size dependent and tunable elastic properties of hierarchical honeycombs with regular square and...
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Simple closed-form results for all the independent elastic constants of macro-, micro- and nanosized first-order regular honeycombs with square and equilateral triangular cells and for the self-similar hierarchical honeycombs were obtained. It is found that, if the cell wall thickness of the first-order honeycomb is at the micrometer scale, the elastic properties of a hierarchical honeycomb are size dependent, owing to the strain gradient effects. Further, if the first-order cell wall thickness is at the nanometer scale, the elastic properties of a hierarchical honeycomb are not only size dependent owing to the effects of surface elasticity and initial stresses, but are also tunable. In addition, the cell size and volume of hierarchical nanostructured cellular materials can be varied, and hierarchical nanostructured cellular materials could also possibly be controlled to collapse.TRANSCRIPT
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Size-dependent and tunable elastic properties ofhierarchical honeycombs with regular square and equilateral
triangular cells
H.X. Zhu a,⇑, L.B. Yan a, R. Zhang a, X.M. Qiu b
a School of Engineering, Cardiff University, Cardiff CF24 3AA, UKb School of Aerospace, Tsinghua University, Beijing 100084, People’s Republic of China
Received 17 January 2012; received in revised form 9 May 2012; accepted 10 May 2012
Abstract
Simple closed-form results for all the independent elastic constants of macro-, micro- and nanosized first-order regular honeycombswith square and equilateral triangular cells and for the self-similar hierarchical honeycombs were obtained. It is found that, if the cell wallthickness of the first-order honeycomb is at the micrometer scale, the elastic properties of a hierarchical honeycomb are size dependent,owing to the strain gradient effects. Further, if the first-order cell wall thickness is at the nanometer scale, the elastic properties of a hier-archical honeycomb are not only size dependent owing to the effects of surface elasticity and initial stresses, but are also tunable. In addi-tion, the cell size and volume of hierarchical nanostructured cellular materials can be varied, and hierarchical nanostructured cellularmaterials could also possibly be controlled to collapse.Crown Copyright � 2012 Published by Elsevier Ltd. on behalf of Acta Materialia Inc. All rights reserved.
Keywords: Size effect; Honeycombs; Hierarchy; Elastic properties; Tunable properties
1. Introduction
In nature, living things evolve constantly to survive theirchanging environment. To support their own weight, toresist external loads and to enable different types of func-tions, their bodies should be structurally optimized andmechanically sufficiently strong. As a consequence, naturalliving materials are usually made up of hierarchical cellularstructures with basic building blocks at the micro- ornanoscale.
The elastic properties of honeycombs at the macroscalehave been extensively studied and well documented [1–7].However, the results obtained for macrohoneycombs maynot apply to their micro- and nanosized counterparts [8].It has been generally recognized that, at the micrometerscale, the strain gradient effect plays an important role in
the mechanical properties [8–14], and that, at the nanometerscale, both surface elasticity [8,15,16] and initial stresses[17,18] can greatly affect the mechanical properties of struc-tural elements. Atomistic simulations [19] suggest that, formetallic structural elements with a size of a few nanometers,the strain gradient effect is irrelevant, and surface elasticityor surface energy dominates the mechanical properties. Thesize-dependent bending rigidities have been obtained formicroplates [11] and nanoplates [18]. The size-dependenttransverse shear rigidities of micro- and nanoplates andthe size-dependent elastic properties of the first-order hon-eycombs with regular hexagonal cells were obtained inRef. [8]. Fan et al. [30] and Taylor et al. [31] have studiedthe effects of structural hierarchy on the elastic propertiesof honeycombs. However, they did not study the size-dependent effect or the tunable elastic properties for hierar-chical honeycombs. The aim of this paper is thus to obtainclosed-form results for the size-dependent and tunablemechanical properties of regular self-similar hierarchical
1359-6454/$36.00 Crown Copyright � 2012 Published by Elsevier Ltd. on behalf of Acta Materialia Inc. All rights reserved.
http://dx.doi.org/10.1016/j.actamat.2012.05.009
⇑ Corresponding author. Tel.: +44 29 20874824.E-mail address: [email protected] (H.X. Zhu).
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honeycombs with square and equilateral triangular cellswhose first-order cell wall thickness is at the micron andnanometer scales.
2. Independent elastic constants of the first-order
honeycombs
The first-order honeycombs are treated as materialswhose size is much larger than the individual cells andare assumed to have uniform cell walls of length L, widthb and thickness h. The wall width b is assumed to be muchlarger than the thickness h. The focus of this paper is onsmall elastic deformation and the elastic properties.Although the cell wall can be of a metallic, biological orpolymeric material, it is always assumed to be isotropicand linear elastic, with Young’s modulus ES and Poissonratio vS, in the analysis that follows. As regular honey-combs with either square cells or equilateral triangular cellshave three orthogonal planes of symmetry, the maximumpossible number of independent elastic constants is nine[4,8,20].
2.1. Honeycombs with equilateral triangular cells
Fig. 1 shows a regular honeycomb with equilateral trian-gular cells. It is easy to show that its in-plane mechanicalproperties are isotropic. To fully determine the relationshipbetween the applied state of effective stress and theresponding state of effective strain, only five independentelastic constants – E1, m12, E3, v31 and G31 – need beobtained. The detailed derivation of these independentelastic constants is given in Appendix A.
The relative density of the first-order honeycomb withequilateral triangular cells is given by
q ¼ 2ffiffiffi3p
hL
ð1Þ
When the honeycomb is compressed by a uniform stressin the x direction, there is no junction rotation because ofthe symmetry, and the inclined cell walls undergo
combined axial compression, transverse shear deformationand plane-strain bending. Only a representative unit cellshown in Fig. 1b is needed for mechanics analysis. Byassuming that the bending stiffness of the cell walls is DB,the shear stiffness is DS and the axial compression stiffnessis DC, it is easy to obtain all five independent elastic con-stants for a perfect regular honeycomb with equilateral tri-angular cells and uniform cell walls.
The in-plane Young’s modulus of a perfect regular hon-eycomb with equilateral triangular cells can be obtained as(see Appendix A)
E1 ¼2DS � D2
C � L2 þ 24DB � D2C þ 24DB � DS � DCffiffiffi
3p
L3 � DS � DC þ 12ffiffiffi3p
L � DB � DC þ 4ffiffiffi3p
L � DB � DS
ð2ÞThe in-plane Poisson ratio is determined as
m12 ¼L2 � DS � DC þ 12DB � DC � 12DB � DS
3L2 � DS � DC þ 36DB � DC þ 12DB � DSð3Þ
and the out-of-plane Young’s modulus is given by
E3 ¼ f1ESq ð4Þwhere ES is the Young’s modulus of the solid material andf1 is a coefficient to be specified in the sections that follow,the value of which depends on the type of honeycomb celland the size scale of the cell wall thickness.
The out-of-plane shear modulus can be obtained as
G31 ¼ f2GSq ð5Þwhere GS is the shear modulus of the solid material and f2
is a coefficient to be specified.The out-of-plane Poisson ratio obviously remains the
same as that of the solid material at both the macro- andmicroscales (in this case, the strain gradient effect isabsent), thus
m31 ¼ mS ð6ÞTo simplify the analysis for honeycomb material with
cells at the nanometer scale, the surface is assumed to beisotropic and to have the same Poisson ratio mS as that of
Fig. 1. (a) A regular honeycomb with equilateral triangular cells of uniform cell wall thickness; (b) the loads applied to the cell walls of a unit cell when thehoneycomb is compressed in the x direction.
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the bulk material. The out-of-plane Poisson ratio m31 of ahoneycomb with nanosized equilateral triangular cells isthus mS. Therefore, in the sections that follow, we only needto obtain the results of four independent elastic constants –E1, m12, E3 and G13 – for perfect regular honeycombs withequilateral triangular cells at different size scales.
2.2. Honeycombs with square cells
The xy plane of perfectly regular honeycombs withsquare cells, as shown in Fig. 2a, is not isotropic. It is easyto verify this, and only six independent elastic constantshave to be determined: E1, m12, G12, E3, v31 and G31. Theirdetailed derivation is given in Appendix B.
The relative density of the first-order honeycomb withsquare cells and uniform cell wall thickness is given by
q ¼ 2hL
ð7Þ
The in-plane Young’s modulus is obtained as
E1 ¼rx
ex¼ DC
Lð8Þ
The in-plane Poisson ratio is determined as
m12 ¼ vSh=L ¼ 1
2mSq ð9Þ
which is the same as that given by Wang and McDowell[21] and applies to the first-order honeycomb with regularsquare cells at different size scales. The in-plane shear mod-ulus is obtained as
G12 ¼6DBDS
DSL3 þ 12DBLð10Þ
and the out-of-plane Young’s modulus is given as
E3 ¼ f3ESq ð11Þwhere f3 is a coefficient to be specified in the sections thatfollow, the value of which depends on the size scale ofthe cell wall thickness.
The out-of-plane shear modulus can be obtained as
G31 ¼ f4GSq ð12Þwhere f4 is a coefficient to be determined.
At the nanoscale, as the Poisson ratio of the surface isassumed to be mS, the out-of-plane Poisson ratio remainsthe same as that of the solid material for different-orderhierarchical honeycombs with regular square cells frommacro- and micro- down to the nanoscale,
m31 ¼ mS ð13ÞIn the sections that follow, we only need to obtain four
independent elastic constants – E1, E3, G12 and G31 – forthe first-order honeycombs with regular square cells whosecell wall thickness is uniform at different size scales.
3. Elastic constants of macrosized first-order honeycombs
For macrosized first-order honeycombs, the bending,transverse shear and axial stretching/compression rigiditiesof the cell walls are given by
DB ¼ES
1� m2S
� bh3
12ð14aÞ
DS ¼GSbh1:2
ð14bÞ
DC ¼ ESbh ð14cÞ
In Eq. (14b) a shear coefficient of 1.2 [22] is introduced forthe rectangular cross-section of the cell walls.
3.1. Honeycombs with regular equilateral triangular cells
Substituting Eqs. (1) and (14a–c) into Eqs. (2)–(5), thedimensionless results of all the four elastic constants canbe obtained as:
E1 ¼E1
13ESq¼
1þ q2
5ð1�mSÞ þq2
12ð1�m2SÞ
1þ q2
5ð1�mSÞ þq2
36ð1�m2SÞ
ð15Þ
Fig. 2. (a) A regular honeycomb with square cells of uniform cell wall thickness; (b) the loads applied to the cell walls of a unit cell when the honeycombundergoes in-plane shear deformation.
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m12 ¼13þ 1
15ð1�mSÞ � q2 � 1
36ð1�m2SÞ� q2
1þ 15ð1�mS Þ � q
2 þ 136ð1�m2
S� q2
ð16Þ
E3 ¼E3
Esq¼ 1 ð17Þ
G31 ¼G31
Gsq¼ 1
2ð18Þ
where the in-plane Young’s modulus is normalizedby 1
3ESq; the out-of-plane Young’s modulus is normalized
by ESq; the out-of-plane shear modulus is normalized byGSq; and the relative density q is given by Eq. (1). Theout-of-plane Poisson ratio is the same as that given inEq. (6). Wang and McDowell [21] obtained the in-plane(i.e. the xy plane) elastic properties for macrosized first-or-der honeycombs with equilateral triangular cells. Theytook cell wall bending as the sole deformation mechanism,and their result is slightly different from Eq. (15).
For the first-order honeycombs with macrosized equilat-eral triangular cells, the relationship between the in-planedimensionless Young’s modulus E1 and the relative densityq is shown in Fig. 3, and the relationship between the in-plane Poisson ratio m12 and the relative density q is pre-sented in Fig. 4. As can be seen from Figs. 3 and 4, boththe in-plane dimensionless Young’s modulus E1 and thePoisson ratio m12 vary so little with the honeycomb relativedensity q over the range from 0 to 0.35 that they can betreated as approximate constants: E1 � 1 and v12 � 0.33.These are the same as the approximate results given byWang and McDowell [21].
3.2. Honeycombs with regular square cells
Using Eqs. (8)–(12) and (14a)–(14c), the dimensionlessresults of all the independent elastic constants of the first-order honeycombs with regular square cells can be easilyobtained as:
E1 ¼E1
12qES¼ 1 ð19Þ
G12 ¼G12
18ð1�vSÞq
3GS¼ 1
1þ 35ð1�mSÞq
2ð20Þ
v12 ¼1
2vSq ð21Þ
G31 ¼G31
Gsq¼ 1
2ð22Þ
The dimensionless in-plane shear modulus G12, whichhas been normalized by 1
8ð1�vSÞGSq3, is plotted against thehoneycomb relative density q, as shown in Fig. 5. Thegreater the honeycomb relative density, the smaller thedimensionless in-plane shear modulus. This is quite differ-ent from Wang and McDowell’s dimensionless result of 1[21]. The dimensionless out-of-plane Young’s modulus(i.e. E3 ¼ E3= ðqESÞÞ is the same as that for equilateral tri-angular honeycombs. Apart from G12 and v12 ¼ 1
2vSq, all
other dimensionless elastic constants (i.e.E1 ¼ E2 ¼ E3 ¼ 1; G31 ¼ 1=2 and m31 = mS) are independentof the honeycomb relative density. Note that E1 and E3 arenormalized by different factors.
Fig. 3. Relationship between the in-plane dimensionless Young’s modulusE1 and the relative density q of regular honeycombs with macrosizedequilateral triangular cells.
Fig. 4. Relationship between the in-plane Poisson ratio m12 and therelative density q of regular honeycombs with macrosized equilateraltriangular cells.
Fig. 5. Relationship between the in-plane dimensionless shear modulusG12 and the relative density q of regular honeycombs with macrosizedsquare cells.
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4. Elastic constants of microsized first-order honeycombs
For uniform plates with thickness at the micrometerscale, the size-dependent bending stiffness is given by Yanget al. [12] as
DB ¼ES
1� m2S
� bh3
12� ½1þ 6ð1� mSÞðl=hÞ2� ð23Þ
and the transverse shear rigidity is given by Zhu [8] as
DS ¼GSbh1:2� ½1þ 6ð1� mSÞðl=hÞ2�2
1þ 2:5ð1þ mSÞðl=hÞ2ð24Þ
In Eqs. (23) and (24), h is the thickness of the cell walls andl is the material intrinsic length for the strain gradient ef-fect. If the first-order honeycomb is made of a metallicmaterial, l is at the submicron to micron scale. The axialstretching/compression stiffness of the cell walls with a uni-form thickness at the micrometer scale is the same as thatgiven in Eq. (14c) because the strain gradient effect is ab-sent. In this section, we consider the elastic properties ofthe first-order honeycombs made of uniform cell wallswhose thickness h is at the micrometer or submicron scale.
4.1. Honeycombs with regular equilateral triangular cells
Substituting DB, DS and DC given in Eqs. (23), (24) and(14c) into Eqs. (2) and (3), the in-plane Young’s modulus(which is normalized by 1
3ESqÞ of the first-order honey-
combs with microsized equilateral triangular cells can beobtained as
E1¼E1
13�ESq
¼1þ 1þ2:5ð1þvS Þ2ðl=hÞ2
5ð1�vS Þ½1þ6ð1�vS Þðl=hÞ2 �q2þ 1
12ð1�v2S Þ� ½1þ6ð1� vSÞðl=hÞ2� �q2
1þ 1þ2:5ð1þvS Þ2ðl=hÞ2
5ð1�vS Þ½1þ6ð1�vS Þðl=hÞ2 �q2þ 1
36ð1�v2S Þ� ½1þ6ð1� vSÞðl=hÞ2� �q2
ð25Þ
and the in-plane Poisson ratio is derived as
m12¼13þ 1þ2:5ð1þvS Þ2ðl=hÞ2
15ð1�vS Þ½1þ6ð1�vS Þðl=hÞ2 �q2� 1
36ð1�v2S Þ� ½1þ6ð1� vSÞðl=hÞ2� �q2
1þ 1þ2:5ð1þvS Þ2ðl=hÞ2
5ð1�vS Þ½1þ6ð1�vS Þðl=hÞ2 �q2þ 1
36ð1�v2S Þ� ½1þ6ð1� vSÞðl=hÞ2� �q2
ð26Þ
when a microsized first-order honeycomb undergoes uniax-ial compression or tension in the z direction (i.e. the out-of-plane direction), the strain gradient effect is absent. Thedimensionless out-of-plane Young’s modulus E3 in the z
direction is the same as that of the macrosized first-orderhoneycomb, and the out-of-plane Poisson ratio m31 is thesame as vs.
As the size of a honeycomb material is much larger thanits cells, when the honeycomb material with microsized cellsundergoes a globally uniform out-of-plane shear deforma-tion in the zx or zy plane (see Fig. 1), the shear strain in eachcell wall is always in the cell wall plane and uniform inamplitude, and any strain gradient effect can thus be
assumed to be absent. Therefore the out-of-plane dimen-sionless shear modulus is the same as that given by Eq.(18) for macrosized first-order honeycombs.
For the first-order honeycombs with regular microsizedequilateral triangular cells and different values of l/h, thedimensionless in-plane Young’s modulus E1, given by Eq.(25), and the in-plane Poisson ratio v12, given by Eq.(26), are plotted against the relative density in Figs. 6and 7, respectively. The Poisson ratio, vS, of the solid mate-rial is chosen as 0.3 in the calculation of the figures. As canbe seen, the thinner the cell walls (i.e. the larger the value ofl/h), the larger the dimensionless in-plane Young’s modulusE1 and the smaller the in-plane Poisson ratio v12.
Eq. (1) can be rewritten as
lh¼ 2
ffiffiffi3p
lqL
orlL¼ ql
2ffiffiffi3p
hð27Þ
where L is the length of the cell walls, which can be definedas the size of the cells. Figs. 6 and 7 demonstrate that, forthe first-order honeycombs with equilateral triangular cellsat the micrometer size scale and with a fixed relative densityq, the smaller the cell size, the larger the dimensionless in-plane Young’s modulus and the smaller the in-plane Pois-son ratio.
4.2. Honeycombs with regular square cells
For the first-order honeycombs with microsized regularsquare cells, the strain gradient effect is clearly absent whenit is uniaxially deformed in either the x, y or z direction.Therefore, its dimensionless elastic constants: E1; E3; G31
and the Poisson ratios: v12 and m31 are exactly the sameas those of the first-order honeycombs with macrosizedregular square cells.
Substituting Eqs. (23) and (24) into Eq. (10), the in-plane shear modulus can be obtained as
G12 ¼G12
18ð1�vSÞq
3GS¼ 1þ 6ð1� vSÞðl=hÞ2
1þ 35ð1�vSÞ �
1þ2:5ð1þvSÞðl=hÞ2
1þ6ð1�vS Þðl=hÞ2 q2ð28Þ
which is normalized by 18ð1�vSÞGSq3.
Fig. 6. Relationship between the in-plane dimensionless Young’s modulusE1 and the relative density q of regular honeycombs with microsizedequilateral triangular cells.
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The relationship between the in-plane dimensionlessShear modulus G12 and the relative density q of the first-order honeycombs with microsized regular square cells isplotted in Fig. 8. The thinner the cell walls, the larger thedimensionless in-plane shear modulus. As the size of thecells can be defined as L, for microsized honeycombs witha fixed relative density, the smaller the cell size, the largerthe dimensionless in-plane shear modulus.
It is easy to verify that, when the strain gradient effect isabsent (i.e. h/l tends to 0), all the elastic constants of thefirst-order honeycombs with either microsized equilateraltriangular cells or square cells reduce to those of their mac-rosized counterparts.
5. Elastic constants of nanosized first-order honeycombs
At the nanometer scale, both the surface elasticity [15]and the initial stresses [17,18] can greatly affect the mechan-ical properties of structural elements. Atomistic simula-tions [19] show that, for metallic structural elements withthe size of a few nanometers, no strain gradient effect exists,
and surface elasticity or surface energy dominates the influ-ence on the mechanical properties.
For uniform plates of thickness at the nanoscale, thecombined effects of surface elasticity and initial stress onthe bending stiffness is obtained as [18]
Db ¼Es
1� v2s
bh3
121þ 6S
Esh� 2s0
Eshvsð1þ vsÞ
� �
¼ Es
1� v2s
bh3
121þ 6ln
hþ e0s
vsð1þ vsÞ1� ms
� �ð29Þ
The transverse shear stiffness is derived as [8]
DS ¼GSbh1:2�
1þ 6lnh þ e0smS
ð1þmS Þ1�mS
h i2
1þ 10lnh þ 30 ln
h
� �2ð30Þ
and the axial stretching/compression stiffness is given by[15]
Dc ¼ Esbhð1þ 2ln=hÞ ð31ÞIn Eqs. (29)–(31), S is the surface elasticity modulus,ln = S/Es is the material intrinsic length at the nanoscaleand s0 is the initial surface stress, the amplitude of whichcan be varied by adjusting the applied electric potential[23–25]. When the initial surface stress s0 is present, the ini-tial elastic residual strains of the bulk material aree0s ¼ � 2s0
Esh ð1� vsÞ in both the cell wall length and widthdirections, and the initial elastic residual strain in the cellwall thickness direction is eh
0 ¼4vss0
Esh ¼ �2vs
1�vse0s. Although
the amplitude of e0scan be varied, the range of the recover-able elastic residual strain is limited by the yield strain ofthe bulk material. For single crystal nanomaterials or poly-meric materials, the yield strain can be 10% or even larger.Atomistic simulation [26] has shown that, if the diameter ofa gold wire is sufficiently small, it can automatically under-go plastic deformation solely owing to the presence of theinitial surface stresses. It is well known that the yieldstrength, ry, of some conductive polymer materials ornanosized metallic materials can be 0.1E (E is the Young’smodulus) or larger [27]. Biener et al. [28] have experimen-tally found that, for nanoporous Au material, by control-ling the chemical energy, the adsorbate-induced surfacestress s0 can reach 17–26 N m�1. If the diameter of the lig-aments is 5 nm, rx
0 would be 20 GPa. As the bulk materialdiscussed in this paper can be metallic, polymeric or biolog-ical, without losing generality, the tunable range ofe0s ¼ � 2s0
Esh ð1� vsÞ is assumed to be from �0.1 to 0.1. Inother words, the von Mises yield strength of the solid mate-rial is assumed to be 0.1ES/(1 � vS). If the actual yieldstrength of the honeycomb solid material is larger or smal-ler than this, the results obtained for the nanosized first-or-der honeycombs can still be obtained by scaling thosepresented in this paper up or down.
When the effect of the initial surface stress s0 is absent,the initial dimensions of the nanosized cell walls areassumed to be length L0, width b0 and thickness h0 for bothregular triangular and square honeycombs. When the effect
Fig. 7. Relationship between the in-plane Poisson ratio m12 and therelative density q of regular honeycombs with microsized equilateraltriangular cells.
Fig. 8. Relationship between the in-plane dimensionless shear modulusG12 and the relative density q of regular honeycombs with microsizedsquare cells.
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of the initial surface stress is present, the dimensions of thecell walls become
L ¼ L0ð1þ e0sÞ ð32aÞb ¼ b0ð1þ e0sÞ ð32bÞ
h ¼ h0ð1þ eh0Þ ¼ h0 1� 2vs
1� vse0s
� �ð32cÞ
and thus the relative density of both the first-order squareand equilateral triangular honeycombs becomes
q ¼ hL0
h0Lq0 ¼ 1� 2vs
1� vse0s
� �q0=ð1þ eosÞ ð33Þ
where e0s ¼ � 2s0
Esh ð1� vsÞ and
q0 ¼ 2ffiffiffi3p
h0=L0 ð33aÞfor equilateral triangular honeycombs and
q0 ¼ 2h0=L0 ð33bÞfor square honeycombs.
5.1. Honeycombs with regular equilateral triangular cells
Substituting DB, DS and DC and the dimensions of thenanosized cell walls given by Eqs. (29)–(33) into Eq. (2),the in-plane dimensionless Young’s modulus of honey-combs with nanosized equilateral triangular cells can beobtained as
E1¼E1
13ESq0
¼
1þ 2lnh
� �þ 1
5ð1�mS Þ �1þ10ln
h þ30 lnhð Þ2
1þ2ln
hð Þ1þ6ln
h þeos �mS ð1þmS Þ
1�mS
h i q2þ 112ð1�m2
S Þ� 1þ 6ln
h þ eos � mS ð1þmS Þ1�mS
h i�q2
1þ 15ð1�mS Þ �
1þ10lnh þ30 ln
hð Þ2
1þ6lnh þeos �
mS ð1þmS Þ1�mS
h iq2þ 136ð1�m2
S Þ�
1þ6lnh þeos �
mS ð1þmS Þ1�mS
h i1þ2ln
h½ � �q2
�1� 2vS
1�vSeos
1þ eos
ð34Þwhere the in-plane Young’s modulus is normalized by13� ESq0 and h and q0 are given by Eqs. (32c) and (33a),
respectively.When the effect of the initial surface stress s0 is absent
(i.e. the initial elastic residual strain e0S of the bulk materialis 0) and the effect of the surface elasticity is present, h = h0
and q = q0, and Eq. (34) reduces to
E1¼1þ 2ln
h
� �þ 1
5ð1�mS Þ �1þ2ln
hð Þ 1þ10lnh þ30 ln
hð Þ2
1þ6lnhð Þ �q2þ 1
12ð1�m2S Þ� 1þ 6ln
h
� ��q2
1þ 15ð1�mS Þ �
1þ10lnh þ30 ln
hð Þ21þ6ln
hð Þ �q2þ 136ð1�m2
S Þ� 1þ6ln
hð Þ1þ2ln
hð Þ �q2
ð35Þ
Fig. 9 shows the effect of the surface elasticity on the rela-tionship between the normalized in-plane (i.e. xy plane)Young’s modulus (given by Eq. (35)) and the relative densityq0 of the nanosized first-order honeycombs with regularequilateral triangular cells. If the surface elasticity modulusis positive (i.e. ln = S/ES > 0), the thinner the cell walls, thelarger the normalized Young’s modulus. Similarly to the
first-order honeycombs with microsized cells, for nanosizedfirst-order honeycombs with a fixed relative density q0, thesmaller the cell size L0, the larger the normalized in-planeYoung’s modulus. If the surface elasticity modulus is nega-tive (i.e. ln = S/ES < 0), the effects are reversed. For example,when ln/h is �0.2, the dimensionless Young’s modulusbecomes 0.6, which is smaller than that of the macrosizedhoneycombs (i.e. ln/h = 0). However, ln/h must be largerthan �1/2, otherwise the elastic modulus E1 would be nega-tive and the honeycomb structure would deform automati-cally [8] to a stable configuration. On the other hand, whenthe effect of the surface elasticity modulus is absent and theeffect of the initial stress/strain is present, Eq. (34) reduces to
E1¼1þ 1
5ð1�mSÞ½1þeos�mS ð1þmS Þ
1�mS��q2þ 1
12ð1�m2SÞ� 1þ eos � mSð1þmS Þ
1�mS
h i�q2
1þ 1
5ð1�mSÞ 1þeos�mS ð1þmS Þ
1�mS
h i �q2þ 136ð1�m2
S Þ� 1þ eos � mSð1þmSÞ
1�mS
h i�q2
�1� 2vS
1�vSeos
1þ eos
ð36ÞEq. (36) can be approximated well by E1 � ð1� 2vSeos=ð1� vSÞÞ=ð1þ eosÞ, and the error is smaller than 1% ifq0 6 0.35. Thus the in-plane dimensionless Young’s modu-lus of a nanosized first-order regular honeycomb with equi-lateral triangular cells can be varied by adjusting theamplitude of the initial surface stress (and hence the initialstrain eos), and the tunable range depends on the Poissonratio vS of the solid materials. When eos is varied from0.1 to �0.1, the tunable range of the dimensionless in-planeYoung’s modulus will be from 0.909 to 1.111 if vS = 0,0.831–1.206 if vS = 0.3, and 0.727–1.5 if vS = 0.5.
The in-plane Poisson ratio can be obtained as
m12¼
13þ 1
15ð1�mSÞ �1þ10ln
h þ30 lnhð Þ2
1þ6lnh þeos�
mS ð1þmS Þ1�mS
h iq2� 136ð1�m2
S�
1þ6lnh þeos�
mS ð1þmS Þ1�mS
h i1þ2ln
hð Þ �q2
1þ 15ð1�mSÞ �
1þ10lnh þ30 ln
hð Þ2
1þ6lnh þeos�
mS ð1þmS Þ1�mS
h iq2þ 136ð1�m2
S�
1þ6lnh þeos�
mS ð1þmS Þ1�mS
h i1þ2ln
hð Þ �q2
ð37ÞWhen the effect of the initial surface stress s0 is absent, Eq.(37) reduces to
m12 ¼13þ 1
15ð1�mS Þ1þ10ln
h þ30 lnhð Þ2
1þ6lnh½ � � q2 � 1
36ð1�m2S Þ� 1þ6ln
h½ �1þ2ln
hð Þ � q2
1þ 15ð1�mSÞ
1þ10lnh þ30 ln
hð Þ21þ6ln
h½ � � q2 þ 136ð1�m2
S Þ� 1þ6ln
h½ �1þ2ln
hð Þ � q2
ð38Þ
Fig. 10 shows that the effect of the surface elasticity onthe in-plane Poisson ratio (given by Eq. (38)) of nanosizedfirst-order honeycombs depends upon the value of ln/h.The thinner the cell walls, the smaller the Poisson ratio.On the other hand, the effect of the initial stress or strainon the Poisson ratio is so small that the result is notpresented.
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From the stretching stiffness of nanoplate given by Eq.(31), the normalized out-of-plane Young’s modulus ofthe first-order honeycombs with nanosized equilateral tri-angular cells can be easily obtained as
E3 ¼E3
Esq0
¼ 1þ 2ln
h
� �� 1� 2vS
1� vSeos
� �=ð1þ eosÞ ð39Þ
The normalized out-of-plane shear modulus can be easilyderived as
G31 ¼G31
Gsq0
¼ 1
21þ 2ln
h
� �1� 2vS
1� vSeos
� �=ð1þ eosÞ ð40Þ
For the nanosized first-order honeycombs with a fixed rel-ative density, the thinner the cell walls, the larger will be thenormalized Young’s modulus and the out-of-plane shearmodulus if ln = S/ES is positive. If the surface elasticitymodulus is negative, the trend of the effects is reversed.As the Poisson ratio of the surface is assumed to be thesame as that of the bulk material, the out-of-plane Poissonratio of a nanohoneycomb, m13, is thus equal to vS. Whenthe effect of the surface elasticity is present and the effectof the initial stress/strain is absent, both the out-of-plane
Young’s modulus and shear modulus are proportional to(1 + 2ln/h). On the other hand, when the effect of surfaceelasticity is absent (or fixed) and the effect of the initialstress/strain is present, both the out-of-plane dimensionlessYoung’s modulus and shear modulus depend not only onthe amplitude of the initial strain eos, but also on the Pois-son ratio vS of the solid material.
5.2. Honeycombs with regular square cells
Substituting Eqs. (29)–(33) into Eq. (8), the in-planedimensionless Young’s modulus of the first-order honey-combs with nanosized square cells can be obtained as
E1 ¼E1
Esq0
¼ 1
21þ 2ln
h
� �1� 2vS
1� vSeos
� �=ð1þ eosÞ ð41Þ
which is normalized by ESq0.The in-plane dimensionless shear modulus of nanosized
first-order honeycombs, which is normalized by 18ð1�vSÞ q
30GS,
can be obtained as
G12¼G12
18ð1�vSÞq
30GS¼
1þ 6lnh þ e0S
mSð1þmSÞð1�mSÞ
1þ 35ð1�vSÞ �
1þ10lnh þ30 ln
hð Þ21þ6ln
h þe0SmS ð1þmS Þð1�mS Þ
q2
�1� 2vS
1�vSeos
1þ eos
!3
ð42ÞWhen the effect of the initial surface stress is absent (i.e. e0S
is 0) and the effect of the surface elasticity is present, Eq.(42) reduces to
G12 ¼G12
18ð1�vSÞGSq3
0
¼1þ 6ln
h
1þ 35ð1�mSÞ �
1þ10lnh þ30 ln
hð Þ21þ6ln
hq2
ð43Þ
The relationship between the dimensionless in-plane shearmodulus G12 and the relative density q of the first-orderhoneycombs with nanosized square cells is plotted inFig. 11. If the surface elasticity modulus is positive (i.e.ln = S/ES > 0), the thinner the cell walls, the larger thedimensionless shear modulus. If the relative density q ofnanosized honeycombs is fixed, the smaller the cell wall
Fig. 10. Size-dependent effect on the relationship between the in-planePoisson ratio m12 and the relative density q of regular nanosized equilateraltriangular honeycombs when the effect of the cell wall initial elasticresidual strain is absent.
Fig. 9. Relationship between the in-plane dimensionless Young’s modulusE1 and the relative density q of regular honeycombs with nanosizedequilateral triangular cells.
Fig. 11. Size-dependent effect on the relationship between the in-planedimensionless shear modulus G12 and the relative density q of regularhoneycombs with nanosized square cells when the effect of the cell wallinitial elastic residual strain is absent.
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length or the cell size L, the larger the dimensionless elasticmodulus. If the surface elasticity modulus is negative (i.e.ln = S/ES < 0), the effects are reversed. For example, ifln=h ¼ �0:1;G12 becomes 0.4, which is smaller than thatfor macrosized honeycombs (i.e. ln/h = 0). Eq. (43) impliesthat ln/h must be larger than �1/6, otherwise the in-planeshear modulus G12 becomes negative and the honeycombstructure will automatically deform until the structural sta-bility is regained [8].
When the effect of the surface elasticity modulus isabsent and only the effect of the initial surface stress is pres-ent, Eq. (42) reduces to
G12 ¼G12
18ð1�vSÞGSq3
0
¼1þ e0S
mSð1þmSÞð1�mSÞ
1þ 35ð1�mSÞ �
1
1þe0SmS ð1þmS Þð1�mS Þ
q2
1� 2vS1�vS
eos
1þ eos
!3
ð44ÞFig. 12 shows the effect of the initial residual elastic
strain e0S of the bulk material (or the initial stress) on thein-plane dimensionless shear modulus of the first-orderhoneycombs with nanosized perfect regular square cells.When vS = 0.3 and the initial strain eos is varied from 0.1to �0.1, the dimensionless in-plane shear modulus G12
can change from 0.6 to 1.5.For the first-order nanosized honeycombs with regular
square cells, it is easy to obtain the same dimensionlessout-of plane Young’s modulus E3 and shear modulus G31
as those given by Eqs. (39) and (40) for the nanosized first-order honeycombs with regular equilateral triangular cells.
It is easy to verify that, for regular nanosized honey-combs with either square cells or equilateral triangularcells, all the elastic constants will reduce to those of theirmacrosized counterparts when the effects of both the sur-face elasticity and the initial stress/strain are absent.
6. Size-dependent and tunable elastic properties of
hierarchical honeycombs
The hierarchical honeycombs are assumed to be self-similar [29]. At all different hierarchy levels, they are
treated as materials whose size is much larger than the indi-vidual cells at the same hierarchy level. The relative densityof the nth-order self-similar hierarchical honeycombs witheither equilateral triangular cells or square cells can be eas-ily obtained as
qn ¼ 1� 2vS
1� vSeos
� �ðq0Þ
n=ð1þ eosÞ ð45Þ
where q0 is given by Eq. (33a) for the first-order honey-combs with equilateral triangular cells and by Eq. (33b)for the first-order honeycombs with square cells. Whenthe initial strain eos is 0, qn reduces to (q0)n.
For the first-order honeycombs with regular equilateraltriangular cells of wall thickness at the macro-, micro- ornanoscale, the five independent elastic constants areobtained as given in Sections 3–5, depending upon the sizescale of their cell wall thickness. For the nth-order self-sim-ilar hierarchical honeycombs with equilateral triangularcells, the five independent dimensionless elastic constantscan be obtained as
ðE1Þn ¼ðE1Þn13ESq0
� q0
3
� �n�1
� ðE1Þ1 ð46Þ
ðv12Þn � 1=3 ð47Þ
ðE3Þn ¼ðE3ÞnEsq0
¼ ðq0Þn�1 � ðE3Þ1 ð48Þ
ðG31Þn ¼ðG31ÞnGsq0
¼ q0
2
� �n�1
� ðG31Þ1 ð49Þ
and (v31)n = vS, where n is the hierarchy level of the self-similar hierarchical honeycombs. In Eqs. (46), (48) and(49), ðE1Þ1; ðE3Þ1 and ðG31Þ1 are the dimensionless Young’smoduli in the x and z directions and the dimensionlessshear modulus in the xz plane of the first-order honey-comb, respectively. It is easy to check that, when n P 2,the errors of Eqs. (46) and (47) are smaller than 0.2% ifq0 6 0.35.
For the nth-order self-similar hierarchical honeycombswith square cells, the six independent dimensionless elasticconstants can be obtained as
ðE1Þn ¼ðE1Þn12q0ES
¼ q0
2
� �n�1
� ðE1Þ1 ð50Þ
ðE3Þn ¼ðE3Þnq0ES
¼ ðq0Þn�1 � ðE3Þ1 ð51Þ
ðG12Þn ¼ðG12Þn
18ð1�vS Þ ðq0Þ
3GS
� q0
8
� �3ðn�1Þ� ðG12Þ1 ð52Þ
ðv12Þn ¼q0
2
� �n�1
� ðv12Þ1 ð53Þ
ðG31Þn ¼ðG31ÞnGsq0
¼ q0
2
� �n�1
� ðG31Þ1 ð54Þ
and (m31)n = mS. In Eqs. (50)–(54), the elastic constants ofthe first-order honeycombs with regular square cells of wallthickness at the macro-, micro- or nanoscale, ðE1Þ1;ðE3Þ1; ðG12Þ1; ðm12Þ1 and ðG31Þ1, are given in Sections 3–5,
Fig. 12. Effect of cell wall initial elastic residual strain on the relationshipbetween the in-plane dimensionless shear modulus G12 and the relativedensity q of regular honeycombs with nanosized square cells when theeffect of the surface elasticity modulus is absent.
H.X. Zhu et al. / Acta Materialia 60 (2012) 4927–4939 4935
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depending upon the size scale of their cell wall thickness.Therefore, the elastic constants of the nth-order self-similarhierarchical honeycombs are functions of those of the first-order honeycombs. It is easy to check that, when n P 2, theerror of Eq. (53) is smaller than 0.4% if q0 6 0.35. Fan et al.[30] and Taylor et al. [31] studied the effects of structuralhierarchy on the elastic properties of honeycombs. How-ever, they did not study the size-dependent effect or the tun-able elastic properties of hierarchical honeycombs. Zhu [8]studied the size-dependent and tunable mechanical proper-ties for single-order regular hexagonal honeycombs, butnot for hierarchical honeycombs.
For regular self-similar hierarchical honeycombs withthe thickness of their first-order cell walls at the nanometer
scale, the dimensionless elastic properties ðE1Þn; ðE3Þn;ðG12Þn and ðG31Þn contain a common factor 1� 2vS
1�vSeos
� �=
ð1þ eosÞ and can thus be varied over a large range byadjusting the amplitude of the initial strain eos. When theinitial strain is absent, the initial cell diameter, area andvolume of an nth-order self-similar hierarchical honeycombare assumed to be (L0)n, (A0)n and (V0)n respectively. Whenthe initial strain eos is present, the dimensionless cell diam-eter, area and volume of an nth-order self-similar hierarchi-cal honeycomb become
ðLÞn=ðL0Þn ¼ 1þ eos ð55ÞðAÞn=ðA0Þn ¼ ð1þ eosÞ2 ð56Þ
and
ðV Þn=ðV 0Þn ¼ ð1þ eosÞ3 ð57Þ
If eos can be controlled to change from �0.1 to 0.1, thedimensionless cell diameter, area and volume of an nth-or-der self-similar hierarchical honeycomb would vary overranges from 0.9 to 1.1, 0.81 to 1.21 and 0.729 to 1.331,respectively. This can be of very important applications.For example, by adjusting the cell size, a hierarchical cellu-lar material could possibly be controlled to change its coloror wettability. Micro- or nanosized porous materials areoften used to select/separate materials with a specific parti-cle size in medical industry. The results given in Eqs. (55)–(57) suggest that the size of the selected/separated particlesis tunable and controllable. Although it is difficult to alterthe cell size and the mechanical properties, such as the stiff-ness, the buckling force and the natural frequency, of a sin-gle-order macro- or microsized porous material, the resultsobtained in this section suggest that it is possible to realizethose for its hierarchical counterpart with the first-ordercell wall/strut thickness at the nanometer scale.
In addition, Eqs. (42) and (52) imply the possibility that,if ln/h is very close to �1/6 (but ln/h should be slightly lar-ger than �1/6, the structure would not be stable), control-ling eos to a negative value (say �0.1) could result in anegative ðG12Þ, and hence could make the hierarchical
cellular material collapse automatically [8]. In practicalapplications, one failing part could help protect others.
7. Conclusion
This paper presents the detailed derivation and closed-form results of all the independent elastic constants ofself-similar hierarchical honeycombs with either regularsquare or equilateral triangular cells. The results imply thatmany interesting geometrical, mechanical and physicalproperties and functions that do not exist in single-ordermacrosized cellular materials become possible in their hier-archical nanostructured counterparts. If the cell wall thick-ness of the first-order honeycomb is at the micrometerscale, the elastic properties of a hierarchical honeycombare size dependent owing to the strain gradient effects. Ifthe cell wall thickness of the first-order honeycomb is atthe nanometer scale, in addition to the size dependenceowing to the effects of surface elasticity, the elastic proper-ties of a hierarchical honeycomb are tunable because of theeffects of the initial stresses/strains, the amplitudes of whichare controllable. More interestingly, if the cell wall/strutthickness of the first order cellular material is at the nano-meter scale, the cell size, surface color, wettability, materialstrength, stiffness, natural frequency and many other inter-esting physical properties of a hierarchical nanostructuredcellular material could be varied over a large range.
Acknowledgement
This work is supported by the EC project PIRSES-GA-2009-247644.
Appendix A. Derivation of the elastic properties of regular
honeycombs with equilateral triangular cells
A.1. In-plane Young’s modulus and Poisson ratio
When a first-order regular honeycomb with equilateraltriangular cells is uniaxially compressed in the x direction,as shown in Fig. 1a, there is no junction rotation because ofthe symmetry of the structure and the applied load. Only arepresentative unit cell structure, as shown in Fig. 1b, isthus needed for the analysis. Node A is assumed to haveno displacement and rotation. The horizontal load appliedat B is assumed to be P1 and the horizontal load applied atC is P2. Obviously, there is no load in the y direction at Band C.
The inclined cell wall AB undergoes bending, transverseshear and axial compression. Its deformation in the x direc-tion is given by
Dx ¼ Dxb þ Dx
s þ Dxc ðA1Þ
where Dxb; Dx
s and Dxc are the deformations in the x direction
owing to cell wall bending, transverse shear and cell wallaxial compression, respectively. By assuming that the bend-ing stiffness of the cell walls is DB, the shear stiffness is DS,
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and the axial compression stiffness is DC, Eq. (A1) can berewritten as
Dx ¼P 1 � sin 60
� � L2
� �3
3DBcos 30
� þP 1 � sin 60
� � L2
DS
� cos 30� þ
P 1 � cos 60� � L
2
DCsin 30
�
¼ P 1L3
32DBþ 3P 1L
8DSþ P 1L
8DCðA2Þ
where L is the length of the cell walls.From Fig. 1b, the dimension of the representative unit
cell in the x direction is
lx ¼L2� cos 60
� ¼ L4
ðA3Þ
The compressive strain of the inclined element AB in the x
direction is therefore
ex ¼Dx
lx¼ P 1L2
8DBþ 3P 1
2DSþ P 1
2DCðA4Þ
The stress component of the honeycomb in x direction dueto force P1 is thus
rx1 ¼P 1
L � sin 60� � b¼ 2P 1ffiffiffi
3p
LðA5Þ
where the width b of the honeycomb is much larger thanthe cell wall thickness h and is assumed to be 1 forsimplicity.
For the horizontal element AC, the deformation com-patibility condition requires that the compressive strainof AC due to force P2 should be the same as that of theinclined element AB in the x direction. Thus,
P 2 ¼ DC � ex ¼ DC �P 1L2
8DBþ 3P 1
2DSþ P 1
2DC
� �ðA6Þ
The stress component of the honeycomb in x direction dueto force P2 is derived as
rx2 ¼P 2
L � sin 60� � b ¼2P 2ffiffiffi
3p
L
¼ P 1 � L � DC
4ffiffiffi3p
DB
þffiffiffi3p
P 1 � DC
DS � Lþ P 1ffiffiffi
3p
LðA7Þ
The total compressive stress in the x direction is thus ob-tained as
rx ¼ rx1 þ rx2 ¼P 1LDC
4ffiffiffi3p
DB
þffiffiffi3p
P 1DC
DSLþ
ffiffiffi3p
P 1
LðA8Þ
The Young’s modulus of the honeycomb is therefore
Ex¼rx
ex¼
P 1�L�DC
4ffiffi3p
DBþffiffi3p
P 1�DCDS �L þ
ffiffi3p
P 1
L
P 1�L2
8DBþ 3P 1
2DSþ P 1
2DC
¼DS �DC �L2þ12DB�DCþ12DB�DS
4ffiffi3p
DB�DS �LDS �DC �L2þ12DB�DCþ4DB�DS
8DB�DS �DC
¼ 2DS �D2C �L2þ24DB �D2
Cþ24DB �DS �DCffiffiffi3p
L3 �DS �DCþ12ffiffiffi3p
L �DB �DCþ4ffiffiffi3p
L �DB �DS
ðA9Þ
The deformation of the inclined cell wall in the y directionis
Dy ¼ Dyb þ Dy
s þ Dyc ðA10Þ
Eq. (A10) can be rewritten as
Dy ¼P 1 � sin 60� � L
2
� �3
3DBsin 30� þ
P 1 � sin 60� � L2
� �DS
� sin 30� �P 1 � cos 60� � L
2
� �DC
cos 30�
¼ffiffiffi3p
P 1 � L3
96DBþ
ffiffiffi3p
P 1 � L8DS
�ffiffiffi3p
P 1 � L8DC
ðA11Þ
From Fig. 1b, the dimension of the representative unit cellin the y direction is
ly ¼L2� sin 60
� ¼ffiffiffi3p
L4
ðA12Þ
The expansion strain in the y direction can be obtained as
ey ¼Dy
ly¼ P 1L2
24DBþ P 1
2DS� P 1
2DCðA13Þ
The Poisson ratio is therefore
v12 ¼ey
ex
¼ L2DSDC þ 12DBDC � 12DBDS
3L2DSDC þ 36DBDC þ 12DBDSðA14Þ
As the honeycomb structure is isotropic, the in-plane shearmodulus G12 can be obtained from Ex and v12, and given as
G12 ¼Ex
2ð1þ v12Þ
¼ffiffiffi3p
L2 � DS � DC þ 12ffiffiffi3p
DB � DC þ 12ffiffiffi3p
DB � DS
4L3 � DS þ 48L � DB
ðA15Þ
A.2. Out-of-plane shear modulus and Young’s modulus
To derive the out-of-plane shear modulus, the size of thehoneycomb material is assumed to be much larger than thehoneycomb cells and thus much larger than the cell walllength L. When the honeycomb material is subjected toan out-of-plane pure shear stress syz (which is in the yz
plane), the shear load T on the cell wall of the representa-tive unit cell is shown in Fig. A1.
The equilibrium in the y direction requires
Q ¼ T � sin 600 ðA16Þand
Q ¼ s�yz
ffiffiffi3p
4L2 ðA17Þ
where syz is the effective out-of-plane shear stress acting onthe area
ffiffi3p
4L2 of the representative unit cell of the honey-
comb material, as shown in Fig. A1.
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In this part, we derive the out-of-plane shear modulusG13 for the first-order honeycombs with nanosized equilat-eral triangular cells. Eqs. (A16) and (A17) lead to
T ¼ syz �1
2L2 ðA18Þ
As the shear stress or strain is uniform in the cell walls (be-cause the honeycomb material is assumed to be much lar-ger than the cell size L), the shear strain ci
yz in theinclined cell wall shown on the right side of Fig. A1 is re-lated to the shear force T by
ciyz ¼ T
�GShLþ 2 � SL
2ð1þ mSÞ
� �
¼ syzL2GShð1þ 2ln=hÞ ðA19Þ
where S is the surface elasticity modulus, the surface Pois-son ratio is assumed to be vS (the same as that of the solidmaterial), S
2ð1þvSÞ is the shear modulus of the surface, ln = S/ES is the material intrinsic length at nanometer scale, and h
is the thickness of the nanosized cell walls.The shear strain of the inclined cell wall is related to the
out-of plane shear strain (i.e. the shear strain in the yz
plane) of the first-order honeycomb by
cyz ¼ci
yz
cos 300¼ Lsyzffiffiffi
3p
GShð1þ 2ln=hÞðA20Þ
As the relative density of the first-order honeycombs withequilateral triangular cells is q ¼ 2
ffiffiffi3p
hL, the out-of-plane
shear modulus of the nanosized honeycomb is thus
G13 ¼ Gyz ¼syz
cyz=ðGSqÞ ¼
1
2ð1þ 2ln=hÞ ðA21Þ
which is normalized by Gsq. As can be seen in Eq. (A21), thedimensionless out-of-plane shear modulus of honeycombswith nanosized cells is size dependent. When the surface ef-fect is absent (i.e. h� ln), Eq. (A21) reduces to the dimen-sionless out-of-plane shear modulus for a honeycombswith macro- or microsized equilateral triangular cells.
The stretching stiffness of a nanoplate is given by [15]
DC ¼ ESbhð1þ 2ln=hÞ ðA22Þ
The dimensionless out-of-plane Young’s modulus of nano-sized first-order honeycombs with equilateral triangularcells can be easily obtained as
E3 ¼E3
Esq¼ 1þ 2ln
hðA23Þ
which is normalized by ESq. Similarly, when the surface ef-fect is absent, it reduces to that of honeycombs with macro-or microsized cells.
Appendix B. Derivation of the elastic properties of regular
honeycombs with square cells
B.1. In-plane Young’s modulus and Poisson ratio
When a regular first-order honeycomb with square cellsis uniaxially compressed in the x direction, there is no junc-tion rotation because of the symmetry of the structure andthe applied load. There is no stress or strain in vertical cellwalls. By taking account the expansion of the horizontalcell walls, the in-plane Poisson ratio of the first-order hon-eycomb can be obtained as v12 ¼ v21 ¼ h
L vS ¼ 12qvS. The in-
plane dimensionless Young’s modulus can be easilyobtained as E1 ¼ E1
12ESq¼ DC
ES h, where q ¼ 2hL is the honeycomb
relative density.To derive the in-plane shear modulus, a pure shear stress
sxy is applied to the honeycomb shown in Fig. 2a. Only arepresentative unit cell structure (shown in Fig. 2b) isneeded for the analysis. The force equilibrium conditionrequires
P ¼ sxyL ðA24ÞIf junction A shown in Fig. 2b has no rotation, the verticaldisplacement of the middle point D of the horizontal cellwall owing to bending and transverse shear should be
DAD ¼ DB þ DS ¼P L
2
� �3
3DBþ
P L2
DSðA25Þ
Obviously, under pure in-plane shear deformation, themiddle points of the horizontal cell walls of the deformedsquare honeycomb always remain in the same straight line,which is assumed to be in the horizontal position in order
Fig. A1. The out-of-plane shear load on the area of a representative cell unit.
4938 H.X. Zhu et al. / Acta Materialia 60 (2012) 4927–4939
Author's personal copy
to simplify the analysis. Thus, the deformed cell wall ADhas a clockwise rotation of hA, which is given as
hA ¼DAD
L=2¼ PL2
12DBþ P
DSðA26Þ
Consequently, owing to cell wall bending, transverse shearand junction rotation, the displacement of point C in thehorizontal direction is obtained as
jDCj ¼ 2hAðL=2Þ ¼ PL3
12DBþ PL
DSðA27Þ
The shear strain c is therefore
cxy ¼jDCjL=2¼ sxyL3
6DBþ 2sxyL
DSðA28Þ
The in-plane shear modulus of a regular square honey-combs is thus
G12 ¼sxy
cxy¼ 6DBDS
DSL3 þ 12DBLðA29Þ
References
[1] Warren WE, Kraynik AM. Mech. Mater. 1987;6:27–37.[2] Papka SD, Kyriakides S. J. Mech. Phys. Solids 1994;42:1499–532.[3] Masters IG, Evans KE. Compos. Struct. 1996;35:403–22.[4] Gibson LJ, Ashby MF. Cellular Solids: Structures and Properties.
2nd ed. Cambridge: Cambridge University Press; 1997.[5] Zhu HX, Hobdell JR, Windle AH. J. Mech. Phys. Solids
2001;49:857–70.[6] Zhu HX, Thorpe SM, Windle AH. Int. J. Solid Struct.
2006;43:1061–78.[7] Wang AJ, McDowell DL. J. Eng. Mater. Technol. 2004;126:137–56.[8] Zhu HX. J. Mech. Phys. Solids 2010;58:696–709.
[9] Toupin RA. Arch. Ration. Mech. Anal. 1962;11:385–414.[10] Nix WD, Gao H. J. Mech. Phys. Solid 1998;46:411–25.[11] Gao H, Huang Y, Nix WD, Hutchinson JW. J. Mech. Phys. Solid
1999;47:1239–63.[12] Yang F, Chong ACM, Lam DCC, Tong P. Int. J. Solid Struct.
2002;39:2731–43.[13] Lam DCC, Yang F, Chong ACM, Wang J, Tong P. J. Mech. Phys.
Solids 2003;51:1477–508.[14] Zhu HX, Karihaloo BL. Int. J. Plast. 2008;24:991–1007.[15] Miller RE, Shenoy VB. Nanotechnology 2000;11:139–47.[16] Wang J, Duan HL, Huang ZP, Karihaloo BL. Proc. Roy. Soc.
2006;A462:1355–63.[17] Zhu HX. Nanotechnology 2008;19:405703.[18] Zhu HX, Wang J, Karihaloo BL. J. Mech. Mater. Struct.
2009;4:589–604.[19] Sun ZH, Wang XX, Soh AK, Wu HA, Wang Y. Comput. Mater. Sci.
2007;40:108–13.[20] Kim B, Christensen RM. Int. J. Mech. Sci. 2000;42:657–76.[21] Wang AJ, McDowell DL. J. Eng. Mater. Technol. 2004;126:137–
156.[22] Gere JM, Timoshenko SP. Mechanics of Materials. 3rd ed. Lon-
don: Chapman & Hall; 1995.[23] Haiss W, Nichols RJ, Sass JK, Charle KP. J. Electroanal. Chem.
1998;452:199–202.[24] Weissmuller J, Viswanath RN, Kramer D, Zimmer P, Wurschum R,
Gleiter H. Science 2003;300:312–5.[25] Kramer D, Viswanath RN, Weissmuller J. Nano Lett. 2004;4:793–
796.[26] Diao D, Gall K, Duan ML, Zimmerman JA. Acta Mater.
2006;54:643–53.[27] Lin ZC, Huang JC. Nanotechnology 2004;15:1509–18.[28] Biener J, Wittstock A, Zepeda-Ruiz LA, Biener MM, Zielasek V,
Kramer D, et al. Nat. Mater. 2009;8:47–51.[29] Lakes R. Nature 1993;361:511–5.[30] Fan HL, Jin FN, Fang DN. Compos. Sci. Technol. 2008;68:
3380–7.[31] Taylor CM, Smith CW, Miller W, Evans KE. Int. J. Solid Struct.
2011;48:1330–9.
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