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  • 8/3/2019 FOLIO CHEMISTRY 2010 (2)

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    Name Mathiarasi Bernabas

    Class 4 Amanah

    Title

    Manufactured Substances in Industry

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    Content Page

    (A) Sulphuric acid

    Manufacture of sulphuric acid 1 3

    Properties of sulphuric acid 4

    The uses of sulphuric acid 5 7

    Sulphur dioxide and environmental pollution 8 9

    (B) Ammonia and its salt

    Manufacture of ammonia 10 11

    Properties of ammonia 12

    The uses and preparation of ammonia 13

    (C) Alloys

    Arrangement of atoms in metals 14

    What are alloys? 15 Composition,properties and uses of alloys 16

    (D) Synthetic polymers

    What are polymers? 17

    Properties of polymers 18

    Monomer in synthetic polymer 19

    Example and uses of synthetic polymers 20

    (E) Glass and ceramics

    Glass-Component and properties of glass 21

    Example and uses of glass 22

    Ceramics-Component and properties of ceramics 23 Example and uses of ceramics 24

    (F) Composite materials

    What are composite materials 25

    Example and their uses 26

    Conclusion of topic 27

    Acknowledgement 28

    References 29

    2

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    (A) Sulphuric acid

    Manufacture of sulphuric acid

    Contact process produces more than 90% of the world sulphuric acid.

    Raw materials used for the manufacture of sulphuric acid :-

    (i) sulphur

    (ii) air(iii) water.

    Contact process consists of 3 stages:

    ~ Production of sulphur dioxide

    ~ Conversion of sulphur dioxide is sulphur trioxide.~ Production of sulphuric acid

    Stage I: Production of sulphur dioxide

    (a)Sulphur is burnt in air to produce sulphur dioxide.

    S(s) + O2(g) SO2(g)

    (b)Burning of metal sulphides such as zinc sulphide and lead sulphide also produces sulphur

    dioxide.

    2ZnS(s) + 3O2(g) 2SO2(g) + 2ZnO(s)

    2PbS(s) + 3O2(g) 2SO2(g) + 2PbO(s)

    (c)The sulphur dioxide is then mixed with excess air.The mixture is dried and purified to removeimpurities such as arsenic compounds.

    (d)Arsenic compounds found in sulphur will poison the catalyst in the converter, making the

    catalyst ineffective.

    Stage II: Conversion of sulphur dioxide to sulphur trioxide

    (a)The mixture of sulphur dioxide and excess oxygen is passed through a converter.The sulphur

    dioxide is oxidised to sulphur trioxide.

    2SO2(g) + O2(g) 2SO3(g)

    (b)Optimum conditions used are as follows.

    (i) Temperature : 450C

    (ii) Pressure : 1 atmosphere

    (iii) Catalyst : Vanadium(V) oxide,V2O5

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    (c)About 97% conversion occurs under these optimum conditions.

    Stage III : Production of sulphuric acid

    (a) The sulphur trioxide is first dissolved in concentrated sulphuric acid to form a productcalled oleum, H2S2O7

    SO3(g) + H2SO4(aq) H2S2O7(l)

    (b) Sulphur trioxide is not dissolved in water to form sulphuric acid.This is because reaction

    between sulphur trioxide and water is very vigorous and produces a large amount of

    heat.The reaction causes the production of a large cloud of sulphuric acid mist.The mist iscorrosive, pollutes the air and is difficult to condense.

    (c) The oleum is then diluted with water to produce concentrated sulphuric acid of about98%.

    H2S2O7(l) + H2O(l) 2H2SO4(aq)

    Flow chart of Contact process.

    burns in air

    O2V2O5,450C, 1 atm

    concentrated H2SO4

    water

    water

    Figure 1 : The manufacture of sulphuric acid through the Contact process

    5

    Sulphuric acid, H2SO4 Oleum, H2S2O7

    Sulphur trioxide, SO3

    Sulphur dioxide,SO2

    Sulphur

    Sulphur dioxide, SO2

    Sulphuric acid, H2SO4

    Oleum,H2S2O7

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    The manufacture of sulphuric acid, H2SO4 in the Contact Process

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    Oily

    liquid

    Highlycorrosive

    Non-

    volatile

    acid

    Viscouscolourless

    liquid

    Dense

    Soluble inwater

    Density

    1.83g cm-3

    Diprotic

    acid

    Boilingpoint

    340oC

    Melting

    point

    10oC

    Molar

    mass

    98 g mol-1

    ChemicalFormula:

    H2SO4

    Propertiesof

    sulphuricacid

    http://www.answers.com/topic/water-annabelle-chvostek-albumhttp://www.answers.com/topic/water-annabelle-chvostek-album
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    Uses of sulphuric acid

    There are many fertilizers that can be made of sulphuric acid. Some of them are:

    a) Calcium hydrogen phosphate (superphosphate)

    b) Ammonium sulphate

    c) Potassium sulphate

    Sulphuric acid is used as:

    to manufacture fertilisers

    to manufacture paint pigment

    to manufacture detergents

    to manufacture synthetic fibre

    to clean metals

    to manufacture plastics

    as an electrolyte in car batteries

    to manufacture other chemicals

    10

    2 H2SO4

    (aq) + Ca3(PO

    4)

    2(s)

    Ca(H

    2PO

    4)

    2(aq)+ 2CaSO

    4(s)

    sulphuric acid + tricalcium phosphate calcium hydrogen phosphate

    H2SO4(aq) +2NH

    3(aq) (NH

    4)

    2SO

    4(aq)

    sulphuric acid + aqueous ammonia ammonium sulphate

    H2SO4(aq) +2KOH

    (aq) K2SO4(aq) + 2H2O(l)

    sulphuric acid + potassium hydroxide solution Potassium sulphate

    http://www.answers.com/topic/hydrogenhttp://www.answers.com/topic/sulfurhttp://www.answers.com/topic/oxygenhttp://www.answers.com/topic/hydrogenhttp://www.answers.com/topic/sulfurhttp://www.answers.com/topic/oxygenhttp://www.answers.com/topic/hydrogenhttp://www.answers.com/topic/sulfurhttp://www.answers.com/topic/oxygenhttp://www.answers.com/topic/oxygenhttp://www.answers.com/topic/sulfurhttp://www.answers.com/topic/hydrogenhttp://www.answers.com/topic/oxygenhttp://www.answers.com/topic/sulfurhttp://www.answers.com/topic/hydrogenhttp://www.answers.com/topic/oxygenhttp://www.answers.com/topic/sulfurhttp://www.answers.com/topic/hydrogen
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    1) To manufacture paint pigments

    The white pigment in paint is usually barium sulphate, BaSO4. The neutralization of

    sulphuric acid and barium hydroxide produces barium sulphate.

    2) To manufacture detergents

    Sulphuric acid reacts with by-products of oil refining to form sulphonic acid.Neutralising the sulphonic acid with an alkali produces detergents.

    3) To manufacture synthetic fibres

    Synthetic fibres are polymers ( long chain molecules). Rayon is an example of a synthetic

    fibre that is produced by the reaction of sulphuric acid eith cellulose threads soaked inalkaline solution.

    4) Cleaning metals

    Before electroplating,sulphuric acid is used for cleaning metals to remove the surface

    oxides.

    5) Other chemicals

    Sulphuric acid is used as other chemicals like pharmaceuticals,insectides, tartaric acidand explosive.

    6) The uses of sulphuric acid in school laboratories are:

    a. As a strong acid

    b. As a drying or dehydrating agent

    c. As an oxidizing agent

    d. As a sulphonating agent

    e. As a catalyst

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    H2SO4(aq) + Ba(OH)2

    (aq) BaSO4(s) + 2H2O(l)

    sulphuric acid + barium hydroxide solution Barium sulphate + water

    http://www.answers.com/topic/hydrogenhttp://www.answers.com/topic/sulfurhttp://www.answers.com/topic/oxygenhttp://www.answers.com/topic/oxygenhttp://www.answers.com/topic/sulfurhttp://www.answers.com/topic/hydrogen
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    Manufacture of car batteries Manufacture of detergents Manufacture of fertilisers

    Manufacture of paints Manufacture of plastic items Manufacture of pesticides

    Figure 2 : Uses of sulphuric acid

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    Metallurgy

    Fertilisers

    Paint pigment

    Detergents

    Synthetic

    Fibre

    Plastics

    Electrolytes

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    Sulphur dioxide and environmental pollution

    1) Sulphur dioxide is released through:-

    (a) Burning of sulphur during Contact process(b) Extraction of some metals from their sulphides ores

    (c) Burning of coals or fuels with high sulphur content

    2) Acid rain occurs when there is sulphurous acid,sulphuric acid and nitric acid in the rain.

    These strong acids will cause the pH of rain to fall between 2.4 and 5.0

    3) Sulphur dioxide accounts for most of the acid rain problems.

    (a) When sulphur dioxide dissolves in rainwater,sulphurous acid is formed

    SO2(g) + H2O (l) H2SO3(aq)(b) Sulphur dioxide can react with oxygen and water to form sulphuric acid

    2SO2(g) + O2(g) + 2H2O(l) 2H2SO4(aq)

    Ways to control and reduce the effects of acid rain:

    Use low-sulphur fuels

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    Add calcium oxide(lime), CaO; calcium hydroxide,Ca(OH)2 and powdered llimestone

    CaCO3 into the acidic lake or river to neutralize the acids present

    CaO(s) + 2H (aq) Ca (aq) +H2O(l)

    Ca(OH)2(s) + 2H (aq) Ca (aq) + 2H2O(l)

    CaCO3(s) + 2H (aq) Ca (aq) + CO2(g) + H2O(l)

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    Environmental problems cause by acid rain

    corrodes buildings,monuments and statues

    calcium carbonate in the marble reacts with H2SO4

    from the rain toform calcium sulphate.CaCO3(s) + H2SO4(aq) CaSO4(s) + CO2(g) +

    H2O(l)

    corrodes metallic structureThe iron from the steel bridges reacts with sulphuric

    acid to form iron(II) sulphate.

    Fe(s) + H2SO4(aq) FeSO4(aq) + H2(g)

    increase the acidity of water

    Acid rain disturbs the ecosystem

    Fish and other aquatic organisms which cannot live in

    acidic water may die.

    increase the acidity of the soil

    plants cannot grow well in acidic soilreaction of sulphuric acid with aluminium compounds

    in the soil forms aluminium sulphate which can

    damage the roots of trees.

    leaches minerals and nutrients in the soil.

    acid react with minerals in the soil to form double

    salts.dissolved salts carried by the rainwater to river.

    plants lack of essential nutrients for growth.

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    (B) Ammonia and its salts

    Manufacture of ammonia in industry

    Ammonia is manufactured in industries through Haber process.

    Raw materials for the Haber process are(i)hydrogen

    (ii)nitrogen

    Nitrogen gas is obtained from the fractional distillation of liquid air.

    Hydrogen gas is obtained by:(i)Reaction between methane from natural gas and steam

    CH4(g) + 2H2O(l) 4H2(g) + CO2(g)

    (ii)The reaction between heated coke and steam

    C(s) + H2O(l) H2(g) + CO(g)

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    The manufacture of ammonia,NH3 through the Haber Process.

    Nitrogen and hydrogen are mixed according to the ratio 1 mole N2 : 3 moles H2.

    The mixture is compressed to 200 atm and heated to a temperature of about 450C

    The mixture is then passed through layers of heated iron catalyst in a reactor.Ammonia is

    produced.

    N2(g) + 3H2(g) 2NH3(g)The reaction is reversible and the production of ammonia gives out heat.The high pressure

    and iron catalyst speed up the rate of reaction.

    The ammonia gas produced is liquefied ans separated to get a better yield.

    The unreacted nitrogen and hydrogen are recycled and passed back into the reactor togetherwith the new source of nitrogen and hydrogen.About 98% of nitrogen and hydrogen are

    converted into ammonia.

    Ammonium fertilisers

    Plants need nutrients like nitrogen, phosphorus, potassium and calcium to grow.

    Nitrogen-make proteins in stalks and leaves

    Nitrogen is absorbed by plants in the form of soluble nitrate ions, NO3-

    Ammonium fertilisers contain ammonium ions.In the soil, the ammonium ions are converted

    to nitrate ions by bacteria

    Examples of ammonium fertilisers:

    (a) Ammonium nitrate, NH4NO3

    (b) Ammonium sulphate, (NH4)2SO4

    (c) Ammonium phosphate, (NH4)2HPO4

    (d) Urea,CO(NH2)2

    Fertilisers that contain a high percentage of nitrogen are more effective.

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    Ammonium fertilisers can be prepared by reactions between ammonia solution and acids.

    Properties of ammonia

    alkaline gas

    very soluble in

    water

    less dense than

    air

    pungent smell

    colourless gas

    Physical

    properties ofammonia

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    Chemical reaction of ammonia:(a) Reacting as a base

    Ammonia ionises partially in water and therefore is a weak base.

    NH3(g) + H2O(l) NH4 (aq) + OH (aq)

    Ammonia undergoes neutralisation with acids to form ammonium salts.

    Ammonia + acid ammonium salt

    (b) Reacting with aqueous metal ions

    Ammonia solution can precipitate some metal hydroxides from their aqueous salt

    solutions.The metal ions combine with the hydroxide ions from aqueous ammonia to

    produce insoluble metal hydroxides : Mn (aq) + nOH (aq) M(OH)n(s)

    Uses of ammonia

    To make fertilisers

    - provide plants the nitrogen they need to grow

    - these fertilisers are ammonium salts obtained from the neutralization of ammonia with

    different acids. Examples:(a) Ammonium phosphate

    - reaction of ammonia with phosphoric acid produces ammonium phosphatesNH3(aq) + H3PO(aq) NH4H2PO4(aq)

    2 NH3(aq) + H3PO(aq) (NH4)2HPO4(aq)

    - good fertilisers because they provide two important nutrients,phosphorus and

    nitrogen.

    (b) Ammonium nitrate

    - ammonia is neutralised by nitric acid,ammonium nitrate is formed

    NH3(aq) + HNO3(aq) NH4NO3(aq)

    (c) Ammonium sulphate

    - ammonia is neutralised by sulphuric acid2NH3(aq) + H2SO4(aq) (NH4)2SO4(aq)

    (d) Urea

    - At a temperature of 200C and a high pressure of 200 atm, ammonia reacts with

    carbon dioxide to produce urea.

    2NH3(g) + CO2(g) CO(NH2)2(s) + H2O(l)

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    - used as a raw material for the manufacture of nitric acid in the Ostwad process.

    - Liquid ammonia used as cooling agent- used as an alkali to prevent the coagulation of latex

    - Ammonia salts is used as smelling salts to revive people who have fainted

    Preparation of ammonia

    The chief commercial method of producing ammonia is by theHaber-Bosch process, whichinvolves the direct reaction of elemental hydrogen and elemental nitrogen.N2 + 3H2 2NH3This reaction requires the use of a catalyst, highpressure (1001,000 atmospheres), and elevated

    temperature (400550 C [7501020 F]). Actually, the equilibrium between the elements and

    ammonia favours the formation of ammonia at low temperature, but high temperature is requiredto achieve a satisfactory rate of ammonia formation. Several different catalysts can be utilized.

    Normally the catalyst isiron containing iron oxide. However, both magnesium oxide on

    aluminum oxide that has been activated byalkali metal oxides andruthenium on carbon havebeen employed as catalysts. In the laboratory, ammonia is best synthesized by the hydrolysis of a

    metal nitride.Mg3N2 + 6H2O 2NH3 + 3Mg(OH)2

    (C) Alloys

    Arrangement of atoms in metals

    Pure metals

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    http://www.britannica.com/EBchecked/topic/250771/Haber-Bosch-processhttp://www.britannica.com/EBchecked/topic/250771/Haber-Bosch-processhttp://www.britannica.com/EBchecked/topic/99128/catalysthttp://www.britannica.com/EBchecked/topic/475388/pressurehttp://www.britannica.com/EBchecked/topic/294242/ironhttp://www.britannica.com/EBchecked/topic/294242/ironhttp://www.britannica.com/EBchecked/topic/436674/oxidehttp://www.britannica.com/EBchecked/topic/356899/magnesiumhttp://www.britannica.com/EBchecked/topic/17944/aluminumhttp://www.britannica.com/EBchecked/topic/15617/alkali-metalhttp://www.britannica.com/EBchecked/topic/15617/alkali-metalhttp://www.britannica.com/EBchecked/topic/514211/rutheniumhttp://www.britannica.com/EBchecked/topic/514211/rutheniumhttp://www.britannica.com/EBchecked/topic/94732/carbonhttp://www.britannica.com/EBchecked/topic/278896/hydrolysishttp://www.britannica.com/EBchecked/topic/416096/nitridehttp://www.britannica.com/EBchecked/topic/416096/nitridehttp://www.britannica.com/EBchecked/topic/250771/Haber-Bosch-processhttp://www.britannica.com/EBchecked/topic/99128/catalysthttp://www.britannica.com/EBchecked/topic/475388/pressurehttp://www.britannica.com/EBchecked/topic/294242/ironhttp://www.britannica.com/EBchecked/topic/436674/oxidehttp://www.britannica.com/EBchecked/topic/356899/magnesiumhttp://www.britannica.com/EBchecked/topic/17944/aluminumhttp://www.britannica.com/EBchecked/topic/15617/alkali-metalhttp://www.britannica.com/EBchecked/topic/514211/rutheniumhttp://www.britannica.com/EBchecked/topic/94732/carbonhttp://www.britannica.com/EBchecked/topic/278896/hydrolysishttp://www.britannica.com/EBchecked/topic/416096/nitride
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    Pure metal is made up of one type of atoms,thus all atoms are of the same size.

    In solid state ,the atoms in a pure metal are orderly arranged

    and closely packed together.Thus,pure metals have highdensities.

    Although the forces of attraction between the metal atoms are strong,they are not

    rigid.Therefore when a force is applied,the layers of atoms can slide over one another.Thus

    metals are ductile or can be stretched.

    Ductile

    Malleable

    Goodconductors of

    heat and

    electricity

    High melting

    & boilingpoints

    High density

    Physical

    properties of

    pure metals

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    Force

    Layers of atoms slide over one another

    Figure 3 : Metals are ductile

    The arrangement of atoms in pure metals are not perfect.There are some empty spaces inbetween the atoms.When a metal is knocked or pressed,groups of atoms may slide and then

    settle into new position.So,metals are malleable.

    Force

    Figure 4 : Metals are malleable

    Pure metals are weak and soft due to their ductility and malleability

    What are alloys?

    An alloy is a mixture of two or more elements with a certain fixed composition in which themajor component is a metal.

    Pure metals are normally soft and easily oxidised.This is the reason why monuments orstatues are made of bronze(an alloy) and not copper(a pure metal).

    Alloy are stronger,harder,resistant to corrosion,have a better finish and lustrous.

    Why make alloys?

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    The aim of making alloy is:

    (a) to increase the strength and hardness of a pure metal

    (b) to increase the resistance to corrosion of a pure metal(c) to improve the appearance of a pure metal

    Figure 5 : Making alloy

    Composition, properties and uses of alloys

    Alloy Composition Properties Uses

    Bronze 90% copper,

    10% tin

    Hard,strong,does not corrode

    easily,shiny surface

    Medals,statues,monuments,art

    objects

    Brass 70% copper

    30% zinc

    Harder than copper Musical instruments,

    kitchenware, door knobs,bulletcases,electric parts,ornaments

    Cupro-nickel 75% copper25% nickel

    Beautifulsurface,shiny,hard,does not corrode easily

    Coins

    Steel 99% iron

    1% carbon

    Hard,strong Buildings,bridges,body of cars,

    railway tracks

    Stainless steel 74% iron,

    8% carbon18%chronium

    Shiny,strong,does not rust Cutlery,surgical

    instruments,sinks,pipes

    Duralumin 93%aluminium3% copper

    3%magnesium

    1%manganese

    Light,strong Body of aircraft and bullet trains

    Pewter 96% tin

    3% copper

    1% antimony

    Shiny, strong,does not

    corrode

    Art objects,souvenirs

    9-carat gold 37.5% gold

    11% silver51.5 % copper

    Shiny, strong,does not

    corrode

    Jewellery

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    (D) Synthetic Polymer

    What are polymers?

    Polymers are large long-chain molecules formed by joining together many identical repeating

    sub-units called monomers.

    Polymerisation is a process by which the monomers are joined together into chain-like

    molecule called polymer.

    Formation of polymer

    Polymers can be divided into 2 types.

    Natural Polymers

    NATURAL POLYMER MONOMER

    Rubber Isoprene

    Cellulose Glucose

    Starch Glucose

    Protein Amino acid

    Fat Fatty acid and glycerol

    Polymers

    Natural Polymers

    Exist in living things in nature

    Ex:Protein,cellulose,wool,silk,

    starch,natural rubber & DNA

    Synthetic Polymers

    They are man-made in laboratory through

    chemical processes.

    Ex: Plastics, nylon

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    Nucleic acid Nucleotides

    Examples of natural polymers and their monomers

    i) Natural polymers and their uses

    NATURAL POLYMER USE

    Rubber Tyres, eraser, condom, electric insulation, elastic bands

    and belts.

    Cellulose Paper, textiles, pharmaceuticals, and explosives

    Starch To stiffen cloth (as in laundering), used in cooking to

    thicken foods, manufactured ofadhesives,paper,textiles

    and as a mold in the manufacture of sweets.Protein Essential in the diet of animals for the growth and repair of tissue,

    Fat Maintaining healthy skinand hair, insulating body organsagainst shock, promoting healthy cell function and serve

    as energy stores for the body

    Synthetic Polymer

    Synthetic polymers are prepared through 2 types of polymerisation processes:

    (a)Addition polymerisation(b)Condensation polymerisation

    Addition polymerisation

    - involves monomers with double bonds between the carbon atoms.- During addition polymerisation, the double bonds between pairs of carbon atoms break

    and the carbon atoms pf adjacent ethene molecules join together to form a molecule of

    poly or polythene.

    Condensation polymerisation

    - involves the joining up of monomers with the formation of other smaller and simple

    molecules.

    Plastics

    Plastics are the largest group of synthethic polymers with the following properties:

    (a)Can be easily moulded

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    (b)Low density

    (c)Strong

    (d)Inert to chemicals(e)Insulator of heat and electricity

    (f)Can be coloured

    Name of polymer Equation forpolymerisation

    Properties Uses

    Polyethylene(polythene)

    H H H H n C=C CC

    H H H H n

    Ethene Polythene

    Durable,light,impermeable,Inert to chemicals,easily

    melted,insulator

    Shopping bags,Plastic cups and

    plates,toys

    Polypropylene(polypropene)

    H CH3 H CH3 n C=C CC

    H H H Hn

    Propene Polypropene

    Durable,light,impermeable,Inert to chemicals,easily

    melted,insulator,can be

    moulded and coloured

    Bottles,furniture,battery casing,

    pipes,toys

    Teflon F F F F n C=C CC

    F F F F n

    Tetrafluo- Teflon

    roethene

    Durable,non-stick,

    Chemically inert,strong,

    impermeable

    Coating for non-

    stick pans,

    electrical

    insulators

    Synthetic fibre

    Synthetic fibre are long-chain polymers which are not easily stretched and have highstrength.

    Polynamides and polyester are two groups of synthetic polymers used as fibres for makingtekstil.

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    Example of polynamide polymers is nylon.

    Example of polyester polymers is terylene.

    Nylon and terylene are produced through condensation polymerisation.

    TYPE OF POLYMER USE

    Polythene a) Make buckets

    b) Make plastic bags

    c) Make raincoats

    d) Make filmse) Make rubbish bins

    Polyvinyl chloride (PVC) a) Make water pipes

    b) Make electric cablesc) Make mats

    d) Make vinyl recordse) Make clothes hangers

    Polypropene a) Make ropesb) Make bottles

    c) Make chairs

    d) Make drink cans

    e) Make carpets

    Perspex a) Make car windows

    b) Make plane windows

    c) Make spectacle lenses (optical instruments)Nylon a) Make ropesb) Make curtains

    c) Make stockings

    d) Make clothes

    Polystyrene a) Make packing boxes

    b) Make buttons

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    c) Make noticeboards

    Terylene a) Make textile items such as clothes and cloths

    Disposal of synthetic polymers has caused environmental pollution problems:

    (a) Synthetic polymers are not easily biodegradable,thus their waste will block or clog up thedrainage system,thereby causing flash flood.

    (b) Waste plastics pollute the lake and river,making the water not suitable for aquaticorganisms to live in

    Ways to solve the problems caused by the use of synthetic polymers:

    (a) Reuse(b) Recycle

    (c) Use biodegradable synthetic polymer

    (d) Dispose of unwanted synthetic polymers in a proper manner.

    (E) Glass and ceramics

    Glass

    The major component of glass is silica or silicon dioxide,SiO2 which can be found in sand.

    Glass can made by heating a mixture of silicon dioxide and metal carbonates to a temperature

    above 1500C.

    Figure 6 : Structure of silicon dioxide

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    Type of glass Composition Properties Uses

    Fused glass Silicon dioxide High melting

    point

    High temperature

    and chemical

    durability

    Resistant tothermal shock

    transparent to

    ultraviolet andinfrared light

    Laboratory

    glassware

    Arc tubes in

    lamps

    Lenses

    Telescope mirrors

    Optical fibres

    Soda-lime glass silicon dioxide

    Sodium oxide

    Low meltingpoint

    Containers suchas bottles,jars.

    Chemically

    inert

    Electricalinsulator

    Heat insulator

    Impermeableto liquid

    Hard but

    brittle

    Transparent

    Physical

    properties of

    glass

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    Calcium oxide High thermalexpansion

    coefficient

    Does not

    withstand heat

    Cracks easily withsudden change in

    temperature

    Good chemical

    durability

    Easy to mouldand shape

    Transparent to

    visible light

    Flat glass

    Windowpanes

    Mirrors

    Light bulbs

    Industrial and art

    objects.

    Borosilicate glass Silicon dioxide

    Boron oxide

    Sodium oxide Calcium oxide

    Transparent to

    visible light

    resistant tochemicals

    Lower thermalexpansion

    coefficient

    Resistant to

    thermal shock

    Can withstand

    wide range of

    temperaturechanges

    Cookware

    Laboratory

    glassware Automobile

    headlights

    glass pipelines

    Electrical tubes

    Lead crystal glass Silicon dioxide

    Lead(II) oxide

    Sodium oxide

    Soft,easy to melt

    Transparent to

    visible light

    High density

    High reactive

    index

    Tableware

    Art objects

    Crystals

    Prisms

    Lenses

    Ceramics

    Ceramics are made from clay such as kaolin.Kaolin is rich in kaolinite(hydrated

    aluminosilicate,Al2O3.2SiO2.2H2O)

    Examples of ceramics are bricks,tile,mugs and clay pots.

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    Resist

    compression

    Very high

    melting point

    Good insulator

    of electricityand heat

    Chemically

    inert and does

    not corrode

    Brittle

    Very hard and

    strong

    Properties ofceramics

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    3 main differences between glass and ceramic:

    Glass can be heated until molten repeatedly but not ceramics

    Glass is usually transparent whereas ceramics are not

    Glass has a lower melting point than ceramics.

    Property Uses Examples

    Hard and strong Building materials Tiles,bricks,roofs,cement,abrasive for grinding

    Attractive,easily moulded andglazed

    Decorative pieces andhousehold items

    Vases,porcelain ware,sinks,bathtubs

    Chemically inert and non-corrosive

    Kitchenware Cooking pots,plates,bowls

    Very high melting point and

    good insulator of heat

    Insulation Lining of furnace, engine

    parts

    Electrical insulators Insulating parts in electrical

    appliances

    Spark plugs,insulators in

    ovens and electrical cables

    Inert and non-compressible Medical and dental apparatus Artificial teeth and bones

    Do notcorrode

    Inert to

    chemicals

    Good heatinsulators

    Good

    electricalinsulators

    Brittle

    strong under

    compression

    Hard and do

    not bend

    Commonproperties of

    glass andceramics

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    `(F) Composite materials

    A composite material is a structural material that is formed by combining two or more

    different materials such as metals,alloys,glass,ceramics and polymers.

    Some common composite materials are:a. Reinforced concrete

    b.Superconductor

    c. Fibre opticd.Fibre glass

    e. Photochromic glass

    Reinforced concrete

    Reinforced concrete is formed when concrete is reinforced with steel wire netting or steelrods.

    Essential for the construction of large structures like high-rise buildings,bridges and oil

    platforms.

    Has a greater strength than ordinary concrete and has higher resistance to impact.

    Superconductors

    capable of conducting electricity without any electrical resistance when they are cooled to anextremely low temperature.

    most of them are alloys of metal compounds or ceramics of metal oxides

    Superconductors also used in :

    (a) magnetic energy-storage system

    (b) magnetically levitated train(c) generators

    (d) transformers

    (e) computer parts(f) very sensitive devices for measuring magnetic fields, voltage or current.

    Fibre Optic

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    consists of a bundle of glass or plastic threads that are surrounded by a glass cladding.

    used to replace copper wire in long distance telephones lines,in mobile phones,video camerasand to link computers within local area networks.

    used in instruments for examining internal parts of the body or inspecting the interior ofmanufactured structural products.

    Fibre glass

    produced when glass fibres are embedded in plastic resins to produce glass fibre reinforced

    plastics.

    has high tensile strength,can be easily coloured,moulded and shaped,inert to chemicals and islow in density.

    Photochromic glass

    changes from transparent to coloured when it is exposed to ultraviolet light, and reverts to

    transparency when the light is dimmed or blocked.

    can be produced by embedding photochromic substances like fine silver chloride.

    photochromic glass helps to:(a) protect our eyes from harmful ultraviolet rays and glare from the sun(b) control the amount of light that passes through it automatically

    (c) reduce refraction of light

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    Sulphuric Acid

    Manufactured by Contact process

    Temperature:450C

    Pressure: 1 atm

    Catalyst : V2O5

    Uses:To make

    fertilizers,detergents,

    electrolyte, and synthetic fibre

    Synthetic Polymer

    Manufactured by

    polymerization.

    Examples and uses:

    Polyethylene:Shopping bags

    Polyvinyl chloride:Pipes

    polystyrene:Packaging

    materials

    Perspex:Lenses

    Nylon:Ropes,textile

    Ammonia

    Manufactured by Haber

    process

    Temperature:450C

    Pressure: 200 atm

    Catalyst : Fe

    Uses:To make fertilizers,

    nitric acid,cooling agent,

    explosives

    Manufactured Substances in

    Industry

    Glass

    Made from sand,SiO2

    Types & uses:Fused glass:Lenses

    Soda-lime glass:mirror

    Borosilicate glass:Beaker

    Lead crystal glass: Glass

    crystals

    Composite materials

    Made by combining two or more

    materials.Examples:

    Reinforce concrete

    Superconductors

    Fibre opticFibreglass

    Photochromic glass

    Alloys

    Made from metal and

    other elements.Examples

    and composition:

    Bronze:Copper & tinBrass:Copper & zinc

    Steel:Iron & carbon

    Pewter:Tin,Copper &

    Antimony

    Stainless Steel:

    Iron,carbon &

    chronium

    Ceramic

    Made from clay,

    kaolinite,Al2O3.2SiO2.

    2H2O

    Properties and uses:

    Hard & strong:Tiles,

    bricks

    Attractive:vases,

    sinks

    Non-corrosive:

    Kitchenware

    High melting point:

    FurnaceInert: Medical &

    dental apparatus

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    First of all,I would like to thank the God for giving me blessings to complete this

    folio just in time.Even I faced a lot of difficulties when doing this project,I managed to

    overcome it by the Gods blessing .

    Then, thanks to my chemistry teacher Mrs.Ng Phek Lan for being such a goodguider while doing this project.She had given us appropriate information about this

    project in order to make us understand more about this project.

    Also a great thanks to my friends and family members who tried their best to givetheir support for me, either by giving me a lot of encouragement while doing this project

    or helping me to gather the data required for the project.

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    B.S.Mathiarasi

    Eng Nguan Hong,Lim Eng Wah,Lim Yean Ching., 2009. Focus Ace SPM Chemistry.,

    Penerbitan Pelnagi Sdn. Bhd., (page 261 287)

    http://www.ravensdown.co.nz/Resources/Education/Properties+of+Sulphuric+Acid.htm

    http://www.britannica.com/EBchecked/topic/20940/ammonia/277712/Preparation-of-

    ammonia

    http://en.wikipedia.org/wiki/Glass

    http://www.tutorvista.com/content/chemistry/chemistry-ii/metals/metalsindex.php

    http://www.ravensdown.co.nz/Resources/Education/Properties+of+Sulphuric+Acid.htmhttp://www.britannica.com/EBchecked/topic/20940/ammonia/277712/Preparation-of-ammoniahttp://www.britannica.com/EBchecked/topic/20940/ammonia/277712/Preparation-of-ammoniahttp://en.wikipedia.org/wiki/Glasshttp://www.tutorvista.com/content/chemistry/chemistry-ii/metals/metalsindex.phphttp://www.ravensdown.co.nz/Resources/Education/Properties+of+Sulphuric+Acid.htmhttp://www.britannica.com/EBchecked/topic/20940/ammonia/277712/Preparation-of-ammoniahttp://www.britannica.com/EBchecked/topic/20940/ammonia/277712/Preparation-of-ammoniahttp://en.wikipedia.org/wiki/Glasshttp://www.tutorvista.com/content/chemistry/chemistry-ii/metals/metalsindex.php