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HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE Das Kopernikus Projekt P2X Andreas Frömmel 09/2019

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Page 1: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

HOCHEFFIZIENTE HOCHTEMPERATUR-CO-ELETROLYSEDas Kopernikus Projekt P2X

Andreas Frömmel09/2019

Page 2: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

THE OBJECTIVE: MITIGATING CLIMATE CHANGE

Page 3: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

+ 5 °C: End of human civilization

+ 4 °C: Drought in Europe; China, India and Bangladesh mainly desert; Polynesia vanished;

American Southwest largely uninhabitable

+ 3 °C: Forests in the Arctic and the loss of most coastal cities

+ 2 °C: Extinction of the world’s tropical reefs, sea-level rise of several meters; abandonment of the Persian Gulf

Sources: https://www.pik-potsdam.de/paris-reality-check/

https://www.nytimes.com/interactive/2018/08/01/magazine/climate-change-losing-earth.html

PARIS CLIMATE AGREEMENT

THE FUTURE HAS TO BE RENEWABLE

· 85 - 100 % renewables needed to reach Paris Climate Target which still leads to significant negative impacts for human civilization

Renewables Everywhere 3

Page 4: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Even in scenarios with large increase of direct electrification liquid and gaseous energy carriers remain necessary to cover the global energy needs in 2050.

Renewables Everywhere

THE NEXT LEVEL OF ENERGY TRANSITION

Sources: IEA, June 2017; World Energy 2014-2050, Political economist, 2014

Renewable Solutions needed for

e-Fuels

e-Gases

e-Chemicals

Renewable ElectricitySolutions available

42019

Page 5: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Renewables Everywhere 5

MEETING THE CLIMATE OBJECTIVES

Demand for synthetic liquid energy carriers 2050 in the EU:up to 2.000 PJ = up to 230 GW installed PtL capacity

(up to 8 GW/a installed capacity from 2020)

Achieving the climate protection goals is only possible with the use of synthetic fuels and gases.

“Power-to-fuel applications offer the lowest marginal abatement costs [for volatile renewable energy integration] in the long term.”

“Even in a battery electric drive dominated scenario, the final energy demand of all transport modes in the EU will be

met with more than 70 % of e-Fuels in 2050.”

2019

Page 6: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

THE SOLUTION: ELECTRICITY BASEDLIQUIDS AND GASES(e-Fuels and e-Gases)

Page 7: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

We want to achieve a zero emission society in transport, industry and energy sectors via electricity based liquids and gases, making renewable energy available wherever and whenever it is needed.

FROM VISIONTO REALITY

Renewables Everywhere 72019

Page 8: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Sunfire-HyLink in Action

SUNFIRE ELECTROLYSIS PRODUCTS

2019Renewables Everywhere 8

Sunfire-HyLink 200

Renewable hydrogen - up to 730 kW per system / 200 Nm³ H₂ per

hour. The world’s most energy efficient electrolysers, with a

system power consumption of down to 3.7 kWh/Nm³ H₂.

Sunfire-SynLink 200

Renewable syngas - up to 790 kW per system / 200 Nm³ syngas

per hour. The world’s only electrolysis technology capable of

producing syngas directly from H2O and CO2.

Highest conversion efficiencies for lowest total costs!Sunfire-SynLink in Action

Page 9: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Renewables Everywhere 9

· Highest efficiencies leading to lowest total cost of ownership (TCO)

· Direct conversion of carbon molecules to provide clean solutions for the energy transition in all sectors

· Non-toxic, no critical and no expensive materials for easy manufacturing

“When steam can be preferably generated from waste heat sources, such as in steelmaking, high temperature electrolysis is the most efficient technology.”

Prof. Dr.-Ing. Heinz Jörg Fuhrmann, CEO and Chairman of the Executive Board of Salzgitter AG

THREE CORE USP

2019

Page 10: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

2019Renewables Everywhere

P2X PRODUCTION PATHWAYS

Hydrogen

Methane

Diesel

Petrol

Jet fuel

Wax

Methanol

Propylene

Ethylene

Ammonia

Methanation*

Methanol Synthesis*

Fischer-TropschSynthesis*

Ammonia Synthesis*

+

+

+

+

ElectrolysisRenewable

Power

+

10

N2

* Exothermic reaction providing steam for e.g. steam electrolysisSource: dena, Heutige Einsatzgebiete für Power Fuels, 08/2018

Page 11: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

„KOPERNIKUS P2X“ WITHSUNFIRE-SYNLINK

Page 12: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Turning renewable electricity and CO2 into e-Fuels for carbon neutral transportation, especially for transport sectors that cannot be electrified directly.

E-FUELSP O W E R - T O - L I Q U I D

2019Renewables Everywhere 12

Page 13: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Synthetic paraffins of high quality as clean raw materials for the replacement of mineral oil in a variety of products in different industries such as Cosmetics, Clothing, Plastic processing and others.

E-WAXP O W E R - T O - C H E M I C A L S

2019Renewables Everywhere 13

Page 14: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

03.06.2019Clean Steel & New Markets with Sunfire 14

P2X FOR EXISTING INFRASTRUCTURES

Synthesis Refinement

SunfirePartner Partner

e-Diesele-Gasolinee-Jetfuele-Methanee-Methanole-Waxes

Sunfire IP*

Sunfire-SynLink

Carbon CapturingCO2 from air or unavoidable sources

Renewable Electricity Ready-to-useDirect effect on existing fleetInfrastructure compatibleNo-regret measure

e-Syngas e-Crude

*Sunfire owns key process patents for production of e-Fuels with electrolysis and Fischer-Tropsch or Methanol synthesis (e.g. WO/2008/014854)

Page 15: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Sunfire-SynLink for e-Syngas production

· Co-electrolysis prototype developed and tested within the framework of the BMBF-funded project Kopernikus P2X

· World‘s first integrated Power-to-Liquid (PtL) test facility to synthesize fuels from the air-captured carbon dioxide

· Container-based test facility integrating all four chemical process steps to implement a continuous process

· Partner: Climeworks, Ineratec, Sunfire and KIT

· Currently operation in PtL Plant (@KIT, Karlsruhe (GER))

Renewables Everywhere 15

Installation Site

CO-ELECTROLYSIS FOR E-FUELS & E-CHEMICALS

2019

Page 16: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

2019Renewables Everywhere 16

Development and testing within Kopernikus P2X (FKZ: 03SFK2QO0)

· System design: · Proof of concept full co-electrolysis system· Co-Electrolyser:max. 10 kWDC

· Feed: CO2, H2O, FTS recycle gas· Product: max. 4 Nm³/h syngas

· Successful system operation > 1300 h

· No higher degradation compared to H2O-SOEC

· Prototype efficiency at 62 %(AC > LHV // comprising losses // producing steam)

· Achievable efficiency > 80 % by reducing losses (+4%), optimizing power electronics (+4%) and heatrecuperation (+10%)

· Various operation modes validated

SUNFIRE-SYNLINK GEN. 0: CO-ELECTROLYSIS SYSTEM

Page 17: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

2019Renewables Everywhere 17

e-Fuels produced in the Kopernikus project

· First phase of Kopernikus P2X project

· Production of Carbon-neutral Fuels from Air, Water and Green Power – Proof of concept

· Capacity: about 10 liters of fuel per day

· Analysis and tests of e-fuels and wax in progress

· Second phase of the Kopernikus P2X project started

· it is planned to develop a plant with a capacity of 200

liters per day

· Third phase of the Kopernikus P2X project

· a pre-industrial demonstration plant in the megawatt

range, i.e. with a production capacity of 1.500 to 2.000 liters per day, will be designed

SUNFIRE-SYNLINK GEN. 0: INTEGRATION IN PTL

Page 18: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Raw Synthetic Product / Diesel Quality Already

· Fisher Tropsch raw product = Mixture of

· Naphta C5….C9

· Middle Destillate C10…C19

· WAX > C20

· Material properties depend on actualoperating conditions the PtL processes areperformed

· Representative Middle Destillate testingconfirmed EN590 property

2019Renewables Everywhere 18

E-CRUDEFUEL PROPERTIES EN590

MIDDLE DISTILLATE unrefined

Min Max Initial test results

Cetane number 51.0 - 76.0

Cetane index 46.0 - 87.9

Density (15 °C) 820 kg/m³ 845.0 kg/m³ 781.7 kg/m³

Polycyclic aromatic hydrocarbons (PAH) - 8.0 wt.-% 0.1 wt.-%

Sulphur content - 10.0 mg/kg ~ 0 mg/kg

Manganese content - 2.0 mg/l ~ 0 mg/l

Flash point 55.0 °C - 51.5 °C

Carbon residue - 0.30 wt.-% < 0.01 wt.-%

Ash content - 0.010 wt.-% < 0.001 wt.-%

Water content - 200.0 mg/kg 47.5 mg/kg

Total impurities - 24.0 mg/kg Not specified

Corrosiveness to copper Class 1 Class 1

Fatty acid methylesters (FAME) - 7 vol.-% ~ 0 vol.-%

Oxidation stability - 25 g/m³ 3 g/m³

Lubricity (wsd) - 460 µm 615 µm

Viscosity (40 °C) 2 mm²/s 4.5 mm²/s 2.09 mm²/s

Distillationvol.-% recovered at 250 °Cvol.-% recovered at 350 °C95 vol.-% recovered at

-85 vol.-%

-

< 65 vol.-%-

360 °C

19.6 vol.-%91.9 vol.-%

362.3 °C

Cold filter plugging point (CFPP) -20 °C 0°C 13 °C

Page 19: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

SUNFIRE PRODUCTSIN ACTION

Page 20: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Sunfire-SynLink for e-Crude production

· Powered by renewable electricity, CO2 and steam:

· Production of more than three tons of 100 % renewable e-Crude providing e-Fuels (Diesel, Gasoline) and e-Wax

· Industrial reactor concept for quick upscaling

· Synthetic fuel with premium properties, verified by AUDI AG

· High cetane value

· Excellent combustion properties

· ASTM certified and drop-in capable (up to 50 %)

· e-Jetfuel tested within Demo-SPK Project

Renewables Everywhere 20

Installation Site

RENEWABLE E-FUELS & E-CHEMICALS

2019

Page 21: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Sunfire-SynLink for e-Crude production

· Sunfire will build the first commercial e-Fuels plant by 2022 in Herøya, Norway

· Multiple off-take agreements in place for 8,000 t/a

· Unique advantages through location

· Low electricity prices (ca. 3 ct€/kWh)

· Continuous supply (>7,000 h)

· Distribution shipping terminal at site

· 10 potential sites for expansion identified

Business case repetitive in other European countries (e.g. Eastern Europe)!

Renewables Everywhere 21

Installation Site in Herøya, Norway

RENEWABLE E-FUELS & E-CHEMICALS

2019

Page 22: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

A POWERFUL ORGANISATION

Page 23: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Knowhow

· ~ 130 Employees in Dresden and Neubrandenburg

· Full value chain from Ceramics, Engineering, Stack + System Production, up to Synthesis Processes, Service etc.

Patents

· More than 60 patent families (e.g. »process patent sunfire« WO/2008/014854)

Revenues

· Multi-million Euro Revenues in Global Markets since 2011

Investors

National and international awards

for innovative and pioneering technology

Sunfire Headquarters

COMPANY FACTS

Renewables Everywhere 232019

Page 24: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

15-05-2019Renewables Everywhere

Recent Paul Wurth Projects References

· Invested 20 M€ in Sunfire series-C round in 2018

· World leading EPC contractor in iron and steel plants

· Clear strategy to go from fossil to renewable

· In-house technology for transition readily available

· Ability to support project financing and de-risk large commercial projects in the range of > 100 MW

· Global presence to support sales and project development

NEW SUNFIRE INVESTOR PAUL WURTH / SMS GROUP

24

Page 25: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Leading provider of solutions to produce fuels and gases from renewable electricity

2019Renewables Everywhere 25

SUNFIRE SERVING TO GIGAWATT MARKETS

Lead generation,

sales

Construction of core

component

Financing support and

de-risking

Integration at customer site

(EPC)Operation

PartnerSunfire Sunfire

After sales

Customer

Page 26: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Renewables Everywhere 26

IMPRESSIONS

Sunfire Headquarter in Dresden

Stack production

e-Fuels plant

Test facilities

2019

Page 27: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

THANK YOU!Andreas FrömmelVP Sales and Marketing

Sunfire GmbH · Gasanstaltstraße 201237 Dresden · Germanywww.sunfire.de

Page 28: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Sunfire-HyLink for e-Hydrogen production

· Powered by renewable electricity and steam:

· Production of hydrogen for annealing process of Stahlwerk Salzgitter AG for over 2 years

· Industrial electrolysis concept for quick upscaling

· Upscaling to megawatt-scale currently ongoing

· High efficiency proven

· Full integration into integrated steel plant

· Hydrogen production according to technical gas supplier quality requirements

Renewables Everywhere 28

Installation Site

RENEWABLE E-HYDROGEN

These projects have received funding from the Fuel Cells and Hydrogen 2 Joint Undertaking under grant agreement No 700300 and No 826350.

2019

Page 29: HOCHEFFIZIENTE HOCHTEMPERATUR- CO-ELETROLYSE

Dual use – additional market access

· Sunfire’s SOC technology is also suitable for direct conversion from gases to power and heat based on the same core component

Fuel cell business with daughter company Sunfire Fuel Cells

· Best in class fuel cell systems to provide power and heat in privat homes – developed and validated together with Vaillant since 2006

· Systems also available for remote application in harsh environments, where fuel cell create a superior solution for remote power supply e.g. in the Oil+Gas sector

· Sunfire fuel cells offer a second market for the Sunfire core components and creates an additional company value

Sunfire-Home 750 decentralized power and heat generation

Sunfire Fuel Cell Production in Neubrandenburgs

FUEL CELL BUSINESS UNIT

Renewables Everywhere 292019