inorganic thin films: future perspectives · inorganic thin films: future perspectives global...
TRANSCRIPT
![Page 1: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/1.jpg)
Inorganic Thin Films:Future Perspectives
Global Climate Energy ProjectSolar Energy Workshop: Thin-Film Photovoltaics
October 19, 2004John P. Benner
Division Manager Electronic Materials and DevicesNational Center for Photovoltaics
![Page 2: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/2.jpg)
Future Perspectives from 1975
2004 CdTe
25.90.845
0.75516.5
![Page 3: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/3.jpg)
Effic
iency
(%)
CuInSe2
CdTe
Amorphous silicon
(stabilized)
Univ. of Maine
Boeing
Boeing
Boeing
Boeing
ARCO
AMETEK
NREL
Boeing
EuroCIS
Univ. of So. Florida
Univ. of So. FL
BP Solar
Kodak
KodakMonosolar
Matsushita
12
8
4
0200019951990198519801975
United Solar
16
20
NREL
2005
RCA
ECD
NREL
Photon Energy
026587181
Effic
iency
(%)
CuInSe2
CdTe
Amorphous silicon
(stabilized)
Univ. of Maine
Boeing
Boeing
Boeing
Boeing
ARCO
AMETEK
NREL
Boeing
EuroCIS
Univ. of So. Florida
Univ. of So. FL
BP Solar
Kodak
KodakMonosolar
Matsushita
12
8
4
0200019951990198519801975
United Solar
16
20
NREL
2005
RCA
ECD
NREL
Photon Energy
026587181
Best ResearchBest Research--Cell EfficienciesCell EfficienciesThinThin--Film Film InorganicsInorganics
![Page 4: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/4.jpg)
World PV Cell/Module Production (MW)World PV Cell/Module Production (MW)
1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 20010
100
200
300
400
Rest of worldEuropeJapanU.S.
33.6 40.2 46.5 55.4 57.9 60.1 69.4 77.6 88.6125.8
154.9201.3
287.7
390.5
2002
500
Source: PV News, March 2004
600 561.8
700
800744.1
2003
~50 MW Thin-Film in 2003
![Page 5: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/5.jpg)
U.S. Thin-Film Manufacturing
0
5
10
15
20
25
1996 1999 2002 2005
a-Si CIS CdTe
Projected
![Page 6: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/6.jpg)
Think Big -- Very Big 2-5 GW Factories
05
10152025303540
1990 1995 2000 2005 2010 2015 2020
GW
Ann
ual M
odul
e Pr
oduc
tion
![Page 7: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/7.jpg)
Ground Rules for GW Scale Factories
• Dedicated float glass line• 5x reduction in glass cost ~$4/m2 finished
• Redundant cluster production tools• 8x reduction in capital cost • ~100 20MW deposition clusters @ $2M each
• Recycled Effluents• 75% utilization
• Advanced Packaging Factory• Aluminum Extruding and Fabrication
M. Keshner, et al, Hewlett Packard Final Rpt NREL#ADJ-3-33631-01
![Page 8: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/8.jpg)
page 10September 20, 2004 hp confidential
Solar Factory ModuleCost Comparisons for Completed Solar Panels
Cost Summary 20 M W Plant 2 GW Plant N et Gain(all numbers are per sq. meter)
Coated Glass $ 23 .62 $ 4 .62 5 x
Operating Ex penses $ 4 .00 $ 1 .50 2 .5x
M ateria ls and deprecia tiona - Si $ 2 .33 + $ 13 .35 $ 0 .31 + $ 2 .67 5xCdTe $ 3 .46 + $ 10 .00 $ 2 .31 + $ 2 .00 7 .5xCuInGaSe2 $ 13 .96 + $ 1 3 .35 $ 9 .3 1 + $ 2 .67 7 .5x
Assembly, Packaging $ 41 .71 $ 1 0 .50 4x & Interconnect
Overa ll process yield 60 % 93 % 1 .55x
Tota l manufacturing cost per w atta - Si ( 7%) $ 2 .02 $ 0 .30
CdTe (11%) $ 1 .25 $ 0 .21CuInGaSe2 (12%) $ 1 .34 $ 0 .26
+
225 volts_
Complete solar panel ready for simple a ttachment onto a roof
Notes: If CdTe and CuInGaSe2 could use effective light trapping and be reduced in thickness to 0.4 um like a-Si, then their cost per W p would be $.19 and $.19, respectively.If a-Si could use a second junction of a-SiGe or uc Si, its efficiency would be circa 10% and its cost per W p would be $.21.
![Page 9: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/9.jpg)
page 10September 20, 2004 hp confidential
Solar Factory ModuleCost Comparisons for Completed Solar Panels
Cost Summary 20 M W Plant 2 GW Plant N et Gain(all numbers are per sq. meter)
Coated Glass $ 23 .62 $ 4 .62 5 x
Operating Ex penses $ 4 .00 $ 1 .50 2 .5x
M ateria ls and deprecia tiona - Si $ 2 .33 + $ 13 .35 $ 0 .31 + $ 2 .67 5xCdTe $ 3 .46 + $ 10 .00 $ 2 .31 + $ 2 .00 7 .5xCuInGaSe2 $ 13 .96 + $ 1 3 .35 $ 9 .3 1 + $ 2 .67 7 .5x
Assembly, Packaging $ 41 .71 $ 1 0 .50 4x & Interconnect
Overa ll process yield 60 % 93 % 1 .55x
Tota l manufacturing cost per w atta - Si ( 7%) $ 2 .02 $ 0 .30
CdTe (11%) $ 1 .25 $ 0 .21CuInGaSe2 (12%) $ 1 .34 $ 0 .26
+
225 volts_
Complete solar panel ready for simple a ttachment onto a roof
Notes: If CdTe and CuInGaSe2 could use effective light trapping and be reduced in thickness to 0.4 um like a-Si, then their cost per W p would be $.19 and $.19, respectively.If a-Si could use a second junction of a-SiGe or uc Si, its efficiency would be circa 10% and its cost per W p would be $.21.
![Page 10: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/10.jpg)
Time to Production:Processes must be better characterized
CIGS - Shellα-Si:H - BP
CdTe – First Solar
0%
20%
40%
60%
80%
100%
120%
Feb-97
Nov-97
Sep-98
Jan-99
Mar-99
Dec-99
Mar-00
Sep-00
Dec-00
1-Jul
Dec-01
Month / Year
Perc
enta
geof
Cap
acity
0.0%10.0%20.0%30.0%40.0%50.0%60.0%70.0%80.0%90.0%100.0%
Yiel
d
![Page 11: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/11.jpg)
16.5% Efficient CdTe Solar Cells
Back-contact (C:HgTe:CuTe)
CdTe (~10 µm)
CdS (0.07 - 0.1 µm)
Zn2SnO4 (0.1 -0.2 µm)
Cd2SnO4 (0.15 -0.3 µm)
Glass substrate
Front-contact (In) CdS – ZTO interdiffuse
CdSxTe1-xO content in CdS
Cu diffusionAnneal in CdCl2
![Page 12: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/12.jpg)
Thin Film Cells are….. ThinAdvantages•Low material consumption
•High throughput potential
•Module patterning
•Improved carrier generation profile
•Drift collection
•Flexible
•Semi-transparent
Challenges•Unique Materials
•Interdiffusion
•Grain size
•Low-lifetime
•Drift collection
•Characterization
![Page 13: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/13.jpg)
Effect of Back Contacts Deposition Temperature on Thin-Film CdTe Solar Cell Performance
⊗⊗
⊗⊗⊗⊗
⊗⊗
⊗
⊗
⊗⊗⊗⊗⊗⊗⊗
⊗
⊗
⊗
⊗⊗
⊗⊗
⊗⊗
⊗⊗
⊗
⊗
⊗⊗
⊗⊗
⊗⊗
⊗⊗
⊗
⊗
25
35
45
55
65
75
200 240 280 320 360 400
Fill
Fact
or (%
)
Contact Deposition Temperature (°C)
⊗⊗⊗⊗⊗⊗⊗⊗
⊗
⊗
⊗⊗⊗⊗⊗⊗⊗
⊗
⊗
⊗
⊗⊗⊗⊗⊗
⊗⊗
⊗
⊗
⊗
⊗⊗⊗⊗⊗
⊗⊗
⊗
⊗
⊗
450
550
650
750
850
200 240 280 320 360 400
Ope
n C
ircui
t Vol
tage
(mV)
Contact Deposition Temperature (°C)
![Page 14: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/14.jpg)
Cu Diffusion from CdCl2 and Contact Processes
High-Resolution SIMS of Cu Concentration
Quantified
1016
1017
1018
1019
1020
1021
Con
cent
ratio
n (a
t/cm
3 )
6543210Depth (µm)
Cu Profiles As grown CdCl2 treated W5 USF W11 NREL W7 NREL ZnTe
ZnTe | CdTe | CdS | SnO2
Un-quantified
100
101
102
103
104
105
106
Seco
ndar
y io
n co
unts
543210Depth (µm)
no contact no CdCl2 no contact wet CdCl2 207¡C 285¡C 335¡C 390¡C
CdTe | CdS | SnO2
ZnTe:Cu
![Page 15: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/15.jpg)
Combined EBIC of ZnTe:Cu Contacted Devices
![Page 16: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/16.jpg)
Think High
• High efficiency– Multi junction– Highly ordered, oriented films– Single crystal
• High rate deposition
![Page 17: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/17.jpg)
Polycrystalline Thin Film Tandem Solar Cell
7059 Cornning glassCTOZTO
S-CdS:O
CdTe
CuxTe back-contactITO
Ni/Al grids
In contact
c-ZTO / i-ZnOCBD-CdS
CISMo
Soda-lime glass
Ni/Al grids
In contact
CdTe top cellAchieved 50%transmission,12.7% efficiency
CIS bottom cellAchieved 14.5% efficiency
FY06 milestone: 15% efficient 4-terminal device will be met one year early
![Page 18: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/18.jpg)
Red QE equals USSC bottom cell
1.0
0.8
0.6
0.4
0.2
0.0
QE
1000900800700600500400300Wavelength (nm)
Q_L1067Q_T2358
µC-Si
a-SiGe
![Page 19: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/19.jpg)
Film c-Si on glass concept
glass
epitaxially thickened c-Si
c-Si seed layer
• Many approaches to both seed and epitaxy under study
See, review by Bergmann & Werner, Thin Sol Films 2002
![Page 20: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/20.jpg)
Ni-seeded c-Si template / HWCVD c-Si
glassPoly c-Si (Ni)
300°C HW poly c-Si
• Si lifetime > ~10 µs– H in grain boundaries?
• Poly-Si growth rate 1 Å/s --> slow at ~3 hr per µm– heavy H2 dilution
glass
Ni
glassSolid-phase crystallized a-Si
Richardson et al, MRS Spring A, 2004
![Page 21: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/21.jpg)
Single Grain Si Films Induced by Hydrogen Plasma Seeding
Single nucleus achieved for holes <0.6 µm
Bo et al, JVST B. May 2002
![Page 22: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/22.jpg)
Ta wire improves epitaxy
(100) substrate
• Ta filament: about 350 nm epitaxy
• W filament:50 to 100 nm epitaxy
• ~ 3Å/s at 270°C a-Si:H cone strained c-Si
![Page 23: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/23.jpg)
Think Small• Defects and nanostructure
• Thinner Devices
![Page 24: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/24.jpg)
CIGS, Ga/(In+Ga)=28.5%SKPMAFM
5 µm 5 µm
G1 G1
G2 G2
100 Pote
ntia
l (m
V)
0 2 4 6 8 10Distance (µm)
Hei
ght (
nm)
100
• Potential height: ~150 mV• Depletion width: 150~400 nm.
![Page 25: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/25.jpg)
Cu0.9(In1-xGa0.30)1.1Se2
Hei
ght o
f pot
entia
l pea
k (m
V)Ef
fi cie
ncy
η (
%)
0
50
100
150
200
0 20 40 60 80 100Ga Content Ga/(In+Ga) (%)
8
12
16
20
24
(a)
(b)28
32
Measured efficiency
Predicted from band gapM. A. Green, Solar Cells, P. 89
1.00E-06
1.00E-05
1.00E-04
1.00E-03
1.00E-02
1.00E-01
1.00E+00
0 0.2 0.4 0.6 0.8 1 1.2X = Ga/(In+Ga)
Jo (m
A/c
m^2
)
1
2
3
4
5
Idea
lity
Fact
or A
Jo A
![Page 26: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/26.jpg)
Difficulty for Ga>30%
• Difficult to dope n-type• Difficult to form n-type Cu-poor layers
S.-H. Wei et al APL 1998
![Page 27: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/27.jpg)
Quantum Efficiency of CIGS Solar Cells
![Page 28: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/28.jpg)
How is a Crystal 10% Cu Poor?Cu2Se
CuInSe2
CuIn3Se5
Cu2In4Se7
CuIn5Se8•••
Zhang et al Phys Rev B 1998
Neutral Defect Complex
(2VCu– + InCu
2+)
Phase SegregationMaterial immediately surrounding dislocations and grain boundaries in device-quality CI(G)S will have higher bandgap
The α/β hole mirror disappears at [Ga]/[Ga+In] ≅ 35%
Stanbery TBP
![Page 29: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/29.jpg)
Million M2 per Year
10
100
10000
1000
1
10 100 1000 10000
Low Cost Processes
Large-Area Optical and Electronic Materials
Glass
Coated Glass
Paint
FPD
PV
SolarFuels
Electrode
Fuel Cell Bipolar plate
$/M2
1
![Page 30: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/30.jpg)
United Solar Shingles
Advances in PV System Design Achieve Cost Advantages
Uni-Solar Amorphous Silicon Field Applied Roofing Products in units to 128W (18’x16”, 17 lbs, 33V & 3.88 A)
![Page 31: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/31.jpg)
Summary• Inorganic Thin-Film PV is on the threshold of
increasing market presence. • Potential for further improvement
• 10x reduction in $/m2• 2-3x increase in module efficiency
• Current fundamental understanding in all material systems contains large gaps
• Large entry investments will demand improved understanding and predictive capability.
• Shared production infrastructure simplifies start-up and growth
![Page 32: Inorganic Thin Films: Future Perspectives · Inorganic Thin Films: Future Perspectives Global Climate Energy Project Solar Energy Workshop: Thin-Film Photovoltaics October 19, 2004](https://reader030.vdocuments.net/reader030/viewer/2022040706/5e054fc461229d19fa0eda11/html5/thumbnails/32.jpg)
Presented with Great Appreciation for the original work, contributions, discussions
and figures from my colleagues:• Mowafak Al-Jassim• Sally Asher• Howard Branz• Miguel Contreras• Tim Coutts• Tim Gessert• Falah Hasoon• Chun-Sheng Jiang• Rommel Noufi
• K. Ramanathan• Manuel Romero• Su-Huai Wei• Xuanzhi Wu• Yanfa Yan• Alex Zunger• Ken Zweibel• Marvin Keshner (HP)• B. Stanbery (HelioVolt)