development of an elevated flare tip to ease 40 cfr … · regulation is not the only driver for...
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© 2018 UOP LLC. A Honeywell Company All rights reserved.
Development of an Elevated Flare Tip to Ease 40 CFR 63.670 Compliance
Matthew Martin
Senior Product Line Manage
Honeywell Fellow
April 3, 2018 4C HSE CONFERENCE 2018 San Antonio, TX
UOP 8133-0
40 CFR 63.670 Major Requirements
Item Requirement Deviation Proof
PilotsAt least one pilot flame
at all timesOne minute of no pilot flame
during a 15-minute blockContinuous monitoring
SmokeLess than 5 minutes within
2 hours when less than smokeless capacity
Greater than 5 minuts of smoke over 2 hours when
less than smokeless capacity
Visual check or video monitoring
Exit Velocity
Less than 60 ft/s or less than Vmax and less than 400 ft/s when less than
smokeless capacity
Greater than the applicable velocity criteria
Calculation and vent gas measurement
Net Heating Value of Combustion Zone
(NHVcz)
Greater than or Equal to 270 Bu/SCF
Less than 270 Btu/SCF on average of a 15 minute
block duration
Calculation and monitors
Air Dilution Operating Limits
(NHVdil)
Greater than or Equal to 22 Btu/ft2
Less than 22 Btu/ft2 on average of a 15 minute
block duration
Calculation and monitors
Operation Above Smokeless Capacity
Multiple Including FGRS and Co-Generation / CHP
Inability to always operate below smokeless rate
Calculation
1
1
2
3
4
5
6
1 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
UOP 8133-1
40 CFR 63.670 Major Requirements
Item Requirement Deviation Proof
PilotsAt least one pilot flame
at all timesOne minute of no pilot flame
during a 15-minute blockContinuous monitoring
SmokeLess than 5 minutes within
2 hours when less than smokeless capacity
Greater than 5 minutes of smoke over 2 hours when
less than smokeless capacity
Visual check or video monitoring
Exit Velocity
Less than 60 ft/s or less than Vmax and less than 400 ft/s when less than
smokeless capacity
Greater than the applicable velocity criteria
Calculation and vent gas measurement
Net Heating Value of Combustion Zone
(NHVcz)
Greater than or Equal to 270 Bu/SCF
Less than 270 Btu/SCF on average of a 15 minute
block duration
Calculation and monitors
Air Dilution Operating Limits
(NHVdil)
Greater than or Equal to 22 Btu/ft2
Less than 22 Btu/ft2 on average of a 15 minute
block duration
Calculation and monitors
Operation Above Smokeless Capacity
Multiple Including FGRS and Co-Generation / CHP
Inability to always operate below smokeless rate
Calculation
2
1
2
3
4
5
6
1 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
UOP 8133-2
40 CFR 63.670 Major Requirements
Item Requirement Deviation Proof
PilotsAt least one pilot flame
at all timesOne minute of no pilot flame
during a 15-minute blockContinuous monitoring
SmokeLess than 5 minutes within
2 hours when less than smokeless capacity
Greater than 5 minutes of smoke over 2 hours when
less than smokeless capacity
Visual check or video monitoring
Exit Velocity
Less than 60 ft/s or less than Vmax and less than 400 ft/s when less than
smokeless capacity
Greater than the applicable velocity criteria
Calculation and vent gas measurement
Net Heating Value of Combustion Zone
(NHVcz)
Greater than or Equal to 270 Bu/SCF
Less than 270 Btu/SCF on average of a 15 minute
block duration
Calculation and monitors
Air Dilution Operating Limits
(NHVdil)
Greater than or Equal to 22 Btu/ft2
Less than 22 Btu/ft2 on average of a 15 minute
block duration
Calculation and monitors
Operation Above Smokeless Capacity
Multiple Including FGRS and Co-Generation / CHP
Inability to always operate below smokeless rate
Calculation
3
1
2
3
4
5
6
1 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
UOP 8133-3
40 CFR 63.670 Major Requirements
Item Requirement Deviation Proof
PilotsAt least one pilot flame
at all timesOne minute of no pilot flame
during a 15-minute blockContinuous monitoring
SmokeLess than 5 minutes within
2 hours when less than smokeless capacity
Greater than 5 minutes of smoke over 2 hours when
less than smokeless capacity
Visual check or video monitoring
Exit Velocity
Less than 60 ft/s or less than Vmax and less than 400 ft/s when less than
smokeless capacity
Greater than the applicable velocity criteria
Calculation and vent gas measurement
Net Heating Value of Combustion Zone
(NHVcz)
Greater than or Equal to 270 Bu/SCF
Less than 270 Btu/SCF on average of a 15 minute
block duration
Calculation and monitors
Air Dilution Operating Limits
(NHVdil)
Greater than or Equal to 22 Btu/ft2
Less than 22 Btu/ft2 on average of a 15 minute
block duration
Calculation and monitors
Operation Above Smokeless Capacity
Multiple Including FGRS and Co-Generation / CHP
Inability to always operate below smokeless rate
Calculation
4
1
2
3
4
5
6
1 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
UOP 8133-4
40 CFR 63.670 Major Requirements
Item Requirement Deviation Proof
PilotsAt least one pilot flame
at all timesOne minute of no pilot flame
during a 15-minute blockContinuous monitoring
SmokeLess than 5 minutes within
2 hours when less than smokeless capacity
Greater than 5 minutes of smoke over 2 hours when
less than smokeless capacity
Visual check or video monitoring
Exit Velocity
Less than 60 ft/s or less than Vmax and less than 400 ft/s when less than
smokeless capacity
Greater than the applicable velocity criteria
Calculation and vent gas measurement
Net Heating Value of Combustion Zone
(NHVcz)
Greater than or Equal to 270 Bu/SCF
Less than 270 Btu/SCF on average of a 15 minute
block duration
Calculation and monitors
Air Dilution Operating Limits
(NHVdil)
Greater than or Equal to 22 Btu/ft2
Less than 22 Btu/ft2 on average of a 15 minute
block duration
Calculation and monitors
Operation Above Smokeless Capacity
Multiple Including FGRS and Co-Generation / CHP
Inability to always operate below smokeless rate
Calculation
5
1
2
3
4
5
6
1 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
UOP 8133-5
40 CFR 63.670 Major Requirements
Item Requirement Deviation Proof
PilotsAt least one pilot flame
at all timesOne minute of no pilot flame
during a 15-minute blockContinuous monitoring
SmokeLess than 5 minutes within
2 hours when less than smokeless capacity
Greater than 5 minuts of smoke over 2 hours when
less than smokeless capacity
Visual check or video monitoring
Exit Velocity
Less than 60 ft/s or less than Vmax and less than 400 ft/s when less than
smokeless capacity
Greater than the applicable velocity criteria
Calculation and vent gas measurement
Net Heating Value of Combustion Zone
(NHVcz)
Greater than or Equal to 270 Bu/SCF
Less than 270 Btu/SCF on average of a 15 minute
block duration
Calculation and monitors
Air Dilution Operating Limits
(NHVdil)
Greater than or Equal to 22 Btu/ft2
Less than 22 Btu/ft2 on average of a 15 minute
block duration
Calculation and monitors
Operation Above Smokeless Capacity
Multiple Including FGRS and Co-Generation / CHP
Inability to always operate below smokeless rate
Calculation
6
1
2
3
4
5
6
1 Pilots
2 Smoke
3 Velocity
4 NHVcz
NHVdil
6 Capacity
5
UOP 8133-6
40 CFR 63.670 Major Requirements
Item Requirement Deviation Proof
PilotsAt least one pilot flame
at all timesOne minute of no pilot flame
during a 15-minute blockContinuous monitoring
SmokeLess than 5 minutes within
2 hours when less than smokeless capacity
Greater than 5 minuts of smoke over 2 hours when
less than smokeless capacity
Visual check or video monitoring
Exit Velocity
Less than 60 ft/s or less than Vmax and less than 400 ft/s when less than
smokeless capacity
Greater than the applicable velocity criteria
Calculation and vent gas measurement
Net Heating Value of Combustion Zone
(NHVcz)
Greater than or Equal to 270 Bu/SCF
Less than 270 Btu/SCF on average of a 15 minute
block duration
Calculation and monitors
Air Dilution Operating Limits
(NHVdil)
Greater than or Equal to 22 Btu/ft2
Less than 22 Btu/ft2 on average of a 15 minute
block duration
Calculation and monitors
Operation Above Smokeless Capacity
Multiple Including FGRS and Co-Generation / CHP
Inability to always operate below smokeless rate
Calculation
7
1
2
3
4
5
6
1 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
UOP 8133-7
Elevated Flare Tip Requirements
• Refiners and Petrochemical plants that need replacement flare tips either need or
pre-emptively want to comply with 40 CFR 63.670
• The new requirements make standby steam usage significantly more costly
8
Lower Chance of Violating NHVcz
Lower Chance of Violating NHVdil
Higher Chance of Visible Emissions
Lower Supplement Gas Requirement
Reduced Tip Life (?)
Higher Purge Gas Requirement (?)
Higher Chance of Violating NHVcz
Higher Chance of Violating NHVdil
Lower Chance of Visible Emissions
Higher Supplement Gas Requirement
Increased Tip Life (?)
Lower Purge Gas Requirement (?)
Less Noise (?) More Noise (?)
2
4
5
2
4
5
More SteamLess Steam
UOP 8133-8
Elevated Flare Tip Requirements
Regulation is Not the Only Driver for Flare Design
9
Flare Tip Quality Good Practice Driven by Regulation
Increased Smokeless Capacity X
No Smoke Under Normal Operation X X
Increased Tip Life Expectancy X
Low Standby Steam X X
Low Noise X
High Stability Flame X
Low Purge Requirement X
Well Characterized Operation X X
Introducing the nViro-XSR
Easier to Operate | Easier to Install | Lower Utility Cost
12
Superior Steam Requirements
Single Steam Connection
No Additional Muffler
RequirementLow Operating Temperature Tip
High Stability Flame
Increased Hydraulic Capacity
No Premix Air
1 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
2 4 5 6
6
5
.0 M
.1 M
.2 M
.3 M
.4 M
.5 M
.6 M
.7 M
nViro-XSR Other Inner Steam Upper Steam
Op
era
tin
g C
os
t (M
illio
ns
US
D/Y
ea
r)Five-Year OPEX Comparison
Smoke Suppressing Steam [$/yr]
Standby Steam [$/yr]
Purge Gas [$/yr]
Makeup Gas [$/yr]
Visible Emissions Violations [$/yr]
nViro-XSR: Reduced Operating Cost
A Flare Tip with an ROI
13
Note: Based on average flaring behavior of 2005-2015 SCAQMD refineries with 2 flares assumed and optimal flare selection. OPEX is per flare.
Standby steam rate for ‘Competitor’ is assumed based on general practice.
Product Comparison Matrix
14
Feature nViro-XSR API 521 Average
Steam-to-Hydrocarbon Ratio (Propane) 0.18 0.30
Steam-to-Hydrocarbon Ratio (Propylene) 0.20 0.55
Vent Gas Flow at Smokeless Maximum / Maximum Flow (Propane) 37% 22% *
Vent Gas Flow at Smokeless Maximum / Maximum Flow (Propylene) 33% 12% *
Minimum Keep Cool Steam (lb/hr) 0 N/A
Minimum Keep Warm Steam (lb/hr) 30 N/A
Maximum Rate Steam Noise @ 500 ft w/out Muffler 83 N/A
Standby Rate Steam Noise @ 500 ft w/out Muffler 77 N/A
Demonstrated Maximum Smokeless Rate in Test (Propane lb/hr) 216,000 N/A
Demonstrated Maximum Smokeless Rate in Test (Propylene lb/hr) 137,000 N/A
Nominal Size of Demonstration Tip 24 N/A
*Publicly published S/HC ratios. Smokeless maximum is based on ratio of S/HC to the nViro-XSR.
Note: Smokeless maximum based on a 5 Psig back pressure limit.
UOP 8133-14
Steam/Hydrocarbon Ratio - Propane
15
• Moderate-high wind
• 28,062 lb/hr steam
• 155,797 lb/hr vent gas
• 0.18 S/HC ratio
1 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
UOP 8133-15
Steam/Hydrocarbon Ratio - Propylene
161 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
• Moderate-high wind
• 27,575 lb/hr steam
• 136,836 lb/hr vent gas
• 0.20 S/HC ratio
UOP 8133-16
Standby Steam
• 90% reduction in steam usage compared
with previous generation
• Unique design uses the vent gas to
moderate the steam-line temperature
Keep Cool Steam Not Required | Ultra-Low Standby Steam
171 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
Metal Temperature vs Wind Speed, Purge Gas Flow Rate
High
Medium
Low
Win
d S
pe
ed
Low Medium High
Purge Gas Flow Rate
Temperature
Low
High
Noise
Low Noise | Integrated Muffler
Vent GasVent Gas Flow Rate
[lb/hr]
Steam Flow Rate
[lb/hr]
Noise (dBA) @
500 ft
None 0 15,403 74
None 0 27,890 83
Propane 83,352 14,369 88
Propane 197,283 26,547 94
Propylene 50,507 15,676 89
Propylene 53,895 15,404 91
181 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
Flame Stability Analysis
Stable Flame Over a Wide Operating Envelope
19
0
10
20
30
40
50
60
70
80
90
100
0 2000 4000 6000 8000 10000 12000 14000 16000 18000
No
ise L
evel
(dB
A)
Frequency
Noise Level vs Frequency (dBA)
Vent Gas Flow 161 klb/hr Vent Gas Flow 132 klb/hr Vent Gas Flow 83 klb/hr Vent Gas Flow 197 klb/hr
Vent Gas Flow 164 klb/hr Vent Gas Flow 54 klb/hr Vent Gas Flow 51 klb/hr Vent Gas Flow 143 klb/hr
Vent Gas Flow 156 klb/hr Vent Gas Flow 137 klb/hr Vent Gas Flow 105 klb/hr
1 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
Scaling
Available in Nominal Sizes 24” to 60”
20
Available Sizes
Smallest
Mid-Size
Large
1 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
Increased Hydraulic Capacity
• The flare tip discharge coefficient reduces
as the steam flow rate increases
• The result is more vent gas capacity with
a lower back-pressure compared to a
fixed orifice
Lower Discharge Coefficient at Higher Flow Rates
21
0 50000 100000 150000 200000 250000
Tip Efficiency vs Flow Rate
1 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
Summary
The nViro-XSR:
• Extensively tested
• Designed to comply with 40 CFR 63.670
• 0.18 S/HC burning propane vent gas
• 0.20 S/HC burning propylene vent gas
• 37% smokeless capacity for propane
• 33% smokeless capacity for propylene
• Low noise with little noise below 500 Hz
• Integrated muffler design
• Low standby steam proven with thermocouple data and analysis
• Increase flow with unique hydraulic capacity increase
• Potentially reduce OPEX 3.6 – 24x vs other technology
22
UOP 8133-22
1 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity
Summary
23
.0 M
.1 M
.2 M
.3 M
.4 M
.5 M
.6 M
.7 M
nViro-XSR Other Inner Steam Upper Steam
Op
era
tin
g C
os
t (M
illio
ns
US
D/Y
ea
r)
Five-Year OPEX Comparison
Smoke Suppressing Steam [$/yr]
Standby Steam [$/yr]
Purge Gas [$/yr]
Makeup Gas [$/yr]
Visible Emissions Violations [$/yr]
UOP 8133-23
1 Pilots
2 Smoke
3 Velocity
4 NHVcz
5 NHVdil
6 Capacity