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CT DEP Reasonable Confidence Protocols
Glen Breland, VP Member CT DEP QA/QC Workgroup
Reasonable Confidence Protocols
(RCPs) Overview
♦ Why develop the RCPs?
♦ What are the RCPs?
♦ What is Reasonable Confidence?
♦ What methods are affected?
♦ Some method highlights
♦ Lab Certification & Project Planning forms
♦ When does this take affect?
Reasonable Confidence Protocols
(RCPs) Overview
♦ Why develop the RCPs
• Ensure known & documented data quality
Reasonable Confidence Protocols
(RCPs) Overview
♦ What are the RCPs?
• Specific performance criteria for labs to follow
– Calibration, QC, Reporting
– Guidance on remedial action
• Based on the MCP model
Reasonable Confidence Protocols
(RCPs) Overview
♦ What is Reasonable Confidence?
• Phrase implies that data reviewer can have
confidence the lab has followed a set of guidelines which will generate data of consistent quality. Lab will
certify this fact.
• Reasonable Confidence will form the basis for the
data reviewer to asses usability
• Narratives are critical elements in assessing usability
CT RCP Methods
� 8260 – Volatiles by MS
� 8270 – Semi Vol by MS
� 8081 - Pesticides
� 8082 - PCB
� 8151 - Herbicides
� 8021 – Volatiles by GC
� Some air methods
�TO 14
�TO 15
�TO 17
� CT ETPH Petroleum
�Mass Methods for EPH & VPH
�Will soon be released
� 6010 – Metals by ICP
� 6020 – Metals by ICP/MS
� 7470/7471 - Mercury
� 7000 Series – Metals by AA
� 9010/9012/9014 - Cyanide
� Hex Chrome
� SPLP & TCLP
RCP Methods Overview
♦ Standard analyte lists
♦ RL equal to lowest cal standard
• ICP exception (check standard at RL)
♦ “B” flag required (“E” flag can be used)
♦ Batch MS/MSD not reported
♦ TICs only done on client request, except drinking
water
RCP Methods Overview
♦ Results below RL reported as “ND”
♦ Specific list of report deliverables
♦ Dilutions of highest analyte in upper 60% of cal
curve
♦ Soil/sediments on dry weight basis
RCP Method Performance Table
CT RCP Forms
♦ Pre-Project Planning Form
♦ Lab Certification Form
• 7 Questions
RCP Laboratory Certification Form
Important Dates
CT DEP Policy letter
Samples collected after Sept 1, 2007
Must follow RCPs or prove equivalency
Soil preservation requirement: 5035
• March 1, 2006
♦ All soils collected after this date must follow the
guidance document for collection and
preservation of soils for volatile analysis
Evaluating Data Usability
Data of known quality should be used to support
decisions that relate to a site’s data quality
objectives (DQO) or the original intended
purpose of obtaining the data
How do we know the quality of the data?
QUALITY CONTROL INFORMATION
Quality Control Information
♦ Why Do I Need It?
• Because we don’t know the sample’s true value or
“what’s in the jar”
♦ We Do Know (or we are just learning) That:
• All measurement systems have bias
• Bias can be negative or positive from the true value
• Bias can be attributed to many factors
– Sample related
– Measurement related
Quality Control Information
♦ What is a matrix spike and how does it differ
from a surrogate spike and why do I care?
♦ Why are duplicates important?
♦ Do I really need a trip blank and when I get it
what does it tell me?
♦ Why does the lab report include a laboratory
control sample (LCS)?
♦ How do I use all of the above to evaluate if the
data is usable?
Basic QA/QC Concepts
♦ Quality Assurance (QA) is a set of general principles designed to establish the reliability of (in this case) a measurement system. Precision, accuracy and sensitivity are several of these principles
♦ Quality Control (QC) defines the specific tools which are used to achieve this measurement reliability. Duplicates and spikes are two of these tools
DUPLICATES
METHOD BLANKS
MATRIX
SPIKES
SU
RR
OG
ATES
DETECTION
LIMIT
S
�Precisionrecision
�Accuracyccuracy
�Representativenessepresentativeness
�Completenessompleteness
�Comparabilityomparability
�Sensitivityensitivity
Quality Assurance Principles
Applying Concepts
♦ Understanding QA concepts is key to
performing a data usability assessment
• Precision: duplicates
• Accuracy: recoveries, blanks
• Sensitivity: methods, matrix issues, DQOs,
regulatory criteria
Connecticut DEP RCP Summary
♦ Standardized Methods – The RCPs
• Some labs require you specifically request these
methods
• Must be performed for samples collected after
September 1, 2007 (or prove equivalency)
♦ Reasonable Confidence
♦ Data Usability