riley stoker corp. is now riley power inc., a babcock power inc. … · reduction of nox emissions...

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Page 1: Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. … · Reduction of NOX Emissions From MSW Combustion Using Gas Reburning by Craig A. Penterson and D. C. Itse Riley
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Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. company. www.babcockpower.com
Page 2: Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. … · Reduction of NOX Emissions From MSW Combustion Using Gas Reburning by Craig A. Penterson and D. C. Itse Riley

Reduction of NOX Emissions From MSW Combustion Using

Gas Reburning

by

Craig A. Penterson and D. C. Itse Riley Stoker Corporation, USA

Hamid A. Abbasi Institute of Gas Technology, USA

Yasujiro Wakamura Takuma Company Ltd., Japan

David G. Linz Gas Research Institute, USA

ABSTRACT A program has been initiated to evaluate the potential for reducing air pollutant emissions from Municipal Solid Waste (MSW) combustion systems using natural gas reburning. The program is being conducted jointly by the Institute of Gas Technology, the Gas Research Institute, Riley Stoker Corporation and Takuma Company Ltd.

Three major tasks are included in the program: (1) acquisition of baseline data from a commercial operating facility, (2) pilot-scale development and testing of the reburning technology, and (3) field demonstration testing of the technology. This paper focuses on the results to date of the first two tasks: baseline data acquisition and pilot scale testing.

The gas reburning concept being evaluated for MSW combustion is similar to the reburn-ing technique being investigated to reduce NO, emissions from fossil fuel combustion systems. Natural gas is introduced above the main combustion zone to create a reducing environment where significant amounts of NO, and other fixed nitrogen species (NHi, HCN), generated in the main combustion zone, are reduced to molecular N2.

Results of the pilot scale testing have demonstrated up to 70% reduction in NO, emissions using gas reburning. The effects of gas injection location, reburning zone stoichiometry and residence time, overall boiler excess air and the amount of natural gas reburning on NO, emissions are characterized. The impact of gas reburning on reducing other emissions such as CO, unburned THC and dioxin is also discussed.

INTRODUCTION

With the expanding waste-to-energy market today, the need to understand more about the combustion characteristics and behavior of municipal solid waste (MSW) and refuse derived fuel (RDF) has increased dramatically. Of primary concern are the air pollu-tant emissions produced during the combustion process and the ability to control these emissions. Flue gas scrubbers are generally employed in modern

facilities at the boiler exit to control the acid gas emissions such as HC1 and SO2. Baghouses or elec-trostatic precipitators are used to remove the par-ticulate emissions as well as the reacted lime from the scrubber. Other emissions could potentially be controlled during the combustion process. These in-clude NON, CO, unburned THC, polychlorinated dibenzodioxins (PCDD's) and polychlorinated dibenzofurans (PCDF's).

© Riley Stoker Corporation 1989

Page 3: Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. … · Reduction of NOX Emissions From MSW Combustion Using Gas Reburning by Craig A. Penterson and D. C. Itse Riley
Page 4: Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. … · Reduction of NOX Emissions From MSW Combustion Using Gas Reburning by Craig A. Penterson and D. C. Itse Riley
Page 5: Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. … · Reduction of NOX Emissions From MSW Combustion Using Gas Reburning by Craig A. Penterson and D. C. Itse Riley
Page 6: Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. … · Reduction of NOX Emissions From MSW Combustion Using Gas Reburning by Craig A. Penterson and D. C. Itse Riley
Page 7: Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. … · Reduction of NOX Emissions From MSW Combustion Using Gas Reburning by Craig A. Penterson and D. C. Itse Riley
Page 8: Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. … · Reduction of NOX Emissions From MSW Combustion Using Gas Reburning by Craig A. Penterson and D. C. Itse Riley
Page 9: Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. … · Reduction of NOX Emissions From MSW Combustion Using Gas Reburning by Craig A. Penterson and D. C. Itse Riley
Page 10: Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. … · Reduction of NOX Emissions From MSW Combustion Using Gas Reburning by Craig A. Penterson and D. C. Itse Riley
Page 11: Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. … · Reduction of NOX Emissions From MSW Combustion Using Gas Reburning by Craig A. Penterson and D. C. Itse Riley
Page 12: Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. … · Reduction of NOX Emissions From MSW Combustion Using Gas Reburning by Craig A. Penterson and D. C. Itse Riley
Page 13: Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. … · Reduction of NOX Emissions From MSW Combustion Using Gas Reburning by Craig A. Penterson and D. C. Itse Riley
Page 14: Riley Stoker Corp. is now Riley Power Inc., a Babcock Power Inc. … · Reduction of NOX Emissions From MSW Combustion Using Gas Reburning by Craig A. Penterson and D. C. Itse Riley