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    Process Safety, Health andEnvironment (CN3135)

    Soh Guat [email protected]

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    Outline of CN3135 Importance of process safety design and

    operation

    Identifying safety and health hazards eg.HAZOP, Fault Tree

    Predicting consequences

    Design for sustainable processes eg. reliability

    engineering, sustainable engineering

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    Module Learning Outcomes

    On successful completion of this module, studentswill be able to:

    Describe and identify chemical process hazards

    Analyze and assess the potential impacts of

    hazards on safety, health, and the environment(SHE)

    Develop methods for controlling process hazardsand minimizing their associated risks.

    Describe the principles and aims of sustainabledevelopment

    Prepare for final year design project

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    Lectures and Tutorials Schedule

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    Lectures and Tutorials Schedule

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    Tutorial Exercises

    Will be assigned by individuallecturers during each lecture

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    Module Assessment

    Mid term test (date, topics, duration) 10%

    HAZOP/ Reliability Engineering project 30%

    Final Examination 60%

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    Textbook for CN3135

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    Chemical Process Safety:Fundamentals withApplications,International Edition, 3/e

    Author : CROWL

    LOUVAR

    Publisher : PearsonISBN : 9780132782838

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    Expectations

    IVLE/CN3135

    Lecture materials - download

    Tutorial problemsAttempt Register your project teams

    oForm team of 4 5 members

    oRegister: IVLE/Workspace/Groups/Sign-up

    Bring textbook for lectures/tutorials

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    Lecture 1Introduction to Loss

    Prevention

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    Learning Outcomes

    Review major process safety accident cases

    Assess loss prevention in process design andoperation

    Analyse incident statistics

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    Why Process Safety ?

    Unexpected releases of toxic, reactive, orflammable liquids and gases in processesinvolving highly hazardous chemicals

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    May result in huge loss oflives, property damage, impactthe environment and $$$

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    Source : The 100 Largest Losses, 1974-2013

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    Source : The 100 Largest Losses, 1974-2013

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    Major Process Safety Accidents

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    Video: Bhopal

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    http://www.youtube.com/watch?v=ELllSxnDS0g

    http://localhost/var/www/apps/conversion/tmp/Videos/Bhopal,%20India%20-%2025%20years%20after%20Union%20Carbide%20gas%20leak.webmhttp://localhost/var/www/apps/conversion/tmp/Videos/Bhopal,%20India%20-%2025%20years%20after%20Union%20Carbide%20gas%20leak.webm
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    Taiwan Gas BlastKaohsiung

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    31stAugust 2014At least 25 fatalities and270 injured

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    Major Process Safety Accidents

    Fire at Shell Bukom

    Fire had started in the course of open de-oiling of

    naphtha from a pipeline that ran through a pump

    house at the refinery

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    Fire at Shell Bukom

    Started 28th Sept 2011@ 1.15pm

    Fire broke out in the pump room of Shell's half-a-million barrel per day Singapore plant

    6 people suffered superficial wounds and 3 fire

    engines were damaged from the fire Damage was contained to the vicinity of the

    pump-house, in an area 50m by 150m

    Caused temporary shut down of refinery

    Extinguished 29th Sept 2011 @9.18pm

    Final handover by SCDF 2nd Oct 2011

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    Shell was charged under Section 11(a) of the Workplace Safety and Health Act(Chapter 354A) for having failed in its duty as an occupier to take reasonablypracticable measures to ensure the safety of persons at its workplace

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    22

    Source: www.wsh-institute.sg

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    Source: www.wsh-institute.sg

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    Source: WORKPLACE SAFETY AND HEALTH REPORT, 2014, WSH Institute

    Workplace Injury Rate, 2006-2014

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    Occupational Disease Incidence Rate, 2006-2014

    Source: WORKPLACE SAFETY AND HEALTH REPORT, 2014, WSH Institute

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    $10B costs

    reported !

    Source: Economic Cost of Work-related Injuries and Ill-health in Singapore, WSH Institute

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    Process Safety Focus

    Prevention of incidents involving leaks, spills,fires or explosions

    Facilities are well designed, safely operatedand properly maintained

    Facilities are designed and engineeredproperly with systems to monitor and controlhazards

    Includes technical, management andoperational systems working together toachieve desired outcome

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    Process Safety Pyramid

    Source: WSH Guidelines on Process Safety Performance Indicators, WSH Council

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    Definitions

    Safety: Strategy of accident prevention. Mainemphasis is on worker safety

    Loss Prevention: Prevention of accidents through useof appropriate technologies to identify and eliminatehazards before an accident occurs. Includes

    protection of people, equipment, production, propertyand the environment

    Hazard:An inherent physical or chemical characteristicof a material, system, process or plant that has the

    potential for causing harm or damage Risk:A measure of the likelihood of occurrence and

    consequence (severity) of an accident

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    Definitions

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    Spitting Cobra

    HAZARD:Venom

    Venom contactseyes may causeblindness

    RISK:

    Lower Risk Level

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    Definitions Accident: Incident which results in consequent

    losses

    Incident:An unplanned or undesired event thatadversely affects a companys work operations

    Include work-related fatalities, major injuries, minorinjuries, first aid cases, occupational illnesses,property damage, spills, fires, dangerousoccurrences or near miss events

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    Accident Pyramid

    Source: Chemical Process Safety, Crowl & Louvar

    1

    100

    500

    10 000

    Disabling Injury

    Minor Injury

    Property Damage

    No Damage

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    What is Acceptable

    Risks?

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    Acceptable Risks

    Any risk that is currently tolerated is consideredto be acceptable (US EPA)

    Tolerable risk: risk which is accepted in a givencontext based on the current values of society(ISO & IEC)

    Level of potential losses that a society orcommunity considers acceptable given existingsocial, economic, political, cultural, technicaland environmental conditions (UN)

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    Acceptable Risks

    Cannot eliminate risks totallyAt design stage, need to decide if risks are

    acceptable

    < Normal day-to-day risks in non-industrialenvironment

    Risks from multiple exposures are additive

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    Risk acceptance is a function of many factorsand varies considerably across industries

    Company culture and the culture of the country

    in which a facility is located influence riskacceptability

    Risk acceptability is also time dependent -what is acceptable today may not beacceptable tomorrow, next year or next decade

    Acceptable Risks

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    Workplace Safety and Health Act

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    Legal Requirements WSH (RiskManagement) Regulations

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    Risk Management using As Low asReasonably Practicable Principles (ALARP)

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    40

    Latest Revision: 2015

    8/3/2015 CN3135 Introduction to Occupational Health and Safety 1

    Obtainable from WorkplaceSafety and Health Councilwebsitewww.wshc.sg

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    Safety and Health Hazards

    Physical (eg. fire, explosion, noise, temperature, radiation) Mechanical (eg. moving parts of machinery, sharp edges,

    work at height)

    Electrical (eg. electricity, static electricity)

    Chemical (eg. corrosives, toxic chemicals) Ergonomics (eg. back strain, repetitive strain injury)

    Biological (eg. pathogens)

    Psychosocial hazards (eg. human & cultural factors)

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    Sources of Hazards

    42

    huMan Machine Method

    Material Physical

    Environment

    Organisation/ Work factors

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    Severity of HazardLevel Score Severity Description

    5 5Catastrophic Fatality, fatal diseases or multiple major injuries

    4 4

    Major

    Serious injuries or life-threatening occupational

    disease (includes amputations, major fractures,

    multiple injuries, occupational cancer, acute

    poisoning, deafness, disabilities)

    3 3

    Moderate

    Injury requiring medical treatment or ill-health leading

    to disability (includes lacerations, burns, sprains,

    minor fractures, dermatitis, work-related upper limb

    disorders)

    2 2

    Minor

    Injury or ill-health requiring first-aid only (includes

    minor cuts and bruises, irritation, ill-health withtemporary discomfort)

    1 1 Negligible Not likely to cause injury or ill-health

    Code of Practice on Risk Management by Workplace Safety and Health Council

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    Likelihood of Occurrence

    Code of Practice on Risk Management by Workplace Safety and Health Council

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    Level Likelihood Description1 Rare

    Not expected to occur but still

    possible.

    2 Remote Not likely to occur under normal

    circumstances.

    3 Occasional Possible or known to occur.

    4 Frequent Common occurrence.

    5 Almost Certain Continual or repeating experience.

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    Risk Ranking and Risk MatrixLikelihood

    Severity

    Rare -

    1

    Remote

    - 2

    Occasional

    - 3

    Frequent

    - 4

    Almost

    Certain - 5

    Catastrophic -

    55 10 15 20 25

    Major - 4 4 8 12 16 20

    Moderate - 3 3 6 9 12 15

    Minor -2 2 4 6 8 10

    Negligible - 1 1 2 3 4 5

    Code of Practice on Risk Management by Workplace safety and Health Council

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    Acceptability of Risk Levels

    Risk Level Risk Acceptable

    Low Risk (1

    3) Acceptable

    Medium Risk (4 12) Tolerable

    High Risk (15-25) Not acceptable

    Code of Practice on Risk Management by Workplace safety and Health Council

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    Hierarchy of Hazard Control

    So u r c e Pat h R ec ei v er

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    Chemical Plant AccidentAccident

    Type

    Scenario Outcomes Probability

    ofOccurrence

    Potential

    forFatalities

    ToxicRelease

    Release +

    DispersionToxic exposure

    to employees

    and

    community

    Low High

    ExplosionIgnition in

    confined space

    Extensive plant

    damageIntermediate Intermediate

    Fire

    Release + Ignition

    l Pre-mix with air?

    Low to

    intermediate

    plant damage

    High Low toIntermediate

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    Nature of Accident Process

    Most common consequence is fire

    Highest percentage of large losses from vapour cloudexplosion

    Toxic release can result in high human andenvironmental impact

    Most frequent cause is mechanical failure (>50%),followed by operator error (18%) and design (10%) *

    Most common hardware failure piping systems,reactors and storage tanks*

    * Data from Chemical Process Safety by Crowl & Louvar

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    Sequence of Accidents

    Initiation Event that starts the accident

    Propagation Event(s) that maintain orexpand the accident

    Termination Event(s) that stop the accidentor diminish it in size

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    Defeating the Accident Process

    Step Desired Effect ProcedureInitiation Diminish Process design

    Inert atmosphereIntrinsically safe equipmentGrounding, bondingProcedures, permit to work

    Risk assessmentTraining

    Propagation Diminish Construction materialsPlant layoutReduce inventories of materialsInstall check and emergency shutoff valvesEmergency material transfer

    Termination Increase Install check and emergency shutoff valvesFire fighting, sprinklers, equipment &ProcedureRelief system

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    Inherent Safety Principles

    Minimise eg. inventory, size of tanks/reactors

    Substitute eg. less toxic, less flammablematerials

    Moderate eg. lower temperature, lower pressure,dilution, particle size

    Simplify eg. Design for Safety, less maintenance,

    housekeeping, easy to follow. Reduceopportunities for error

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    Bhopal Accident

    Methyl isocyanate used in pesticidemanufacturing

    Heavier than air

    Reacts exothermically with water

    Substitute with less hazardous chemical thatproduce a less toxic chloroformate

    intermediate (Substitute) Decrease inventory of MIC on site (Minimise)

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    Video: Sugar Dust Explosion

    Port Wentworth, Georgia

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    http://www.youtube.com/watch?v=Jg7mLSG-Yws

    http://localhost/var/www/apps/conversion/tmp/Videos/%E2%96%B6%20Inferno%20Dust%20Explosion%20at%20Imperial%20Sugar.mp4http://localhost/var/www/apps/conversion/tmp/Videos/%E2%96%B6%20Inferno%20Dust%20Explosion%20at%20Imperial%20Sugar.mp4
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    Port Wentworth Accident

    Conveying equipment not designed tominimise release of sugar dust and eliminateall ignition sources (Minimise)

    Poor housekeeping (Minimise, Simplify) Company knows but fail to correct unsafe

    condition (Company leadership issue)

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    Combustible Dust ExplosionAutomobile Metal Parts Polishing Supplier, Kunshan

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    2ndAugust 201468 fatalities, about 190 injured

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    TaipeiFormosaWater ParkFire

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    Major Process Safety Accidents

    Fire at Shell Bukom

    Fire had started in the course of open de-oiling of

    naphtha from a pipeline that ran through a pump

    house at the refinery

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    Shell Bukom Fire - 3 Main Lapses

    1) Contractors drain naphtha from two openvalves and an open flange joint of the pipelineinto trays.

    Naphtha vapour to escape into the atmosphere

    resulting in an accumulation of flammablevapour, which would in turn pose a danger ofignition

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    2) Use of a plastic tray, which was a non-conductive container, as a receptacle forcollection of naphtha

    Free fall of naphtha onto the plastic tray allowed

    accumulation of static chargesA spark could be caused and be sufficient to

    ignite the naphtha vapour which is withinflammable range in the atmosphere

    Shell Bukom Fire - 3 Main Lapses

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    3) Failed to deploy portable gas monitorssufficiently close to the open de-oiling area togive the warning when the build-up of theflammable vapour reached an undesirable level

    Shell Bukom Fire - 3 Main Lapses

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    Performance Monitoring

    Provide assurance that process safety risks are adequatelycontrolled

    Leading Indicators - monitor proactively the effectivenessof risk control systems and provide feedback on safetyperformance before an incident or accident happens

    Evaluate present state of workplace through routine andsystematic inspections

    Lagging Indicators when desired safety outcome hasfailed. Monitor reactively the effectiveness of risk controlsystems, identify gaps and weaknesses in these systems,

    and report on incidents or accidents

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    Source: WSH Guidelines on Process Safety Performance Indicators, WSH Council

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    Examples of Leading Indicators

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    Examples of Leading Indicators

    Source: WSH Guidelines on Process Safety Performance Indicators, WSH Council

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    Examples of Leading Indicators

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    Examples of Leading Indicators

    Source: WSH Guidelines on Process Safety Performance Indicators, WSH Council

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    Accident Statistics

    Ministry of Manpower

    Fatality Rate: per 100 000 employed persons

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    Accident Statistics

    OSHA (Occupational Safety & HealthAdministration)

    # of injuries & Illness*200,000

    Total hrs worked by all employees

    Incidence rate per 100 worker years

    40 502000

    hrs wk hrWorkYear

    yrwk yr

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    Accident Statistics

    FAR (Fatal Accident Rate): Fatalities per1000 employees over 50 years ( = 108 working hours)

    Depends on no. of exposed hours

    FAR = No. of Fatalities x 108

    Total hrs worked by ALLemployees during period covered

    [NB. 1 worker - 40 hr/wk, 50 wk/yr, and 50 exposed- yr/lifetime = 105 exposed-hr/lifetime]

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    Assessing Risks

    Target FAR For planning, design to meet national or

    company requirements

    Sum of risks for most exposed person on site

    < 2 deaths/108 exposed-hr

    Single risk < 0.4 deaths/108 exposed-hr

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    Accident Statistics

    FR (Fatality Rate): per person per year

    Independent of hours actually worked

    FR = No. of fatalities per year

    Total no. of people inapplicable population

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    Assessing Risks

    Acceptability Criteria

    10-3/yr unacceptable10-4/yr public money spent to control

    10-5/yr some degree of inconvenience10-6/yr no great concern

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    Engineering Ethics

    Use knowledge and skill for enhancement ofhuman welfare

    Be honest and impartial

    Strive to increase competence and prestige ofengineering profession

    Hold paramount the safety, health and welfareof public

    (Extracted from American Institute of Chemical Engineers Code ofProfessional Ethics)

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    Your Role in Loss Prevention

    Eliminate, design out the hazard

    Mitigate the risk by reducing the severityand probability of occurrence of theincident

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    Zero Harm

    V S ON

    Z RO

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    Achievable?

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    Tutorial Questions 19th Aug

    Attempt problems 1-1, 1-2, 1-4, 1-6(a), 1-22and 1-23 from textbook

    3rd Edition