morphisto gmbh safety data sheet...this msds covers the following products in all container sizes: -...
TRANSCRIPT
according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Sodium hydrate 5 - 40%
Revision date: 24.11.2020 Product code: 11204_collect Page 1 of 12
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Sodium hydrate 5 - 40%
1.1. Product identifier
This MSDS covers the following products in all container sizes:
- REF 11204.xxxxx Natronlauge / NaOH 10 % (~ 2,7 mol/l)
- REF 12016.xxxxx Natriumhydroxid (NaOH)-Perlen
- REF 12666.xxxxx Natronlauge / NaOH 40 % (~ 14,3 mol/l)
- REF 12809.xxxxx Natronlauge / NaOH 10,0 mol/l (~ 30 %)
- REF 12806.xxxxx Natronlauge / NaOH 2,0 mol/l (~ 8 %)
- REF 13596.xxxxx Natronlauge / NaOH 3,0 mol/l
- REF 13612.xxxxx Natronlauge / NaOH 25 %
- REF 14761.xxxxx Natronlauge / NaOH 15 %
- REF 15176.xxxxx Ätzmittel für Aluminiumschweißverbindungen
- REF 11078.xxxxx Natronlauge / NaOH 5,0 mol/l
- REF 18469.xxxxx Natronlauge / NaOH 20 %
- REF 18913.xxxxx Natronlauge / NaOH 5%
Further trade names
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Use as laboratory reagent.
The product is intended for research, analysis and scientific education.
Any non-intended use.
Uses advised against
1.3. Details of the supplier of the safety data sheet
Manufacturer
MORPHISTO GmbHCompany name:
Street: Schumannstr. 142/144
Place: D-63069 Offenbach
Telephone: Telefax:+49 (0) 69 / 400 3019-60 +49 (0) 69 / 400 3019-64
http://www.morphisto.deInternet:
Supplier
Company name: MORPHISTO GmbH
Street: Schumannstr. 142/144
Place: D-63069 Offenbach
Telefax:Telephone: +49 (0) 69 / 400 3019-60 +49 (0) 69 / 400 3019-64
e-mail: [email protected]
Internet: http://www.morphisto.de
1.4. Emergency telephone
number:
Poison Information Center Mainz, Germany, Tel: +49(0)6131/19240
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Regulation (EC) No. 1272/2008
Hazard categories:
Substance or mixture corrosive to metals: Met. Corr. 1
Skin corrosion/irritation: Skin Corr. 1A
Serious eye damage/eye irritation: Eye Dam. 1
Hazard Statements:
May be corrosive to metals.
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according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Sodium hydrate 5 - 40%
Revision date: 24.11.2020 Product code: 11204_collect Page 2 of 12
Causes severe skin burns and eye damage.
Causes serious eye damage.
2.2. Label elements
Regulation (EC) No. 1272/2008
Hazard components for labellingSodium hydroxide; caustic soda
Signal word: Danger
Pictograms:
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
Hazard statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing
protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water
or shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
Precautionary statements
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
2.3. Other hazards
SECTION 3: Composition/information on ingredients
3.2. Mixtures
aqueous solution: sodium hydroxide.Chemical characterization
Hazardous components
QuantityChemical nameCAS No
EC No Index No REACH No
GHS Classification
40 - < 45 %1310-73-2 Sodium hydroxide; caustic soda
215-185-5 011-002-00-6 01-2119457892-27
Met. Corr. 1, Skin Corr. 1A; H290 H314
Full text of H and EUH statements: see section 16.
Specific concentration limits and M-factors
QuantityChemical nameCAS No EC No
Specific concentration limits and M-factors
1310-73-2 215-185-5 40 - < 45 %Sodium hydroxide; caustic soda
Skin Corr. 1A; H314: >= 5 - 100 Skin Corr. 1B; H314: >= 2 - < 5 Skin Irrit. 2; H315: >= 0,5 - < 2
Eye Irrit. 2; H319: >= 0,5 - < 2
Further Information
Product does not contain listed SVHC substances > 0,1 % according to Regulation (EC) No. 1907/2006 Article
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according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Sodium hydrate 5 - 40%
Revision date: 24.11.2020 Product code: 11204_collect Page 3 of 12
59 (REACH)
SECTION 4: First aid measures
4.1. Description of first aid measures
First aider: Pay attention to self-protection! Remove affected person from the danger area and lay down. In
case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet
if possible).
Remove contaminated, saturated clothing immediately.
General information
Provide fresh air. Medical treatment necessary. Remove casualty to fresh air and keep warm and at rest. In
case of respiratory tract irritation, consult a physician. Apply cortisone spray at early stage.
After inhalation
After contact with skin, wash immediately with plenty of water and soap. Take off immediately all contaminated
clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention.
After contact with skin
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids
apart and consult an ophthalmologist. Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. Consult an ophthalmologist. Danger of blindness!
After contact with eyes
Observe risk of aspiration if vomiting occurs. Adverse human health effects and symptoms: Gastric perforation.
Do not allow a neutralisation agent to be drunk. Call a physician immediately. Do NOT induce vomiting. Rinse
mouth thoroughly with water. Let water be drunken in little sips (dilution effect). Never give anything by mouth
to an unconscious person or a person with cramps.
After ingestion
4.2. Most important symptoms and effects, both acute and delayed
If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects).
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Co-ordinate fire-fighting measures to the fire surroundings. Carbon dioxide (CO2). Dry extinguishing powder.
alcohol resistant foam. Atomized water.
Suitable extinguishing media
High power water jet.
Unsuitable extinguishing media
5.2. Special hazards arising from the substance or mixture
The product itself does not burn.
Wear a self-contained breathing apparatus and chemical protective clothing. Full protection suit.
5.3. Advice for firefighters
Suppress gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water separately.
Do not allow entering drains or surface water.
Co-ordinate fire-fighting measures to the fire surroundings.
Additional information
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eyes and
clothes. Use personal protection equipment. (See section 8.)Special danger of slipping by leaking/spilling
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according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Sodium hydrate 5 - 40%
Revision date: 24.11.2020 Product code: 11204_collect Page 4 of 12
product.
Do not allow to enter into surface water or drains. Discharge into the environment must be avoided.6.2. Environmental precautions
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the
recovered material as prescribed in the section on waste disposal.Clean contaminated objects and areas
thoroughly observing environmental regulations.
6.3. Methods and material for containment and cleaning up
Safe handling: see section 7
Personal protection equipment: see section 8
Disposal: see section 13
6.4. Reference to other sections
SECTION 7: Handling and storage
7.1. Precautions for safe handling
If handled uncovered, arrangements with local exhaust ventilation have to be used. Use extractor hood
(laboratory). Do not breathe gas/fumes/vapour/spray. Personal protection equipment (See section 8.) Always
close containers tightly after the removal of product.
Advice on safe handling
Usual measures for fire prevention.
Advice on protection against fire and explosion
Conditions to avoid: generation/formation of aerosols
Avoid contact with skin, eyes and clothes.
General protection and hygiene measures: See section 8.
Further information on handling
7.2. Conditions for safe storage, including any incompatibilities
Keep container tightly closed. Keep locked up. Store in a place accessible by authorized persons only. Provide
adequate ventilation as well as local exhaustion at critical locations. Unsuitable container/equipment material:
Metal. Keep only in the original container in a cool, well-ventilated place.
Make sure spills can be contained, e.g. in sump pallets or kerbed areas.
Suitable floor material: Alkali-resistant
Requirements for storage rooms and vessels
Do not store together with: Explosives. Oxidizing solids. Oxidizing liquids. Organic peroxides. Self-reactive
substances and mixtures. Radioactive substances. Infectious substances. Food and fodder.
Hints on joint storage
Keep the packing dry and well sealed to prevent contamination and absorbtion of humidity.
Recommended storage temperature: 15-25 °C
Protect against: frost. UV-radiation/sunlight. heat. Humidity
Further information on storage conditions
7.3. Specific end use(s)
Use as laboratory reagent.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Exposure limits (EH40)
Categoryfibres/mlmg/m³ppmSubstanceCAS No Origin
STEL (15 min)-Sodium hydroxide1310-73-2 2 WEL
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according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Sodium hydrate 5 - 40%
Revision date: 24.11.2020 Product code: 11204_collect Page 5 of 12
DNEL/DMEL values
CAS No Substance
DNEL type Exposure route Effect Value
1310-73-2 Sodium hydroxide; caustic soda
Worker DNEL, long-term inhalation local 1 mg/m³
Consumer DNEL, long-term inhalation local 1 mg/m³
8.2. Exposure controls
Technical measures and the application of suitable work processes have priority over personal protection
equipment. If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe
gas/fumes/vapour/spray. Use extractor hood (laboratory). Provide adequate ventilation.Provide washing
facilities at the workplace, provide an eye shower or eyewash bottle and mark them.
Appropriate engineering controls
Wear protective gloves/protective clothing and eye/face protection. Remove contaminated, saturated clothing
immediately. Wash hands and face before breaks and after work and take a shower if necessary . Draw up and
observe skin protection programme. When using do not eat, drink, smoke, sniff. Always close containers
tightly after the removal of product.
Protective and hygiene measures
Suitable eye protection: goggles. Tightly sealed safety glasses. DIN EN 166
In the event of splashes: Face protection shield
Eye/face protection
When handling with chemical substances, protective gloves must be worn with the CE-label including the four
control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the
specific working place concentration and quantity of hazardous substances. For special purposes, it is
recommended to check the resistance to chemicals of the protective gloves mentioned above together with the
supplier of these gloves. Pull-over gloves of rubber. EN ISO 374
Suitable material:
(penetration time (maximum wearing period): >= 8h)
Butyl rubber.
FKM (fluororubber).
(penetration time (maximum wearing period): >= 2h)
CR (polychloroprenes, Chloroprene rubber).
Before using check leak tightness / impermeability.
Hand protection
Use of protective clothing. Lab apron.
Minimum standard for preventive measures while handling with working materials are specified in the TRGS
500 (D).
Skin protection
Respiratory protection necessary at:
- generation/formation of aerosols
- insufficient ventilation
- exceeding exposure limit values
Suitable respiratory protective equipment: Particle filter device (DIN EN 143) - Type P2/3
The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates)
that may arise when handling the product. If the concentration is exceeded, self-contained breathing apparatus
must be used.
Respiratory protection
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according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Sodium hydrate 5 - 40%
Revision date: 24.11.2020 Product code: 11204_collect Page 6 of 12
Do not allow uncontrolled discharge of product into the environment.
Environmental exposure controls
colourless
liquidPhysical state:
Colour:
9.1. Information on basic physical and chemical properties
SECTION 9: Physical and chemical properties
characteristicOdour:
pH-Value (at 20 °C): >14
Changes in the physical state
not determinedMelting point:
100 °CInitial boiling point and boiling range:
not determinedSublimation point:
not determinedSoftening point:
not determinedPour point:
not determinedFlash point:
Sustaining combustion: Not sustaining combustion
Flammability
No information available.Solid:
No information available.Gas:
The product is not: Explosive. none
Explosive properties
not determinedLower explosion limits:
not determinedUpper explosion limits:
not determinedIgnition temperature:
Auto-ignition temperature
No information available.Solid:
No information available.Gas:
not determinedDecomposition temperature:
none
Oxidizing properties
6,1 hPaVapour pressure:
(at 20 °C)
Vapour pressure:
(at 50 °C)
No information available.
Density (at 20 °C): 1,27 g/cm³
Bulk density: No information available.
Water solubility: completely miscible
Solubility in other solvents
No information available.
not determinedPartition coefficient:
Viscosity / dynamic: not determined
Viscosity / kinematic: not determined
Flow time: not determined
Vapour density: not determined
Evaporation rate: not determined
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according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Sodium hydrate 5 - 40%
Revision date: 24.11.2020 Product code: 11204_collect Page 7 of 12
No information available.Solvent separation test:
>60%Solvent content:
9.2. Other information
>40,00 %Solid content:
SECTION 10: Stability and reactivity
10.1. Reactivity
Corrosive to metals.
10.2. Chemical stability
The product is chemically stable under recommended conditions of storage, use and temperature.
10.3. Possibility of hazardous reactions
Exothermic reaction with: Acid, Peroxides, Oxidizing agent. Possibly extensive generation of hydrogen on
contact with amphoteric metals (e.g. aluminium, lead, zinc) (explosive hazard!).
Violent reaction with: Acid
heat. UV-radiation/sunlight. frost.
10.4. Conditions to avoid
Metal. Keep away from: Acid, Oxidizing agent, Peroxides. Materials to avoid: Alkali metals. Oxidizing agents.
Strong acid. Nitrile. light metals. Phenols. Metal.
10.5. Incompatible materials
No known hazardous decomposition products.
10.6. Hazardous decomposition products
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicocinetics, metabolism and distribution
No information available.
Acute toxicity
Based on available data, the classification criteria are not met.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Irritation and corrosivity
Sensitising effects
Based on available data, the classification criteria are not met.
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.
Keine Bekannt
STOT-single exposure
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
STOT-repeated exposure
Aspiration hazard
Based on available data, the classification criteria are not met.
No information available.
Specific effects in experiment on an animal
The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP].
Additional information on tests
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according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Sodium hydrate 5 - 40%
Revision date: 24.11.2020 Product code: 11204_collect Page 8 of 12
SECTION 12: Ecological information
12.1. Toxicity
The product has not been tested.
CAS No Chemical name
[h] | [d]Aquatic toxicity Dose SourceSpecies Method
Sodium hydroxide; caustic soda1310-73-2
Acute fish toxicity 96 h Adema, D.M.M.
1985., GESTIS.
LC50 196 mg/l
Acute crustacea toxicity 48 h Warne and
Schifko, 1999;
ECHA Dossier.
EC50 40,4
mg/l
Ceriodaphnia sp.
12.2. Persistence and degradability
The methods for determining the biological degradability are not applicable to inorganic substances.
12.3. Bioaccumulative potential
No indication of bioaccumulation potential.
No information available.
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
No information available.
12.6. Other adverse effects
Avoid release to the environment. Do not allow to enter into surface water or drains.
Further information
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Disposal recommendations
Do not allow to enter into surface water or drains. Dispose of waste according to applicable legislation. Consult
the local waste disposal expert about waste disposal. Non-contaminated packages may be recycled. The
allocation of waste identity numbers/waste descriptions must be carried out according to the EEC, specific to
the industry and process.
Control report for waste code/ waste marking according to (EWC) European Waste Catalogue:
List of Wastes Code - residues/unused products
160507 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and
discarded chemicals; discarded inorganic chemicals consisting of or containing hazardous
substances; hazardous waste
List of Wastes Code - used product
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and
discarded chemicals; discarded inorganic chemicals consisting of or containing hazardous
substances; hazardous waste
160507
List of Wastes Code - contaminated packaging
WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND
PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately
collected municipal packaging waste); packaging containing residues of or contaminated by
hazardous substances; hazardous waste
150110
Wash with plenty of water. Completely emptied packages can be recycled. Handle contaminated packages in
the same way as the substance itself.
Contaminated packaging
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according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Sodium hydrate 5 - 40%
Revision date: 24.11.2020 Product code: 11204_collect Page 9 of 12
SECTION 14: Transport information
Land transport (ADR/RID)
14.1. UN number: UN 1824
SODIUM HYDROXIDE SOLUTION14.2. UN proper shipping name:
814.3. Transport hazard class(es):
14.4. Packing group: II
Hazard label: 8
Classification code: C5
Limited quantity: 1 L
Excepted quantity: E2
Transport category: 2
80Hazard No:
Tunnel restriction code: E
Inland waterways transport (ADN)
14.1. UN number: UN 1824
14.2. UN proper shipping name: SODIUM HYDROXIDE SOLUTION
14.3. Transport hazard class(es): 8
14.4. Packing group: II
Hazard label: 8
C5Classification code:
Limited quantity: 1 L
Excepted quantity: E2
Marine transport (IMDG)
14.1. UN number: UN 1824
SODIUM HYDROXIDE SOLUTION14.2. UN proper shipping name:
14.3. Transport hazard class(es): 8
14.4. Packing group: II
Hazard label: 8
NOMarine pollutant:
-Special Provisions:
Limited quantity: 1 L
Excepted quantity: E2
EmS: F-A, S-B
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number: UN 1824
SODIUM HYDROXIDE SOLUTION14.2. UN proper shipping name:
814.3. Transport hazard class(es):
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according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Sodium hydrate 5 - 40%
Revision date: 24.11.2020 Product code: 11204_collect Page 10 of 12
II14.4. Packing group:
Hazard label: 8
Special Provisions: A3 A803
Limited quantity Passenger: 0.5 L
Y840Passenger LQ:
Excepted quantity: E2
851IATA-packing instructions - Passenger:
1 LIATA-max. quantity - Passenger:
855IATA-packing instructions - Cargo:
30 LIATA-max. quantity - Cargo:
14.5. Environmental hazards
noENVIRONMENTALLY HAZARDOUS:
14.6. Special precautions for user
Warning: strongly corrosive. Refer to section 6-8
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
not relevant
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
No information available.2010/75/EU (VOC):
No information available.2004/42/EC (VOC):
Information according to 2012/18/EU
(SEVESO III):Not subject to 2012/18/EU (SEVESO III)
Additional information
The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP].
REACH 1907/2006 Appendix XVII, No (mixture): 3
National regulatory information
Observe restrictions to employment for juveniles according to the 'juvenile
work protection guideline' (94/33/EC). Observe employment restrictions
under the Maternity Protection Directive (92/85/EEC) for expectant or
nursing mothers.
Employment restrictions:
1 - slightly hazardous to waterWater hazard class (D):
15.2. Chemical safety assessment
Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information
Changes
Rev. 1,00; 25.06.2011. Initial release
Rev. 1,01; 21.11.2012
Rev. 1,1; 03.11.2016, Changes in chapter: 1, 2, 3, 4, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16.
Rev. 1,2; 07.08.2018, Changes in chapter: 1, 3, 8, 13, 15, 16.
Rev. 1,3; 26.11.2019, Fusion into Collect Data SDB
Rev. 1,4; 24.11.2020, Changes in chapter: 1-16; Adding the UFI code.
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Safety Data SheetMORPHISTO GmbH
Sodium hydrate 5 - 40%
Revision date: 24.11.2020 Product code: 11204_collect Page 11 of 12
Abbreviations and acronyms
ADR: Accord européen sur le transport des marchandises dangereuses par Route
AwSV: Verordnung über Anlagen zum Umgang mit wassergefährdenden Stoffen
AGW: Arbeitsplatzgrenzwert
AVV: Abfallverzeichnisverordnung
CAS Chemical Abstracts Service
CLP: Classification, Labelling and Packaging of substances and mixtures
DNEL: Derived No Effect Level
d: day(s)
EAKV: Europäisches Abfallverzeichnis gemäß Entwurf Abfallverzeichnisverordnung
EINECS: European INventory of Existing Commercial chemical Substances
ELINCS: European LIst of Notified Chemical Substances
ECHA: European Chemicals Agency
EWC: European Waste Catalogue
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)
h: hour
LOAEL: Lowest observed adverse effect level
LOAEC: Lowest observed adverse effect concentration
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
NOAEL: No observed adverse effect level
NOAEC: No observed adverse effect level
NLP: No-Longer Polymers
N/A: not applicable
OECD: Organisation for Economic Co-operation and Development
PNEC: predicted no effect concentration
PBT: Persistent bioaccumulative toxic
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de
fer (Regulations Concerning the International Transport of Dangerous Goods by Rail )
REACH: Registration, Evaluation, Authorisation of Chemicals
SVHC: substance of very high concern
TRGS Technische Regeln fuer Gefahrstoffe
UN: United Nations
VOC: Volatile Organic Compounds
VwVwS: Verwaltungsvorschrift wassergefaehrdender Stoffe
WGK: Wassergefaehrdungsklasse
CLP: Classification, labelling and Packaging
REACH: Registration, Evaluation and Authorization of Chemicals
GHS: Globally Harmonised System of Classification, Labelling and Packaging of Chemicals
UN: United Nations
CAS: Chemical Abstracts Service
DNEL: Derived No Effect Level
DMEL: Derived Minimal Effect Level
PNEC: Predicted No Effect Concentration
ATE: Acute toxicity estimate
LL50: Lethal loading, 50%
EL50: Effect loading, 50%
EC50: Effective Concentration 50%
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Safety Data SheetMORPHISTO GmbH
Sodium hydrate 5 - 40%
Revision date: 24.11.2020 Product code: 11204_collect Page 12 of 12
ErC50: Effective Concentration 50%, growth rate
NOEC: No Observed Effect Concentration
BCF: Bio-concentration factor
PBT: persistent, bioaccumulative, toxic
vPvB: very persistent, very bioaccumulative
ADR: Accord européen sur le transport des marchandises dangereuses par Route
(European Agreement concerning the International Carriage of Dangerous Goods by Road )
RID: Regulations concerning the international carriage of dangerous goods by rail
ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
(Accord européen relatif au transport international des marchandises dangereuses par voies de navigation
intérieures)
EmS: Emergency Schedules
MFAG: Medical First Aid Guide
MARPOL: International Convention for the Prevention of Marine Pollution from Ships
IBC: Intermediate Bulk Container
For abbreviations and acronyms, see table at http://abbrev.esdscom.eu
Classification for mixtures and used evaluation method according to Regulation (EC) No. 1272/2008 [CLP]
Classification procedureClassification
Met. Corr. 1; H290 Calculation method
Skin Corr. 1A; H314 Calculation method
Eye Dam. 1; H318 Calculation method
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
Relevant H and EUH statements (number and full text)
The information is based on the present level of our knowledge. It does not, however, give assurance of
product properties and establishes no contract legal rights. The receiver of our product is singularly responsible
for adhering to existing laws and regulations. Classification according to Regulation (EC) No 1272/2008 [CLP] -
Classification procedure:
Health hazards: Calculation method.
Environmental hazards: Calculation method.
Physical hazards: On basis of test data and / or calculated and / or estimated.
The above information describes exclusively the safety requirements of the product and is based on our
present-day knowledge. The information is intended to give you advice about the safe handling of the product
named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be
transferred to other products. In the case of mixing the product with other products or in the case of
processing, the information on this safety data sheet is not necessarily valid for the new made-up material.
Further Information
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)
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