808-

?9999-

80800-

78800-

68080-

seaea-40088-

30888-

20088-

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Data File: >C6?41::UOName: IFB/UOA 5x19/89 CMisc: CA0253U,QU7014U,L:ri6 ,5, ,

Id File: I CIO 17: :UST i t l e : IFBLast Calibration: 890519 11:02

Operator ID: GM6356Quant Time: 890519 21:17Injected at: 390519 20:36

Quant Output File

34

QUANT REPORT

Operator ID: GM6356Output File: ^C6341::AQData File: >C6341::UOName: IFB/'UOA 5/19.--89 CMisc: CA0253U,QU7014U,L:M6,5 , ,

ID File: IC1017::UST i t l e : IFBLast Ca l i b r a t i o n : 890519 11:02

Compound

Quant Rev: 7 Quan t T imeInjected at

Di lut ion Factor

Page 1

890519 21:17890519 20:36

1.00000

R.T. Scan* Area Cone Units

1) *Bromochloromethane13)15)29)

1,*1,*Ch

2-Dichloroethane-D4 CSURR)4-Di f luorobenzeneIorobenzene-d5

13152323

.21

.99

.39

.57

309380569700

7468794874343932250983

250227250250

. 00

.85

.00

.00

NGNGNGNG

92369392

38) p-8romof1uorobenzene CSURR)

* Compound is ISTD

35.03 866 152333 230.22 NG 94

35

Til* >C634l irB'VOO 5^19."89 C . C00253V .QV7014U ,L :M6 .5 , , Scan 15Bpk flb 9999 SUB NRM 1.70 mm.

11000-

18800-

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7888-

6888-

5888:

4088-

3000

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J

44

85 90, / / X

50 68 78 80 90 180

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Data File: >C6341::UOName: IFB/UOA 5x19x89 CMisc Data: CA0257U .QU7014LJ ,L: M6 ,5 , ,RT (mm): 1.70Scan: 1?Area: 22397064 Rank: 1Semi-quantitative Cone (uncorrected ): 11674.50 NGSemi -quan t 11 a t i ve Cone <. corrected ): 2334.90 ugxlCalculated using Istd: Bromochloromethane @ 13.21 minutes

No PBM hits for this scan.

36

ETC

STANDARDS DATA

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fitle: THFCalibrated: 890615 17:04

Files: >C627S >C6274 K62H >C627V >C6271RF Rh Rr RF PF __ _

Compound 1UU.UII 'rtll.UU 5UO.UI1 75U.UU 10UO.U KKI KF X WSU

Tetrahydrofuran .ibflS* .JOAVl .>26i!/' . 64; . 114 1.U6B

Rf - Response Factor (Subscript is anount in Ijtj)

RKT - Average Relative Retention hue (RT Std/RT Istd)

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WSO - Percent Relative Standard Deviation

Page 1 of 1

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QUANT REPORT Page 1

Operator ID: JM3343 Quant Rev:Output F i l e : -C6275::AQData File: >C6275::UOName: UQA 5/16/89 Cflisc: QC700US,QU70012,L:M6,5 , , 2 UL SPIKE

7 iJi-La_ri.t. 1 i. me.:Injected at

D i l u t i o n Kactor

ID F!le: IC1016::UST i t l e : IFB'_ast C a l i b r a tion: 890516 16:.

890516 15:111.000:.: :.i

Compound R . T . Sc a n # Area Cone Un i t s

112)3)4)

^5-6)•7 >3)9)10)11 '•12)13 >14)15 '16)17)IS)18 !19.)2 0 '2 1 )•32 :'3)

24 i25)26 :•27)28 '29.'30 >31)32 '333435363738.'39 )40 J41)

*Bromoch loro me thaneMe t hy 1 c h l o r i d eMe t hy 1 brom i deU i ny 1 ch 1 o r i deCh 1 o roe t haneMethylene chlorideAce t oneCarbon disult'ide1 , 1-Dich loroethylenei,l-Dichloroethane1 ,2-Trans-d ich loroethyleneCh loro form1 ,2-0 ich loroe thane-D4 ( SURR )1 ,2-Dich loroe thane

* 1 , 4-D i f 1 uorobenzeneMethyl ethyl ketone1,1,1-TrichloroethaneCarbon t e t rach lor i deCarbon t e t r ach 1 o r i deU i n y 1 acetateDich loro bromo methane1 , 2 - D i c h loropropanec is-1 ,3-Dich loropropyleneTr ich loroethyleneCh lorod ibromornethaneBenzene1 , 1 ,2-Tr ich loroethanetrans-1, 3-D ich loropropyleneBr omo f orm*Ch Iorobenzene-d5Me t hy 1 - i so-bu ty 1 ketone2 - He x a n o n e1 , I ,2 /2-Tet rach loroethaneTet rach loroethyleneToluene-D8 (SUPR)To 1 ueneCh 1 orobenzeneE t h y 1 b e n z e n ep-Bromo f 1 uorobenzene (SURR)S t y r e n em-Xy leneo+p-Xy 1 enes

13.2 .4.f.•79 .10.11.12.14.14.15.16.16.23.15.17.17.17.17.13.19.19.20.21.20.21.21.23.28.24.25.26 .25.27.27.23.31.35.37.37.39.

219933393488554970117740031539955248878334719441129220207954186703940932693608155911

309489512215V22424126529633234936538138456937941941842842744U4754814935115065135135797fjO58962763663466366970477286''920931970

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Quan t Rev: rOperator ID: JM3343Output File' "Co'.'' 74: : rtQData File: >C6274::UO-larr.e: UO^ 5-'l6''S9 CMisc: QC70012US.QU70012,L:M6,5,, 5 UL SPIKE

ID F i l e : IC1016::UST i t l e : IFBLa:t C a l i b r a t i o n : 890516 16 = 4?

'.Juan t "i • me :i njected at:

D i l u t i o n Factor:

Page 1

SQ!'-16 16 :r-:.'8 9 M 516 14 : 1 <*

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1 )2 ,ij. )4 >5 )

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3 .'9 i1 0 )11 <12;13 •1^+ )15 i16)17'18)18 -'19 ;i20 ::21)22 '•'2 "*> )•s^ ,25 i2fc .12.7;,V !-' ":

29)30 •31 )." l' !33)3-4 '7.5 j3o37j38 '39 )40 >4 1)

* B r o mo c h lororne thaneMe t hy 1 c h l o r i d eMethyl bromideU i n y 1 chlorideCh 1 o r oe t haneMethylene c h l o r i d enee t oneCarbon d i s u 1 f i d e1 ,1-D ich loroethylene1 , 1-0 ich loroethanel,2-Tran5-dichloroethyleneChloroform1 ,2-Dich 1 or oe thane-D4 CSUrVk .11 , 2 - u i c h loroethane

* 1 ,-*-Di f luorobenzeneMethyl ethyl ketone1 , 1 , 1-Tr ich loroethaneCarbon t e t r ach 1 o r i deCarrion t e t r a c h l o r i d eU i n v 1 acetateC1 1 c h 1 o r o b r o mo me t h a n e1 , 2 - D i c h 1 o r o p r o p a n ec is-1 , 3-D ich loropropyleneTr ich loroethyleneCh lorodibromornethaneBenzene1 , 1 , 2- Tr i ch 1 o r oe t hanetrans-l,3-DichloropropyleneBromo form

*Ch Iorobenzene-d5Me khyl- isQ-butyl ketone2-Hexanonei , 1 , 2 , 2-TetrachloroethaneTet rach loroethyleneTo ! uene-D8 ' SURf? )To lueneCh 1 o robenzeoeE t h y 1 b e n z e n ep-Bromo f 1 uorobenzene C SUPR )S t y r e n em-Xy 1 eneo +p-Xy 1 enes

13.3 .4 .c _7.9 .10.11 .12.14.14.15 .15.16.23 .15.17.17.17.17.18.19.19.20.21.20.21.21.•-it, _28.24.25.26.25.••p 71

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QUANT REPORT

Quant Rev: 7Operator ID: JM3343Output F i l e : -C6273::AQData F i le : > C 6 2 ? 3 : : U GName: 'JOft 5-'16.--'89 Criisc: QC70012US,QU70012,L:M6 ,5,, 10 SPIKE

ID F i l e : IClDlo::UST i t l e : 1FBLast C a l i b r a t i o n : 390516 16:47

Quan t T i m e ;Injected at

D i l u t i o n Fac t o r:

Page 1

890516 16:5489051o 13:2o

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* 1 , 4- D i f luorobenzeneMe t h y 1 ethyl k e t o n e1 ,1 ,1-TrichloroethaneCarbon t e t r ach 1 o r i deCarbon tetrachloride'-.' i n • .1 1 a c e t- a t eUmyl acetateD i " h 1 o r o b r o mo r.ie t h a n e1 , 2-Dichloropropanec i s. - 1 , 3-D ich loropropyleneTr ich loroethyleneCh iorod ibro rno me thaneBenzene1 . 1 , 2 - T r ich Ioroethanet rans-1, 3-D ich loropropyleneBra mo form*Ch Iorobenzene-d5Me f hyl - »so-butyl ketone2-Hexanone1,1 ,2 , 2 - T e t r a c h 1 o r o e t h a n eTe t r ach loroethyleneToluene-DS ( SU^R >To lueneCh ! or o benzeneEthylbenzenep-Sr orno f 1 uo ro benzene (SURR )S t y r e n em-' •'. v1 1 ene

13.3 .4 .5 .•79.10.11.11.12.14.1-4.

15 .16.16.23.15.17.17.17.I"1.17.18.19.19.20.21.20.21.21.9-128.24.25 .26.25.27.27.23.31.35.37.37.

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QUrtNT REPORT Page 2

Operator ID: JM3743 Quant Rev: 7 Quant Time: 390516 16:54Output F i l e : ^06273: : rtQ Injected at: 3'? 0516 17:26Data F i l e : >C6277::UO D i l u t i o n Factor: 1.00000Name: UOA 5/16/89 CMisc: QC7G012US,QU70012,L:M6,5,, 10 SPIKE

ID File: IClOlo::UST i t l e : IFBLast Cal i b r a t i o n : 890516 16:4?

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QLlHNT REPORT Page 1

Operator ID: JM3343Qu * p u t F i l e : "'C6 2 72 : : ttQOat a Fi le : > Co'272: : UO^ame: UOn 5'''l6-'89 Cdisc: QC70012US,QU70012,L:M6,5,, 15 SPIKE

I D F i 1 e : I C1 0 16 : : UST i t l e : IFBLast C a l i b r a t i o n : 890516 16:47

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* B r o mo c h loromethaneMethyl chlorideMethyl bromideUinyl chlorideCh 1 o roe t haneMethylene chloridertce t oneCarbon d i s u l f i d e1 , 1 - D i c h 1 o r o e t h y 1 e n e"1 , 1 -TJ i c h "1 o r o e t h a n e1 , 2 - T r a n s - d i c h 1 o r o e t h y 1 e n eCh 1 o r o f o r m1 , 2-Dich loroe t hane -04 ', SURR ')1 ,2-Dichloroethane

* 1 , **- 0 i f luorobenzeneMethyl ethyl ketone1,1,1-TrichloroethaneCarbon t e t rach 1 o r i deCarbon t e t rach 1 o r i deU i n y 1 acetate'.'ir.yl ace-, ateL i c h 1 o r o b r o mo me thane1 , 2 - D i c h 1 o r o p r o p a n ecis-1, 3-D ic h loropropyleneTr ich loroethyleneCh 1 o rod i b r omome t haneBenzene1 , 1 ,2-Tr ich loroethanet r a n 3 - 1 , 3 - D i c h loropropyleneBr orno form

* L h i o r o b -. n z e n e - d 5Me t h y 1 - i 3 o - b u t y 1 ketone2 - H e x a n o n e1,1,2,2-TetrachloroethaneTe t rach 1 o r o e t h y 1 e n eToluene -08 (.SURptTo 1 ueneCh 1 or obenzeneE t h y 1 b e n r e n ep - B r o mo f 1 u o r o b e n z e n e <• SURR )S t y r e n ern-Xy 1 eneo +p-Xy 1 enes

R.

13.3.4.5.7 .9 _10.11.12.14.14.15.16.16.23.15.17.17.17.17.17.18.19.19.20.21.20.21.21.•~>T28.24 .25 .26 .25..-1 —iJ- / •

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31050971241 6 Li2252-4426529637234«36538138356*3804lv4194'2v41942^-+4047543149351150651451358069'=53962^63763k663669^03"77' '806919930962

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7350314767342531SC35340751306347111123995^:1062-94005P44702t:r.90464494412?4125607653229782VH59

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250.748.703.739.734.718.654.767.74* .763.742 .738.26^ .757.250.736.73 a.95.

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Data F i l e : ,C6271::UOName: UOtt 5X16/89 CM i s e r QC niJ012US,QU70012,L:H6,5, , 20 UL SPIKE

Id File: IClOlo::UST i t l e : IFBLast Calibration: 890?16 16:47

Operator ID: JM37-4?Quant Time: 890516 16:53Injected at: 890516 11:42

Quant Output F i l e : /XC6271: : AL|

49

QUANT REPORT Page

Operator ID: JM3743 Quant Rev:Qu.t o_u_t F i l e : "'Co2 71 : : AQData F i l e : >C6271::UOName: UQA 5--'l6.--'S9 CMisc: QC70012US,QU70012,L:M6,5,, 20 UL SPIKE

ID Fi le: IC1016: :UST i t l e : IFBLast C a l i b r a t i o n : 890516 16:47

7 Quan t Time:I n i.ec ted at :

D i l u t i o n Factor

8 ? 0 5 1 6 16:5 o890510 LL:4Z

1.00 0 U 0

Compound R.T. Scan* Area Cone Un i t s

•1 }

i. -'3.14 ')5 ,'

v 6 )7)8)9 'J

10 J11 <12 J13 '1-+,'

15 i16)17 :18 J18 <19 :<19 •2 0 »21 •22 >V7 ''24)25 •'26 J2 7 )23)2° '30 '71 i32)37 ;

74)7r '•3o j7 ~' •

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*Bromoch loromethaneMethyl chlorideMethyl bromideUinyl chlorideCh loroethaneMethylene chlorideAce t oneCarbon d i s u l f i d e1 , 1-Dich loroethylene1 , 1-Dich loroethane1 ,2-Trans-d ich loroe thyleneCh 1 oro f o rrnl,2-Dichioroethane-D4 C SUHr1 J1 ,2-Dich loroethane

* 1 ,4-Di f luorobenzeneMethyl ethyl ketone1, 1,1 -Trie h loroe thaneCarbon t e t r ach 1 o r i deCarbon t e t r ach 1 o r i deU i n y 1 acetateUinyl acetateDich lorobromomethane1 ,2-Dichloropropanec is-1 ,3-Dich loropropyleneT r i c h loroethyleneCh 1 o rod ib rornome t haneBenzene1 ,1 , 2 -Trich loroethanet r a n -3 - 1 , 3 - D i c h 1 o r o p r o p y 1 e n eBr omo form

* Ch !orobenzene-d5Me t h y 1 - i 5 o - b u t y 1 !< e t a n e2 - H e x a n G n e1 , 1 ,2 ,2-Tet rach loroethaneT e ' rach loroe thyleneToluene -OS (.SURR)TolueneCh lorobenzeneE t h y 1 b e n z e n ep-Br omo f 1 uo r obenzene C SURR )S t y r e n em-Xy 1 eneo + p-Xy 1 enes

13.3.4.6.7 .10.10.11.12.14.14.15.16.16.23.15.17.17.17.17.17.18.19.19.20.21.20.21.21.23.28.24.25.26.26 .27 .27.28.31.35.37.37.39.

2907910145007i*537411784003154499525291568733759546169728248758227111031336744412246308

311509712516222724626629733234'-'36538138457038041941942942042344147648149451250751551458170159062863363666467070577486392293296*

80288221338588611095225930841209412^686

131713235045875^2064 1:-: 8 7586^1517:1937323423 4 U 5 0 73^734

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814.850.946.250.822.701!.867.8S~7.241.977 .952.96t; .244.977.962.1904.

00188429003789469633120119970033700946414235068622507478410600038655026052036563185682

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG

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Lab Nam«:ETC Corp.. I Labora tory C o n t r a c t :

Lab Code: Case No. : b«S Nn . : bl.Ji-i No. :

Instrument iO:£CxMS C Ca I ibrat ton Uat« : H5X19XH9 l imn : lull

Lab Fi le 10: >L6331 Init Cal ib. D* te* ' .s>: 05X16X89 OV>xl6X89

Ma t r i x : (so i 1 Xua t er ) Ulrt I ttf Lave 1 : < 1 ouiXmed ) LI.IUJ Co 1 umn : < parkxcan ) Pfti :K

Mm RRF50 for SPCC(f) - 0 . 3 0 0 ( 0 . 2 5 0 for Bromoform) Max SwSD for O C ( * > - 30. US

11 COMPOUND

1 Ch loromethane1 Bromomet hane1 Ui ny 1 Ch lor ide1 Ch loroethaneIMathylene Chloride1 AcetoneICarbon Disulfide1 1 ,1-Dichloroethene1 1 ,1-Dir.h loroethane1 1 ,2-Dich lorethene (total1 Ch 1 o r o f o r m1 1 , 2- Dich loroethane1 2-But anone1 1 ,1 ?l-TrichloroethaneICarbon fetr^rhloride1 Uiny 1 Are t ate1 Bromod i ch loro methane1 1 ,2-Dichloropropanelcis-1 , 3-Di ch lornpropene_1 Trichloroethene1 Oi bromoch 1 orome thane1 1,1 ,2-Trichloroethane1 Benzene

1I

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1 trans-l,3-Dichl oropropene _ 11 6 r o mo form *1 4- Me thy 1-2-Pent anone1 2 - He x an on 9ITetrachloroethene

111

1 1 , 1 ,2 ,2- 1 et rach loroethane _ #1 To luene *ICh lorobenzene1 tt hy Ibenzene1 St wrene1 Xy lene ( t o t a l )

1 To 1 uene-d81 Bromof luorobenzenw11,2-Dichloroethane-dA1

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Id File: IC1017::UST i t l e : IFBLast C a l i b r a t i o n : 890519 08:50

Operator ID: KB6656Quant Time: 890519 10:52Injected at: 590519 10:11

Quant Output File: C63?1::HQ

QUANT REPORT Page

Quant Rev: 7Operator ID: KB6656Output F i l e : ~C6331::AQData F i l e : >C6331::UQName: IFB/UOA 5/19/89 CM:sc: QC70014US,QU70014,L: :M6 , 5,, 5UL CAL

Quan t TimeInjected at

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Compound R.T. Scan* Area Cone Units

1)O |

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*BromochloromethaneMethyl chlorideMe thyl bromideUinyl chlorideCh 1 oroe thaneMethylene chlorideAce toneCarbon d i s u l f i d e1.1-Dichloroethylene1 , 1-Dich loroethane1 ,2-Trans-dichloroethyleneCh 1 o ro form1 ,2-Dich loroethane-D4 ' SURR J1,2-Dich loroethane

*1 ,4-Di f luorobenzeneMethyl ethyl ketone1,1 ,1-TrichloroethaneCarbon tet rach lor ideCarbon t e t rach lo r i deU i n y 1 acetateDich lorobromomethane1 ,2-Dichloropropanec is-1 ,3-Dich loropropyleneTr ich loroethyleneCh 1 orod ibromome t haneBenzene1 ,1,2-Trichloroethanetrans-1 ,3-DichloropropyleneBromoform

*Ch Iorobenzene-d5Met hyl- iso-butyl ketone2 - He x a n o n e1 ,1 ,2,2-TetrachloroethaneTet rach loroethyleneToluene-08 C SURR )To lueneCh 1 o robenzeneEt hy Ibenzenep-Bromof luorobenzene '.SURR)S t y r e n em-Xv leneo »p-Xy lenes

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i 1

ii ||]lIIn111j

I < 1

Ij1

i 1i i i

1 'L jJu-jL^j v u i24 28 32 36 4(5

Data F i l e : >C6?46::UOName: IFB/UDA 5/20/89 CMisc: QC70014US,QU70014,I_: :M6,5, , 5UL CAL I + I I

Id File: IC1017::UST i t l e : IFBLast C a l i b r a t i o n : 890520 09:5^

Operator IQ: GM6356Ouant Time: 890520 11:10Injected at: 890520 10:29

Quant Output File: 'sC634e::AQ

55

QUANT REPORT Page

Operator ID: GM6356 Quant Re1

Output File: ^C634o::HQData File: >C63*6;:UOName: IFB/UOA 5x20x39 CMisc: QC70014US,QU70014,i_: :M6 ,5 , , 5UL CAL I + I I

7 Quan t Time:Injected at


390520 11:10890520 10:29

1.00000

ID File: IC1017:T i t l e : IFBLas t Ca1i b ra 11on:

/-v

US

890520 09:54

Compound R.T. Scan* Hrea Lone Un i t 3

1)2 'J )4 >5 )o .'7)J ,'

9 ')10 >11 J12.'13J14.'15,'16.'17 J18 .'19)19 >20;9 ' i

22 J23,'24J25)26)27,'28 J2<j j70;71.'72 J•*. - i74 J75 ,'76)37 '78 .'7° '40)4l >

*Bromoch loromethaneMe t hy I chlorideMet hy 1 brom ideU i n y 1 chlorideCh 1 oroe thaneMethylene chloridenee t oneCarbon d i s u l f i d e1 , 1-Dich loroethylene1 ,1-Dichloroethane1 ,2-Trans-d ic h loroethyleneCh 1 o ro f o rm1 , 2-Dichloroethane-04 ' SURR)1 ,2-Dich loroethane

* 1 , 4- 0 i f luorobenzeneMethyl ethyl ketone1 , 1 , 1-Tr ich loroethaneCarbon t e t rach lor i deCarbon tet r a c h l o r i d eU i n y 1 acetateDich 1 o r o b r o mo me t h a n e1 ,2-0 ich loropropanec 15-1 , 3 - D i c h loropropyleneTr ich loroethyleneCh lorod ibromomethaneBenzene1 , 1,2-Trichloroethanetrans-1 ,3-Dich loropropylene3 r o mo form

*Ch lorobenzene-d?Me t hy 1 - i so-bu t y 1 ketone2-Hexanone1, 1,2, 2- Tetrach loroethaneTet rach loroethyleneToluene-08 .SURR)To 1 ueneCh 1 or obenzeneE t h y 1 b e n z e n ep-Bro mo f luorobenzene i SURR )S t y r e n em-Xy leneo+p-Xy lenes

13.3.4 .5 .—f

9.10.11.12.14.14.15.15.16.•-i-r. _

15.I7.17.17.17.13.19.19.20.21.20.21.21.23.23.24 .25 .26 .25.•~> ~7

2 '"' .23.71.74.77.37.38.

21038792333854447007"7 "•*

3ol^t O

1043954747878334719445169623198257*_ j.

7006981231683599074699

7094*96127159224241264296331348364380383570379418418428427^+40475431494512507514513580700590628e?7635o64669704772365918928967

•?o39542712166382795122S60M1023727656017014174933.18294087523

2290321180031743903501589258

179239271292094101540441984571207711757391533552039772979681025651483461702632487551155^987145123665126398278075191997270877122897185697257136149456282372

250.265.248.253.142.267.261.249.254.257.252.259 .275.257.250.263.251.33.

256.411.250.256.249.236.255.254.254.253.252.250.265.272.311.262.226.260.263.259.283.262.253.517.

0052•- •->95"752926*930537*3"7 '3

500074461810Si5232•-» ~~y

0775074042940054026258804<u491215420789

MGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG

9799989996979o9995979895°299949999959995*790979099978996^7949^949796Q299°63192939991

VOLATILE ORGAN ICS INITIAL CALIBRATION DATA

Lab Name:ETC Corp. I Laboratory Contract:

Lab Code: Case No.: SAS No.: SDG No.:

Instrument ID:GC/MS D Calibration Date(s) 05/19/39 05/18/bv

Matrix:(soiI/water) SOIL Leve1:(low/med).LOW Column:(pack/cap) PACK

Mm RRF for SPCC(#) - 0.300 CO.250 for Bromoform) Max SRSD for CCC(») - 30.! .

ILAB FILE ID:IRRF100->D6513

RRF20 ->D6515RRF150->D6512

RRF50RRF200->D6511

II COMPOUND

I IIRRF20 IRRF50.|......).....,_*

I

I IRRF100IRRF150IRRF200 RRF RSD

II Ch lorome than e_________,Bromome thane ____lUinyl Chloride____________»I Ch loroe thane___________ IIMethylene Chloride________II Acetone ______________ IICarbon Disulfide__________II 1, 1-D ich loroe thene________»11.1-Dich loroe thane________*11.2-Dichlorethene (total)_II Ch lorof orm_______________*I 1,2-Dichloroethane.12-Butanone_______I1,1,1-Trichloroethane.ICarbon Tetrachloride_lUinyl A c e t a t e _ _ _ _ _IBromodichloromethane.I 1,2-Dichloropropane.

.1 1

lcis-l,3-Dichloropropene.ITrichloroethene.

/"""NDibromoch lorome thane_I 1,1,2-Trichloroethane.I Benzene_____________

I

It rans-1,3-Dichloropropene_IIBromofor m ___ *

I 2 - H e x a n o n e _ _ _ _ II T<» t rach loroe thene_________I11,1,2,2-Tetrachloroethane_tI To luene___________________*I Chlorobenzene__I E:hylbenzone___IStyrene_______IXylene (total).

.* 1

.974

.559

.798

.403

.773

.269

.410

.093

.326

. 174

.777

.797

.026

.156

.214

.021

.047

.355

.654

.499

.987

.347

.935

.756

.717-.6.6.8.465.711.708.856.278.520.073.868

.778

.441

.873

.462

.500

.142I 3.491I 1IIIIII 1

I 1

III 1I

0693.3151.2614.7745.719. 044149

1.237.047103395710512076.389.994.826.848.796.587.726.754.868

1.310.638

1.392.900

,7921,37718121,6811,4571,1181

04411311190139112781045103611771027106113921722151110473881UU8I8271

.8141.611.684.755.851..250.624...489.817

. 799 I

.3641

.5601669 I1681

0971175121513121

5.0971

.98011.0791.0571

1.11651.4181. 7641.5451

I 1.U73I.4141..0881.8471

.9121. 7031. 76 0 I.835.936.377.659.392.804

.518

.282

.463

.3591.207.772

3.-58.993

2.3271.1223.6854.159.::*2.841.V16.817.340.352..-/27.467. 732.312.V59.643. 7Q9.668.'505.661.r.45.825

1. 167.545

1.U99.631

.772

.405

.726

.4931.5211.0943.5621.0593. 1551.1924.3885.210. 038

1.0321. 125.194

1.023.382.695.5U7.993.370

.780

.323

.772.574.703

21.25.5122.4"26.2114.3 !17.315.V i4.1*6.44.3110. :• •12 . 6 I22. *12.7111.7

179.9 I10.': :7.5*T '-l/ •

5 . 6 112.410.916..' :

10.8113.-J:j13.5116.2'

5 .419.' 44.3*6. ; -10. 2»13.

.8671.276.597

1.269.8U4I 13.01

I To 1uene-d8___________IBromofluorobenzene___I 1,2-Dichloroethane-d4.

,262.188.540

1.2551. 1803.446

1.1981.1503.394

1.2011.0623.152

1.269

3.197

1.2371 2.811.1191 6.v:3.3461 5.UI

IFORM UI UOA 1/87 Re-;.

57

QUANT REPORT

Operator ID: 3C466QOutput F i l e : D6515::AQData F i l e : >D6515: :UOHame: 2:FBx'.iQA 5 -18 --'89 DMi «.c: aC70011U3,QU7Q011 ,

Quant Rev:

:M6,5 , ,

~" Quan r TimeInjected at


UL CAL I + I I

390519 12:->23 ° 0 5 19 0 ') : C1 0

1.0000 0

T i t l e : IF3Last C a l i b r a t i o n : 390519 11:46

Compound P.T. Scan* Area Cone Un : t 5

1A

111111t12.-\_j.j2_-l

-I

2T

T

7

T

"T

T

T

7

T

T

^

•H

1 '>2 )3 ,i4 i5 )o )-^ j

S '9)0 i1 .'2 )7)4)5)" 1

•6-T-3.'0 >„. ;

.-l ,

7 '4 ,'I— ,

6)" ,

3)W 'l

0 '^ 1^ .1T ',

-4 1

5 .'0 J— ,; 'v i0 >i

•Sromoch loro me thaneMethyl chlorideMethyl bromideU i n y 1 chlorideCh loroethaneMethylene chlorideAce t oneCarbon disulfide1 , 1-Dich loroethylene1,1-Dichloroe thane1 ,2-Trans-d ich loroethyleneCh 1 or o f o rm1 ,2-Dich loroethane-D4 ( SURR '1 ,2-Dich loroethane

* 1 ,4-Di f luorobenzene1,1,1-Trichloroethane

Carbon t e t r ach 1 o r i deDich lorobromo me thane1 ,2- Dich loropropanec 13-i ,3- Dich loropropyleneT r ich I o r o e t h y 1 e n eCh lorod ibromomethaneBenzenei , i , 2 - T r ich loroethanet rans-1 , 3 - Dich loropropyleneBromo form

*Ch Iorobenzene-d5Me t hy 1 - i so-bu ty 1 ketone2 -Hexanone1 ,1 ,2 , 2- Tetrach loroethaneT*t rach loroethyleneToluene-08 ''. SURR)To 1 u e n eI h 1 o r o b * n s e n eE t h '-,' i&enzenep - B r o mo f 1 u o r o b e n r e n e ' 3LJPR '3 1 y f e n ew- /,' 1 eneo *p - "y 1 ene 5

12.••)4 .5.6 .9.9.10.12.13.14.IS.15.15.23.17.

—— t^T

17.18.19.I'3.20.20.20.20.20.23.23.23.25.25 .25 .2o.•1 "

28.3 i .?**.T ""*T "7

33.

81961314612398952770400668801719•f? —580544681838649692634193533884'SS1~cr —

3293

024?

35

30243

7810414221122925*2883253433603 6379569415*15 ——4254374734.7949251050451251158170459063063«o33DO 7_ -"••''-> ' m.

^08->-?*37292613 3 7'S T"

Io4306402367252462649

116548343224087186

21860?717

3139258169380966917031975

——— ?Q173353528968'381013037157962729625365'36132091719829559231494**10412L58361591?-0607r=i5o2359-'1163966-tl52^0131917733353

250126138110811161169510310598103264111250111

107102929493QQ

94939687

250363195

100•-•cc93100S"72o53410621o

. 00

. 13

. 10

.02-?— »

.56

.05

.71

.23

.44

.49

.36

.54

.26

.00

.96TtrQ-.93. 34.70. 0 0. 73, 7 6. 15.3°.94.0. 00.53. 0s. 7-*. -*"

- -i

71 I

1 K

. 12i

. -» A

^ "7. i -*. 'J5

riGNGriGMGNGNGNGNGNGNGNGNGNGNGNGNG-Ns ———NGf-iGNGNGNGMGNGMGNGt-iGMGNGNGMGNG(• i GNG, |.~

NG»'J

NG,' )ij

NG

1

3-

f.•?~*

9:?g"*o3•33

•3

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-5

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5~.

•n

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-.•3

~

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:

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-

-

O~*

tr~™

CT

-,

J

-*~

-*'

-~-.7-_:'•-

"-

* Compound is I3TD

59

QLJt-NT REPORT

Quant Re^: 7Operator ID: 3C4660Output F i l e : D6515::AQData Fi Is: >06519: :DOName: 2IFB''.'OA 5-18--'99 0Misc: QC700ilUS,a<j;>Q011 ,L: :M6,5 , , 2 UL CAL I + II

ID F i l e : I DIG 16: :UST i t l e : IF3Last C a l i b r a t i o n : 390519 11:46

7 Quan t i i me:Injected a t :


c a g e 1

39 0511? 12:423 ° 0 5 1 ° 0 0 : 0 0

I . 0 0 0 0 0

Compound R.T. Scan* Hrea Cone Un : t =.

1iiiiiti2,-\._»,j2ta22;7.

J7

T

'7

T

T

T

-?,

T

_*

*

-

i >2 J3.'4 .15 ')6 )7 ,l

8 J9;0 'I'.- .

3)4 )5J

3.'0.'^ :.-i ,7 i4 .'5 '6 >~* t

8 )V I

0 '^ 1^ .1T 'i

_t 15 '0 >— ,

iit

.L

c

"Bromoch lorome thaneMethyl chlorideMethyl bromideUiny 1 ch lor ideCh loroethaneMethylene chlorideAce toneCarbon d i 3 u 1 f i d ei , 1-Dich loroethylene1,1-Dichloroethane1 ,2-Trans-d ich loroethyleneCh 1 o ro f o r m1, 2-D ich loroethane- D4 < SURR >1 , 2-D i ch loroethane

*l,4-Difluorobenzene1,1 ,1-Trichloroethane

—— Cai bun I eli a i l i l u i lUe ———— : —————Carbon t e t r a chlorideDich lorobromomethane1 , 2-D ich loropropanec is-1 ,3-DichloropropyleneT r ich loroethyleneCh 1 o r o d i b r o mo me t h a n eBenzenei , i , 2 - T r ich loroethanet rans- 1 ,3-D ich loropropyleneSr omo form

*Ch Iorobenzene-d5Tie t hy 1 - i so-bu t y 1 ketone2 -Hexanone1 ,1 ,2 ,2-TetrachloroethaneT • t r a c h loroethyleneToijene-08 'SUFR)To 1 u e n eI h 1 o r o b e r, z e n eE t h v 1 b e n z e n ep - B f o mo f 1 u o r o b e n z e n e ' 3UPR ')3 1 • ,j c e n e.vi-. .',' 1 eneo *p-Xy 1 ene 5

ompoijnd is 1 3TL1

12•-5

45699

101213141515152317

1718191°20202020202323232525252o.-i -i283 ].?**i;-1

~ -1

33

.31

.96

. 13

. 14

.61

.23

.98

.95

.27

.70

.40

.06

.63

.80

. 17

. 19

. 19

.58

. 05

.44

.08

. 18

.38

. 64

.96

.92

.67

.41

.93

.53

.38

.34

. '^B

. 1~

.'57

. 32

. i;>3

. 02

. 4?

.35

302437810414221122925*2833253433607 6379569415

425437477-4.79492510504512511581704590630o7Qo33067o72"OS77'3

•-1 '•' «

*26Q7797?

Io4306402367252462649

11654834322408"136

2136077173139258169330966917031975

—— 70173358523968'=8101303713796272 625365°613

2091719829559231494**10412158361591370607I'3 1502 8 5 '5 7116396 0 -4 1 5

2-*OiJ1917773859

250.126 .138.110.81.

116.116.95.

103.105.98.

103.264.111.250.111.

107.102.92 .94.93.'39 .

94.C " t

96.87.

250.36.31.95 .

100.-•cc•'3.

100.y7.

2o5.34.

106.21o.

00171002"'T5605712344493654260096•6-6-93347000737o153 '3

940700^ 30K•"44*^

7* '

1512— i5"34

05

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG' *'—

NG- .~

NGI lij

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4

3

-

f.3"

939-*•3

3•33

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tor ID: 3C46oO Quant F i l e : -De514: : AQ- l i e : D6514: :IJO2 [FB--','OA 5----18, 99 DQC70011'.<S,QU70011 ,i_: : Mb , 5 , , 5

le: IDlOlo: : US: IFBC a l i b r a t i o n : 39 0 519 1 1 : 4&

Compound

"Bromoch loromethane

Methyl c h l o r i d eMethyl bromideU i n y I c h l o r i d eCh lo roe t haneMethyl ene chlorideHce toneCarbon disulfidei , 1-Dich loroethylene1 , 1-Dich lor o ethane1 ,2-Trans-d ich loroethyleneL h 1 o r o f o r ml,2-Dichloroethane-D4 'SURR )1,2-Dichloroethane

*• 1 , 4 - D i f luorobenzeneMe t h y 1 ethyl k e t o n e1 ,1,1-TrichloroethaneCai-bon >. e t i- aeh I 01- i de —————————Carbon t e t r a c h l o r i d eD i c h 1 o r o b r o mo me thane1 , 2 - D i c h 1 o r o p r o p a n e•: is-1 , 3 - D i c h 1 o r o p r o p y 1 e n eT r ich loroethylene'i- 'i V~.J"i •'S/i 'i T '*:/T!(/nft, W?.-

Benzene1 , 1,2-Trichloroethanetrans-1 ,3-DichloropropyleneBrornof orm

• Ch I orobenzene-d5Me t h y 1 - i s o - b u t y 1 k e t one2 -He • anonei , i ,2 ,2-Tet rach loroethaneT e t rach loroethylene"oiuene-C'3 'SURR,17 o 1 u e n eC h 1 c r o benzeneEt^ylbenrenep - 5 r c rno r luorooenzene • SURR 'S t ','f enerfi-. ' ,' 1 eneo «p-Xy lenes

t Pe

JU

P.

12.

•*, _4.5 .6 .9 .

10.10.12.13.14.15.15 .15.23.15.17.1?.I"1.18.i13 .19.20.•in.20.20.20.23 .23.27 .25 .2C .25 .26..-, -71

23.T *

74.?o .77.73 .

l-Ur

CHI_

T.

31

001317653202953170400668SO216419-f3-58094*0818aa6596965 ?41°3573334i41 —i

?:->

J'59 ~95743C

i

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D i I u t i

1 * 1 1

Scantf

702

4973105143212230254289325343760376379570375415

425*73477*~*94925 .LQ.50*512512530704-9Q630o?9o33006672"08•'•'a3-2924'=34'5"7

uanr T i r,-,e :j e c * e d at:~ n Factor:

^rea

13505

14400

316316163854827- 22112*64593197886173323337383*163767105328763407346

37709———— 0 2 0 0 ——

9**4o34223301^85*2033908o3.212."'7533*2967267032o*77464023509--17"'60':-*329ijiln45C'

= '33*~""7 5 5 8 iOTC -0

-03*8-•c-c; 2~9 Q 1 3 25oS01115192

•-i ° C:'C0

Cone

250.

251.272.700.234.2<*6.260.24*.252.2e2.264.i 7--.

257 .274.250.290.278.

275.20* .253.2"^ .•TC-T

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CNVO

QUANT REPORT •-'aqe

Quan t Rev: 7Operator ID: 3C466GOutput T i l e : '•06513: : AQjar a F i l e : >D6513: :DOName: JIFB-'UOA 5- 18x39 DMisc: QC7G011US,QU70011,L:':Mo ,5 , , 10 UL CAL 1*1 I

ID F i l e : IDlOle::UST i t I e : IFBLast C a l i b r a t i o n : 890519 11:46

Quan t Time:I n j e c t e d at:


S 9 0 ? 1 ° 1 2 : 7 "i'?05;3 ::::->

1.00 0 0 0

1)—

2 )"^ i* >5 j0 J

Compound

*Bromoch loromethane— t4e-J- — ' — -J— ' — —— ' ———————————————

MeMeUiChMe

-. 1 1 J, » «— . • . w • • •— w

thyl chloridet h y 1 bromideny 1 chloride1 oroe thanethylene chloride

7 . Ace tone

i11

SJ9 .10)1.'2 )

13 i14 )15 >16)1t

_'

•1

J

2j22•-i'22T

T

"T

7

r

T.

-T

-y.

.?"7

.4

-4

~/ \

3 '0;!_ 1

2 .17 ,

-t 1

5 j6 )

Carbon d i s u l f i d e1,1,1,Ch1,1,

*1,Mei,

1-Dich loroethylene1-Dich loroethane2-Trans-d ich loroethylene1 or o f o rm2-Dich loroe thane-D4 'SURR)2-Dich loroethane4-0 i f luorobenzenethyl ethyl ketone1 , 1-Tr ich loroethane

Carbon tetr. a c h l o r i d eL1 1 c h 1 o r o b r o mo me t h a n e1,c iTrCh

2-Dich loropropanes-1 , 3-D ich loropropyleneich loroethylenelorod ibromomethane

Benzene1,1 ,2-Tr ichloroethane

~ i t rans-l,3-0ichloropropylenea.*•3 'i

0 Ji •2 i7 .-4 ,'5 'O '-i ,3 .'9 -G;i '

Bromoform•ChMe•-t

i,TeToToChEtP-Stm-o *

Iorobenzene-d5thyl- iso-butyl ketoneHex an one1 ,2,2-Tetrachloroethanet rach loroethyleneiuene-08 < SURR >1 u e n eicrcDenzeneh y i b e n r e n eE r o mo t 1 u o r o b e n z e n e <. SURR ')yr en*Xy 1 enep-Xy ienes

R.

12.— •2 ,4 .5.6.9 .

10.10.12.13.14.15.15 .15.23.15.17.

17.18.19.19.20.20.20.20.20.23.23.24.25 •.25.25 .26.'"' 7 .23.71 .7*.3s.77 .73.

T. Scan#

35

96091461290295277140066380176820n ft

58094*681338659692oO41025*3335Q8]_ T

57299??97*O 1' •* A

303* '

4877104142211230254283325343360376379569376415

— 445—42543847347949251050451251158070*591630639o33o6767270S7733. "2925Q3*972

Area

17b33J J -M- J

279461329428650239995137739441124238368151104174195715484659847186133716036378

148394—— 1*81?168561151904561621034777321714995814436655565113*671260086151410010775186923o73*111"'771*10*7*51573297ib3G*" 0 1 91709301017772010*7

Cone

250*.->•->

513465559690478511494*92496498500253506250539501

52351851251950452750752*53053*2505275325104322*2*9043*52225654"517

IClo

. 0 0

. 0?

.03

.85

.38

.23

.80

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.65

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NG-MS ———NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG

NGNGNG; iGNGNGNGNGNGf iGNG.' ;<jNG•iGNGr i'jNG'••GNG• . _?NG; '-I-NG

q3 3

13 89oQQ

97977400

79967799949 4

97'J L

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a aV5•33o9313 I

313837"' 35oc ~?" 1j —9-.~

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63

IONP i i « •r"«?li ?" . ?~£^? .3 itt'j.. c l~ o •• '••'0™ "''lo-1?1? D IJC~'?'?11»'? •,'*'"'~&yl.l ,>. !

TIC Isee 400 1000 ;

j 1

L Ub y4 8 12 16 £0 34 £8 32 36 40

Quant Output File: -D6512:Data P i l e : /06512::UOName: 2IFS--OOA 5/18/39 0Misc: QCr0011US,QU70011,L: :M6,5,, 15 UL CAL 1*1 I

Id File: 1010lo::UST i t l e : IFBL a s t C a l i b r a t i o n : 89051° 11:^*6

O p e r a t o r ID: SC4o60Q u a r t Time: 3°051° 12:35I n j e c t e d at: 39 05 18 21: J"7

64

GLJHNT REPORT

Operator ID: SC-660 Quant Re*.;: -Output F i l e : "06512::^QDa t a F i l e : •-"Db'Vj.'i: :'0'I) '"o-Name: 2 I F3--UOA 5'18/89 DMisc: CC-0011US,QU70011 ,L: :M6 ,5 , , 15 UL Cni

ID F i l e : IDlOlc:: UST i t l e : IFBLast C a l i b r a t i o n : 390519 11:46

Quant ~imeInjected at

1*1 I

11111111t1

2'_J'2^-t'jJj2

7T

T

T

T

T

T

--

7

.4

4

1 )

•I j

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2 •~T_ (

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* -'

6 •~ !

3.'•3 i

0 :•12 'T |

« i- |

o '-•

8 J3 i

0i

Compound

* 8 r o rno c h loromethane— Me'hyl ehloi-ide ——————————————

Methyl c h l o r i d eMethyl bromide1 -' inyl chlorideCh loroet haneMethylene chlorideAce t oneCarbon d isu 1 f ide1 , 1-0 ich loroethylene1 , 1-Dich loroethane1 ,2-Trans-dichloroethyleneCh lor o form1 ,2-0 ich loroe thane-D4 ( SURR ''1 ,2-Oich loroethane

*1 ,4-Oi f luorobenzeneHe t h y 1 ethyl k e t o n e1 , 1 ,1-TrichloroethaneCerbon t e > i- ash l u i - ide —————————Carbon tetrachiorideC1 : c h I o r o b r o mo me t h a n e1 , 2 - 0 i c h 1 o r o p r o p a n e<: i 5-1 , 3 - D i c n loropropyleneTr ich loroethyleneCh 1 c r o d i b r o mo me t h a n eBenzenei , i ,2-Tr ich loroethanet rans-1 ,3-0 ich loropropyleneB r o mo t o r m* C h Iorobenzene-d5Met hyl- iso-butyl ketone2-He • anonei ,1 , 2/2-Tetrachloroethan*T * t r a c h loroethyleneTo luene-03 • 5UPP 'T ;, 1 u « n e2 h L o r o b e r, z s n eE t h v 1 1' e n z e n ep - B r o mo '•luorobenzene ( UPP ''3 1 ','r enerfi-/./ i eneo *p-/'y 1 ene 5

R.

12.

3.<4.

5.Q. •Q _

10.10.12.13.14.15.15 .15.23.15.I"7.i — i

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2o.'-'— _23.71.7*.T, n

— T*

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85

001313653206952775410672301763"> n•• p

59094508IS836596966038•30

5-*3931'341-4

5?25'3Q

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303

4973105143212231254238326343360377379569776415mi?425•4384734-<»49251050-4^ I ~

512530-07"9Qc 3 0'o39637006o~i-07T"!7"

3-1•3 '"• _i335973

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4817621952410343376710070370432237041o6l62191^92732632601166337630746331301105-4

240374-i .-• .-k

26435^2 o 1 2 3 910267013-7-617331026723026-004101604207329236000o777'31843o814202-'Io834o1576123 0°-*o

1 P '-1 i 7 :

27323-13712-"15-7

23139*1677703 2 49 SI

Cone

250.

-75.b74.-'03.351.323.300.327.776 .75*.764.-3- .235.-33.250 .355 .711.

-- I—

-19.-3 0 .320.327 .3 0 o .310.321.379.3 la.376.250.33o.917.3-+-.304.242 .30°.3 0 S .82-.27- .3 ' '-R- .

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596023730157316475010352"50031o9

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3-lo•42

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7-t3-4

Un i t :

NG

MGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGr n~NG••)'jNG: 'C-NGMGNGfiGMG.' i1-"

nGr :jDG' ''.r

NGr-G" ' '"^

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65

TOTSL ION i;I r, i „ , 0 4 * 1 1 T;; • lo-' 6'? 0 'I* 'I •" & 011 '•• 5 t 'I1 'v ~* 0 01 i i i-

Quant Output File: 'D6511Data File: ?D6f11::UOName: 2IFB.'UQH 5x19/89 DMisc: QC70011US,QU70011,L: :H6,5,, 20 UL CAL 1*1 I

Id File: I Did 16: :UST i t l e : IFBLast C a l i b r a t i o n : 390519 11:46

O p e r a t o r ID: S C^6 s0Quant- T i m e : 39051* 12:72I n j e c t e d a t : 890519 2 Q : * 9

QUANT REPORT

Quan t Rev: 7Operate^ ID: SC4660Output F i l e : ••D6511::AQData F i l e : >06511::UOname: 2IF6-'UOA 5-' 18x89 0M i s c : QC70011'JS,aU70011,L: : M6 ,5 , , 20 UL CAL 1*1 I

ID File: ID1016::UST i t l e : IFBLast C a l i b r a t i o n : 390519 11:46

Qu-an t T i meInjected at


-age 1

39051' .2:72qo fie i^g - ,; : .j

1 . 0 ij 0 0 0

1,1-*• -'

2 ')j .14)

5 J6 '-• .3 >9 .<

lO.i11 .'12 y13 <14)15;16 •17 '

1? .'19 .'2 0 .— x J

2 -J '-« 7 ,

2^+ •- c ,

2o >2 '-j c ,29 j7 u7 i 'T -

"- T

-j ^ '

~ & ,

7 1 -.- -1 ,7 j

7 O

-* 'J

-t i '

Compound

•Bromoch loro me thaneMethyl shlui' ide ——————————————Methyl chlorideMet hy 1 brom i de'•) i ny 1 ch 1 or i deCh loroethaneMethylene chlorideAce t oneCarbon d i s u l f i d ei , 1-Dich loroethylene1 , 1-Dich loroethane1 , 2 -Trans-d ich loroethyleneCh loro form1 ,2-Dich loroe thane-D4 tSURP''1 ,2-Dich loroethane

* 1 , -4-D i f luorobenzeneMethyl ethyl ketone1 , 1 , 1-Tr ich loroethane

Carbon tetr a chloride' •' i n y 1 acetate0 i c h 1 o r o b r o mo methanei ,2-Dich loropropane.; i«,-l ,3-DichloropropyleneTr ich loroethyleneCh i o r oc1 ib r omome thaneBenzene1 , 1 ,2-Tr ich loroethanef. rans-1 ,3-Dich loropropylene3r 3 mo f o rm• C h Iorobenzene-d5Me t ny 1 - i so-bu t y 1 ketone2-He <anone1 , 1 ,2 ,2-Tet rach loroethaneTe t rach loroethylene*:. lu«r,e-i:.i '.SURP'To 1 u e n eCh lorcoenreneE t "i -, i b e n r e n ?p - 5 r o mo f 1 u o f o b e n z e n e I 3IJKPs t y r e n em-Xv 1 ene:. *p-.<y lenea

R.

12.,-x*• •

3.4 .c; _6 .9 .

10.10.12.13.14.15 ,15.15.23.15.17.

I"1.17.13.19.19.20.20.20.20.20.23.28.27 .25 .25 .25 .26.2"* .23.71.7-47o7 ~7

73

T.

89C 1-1" "-'

00132169361499317544107284176920-*e-59590945681833o5909260739950P '

319-.i-*5025. -+

. 59

.33

.3o

Scan*

704TT ,rf- ^

4978106144213237255289326344361377380569376415

—— 417425<*25438-t73479-+92510504512511580~"0?590o29o?'15*7~'66--."170-,—.- -1

aT'5 2 507C

':i"'7

Area

25380•^1 • i?l T. A V w .

52o012362647024364791225317340**351064"1D1T762286948-1138317741328112942223411552914695

388597

4273697 7 -B oi33302316200-^23934221537436148--.34155144209297188727530385^323663^173316223^1-t27400'51123o229213341773919J050WWi7393i+o22-44^*7-»4c:347

Cone

250 .'"' "'r*• ' •" "670.696 .o78.728.793.706.970 .V77.396.940.379.238.798 .250.342.814.

314.

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3 2 0 .°20 .9 I] i .921.737.940.347.32-..3el.250.365.•ZJ " O

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39934597350370If?0085903530001265

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riG*.ll~, , _.

NGNGNGNGNGNGNG>'ltNGNGNGNGNGNGNGNG

NGr;GNGNGNGr:GNGNGNG•i jNGr i~

NG• iGNG• . :-.' iG•' "jiNG' • --1h.;."_.' .GMG•iG

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I STD67

UOLATILE CONTINUING CALIBRATION CHECK

Lab Name:£TC Corp. I Laboratory Contract:

Lab Code: Case No.: SAS No.: SDG No

Instrument ID:GC/MS D

Lab File ID: >De520

Calibration "Date: ime-:

I n i t Calib. Dates(s): 09/19x89 05/18x89

Matrix:(soiI/water) SOIL Leva I:(lowXmed) LOW Column:Cpackxcap) PACK

Mm RRF50 for SPCC(#) - 0.300 (0.250 for Bromoform) Max HRSD for CCC(») - 30.OS

11 COMPOUND

1 Ch lorome thane IM1 Bramome thane .. „ IMII ,lUinyl Chloride1 Ch loroethanaIMethylene Chloride(Acetone1 Carbon Disulfide1 1 r 1-Dich loroethene1 1 rl-Dichloroethane_1 1,2-Dich lorethene (total)1 Ch lorof orm1 1 f2-Dich loroethane „,12-Bu t anone ._1 1.1,1-Tr ichloroethane ... .ICarbon Tat rach lor idelUinyl Acetate1 Bromod ich lorome thane1 1 , 2-Dich loropropanelcis-l,3-Dich loropropene _1 Tr ich loroethene1 Dibromoch lorome thane11,1,2-Trich loroethane1 Benzene

11

*1»1111**

__ 1*111111*

__ 11111

__ 1 1*RF IRRF50 1

11313145

11

1

1 t rans-1 ,3-Dich loropropene _ 11 Bromoform ..,, , *1 4-Methyl-2-Pentanone _ ,,„,1 2-Hexanone,__1 let rach loroethane11,1,2 ,2-Tetrach loroetnane1 Toluene1 Ch lorobenzene1 EthulbenzeneIStureneIXvlene (total)

1 To Iuene-d81 Bromof luorobenzene1 1 F2-Dich Ioroethane-d41

111

__ ****11

1111

1

1

113

.7721

.4051

.7261

.4931

.5211

.0941

.5621

.0591

.1551

.1921

.3881

.2101

.0381

.0321

. 1251

.1941

.0231

.382)

.695 1

.5071

.9*31

.3701

.9931

.7801

.8-31

.7721

.5741

.7081

.7391

.8-71

.2761

.5971

.2b9l

.8041

.2371

.1191

.34611

•

•

1.1.3.1.5.5.

1.1.

•

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t

•

•

•

1.

1.1.

1.1.4.

5121349174614041idOl9381952I92111721050134615121U30I183127311941930135713841387134212811690166215751454137915161o61l8321069 15851Sd9l0071

250115615741

1

*D

33.13.2.18.22.14.45.13.

11.21.5.19.1«.13.

4.6.16.23.15.23.30.15.JO.41.34.27.37.4.16.2.25.25.

1.3.36.

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013i71

i

68 FORM U11 UOrt 1/87 Rev.

TOTOL ION

1400001

130006-

00

36 40

Data F i le : > D o 5 2 0 : : U OName: 2 [FBxUQA 5/18x39 DM i s c : QC70011US,QU70011,L::M6,5,, 5UL CnL 1 * 1 1

Id FiIs: ID1016::UST i t l e : IFBLast Ca l i b ra t i on : 390519 11:46

O p e r a t o r ID: RL9134Q u a n t T i m e : 390519 13:12I n j e c t e d a t : 390519 12:30

Quant Output Fi le: "D6520 : :AQ

69

QUnNT REPORT

Quant Rev: 7Operator ID: PL'? 134Output File: "D6520::HQData F i l e : >D652Q::UOName: 2IFB/UOA 5/18/89 QMisc: OC7G011iJS,QiJ70011,L: :M6 ,5, , 5ULC6L I » I I

ID F i l e : ID1016::UST i t l e : IFBLast C a l i b r a t i o n : 390519 11:46

(Juan t i i me :Injected at:


3* 051* 1.7 : 12:: a o e, i o :2:70

1.00000

Compound R.T. Scan* nrea Lone Ijn i t 5

111111111

1

I2-,',j;

22'j_^_i.T

7

777-*•?777_»

1)2 '.-i -i

3 J* j5 )K j

6 /7 )3 )9 )O.|1)•-> .i. -'

3J4 J5 JG .'7 J3 >3.'•3 i

0 )

i '

2 ''3 i4 >5 >O J"7 ,

3 J* j0 t1 12 .'T ,

* .1

6 .;7 i3.-9 •'0 '

•Bromoch loro me thaneMe thy I chlorideMethyl chlorideMethyl bromide'Jinyl chlorideCh loroethaneCh. lar ae, th a_ne_Methylene chlorideAce t oneCarbon disulfide1 , 1-Dich loroethylene1 , 1-Dich loroethane1 ,2-Trans-d ich loroethyleneCh loroform1 ,2-Dich loroethane-D4 (SURR)1 ,2-Dich loroethane

•* 1 ,4-Di f luorobenzeneMethyl ethyl ketone1 , 1 , 1-Tr ich loroethaneCarbon tetrachlorideCaroon tetrachloride'• ' i n y i acetate0 i en lorobromomethane1 ,2-Dich loropropane£ i s- 1 , 3-D i eh 1 oropropy leneTr ich loroethyleneCh 1 o r od i b r omo me thaneBenzene1 ,1,2-Trichloroethanet rans-1 ,3-Dich loropropyleneBr omo f o rm

* Ch Iorobenzene-d5Me t hy 1 - i so-bu t y 1 ketone2 -Hexanone1,1 ,2,2-TetrachloroethaneTetrachloroethyleneToluene-D3 i SURR JT o 1 u e n eCh lor o benzeneEthyloenzenep-Sromot luorobenzene < SURP '3 t y r e n ern- Xv lane

12.2 .3.4.5.o .7 .9.10.11.12.17.14.15.15.15.23.15.17.17.17.15.13.19.19.20.20.20.21.20.23.23.24.25 .•-•£. _

25 .2o .27 ._ O •

31.74.7o .76.

915509141966053404043376461274361974252564741150742494710293o229

014333308909-tl055364'3Q

304375178105143153212230256289326344361377380569377416416*2637743847**8049351150551351258070059Q623^3767oD64069'037713o2915-24

4042174592071014108M3016816310*1544770937917789103721112822342451

216071184899M222817198893

60212353012070*25325338645M19493270915M116103769571673381371485597513176611*4131303793 l'5c,56332*3723o97037

225*3*f"!15001 OM192322105563203*73236700172051

250 .59.

165.215.257.204.52.

193.21*.137.217.251.220.30*.741.264.250.200.286.23.

233.250.•-> •»; Q _277.209 .190.211.173.19 Ij.212.174.250 .147.164.i5o .132.252 .~. 7 .3

20*.2*5 .253.717."'*"'.

0073356018651296390028392157305100425314046750053635* i63i-4

3"- •

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91i 'i "T

i?~675T -1

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J 'J

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG;>GNGNGNGNGNGNGNG'iGNGr ; j^,

NG' iGNGf j'~NGr-.GNG: iG

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70

QUANT REPORT Page 2

Operator ID: RL9134 Quant Ke^: " Quant T i me: S'^O1?!1? 17:12Output File: ~D<3<520::AQ Injected at: 89Q'519 12:70Data File: >D6?20::UO D i l u t i o n Factor: 1.00000Name: 2IFB/UQ^ 5/18/89 0Misc: QC70011US,QU70011,L: sMo,1?, , ?UL CAL 1 * 1 1

ID File: ID1016::UST i t l e : IFBLast C a l i b r a t i o n : 890511' 11:46

Compound R.T. Scan* Area Cone Units

•41J o+p-Xylenes 38.43 961 763423 o26.?2 UG

* Compound is ISTD

71

SMUQLATILE INI'EPNAL S I ANUAM'i «Wr A SUMMARY

Lab Name: MC Corp. Lontrart:

Lab Code: Lase Nn . : SAS Nn . : Si)G No.:

Lab F i l e ID (Standard): >i:63*l Data Analyzed:

Instrument ID: GL/'MS C lime Anflls>^*d: 111'11

Ma t r i x : (soi I /'wa ten) WA"I b K I eve 1 : C 1 ow/med .' L IIUJ Ln I iimn : t nark /can )

01020304II1?06II X

OH09

111111 V13141 >1617IB

2 0

•"I i jJ~ •'.

\I

*

1*

12 HLIUR S'l'fJ

UPPER L IM IT

LUUIH.R LI fill

EPA SAMPLENI.J.

IJC70U 1 4UCA02'i'3U

l si (Bi.:M)AREA #

78422

1^6844

39211

69HV6

R l

1S.24

1 5 . 1 6

13.2 1

1 SV ( Ur H )AREA #

3 27 OH

7lll?416

176 5^4

311/U6345932

R l

23 . 4V

V 5 . 4','23. 5V

1 SM 1 :H/)ARh A #

2600/1

>?VU'J42

1 HI 036

VV H 6 ^ 4

P,

28.52

VH . 2

1 I I I1 I I I1 I I I1 I I I1 I I I

SI ( Bl :M; - Hromoch 1 ornme thane IJPHt R L I M I T - + JUUSiS2 (D rb ) - 1 ,4-Di f luorobenzene of internal standard a r e a ,a 3 1 I -H^ ) " l ih lorobenzene — rl1? LLtUllr W LI Mil • — ^HSi

of in ternal s tandard area.

Ciolumn used to f l a q in te rna l s tandard ares values w i t h an a s t e r i s k

_/_ of _l_

rUWM Ul 1 I UI.IA !/«/ R

72

HAWJLAlILb INItWNAL S I ANUAP.U AWKA SUMMAWY

Lab Name: b~ I C Lorp. Contract:

Lab Code: Case No.: SAS No.: SUG No.:

Lab File 10 (Standard): >i.:6346 Data Analyzer):

Instrument ID: GL/MH C . • 1 i m* AnalyTed: 1U29

Hat r i* : ( so i l/utat«r ) UIATKP Lave 1:( low/medJ Li ILJ r.o 1 umn :( pack/cap >

12 HOUR S1D

UPPER LIMIT

LCJUIEW L I M I T

EPA SAMPLENI..1 .

1S1 (BLM)tlLjL. J*N 4fcw> c.™ TT

7<S3S"?

1S2790

3H19B

R l

13.21

1 SV ( DH H )AWhft #

3MJ^B

700316

l^U/V

Kl

23.43

1 S3 ( UH^ )AHtA #

24H71?1?

4V/"?'L 0

124378

PI

2H.5*

0102113114O1?0607UH0VII)1 J121314

161718

202122

MC7HOI 'J * . 1 V13.24

* H H 6 '1 H V * . 4*»23.4V2 .* . 4V

VH.1?1?

VH .

I SI (HUM) - bromochIoromathan«Ib2 (DI-B) - 1 ,4-Dif luorobanzene

(UBZ) - l.:h lorobanzene-d1?

L 1 M I r - * 1of internal standard ar«a.LUUItH LI Ml I - - 'yU*of internal standard

# Loliimn used to flag internal standard ar«a

page | of I

FUWM Ot 1 1 UlA

73

with an asterisk.

8AVOLATILE INTERNAL STANDARD AREA SUMMARY

Lab Nama: ETC Corp. Contract:

Lab Code: Case No.: SAS No.: SDG No.:

Lab File ID (Standard): >D6520 Data Analyzed: 09/19X39

Instrument ID: GC/MS D lima Analyzed: 1230

Matrix:(soiI/water) SOIL Level:(low/mad)'LOW Column:(pack/cap)

111 12 HOUR STD

1 UPPER LIMIT

1 LOWER LIMIT

1 EPA SAMPLE1 NO.

01IQC70011Y0218J1630U03ICA0212US04ICA0212U05ICA0212UR06I3J1630US07IBJ1630UR08!09110!Ill12i13114:15116!17118!19120:21122 !

ISKBCM)AREA t

40421

80842

20211

45655340203018338547303222733127557

RT

12.91

12.8812.9112.8712.8912.9012.8612.86

IS2CDFB)AREA *

198893

397786

99446

193528152150143199179208145727134633128870

RT

23.19

23.2023.2323.1923.2123.2223.2223.22

IS3CC8Z)AREA *

180379

360758

90190

159211124024124236155251132211116441103451

RT 1

28.291

1

1

II

26.29!28 . 48 126.28)28.42128.47'28.47128.4?!

1;1:1

1

111

1

1

152 tDFB)153 (CBZ)

1,4-Dif luorobanzeneChlorobanzene-d5

of internal standard area.LOWER LIMIT - - 5UXof internal standard area.

t Column used to flag internal standard area values with an asterisk,

pa-ge i of <

FORM YIII UOA 1/87 Rev.

74

ETC

RAW QC DATA

75

MS Data F t le: > C 6 2 7 Q : :(JO

Name: UOA *''ttisc : P-BFB

O p e r a t o r : JM33«*3 D a t e - T i m e : ? • '1 o. -3 '?

Fil. ,Cb278Bpk H6 1165

1290-

1100:

oae-888-

799

699-

590-

490-

390:£00:

VOft 5/16/39. C P-BFB 'ctn 209 |13.23 mm. |

y f"

75 .j

44

'ii40

57

iU ae

I I I !

• 1-199174

!

i

-69

-79

-68

_=nf-'

•207

i

-ta

-29

u«' «9 ' 88 ' 190 129 ' 149 169 189 299

76

MS Data File: >C6270 : '• UO

Name: UOrt 5/16/89.CMisc: P-BFB

O p e r a t o r : JM3343 Da t e ~ i me : 5/io- 39

C6270208

UQft 5x16/89,CNRM

P-BFB

File: >

m/z

77.0033.1039.0541.0?43.05

/•"V 44. 0045.00

C62

I

7a8

10162918

70 Scan *p:

n t . m/z

.554

.326

.240

.987

.223

.700

.627

51.55.56.57.58.59.61.

05101010109505

203

Int.

3.7.5.12.9 .T _

4 ,

155382150189871348979

Retn .

m/z

62.67.63.69.71.73.74.

05100505150000

t i me :

Int .

421313•nA.

1015

.893

.146

.476

.391

.313

.901

.451

13.23

m/z

75.76.73.36.87.38.94.

10109500000510

In

52.5.4.3.6 .8.10.

t .

01740320617o695Oo9386

m/z

"5.96.

174.175.176.177.207.

10100005050505

In

100.8 .

91.o .87.6 .10.

t .

l 0 006924552429613012*

50.05 24.721

OO

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t -a o rj * »• i» IB 10 *•a > « e > > ] i « < » « * < a o a « * « a « oB. , .?. , .J. , .?. , .?. , .?. , .f . , .?. , .?. . .?. , .?. , .?. , .r ,

/c17

7y*

L_^— --~lc_ _

" I>

A- • "j.1 " '&' "-A" "iri " j,1 " 'j.1 • • 'J/ • • • r TT""1:J O « i ® » » O ' ® « C B '

y

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<D

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>>

2 Z•~ (*o' 3

T) <1i o

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CO

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t.I)ao

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u> ^—

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a

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® O O O «> * S 5

o M — •» •» to r- '.o U/ » r cj

C

1S Data Fi le: >C6330: : (JO

Name: UOtt 5/19/89,C1isc: P-8FB

Operator: GM6356 Date/Time: 5/19/89 8:58

C6330208

UOA 5/19/89,CSUB NRh

P-8FB

'lie: >C6330 Scan #:

m/z Int . m/z

:08 Retn. time: 13.26

Int . m/z Int . m/z Int. m/z Int.

38.39.41.

rg;45.48.50.51.55.

100505

000095050500

9.3603.3541.794.936

1.0144. 1344.68020.8277.0985.304

56.2057.1058.1059.0561.0562.0563.0568.0569. 0570.05

1.2..

5.5.3.11.12.2.

404496390156850070432934246730

73.0074.0075.1078.9580.9587. 1088.0592.0593. 1094.10

5.53818.48753.2764.2125.0705.6161.7162.7303.9789.750

95.1096.10102.90119.05125. 00133.00147. 05163.00174. 00174.95

100.8.2.3.2.3.2.2.

93.7.

000346496744886354574418292098

175.177.179.191.193.194.205.207.249.

950505101005050500

89.6266.7032.7302.3033.3542.4134. 1341.2484.212

IS Data File: >C6330::UO

Name: UO* 5/19X89,Clisc: P-BFB

Operator: GM6756 DatexTime: 5x19x89 8:58

!

O

Flit >C6

9000-•:

I]M.JZi53vv-•

:n-v -;

^39*-

?(tBnj

100^

0-

330 35.0-260. a MU. VOfl 5'-19^89,C

40 88 128 164 30

,

^^N^MfVH^^V^

6.0 7.0 8.0 9.0 10.011.012.013

P-BFB

Id 243 2S*• , 1 , , , 1 ,

\1\

ikV'\\'lI\

)\lxM^*.

.0 14.0 15.0 16.0 17.

•\*&

-9Q

-ACl

-70

-T.W

-59

-40

-30

'•19

-90

81

•s Data Fi le: >C6/45: :UO

l.sr,-,e: 'JQK 5/'20-'89,C Operator: SC4660 Da t e-T i me : 5/20'89 9:S5Use: P-BFB

r

F l i t .'C6J45Bpk Ob 1178

•

128*-

1198-

1998^

890:799-j

699:

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!!D:

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199:

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VOA 5-20-89. C P-BFB Se»n 288SUB 13.25 i* in .

95r

75

I I I . . . . . . . . . . . . .

174

„ rl 193X

69 88 18* 12* 14* 168 180 20t

;

1-108

**

•60

•70

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-38

-20

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82

IS Data Fi le: >Co345: : UO

Same: UQ« 5/20/89, C Operator: SC4660 Dats.-Time: 5/20/39Use: P-BFB

'C6345 UOfl 5/20/89, C P-8FB208 SUB NRM

' l i e : X

m/z

3 7 . 0 078 .0039. 0541.05N? . 05•4 5 . 0049. 05

1634

I n

8.7 ..

7.f

m

2.

>5 S

t .

319725849385085424547

can

m

50515961626268

*:

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.05

.05

.95

.05

.05

.95

.05

I

2272654

12

208

nt .

.326

.555

.207

.282

.603

.075

.224

R e t n .

m/z

69.0573.1074.0075.1076. 1078.8580.95

t 1B1

In

12.10.16.49.4.3.3.

ie :

t .

564187553151669311990

13.25

m/z

87.0038.059 3 . 0 094.0095.1096. 10

In

5.3.3.3.

100.6.

t .

348565480574000621

m/

174.175.175.176.193.207.

'z

000595950005

Int .

88.9646 .961

86.4185.9621.952

.255

83

ib Data Fi le: >C63«*5 : :UO

Name : U0« 5 '"2 0/39 , Cl iac: P-BFB

Operator: SC4660 Date/Time: 5--'20/'89 9:55

Fil* .. Cb

6509-

6099-

" WWlr

5000-

4599-

4090-

3530-

3896-

2509-

2000-

159*-

1000-

500-

Q«

345 35.8-260.0 MU. v(31

40 80 12ti

v -J6 '.9 r'.e 3'.9 9.'o 10

1 5 x* 2 w '* 3 '9 j C

160 28

'.• ll'.9 12.0 13

0

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P-BFB '

W^v^vvAV

14.9 IS'. 9 16.0 17

-100

•90

•99

r:»•W0

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•28

-19

-99

84

MS Cat.a File: Do?10: :JQ

Same: ')OA 5/Misc: P-BFB

Ope r a t o r : SC46 & 0 Da t e -• T i me : -• • 18 --'3 9 2 0 : 0 -.

j Bp* HDs-06510 VOfl 5.'18^89 0 P-BPB

SUB CNHSc*

12.45 mm.

i".

1 VT

69±588-

ii480-

300:•

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180-

: 140

50

68

!

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75

i|| ,|30

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1471" 133 /I ' \ia0 : 160

74i

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V ,''! iaoe ' 248

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7180

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:78

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58

48

30

28

18

85

MS Da -a ci is: -06? 10: :UQ

Mame: UOA 5--13--89 D Operator: SC4660 Date- Time: -"-'IS -39 C0:0oMisc: P-8F3

; 065 1C UOA 5/18<'89 D P-BF8216 SUB NRM ENH

File: >•

m-'z

77. 1037.9542.9549.9550.955 6 . 0 5

k 56 . 95

D65 10 Scan #:

Int.

123j.

329

55

. 160

.563

. 104

.247

.646

.439

.695

m/z

60.95o5.7567.9563.9573.9574.95?5. 95

216

Int .

7.722.821

15.72614.32313.75158.799

5.618

Retn .

m/"z

78.8580.953o.3587.35''3. 0594.0595.05

i t ime : '

Int.

3.3224. 1821.7703.5151.001

11.262100.000

12.45

m/T

95.95116.90137. 00147.00174.00174.90

Int .

' 5 .823.893. 130

2.950'53.433

6.875

nv

176.177.1* 1 .202.207.253.

4.

000035950505

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•52.7*18.20*

. 372

.949

.3352.540

86

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