iprime annual meeting · modern polymer characterization methods-1 (mp) p. 7 interfacial rheology,...

IPrime

Annual Meeting May 27 – 29, 2014

University of Minnesota, Minneapolis

East Bank Campus

Schedule & Events Program Reviews

Board & Committee Meetings

Special Topic Workshops

2 Poster Sessions

Faculty-Industry Meet & Greet

Welcome! I would like to thank you for attending the IPrime 2014 Annual Meeting at the University of Minnesota. IPrime is the Industrial Partnership for Research in Interfacial and Materials Engineering, and is the largest industrial consortium in the University. It connects industrial companies to selected research programs in the NSF-supported Materials Research Science and Engineering Center (MRSEC), the Colleges of Science and Engineering; Biological Sciences; Food, Agriculture and Natural Resource Sciences; and the Academic Health Center. IPrime currently includes over 50 faculty and associated graduate students from 10 departments working in 8 research programs, with support from 44 member companies. The IPrime Annual Meeting is an ideal opportunity to network with other member companies, to learn about latest research results, and to meet with more than 150 dedicated young engineers and scientists. This year, IPrime researchers will be sharing their expertise in areas such as biotechnology, bio and pharmaceutical materials, electronic materials and devices, organic semi-conductors, polymers, coatings, and renewable energy materials. In addition there are five exciting workshops and a plenary lecture on innovation. This year we are excited to introduce a new program, Electronic Materials and Devices, which substantially expands the work done previously in the Magnetic Heterostructures program. On the following pages you will find the schedules and abstracts for both the presentations and posters. You will also find the location of the meeting rooms and a map of the poster sessions. Complete information is available on our website, www.iprime.umn.edu. Following the Annual Meeting, many of the presentations and posters will be available on our website that you will be able to access with your company password. We welcome your feedback through your company’s Technical Advisory Committee Representative(s) (TAC). Again, thank you for your membership in IPrime and for participating in the 2014 IPrime Annual Meeting. Sincerely,

Chris Macosko Director, IPRIME

Industrial Partnership for Research in

Interfacial and Materials Engineering

An entry for industrial connections to University of Minnesota research through 54 faculty. IPRIME research is pre-competitive, non-proprietary and focuses on two-way knowledge transfer within eight research partnership programs.

Biocatalysis and Biotechnology

Biomaterials and Pharmaceutical Materials

Coating Process Fundamentals

Electronic Materials and Devices

Microstructured Polymers

Nanostructural Materials and Processes

Organic Optoelectronic Interfaces

Renewable Energy Materials

Partnership Scientific Exchange with the Academic Sector Influence Research Directions Leverage Government Funding Industrial Fellows Program Industry Source of Research Topics

Future Employees Early Access to Ph.D. Students and

their Research

Facilities Characterization Facility* Polymer Characterization—Rheology* University Imaging Center * Coating Process and Visualization Lab Polymer Synthesis Tissue Mechanics Lab

Technology Transfer Annual Meetings Short Courses Industrial Fellows Program Workshops throughout the Year Online Resources: Webcasts

IPRIME MEMBERSHIP BENEFITS

www.iprime.umn.edu

PARTNERSHIP PROGRAMS

* Member Discount

3M Anasys Asahi Kasei Ashland Inc. BASF Bergquist Boston Scientific Bruker Cabot Corning, Inc. Covidien Dai Nippon Printing Dow Chemical EarthClean Ecolab Evonik ExxonMobil General Mills Hearing Components Henkel Infineum INOAC

Member Companies

Lord Corporation MeadWestvaco Medtronic Nanocopoeia NewPage NIST Nitto Optomec Physical Electronics RTP Company Sage Electrochromics Sandia Livermore Sappi Schlumberger Segetis Stratasys SVT Associates TA Instruments Teknapack, Inc. Total Upsher-Smith Valspar

Industrial Partnership for Research in

Interfacial and Materials Engineering

www.iprime.umn.edu

Industrial Partnership for Research in Interfacial and Materials Engineering 2014 Annual Meeting

IPRIME ANNUAL MEETING 2014 TABLE OF CONTENTS

Special Events p. 2 Partnership Programs, Descriptions & Abbreviations p. 3 Quick View: Schedule of Events Back cover

Workshops:

Coating and Printing with Inks, Paints and Particulate Suspensions (CPF) p. 6

Modern Polymer Characterization Methods-1 (MP) p. 7

Interfacial Rheology, Nanostructural Materials and Processes (NMP) p. 8

Microneedle Based Delivery of Therapeutics (BPM) p. 9

Materials and Processes for Printed Electronics (OEI/CPF) p. 10


Synthetic Biology and Bioprocessing (BB) p. 12

Poster Session Tuesday Evening p. 13 Plenary Luncheon p. 14

Program Reviews:

Renewable Energy Materials p. 17-18

Biomaterials and Pharmaceutical Materials p. 19

Coating Process Fundamentals I p. 20

Electronic Materials and Devices p. 21

Microstructured Polymers I p. 22

Nanostructural Materials and Processes I p. 23-24

Organic Optoelectronic Interfaces p. 25-26

Biocatalysis and Biotechnology p. 27

Coating Process Fundamentals II p. 28

Microstructured Polymers II p. 29

Nanostructural Materials and Processes II p. 30

Poster Sessions p. 31-43 Daily Schedules by Date and Time p. 45-57 Building Names and Map p. 58

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SPECIAL EVENTS & PPB/TAC MEETINGS

Poster Session 1 Tues, May 27, 5:45 – 7:00 PM, McNamara Alumni Center, Memorial Hall Plenary Luncheon Wed, May 28, 11:45- 1:00 PM, McNamara Alumni Center, Johnson Great Room

Faculty- Industry Meet & Greet Wed, May 28, 5:00-5:45 PM, McNamara Alumni Center, Johnson Great Room Poster Session 2 Wed, May 28, 5:45 – 7:30 PM, McNamara Alumni Center, Memorial Hall Poster Awards at 7:00 PM

Characterization Facility Tour Wed, May 28, 7:00-8:30 PM, Shepherd Labs (Meet Greg Haugstad at the CharFac table in McNamara at 7pm)

Planning and Policy Board Breakfast Thu, May 29, 7:00-8:15 AM, The Commons Hotel, Think 5 Room

Technical Advisory Committee (TAC) Meetings & Luncheons Thu, May 29, 12:00-1:45 PM, Coffman Memorial Union, 4rd Floor, Campus Club Meeting rooms in Coffman: BB TAC Room 410 MP TAC Dale Shepherd Room BPM TAC Room 411 NMP TAC Room A CPF TAC Room B/C REM TAC Room 409 Planning and Policy Board Meeting Thu, May 29, 2:00-3:30 PM, Coffman Memorial Union, 3rd Floor, President’s Room

WI-FI Network Guest Access at the University of Minnesota

To connect to the U of M Free Wi-Fi, log in using the “U of M Guest” SSID and enter your active email address. Please note that this service offers no encryption and is limited in bandwidth and capacity.

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PARTNERSHIP PROGRAMS NAMES & ABBREVIATIONS

Biocatalysis and Biotechnology (BB) Enzymatic synthesis for biofuels, biopolymers, biosensors, biofuel cells, and specialty chemicals. Enzymes to produce chemicals for end use and as synthons; biotechnological applications of enzymes for use in biofuels production and chemical synthesis; metabolic and pathway engineering for synthesis of bioactive compounds; microbial synthesis of biodegradable polymers; functional genomics for enzyme discovery; biocatalysis in nanoscale environments; Nanotechnology for micro bioreactors, membrane and interfacial catalysis, bioactive materials, and coatings. Biomaterials and Pharmaceutical Materials (BPM) Synthesis and characterization of novel hard and soft materials and composites for biomedical and pharmaceutical applications; dynamics of mechanical, chemical and transport properties of biomaterials; evaluation and elucidation of materials interactions with biological tissues and media, and with pharmaceuticals. Coating Process Fundamentals (CPF) Process and prototype visualizations, microscopies, nanotesting, NMR and other spectroscopies, and microstructure probes combined with theory, computational methods, and computers to support the electronics, photonics, magnetics, specialty-films, and many other industries. Electronic Materials and Devices (EMD) Focuses on synthesis, structural and chemical characterization, and a plethora of electronic, optical and magnetic characterization techniques. Particular emphasis is placed on the understanding of the fundamentals of electronic structure and transport in electronic and magnetic materials in addition to the materials science, physics and chemistry of the interfaces and nanostructures that play such a vital role in devices. Microstructured Polymers (MP) Design and synthesis of novel polymers, characterization of their structural and mechanical properties, and investigation of their rheology and processing behavior for both commodity and high value-added polymer products. Nanostructural Materials and Processes (NMP) Identifying key molecular parameters and principles governing the assembly and properties of molecular thin films, surfactants, and ordered molecular phases of molecular systems for synthesis of specialty materials in agricultural, cosmetics, pharmaceuticals, personal care, and other businesses. Organic Optoelectronic Interfaces (OEI) The Organic Optoelectronic Interfaces (OEI) program is active in defining critical structure-property relationships for charge transport and excited state behavior in organic semiconductor thin films and single crystals. Fundamental advances guide the design of novel materials and device architectures for application in light-emitting devices, solar cells, sensors and flexible electronics. As a team, expertise in OEI spans all aspects of organic electronics, including molecular synthesis, device design, modeling and characterization. Renewable Energy Materials (REM). Sustainable generation, conversion, storage, and utilization of energy using abundant and nontoxic materials are among the most significant challenges we face in the 21st century. Mission: Develop materials and systems for renewable energy applications

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--NOTES--

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WORKSHOPS Tuesday afternoon through Wednesday

Coating and Printing with Inks, Paints and Particulate

Suspensions (CPF) p.6


Interfacial Rheology, Nanostructural Materials

and Processes (NMP) p. 8

Microneedle Based Delivery of Therapeutics (BPM) p. 9

Materials and Processes for Printed Electronics (OEI/CPF) p. 10


Synthetic Biology and Bioprocessing (BB) p. 12

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Tuesday, May 27 1:30-5:20 PM | Keller Hall, Room 3-180

Coating and Printing with Inks, Paints and Particulate Suspensions

Coating Process Fundamentals Program Satish Kumar, Coordinator

This workshop will focus on issues related to coating and printing with inks, paints, and particulate suspensions. The scope of the workshop includes synthesis and formulation, structure and rheology, wetting and spreading, and drying and solidification. Talks covering fundamentals or applications are welcome. AGENDA

Time Title Authors

1:30 PM Use of Tidas Tester to Assess Dispersion Quality of Filled Systems

Maria Nargiello, Evonik

2:05 PM High Speed Imaging to Characterize Spray-Applied Waterborne Latex Coatings

Keith Kirkwood, Valspar

2:40 PM Silica Dispersions as Reinforcing Additives Waterborne Composites: Coatings and Adhesives

Arthur Scholz, Cabot

3:00 PM Break

3:20 PM Development and Characterization of a Spray Deposited CNT/PVDF Thin Film

Brian Loyola, Sandia

3:55 PM Application of High Throughput Screening for a Clear Concrete Sealer Formula

Vincent Goldman, BASF

4:30 PM Through Thick and Thin—Imaging the Microscopic Structure of Shear Thinning and Thickening Colloidal Suspensions

Xiang Cheng, University of Minnesota

- 6 -



Modern Polymer Characterization Methods I

Microstructured Polymers Program Marc Hillmyer, Program Leader | Tim Lodge, Co-coordinator

Speakers will include: Dr. Paul Bulter, NIST [small-angle neutron scattering] Dr. Willem deGroot, Dow Chemical Company [size exclusion chromatography] Prof. Scott Grayson, Tulane University [mass spectrometry] Prof. Chinedum Osuji, Yale University [small-angle x-ray scattering] Prof. Dan Savin, University of Southern Mississippi [light scattering] Prof. Gila Stein, University of Houston [grazing incidence small-angle x-ray scattering]

AGENDA

Time Title Authors

1:10 PM Light Scattering Characterization of Responsive Materials

Daniel Savin, U of Southern Mississippi

2:10 PM Pushing the Limits on Molecular Structure Determination of Polyolefins using Multi-Detector GPC, CEF and HTLC

Alexander DeGroot, Dow Chemical

3:10 PM Break

3:40 PM Applications of Mass Spectrometry Toward Elucidating the Structure of Synthetic Polymers

Scott Grayson, Tulane University

4:40 PM Small Angle X-ray Scattering: Characterizing Structure and Thermodynamics of Polymer Systems

Chinedum Osuji, Yale University

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Interfacial Rheology

Nanostructural Materials and Processes Program Joe Zasadzinski, Coordinator

The stability of foams, emulsions, and other complex fluid mixtures often is determined by the viscosity and elasticity of the multiple interfaces present in such materials. However, isolating these interfacial properties from the bulk is problematic; it is difficult to create experimental approaches that cleanly separate interfacial properties from bulk properties. It is also often difficult to not permanently disturb the interface during the measurement process, thereby introducing systematic errors into the measurements that can lead to confusion. In our workshop, we will present the state of the art measurements of interfacial viscosity and elasticity at air-water and oil-water interfaces important to technology, physics, and medicine. Each set of interfaces presents a unique set of challenges that can be overcome by proper experimental design and theoretical models.

AGENDA

Time Title Authors

1:30 PM Introduction Joe Zasadzinski, U of M

1:40 PM Drainage and stratification kinetics of foam films Vivek Sharma U of Illinois, Chicago

2:30 PM Characterizing the Dilatational Interfacial Rheology of Insoluable Layers in a Microscale Tensiometer

Shelley Anna, Carnegie Mellon University

3:20 PM Break

3:40 PM Rheology of Bacterial Bioflims: A Tale of Two Microbes

Lynette Cegelski, Stanford University

4:30 PM Interfacial Dynamics of Atmospheric Particles: Cold, Complex and Charged Surfaces

Cari Dutcher, U of M

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Wednesday, May 28 8:30-11:40 AM | Physics & Nanotechnology, Room 110

Microneedle Based Delivery of Therapeutics Workshop

Biomaterials and Pharmaceutical Materials Program Jayanth Panyam, Coordinator

Microneedle technology offers the ability to deliver therapeutic agents across or into the skin with the efficiency of an injection but without the pain. Various microneedle designs have been examined for the purpose of drug delivery including drug-coated solid microneedles, dissolvable polymer microneedles embedded with drug, and hollow microneedles capable of infusing drug solutions. Microneedles can be used to deliver a wide variety of therapeutic agents including small molecules, macromolecules, and colloidal carriers. Therapeutic applications include sustained release of drug molecules as well as vaccine delivery. This workshop will discuss the latest developments in microneedle technology and therapeutic applications.

AGENDA

Time Title Authors

8:25 AM Welcome and Introduction Jayanth Panyam , U of M

8:30 AM 7-Day Microneedle Enhanced Transdermal Delivery: Bench to Bedside

Audra Stinchcomb, U of Maryland

9:15 AM Development and Scale-Up of Microneedle Based Drug Delivery Systems

Lisa Dick, 3M

10:00 AM BREAK

10:30 AM Delivering Macromolecules Through the Skin Using Biodegradable Microstructures

Gary Cleary, Corium International

11:15 AM Panel Discussion

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Wednesday, May 28 8:30-11:40 AM | Keller Hall, Room 3-180

Materials and Processes for Printed Electronics

Organic Optoelectronics Interfaces Program/Coating Process Fundamentals Program Russell Holmes, Program Leader/Lorraine Francis and Satish Kumar Co-program Leaders

This workshop will cover innovations in materials and processes that underlie the development of printed electronics on flexible substrates. Industrial speakers will discuss product ideas and challenges in printed electronics, as well as technical accomplishments in the fabrication of devices by printing electronically functional inks.

AGENDA

Time Title Authors

8:30 AM Hybrid Manufacturing – A Path to Commercialization for Printed and Flexible Electronics

John Heitzinger President, Soligie, Inc.

9:10 AM Additive Printing and Assembly for Large Area Electronic Systems

Greg Whiting PARC

9:50 AM BREAK

10:20 AM Carestream Advanced Materials Aaron Clapp Carestream Health, Inc.

11:00 AM High Performance Inks for Printed Electronics Brett Walker Electroninks

- 10 -


Wednesday, May 28

9:20-11:40 AM | Keller Hall, Room 3-210

Modern Polymer Characterization Methods II Microstructured Polymers Program

Marc Hillmyer, Program Leader

Time Title Authors

9:20 AM Grazing Incidence Small Angle X-Ray Scattering: Characterization of Nanostructured Polymer Films

Gila Stein University of Huston

10:20 AM Break

10:40 AM Applications of Neutron Scattering to Soft Materials Problems

Paul Butler NIST

- 11 -


Wednesday, May 28 1:15 – 5:00 PM | Amundson Hall, Room 240

Synthetic Biology and Bioprocessing Workshop Biocatalysis and Biotechnology Program

Ping Wang, Coordinator

This workshop introduces both frontier advances and industrial practices of industrial biotechnologies. One focus is on synthetic biology which seeks design and synthesis of genetic parts that can be assembled for construction of synthetic circuits and devices, leading to cells possessing non-native cellular mechanisms and functionalities. Both fundamental concepts and technology tools will be discussed along with application potentials. The second half of the workshop discusses essentials for bioprocessing and bio-manufacturing, concerning both operational and instrumental factors. The topics will likely to benefit a variety of biotechnological areas including drug discovery and production, bio-renewable chemical and fuels, protein synthesis, biomaterials, cellular programming and biomedical engineering.

AGENDA

Time Title Authors

1:15 PM Opening Remarks Kechung Zhang, U of M

1:20 PM The Biotechnology Resource Center University of Minnesota; Possibilities and Examples

Tim Tripp, U of M

1:55 PM Photo-Activated Drug Release of a Liposomal Carrier Maria Ogunyankin, U of M

2:30 PM Synthetic Biology Towards Combinatorial Biosynthesis of Pharmaceutically Important Coumarins

Yajun Yan, U of Georgia

3:05 PM BREAK

3:30 PM Engineering New Microbial Factories for Sustainable Chemicals

Kechung Zhang, U of M

4:05 PM Cheminformatic Tools to Enabling Metabolic Synthesis of Novel Chemicals, Drugs, and Fuels

Keith Tyo, Northwestern University

4:40 PM Development of Transcription Activator-Like Effectors as Molecular Tools to Improve Production of Fatty-Acid Derived Compounds in Escherichia coli

Matthew Copeland, U of Wisconsin-Madison

- 12 -


POSTER SESSION I

TUESDAY EVENING 5:45 PM to 7:00 PM

MCNAMARA, MEMORIAL HALL

For a complete list of posters for both days please see pages 31-43

The posters will also be on display Wednesday at the same times.

Poster awards will be announced on Wednesday Night.

- 13 -


PLENARY LUNCHEON

WEDNESDAY 11:45 AM to 1:05 PM

MCNAMARA, JOHNSON GREAT ROOM

Guest Speaker Andrew Ouderkirk

Corporate Scientist 3M , Electronic Markets Materials Division

"Balancing Breadth and Depth of Expertise for Innovation"

Andy Ouderkirk develops new product platforms and establishes entrepreneurial teams within 3M’s Electronics and Energy business. An example is the platform that Andy formed and led developing 3M’s Multilayer Optical Film business. This platform includes the world’s first commercially successful reflective polarizer, now commonly used in smartphones, tablets, and TVs. The platform also includes extremely reflective films used in LED lighting, solar-control films, and light piping. Andy is a lead developer of a framework in 3M for managing people, culture, and processes for platforms and entrepreneurial activities. Andy is an inventor of 176 US patents, is a member of the National Academy of Engineering, was awarded the Fast Company Fast 50, the American Chemical Society Award for creative invention, and the 2013 R&D Magazine Innovator of the year. He has served or is a board member of Singapore’s National Research Foundation, Singapore Economic Strategy Committee, and the USC Center for Global Innovation.

- 14 -


PROGRAM REVIEWS

Renewable Energy Materials p. 17-18

Biomaterials and Pharmaceutical Materials p. 19

Coating Process Fundamentals I p. 20

Electronic Materials and Devices p. 21

Microstructured Polymers I p. 22

Nanostructural Materials and Processes I p. 23-24

Organic Optoelectronic Interfaces p. 25-26

Biocatalysis and Biotechnology p. 27

Coating Process Fundamentals II p. 28

Microstructured Polymers II p. 29

Nanostructural Materials and Processes II p. 30

Please note: All University of Minnesota authors unless otherwise noted

- 15 -


---Notes---

- 16 -


Tue, May 27, 1:30-5:20 PM | Physics & Nanotechnology, Room110

Renewable Energy Materials Program Review Eray Aydil and Uwe Kortshagen, Co-Program Leaders

Time Title Authors: University of Minnesota author

unless otherwise noted

1:30 PM Effects of Alkali Metal Impurities on the Microstructure and Electronic Properties of Cu2ZnSnS4 Thin Films

Melissa Johnson Sergey Baryshev ( Argonne Nat’l Lab), Elijah Thimsen, Michael Manno, Xin Zhang, Chris Leighton, Eray Aydil

1:50 PM Surface Chemistry and Colloidal Forces for Nanocrystal Stability in Media Spanning Hexane to Water

Lance Wheeler Nicolaas Kramer, Uwe Kortshagen

2:10 PM Synthesis of Metal-Sulfide Nanocrystals with Controlled Composition and Crystal Structure by a Nonthermal Plug Flow Plasma Reactor

Elijah Thimsen Uwe Kortshagen, Eray Aydil

2:30 PM Light-Induced Hydrosilylation of Silicon Nanocrystals

Jeslin Wu Anne Sledd (Carlton Col.), Uwe Kortshagen

2:50 PM Insights into the Microstructure Development of Polycrystalline Cu2ZnSn(SxSe1-x)4 Thin Films During Annealing of Colloidal Nanocrystal Coatings

Boris Chernomordik Amelie Beland, Anne Hunter, Priyanka Ketkar, Donna Deng, Lorraine Francis, Eray Aydil

3:10 PM Crossover from Intergranular Hopping to Conventional Charge Transport in Pyrite Thin Films

Xin Zhang Michael Manno, Andrew Baruth, Melissa Jophnson, Eray Aydil, Chris Leighton

3:30 PM Break

4:00 PM UV and Air Stability of High-Efficiency Photoluminescent Silicon Nanocrystals

Jihua Yang Richard Liptak, David Rowe, Jeslin Wu, James Casey, David Witker, Steve Campbell, Uwe Kortshagen

- 17 -


Renewable Energy Materials Program Review, Continued

4:20 PM Plasmonic Properties of Boron and Phosphorus Doped Silicon Nanocrystals

Nicolaas Kramer Katelyn Schramke, Uwe Kortshagen

4:40 PM Synthesis of Abundant Metal Sulfides for Photovoltaic Applications using Microwave Heating

Theodore Knutson Parker Hanson, Eray Aydil, R. Lee Penn

5:00 PM Adjourn

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Wed, May 28, 1:15-5:00 PM | PAN, Room 110

Biomaterials and Pharmaceutical Materials Program Review

Ron Siegel, Program Leader

Time Title Authors: University of Minnesota author unless otherwise noted

1:20 PM Semi-Solid Biodegradable Polymers for Drug Delivery: Recent Progress

Chun Wang

1:40 PM The Design of Novel Peptide-Amphiphiles for Targeted Thermosensitive Stealth Liposomes.

Kamlesh Shroff Efrosini Kokkoli

2:00 PM Engineering of Biomaterials Using Self-Assembling Biopolymers

Wei Shen

2:20 PM Successful Development of 5-Fluorocytosine Through Integrated Crystal and Particle Engineering

Calvin Sun S. Reddy Perumalla

2:40 PM Break

3:10 PM New Results on Remote Sensing Using Hydrogels Ronald Siegel

3:30 PM Cardiovascular Medical Devices Based on Engineered Tissue Tubes

Zeeshan Syedain Robert Tranquillo

3:50 PM Surface Functionalization of Nanoparticles with Fibrinolytic Enzymes to Improve Their Intratumoral Penetration

Ameya Kirtane Jayanth Panyam

4:10 PM Investigating the Role of Polymer Concentration and Hydrogen Bonding on the Physical Stability of Nifedipine-PVP Solid Dispersions

Vishard Ragoonanan Raj Suryanarayanan

4:30 PM Adjourn

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Wed, May 28, 1:15-5:00 PM | Keller Hall, Room 3-180

Coating Process Fundamentals Program Review I

Lorraine Francis and Satish Kumar, Co-Program Leaders


1:30 PM Toward an Understanding of Electrostatic Assist: Experiments and Models for Electrohydrodynamic Deformation of Liquids in Cavities

Aruna Ramkrishnan Satish Kumar

1:50 PM Three Dimensional Analysis of Liquid Transfer Between a Cavity and a Moving Roll

Diego Campana (PUC-Rio) Marcio Carvalho (PUC-Rio)

2:10 PM Electrohydrodynamic Effects in the Spreading of Liquid Films

Andrew Corbett Satish Kumar

2:50 PM Break

3:10 PM Slot Coating of Particle Suspensions Simone Bochner de Araujo ( PUC-Rio) Marcio Carvalho (PUC-Rio)

3:30 PM Dynamic Wetting Failure in Surfactant Solutions Chen-Yu Liu Satish Kumar

3:50 PM Simultaneous Multilayer Coating of Miscible Solutions

Ryo Horiuchi ( Asahi Kasei) Wieslaw J. Suszynski, Satish Kumar, Marcio Carvalho (PUC-Rio)

4:10 PM Drying Regimes for Colloidal Droplets Spreading on Heated Inclined Substrates

Leonardo Espin Satish Kumar

4:30 PM Tour of CPF Labs

- 20 -


Wed, May 28, 1:15-5:00 PM | PAN, Room 130

Electronic Materials and Devices Program Review

Steve Koester, Program Leader


1:15 PM Overview of the Electronic Materials and Devices (EMD) Program

Steven Koester

1:40 PM Graphene-Based Wireless Sensors Eric Olson Mona Ebrish, David Deen, Rui Ma, He Shao, Steven Koester

2:10 PM Hybrid Molecular Beam Epitaxy Growth of Binary and Ternary Oxide Films

Bharat Jalan

2:40 PM Novel Electrolytes for High Performance Electrolyte Gated Transistors

Jae-Hong Choi Yuanyan Gu, Wei Xie, Daniel Frisbie, Timothy Lodge

3:00 PM Break

3:30 PM Phase Stability and Electronic Transport Mechanisms in Thin Film Iron Pyrite

Xin Zhang, Tom Scott (U of NE), Tyler Socha, David Nielson, Mike Manno, Melissa Johnson, Yuqi Yan, Peter Dowben, (U of NE), Eray S. Aydil, Chris Leighton,

3:50 PM Film Growth and Electronic Transport Study of BaSnO3 Deposited via High Pressure Oxygen Sputtering

Koustav Ganguly Palak Ambwani, Jong Seok Jeong, Andre Mkhoyan, Chris Leighton, Bharat Jalan

4:20 PM Recent Progress in Ferromagnet-Semiconductor Heterostructures

Chad Geppert S. Patel, Kevin Christie, Chang Liu, Lee Wienkes, Chris Palmstrom, Paul Crowell

- 21 -



Microstructured Polymers Program Review I

Marc Hillmyer, Program Leader


1:40 PM Introduction Marc Hillmyer

1:50 PM Polylactide Vitrimers Jake Brutman Paula Delgado, Marc Hillmyer

2:10 PM Scalable Production of Mechanically Tunable Block Polymers from Sugar

Debbie Schneiderman, Mingyong Xiong, Frank Bates, Marc Hillmyer, Kechun Zhang

2:30 PM Block Co-Oligomers for Lithography Morgan Schulze Marc Hillmyer

2:50 PM Carboxy-Telechelic Polyolefins in Crosslinked Elastomers

Henry Martinez Marc Hillmyer

3:10 PM Break

3:50 PM The Order-Disorder Transition in Short Diblock Copolymers

Timothy Gillard Sangwoo Lee, Frank Bates

4:10 PM Diblock Copolymer Surfactants for Cell Membrane Sealing

Karen Haman Frank Bates

4:30 PM Designing Chewing Gum Rheology using the Block Copolymer Toolkit

Alex Mannion Sangwoo Lee, Luca Martinetti, Frank Bates, Chris Macosko

4:50 PM Metastability of Aqueous Methylcellulose Solutions

John McAllister Joseph Lott, Pater Schmidt, Timothy Lodge, Frank Bates

- 22 -

https://orgs.cems.umn.edu/iprime2014/admin/presentation2.php?presid=3962



Nanostructural Materials and Processes Program Review I Alon McCormick, Program Leader


1:20 PM Introduction--Overviews Alon McCormick, Greg Haugstad, Daniel Frisbie, Andreas Stein

1:40 PM Overview of Nano-Characterization Methods Applied to Multiphase, Biomedical and Liquidy Materials

Greg Haugstad

1:55 PM Characterization of Electro-Nanosprayed Drug Particles Suspended in a Polymer Matrix

Jacob Warner Greg Haugstad, Jim Lasch (Nanocopoeia),Allison Huessler (Nanocopoeia), Pat Ryan (Nanocopoeia), Bob Hoerr (Nanocopoeia), Han Fu (Nonocopoeia)

2:10 PM Characterization of Drug and Polymer Crystallization in Coatings of Drug plus Polymer

Klaus Wormuth

2:25 PM Measuring Polymer-Nanoparticle Interactions Using Atomic Force Microscopy

Arthur Scholz Greg Haugstad, Chris Macaosko

2:40 PM Break

3:20 PM Step Wise Growth and Comprehensive Characterization of Pi-Conjugated Molecular Wires on Gold

Abel Demissie Daniel Frisbie

3:40 PM Electrical Characterization of π-conjugated Molecular Wires by Conductive Probe Atomic Force Microscopy (CP-AFM)

Davood Taherinia Daniel Frisbie

- 23 -


Nanostructural Materials and Processes Program Review I, Continued

4:00 PM

Ion-Selective Electrodes Based on Templated Porous Carbon

Jinbo Hu Philippe Buhlmann, Andreas Stein

4:20 PM Li8ZrO6 as a Cathode Material for Lithium Ion Batteries: a Computation-guided Experimental Study

Yuan Fang Bo Wang, Benjamin Wilson, Nam Tran, Anh Vu, Andreas Stein, Donald Truhlar, William Smyrl

4:40 PM 3DOm Carbon Materials Utilizing an Ionic Liquid Precursor for High Performance Supercapacitors

Benjamin Wilson Andreas Stein

5:00 PM Adjourn

-

- 24 -



Organic Optoelectronic Interfaces Program Review Russell Holmes, Program Leader


1:20 PM Introduction Russell Holmes

1:25 PM Development of a Self-Aligned Manufacturing Process for Printed Electronics-Part 1

Ankit Mahajan Woo Jin Hyun , Steven Brett Walker (Harvard),Jennifer Lewis (Harvard),Lorraine Francis, Daniel Frisbie

1:45 PM Development of a Self-Aligned Manufacturing Process for Printed Electronics-Part 2

Woo Jin Hyun Ankit Mahajan , Steven Brett Walker (Harvard),Jennifer Lewis (Harvard),Lorraine Francis, Daniel Frisbie

2:05 PM Analytical Theory of Magneto-Electroluminescence in Organic Heterojunction Light-Emitting Devices

Feilong Liu Scott Crooker (Los Alamos), Paul Ruden, Darryl Smith (Los Alamos)

2:25 PM Synthesis and Crystal Engineering of Tetracene-Based Organic Semiconductors

Matthew Bruzek Chris Douglas, Daniel Frisbie

2:45 PM Understanding the Rate-Limiting Processes for the Purification of Small Molecule Organic Semiconductors

Nathan Morgan Yi Zhang, Erich Molitor (Dow), Bruce Bell (Dow),Russell Holmes, Ed Cussler

3:05 PM Break

3:40 PM 7.9% Efficient Vapor-Deposited Organic Photovoltaic Cells Based on a Simple Mixed Heterojunction

Yunlong Zou James Holst (Sigma-Aldrich),Yong Zhang (Sigma-Aldrich), Russell Holmes

- 25 -


Organic Optoelectronic Interfaces Program Review, Continued

4:00 PM Correlation between Mechanical Strain and Workfunction in Organic Semiconductors

Yanfei Wu Geoffrey Rojas, Wei Xie, Greg Haugstad, Daniel Frisbie

4:20 PM Dilute Donor Organic Photovoltaic Cells Incorporating a Photoactive Host

Matthew Menke Russell Holmes

4:40 PM Excited State Dynamics and Interfacial Electron Transfer in an Electronically Tunable Series of Thiophene Oligomers

Antonio Sanchez Diaz Miguel Planells Dilunde (Imperial College London), Amanda Oehrlein, Neil Robertson (U of Edinburgh), David Blank

5:00 PM Adjourn for Poster Session

- 26 -


Thu, May 29, 8:20-11:40 AM | Keller Hall, Room 3-111

Biocatalysis and Biotechnology Program Review

Ping Wang, Program Leader


8:20 AM Introduction Ping Wang

8:30 AM Enzymes for Industrial Chemistry Larry Wackett

9:00 AM Enzymatic Protein Labeling Using Prenyltransferases

Mark Distefano

9:30 AM Scalable Production of Mechanically Tunable Block Polymers from Sugar

Kechun Zhang

10:00 AM Break

10:30 AM Carbonization and Nanofabrication of Cellulosic Materials for Bio-Electronic Applications

Ping Wang

11:00 AM Domestication of Fungi to Improve Complex Traits: Non-GMO Trichoderma Variants that Grow as Single Cells or Degrade Cellulose Faster

Hui Lin Michael Travisano, Romas Kazlauskas

- 27 -



Coating Process Fundamentals Program Review II

Lorraine Francis & Satish Kumar, Co-Program Leaders


8:30 AM Microstructure and Performance of Block Copolymer Modified Epoxy Coatings

Tuoqi Li Frank Bates, Lorraine Francis

8:50 AM Fundamental Studies of Stress Development in the Absence of Lateral Drying

Kyle Price Alon McCormick, Lorraine Francis

9:10 AM The Drying Behavior of Hard Particulate Coatings Yan Wu Lorraine Francis

9:30 AM Novel Methods for Embedding High-Resolution, High-Aspect Ratio Printed Metal Lines in Plastic

Ankit Mahajan

9:50 AM Break

10:10 AM Processing of Solar Absorber Coatings from Nanocrystal Dispersions

Bryce Williams Eray Aydil, Lorraine Francis

10:30 AM Surfactant Effects in Coating of Discrete Objects Weihua Li Satish Kumar

10:50 AM Particle Tracking as a Tool for Local, Real-Time Analysis of Sag in Drying Coatings

Robert Lade Chris Macosko, Lorraine Francis

11:10 AM Study of Water-Based Coatings For 3D Printed Parts

Jenny Zhu (Stratasys)

11:40 AM Adjourn

- 28 -



Microstructured Polymers Program Review II Marc Hillmyer, Program Leader


8:40 AM Cationic Glycopolymeric pDNA Delivery Systems Exhibit Molecular Weight, Charge S

Yaoying Wu Miao Wang, Dustin Sprouse, Adam Smith (Ole Miss),Theresa Reineke

9:00 AM Solution-State Polymer Assemblies Influence BCS Class II Drug Dissolution and Supersaturation Maintenance

Swapnil Tale

9:20 AM Polymeric Nanocylinders by Combining Block Copolymer Self-Assembly and Nanoskiving

Mohammadreza Nasiri, Arthur Betrand, Marc Hillmyer, Theresa Reineke

9:40 AM Improving Fracture Toughness in Unsaturated Polyester Using Extremely Low Loadings of Graphene or Graphene Oxide

Nicholas Petkovich Yong Tae Park (Myongji U) Greg Moriarty, Clement Chan, Taewon Suh, Wenhao Liu, Chris Macosko, Andreas Stein

10:00 AM Break

10:20 AM Molecular Exchange Through the Membranes of Polymersomes with Ionic Liquid Interiors Dispersed in Water

Soonyong So Timothy Lodge

10:40 AM Phase Behavior of Symmetric Diblock Copolymer-Homopolymer Ternary Blends

Robert Hickey Tim Gillard, Brian Habersberger, Timothy Lodge, Frank Bates

11:00 AM Chain Exchange in Block Copolymer Micelles Jie Lu Frank Bates, Timothy Lodge, SooHyung Choi

11:20 AM Reactive Compatibilization of Polyethylene and Poly(lactic acid)

Christopher Thurber Yuewen Xu Timothy Lodge, Chris Macosko

- 29 -



Nanostructural Materials and Processes Program Review II

Alon McCormick, Program Leader


8:20 AM Two-Dimensional Zeolites Michael Tsapatsis

8:40 AM Overviews-Introduction Ilja Siepmann, Wayne Gladfelter, Joseph Zasadzinski

9:00 AM Understanding the Unusual Adsorption Behavior in Hierarchical Zeolite Nanosheets

Peng Bai Michael Tsapatsis, Ilja Siepmann

9:13 AM Molecular Modeling of Fluid Phase Equilibria for Ternary Mixtures With Two Or Three Liquid Phases

David Harwood Angela Cortes-Morales, Peng Bai, Ilja Siepmann

9:20 AM Binding and Electron Transfer Studies of Terthiophene Dyes with Zinc Oxide Nanocrystals

Amanda Oehrlein Wayne Gladfelter

9:40 AM Break

10:20 AM Continuous vs Pulsed Near Infra-red Heating of Hollow Gold Nanoparticles - Implications and Applications

Joseph Zasadzinski Maria Ogunyankin, Jeong Eun Shin

10:40 AM The Role of Cryogenic Electron Microscopy in Soft Materials Processing: Clarifying Structure Questions

Hanseung Lee Chris Macosko, Frank Bates, Jing Han, Chris Frthem, Eric Morrison (EarthClean Corp)Joseph Zasadzinski, Alon McCormick

11:00 AM Overview-Introduction Lee Penn

11:05 AM Two-Step Phase Transformation of Anatase to Rutile in Aqueous Suspension

Kairat Sabyrov Lee Penn

11:25 AM Heterogeneous Oriented Aggregation and Phase Transformation in Iron Oxide Nanoparticles

Jennifer Soltis Martin Kuhn (Arizona State), Jacqueline Harapan, Lee Penn

11:45 AM Adjourn

- 30 -


POSTER SESSIONS Tue & Wed, May 27 & 28, 5:45-7:30 PM

McNamara Alumni Center, Memorial Hall

In numerical & alphabetical order by IPrime Partnership Program

- 31 -


1/2

BB

3/497

BB

4/5

BPM

6/7

BPM

8/9

BPM

10/11

BPM

12/13

BPM

14/1498

BMP

15/16

CPF

17/18

CPF

19/20

CPF

21/22

CPF 4599 CPF

45 MP

44/43

EMD

42/41

EMD

40/39

EMD

38/37

EMD

36/35

EMD

34/33

EMD

32/31

EMD

30/29

CPF

28/27

CPF

26/25

CPF

24/23

CPF

46/47

MP

48/49

MP

50/51

MP

52/53

MP

54/55

MP

56/57

MP

58/59

MP

60/61

MP

62/63

MP

65/64

MP <>/79 OEI

78/77

NMP

7600 7601

BB

76/75

NMP

74/73

NMP

72/71

NMP

70/69

NMP

6901 NMP

6801BB 68

NMP

67/66

MP

80/81

OEI

82/83

OEI

84/85

OEI

86/87

OEI

8801 EMD 8701 NMP

88/89

OEI

9401 MP

94/93

REM

92/91

REM

9100 REM

90/<>

REM

IPrime Poster Session Layout

McNamara Alumni Center, Memorial Hall, May 30, 5:45-7:30p

MSI

MRS

EC

Char

Fac

BTI /

UIC

Stage

EXIT

Johnson Great Room

Handouts Buffets

Walnut St. Entrance

Uni

vers

ity A

ve

Oak St SE

Restrooms

Memorial Hall Not to Scale

MO

T

- 32 -


Poster Sessions

University of Minnesota author unless otherwise noted

Biocatalysis and Biotechnology

Poster # Program Author Title

1 BB Lu Wang Thin-film Enzyme Paper Sensor for Point-of-Care Bioassay

2 BB Bo Tang Z Qiao

Growth of Bacteria on Nano-Carbon Electrode for Power Generation

3 BB Yi-Shu Tai Mingyong Xiong, Kechun Zhang

Engineering Biosynthesis of Medium-Chain Esters in Escherichia coli

Biomaterials and Pharmaceutical Materials

Poster # Program Author Title

4 BPM Yogesh Dhande Bharat Wagh, Theresa Reineke

Liver-targeted Glycopolymers for Gene Therapy

5 BPM Haley Phillips Zachary Tolstyka, Theresa Reineke

Stabilization of DNA-Copolymer Complexes by Polytrehalose and Polyglucose

6 BPM Bin Xu Ronald Siegel, Wei Shen

Preparation of Recombinant Protein Conjugated Gold Nanoparticles for Anti-HIV Application

7 BPM Mamta Kapoor Ronald Siegel

Platform-Technology Based on Prodrug/Enzyme Systems for Rapid Absorption of Hydrophobic Drugs: Toward Intranasal Treatment of Seizure Emergencies

8 BPM Andrew Mullins Tom Hoye, Marc Hillmyer

Bio-Based Block Copolymers Prepared Via a Novel RAFT Agent

9 BPM Timothy Pearce

Efie Kokkoli

DNA Nanotubes and Nanotapes Formed Via Self-Assembly of ssDNA-Amphiphiles

10 BPM Rachel Levine Timothy Pearce, Maroof Adil, Efie Kokkoli

Peptide-Targeted Liposomal Gene Delivery for Cancer Therapy

11 BPM Carolyn Scott Efie Kokkoli

Fibronectin Mimetic Peptide-Amphiphile Hydrogels for 3D Cell Entrapment

- 33 -



Biomaterials and Pharmaceutical Materials, Continued

Poster # Program Authors Title

12 BPM Xingchu Gong Changquan Calvin Sun

A New Brittleness Index for Tablets and its Relationship with Tablet Friability

13 BPM Benyong Lou Changquan Calvin Sun

Significant Expansion of Solid State Landscape of Molecules Based on Charge-Assisted Hydrogen Bonding Interactions

14 BPM Justin Song (Upsher-Smith) Dan Virnig, Roger Zanon

Assessment of Drug-Product-Representative Excipient Compatibility by Isothermal Microcalorimetry

Coatings Process Fundamentals Poster # Program Authors Title

15 CPF Ankur Bordoloi Ellen Longmire

Surface Wetting Effects on Drop Motion Through a Circular Orifice

16 CPF Leonardo Espin Satish Kumar

Drying Regimes for Colloidal Droplets Spreading on Heated Inclined Substrates

17 CPF Aruna Ramkrisnan Satish Kumar

Toward an Understanding of Electrostatic Assist: Experiments and Models for Electrohydrodynamic Deformation of Liquids in Cavities

18 CPF Weihua Li Satish Kumar

Surfactant Effects in Coating of Discrete Objects

19 CPF Chen-yu Lui Satish Kumar

Dynamic Wetting Failure in Surfactant Solutions

20 CPF Chung Hsuan Huang Satish Kumar

Mechanisms of Liquid Transfer in Printing Processes

21 CPF Robert Lade

Chris Macosko, Lorraine Francis

Particle Tracking as a Tool for Local, Real-Time Analysis of Sag in Drying Coatings

22 CPF Sarit Dutta Kevin Dorfman, Satish Kumar

Dynamic Simulation of Polymer Adsorption in Flowing Fluids for Design of Polymer Thin-Film Materials

- 34 -



Coatings Process Fundamentals, Continued


23 CPF Ryo Horiuchi Asahi Kasei, Wieslaw Suszynski, Satish Kumar, Marcio Carvalho (PUC-Rio)

Simultaneous Multilayer Coating of Miscible Solutions

24 CPF Yan Wu Lorraine Francis

The Drying Behavior of Hard Particulate Coatings

25 CPF Andrew Corbett Satish Kumar

Electrohydrodynamic Effects in the Spreading of Thin Liquid Films

26 CPF Bryce Williams Eray Aydil, Lorraine Francis

Processing of Solar Absorber Coatings from Nanocrystal Dispersions

27 CPF Kyle Price Wenjun Wu (Arkema) Stephanie Kong, Alon McCormick, Lorraine Francis

Investigating the Influence of Particle Morphology on the Performance of Core-Shell Latexes

28 CPF Xiang Cheng Through Thick and Thin – Imaging the Microscopic Structure of Shear Thinning and Thickening Colloidal Suspensions

29 CPF Koki Tomioka (Nitto Denko Corp.), Satish Kumar

Polymer Processing Simulation: Obtaining the Parameters in Viscoelastic Constitutive Equations

Electronic Materials and Devices


30 EMD Hongchul Moon Timothy Lodge, Daniel Frisbie

Solution Processable Electrochemiluminescent Ion Gels for Flexible, Low Voltage, Emissive Displays on Plastic

31 EMD Kevin Christie Efficient Spin Injection in Co2FexMn1-xSi / GaAs Heterostructures

32 EMD Changjiang Liu Electrical Detection of FMR in Epitaxial FM/n-GaAs Heterostructures by Tunneling Anisotropic Magnetoresistance

33 EMD Peng Xu Daniel Phelan, Seok Jeong, Andre Mkhoyan, Bharat Jalan

Stoichiometry-Control of Electronic Transport at Complex Oxide Interfaces

- 35 -



Electronic Materials and Devices, Continued

34 EMD Chang-Hyun Kim Daniel Frisbie

Simultaneous Electrochemical and Field-effect Control of Fermi-level Position and Electronic Transport in Graphene Transistors

35 EMD Koustav Ganguly Palak Ambwani, Jong Seok Jeong

Film Growth and Electronic Transport Study of BaSnO3 Deposited via High Pressure Oxygen Sputtering

36 EMD Mona Ebrish Understanding the Electrical Properties of Graphene Using the Quantum Capacitance Effect

37 EMD Nazila Haratipour Yoska Anugrah, Sanfeng Wu (U of WA), Xiaodong Xu (U of WA), Steven Kostner

Chemical Doping for Threshold Control and Contact Resistance Reduction in Graphene and MoS2 Field Effect Transistors

38 EMD Srinivas Polisetty Shameek Bose, Shun Wang, Chris Leighton

Influence of the SrTiO3 Phase Transformation on Magnetotransport Phenomena in Ultrathin SrTiO3(001)/La0.5Sr0.5CoO3-δ

39 EMD Forrest Johnson Sreejith Karthikeyan, Bing Lou, Stephen Campbell

High Performance Metal Oxide Broken Gap Junctions

40 EMD Palak Ambwani Bharat Jalan, Chris Leighton

Highly-Stoichiometric Epitaxial SrTiO3 via High-Presure Oxygen Sputter Deposition

41 EMD Liam O’Brien M.J. Erickson, Dima Spivak H. Ambaye ( Oak Ridge National Lab [ORNL]) R. J. Goyette,( ORNL), V. Lauter, ( ORNL), Paul Crowell, Chris Leighton

Kondo Suppressed Spin Accumulation in Nanoscopic Non-Local Spin Transport Devices

42 EMD Jeff Walker Shun Wang, Chris Leighton

Charge Modulation in La1-xSrxCoO3-δ Thin Films via Ion Gel Gating

43 EMD Yang Su Mona Ebrish, Eric Olson, Steven Koester

Physical and Electrical Characterization of Exfoliated SnSe2 Thin Films

44 EMD Shameek Bose Engineering Magnetism and Transport at Cobaltite Interfaces via Controlled Oxygen Vacancy Ordering

- 36 -



Microstructured Polymers


45 MP Matthew Irwin Polymeric Bicontinuous Microemulsions as Versatile Templates for Structured, Functional Materials

46 MP Tuoqi Li

Microstructure and Performance of Block Copolymer Modified Epoxy Coatings

47 MP Yiming Zeng Mechanism and Application of Selective Hydrogen-Deuterium Exchange Reaction for Saturated Polyolefins

48 MP Ralm Ricarte Electron Microscopy Characterization of Solid State Drug/Polymer Dispersions

49 MP Jennifer Laaser Timothy Lodge

Synthesis and Characterization of Polybasic Micelles for Amphiplex Formation and Gene Delivery

50 MP Jae-Hong Choi

Yuanyan Gu, Kihyun Hong, Wei Xie, Daniel Frisbie, Timothy Lodge

High Capacitance, Photo Patternable Ion Gel Gate Insulators for High Performance Electrolyte Gated Transistors

51 MP Theodoros Vasilakopoulos Synthesis of Asymmetric SIOS' Tetrablock Terpolymers

52 MP James Gallagher Marc Hillmyer, Theresa Reineke

Thermoset Materials from Sugar-Derived Dilactones

53 MP Jeffrey Ting Tusher Navale, Frank Bates, Theresa Reineke

Design of Tunable HPMCAS-inspired Polymers as Modular Oral Excipients

54 MP Alex John William Tolman, Marc Hillmyer

High-Activity Dehydrative Decarbonylation Catalysts for the Production of Olefins from Biomass

55 MP Dustin Sprouse Theresa Reineke

Block vs. Statistical Glycopolycations Containing Primary & Tertiary Amines for Gene Delivery

56 MP Timothy Gillard Pavani Medapuram, Frank Bates, David Morse

Comparison between Experiments, Simulations, and Advanced Theory: Scattering, Calorimetry, and ODT in Short Diblock Copolymers

57 MP Siddharth Chanpuriya Synthesis of ABCA' Tetrablock Terpolymers for Phase Behavior Studies

- 37 -



Microstructured Polymers, Continued


58 MP Pranav Agrawal Scott White, Nilesh Ingle Theresa Reineke, Kevin Dorfman

Controlled Delivery of Therapeutics to a Single Cell Using Biomicrofluidics

59 MP Zaifei Wang Chris Macosko, Frank Bates

Tuning Surface Properties of Poly(butylene terephthalate) Melt Blown Fibers by Alkaline Hydrolysis and Fluorination

60 MP Yuewen Xu Chris Macosko, Marc Hillmyer

Reactive Compatibilization of Polylactide (PLA)/Polyolefin Blends

61 MP Paula Delgado Kristina Masica, Steven Heilmann

Hydrochars as Reinforcement in Poly(L-lactide) Composites

62 MP Samuel Dalsin Marc Hillmyer, Frank Bates

Bulk Rheological Properties of Polypropylene-Based Bottlebrush Polymers

63 MP Taher Ghasimakbari Catch and Hunt for ODT in Cubic Phases

64 MP Ayumu Sakai (INOAC) Chris Macosko

Preparation and Characterization of Heat-Resistant Polyurethane Foam Using Polycarbonatediol

65 MP Lindsay Johnson Ligeng Yin, Marc Hillmyer

Hydroxypropyl Methylcellulose (HPMC) Esters for Hydrophobic Drug Dissolution Enhancement

66 MP Liangliang Gu

Controlling Pore Structure of Macroporous Polyethylene Derived from Cocontinuous Polyethylene/Polylactic Acid Blends

67 MP Teresa Sells Molecular Dynamics Simulations of Multiblock Polymers

Nanostructural Materials and Processes

68 NMP Benjamin Wilson Andreas Stein

3DOm Carbon Materials Utilizing an Ionic Liquid Precursor for High Performance Supercapacitors

69 NMP Jinbo Hu Phillipe Buhlmann, Andreas Stein

Ion-Selective Electrodes Based on Templated Porous Carbon

- 38 -



Nanostructural Materials and Processes, Continued


70 NMP Camille Malonzo Wood-Templated CeO2: A Highly Stable Porous Structure

for Enhancing the Kinetics of Thermochemical CO Production by CeO2

71 NMP Peng Bai David Olson (Rutgers), Michael Tsapatisis, Ilja Siepmann

Understanding the Unusual Adsorption Behavior in Hierarchical Zeolite Nanosheets

72 NMP Greg Haugstad Overview of Nano-Characterization Methods Applied to Multiphase, Biomedical and Liquidy Materials

73 NMP Connor Colling Greg Haugstad, Alon McCormick, Maggie Zeng (Boston Scientific), Klaus Wormuth

Nanoscale Analysis of UV-cured Catheter Coatings Using Novel AFM Scanning Methods and MATLAB Data Processing

74 NMP Yuan Fang Bo Wang, Benjamin Wilson Nam Tran, Anh Vu, Andreas Stein, Donald Truhlar, William Smyrl

Li8ZrO6 as a Cathode Material for Lithium Ion Batteries: a Computation-guided Experimental Study

75 NMP Peter Barnett (Covidien) Klaus Wormuth

Characterization of Drug and Polymer Crystallization in Coatings of Drug plus Polymer

76 NMP David Riehm Alon McCormick

How Do Oil Dispersants Work? Exploring the Physical Phenomena Which Drive Chemical Oil Spill Dispersion

77 NMP Hanseung Lee Jing Han, Eric Morrison (EarthClean Corp), Chris Frethem, Joseph Zasadzinski, Chris Macosko, Frank Bates, Alon McCormick

The Role of Cryogenic Electron Microscopy in Soft Materials Processing: Clarifying Structure Questions

- 39 -



Nanostructural Materials and Processes, Continued


78 NMP Jake Warner Jim Lasch (Nanocopoeia), Pat Ryan (Nanocopoeia), Bob Hoerr (Nanocopoeia), Han Fu (Nanocopoeia), Greg Haugstad

Characterization of Electro-Nanosprayed Drug Particles Suspended in a Polymer Matrix

Organic Optoelectronic Interfaces


79 OEI Sha Shi Feilong Liu, Paul Ruden

Spin-injection for Organic Semiconductor Spin-Valves

80 OEI Matthew Menke Russell Holmes

Dilute Donor Organic Photovoltaic Cells Incorporating a Photoactive Host

81 OEI Yunlong Zou James Holst (Sigma-Aldrich Corp), Yong Zhang (Sigma-Aldrich), Russell Holmes

7.9% Efficient Vapor-Deposited Organic Photovoltaic Cells Based on a Simple Mixed Heterojunction

82 OEI Tyler Mullenbach Russell Holmes

Measuring Recombination and Transit Rates Using Impedance Spectroscopy

83 OEI Tom Pundsack Zhongjian Hu (U of TX), David Vanden Bout (U of TX), David Blank

Mimicking P3HT Aggregation Using a Triblock Copolymer in Solution

84 OEI Yanfei Wu Geoffrey Rojas, Wei Xie, Greg Haugstad, Daniel Frisbie

Correlation between Mechanical Strain and Workfunction in Organic Semiconductors

85 OEI Phillip Goff David Blank

Pump-Probe Studies of the Ultrafast Dynamics of Conjugated Statistical Copolymers

- 40 -



Organic Optoelectronic Interfaces, Continued


86 OEI William Ogden Kathryn McGarry, Christopher Douglas

Synthesis and Crystal Structure Engineering of Rubrene Derivatives for Use in Organic Electronic Devices

87 OEI Tom Fielitz Russell Holmes

Organic Thin-Film Annealing: Effects on Morphology and Epitaxial Organic Photovoltaic Device Performance

88 OEI Ankit Mahajan Woo Jin Hyun, Steven Brett Walker (Harvard), Jennifer Lewis (Harvard), Lorraine Francis, Daniel Frisbie

Development of a Self-Aligned Manufacturing Process for Printed Electronics

89 OEI Abel Demissie Daniel Frisbie

StepWise Growth and Comprehensive Characterization of Pi-Conjugated Molecular Wires on Gold

Renewable Energy Materials


90 REM Boris Chernomordik

Amelie Beland, Anne Hunter, Priyanka Ketkar, Donna Deng, Lorraine Francis, Eray Aydil

Insights into the Microstructure Development of Polycrystalline Cu2ZnSn(SxSe1-x)4 Thin Films During Annealing of Colloidal Nanocrystal Coatings

91 REM Gregory Moriarty Nicholas Petkovich, Siyao He, Yuqiang Qian, Taewon Suh, Clement Chan, Chris Macosko, Andreas Stein

Improvements in Fracture Toughness of Unsaturated Polyester by Addition of Low Loadings of Functionalized Graphene Oxide

92 REM Katelyn Schramke Nicolaas Kramer, Uwe Kortshagen

Localized Surface Plasmon Resonance of Boron and Phosphorus Doped Silicon Nanocrystals

- 41 -



Renewable Energy Materials, Continued


93 REM Sreejith Karthikeyan

Mandip Sibakoti, Richard Liptak (Rose-Hulman Inst of Tech), Sang Ho Song, Joel Abrahamson, Eray Aydil

Photovoltaic Application of Copper Indium Aluminum Gallium diSelenide Wide Band-Gap Absorber Layer

94 REM Theodore Knutson Synthesis of Abundant Metal Sulfides for Photovoltaic Applications using Microwave Heating

LATE ADDITIONS: (see poster map for locations: lead number indicates area)


4.97 BB Mingyong Xiong Innovative Synthesis of Biodegradable Polymer Monomer by Engineered E. coli 14.98 CPF Yi Peng Soft Matter Physics Research B. Zhang, L. Bai, R. Zhao, X. Cheng 14.99 CPF Yuyang Du Structuring of Coatings and Surfaces with UV Curing-A Prospectus 76.00 BB Yi Zhang Simultaneous Site-specific Dual Protein Labeling Using Multiple Protein Prenyltransferases 76.01 BB Sujin Yeom Encapsulated Bacteria for Removal of Cyanuric Acid from Pool Water 69.01 NMP Han Zhang Flexible Molecular Sieve Membranes from Zeolite C. Macosko, M.Tsapatsis Nanosheets 68.01 BB Mohsen Mahmoodi Nitrodibenzofuran: an Efficient One- and Two-Photon M. Distefano Sensitive Photoremovable Protecting Group for Thiol Protection in Peptides

- 42 -



LATE ADDITIONS:

(see poster map for locations: lead number indicates area) 88.01 EMD Mehmet Topsakal Accurate projected augmented wave (PAW) datasets for R. Wentzcovitch rare-earth elements (Re=La-Lu) 87.01 NMP Maggie Zeng (Boston Environmental AFM Methods Applied to UV-Crosslinked Scientific), Alon Biomedical Coatings McCormick, Klaus Wormuth, Greg Haugstad 91.00 REM Jihua Yang UV and Air Stability of High-Efficiency Photoluminescent R. Liptak, D. Rowe, J. Wu, Silicon Nanocrystals J. Casey, D. Witker, S. Campbell, U. Kortshagen 94.01 MP Lian Bai Co-Continuous Polymer Blends with Interfacial Silica Xiang Cheng, Nanoparticles Chris Macosko

- 43 -




--NOTES--

- 44 -


Presentations by

Date & Time

- 45 -


--NOTES--

- 46 -


TUESDAY, MAY 27

AFTERNOON SESSIONS | 1:10 – 5:20 PM University of Minnesota author unless otherwise noted

WS = workshop PR = program review

Time Event Title Authors

1:10 PM MP WS Light Scattering Characterization of Responsive Materials

Daniel Savin (U of So. MS)

1:30 PM CPF WS Use of Tidas Tester to Assess Dispersion Quality of Filled Systems

Maria Nargiello (Evonik)

NMP WS Introduction to Workshop Joe Zasadzinski

REM PR Effects of Alkali Metal Impurities on the Microstructure and Electronic Properties of Cu2ZnSnS4 Thin Films

Melissa Johnson Serge Baryshev, Elijah Thimsen, Michael Manno, Xin Zhang, Chris Leighton, Eray Aydil

1:40 PM NMP WS Drainage and Stratification Kinetics of Foam Films Vivek Sharma (U of IL)

1:50 PM REM PR Surface Chemistry and Colloidal Forces for Nanocrystal Stability in Media Spanning Hexane to Water

Lance Wheeler Nicolaas Kramer, Uwe Kortshagen

2:05 PM CPF WS High Speed Imaging to Characterize Spray-Applied Waterborne Latex Coatings

Keith Kirkwood (Valspar)

2:10 PM MP WS Pushing the Limits on Molecular Structure Determination of Polyolefins using Multi-Detector GPC, CEF and HTLC

Alexander deGroot (Dow Chem)

REM PR Synthesis of Metal-Sulfide Nanocrystals with Controlled Composition and Crystal Structure by a Nonthermal Plug Flow Plasma Reactor

Elijah Thimsen Uwe Kortshagen, Eray Aydil

2:30 PM NMP WS Characterizing the Dilatational Interfacial Rheology of Insoluable Layers in a Microscale Tensiometer

Shelly Anna (Carnegie Mellon)

REM PR Light-Induced Hydrosilylation of Silicon Nanocrystals Jeslin Wu Anne Sledd, Uwe Kortshagen

2:40 PM CPF WS Silica Dispersions as Reinforcing Additives Waterborne Composites: Coatings and Adhesives

Arthur Scholz Christopher Galli, Saeed Choudhary, Brian Prevo

2:50 PM REM PR Insights into the Microstructure Development of Polycrystalline Cu2ZnSn(SxSe1-x)4 Thin Films During Annealing of Colloidal Nanocrystal Coatings

Boris Chernomordik Amelie Beland, Anne Hunter, Priyanka Katkar, Donna Deng, Lorraine Francis, Eray Eydil

3:10 PM REM PR Crossover from Intergranular Hopping to Conventional Charge Transport in Pyrite Thin Films

Xin Zhang Mike Manno, Andrew Baruth, Mellissa Johnson, Eray Aydil, Chris Leighton

3:20 PM CPF WS Development and Characterization of a Spray Deposited CNT/PVDF Thin Film

Brian Loyola (Sandia)

3:40 PM MP WS Applications of Mass Spectrometry Toward Elucidating the Structure of Synthetic Polymers

Scott Grayson (Tulane U)

NMP WS Rheology of Bacterial Biofilms: A Tale of Two Microbes Lynette Cegelski (Stanford)

3:55 PM CPF WS High Throughput Study to Evaluate Coalescents in a Clear Concrete Sealer.

Vincent Goldman (BASF)

Rooms CPF: Keller Hall 3-180 MP: Keller Hall 3-210 NMP: Keller Hall 3-230 REM: PAN 110

- 47 -






TUESDAY, MAY 27, CONTINUED

Locations listed on previous page


4:00 PM REM PR UV and Air Stability of High-Efficiency Photoluminescent Silicon Nanocrystals

Jihua Yang Richard Laptak, David Rowe, Jeslin Wu, James Casey, David Witker, Steve Campbell, Uwe Kortshagen

4:20 PM REM PR Plasmonic Properties of Boron and Phosphorus Doped Silicon Nanocrystals

Nicolaas Kramer Katelyn Schramke, Uwe Kortshagen

4:30 PM CPF WS Through Thick and Thin – Imaging the Microscopic Structure of Shear Thinning and Thickening Colloidal Suspensions

Xiang Cheng

NMP WS Interfacial Dynamics of Atmospheric Particles: Cold, Complex and Charged Surfaces

Cari Dutcher

4:40 PM REM PR Synthesis of Abundant Metal Sulfides for Photovoltaic Applications using Microwave Heating

Theodore Knutson

- 48 -




WEDNESDAY, MAY 28

MORNING SESSIONS | 8:30 – 11:40 AM University of Minnesota author unless otherwise noted



8:25 AM BPM WS Introduction Jayanth Panyam

8:30 AM BPM WS 7-Day Microneedle Enhanced Transdermal Delivery: Bench to Bedside

Audra Stinchcomb (U of MD)

OEI/CPF WS

Hybrid Manufacturing – A Path to Commercialization for Printed and Flexible Electronics

John Heitzinger (Soligie)

9:10 AM OEI/CPF WS

Additive Printing and Assembly for Large Area Electronic Systems

Gregory Whiting (PARC)

9:15 AM BPM WS Delivering Macromolecules Through the Skin Using Biodegradable Microstructures

Gary Cleary (Corium Intl)

9:20 AM MP WS

Grazing Incidence Small Angle X-Ray Scattering: Characterization of Nanostructured Polymer Films

Gila Stein (U of Huston)

10:20 AM OEI/CPF WS

Carestream Advanced Materials Aaron Clapp (Carestream Health)

10:30 AM BPM WS Development and Scale-Up of Microneedle Based Drug Delivery Systems

Lisa Dick (3M)

10:40 AM MP WS Applications of Neutron Scattering to Soft Materials Problems

Paul Butler (NIST)

11:00 AM OEI/CPF WS

High Performance Inks for Printed Electronics Brett Walker (Electroninks)

Rooms BPM: PAN 110 CPF/OEI: Keller 3-180 MP: Keller Hall 3-210

- 49 -



WEDNESDAY, MAY 28

AFTERNOON SESSIONS | 1:15 – 5:00 PM University of Minnesota author unless otherwise noted



1:15 PM BB WS Introduction Kechen Zhang

EMD PR Overview of the Electronic Materials and Devices (EMD) Program

Steven Koester

NMP PR1 Program Review Overviews Alon McCormick, Greg Haugstad, Dan Frisbie, Andreas Stein

1:20 PM BPM PR Semi-Solid Biodegradable Polymers for Drug Delivery: Recent Progress

Chun Wang

OEI PR Introduction Russell Holmes

BB WS The Biotechnology Resource Center University of Minnesota; Possibilities and Examples

Tim Tripp

1:25 PM OEI PR Development of a Self-Aligned Manufacturing Process for Printed Electronics

Ankit Mahajan Woo Jin Hyun, Steven Brett Walker (Harvard), Jennifer Lewis (Harvard), Lorraine Francis, Daniel Frisbie

1:30 PM CPF PR1 Toward an Understanding of Electrostatic Assist: Experiments and Models for Electrohydrodynamic Deformation of Liquids in Cavities

Aruna Ramkrishnan Satish Kumr

1:40 PM BMP PR The Design of Novel Peptide-Amphiphiles for Targeted Thermosensitive Stealth Liposomes

Kamlesh Shroff Efronsini Kokkoli

EMD PR Graphene-Based Wireless Sensors Steven Koester

MP PR1 Introduction Marc Hillmyer

NMP PR1 Overview of Nano-Characterization Methods Applied to Multiphase, Biomedical and Liquidy Materials

Greg Haugstad

1:45 PM OEI PR Development of a Self-Aligned Manufacturing Process for Printed Electronic

Woo Jin Hyun Ankit Mahajan, Steven Brett Walker (Harvard), Jennifer Lewis (Harvard), Lorraine Francis, Daniel Frisbie

1:50 PM CPF PR1 Three Dimensional Analysis of Liquid Transfer Between a Cavity and a Moving Roll

Diego Campana (PUC-Rio)

MP PR1 Block Co-Oligomers for Lithography Morgan Schulze Marc HIllmyer

1:55 PM BB WS Photo-Activated Drug Release of a Liposomal Carrier Maria Ogunyankin Joe Zasadzinski

Rooms BB: AmH 240 | BPM: PAN 110 | CPF: Keller 3-180 | EMD: PAN 130 | MP: Keller Hall 3-210 | NMP: Keller Hall 3-230 OEI: Keller Hall 3-111

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WEDNESDAY, MAY 28

AFTERNOON SESSIONS, CONTINUED Rooms BB: AmH 240 | BPM: PAN 110 | CPF: Keller 3-180 | EMD: PAN 130 | MP: Keller Hall 3-210 | NMP: Keller Hall 3-230 OEI: Keller Hall 3-111

Time Event Title Authors 1:55 PM NMP PR1 Characterization of Electro-Nanosprayed Drug

Particles Suspended in a Polymer Matrix Jacob Warner Jim Lasch*, Allison Huessler*, Pat Ryan*, Bob Hoerr*, Han Fu*, (*Nanocopoeia), Greg Haugstad

2:00 PM BMP PR Engineering of Biomaterials Using Self-Assembling Biopolymers

Wei Shen

2:05 PM OEI PR Analytical Theory of Magneto-Electroluminescence in Organic Heterojunction Light-Emitting Devices

Feilong Liu Scott Crooker (Los Alamos), Darryl Smith (Los Alamos), Paul Ruden

2:10 PM CPF PR1 Electrohydrodynamic Effects in the Spreading of Thin Liquid Films

Andrew Corbett Satish Kumar

EMD PR Hybrid Molecular Beam Epitaxy Growth of Binary and Ternary Oxide Films

Bharat Jalan

MP PR1 Scalable Production of Mechanically Tunable Block Polymers from Sugar

Debbie Schneiderman Mingyong Xiong, Frank Bates, Marc Hillmyer, Kechun Zhang

NMP PR1 Characterization of Drug and Polymer Crystallization in Coatings of Drug plus Polymer

Klaus Wormuth

2:20 PM BPM PR Successful Development of 5-Florocytosine Through Integrated Crystal and Particle Engineering

Calvin Sun Reddy Perumalla

2:25 PM NMP PR1 Measuring Polymer-Nanoparticle Interactions Using Atomic Force Microscopy

Arthur Scholz Greg Haugstad, Chris Macosko

OEI PR Synthesis and Crystal Engineering of Tetracene-Based Organic Semiconductors

Matthew Bruzek Chris Douglas, Daniel Frisbie

2:30 PM BB WS Synthetic Biology Towards Combinatorial Biosynthesis of Pharmaceutically Important Coumarins

Yajun Yan

MP PR1 Polylactide Vitrimers Jacob Brutman Paula Delgado, Marc Hillmyer

2:40 PM EMD PR Novel Electrolytes for High Performance Electrolyte Gated Transistors

Jae-Hong Choi Yuanyan Gu, Wei Xie, Daniel Frisbie, Timothy Lodge

2:45 PM OEI PR Understanding the Rate-Limiting Processes for the Purification of Small Molecule Organic Semiconductors

Nathan Morgan Yi Zhang, Erich Molitor (Dow), Bruce Bell (Dow), Russell Holmes, Ed Cussler

2:50 PM MP PR1 Carboxy-Telechelic Polyolefins in Crosslinked Elastomers

Henry Martinez Marc Hillmyer

3:10 PM BPM PR New Results on Remote Sensing Using Hydrogels Ronald Siegel

CPF PR1 Slot Coating of Particle Suspensions Simone Bochner de Araujo (PUC-Rio) Marcio Carvalho (PUC-Rio)

3:20 PM

NMP PR1 Step Wise Growth and Comprehensive Characterization of Pi-Conjugated Molecular Wires on Gold

Abel Demissie Dan Frisbie

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WEDNESDAY, MAY 28



3:30 PM BB WS Engineering New Microbial Factories for Sustainable Chemicals

Kechun Zhang

3:30 PM BMP PR CPF PR1 EMD PR

Cardiovascular Medical Devices Based on Engineered Tissue Tubes Dynamic Wetting Failure in Surfactant Solutions Phase Stability and Electronic Transport Mechanisms in Thin Film Iron Pyrite

Zeeshan Syedain Robert Tranquillo Chen-Yu Liu Satish Kumar Xin Zhang Tom Scott (U of NE), Tyler Socha, David Nielson, Mike Manno, Melissa Johnson, Yugi Yan, Pater Dowben (U of NE), Eray Aydil, Chris Leighton

3:40 PM NMP PR1 OEI PR

Electrical Characterization of π-conjugated Molecular Wires by Conductive Probe Atomic Force Microscopy (CP-AFM) 7.9% Efficient Vapor-Deposited Organic Photovoltaic Cells Based on a Simple Mixed Heterojunction

Davood Taherinia Daniel Frisbie Yunlong Zou James Holst (Sigma-Aldrich), Yong Zhang (Sigma-Aldrich), Russell Holmes

3:50 PM BPM PR EMD CPF PR1 MP PR1

Surface Functionalization of Nanoparticles with Fibrinolytic Enzymes to Improve Their Intratumoral Penetration Film Growth and Electronic Transport Study of BaSnO3 Deposited via High Pressure Oxygen Sputtering Simultaneous Multilayer Coating of Miscible Solutions The Order-Disorder Transition in Short Diblock Copolymers

Ameya Kirtane Jayanth Panyam Koustav Ganguly Palak Ambiwani, Jong Seok Jeong, Andre Mkhoyan, Chris Leighton, Bharat Jalan Ryo Horiuchi Wieslaw Suszynski, Satish Kumar, Marcio Carvalho (PUC-Rio) Timothy Gillard Sangwoo Lee, Frank Bates

4:00 PM NMP PR1 OEI PR

Li8ZrO6 as a Cathode Material for Lithium Ion Batteries: a Computation-guided Experimental Study Correlation between Mechanical Strain and Workfunction in Organic Semiconductors

Yuan Fang Bo Wang, Benjamin Wilson, Nam Tran, Ahn Vu, Andreas Stein, Donald Truhlar, William Smyrl Yanfei WU Geoffrey Rojas, Wei Xie, Greg Haugstad, Daniel Frisbie

4:05 PM BB WS Cheminformatic Tools to Enabling Metabolic Synthesis of Novel Chemicals, Drugs, and Fuels

Keith Tyo (Northwestern U)

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WEDNESDAY, MAY 28



4:10 PM CPF PR1 Drying Regimes for Colloidal Droplets Spreading on Heated Inclined Substrates

Leonardo Espin Satish Kumar

MP PR1 BMP PR

Diblock Copolymer Surfactants for Cell Membrane Sealing Investigating the Role of Polymer Concentration and Hydrogen Bonding on the Physical Stability of Nifedipine-PVP Solid Dispersions

Karen Haman Frank Bates Khushboo Kothari Raj Suryanarayanan

4:20 PM OEI PR EMD PR NMP PR1

Dilute Donor Organic Photvoltaic Cells Incorporating a Photoactive Host Recent Progress in Ferromagnet-Semiconductor Heterostructures Ion-Selective Electrodes Based on Templated Porous Carbon

Matthew Meinke Russell Holmes Paul Crowell Jinbo Hu Philippe Buhlmann Andreas Stein

4:30 PM MP PR1 Designing Chewing Gum Rheology using the Block Copolymer Toolkit

Alex Mannion Sangwoo Lee Luca Martinetti Frank Bates Chris Macosko

4:40 PM BB WS NMP PR1 OEI PR

Development of Transcription Activator-Like Effectors as Molecular Tools to Improve Production of Fatty-Acid Derived Compounds in Escherichia coli 3DOm Carbon Materials Utilizing an Ionic Liquid Precursor for High Performance Supercapacitors Excited State Dynamics and Interfacial Electron Transfer in an Electronically Tunable Series of Thiophene Oligomers

Matthew Copeland ( U of WI) Marl Politz (U of WI) Charles Johnson (U of WI) Brian Pfleger (U of WI) Benjamin Wilson Andreas Stein Antonio Sanchez Diaz Miquel Planells Dillhunde (Imperial College of London) Amanda Oehrlein Neil Robertson (Imperial College of London) David Blank

4:50 PM MP PR1 Metastability of Aqueous Methylcellulose Solutions John McAllister Joseph Lott Peter Schmidt Timothy Lodge Frank Bates

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THURSDAY, MAY 30

MORNING SESSIONS | 8:20 – 11:40 AM University of Minnesota author unless otherwise noted


8:20 AM NMP PR2 Two-Dimensional Zeolites Michael Tsapatsis

8:30 AM BB PR CPF PR2

Enzymes for Industrial Chemistry Microstructure and Performance of Block Copolymer Modified Epoxy Coatings

Larry Wackett Tuoqi Li Frank Bates Lorraine Francis

8:40 AM MP PR2 NMP PR2

Cationic Glycopolymeric pDNA Delivery Systems Exhibit Molecular Weight, Charge Species, and Cell-Type Dependence Introduction and Overview

Yaoying Wu Miao Wang Dustin SProuse Adam Smith (Ole Miss) Theresa Reineke Alon McCormick

8:50 AM CPF PR2 Fundamental Studies of Stress Development in the Absence of Lateral Drying

Kyle Price Alon McCormick Lorraine Francis

9:00 AM BB PR MP PR2 NMP PR2

Enzymatic Protein Labeling Using Prenyltransferases Solution-State Polymer Assemblies Influence BCS Class II Drug Dissolution and Supersaturation Maintenance Understanding the Unusual Adsorption Behavior in Hierarchical Zeolite Nanosheets

Mark Distefano Swapnil Tale Molly Dalsin Peng Bai David Olson (Rutgers) Michael Tspatsis Ilja Siepmann

9:10 AM CPF PR2 The Drying Behavior of Hard Particulate Coatings Yan Wu Lorraine Francis

9:13 AM NMP PR2 Molecular Modeling of Fluid Phase Equilibria for Ternary Mixtures With Two Or Three Liquid Phases

David Harwood Angel Cortes-Morales Peng Bai Ilja Siepmann


Polymeric Nanocylinders by Combining Block Copolymer Self-Assembly and Nanoskiving Binding and Electron Transfer Studies of Terthiophene Dyes with Zinc Oxide Nanocrystals

Mohammadreaza Nasiri Arthur Bertrand Marc Hillmyer Theresa Reineke Amanda Oehrlein Wayne Gladfelter

9:30 AM BB PR CPF PR2

Scalable Production of Mechanically Tunable Block Polymers from Sugar Novel Methods for Embedding High-Resolution, High-Aspect Ratio Printed Metal Lines in Plastic

Kechun Zhang Ankit Mahajan

Rooms BB: Keller Hall 3-111 CPF: Keller Hall 3-180 MP: Keller Hall 3-210 NMP: Keller Hall 3-230

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THURSDAY, MAY 30, CONTINUED



9:40 AM MP PR2

Improving Fracture Toughness in Unsaturated Polyester Using Extremely Low Loadings of Graphene or Graphene Oxide

Nicholas Petkovich Yong Yae Park (Myongji U) Greg Moriarty Clement Chan Taewon Suh Wenhao Liu Chris Macosko Andreas Stein

10:10 AM CPF PR2 Processing of Solar Absorber Coatings from Nanocrystal Dispersions

Bryce Williams Eray Aydil Lorraine Francis


Molecular Exchange Through the Membranes of Polymersomes with Ionic Liquid Interiors Dispersed in Water Continuous vs Pulsed Near Infra-red Heating of Hollow Gold Nanoparticles - Implications and Applications

Soonyong So Timothy Lodge Joseph Zasadzinski

10:30 BB PR CPF PR2

Carbonization and Nanofabrication of Cellulosic Materials for Bio-Electronic Applications Surfactant Effects in Coating of Discrete Objects

Ping Wang Weihua Li Satish Kumar


Phase Behavior of Symmetric Diblock Copolymer-Homopolymer Ternary Blends The Role of Cryogenic Electron Microscopy in Soft Materials Processing: Clarifying Structure Questions

Robert Hickey Tim Gillard Brian Habersberger Tim Lodge Frank Bates Hanseung Lee Eric Morrison (EarthCLean) Jing Han Chris Frethem Joe Zasadzinski Chris Macosko Frank Bates Alon McCormick

10:50 AM CPF PR2 Particle Tracking as a Tool for Local, Real-Time Analysis of Sag in Drying Coatings

Robert Lade Chris Macosko Lorraine Francis


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THURSDAY, MAY 30, CONTINUED



11:00 AM 11:05 AM

BB PR MP PR2 NMP PR2 NMP PR2

Domestication of Fungi to Improve Complex Traits: Non-GMO Trichoderma Variants that Grow as Single Cells or Degrade Cellulose Faster Chain Exchange in Block Copolymer Micelles Introduction-Overview Two-Step Phase Transformation of Anatase to Rutile in Aqueous Suspension

Hui Lin Michael Travisano Romas Kazlauskas Jie Lu SooHyung Choi Frank Bates Tim Lodge Lee Penn Kairat Sabyrov Lee Penn

11:10 AM CPF PR2 Study of Water-Based Coatings For 3D Printed Parts Jenny Zhu (Stratasys)

11:20 AM 11:25 AM

MP PR2 NMP PR2

Reactive Compatibilization of Polyethylene and Poly(lactic acid) Heterogeneous Oriented Aggregation and Phase Transformation in Iron Oxide Nanoparticles

Christopher Thurber Tim Lodge Chris Macosko Jennifer Soltis Martin Kuhn (Arizona State) Jacqueline Harapan Lee Penn


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THURSDAY, MAY 30, CONTINUED Special Events

TAC Meetings Coffman Union | 4th Floor

12:00 PM – 1:45 PM

BB Room 410 BPM Room 411 NMP Conference Room “A” CPF Rooms “B/C” MP Dale Shepard Room

PPB Meeting Coffman Union | Room 332

2:00 PM – 3:30 PM 3th Floor

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BUILDING INFORMATION

SEE MAP

Amundson Hall (AmH) 421 Washington Avenue SE Coffman Memorial Union (CMU) 300 Washington Avenue SE Keller Hall (KH) 200 Union Street SE McNamara Alumni Center (MAC) 200 Oak Street SE Physics and Nanotechnology (PAN) 115 Union St. SE The Common’s Hotel 615 Washington Avenue SE

WI-FI Network Guest Access at the University of Minnesota To connect to the U of M Free WiFi, log in using the “U of M Guest” SSID and enter your active email address. Please note that this service offers no encryption and is limited in bandwidth and capacity.

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IPRIME ANNUAL MEETING SCHEDULE MAY 27 – 29, 2014

May 27 Tuesday Afternoon CPF MP NMP REM Special Events Workshop 1 Workshop 1 Workshop Program Poster Session 1 Keller 3-180 Keller 3-210 Keller 3-230 PAN 110 McNamara Alumni Ctr

Memorial Hall

1:30 – 5:20p 1:10 – 5:20p 1:30 – 5:20p 1:30 – 5:20p 5:45 – 7:00p

May 28 Wednesday Morning

BPM CPF & OEI MP Special Events Workshop Workshop 2

Workshop 2

Plenary Session & Luncheon

PAN 110 Keller 3-180

Keller 3-210 McNamara Alumni Ctr

Johnson Great Room 8:30 – 11:40a 8:30 – 11:40a 9:20 – 11:40a 11:45a – 1:05p

May 28 Wednesday Afternoon BB BPM CPF EMD MP NMP OEI Special Events

Workshop Program Program 1 Program Program 1 Program 1 Program Faculty-Industry Meet & Greet McNamara, Johnson Rm, 5–5:45p AmundH 240 PAN 110 Keller 3-180 PAN 130 Keller 3-210 Keller 3-230 Keller 3-111

Poster Session 2 + Awards

McNamara, Memorial, 5:45–7:30p 1:15 – 5:00p 1:15 – 5:00p 1:15 – 5:00p 1:15 – 5:00p 1:15 – 5:00p 1:15 – 5:00p 1:15 – 5:00p Characterization Facility Tour

Shepherd Labs , 7 – 8:30p

May 29 Thursday Morning / Afternoon BB CPF MP NMP Special Events

Program Program 2 Program 2 Program 2 PPB Breakfast Meeting, 7–8:15a Keller 3-111

Keller 3-180

Keller 3-210 Keller 3-230 Commons Hotel, Think 5 Room

BB, BPM, CPF, MP, NMP TAC Meetings, 12 – 1:45p 8:20 – 11:40a 8:20 – 11:40a 8:20 – 11:40a 8:20 – 11:40a (5) Coffman Union, 4th Floor

PPB Board Meeting, 2 – 3:30p Coffman Union, President’s Room

iprime annual meeting · modern polymer characterization methods-1 (mp) p. 7 interfacial rheology,...

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