esbo nanya
TRANSCRIPT
-
8/18/2019 ESBO Nanya
1/12
H
H
E
HPI# ng{'n'€ FRaIE-l
NAN YA PLASTICS CORPG'RATION
-
8/18/2019 ESBO Nanya
2/12
Epoxidized
Soybean
Oil
ESO
132,ESO
-
132D
Introduction
Physical
& Chemical
Properties
Characters
Applications
& Description n PVC
Processing
Packing
& Operation
Material
SafetyData
Sheet
MSDS)
Appendix
. JHPA
CertihcateFor ESO
-
132,ESO-I32D
-
8/18/2019 ESBO Nanya
3/12
Epoxidizedoybean
il
ESO-132,aproductafter
oxidation f soybeanil
,
is widely
sed
snon-toxic
stabilizernd
plasticizer
n
PVCprocessing.
The
production
echnology
is based n hecooperation
between anYa and
Nippon
Sanwa osei.
ESO-132D
Deodorized
Epoxidized
oybean
il),
madeof SO-132bya
series f deodorization
purifications
s
produced
o
meethespecialequestsn
some pplications.
-
8/18/2019 ESBO Nanya
4/12
Chemical
Name
Eooxidized
ovbean il
I{,C
-
O
-
C
-
C
-(CHr)x -
CH
-
CH
-
R
| \ / /
Hl
-
o
-
c
-
c
-(cH,)x
cH cH R'
I lC-O-C-C-(CH,)x-CH
_CH
o
MolecularWeisht
MeltedPoint
>
150i5mmHg
oiling Point
3r5.6
SpecificGravity
0.982 1.002
25'C
400
a
50 cps
25t
)
Weight
Loss after Heating
Refractive ndex
t.470 0.0022st )
Color
Number
200
APHA)
6.4-6.8o/oxiraneOxygen
Iodine Value
-
8/18/2019 ESBO Nanya
5/12
l. Non-toxic
BesidesheapprovalromJHPA,PL specification.7,
tem (Approval
o.
J-7885), lso
meet
trict
FDA equirement,ccordingo thestipulationsnFoodAdditives18 .27 nd175.300).
ESO 132andESO 132D canbeusedn association
ith
stabilizers.or
example,hecombination
between a-ZnandCa-Zn eries tabilizers
ith ESO, s in
non-toxic pplications.hisnon-toxic
combination ill
be
hemainstreamn PVC
processing.
2. Heat stability and Weather
-
resistance
Thesynergisticffect anbeexpectedn case fthe combination ith metal
eries tabilizers.
hanks
to the
capability fthe active poxy
ing o catchHCI and ts antioxidation
ffect gainst egradation.
After heating nd ight exposure,hecross-linkingmong VCmolecules
anbeminimized.
Namely,hebig-scale nhancementn both
heat tability nd
weatheresistanceor PVC
products
an
beexoected.
3.
Low
volatility and High molecule
plasticizer
Much
ower n volatility han
DOP
about
0%of DOP), t
provides
etter tabilityn PVC lexibility.
With aboutM.W. 1000,ESO 132canbe egardedsa
good
plasticizer
n
PVC
processing.
4. Low I.V., Good in non-migration
esistance
nd extraction esistance
Low
I.V.,
good
ompatibility ith PVC
Plasticizers,t therefore rovides oodperformance
n non-
migration nd
extraction
esistance.
5. Water
-
resistance,Oil
-
resistance nd
Low
loss n transparency.
-
8/18/2019 ESBO Nanya
6/12
ApplicationsFormulas
PVCLeather'.llm.
Coatingnd
Ertmsion
Fi lnrsbl
packing
\on-tor ic
Description
.
Better
cat-r'csislanccn conrbinrtiour th nletrl stiibilizcrs .
a
Irrpro\
ng transfatcnc)'.
e Suguestcdosagc .5 - 1.0 PHR.
o
I'rrpcrlr tblrrLrlatirg r th DO.\
or
DINA.
uscdasanti-
l l r ' .z i r ' l r l . r ' t iz,
'
i r P\
(
|
'
'
.
o
Srrggestct llosauc(1.( l 10.0PHR.
r
Appl icrblc n
combinat ion
\
lh Bl-Zn. Ca-Znslabi l izcrs.
o
Suggestecilosage
o
PVC Lel ther . l lnr : . ( l l . ( l PHR.
oToys
ancl nject ion roducts:
1.( l 5.0
PHR.
r
Good o bc pplicd in non toric
PfodLlct\-
Lrchs to]-s.
glo\
c etc.
r
(irxxlrrc(ing
to color
urrtlcr.
o nhanceonrl)alibilil
\ ith
I ' \ ' ( poir
lcr
l icr
blcnding
i th DOP.DI\P
and
DIDP.
o
Rcducing onrpouncl in{iscosi tv t icrmir ing $ i th
inolgunic
ignrcnts.
r
Suggcstccloslgc:
i .0
6.0 ' l lR.
o
Appl icrble o iorking i th Br Zn sel ies tabi l izels.
r
SLrggcsledosrge:1.0 1.0PI R.
o
Widclv
uscdascor clrgc lil nr in ugricullure ndcxterior
hydrolvsis-rcsisliinc.
lolh.
o
, \ppl icablen corrbinat ioni th stabi l izcls.o rnake
rp
thc stabilitv n illc leturilrtion irr
Sb,O,
ancl lrO,.
. Suggcslcdosagc: .0
-s.0
l lR.
r
In
pair
ith
poli"estef-tlle hsticizeN
o enhanceon nrigntiol.
o Suggcstcdlosage ccordingo diftcfent
prodrrcts:
o
Non-nigrat ion able ncl i re
5.0
I0.0 PHR.
eGasket f le i i igelator :
bout 0 PHR.
r
,\pplicablc n pair r
th TOT1\'1o l s 1o nhrncc inli-
firi.rrintpr.oducts.
o
\Lr ' - r . :c. tcJ
l , r . : r : t - . :
t t .
0 { l
PHR
o
\Vi ld l l 'appl icd
n crr
prncl products.
r
Couplingu'ith polyester ) \\ 'ork s a plasticizcrbr
solr.ent ndoil resistantbrmLrlas.
.
Suggestedosage: .0 5.0PHR.
o
Wildlv
uscd n l lexible ubcs.
&
Toncr&
\'iastcr atch
Anti-weathel'
Non-nr israt ion
F re-retuldat ion
.,\nti fbgging
Low cxtractior'l
tbrrnLrlas
-
8/18/2019 ESBO Nanya
7/12
Packing
and Notices
,F
a
In
use
l .
Fol ' \ ' (
lcr th ' r .
l lnr . . .c lc.
hc
LLtgcstcd
osage
o nr() fc
l l rn
1.0
pHR.
i f
crceedcd.
einupr ro
blcedin-r :.
L I ior
' \
(
packinr
i l r l .
lhc nar inrunr
oslgc
hould
cbelorr
0.0
pHR
Il.
erccct lecl
bcculc l i r l
v i th
leeding.
-1.
\ 'hcn
r int inu
s rccl r rcstcd
lhe
nlrxintunr
osaqehould
cbelos
.0
Pll l l
.
i i ' crcccdcd.
hc cak
cohc'sion
cl r lccn
r int inu
nk
and
pVC
prodlrc ls
l 'nt \
entefgc.
-1.With
consicleration
l
thc
poor
n i t ia l
olor.to
\rC.
in
tcr .n ts
l ' those
ruppl ical ions
bal
n i t ia l
olor.arc
sscnt i l l
theESO
losauc
s ota l l1 , .
depcndcnt
n he
dosl lc
ol 'stabi l izer..
he ugsested
osasc
s 1.0
.0 pHR
.
5. 1.0PIIR
dosasc'\
l l
br ins h '
o i ipoint
f ' I , \ rC lorvnboLrt
'C
l :spcciu l lv.
bl r ig idP\ i t
appl ications
thc
closagehoult l
c
Lrnclerropcr.
con ro
Storage
and Transportation
l . ESO
hould
e
propcr lv
lored
t h '
crnpcrrture
clou.-15
.
Ifcxceeded.
polvmcrization
i l l rake lace
L Conti ln l inrt ionlom Lrst nd and...elci l l lead o thcpolvnrer ization.t
is suggcsted
o pu1
rct i l l
creen
28
mcsh
min.)
n the ents
f
arrsroragc
tanks.
he egular
lcaninrr
f the
ntcta l
creen
hould
cclonc.
i . Bclorr
0
.C.
the
iscosi t l
f EsO
sour .s
p. f lor ierthan
5
,C.
i t is
n thc
paslc
irm
(l ike
arul) .
l is
eas),to ct
hard
n pipe
ranspoftation.
eatins
t
up o.l5
nta\ .can
ase
ff theproblcm.
Safety
L Skin
contact ral
carrse
rr i tat ion.
spccial ly
o thosc
skjn- l l lcrgic
peoplc.
l l
conl i tcted.rash
ol l 'contuninat ion
\ ' i th
soup
and \ , r ter .
cck
ntedical
l l lcnt ion
i f
i t r i tat i r rn crsisrs.
L
l l 'cvc
cont i rcteci .insc
ir l l5
nt inutcs
nininrunt
i th
a
gcnt lc
water
strei lnt .
obl l in nrcdical
t tenl ion f the
syntptonls
crsist .
Packing
L Loldcd
n 53-gallon
ror
dr.um.
00ku
ncrpcr
drum.
2. SO
ank
vai lable.lMT
per
et
raccording
ontnct .
-
8/18/2019 ESBO Nanya
8/12
L lvlanufacturer/
Manufacturer
Supplier
Name HP Plant Plastics th Division NanYa Plastics
orporation
ManufacturerSupplierAddress20l,Tung
waN. Rd.,Taipei, aiwan,
.O.C.
Consultants ameandPhoneNo. :
(02
2712221|xt .
Emergencyontact hone o.
(02)
27122211xt. FaxNo.:
02)
27178530
Appearance
Clear
iquid
Vapor
ressureNA
-Er--
Specificnvity
tlo:
l) :0.982
-
1.002
Product ame Eooxidized ovbean il
Short-term
Exposure
Limit
(STEL)
Evaporationate(Ethyl cetate: ) :NA
Solubilityn
Water
0.01%
(
20t
)
-
8/18/2019 ESBO Nanya
9/12
Flash oint 600 F
TestMethod:
v)
Open up
)
Closedcup
LowerExplosion
imit LEL : No data
UpperExplosion imit
(
UEL
)
: No data
Fire Fighting
Agent
Dry
chemical
alcohol oamor carbon
ioxide.
Special ireFighting roceduresNone
Conditions
o Avoid
Hazardous ecomposition
Materialso Avoid Strone cidanddust.
(
v
)
Inhalation
v)
Skin
ontact
(
v)
Ingestion
(v
)
Eyes ontact
Skin contact
may cause rritation of the skin.
Eyescontact
will
cause
rritation
of eyes.
Inhalation
l. Removeo freshair.
2. Ifbreathing
s
difficult
,
ensure
irway s clearand
give
oxygen.
Ifnot breathinginstituteCardiopulmonaryesuscitation
CPR).
3.
Keep ffected
erson
armandat rest.
Get mmediate edical ttention.
Skin ontactIrnmediately
ash ith
plenty
f soap ndwaterwhile emoving
contaminatedlothing.
Eyes
ontact
l. Flushmmediatelyith
plenfy
fwater or at east15minutes.
Eyelids hould e
held way
rom heeyeballo ensurehoroughinsing.
2. Get mmediateedical ttention.
Ingestion I . If afiected
enon
awake,insehis(her)mouth.
2. Let
drink
plenty
fwarmwater
r
milk,
and hen nduce omiting.
3. Get mmediate edical ttention.
Emergencyesponse
&
First
Aid
Measures
-
8/18/2019 ESBO Nanya
10/12
7.
Measures
o
Prevent xposure
Pcrssnlrl
E1-r"'s\\ iear
chenticl l
sulctv
gogglcs.
Pfotcclivc
['-cluipntcnt
(i]or
es Use Lrtrbcr
lor
cs ol chenricul
lolccl ir
c
l loves.
Vcnt i l l t ion Equip ,ent i lat i r cclLl i ln ' rcnlr
l rc i l i t r . Kccp
ir l icsh.
l l lndl inq &
Slorasc
Should e
stotedundcr
{5
C.
Prccattlions
I . Placc onta niniltedlothin_l
n closcci ontaincr
irr slolagc Lnti launder.cdI dirclrrrlcLl.
l
clL,thrr.-:
is o be aundcradinlir lrn
pclson cl l i l rninu
opcralion f contaminanlhrz;rrdorrs
'rr,rper
ir
'
Pcrsonal
l . Do notcr t . d l ink.
snroke. lncl ur l r ' l rshteln rolk ing
arcas.
| |y- rcnc
J.
After handling washhands horoughl\.
,1.
Kccp he l'orking tcrts
lcan.
8. Responeo Spill andWaste
Disposal
I Isolatc
hc
cont i l r l inuted
rcus
i
i th in sund
caf ihor c lout o bui ld
enrpolulvl ikc:
I--nrc'rgcncl
in cast' l ' lc'akruc
nlir lgc.
I lcsl tonc o
Slt i l ls
l .
L.sc'c loLr t
o i rbsolb pi l l
or
r rsc. inr i lur rc lhrxl
o l fe i r t Nn( l hcn rrc inc| l tc hecLrLr l r
-1.
C can
i
it l t
sorp and llcf.
\ \ ' i rstc i :pu. l l
lnc
n
e
r r r . '
ML-thods
9.
Transportationnformation
Llni lcd
Nat ion
NLrnrbcr ' ( l . lN.No)
Hazard
( ' lassi l lcl t ion
I lazard abcls
I : l . t l t t t l r tb le
l . iquid
10. nformation
of
MSDSheparation
\anre : \ul Yu Plltstics orporation
(
)r 'ganzrt on
that
f rc lared
. \ddress Fornrosn
ldrrst l i i r l' i r lk o.
I . \ la i l i ro. \ iLn] inCountr .Tl i r ran I l .O.( .
IhC { SDS
Telephonc
(05
68l l - .1-+5\1.
Pclsnn hu
pr.p,u.r i, f ' , .
niSOS
lob Tit lc : SafiyanclSanit
ior Munrgcr
Nanrc SuYu-lVling
Dalc hcMSDS
Dav:0.1
l \ lonth: . lunc Ycur ' :1999
\\ ls
prcpaleo
-
8/18/2019 ESBO Nanya
11/12
HiTtrE
J 7 BB5
Aftn'r+li
|
|
+
2 ,H o El
,tJif
l 'Ll: l : ; ld,F;=ii l : t ' t ')c7"+t;EE
,=il
i +
rF
*
6i
* +
a
rr"
Y.
=
)
v
jl
B? f: iAE
7":r f,.1: iH
u
fr
*Et6
(Jllp+n
f
)
i:
i-iit
L
-aL
'.7r
u-:a
ft.if.l-:
I:
l:rlEi
4.
'Fr [
l1
1l - -
2)l
l5R
) i rv
' .Li i t i t r ' ,
2. \42
'+
HCCffi
=L U
l l r : l
(FOI{ I
3
,
lNtr".
EIt
c
=
)v#lEE#A
i
6 e*E*+
(;
F€
6 E
+*Ei*
EE
E
=aB
=r
HtrSryIfltiiE,,EilFl
{ i"}fsiftlit
t-,
.J<
rF
trt.ru
tr:v
Fq€
+*t l
q, ( [Hi l
tfiffia
(ffifi8)
LSO- 132
i lSO-1:J2D
-
8/18/2019 ESBO Nanya
12/12
al
t't
Printed on Nan Ya PP Synthet ic
Paper.
Pleasedo not mix
wilh other
9ene6l
paper
ecycle.
(1999.09.1000)
ffi H lE flgr # Hlfi€ [Rr*=l
NAN YA PLASTICS
CORPORATION
201, UNHWA
N. ROAD. AIPEI,AIWAN,
.OC.
TEL:
O2\
712-2211