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Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York. R. Paul Philp, Ph. D., D.Sc. May 4, 2010 Expert Report

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Page 1: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City

Park, Long Island, New York.

R. Paul Philp, Ph. D., D.Sc.

May 4, 2010

Expert Report

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Introduction

Stable isotopes have become an important tool in environmental investigations in the past two decades (Philp and Kuder, 2006). The development of the combined gas chromatograph­isotope ratio mass spectrometer (GCIRMS) permits carbon isotope values to be determined on low ppb concentrations of contaminants in groundwater samples. Carbon exists as two stable isotopes, 12C and 13C with a natural abundance of approximately 99:1. Organic compounds derived from different sources that have not been altered in any way, can be expected to contain different proportions of these two isotopes and hence have different isotopic compositions, or

o13C ratios, which are the source signatures. Therefore the first use of the isotopes is as a tool to differentiate possible sources of contaminants. A second application of these ratios is to monitor the onset and extent of biodegradation. In general as a compound degrades it becomes enriched

in the heavier isotope and hence its o13C ratio becomes less negative. This isotopic enrichment along with the presence of degradation products is clear evidence for biodegradation, or natural attenuation. If the trichloroethylene (TCE) is produced as a degradation product of perchloroethylene (PCE) one would anticipate an isotopic difference of 2-3 per mil between them. If the enrichment of the TCE is significantly more than 2-3 per mil and there are no degradation products present, then the TCE is most likely derived from a separate source. The use of stable isotopes has become well established in environmental investigations and many papers have been published in the peer reviewed literature (See Philp and Kuder, 2006 and Philp and Jarde, 2006 for extensive lists of published articles).

In the present investigation, groundwater samples were collected in 2005 from 7 monitoring wells from a site referred to as the Fulton Ave. site in order to ascertain whether or not TCE in the Garden City water supply wells 9, 13 and 14 could have originated directly, or indirectly, from the Fulton Ave. property. TCE can either be derived from a direct release or as a degradation product of PCE. If it is formed from degradation then one would also expect to see the presence of 1 ,2-cis-dichloroethylene ( 1 ,2-cis-DCE) and possibly vinyl chloride, depending on the extent of degradation. In this study carbon isotope values were determined and used to evaluate potential origins of the TCE.

Information relied upon in forming the opinions formed in this report

The information utilized in preparing this report is listed below and copies of these reports and tables are attached in the Appendix II.

l.Report on Carbon Isotope Study, 150 Fulton Avenue, prepared by Tomasz Kuder (Dec 10, 2006).

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2. Figure 1, Well Locations, 150 Fulton Avenue, Garden City Park, NY (ERM, April 13, 2010)

3. Figure 3-1, Water Table Elevation and Potentiometric Surfaces of Upper and Mid-Magothy Aquifer 11 & 13 December 2001, 150 Fulton Avenue, Garden City Park, NY (ERM, Oct 12, 2004)

4. Figure 2, Areal Extent of Chlorinated VOCs in Groundwater, 150 Fulton A venue, Garden City Park (ERM, Dec 24, 2009)

5. Table 1, Groundwater Sampling Results- November 2005, 150 Fulton Avenue Site

6. Table 2-3, List of Groundwater Wells Sampled during the 150 Fulton Avenue Remedial Investigation, Garden City Park, NY (ERM)

7. Table 1, Volatile Organics in Groundwater, 150 Fulton Avenue, Garden City, New York (October/November 2005)

8. Appendix A, Nassau County Department of Health, Public Supply Well Sample Results (Well No. N-07058)

9. Appendix A, Nassau County Department ofHealth, Public Supply Well Sample Results (Well No. N-08339)

10. Laboratory Reports for samples at Well13, Holzmacher, McLendon and Murrell, P.C. (9/23/1980; 9117/1981; 9/2111982; 911511983; 12112/1984; 6/24/1985; 5/1311986)

11. Laboratory Reports for samples at Well 14, Holzmacher, McLendon and Murrell, P.C. (10/411979; 12/5/1980; 11/16/1981; 10/14/1982; 11/3/1983; 11/25/1984; 6/4/1985; 5/27/1986)

QAJQC Procedures for GCIRMS Analyses of PCE/TCE samples.

The most important part of our operational procedure is the use of internal and external standards of known isotopic composition. Whether the standards are run externally or internally depends upon the complexity of the mixture. We have to ensure if used as internal standards, they do not co-elute with any compounds indigenous to the sample. If the standards are run externally, basically this means we run them several times during the course of running the unknown samples. Since the isotopic values are known, if these values are not obtained as the standard is run, no additional samples are analyzed until the appropriate values for the standards are obtained.

PCE and TCE are extracted from the water samples using purge and trap (PT) interfaced to the GC-IRMS system.

Quantitation limits (GC at 55°C. isothermal):PCE, TCE 3 ppb per 25 ml sample.

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Purge and Trap: Model OI 4560; trap: Vocarb 3000; purge 12 min, sample at 25°C, desorb 5 min @ 180°C, bake 20 min @ 220°C; PT transfer line coupled to GC column with a liquid nitrogen cryofocussing interface; carrier gas flow during desorption 25 ml/min.

GC Conditions: Instrument: Varian 3410; He carrier gas; column DB-MTBE, 60 m x 0.32 mm i.d., film thickness 1.8 J.!m; flow rate 2 ml/min. at ambient temperature, constant pressure mode; analysis - isothermal at 40 °C for 10 min., then cleaned at 21 0°C for 15 min.

Combustion reactor conditions: Thermal conversion takes place in an alumina tube with 3 oxidized Ni wires and 2 Pt catalyst wires, with auxiliary oxygen trickle, at 980°C.

Mass spectrometer conditions: Instrument: Finnigan MAT 252; 13C/12C configuration.

~The isotopic composition of the samples was measured relative to C02 standard that was introduced directly into the ion source as a series of pulses. Daily standards of PCE/TCE are run to check PT -GCIRMS performance. Standard deviation of standards calculated from runs collected over several week period are expected to be in the +/- 0.2 per mil range for o13C. Selected samples are run as duplicates.

Summary of Opinions

1. Monitoring well (MW) 26G does not contain detectable levels of DCE, suggesting the presence of unaltered TCE and PCE in that well. The isotopic difference between the PCE and TCE is too large to suggest that the TCE is coming from the PCE. If the TCE were derived from the PCE one would expect a 2-3 per mil difference in the isotope ratios of the PCE and TCE. Furthermore if the TCE were derived from PCE one would also anticipate the presence of degradation products, such as cis-1 ,2-DCE which is absent from this well.

2. MW 23C has very low concentrations of DCE, indicating a small level of degradation. The isotopic difference between PCE and TCE is less in MW23C than in MW26G, which is also supportive of the early stages of degradation. The concentration of TCE>PCE and the relative proportions of PCE and TCE are similar in both MW23C and 26G.

3. It is my opinion that in all probability the TCE and PCE in MW 23 and MW 26 are coming from the same source, and that is a different source than the Fulton Ave. plume. The concentration ratio of TCE> PCE reflects the ratio in the original source and the TCE is not derived from the PCE in either of these wells. This is an original source signature.

4. It is my opinion that based on the location of MW 23C and 26G and Garden City supply well #9, plus the relative proportions of TCE and PCE, that the supply well #9 has been impacted by the same plume detected in MW 23C and 26G which is a separate plume from the Fulton Ave. plume.

5. In the other 5 wells (GCP01; GCP08; GCP18S; MW15A; and MW21C), which are located along the plume from the Fulton Ave. site, it would appear that the contaminants

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in all of these wells have been affected by varying degrees of biodegradation. This is evidenced by both the presence of degradation products and isotopic enrichment of the PCE and TCE in a number of the wells.

6. In view of well locations and direction of groundwater flow, if only PCE was released at Fulton Ave. then in all probability at least some of the TCE in the Fulton Ave. plume is derived from the degradation of PCE. The DCE could be derived from either, or both, the PCE and TCE.

7. The most extensive degradation of PCE is in the area of monitoring well GCP18S which has the most isotopically enriched PCE and TCE along with relatively high concentrations of DCE.

8. Based on the isotopic enrichment of the TCE and DCE, and the presence of vinyl chloride, monitoring well GCP08 shows extensive degradation of both TCE and DCE. While the PCE appears to show an unaltered isotope signature, any degradation of the PCE may be masked by the addition of unaltered PCE in this well.

9. As you move further down-gradient, monitoring well 21 C does not show enhanced concentrations of DCE or TCE. If all other things are equal, DCE moves faster than TCE and TCE faster than PCE. However in well 21 C the concentrations of all the compounds are much lower than in the upgradient wells. The isotope values suggest that while degradation has occurred it has not been extensive. Since MW21 C is closest to the Garden City supply wells 13 and 14, if the Fulton Ave. plume was impacting those supply wells in 2005, similar distributions of the contaminants could be expected in all three of these wells, which is not the case.

10. The PCEffCE concentration ratio in supply wells 13 and 14 is relatively constant in 2004 up until Nov. 2005. After Nov 2005, the PCE/TCE ratio starts to increase and in May 2007 cis 1 ,2-DCE starts to appear. In 2008 1, 1-dichloroethylene (1, 1 DCE), another degradation product of PCE, starts to appear. Based on these observations it is my opinion that prior to 2006, the degradation products in the Fulton Ave. plume did not have any significant impact on the Garden City supply wells 13 and 14.

11. Prior to that time period it is virtually impossible to say with a reasonable degree of scientific certainty based on the isotopic data that the TCE in the Garden City supply wells, 13 and 14, was coming from the Fulton Ave plume.

12. The concentration data for the supply wells 13 and 14 indicate that the concentration of the TCE was greater than that of PCE in virtually all samples, similar to that observed in MW23 and 26. It is unlikely in my opinion that you can say prior to 2005 that the TCE in the Garden City supply wells 13 and 14 was coming from the Fulton Ave. plume in the absence of degradation products in these wells and the fact that only PCE was released at Fulton Ave.

References.

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PHILP R. P. and JARDE, E. (2006). Application of Stable and Radioisotopes in Environmental

Forensics. In: Introduction to Environmental Forensics (B. MURPHY and R. MORRISON Eds.).

PHILP, R.P. and KUDER, T. (2006). Biomarkers and Stable Isotopes in Environmental

Forensics. (A. BALL and S. MUDGE, Eds).

Compensation

For this case my fees are $180/hour for revie\\'ing data and preparation of reports, discussions, etc. If required to give a deposition or testify then the rate is $250/hour.

Previous Cases, Depositions and Testimony.

1. Giley, et al., v. Kansas Gas Service Company, Case No. 01-C-157. Case related to the gas explosion in Hutchinson Kansas. Deposed Feb. 251

h, 2004.

2.Smith!Giley, et al., v. ONEOK. Case related to the gas explosion in Hutchinson Kansas. Testified Sept. 81

h, 2004. Kansas City.

3. Port ofVancouver, USA v. Cadet Manufacturing Company. Deposed in August, 2005.

4.Richard Bard et al., v. Reynolds Metals, Cause No. 37,761. District Court of Wharton County, Texas, 23rct Judicial District. Deposed May 2004.

5. Prices et al. v. Plum Creek Timber Company. Cause No. DV -03-402B. Montana Eleventh Judicial District Court, Flathead County. Deposed 2007. Settled out of court.

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Appendix I. Resume and Publications

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R. Paul Philp, Professor School of Geology and Geophysics,

The University of Oklahoma, Norman, Oklahoma, 73019.

Tel: (405)-325-4469 Fax: (405)-325-3140

E-mail: [email protected]

Date of birth: 26 August, 1947

Place of birth: Plymouth, Devon, England

Countrv of citizenship: USA

Address: School of Geology and Geophysics University of Oklahoma, Norman, Oklahoma 73019

Education

D.Sc. 1998 University of Sydney, Australia Ph.D. 1972 University of Sydney, Australia B.Sc. 1968 University of Aberdeen, Scotland

Professional Experience Professor ofPetroleum Geochemistry, University of Oklahoma. June 1987-to date Interim Director, School of Geology, University of Oklahoma. Jan 1987 to July 1989 Associate Professor ofPetroleum Geochemistry, University of Oklahoma, June 1984-July 1987. Principal Research Scientist, C.S.I.R.O., Sydney, Australia.Dec.1977-June 1984. Associate Research Chemist, University of California, Berkeley, California. January 1974 -December 1977. Post-doctoral fellow, University of Bristol, England. Post-doctoral fellow. March 1972 -December 1973.

Research Interests: Petroleum, Environmental and Forensic geochemistry with the emphasis on molecular and isotopic characterization of oils, gases, rock extracts and contaminants for the purposes of source determination, characterization of depositional environments, maturity, biodegradation and for correlation purposes.

Professional Activities: American Chemical Society European Association of Organic Geochemists Association of Latin American Geochemists

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Awards George Lynn Cross Research Professor, University of Oklahoma, April 1990. Assoc. Editor of Chem.Geol. Regents Award for Outstanding Research, University ofOklahoma, April, 1989 Joe and Robert Klabzuba Professor of Organic Geochemistry, University of Oklahoma, July 1984-Best Paper of 1974-1975 award presented by the Organic Geochemistry Section of the Geochemical Society

Additional Information

In addition to presenting papers at a number of International meetings listed in the attached abstracts list, I have taught a number of Petroleum and Environmental Geochemistry courses in the following countries and to the following companies: Yacimentos Petroleo Fiscales, Buenos Aires, Argentina; China at invitation of Academia Sinica to lecture at various institutes and universities; Japanese National Oil Company in Tokyo; Petrobras, Brazil; New Zealand Geological Survey on petroleum geochemistry; INTEVP - Caracas, Venezuela; Taiwanese National Oil Company, Taipei; Tanzanian Petroleum Development Corporation, Dar­es-Salem, Tanzania; Peruvian National Oil Company; ARAMCO, Saudi Arabia; Ecopetrol Colombia; Petronas Malaysia; Indonesian Petroleum Association; Shengli oil field China; Petrovietnam, Hanoi and HoChiMinh City; Sonatrach, Algeria.

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Bibliography

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2. KIMBLE, B.J., MAXWELL, J.R., PHILP, R.P., EGLINTON, G., ALBRECHT, P., ENSMINGER, A., ARPINO, P. and OURISSON, G. (1974). Tri- and tetraterpenoid hydrocarbons in the Messel oil shale. Geochim. Cosmochim. Acta., 38, 1165-1181.

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5. EGLINTON, G., MAXWELL, J.R. and PHILP, R.P. (1974) Organic geochemistry of sediments from contemporary aquatic environments. In: Advances in Organic Geochemistry 1973, (eds. B. Tissot and F. Biener), Editions Technip, Paris, 1974, pp. 942-961.

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10. PHILP, R.P. and CALVIN, M. (1976). Possible origin for insoluble organic (kerogen) debris in sediments from insoluble cell-wall materials of algae and bacteria. Nature, 262, 134-136.

11. PHILP, R.P. and YANG, E. (1977). Alkaline potassium permanganate degradation of insoluble organic residues (kerogen) isolated from recently-deposited algal mats. Energy Sources, J.(2), 149-161.

12. PHILP, R.P. and ROBERTSON, A.V. (1977). Cyclic hydroxycarboxylic Acids. II. Lactonization reactions on 2-hydroxycyclopentanecarboxylic acids and 3-hydroxyprolines. Aus. J. Chern., 30(1), 123-131.

13. PHILP, R.P. and ROBERTSON, A.V. (1977). Cyclic Hydroxycarboxylic Acids. III. Tosylation studies on mono- and dihydroxycyclopentanecarboxylates and mono- and dihydroxyproline. Aus. J. Chern., 30( 1 ), 131-141.

14. PHILP, R.P. and ROBERTSON, A.V. (1977). Cyclic Hydroxycarboxylic Acids. IV. Synthesis of 2,3-cis-2,3-dihydroxycyclopentanecarboxylic acid derivatives. Aus. J. Chern., 30(2), 437-442.

15. PHILP, R.P. ( 1977) Recent advances in the study of potential kerogen precursors from recently-deposited algal-mats. A. C. S. Division of Fuel Chemistry Preprints, 22(3 ), 177-182.

16. PHILP, R.P. and CALVIN, M. (1977). Kerogenous material in recent algal mats at Laguna Mormona, Baja Californa. In: Advances in Organic Geochemistry 1975 (Eds., J.A. Gomez Angulo and R. Campos), Endimsa, Madrid, pp. 735-752.

17. NISHIMURA, HIROYUKI, PHILP, R.P. and CALVIN, M. (1977). Lipids ofHevea Brasiliensis and Euphorbia Coerulescens. Phytochemistry, lQ, 1 048-1049.

18. BROOKS, P.W., EGLINTON, G., GASKELL, S.J., MAXWELL, J.R., McHUGH, D.J. and PHILP, R.P. (1977). Lipids ofRecent Sediments. Part II: Branched and cyclic alkanes and alkanoic acids of some temperate lacustrine and subtropical lagoonal/tidal flat sediments. Chern. Geol., 20, 189-204.

19. PHILP, R.P. BROWN, S. and CALVIN, M. (1978). lsprenoid hydrocarbons produced by thermal alteration of Nostoc muscorum and Rhodopseudomonas spheroides. Geochem. Cosmochim. Acta, 42, 63-68.

20. PHILP, R.P., BROWN, S., CALVIN, M., BRASSELL, S. and EGLINTON, G. (1978). Hydrocarbon and fatty acid distributions in recently deposited algal mats at Laguna Guerrero, Baja California. In: Environmental Biogeochemisty and Geomicrobiology Vol. l, (Ed., W.E. Krumbein). Ann Arbor Science, Michigan, pp. 255-270.

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21. PHILP, R.P., CALVIN, M., BROWN, S. and YANG, E. (1978). Organic geochemical studies on kerogen precursors in recently deposited algal mats and oozes. Chern. Geol., 22, 207-231.

22. PHILP, R.P. (1978) Recent studies on the origin and structure of possible kerogen precursors. In: Proceedings of the Second Joint CIC-ACS Conference, Montreal, Canada, 1977, (Ed., 0. Strauz), Verlag Chemie International, Inc., New York, pp. 325-344.

23. PHILP, R.P., BROWN, S. and CALVIN, M. (1978). Saponification of the insoluble organic residues from oil shales, algal oozes and algae. Energy Sources, 1(2), 113-125.

24. BRASSELL, S.C., EGLINTON, G., MAXWELL, J.R. and PHILP, R.P. (1978). Natural background of alkanes in the aquatic environment. In: Aquatic Pollutants (Eds., 0. Hutzinger, I.H. van Lelyveld and B.C.J. Zoeteman). Pergamon Press, Oxford and New York, pp. 69-86.

25. PHILP, R.P. and GILBERT, T.D. (1980). Application of computerized-gas chromatography-mass spectrometry to oil exploration in Australia. APEA L 221-228.

26. VAN DE MEENT, D., BROWN, S.C., PHILP, R.P. and SIMONEIT, B.R. (1980). Pyrolysis-high resolution gas chromatography and pyrolysis gas chromatography-mass spectrometry of kerogens and kerogen precursors. Geochim. Cosmochim. Acta, 44, 999-1013.

27. PHILP, R.P. (1980) Comparative organic geochemical studies of recent algal mats and sediments of algal mats and sediments of algal origin. In: Biogeochemistry of Ancient and Modem Environments (Eds., P.A. Trudinger, M.R. Walter and B.J. Ralph), pp. 173-185.

28. PHILP, R.P. and RUSSELL, N.J. (1980). Pyrolysis-gas chromatography-mass spectrometry of batch autoclave products derived from coal macerals. In: Advances in Organic Geochemistry, 1979. (Eds., A. Douglas and J.R. Maxwell) Pergamon, Oxford, pp. 653-661.

29. PHILP, R.P. and SAXBY, J.D. (1980). Organic geochemistry of coal macerals from the Sydney Basin (Australia). In: Advances in Organic Geochemistry, 1979. (Eds., A. Douglas and J.R. Maxwell). Pergamon, Oxford, pp. 639-651.

30. GILBERT, T.D., PHILP, R.P. and RUSSELL, N.J. - Characterization of coals by pyrolysis-gas chromatography-mass spectrometry. In: "5th Australian Workshop on Coal Hydrogenation", (1980) pp. 7-8-7-11.

31. PHILP, R.P., GILBERT, T.D. and RUSSELL, N.J.- Characterization of coals- derived products by thermal distillation-gas chromatography-mass spectrometry. In: "5th Australian Workshop on Coal Hydrogenation". (1980) pp. 4-3-4-7.

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32. RULLKOTTER, J. and PHILP, R.P. (1981). Extended hopanes up to C40 in Thornton bitumen. Nature, 292, 616-618.

33. PHILP, R.P., GILBERT, T.D. and FRIEDRICH, J. (1981). Bicyclic sesquiterpenoids and diterpenoids in Australian crude oils. Geochem. Cosmochim. Acta, 45, 1173-1180.

34. PHILP, R.P., RUSSELL, N.J. and GILBERT, T.D. (1981). Hydrogenation of Tasmanian alginite - analysis of hexane-soluble products by thermal distillation - gas cchromatography-mass spectrometry. Fuel, 60, 937-944.

35. PHILP, R.P. (1981) Diagenetic organic matter in Recent sediments and environments of deposition. BMR J. Aust. Geol. and Geophys., .Q, 304-406.

36. PHILP, R.P. (1981). Organic geochemical studies ofRecent algal mats, coals, shales and Precambrian sediments. In: The Impact of the Triebs Porphyrin Concept on the Modem Organic Geochemistry (kEd., A.A. Prashowsky). Halbigdruck, Wurburg, pp. 159-182.

37. GILBERT, T.D. and PHILP, R.P. - A study of brown coal formation by pyrolysis-gas chromatography-mass spectrometry. In: "6th Australian Workshop on Coal Hydrogenation. Abstracts and Papers." (1981), pp. 7-1- 7-4.

38. PHILP, R.P., GILBERT, T.D. and RUSSELL, N.J. (1982). Characterization by pyrolysis-gas chromatography-mass spectrometry of the insoluble organic residues derived from the hydrogenation ofTasmanites sp. oil shale. Fuel,.Ql(3), 221-226.

39. PHILP, R.P. and GILBERT, T.D. (1982). Value of organic geochemistry to petroleum exploration. Australian Energy Review, 3-6, May.

40. PHILP, R.P. GILBERT, T.D. and FRIEDRICH, J. (1982). Geochemical correlation of Australian crude oils. APEA J., 188-199.

41. NOMURA, M., YOSHIDA, T., KIKKAWA, S., and PHILP, R.P. (1982). Effects of petrographic constituents in three Yalloum brown coal lithotypes on hydroliquefaction processes. Fuel, 61(5), 472-473.

42. PHILP, R.P. (1982) Application of pyrolysis-GC and pyrolysis-GC-MS to fossil fuel research. Trends in Anal. Chern., 1(10), 237-241.

43. PHILP, R.P. and GILBERT, T.D. (1982). Unusual distribution of biological markers in an Australian crude oil. Nature, 299, 245-247.

44. PHILP, R.P. (1982). Application of computerized gas chromatography-mass spectrometry to fossil fuel research. Spectra, ~(2,3), 6-31.

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45. PHILP, R.P. and CRISP, P.T. (1982). Surface geochemical methods used for oil and gas prospecting. A review. J. Geochem. Exploration, 11, 1-34.

46. PHILP, R.P., GILBERT, T.D. and RUSSELL, N.J. (1982). Characterization of Victorian Brown Coals by pyrolysis techniques combined with gas cchromatography and gas chromatography-mass spectrometry. In: Proceedings of Geological Society of Australia Coal Group Symposium entitled: Coal Resources-Origin Exploration and Utilization in Australia (Ed., C.W. Mallet), pp. 228-243.

47. PHILP, R.P., RUSSELL, N.J., GILBERT, T.D. and FRIEDRICH, J.M. (1982). Characterization of Victorian soft brown coal wood by microscopic techniques and Curie point pyrolysis combined with gas chromatography-mass spectrometry. J. Anal. Appl. Pyrol., 1_, 143-161.

48. SIMONEIT, B.R.I. and PHILP, R.P. (1982) Organic geochemistry of lipids and kerogen and the effects of basalt intrusions on unconsolidated oceanic sediments: sites 4 77,4 78 and 481, Guaymas Basin, Gulf of California. In: Curray, J.R., Moore, D.G. et al., Init. Repts. DSDP 64, Part 2, Washington (U.S. Govt. Printing Office), 883-904.

49. JENDEN, P.D., SIMONEIT, B.R. and PHILP, R.P. (1982). Hydrothermal effects on proto kerogen of unconsolidated sediments from Guaymas Basin, Gulf of California: Elemental compositions, stable carbon isotope ratios and electron spin resonance spectra. In: Curray, J.R., Moore, D.G. et al., Init. Repts. DSDP 64, Part 2, Washington (U.S. Govt. Printing Office), 905-912.

50. PHILP, R.P. and GILBERT, T.D. (1982). The role of mass spectrometry in the characterization of coals and coal-derived liquids. In: 7th Australian Workshop on Coal Hydrogenation." Abstracts and Papers ( 1982), pp. 14-21.

51. PHILP, R.P. (1982) Oil Exploration Studies. Geology-Geochemistry, 11 55-60, (In Chinese).

52. PHILP, R.P. (1983). Correlation of crude oils from the San Jorges Basin, Argentina. Geochim. Cosmochim. Acta, 47(2), 267-277.

53. COLLIN, P.J., GILBERT, T.D., PHILP, R.P, and WILSON, M.A. (1983). Structure of the distillates obtained from hydrogenation and pyrolysis of Liddell coal. Fuel, 62, 450-458.

54. WILSON, M.A., PHILP, R.P., GILBERT, T.D., GILLAM, A.H. and TATE, K.R. (1983). A comparative study of the structure of humic substances from aquatic and terrestrial sources by pyrolysis-gas chromatography-mass spectrometry. Geochim. Cosmochim Acta, 47, 497-502.

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55. PHILP, R.P. and GILBERT, T.D. (1983). Pyrolysis-gas chromatography and pyrolysis­gas chromatography-mass spectrometry. Proceedings of the First Australian Workshop on Oil Shale, pp. 76-79.

56. GILBERT, T.D. and PHILP, R.P. (1983). Triterpane stereochemistry; maturation effects due to an intrusion in Rundle oil shale. Proceedings of the First Australian Workshop on Oil Shale, pp.84-86.

57. PHILP, R.P., GILBERT, T.D. and FRIEDRICH, J. (1983). Characterization of the insoluble organic matter of coals by Curie-point pyrolysis combined with computerized-gas chromatography-mass spectrometry. In: Chemical and Geochemical Aspects of Fossil Energy Extraction. Eds., T.F. Yen, F.K. Kawahara, R. Hertzberg. Ann Arbor Science, Michigan, pp. 63-84.

58. PHILP, R.P. and van de MEENT, D. (1983). Characterization of Precambrian kerogens by analytical pyrolysis. Precam. Res., 20, 3-16.

59. PHILP, R.P., SIMONEIT, B.R.T. and GILBERT, T.D. (1983). Diterpenoids in crude oils and coals of South Eastern Australia. In: Advances in Organic Geochemistry 1983 (Eds., M. Bjor0y et al.), Wiley, London, pp. 698-704.

60. BROPHY, J.J., CAVILL, G.W.K., DAVIS, N.W., GILBERT, T.D., PHILP, and R.P., PLANT, W.D. (1983). Hydrocarbon constituents of three species of dolichoderine ants. Insect Biocchem. 13(4), 381-389.

61. BUBELA, B., PHILP, R.P. and GILBERT, T.D. (1983). Effect of microbial activity on buried cyanobacterial organic material. Geomicrobiol. J., .:2_, 231-244.

62. SANDSTROM, M.W. and PHILP, R.P. (1984). Biological mmarker analysis and stable isotopic composition of oil seeps from Tonga. Chem-Geol. 43, 167-180.

63. SMYTH, M., COOK, A.C. and PHILP, R.P. (1984). Birkhead revisited. Petrological and geochemical studies of the Birkhead Formation. Eromanga Basin. APEA J., 362-374.

64. SIMONEIT, B.R.T., PHILP, R.P., JENDEN, P.D. and GALIMOV, E.M. (1984). Organic geochemistry of Deep Sea Drilling Project sediments from the Gulf of California -Hydrothermal effects on unconsolidated diatom ooze. Org. Geochem., 1(3/4), 173-205.

65. PHILP, R.P. and GILBERT, T.D. (1984). Characterization of petroleum source rocks and shales by pyrolysis-gas chromatography-mass spectrometry-multiple ion detection. Org. Geochem., .Q, 489-501.

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66. NOMURA, M., YOSHIDA, T., PHILP, P., and GILBERT, T. (1985). Structural studies of hexane soluble products from hydroliquefaction of three Yalloum brown coal lithotypes over molten salt catalysts. Fuel, 64(1 ), 108-113.

67. PHILP, R.P. (1985). Biological markers in fossil fuel production. Mass Spectrometry Rev., 1(1), 1-54.

68. PHILP, R.P. (1985). Fossil Fuel Biomarkers. Applications and Spectra. Elsevier, Amsterdam. p. 294.

69. GILBERT, T.D., STEPHENSON, L.C. and PHILP, R.P. (1985). Effect of a dolerite intrusion on triterpane stereochemistry and kerogen in Rundle oil shale, Australia. Org. Geochern., ~(2), 163-169.

70. PHILP, R.P. and GILBERT, T.D. (1985). Source rock and asphaltene biomarker characterization by pyrolysis-gas chromatography-mass spectrometry-multiple ion detection. Geochirn. Cosrnochirn. Acta, 49( 6), 1421-1432.

71. PHILP, R.P. (1985). Review of book entitled "Petroleum Formation and Occurrence" by B.P. Tissot and D. Welte. Trans. Am. Geophys. Union, 66(37), 643-645.

72. GLIKSON, M., GIBSON, D.L. and PHILP, R.P. (1985). Organic matter in Australian Cambrian oil shales and other lower Palaeozoic shales. Chern. Geol., n(3/4), 175-192.

73. PHILP, R.P. (1985). Advances in kerogen analysis. Nature, 318, 232-233.

74. STEPHENS, J.F., LEOW, H.M., GILBERT, T.D. and PHILP, R.P. (1985). Aqueous sodium dichromate oxidation of Australian vitrinite concentrations. Fuel, 64(11 ), 1531-1536.

75. STEPHENS, J.F., LEOW, H.M., GILBERT, T.D. and PHILP, R.P. (1985). Investigation of the relationship between coal maturity and arornaticity. Characteristics of sodium dichromate oxidation products of Australian vitrinite concentrates. Fuel, 64( 11) 1537-1541.

76. JIYANG, SHI, and PHILP, R.P. (1985). Py-GC, py-GC-MS analyses of source rocks from Zhanhua Depression and their geochemical significance. Acta Sedirnentologica Sinica, J(3), 65-73.

77. PHILP, R.P. (1985). Brown coal utilization in Australia. Collection III of lecture notes of research meeting on resources and energy. Kansai University of Industrial Technology Institute, Vol. 3, p.l-9.

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78. PHILP, R.P., GILBERT, T.D. and WALTERS, C.K. (1985). Geochemical correlations studies of Alaska North Slope and oils and source rocks. AAPG Studies in Geology #20 ( eds. L.B. Magoon and G.E. Claypool), pp. 571-591. AAPG, Tulsa.

79. PHILP, R.P. ( 1986). Geochemistry in the search for oil. Chemical and Engineering News, 64(6), 28-43.

80. PHILP, R.P, and GILBERT, T.D. (1986). A geochemical investigation of oils and source rocks from the Surat Basin. Aust. Petrol. Expl. Assocn. J., ~ 172-186.

81. PHILP, R.P. and GILBERT, T.D. (1986). The detection of biological markers by computerized-gas chromatography-mass spectrometry. In: Biological Markers in the Sedimentary Record, Methods in Geochemistry and Geophysics, 24 (ed. R.B.Johns), Elsevier Amsterdam. p.227-248.

82. PHILP, R.P. and GILBERT, T.D. (1986). Biomarker distributions in Australian oils predominantly derived from terrigenous source material. In: Advs. in Org. Geochem. 1985 ( eds. D. Leythauser and J. Rulkotter), Pergamon Press, Oxford, pp. 73-84.

83. PHILP, R.P. and LEWIS, C.A. (1987). Organic geochemistry of biomarkers. Ann. Rev. Earth Planet. Sci., U, 363-395.

84. PHILP, R.P. (1987). Surface prospecting methods for hydrocarbon accumulations. In "Adv. in Petroleum Geochem. II", (eds. J. Brooks and D. Welte), Academic Press, London. pp. 205-249.

85. PHILP, R.P. and EGLINTON, T.I. (1987). The Role of Petroleum Geochemistry in Exploration. Oil and Gas Australia, pp. 36-42, June, 1987.

86. FAN, Z. and PHILP, R.P. (1987). Laboratory biomarker fractionations and implications for migration studies. Org. Geochem., 11 (3), 169-175.

87. PHILP, R.P. and GILBERT, T.D., (1987). Biomarkers in kerogens as determined by pyrolysis-gas chromatography and pyrolysis-gas chromatography-mass spectrometry. Anal. Pyrolysis. 11,93-108.

88. PHILP, R.P. and FAN, Z., (1987). Investigation of oils and source rocks from Qianjiang Depression of Jianghan Basin, A Terriginous Basin, China. Organic Geochemistry, 11(6), 549-562.

89. PHILP,R.P. and ENGEL, M.H., (1987). The effects of migration on the distribution of biomarkers and stable carbon isotopic composition of crude oils. In: "Migration of Hydrocarbons in Sedimentary Basins" (ed. B. Doligez), Editions Technip, Paris, pp. 615-632.

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90. TRINDADE, L.A.F., CARMINATTI, M. and PHILP, R.P. (1987). Evidencias geoquimicas de migracao de hidrocarbonetos na bacia de compos. Proc. of 1st Congresso Brasileiro de Geoquimica, 2_, 343-361. Porto Alegre, Brazil.

91. PHILP, R.P. (1988). Book Review entitled "Histoire et Diagenese Organique" by P. Robert. J.Sed.Pet.,58(1), Jan. 1988.

92. PHILP, R.P. and BAKEL, A., (1988). Production of Heteroatomic compounds by pyrolysis of asphaltenes, coals and source rocks. Energy and Fuels, 2_, 59-64.

93. PHILP, R.P., (1988). The application of petroleum geochemistry to exploration problems with particular reference to Australia and New Zealand. In : "Petroleum Geochemistry and Exploration in the Afro-Asian Region" (eds. R.K. Kumar, P. Dwideudi, V. Banerjie, and V. Gupta), A.A. Balhema, Rotterdam, pp. 75-82.

94. JIANG, Z., PHILP, R.P. AND LEWIS, C.A., (1988). Identification of novel bicyclic alkanes from steroid precursors in crude oils from Kelamayi Oilfield in China. Geochim. Cosmochim Acta. 52, 491-498.

95. BAIRD, R.A. and PHILP, R.P. (1988). Hydrocarbon potential of the Upper Jurassic/Lower Cretaceous of the Australian Northwest Shelf. J. Petrol Geol., ll(2), 125-140.

96. EGLINTON, T.I., PHILP, R.P. and ROWLAND, S.J. (1988) Flash pyrolysis of artifically matured kerogens. Org. Geochemistry. 12(1 ),33-42.

97. PHILP,R.P., OUNG, J., and LEWIS, C.A. (1988). Biomarker determinations in crude oils using a triple stage quadrupole mass spectrometer. J.Chromatog., 446, 3-16.

98. PHILP, R.P. and JOHNSTON, M. (1988). Determination of biomarkers in geological samples by tanden mass spectrometry. In: Geochemical Markers" (eds. T.F. YEN and J.M. MOLDOW AN) 253-274. Harwood Academic Publishers, New York. 438pp.

99. CZOCHANSKA, Z., WESTON, R.J., WOOD, T.A., WOOLHOUSE, A.D., GILBERT, T.D. and PHILP, R.P. (1988). A Biological Marker Study of the Crude Oils of the Taranaki Basin ofNew Zealand. Org. Geochemistry, li, 123-135.

100. PHILP, R.P. and OUNG, J.N. (1988). Biomarker, Occurrence, Formation and Detection. Anal. Chern. 60(10), 887 A-896A.

101. FAN, P., PHILP, R.P., MENG, Q., CHEN, X., LI, J., YU, X., Ll, J., and CHEN, N. ( 1988). Biomarkers indicating sedimentary paleoenvironments. Special Publication of Lanzhou Institute of Geology, Academia Sinica. 39 pp.

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102. ZHUSHENG, J., PHILP, R.P. and LEWIS, C.A. (1988). Fractionation of biological markers in crude oils during migration and the effects on correlation and maturation parameters. In: Advances in Organic Geochemistry 1987, pp 561-571.

103. WESTON, R.J., ENGEL, M.H., PHILP, R.P. and WOOLHOUSE, A.D. (1988). The stable carbon isotopic composition of oil from the Taranaki Basin of New Zealand. Org. Geochem., 12,487-493.

102. ZHUSHENG, J., PHILP, R.P. and LEWIS, C.A. (1988). Fractionation of biological markers in crude oils during migration and the effects on correlation and maturation parameters. In: Advances in Organic Geochemistry 1987, pp 561-571.

103. WESTON, R.J., ENGEL, M.H., PHILP, R.P. and WOOLHOUSE, A.D. (1988). The stable carbon isotopic composition of oil from the Taranaki Basin of New Zealand. Org. Geochem., 12,487-493.

104. PHILP, R.P., BAKEL, A., GALVEZ-SINIBALDI, A. and LIN, L.H. (1988). A comparison of organosulphur compounds produced by pyrolysis of asphaltenes and those present in related crude oils and tar sands. In "Advances in Organic Geochemistry 1987" pp 915-926.

105. PHILP, R.P. and OUNG, J-N. (1989). Biomarker quantitation as determined by MS/MS and use of the direct insertion probe. Div. Pet. Chern. Am. Chern. Soc. Preprint Series, 34(1 ), 170-175.

106. VALLEJOS, C., TALUKDAR,S., and PHILP,R.P. (1989). The distribution of organosulphur compounds in artificially matured rocks and kerogens of the La Luna Formation, Maracaibo Basins, Venezuela. Org. Geochem., J.(3), 366-369.

107. PHILP, R.P. and LEWIS, C.A. (1989). The use of the Ion Trap Detector in Petroleum Geochemistry. Org. Geochem. 14(2), 183-187.

108. PHILP, R.P., LI, J. and LEWIS, C.A. (1989) A geochemical investigation of crude oils from Shanganning, Jianghan, Chidamu, and Zhungeer Basins, China. Org. Geochem. 14( 4 ), 447-460.

109. WESTON, R.J., PHILP, R.P., SHEPPARD, C.M. and WOOLHOUSE, A.D.(1989). Sesquiterpanes, diterpanes and other higher terpanes in oils from the Taranaki Basin of New Zealand. Org. Geochem., 14(4), 405-422.

110. PHILP, R.P., JONES, P.J., LIN, L.H. and MICHAEL, G.E. (1989). An organic geochemical study of oils, source rocks, and tar sands in the Anadarko Basin. Oklahoma Geological Survey Notes, (Proceedings of Anadarko Basin Symposium, Norman, Oklahoma, April 1988), Circular 90, pp65-76.

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111. LEWIS, S., TENG, SIU and PHILP, R.P.(1989). Automated GC/MS/MS Analysis of Biomarkers using Short Open-Tubular Fused-Silica Columns. Finnigan Application Notes

112. LIN, L.H., MICHAEL, G.E., KOV ACHEY, G., ZHU, H., PHILP, R.P. and LEWIS, C.A. (1989). Biodegradation of tar-sand bitumens from the Ardmore Basin, Carter County, Oklahoma. Org. Geochem., 14(5), 511-523.

113. CHEN, J.H., PHILP, R.P., FU, J.M. and SHENG, G.Y. (1989). The occurrence and identification of C30-C32 lanostanes. A novel series of tetracyclic triterpene hydrocarbons in the geological record ofBiyang Basin, China. Geochim. Cosmochim. Acta, 53(10), 2775-2779.

114. CLARK, J.P. and PHILP, R.P. (1989) Geochemical Characterization of Evaporite and Carbonate Depositional Environments and Correlation of Associated Crude Oils in the Black Creek Basin, Alberta. Bulletin of Canadian Petroleum Geology, 37(4), 401-416.

115. MICHAEL, G.E., LIN, L.H., PHILP, R.P., LEWIS, C.A. and JONES, P.J. (1989) Biodegradation of tar-sand bitumens from the Ardmore/Anadarko Basins, Oklahoma-H. Correlation of oils, tar sands and source rocks. Org. Geochem., 14(6), 619-634.

116. ZHUSHENG, J., FOWLER, M.G., LEWIS, C.A. and PHILP, R.P. (1990). Polycyclic alkanes in a biodegraded oil from the Kelamayi oilfield, northwestern China. Org. Geochem., 12.(1), 35-46.

117. WANG, T.-G, SIMONEIT, B.R.T., PHILP, R.P. and Yu, C.-P.(1990). Extended 8I3(H)­drimane and 8, 14-secohopane series in a Chinese Boghead coal. J. Energy & Fuels, :1(2), 177-183.

118. BAKEL, A.J., PHILP, R.P. and GALVEZ-SINIBALDI, A. (1990). Characterization of Organosulfur Compounds in Oklahoma Coals By Pyrolysis-Gas Chromatography. In: Geochemistry of Fossil Fuels (Eds. W.L. Orr and C.M. White) ACS Symposium Series 429, pp326-344. 119. JONES, P.J. and PHILP, R.P. (1990). Oils and source rocks from Pauls Valley, Anadarko Basin, Oklahoma, U.S.A. Applied Geochemistry, ,2, 429-448.

120. YU XINKE, FAN PU and PHILP, R.P., (1990). Novel Biomarkers found in South Florida Basin. Org. Geochem., 12.(4), 433-438.

121. SUZUKI N. and PHILP, R.P. (1990). Formation ofmelanoidins in the presence ofH2S. Org. Geochem., 12.(4), 361-366.

122. BAKEL, A.J. and PHILP, R.P. (1990). The distribution and quantitation of organonitrogen compounds in crude oils and rock pyrolysates. In: Advances in Organic Geochemistry, 1989, (eds. B. Durand and F. Behar), Pergamon Press, Oxford, pp.353-367.

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123. PHILP, R.P., OUNG, J.-N., YU, C.P. and LEWIS, S. (1990). The determination of biomarker distributions by tandem mass spectrometry. In: Advances in Organic Geochemistry, 1989, (eds. B. Durand and F. Behar), Pergamon Press, Oxford, pp. 1211-1220.

124. FAN PU, PHILP, R.P., ZHENXI, LI and GUANGGUO, Y. (1990). Geochemical characteristics of aromatic hydrocarbons of crude oils and source rocks from different sedimentary environments. In: Advances in Org. Geochem. 1989, (eds. B. Durand and F. Behar), Pergamon Press, Oxford, pp. 427-436.

125. SUZUKI, N. and PHILP, R.P. (1989). Origin of sulphur in high-sulphur crude oils. Jour. Japanese Assoc. of Petrol. Technol., 54, p. 306-307.

126. SUZUKI, N. and PHILP, R.P. (1990). Geopolymerization and formation of organa­sulphur compounds in the presence ofH2S. Res. Org. Geochem., 7, p. 37-40.

127. PHILP, R.P. and GARG, A.K. (1991). Characterization of some sedimentary sequences from Cambay Basin, India by pyrolysis-GC. Journal of Southeast Asian Earth Sciences, 5, p. 31-38.

128. PHILP, R.P., FAN, P., LEWIS, C.A., LI, J., ZHU, H. and WANG, H. (1991). A geochemical study of oils and source rocks from the Chaidamu, Shanganning and Jianghang Basins, China. Journal of Southeast Asian Earth Sciences, 5, pp. 351-358.

129. JIANG, Z. and PHILP, R.P. (1991). Novel tricyclic alkanes in the crude oils from Kelamayi oilfield of China. Journal of Southeast Asian Earth Sciences, 5, pp. 155-165.

130. CZECHOWSKI, F., PHILP, R.P., and KIDAWA, H. (1991). Biomarkers distribution in relation to coal maturity and petrographic composition. In: Proceedings of Int. Conference on Structure and Properties of Coals. Wroclaw, Poland, June 17-19, 1991. pp 13-16.

131. CHEN, J.H. and PHILP, R.P. (1991 ). Porphyrin distributions in crude oils from the Jianghan and Biyang basins, China. In: Chemical Geology, 91(2), 139-151.

132. PHILP, R.P. and GALVEZ-SINIBALDI, A. Characterization of organic matter by various pyrolysis techniques. AAPG Handbook ofPetroleum Geology., pp. 107-112.

133. DEL RIO, J.C., GALVEZ-SINIBALDI, A., PHILP, R.P., GARCIA-MOLLA, J., GONZALEZ-VILA, F.J. and MARTIN, F. (1991). Determination of complex mixtures of hydrocarbons in a Spanish oil shale by means of GC-MS/MS. 12th Int. Mass Spec. Conf., Amsterdam, August 1991. (extended abstract).

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134. MPANJU, F. and PHILP, R.P. (1991). Organic Geochemical Characterization of Bitumens and Oil Seeps from Tanzania. In: Organic Geochemistry - Advances and Applications in Energy and the Natural Environment, (ed. D. Manning), pp. 85-87. University of Manchester Press, Manchester.

135. GALVEZ-SINIBALDI, A., LANDAIS, P. and PHILP, R.P. (1991). Artificial maturation studies of Pseudoplexarua porosa and its zooxanthellae -Major constituents of coral reefs. In: Organic Geochemistry - Advances and Applications in Energy and the Natural Environment, ( ed. D. Manning), pp. 295-297. University of Manchester Press, Manchester.

136. RUBLE, T.E. and PHILP, R.P. (1991). Organic Geochemical Characterization ofNative Bitumens from the Uinta Basin, Utah, U.S.A. In: Organic Geochemistry - Advances and Applications in Energy and the Natural Environment, ( ed. D. Manning), pp. 99-103. University of Manchester Press, Manchester.

137. DEL RIO, J.C. and PHILP, R.P. (1991). Occurrence of High Molecular Weight Hydrocarbons (Above C40) in Geological Materials. In: Organic Geochemistry- Advances and Applications in Energy and the Natural Environment, (ed. D. Manning), pp. 183-185. University of Manchester Press, Manchester.

138. UNOMAH, G.I., EKWEOZOR, C.M. and PHILP, R.P. (1991). Use of Biomarkers for Determination of Organofacies Provinces and Paleoenvironment of Upper Cretaceous Sediments, Lower Benue Trough, Nigeria. In: Organic Geochemistry - Advances and Applications in Energy and the Natural Environment, (ed. D. Manning), pp. 394-396. University of Manchester Press, Manchester.

139. SOYLU, CENGIZ and PHILP, R.P. (1991). Petroleum Geochemistry of the Adiyaman Area Oils, S.E. Turkey. In: Organic Geochemistry- Advances and Applications in Energy and the Natural Environment, (ed. D. Manning), pp. 114-115. University of Manchester Press, Manchester.

140. SCHREIBER, B.C., BENALIOULHAJ, S., PHILP, R.P. and LANDAIS, P. (1991). Evaporites as a source for oil. DOE Sedimentary Basin Workshop Proceedings,, University of Oklahoma Norman, Oklahoma, November, 1991, pp. 51-59.

141. PHILP, R.P., ALAM, M. and WANG, H.D. (1991). An organic geochemical study of crude oils and source rocks in the Anadarko Basin, Oklahoma. DOE Sedimentary Basin Workshop Proceedings,, University of Oklahoma Norman, Oklahoma, November, 1991, pp. 142-160.

142. FAN PU, PHILP, R.P., LI ZHENXI, YU XINKE and YING GUANGGUO (1991). Biomarker distributions in crude oils and source rocks from different sedimentary environments. Chern. Geol., 93, 61-78.

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143. LAWWONGNAGAM,K. and PHILP, R.P. (1991). Geochemical characteristics of oils from the Sirikit Basin, Phisanulok Basin, Thailand. Chern. Geol., 93, 129-146.

144. PHILP, R.P. and OUNG, J-N. (1991). Biomarker distribution in crude oils as determined by tandem mass spectrometry. In:Biological Markers in Sediments and Petroleum (Eds. J.M.Moldowan, P.Albrecht and R.P.Philp), Prentice Hall, Englewood Cliffs, New Jersey, pp106-123.

145. PHILP, R.P. and XAVIER DE LAS HERAS, F. (1991). Fossil Fuels. Chromatography, 5th Edition: Fundamentals and applications of chromatography and related differential migration methods. (Edited by E. Heftman), p. B447- B473.

146. PHILP, R.P. Petroleum Geochemistry and Application to Exploration Problems. 8th Petroleum Congress ofTurkey, April, 1990, Ankara, Turkey, pp. 1-11.

147. WOOLHOUSE, A.D., OUNG, J-N, PHILP, R.P. and WESTON, R.J. (1992). Triterpanes and Ring-A Degraded Triterpanes as Characteristic of Tertiary Oils Derived from Predominantly Higher Plant Sources. Org. Geochem. 18, 23-31.

148. PHILP, R.P., OUNG, J-N, GALVEZ-SINIBALDI, A. and ALLEN, J. (1991). Tandem Mass Spectrometry- An Additional Dimension of Chromatography. Snyder Honor Volume, J. Chromatography, 550,193-212.

149. CZECHOWSKI, F. and PHILP, R.P. (1991). Structural Characterization of Biomarkers and Group Components of Brown Coal Lithotypes. Second Int. Symp. on Biological Processing of Coal, San Diego, California, May, 1991.

150. MOLDOWAN, J.A., ALBRECHT, P., and PHILP, R.P. (Editors) (1991). Biological Markers in Sediments and Petroleum, Prentice Hall, Englewood Cliffs, New Jersey, 411p.

151. CZECHOWSKI, F., LATOS-GRAZYNSKI, L., and PHILP, R.P. (1991). Composition of

Iron Porphyrins from Coal- 1H NMR Studies. IIIrd Symposium on Inorganic Biochemistry and Molecular Biophysics, Wroclaw University, Poland.

152. RUBLE, T.E. and PHILP, R.P. (1991). Geochemical investigation ofNative Bitumens from the Uinta Basin, Utah, U.S.A. The Compass, 68(3), 135-150.

153. BAKEL, A. and PHILP, R.P.(1991). The Distribution of Organonitrogen Compounds Produced by Pyrolysis ofNSO Fractions, Asphaltenes and Kerogens. The Compass, 68(4), 202-220.

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154. DEL RIO, J.C. and PHILP, R.P. (1992). Nature and Geochemistry of High Molecular Weight Hydrocarbons (Above C40) in Oils and Solid Bitumens. Org. Geochem. ~(4), 541-553.

155. DEL RIO, J.C. and PHILP, R.P. (1992). High Molecular Weight Hydrocarbons: A New Frontier in Organic Geochemistry. Trends in Anal. Chern., 11(5), 187-193.

156. PHILP, R. P. and OUNG, J-N (1992). Biomarkers, Occurrence, Utility and Detection. In: Instrumentation in Analytical Chemistry, 1988-1991 (ed. Louis Voress). American Chemical Society, Washington, D.C. pp. 368-376.

157. RUBLE, T.E. and PHILP, R.P. (1992). A Reevaluation ofthe Geochemical Characteristics of Solid Bitumens from the Quachita Mountains, Oklahoma. Oklahoma Geological Survey Circular 93, pp. 337-342.

158. PHILP, R.P., CHEN, J., GALVEZ-SINIBALDI, A., HUAIDA WANG and ALLEN, J.D. (1992). Effects of Weathering and Maturity on the Geochemical Characteristics of the Woodford Shale. Oklahoma Geological Survey Circular 93, pp. 106-121.

159. PHILP, R.P., SUZUKI, N. and GALVEZ-SINIBALDI, A. (1992). Early stage incorporation of sulphur into protokerogens and possible kerogen precursors. Organic Matter: Productivity, Accumulation, and Recent and Ancient Sediments. (Edited by J. Whelan and J. W. Farrington), p. 264-282. Colulmbia University Press, New York.

160. DEL RIO, J.C. and PHILP, R.P. (1992). Oligomerization of Fatty Acids as a Possible Source For High Molecular Weight Hydrocarbons and Sulphur-Containing Compounds in Sediments. Org .. Geochem., ~(6), 869-880.

161. PHILP, R.P., CHEN, J.H., FU, J.M. and SHENG, G.Y. (1992). A Geochemical Investigation of crude oils and source rocks from Biyang Basin, China. Org. Geochem., ~( 6), 933-945.

162. HAZAI, I. GALVEZ-SINIBALDI, A, and PHILP, R.P. ( 1992). Identification of Pentacyclic Triterpanes by GCMSMS. J. High Res. Chromatog., U(12), 791-794.

163. PHILP, R.P. (1993). Oil-oil and oil-source rock correlations: Techniques. In:Organic Geochemistry (Eds. M.H. Engel and S.A. Macko), Plenum Press, New York, pp.445-460.

164. HOOPER, J.B., THOMAS, J.V., SUTTON, D.V., LINTELMAN, K.A., TRACING, R.J., PHILP, R.P. (1993). Petroleum and Coal. Analytical Reviews, 65(12), 171R-198R.

165. MICHELS, R., LANDAIS, P., GERARD, L., MANSUY, L., PHILP, R.P., TORKELSON, B.E. ( 1993). Are temperature and time the only constraints to the simulation of organic matter.

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In: Proceedings of the 16th International Meeting of the European Association of Organic Geochemists, Stavanger, September, 1993.

166. BAKEL, A.J., DYER, R. M., RUBLE, T.E., and PHILP, R.P. (1993). Carbon isotope composition of n-alkanes and isoprenoids in slightly biodegraded oils from the Phillipstown field, IL. In: Proceedings of the 16th International Meeting of the European Association of Organic Geochemists, Stavanger, September, 1993.

168. WANG, H.D., PHILP, R.P. and ALAM, M. (1993). Source rock correlation using biomarker characteristics in the Anadarko Basin. In: Proceedings of the 16th International Meeting of the European Association of Organic Geochemists, Stavanger, September, 1993.

169. CHEN, G. AND PHILP, R.P. (1993). Geochemical characteristics of the evaporite cycles in the Paradox Basin of Southeastern Utah and Southwestern Colorado. In: Proceedings of the 16th International Meeting of the European Association of Organic Geochemists, Stavanger, September, 1993.

170. GALVEZ-SINIBALDI, G. and PHILP, R.P. (1993). Diagenesis and catagenesis of steranes produced by artificial maturaation of carbonate mud derived from reef dwelling organisms. In: Proceedings of the 16th International Meeting of the European Association of Organic Geochemists, Stavanger, September, 1993.

171. RUBLE, T.R. and PHILP, R.P. (1993). Fractionation of biological markers by column chromatography using novel molecular sieves. In: Proceedings of the 16th International Meeting ofthe European Association of Organic Geochemists, Stavanger, September, 1993.

172. ALAM, M., WANG, H.D. and PHILP, R.P. (1993). Extended tricyclic terpanes in sediments from the Anadarko Basin. In: Proceedings of the 16th International Meeting of the European Association of Organic Geochemists, Stavanger, September, 1993.

173. BENALIOULJAH, S., SCHREIBER, B.C., PHILP, R.P. andAND LANDAIS, P. (1993). Assessment of biomarkers characteristic of hypersalinity using artificial maturation on sediments from diverse evaporitic environments. In: Proceedings of the 16th International Meeting of the European Association of Organic Geochemists, Stavanger, September, 1993.

174. KASHIRTSEV, V., PHILP, R.P., ALLEN, J. and GALVEZ-SINIBALDI, A. (1992). Biodegradation of biomarkers in natural bitumen of Olenek Uplift. Geology and Geophysics. (Published). In Russian.

175. LAWWONGNGAM, K. and PHILP, R.P. (1993). Preliminary investigation of oil and source rock organic geochemistry from Tertiary Basins of Thailand. 9th Regional Conference on Geology, Mineral and Energy Resources of Southeast Asia (GEOSEA VII), Bangkok, Thailand, November 1991. J.SE Asian Earth Sciences, ~(1-4), 433-448.

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176. PHILP, R.P. (1994). Geochemical characteristics of Oils derived predominantly from terrigenous source materials. Coal and Coal-bearing Strata as Oil-prone Source Rocks? Geological Society Special Publication No. 77 (Eds. A.C. Scott and A.J. Fleet). London, England. pp.71-91.

177. MPANJU, F.M. and PHILP, R.P. (1994). Organic Geochemical Characterization of Bitumens, Seeps, Rock Extracts and Condensates from Tanzania. Org. Geochem., 21(3/4), 359-371.

178. GARG, A.K. and PHILP, R.P. (1994). Source rock and hydrocarbon generation in Gandhar field, Cambay Basin, India. Org. Geochem., 21(3/4), 383-392.

179. BENALIOULHAJ, S., SCHREIBER, B.C. and PHILP, R.P. (1994). Relationship of Organic Geochemistry to Sedimentation under Highly Variable Environments, Lorca Basin, Spain: Preliminary Results. In:Sedimentary and Geochemistry of Modern and Ancient Saline Lakes. SEPM Special Publication, 50, 315-324.

180. LANDAIS, P., DEREPPE, J-M, DUBESSY, J. and PHILP, R.P. (1993). Characterization of graphite alteration and bitumen genesis in the Cigar Lake deposit (Saskatchewan, Canada). Can. J. Earth Sci. 30, 743-753.

*181. RUBLE, T., BAKEL, A., PHILP, R.P. (1994). Stable Isotopic Compositions oflndividual Biomarkers from Unita Basin Bitumens. In: "Compound Specific Isotope Analysis in Biogeochemistry and Petroleum Research" (Eds. M. Schoell and J.M. Hayes) Org. Geochem., 21,661-671.

182. CHEN, J.H., PHILP, R.P., FU, J.M. and SHENG, G.Y. (1994). A geochemical study of primary oil migration in Biyang Basin, China. J.SE Asian Earth Sciences, 2.(3), 207-220.

183. PHILP, R.P. (1994). High temperature gas chromatography for the analysis of fossil fuels. In: The Uses of Chromatography for Analysis of Synthetic and Fossil Fuels. J. High Res. Chromatography, 11(6), 398-406.

184. OUNG, J-N and PHILP, R.P. (1994). Geochemical Characteristics of Oils from Taiwan. J. S.E. Asian Earth Sciences, 2.(3 ), 193-206.

185. MICHELS, R., LANDAIS, P., PHILP, R.P., and TORKELSON, B.E. (1994). Effects of pressure on organic matter maturation during confined pyrolysis of Woodford kerogen. Energy and Fuels, li, 741-754.

186. BISHOP, A.N., and PHILP, R.P.(1994). The potential for amorphous kerogen formation via adsorption of organic material at mineral surfaces. Energy and Fuels, li, 1494-1497.

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187. CHEN, J.H., PHILP, R.P., FU, J.M. and SHENG, G.Y. (1994). A geochemical study of primary oil migration in Biyang Basin, China. J. SE Asian Earth Sciences, 2(3), 207-220.

188. RUBLE, T. and PHILP R.P.(1995). Uinta Basin Wurtzilite: a product of natural vulcanization. Org. Geochem., 22, 127-136.

189. PHILP, R.P. and BISHOP, A.N. (1995). Exploration and reservoir geochemistry: Concepts, applications and results. In: Proceedings of PETROTECH-95, pp57-77. Meeting held in New Delhi, India, January 1995.

190. PHILP, R.P., BISHOP, A.N., DEL RIO, J.C., AND ALLEN,J. (1995). Characterization of high molecular weight hydrocarbons (>C40) in oils and reservoir rocks. In:The Geochemistry of Reservoir Rocks, (Eds. J.M. Cubitt and W.A. England) Geological Society Special Publication No. 86, London. pp71-85.

191. BENALI, S., SCHREIBER, B.C., HELMAN, M.L., AND PHILP R.P. (1995). Characterization of organic matter from a restricted/evaporative sedimentary environment: Late Miocene ofLorca Basin (SE Spain). AAPG Bull., 79(6), 816-830.

192. MUELLER, E., PHILP, R.P. and ALLEN, J. (1995). Geochemicla characterization and relationship of oils and solid bitumens from SE Turkey. J. Petrol. Geol., _lli(3), 289-308.

193. SUZUKI, N. and PHILP, R.P. (1995). Pyrolysis-GC analyses of the recent cyanobacterial mats reacted with H2S under mild conditions. Geochem.Journal, 29, 137-148.

194. WANG, H.D., ALLEN, J., and PHILP, R.P. (1995). An organic geochemical investigation of oils and source rocks from two mesozoic formaitons of Shanganning Basin, China. J. S.E. Asian Earth Sciences, 11(4), 277-288.

195.BISHOP, A.N.,PHILP, R.P., ALLEN,J and RUBLE, T.E. (1995). High molecular weight hydrocarbons and the precipitation of petroleum derived waxes. In: Organic Geochemistry: Developments and Applications to Energy, Climate, Environment, and Human History, Proceedings of the 17th International Meeting on Organic Geochemistry, Donostia, San Sebastian, Spain. September 1995-extended abstracts, (Ed. J.O. Grimalt and C. Dorronsoro), pp356-357.

196.BISHOP,A.N., FARRIMOND,P., PHILP, R.P., and GALVEZ-SINIBALDI, A. (1995). The influence of kerogen formation mechanisms on biomarker diagenesis. In: Organic Geochemistry: Developments and Applications to Energy, Climate, Environment, and Human History, Proceedings of the 17th International Meeting on Organic Geochemistry, Donostia, San Sebastian, Spain. September 1995-extended abstracts, (Ed. 1.0. Grimalt and C. Dorronsoro), pp356-357.

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197.TRIGUIS, J.A., ARAUJO, J.M., ARAUJO, C.V., PHILP, R.P.(1995). Parana Basin-Brazil: A huge pyrolyser. Comparison between molecular distributions in pyrolysed samples and source rocks affected by igneous intrusions. In: Organic Geochemistry: Developments and Applications to Energy, Climate, Environment, and Human History, Proceedings of the 17th International Meeting on Organic Geochemistry, Donostia, San Sebastian, Spain. September 1995-extended abstracts, (Ed. J.O. Grimalt and C. Dorronsoro), pp356-357.

198.RUBLE, T.E., LEWAN, M.D.and PHILP, R.P. (1995). Recognition of distinctive source facies by hydrous pyrolysis: Important implications for basin mode1s.ln: Organic Geochemistry: Developments and Applications to Energy, Climate, Environment, and Human History, Proceedings of the 17th International Meeting on Organic Geochemistry, Donostia, San Sebastian, Spain. September 1995-extended abstracts, (Ed. J.O. Grimalt and C. Dorronsoro), pp 188-192.

199.L. STALKER, PHILP, R.P. C. McCAULEY. An integrated study of sulphur in coals. In: Organic Geochemistry: Developments and Applications to Energy, Climate, Environment, and Human History, Proceedings of the 17th International Meeting on Organic Geochemistry, Donostia, San Sebastian, Spain. September 1995-extended abstracts, (Ed. J.O. Grimalt and C. Dorronsoro), pp356-357.

200.CZECHOWSKI, F.,PHILP, R.P. AND WOLOWIEC, S. (1995). Early diagenetic Protohem­IX products from Texas Fairfield lignite. In: Organic Geochemistry: Developments and Applications to Energy, Climate, Environment, and Human History, Proceedings of the 17th International Meeting on Organic Geochemistry, Donostia, San Sebastian, Spain. September 1995-extended abstracts, (Ed. J.O. Grimalt and C. Dorronsoro), pp 234-237.

20l.ABD EL-GAWAD, E.A., PHILP, R.P., and ZEIN EL-DIN, M.Y. (1995). Evaluation of possible source rocks in Faghur-Siwa Basin, Western Desert Egypt. In: Organic Geochemistry: Developments and Applications to Energy, Climate, Environment, and Human History, Proceedings of the 17th International Meeting on Organic Geochemistry, Donostia, San Sebastian, Spain. September 1995-extended abstracts, (Ed. J.O. Grimalt and C. Dorronsoro), pp356-357.

202.HOOPER, J.B., THOMAS, J.V., SUTTON, D.V., LINTELMAN, K.A., TRACINO, R.J., PHILP, R.P. (1995). Petroleum and Coal. Analytical Reviews, 65(12), 171R-198R.

203.LI JINGGUI, PHILP, R.P., and FAN PU.(1996). Long chain alkenones in Qinghai Lake sediments. Geochim. Cosmochim. Acta, 60(2), 235-241.

204.PHILP, R.P. and BISHOP, A.N. (1996). Reservoir Geo-chemistry:concepts, applications and results. In: Johnson, K.S. (ed.), Deltaic Reservoirs in the southern Midcontinent, 1993 symposium: Oklahoma Geological Survey Circular 98, pp. 188-196.

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205.KONTOROVICH, A.E., KASHIRTSEV, V.A and PHILP, R.P. (1995). Biohopanes in the Precambrian deposits of the north east Siberian Platform. Reports of the Russian Academy of Science, 345, 106-111.

*206.PHILP, R.P., ALLEN, J. and KOMBRINK, M. (1995). an investigation into the potential of GCIRMS as a technique for the correlation of weathered oil spill samples to their source. Hydrocarbon Contaminated Soils, pp363-380. Amherst Scientific Publishers, Amherst.

*207.PHILP,R.P., ALLEN, J., MANSUY, L. (1996) The Application of Gas Chromatography­Isotope Ratio Mass Spectrometry to problems in Petroleum, Reservoir, Environmental and Forensic Geochemistry.In: Proceedings of the 5th Latin American Organic Geochemistry Congress, Cancun, Mexico, October 1996, pp369-371.

208.TRINDADE,L.A.F., PHILP, R.P., MIZUSAKI, A.M.P., DOS SANTOS, R.L.A., TCHOUP AROV A, E. and SIAMAK DJAF ARIAN, M. (1996). Geochemical characterization of waxy oils from the Dom Joao oil field, Reconcavo Basin, Brazil. In: Proceedings of the 5th Latin American Organic Geochemistry Congress, Cancun, Mexico, October 1996, pp281-283.

209.HWANG, H.D. and PHILP, R.P. (1997). Geochemical study ofpotential source rocks and crude oils in the Anadarko Basin, Oklahoma. AAPG Bull., ~(2), 249-275.

*210.PHILP, R.P., ALLEN, J. and MANSUY, L. (1997). The utilization of combined gas chromatography-isotope ratio mass spectrometry to monitor the origin and fate of crude oils. Proceeding ofTechnical Exchange Meeting ARAMACO, Saudi Arabia, May 1997, pp250-265.

211.HUAI DA WANG and R. PAUL PHILP (1997). A geochemical study of Viola source rocks and associated crude oils in the Anadarko Basin, Oklahoma. Oklahoma Geological Survey Circular 99,87-101.

212.PHILP,R.P., ALLEN, J. and WEBER, J. (1997). Organic geochemical characteristics of oils and possible source rocks from the Ames Impact structure. Oklahoma Geological Survey Circular 100, 259.

213.MANSFIELD, C.T., BARMAN, B.N., THOMAS, J.V., MEHROTRA, A.K. and PHILP, R.P. (1997). Petroleum and Coal. Anal. Chern. Application Reviews, 59R-94R.

214.PHILP, R. PAUL, and MANSUY, L. (1997). Petroleum geochemistry: concepts, applications and results. Energy and Fuels.,ll, 749-760.

215.COATES, J.D., WOODWARD, J., ALLEN, J., PHILP, R.P. AND LOVLEY, D.R. (1997). Anaerobic degradation of polycyclic aromatic hydrocarbons and alkanes in petroleum­contaminated marine harbor sediments. Applied and Environmental Microbiology, 63,(9), 3589-3593.

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*216. PHILP, R. PAUL,(1997)Forensic Geochemistry, Natural Resources and Environment, 67-69.

*217. R.PAUL PHILP, LAURENCE MANSUY, and JON ALLEN.(1997).Monitoring the fate of crude oils spills in the environment by gcirms and gems. Environ. Sci. and Technol., .ll, 3417-3425.

218. PHILP, R.P. (1997).The use of biomarkers in understanding oil accumulations. SMU Meeting, October 1997.

219. ELLI CHOUPAROVA, KURT ROTTMANN, and R.PAUL PHILP (1997). The effect of water flooding on produced oil composition from Bartlesville reservoir, Prairie Gem Field, Central Oklahoma. AAPG Mid Sectonal Meeting. Oklahoma City, Sept. 1997.

220.R.PAUL PHILP, LAURENCE MANSUY, JON ALLEN, and JAMES K. ANDERSON(1997).Preferential biodegradation of aromatic components in Ordovician crude oils. Extended Abs. of 18th International Meeting on Organic Geochemistry, pp241-242. Maastricht, Sept. 1997. KFA, Julich, Germany.

*221.LAURENCE MANSUY,R.PAUL PHILP and M.H. ENGEL (1997). effects of maturation on the stable carbon isotope compositions of organic matter.Extended Abs. of 18th International Meeting on Organic Geochemistry, pp201-202. Maastricht, Sept. 1997. KFA, Julich, Germany.

*222.R.PAUL PHILP, LAURENCE MANSUY, and JON ALLEN.(1997). Monitoring the fate of crude oils spills in the environment by gcirms and gcms.Extended Abs. of 18th International Meeting on Organic Geochemistry, pp487-488. Maastricht, Sept. 1997. KFA, Julich, Germany.

223.RUBLE, T.E., PHILP, R.P. and LEWAN, T.D. (1997). Quantitative analysis ofbiomarkers from Green River Shale hydrous pyrolysis.Extended Abs. of 18th International Meeting on Organic Geochemistry, pp413-414. Maastricht, Sept. 1997. KFA, Julich, Germany.

224.W. J. CARRIGAN, M.H. TOBEY A, P.J. JONES A, H.I. HALPERN A, R. P. PHILP AND J. ALLEN (1997). Geochemical Variations of Paleozoic Gas/Condensate Reservoirs from the Ghawar Structure of Saudi Arabia: Gas Souring, Filling History, and Reservoir Compartmentalization. Extended Abs. of 18th International Meeting on Organic Geochemistry, pp601-602. Maastricht, Sept. 1997. KFA, Julich, Germany.

225. PHILP, R.P. and CHOUPAROVA, E. (1997). Time dependent changes in waxes and asphaltenes during oil production. Extended Abs. of 18th International Meeting on Organic Geochemistry, pp591-592. Maastricht, Sept. 1997. KFA, Julich, Germany.

226.STALKER, L. AND PHILP,R.P. (1997). Distribution variations of sulphur-linked coals determined by chemolysis. Extended Abs. of 18th International Meeting on Organic Geochemistry, pp441-442. Maastricht, Sept. 1997. KFA, Julich, Germany.

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227. KASHIRTSEV, V.A., PHILP, R.P., CHALAYA, O.N., ZUEVA, LN., and TRUSHCHELEVA, G.S. (1997). Genetic families of naphthoids of the eastern part of the Siberian platform. Geology of the Fatherland, li, 28-29.

228. MUELLER, E. and PHILP, R.P. (1998). Paraffin waxes in source rock extracts. Org. Geochem., 28(9/10), 625-632.

229.RUBLE, T.E. and PHILP, T.E. (1998). Stratigraphy, Depositional Environments and Organic Geochemistry of Source-rocks in the Green River Petroleum System, Uinta Basin, Utah. In:Modern and Ancient Lake Systems, Utah Geological Association Guidebook;( eds. J .K. Pitman and A. R. Carroll) pp289-321.

230.WILLIAM J. CARRIGAN, PETER J. JONES, MARK H. TOBEY, HENRY I. HALPERN, LAWRENCE E.WENDER, RICHARD PHILP AND JONATHAN ALLEN (1998).Geochemistry of Eastern Saudi Arabia Paleozoic Gas/Condensates. GE098, Bahrain, April 1998. pp48-60.

*231. R. PAUL PHILP AND JON ALLEN(1998). Development of gas chromatography-isotope ratio mass spectrometry (GCIRMS) as an ancillary technique for tracking, monitoring and determination of the origin of hydrocarbon spills in the environment. In:Proceedings of a Speciality Conference on The Measurement of Toxic and Related Air Pollutants 98. Sept. 1998. (Published by the Air and Waste ManagementAssociation Dec. 1998). Cary, North Carolina. pp85-100.

232. R.P. PHILP AND M. HSIEH, E. MUELLER, AND J. ALLEN (1998). Characterization of the C4o+ Fraction of Source Rocks and Crude Oils. ALAGO Meeting, Venezuela, October 1998. pp70-75.

233. R.P. PHILP (1998). Characterization of the C4o+ Fraction of Source Rocks and Crude Oils. In the Proceedings of the III Symposium Badania Geochemiczne I Petrofizyczne W Poszukiwaniach Ropy Naftowej, Ustron Poland, November, 1998. pp247-256.

234. W. J. CARRIGAN, M.H. TOBEY A, P.J. JONESA, H.I. HALPERN, R. P. PHILP AND J. ALLEN ( 1997). Geochemical Variations of Paleozoic Gas/Condensate Reservoirs from the Ghawar Structure of Saudi Arabia: Gas Souring, Filling History, and Reservoir Compartmentalization. Org. Geochem., 29, 785-798.

235. PHILP, R.P. and CHOUPAROVA, E. (1997). Time dependent changes in waxes and asphaltenes during oil production. Org. Geochem., 29, 449-462.

236. PHILP, R. P. (1998). Forensic Geochemistry, Natural Resources and Environment., 67-69.

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237. THANH, N.X., HSIEH, M. and PHILP, R.P. (1999). Waxes and asphaltenes in crude oils. Org. Geochern .. 30, 119-132.

238.DEL RIO, J.C. and PHILP, RP. (1999). Field ionization mass spectrometric study of high molecular weight hydrocarbons in a crude oil and a solid bitumen. Org. Geochern.. 30, 279-286.

239. STOUT, S.A., UHLER, RICHARD, M., PHILP, R. PAUL., ALLEN, JON, UHLER, ALLEN, D. (1998). Source differentiation of individual chlorinated solvents dissolved in groundwater using compound specific carbon isotope analyses. Am. Chern. Soc., Div. Environ. Chern. 1988., Preprints of Extended Abs., 38(2), 2-5.

*240.PHILP, R.P. (1999). Carbon Isotopes in Gas Exploration and Production. In: Proceedings of the Tornsk Gas Company, pp86-88. Tornsk, Russia.

241. HSIEH, M. and PHILP, R.P. (1999). Characterization of High Molecular Weight Biomarkers in Crude Oils. In: Extended Abstracts of the International Meeting of the European Organic Association of Geochemists, Istanbul, September, 1999.

242.MATYASIK, I., STECZKO, A. and PHILP, R.P. (1999). Geochemical Characterization of Oils from Selected Boreholes from the Eastern Carpathians - Poland. In: Extended Abstracts of the International Meeting of the European Organic Association of Geochemists, Istanbul, September, 1999.

243.RUBLE, T.E., LEWAN, M.D. and PHILP, R.P. (1999). Variability in the immiscible oils generated during hydrous pyrolysis of distinct lacustrine organofacies within the Green River Petroleum System, Uinta Basin. In: Extended Abstracts of the International Meeting of the European Organic Association of Geochemists, Istanbul, September, 1999.

244.DEL RIO, J.C. and PHILP, RP. (1999). Field ionization mass spectrometric study of high molecular weight hydrocarbons in crude oils and solid bitumens. In: Extended Abstracts of the International Meeting of the European Organic Association of Geochemists, Istanbul, September, 1999.

245. KASHIRTSEV, V.A., KONTOROVISCH, A.E. PHILP, R.P., CHALAYA, O.N., ZUEVA, LN., and MEMETOVA, N.P. (1999). Biomarkers in crude oils of the eastern Siberian Platform as indicators of paleoenvironment of source rock deposition. Geologiya I Geofizika, 40 ( 11 ), 1700-1711.

246. Ll, J., PHILP, R.P. and CUI, M. (2000). Methyl diamantane index (MDI) as a maturity parameter for Lower Palaeozoic carbonate rocks at high maturity and over maturity. Org. Geochern., 31, 267-272.

*247.PHILP, R.P. (2000). Unique Fingerprints derived the Isotopic Composition oflndividual

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Compounds in Complex Mixtures. International Business Conference Meeting, Washington, June 2000.

248. R. PAUL PHILP, M. HSIEH and D. KIM, (2000). Waxes and asphaltenes in crude oils and source rock extracts. In: Proceedings of the ih ALAGO Meeting, Iguassu, Brazil, pp288-292.

*249. PHILP, R. PAUL, SMALLWOOD, B., and ALLEN, J.. (2000). Gas chromatography­isotope ratio mass spectrometry. An alternative approach for monitoring the origin and fate of contaminants in the environment. ALAGO Meeting, Iguassu, Brazil, pp. 245-249.

250.PHILP, R. P. (2000). Geochemical Analysis: Gas Chromatography and GC-MS. Encyclopedia of Separation Science. Wilson ID, Adlard ER, Cooke M and Poole CF (Eds) Vol 7:2948-2959. London: Academic Press.

251. M. HSIEH and PHILP, R. P., (2000).Characterization of High Molecular Weight Biomarkers in Crude Oils. Org. Geochem., 31(12), 1581-1588.

252. GOLOVKO, J., PHILP, R.P., PENEVA, G., and GOLOVKO, A., (2000). High molecular weight n-alkanes in oils of West Siberia and Sakhalin Island. In: Novelties in Enhanced Oil and Gas Recovery (I. Lakatos, ed.). Akademiai Kiado, Budapest, pp 315-324.

253. PHILP, R.P.(1999). Petroleum-Surface Prospecting, In [C.Marshall and R.W. Fairbridge, eds.], Encyclopedia of Geochemistry, Kluwer Academic Publishers, The Netherlands, 502-504.

254. BENALIOULHAJ, S., TRICHET, J., BENALIOULHAJ, N., LUCAS, J., SCHREIBER, B.C. and PHILP, R.P (2000). Black Shales and Phosphorites, Results of Differential Diagenetic Evolution of Organic Matter in the Oulad Abdoun-Timahdit Sedimentary Basin (Morocco). In Marine Authigenesis: From Global to Microbial, (Eds. Craig R. Glenn, Liliane Prevot-Lucas and Jacques Lucas), SEPM Special Publication No. 66, pp. 234-252.

*255. PHILP, R. PAUL, SMALLWOOD, B., ALLEN, J. (2000). Correlation ofweathered and unweathered oil samples using the carbon isotopic composition of individual components in the crude oil. In: Oil and Hydrocarbon Spills, II. (Eds. G.R. Rodriguez and C.A. Brebbia). WIT Press, Southampton, UK. pp211-221.

256. LI, J., PHILP, R.P. and CUI, M. (2000). Methyl diamantane index (MDI) as a maturity parameter for Lower Palaeozoic carbonate rocks at high maturity and over maturity. Org. Geochem., 31, 267-272.

257. MATYASIK, I., STECZKO, A., PHILP, R.P., (2000). Biodegradation and migrational fractionation of oils from the Eastern Carpathians, Poland. Org. Geochem.,31, 1509-1524.

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*258. SMALLWOOD, B.J., PHILP, R. PAUL, BURGOYNE, T. W., and ALLEN, J.D. (2001) The use of stable isotopes to differentiate specific source markers for MTBE. Environmental Forensics, 2(3), 215-222.

*260.SMALLWOOD, B. J. PHILP, R. PAUL and ALLEN, J.D. (2002). Stable carbon isotopic composition of gasolines determined by isotope ratio monitoring gas chromatography mass spectrometry. Organic Geochemistry, 33, 149-159.

261.WANG, H.D. and PHILP, R.P. (2001). Geochemical characterization of selected oils and source rocks from the Chester Formation, Springer Formation and Morrow Group of the Anadarko Basin. In: Johnson, K.S. (ed.), Pennsylvanian and Permian geology and Petroleum in the southern Midcontinent, 1998 symposium: Oklahoma Geological Circular 104, p41-57.

262.KIM, DONGWON and PHILP, PAUL R. (2001). Extended tricyclic terpanes in Mississippian Rocks from the Anadarko Basin. In: Johnson, K.S. (ed.), Silurian, Devonian, and Mississippian geology and petroleum in the Southern Midcontinent, 1999 symposium; Oklahoma Geological Survey Circular, 105, p109-127.

263. B.C. SCHREIBER, R.P. PHILP, S. BENALI, M L. HELMAN, J.A DE LA PENA, R. MARFIL, P. LANDAIS, A.D. COHEN, and C.G.ST.C. KENDALL. (2001). Characterization of organic matter formed in hypersaline carbonate/evaporite environments: hydrocarbon potential and biomarkers through artificial maturation studies. J. Petrol. Geol. 24(3), 309-338.

264.HSIEH, M. and PHILP, R. PAUL (2001). Ubiquitous occurence of high molecular weight hydrocarbons in crude oils. Org. Geochem. 32(8), 955-966.

265. PHILP, R. PAUL (200 1 ). Application of Stable and Radioisotopes in Environmental Forensics. In: Introduction to Environmental Forensics (B. Murphy and R. Morrison,Eds.), Academic Press, London. pp 99-136.

266. RUBLE, T., LEWAN, M.D. and PHILP, R.P. (2001). New insights on the Green River petroelum system in the Uinta Basin from hydrous pyrolysis experiments. AAPG Bull., 85(8), 1333-1371.

267. WANG, H.D. and PHILP, R. P. (2001). Geochemical characteristics of selected oils and source rocks from the Chester Formation, Springer Formation, and the Morrow Group of the Anadarko Basin. In: Pennsylvanian and Permian geology and petroleum in the southern Midcontinent, 1998 Symposium (ed. K.S. Johnson): Oklahoma Geological Survey Circular 104, p.41-57.

268.CHOUPAROVA, E., ROTTMAN, K., and PHILP, R.P. (2001). Geochemical study of oils produced from Four Pennsylvanian Reservoirs in Prairie Gem Field, Central Oklahoma. In: Pennsylvanian and Permian geology and petroleum in the southern Midcontinent, 1998 Symposium (ed. K.S. Johnson): Oklahoma Geological Survey Circular 104, p.105-113 ..

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269. OLSON, PAUL E., FLETCHER, JOHN S. and PHILP, R.PAUL (2001). Natural attenuation /phytoremediation in the vadose zone of a former industrial sludge basin. Environ. Sci. And Poll. Res., 8(4), 243-249.

270.HUNT, J. M., PHILP, R.P. and KVENVOLDEN, K. (2002). Early developments m petroleum geochemistry. Org. Geochem. 33(9), 1025-1052.

271. LI JINGGUI, R. PAUL PHILP, CUI MINGZHONG (2002). Origin of Unusual n-Alkane Distributions in Extracts of Marine Carbonate Rocks at High Levels of Maturity and Overmaturity. Chinese J. of Geochemistry, 21(3), 322-333.

272. R. PAUL PHILP, JOHANA VARGAS, (2002). Reservoir geochemistry studies in the Maranon Basin, Peru. INGEPET2, Lima, Peru, November, 2002.

273. R. PAUL PHILP and M. HSIEH (2002). Separation ofwaxes and asphaltenes in crude oils. INGEPET2, Lima, Peru, November, 2002.

274. R. PAUL PHILP, JON ALLEN, and TOMASZ KUDER (2002). The Use ofthe Isotopic Composition oflndividual Compounds for Correlating Spilled Oils and Refined Products in the Environment with Suspected Sources. AMOPS Conference, Calgary, June 2002.

275. R. PAUL PHILP, JON ALLEN, and TOMASZ KUDER (2002). The Use of Stable Isotopes for Correlating Spilled Oils and Refined Products in the Environment with Suspected Sources. International Oil Spill Conference, Rhodes, Greece, September 2002. In: Oil and Hydrocarbon Spills, II. (Ed. C.A. Brebbia). WIT Press, Southampton, UK. Pp67-76.

276. R. PAUL PHILP, JON ALLEN, and TOMASZ KUDER (2002). The Use of the Isotopic Composition of Individual Compounds for Correlating Spilled Oils and Refined Products in the Environment with Suspected Sources. J. Environ. Forensics, 3, 341-348.

277. YIM, W.W.-S., CHAN, L.S., HSIEH, M., PHILP, R.P., and RIDLEY THOMAS, W.N. (2002). Carbon flux during the last interglacial cycle in the inner continental shelf of the South China Sea off Hong Kong. Global and Planetary Change, 35, 29-45, 2002.

278. R. PAUL PHILP, TOMASZ KUDER and JON ALLEN, (2002). An Improved Fingerprinting Method for Refined Hydrocarbon Products. NGW A Workshop volume. In press.

279. T. KUDER, R.P. PHILP, R. KOLHATKAR, J.T. WILSON and J. ALLEN (2002). Application of Stable Carbon and Hydrogen Isotopic Techniques for Monitoring Biodegradation of MTBE in the Field. NGW A Meeting, Atlanta, November, 2002. In: Proceedings of the Petroleum Hydrocarbons and Organic Chemicals in Groundwater, National Groundwater Association: Atlanta, GA, pp. 371-381.

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280. KOLHATKAR, R., KUDER, T., PHILP, R.P., ALLEN, J., and WILSON, J.T. (2002). Use of compound specifc carbon isotope analyses to demonstrate anaerobic biodegradation of MTBE in groundwater and a gasoline release site. Environ. Sci. Technol., 36(23), 5139-5146.

281. PHILP, R.P., (2003). Formation and Geochemistry of Oil and Gas. In "Treatise On Geochemistry" (Vol. Ed. F. Mckenzie; Ex. Eds. H.D. Holland and K. Turekian.), Vol. 7, Chapter 10, pp. 223-256. Published Dec. 2003, Elsevier, New York.

282. R. PAUL PHILP, JON ALLEN, and TOMASZ KUDER (2003). Environmental Forensic Applications of Stable Carbon and Hydrogen Isotopes. Battelle Meeting, Orlando, June 2003.

283 KUDER, T., PHILP, R. P., ALLEN, J., KOLHATKAR, R., WILSON, J., and LANDMEYER, J., (2003). Compound-specific stable isotope analysis to demonstrate in-situ MTBE biotransformation. Battelle Meeting, Orlando, June 2003.

284.SABER, D., MAURO, D., PHILP, R.P., ALLEN, J., and KUDER, T., (2003). Carbon isotope ratios of P AHs in urban background soil. Battelle Meeting, Orlando, June 2003.

285. T. KUDER, R. KOLHATKAR, J. WILSON, K. O'REILLY, P. PHILP, J. ALLEN, (2003). Compound-Specific Carbon and Hydrogen Isotope Analysis - Field Evidence of MTBE Bioremediation. NGW A Meeting, June 2003. Baltimore.

286. T. KUDER, R. KOLHATKAR, J. WILSON, K. O'REILLY, P. PHILP, J. ALLEN, (2003). Compound-Specific Isotope Analysis - Field Evidence of MTBE Bioremediation. NGW A Meeting Costa Mesa, August, 2003.

287. PHILP, R. P. (2003). The use of thermal analytical methods in organic geochemistry. In: Natural and Laboratory Simulated Thermal Geochemical Methods-(ed. R. Ikan). Kluwer Academic Publishers, Dordrecht, pp.297-325.

288. NANNY, M., ANDRUS, V.E., and PHILP, R.P. (2003). Humate as a prom1smg remediation enhancer for crude oil spills in surface soils: Interpreting microcosm and adorption experiment results. In : Proceeding of the Fifth International Oil and Gas Conference-Tomsk 2003 ( ed. A.K. Golovko ). Published by the Publishing House of the Institute of Atmospheric Optics SB RAS, Tomsk. pp. 552-555

289. PHILP, R. P. (2003). Book review of "Analytical Advances for Hydrocarbon Research (ed. Chang Samuel Hsu). Kluwer Academic/Plenum Publishers. Journal of the American Society for Mass Spectrometry, 14(11), 1327-1328.

290. JINCAI TUO AND R. PAUL PHILP (2003). Occurrence and distribution of high molecular weight hydrocarbons in selected non-marine source rocks from the Liaohe, Qaidam and Tarim Basins, China. Organic Geochemistry, 34, 1543-1558.

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291. PHILP, R. P., 2003, Petroleum geochemistry, with a brief introduction to applications to exploration and production in Oklahoma. Shale Shaker, 54(3), 69-79.

292. CHOUPAROV A, E., LANZIROTTI, A., FENG, H., JONES, K. W., MARINKOVIC, N., WHITSON, C. and PHILP, P. (2004). Characterization of petroleum deposits by synchrotron radiation-based microanalyses. Energy & Fuels~' 1199-1212.

293. T. KUDER, R. KOLHATKAR, J. WILSON, P. PHILP, J. ALLEN(2004). Compound­Specific Isotope Analysis of MTBE and TBA for Bioremediation Studies. NGW A Meeting Baltimore. Aug. 2004. Extended Abs.

294. PHILP, R. P., HSEIH, M. and TAHIRA, F., (2004). A Review of Developments Related to the Characterization and Significance of High Molecular Weight Paraffins (>C40) in Crude Oils. In: Understanding Petroleum Reservoirs:towards an Integrated Reservoir Engineering and Geological Approach (Cubitt, J.M., England, W.A. and Larter, S. eds) Royal Geological Society, London, 237,37-51.

295. PHILP, R. PAUL, and MICHAEL HSIEH, (2004). High Molecular Weight Paraffins (>C40) in Crude Oils and Source Rocks. AAPG Meeting Cancun, October, 2004. Extended abstract.

296. BOUKADI, A., PHILP, R.P., THANH, N.X. (2005). Characterization of Paraffinic Deposits in Crude Oil Storage Tanks using High Temperature Gas Chromatography. Applied Geochemistry, 20(10), 1974-1983.

297. LI, J., PHILP, R.P., ZIFANG, M., WENHUI, L., JIANJING, Z., GUOJUN, C., LI, M. and WANG, Z. (2005). Aromatic Compounds in Crude Oils and Source Rocks and Applications to Oil-Source Rock Correlations in the Tarim Basin, NW China. J.SE Asian Earth Sciences, 25(2), 251-268.

298. ABBOUD, M., PHILP, R.P. and ALLEN, J. (2005). Geochemical characterization of oils and source rocks from the Arabian Platform and Mesopotamian Basin, NE Syria. J. Petroleum Geology, 28(2), 203-218,2005.

299. YOUNES, M.A. and PHILP, R. P., (2005). Source rock characterization based on biological marker distributions of crude oils in the Southern Gulf of Suez, Egypt. J. Petroleum Geology, 28(3),

300. TUO, J. and PHILP, R.P. (2005). Saturated and aromatic diterpenoids and triterpenoids in Eocene coals and mudstones from China. Applied Geochemistry, 20, 367-381.

301. KUDER, T., WILSON, J., KAISER, P., KOLHATKAR, R., PHILP, R. P. and ALLEN, J. (2005). Enrichment of stable carbon and hydrogen isotopes during anaerobic biodegradation of MTBE: microcosm and field evidence. Environ. Sci. and Technol., 39, 213-220.

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302. MICHAEL HSIEH, R. PAUL PHILP, WYSS YIM (2005). Utilization of Lipid Markers to Delineate Sources of Organic Matter in Recent Core Sediments from Victoria Harbour, Hong Kong. International Meeting of Organic Geochemists, Seville, Spain. (Extended Abstract).

303. DONGWON KIM and PAUL R. PHILP (2005). Mixing of crude oils and solid deposition in the Hitch reservoir, Southwest Kansas. International Meeting of Organic Geochemists, Seville, Spain. (Extended Abstract).

304. TOMASZ KUDER, PAUL PHILP, JOHN WILSON, and JON ALLEN (2005). Compound­specific isotope analysis applied to MTBE biodegradation studies. International Meeting of Organic Geochemists, Seville, Spain. (Extended Abstract).

305. XUEMING PAN and R. PAUL PHILP (2005). Identification of 17,21-Secohopanoic Acids in Source Rocks and Crude Oils. International Meeting of Organic Geochemists, Seville, Spain. (Extended Abstract).

306. PAMELA GERREZ V. TANEZA, and R. PAUL PHILP (2005). Occurrence ofpolycylic aromatic hydrocarbons (PAHs) and organochlorine compounds in Iloilo River, Philippines. International Meeting of Organic Geochemists, Seville, Spain. (Extended Abstract).

307. GOLOVKO, J., PHILP, R.P., PEVNEVA, G. and GOLOVKO, A. (2005). High molecular weight hydrocarbon distributions in marine oils, Volga-Ural Basin, Russia. International Meeting of Organic Geochemists, Seville, Spain. (Extended Abstract).

308. GURGEY, K., PHILP, P., CLAYTON, C., EMIROGLU, H., SlY AKO, M. (2005). Geochemical and isotopic approach to maturity/source/mixing estimations for natural gas and associated condensates in the Thrace Basin, NW Turkey. Applied Geochemistry, 20, 2017-2037.

309. WILSON, J., KOLHATKAR, R., KUDER, T., PHILP, R. P. and DAUGHERTY, S. (2005). Stable Isotope Analysis of MTBE to Evaluate the Source of TBA in Ground Water. Ground Water Monitoring and Remediation, 25(4), 108-116.

310. PHILP R. P. and JARDE, E. (2006). Application of Stable and Radioisotopes in Environmental Forensics. In: Introduction to Environmental Forensics (B. MURPHY and R. MORRISON Eds.).

3ll.PHILP, R.P. and KUDER, T. (2006). Biomarkers and Stable Isotopes in Environmental Forensics. (A. BALL and S. MUDGE, Eds).

312. XUEMING PAN and R. PAUL PHILP (2006). Identification of 17 ,21-Secohopanoic Acids in Source Rocks and Crude Oils. Organic Geochemistry, 37,1085-1100.

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313. PHILP, R. P. and HSIEH, M. (2006). The Evolution of Reservoir Geochemistry. 26th Annual Gulf Coast Section SEPM Foundation Bob F. Perkins Research Conference, Houston Dec. 2006. pp1190-1232.

314. R. PAUL PHILP, TOMASZ KUDER, JON ALLEN, (2006). Environmental forensics­Emergence of novel aproaches for existing problems. ALAGO Meeting Brazil, Nov. 2006.

315. A.E. NAVARRO FROMETA, R.P. PHILP, (2006). Thiosteranes as biomarkers to assess water pollution. ALAGO Meeting Brazil, Nov. 2006.

316. R. PAUL PHILP, TOMASZ KUDER and JON ALLEN (2006). The Emerging Role of Stable Isotopes in Environmental Forensic Studies. 2006 NGWA Ground Water and Environmental Law Conference, Chicago, July, 2006.

317. PHILP, R. PAUL, (2006). The role of geochemistry in tight gas shale exploration. Caney Shale Gas Workshop, Oklahoma City, August 2006.

318. PHILP, R.P. (2007). The Emergence of Stable Isotopes in Environmental and Forensic Geochemistry Studies. Environmental Chemistry Letters, 5(2), 57-66.

319. PHILP, R.P., PIRKLE, R.J., McCOUGHLIN, P.W., PEACOCK, A.D., and YANG, X. (2007). Monitored natural attenuation forum: The use of carbon isotope analyses at MNA sites. Remediation, 127-137.

318. Liang, X., Dong, Y., Kuder, T., Krumholz, L., Philp, R.P., and Butler,E.C. 2007. Distinguishing abiotic and biotic transformation of tetrachloroethylene and trichloroethylene by stable carbon isotope fractionation. Environmental Science and Technology, Environmental Science and Technology 40, 7094-7100.

319. PAMELA GERREZ V. TANEZA, and R. PAUL PHILP (2009). Occurrence ofpolycylic aromatic hydrocarbons (P AHs) and organochlorine compounds in Iloilo River, Philippines. L Environ. Forensics, 10(1), 68-82.

320. KUDER, T. and PHILP, R. PAUL. (2008). Modern geochemical and molecular tools for monitoring in-situ biodegradation ofMTBE and TBA. Rev. Environ. Sci. Biotechnol., 7, 79-91.

321. PHILP, R. PAUL and KUDER, TOMASZ. (2008). Biomarkers and stable isotopes in environmental forensic studies. In: (S.M. Mudge-Editor) Methods in Environmental Forensics. Ch. 4. pp. 113-171. CRC Press, Boca Raton, Florida. pp315-334.

322. PHILP, R. PAUL (2009). The Utilization of Stable Isotopes in Environmental and Forensic Geochemistry Studies. In: Environmental Impact Assessments (Eds. G.T. Halley and Y.T. Fridian). Nova Science Publishers, New York. Chapter 10, pp31-334

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323. KUDER, T., PHILP, R.P. and ALLEN, J. (2009). Effects of Volatilization on Carbon and Hydrogen Isotope Ratios of MTBE. Environ. Sci. Techno!., Articles ASAP (As Soon As Publishable)Publication Date (Web): February 12,2009 (Article)DOI: 10.1021/es802834p. Environ. Sci. Techno!., 43 ( 6), 1763-1768.

324. DONG, Y., LIANG, X., KRUMHOLZ, L.R., PHILP, R.P. and BUTLER, E.C. (2009). The Relative Contributions of Abiotic and Microbial Processes to the Transformation of Tetrachloroethylene and Trichloroethylene in Anaerobic Microcosms. Environ. Sci. Techno!., 2009, 43 (3), 690-697.

325. SLATT, ROGER, SINGH, PRERNA, PHILP, R. PAUL, K.J. MARFURT, KURT, J., ABOUSLEIMAN, YOUNANE, and O'BRIEN, N.R. (2008). Workflow for Stratigraphic Characterization of Unconventional Gas Shales. 2008 SPE Shale Gas Production Conference, in Fort Worth, Texas, U.S.A., 16-18 November 2008. Published in the SPE Proceedings.

326. KUDER, T. and PHILP, R. PAUL (2009). Monitoring of gasoline range contaminant attenuation by stable isotope analyses. Presented at the 21st Annual National Tanks Conference and Exposition, Sacramento, CA. March 30th_April1 5\ 2009. Poster only.

327. NAVARRO FROMETA, A. E., CASO VARGAS, L.R., PHILP, R. P. (2009). Low molecular weight oxygenated organic compounds as tracers of anthropogenic inputs to surface waters. Submitted to ALAGO J.

328. PHILP, R.P. (2009). Environmental forensic geochemistry studies and stable isotopes. ALAGO J., 1, 68-76.

329. JORGE E. CORTES, JOSE M. RINCON, JOSE M. JARAMILLO, R. PAUL PHILP and JON ALLEN (20 1 0). Biomarkers and compound-specific stable carbon isotope composition of n-alkanes in crude oils from Eastern Llanos Basin, Colombia. J. S. Am. Earth Sci., 29, 198-213.

330. LIANG, X., PHILP, R.P. and BUTLER, E.C. (2009). Kinetic and isotope analyses of tetrachloroethylene and trichloroethylene degradation by model Fe (H)-bearing minerals. Chemosphere, 75(1), 63-69.

331. Savage, Kristen; Krumholz, Lee; Gieg, Lisa; Parisi, Victoria; Suflita, Joseph; Allen, Jon; Philp, R. Paul; Elshahed, Mostafa (20 1 0). Biodegradation of low molecular weight alkanes under mesophilic, sulfate-reducing conditions: metabolic intermediates and community patterns FEMS Microbiology Ecology

332. Dongwon Kim, R. Paul Philp, and Raymond P. Sorenson (2010). Geochemical characterization of solid bitumen in the Chesterian (Mississippian) sandstone reservoir of the Hitch Field, Southwest Kansas. Am. Assoc. Petrol. Geol. Bull., -In press.

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333. Norelis D. Rodriguez Maiz and R. Paul Philp (2010). Geochemical characterization of gases from the Mississippian Barnett shale, Fort Worth Basin, Texas. Am. Assoc. Petrol. Geol. Bull., -In press.

334. R. Paul Philp and Guillermo Lo Monaco (20 1 0). Applications of stable isotopes in hydrocarbon exploration and environmental forensics. Submitted.

335. Yiran Dong; Elizabeth C Butler; Richard P Philp; LeeR Krumholz. (2010). Impacts of Microbial Community Composition on Isotope Fractionation during Reductive Dechlorination of Tetrachloroethylene. Biodegradation J. Submitted.

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Published Abstracts 1. TOSTE, A.P., STEEL, G., PHILP, R.P. and CALVIN, M. (1974). Incorporation and microbial diagenesis of sterols in Recent sediments. Proc. 1974 Geol. Soc. Amer. Meeting, p.989.

2. PHILP, R.P. (1975). Pyrolysis experiments on kerogen-precursors isolated from recently-deposited algal oozes. Proc. 1975 Geol. Soc. Amer. Meeting, 7(7), p. 1228.

3. PHILP, R.P., TOSTE, A and CALVIN, M. (1975). Early stage formation and structure of kerogen-like material in Recent sediments. Proc. Pac. Conf. Chern and Spec., p. 70.

4. PHILP, R.P., CALVIN, M., BROWN, S. and YANG, E. (1976). Organic geochemical studies on kerogen precursors in recently-deposited algal mats and oozes. 25th International Geological Congress, J, p. 253.

5. NISHIMURA, H., PHILP, R.P. and CALVIN, M (1976). Lipids of Hevea brasiliensis and Euphorbia coerulescens. lOth I.U.P.A.C. Symposium on Nat. Prods., p. B8.

6. PHILP, R.P. and YANG, E. (1977). Saponification ofthe insoluble residues from algae, phytoplankton, and algal oozes. Proc. 53rd Annual Meeting of the AAAS Southwestern and Rocky Mountain Division, Denver, February, 1977, p. 34.

7. PHILP, R.P. and GILBERT, T.D. (1980). Pyrolysis-gas chromatography-mass spectrometry of coals and oil source rocks. ANZSMS Abstracts 1980, p.79.

8. SIMONEIT, B.R.T. and PHILP, R.P. (1980). Effects ofbasalt intrusions on kerogens in unconsolidated oceanic sediments in Guaymas Basin, Gulf of California. AAPG-SEPM-EMD Ann. Conv., Denver, June 8-11, 1980.

9. PHILP, R.P. GILBERT, T.D. and FRIEDRICH, J. (1980). Characterization of the insoluble organic matter of coals and oil shales by Curie-point pyrolysis combined with gas chromatography and computerized-gas chromatography-mass spectrometry. Am. Chern. Soc. Meeting, Las Vegas, August 24-29, 1980.

10. GILBERT, T.D. and PHILP, R.P. (1980). The characterization of Australian coals by Curie point pyrolysis combined with computerized gas-chromatography-mass spectrometry. 12th Australian Spectroscopy Conf., Sydney, August 25-29.

ll.PHILP, R.P. and GILBERT, T.D. (1981). The application of pyrolysis-gas chromatography­mass spectrometry to the structural characterization of Australian coals. Abs. of Amer. Soc. Mass Spec., Minneapolis, p. 212.

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12. GILBERT, T.D., PHILP, R.P. and FRIEDRICH, J.M. (1981). An investigation into the organic geochemistry of fossil fuels by pyrolysis-gas chromatography-mass spectrometry. ANZMS Abstracts 1981, p. 27.

13. GILBERT, T.D. and PHILP, R.P. (1983). The detection of biological markers in crude oils and source rocks by gas chromatography-mass spectrometry. ANZMS Abstracts 1983, p.20.

14. PHILP, R.P. and GILBERT, T.D. (1983). Combined liquid chromatography-mass spectrometry studies in fossil fuel research. ANZMS Abstracts 1983, p.22.

15. BROPHY, J.J., CAVILL, G.W.K., DAVIES, N.W., GILBERT, T.D. PHILP, R.P. and PLANT, W.D. (1983). Hydrocarbon constituents of three Australian Dolichoderine ants. ANZMS Abstracts 1983, p.40.

16. GILBERT, T.D. and PHILP, R.P. (1984). Terrestrial plant organic matter its contribution to the formation of crude oil in Australia and New Zealand: GC/MS evidence. ANZSMS Abstracts 1984, p.24.

17. PHILP, R.P. and GILBERT, T.D. (1985). Geochemical investigation of Australian and New Zealand crude oils. AAPG Ann. Meeting, 1985 (Abs. only).

18. PHILP, R.P. and JOHNSTON, M. (1985). Biomarkers in terrestrially derived crude oils from Australia and New Zealand as determined by GCMS and MS/MS. ACS Meeting, Miami, April, 1985.

19. PHILP, R.P. and JOHNSTON, M. (1985). Biomarker determinations in crude oils and source rock extracts by tandem mass spectrometry. lOth Int. Mass Spec. Conf., Swansea, Wales, Sept., 1985.

20. JONES, P. and PHILP, R.P. (1986). The petroleum geochemistry of oils and source rocks from the Pauls Valley area of the Anadarko Basin, Oklahoma. ACS National Meeting, New York, April, 1986.

21. PHILP, R.P. and BAKEL, A. (1986). Microscale pyrolysis of source rocks and coals and production of sulfur compounds. ACS Meeting, Anaheim, Sept., 1986.

22. BONILLA, J.V., ENGEL, M.H., LEWIS, C.A. and PHILP, R.P. (1986). Redistribution of biological marker compounds during crude oil migration. GSA Meeting, 1986, San Antonio. (Abs. only).

23. PHILP, R.P. and BAKEL, A. (1987). Production ofheteroatomic compounds from coals and source rocks of varying maturities and source materials. ACS Meeting, Denver, April, 1987. (Abs. only).

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24. JONES, P.J., LEWIS, C.A., PHILP, R.P., LIN, L.H. and MICHAEL, G.H. (1987). A geochemical study of oils, source rocks and tar sands in the Pauls Valley Area, Anadarko Basin, Oklahoma. AAPG Meeting, Los Angeles, June, 1987.

25. MICHAEL, G.E. and PHILP, R.P. (1987). Effects of biodegradation upon porphyrin biomarkers in Upper Mississippian Tar Sands and related oils, Southern Oklahoma. AAPG Meeting, Los Angles, June, 1987.

26. BAKEL, A., GALVEZ-SINIBALDI, A. and PHILP, R.P. (1987). Variations in Sulphur Containing Compounds Produced by Pyrolysis of Kerogens, Asphaltenes and Kerogen Precursors and resulting from variations in source, maturity and depositional environments. Int. Org. Geochem. Meeting, Venice, 1987.

27. ZHUSHENG, J. and PHILP, R.P., (1987). Fractionation of biological markers in crude oils during migration and the effects on correlation and maturation parameters. Int. Org. Geochem. Meeting, Venice, 1987.

28. PHILP, R.P. and LEWIS, C.A. (1987). Biomarker determinations using the Ion Trap Detector. ACS National Meeting, New Orleans, Sept. 1987.

29. PHILP, R.P. ( 1987). Geochemistry in Petroleum Exploration. UNESCO Meeting, Bangkok, Thailand, October 1987.

30. PHILP, R.P. (1987). The use of the triple stage quadrupole mass spectrometer m geochemistry. 6th International Danube Symposium, Varna, Bulgaria, October 1987.

31. OUNG, J.N. and PHILP, R.P. (1988). Biomarker determinations in Crude oils using a Triple Stage Quadruple Mass Spectrometer. ACS Regional Meeting, Ponca City, April 1988.

32. CLARK, J.P. and PHILP, R.P. (1988). The Biomarkers of evaporite and carbonate sourced petroleum, Black Creek Basin, Alberta Canada.

33. MICHAEL, G.E. and PHILP, R.P. (1988). Effect of biodegradation upon parphyrin biomarkers in Upper Mississippian Tar Sands and Related Oils, Southern Oklahoma. ACS Regional Meeting, Ponca City, April 1988.

34. WENGER, L.M., PHILP, R.P. and BAKER, D.R. (1988). Delineation of organic matter source in Pennsylvannian Aged sediments of Oklahoma and Kansas using pyrolysis-gas chromatography and biomarker distributions. V. M. Goldschmidt Conference, Baltimore, Maryland, May 1988.

35. PHILP, R.P., OUNG, J-N., and LEWIS, C.A. (1988). Advances in mass spectrometric techniques applied to petroleum geochemistry. V. M. Goldschmidt Conference, Baltimore, Maryland, May 1988.

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36. WENGER, L.M., PRICE L.C. and PHILP, R.P. (1988). The effect of pressure on artificial maturation studies. Southern Regional Geochemistry Meeting Cabs. only), Houston, May 1988.

37. WOOLHOUSE, A.D., OUNG, J-N., PHILP, R.P. and WESTON, R.J. (1988). Occurrence and identification of novel terpanoids in terrestrial oils from Tertiary Basins. Southern Regional Geochemistry Meeting Cabs. only), Houston, May 1988.

38. SUZUKI, NORlYUKI and PHILP, R.P. (1988). Sulphur incorporation by H2S into recent algal mat and melanoidin. Southern Regional Geochemistry Meeting (abs. only), Houston, May 1988.

39. OUNG, J-N. and PHILP, R.P. (1988). Biomarker determinations by MS/MS. Southern Regional Geochemistry Meeting (abs. only), Houston, May 1988.

40. PHILP, R.P. and GARG, A.K. (1988). Characterization of some sedimentary sequences from Cambay Basin, India by pyrolysis-gas chromatography. Proc. 2nd Afro-Asian Petroleum Geochemistry Conference (submitted).

41. PHILP, R.P., FAN, P., LEWIS, C.A., LI, J., ZHU, H. and WANG, H. (1988). A geochemical study of oils and source rocks from the Chaidamu, Shanganning and Jianghang Basins, China. Proc. 2nd Afro-Asian Petroleum Geochemistry Conference (submitted).

42. JIANG, Z. and PHILP, R.P. (1988). Novel tricyclic alkanes in the crude oils from Kelamayi oilfield of China. Proc. 2nd Afro-Asian Petroleum Geochemistry Conference (submitted).

43. VALLEJOS, C., TALUKDAR, S. and PHILP, P. (1988). Distribution of Organic Sulfur Compounds in Artificially Matured Source-Rocks and Kerogens. 1st Organic Geochemistry Conference of Latin America, Rio de Janerio, Brazil, Nov. 1988.

44. PHILP, R.P. (1988). Advances in Mass Spectrometric Techniques Applied to Petroleum Geochemistry. 1st Organic Geochemistry Conference of Latin America, Rio de Janerio, Brazil, Nov. 1988.

45. PHILP, R.P. (1988). Kerogen - Origin, Formation and Destruction. GSA Meeting, Denver, November 1988.

46. SUZUKI, N. and PHILP, R.P. (1988). Sulfur incorporation by H2S into Recent algal mats and melanoidins. The 1988 Annual Meeting of the Geochem. Soc. of Japan, Hiroshima, Japan.

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47. PHILP, R.P., ZHU, H. and FAN, P. (1989). The Geochemical Characteristics of some Oils derived from Lacustrine Sediments, China. AAPG Meeting, San Antonio, April 1989.

48. PHILP, R.P., WENGER, L., BAKEL, A. and GALVEZ-SINIBALDI, A. (1989). Characterization of Organosulphur Compounds in Oklahoma Coals by Pyrolysis-Gas Chromatography. ACS National Meeting, Dallas, April 1989.

49. OUNG, JUNG-NAN and PHILP, R.P. (1989). Quantitative Biomarker Determinations by MS/MS. ACS National Meeting, Dallas, April1989.

50. CHEN, J. and PHILP, R.P. (1989). Porphyrin Distributions in Crude Oils from the Jianghan and Tarim Basins, China. ACS National Meeting, Dallas, April1989.

51. PHILP, R.P. ( 1989). Biomarkers in Oil Exploration. International Geological Congress, Washington, July 1989.

52. PHILP R.P. (1989). Thermal Maturity of Sedimentary Basins using Molecular Organic Geochemistry. International Geological Congress, Washington, July 1989.

53. BAKEL, A.J. and PHILP, R.P. (1989). The Distribution and Qunatification of Organic Nitrogen Compounds in Crude Oils and Kerogen Pyrolysates. International Geochemistry Meeting, Paris, Sept. 1989.

54. YU XINKE, FAN PU and PHILP, R.P. Novel biomarkers found in South Florida Basin. International Geochemistry Meeting, Paris, Sept. 1989.

55. FAN PU, LI ZHENXI, YING GUANGGUO and PHILP, R.P. (1989). Geochemical characteristics of aromatic hydrocarbons of crude oils from different sedimentary environments. International Geochemistry Meeting, Paris, Sept. 1989.

56. RUBLE, T.E., and PHILP, R.P. (1989). Geochemical characterisation of some native bitumens from the Uinta Basin, Utah, U.S.A. 1989 Geol. Soc. Am. Ann. Meeting. (abst. only).

57. FAN, PU, PHILP, R.P., MENG, Q., CHEN, X., LI, J., YU, X., LI, Z. and CHEN, N. (1989). Biomarkers indicating sedimentary Paleoenvironments. Am. Chern. Soc. Natl. Meeting. Honolulu, Hawaii, December 1989 (abst. only).

58. LAWWONGNGAM, K., PHILP, R.P. and GALVEZ-SINIBALDI, A. (1989). Biomarker characterization of crude oils from Sirikit Oilfield, Phisanuloke Basin, Thailand. Am. Chern. Soc. Natl. Meeting. Honolulu, Hawaii, December 1989 (abst. only).

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59. PHILP, R.P., GALVEZ-SINIBALDI, A., RUBLE, T. and LA WWONGNGAM, K. ( 1989). Characterization of contemporary and fossil resins by pyrolysis-gas chromatography­mass spectrometry. Am. Chern. Soc. Natl. Meeting. Honolulu, Hawaii, December 1989 (abst. only).

60. XAVIER DE LAS HERAS, F. and PHILP, R.P. (1990) Caracterizacion de petroleos mediante GC/MS/MS. Biennal Meeting on GC. Catalonia (1990).

61. WESLOWSKI, D.J., HATCHER, R.D. and COLE, D.R.(1990). Cosplum (crystalline overthrust structures on the platform localizing unconventional methane): A proposed 3 km CSDP drilling project in the Eastern Blue Ridge Province of the Southern Appalachian overthrust belt. GSA Annual Meeting. Dallas, Texas 1990.

62. PHILP, R.P. (1990). Biomarkers-The interaction between organic chemistry and geology in petroleum exploration. 11th Biennial Conf. on Chern. Education. Georgia Institute of Technology Education Extension, Atlanta, Georgia, August, 1990.

63. PHILP, R.P., RUBLE, T., GALVEZ-SINIBALDI, A., AND CZECHOWSKI, F. (1990). Characterization of natural bitumens by pyrolysis-gas chromatography and pyrolysis-gas chromatography-mass spectrometry. Am. Chern. Soc. Meeting., Washington, August, 1990.

64. MPANJU, F. and PHILP, R.P. (1991). Geochemical Characteristics of Bitumens and Seeps from Tanzania. AAPG Convention. Dallas, Texas, April, 1991.

65. XINYU Ll, PHILP, R.P. (1991). Geochemical Characterization of Jurassic Coals in Minghe Basin, Shaanxi-Gansu Province (P.R. China). AAPG Convention, Dallas, Texas, April, 1991.

66. KASHIRTEV, V., PHILP, R.P., ALLEN, J. and GALVEZ-SINIBALDI, A. (1991). Geochemical Characterisation of Natural Bitumens from Yakutia, in the Olenek Uplift region of the North-East Siberian Platform. Int'l. Conf. on Petr. Chern., Tomsk, USSR, October, 1991. 67. PHILP, R.P. (1991). Recent Developments in Biomarker Geochemistry and Related Analytical Techniques. Int'l. Conf. on Petr. Chern., Tomsk, USSR, October, 1991.

68. MPANJU, F. and PHILP, R.P. (1991). Organic Geochemical Characterization of Bitumens and Oil Seeps from Tanzania. 15th Int. Meeting, Univ. of Manchester, England, September, 1991.

69. GALVEZ-SINIBALDI, A., LANDAIS, P. and PHILP, R.P. (1991). Artificial maturation studies of Pseudoplexarua porosa and its zooxanthellae -Major constituents of coral reefs. 15th Int. Meeting, Univ. ofManchester, England, September, 1991.

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70. RUBLE, T.E. and PHILP, R.P. (1991). Organic Geochemical Characterization ofNative Bitumens from the Uinta Basin, Utah, U.S.A. 15th Int. Meeting, Univ. of Manchester, England, September, 1991.

71. DEL RIO, J.C. and PHILP, R.P. (1991). Occurrence of High Molecular Weight Hydrocarbons (Above C4Q) in Geological Materials. 15th Int. Meeting, Univ. of Manchester, England, September, 1991.

72. UNOMAH, G.I., EKWEOZOR, C.M. and PHILP, R.P. (1991). Use of Biomarkers for Determination of Organofacies Provinces and Paleoenvironment of Upper Cretaceous Sediments, Lower Benue Trough, Nigeria. 15th Int. Meeting, Univ. of Manchester, England, September, 1991.

73. SOYLU, CENGIZ and PHILP, R.P. (1991). Petroleum Geochemistry of the Adiyaman Area Oils, Se Turkey. 15th Int. Meeting, Univ. ofManchester, England, September, 1991.

74. CZECHOWSKI, F. and PHILP, R.P. (1991). Structural Characterization of Biomarkers and Group Components of Brown Coal Lithotypes. Second Int. Symp. on Biological Processing of Coal, San Diego, California, May, 1991.

75. BENALIOULHAJ, S., SCHREIBER, B.C. and PHILP, R.P. (1991). Contributions to the reconstruction of depositional conditions during restricted and evaporitic sedimentation through the study ofbiomarker. Saline Lakes Conference, Saskatoon, Canada, August, 1991. 1991.

76. BENALIOULHAJ, S., SCHREIBER, B.C., PHILP, R.P. and LANDAIS, P. (1991). Confined Pyrolysis: A powerful technique of simulation applied to recent sediments from evaporative systems. Environments of Exploration, Calgary, Canada, June, 1992.

77. BENAIOUHAJ, SAID, TRICHET, J., SCHREIBER, B.C. and PHILP, R.P. (1991). Comparative study of the organic geochemistry in the Oulad Abdoun (Phosphate) and Timahdit (Oil Shale) Basins of Morocco. Enviornments ofExploration, Calgary, Canada, June, 1992.

78. BENAIOULHAJ, SAID, SCHREIBER, B.C., PHILP, R.P. and TRICHET, J. (1991). Diagenetic interaction between sulfur and organic matter in the phosphate series of Oulad Abdoun and in the laterally equivalent Black Shale Series of Timahdit (Morocco). 29th International Geological Congress, Kyoto, Japan, August, 1992.

79. BENAIOULHAJ, S., SCHREIBER, B.C., PHILP, R.P. and LANDAIS, P. (1991). Evaporites as a source for petroleum. 29th International Geological Congress, Kyoto, Japan, August, 1992.

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80. WANG, H.D. and PHILP, R.P. (1991). An organic geochemical investigation of oils and source rocks from two Mesozoic Formations of the Shanganning Basin, China. 29th International Geological Congress, Kyoto, Japan, August, 1992.

81. LAWWONGNGAM, K. and PHILP, R.P. (1991). Preliminary investigation of oil and source rock organic geochemistry from Tertiary Basins of Thailand. 9th Regional Conference on Geology, Mineral and Energy Resources of Southeast Asia (GEOSEA VII), Bangkok, Thailand, November 1991.

82. PHILP, R.P. (1991). Characterization of crude oils and source rock extracts by tandem mass spectrometry. UK Tandem Mass Spectrometry Club, Bristol, England, December 1991.

83. RUBLE, T.E., PHILP, R.P. and BAKEL, A.J. (1992). Compound-specific isotopic analysis of Uinta Basin native bitumens. 203rd American Chemical Society National Meeting and Exposition, San Francisco, California, April, 1992.

84. PHILP, R.P. Geochemical characterization of terrestrial oils and source rocks. The International Symposium on Hydrocarbons from Non-Marine Sediments. Lanzhou, China, September, 1992.

85. LI, XINYU, PHILP, R.P. and HAZAI, I. (1991). Geochemical Characterization of a Tertiary Brown Coal from Nanning Basin, South Eastern China. The International Symposium on Hydrocarbons from Non-Marine Sediments. Lanzhou, China, September 1992. (Abstract only).

86. PHILP, R.P. and DEL RIO, J.C. (1992). High Molecular Weight Hydrocarbons (>C40) in Geological Samples. Third Latin American Congress on Organic Geochemistry, Manaus, Brazil, November, 1992.

87. CHEN, G. and PHILP, R.P. Organic Geochemical Investigation of the Evaporitic Cycles in the Paradox Basin of Southeastern Utah and Southwestern Colorado. Workshop on the Pennslyvania Sediments ofthe Paradox Basin, Denver, Colorado, September, 1992.

88. BENALIOULHAJ, S., SCHREIBER, B.C. and PHILP, R.P. (1993). Reconstruction of Depositional Conditions During Restricted and Evaporitic Sedimentation. AAPG Meeting, New Orleans, Lousiana, 1993.

89. BENALIOULHAJ, S., SCHREIBER, B.C., TRICHET, J. and PHILP, R.P. (1993). Factors Controlling Diagenetic Evolution of Organic Matter in the Septentrional Gulf (Morocco). AAPG Meeting, New Orleans, Lousiana, 1993.

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90. DEL RIO, J.C., PHILP, R.P., ALLEN, J., GONZALEZ-VILA, F.J., MARTIN, F. and BISHOP, A. (1992). Pyrolysis-high temperature gas chromatography as a new tool to evaluate the presence of high molecular weight hydrocarbons in asphaltene fractions. Int. Meeting of Appl. Pyrol. Hamburg, Germany, Sept., 1992.

91.PHILP, R.P., BISHOP, A., ALLEN, J., and G. CHEN. (1993). Reservoir Geochemistry­Concepts, Applications, and Results. Fluvial-dominated Deltaic Reservoirs in the Southern Midcontinent. OGS Workshop-March 23, 1993.

92. PHILP, R.P., BISHOP, A., ALLEN, J., and DEL RIO, J.C. (1993). Origin and Distribution of Hydrocarbons Above C40 in Crude Oils and Other Fossil Fuels. ACS National Meeting, Chicago, August 1993.

93. GALVEZ-SINIBALDI, A., PHILP, R.P. and CIERESZKO, L.S. (1993). Characterization of Resistant Biopolymers Isolated from Dinoflagellate Symbionts Occurring in Caribbean Coelenterates (Gorgonians) by Py-GC and Py-GC-MS. ACS National Meeting, Chicago, August 1993.

94. PHILP, R.P., BISHOP, A.N., ALLEN, J., WANG, H.-D. and ROTTMANN, K. (1993). The Application of Reservoir Geochemistry in Central Oklahoma: The Prairie Gem Field, Lincoln Co. (1993). TSOP Meeting, October 1993.

95. RUBLE, T.E., PHILP, R.P., GALVEZ-SINIBALDI, A., MAXWELL, J.R., and HARRISON, W.N. (1993). Uinta Basin Wurtzilite: A Product of natural Vulcanization. TSOP Meeting, October 1993.

96. GALVEZ-SINIBALDI, A., PHILP, R.P., and CHISSOE, W. (1993). Pyrolysis-gas chromatography and scanning electron micrscopy of artificially matured samples of Pseudoplexaura porosa. TSOP Meeting, October 1993.

97. BISHOP, A. and PHILP, R.P. (1994). The potential for amorphous kerogen formation via adsorption of organic material at mineral surfaces. American Chemical Society 207th National Meeting, San Diego March, 1994. Abs. only.

98. BISHOP, A., PHILP, R.P. and ALLEN, J. (1994). Controls on the precipitatiOn of hydrocarbons in petroleum reservoirs. American Chemical Society 207th National Meeting, San Diego March, 1994. Abs. only.

99. PHILP, R.P. (1994). Asphaltene characterization by pyrolysis techniques. American Chemical Society 207th National Meeting, San Diego March, 1994. Abs. only.

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100. RUBLE,T.E., BISHOP, A., and PHILP, R.P. (1994). Identification and characterization of a liquid precursor to gilsonite. American Chemical Society 207th National Meeting, San Diego March, 1994. Abs. only.

100. PHILP, R.P., WANG, H., ALLEN, J., and BISHOP, A.B. (1994). Geochemical characteristics of Viola oils and source rocks. Oklahoma Geological Survey Symposium on Simpson and Viola Groups in the Southern Mid-Continent. Norman OK. March 1994.

101. BISHOP, A.N., PHILP, R.P., and ALLEN, J., (1995). Quantification of high molecular weight hydrocarbons in crude oils. European Asssociation Petroleum Engineers Meeting. June 1995.

102. Ruble et al. ACS Meeting.

103. Philp et al OGS Study-AMES Crater

*104. PHILP, R.P., ALLEN, J. and KOMBRINK, M. (1995). an investigation into the potential of GCIRMS as a technique for the correlation of weathered oil spill samples to their source. American Chemical Society 210th National Meeting, Chicago, August, 1995. Abs, only.

105. PHILP, R.P. ( 1995). Geochemistry and petroleum exploration. In: Proceedings of the Seminar on Source Rocks and Hydrocarbon Habitat in Tunisia, Tunis, Nov. 1995, pl. Abs. only.

106.PHILP, R.P. (1995). Reservoir geochemistry for geologists, geochemists, reservoir and production engineers. In: Proceedings of the Seminar on Source Rocks and Hydrocarbon Habitat in Tunisia, Tunis, Nov. 1995, p71. Abs. only.

107.LI,X.-Y and PHILP, R.P.(1996). Paleoecological significance of pigment distribution in organic-rich deposits from the postglacial Lake Erie basin. ACS National Meeting, Miami, Aug. 1996.

108.PHILP, R.P., DERMAN,A.S., ALLEN,J., MANSUY,L., KIM,D., and TCHOUPOROVA, E. (1996). Geochemical Characteristics of Oils from the Raman, Yanankoy, Devecatagi and K. Osmancik fields, Turkey. Presented at the 2nd International Conference on the Petroleum Geology ofthe Black Sea, Turkey, September, 1996.

*109. PHILP,R.P. (1996). Recent Advances in Petroleum and Reservoir Geochemistry. Presented at the 2nd Conference on The Geochemical and Petrophysical Investigations in Oil and Gas Exploration. (Abs. only pp228-229). Cracow, Poland, 1996.

110. SAIDI, M., PHILP, R.P. (1996). Geochemical characterization and relationship of oil seeps and source rocks from Northern Tunisia. Submitted to the AAPG Annual Convention, 1996.

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111. PHILP, R.P. and CHOUPAROVA, E. (1997). Time dependent changes in waxes and asphaltenes during oil production. ACS Meeting Cancun, Nov., 1997.

112. PHILP, R.P. and CHOUPAROVA, E. (1997). Time dependent changes in waxes and asphaltenes during oil production. Colombian AAPG Meeting, Cartagena, Colombia, Sept. 1997.

113. KASHIRTSEV, V. and PHILP, R.P.(1997). Biomarkers and carbon isotopes of oils and natural bitumens in the Precambrian and Paleozoic-Mesozoic Formations of the Siberian Platform. AAPG Annual Meeting, Dallas, April, 1997.

114. TRINDIADE, L.A.F., CERQUEIRA, J.R., MIZUSAKI, A.M.P., SANTOS, R.P., and PHILP, R.P. (1997). Geochemical characterization of the Dom Joao oilfield, Reconcavo Basin, Brazil. ACS Meeting Cancun, Nov., 1997.

115. PHILP. R.P. (1997).Recent developments in the use of biomarkers in Petroleum and Reservoir Geochemistry. 3rd International Conference on Petroleum Chemistry, Tomsk, Russia, December, 1997.

116.KASHIRTSEV, V. and PHILP, R.P.(1997). Biomarkers and carbon isotopes of oils and natural bitumens in the Precambrian and Paleozoic-Mesozoic Formations of the Siberian Platform. 3rd International Conference on Petroleum Chemistry, Tomsk, Russia, December, 1997.

*117.PHILP, R.P., ALLEN, J. and MANSUY, L. (1997). The utilization of combined gas chromatography-isotope ratio mass spectrometry to monitor the origin and fate of crude oils. Technical Exchange Meeting ARAMACO, Saudi Arabia, May 1997.

118. W. J. CARRIGAN, M.H. TOBEY, P.J. JONES, H.I. HALPERN, R. P. PHILP AND J. ALLEN (1997). Geochemical Variations of Paleozoic Gas/Condensate Reservoirs from the Ghawar Structure of Saudi Arabia: Gas Souring, Filling History, and Reservoir Compartmentalization. Technical Exchange Meeting ARAMACO, Saudi Arabia, May 1997.

*119.R. PAUL PHILP, JON ALLEN, and LAURENCE MANSUY The utilization of combined gas chromatography-isotope ratio mass spectrometry to monitor the origin and fate of crude oil spills. 1997 National ASMS Meeting, Palm Springs, April, 1997.

120.R.PAUL PHILP1, LAURENCE MANSUY1, JON ALLEN1, and JAMES K.

ANDERSON2(1997).Preferential biodegradation of aromatic components in Ordovician crude oils. Extended Abs. of 18th International Meeting on Organic Geochemistry, pp241-242. Maastricht, Sept. 1997. KFA, Julich, Germany.

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*121.LAURENCE MANSUY1,R.PAUL PHILP 1 and M.H. ENGEL (1997). effects of maturation on the stable carbon isotope compositions of organic matter.Extended Abs. of 18th International Meeting on Organic Geochemistry, pp201-202. Maastricht, Sept. 1997. KFA, Julich, Germany.

*122.R.PAUL PHILP, LAURENCE MANSUY, and JON ALLEN.(1997). Monitoring the fate of crude oils spills in the environment by GCIRMS and GCMS.Extended Abs. of 18th International Meeting on Organic Geochemistry, pp487-488. Maastricht, Sept. 1997. KFA, Julich, Germany.

123.RUBLE, T.E., PHILP, R.P. and LEWAN, T.D. (1997). Quantitative analysis ofbiomarkers from Green River Shale hydrous pyrolysis.Extended Abs. of 18th International Meeting on Organic Geochemistry, pp413-414. Maastricht, Sept. 1997. KFA, Julich, Germany.

124.W. J. CARRIGAN, M.H. TOBEY A, P.J. JONESA, H.I. HALPERNA, R. P. PHILP AND J. ALLEN (1997). Geochemical Variations of Paleozoic Gas/Condensate Reservoirs from the Ghawar Structure of Saudi Arabia: Gas Souring, Filling History, and Reservoir Compartmentalization. Extended Abs. of 18th International Meeting on Organic Geochemistry, pp60 1-602. Maastricht, Sept. 1997. KF A, Julich, Germany.

125. PHILP, R.P. and CHOUPAROVA, E. (1997). Time dependent changes in waxes and asphaltenes during oil production. Extended Abs. of 18th International Meeting on Organic Geochemistry, pp591-592. Maastricht, Sept. 1997. KFA, Julich, Germany.

126.STALKER, L. AND PHILP,R.P. (1997). Distribution variations of sulphur-linked coals determined by chemolysis. Extended Abs. of 18th International Meeting on Organic Geochemistry, pp441-442. Maastricht, Sept. 1997. KFA, Julich, Germany.

127.PHILP, R. P. and WANG, H. (1998). Geochemical characteristics of selected Pennsylvannian oils and rocks. OGC Workshop, April1998, Norman Oklahoma.

128.CHOUPAROVA, E., ROTTMAN, K., and PHILP, R.P. (1998). Geochemical study of oils produced from the Bartlesville, Red Fork, and Skinner Formations. OGC Workshop, April 1998, Norman Oklahoma.

129. R.P. PHILP AND E. TCHOUPOROVA (1998). Characterization of the C40+ fraction of crude oils. ACS National Meeting, Petroleum Division, Dallas, March, 1998.

130. M. HSIEH, E. MUELLER, J. ALLEN AND R. P. PHILP (1998).High molecular weight hydrocarbons (>C40) in crude oils and rock extracts. ACS National Meeting, Geochemistry Division, Dallas, March, 1998.

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13l.M. HSIEH, E. TCHOUPOROVA, J. ALLEN, AND R. P. PHILP (1998).Paraffin and asphaltene deposition resulting from commingling of oils during pipeline transportation and storage. ACS National Meeting, Fuel Division, Dallas, March, 1998.

*132. PHILP, R. PAUL (1998). Forensic Geochemistry- or who was responsible for that spill. Environmental Forensics Conference, Houston, Sept. 1998.

133.PHILP, R. PAUL and ALLEN, J. (1998). Development of gas chromatography-isotope ratio mass spectrometry (GCIRMS) as an ancillary technique for tracking, monitoring and determination of the origin of hydrocarbon spills in the environment. EP AI Air and Waste Management Association Symposium, Research Triangle Park, Sept. 1998.

134. PHILP, PAUL R. and KIM, DONGWON(1999).Geochemical characteristics of Mississippian Limestone and Chester Formation rocks in the Anadarko Basin, Oklahoma. OGS Conference, Norman, March 1999.

*135.SMALLWOOD, B.J., PHILP, R.P. and ALLEN, J. (1999). Source determination of gasoline contamination using GCIRMS. 6th Annual International Petroleum Environmental Conference, Houston, TX. November, 1999.

*136. SMALLWOOD, B.J., PHILP, R.P. and ALLEN, J. (1999). Source determination of gasoline contamination using GCIRMS. 20th Annual Meeting of the Society of Environmental Toxicology and Chemistry, Philadelphia, November 1999.

137.HSIEH, M. and PHILP, R. P. (2000). C100 Hydrocarbons in source rocks and related crude oils. 219 th ACS National Meeting, San Francisco, March 2000. (Abs. Only).

138.CHOUPAROVA, E., PHILP, R.P. NAGARAJAN, N.R. and WILSON, C.(2000). N-Alkane distributions in organic solid deposits vs. temperature of deposition. 219 th ACS National Meeting, San Francisco, March 2000. (Abs. Only).

139. CHOUPAROVA, E. and PHILP, R.P. (2000). Solubility and crystallization behaviour of Polywax 1000 hydrocarbon stanadard in different solvents. 219 th ACS National Meeting, San Francisco, March 2000. (Abs. Only).

*140. PHILP, R.P. (2000). Forensic Geochemistry. Seminar presented at U. Illinois, Carbondale. April2000.

* 141. PHILP, R.P. (2000). Unique Fingerprints derived the Isotopic Composition of Individual Compounds in Complex Mixtures-Applications to Environmental Problems involving MTBE, PCE and TCE and Hydrocarbon Spills. EPA Star Meeting-Research Triangle Park, N. Carolina, September 2 000.

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*142.PHILP, R. P., SMALLWOOD, B. and ALLEN, J. (2000). Gas Chromatography-Isotope Ratio Mass Spectrometry(GCIRMS)-Applications to Environmental Monitoring Studies. ACS National Meeting, Washington, August, 2000.

* 143 .PHILP, R.P. (2000). Unique Fingerprints derived the Isotopic Composition of Individual Compounds in Complex Mixtures. International Business Meeting, Washington, June 2000.

*144.PHILP, R. P., SMALLWOOD, B. and ALLEN, J. (2000). The use of gas chromatography-isotope ratio mass spectrometry(GCIRMS) to monitor MTBE in the environment. IPEC Meeting Albuquerque, November 2000.

*145. PHILP, R. P., ALLEN, R.P., KUDER, T., (2000) Discrimination of gasolines by gas chromatography-isotope ratio mass spectrometry. 1st Meeting of the French Society on Stable Isotopes, Nancy France, December, 2000. (Abs. Only).

*146. PHILP, R.P., (2000). Unique Fingerprints derived from the Isotopic Composition of Individual Compounds in Complex Mixtures-Applications to Environmental Problems involving MTBE and Hydrocarbon Spills. EPA STAR Meeting, Research Triangle Park, North Carolina, September, 2000.

*147. PHILP, R.P.,SMALLWOOD, B., KUDER, T., and ALLEN, J., (2000). Unique Fingerprints Derived from the Isotopic Composition of Individual Compounds in Complex Mixtures - Applications to Environmental Problems Involving MTBE and Hydrocarbon Spills. EPA National Environmental Monitoring Technology Conference, Boston September 19-20.

* 148. PHILP, R.P ., SMALL WOOD, B., and ALLEN, J. (2000). The use of gas chromatography-isotope ratio mass spectrometry(GCIRMS) to monitor MTBE in the environment. IPEC Meeting Albuquerque, New Mexico, November, 2000.

149. HSIEH, M., and PHILP, R.P. (2000). C40+ hydrocarbons in source rocks and related crude oils. ACS National Meeting, San Francisco, March 2000.

150. CHOUPAROVA, E., PHILP, R.P., NAGARAJAN, C.N., WHITSON, C. (2000) n-Alkane distributions in organic solid deposits vs. temperature of deposition. ACS National Meeting, San Francisco, March 2000.

151. CHOUPAROV A, E., and PHILP, R.P. (2000). Solubility and crystallization behavior of a Polywax 1000 hydrocarbon standard in different solvents. ACS National Meeting, San Francisco, March 2000.

152. Mark A. Nanny, Joseph M. Suflita, Irene Davidova, Kevin Kropp, Matthew Caldwell and R. Paul Philp. (200 1 ). Intrinsic Anaerobic Bioremediation of Hydrocarbons in Contaminated Subsurface Plumes and Marine Sediments. AGU Meeting, Spring 2001.

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*153. K. Giirgey 1 P. Philp2, H. Emirolu1

, M. Siyako1, E.Uygur1

, and T.Iolk1

Stable carbon isotope variation of bulk and individual n-alkanes in crude oils and associated condensates from Thrace Basin, Turkey. Turkish International Petroleum Congress 2001.

154. JU.A. GOLOVKO, 2R.P. PHILP, 1G.S. PEVNEVA, 1A.K. GOLOVKO (2001). High molecular weight n-alkanes in oils of West Siberia and Sakhalin Island. EOAG Meeting, Nancy, 2001.

155. HSIEH, M., PHILP, R.P. and DEL RIO, J.C. (2001). Characterization of high molecular weight biomarkers in crude oils. Presented at the OGS Workshop, May 8-9, 2001, OKC.

156. KIM, D. and PHILP, R.P. (2001). Characterization of solid bitumen within the Hitch Field, South West Kansas. Presented at the OGS Workshop, May 8-9,2001, OKC.

*157. ALEJANDRO A. SOSA PATRON, R. PAUL PHILP*, ERNESTO CABALLERO GARCIA. (2001). Caracterizacion genetica de los gases de la cuenca de macuspana, Tabasco Mexico. PEMEX gas workshop, Mexico City, May, 2001.

158. Mark A. Nanny 1•2

, Vladimir E. Andrusevich3, R. Paul Philp3

, Crystal Stearns 1, and Lixia

Chen 1 (200 1 ). Humate-induced remediation of petroleum contaminated surface soils. IPEC HOUSTON, NOVEMBER 2001.

159. MAURO AND PHILP SOILS MEETING

160. Kolhatkar, R., Wilson, J., and Philp, R. P. (2002). Use of stable isotopic analyses to evaluate natural biodegradation ofMTBE in ground water. U. Mass. Ground Water Symp. April, 2002. San Diego California.

161. BOUKADI, A. and PHILP, R. P. (2002). Characterization of paraffinic deposits in crude oil storage tanks using high temperature high resolution gas chromatography. Sixth International Conference on the Geology ofthe Arab World, Cario University, February, 2002.

163. R. PAUL PHILP and JOHANA VARGAS, (2002). Reservoir Geochemistry Studies In The Maranon Basin, Peru. INGEPET Meeting, Lima, Peru, November, 2002.

164. PHILP, R.P. and AND HSIEH, M. (2002). Separation of Waxes and Asphaltenes in Crude Oils._INGEPET Meeting, Lima, Peru, November, 2002.

165. PHILP, R.P. (2003). A Review of Developments Related to the Characterization and Significance of High Molecular Weight Paraffins (>C4o) in Crude Oils. Reservoir Geochmistry Workshop, London, February, 2003.

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166. T. Kuder, R.P. Philp, R. Kolhatkar, J.T. Wilson and J. Allen (2002). Application of Stable Carbon and Hydrogen Isotopic Techniques for Monitoring Biodegradation of MTBE in the Field. NGW A Meeting, Atlanta, November, 2002.

167. R. Paul Philp, Tomasz Kuder and Jon Allen. (2002). An Improved Fingerprinting Method for Refined Hydrocarbon Products. NGW A Meeting, Atlanta, November, 2002.

168. R. Paul Philp, Tomasz Kuder and Jon Allen. (2003). Gas Chromatography-Isotope Ratio Mass Spectrometry- A Tool For Use In Correlation Of Soil And Groundwater Contaminants. BPWorkshop, Houston, TX, October, 2002.

169. R. Paul Philp, Jon Allen, and Tomasz Kuder, (2003). Environmental Forensic Applications of Stable Carbon and Hydrogen Isotopes. Battelle Workshop, Orlando, June 2003.

170. T. Kuder, R. Kolhatkar, J. Wilson, P. Philp. (2003). Compound-specific stable isotope analysis to demonstrate MTBE in-situ biotransformation. Battelle Workshop, Orlando, June 2003.

171. T. Kuder, R. P. Philp, R. Kolhatkar, J.T., Wilson and J. Allen (2002). Carbon and hydrogen GC-IRMS method for MTBE field attenuation monitoring; NGW A

MTBE Conference: Assessment, Remediation Technologies, and Public Policy; Orange CA 2002

172. T. Kuder, R.P. Philp, R. Kolhatkar, J.T., Wilson and J. Allen (2002). Application of Stable Carbon and Hydrogen Isotopic Techniques forMonitoring Biodegradation ofMTBE in the Field NGW A Petroleum Hydrocarbons Conference; Atlanta GA 2002.

173. T. Kuder, R. Kolhatkar, P. Philp , J. Wilson , J. E. Landmeyer , J. Allen (2002). Compound-Specific Carbon and Hydrogen Isotope Analysis - Field Evidence of MTBE Bioremediation. AGU Fall Meeting; San Francisco CA 2002

174. T. Kuder, R. Kolhatkar , J. Wilson , P. Philp (2003). Compound-specific stable isotope analysis to demonstrate in-situ MTBE biotransformation. Battelle International Symposium on In Situ Remediation. Orlando, FL 2003

175. T. Kuder, R. Kolhatkar, J. Wilson, K. O'Reilly, P. Philp, J. Allen (2003). Compound­Specific Carbon and Hydrogen Isotope Analysis - Field Evidence of MTBE Bioremediation. NGW A MTBE and Other Recalcitrant Compounds Conference: Assessment Remediation Technologies, and Public Policy 2003.

176.Philp, R. Paul. (2003). A Review of Developments Related to the Characterization and Significance of High Molecular Weight Paraffins (>C40) in Crude Oils. Reservoir Geochemistry Meeting, Royal Geological Society, London, January, 2003.

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177. HSIEH, M. and PHILP, R. P. (2003). ACS Meeting New Orleans, March 2003.

178. XUEMING PAN and R. PAUL PHILP (2003). The Role Of Carboxylic Acids In Crude Oil Formation And Biodegradation, ACS Regional Meeting, OKC, October 2003.

179. R. PAUL PHILP and XUEMING PAN (2003 ). The Significance of Carboxylic acids in Degraded and Non-Degraded Crude Oils. European Geochemistry Meeting, Kracow, Poland, Sept. 2003.

180. PHILP, R.P., KIM, D., HSIEH, M., and TAHIRA, F., 2003. Recent advances in the characterization of waxes in crude oils and source rock extracts. Organic Geochemistry, 21st International Meeting, Krakow, Poland

181. KIM, D. and PHILP, R.P., 2003. Geochemical characterization of core extracts and oils in the Hitch and Etzold fields. ACS 59th Southwest Regional Meeting, Oklahoma City, OK

182. KIM, D. and PHILP, R.P., 2003. Geochemical characterization of core extracts and oils in the Hitch and Etzold fields. AAPG Mid-continent Meeting, Tulsa, OK

183. HSIEH, M., PHILP, R. P., 2003. Geochemical characterization of organic matter in Victoria Harbour Sediments, Hong Kong Special Administrative Region of China. 591

h ACS Southwest Regional Meeting, Oklahoma City, October 2003. (abstract)

184. HSIEH, M., PHILP, R. P., KIM, D., 2003. Occurrence of high molecular weight monomethyl- and dimethyl-alkanes (C4o+) in crude oils and wax deposits. 2251

h National Meeting of the ACS, New Orleans, March 2003. (abstract)

185. PHILP, R. P., KIM, D., HSIEH, M., TAHIRA, F., 2003. Recent advances in the characterization of waxes in crude oils and source rock extracts. 21st International Meeting on Organic Geochemistry, Krakow, Poland, September 2003. (extended abstract)

186. SABER, D., MAURO, D., PHILP, R.P. and ALLEN, J.A. 2003. Carbon isotope ratios of PAHs in urban background soil. Natural Gas Technologies II-GTI Conference, Phoenix, February. Abs. only.

187. PHILP, R.P., KUDER, T. and ALLEN, J.A. 2003. The use of stable isotopes in environmental and forensic geochemistry studies. Natural Gas Technologies II-GTI Conference, Phoenix, February. Abs. only.

188. SABER, D., BOMBICH, W., GREGG, W., MAURO, D., PHILP, R.P. and ALLEN, J.A. 2003. Results of chemical fingerprinting of sediments and soils in the location of a former MGP site, Superior, Wisconsin. Natural Gas Technologies II-GTI Conference, Phoenix, February. Abs. only.

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189. T. KUDER, R. KOLHATKAR, J. WILSON, P. PHILP, J. ALLEN(2004). Compound­Specific Isotope Analysis ofMTBE and TBA for Bioremediation Studies. NGWA Meeting Baltimore. Aug. 2004.

190. R. PAUL PHILP, TOMASZ KUDER AND JON ALLEN (2004). An Evaluation ofthe use of Stable Isotopes as a Tool for Studying the Origin and Fate of MTBE. IPEC Meeting Albuquerque, October, 2004.

191. TOMASZ KUDER, R. PAUL PHILP, JON ALLEN, RA VI KOLHATKAR and JOHN WILSON (2004). Demonstration of in-situ MTBE biotransformation by compound specific stable isotope analysis. IPEC Meeting Albuquerque, October, 2004.

192. R. PAUL PHILP and XUEMING PAN, (2004). Hopanoic and Steroidal Acids in Crude Oils and Source Rocks. ALAGO Meeting, December 2004. Mexico.

193. R. PAUL PHILP, TOMASZ KUDER and JON ALLEN, (2004). Recent Developments in the Use of Stable Isotopes oflndividual Compounds in Environmental Forensic Studies. ALAGO Meeting, December 2004. Mexico.

194. SABER, D., MAURO, D., PHILP, R.P. and ALLEN, J.A. 2005. Chemical fingerprinting of sediments and soils near a former MPG site. 3rd International Conference on Remediation of Contaminated Sediments. New Orleans, January 2005. Abs. only.

195. MAURO, D., SABER, D., SIRIVEDHIN, T., PHILP, R.P. and ALLEN, J.A. (2005). Carbon isotope ratios of P AHs in urban background soil. 3 rd International Conference on Remediation of Contaminated Sediments. New Orleans, January 2005. Abs. only.

196. PHILP, R.P., ALLEN, J. and KUDER, T. (2005). Forensic and environmental applications of stable carbon, hydrogen and chlorine isotope composition of individual compounds. 5ih Annual Meeting American Academy ofForensic Sciences, Feb. 21-261

\ New Orleans.

197. CRAIG, D.R., MAURO, D., SABER, D., SIRIVEDHIN, T., PHILP, R.P. and ALLEN, J.A. (2005). Carbon isotope ratios of PAHs in urban background soil. 3rd International Conference on Remediation of Contaminated Sediments. 5ih Annual Meeting American Academy of Forensic Sciences, Feb. 21-261

\ New Orleans.

198. K. L. Pigott, M. H. Engel, R. P. Philp (2005). High-Resolution Carbon Isotope Stratigraphy: Separating Global from Local Effects on a Jurassic Carbonate Ramp of the U.S. Gulf Coast. AAPG Meeting Paris, 2005.

199. PHILP, R.P., (2005). The Evolution of Stable Isotopes in Environmental and Forensic Geochemistry Studies. 34th Spring Academic Symposium Program, May 2005, The Korean Society of Analytical Sciences, Seolakdong, Korea. (Plenary Lecture).

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200. MIN SOOK, J. and PHILP, R.P., (2005). Environmental and Forensic Applications of Isotopic Ratio Mass Spectrometry. 34th Spring Academic Symposium Program, May 2005, The Korean Society of Analytical Sciences, Seolakdong, Korea.

201. PAUL PHILP, TOMASZ KUDER and JON ALLEN (2005). Compound-specific isotope analysis applied to groundwater contaminant studies. Oklahoma Water 2005 Conference. Tulsa, Sept. 2005.

202. PAUL PHILP (2005). The Evolution of Stable Isotopes in Environmental and Forensic Geochemistry Studies. International Meeting on Environmental Forensics, Taipai, Taiwan, Sept. 2005.

203. PAUL PHILP (2005). The Attorney's Favorite Question: How long has that residue been there? International Meeting on Environmental Forensics, Taipai, Taiwan, Sept. 2005.

204. PAUL PHILP, TOMASZ KUDER and JON ALLEN (2005).Compound-specific isotope analysis applied to groundwater contaminant studies. Oklahoma State Groundwater Conference, Tulsa, September 2005.

205. R. PAUL PHILP, TOMASZ KUDER, JON ALLEN, (2006). Environmental forensics­Emergence of novel aproaches for existing problems. ALAGO Meeting Brazil, Nov. 2006.

206. A.E. NAVARRO FROMETA, R.P. PHILP, (2006). Thiosteranes as biomarkers to assess water pollution. ALAGO Meeting Brazil, Nov. 2006.

207. R. PAUL PHILP, TOMASZ KUDER and JON ALLEN (2006). The Emerging Role of Stable Isotopes in Environmental Forensic Studies. 2006 NGWA Ground Water and Environmental Law Conference, Chicago, July, 2006.

208. PHILP, R. PAUL, (2006). The role of geochemistry in tight gas shale exploration. Caney Shale Gas Workshop, Oklahoma City, August 2006.

209. KIM, D. and PHILP, R. P (2006). Reservoir Characterization of solid hydrocarbons deposited in the Mississippian Sandstones of the Hitch Field, Southwest Kansas. AAPG Meeting, Norman, OK, March 2006.

210. TANEZA, P. and PHILP, R.P. (2006). Occurrence ofpolycylic aromatic hydrocarbons (PAHs) in Iloilo River, Philippines. GSA Abstracts with Programs VoL 38, No. 1, Sectional Meeting, Norman, OK. March, 2006.

211. BISCHOFF K., JARD:E E. and PHILP, P. (2006) Stable isotopes of chlorine and carbon as tracers for the fate of chlorinated solvents in groundwater. 51st Annual Oklahoma ACS Pentasectional Meeting- 1 April 2006, Bartlesville, Oklahoma (USA).

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212. PAMELA GERREZ V. TANEZA and R. PAUL PHILP (2006). Persistent Organic Pollutants in Iloilo River, Philippines. 51st Annual Oklahoma ACS Pentasectional Meeting- 1 April 2006, Bartlesville, Oklahoma (USA).

213. DONGWON KIM and R. PAUL PHILP (2006). Occurrence ofMonocyclic and N­alkylaromatic Alkanes in Crude Oils and Thermal Extracts from the Hitch Reservoir. 51st Annual Oklahoma ACS Pentasectional Meeting- 1 April2006, Bartlesville, Oklahoma (USA).

214. PIGOTT, KUL WADEE L., ENGEL, MICHAEL, PHILP, RICHARD P., and PIGOTT, JOHN D., (2006). Carbon Isotope Proxy for the Discrimination of Eustatic from Transgressive-Regressive Changes in Accommodation Space for Carbonate Ramps: Oxfordian Smackover of Alabama USA ExampleU.S.A. ill_AAPG International Conference and Exhibition November 5-8, Perth, Australia.

215. PHILP, R. P. (2006). Chemical Evidence for the Natural Fate ofPetroleum Hydrocarbons in the Environment. ISEF Workshop, Honolulu, April, 2006.

216. PHILP, R. P. (2006). Forensic Geochemistry-or Whose Oil is it? Invited Seminar, Uni. Illinois at Chicago. April 2006.

217. PHILP, R. P. (2006). Environmental Forensics. Invited Seminar, Hill Air Force Base, Utah, April2006.

218. PHILP, R. P. (2006).The Role of Stable Isotopes in Environmental Investigations. Izucar, Mexico meeting.

219. PHILP, R. P. (2006). Environmental forensics--or whose oil is it? Izucar, Mexico meeting.

220. PHILP, R. P. (2006). Environmental Forensics. Invited Presentation, Montgomery, AL. Underground Storage Tank Meeting, May 2006.

221. PHILP, R.P. (2006). Stable Isotopes in Environmental and Forensic Geochemistry Studies. Battelle Conference Workshop, Monterey, May 2006.

222. PHILP, R.P. (2006). Reservoir Geochemistry-Concepts, Evolution and Applications. SPE Meeting Lima Peru, August 2006.

223. R. PAUL PHILP, (2006). Isotopic Characterization of Hydrocarbons in Oil and Gas Reservoirs. Invited Talk for the Polish Oil and Gas Corporation, Zakopane, Poland, September, 2006.

224. R. PAUL PHILP, (2006). The Use of Biomarkers in Undertaking Oil/Source Rock Correlations. Invited Talk for the Polish Oil and Gas Corporation, Zakopane, Poland, September, 2006.

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225. R. PAUL PHILP, (2006). Characterization of Hydrocarbons Generated from Source Rocks using High Temperature Pyrolysis. Invited Talk for the Polish Oil and Gas Corporation, Zakopane, Poland, September, 2006.

226. R. PAUL PHILP, TOMASZ KUDER and JON ALLEN, (2006). Stable Isotopes-An Emerging Tool in Forensic Geochemistry. IPEC Meeting San Antonio, October, 2006.

227. TOMASZ KUDER, PAUL PHILP, JON ALLEN and EVELYN CORTEZ (2006). Compound-specific isotope analysis-A study of anaerobic biodegradation of MTBE. IPEC Meeting San Antonio, October, 2006.

229. TOMASZ KUDER, EVELYN CORTEZ, JON ALLEN, EMILIE JARDE, AND R. PAUL PHILP (2006). Stable Isotopes-An Emerging Tool in Forensic Geochemistry. Gas Technology Institute, Orlando, October, 2006.

230.PHILP, R. P. (2006). Incorporation of Stable Isotope Data in the Exploration and Production of Shale Gas. Rocky Mountain Geological Society Meeting, August, 2006.

23l.PAUL PHILP, T. KUDER, E. CORTEZ and J. ALLEN (2006). Utilization of Stable Isotopes as a Tool for Monitoring Natural Attenuation. EPA Workshop Invited Talk, Long Beach, Nov. 2006.

232. Tim E. Ruble, Brian Jarvie, Michael D. Lewan, R. Paul Philp, and Daniel M. Jarvie (2007). Recognizing Geochemical Facies to Improve Oil Shale Resource Assessment and Development. AAPG Annual Convention, April, 2007.

233. K.N. Savage, M.S. Elshahed, J. D. Allen, R. P. Philp, L.R. Krumholz (2007). Biodegradation of short chain (C2-C6) n-alkanes under methanogenic and sulfate-reducing conditions. ASM Meeting, 2007.

234. R. Paul Philp, Jon Allen, and Tomasz Kuder (2007). Stable Isotopes and their Use in Forensic Studies. AAFS Annual meeting San Antonio, February 2007.

235. Xiaomin Yang, John Wilson, Cherri Adair, Jennifer Busch-Harris, Kerry Sublette, Eleanor Jennings, Tomasz Kuder, Paul Philp, Greg Davis, and William E. Holmes, (2007). Stable Isotope Probing with 13C-MTBE-amended Bio-Sep® Beads in MTBE-degrading Microcosms. 3rd European MTBE conference.

236. Kuder,T., Philp,P. and Allen, J. (2007). Stable isotope tl'actionation resulting from biotic and abiotic MTBE attenuation processes. Geophysical Research Abstracts. 9, 05794. 2007.

238. Aaron Swank, R. Paul Philp, Charles Holbert, (2007). Evaluation of monitored natural attenuation ofMTBE at OUll, Hill AFB, Utah. IRNA Conference, July 2007.

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239. Kuder, T.; Philp, P.; Allen, J. "Stable Isotope Fractionation Resulting from Biotic and Abiotic MTBE Attenuation Processes". Submitted for The 23rd International Meeting on Organic Geochemistry, 9-14 September 2007, Torquay, United Kingdom.

240. Kuder, T.; Philp, P.; Allen, J. "Stable Isotope Fractionation Resulting from Biotic and Abiotic MTBE Attenuation Processes". Submitted for AEHS Annual International Conference on Soils, Sediments & Water, 15-18 October 2007, Amherst, Massachusets.

241. Kuder, T.; Philp, P.; Allen, J. "Forensic geochemistry- stable isotope fingerprinting of gasolines". Submitted for The 14th Annual International Petroleum Environmental Conference, 6-9 November 2007, Houston, Texas.

242.Kuder, T.; Philp, P.; Yang, X; Allen, J. "Monitoring ofMTBE attenuation by stable isotope analysis". Submitted for The Stable Isotope Conference - Stable Isotope Tools for the Assessment of Chemical and Microbial Transformation Reactions in Complex Natural and Contaminated Environments, 18- 23 November 2007, Mt. Verita, Switzerland.

243. AAPG Meeting Greece Piggot and Abdullah

244. PHILP, R. Paul (2007). The role of geochemistry in characterization of gas shales and produced gas. Geological Society of America Annual Meeting 2007. Denver. Abs. only.

245. R. Paul Philp, Jon Allen, and Tomasz Kuder (2007). Environmental Forensics and Stable Isotopes. FIRMS Meeting, Dunedin, NZ. November 2007.

246. Xiaoming Liang, Yiran Dong, Tomasz Kuder, Lee Krumholz, R. Paul Philp, and Elizabeth C. Butler (2007). Identification of Reactive Geochemical Species Associated with Abiotic Tetrachloroethylene (PCE) and Trichloroethylene (TCE) Reductive Dechlorination in Well­Defined Microcosms. SERDP Meeting Washington, Dec. 2007.

24 7. Kuder Vancouver Goldschmidt Conference

248. R. Paul Philp, Jon Allen, and Tomasz Kuder (2008). The Role of Stable Isotopes in Environmental Forensics. ACS National Meeting, Philadelphia, Aug. 2008. (Abs. only).

249. R. Paul Philp (2008). Environmental Forensics or CSI without the Violence. ACS National Meeting, Philadelphia, Aug. 2008. (Abs. only).

250. T. Kuder and R. P. Philp (2008). Monitoring of MTBE attenuation by Stable Isotope Analyses. GSA Annual Meeting, Houston, October 2008. Abs. only.

251. R. Paul Philp and Anne Saison (2008). INGEPET Poster.

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252 .. SLATT, Roger M, SINGH, Prema, PHILP, R. Paul, SAISON, Anne, ABOUSLEIMAN, Younane, O'BRIEN, Neal R., and ESLINGER, Eric V. (2009). Workflow for stratigraphic characterization of unconventional gas shales. GSA South-Central Meeting, Dallas, March, 2009.

253. BUSCHECK, T., KUDER, T., PHILP, P., KOLHATKAR, R., and KLINCHUCH, L., 2009. Two dimensional Compound Specific Isotope Analayses to assess Remediation system Effectiveness. Battelle conference May 2009.

254. SINGH, P., SLATT, R.M., PHILP,R.P., SAISON,A.,ABOUSLEIMAN, Y., O'BRIEN, N.R., and ESLINGER, E.V. (2009). Workflow for stratigraphic characterization of unconventional gas shales. AAPG Annual Meeting-Denver, June 2009. Abs. only.

255. Andrea Miceli Romero and R. Paul Philp (2009). Geochemical Characterization of the Woodford Shale, Southeastern Oklahoma. AAPG Search and Discovery.

256. Roger M. Slatt, Prema Singh, R. Paul Philp, K.J. Marfurt, andY. Abousleiman (2009). Workflow for Stratigraphic Characterization of Unconventional Gas Shales. Presented at SPE Symposium, Mexico, Feb. 2009.

257. R. Paul Philp (2009). Isotopes for Forensic Fingerprinting and the Monitoring of Natural Attenuation. AEHS Environmental Forensics Meeting Stresa, Italy. May 2009.

258. R. Paul Philp (2009). Biomarkers in Environmental Forensics, INEF Meeting Calgary, August, 2009.

258. R. Paul Philp, T. Kuder, and J. Allen, (2009). Stable Isotopes in Environmental Forensics. INEF Meeting Calgary, August, 2009.

259. Nicholas B. Harris, Ting-Wei Ko, R. Paul Philp , Trevor Stroker, and Andrew Govert (20 1 0). Natural Gas Compositions from Large Tight-Gas-Sand Fields in the Rocky Mountains, a Clue to How These Reservoir Fill. Gulf Coast Association of Geological Societies

260. R. Paul Philp (2010). The role of CSI in environmental forensics and remediation studies. 2010 Air Force Restoration and Technology Transfer Workshop, San Antonio, April 6-9th, 2010. Invited Speaker

261. Tomasz Kuder, J. Graham Rankin, and Paul Philp (2010). Individualization of gasolines by GCIRMS and GCMS fingerprinting. Geophysical Research Abstracts,Vol. 12, EGU2010-PREVIEW, 2010,EGU General Assembly 2010.

262. Tomasz Kuder, John T. Wilson, Paul Philp, andY. Thomas He (2010). Reactions of 1,2-dibromoethane with FeS and hydrogen sulfide: kinetics, products and isotope fractionation.

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Geophysical Research Abstracts, Vol. 12, EGU2010-PREVIEW, 2010,EGU General Assembly 2010.

263. R. Paul Philp (2010). Recent advances in environmental forensics. FIRMS Meeting, Washington, DC. Plenary Lecture.

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Appendix II. Reports and Tables used in preparing this report.

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cis-DCE -42*

GCPOS-54.2 -18.4

TCE

-24.1

PCE

-27.0

-26.6

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MW15A-145

GCP01-52.5

MW15A-145

MW23C-403

cis-DCE TCE -25.0

0.4

-26.1

.4

PCE

0.1

-28.2

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_...,.. "'"'"''"

Page 78: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

··.;..··~=··~

f'OT[HTJOY('TRIC StJflf'AC[ IH TH£ WAGOTHY M)tJIHR SCREEN l.ONt - 15' TO -77' I'SL

·~· ~~~10~0~c_:~~r~gr ~;?~~E~S~THY AOUif[R

$\Jf'I'LY W[ll

(A26'-A68' )•SCR1:[H INTtiiVAl

Page 79: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York
Page 80: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

TABLE 1. GROUNDWATER SAMPLING RESULTS- NOVEMBER 2005 150 FULTON AVENUE SITE

CONSTITUENT cis-1 ,2-Dichloroethene Tetrachloroethene Trichloroethene Vinyl chloride

NOTES

U - Not Detected

J - Estimated Value

(ug/1) (ug/1) (ug/1) (ug/1)

<10 u 580 120 <10 u

GCPOS GCPOS-54.25

11/412005 67

280 26

<20 u

GCP18S GCP18s-48.5

1113/2005 550 120 76

<10 u

MW15A MW15A-145

11/212005 69

2000 240 <20 u

MW21C MW21C-395

11/112005 9

260 9

<5 u

MW23C MW23C-403 10/31/2005

<4J 28

130 <4U

MW26G MW26G-443 10/31/2005

<1 j

6 42 <1 u

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TABLE 2-3 LIST OF GROUND WATER WELLS SAMPLED DURING THE 150 FULTON AVENUE REMEDIAL INVESTIGATION GARDEN CITY PARK, NEW YORK

Depth to Sump Total Well Bottom of Length In Depth in

Feet Feet 0 80 0 59 40.5 0 59 40.5

49 0 59 40.5 49 0 59 40.5 49 0 59 40.5 105 3 120 105 3 120 105 3 120 105 3 120 105 3 120

0 59 0 40 0 61 0

ERM Page 1 of3

Well Diameter in Feet

Well Well X y

0016775

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TABLE 2-3 LIST OF GROUND WATER WELLS SAMPLED DURING THE 150 FULTON AVENUE REMEDIAL INVESTIGATION GARDEN CITY PARK, NEW YORK

Depth to Sump Total Well Top of Bottom of Casing Length In Depth In Screen

Total Well Bottom Bottom wen Well wen

Screen Elevation Well Diameter X y Screen Len th Feet Feet Elevation Elevation In Feet Material In Feet Coordinate Coordinate

455 435 5 460 -357.7 -377.7 -382.7 STEEL 0.33 -324.02 -344.02 -349.02 STEEL 0.33 -99.46 -119.46 -124.46 STEEL ~ -133 -153 -153 PVC 0.33

-48.54 . -58.54 0.17 -48.54 -58.54 -48.54

150 140 150 140 150 140 360 350 360 350 360 350

~ 350 360

3 3 ·-'--"'='--1-.c=:.:::...--'-'STEEL . .L.._:::O.c1c7:__-L_:::06ie:_2oo:8,;:.;i0e_:1c_L,_07/03/J_<:0'..'_1_].2_l!!:_4_''~~-l_L_l!~'"'~~L----~~~~cs ______ :,_-=::o:..=:c: ..

ERM Page 2 of 3 0016775

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TABLE 2-3 LIST OF GROUND WATER WELLS SAMPLED DURING THE 150 FULTON AVENUE REMEDIAL INVESTIGATION GARDEN CITY PARK, NEW YORK

Well local

ERM

Depth to Bottom of

Sump Total Well Length in Depth In

Feet Feet 3 411

Well Well Well Well Diameter Construction Construction X

Start Date End Date

Page 3of3 0016775

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TABLE 1 Page: 1 of16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE GCP01 GCP01D GCP08 GCP15S

CONSTITUENT SAMPLE ID GCP01-52.5 GCP01D-110 GCP08-54.25 GCP15S-51

DATE 11/03/2005 11/03/2005 11/04/2005 11/03/2005

cis-1 ,2 -Dichloroethene (ug/1) 10 u 1 u 67 1 u

Tetrachloroethene (ug/1) 580 16 280 2

T richloroethene (ug/1) 120 1 u 26 0.2 J

Vinyl chloride (ug/1) 10 u 1 u 20 u 1 u

1 , 1 , 1-Trichloroethane (ug/1) 10 u 1 u 20 u 1 u

1,1 ,2,2-Tetrachloroethane (ug/1) 10 u 1 u 20 u 1 u

1,1 ,2-Trichloroethane (ug/1) 10 u 1 u 20 u 1 u

1, 1-Dichloroethane {ug/1) 10 u 1 u 20 u 1 u

1 , 1-Dichloroethene {ug/1) 10 u 1 u 20 u 1 u

1 ,2-Dichloroethane (ug/1) 10 u 1 u 20 u 1 u

1 ,2,4-Trichlorobenzene {ug/1) 10 u 1 u 20 u 1 u

1 ,2-Dibromo-3-chloropropane (ug/1) 10 u 1 u 20 u 1 u

1 ,2-Dibromoethane (ug/1) 10 u 1 u 20 u 1 u

1 ,2-Dichlorobenzene {ug/1) 10 u 1 u 20 u 1 u

1 ,2-Dichloropropane {ug/1) 10 u 1 u 20 u 1 u

1 , 3-Dichlorobenzene {ug/1) 10 u 1 u 20 u 1 u

1, 4-Dichlorobenzene (ug/1) 10 u 1 u 2J 1 u

1 ,4-Dioxane (ug/1) 250 u 25 u 500 u 25U

2-Butanone (ug/1) 50 u 5U 100 u 5U

2-Hexanone {ug/1) 50 u 5U 100 u 5U

4-Methyi-2-Pentanone (ug/1) sou 5U 100U 5U

Acetone (ug/1) sou 5U 100 u 5U

Benzene (ug/1) 10U 1 u 20U 1 u

Bromochloromethane (ug/1) 10U 1 u 20 u 1 u

Bromodichloromethane (ug/1) 10 u 1 u 20 u 1 u

Bromoform (ug/1) 10 u 1 u 20U 1 u

Bromomethane (ug/1) 10 u 1 u 20 u 1 u

Carbon Disulfide (ug/1) 10 u 1 u 20U 1 u

Carbon Tetrachloride (ug/1) 10 u 1 u 20 u 1 u

J- ESTIMATED VALUE

U - NOT DETECTED

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TABLE 1 Page: 2 of 16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE GCP01 GCP01D GCP08 GCP15S

CONSTITUENT SAMPLE ID GCP01-52.5 GCP01D-110 GCPOS-54.25 GCP15S-51

DATE 11/0312005 11/03/2005 11/04/2005 11103/2005

Chlorobenzene (ug/1) 10 u 1 u 20 u 1 u

Chloroethane (ug/1) 10 u 1 u 20 u 1 u

Chloroform (ug/1) 10 u 0.3 J 20 u 1 u

Chloromethane (ug/1) 10 u 1 u 20 u 1 u

cis-1 ,3-Dichloropropene (ug/1) 10 u 1 u 20 u 1 u

Dibromochloromethane (ug/1) 10 u 1 u 20 u 1 u

Ethylbenzene (ug/1) 10 u 1 u 20 u 1 u

Methylene Chloride (ug/1) 20 u 2U 40 u 2U

Styrene (ug/1) 10 u 1 u 20 u 1 u

Toluene (ug/1) 10 u 1 u 20 u 1 u

trans-1 ,2-Dichloroethene (ug/1) 10 u 1 u 20 u 1 u

trans-1 ,3-Dichloropropene (ug/1) 10 u 1 u 20 u 1 u

Xylene (total) (ug/1) 10 u 1 u 20 u 1 u

J- ESTIMATED VALUE

U - NOT DETECTED

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TABLE 1 Page: 3 of 16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE GCP18D GCP18S MW15A MW15B

CONSTITUENT SAMPLE ID GCP18D-118 GCP18S-48.5 MW15A-145 MW15B-356

DATE 11/03/2005 11/03/2005 11/02/2005 11/02/2005

cis-1 ,2-Dichloroethene (ug/1) 1 u 550 69 3

Tetrachloroethane (ug/1) 0.4 J 120 2000 250

Trichloroethane (ug/1) 1 u 76 240 39

Vinyl chloride (ug/1) 1 u 10 u 20 u 2U

1, 1, 1-Trichloroethane (ug/1) 1 u 10 u 4J 0.9 J

1,1 ,2,2-Tetrachloroethane (ug/1) 1 u 10 u 20 u 2U

1,1 ,2-Trichloroethane (ug/1) 1 u 10 u 20 u 2U

1, 1-Dichloroethane (ug/1) 1 u 10 u 20 u 2U

1, 1-Dichloroethene (ug/1) 1 u 10 u 20 u 1 J

1 ,2-Dichloroethane (ug/1) 1 u 10 u 20 u 2U

1 ,2,4-Trichlorobenzene (ug/1) 1 u 10 u 20 u 2U

1 ,2-Dibromo-3-chloropropane (ug/1) 1 u 10 u 20 u 2U

1 ,2-Dibromoethane (ug/1) 1 u 10 u 20 u 2U

1 ,2-Dichlorobenzene (ug/1) 1 u 10 u 20 u 2U

1 ,2-Dichloropropane (ug/1) 1 u 10 u 20 u 2U

1 ,3-Dichlorobenzene (ug/1) 1 u 10 u 20U 2U

1 ,4-Dichlorobenzene (ug/1) 1 u 10 u 20 u 2U

1 ,4-Dioxane (ug/1) 25 u 250 u 500 u 62 u

2-Butanone (ug/1) 5U 50 u 100 u 12 u

2-Hexanone (ug/1) 5U 50 u 100 u 12 u

4-Methyl-2-Pentanone (ug/1) 5U 50 u 100 u 12 u

Acetone (ug/1) 5U 50 u 100 u 12 u

Benzene (ug/1) 1 u 10 u 20 u 2U

Bromochloromethane (ug/1) 1 u 10 u 20 u 2U

Bromodichloromethane (ug/1) 1 u 10 u 20 u 2U

Bromoform (ug/1) 1 u 10 u 20 u 2U

Bromomethane (ug/1) 1 u 10 u 20 u 2U

Carbon Disulfide (ug/1) 1 u 10 u 20 u 2U

Carbon Tetrachloride (ug/1) 1 u 10 u 20 u 2U

J- ESTIMATED VALUE

U- NOT DETECTED

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TABLE 1 Page: 4 of 16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE GCP18D GCP18S MW15A MW15B

CONSTITUENT SAMPLE ID GCP18D-118 GCP18S-48.5 MW15A-145 MW15B-356

DATE 11/0312005 11/0312005 11/0212005 1110212005

Chlorobenzene (ug/1) 1 u 10 u 20 u 2U

Chloroethane (ug/1) 1 u 10 u 20 u 2U

Chloroform (ug/1) 0.1 J 10 u 20 u 2U

Chloromethane (ug/1) 1 u 10 u 20 u 2U

cis-1 ,3-Dichloropropene (ug/1) 1 u 10 u 20 u 2U

Dibromochloromethane (ug/1) 1 u 10 u 20 u 2U

Ethylbenzene (ug/1) 1 u 10 u 20 u 2U

Methylene Chloride (ug/1) 2U 20 u 40 u 5U

Styrene (ug/1) 1 u 10 u 20 u 2U

Toluene (ug/1) 1 u 10 u 20 u 2U

trans-1 ,2-Dichloroethene (ug/1) 1 u 10 u 20U 2U

trans-1 ,3-Dichloropropene (ug/1) 1 u 10 u 20 u 2U

Xylene (total) (ug/1) 1 u 10 u 20 u 2U

J- ESTIMATED VALUE

U - NOT DETECTED

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TABLE 1 Page: 5 of 16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE MW21A MW21B MW21C MW23A

CONSTITUENT SAMPLE ID MW21A-125 MW21B-335 MW21C-395 MW23A-265

DATE 11/01/2005 11/01/2005 11/01/2005 10/31/2005

cis-1 ,2-Dichloroethene (ug/1) 1 u 4J 9 1 u

Tetrachloroethane (ug/1) 4 1000 260 1 u

Trichloroethane (ug/1) 1 u 43 9 4

Vinyl chloride (ug/1) 1 u 10 u 5U 1 u

1 , 1,1-Trichloroethane (ug/1) 0.3 J 10 u 5U 1 u

1,1 ,2,2-Tetrachloroethane (ug/1) 1 u 10 u 5U 1 u

1,1 ,2-Trichloroethane (ug/1) 1 u 10 u 5U 1 u

1, 1-Dichloroethane (ug/1) 1 u 10 u 5U 1 u

1 , 1-Dichloroethene (ug/1) 1 u 10 u 5U 1 u

1 ,2-Dichloroethane (ug/1) 1 u 10 u 5U 1 u

1 ,2,4-Trichlorobenzene (ug/1) 1 u 10 u 5U 1 u

1 ,2-Dibromo-3-chloropropane (ug/1) 1 u 10 u 5U 1 u

1 ,2-Dibromoethane (ug/1) 1 u 10 u 5U 1 u

1 ,2-Dichlorobenzene (ug/1) 1 u 10 u 5U 1 u

1 ,2-Dichloropropane (ug/1) 1 u 10 u 5U 1 u

1 ,3-Dichlorobenzene (ug/1) 1 u 10 u 5U 1 u

1 ,4-Dichlorobenzene (ug/1) 1 u 10 u 5U 1 u

1 ,4-Dioxane (ug/1) 25 u 250 u 120 u 25 u

2-Butanone (ug/1) 5U 50 u 25 u 5U

2-Hexanone (ug/1) 5U 50 u 25 u 5U

4-Methyi-2-Pentanone (ug/1) 5U 50 u 25 u 5U

Acetone (ug/1) 1 J 50 u 25 u 5U

Benzene (ug/1) 1 u 10 u 5U 1 u

Bromochloromethane (ug/1) 1 u 10 u 5U 1 u

Bromodichloromethane (ug/1) 1 u 10 u 5U 1 u

Bromoform (ug/1) 1 u 10 u 5U 1 u

Bromomethane (ug/1) 1 u 10 u 5U 1 u

Carbon Disulfide (ug/1) 1 u 10 u 5U 1 u

Carbon Tetrachloride (ug/1) 1 u 10 u 5U 1 u

J- ESTIMATED VALUE

U - NOT DETECTED

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TABLE 1 Page: 6 of 16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE MW21A MW21B MW21C MW23A

CONSTITUENT SAMPLE ID MW21A-125 MW21B-335 MW21C-395 MW23A-265

DATE 11/01/2005 11/01/2005 11/01/2005 10/31/2005

Chlorobenzene (ug/1) 1 u 10 u 5U 1 u

Chloroethane (ug/1) 1 u 10 u 5U 1 u

Chloroform (ug/1) 1 u 10 u 5U 1 u

Chloromethane (ug/1) 1 u 10 u 5U 1 u

cis-1 ,3-Dichloropropene (ug/1) 1 u 10 u 5U 1 u

Dibromochloromethane (ug/1) 1 u 10 u 5U 1 u

Ethylbenzene (ug/1) 1 u 10 u 5U 1 u

Methylene Chloride (ug/1) 2U 20 u 10 u 2U

Styrene (ug/1) 1 u 10 u 5U 1 u

Toluene (ug/1) 0.04 J 10 u 5U 0.04 J

trans-1 ,2-Dichloroethene (ug/1) 1 u 10 u 5U 1 u

trans-1 ,3-Dichloropropene (ug/1) 1 u 10 u 5U 1 u

Xylene (total) (ug/1) 1 u 10 u 5U 1 u

J- ESTIMATED VALUE

U - NOT DETECTED

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TABLE 1 Page: 7 of 16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE MW23B MW23C MW23D MW26 CONSTITUENT SAMPLE ID MW23B-350 MW23C-403 MW23D-447 MW268-271.5

DATE 11/02/2005 10/31/2005 11/02/2005 10/31/2005

cis-1 ,2-Dichloroethene (ug/1) 10 u 1 J 1 u 1 u

Tetrachloroethane (ug/1) 12 28 1 u 1 u

Trichloroethane (ug/1) 170 130 1 u 1 u

Vinyl chloride (ug/1) 10 u 4U 1 u 1 u

1,1, 1-Trichloroethane (ug/1) 10 u 4U 1 u 1 u

1, 1 ,2,2-Tetrachloroethane (ug/1) 10 u 4U 1 u 1 u

1,1 ,2-Trichloroethane (ug/1) 10 u 4U 1 u 1 u

1, 1-Dichloroethane (ug/1) 10 u 4U 1 u 1 u

1, 1-Dichloroethene (ug/1) 10 u 4U 1 u 1 u

1 ,2-Dichloroethane (ug/1) 10 u 4U 1 u 1 u

1 ,2,4-Trichlorobenzene (ug/1) 10 u 4U 1 u 1 u

1 ,2-Dibromo-3-chloropropane (ug/1) 10 u 4U 1 u 1 u

1 ,2-Dibromoethane (ug/1) 10 u 4U 1 u 1 u

1 ,2-Dichlorobenzene (ug/1) 10 u 4U 1 u 1 u

1 ,2-Dichloropropane (ug/1) 10 u 4U 1 u 1 u

1 ,3-Dichlorobenzene (ug/1) 10 u 4U 1 u 1 u

1 A-Dichlorobenzene (ug/1) 10 u 4U 1 u 1 u

1 ,4-Dioxane (ug/1) 250 u 100 u 25 u 25 u

2-Butanone (ug/1) 50 u 20 u 1 J 5U

2-Hexanone (ug/1) 50 u 20 u 5U 5U

4-Methyi-2-Pentanone (ug/1) 50 u 20 u 5U 5U

Acetone (ug/1) 50 u 20 u 21 5U

Benzene (ug/1) 10 u 4U 2 1 u

Bromochloromethane (ug/1) 10 u 4U 1 u 1 u

Bromodichforomethane (ug/1) 10 u 4U 1 u 1 u

Bromoform (ug/1) 10 u 4U 1 u 1 u

Bromomethane (ug/1) 10 u 4U 1 u 1 u

Carbon Disulfide (ug/1) 10 u 4U 1 u 1 u

Carbon Tetrachloride (ug/1) 10 u 0.3 J 1 u 0.5 J

J- ESTIMATED VALUE

U - NOT DETECTED

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TABLE 1 Page: 8 of 16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE MW23B MW23C MW23D MW26

CONSTITUENT SAMPLE ID MW23B-350 MW23C-403 MW23D-447 MW26B-271 .5

DATE 11/02/2005 10/31/2005 11/02/2005 10/31/2005

Chlorobenzene (ug/1) 10 u 4U 1 u 1 u

Chloroethane (ug/1) 10 u 4U 1 u 1 u

Chloroform (ug/1) 10 u 0.3 J 1 u 1 u

Chloromethane (ug/1) 10 u 4U 1 u 1 u

cis-1 ,3-Dichloropropene (ug/1) 10 u 4U 1 u 1 u

Dibromochloromethane (ug/1) 10 u 4U 1 u 1 u

Ethylbenzene (ug/1) 10 u 4U 0.08 J 1 u

Methylene Chloride (ug/1) 20 u 8U 2U 2U

Styrene (ug/1) 10 u 4U 0.1 J 1 u

Toluene (ug/1) 10 u 4U 0.5 J 0.07 J

trans-1 ,2-Dichloroethene (ug/1) 10 u 4U 1 u 1 u

trans-1 ,3-Dichloropropene (ug/1) 10 u 4U 1 u 1 u

Xylene (total) (ug/1) 10 u 4U 0.4 J 1 u

J- ESTIMATED VALUE

U - NOT DETECTED

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TABLE 1 Page: 9 of 16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE MW26 MW26 MW26 MW26

CONSTITUENT SAMPLE ID MW26F-410.5 MW26E-377 MW26C-325 MW26D-350.5

DATE 10/31/2005 1013112005 10/31/2005 10/31/2005

cis-1 ,2-Dichloroethene (ug/1) 0.8 J 1 u 1 u 1 u

Tetrachloroethane (ug/1) 1 1 u 1 u 1 u

Trichloroethane (ug/1) 10 1 u 1 u 1 u

Vinyl chloride (ug/1) 1 u 1 u 1 u 1 u

1 , 1 , 1-T richforoethane (ug/1) 1 u 1 u 1 u 1 u

1,1 ,2,2-Tetrachloroethane (ug/1) 1 u 1 u 1 u 1 u

1,1 ,2-Trichloroethane (ug/1) 1 u 1 u 1 u 1 u

1, 1-Dichforoethane (ug/1) 1 u 1 u 1 u 1 u

1, 1-Dichloroethene (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dichforoethane (ug/1) 1 u 1 u 1 u 1 u

1 ,2,4-Trichlorobenzene (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dibromo-3-chloropropane (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dibromoethane (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dichforobenzene (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dichforopropane (ug/1) 1 u 1 u 1 u 1 u

1 ,3-Dichforobenzene (ug/1) 1 u 1 u 1 u 1 u

1 ,4-Dichlorobenzene (ug/1) 1 u 1 u 1 u 1 u

1, 4-Dioxane (ug/1) 25 u 25 u 25 u 25 u

2-Butanone (ug/1) 5U 5U 5U 5U

2-Hexanone (ug/1) 5U su 5U 5U

4-Methyi-2-Pentanone (ug/1) su 5U 5U 5U

Acetone (ug/1) 5U 5U 5U 5U

Benzene (ug/1) 1 u 1 u 1 u 1 u

Bromochforomethane (ug/1) 1 u 1 u 1 u 1 u

Bromodichforomethane (ug/1) 1 u 1 u 1 u 1 u

Bromoform (ug/1) 1 u 1 u 1 u 1 u

Bromomethane (ug/1) 1 u 1 u 1 u 1 u

Carbon Disulfide (ug/1) 1 u 1 u 1 u 1 u

Carbon Tetrachloride (ug/1) 1 u 1 u 0.08 J 1 u

J- ESTIMATED VALUE

U - NOT DETECTED

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TABLE 1 Page: 10 of 16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE MW26 MW26 MW26 MW26

CONSTITUENT SAMPLE ID MW26F-410.5 MW26E-377 MW26C-325 MW26D-350.5

DATE 10/31/2005 10/31/2005 10/31/2005 10/31/2005

Chlorobenzene (ug/1) 1 u 1 u 1 u 1 u

Chloroethane (ug/1) 1 u 1 u 1 u 1 u

Chloroform (ug/1) 0.07 J 0.2 J 0.08 J 1 u

Chloromethane (ug/1) 1 u 1 u 1 u 1 u

cis-1 ,3-Dichloropropene (ug/1) 1 u 1 u 1 u 1 u

Dibromochloromethane (ug/1) 1 u 1 u 1 u 1 u

Ethylbenzene (ug/1) 1 u 1 u 1 u 1 u

Methylene Chloride (ug/1) 2U 2U 2U 2U

Styrene (ug/1) 1 u 1 u 1 u 1 u

Toluene (ug/1) 0.08 J 0.08 J 0.04 J 0.2 J

trans-1 ,2-Dichloroethene (ug/1) 1 u 1 u 1 u 1 u

trans-1 ,3-Dichloropropene (ug/1) 1 u 1 u 1 u 1 u

Xylene (total) (ug/1) 1 u 1 u 1 u 1 u

J- ESTIMATED VALUE

U- NOT DETECTED

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TABLE 1 Page: 11 of 16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE MW26 MW26 MW26 MW27

CONSTITUENT SAMPLE ID MW26G-443 MW26A-229 MW26H-478.50 MW27H-476.5

DATE 10/31/2005 10/31/2005 10/31/2005 11/01/2005

cis-1 ,2-Dichloroethene (ug/1) 0.4 j 1 u 1 u 1 u

Tetrachloroethane (ug/1) 6 1 u 1 u 1 u

Trichloroethane (ug/1) 42 1 u 1 u 1 u

Vinyl chloride (ug/1) 1 u 1 u 1 u 1 u

1,1, 1-Trichloroethane (ug/1) 1 u 1 u 1 u 1 u

1,1 ,2,2-Tetrachloroethane (ug/1) 1 u 1 u 1 u 1 u

1,1 ,2-Trichloroethane (ug/1) 1 u 1 u 1 u 1 u

1, 1-Dichloroethane (ug/1) 1 u 1 u 1 u 1 u

1 , 1-Dichloroethene (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dichloroethane (ug/1) 1 u 1 u 1 u 1 u

1 ,2,4-Trichlorobenzene (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dibromo-3-chloropropane (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dibromoethane (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dichlorobenzene (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dichloropropane (ug/1) 1 u 1 u 1 u 1 u

1 ,3-Dichlorobenzene (ug/1) 1 u 1 u 1 u 1 u

1 ,4-Dichlorobenzene (ug/1) 1 u 1 u 1 u 1 u

1 ,4-Dioxane (ug/1) 25 u 25 u 25 u 25 u

2-Butanone (ug/1) 5U 5U 5U 5U

2-Hexanone (ug/1) 5U 5U 5U 5U

4-Methyi-2-Pentanone (ug/1) 5U 5U 5U 5U

Acetone (ug/1) 5U 5U 5U 5U

Benzene (ug/1) 1 u 1 u 1 u 1 u

Bromochloromethane (ugil) 1 u 1 u 1 u 1 u

Bromodichloromethane (ug/1) 1 u 1 u 1 u 1 u

Bromoform (ug/1) 1 u 1 u 1 u 1 u

Bromo methane (ug/1) 1 u 1 u 1 u 1 u

Carbon Disulfide (ug/1) 1 u 1 u 1 u 1 u

Carbon Tetrachloride (ug/1) 1 u 1 u 1 u 1 u

J- ESTIMATED VALUE

U - NOT DETECTED

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TABLE 1 Page: 12 of 16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE MW26 MW26 MW26 MW27

CONSTITUENT SAMPLE ID MW26G-443 MW26A-229 MW26H-478.50 MW27H-476.5

DATE 10/31/2005 10/31/2005 10/31/2005 11/01/2005

Chlorobenzene (ug/1) 1 u 1 u 1 u 1 u

Chloroethane (ug/1) 1 u 1 u 1 u 1 u

Chloroform (ug/1) 0.1 J 1 u 1 u 1 u

Chloromethane (ug/1) 1 u 1 u 1 u 1 u

cis-1 ,3-Dichloropropene (ug/1) 1 u 1 u 1 u 1 u

Dibromochloromethane (ug/1) 1 u 1 u 1 u 1 u

Ethylbenzene (ug/1) 1 u 1 u 1 u 1 u

Methylene Chloride (ug/1) 2U 2U 2U 2U

Styrene (ug/1) 1 u 1 u 1 u 1 u

Toluene (ug/1) 0.08 J 1 u 0.07 J 0.08 J

trans-1 ,2-Dichloroethene (ug/1) 1 u 1 u 1 u 1 u

trans-1 ,3-Dichloropropene (ug/1) 1 u 1 u 1 u 1 u

Xylene (total) (ug/1) 1 u 1 u 1 u 1 u

J- ESTIMATED VALUE

U - NOT DETECTED

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TABLE 1 Page: 13 of 16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE MW27 MW27 MW27 MW27

CONSTITUENT SAMPLE ID MW27D-329.5 MW27G-443 MW27E-369 MW27F-413.5

DATE 1110112005 1110112005 1110112005 1110112005

cis-1 ,2-Dichloroethene (ug/1) 1 u 1 u 1 u 1 u

Tetrachloroethene (ug/1) 1 u 1 u 1 u 1 u

T richloroethene (ug/1) 1 u OAJ 1 u 1 u

Vinyl chloride (ug/1) 1 u 1 u 1 u 1 u

1,1, 1-Trichloroethane (ug/1) 1 u 1 u 1 u 1 u

1,1 ,2,2-Tetrachloroethane (ug/1) 1 u 1 u 1 u 1 u

1,1 ,2-Trichloroethane (ug/1) 1 u 1 u 1 u 1 u

1, 1-Dichloroethane (ug/1) 1 u 1 u 1 u 1 u

1, 1-Dichloroethene (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dichloroethane (ug/1) 1 u 1 u 1 u 1 u

1 ,2,4-Trichlorobenzene (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dibromo-3-chloropropane (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dibromoethane (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dichlorobenzene (ug/1) 1 u 1 u 1 u 1 u

1 ,2-Dichloropropane (ug/1) 1 u 1 u 1 u 1 u

1 ,3-Dichlorobenzene (ug/1) 1 u 1 u 1 u 1 u

1 ,4-Dichlorobenzene (ug/1) 1 u 1 u 1 u 1 u

1 ,4-Dioxane (ug/1) 25 u 25 u 25 u 25 u

2-Butanone (ug/1) 5U 5U 5U 5U

2-Hexanone (ug/1) 5U 5U 5U 5U

4-Methyi-2-Pentanone (ug/1) 5U 5U 5U 5U

Acetone (ug/1) 5U 5U 5U 5U

Benzene (ug/1) 1 u 1 u 1 u 1 u

Bromochloromethane (ug/1) 1 u 1 u 1 u 1 u

Bromodichloromethane (ug/1) 1 u 1 u 1 u 1 u

Bromoform (ug/1) 1 u 1 u 1 u 1 u

Bromomethane (ug/1) 1 u 1 u 1 u 1 u

Carbon Disulfide (ug/1) 1 u 1 u 1 u 1 u

Carbon Tetrachloride (ug/1) 0.05 J 0.1 J 1 u 0.07 J

J- ESTIMATED VALUE

U - NOT DETECTED

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TABLE 1 Page: 14 of 16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE MW27 MW27 MW27 MW27

CONSTITUENT SAMPLE ID MW27D-329.5 MW27G-443 MW27E-369 MW27F-413.5

DATE 11/01/2005 11/01/2005 11/01/2005 11/01/2005

Chlorobenzene (ug/1) 1 u 1 u 1 u 1 u

Chloroethane (ug/1) 1 u 1 u 1 u 1 u

Chloroform (ug/1) 1 u 0.05 J 1 u 1 u

Chloromethane (ug/1) 1 u 1 u 1 u 1 u

cis-1 ,3-Dichloropropene (ug/1) 1 u 1 u 1 u 1 u

Dibromochloromethane (ug/1) 1 u 1 u 1 u 1 u

Ethylbenzene (ug/1) 1 u 1 u 1 u 1 u

Methylene Chloride (ug/1) 2U 2U 2U 2U

Styrene (ug/1) 1 u 1 u 1 u 1 u

Toluene (ug/1) 0.06 J 0.05 J 0.1 J 0.2 J

trans-1 ,2-Dichloroethene (ug/1) 1 u 1 u 1 u 1 u

trans-1 ,3-Dichloropropene (ug/1) 1 u 1 u 1 u 1 u

Xylene (total) (ug/1) 1 u 1 u 1 u 1 u

J- ESTIMATED VALUE

U - NOT DETECTED

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TABLE 1 Page: 15of16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CITY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE MW27 MW27 MW27

CONSTITUENT SAMPLE ID MW27C-289 MW27A-197 MW27B-241

DATE 11/01/2005 11/01/2005 11/01/2005

cis-1 ,2-Dichloroethene (ug/1) 1 u 1 u 1 u

Tetrachloroethene (ug/1) 1 u 1 u 1 u

Trichloroethene (ug/1) 1 u 1 u 1 u

Vinyl chloride (ug/1) 1 u 1 u 1 u

1 , 1 , 1-Trichloroethane (ug/1) 1 u 1 u 1 u

1, 1 ,2,2-Tetrachloroethane (ug/1) 1 u 1 u 1 u

1,1 ,2-Trichloroethane (ug/1) 1 u 1 u 1 u

1, 1-Dichloroethane (ug/1) 1 u 1 u 1 u

1, 1-Dichloroethene (ug/1) 1 u 1 u 1 u

1 ,2-Dichloroethane (ug/1) 1 u 1 u 1 u

1 ,2,4-Trichlorobenzene (ug/1) 1 u 1 u 1 u

1 ,2-Dibromo-3-chloropropane (ug/1) 1 u 1 u 1 u

1 ,2-Dibromoethane (ug/1) 1 u 1 u 1 u

1 ,2-Dichlorobenzene (ug/1) 1 u 1 u 1 u

1 ,2-Dichloropropane (ug/1) 1 u 1 u 1 u

1 ,3-Dichlorobenzene (ug/1) 1 u 1 u 1 u

1 ,4-Dichlorobenzene (ug/1) 1 u 1 u 1 u

1 ,4-Dioxane (ug/1) 25 u 25 u 25 u

2-Butanone (ug/1) 5U 5U 5U

2-Hexanone (ug/1) 5U 5U 5U

4-Methyi-2-Pentanone (ug/1) 5U 5U 5U

Acetone (ug/1) 5U 5U 5U

Benzene (ug/1) 1 u 1 u 1 u

Bromochloromethane (ug/1) 1 u 1 u 1 u

Bromodichloromethane (ug/1) 1 u 1 u 1 u

Bromoform (ug/1) 1 u 1 u 1 u

Bromomethane (ug/1) 1 u 1 u 1 u

Carbon Disulfide (ug/1) 1 u 1 u 1 u

Carbon Tetrachloride (ug/1) 1 u 1 u 1 u

J- ESTIMATED VALUE

U - NOT DETECTED

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TABLE 1 Page: 16 of 16

VOLATILE ORGANICS IN GROUNDWATER

150 FULTON AVENUE, GARDEN CiTY, NEW YORK

PERIOD: Sampling Round October/November 2005

SAMPLE TYPE: Water

SITE MW27 MW27 MW27

CONSTITUENT SAMPLE ID MW27C-289 MW27A-197 MW27B-241

DATE 11/01/2005 11/0112005 11101/2005

Chlorobenzene (ugll) 1 u 1 u 1 u

Chloroethane (ugll) 1 u 1 u 1 u

Chloroform (ug/1) 1 u 1 u 1 u

Chloromethane (ugll) 1 u 1 u 1 u

cis-1 , 3-Dichloropropene (ug/1) 1 u 1 u 1 u

Dibromochloromethane (ug/1) 1 u 1 u 1 u

Ethylbenzene (ugll) 1 u 1 u 1 u

Methylene Chloride (ug/1) 2U 2U 2U

Styrene (ug/1) 1 u 1 u 1 u

Toluene (ug/1) 1 u 1 u 0.1 J

trans-1 ,2-Dichloroethene (ug/1) 1 u 1 u 1 u

trans-1 ,3-Dichloropropene (ugll) 1 u 1 u 1 u

Xylene (total) (ug/1) 1 u 1 u 1 u

J- ESTIMATED VALUE

U- NOT DETECTED

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APPENDIX A NASSAU COUNTY DEPARTMENT OF HEALTH

PUBLIC SUPPLY WELL SAMPLE RESULTS

WELL NUMBER N-07058 N-07058 N-07058 N-07058 N-07058 N-07058 N-07058 N-07058 N-07058 N-07058 SAMPLE DATE 3/22/88 9/27/88 11/22/88 5/16/89 5/16/89 5/16/89 6/1/89 6/2/89 7/6/89 7/11/89 1,2,3-Trichlorobenzene u u u NA NA NA u u u u 1,2,4-Trichlorobenzene u u u NA NA NA u u u u 1,2,4-Trimethylbenzene u u u NA NA NA u u u u 1,2-Dichlorobenzene u u u NA NA NA u u u u 1,3,5-Trimethylbenzene u u u NA NA NA u u u u 1,3-Dichlorobenzene u u u NA NA NA u u u u 1 A-Dichlorobenzene u u u NA NA NA u u u u 0-Chlorotoluene u u u NA NA NA u u u u p-Chlorotoluene u u u NA NA NA u u u u Benzene u u u u u u u u u u Bromobenzene u u u NA NA NA u u u u Chlorobenzene u u u u u u u u u u Ethyl Benzene u u u u u u u u u u Hexachlorobutadiene u u u NA NA NA u u u u lsopropylbenzene u u u NA NA NA u u u u m-Xylene u u u NA NA NA u u u u n-Butylbenzene u u u NA NA NA u u u u n-Propylbenzene u u u NA NA NA u u u u o-Xylene u u u NA NA NA u u u u p-lsopropyltoluene u u u NA NA NA u u u u p-Xylene u u u NA NA NA u u u u sec-Butylbenzene u u u NA NA NA u u u u Styrene u u u NA NA NA u u u u tert-Butylbenzene u u u NA NA NA u u u u Toluene u u u u u u u u u u 1,1, 1,2-Tetrachloroethane u u u NA NA NA u u u u 1,1,1-Trichloroethane u u u u u u u u u u 1,1,2,2-Tetrachloroethane u u u NA NA NA u u u u 1,1,2-Trichloroethane u u u u u u u u u u 1,1-Dichloroethane u u u u u u u u u u 1,1-Dichloroethene u u u u u u u u u u 1,1-Dichloropropene u u u NA NA NA u u u u 1,2,3-Trichloropropane u u u NA NA NA u u u u 1,2-Dichloroethane u u u u u u u u u u 1,2-Dichloropropane u u u NA NA NA u u u u 1,3-Dichloropropane NA u u NA NA NA u u u u 2,2-Dichloropropane 0.00 0.00 0.00 NA NA NA 0.00 0.00 0.00 0.00

Bromochloromethane u u u NA NA NA u u u u Bromodichloromethane u u u u u u u u u u Bromoform u u u u u u u u u u Bromomethane u u u NA NA NA u u u u Carbon Tetrachloride u u 1.20 u u u u 0.60 u u Chlorodibromomethane u u u u u u u u u u Chloroethane u u u NA NA NA u u u u Chloroform u u u u u u u u u u Chloromethane u u u NA NA NA u u u u cis-1,2-Dichloroethene u u u u u u u u u u cis-1,3-Dichloropropene u u u NA NA NA u u u u Dibromomethane u u u NA NA NA u u u u Dichlorodifluoromethane u u u NA NA NA u u u u Methylene Chloride u u u NA NA NA u u u u Tetrachloroethane NA 0.60 1.40 1.00 1.00 1.00 0.50 1.20 u u trans-1,2-Dichloroethene u u u u u u u u u u trans-1 ,3-Dichloropropene u u u NA NA NA u u u u Trichloroethane 11.00 6.30 12.00 7.00 8.00 7.00 4.10 8.80 2.00 0.70

Trichlorofluoromethane u u u NA NA NA u u u u Vinyl Chloride u u u NA NA NA u u u u

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APPENDIX A NASSAU COUNTY DEPARTMENT OF HEALTH

PUBLIC SUPPLY WELL SAMPLE RESULTS

WELL NUMBER N-07058 N-07058 N-07058 N-07058 N-07058 N-07058 N-07058 N-07058 N-07058

SAMPLE DATE 7/18/89 8/1/89 8/13/89 8115/89 9/27/89 10/24/89 11/28/89 12/19/89 1/30/90

1,2,3-Trichlorobenzene u u NA u u u u u u 1,2,4-Trichlorobenzene u u NA u u u u u u 1,2,4-Trimethylbenzene u u NA u u u u u u 1,2-Dichlorobenzene u u NA u u u u u u 1,3,5-Trimethylbenzene u u NA u u u u u u 1,3-Dichlorobenzene u u NA u u u u u u 1 A-Dichlorobenzene u u NA u u u u u u 0-Chlorotoluene u u NA u u u u u u p-Chlorotoluene u u NA u u u u u u Benzene u u u u u u u u u Bromobenzene u u NA u u u u u u Chlorobenzene u u u u u u u u u Ethyl Benzene u u u u u u u u u Hexachlorobutadiene u u NA u u u u u u Isopropyl benzene u u NA u u u u u u m-Xylene u u NA u u u u u u n-Butylbenzene u u NA u u u u u u n-Propylbenzene u u NA u u u u u u o-Xylene u u NA u u u u u u p-lsopropyltoluene u u NA u u u u u u p-Xylene u u NA u u u u u u sec-Butylbenzene u u NA u u u u u u Styrene u u NA u u u u u u tert-Butylbenzene u u NA u u u u u u Toluene u u u u u u u u u 1,1,1,2-Tetrachloroethane u u NA u u u u u u 1,1,1-Trichloroethane u u u u u u u u u 1,1,2,2-Tetrachloroethane u u u u u u u u u 1,1,2-Trichloroethane u u u u u u u u u 1,1-Dichloroethane u u u u u u u u u 1,1-Dichloroethene u u NA u u u u u u 1,1-Dichloropropene u u NA u u u u u u 1,2,3-Trichloropropane u u NA u u u u u u 1,2-Dichloroethane u u u u u u u u u 1,2-Dichloropropane u u u u u u u u u 1,3-Dichloropropane u u NA u u u u u u 2,2-Dichloropropane 0.00 0.00 NA 0.00 0.00 0.00 0.00 0.00 u Bromochloromethane u u NA u u u u u u Bromodichloromethane u u u u u u u u u Bromoform u u u u u u u u u Bromomethane u u NA u u u u u u Carbon Tetrachloride u u u u u u u u u Chlorodibromomethane u u u u u u u u u Chloroethane u u NA u u u u u u Chloroform u u NA u u u u u u Chloromethane u u NA u u u u u u cis-1,2-Dichloroethene u u u u u u u u u cis-1,3-Dichloropropene u u NA u u u u u u Dibromomethane u u NA u u u u u u Dichlorodifluoromethane u u NA u u u u u u Methylene Chloride u u NA u u u u u u Tetrachloroethane 1.20 u 2.00 0.50 1.30 1.10 1.50 1.30 1.10

trans-1,2-Dichloroethene u u u u u u u u u trans-1,3-Dichloropropene u u NA u u u u u u Trichloroethane 11.00 2.10 9.00 6.30 12.00 9.40 13.00 11.00 10.00

Trichlorofluoromethane u u u u u u u u u Vinyl Chloride u u NA u u u u u u

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APPENDIX A NASSAUCOUNTYDEPARTMENTOFHEALTH

PUBLIC SUPPLY WELL SAMPLE RESULTS

WELL NUMBER N-08339 N-08339 N-08339 N-08339 N-08339 N-08339 N-08339 N-08339 N-08339 N-08339

SAMPLE DATE 3/10/87 3/27/87 8/10/88 9/20/88 9/20/88 9/20/88 9/20/88 9/20/88 9/20/88 9/20/88

1,2,3-Trichlorobenzene NA NA NA NA NA NA u NA NA NA 1,2,4-Trich!orobenzene NA NA NA NA NA NA u NA NA NA 1,2,4-Trimethylbenzene NA NA NA NA NA NA u NA NA NA 1,2-Dich!orobenzene u NA NA NA NA NA u u u u 1,3,5-Trimethylbenzene NA NA NA NA NA NA u NA NA NA

1,3-Dichlorobenzene u NA NA NA NA NA u u u u 1 A-Dichlorobenzene u NA NA NA NA NA u u u u 0-Chlorotoluene NA NA NA NA NA NA u NA NA NA p-Chlorotoluene NA NA NA NA NA NA u NA NA NA Benzene u u u u u u u NA NA NA Bromo benzene NA NA NA NA NA NA u NA NA NA

Chlorobenzene u u u u u u u u u u Ethyl Benzene u u u u u u u NA NA NA

Hexachlorobutadiene NA NA NA NA NA NA u NA NA NA lsopropylbenzene NA NA NA NA NA NA u NA NA NA

m-Xylene u NA NA NA NA NA u NA NA NA n-Butylbenzene NA NA NA NA NA NA u NA NA NA

n-Propylbenzene NA NA NA NA NA NA u NA NA NA

o-Xylene u NA NA NA NA NA u NA NA NA

p-lsopropyltoluene NA NA NA NA NA NA u NA NA NA

p-Xylene u NA NA NA NA NA u NA NA NA

sec-Butyl benzene NA NA NA NA NA NA u NA NA NA

Styrene NA NA NA NA NA NA u NA NA NA

tert-Butylbenzene NA NA NA NA NA NA u NA NA NA

Toluene u u u u u u u NA NA NA

1,1,1,2-Tetrachloroethane u NA NA NA NA NA u u u u 1,1,1-Trichloroethane u u u u u u u u u u 1,1,2,2-Tetrachloroethane NA NA NA NA NA NA u NA NA NA

1,1,2-Trichloroethane u u u u u u u u u u 1,1-Dichloroethane u u u u u u u u u u 1,1-Dichloroethene u u NA u u u u u u u 1,1-Dichloropropene NA NA NA NA NA NA u NA NA NA

1,2,3-Trichloropropane NA NA NA NA NA NA u NA NA NA

1,2-Dichloroethane u NA NA NA NA NA u u u u 1,2-Dichloropropane u NA NA NA NA NA u u u u 1,3-Dichloropropane NA NA NA NA NA NA u NA NA NA

2,2-Dichloropropane NA NA NA NA NA NA 0.00 NA NA NA

Bromochloromethane NA NA NA NA NA NA u NA NA NA

Bromodichloromethane u u u u u u u u u u Bromoform u u u u u u u u u u Bromomethane u NA NA NA NA NA u u u u Carbon Tetrachloride 5.00 4.00 5.00 5.00 5.00 5.00 4.80 4.00 4.00 4.00

Chlorodibromomethane u u u u u u u u u u Chloroethane u NA NA NA NA NA u u u u Chloroform u u u u u u 0.60 u u 4.00

Chloromethane u NA NA NA NA NA u u u u cis-1,2-Dichloroethene u u u u u u u u u u cis-1,3-Dichloropropene u u u u u u u u u u Dibromomethane NA NA NA NA NA NA u NA NA NA

Dichlorodifluoromethane u NA NA NA NA NA u u u u Methylene Chloride 1.00 u NA NA NA NA u u u u T etrachloroethene NA 3.00 5.00 4.00 3.00 4.00 2.60 NA NA NA

trans-1,2-Dichloroethene u u u u u u u u u u trans-1 ,3-Dichloropropene u NA NA NA NA NA u u u u Trichloroethane 4.00 6.00 u u u u u u u u Trichlorofluoromethane u u u u u u u u u u Vinyl Chloride u NA NA NA NA NA u u u u

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APPENDIX A NASSAU COUNTY DEPARTMENT OF HEALTH

PUBLIC SUPPLY WELL SAMPLE RESULTS

WELL NUMBER N-08339 N-08339 N-08339 N-08339 N-08339 N-08339 N-08339 N-08339 N-08339 N-08339 SAMPLE DATE 12/9/88 1/10/89 1/11/89 1112/89 1/13/89 1/16/89 3/10/89 3117/89 4/4/89 4111/89 1,2,3-Trichlorobenzene u u u u u u u u u u 1,2,4-Trichlorobenzene u u u u u u u u u u 1,2 ,4-T rimethylbenzene u u u u u u u u u u 1,2-Dichlorobenzene u u u u u u u u u u 1,3,5-Trimethylbenzene u u u u u u u u u u 1,3-Dichlorobenzene u u u u u u u u u u 1,4-Dichlorobenzene u u u u u u u u u u 0-Chlorotoluene u u u u u u u u u u p-Chlorotoluene u u u u u u u u u u Benzene u u u u u u u u u u Bromobenzene u u u u u u u u u u Chlorobenzene u u u u u u u u u u Ethyl Benzene u u u u u u u u u u Hexachlorobutadiene u u u u u u u u u u lsopropylbenzene u u u u u u u u u u m-Xylene u u u u u u u u u u n-Butylbenzene u u u u u u u u u u n-Propylbenzene u u u u u u u u u u o-Xylene u u u u u u u u u u p-lsopropyltoluene u u u u u u u u u u p-Xylene u u u u u u u u u u sec-Butyl benzene u u u u u u u u u u Styrene u u u u u u u u u u tert-Butylbenzene u u u u u u u u u u Toluene u u u u u u u u u u 1,1, 1 ,2-Tetrachloroethane u u u u u u u u u u 1,1 , 1-Trichloroethane u u u u u u u u u u 1,1 ,2,2-Tetrachloroethane u u u u u u u u u u 1,1 ,2-Trichloroethane u u u u u u u u u u 1 , 1-Dichloroethane u u u u u u u u u u 1,1-Dichloroethene u u u u u u u u u u 1 , 1-Dichloropropene u u u u u u u u u u 1 ,2,3-Trichloropropane u u u u u u u u u u 1,2-Dichloroethane u u u u u u u u u u 1 ,2-Dichloropropane u u u u u u u u u u 1 ,3-Dichloropropane u u u u u u u u u u 2,2-Dichloropropane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

Bromochloromethane u u u u u u u u u u Bromodichloromethane u u u u u u u u u u Bromoform u u u u u u u u u u Bromomethane u u u u u u u u u u Carbon Tetrachloride 5.40 5.40 6.20 1.90 5.30 5.90 6.60 6.40 0.50 1.30

Chlorodibromomethane u u u u u u u u u u Chloroethane u u u u u u u u u u Chloroform u 0.50 u u 0.70 1.00 u u u u Chloromethane u u u u u u u u u u cis-1 ,2 -Dichloroethene u u u u u u u u u u cis-1 ,3-Dichloropropene u u u u u u u u u u Dibromomethane u u u u u u u u u u Dichlorodifluoromethane u u u u u u u u u u Methylene Chloride u u u u u u u u u u Tetrachloroelhene 4.00 2.20 2.50 0.70 2.50 1.80 3.20 2.80 0.50 0.50

trans-1 ,2 -Dichloroethene u u u u u u u u u u trans-1 ,3-Dichloropropene u u u u u u u u u u T richloroethene u u u u u u u u u u T richlorofluoromethane u u u u u u u u u u Vinyl Chloride u u u u u u u u u u

Page 146

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APPENDIX A NASSAU COUNTY DEPARTMENT OF HEALTH

PUBLIC SUPPLY WELL SAMPLE RESULTS

WELL NUMBER N-08339 N-08339 N-08339 N-08339 N-08339 N-08339 N-08339 N-08339 N-08339 SAMPLE DATE 5/11/89 7/6/89 8/10/89 8/16/89 9/29/89 10/17/89 11/28/89 12/19/89 1/23/90 1,2,3-Trichlorobenzene NA u u NA u u u u u 1,2,4-Trichlorobenzene NA u u NA u u u u u 1,2,4-T rimethylbenzene NA u u NA u u u u u 1,2-Dichlorobenzene NA u u NA u u u u u 1,3,5-Trimethylbenzene NA u u NA u u u u u 1,3-Dichlorobenzene NA u u NA u u u u u 1 A-Dichlorobenzene NA u u NA u u u u u 0-Chlorotoluene NA u u NA u u u u u p-Chlorotoluene NA u u NA u u u u u Benzene u u u u u u u u u Bromobenzene NA u u NA u u u u u Chlorobenzene u u u u u u u u u Ethyl Benzene u u u u u u u u u Hexachlorobutadiene NA u u NA u u u u u lsopropylbenzene NA u u NA u u u u u m-Xylene NA u u NA u u u u u n-Butylbenzene NA u u NA u u u u u n-Propylbenzene NA u u NA u u u u u o-Xylene NA u u NA u u u u u p-lsopropyltoluene NA u u NA u u u u u p-Xylene NA u u NA u u u u u sec-Butylbenzene NA u u NA u u u u u Styrene NA u u NA u u u u u tert-Butylbenzene NA u u NA u u u u u Toluene u u u u u u u u u 1, 1,1,2-Tetrachloroethane NA u u NA u u u u u 1,1,1-Trichloroethane 6.00 u u u u u u u u 1,1,2,2-Tetrachloroethane NA u u u u u u u u 1,1,2-Trichloroethane u u u u u u u u u 1, 1-Dichloroethane u u u u u u u u u 1,1-Dlchloroethene u u u NA u u u u u 1, 1-Dichloropropene NA u u NA u u u u u 1,2,3-Trichloropropane NA u u NA u u u u u 1,2-Dichloroethane u u u u u u u u u 1,2-Dichloropropane NA u u u u u u u u 1,3-Dichloropropane NA u u NA u u u u u 2,2-Dichloropropane NA 0.00 0.00 NA 0.00 0.00 0.00 0.00 u Bromochloromethane NA u u NA u u u u u Bromodichloromethane u u u u u u u u u Bromoform u u u u u u u u u Bromomethane NA u u NA u u u u u Carbon Tetrachloride u 4.10 u 3.00 3.40 3.40 4.40 4.00 4.50

Chlorodibromomethane u u u u u u u u u Chloroethane NA u u NA u u u u u Chloroform u u u NA u u 0.60 0.60 u Chloromethane NA u u NA u u u u u cis-1,2-Dichloroethene u u u u u u u u u cis-1,3-Dichloropropene u u u NA u u u u u Dibromomethane NA u u NA u u u u u Dichlorodifluoromethane NA u u NA u u u u u Methylene Chloride NA u u NA u u u u u T etrachloroethene 5.00 4.30 u 4.00 5.20 4.80 6.10 6.30 6.30

trans-1,2-Dichloroethene u u u u u u u u u trans-1,3-Dichloropropene NA u u NA u u u u u Trichloroethane u 6.20 u 9.00 16.00 13.00 14.00 11.00 13.00

Trichlorofluoromethane NA u u u u u u u u Vinyl Chloride NA u u NA u u u u u

Page 147

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~ HOLZMACHER, McLENDON and MURRE,M.., P.C.

~ H2MCORP. LABORATORY

REPORT !57!5 BROAD HOLLOW ROAD, MELVILLE; NEW YORK tt747

Tel. <~to> eD•·3040 CLIENT NAME ANO ADDRESS

Inc. Village of Garden City 351 Stewart Ave. Garden City, NY 11530

VOLATILE HALOGENATED

methylene chloride • • • • < 1 1,1-dichloroethylene •••••• <l 1,1-dichloroethane ••••••• <l trans-1,2-dichloro~thylene ••• <l

. cis-1,2-dich!oroethylene •••• <l ·*[chloroform • • • • • • • • • • <1

lrlf2-trichlorotrifluoroetbane <1 ·1, 2-d ichloroethane • • • • • • • <1 1,1,1-trichloroethane~ ••••• <1 carbon tet.rachloride • • • • • ~ <1

LAB tO 0~

LAB. N0·------~8~73~2~9~1~~-----TYPE WATER Potable SAMPLING PT. Well i 13 (N-7058)

i£*4 i?';t

DATE SAMPLED_---::::9-'-/..;;.1..:.:.6._/.::;:.8 ~0 ----TIME SAMPLED ________________ __

RUN TIME (WELL)--==--""~-----COLLECTED BY CL 99

PESTICIDES

lindane • • • • • • • • --­heptachlor • • • • • • • ---aldrin.· • • • • • • • • __ _ heptachlor epoxide ••• __ ...;. dieldrin. • • • . • • • • ---endr'in ••••••••• __ _ o, p 'DDT • • • • • • •• __ ...,. p,p'DDT • • • • • • • • ---methoxychlor. ·• • •

brornodichloromethane • • •. ! _<.:..;1?--* [1, 2-dichloropropa. ne_.. • • • •. • • <1 -.,.,.-------- ••• __ __

2, 3~d ichloropropene. • • • • <1. · • • • __ _

toxaphene • • • • • • • --,.... chlordane • • • • • • • -.....--.-

trans-1, 3-dichloropropene. • • ....-<-t:-· ) _ _,_......_. ___ _..... ___ ••• __ _ trichloroethylene. • • • r.. 1 __ /~~=-=-~=:-:::------1,1,2-trichloroethane. ~ •• ~-~- HERBICIDES

* chl orod .ibromome thane • ~ ·. • • • • < 1 cis-1,3-dichloropropene ••••• -<~1..__ 2,4-D ••••••• . ·---* bromoform.· •••• • •••••• S::l ·. 2,4,5-TP (silvex) • 1, 1, l, 2-tetrachloroethane. • • • -.;<~1~-

. ·~--* tetrachloroethylene •• • •••• <1 OTHERS

1,1,2,2-tetrachloroetbane •••• <1 )l:in)!'l. chloride· · • • • .. < l chloroben~ene . • • • · < 1

'JOLATILE NON-HALOGENATED

t:>enzene •• toluene.

•[m..,.xy1ene p-xylene o-xylene •

. . . . -.. -~-. ..... ~ ---. . . ..... ---. . . . . . ---. ......... ---_______________ _..... ___________ . . . . -----tt • • •

--------------~---· . ·--------------------....--- .. ·-----____ _.....~-------- .. ·-----------------------· . ·-------------~------~· . ·-----

-----------------· .. --------~-------------· . ·-----. . .

RUN NO. (S) *Reported value represents total

Results reported meet N.Y.s. Drinking Water Standards.

Page 106: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

:~-. . · ~t!LZM __ ACHER, McLENDON and MURRELL, P.C.

~~1i2MCOAP. LABORATORY

REPORT !57!5 SROAO HOLLOW ROAO, MELVILLE, NEW YORK f 1747

Tel. C !5JS) 594·3040

CLIENT NAME AND AODRESS

Inc. Viliage of Garden City 351 Stewart Ave. Garden City, NY ll53D

VOLATILE HALOGENATED O 111 ll"eear ~,.~t>~~

E.SL!. methylene Chloride • • • • , < 1 1,1-dichl oroethylene • • • • ·< 1 l,l-dith1oroethane • • <1 trans-l ,2--dichloroethylene • • • <I . <1 cis-1 ,2,..dichloroet:hylene ••••

· * fchl oroform • • • • • • • • • • < 1 {1, 1, 2-trichl orotrifluoroethane <I ·1,2~dichloroethane ••••••• <1 l1 1, 1-trichl oroethane. < 1 carbon t-etrachloride • • .. • ._ < 1 brornddichloromethane • • • • < 1

•-·fl, 2-dichloropropane. .. < 1 i2, 3-cHc hl oropropene • • • "' • • • < 1 tran$-1, 3-di chloropropene.. • < 1 trichloroethylene. • • • • • . .. • __ 2_ 1, l, 2-t richl oroethane. • • .. • • · < 1

* chlorodibromomethane • • < 1 cis-1, 3-dichloropropene. • < l

* ·bromoform. • • • • • • • • • • • < 1 1,1, 1, 2-tetrachloroethane. < 1

* tetrachloroethylene. • • • <1 1, 1,2,2-tetrachloroethane. • • • < l vinyl chloride · . < 1 di chlo rodi fl uo rom~th.:me < 1 chlorobenz ene < 1

'lOLATILE NON-HALOGENAT£D

oenz·ene. • _ · ._ -. • . • • toluene. • • • •. • • . • • __ _

* rm-xy'lene .• • • • • • • • • • • • ---. p-xylene • • • • • • • • • • • • __ _

o-xyl ene • • • • o'" • • • • • • • ---

-----~-.......... -----...,.----. . '. . ----. . . .

LAB 1'0 03

LAB. NO• 1544 97 TYPE WA1'ER Potable SAMPLING PT:. Well .il3 (N-7058)

~vW

DATE SAMPLED 9/8/81 TIME SAMPLED---....,-----­'RUN TIME {WE!.L):.....,..~--rr~---~ COLLECTED BY . . CL 9'9

PESTICIDES

-lindane • • • • • • ·• • ---beptc:~:chlor. • • • • • • __ _ aldrin ••••••• heptachlor epoxide ••• __ _ dieldrin. . . • •• ---e-ndrin ••••.••• • ··--­o"p'DDT •••• • • • • ---P• p 'DDT • • .. me thox:ychlor. • • • • • __ _ toxaphene • chlordane ••

---..,.-_..,...---- . .. "'· -----ftERBI'C: !DES

2,4-D •••••• • 2 , 4 , 5- T P ( s il vex) . • • • ____ _

OTHERS

--------~--~---· .. --~-__________ .......... _____ . . . ---------------"------- . . .• ----

----------------· .. -------------------- . . . --~-

RUN NO. (S) ·~epqrted va!1..,1e repre$ents total

Results reported meet N.Y. s. Drinking Water Standards.

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HOLZMACHER, McLENDON and MURRELL, P.C~

H2M CORP. LABORATORY

REPORT !57::S BROAD HOLLOW ROAC, MEL.VJL.L.E, NEW YORK f 1747

Tel. C!SI8) 89 .. ·30.CO . LAB ID 03

CLIENT NAME AND ADDRESS

Inc. Village of Garden City · 351 Stewart Ave.

Garden City,_ NY 11530

VOLATILE HALOGENATED ._ j tiii:OO:~.;...~.:::.:..~:;.-:-~~--· methylene chloride •••.••• i,l-dichloroethylene •••.•

J •

1, 1-dlchloroethane ••• trans-1,2-dichloroethylene ••• cis-1,2-dichloroethylene . • • •

·.[chloroform .••••.•..•. 1,1,2-trichlorotrifluoroethane '1, 2-d ichloroethane . • • • • • • 1,1,1-trichloroethane. carbon tetrachloride • bromodichlorornethane •

* [1, 2-dichloropropane •• 2,3-dichloropropene ••••••• trans-1,3-dichloropropene .. trichloroethylene •••• 1,1,2-trich1oroethane ••.

* chlorod ibromome thane • • cis-1,3-dichloropropene •••••

* bromoform .••••••.. 1,1,1,2-tetrachloroethane.

* tetrachloroethylene .••• 1, 1,2 t,2-tetrachloroethane. . Viny~chloride • • • • Chlorobenzene

'JOLATILE NON-H.l\LOGENATED

Qenzene •• toluene. •

•[m-xylene • p-xylene o-xylene •

sL! <1 <1 <I <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

3 <1 <1 <1 <1 <1 <1 <1 . <1 <1

LAB. NO. 2~~1~A

TyPE WATER Potable Water SAMPLING PT. . Well #13 (N-7058

.a - aa..-. .. t.J2M4:;;;;q

DATE SAMPLED__.. __ 9~/~1~j~/_s_2~---~·---TIME SAMPLED __________________ _

RUN TIME (WELL} _ _.,.,,..--,.,...----COLLECTEb BY CL-99

PESTICIDES

lindane • · • • • • • heptachlor. • • • • aldrin ••••.•• heptachlor epoxide. dieldrin. • • • • • endrin. • • • • .

. . ---

. ·---. ·---

o,p'PDT ••••• • • • --­p,p'DDT •• • • • • • • ---methoxychlor •• toxaphene • • • • • • • __ _ chlordane .• •

--------- . . . ------------- ... ---HERBICIDES

2,4-D ••••••• 2,4,5-TP (silvex)

OTHERS

---------. . . ------------ . . . ---

RUN NO. (S) *Reported value represents total

Results reported~ __ ME __ ET __________ _ N.Y.S. Drinking Water Standards.

t ~'~ ~-----·------------------------------------------~~~~~~~~~~~--------------------------

Page 108: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

ti~A.~ HOLZMACHER, McLENDON and MURRELL. P.C. LfT'- H2M CORP. LABORATORY

REPORT 575 BROAD HOLLOW ROAD, MELVILLE. NEW YORK 11747 Tel. (516) 694·3040

CLIENT NAME AND ADDRESS

Garden City, Inc. Village of 351 Stewart Avenue Garden City, NY 11530

VOLt\JJ~J:":_HALOGENATED,_~ ug/1

..,_[vinyl chloride. . . . • . . . . • • . • . . • . <: 1 " diChlorodifluoromethane........ <1.

methylene chloride............. <1 t:richlorofluoromethane... • • . • • . < 1 1 , 1-dich loroe thylene. • • • • . • . • . • <.1

· 1, 1-dichloroethane............. <1 *[. t::-an$-1,27dichloroethylen.e ...... <1 cl.s-1, 2-dl.chloroethylene.... . . . <1 chlorofo.m... . . . . . . . . . . . . . • . . . . <:1 1, 1, z;;;.trichlorotrifluoroethane. .<::1 1, 2-dichloroethane ••..•• :. . . • • . ~ 1 1,1,1-trichloroethane •.••.•.... ,c.l

b hl d '/ 1. car on tetrac . ori e ••••.•.• ~ •• -'-h----bromodichloromethane ........... Z 1

..,.. [1, 2-dichloropropane.. . . . . . • . . • • <0:1 " 2, 3-dichloropropane... . . • • • • • • • < l

trans-1, 3-dichloropropene ...... <.1 trichloroethylene.............. <3

[

1,1,2-trichloroethane ••.•••..•• -z-r-­·k c~lorod. ibromomethane .•..•..••... ~

Cl.s-1,3-dichloropropene •••••••• <1 * ·tb. rom. o ... ·form ••... · ...•... · ••.. •· .. · .••...•.. · • • • • • • < 1 l, 1, 1, 2-tetrachloroethane...... < 1 * tetrachlorethylene ••••••.•••••• <1

1,1,2,2•tetrachloroethane •.•.•. < 1 chlorobenzene.. . . . . . . . • • . . . . . • . <1 VOLATILE NON-HALOGENATED

[benzene •........••.........•••. __ _

* cis-1,2-dichloroethylene •••..•• ____ _ toluene . ....................... __ _ ethylbenzene ....•...........••• -~-p..;..xy lene . .......................... __ _

rm-xylene .........•..•.•••...... _,..---* L chlorobenzene ....••••..•••••.•. -~-

o -xylene . ...................... ___ _

* Reported value represents total.

LAB NO. 355722 TYPE SAMPLE Potable Water SAMPLING PT. 2ll.f 13 ]N-7058)

DATE SAMPLED 9/6/83 TIME SAMPLED RUN TIME (WEL-L~)----___,_ ____ _ COLLECTED BY CL 9q

PESTICIDES ug/1

lindane ................ --'-heptachlor ............. __ _ a.ldrin . ................... -.---heptachlor epoxide ..... __ ,_ die ldri.n .... · ..........•. -"--'--end.!;" in •••••. ••••••••••• __ _ o ,p'DDT ••.............. --­P-' P· •·oor- . . · ............•. ---methoxychlor .••...•.... __ .,.. toxaphene •....•.....•.. __ _ chlordane-. • ............. ~-,.---

.. -------------~----~ -----

H;ERalCIDES

2, 4-D . ................... ~--2, 4, 5-TP (silvex) •••••• __ _

OTHERS

Page 109: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

HOLZMACHER, McLENDON and MURRELL, P.C • CONSULTING ENGINEERS, ENVIRONMENTAL SCIENTISTS and PLANNERS

575 BROAD HOLLOW ROAD, MELVILLE. N.Y ~1747 • 516-694-{3040

CLIENT NAME AND ADDRESS

Garden City, Inc. Vill. of 351 Stewart Ave. Garden City/ NY 11530

VOlATILE HA.J:.iX;ENATED

Lab .. No. 466169 Type: Potb.a le Water Sampling Pt. Well # 13 LN- 70SB j

Date Sampled: 11/27/84 Collected By CL. ~9

ug/1

vinyl chloride ...............•..................•...•. < 1 dichlorcdifluoranethane ............................... < 1 rrethy lene chloride •..•..............................•• < ":l:· - · tr ichlorofl uoro:rethane ................................ < 1 1, 1-dichloroethy lene ..........•....................... < 1 , 1-dichloroethane ........•........................... < 1 trans-1,2-dichloroethylene ............................ < 1 cis-1,2-dichloroethylene .....................•........ < 1 chloroform ....•................. ~ ..................•.. < 1 1, 1,2-trichlorotrifluoroethane ..•................•..•. < 1 1, 2-dichloroethane .......................•............ < 1 1, 1, 1-trichloroethane ................................. < 7 carl::x:n tetrachloride ........•......................... < 1 brorrodichlororrethane .....•............................ < 1 1, 2-dichloropropane ........................•.........• < 1 2, J-dichloroprop2ne .................................•. < trans- 1 , J-dichloroprop2ne ............................. < trichloroethylene. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . < 1, 1, 2-trichloroethane ................................. < chlorcdibromamethane .................................. < cis- 1 , J-dichloroprop2ne ............................... < brorroform ............................................. < 1, 1 , 1 , 2-tetrachloroethane ............................. < tetrachloroethylene ................................... < 1, 1 r 2' 2-tetrachloroethane ..................... ·r . /· ... < 1 ·' '\

:;h~~~~~~=i ~~. ~~~;~~~~~. ~;t;,i: ...... fut~ .. i/ef;;rt: . :11; 12/84

~- '/ (~~ c don, P.E. raj Director

Melville, New Yor1< • Farmingdale, Now York • Riverhead, New Yorx

Page 110: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

HOLZMA.CHER, McLENDON and MURRELL, P.C • CONSULTING ENGINEERS, ENVIRONMENTAL SCIENTISTS and PLANNERS

575 BROAD HOLLOW ROAD. MELVILLE. N.Y. 11747 • 516-694-3040

CLIENr NAME AND ADDRESS

Garden City, Inc. Vill. of 351 Stewart Ave.

Lab. No. 557589 Type: Potable water

Garden City, NY 11530 Sarrpling pt, Well #13(N-7058) Taken @ 9:45 am Running: 12 Hrs. Date Sampled: 6/18/85 Collected By CL 99

VOIATILE Ii.AID8ENATED ~

viny 1 chloride •.•.••..••••.•.••••..••••.••....••..... dichlorcxiifloorarethane •••.•.•••...•........ •o• •••••••

rrw:::rtr~y lene chlor-ide ••••••• ; ...••••.••••••.. ~ ....•....• trichlorofluorarethane ••••••.••••••••....•....••....• 1 ,. 1-di.chloroethy lene .•••• · •.•.•••.•.••••.............. 1 , 1-dichloroethane. . . • . . . . . • ....•..•.•..•......••..•• trans-1 ,2-di.chloroethylene •..••••..•.•.•...•..••••.•• cis-1,2-dichloroethylene .•.•.•.•...•..•.............. chlorofonn ........•.......•..•.•......•..•.•......... 1,1,2-trichlorotrifluoroethane ••.....••...••......... 1 , 2...dichloroethane .•••.• , •.•.•••••..•................ ~, 1 , 1-trichloroethane ......•.......•.•..•......••.... carl:x:>n tetrachloride . ................................. . btan:xiichlorarethane •.••••...•••...•.••..••.....••..• 1, 2-di.chloropropane •.....•.•.••.••.•••.••••.....•••... 2, 3-di.chloropr~e . ................................. -trans-1, 3-di.chioropropene ••••••••..••••...•.......... trichloroethylene •....••••...•••....••••.....•.....•• 1, 1 ,2-trichloroethane .•••••..•••.•.•.•••••...•.•••..• chlorcxiib~thane ••...•••..••.......•........•.... cis-1 , 3-dichlorapropene •.•••..••....••••.••.•...•.••• brarofonn . .... ~ ... · .................................... . 1, 1, 1 , 2-tetrachloroethane •.•.•...•................... tetrachloroethylene ••..•••....•••..•••••............. 1, 1,2,2-tetrachloroethane •••...•••...•.•.......•.•.... chlorober1zene ••..•••...••••.....................•.... * Reported value represents total. Results rep::>rted rreet N.Y. S.

< 1 < l < 1 < 1 < 1 < 1 < 1 < l < 1 < 1 < 1 < 1 < 1 < 1

< 1 < 1 < 1

6 < 1 < 1 < 1 < 1 < 1

< 1 < 1 < 1

Drinking Water Limits. Date Rep::>rted: 6/24/85 '--~- X 4-~---!'/ ~ ' ~

S.ff. LEmdon, P. E. Utl::oratory Director

Page 111: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

---~~ . . ·// ..--~-- " " j/ !I.

(,~

HOLZMACHER, McLENDON and MURRELL, P.C • CONSULTING ENGINEERS, ENVIRONMENTAL SCIENTISTS and PLANNERS

575 BROAD HOLLOW ROAD. MELVILLE. N.Y. 11747 • 516-694-3040

Garden City, Inc. Vill. of 351 Stewart Ave. Garden City, NY 11530

Sample lab t-Jo. 655075 Date ColleCted: 5/6/86 Date ReCeived~ 5/6/86 Type: Potable Water Point: Well #13(N-7058) Collected By: CL 99

ANALYTICAL RESULTS FOR VOlATILE HAJ:.[X;ENATED ORGANICS

Ca:rpound vinyl chloride • • • • • • • • dichlorodifl UOr<l"!ethane. • • • • .. • • rethylene chloride . • • • • trichlorofluorarethane • • ••••. 1 , 1-dichloroethy lene • • 1, 1-dichloroethane • • • trans-1 ,2-dichloroethylene • cis-1,2-dichloroethylene • chlorofonn . . • • • • • • . 1, 1,2-tr:i.:chloro:trifluoroethane • • • l, 2--dichloroet:hane • • T , 1 , 1-trichloroethane. car:t.on tetrachloride oro:todichlorcmethane • 1 , 2-dichloroprop:me.

. .. . . ... .. .

2, 3-dichloropr<:Jpe.ne. • trans-1,3-dlchloropropene. trichloroethylene. , • • • l, 1,2-trichloroethane. • • chlorodibrcm:::m:rthme • • . • • • cis-1,3,..mchloropropene .• bran::rform. • • • · • • • • • • • • • 1,1,1,2-tetrachloroethane.

* S tetrachloroethylene. • • _. ~1,1,2,2-tetrachloroethane.

chlorobenzene. • . . • • • Results reported neet N.Y. S. Drinking Water Limits. Date Reported: 5/13/86

. . ..

. ..

. .

ug/1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 2 < 1 < 1 < 1 < 1 < 1

19 < 1 < 1 < 1 < 1 <

1

<

* Reported value :represents total.

*******************

.C. McLendon, P.E. Laboratory Director

Page 112: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

HOLZMACHER, McLENDON and MVRRELL, P.C. ..... .:....

H2M CORP. 500 BROAD HOLLOW ROAD, MELVILLE, NEW YORK 11747

TeL (51~) G94·3040

LABORATORY REPORT LAB IO 0~

CLIENT NAME AND ADDRESS LAB. NO. _..__,......---=-9"'-5 2::::.;8.,"0,._]'------TYPE WATER ________ ~p~o~t~a~b~l~e~----

Inc. Vill. of Garden City 351 Stewart Ave.

SAMPLING PT. t-1ell 14 (N-S ~39)

GArd~n City, N.Y. 11530

VOLATILE HALOGENATED

DATE SAM PLED ___ ..z.9_,_/-=l"""-8-<-/-'-7 9"'---..,--TIME SAMPLED~---------------­RU N T I ME ( WE LL }--.,:-::----=--::--...,._--COLLECTED BY Cl 99

PESTICIDES

lindane • • . . . . methylene chloride • 1,1-dichloroethylene 1,1-dicbloroetbane • t~ans~l,2-dichloroethylene ••• cis-1, 2~dichl,oroethy1ene • • • •

• .• • ...,....<-:-e:l:---• heptachlor. • • •. • . <1 aldrin • . . • • • • • • __ .._,._

*)chloroform • • • • • • • • • • (1, 1,2..,.trichlorotrifluoroethane ·1, 2,..d ichloroetbane • • • • • 1,1,1-trichloroethane ••••.• c~rbon tetrachloride •

. bromodichloromethane • • * rl ( 2-d ichloropropan.e. • • • • • • · 2¥ 3-dicblorop.ropene •••••••

trans-1,3-dichloropropene. • • • trichloroethylene ••••• 1, .1, 2-t r ichloroethane. • •

* chlorod ibromome thane • • • • . • cis-1, 3-dichloropropen.e. • • • •

* bromoform •••••••••••.•. l,l 1 1,2-tetrach1oroethane ••••

* tetrachloroethylene .••• 1,1,2,2-tetrachloroethane ••••

<1 heptachlor epoxide ••• __ _ ~1 dieldrin. • • • • . <1 endrin. • • • • • • < 1 o, p 1 DDT • • • . ·---<1 p,p 1 DDT •• •

·<I methoxychlor •. 1 toxaphene • . .. ---

<I chlordane • • {1 <1 <1 'l <1 <1 <1 <1 <1

'<1 <I

--------------~-· . ·--~~ HERBICiDES

2,4-P ~ • , •••• 2,4,5-TP (silvex) ~

OTHERS

. . -~-1l0LATILE NON-RALOGENATED

benzene. toluene. • •

. . *[m-xyl .. ene ••••••

p-xylene o-xylene ,

--~~----~----~ . . . -----

. ... ---. ... --- --------~-------· .. -----

------------~--------~-· . . . RUN NO. (S) 1897 *Reported value represents. total

Results reported ____ ~mme~e~t._ ________ _ N. Y •. S. Drinking water Standards.

::

Page 113: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

HOLZMACHER, MclENDON and MURRELL, P.C.

H2M CORP. LABORATORY

#'REPORT . '!575 BROAD HOLLOW ROAD, MELVILLE, NEW YORK t 1747

Tel.< !516 > 6:9.4·3040 .

CLIENT NAME ANP ~ODRESS

Inc. Village of Garden City ~

VOLATILE HALOGENATED

LAB tO 03

LAB. NO.. 87 4484 TYPE WATER Potable SAMPLING PT •. Well It 14 (N-8339}

DATE SAMPL~D. 11/17/BO TIME SAMPLED------~------~-­R:UN 1' IME CWE,:LL )_ . ..,.....,,..._~.,--_,......_,...,...,.,._ COLLECTED BY Ct. 99.

PESTICIDES

li n¢Ja ne • • • • • • • • _ _,. .... methylen• chlorid¢ • • • • • • • <I 1~.1:-diqhlorbethylene • • .. • <1 1, 1-dichlqr.oethane • • • • • • •. <l tra,ns-1, 2..,dichl.oroethyler:te .. • • < 1 cis.-.1, 2-dichlP1:0ethylene ••••. <1

. heptachlor. • • • • • • __ _ · aldr: in. • • • • • • •. • ....,...............,,_

·*-[cnJ.orot'onn -~ ·• • • • • • • •• • • <1 · lrl,2.,.trichlorotrifluoroet..han~ . 31--·.

·1, 2-di.Ghloroethane •••• , ~ • .<1 1,l,l-trichloroethane •. , •••• <2 "" carbon tetr:qChlor~de • . •• · 1

. bromodichloromethaoe • <1 · •fl,.27d~chlo;-opropane •••• ~ •• <l

• 2,3,.,dlchloropropene. • • • • <l tr,ans.,l,J-dichlol:opr.<;:lpEme ••• ~ <l trichloroethylene. • . · ••• ~ • <1 ~1,1,2-trich,loroethane ••••• , <1 chl orod i ht"omome thane ~ ~ • • • • .· < 1 · cis-l,J~dichloropropene ••..••. ')1 ·

·;· t:n::omof.onn •• ·• • • • • • • • <l 1.,.1 ~ 1, 2-tetrach lproetharie ~ .. · , • o

* ~~~ra~hlor:6ethylene:. • • • . • • 1 1, l, 2, 2.- tet.rach lorqe th.;an.e. • • .. ..,......,......,..-

vin~l cbJoride , •••. ·· <1 .. · ~J probenzene . ·· · ·· · • • • • <r- · 'lOLA TILE NON -HALO:GENA'l'ED

t:>eoze ne! . t.olue ne. , ~ • •

·f;=~~i:~: . . . . : : : . .• ' .

.. ' ~ . . -,.,..,...,....,.-· q'""xyl.ene • . . . . . . .

,"!: • ,., •

heptachlor e:poxiqe. • • -,---dield.ri n. • • • • • • • __ _ end r i n ;· • . ~ · • .. •. • _,_____._ o, pI DDT . • • ,. • • • • ~-~....,...,..

p, p 'DDT • • • • • • • ~ _....,..-,...,...,... methoxychlor. • • . • • _ ___,__ toxaphene· • • • , thlot;da.ne • • • , • • • _.,........_

HERBICIDES

2,4-1) . ~ ..... ._ • .. \', _,.....,._.,.. 2,4,5-TP.(sUv-e~} ••• ..,.....,.,___,._.,_

OTHERS

_,....,,_..._..__,........ ______ . . . ,.....,.._.,..

...,.,..--------.,..---'-- . . ~ ..,..,...._...,.._

-..,------,-'-----..,.,._ . . . ---

RUN NO,(.$) *Re}?Orted value represents total

Resu 1 ts reported . . meet N.Y.s. Drinking Water Standards.

DATE REPORTED 12 15 8

Page 114: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

~ HOLZMACHER, McLINDON 8nd MURRELL. P.C.

~ H2MCORP. LABORATORY

REPORT S7!5 BROAD HOLLOW ftOAD. MELVILI..K, NEW YORK 1 17.&7

Tel. CS18l 8M·30.11.0 LA! tO 03

CLIENT NAME AN~r( AOOIIfESS

Garden City, Village of 351 Stewart Avenue Garden City; NY 11530

VOLATILE HALOGENATED

methylene chloride • 1,1-dichloroethylene •••••• 1,1-dichloroethane • trans-1,2-dichloroethylene ••• cis-1, 2-dichloroethylene ••••

·* [chloroform • . • • • • • • • • 1,1,2-trichlorotrifluoroethane 1,2-dichloroethane ••••••• 1,1,1-trichloroethane .••••• carbon tetrachloride • • • • bromodichloromethane • • • •

* [1, 2-d ichloropropane. • 2,3-d ichloropropene. • • • ••• trans-1,3-dichloropropene •••• trichloroethylene •••••• 1,1,2-trichloroethane •••

* ch1orodibromomethane •• cis-1, 3-dich1oropropene ••••.

* bromoform. • • • • • • • • 1,1,1,2-tetrachloroethane.

* tetrachloroethylene ••••

~

<1 <1 <1 <i <1

·-·l <1 <1 <1

3 <1 <1 <;1

I <1 <1 <1 <1 <1 1

1,1,2,2-tetrachloroethane •••• ____ _ · Vinylchloride • • • • Dichlorodifluoro methane •.• Chlorobenzene .•••

<1 <l <1

LAB. NO • ....!1!oi.5u.5~>.5~3+1_,....,r--;;;-""L':"::::--~­. TYPE WATERPotable Wa tar

SAMPLING PT. well t14 (N-8339) .,.,.....£ -~ ~d'7""- .L~

DATE SAMPLED_..::1:..::1:..c..(.;;::.1::....0/c......;8::.:1=-----TIME SAMPLED ________________ __ RUN TIME (WELL),__,.,._ ____ _ COLLECTED BY Ct=99

PESTICIDES

1 i nda ne • • • • • · • • • --,....-. heptachlor. • • • • • • __ _

aldrin ••••••• heptachlor epoxide •• ·----dieldrin. • • • endrin •••• . . . o, p' DDT • • • • • • • • ---p,p'DDT ••• methoxychlor •• toxaphene • • • • • __ _ chlordane • • • •

-----------------· . ·-----HERBICIDES

2 I 4 -D • • • 2,4,5-TP (silvex) •

OTHERS

------~----------· . ·-----'./l'JLATILE NON-HALOGENATED ---

I'Jenzene. • • . . . . . ... ---toluene.

•[m-xylene • • • • p-xylene • • • • • a-xylene • • • • • • • •

..... ---..... ---

-------------------------· . . . t! • • •

)'

-----------------·. ·---------~-----------· .. -----------------------· .. ----------------------· .. ----------------------- . . . -----

. . . RUN NO. (S) *Reported value represents total

Results reported __ ~M~e~e~t ___________ ___ N.Y.S. Drinking Water Standards.

DATE REPORTED

Page 115: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

HOLZMACHER, Mct.ENDON •nd MURRELL. P.C.

H2M CORP. LABORATORY

REPORT ~~1{g ~7:5 BROAD HOLLOW ROAD, MELVILLE, NEW YORK 11747

Tel. <!SUS) &9.-·3040 LAB TO 0:5 Jo(FC/ff~

CLIENT NAME ANO ADDRESS

Inc. Village of Garden City 351 Stewart Ave. Garden City, NY 11530

VOLATILE HALOGENATED !!9.L!. methylene ~hloride • • • • <1 1, 1-dichlo'roethylene • • • • • • <1 1,1-dichloroethane • • • • • • • <I · trans.,...l,2-dichloroethylene • <1 cis-1, 2-dichlot:oethylene • • • • <1

· * fchlor9forin • • • • • • • • • • • <1 1, 1,2-trichlorotrifluoroethane <1 ·1, 2-d.ichloroethane • • <l l, 1 1 1-t r ichl oroethane. • • • • • <1 carbon tet.rachloride • 3 hromodichlorane thane • • • · • <1

* fl, 2-dichlo~opro.pane. • • • • • • <1 2, 3""d ichloroplfopene. • • • • <1 trans-1, 3-dichl oropropene. <1 . tr ichloroe~tbylene. • • • • <1 1,1, 2-tricploroethane. • • • • • <1

* chlorodibrbmomethane • • • • • • <1 cis-1,3-dichloropropene. • • • • <1

* bromoform.. • • • • • ·• • • <l 1,1,1,2-tetrachloroethane. • • • <1 _

* tettachloroethylEme. • • • . • • • _.....:1=--1, 1, 2 (,.2-tetrachlo-roethane. • • • __ _

VinyJ.chlori<l:t;} · , • • • • <1 Cblorol)E;!nz~ne · • • • • <1

•JOLATILE NON-HALOGENATED

oenze ne. • toluene. •

•[m-xylene • p-xylene o-xylene

. ~ . . . . . . . . . . . _ ___, ___ ....._ _______ ... ·---

\ ... ---

LAB. NO. __::2:.25..L59z.7.t..:.2~-:-:----­TYPE WATER Potable Water SAMPLING PT. ':ell ~14 fN...,8339)

DA.TE SAMPLED 10/5/82 TIME SAMPLED ____ ~------------RUN TIME (WELL)._"""""_,~----COLLECTED BY CL-99

PESTICIDES

lindane • • ·• • • • heptachlor. • • • • aldrin ••••••• heptachlor epoxide. dieldrin. • • •

. . ---. . ---. ·---

. ·---endrin. • • • • • ·--------o·,.p 'DDT • • • • • • • • --­p, p ' DDT • • • • • • • • ---methoxychlor. • • • toxaphene • chlordane • • • • • • • __ _

-..--------------- . . . -....---HERBICIDES

2,4-D ••••••• . ·---2,4,5-TP (silvex) •

OTHERS

-------------~--· . ·------------....---------· . ·~·--------------------· . ·---------~---------------· . ·-------~---------------· . ·--------------------· . ·-----------------------·. ·---------------. . . -------------. . . ---

RUN NO~(S) *Reported value represents total

Results reported ______ ME_ET ______________ _ N.Y. S. Drinking Water Standards.

t .

Page 116: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

--.J~ ~~ HOLZMACHER, MclENDON and MURRELL, P.C. II I..;VT1l H2M CORP, LABORATORY

REPORT 575 BROAD HOlLOW ROAD. MELVILLE. NEW YORK 11747-Tel. ($16} 694•3040

CLIENT NAME AND ADDRESS.

Garden City, Inc., Village of 351 Stewart Avenue Garden City, ~~ 11530

VOLATILE HALOG-ENATED ug/1

.. ~[vinyl chloride........ . • . . . . . . . <1 ". dichlorodifluorc:'methane........ <1

methylene chlon.de............. <1 trichlorofluoromethane... . . . . . . <1 1, 1-dichloroethylene..... . . . • • • <I 1,1-dichloroethane ...•.•...•.•.. <1

. [t:rans-1, 2-di.chloroethylene... • • <1 w[eis-1,2-dichloroethylene •.....• <1

chloroform •..•........ ~ ......... <1 1,1, 2-t;.'richloro-trifluoroethane. <1 1, 2-diehloroethane.. . . • . . . • . • . . <1 1, 1,1-trichloroethane. . . . . . . • . • <1 ca,rbon tetrachloride.. . • . . . . • . • <1 bromodiehloromethane ............ --2-

~-: [1 y 2:d_-_ ~chloropr_ opan_ e. . . . • . . • • • • . <1 2:, 3 dJ.chloropropane. • . . • . • • • • . • <1 trans-1 ,3-dichloropropene...... <1 trichloroethylene........ . . . • • • . 1

[

1 ,l, 2- trichloroethane. . . • • . . • • • <1 ,~ c~lor_ odib:=-omomethane. · .... _.... . . ·<1

CLs-1,3-dLchloropropene .••••..• <1

* tbrom.of orm .. _ .. ___ · .. _ .. __ ....... _.. .. • • • • • • <1 1,1,1,2-tetrachloroethane •..... <1 ~ tetrachloroet~ylene ..........• 1 ~ 1,1, 2, 2-tetrachloroethane •...•. -.c-:-­

-:-ch lorobenzene. . . . . . . . . . . . . . . . . . <1

VOLATI.LE .. NON--HALOGENATED

[benzene .............•.. • .......• __ _

* cis-1, 2-dichloroethylene ....... __ _ toluene ........................• ~--e thy lbenzene ....... , ........... ___ _ p-xylene ....................... __ _

]m-xyle·ne ....................... __ _ * l chlorobenzene .................. __ _

a-xylene ....................... __ _

* Reported value represents total.

LAB NO. 357832 TYPE SAMPLE Potable Water SAMPLING PT. Well f 14 (N..,.83)9) ---DATE SAMPLED 11/~/83 TIME SAMPLED_:--------­RUN TIME (WELL)_-;::-:;;---::::-:;:::---...,.._..~ COLLECTED BY CL 99

PESTICIDES ug/l

lindane ....... - ....... ~ . __ _ heptachlor ............. __ _ aldr:in .............. ·. · · · __ _ heptachlor epoxide ..... __ _ dieldrin •...•.......... __ _ endrin ................. __ _ o, p' DDT ••••••••••••.•••. _ _.___._ p, p' DDT •••••• • • • • • · • • • • --'---methoxychlor ........... ___ _ toxaphene •••.•..•. ~ ..• ~ • __ _ chlordane ...... • ....... --'--

HERB ICII.)E$

2 , 4--D • • • . • • . • • • • . • • . • . . -.,.---2,4,5-TP (silvex) .... ~ . __ _

OTHERS

---------------------------···-----

Resutts reported ___ M_E_E_T ______ __ N.Y.S. Drinking Water Standards.

11/3/83 qATE REPORTED

Page 117: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

HOLZMACHER, MclENDON and MURREll., P.C • CONSULnNG ENGINEERS, ENVIRONMENTAL SCIENnSTS and PLANNERS

575 BROAD HOLLOW ROAD, MELVILLE, N.Y. 11747 • 516-694-3040

CLIENr NAME AND ADDRESS

Garden City, Inc. Vill. of 351 Stewart Avenue

Lab. No. 465477 Type: Potable Water

Garden City, NY 11530 Sampling Ft. Well H14(N-8339)

Date Sampled: 11/7/84 Collected By CL 99

ug/1

vinyl chloride .......•.......................•.....•... dichlorodifluoramethane ...•..•.............•••..•••.... ~thylene chloride .............•................•...... trichlorofluoramethane ................................. . -1, 1-dichloroethylene ........ : ......................•... 1, 1-didlloroethane .....•...•....•.•........•.•.......... trans-1 , 2-dichloroethylene ...•........•.....•.....•..... cis-1 ,2-dichloroethylene .....• _, ..•..........••.......... chlorofonn .....•.....•.......••.•••.....•............. 1, 1,2-trichlorotrifluoroethane ..............•.......... 1, 2-dichloroethane ...•....•.......................••... 1, 1 , !-trichloroethane .....•........................•... carbon tetrachloride. . . . . . . ..........••...........••... brart:ldichlorarethane ......•..........•.....•.•...•••... 1, 2-dichloropropane .•.....•..........................•. 2 , 3-dichloropropene •.•....•.......•...•......•..•..•... trans-1 , 3-dichloropropene .•.................•......••.. trichloroethylene. , .......•............................ 1,1 ,2-trichloroethane ................................. . d1lorodibr(li'C(IJ2thane. . . . . . . .•.....•................•... cis-1, 3-dichloropropene ................ ·r ...... ....•... brarof onn. . . . . . . . . . . . • . . . . . . . . . . . . . . . . . .' . . . . • . . . . . . • . • . 1, 1, 1,2-tetrachloroethane ••....•..••...•....•..........

* S tetrachloroethylene ...•...•.............. ;~·:;:.; ......... . Z. 1, 1,2,2-tetrachloroethane ...•.•......•.•.........•••..

chlorobenzene. . • . . . . • . . . . . • . . . • . • . . . . . . . . . .......•.•...

< 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1

1 < 1 < 1 < 2

5 < 1 < 1 < 1 < 1

1 < 1 < l < 1 < 1 < 1

12

< 1

* Reported value represents total. Date Reported 11/25/84 Results reported meet N.Y.S. Drinking water Limits.

Page 118: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

HOLZMACHER, McLENDON and MURRELL, P.C • CONSULTING ENGINEERS, ENVIRONMENTAL SCIENTISTS and PLANNERS

575 6ROAD HOLLOW ROAD, MELVILLE, N.Y. 11747 • 516-694-3040

CLIENr NAME AND ADDRESS

Garden City, Inc. Vill. of 351 Stewart 'Ave.

Lab. No. 556414 Typ::: Potable Water

Garden City, NY 11530 Sarrpling Pt. Well #14(N-8339) Taken @ 9 : 00 am Running: 90 mi.ns • Date Sampled: 5/21/85 Collected By CL 99

vinyl chlorj_de . .......................................... . clichlorod.ifluoranethane .....•..•..•..•.•••....•...... rrethylene chloride .••••.•.•••.•....•.•..•..••.••....•.• trichlorofluoranet.hane ....••...•..•..• ~ ............. . 1 , 1-dichloroethylene .......•............••.........•. 1 , 1-dichloroethane •..•..............•........•....... trans-1,2-dichloroethylene .•........•................ cis-1, 2-di.chloroethylene ...•.....•••...•........•.••• d1.l.orofonn. .. ....•.. , ..•.•.•..•.. • ....................... . 1,1,2-trichlorotrifluoroethane •...•.•••..•••..•....•• 1, 2 -dichloroethane ...•.....•.•......•.... , ....•....•. 1 , 1 , 1-trichloroethane ....•.•..... ~ ....•.............. carbon tetrachloride .•........... : ..•...•............ bran:xlichloranethane .......•......................... l , 2-dichloropropane •.......•.•.....•......•....•.••.• 2, 3-cli:chloropropene .••.••..••••...•••.•••.....••..••. trans-1 , 3-dichloropropene ....••.....•.•••....•••••••• tr id1.l.oroethy lene ...•••.•..••.......•• , ...........•.. 1, 1 ,2-trichloroethane •.•...•. , •...•••..•........•...•• chlorcdi.br~thane ................................. . cis~l,3-dichloropropene ••..•••••.•.•••.•.••...••••.•• br'arofonn . ................. " . . e. • ,. • ., .... 1:1 .- ..................... .

1 , 1 ~ 1 , 2-tetrachloroethane ............•........•...••. * <;tetrachloroethylene ..•.•...••....••..•...•......•....

G1, 1 ,2,2-tetrachloroethane •....... ~ .••..•.....•....... chlorobenzene .................•........•.......•.•..• * Repxted value represents total.

Results reported meet N.Y. s. Drinking Water Limits.

Date Reported: 6/4/85

< 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1

4 < 1 < l < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1

1

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_q~ ~ratory 01-rector

Melville, Ne,.. Yor1< • Farmlngd>lle, No., Yon< • Fll"flrhooo. New York

Page 119: EXPERT REPORT ON THE INTERPRETATION OF THE ISOTOPIC DATA ... · Report on the Interpretation of the Isotopic Data from the Fulton Ave. site, Garden City Park, Long Island, New York

HOLZMACHER, McLENDON and MURRELL, P.C • CONSULTING ENGINEERS, ENVIRONMENTAL SCIENTISTS and PLANNERS

575 BROAD HOLLOW ROAD. MELVILLE. N.Y. 11747 • 516-694-3040

Garden City, Inc. Vill. of 351 Stewart Ave. Garden City, NY 11530

Sample Lab No. 655606 Date Collected: 5/20/86 Date Received: 5/20/86 T-j'pe: Potable Water - Annual well Point: Well # 14 Collected By: CL 99

ANALJ:'TICAL RESULTS FOR VOlATILE HAIJ:X;ENATED ORGANICS

Ccrrp::?und viny 1 chloride . . . . . dichlorodifluoramethane. nethylene chloride . • ••• trichlorofluor~~e . 1 , 1-dichlorc:.ethy iene • • 1 , 1-dichlorc:.e:thane • • . trans-1,2-dichloroethylene . cis-1 r 2-dichlorcet.i).ylene • • chloroform . . • • • • . . • 1,1,2-trichlorotrifluoroethane • 1 , 2-dichloroethal1e • • • • 1,1,1-trichloroethane •. carbon tetrachloride • brcm:xlichlorcmat.ha.D.e 1 ,2-dichlorcprcpane. 2,3-dichlorcprcpene. trans-1 , 3-dichlaropropene. • trichlorc:.ethy 1 ene. • . • • • • . 1,1,2-trichloroethane •. chlorc:dibraoctrethane • • • cis-l , 3-dichloroprcJf?Eme. • • • • • • b:ro:rofo:an. . . • . • . • 1,1,1,2-tetrachloroethane .••..••••

* 5 tetrachloroethylene. • • . ~1,1,2,2-tetrachloroe~~.

chlorobenzene. . . . • . . . Results reported meet N.Y.S. Drinking Water Limits . Date Reported: 5/27/86

ug/1 < 1 < 1 < 1 < 1 < 1 < 1 < l < 1 < 1 < 1 < 1 < 3

6 < 1 < 1 < 1 < 1

6 < 1 < 1 < 1 < 1 < 1

3

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* Reported value represents total.

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