OLI 35th Anniversary User ConferenceOctober 5-6, 2005

It’s Not Magic…Just Great Technology

Welcome

Marshall Rafal

OLI Systems, Inc.Value Through Technology• Founded 34+ Years Ago• Mission: Provide value to

the CPI through simulation of complex chemical systems

• OLI is committed to:• Advanced technology

development• Customer solutions and

service

Focus Areas: Electrolytes• Aqueous reactions and separations processes• Reactive separations including acid gas treatment• Scaling and fouling of towers, heat exchangers, oil

and gas wells• Corrosion of equipment in the plant and oilfield• Chemical conversion, crystallization, pH control• Water and offgas treatment• Environmental behavior of wastes, discharges, and

accidental releases

Major Government FundingLeveraged Funding for our Customers

• Corrosion in mixed-solvent environments (U.S. Department of Energy, $1.2M)• Thermodynamic and

transport property models

• Rates of uniform corrosion

Major Government FundingLeveraged Funding for our Customers

•Crystallization modeling (U.S. Department of Energy $2.5M)• Process simulation for

crystallization• Mixed-solvent electrolyte

databank• CFD crystallizer design

(Fluent)

DTB Crystallizer

Major Government FundingLeveraged Funding for our Customers

• Localized corrosion (U.S. Department of Commerce, Advanced Technology Program, $2.0M)• Model for predicting localized

corrosion• Localized corrosion of alloys and

fabricated materials (U.S. Department of Energy, $3.2M)• Generalization of the localized

corrosion model and extension to fabricated components

OLI Software Users

• Industrial• More than 125 companies on 6 continents• Spanning all sectors of the chemical

process industry• Government

• Department of Energy laboratories• US Environmental Protection Agency

• Universities (For education and research)

Partial List of OLI CustomersLeveraged Funding Via SW Leases

Government Laboratories

Bechtel BettisHanford

Idaho Japan Atomic Energy

Lawrence LLLos AlamosOak Ridge

Savannah River

Oil and GasAdvantica

Amerada HessBohai OilBrentagg

BP AmocoChampion

ChevronTexacoCNOOC

ConocoPhillipsEncana Oil & Gas

ExxonMobilJapan Energy

Marathon Oil Plus

ONGC BarodaPEMEX

PetrobrasPetro-Canada

PetroChinaPGS Production

PrimasPetrochina

SinoPecShell

SW Oil FieldTotalFinaElf

ChemicalsAir Products

Ajinomoto Chemicals`Akzo-Nobel

BayerCargillDaikin

Degussa-HulsDow Chemical

DuPontFMC

INEOS ChlorINEOS FluorINEOS Oxide

Mitsubishi ChemicalMitsui Chemical

MonsantoNalco Chemical

Nippon ChemicalNippon ZeonNorsk Hydro

PallProctor and Gamble

RayovacRhodia

Rohm & HaasSGL Carbon

SolvaySpecialitiesSumitomoSyngenta

Tokuyama ChemicalsToshiba

UBEUOP

Metals/Mining/UtilitiesAlcoa

FramatomeIHI

Kawasaki Heavy IndustrySasol

Mitsubishi Heavy IndustrySpecialty Minerals

Research InstEPRI

Southwest ResearchSTFI

UniversitiesCurtin UDelft U

F. MannheimMcGill U.

Mississippi StateNanyang Tech U

Penn State U Queens College

Rutgers UStavenger College

Tohoku UToyama UTsinghua U

UCLAU. Of ColoradoU of CapetownU of Cincinnati

U of GuelphU of Montreal

U of OuluU SaskatchewanU of S Carolina

U of SydneyU of Toronto

Wageningen UYale University

EnvironmentalCanada Natl Resources

Entec UK, LtdKurita Water

Paques Bio SystemsRand Water

USEPAUS Filter

Engineering & Construction

Cogema EngineeringColt Engineering

Dowell SchlumbergerEnviroscrub Tech

FluorIdemitsu Engineering

JFE EngineeringJGC

KvaernerMEG Worley

PallSNC Lavalin

SwensonToyo Engineering

Simulation SoftwareAspen Technology

HoneywellIDEAS Technology

Process Systems (PSE)Simulation Sciences

Thermfact Ltd

Pulp and PaperMead Westvaco

PharmaceuticalsEli Lilly

• Simtech (Japan/Supervisor for Asia)• APS (North/South America/Europe)• Ecoengineers (Australia)• Harris Scientific Products (Canada)• Intratec (South America)• Poly-Doctor Petrotech (China)• Lal Mehta (Canada/Middle East/India)• Oilfield Optimization E&P (SE Asia)

Worldwide Agents - LocalSupport Throughout the World

Alliance PartnersAccess OLI From Your Simulator of Choice

• Principal simulator alliance• Honeywell (UniSim OLI and UniSim OLI Corrosion)

• Process simulator providers• Aspentech (HYSYS OLI)

• AspenTech (Aspen OLI)

• Ideas Simulation (IDEAS OLI)

• Invensys Simsci (PROIIE)

• PSE (gPROMS OLI)

Alliances with IndustryAssuring the Best R&D Solutions

• Industrial Teaming Partners• DOE general corrosion project: Dow, DuPont, MTI, Westvaco

• DOE crystallization project: Dow, Eli Lilly, Nippon Chemical

• DOE localized corrosion project: ChevronTexaco, DuPont, Haynes, Mitsubishi Chemical, Shell, Toyo

• Technology Partners• SwRI (localized corrosion lab)

• Fluent, Inc. (CFD for crystallization)

• Oak Ridge National Labs (thermo for alloys)

• Materials Technology Institute (corrosion)

• Environmental Simulation Program• $1.2M - Exxon, DuPont, ICI, Texaco, IBM, Davy McKee, Waste

Management

• Corrosion Simulation Program• $1.5M - Exxon, DuPont, ICI, Mobil, Chevron, Shell, Amoco,

Mitsubishi, Gas Research Institute, Toyo, Framatome, Bechtel-Bettis

• Mixed Solvent Electrolyte (MSE)• $750K – Dow, DuPont, Mitsubishi, Shell, Rohm & Haas, Alcoa

• Crystallization Simulation Program• $600K - Amoco, DuPont, Dow, ICI, Nippon, Ajinomoto

Research PartnershipsIndustry

Leveraged Funding for Members and Customers

OLI Simulation Studio

OLI EngineStream Analyzer UI

Includes Lab/SCORE Interfaces--------------------------------------------

OLI Alliance Engine

Simulator Interfaces

ESPElectrolyte

Process Simulation

CSPCorrosion Analyzer UI

ScaleChemOilfield Scaling

Callable Interfaces

All Products Use Same Core Technology

Thermophysical PropertiesFirst Generation: Aqueous Model

• Currently, the standard aqueous model for the OLI Simulation Studio

• Validity range:• Temperature -50 to 300 oC

• Pressure 0 to 1500 bar

• Concentration 0 to 30 molal IS

• Organic components Up to x = 0.35

Thermophysical PropertiesNext Generation: MSE

• Emerging as the all-encompassing electrolyte model for the OLI Simulation Studio

• Validity range:• Temperature -35 to 90% of critical T

• Pressure 0 to 1500 bar

• Concentration No limit

• Organic components No limit

OLI Engine - What’s Special?1. Complete speciation model for complex mixtures

for both aqueous and MSE-based systems

2. Extensive in-place databanks provides out-of-the box predictions

3. Predictive over broad range of concentration (unlimited for MSE), temperature, and pressure

4. Core Engine (databank) developed subject to rigorous QA standards

5. Data service - rapid-response data development

6. OLI hotline – rapid response to user inquiries

7. Transport property prediction

• Databank for MSE• Analyzer product line• Flowsheet simulator UI• Databank for predicting rates of corrosion• Localized corrosion of base metals and

fabricated components• EVS for prediction of useful service life of

materials

OLI’s Current Applied R&D

WelcomeMarshall RafalOLI Systems, Inc.Value Through TechnologyFocus Areas: Electrolytes Major Government Funding Leveraged Funding for our Customers Major Government Funding Leveraged Funding for our Customers Major Government Funding Leveraged Funding for our CustomersOLI Software UsersWorldwide Agents - LocalSupport Throughout the WorldAlliance PartnersAccess OLI From Your Simulator of ChoiceAlliances with IndustryAssuring the Best R&D SolutionsOLI Simulation StudioThermophysical PropertiesFirst Generation: Aqueous ModelThermophysical PropertiesNext Generation: MSEOLI Engine - What’s Special?