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usesscience for a changing world
Molecular Stratigraphy of the Devonian Domanik Formation, Timan-Pechora Basin,
by Michele L. W. Tuttle, 1 Paul G. Lillis, 1 and Jerry L. Clayton 1
Open-File Report 99-379
1999
This report is preliminary and has not been reviewed for conformity with U.S. Geological Survey editorial standards or with the North American Stratigraphic Code. Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government.
U.S. DEPARTMENT OF THE INTERIOR U.S. GEOLOGICAL SURVEY
'Denver, Colorado
Table of Contents
Page
Introduction .............................................. 1Methods ................................................... 3The Geochemistry of Domanik Source Rocks .................. 7
Lithology and Mineralogy ............................. 7Organic Geochemistry ................................. 7Trace Metal Geochemistry ............................ 17Sulfur Geochemistry ................................. 23
Paleoenvironmental Conditions during Deposition of theDomanik Formation ...................................... 24
References ............................................... 24
List of Tables
Page
Table 1. Selected trace element concentrations and V/(V+Ni) ratios in a variety of shales and sediments ........................................... 21
List of Figures
Page
Figure 1. Index map of Russia and map of Timan-Pechora basin showing study location inside square around the town of Ukhta. Modified from Ulmeshek (1982) ....2
Figure 2. Domanik Formation sample localities, Ukhtaarea ................................................. 4
Figure 3. Stratigraphic location of samples and theirlithology at each sampling location. [Note change in depth scale within Outcrop 7 column.] ................ 5
Figure 4. Crossplots of (A) calculated calcite (wt. %), (B) organic carbon (wt. %), and (C) calculated clay (wt. %) versus calculated silica (quartz) content (wt. %) ...................................... 8
Figure 5. X-ray diffraction traces of a typical limestone, massive shale, and fissile shale from the Domanik Formation ............................................ 9
Figure 6. Organic-carbon content and kerogen elementalcomposition from the lower 0.6 meters of the Domanik Formation ........................................... 10
Figure 7. Crossplot of S2 (mg HC/gm rock) versus organiccarbon (wt. %) ...................................... 11
Figure 8. Crossplot of HI versus 01 ..................... 12
Page
Figure 9. Crossplot of extractable organic matter (ppm) versus total organic matter (wt. %). Organic matter was calculated using 1.326 times the organic-carbon value. This conversion factor was derived from the atomic composition of the organic fraction and was constant throughout the data set .................... 14
Figure 10. Stable carbon isotope values of saturated and aromatic hydrocarbon fractions of the bitumen extract and the kerogen fraction ............................ 15
Figure 11. Histograms of (A) vanadium pophyrins (ppm) and(B) nickel pophyrins (ppm) in bitumen ............... 16
Figure 12. Extract biomarker composition from the lower0.6 meters of the Domanik Formation ................ 18
Figure 13. Crossplots of metal concentrations in agua-regia extracts and bulk rock ........................ 19
Figure 14. Crossplots of total vanadium and total nickel versus organic carbon (wt. %), with correlation coefficients for other metals ....................... 22
Figure 15. Depth profile of organic carbon (wt. %) for entire Domanik section sampled and 0.6 meter cycle within the Lower Domanik Formation ....................
Appendix TablesPage
Table Al. Data on outcrop samples collected 1994,including Rock Eval data, inorganic chemistry, and sulfur speciation and their isotopic composition. Ar, analysis done on aqua regia extract; tot, analysis done on whole rock; %, weight basis; calc, calculated. Sulfur isotopes reported in &> relative to Canon Diablo Troilite standard ........ Al-1
Table A2. Data on outcrop samples collected 1995,including Rock Eval data, inorganic chemistry. Ar, analysis done on aqua regia extract; tot, analysis done on whole rock; %, wt. basis; calc, calculated A2-1
Table A3. Rock Eval data for finely spaced drillsamples ........................................... A3-1
Table A4. Information on samples in subset. All sampleswere collected in 1995 ............................ A4-1
11
Page
Table A5. Data on subset of samples, including mineralogy of the whole rock; atomic ratios of organic matter; carbon isotopes and V and Ni porphyrin (P) content in bitumen extracts; and sulfur speciation and their isotopic composition. Mineralogy in peak height (chart units), carbon isotope data relative to PDB standard, and sulfur isotopes in &> relative to Canon Diablo Troilite standard .......................... A5-1
Table A6. Extraction and column chromatography data for the Domanik bitumen extracts. [Note, 96010914- 96019017 are oils collected in the vicinity of the Domanik rock samples and although not discussed in the text, the oil data are included in this table.]A6-1
Table A7. Biomarker ratios of Domanik bitumen extracts.See parameter key at end of table ................. A7-1
Table A8. Saturated hydrocarbon gas chromatography datafor Domanik bitumen extracts ...................... A8-1
111
Molecular stratigraphy of the
Devonian Domanik Formation,
Timan-Pechora Basin, Russia
by Michele L.W. Tuttle, Paul G. Lillis,
and Jerry L. Clayton
Introduction
The Timan-Pechora Basin occupies 322,000 km2 in northwest Russia (Ulmishek, 1982) (fig. 1). The Domanik Formation of Late Devonian age is considered the major source rock for the petroleum within this basin (possibly as much as 95% of the oil within the region; Ulmishek, 1988). The formation is mature throughout the basin except for parts of the southwestern margin of the basin where our study area is located.
The Domanik Formation is widespread throughout the Timan- Pechora Basin. The organic-rich nature of the formation is thought to have resulted from a productive water column and pelagic sedimentation in an anoxic marine environment. Variation in organic-carbon content has been attributed to changes in the magnitude of anoxia within the depositional basin (Ulmishek, oral commun., 1999).
The goal of our study is to characterize the variability in the organic and inorganic geochemistry of the immature Domanik source rock. This report tabulates our geochemical data. Complete profiles of inorganic chemistry and systematic Rock-eval data are tied to variations in lithofacies of the source rock. Lithofacies are further characterized with detailed organic geochemical stratigraphy, sulfur speciation and isotopy, and bulk mineralogy. The data tabulated herein are used to correlate the variability of lithofacies and geochemical data with changes in paleoenvironmental conditions at the time of deposition and early diagenesis of this important petroleum source.
Collaborators at VNIGRI (All Russia Petroleum Research Exploration Institute) in Ukhta, Russia, have provided field support, biostratigraphic control on sampling intervals, oil samples from the vicinity of our field area, and technical advice on petroleum geology and geochemistry of the basin.
1300 km
Barents Sea
Rivers TownsD Study Area
Figure 1. Index map of Russia and map of Timan-Pechora basin showing location of study area inside square around the town of Ukhta. Modified from Ulmeshek (1982).
Collaborators include Dr. Vladimir I. Bogatsky, Dr. Sergey A. Danilevsky, Dr. Yulia Yudina, and Margarita Moskalenko. Ella Bogatsky and Alexander Kutlinsky were our interpreters.
Methods
In 1995, outcrops and quarries near Ukhta, Russia, were sampled (fig. 2). The quarry locations are approximate. The sampling strategy was to collect closely spaced samples of the immature Domanik Formation. Sampling intervals in the field {fig. 3) were determined by changes in lithology, color, texture, and carbonate content as measured by reaction with hydrochloric acid. Our assumption was that changes in the depositional/diagenetic environment are reflected in the variability of these gross field characteristics.
A total of 138 samples were collected {107 in 1995 and 31 in 1994) from more than 60 meters of vertical stratigraphic thickness and tied to paleontological marker beds identified by Yudina and Moskalenko (VNIGRI, unpublished data). In addition, 13 high-resolution samples were taken in organic- matter rich intervals with a drill for Rock Eval in order to determine the scale of variability in organic matter. The stratigraphic position of the samples are given in the All source-rock samples were analyzed for total sulfur {elemental analyzer technique); total and aqua-regia extracted major-, minor-, and trace-element compositions {induction coupled plasma spectrophotometry); and organic pyrolysis characteristics (Rock-eval). The 13 drill samples were analyzed by Rock-Eval pyrolysis only. A suite of 40 samples were analyzed for whole-rock mineralogy (X-ray diffractometry) and for bulk and molecular organic composition.
The soluble organic matter was extracted by soxhlet using chloroform as a solvent. The extract was fractionated into saturated hydrocarbons, aromatic hydrocarbons, NSO compounds and asphaltenes by first precipitating asphaltenes in iso- octane followed by elution chromatography using constructed alumina/silica columns. The CR+ saturated and aromatico
hydrocarbon fractions were analyzed with a gas chromatograph (GC) equipped with a DB-1 60m x 0.32mm column and a flame ionization detector. Biomarker distributions were determined by analyzing combined saturated and aromatic hydrocarbon fractions by gas chromatography-mass spectrometry. The GC equipped with a DB-1701 60 m x 0.32 mm column was directly interfaced to a magnetic sector mass spectrometer operating in multiple ion detection mode at a mass resolution of 3000. The selected ions were m/z 191.1800 (terpanes), m/z 217.1956 (steranes), m/z 231.1174 (triaromatic steroids) and m/z 253.1956 (monoaromatic steroids). Peak identifications were based on elution time and mass spectra (Philp, 1985). Kerogen (insoluble organic matter) was isolated by digestion in HC1
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and HF followed by separation with ZnBr2 . Stable carbon isotope ratios were determined for the C15+ saturated and aromatic hydrocarbon fractions and the kerogen fraction by analyzing the C02 from sealed quartz tube combustion with a dual inlet isotope ratio mass spectrometer. The results areexpressed in the delta (8) notation that represents the deviation of the 13C/ 12C ratio in parts per thousand (per mil, or &) relative to the Peedee belemnite (PDB) standard. Isolated kerogen was analyzed for hydrogen, carbon, oxygen, and nitrogen by combustion on a CHNO elemental analyzer. Nickel and vanadyl porphyrins in the extracted bitumen were measured with a ultraviolet/visible diode array spectrophotometer. Analytical results are tabulated in the Appendix.
The suite of 40 samples plus 34 others were analyzed for sulfur phases (wet-chemical separation and gravimetric determination; Tuttle and others, 1986) and for sulfur isotopic composition of each phase (Tuttle, 1988). Theisotope results are expressed in the delta (8) notation that represents the deviation of the 34S/ 32 S ratio in parts per thousand (per mil, or &>) relative to the Canon Diablo Troilite (CTD) standard. Analytical results are tabulated in the Appendix. Thin sections were prepared from 19 representative samples and examined by transmitted- and reflective-light microscopy.
Included in Appendix tables Al and A2 are estimates of various mineral phases calculated from chemical data. The amount of calcite (the only carbonate phase identified with X-ray diffraction) was calculated with the formula below:
calcite % = (Ca% .(AR) * 1.25) + (Mg% (AR) * 3.5).
We assume that all calcium and magnesium extracted in the aqua-regia treatment resided in this carbonate phase. Clay content was calculated assuming all aluminum resides in illitic or kaolinitic clays (assumptions are substantiated with X-ray diffraction data and transmitted-light microscopy):
clay % = total Al% * 4.8.
Silica (Si02 as quartz) was calculated from the following equation:
Si02 % = 100 - ((organic C % * 1.25) + clay % + calcite %)),
where (organic C % * 1.25) is organic carbon content converted to percent organic matter. The calculated Si02 values correlate very well with quartz peak heights from the X-ray diffractograms.
The Geochemistry of Domanik Source Rocks
Lithology and Mineralogy
The Domanik source rocks contain predominantly quartz, calcite, and varying amounts of organic matter and clay (fig 4). With the exception of two samples, clay contents are anomalously low, almost always less than 10 wt% even in most fissile shaly samples (figs. 4 and 5). Conversely, calculated Si02 contents are high, nearly 100 wt% in end- member samples (right side of fig. 4A). The dominant Si02 phase is by far quartz (fig. 5). Detrital quartz is ruled out as the dominant source because other detrital minerals associated with clastic sediment are very minor, and no evidence of eolian sand grains was observed in thin sections. The origin of most the quartz must be biogenic opal that recrystalized to fine-grained quartz with increasing temperature. Thin sections do show silicified remains of organisms in samples containing large Si02 contents. The other end member on figure 4A is also a biogenic component-- calcite that forms limestone--defined here as sample having greater than 50 wt% calcite (Bates and Jackson, 1980) . The limestone is composed of variable amounts of calcite and silica (<40%) with very small amounts of clay or organic carbon.
Organic Geochemistry
The amount of organic carbon in the rock is controlled by dilution with minerals, primarily biogenic Si02 , and, secondarily, calcite and clay in the sample (fig. 4), The highest organic contents are in fissile shale. Despite the wide variability in lithology and organic-carbon content, the gross organic facies type is remarkably uniform as indicated by the narrow range in H/C composition (1.10-1.24). For., example, the lowest portion of the Domanik has an organic- carbon range of 0.8 to over 25 weight percent while the H/C ranges only from 1.13 to 1.21 (fig. 6). This would classify the organic matter as Type II kerogen as defined by Tissot and others (1974). Furthermore, there is a good correlation (r = .98) between the pyrolysis S2 values (generated hydrocarbons/gm organic carbon) and organic-carbon values (fig. 7). The "true" average Hydrogen Index (HI) is the slope of the regression line for this correlation (Langford and Blanc-Valleron, 1990), which is equal to 553 mg HC/g organic carbon. Because of the similarity in the type of organic matter within the section, the amount of oil that can be generated from the rock (generative potential) is only dependent on the amount of organic carbon in the rock (fig. 7). All but the limestones have very good generative potential (Peters, 1986). The HI versus Oxygen Index (01) plot (fig. 8) relate sample data to Types I, II and III kerogen maturation curves (Espitalie and others, 1977).
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11
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12
Samples with 01 values greater than 60 on the average have the same carbonate content as those with values less than 60.
The extractable organic matter/organic carbon (EOM/organic carbon) ratios are variable depending on the lithology and are, on average 22% (table A5; fig. 9), unusually high for immature source rocks. Domanik Rock-Eval Tm3Y values are
IllcLX
generally less than 430°C while the beginning of the typical oil window is approximately 435°C and peak oil generation is approximately 445°C (Peters, 1986). In immature source rocks, EOM/organic-carbon ratios greater than 20% are often attributed to non-indigenous hydrocarbons that have migrated from mature sources elsewhere (Hunt, 1979, p. 267; Tissot and Welte, 1984, p 514). However, there are many examples of immature clay-poor source rocks such as the Austin Chalk, and rocks in the Los Angeles and Ventura Basins that have high amounts of indigenous bitumen and EOM/organic-carbon values exceeding 20% (Hunt and McNichol, 1984; Leigh Price, written commun., 1999). Because the Domanik is clay-poor and because the average S^organic-carbon ratio (0.7) is significantly less than 1.5 (Hunt, 1996, p. 491), the extractable organic matter is interpreted as being indigenous. The high EOM/organic carbon ratios are due to either early bitumen/oil generation from thermal maturation or reduced polymerization of organic matter due to extremely reducing conditions during diagenesis (Powell, 1984).
The 813C kerogen values show a negative shift in the first few meters above the base of the Domanik, and a large positive excursion at 50.25 meters above the base of the Domanik (sample 96018-089) which is in the Middle to Upper Domanik (fig. 10). The isotopic shift observed at about 20 meters above the base of the formation may be caused by differences in outcrop locality. The lower ten samples show an approximately one per mil variation in the 813C aromatic hydrocarbon values which correspond with the total organic carbon content and lithologic variations observed in the field (figs. 3, 6, 10). However, the 813C kerogen values show minimal variation in this same interval. The 813C saturated hydrocarbon values are relatively uniform throughout the Domanik (fig. 10).
Vanadium- and nickel-pophyrin concentrations in the bitumen are high relative to those in bitumen from other source rocks (Lewan and Maynard, 1982); values range from 67 to 6633 ppm V porphrin and 15 to 1814 ppm Ni porphyrin (fig. 11).
The overall biomarker compositions of the bitumen extracts are quite consistent throughout the Domanik Formation with some minor variations of the tricyclic, pentacyclic terpanes. The lowest sample (96018-001) and the highest sample (96018- 094) are nearly identical in biomarker composition (table A7)
13
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Figure 9. Crossplot of extractabable organic matter versus total organic matter. Organic matter was calculated using 1.326 times the organic carbon value. This conversion factor was derived from atomic composition of the organic matter and was constant throughout the data set.
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Figure 10. Stable carbon isotope values of the kerogen fraction and the saturated and aromatic hydrocarbon fractions of the Domanik Formation.
15
A.
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V porphyrin in bitumen (ppm)
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16
despite the three per mil difference in the 513C kerogen values.
In general, the Domanik tricyclic/pentacyclic terpane mass chromatograms (m/z 191) look quite typical with dominant C30 hopane and secondary norhopane, and decreasing concentrations of the C31 to C34 homohopanoids with a slightly elevated C35 . The Ts/Tm values range from about 0.4 to 0.6, the C23 tricyclic terpane/hopane values range from about 0.2 to 0.4, and the C24 tetracyclic terpane is approximately the same concentration as the C26 tricyclic terpane isomers. Gammacerane/hopane values are normal (0.05 to 0.15) except for samples 96018-036, 96018-037 and 96018-093 which have elevated values (>0.3).
In general, the Domanik sterane mass chromatograms (m/z 217) show low concentrations of diasteranes and pregnanes, and the C29 steranes are slightly greater than C27 steranes noticeably larger than C28 steranes. Small C30 and C26 steranes are recognized but are minor.
The dramatic sawtooth pattern observed in the TOC and 813C aromatic hydrocarbon data for the Lower Domanik is not reflected significantly in the biomarkers. An exception is seen in the relative percentage of C27 steranes and tricyclic terpanes, and to a lesser degree the biomarker maturity parameters such as C31 S/S+R (see example in fig. 12).
The Domanik Formation is slightly more thermally mature to the east (Outcrop 21) than to the west (Outcrop 7 or 28) based on a number of biomarker maturity parameters, includingS/S+R C29 steranes (C29SR) , PP/PP+CXCX C29 steranes (C29BBAA) , triaromatic cracking (TRIOCR), Ts/Tm, moretane/hopane (MOR/HOP), and the C29 neonorhopane/norhopane (NEO/NOR) ratios. For example, the S/S+R C29 sterane (C29SR) values of the western outcrop average 0.32 whereas the eastern outcrop values average 0.38. However, the difference in thermal maturity between west and east is not apparent based on Rock- Eval Tmax, S/S+R C31 hopanes (C31HSR) or triaromatic/monoaromatic sterane (T/T+M) values.
Trace Metal Geochemistry
Most metal contents in the Domanik Formation are positively correlated with organic-matter contents. The total concentration of metals such as Ni, Cu, Zn, Mo are essentially the same as respective concentrations in the aqua-regia extractions (1:1 correlation with r values of .95 to .99; fig. 13). The extractable metals are primarily associated with organic carbon and perhaps, secondarily, with oxy-hydroxides, both of which are decomposed by aqua-regia. Total vanadium concentrations are twice that measured from
17
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Figure 13. Crossplots of metal concentrations in aqua-regia extracts (AR) versus bulk rock (Tot).
19
the aqua-regia extraction, but the two concentrations are highly correlated (r value of 0.93). Total chromium is, on the average, five times greater than aqua-regia extractable chromium, with the two values not correlated. Half the vanadium and the majority of chromium are associated with resistate minerals that are not solubilized by aqua-regia. In the case of vanadium, the mineral is associated with the organic matter to preserve the high correlation between the total and extractable concentration; clay is the most probable mineral.
Metal enrichment is dependent on redox conditions during deposition and on metal source. If the metal source is sea water, then metal accumulation also is controlled by the amount of time that the sediment remains "open" to metal- bearing waters. The degree of "openness" is sensitive to such factors as watercolumn turnover rates, sediment accumulation rates, and porosity of the sediment (Lewan and Maynard, 1982). To separate the influence of redox conditions from metal supply, metal ratios, such as V:(V+Ni) ratio, are often used because different metals preferentally accumulate under different redox conditions (Lewan, 1984).
The V:(V+Ni) ratios in the Domanik (average of .82) are consistent with an anoxic to euxinic (H2S-bearing) bottom waters (Hatch and Leventhal, 1992). Metal contents, although high relative to average shale abundance, are less than those in some marine shales deposited under similar euxinic conditions (i.e. similar V:(V+Ni) ratios) (table 1). The lower metal contents suggest that the sediment accumulation rates were greater than in the "metalliferous" shale, isolating the sediment more quickly from the overlying water column, thus inhibiting accumulation of metals over time. Additionally, fissile shale has metal contents that, on the average, are much lower than expected from their organic- carbon content (fig. 14). Accumulation of the fissile shale was more rapid than accumulation of the massive shale. In support of this hypothesis, the fissile nature of the shale cannot be attributed to high clay contents, and may have resulted from rapid accumulation of layers of organic matter. Such layers form in mineral-poor turbidite sequences (see Dean and others, 1984 for discussion on the role of turbidites in formation of Cretaceous black shale in the Atlantic).
Unlike most metal contents, that of iron is not related to organic-carbon, and is low with an average of 0.46 wt % compared to 4.7 wt % in the average shale (Krauskopf, 1979). The low contents are due to low content of detrital minerals in the shales. On the average, 25 % of the iron in the sediment resides as pyrite.
20
Tabl
e 1.
S
elec
ted
trac
e el
emen
t co
ncen
trat
ions
and
V:(
V+N
i) ra
tios
in a
var
iety
of s
hale
s an
d se
dim
ents
.
Shale
/Sedim
ent
Cr
ppm
C
u pp
m
Mo
ppm
N
i ppm
V
ppm
Zn
ppm
V
/(V
+N)
Ref
eren
ces
Ave
rage
sha
le
Mod
ern
Oxi
dize
d P
elag
ic c
lay
100
90
50
25
0
2 27
140
22
5
13
0
120
80
165
0.4
8*
0.3
5*
tabu
late
d in
'79
Che
ster
and
Kra
usko
pf
Ast
on'7
6 as
cite
d in
Dea
n '8
4M
oder
n B
altic
Sea
Sed
imen
t/ano
xic
Mod
ern
Bla
ck S
ea S
edim
ent/e
uxin
ic
Cre
tace
ous
Bla
ck S
hale
-Ang
ola
Bas
in
Dev
onia
n D
oman
ik F
issi
le S
hale
Dev
onia
n D
oman
ik M
assi
ve S
hale
Pen
nsyl
vani
an S
tark
Sha
le-e
uxin
ic
Pen
nsyl
vani
an S
tark
Sha
le-a
noxi
c
Pen
nsyl
vani
an S
tark
Sha
le-
90
14
3
22
2
34
23
51
0
465
48
0
78
38
170
61 30
125
70
90
35
13
26
33
18
510
21
0
315
43
82
181
100
60
43
5
27
5
33
0
13
0
225
69
2
47
0
375
25
20
11
50
16
30
110
98
78
2
{;i:'6
5;/
' 1;6
oir
'"
27
30
12
90
1800
0.7
5*
0.7
3*
0.7
8*
0.7
8
0.8
3
0.8
5
0.7
2
0.7
7
Man
heim
'61
Dea
n '8
4H
irst
'74
as'8
4
Dea
n '8
4
Thi
s S
tudy
Thi
s S
tudy
Hat
ch '
92
Hat
ch '
92
Hat
ch '
92
as c
ited
in
cite
d in
Dea
n
euxi
nic/
anox
ic
"Cal
cula
ted
usin
g av
erag
e V
and
Ni
conc
entr
atio
ns
V/V+Ni>.82 V = 30 + 88 OC
= .86
10 15 20 Organic Carbon %
- V/V+Ni >.82 . Nl = 7.5 + 11 OC
r = .88 clay, ratio >.82o clay, ratio <.82
fissile shale, ratio >.82 fissile shale, ratio <.82 limestone, ratio >.82 limestone, ratio <.82 massive shale, ratio >.82 massive shale, ratio <.82
0 10 15 20 Organic Carbon %
clay, V/V+Ni ratio >.82o clay, V/V+Ni ratio <.82x fissile shale, V/V+Ni ratio >.82+ fissile shale, V/V+Ni ratio <.82 limestone, V/V+Ni ratio >.82n limestone, V/V+Ni ratio <.82 massive shale, V/V+Ni ratio >.82O massive shale, V/V+Ni ratio <.82
Correlation Coefficient for samples with V/V+Ni >.82
MoCuZnCrP
r = .69 r = .88
r = .72 r = .77 r = .81
Figure 14. Crossplots of total vanadium and total nickel (both in ppm versus organic carbon (wt%), with correlation coefficients for other metals.
22
Sulfur Geochemistry
Pyrite formation undoubtedly was limited by the amount of reactive iron available during production of H2 S by sulfate- reducing bacteria in the sediment. Pyritic sulfur in the Domanik source rock is enriched in 34S (534S values between 2. 6%0 and 21.0fe) when compared to most marine shales (534S commonly near -20&>) . A similar enrichment is reported for pyrite in Monterey Formation source rock (534S values between-18& and 11.9fe; Zaback and Pratt, 1992). Isotopic compositions of organosulfur in both formations are similarly enriched (l.Sfe to 21.7fe in the Monterey; Zaback and Pratt, 1992, and 8.9 to 22.5&> in the Domanik; this study). Zaback and Pratt (1992) attribute the 34S-enrichment in organosulfur relative to pyrite in the Monterey to (1) formation of pyrite at the sediment/water interface under mildly reducing conditions and (2) formation of organosulfur deeper in the sediment when strongly reducing conditions were established. The more 34S-enriched isotopic values in the Domanik pyrite suggest near complete reduction of sulfate by bacteria- and pyrite formation in the same zone as organosulfur. As discussed earlier, high V:(V+Ni) and EOM:organic carbon ratios in the Domanik are consistent with highly reducing, likely euxinic bottom waters. In modern euxinic oceans/seas,the 834S value of the H2S in bottomwater layers is far more depleted in 34S than sulfur in Domanik pyrite (534S. values average +12fe) . For example, 534S values of H2 S in the bottom water of the Black Sea are -36fc to -41fe (Fry and others 1991) and in Framvaren Fjord, Norway, values are between -22fe and-life (Saelen and others, 1993). If the Domanik was deposited in euxinic water, then one of two scenarios is required. First, the bottomwater layer had to be extremely stable with respect to mixing and most of the sulfate bacteriogenically reduced, increasing the 834S of the H2S. Alternatively, the bottom water could have been euxinic and rapid accumulation rates resulted in isolating pore water where additional bacterial activity reduced most of the remaining sulfate. This latter scenario explains, in part, the 34S-enrichment in pyrite in relatively shallow sediment of the Black Sea (albiet the enrichment is smaller than in the Domanik). Either scenario supports the lower metal contents observed in the Domanik shales relative to sediment deposited in an euxinic, but less restricted water or sediment column.
Because the amount of iron available for pyrite formation was low, excess H2 S reacted with organic matter. The Sorganic /Corganic ratios average 0.03 compared to ratios of 0.01 in living organisms. Twenty percent of the values are greater than 0.04, a value above which source rocks generate sulfur-rich oils at lower temperatures than estimated for most source rocks (Orr, 1986) .
23
Paleoenvironmental Conditions during Deposition of the Domanik Formation
The Domanik Formation was deposited in an euxinic marine basin during the highest sea level rise of the Late Devonian Epoch. Water depths were sufficiently deep to preserve laminated sediments and isolate euxinic bottomwater layers from frequent mixing. This deepwater-restricted deposition was periodically interrupted. The deepwater shales are massive to fissile silicieous pelagic rocks composed of biogenic silica, with varying amounts of clay and calcite. The extremely low clay content and the lack of other clastic minerals in these shales indicate a long distance to the nearest strandline, or a basin isolated by landward banktops/sills and adjacent proximal basins.
The organic matter deposited is remarkably uniform with respect to gross composition. Organic-matter concentration in the sediment was controlled primarily by dilution of biogenic silica produced in the overlying water column, which in turn was controlled by upwelling. The variation of organic carbon in figure 15 is suggestive of cycles within variable depth intervals that are more or less complete depending on sample density. The 0.5-m cycle (.12 to .57 m above base) illustrates two orders of cycles. The large cycle (0.5 m) is comprised of at least 4 smaller cycles and is bounded by two limestone beds (fig. 3), the lowermost being the basal Domanik limestone at 0 m. Limestone throughout the section generally has much lower organic carbon contents than adjacent shale (0.77 wt % organic carbon in the upper limestone bed of this cycle). Deposition of limestone likely records times when water circulation was less restricted and reducing conditions less extreme.
The smaller cycles between the limestone beds occur on the order of 20 to 40 cm and are related to dilution of organic carbon (and most other constituents as well) by Si02 . These cycles likely are controlled by processes related to the silica budget (Broecker and Peng, 1982).
References
Bates, R.L. and Jackson, J.A., eds., 1980, Glossary of Geology, Second Edition. Falls Church, American Geological Institute, p. 360.
Bray, E.E., and Evans, E.D., 1961, Distribution ofn-paraffins as a clue to recognition of source beds: Geochimica et Cosmochimica Acta, 22, p. 2-15.
Brocker, W.S., and Peng, T.,1982, Tracers in the Sea. Palisades, Columbia University, 690 p.
24
5 10 15 20 25 30
Organic carbon (wt%)
Organic carbon (wt%)
Figure 15. Depth profile of organic carbon (wt. %) for entire Domanik section sampled and 0.6 meter cycle within the Lower Domanik Formation.
25
Chester, R., and Aston, S.R., 1976, Geochemistry of deep-sea sediments, in, Riley, J.P., and Chester, R. (eds.)/ Chemical Oceanography, Volume 6. New York, Academic Press, p. 281-390.
Dean, W.E., Arthur, M.A., Stow, D.A.V., 1984, Origin and geochemistry of Cretaceous deep-sea black shales and multicolored claystones, with emphasis on Deep Sea Drilling Project Site 530, in, Hay, W.W., Sibuet J.C., et al., Initial Reports of the Deep Sea Drilling Project, Volume LXXV. Washington, U.S. Government Printing Office, p. 819-843.
Espitalie, J., Madec, M., Tissot, B., Mennig, J.J., andLeplat, P., 1977, Source rock characterization method for petroleum exploration: Proceedings of the 9 th . Annual Offshore Technology Conference, 3, p. 439-448.
Fry, B., Jannasch, H.W., Moyneaux, S.J., Wirsen, C.O., Muramoto, J.A., and King, S., 1991, Stable isotope studies of the carbon, nitrogen, and sulfur cycles in the Black Sea and the Cariaco Trench: Deep-Sea Research, 38, p. 1003-1019.
Hatch, J.R., and Leventhal, J.S., 1992, Relationship between inferred redox potential of the depositional environment and geochemistry of the Upper Pennsylvanian (Missourian) Stark Shale Member of the Dennis Limestone, Wabaunsee County, Kansas, U.S.A.: Chemical Geology,, 99, p. 65- 82.
Hirst, D.M., 1974, Geochemistry of sediment from eleven Black Sea cores, in Degens, E.T. , and Ross, D.A. , (eds'.), The Black Sea--Geology, Chemistry and Biology: American Association- of Petroleum Geologist Memoir 20, p. 430- 455.
Hunt, J.M., 1979, Petroleum Geology and Geochemistry. San Francisco, Freeman and Company, 617 p.
Hunt, J.M., 1996, Petroleum Geology and Geochemistry, Second Edition. San Francisco, Freeman and Company, 743 p.
Hunt, J.M., and McNichol, A.P., 1984, The Cretaceous Austin Chalk of South Texas a petroleum source rock, in, Palacas, J.G., ed., Petroleum Geochemistry and Source Rock Potential of Carbonate Rocks: American Association of Petroleum Geologist's Studies in Geology #18: Tulsa, American Association of Petroleum Geologist's, p. 117- 125.
Krauskopf, K.B., 1979, Introduction to Geochemistry. New York, McGraw-Hill Book Company, 617 p.
Langford, F.F., and Blanc-Valleron, M.M., 1990, Interpreting Rock-Eval pyrolysis data using graphs of pyrolyzable hydrocarbons vs. total organic carbon: American Association of Petroleum Geologist's Bulletin, 74, p. 799-804.
Lewan, M.D., 1984, Factors controlling the proportionality of vanadium to nickel in crude oils: Geochimica et Cosmochimica Acta, 48, p. 2231-2238.
26
Lewan, M.D. and Maynard, J.B., 1982, Factors controlling enrichment of vanadium and nickel in the bitumen of organic sedimentary rocks: Geochimica et Cosmochimica Acta, 46, p. 2547-2560.
Manheim, F.T., 1961. A geochemical profile in the Baltic Sea: Geochimica et Cosmochimica Act, 25, p. 52-71.
Marzi, R., Torkelson, B.E., and Olson, R.K., 1993, A revised carbon preference index: Organic Geochemistry, 20, p. 1303-1306.
Orr, W.L., 1986, Kerogen/asphaltene/sulfur relationships in sulfur-rich Monterey oils: Organic Geochemistry, 10, p 499-516.
Peters, K.E., 1986, Guidelines for evaluating petroleum source rock using programmed pyrolysis: American Association of Petroleum Geologist's Bulletin, 70, p. 318-329.
Peters, K.E., and Moldowan, J.M., 1993, The BiomarkerGuide Interpreting Molecular Fossils in Petroleum and Ancient Sediments. New York, Prentice Hall, 363 p.
Philippi, G.T., 1965, On the depth, time and mechanism ofpetroleum generation: Geochimica et Cosmochimica Acta, 29, p. 1021-1049.
Philp, R.P., 1985, Fossil Fuel Biomarkers Applications -and- Spectra. Amsterdam, Elsevier, 294 p.
Powell, T.G., 1984, Some aspects of the hydrocarbongeochemistry of a Middle Devonian barrier-reef complex, Western Canada, in, Palacas, J.G., ed., Petroleum Geochemistry and Source Rock Potential of Carbonate Rocks: American Association of Petroleum Geologist's Studies in Geology #18. Tulsa, American Association of Petroleum Geologist's, p. 45-61.
Saelen, G. , Raiswell, R. , Talbot, M.R., Skei, N.M. , Bottrell S.H., 1993, Heavy sedimentary sulfur isotopes as indicators of super-anoxic bottom-water conditions: Geology, 21, p. 1091-1094.
Scalan, R.S., and Smith, J.E., 1970, An improved measure of the odd-even predominance in the normal alkanes of sediment extracts and petroleum: Geochimica et Cosmochimica Acta, 34, p. 611-619.
Tissot, B.P., Durand, B., Espitalie, J., and Combax, A., 1974, Influence of nature and diageneisis of organic matter in formation of petroleum: American Association of Petroleum Geologist's Bulletin, 58, p. 499-506.
Tissot, B.P., and Welte, D.H., 1984, Petroleum Formation and Occurrence. Berlin, Springer-Verlag, 699 p.
Tuttle, M.L., 1988, Geochemical evolution and depositionalHistory of Sediment in Modern and Ancient Saline Lakes: evidence from sulfur geochemistry. Unpublished Ph.D. dissertation, Colorado School of Mines, 312 p.
Tuttle, M.L., Goldhaber, M.B., Williamson, D.L., 1986, An analytical scheme for determining forms of sulphur in oil shales and associated rocks: Talanta, 33, p. 953- 961.
27
Ulmishek, G., 1982, Petroleum geology and resource assessment of the Timan-Pechora Basin, USSR, and the adjacent Barents-Northern Kara Shelf: Argonne National Laboratory Report ANL/EES-TM-199, 197 p.
Ulmishek, G.F., 1988, Upper Devonian-Tournaisian facies and oil resources of the Russian craton's eastern margin, in, McMillan, N.N., Embry, A.F., Glass, D.J., eds., Devonian of the World, Volume I: Regional Syntheses. Calgary, Canadian Society of Petroleum Geologists, p. 527-549.
Zaback, D.A., and Pratt, L.M., 1992, Isotopic composition and speciation of sulfur in the Miocene Monterey Formation: Reevaluaation of sulfur reactions during early diagenesis in marine environments: Geochimica Cosmochimica Acta, 56, pp. 763-774.
28
Tabl
e A
1.
Dat
a on
out
crop
sam
ples
col
lect
ed 1
994,
inc
ludi
ng R
ock
Eva
l da
ta,
inor
gani
c ch
emis
try,
and
sul
fur
spec
iatio
n an
d th
eir
isot
opic
com
posi
tion.
A
r, a
naly
sis
done
on
aqua
reg
ia e
xtra
ct;
tot,
anal
ysis
don
e on
who
le r
ock;
%,
wei
ght
basi
s; c
alc,
cal
cula
ted.
S
ulfu
r is
otop
es r
epor
ted
rela
tive
to C
anon
Dia
blo
Troi
lite
stan
dard
.
Sam
ple
id
Fiel
d N
o.
m a
bove
bas
eLo
calit
yA
geLi
thol
ogy
Col
or
TMA
X°C
S1
mg/
gm
S2
mg/
gm94
087-
001
9408
7-00
2 94
087-
003
9408
7-00
4 94
087-
005
9408
7-00
6 94087-0
07
9408
7-00
8 94
087-
009
9408
7-01
094
087-
01 1
9408
7-01
294
087-
013
9408
7-01
494
087-
015
94087-0
16
94087-0
17
9408
7-01
894
087-
019
94087-0
20
9408
7-02
194
087-
022
9408
7-02
394
087-
024
9408
7-02
594
087-
026
94087-0
27
94087-0
28
9408
7-02
994
087-
030
9408
7-03
1
TP
-01
TP
-02
T
P-0
4
TP
-05
TP
-06
TP
-07
T
P-0
8 T
P-9
A g
ray
TP
-9A
bro
wn
TP
-09
TP
-10
TP
-11
TP
-12
TP
-13
TP
-14
TP
-15
TP
- 17
brow
nT
P-1
7gra
yT
P-1
8T
P-1
9T
P-2
0T
P-2
1T
P-2
2T
P-2
3T
P-2
4 br
own
TP
-24
gra
yT
P-2
5T
P-2
6T
P-2
7T
P-2
8 bl
ack
TP
-28
gra
y
24.2
0
23.8
0
23.2
0
22.8
0
21.4
0
21.1
0
20.6
0
20.2
0
20.1
020
.15
5.94
5.11
4.61
3.9
03.3
02
.60
11.3
311
.38
12.5
49.
8540.6
043.1
044.1
045.8
046.1
446
.09
47.1
948
.19
52.3
953
.54
53.5
9
Old
Moto
r R
oad
Q.
M.
Old
Moto
r R
oad
Q.
M.
Old
Moto
r R
oad
Q.
M.
Old
Moto
r R
oad
Q.
M.
Old
Moto
r R
oad
Q.
M.
Old
Moto
r R
oad
Q.
M.
Old
Moto
r R
oad
Q.
M.
Old
Moto
r R
oad
Q.
M.
Old
Moto
r R
oad
Q.
.. M
.O
ld M
oto
r R
oad
Q.
M.
Outc
rop 7
Out
crop
7O
utcr
op 7
Out
crop
7O
utcr
op 7
Out
crop
7O
utcr
op 7
Out
crop
7O
utcr
op 7
Out
crop
7O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1B
lack
Dog
Bla
ck D
ogB
lack
Dog
Bla
ck D
ogB
lack
Dog
Bla
ck D
ogB
lack
Dog
Q.
Q.
Q.
Q.
Q.
Q.
Q.
L. L. L. L. L. L. L. L. L. L. M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
Dom
anik
D
oman
ik
Dom
anik
D
oman
ik
Dom
anik
D
oman
ik
Dom
anik
D
oman
ik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
- U
. D
oman
ik-
U.
Dom
anik
- U
. D
oman
ik-
U.
Dom
anik
- U
. D
oman
ik-
U.
Dom
anik
- U
. D
oman
ik-
U.
Dom
anik
- U
. D
oman
ik-
U.
Dom
anik
- U
. D
oman
ik
mas
sive
sha
le
mas
sive
sha
le
mas
sive
sha
le
mas
sive
sha
le
fissi
le s
hale
fis
sile
sha
le
mas
sive
sha
le
mas
sive
sha
le
mas
sive
sha
lem
assi
ve s
hale
fissi
le s
hale
mas
sive
sha
lem
assi
ve s
hale
mas
sive
sha
lelim
esto
nem
assi
ve s
hale
mas
sive
sha
lem
assi
ve s
hale
mas
sive
sha
lem
assi
ve s
hale
mas
sive
sha
lem
assi
ve s
hale
mas
sive
sha
lefis
sile
sha
lem
assi
ve s
hale
mas
sive
sha
lefis
sile
sha
lefis
sile
sha
lefis
sile
sha
lem
assi
ve s
hale
mas
sive
sha
le
brow
n br
own
brow
n br
own
gray
br
own
brow
n gr
ay
brow
nbr
own
brow
nbr
own
brow
ngr
aybr
own
brow
nbr
own
gray
brow
nbr
own
gray
brow
nbr
own
brow
nbr
own
gray
brow
nbr
own
brow
nbr
own
gray
423
423
428
422
428
426
428
425
424
428
434
428
424
429
428
431
427
429
428
423
426
431
425
416
424
426
421
418
422
427
431
1.8
3.3
1.5
2.7
2.6
2.3
0.57
1.
3 2.
50.
890
0.76
0.5
30.
530.
780.3
71.
21.
10.
53 4.5
0.77
0.4
60.8
3 11 2.6
1.6
3.5 13 1.5
1.2
0.85
32
35
22
39
48
39
9.1 15
34 12 14 9.5 6 8 8
4.5 25 14 14 56 14 8.5
9.0
141 31 16 40 159 40 16 9.6
A1-1
Tabl
e A
1.
Con
tinue
d.
Sam
ple
id
TOC
%H
IO
l To
t S
%
Na
% (
AR
) To
t N
a %
M
g %
(A
R)
Tot
Mg
%
Al %
(A
R)
Tot A
l%
P%
(A
R)
Tot
P %
94087-001
94087-002
9408
7-00
394
087-
004
9408
7-00
594
087-
006
9408
7-00
794
087-
008
9408
7-00
994087-010
9408
7-01
194087-012
9408
7-01
394087-014
94087-015
9408
7-01
694087-017
9408
7-01
894087-019
94087-020
9408
7-02
194087-022
94087-023
9408
7-02
494087-025
94087-026
9408
7-02
794087-028
9408
7-02
994
087-
030
9408
7-03
1
6.5
5.9
4.0
6.2
9.3
7.4
1.4
1.9
5.3
2.3
4.2
1.7
0.79 1.3
1.6
0.93 4.2
2.3
2.6
9.3
2.4
1.3
2.1 22 4.6
2.2
5.7
24 6.8
3.2
2.5
484
595
553
631
524
526
661
634
650
664
340
552
797
577
499
486
581
598
548
596
565
635
439
639
678
727
698
656
592
493
384
96 102
102 73 64 68 114
132 89 107
108
141 96 139
158
148
116
103
157 43 100
121 78 38 67 95 50 17 25 90 109
0.32
0.41
0.25
0.36
0.70
0.55
0.21
0.40
0.30
0.26
0.21
0.26
0.22
0.23
0.32
0.16
0.27
0.19
0.20 1.1
0.28
0.36
0.33
0.90
0.26
0.39
0.41 1.4
1.6
0.21
0.20
0.02
0.03
0.03
0.02
0.02
0.02
0.02
0.02 nd
0.02
0.03
0.02
0.03
0.02
0.02
0.03
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.03
0.02 nd
0.03 nd
0.02
0.02
0.02
0.06 nd
0.06
0.07
0.06
0.05
0.07
0.07
0.05
0.06
0.06
0.07
0.08
0.07
0.04
0.07
0.07
0.07
0.09
0.05
0.06
0.06
0.06
0.05
0.06
0.06
0.07
0.04
0.08
0.06
0.06
0.09
0.11
0.16
0.08
0.07
0.15
0.01
0.39 nd
0.02
0.19
0.04
0.02
0.01
0.25
<0.0
10.
100.
060.14
0.29
0.01
0.01
0.01
0.67
0.11 nd
0.10 nd
0.13
0.02
0.03
0.14 nd
0.26
0.18
0.26
0.31
0.02
0.31
0.40
0.04
0.39
0.07
0.03
0.03
0.30
0.01
0.16
0.08
0.21
.0.
220.
050.04
0.04
0.81
0.28
0.35
0.18
0.93
0.61
0.04
0.05
0.07
0.11
0.07
0.08
0.14
0.13
0.02
0.04 nd
0.03
0.18
0.06
0.02
0.02
0.06
0.02
0.07
0.04
0.09
0.11
0.05
0.03
0.04
0.11
0.10 nd
0.13 nd
0.28
0.04
0.05
0.79 nd
0.86 1.0
1.5
1.5
0.28
0.81
0.46
0.29 1.6
0.49
0.27
0.32
0.40
0.24
0.74
0.45
0.98 1.2
0.49
0.35
0.40 1.1
0.98
0.63 1.0
0.83 4.7
0.37
0.39
0.06
0.06
0.07
0.06
0.09
0.09
0.02
0.03 nd
0.03
0.08
0.03
0.03
0.02
0.05
0.02
0.05
0.03
0.06
0.11
0.04
0.02
0.03
0.10
0.05 nd
0.06 nd
0.05
0.02
0.02
0.07 nd
0.07
0.07
0.09
0.09
0.03
0.07
0.03
0.03
0.08
0.04
0.03
0.02
0.05
0.02
0.05
0.04
0.06
0.11
0.05
0.02
0.03
0.10
0.06
0.04
0.06
0.10
0.06
0.02
0.03
A1-2
Tabl
e A
1.
Con
tinue
d.
Sam
ple
id
K%
(A
R)
Tot
K %
C
a %
(A
R)
Tot
Ca
%
Sc
ppm
(A
R)
Tot
Sc
ppm
To
t Ti
%
V p
pm (
AR
) To
t V
ppm
C
r pp
m (
AR
)94
087-
001
9408
7-00
294
087-
003
94087-004
9408
7-00
594
087-
006
9408
7-00
794087-008
9408
7-00
994087-010
9408
7-01
194087-012
9408
7-01
394087-014
94087-015
94087-016
9408
7-01
794
087-
018
9408
7-01
994
087-
020
94087-
021
9408
7-02
294
087-
023
94087-024
94087-025
9408
7-02
694
087-
027
94087-028
9408
7-02
994087-030
94087-
031
0.06
0.08
0.05
0.06
0.11
0.09
0.01
0.03 nd
0.02
0.12
0.04
0.01
0.01
0.04
0.01
0.05
0.03
0.05
0.07
0.04
0.02
0.03
0.09
0.07 nd
0.09 nd
0.17
0.03
0.03
0.24 nd
0.38
0.39
0.58
0.52
0.09
0.28
0.13
0.10
0.56
0.17
0.09
0.08
0.19
0.07
0.22
0.14
0.33
0.43
0.18
0.11
0.14
0.42
0.34
0.22
0.34
0.33 1.2
0.12
0.13
8.5 11 16 7.8
4.1
9.9
0.67 12 nd 1.5 16 2.6
1.5
1.1 23
0.15 10 4.9 12 9.1
1.0
1.3
0.78 15 8.1 nd 8.8 nd 7.3
1.3
1.9
9.9 nd 17 8.3
4.7 10
0.83 7.6 13 1.8 19 3.0
1.6
1.4
260.
22 12 5.7 14 9.3
1.4
1.6
0.93 17 9.5 16 9.4 17 7.6
1.5
2.1
1.0
1.3
1.6
1.7
1.5
2.6
<0.5 1.0 nd
<0.5 2.2
0.5
<0.5
<0.5 1.0
<0.5 2.0
0.6
1.3
1.9
<0.5
<0.5
<0.5 1.4
1.4
nd 1.7 nd 3.1
<0.5 0.6
1.6 nd 2.3
2.3
3.2
3.7
0.6
1.9
1.2
0.7
3.8
1.1
0.5
0.5
1.4
<0.5 2.3
1.1
2.1
2.5
1.1
0.8
0.7
2.5
2.0
1.5
2.3
2.4
7.6
0.7
0.9
0.03 nd
0.05
0.06
0.07
0.07
0.01
0.04
0.02
0.01
0.09
0.02
0.01
0.01
0.02
0.01
0.03
0.03
0.07
0.06
0.02
0.01
0.02
0.05
0.04
0.03
0.05
0.04
0.27
0.02
0.02
67 116
200
261
564
374
160
158 nd
242 91 191 74 94 118
106
102 77 134
519
176
136
242 67 238 nd
335 nd 105
210
183
106 nd
357
500
1160 652
205
386
199
328
258
267
102
116
153
125
235
152
329
789
317
223
364 89 417
284
588 79 322
320
276
8 12 6 8 21 14 20 8 nd 24 8 27 21 24 4 26 6 13 7 11 31 22 27 7 11 nd 11 nd 10 18 17
A1
-3
Tabl
e A
1.
Con
tinue
d.
Sam
ple
id
Tot
Cr
ppm
M
n pp
m (
AR
) To
t M
n pp
m
Fe %
(A
R)
Tot
Fe %
C
o pp
m (
AR
) To
t C
o pp
m
Ni p
pm (
AR
) To
t N
i ppm
9408
7-00
194
087-
002
94087-003
9408
7-00
494087-005
9408
7-00
694087-007
9408
7-00
894
087-
009
9408
7-01
09408
7-01
194
087-
012
9408
7-01
394087-014
9408
7-01
594
087-
016
94087-017
94087-018
94087-019
94087-020
9408
7-02
194087-022
9408
7-02
394
087-
024
94087-025
9408
7-02
694087-027
9408
7-02
894087-029
94087-030
9408
7-03
1
16 nd 13 32 30 49 30 25 14 33 29 10 7 29 12 13 17 9 16 38 35 31 38 15 26 17 27 12 71 20 7
65 76 61 34 94 24 11 30 nd 1826
3 29 19 27 118 17 75
'
31 94 43 19 17 12 116 43 nd 45 nd 66 17 36
64 nd 59 34 94 28 12 38 29 1825
9 27 19 28 112 18 74 35 87 44 18 15 13 116 41 62 44 105 72 18 28
0.28
0.88
0.20
0.23
0.58
0.51
0.21
0.15 nd
0.27
0.51
0.38
0.26
0.31
0.20
0.37
0.35
0.20
0.73
0.29
0.32
0.43
0.29
0.60
0.26 nd
0.19 nd 1.4
0.27
0.46
0.35 nd
0.27
0.31
0.76
0.62
0.24
0.34
0.17
0.30
0.76
0.42
0.26
0.35
0.24
0.41
0.43
0.30
0.78
0.33
0.28
0.46
0.33
0.76
0.29
0.17
0.27 1.3
1.9
0.31
0.39
2 4 2 3 5 2 <11 nd <1 2 1 2 1 3 2 3 1 3 3 2 1
<1 6 2 nd 2 nd 8 2 2
2 nd <1 1 5 1 <1 1 <1 <1 2 <1 <1 <1 1 <1 1 <1 2 4 <1 <1 <1 5 1 2 <1 7 7 <11
48 62 61 70 141
113 27 32 nd 42 109 42 20 28 43 31 61 47 69 87 31 23 35 40 43 nd 68 nd 160 71 67
49 nd 58 66 141
106 28 67 29 44 111 44 22 31 39 34 61 49 64 88 35 25 39 39 48 30 63 40 153 78 68
A1
-4
Tabl
e A
1.
Con
tinue
d.
Sam
ple
id
Cu
ppm
(A
R)
Tot
Cu
ppm
Zn
ppm
(A
R)
Tot
Zn p
pm
As
ppm
(A
R)
Tot
As
ppm
S
r pp
m (
AR
) To
t S
r pp
m
Y p
pm (
AR
)94
087-
001
9408
7-00
2 94
087-
003
9408
7-00
4 94
087-
005
9408
7-00
6 94
087-
007
9408
7-00
8 94
087-
009
9408
7-01
0 94
087-
011
9408
7-01
2 94
087-
013
9408
7-01
4 94
087-
015
9408
7-01
6 94
087-
017
9408
7-01
8 94
087-
019
9408
7-02
0 94
087-
021
9408
7-02
2 94
087-
023
9408
7-02
4 94
087-
025
9408
7-02
6 94
087-
027
9408
7-02
8 94
087-
029
9408
7-03
0 94
087-
031
A1-5
25 38 23 34 85 75 16 23 nd 24 25 24 15 18 18 17 17 12 35 62 20 18 20 63 31 nd 34 nd 51 23 21
22 nd 18 28 78 64 16 48 19 23 21 23 14 18 12 16 14 9.6 29 46 22 18 20 57 29 15 29 70 42 23 19
15 185 61 69 240
240 31 46 nd 45 30 82 50 50 89 67 74 23 218
139 27 32 56 30 63 nd 116 nd 259
144
110
15 nd 57 66 255
225 40 114 43 50 32 89 60 58 80 80 75 24 209
155 37 36 64 32 81 48 110 22 257
169
120
3 18 5 7 11 11 5 7 nd <3 <3 <3 <3 4 7 <3 4 <3 6 8 <3 6 3 7 5 nd 5 nd 10 5 6
8 nd <3 9 16 17 4 4 5 6 <3 <3 6 4 3 <3 8 6 <3 <3 4 3 <3 7 <3 8 9 <3 <3 6 4
327
407
531
238
109
233 17 178 nd 39 569 49 26 19
260
4.1
318
158
429
242 28 31 34 529
198 nd
336 nd 274 59 77
517 nd 518
245
141
235 33 198
182 60
589 59 33 30 243 12
349
183
428
255 60 49 52 559
237
349
384
551
314 90 104
13 18 28 22 23 29 5.8 11 nd 7.9 24 9.0
5.1
4.3 12 3.1 25 14 24 27 9.8
6.8
6.2 19 17 nd 21 nd 20 6.9
9.6
Tab
le A
1.
Con
tinue
d.
Sam
ple
id
Tot
Y p
pm
Zr
ppm
(A
R)
Tot
Zr
ppm
T
ot M
o pp
m
Ag
ppm
(A
R)
Ba
ppm
(A
R)
Tot
Ba
ppm
La
ppm
(A
R)
Tot
La
ppm
94087-
001
9408
7-00
294
087-
003
9408
7-00
494087-005
9408
7-00
694
087-
007
9408
7-00
894087-009
9408
7-01
094087-01 1
94087-012
9408
7-01
394
087-
014
94087-015
9408
7-01
694087-017
9408
7-01
894
087-
019
94087-020
94087-021
94087-022
9408
7-02
394
087-
024
94087-025
94087-026
94087-027
94087-028
94087-029
94087-030
94087-
031
13 nd 26 21 24 27 6.2 18 9.9
8.0
25 9.5
5.0
4.9 12 3.7
25.
14 23 27 12 7.1
6.8 19 17 13 20 18 24 7.6
9.8
4.4
5.7
7.1
6.7 11 9.8
3.1
5.6 nd 2.9
7.2
4.1
2.6
3.7
6.4
2.3
5.1
3.8
5.7
9.1
3.1
2.7
4.0 11 5.6 nd 5.9 nd 24 4.1
5.3
16 nd 20 27 42 36 9.7
21 9.4 11 40 13 8.1
9.3 11 8.3
21 13 26 31 14 9.6 12 35 21 13 22 27 179 13 13
13 nd 7 10 15 14 5 20 11 12 11 12 7 13 8 7 8 13 16 22 8 7 14 11 12 6 27 11 50 21 18
<0.2 0.4
0.4
0.9
1.2
1.1
0.4
0.7 nd
<0.2
<0.2 0.3
<0.2 0.4
<0.2 0.5
0.2
0.4
1.2
0.9
0.3
<0.2 0.5
0.9
0.6 nd 0.5 nd 0.8
0.7
0.7
12 15 10 10 14 11 4 5 nd 4 21 6 3 4 7 4 17 12 16 7 4 2 4 9 8 nd 11 nd 13 7 8
63 nd 54 61 72 62 20 48 22 21 84 25 14 17 27 19 81 55 76 52 27 16 24 47 50 28 50 41 190 30 27
7.8
8.9 16 11 12 17 3
6.5 nd 3.3 15 5
2.4 3
7.5
1.6 13 7.4 14 13 4.1
3.2
2.7 15 9.6 nd 9.5 nd 14 2.9
4.7
8.4
nd 14 10 13 16 2.7
9.1
5.0
3.4 17 4.8
2.3
2.5
5.5
1.6 13 6.6 14 13 5.2^
3.2
3.3 17 9.5
7.0 10 14 31 3.5
4.6
A1
-6
Tabl
e A
1.
Con
tinue
d.
Sam
ple
id
Pb
pp
m(A
R)
Tot
Pb
ppm
S
IO2
% (
calc
) C
lay%
(cai
c)
Cal
cite
% (
calc
) S
mono
sulfld
e %
So/
dl
sulfl
de '°
>SO
4'o
rgan
ic '°
94087-001
94087-002
9408
7-00
394
087-
004
94087-005
9408
7-00
694
087-
007
94087-008
9408
7-00
994087-010
94087-01 1
94087-012
9408
7-01
394
087-
014
94087-015
94087-
016
94087-017
94087-018
94087-019
94087-020
94087-021
9408
7-02
294087-023
9408
7-02
494
087-
025
94087-026
9408
7-02
794087-028
94087-029
9408
7-03
09408
7-03
1
4 9 5 4 7 5 2 <2 nd 5 <2 4 <2 4 <2 24 <2 3 5 2 2 6 2 7 3 nd 6 nd 7 <2 <2
<2 nd 2 2 7 6 2 6 <2 <2 <2 <2 <2 <2 3 26 2 <2 5 5 3 6 <2 5 <2 <2 4 5 5 <2 <2
70 66 55 73 78 66 97 67 94 93 54 91 95 96 39 99 70 85 65 65 95 95 96 34 74 97 71 71 73 93 92
3.8 nd 4.1
4.9
7.2
7.2
1.3
3.9
2.2
1.4
7.7
2.4
1.3
1.5
1.9
1.2
3.6
2.2
4.7
5.5
2.4
1.7
1.9
5.2
4.7
3.0
4.9
4.0 22 1.8
1.9
11 14 20 10 5.4 13
0.87 16 nd 1.9
21 3.4
1.9
1.4
300.21 13 6.3 16 12 1.3
1.6
1.0
21 10 nd 11 nd 9.5
1.7
2.4
0.00
70.007
0.00
70.007
0.007
0.00
70.007
0.007
0.00
70.
007
0.007
0.00
70.
011
0.00
70.007
0.00
70.007
0.007
0.00
70.030
0.00
70.
016
0.00
70.13
0.020
0.010
0.00
70.
020
0.08
00.
007
0.00
7
0.00
70.
041
0.00
70.007
0.12
0.05
20.030
0.030
0.03
00.
035
0.00
70.
063
0.040
0.030
0.00
70.
025
0.01
30.
038
0.051
0.34
0.03
40.
160.
072
0.01
00.
020
0.090
0.030
0.52 1.1
0.02
40.
023
0.007
0.007
0.007
0.00
70.010
0.007
0.007
0.05
00.040
0.00
70.007
0.007
0.007
0.007
0.060 nd
0.076
0.007
0.007
0.050
0.007
0.02
70.007
0.050
0.007
0.020
0.020
0.040
0.06
00.
007
0.007
0.30
0.35
0.23
0.34
0.56
0.48
0.17
0.31
0.22
0.21
0.19
0.18
0.16
0.19
0.25
0.13
0.17
0.14
0.13
0.64
0.23
0.16
0.24
0.71
0.21
0.27
0.35
0.81
0.38
0.17
0.16
A1-7
Tab
le A
1.
Con
tinue
d.
Sam
ple
id
S S
d|Suif
|de%c
634S
'org
anic
9408
7-00
194087-0
02
94087-0
03
94087-0
04
94087-0
05
94087-0
06
94087-0
07
9408
7-00
894087-0
09
9408
7-01
094
087-
01 1
94087-0
12
94087-0
13
94087-0
14
94
08
7-0
15
9408
7-01
694087-0
17
94087-0
18
9408
7-01
994087-0
20
9408
7-02
194087-0
22
94087-0
23
9408
7-02
494
087-
025
94087-0
26
94087-0
27
94087-0
28
94087-0
29
9408
7-03
094
087-
031
Insu
ff21
.0 nd nd11
.9 8.5
9.7
9.8
9.9 nd
Insu
ff nd 5.4
11.2
Insu
ff11
.919
.3 2.6
4.0
16.2 nd
20.8
20.7 2.9
11.1
18.4 nd 8.8 nd
10.9
11.2
16.1
Insu
ff nd nd12
.412
.311
.314
.214
.0 nd10
.7 nd 9.5
10.2
10.8 9.2
9.7
8.9
9.1
22.5 nd
18.4
18.5
22.5
20.2
20.0 nd
22.0 nd
11.3
11.8
A1
-8
Tabl
e A
2.
Dat
a on
out
crop
sam
ples
col
lect
ed 1
995,
inc
ludi
ng R
ock
Eva
l da
ta,
inor
gani
c ch
emis
try.
A
r, a
naly
sis
done
on
aqua
reg
ia e
xtra
ct;
tot,
anal
ysis
don
e on
who
le r
ock;
%, w
eigh
t ba
sis;
cal
c, c
alcu
late
d.
Sam
ple
id
Fiel
d no
. m
abo
ve b
ase
Loca
lity
Age
Lith
olog
y C
olor
T
MAX
°C
S1
mg/
gm
S2
mg/
gm96
018-
001
9601
8-00
296
018-
003
9601
8-00
496
018-
005
9601
8-00
696
018-
007
9601
8-00
896
018-
009
9601
8-01
096
018-
011
9601
8-01
296
018-
013
9601
8-01
496
018-
015
9601
8-01
696018-0
17
9601
8-01
896
018-
019
9601
8-02
096
018-
021
9601
8-02
296
018-
023
9601
8-02
496
018-
026
9601
8-02
796
018-
028
9601
8-02
996
018-
030
9601
8-03
196
018-
032
UK
1U
K2
UK
3U
K4
UK
5U
K6
UK
7U
K8
UK
9
UK
10U
K11
UK
12U
K13
UK
14U
K15
UK
16U
K17
UK
18U
K19
UK
20U
K21
UK
22U
K23
UK
24U
K26
UK
27U
K28
UK
29U
K30
UK
31A
UK
31B
0.12
0.16
0.20
0.22
0.28
0.3
20.
350.
390.
42
0.45
0.57
3.9
04.
615.
948.
809.
809.
8510
.58
10.9
812
.05
12.3
012
.54
13.5
013
.76
14.7
615
.22
15.2
515
.45
15.7
020.6
720.0
0
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
Out
crop
7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7
L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L. L.
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
mas
sive
sha
lefis
sile
sha
lem
assi
ve s
hale
fissi
le s
hale
mas
sive
sha
lefis
sile
sha
lem
assi
ve s
hale
mas
sive
sha
lefis
sile
sha
lem
assi
ve s
hale
limes
tone
limes
tone
mas
sive
sha
lelim
esto
nefis
sile
sha
lem
assi
ve s
hale
fissi
le s
hale
mas
sive
sha
lem
assi
ve s
hale
mas
sive
sha
lelim
esto
nem
assi
ve s
hale
limes
tone
mas
sive
sha
lefis
sile
sha
lem
assi
ve s
hale
mas
sive
sha
lem
assi
ve s
hale
limes
tone
mas
sive
sha
lelim
esto
ne
brow
nbl
ack
brow
ngr
aybr
own
blac
kbr
own
brow
ngr
aybr
own
brow
nbr
own
blac
kbr
own
blac
kbr
own
blac
kbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
blac
kbr
own
brow
nbr
own
brow
n
415
414
416
414
418
416
418
419
418
416
426
422
423
421
416
422
418
419
420
423
423
422
419
420
416
414
416
417
420
423
422
2.3 20 3.3 19 3.7 11 3.2
5.4 10 5.3
0.32 2.3
0.81
0.28 9.
51.
78.
82.
51.
81.
20.
010.
91 1.4
1.3 10 6.5
1.7
7.8
0.33 1.
71.
3
26 132 35 121 26 75 20 38 69 38 3.2 14 6.9
3.0 88 22 85 23 14 15
0.11 26 13 18 85 52 16 82 5.
8 22 20
A2-
1
Tabl
e A
2.
Con
tinue
d.
Sam
ple
id
S3
mg/
gm
PI
S2/
S3
PC
TO
G %
HI
Ol
Tota
l S
%
Na%
(AR
) T
otN
a%
M
g%
(AR
) To
t M
g %
9601
8-00
196
018-
002
9601
8-00
396
018-
004
9601
8-00
596
018-
006
9601
8-00
796
018-
008
9601
8-00
996
018-
010
9601
8-01
196
018-
012
9601
8-01
396
018-
014
9601
8-01
596
018-
016
9601
8-01
796
018-
018
9601
8-01
996
018-
020
9601
8-02
196
018-
022
9601
8-02
396
018-
024
9601
8-02
696
018-
027
9601
8-02
896
018-
029
9601
8-03
096
018-
031
9601
8-03
2
1.4
6.7
1.7
4.1
0.72 3.
70.
58 1.0
2.1
1.3
0.44
0.63
0.67
0.26 2.8
1.9
3.3
1.8
0.63 1.
40.
09 2.9
0.72 1.
11.
92.
00.
55 2.2
0.66 2.
01.
5
0.08
0.13
0.09
0.14
0.12
0.13
0.14
0.13
0.13
0.12
0.09
0.14
0.10
0.08
0.10
0.07
0.09
0.10
0.12
0.07
0.08
0.03
0.09
0.07
0.11
0.11
0.10
0.09
0.05
0.07
0.06
18 20 21 30 36 20 35 38 34 29 7.3 23 10 12 32 12 26 13 22 10 1.2
8.9 18 16 45 27 29 37 8.8 11 13
2.4 13 3.2 12 2.5
7.2
1.9
3.6
6.6
3.6
0.29 1.
40.
640.
27 8.1
1.9
7.9
2.1
1.3
1.3
0.01 2.
31.
21.
67.
94.
91.
57.
50.
52.
01.
8
4.7 25 6.4 24 4.7 16 3.9
6.8 14 7.1
0.77 2.9
1.6
0.69 16 4.3 15 5.0
2.5
3.2
0.02 6.
92.
33.
1 16 9.6
3.0 14 1.5
4.7
3.7
556
520
550
510
561
477
511
548
485
540
418
506
442
439
555
507
555
453
544
466
550
381
564
565
537
545
538
594
393
466
542
30 26 26 17 15 23 14 14 14 18 57 22 42 37 17 43 21 36 25 44 450 42 30 36 12 20 18 15 44 41 41
0.46
2.26
0.50 2.2
1.1
1.3
1.2
0.72 1.
10.
730.
130.
370.
220.
14 1.7
0.29 1.
60.
390.
410.
230.
035
0.41
0.13
0.29 1.
80.
91 1.0
1.5
0.60
0.43
0.42
0.03
0.04
0.03
0.04
0.03
0.03
0.03
0.03
0.03
0.03
0.02
0.02
0.03
0.02
0.02
0.03
0.02
0.03
0.02
0.02
0.02
0.03
0.02
0.02
0.03
0.03
0.02
0.03
0.02
0.03
0.03
0.08
0.08
0.08
0.06
0.08
0.06
0.07
0.08
0.07
0.08
0.02
0.04
0.07
0.03
0.06
0.06
0.06
0.06
0.06
0.07
0.02
0.07
0.04
0.05
0.05
0.05
0.07
0.05
0.03
0.07
0.06
0.01
0.12
0.02
0.12
0.02
0.12
0.02
0.06
0.12
0.06
0.32
0.19
0.05
0.25
0.25
0.14
0.15
0.17
0.09
0.06
0.39
0.17
0.18
0.09
0.19
0.19
0.12
0.15
0.24
0.15
0.08
0.04
0.32
0.06
0.29
0.06
0.26
0.05
0.10
0.27
0.12
0.33
0.24
0.07
0.30
0.40
0.22
0.27
0.31
0.14
0.18
0.40
0.50
0.23
0.15
0.30
0.26
0.15
0.25
0.28
0.24
0.14
A2-2
Tabl
e A
2.
Con
tinue
d.
Sam
ple
id
AI%
(AR
) T
otA
I%
P%
(A
R)
Tot
P %
K
% (
AR
) T
otK
%
Ca
% (
AR
) T
otC
a%
S
c pp
m (
AR
) To
t S
c pp
m
To
tTi%
9601
8-00
196
018-
002
9601
8-00
396
018-
004
9601
8-00
596
018-
006
9601
8-00
796
018-
008
9601
8-00
996
018-
010
9601
8-01
196
018-
012
9601
8-01
396
018-
014
9601
8-01
596
018-
016
9601
8-01
796
018-
018
9601
8-01
996
018-
020
9601
8-02
196
018-
022
9601
8-02
396
018-
024
9601
8-02
696
018-
027
9601
8-02
896
018-
029
9601
8-03
096
018-
031
9601
8-03
2
0.03
0.18
0.04
0.16
0.03
0.13
0.03
0.06
0.13
0.06
0.01
0.04
0.03
0.03
0.07
0.05
0.07
0.11
0.04
0.07
<0.0
10.
250.
040.
040.
060.
040.
010.
06<0
.01
0.07
0.03
0.47 2.2
0.53 2.0
0.5
1.7
0.42
0.66 1.
90.
740.
170.
450.
330.
39 1.1
0.79 1.
11.
20.
50 1.1
0.04 2.9
0.50
0.61
0.81
0.56
0.25
0.77
0.12
0.80
0.55
0.03
0.19
0.04
0.12
0.02
0.11
0.02
0.05
0.09
0.04
0.01
0.04
0.04
0.03
0.08
0.04
0.07
0.09
0.07
0.04
0.04
0.07
0.02
0.03
0.10
0.08
0.03
0.10
0.02
0.08
0.04
0.04
0.20
0.04
0.13
0.03
0.11
0.03
0.04
0.10
0.05
0.01
0.04
0.05
0.03
0.09
0.05
0.08
0.09
0.07
0.05
0.04
0.07
0.03
0.04
0.11
0.08
0.03
0.11
0.02
0.09
0.04
0.02
0.08
0.02
0.08
0.02
0.06
0.02
0.03
0.06
0.03
0.01
0.03
0.02
0.03
0.06
0.05
0.07
0.08
0.04
0.06
<0.0
10.
170.
040.
040.
050.
040.
020.
050.
010.
040.
03
0.13
0.68
0.17
0.62
0.16
0.53
0.13
0.27
0.56
0.26
0.04
0.17
0.10
0.16
0.45
0.33
0.47
0.52
0.20
0.41
<0.0
11.
230.
200.
240.
330.
230.
080.
310.
030.
290.
18
0.76 6.1
1.6
7.1
1.3
9.0
1.5
4.3
9.2
4.4 31 24 4.9 28 7.8 14 7.4 15 7.6
4.5 32 12 21 10 16 19 4.4 15 28 10 6.8
0.89 7.3
1.8
8.4
1.7 11 1.9
4.6 12 5.3 34 28 6.2 33 9.3 16 9.0 17 8.6
5.7 36 14 25 13 19 24 5.0 19 35 13 8.8
<0.5 2.9
0.7
2.5
0.6
2.4
<0.5 1.1
2.1
1.1
<0.5 1.1
0.6
0.6
1.0
1.0
1.0
1.8
0.8
2.9
<0.5 2.0
0.7
0.7
1.0
0.8
<0.5 1.0
<0.5 1.3
0.9
0.8
5.4
1.0
5.0
1.0
4.3
0.9
1.2
4.2
1.9
0.6
1.5
0.8
1.3
2.2
1.6
2.3
2.9
1.2
4.0
0.5
5.1
1.2
1.3
1.9
1.5
0.5
1.9
0.5
1.8
1.4
0.02
0.11
0.02
0.10
0.02
0.09
0.02
0.04
0.09
0.04
<0.0
10.
020.
010.
020.
050.
040.
050.
070.
020.
07<0
.01
0.15
0.03
0.03
0.04
0.03
0.01
0.04
<0.0
10.
040.
02
A2-3
Tabl
e A
2.
Con
tinue
d.
Sam
ple
id
V p
pm (
AR
) To
t V
ppm
C
r pp
m (
AR
) To
t C
r pp
m
Mn
ppm
(A
R)
Tot
Mn
ppm
Fe
% (
AR
) To
t Fe
%
Co
ppm
(A
R)
9601
8-00
196
018-
002
9601
8-0
0396
018-
004
9601
8-00
596
018-
006
9601
8-00
796
018-
008
9601
8-00
9
9601
8-01
096
018-
011
9601
8-01
296
018-
013
9601
8-01
496
018-
015
9601
8-01
696
018-
017
9601
8-01
896
018-
019
9601
8-02
096
018-
021
9601
8-02
296
01 8
-023
9601
8-02
496
018-
026
9601
8-0
2796
01 8
-028
9601
8-02
996
01 8
-030
9601
8-03
196
01 8
-032
8434
9 9226
1 8727
3 71 127
227
131 35 116 86 46 63 71 62
348
144
163 17
284
113 53 50 35 12 39 8
283
162
115
593
101
402
112
43
711
818
0438
206 48 142
111 73 89 106
8868
822
938
3 1672
619
0 83 66 47 16 57 9
505
236
2 11 2 9 2 8 2 3 7 4 1 9 4 2 5 2 4 8 4 4 1 9 3 1 4 2 1 3<1
7 4
740
733
831
5 12 31 151
11 3 6 14 10 13 35 13 22 <1 438 7 10 7 3 9
<1 25 11
14 92 36 103 35 121 27 57 100 58 182 64 21 58 169
100
145 54 27 24 79 66 77
151
215
241 58
220
339 40 27
21 99 34 111 38 130 28 51 112 59 188 62 23 58 174
105
152 55 28 27 79 75 79 183
214
247 59
233
367 45 32
0.36
1.29
0.33
1.26
0.80
0.81
0.93
0.42
0.63
0.44
0.14
0.14
0.12
0.17
0.70
0.20
0.61
0.29
0.18
0.2
70.
050.
610.1
00.
190.
650.3
80.
560.4
70.
490.
230.
23
0.46
1.66
0.39
1.51
1.27
1.01
0.95
0.52
0.86
0.53
0.14
0.18
0.15 0.
20.
850.
280.
780.
410.
260.
390.
050.
950.
150.
250.
770.
480.
630.
630.
440.
31 0.3
2 6 3 10 2 5 1 3 5 3<1
1 1 1 6 1 6 2 1 2<1
2<1
4 7 5 2 6 1 1<1
A2-4
Tabl
e A
2.
Con
tinue
d.
Sam
ple
id
Tot
Co
ppm
N
i pp
m (
AR
) To
t N
i pp
m
Cu
ppm
(A
R)
Tot
Cu
ppm
Zn
ppm
(A
R)
Tot
Zn p
pm
As
ppm
(A
R)
9601
8-00
1 96
018-
002
9601
8-00
3 96
018-
004
9601
8-00
5 96
018-
006
9601
8-00
7 96
018-
008
9601
8-00
9 96
018-
010
9601
8-01
1 96
018-
012
9601
8-01
3 96
018-
014
9601
8-01
5 96
018-
016
9601
8-01
7 96
018-
018
9601
8-01
9 96
018-
020
9601
8-02
1 96
018-
022
9601
8-02
3 96
018-
024
9601
8-02
6 96
018-
027
9601
8-02
8 96
018-
029
9601
8-03
0 96
018-
031
9601
8-03
2
A2-5
2 6 2 9 2 6 2 2 5 2 :1 :1 :1 6 2 6 2 :1 2 :1 2 :1 4 6 4 3 6 :1 1 1
5258
200 64 167 37 107 30 47 85 48 13 32 24 12 41 40 42 108 29 54 12 111 23 36 28 18 6 27 3 61 40
202 61 168 40 109 40 46 93 53 12 31 27 13 43 40 44 105 30 59 11 110 25 40 29 19 11 31 4 65 45
17 121 25 109 25 79 22 38 69 37 7.1 25 21 11 64 22 58 52 17 28 3.8
68 12 17 46 32 12 49 6.4
30 24
16 124 22 108 29 78 23 31 72 36
<0.5 19 20 3.3 63 18 57 47 16 27
<0.5 64 7.3 15 41 29 12 49
<0.5 29 23
359
615
362
215 33 105 52 29 42 52 61 68 54 41 11 1.7
6.0
219 54 81 14
296 15 5.4
7.9
5.3
1.4
8.3
1.6
121 75
438
636
313
212 36 86 64 24 46 54 53 64 57 41 15 2.0
7.0
204 59 85 9.9
284 13 5.7
7.8
4.1
1.1
8.1
<0.5
119 82
3 12 5 11 8 8 6 7 7 5 -3 4 -3 4 7 5 5 8 <3 <3 <3 9 <3 4 4 7 3 5 4 6 7
Tab
le A
2.
Con
tinue
d.
Sam
ple
id
Tot
As
ppm
__S
r pp
m (
AR
) T
ot S
r pp
m
Y p
pm (
AR
) T
ot Y
ppm
Z
r pp
m (
AR
) T
ot Z
r pp
m
Mo
ppm
(A
R)
Tot
Mo
ppm
96018-001
96018-002
96018-003
96018-004
9601
8-00
596018-
006
96018-007
9601
8-00
896018-009
9601
8-01
096018-011
9601
8-01
296018-013
96018-014
96018-
015
9601
8-01
696018-
017
96018-018
9601
8-01
996
018-
020
9601
8-02
196018-022
96018-023
96018-024
9601
8-02
696018-027
96018-028
96018-029
96018-030
9601
8-03
196
018-
032
11 12 10 9 8 3 <3 9 6 <3 <3 <3 <3 <3 <3 <3 8 6 <3 6 <3 23 7 <3 9 <3 <3 <3 5 7 9
16 135 32 147 22 160 27 82 193 75 251
381 84 317
177
260
162
254
113 71 322
222
396
148
331
414
100
339
510
229
158
30 147 45 157 39 176 39 87 217 91
237
386 98 319
204
275
191
267
118
91.4
315
241
413
168
335
447
109
366
556
254
190
6.7
39 9.4
31 5.9
27 5.2 11 23 11 8.5 15 9.1 11 14 13 13 26 15 14 2.7
27 11 9.4 14 11 3.1 12 2.5 20 11
6.9
42 9 32 6.6
28 6.1 11 25 12 8.6 14 9.5 11 14 13 14 26 15 15 2.5
28 11 10 14 12 3.2 13 2.6 21 12
1.5 15 2.8 12 2.2
9.9
1.8
4.2
8.5
4.3
4.0
3.7
2.7
2.3
7.0
4.9
6.6
5.8
4.1
5.0
2.7 11 2.7
4.6
7.0
4.9
1.6
6.7
2.1
4.4
3.6
11 55 13 46 13 41 12 16 40 23 6.2
9.3 11 7.6
29 19 26 24 22 27 2.0 63 11 16 22 15 8.3
22 3.3 19 15
25 127 42 100 19 46 11 30 35 31 2 4 5 6 23 8 23 20 4 7 2 13 5 10 8 5 2 6 <1 7 8
34 137 39 108 27 52 15 23 41 36 4 7 6 8 26 9 27 23 5 11 4 17 7 12 11 8 4 9 2 10 11
A2-6
Table A2.
Continued.
Sam
ple id A
g ppm (A
R)
Ba ppm
(AR
) Tot B
a ppm
La ppm (A
R) Tot La ppm
Pb ppm
(AR
) Tot Pb ppm96018-00196018-0029601 8-00396018-00496018-00596018-00696018-0
07
96018-0
08
96018-0
09
96018-01096018-01196018-01296018-0
13
96018-0
14
96018-0
15
96018-0
16
96018-0
17
96018-01896018-01996018-0
20
96018-02196018-0
22
96018-0
23
96018-0
24
96018-0
26
96018-02796018-02896018-02996018-0
30
96018-03196018-032
0.3<
20.20.50.30.20.60.2<
2
<2<2
<2
0.30.3<
20.30.30.70.20.3<
20.5<
20.5<
2<
20.30.4<
20.60.3
12171013996119102685117101165314669858299
861068810582974984969032020176643625727411
11523343626163544336
3.5215.7173.3152.86.813
6.55.2115.26.7119.511158.47.63156.4713113122.5116
3.9235.1193.9173.76.51572.88.54.55.6139.212157.57.90.7195.56.613102.4121.2115.9
7638
1063681356514229
12166467510756<
212668538364
9134893310132529727
1093<2<
2<26<284<24<
27<
2<
23<22<2<
2<23
A2-7
Tabl
e A
2.
Con
tinue
d.
Sam
ple
id96
018-
001
9601
8-00
296
018-
003
9601
8-00
496
018-
005
9601
8-00
696
018-
007
9601
8-00
896
018-
009
9601
8-01
096
018-
011
9601
8-01
296
018-
013
9601
8-01
496
018-
015
9601
8-01
696
018-
017
9601
8-01
896
018-
019
9601
8-02
096
018-
021
9601
8-02
296
018-
023
9601
8-02
496
018-
026
9601
8-02
796
018-
028
9601
8-02
996
018-
030
9601
8-03
196
018-
032
SI02
% (
calc
)92 54 88 53 91 58 92 81 59 80 21 36 86 28 61 60 62 55 78 85 18 60 44 70 39 40 85 44 28 69 77
Cla
y %
(ca
lc) 2.3 10 2.5
9.6
2.4
8.2
2.0
3.2
8.9
3.6
0.82 2.2
1.6
1.9
5.2
3.8
5.3
5.9
2.4
5.1
0.19 14 2.4
2.9
3.9
2.7
1.2
3.7
0.58 3.
82.
6
Cal
cite
% (
calc
) 1.1 8.3
2.2
9.4
1.7 12 1.9
5.5 12 5.7 38 30 6.2 35 10 17 9.5 20 9.7
5.9 40 16 27 13 21 24 5.5 19 35 13 8.6
0.0
A2
-8
Tabl
e A
2.
Con
tinue
d.
Sam
ple
id
Fiel
d no
. m
abo
ve b
ase
Loca
lity
Age
Lith
olog
y C
olor
T
MAX
°C
S1 m
g/gm
S
2 m
g/gm
96018-0
33
9601
8-03
496
018-
035
9601
8-03
696
018-
037
9601
8-03
896
018-
039
9601
8-04
096
018-
041
9601
8-04
296
018-
043
9601
8-04
496
018-
045
9601
8-04
696
018-
047
9601
8-04
896
018-
049
9601
8-05
096
018-
051
9601
8-05
296
018-
053
9601
8-05
496
018-
055
9601
8-05
696
018-
057
9601
8-05
896
018-
059
9601
8-06
096
018-
061
9601
8-06
296
018-
063
9601
8-06
496
018-
065
UK
32U
K33
UK
34U
K35
UK
36U
K37
UK
38U
K39
UK
40U
K41
UK
42U
K43
UK
44U
K45
UK
46U
K47
UK
48U
K49
UK
50U
K51
UK
52U
K53
UK
54U
K55
UK
56U
K57
UK
58U
K59
UK
60U
K61
UK
62 (
P-9
4)U
K63
UK
64
19.7
020
.00
20.3
520
.40
20.7
320
.96
21.2
622
.46
23.4
620
.60
20.1
619
.58
18.9
518
.85
22.2
722.6
324
.25
27.0
027
.82
36.5
336
.58
36.8
037
.12
37.2
237
.48
37.5
438
.01
38.2
538
.65
38.7
639
.55
39.5
940
.14
Outc
rop 2
8O
utcr
op 2
8O
utcr
op 2
8O
utcr
op 2
8O
utcr
op 2
8O
utcr
op 2
8O
utcr
op 2
8O
utcr
op 2
8O
utcr
op 2
8O
ld M
otor
Roa
dO
ld M
otor
Roa
dO
ld M
otor
Roa
dO
ld M
otor
Roa
dO
ld M
otor
Roa
dO
ld M
otor
Roa
dO
ld M
otor
Roa
dO
ld M
otor
Roa
dY
anke
e Q
.Y
anke
e Q
.O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1
L. L. L. L. L. L. L. L. L.Q
.M.
Q.M
.Q
.M.
Q.M
.Q
.M.
Q.M
.Q
.M.
Q.M
.M
.M
.M
.M
.M
.M
.M
.M
.M
.M
.M
.M
.M
.M
.M
.M
.- M
. D
oman
ik-
M.
Dom
anik
- M
. D
oman
ik-
M.
Dom
anik
- M
. D
oman
ik-
M.
Dom
anik
- M
. D
oman
ik-
M.
Dom
anik
- M
. D
oman
ikD
oman
ikD
oman
ikD
oman
ikD
oman
ikD
oman
ikD
oman
ikD
oman
ikD
oman
ikD
oman
ikD
oman
ik-
U.
Dom
anik
- U
. D
oman
ik-
U.
Dom
anik
- U
. D
oman
ik-
U.
Dom
anik
- U
. D
oman
ik-
U.
Dom
anik
- U
. D
oman
ik-
U.
Dom
anik
- U
. D
oman
ik-
U.
Dom
anik
- U
. D
oman
ik-
U.
Dom
anik
- U
. D
oman
ik
mas
sive
mas
sive
mas
sive
mas
sive
shal
esh
ale
shal
esh
ale
limes
tone
mas
sive
mas
sive
shal
esh
ale
limes
tone
mas
sive
shal
elim
esto
nem
assi
vem
assi
vem
assi
vem
assi
vem
assi
vem
assi
vem
assi
ve
shal
esh
ale
shal
esh
ale
shal
esh
ale
shal
elim
esto
nem
assi
vem
assi
vem
assi
vem
assi
vem
assi
vem
assi
vem
assi
vem
assi
vem
assi
vem
assi
vem
assi
vem
assi
vem
assi
vem
assi
vem
assi
ve
shal
esh
ale
shal
esh
ale
shal
esh
ale
shal
esh
ale
shal
esh
ale
shal
esh
ale
shal
esh
ale
shal
e
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
n
421
418
418
420
423
420
419
425
421
424
418
422
421
420
421
420
419
424
421
421
421
419
421
421
422
421
421
420
420
422
422
424
419
0.62 4.3
4.6
1.7
0.02 3.
31.
60.
12.
10.
26 2.2
5.4
6.4
3.0
1.8
2.4
2.2
1.2
2.0
3.5
2.1
3.9
3.5
3.6
3.8
4.4
2.0
3.1
2.9
1.4
2.9
0.61 3.
9
23
42 42 180.
81 35 26 2.3
283
25 45 44 31 23 27
26 5.3 23 22 15 32 26 26 32 34 17 29 27 12 38 6.7
31
A2
-9
Tab
le A
2.
Con
tinue
d.
Sam
ple
id
S3
mg/
gm
PI
S2/S
3__P
C
TO
C %
HI
Ol
Tot
al S
%
Na%
(AR
) T
otN
a%
M
g %
(A
R)
Tot
Ma
%96
018-
033
96018-034
9601
8-03
596
018-
036
9601
8-03
796018-038
96018-039
96018-040
96018-
041
9601
8-04
296
018-
043
96018-044
9601
8-04
596018-046
96018-047
9601
8-04
896018-049
9601
8-05
096018-
051
9601
8-05
296
018-
053
96018-054
9601
8-05
596018-056
96018-057
9601
8-05
896018-059
96018-060
9601
8-06
196
018-
062
96018-063
9601
8-06
496018-065
0.83
0.94 2.0
0.84
0.17
0.98
0.89
0.22 2.1
0.48 1.3
3.04 1.3
0.93 1.5
1.7
2.1
0.8
1.8
0.29
0.38 1.1
0.48
0.39
0.55
0.71
0.73 1.1
1.1
0.73 2.4
0.68 1.3
0.03
0.09
0.10
0.08
0.02
0.09
0.06
0.04
0.07
0.08
0.08
0.11
0.13
0.09
0.07
0.08
0.08
0.18
0.08
0.14
0.13
0.11
0.12
0.12 0.1
0.12
0.10
0.10
0.10
0.10
0.07
0.08
0.11
27 45 21 22 4.8
35 29 10 13 6.3 19 15 34 33 15 15 12 6.6 13 75 39 31 55 67 59 47 24 26 25 16 16 9.8
25
1.9
3.9
3.8
;1.7
0.06 3.2
2.3
0.2
2.5
0.27 2.3
4.2
4.2
2.8
2.0
2.4
2.4
0.54 2.1
2.1
1.4 3
2.5
2.5
3.0
3.2
1.6
2.7
2.5
1.1
3.4
0.6
2.9
4.4
7.1
8.9
3.2
0.21 6.4
4.4
0.47 5.8
0.67 4.4
9.4
7.9
5.0
4.4
5.0
5.1
1.2
4.4
3.6
2.8
6.1
4.4
4.4
5.4
6.0
3.3
5.3
4.8
2.4
7.8
1.5
5.9
509
592
465
579
385
545
597
489
481
447
570
483
563
613
518
532
507
438
515
600
527
528
600
592
604
558
529
556
557
494
487
443
525
18 13 22 26 80 15 20 46 36 71 30 32 16 18 34 34 41 66 40 8 13 17 10 8 10 11 22 21 22 31 30 45 21
0.98
0.74
0.65
0.33
0.00
10.80
0.44
0.14
0.55
0.067
0.35
0.67
0.90
0.41
0.33
0.32
0.27
0.11
0.19
0.52
0.37
0.59
0.56
0.59
0.64
0.83
0.49
0.69
0.51
0.30
0.61
0.19
0.58
0.03
0.02
0.03
0.02
0.02
0.02
0.02
0.02
0.03
0.02
0.02
0.03
0.03
0.02
0.02
0.03
0.03
0.02
0.03
0.02
0.02
0.03
0.02
0.02
0.02
0.02
0.02
0.02
0.03
0.02
0.02
0.02
0.02
0.06
0.05
0.04
0.05
0.02
0.06
0.06
0.03
0.05
0.03
0.07
0.05
0.05
0.07
0.06
0.07
0.06
0.04
0.07
0.05
0.05
0.05
0.06
0.05
0.05
0.06
0.05
0.05
0.05
0.05
0.05
0.05
0.06
0.15
0.08
0.22
0.09
0.31
0.10
0.06
0.31
0.13
0.69
0.03
0.37
0.46
0.05
0.07
0.07
0.09
0.28
0.12
0.06
0.13
0.15
0.06
0.07
0.14
0.26
0.35
0.49
1.57
0.08
0.09
0.02
0.23
0.45
0.14
0.30
0.12
0.37
0.15
0.10
0.35
0.23
0.76
0.09
0.26
0.46
0.11
0.14
0.15
0.16
0.31
0.19
0.10
0.16
0.21
0.10
0.11
0.21
0.36
0.43
0.58 1.6
0.09
0.15
0.03
0.36
A2-1
0
Tab
le A
2.
Co
nti
nu
ed.
Sam
ple
id
AI%
(AR
) T
otA
I%
P%
(A
R)
To
t P
%
K%
(A
R)
To
tK%
C
a%
(AR
) T
otC
a%
S
c pp
m (
AR
) T
otS
c
ppm
T
otT
i%96018-033
9601
8-03
496018-035
96018-036
9601
8-03
796018-038
9601
8-03
996
018-
040
96018-041
9601
8-04
296018-043
96018-044
96018-045
9601
8-04
696
018-
047
96018-048
96018-049
96018-050
9601
8-05
196018-052
9601
8-05
396018-054
9601
8-05
596018-
056
9601
8-05
796018-058
96018-059
96018-060
9601
8-06
196
018-
062
9601
8-06
396
018-
064
9601
8-06
5
0.16
0.03
0.06
0.03
<0.0
10.03
0.03
0.02
0.05
0.02
0.04
0.06
0.06
0.04
0.04
0.05
0.04
0.02
0.07
0.04
0.03
0.06
0.04
0.04
0.06
0.07
0.07
0.05
0.05
0.03
0.05
0.03
0.09
2.9
0.53
0.77
0.45
0.18
0.59
0.45
0.19
0.81
0.25
0.64
0.80
0.89
0.63
0.63
0.89
0.79
0.26
0.80
0.45
0.37
0.62
0.53
0.52
0.75
0.88
0.75
0.77
0.52
0.33
0.63
0.24 1.3
0.05
0.03
0.04
0.02
<0.0
10.
030.02
0.02
0.06
0.03
0.04
0.12
0.06
0.04
0.03
0.05
0.04
0.02
0.04
0.04
0.03
0.05
0.04
0.06
0.09
0.10
0.06
0.05
0.04
0.02
0.08
0.03
0.07
0.05
0.03
0.05
0.02
0.01
0.04
0.03
0.02
0.06
0.03
0.04
0.12
0.06
0.05
0.04
0.05
0.05
0.02
0.05
0.05
0.04
0.05
0.05
0.06
0.09
0.11
0.06
0.06
0.04
0.02
0.07
0.03
0.07
0.11
0.03
0.05
0.03
<0.0
10.03
0.02
0.02
0.05
0.02
0.03
0.05
0.05
0.03
0.03
0.04
0.04
0.02
0.04
0.03
0.02
0.04
0.03
0.03
0.04
0.05
0.04
0.04
0.04
0.02
0.04
0.02
0.06
1.0
0.20
0.29
0.16
0.02
0.21
0.15
0.08
0.33
0.10
0.21
0.30
0.33
0.18
0.22
0.30
0.26
0.09
0.28
0.15
0.13
0.22
0.16
0.17
0.26
0.32
0.26
0.26
0.18
0.10
0.23
0.08
0.46
11 7.2 19 8.7
29 8.8
5.5 29 12 27 2.9 13 11 5.1
7.9
7.0
8.5
25 10 5.3 10 13 5.5
7.2
8.1
8.5 14 8.7 15 2.1
8.9
1.6
7.9
12 9.2
21 9.8
38 10 6.6
33 14 31 3.4 15 13 6.3
9.9
8.3 11 30 12 6.8 12 15 7.0
8.1
9.2 11 16 11 17 2.5 10 2.0
9.7
2.4
1.1
2.0
0.8
<0.5 1.3
0.8
<0.5 1.5
0.6
0.7
2.1
1.9
1.0
0.8
1.2
1.0
0.5
1.5
0.7
0.7
1.3
0.8
1.1
1.5
1.5
1.7
1.3
1.5
0.6
1.7
<0.5 1.8
5.1
1.5
2.7
1.0
0.6
1.5
1.0
0.9
2.2
1.0
1.2
2.7
2.8
1.3
1.3
1.9
1.8
0.8
1.9
1.1
1.0
1.7
1.4
1.4
2.0
2.4
2.3
2.1
1.8
0.6
1.9
<0.5 2.7
0.19
0.03
0.04
0.02
<0.0
10.
030.
010.01
0.04
0.01
0.03
0.04
0.04
0.02
0.03
0.04
0.03
0.01
0.04
0.02
0.02
0.03
0.02
0.02
0.03
0.04
0.04
0.03
0.03
0.01
0.03
<0.0
10.
06
A2
-11
Tabl
e A
2.
Con
tinue
d.
Sam
ple
Id
Vp
pm
(A
R)
Tot
V pp
m
Cr
ppm
(A
R)
Tot
Cr
ppm
M
n pp
m (
AR
) To
t M
n pp
m
Fe %
(A
R)
Tot
Fe %
C
o pp
m (
AR
)96018-033
9601
8-03
496
018-
035
9601
8-03
696018-037
9601
8-03
896018-039
96018-040
96018-041
9601
8-04
296018-043
96018-044
9601
8-04
596018-046
96018-047
9601
8-04
896
018-
049
9601
8-05
096
018-
051
96018-052
96018-053
96018-054
96018-055
96018-056
96018-057
96018-058
9601
8-05
996
018-
060
96018-061
9601
8-06
296018-063
9601
8-06
496018-065
67 172
453
171 38 322
237 28 434 37 190
586
302
203
144
186 73 74 128
217
225
392
245
277
305
342
192
222
271
110
415
141
282
210
280
658
251 57 441
317 38 708 52 346
946
461
352
276
391
175
121
419
346
310
578
390
404
483
571
308
313
324
129
621
176
540
5 4 9 4 <1 5 3 2 9 4 4 19 9 5 3 5 4 4 6 6 9 9 6 8 7 8 8 5 9 3 15 6 7
40 13 29 12 <1 21 14 2 33 7 22 54 29 24 12 25 13 5 23 22 18 28 23 25 28 31 25 15 17 8 44 13 33
140 62 106 73 118 38 31 67 34 79 12 31 34 23 26 31 64 82 58 16 25 37 30 28 27 30 73 53 58 8 22 4 37
146 68 103 72 127 42 33 67 40 79 14 37 37 29 31 34 69 78 61 20 27 40 34 30 30 35 78 56 57 8 24 5 40
0.71
0.19
0.22
0.24
0.07
0.35
0.12
0.09
0.25
0.12
0.17
0.29
0.27
0.19
0.18
0.19
0.33
0.20
0.21
0.16
0.09
0.13
0.19
0.15
0.15
0.32
0.21
0.26
0.12
0.07
0.14
0.07
0.24
1.07
0.26
0.29
0.22
0.08
0.39
0.16
0.11
0.33
0.15
0.23
0.38
0.36
0.24
0.25
0.28
0.43
0.22
0.30
0.21
0.12
0.19
-
0.26
0.18
0.22
0.45
0.31
0.39
0.17
0.08
0.19
0.09
0.37
3 3 2 1<1 <1 2 2 2 <1 <1 2 2 <1
1 2 2 <1 2 1 1<1 2 <1 3 2 3 2 <1
1 1<1 <1
A2-1
2
Tabl
e A
2.
Con
tinue
d.
Sam
ple
id
Tot
Co
ppm
M
i ppm
(A
R)
Tot
Ni
ppm
C
u pp
m (
AR
) To
t C
u pp
m
Zn p
pm (
AR
) To
t Zn
ppm
A
s pp
m (
AR
)96
018-
033
9601
8-03
4 96
018-
035
9601
8-03
6 96
018-
037
9601
8-03
8 96
018-
039
9601
8-04
0 96
018-
041
9601
8-04
2 96
018-
043
9601
8-04
4 96
018-
045
9601
8-04
6 96
018-
047
9601
8-04
8 96
018-
049
9601
8-05
0 96
018-
051
9601
8-05
2 96
018-
053
9601
8-05
4 96
018-
055
9601
8-05
6 96
018-
057
9601
8-05
8 96
018-
059
9601
8-06
0 96
018-
061
9601
8-06
2 96
018-
063
9601
8-06
4 96
018-
065
A2-1
3
3 2 1 1 :1 1 2 :1 2 :1 :1 :1 1 1 :1 1 2 :1 :1 1 1 :1 1 :1 :1 1 1 2 :1 :1 :1 1 1
65 100 93 38 5 53 40 8 85 14 42 106 99 41 37 56 46 20 63 39 39 49 38 42 51 62 36 50 43 23 90 29 53
65 114 91 40 5 55 42 9 90 14 43 103 92 62 40 59 49 19 65 46 40 50 42 42 51 68 38 55 44 23 86 36 56
41 39 56 24 4.7
43 23 7.5
40 8.9
22 65 67 27 22 34 29 9.1 27 26 21 36 30 31 35 38 28 28 32 16 44 15 33
38 39 50 20<0
.5 38 19<0.5 37 3.4
20 63 56 30 20 30 27 2.7
24 25 18 31 29 26 33 37 25 27 28 14 37 14 30
45 27 191 96 14 109 68 27 156 35 59 170
162
108 41 100 26 37 49 132 98 65 82 87 81 116 80 76 65 22 139 41 80
49 28 172 85 11 104 69 23 157 31 60 159
145
115 42 100 26 30 48 150 95 60 87 83 80 125 79 79 63 22 128 43 79
5 5 3 5 5 8 6 4 9 3 <3 10 9 4 6 6 9 3 <3 <3 <3 8 8 5 5 7 6 7 5 5 6 <3 4
Tab
le A
2.
Co
nti
nu
ed.
Sam
ple
id
To
t A
s pp
m
Sr
ppm
(A
R)
To
t S
r pp
m
Y p
pm (
AR
) T
ot
Y p
pm
Zr p
pm (
AR
) T
ot
Zr p
pm
Mo
ppm
(A
R)
To
t M
o pp
m96018-033
9601
8-03
496018-035
96018-036
96018-037
96018-038
9601
8-03
996018-040
9601
8-04
196018-042
96018-043
96018-044
9601
8-04
596018-046
96018-047
9601
8-04
896
018-
049
96018-050
9601
8-05
196018-052
9601
8-05
396018-054
96018-055
9601
8-05
696018-057
9601
8-05
896018-059
9601
8-06
09601
8-06
196
018-
062
9601
8-06
396018-064
9601
8-06
5
7 4 5 <3 8 <3 8 10 9 <3 <3 8 6 <3 10 11 12 <3 5 7 <3 5 13 6 4 8 8 11 <3 8 7 8 11
227
122
323
129
338
154
107
658
238
422 64
281
224
108
248
205
325
932
391
120
225
304
132
186
208
222
362
207
361 58
207 50 217
250
174
345
186
371
229
182
653
305
416
112
309
276
157
312
242
535
937
425
154
235
324
168
199
225
263
392
257
377 75 220 65 265
17 14 33 13 4.6 18 10 9.0
23 9.9 10 32 22 14 11 16 12 9.5 18 12 11 20 13 16 21 22 20 16 16 6.2
24 7.3
20
19 16 32 12 4.9 18 10 8.9 24 9.4 11 31 21 1-4
12 16 13 9.3 19 14 12 20 13 16 21 24 20 16 16 6.0
23 6.9
21
12 3.7
7.2
4.3
4.2
5.7
3.9
3.5
6.5
2.9
2.6
8.6
7.2
3.6
3.9
3.5
3.1
3.4
4.0
3.8
3.5
5.5
2.7
3.7
4.4
5.5
4.3
5.2
5.7
3.0
6.1
2.5
5.2
99 18 23 14 4.3
21 15 5.3
23 5.7 18 26 25 14 18 20 17 6.2
20 13 11 17 13 14 18 21 17 18 16 11 20 9.4
25
13 48 21 7 3 16 7 1 9 2 5 16 46 9 8 7 12 2 4 6 6 8 5 6 8 11 6 16 12 6 7 3 14
17 58 25 10 4 16 10 4 12 4 8 18 48 11 10 9 14 4 5 8 7 10 6 7 9 15 9 20 13 7 8 3 17
A2-1
4
Tabl
e A
2.
Con
tinue
d.
Sam
ple
Id
Ag
ppm
(A
R)
Ba
ppm
(A
R)
Tot
Ba
ppm
La
ppm
(A
R)
Tot
La p
pm
Pb p
pm (
AR
) To
t Pb
ppm
9601
8-03
396
018-
034
9601
8-03
596
018-
036
9601
8-03
796
018-
038
9601
8-03
996
018-
040
9601
8-04
196
018-
042
9601
8-04
396
018-
044
9601
8-04
596
018-
046
9601
8-04
796
018-
048
9601
8-04
996
018-
050
9601
8-05
196
018-
052
9601
8-05
396
018-
054
9601
8-05
596
018-
056
9601
8-05
7.96
018-
058
9601
8-05
996
018-
060
9601
8-06
196
018-
062
9601
8-06
396
018-
064
9601
8-06
5
0.6
0.5
0.4 <2 <2 0.9
0.4
0.3
0.9
0.3
0.3
0.9
0.6
0.5 <2 0.4
0.4
0.2
0.4
0.6
0.6
0.5
0.7
0.5 <2 0.5 <2 0.6
0.4
0.6
0.7
0.6
0.5
11 5 7 5 2 5 5 4 7 4 11 10 8 7 8 9 8 12 11 5 4 7 4 5 6 6 6 6 5 5 6 4 8
93 35 31 221
26 26 9 44 11 44 41 42 36 39 52 57 22 69 20 17 28 22 24 35 40 32 38 22 18 29 14 53
14 8.1 19 7.3 3 10 5.8
6.3 10 6.6
4.8 15 11 6.3
5.8
8.6 6
6.2 12 5.9
5.7
9.6
5.3
7.8
9.8 11 11 8.1
9.6
3.2 11 3.3 10
23 9.2 18 6.7
1.1 11 6
4.3 11 4.9
6.0 14 12 6.8
6.6
8.6
7.4
4.5 11 6.1
5.2
9.5
6.0
7.0 10 12 11 9.2
8.8
3.0 10 3.1 12
6 7 4 6 4 8 7 3 8 5 6 8 9 5 4 <2 3 7 4 7 2 8 5 5 4 4 4 5 8 4 7 5 5
3 <2 <2 4 <2 4 3 <2 3 <2 2 4 5 <2 <2 <2 <2 <2 <2 <2 <2 <2 2 <2 <2 4 4 4 3 2 4 6 4
A2
-15
Tabl
e A
2.
Con
tinue
d.
Sam
ple
id
SIO
2 %
(ca
lc)
Cla
y %
(ca
lc)
Cal
cite
% (
calc
) 14 9.1 23 11 37 11 6.9
36 15 34 3.8 17 14 6.5 10 8.9 11 32 13 6.7 13 16 7.0
9.1 10 11
18
11
19
2.
8 11
2.1 10
9601
8-03
396
018-
034
9601
8-03
596
018-
036
9601
8-03
796
018-
038
9601
8-03
996
018-
040
9601
8-04
196
018-
042
9601
8-04
396
018-
044
9601
8-04
596
018-
046
9601
8-04
796
018-
048
9601
8-04
996
018-
050
9601
8-05
196
018-
052
9601
8-05
396
018-
054
9601
8-05
596
018-
056
9601
8-05
796
018-
058
9601
8-05
996
018-
060
9601
8-06
196
018-
062
9601
8-06
396
018-
064
9601
8-06
5
68 73 42 74 25 70 81 26 63 29 87 54 61 81 75 76 72 34 68 82 70 60 81 77 73 70 60 70 52 92 68 94 72
14 2.5
3.7 2.2
0.86 2.8 2.2
0.91 3.
91.
23.
13.
84
.33
.03.
04.
33.
81.
23.
82.
21.
83
.0 2.5
2.5
3.6
4.2
3.6
3.7
2.5 1.6
3.0
1.2
6.1
A2-1
6
Tabl
e A
2.
Con
tinue
d.
Sam
ple
id
Fiel
d no
. m
abo
ve b
ase
Loca
lity
Age
Lith
olog
y C
olor
T
MAX
°C
S1 m
g/gm
S
2 m
g/gm
9601
8-06
696
018-
067
9601
8-06
896
018-
069
9601
8-07
096
018-
071
9601
8-07
296
018-
073
9601
8-07
496
018-
075
9601
8-07
696
018-
077
9601
8-07
896
018-
079
9601
8-08
096
018-
081
9601
8-08
296
018-
083
9601
8-08
496
018-
085
9601
8-08
696
018-
087
9601
8-08
896
018-
089
9601
8-09
096
018-
091
9601
8-09
296
018-
093
9601
8-09
4
UK
65U
K66
UK
67U
K68
UK
69U
K70
UK
71U
K72
UK
73U
K74
UK
75U
K76
UK
77U
K78
UK
79U
K80
UK
81U
K82
UK
83U
K84
UK
85U
K86
UK
87U
K88
UK
89U
K90
UK
91U
K92
UK
93
(P-9
6)4
1.0
041.2
041
.55
41.7
842.0
343
.42
43.5
043.5
844
.42
44.5
044
.79
45.3
845
.66
45.8
345
.85
46.4
947
.45
47.7
648
.21
48.4
748
.57
49.1
749
.63
50.2
551
.19
51.2
153
.44
54.7
655
.17
Ou
tcro
p 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1O
utcr
op 2
1B
lack
Dog
Q.
Bla
ck D
og Q
.B
lack
Dog
Q.
Bla
ck D
og Q
.B
lack
Dog
Q.
Bla
ck D
og Q
.B
lack
Dog
Q.
Bla
ck D
og Q
.B
lack
Dog
Q.
Bla
ck D
og Q
.B
lack
Dog
Q.
Bla
ck D
og Q
.B
lack
Dog
Q.
Bla
ck D
og Q
.B
lack
Dog
Q.
Bla
ck D
og Q
.B
lack
Dog
Q.
Bla
ck D
og Q
.B
lack
Dog
Q.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
M.
-U.
-U.
-U.
-U.
-U.
-U.
- U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.-U
.
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
Dom
anik
mas
sive
sha
lem
assi
ve s
hale
mas
sive
sha
lelim
esto
nefis
sile
sha
lefis
sile
sha
lelim
esto
nem
assi
ve s
hale
limes
tone
fissi
le s
hale
mas
sive
sha
lem
assi
ve s
hale
mas
sive
sha
lem
assi
ve s
hale
mas
sive
sha
lem
assi
ve s
hale
mas
sive
sha
lem
assi
ve s
hale
limes
tone
mas
sive
sha
lem
assi
ve s
hale
mas
sive
sha
lem
assi
ve s
hale
clay
mas
sive
sha
lend m
assi
ve s
hale
limes
tone
fissi
le s
hale
brow
nbr
own
brow
nbr
own
blac
kbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbl
ack
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
brow
nbr
own
blac
knd br
own
brow
nbr
own
420
424
418
424
422
422
415
416
424
424
416
420
419
418
419
420
418
420
420
418
418
415
414
415
417
418
423
419
423
3.3
4.1
4.8
0.1
5.1
2.9
0.64 4.4
0.06 1.
92.
32.
54.
4 10 3.4
1.6
1.4
1.9
0.13 4.
46.
38.
47.
50.
49 6.1
4.0
1.6
0.28 1.
2
28 39 38 1.4 63 36 2.8
41 1.0 26 23 26 39 84 36 17 24 17 1.4
37 50 61 56 12 44 24 22 2.6 16
A2
-17
Tabl
e A
2.
Con
tinue
d.
Sam
ple
id
S3
mg/
gm
PI
S2/
S3
PC
TO
G %
HI
Ol
Tota
l S%
N
a%(A
R)
To
tNa
%
Mg
%(A
R)
Tot
Mg
%96
018-
066
9601
8-06
796
018-
068
9601
8-06
996
018-
070
9601
8-07
196
018-
072
9601
8-07
396
018-
074
9601
8-07
596
018-
076
9601
8-07
796
018-
078
96018-0
79
9601
8-08
096
018-
081
9601
8-08
296
018-
083
9601
8-08
496
018-
085
9601
8-08
696
018-
087
9601
8-08
896
018-
089
9601
8-09
096
018-
091
9601
8-09
296
018-
093
9601
8-09
4
1.5
3.5
1.6
0.38 6.2
2.7
0.17 1.
30.
29 2.6
0.66 1.
70.
76 1.4
0.61
0.85 1.
10.
790.
140.
800.
63 1.9
2.8
0.33
0.87
0.64 2.7
0.31 2.
3
0.10
0.10
0.11
0.07
0.07
0.08
0.19
0.1
00.
060.0
70.
090.
090.
100.
110.
090.
080.
050.
100.
090.
110.
110.
120.
120.
040.
120.
140.
070.
100.
07
19 11 23 3.7 10 13 16 32 3.5 10 35 16 52 61 59 20 22 21 9.8
46 79 32 20 37 50
38 8.1
8.3
6.7
2.6
3.6
3.6
0.12 5.
73.
20.
28 3.8
0.09 2.
32.
12.
43.
67.
83.
31.
52.
11.
60.
12 3.4
4.7
5.8
5.3
1.1
4.2
2.3
1.9
0.23 1.
4
5.4
8.9
7.1
0.4
2 15 6.7
0.4
76.
80.2
65.
53.
95.
26.
9 16 6.3
3.1
4.2
3.1
0.2
76.
37.
9 12 10 2.5
8.3
4.2
5.0
0.7
03.
5
518
434
533
330
413
534
593
602
392
475
593
503
570
515
572
540
574
547
507
579
632
518
543
493
530
575
429
365
450
27 39 22 90 40 40 36 1911
1 46 16 32 11 8 927 26 25 51 12 8 16 26 13 10 15 53 44 66
0.5
20.8
40.6
60.2
01.
10.4
50.0
60
.60
0.0
50.3
40
.37
0.4
50.7
31.
60.5
70.
310.
310.3
20.2
80.6
00.9
21.
30.7
74
.5 1.3
0.4
30.2
41.
10.1
9
0.02
0.02
0.03
0.02
0.02
0.02
0.02
0.03
0.02
0.0
30.0
20.
020.
030.0
20.
020.
030.
020.
020.
030.
030.
030.
030.
030.
020.
030.
030.
020.
020.
02
0.0
50.0
60.0
50.0
20.
050.
050.0
20.0
40.0
30.0
60.
060.
050.0
50.0
50.
060.
050.
060.
060.
030.
050.
060.
060.
050.3
70.0
60.
060.0
70.0
30.0
6
0.33
0.08
0.12
0.2
70.
080.
080.
360.1
50.
360.
160.0
60.
140.
160.0
80.
04 3.4
0.05
0.04
0.56
0.91
0.14
0.09
0.34
0.10
0.12
0.18
0.10
0.29
0.14
0.4
20.2
50.2
30.2
80.3
00.1
70.
360.2
00.3
70.
320.
110.
250.
250.2
90.1
23
.40.0
90.0
70.
56 1.0
0.3
00.
300.
560.8
70.3
00.2
20.2
70.3
30.
21
A2-1
8
Tabl
e A
2.
Con
tinue
d.
Sam
ple
id
Al %
(A
R)
To
tAI%
P
% (
AR
) To
t P
%
K%
(A
R)
To
tK%
C
a %
(A
R)
Tot
Ca
%
Sc
ppm
(A
R)
Tot
Sc
ppm
9601
8-06
696
018-
067
9601
8-06
896
018-
069
9601
8-07
096
018-
071
9601
8-07
296
018-
073
9601
8-07
496
018-
075
9601
8-07
696
018-
077
9601
8-07
896
018-
079
9601
8-08
096
018-
081
9601
8-08
296
018-
083
9601
8-08
496
018-
085
9601
8-08
696
018-
087
9601
8-08
896
018-
089
9601
8-09
096
018-
091
9601
8-09
296
018-
093
9601
8-09
4
0.07
0.14
<0.0
10.
010.
160.
07<0
.01
0.05
0.01
0.11
0.04
<0.0
10.
090.
170.
060.
080.
040.
030.
020.
080.
130.
140.
080.
320.
140.
030.
110.
020.
07
0.84 1.
51.
00.
12 1.9
0.82
0.05
0.52
0.09 1.
50.
610.
930.
94 1.8
0.82
0.75
0.51
0.45
0.13
0.88 1.
51.
90.
99 7.5
2.4
0.48 1.
50.
230.
80
0.07
0.13
0.13
0.02
0.15
0.08
0.01
0.08
0.01
0.08
0.04
0.08
0.08
0.15
0.05
0.05
0.05
0.03
0.01
0.05
0.09
0.07
0.06
0.01
0.05
0.03
0.05
0.01
0.03
0.07
0.14
0.13
0.02
0.17
0.09
0.01
0.08
0.01
0.10
0.05
0.09
0.09
0.16
0.06
0.05
0.05
0.04
0.01
0.05
0.10
0.08
0.07
0.04
0.05
0.03
0.06
0.02
0.04
0.05
0.09
0.07
<0.0
10.
100.
06<0
.01
0.04
0.01
0.07
0.03
0.06
0.06
0.10
0.05
0.05
0.03
0.02
0.01
0.05
0.08
0.10
0.06
0.21
0.09
0.03
0.08
0.02
0.05
0.31
0.58
0.39
0.04
0.71
0.32
0.02
0.19
0.04
0.53
0.21
0.35
0.35
0.68
0.27
0.28
0.16
0.14
0.03
0.31
0.55
0.70
0.38 2.1
0.61
0.17
0.53
0.10
0.29
13 6.1
9.3 30 5.7
8.4 31 17 31 11 5.6 13 14 6.3
3.9 12 5.0
4.7 31 16 9.4
6.5 15 1.5
8.6 16 8.3 29 14
15 7.2 10 34 6.9 11 35 20 34 15 6.8 15 16 7.4
5.0 14 6.2
6.0 34 18 11 7.6 18 2.0
9.7 18 10 31 16
1.6
3.4
2.3
<0.5 2.6
1.8
<0.5 1.1
<0.5 2.0
1.0
2.2
1.7
2.6
1.2
2.1
0.9
0.7
<0.5 1.5
1.9
2.4
1.3
1.6
1.8
1.1
2.0
<0.5 1.6
2.3
5.0
3.1
1.1
4.9
2.5
<0.5 1.5
0.8
3.5
1.4
3.0
2.8
4.5
1.9
2.6
1.2
1.1
0.8
2.4
3.3
4.7
2.4 11 3.6
1.3
3.4
0.8
2.1
0.04
0.08
0.05
<0.0
10.
090.
04<0
.01
0.03
<0.0
10.
090.
020.
050.
040.
090.
030.
040.
020.
02<0
.01
0.04
0.08
0.09
0.04
0.46
0.11
0.03
0.10
0.01
0.04
A2
-19
Tabl
e A
2.
Con
tinue
d.
Sam
ple
id
V p
pm (
AR
) To
t V
ppm
C
r pp
m (
AR
) To
t C
r pp
m
Mn
ppm
(A
R)
Tot
Mn
ppm
Fe
% (
AR
) To
t Fe
%
Co
ppm
(A
R)
9601
8-06
696
018-
067
96018-068
96018-069
9601
8-07
096
018-
071
9601
8-07
296018-073
9601
8-07
496
018-
075
9601
8-07
696
018-
077
9601
8-07
89601
8-07
996
018-
080
96018-081
96018-082
9601
8-08
39601
8-08
496
018-
085
96018-086
9601
8-08
79601
8-08
896
018-
089
9601
8-09
096
018-
091
96018-092
96018-093
9601
8-09
4
215
579
467 71 768
274 21 169 61 184
132
292
426
920
345
241
183
145 40 202
393
423
104 30 233
129
173 39 221
293
1190 810 84
1770 517 21 220 65 438
190
551
800
1850 717
316
300
221 46 291
878
925
145
191
476
182
452 79 483
8 22 18 2 25 12 1 4 2 11 4 18 14 25 9 16 6 4 1 7 10 10 6 9 8 5 8 2 7
20 83 54 3 94 38 <1 9 139 14 48 40 86 35 29 20 11 1 17 39 44 15 85 39 11 39 4 25
36 22 33 62 18 28 39 43 100 55 25 51 23 16 13 105
386 17 48 63 40 35 103 74 57 77 83 113
114
40 31 37 58 36 32 37 42 95 67 27 57 29 29 17 104
407 21 44 65 48 44 108 95 58 74 90 108
111
0.17
0.29
0.27
0.40
0.27
0.18
0.05
0.12
0.10
0.29
0.18
0.16
0.20
0.27
0.21
0.25
0.12
0.10
0.24
0.24
0.26
0.65
0.37 3.3
0.95
0.14
0.46
0.92
0.52
0.26
0.49
0.37
0.39
0.53
0.30
0.06
0.17
0.10
0.48
0.22
0.28
0.35
0.51
0.29
0.29
0.16
0.14
0.24
0.32
0.44
0.83
0.50 4.0
1.2
0.20
0.71
0.81
0.62
1 1 2 <11 2 <1 3 <1 2 <1 <11 3 1 1
<1 <1 <1 2 5 4 5 20 3 2 3 2 3
A2-2
0
Tabl
e A
2.
Con
tinue
d.
Sam
ple
id
Tot
Co
ppm
N
i pp
m (
AR
) To
t N
i pp
m
Cu
ppm
(A
R)
Tot
Cu
ppm
Zn
ppm
(A
R)
Tot
Zn p
pm
As
ppm
(A
R)
9601
8-06
696
018-
067
9601
8-06
896
018-
069
9601
8-07
096
018-
071
9601
8-07
296
018-
073
9601
8-07
496
018-
075
9601
8-07
696
018-
077
9601
8-07
896
018-
079
9601
8-08
096
018-
081
9601
8-08
296
018-
083
9601
8-08
496
018-
085
9601
8-08
696
018-
087
9601
8-08
896
018-
089
9601
8-09
096
018-
091
9601
8-09
296
018-
093
9601
8-09
4
<1 2 1<1 1 1<1 2 <1 2 1 1 1 3 <1 <1 <1 <1 <1 3 3 3 5 20 3 1 2 <1 <1
53 134 81 16
204 82 6 55 8 82 31 71 81 219 64 47 85 35 8 72 150
138 68 55 144 56 90 20 65
56 141 80 16
224 91 6 55 7 90 34 74 84 224 68 48 90 38 7 71 156
145 66 64 138 59 93 16 63
34 83 54 7.8 90 48 3.4 27 4.9 54 23 35 43 89 38 32 22 19 5.0 45 57 96 38 79 73 30 43 5.6 30
29 79 46 1.0 92 48
<0.5 21
<0.5 55 21 32 40 87 36 28 19 18
<0.5 40 56 89 34 75 63 26 40
<0.5 26
107
283
163 78 407
115
3.7 54 19 169 58 136
153
402
120
113
101 39 25 79 216
272 40 48 259
176
243
9.5
277
107
288
154 70 434
120
1.0 51 15 180 62 138
136
416
125
111
104 40 21 76 218
270 40 56 242
117
243
9.2
262
<3 7 7 7 7 6 <3 7 <3 4 4 4 6 9 9 6 4 <3 4 8 7 12 6 6 21 <3 9 6 11
A2
-21
Tab
le A
2.
Con
tinue
d.
Sam
ple
id
Tot
As
ppm
S
r pp
m (
AR
) T
ot S
r pp
m
Y p
pm (
AR
) T
ot Y
ppm
Z
r pp
m (
AR
) T
ot Z
r pp
m
Mo
ppm
(A
R)
Tot
Mo
ppm
9601
8-06
696018-067
9601
8-06
896018-069
96018-070
9601
8-07
196018-072
96018-073
9601
8-0
7496018-075
96018-076
9601
8-07
796
018-
078
96018-079
9601 8-0
8096018-081
9601
8-08
296018-083
9601
8-08
496
018-
085
9601
8-08
696018-087
9601
8-08
896
018-
089
96018-
090
96018-091
9601
8-09
296018-093
96018-094
<3 8 5 4 12 8 5 19 <3 <3 8 3 <3 14 10 <3 4 6 11 13 13 12 5 8 4 6 10 <3 7
406
209
287
480
219
265
619
507
905
516
157
400
357
234
137
352
169
149
394
544
361
263
591 48 285
470
287
685
486
421
265
315
468
299
349
604
526
853
623
185
454
397
299
212
376
258
203
377
594
463
365
671
246
309
490
395
661
612
19 40 31 8.7
40 21 1.5 18 7.1 23 11 27 23 39 16 16 13 9.3
3.7
20 27 21 17 3.9 18 13 19
.5.4 32
19 41 30 8.1 43 23 1.4 17 6.5
26 12 28 24 42 17 16 13 10 3.5
20 29 23 18 17 18 13 21 5.6
31
6.3 11 8.6
1.2 14 7.2
2.8
4.8
3.4
6.9
3.5
6.3
6.0 14 5.0
5.0
3.7
3.7
2.9
5.2
6.6 12 6.5
22 13 6.6
9.0
5.0
6.5
23 43 29 2.8
50 27 1.8 15 3.5
39 15 25 23 48 20 18 14 13 2.9
21 32 47 23 319 63 21 50 9 26
8 15 11 7 15 7 6 37 2 4 8 6 22 65 23 8 10 14 4 43 45 56 39 2 64 29 17 4 25
10 18 13 7 19 10 8 40 3 6 10 8 27 74 27 12 12 17 6 47 54 66 44 4 69 35 21 7 27
A2-2
2
Tabl
e A
2.
Con
tinue
d.
Sam
ple
Id
Ag
ppm
(A
R)
Ba
ppm
(A
R)
Tot
Ba
ppm
La
ppm
(A
R)
Tot
La p
pm
Pb
ppm
(A
R)
Tot
Pb
ppm
9601
8-06
696
018-
067
9601
8-06
896
018-
069
9601
8-07
096
018-
071
9601
8-07
296
018-
073
9601
8-07
496
018-
075
9601
8-07
696
018-
077
9601
8-07
896
018-
079
9601
8-08
096
018-
081
9601
8-08
296
018-
083
9601
8-08
496
018-
085
9601
8-08
696
018-
087
9601
8-08
896
018-
089
9601
8-09
096
018-
091
9601
8-09
296
018-
093
9601
8-09
4
0.4
1.2
1.0
0.6
1.1
0.5
0.3 <2 <2 0.4
0.2
0.4
1.0
1.0
1.0
0.5
0.3 <2 <2 0.4
0.7
0.7
0.3
0.3 2 <2 0.5 <21
7 9 7 2 9 5 2 5 4 8 5 7 6 8 5 5 7 4 1 7 8 8 7 13 8 5 11 5 12
45 72 44 4 93 37 3 28 6 60 27 38 43 85 38 33 26 23 2 40 69 82 50 344 72 31 65 11 45
9.9 18 15 4.8 17 10 1.9
9.9
4.7 13 5.8 14 11 16 6.7
9.3
6.0
4.7
2.5 12 12 8.6 10 4.7 10 8.4 11 3.3 15
10 20 15 3.7 21 12
<0.
59.
22.
8 16 6.5 15 12 19 8.2
9.6
7.0
4.5
0.7 13 15 13 12 58 15 8.2 15 1.9 16
8 10 8 4 8 6 _2 5 5 6 4 3 6 10 7 2 3 3 4 7 8 9 4 17 10 6 7 6 <2
4 8 3 <2 8 4 <2 <2 <2 5 4 2 3 7 5 5 <2 3 <2 4 6 10 5 10 8 <2 4 <2 5
A2-2
3
Tabl
e A
2. C
ontin
ued.
Sam
ple
id96
018-
066
9601
8-06
796
018-
068
9601
8-06
996
018-
070
9601
8-07
196
018-
072
9601
8-07
396
018-
074
9601
8-07
596
018-
076
9601
8-07
796
018-
078
9601
8-07
996
018-
080
9601
8-08
196
018-
082
9601
8-08
396
018-
084
9601
8-08
596
018-
086
9601
8-08
796
018-
088
9601
8-08
996
018-
090
9601
8-09
196
018-
092
9601
8-09
396
018-
094
SI02
% (
calc
) 60 74 68 24 67 71 21 48 21 64 81 62 56 65 83 54 82 84 21 49 67 69 50 93 68 54 73 26 60
Cla
y %
(cal
c) 4.0
7.3
4.8
0.58 8.9
3.9
0.24 2.5
0.43 7.2
2.9
4.5
4.5
8.4
3.9
3.6
2.4
2.2
0.62 4.2
7.1
9.1
4.8 36 12 2.3
7.2
1.1
3.8
Cal
cite
% (
calc
) 16 8.1
11.6 37 7.6 11 39 22 39 15 7.2 16 18 8.4
5.1 15 6.4
6.0 39 20 12 8.6 19 2.9 11 20 11 36 18
A2
-24
Tabl
e A
3.
Roc
k E
val
data
fo
r fin
ely
spac
ed d
rill
sam
ples
.
Sam
ple
id
Fiel
d no
. m
abo
ve b
ase
Sam
plin
g yr
. Lo
calit
yA
geT
max
°C
S1
mg/
gm
S2
mg/
gm96
0190
01
D1
9601
9002
D2
9601
9003
D3
9601
9004
D4
9601
9005
D5
9601
9006
D6
9601
9007
D7
9601
9008
D8
9601
9009
D9
9601
9010
D10
9601
9011
D
1196
0190
12 D
1296
0190
13 D
13
Sam
ple
id
Fie
ld n
o.96
0190
01
D1
9601
9002
D2
9601
9003
D3
9601
9004
D4
9601
9005
D5
9601
9006
D6
9601
9007
D7
9601
9008
D8
9601
9009
D9
9601
9010
D10
9601
9011
D
1196
0190
12 D
1296
0190
13 D
13
22.1
8
22.2
2
22.2
8
22.3
5
22.6
5
22.8
1 22.8
7
23.1
8
23.2
523.4
945.3
445.8
345.8
5
S3
mg/
gm4.
02.
51.
91.
81.
92.
42.
42
.92.
83
.6 1.3
1.6
0.7
9
1 995
Old
Mot
or R
oad
Q.
M.
Dom
anik
1 9
95 O
ld M
otor
Roa
d Q
. M
. D
oman
ik
1 995
Old
Mot
or R
oad
Q.
M.
Dom
anik
1 9
95 O
ld M
otor
Roa
d Q
. M
. D
oman
ik
1995
Old
Mot
or R
oad
Q.
M.
Dom
anik
19
95 O
ld M
otor
Roa
d Q
. M
. D
oman
ik
1995
Old
Mot
or R
oad
Q.
M.
Dom
anik
19
95 O
ld M
otor
Roa
d Q
. M
. D
oman
ik
1995
Old
Mot
or R
oad
Q.
M.
Dom
anik
1995
Old
Mot
or R
oad
Q.
M.
Dom
anik
1995
Bla
ck D
og Q
.19
95 B
lack
Dog
Q.
1995
Bla
ck D
og Q
.
PI
S2
/S3
0.12
0.0
80.
050.
070.
100.
09o.
io0.
080.
080.
100.
110.
110.1
0
M. -U
.M
. -U
.M
. -U
.
PC
0.87 13 14 13 12 11 7.1 12 13 12 35 59 40
Dom
anik
Dom
anik
Dom
anik
0.33 2.9
2.2
2.1
2.2
2.5
1.6
3.0
3.2
3.9
4.2
8.6
2.9
499
420
422
422
422
420
424
419
420
419
419
416
419
TO
C0.
33 6.5
5.0
4.4
4.8
6.0
3.9
7.2
7.4
8.8
8.4 18 6.0
0.50
2.
8 1.
3 1.
7 2.
6 2.
7 1.
9 2.
9 2.
94.
75.
8 12 3.5
HI
1060
491
511
529
502
453
430
466
474
480
535
502
528
3.5 32
25
23
24
27
17
33
35 42 45 91 32
Ol
1212 38 37 40 40 40 60 40 37 40 15 8 13
A3
-1
Table A4. Information on samples in subset. All samples were collected in 1995.
Sample id Field no. m above baseLocalityAgeLithologyColor96018-00196018-00296018-00396018-00496018-00596018-00696018-00796018-00896018-00996018-01096018-01196018-01296018-01696018-01796018-02896018-02996018-03096018-03196018-03496018-03596018-03696018-03796018-04496018-05396018-05496018-05596018-05696018-05896018-05996018-06396018-06696018-06796018-07096018-07196018-07296018-07396018-07696018-07996018-08696018-08896018-08996018-09296018-09396018-094
UK1UK2UK3UK4UK5UK6UK7UK8UK9
UK10UK11UK12UK16UK17UK28UK29UK30
UK31AUK33UK34UK35UK36UK43UK52UK53UK54UK55UK57UK58UK62UK65UK66UK69UK70UK71UK72UK75UK78UK85UK87UK88UK91UK92UK93
0.120.160.200.220.280.320.350.390.420.450.573.909.809.8515.2515.4515.7020.6720.0020.3520.4520.7319.5836.5836.8037.1237.2237.5438.0139.5541.0041.2042.0343.4243.5043.5844.7945.8348.5749.6350.2553.4454.7655.17
Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 7Outcrop 28Outcrop 28Outcrop 28Outcrop 28
Old Motor Road Q.Outcrop 21Outcrop 21Outcrop 21Outcrop 21Outcrop 21Outcrop 21Outcrop 21Outcrop 21Outcrop 21Outcrop 21Outcrop 21Outcrop 21Outcrop 21
Black Dog Q.Black Dog Q.Black Dog Q.Black Dog Q.Black Dog Q.Black Dog Q.Black Dog Q.Black Dog Q.
L DomanikL. DomanikL. DomanikL. DomanikL. DomanikL. DomanikL. DomanikL. DomanikL. DomanikL. DomanikL. DomanikL. DomanikL. DomanikL. DomanikL. DomanikL. DomanikL. DomanikL. Domanik
L. - M. DomanikL. - M. DomanikL. - M. DomanikL. - M. Domanik
M. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. DomanikM. - U. Domanik
massive shalefissile shale
massive shalefissile shale
massive shalefissile shale
massive shalemassive shale
fissile shalemassive shale
limestonelimestone
massive shalefissile shale
massive shalemassive shale
limestonemassive shalemassive shalemassive shalemassive shale
limestonemassive shalemassive shalemassive shalemassive shalemassive shalemassive shalemassive shalemassive shalemassive shalemassive shale
fissile shalefissile shalelimestone
massive shalemassive shalemassive shalemassive shalemassive shale
claymassive shale
limestonefissile shale
brownblackbrowngray
brownblackbrownbrowngray
brownbrownbrownbrownblackblackbrownbrownbrownbrownbrownbrownbrownbrownbrownbrownbrownbrownbrownbrownbrownbrownbrownblackbrownbrownbrownbrownblackbrownbrownbrownbrownbrownbrown
A4-1
Tabl
e A
5.
Dat
a on
sub
set
of s
ampl
e, i
nclu
ding
min
eral
ogy
of th
e w
hole
roc
k; a
tom
ic r
atib
s of
org
anic
mat
ter;
carb
on i
soto
pes
and
V a
nd N
i po
rphy
rin
(P)
cont
ent
in b
itum
en e
xtra
cts;
and
sul
fur
spec
iatio
n an
d th
eir
isot
opic
com
posi
tion.
M
iner
alog
y in
pea
k he
ight
(ch
art
units
), ca
rbon
iso
tope
dat
a re
lativ
e to
PD
B s
tand
ard,
an
d su
lfur
isot
opes
rel
ativ
e to
Can
on D
iabl
o Tr
oilit
e st
anda
rd.
Samp
le id
m abo
ve base
Quartz p
k ht
Calcite pk ht
atom
ic H/C
atomic O/C
atomic N/C
Bit.
9601
8-00
196018-002
9601
8-00
396018-004
9601
8-00
596018-006
96018-007
9601
8-00
896
018-
009
9601
8-01
096
018-
011
9601
8-01
296018-016
96018-017
96018-028
96018-029
9601
8-03
096018-031
96018-034
9601
8-03
596018-036
9601
8-03
796
018-
044
9601
8-05
396
018-
054
9601
8-05
596018-056
96018-058
96018-059
9601
8-06
3
0.12
0.16
0.20
0.22
0.28
0.32
0.35
0.39
0.42
0.45
0.57
3.90
9.80
9.85
15.2
515
.45
15.7
020
.67
20.0
020
.35
20.4
020
.73
19.5
836
.58
36.8
037
.12
37.2
237
.54
38.0
139
.55
6302
1181
5252
1364
5907
2259
5427
4327
2120
3883 79 875
2325
2658
3870
1085 156
2066
2965
1009
3567 21
1839
2403
2812
2816
3830
3539
1784
3329
69 560
160
124
178
1153 307
565
1196 582
2701
1771
1559 912
694
1597
2400 786
786
1463
1121
2979
1299 884
1410
412
927
985
1270
1018
1.17
1.18
1.18
1.16
1.18
1.17
1.19
1.21
1.19
1.19
1.13
1.20
1.20
1.20
1.23
1.23
1.13
1.20
1.24
1.20
1.22 nd
1.18
1.22
1.20
1.23
1.24
1.24
1.22
1.18
0.10
90.
089
0.11
20.078
0.064
0.07
70.
055
0.075
0.069
0.09
10.124
0.05
40.118
0.080
0.06
80.
070
0.10
90.119
0.068
0.08
30.
079 nd
0.105
0.052
0.07
90.
051
0.063
0.050
0.06
60.
112
0.029
0.032
0.029
0.03
30.
031
0.03
30.
035
0.03
40.032
0.03
10.
033
0.030
0.02
70.02
80.
028
0.028
0.024
0.025
0.029
0.029
0.028 nd
0.03
10.03
00.
029
0.029
0.029
0.02
70.029
0.028
Ex. pp
m VP
15421
2854
827
576
2696
224
547
2323
510105
2549
221
947
2377
711
887944
8577
14562
5026
2327
91606
5501
15784
10234
14039
313
2224
45634
1369
219833
15970
15359
5476
14399
in b
it
NiP
in bit
937
1622 834
2758
1581
2998
2130
1977
3028
2175
1467
5080 583
1065 657
511 67
1445
2906
6038
2495 nd
1213
6037
2978
2488
2690
2630
1005
1451
78 251 73 372 98 207
142
136
228
132
111
215 38 114
114 94 15 84 392
358 78 nd 80 254
136 70 129
159 76 45
A5-1
Tabl
e A
5.
Con
tinue
d.
Sam
ple
id
S13C
satu
rate
s81
3Car
omat
lcs
613C
kero
gen
°dls
ulf
lde
wt%
S
orga
nic
wt%
634S
, dlsu
lflda
634S
'org
anic
9601
8-00
196018-002
9601
8-00
396018-004
96018-005
9601
8-00
696018-007
9601
8-00
896018-009
9601
8-01
096018-011
96018-012
9601
8-01
696018-017
96018-
028
96018-029
96018-030
96018-031
96018-
034
9601
8-03
596018-036
9601
8-03
796018-
044
9601
8-05
396018-
054
96018-055
96018-056
96018-058
9601
8-05
996018-063
-29.8
-29.7
-29.7
-29.7
-29.7
-29.7
-29.7
-29.6
-29.7
-29.6
-29.6
-30.0
-29.6
-29.5
-29.7
-29.7
-29.8
-29.9
-29.7
-29.7
-29.6
-29.5
-29.5
-29.4
-29.6
-29.6
-29.5
-29.4
-29.5
-29.5
-29.2
-28.2
-29.2
-28.2
-29.7
-28.5
-29.0
-29.1
-28.6
-29.1
-29.2
-28.8
-28.8
-27.9
-28.4
-28.3
-28.9
-29.3
-28.2
-27.9
-28.5
-27.9
-29.1
-29.0
-29.1
-29.2
-29.2
-29.1
-28.9
-29.2
-26.
8-27.0
-27.3
-27.0
-27.2
-27.
1-27.2
-27.2
-27.2
-26.9
-27.2
-28.6
-29.5
-28.7
-28.3
-28.2
-28.2
-29.5
-27.7
-28.4
-28.
1 nd-29.5
-29.9
-29.5
-29.5
-29.9
-29.7
-29.7
-29.9
0.062
0.28
0.054
0.69
0.85
0.28
0.88
0.28
0.28
0.12
0.08
40.
082
0.0041
0.28
0.52
0.39
0.27
0.02
70.
160.074
0.10 nd
0.04
90.055
0.023
0.14
0.10
0.20
0.09
20.016
0.30 1.2
0.36
0.99
0.27
0.71
0.35
0.35
0.62
0.38
0.044
0.22
0.22
0.78
0.33
0.77
0.12
0.32
0.37
0.43
0.23 nd
0.55
0.23
0.38
0.35
0.34
0.42
0.26
0.41
24.3
13.4
23.2 5.4
14.4 4.5
15.0 9.8
-2.9 7.9
10.4 4.2
insuff
-4.3
14.0
-2.2
17.9
11.7 7.3
0.6
12.8 nd 9.0
11.5
11.0
18.5
13.6
17.2
18.2
insuff
13.1
16.8
14.9
17.4
14.4
16.8
14.7
15.1
15.7
14.3
insuff
12.6
15.0
18.5
17.4
21.1
17.4
17.8
14.8
14.9
13.5 nd
12.4
20.4
20.8
19.5
20.0
21.7
21.1
19.7
A5-2
Tabl
e A
5.
Con
tinue
d.
Sam
ple
id
m a
bove
bas
e Q
uart
z pk
ht
Cal
cite
pk
ht
atom
ic H
/C
atom
ic O
/C
atom
ic N
/C
Bit.
Ex.
Ppm
V
OP
in b
it N
iP in
bit
9601
8-06
696
018-
070
9601
8-07
196
018-
072
9601
8-07
396
018-
076
9601
8-07
996018-086
96018-088
9601
8-08
996
018-
092
9601
8-09
396
018-
094
41.0
042
.03
43.4
243
.50
43.5
844
.79
45.8
348
.57
49.6
350
.25
53.4
454
.76
55.1
7
2485
2142
2960 134
1640
4477
2386
2593
1246
1284
2880 184
2381
1325 577
1048
3227
1799 731
758
1106
1731 103
1020
2998
1549
1.16
1.11
1.19
1.23
1.21
1.21
1.19
1.23
1.19
1.18
1.14
1.19
1.13
0.096
1.39
0.11
90.054
0.07
10.062
0.064
0.051
1.01
0.084
0.15
30.072
0.149
0.02
70.03
50.
030
0.02
80.
023
0.02
70.
034
0.03
60.
030
0.02
70.
034
0.03
60.03
5
13158
13926
12202
2688
13227
11594
19457
14698
1437
118
495451 840
6197
1735 947
1211
1652
1344
2443
6633
3218 676
939
328
4431 589
95 30 68 126 58 118
485
303 89 145 66
1814 48
A5-3
Tabl
e AS
. C
ontin
ued.
Sam
ple
id
696
018-
066
9601
8-07
096
018-
071
9601
8-07
296
018-
073
9601
8-07
696
018-
079
9601
8-08
696
018-
088
9601
8-08
996
018-
092
9601
8-09
396
018-
094
** s
atur
ates
O
-29.
5-2
8.7
-29.
1-2
9.6
-29.
0-2
9.2
-28.
9-2
9.3
-29.
5-2
9.2
-29.
6-3
0.1
-29.
6
* *
arom
atlc
s 0
-29.
0-2
8.9
-29.
2-2
9.3
-29.
3-2
9.2
-28.
9-2
9.1
-28.
9-2
8.5
-29.
2-2
8.0
-29.
2
13
XN
Q
' **
ker
ogen
°d
ls
-29.
6-3
0.1
-30.
5-3
0.1
-29.
9-2
9.7
-30.
2-3
0.0
-29.
1-2
7.3
-29.
2-2
9.7
-29.
8
iulfl
de W
t%
0.0
33
0.01
70.
038
0.01
90.
021
0.04
80.
220.
290.
10 3.9
0.01 1.
10.
01
Sorg
anic
Wt%
6
0.3
6
0.75
0.36
0.03
60.
380.
270.
900.
410.
540.
210.
230.
046
0.15
Sd
lsu
lfld
e
5
10.2
18.8
14.8
18.6
4.9
19.8
13.8
13.3 1.7
-1.7 5.8
13.0
14.3
^org
anic
17.8
20.9
19.7
insu
ff19
.818
.820
.821
.217
.817
.513
.617
.715
.0
A5-4
Tabl
e A
6. E
xtra
ctio
n an
d co
lum
n ch
rom
atog
raph
y da
ta f
or t
he D
oman
ik b
itum
en e
xtra
cts.
[Not
e, 9
6019
014-
9601
9017
are
oils
col
lect
ed in
the
vici
nity
of t
he D
oman
ik r
ock
sam
ples
and
, al
thou
gh n
ot d
iscu
ssed
in
the
text
, the
oil
data
are
incl
uded
in th
is ta
ble.
]
Bitu
men
B
itum
en
Sat
/Aro
m
on c
olum
n S
ampl
e id
(p
pm-r
ock)
ra
tio
(mg)
96
01
80
01
15
421
1.97
49
96018002
28
54
8
3.13
53
96018003
27576
1.80
40
96018004
26
96
2
2.18
47
96018005
24547
1.67
36
96018006
23
23
5
2.43
49
96018007
1010
5 2.
20
5296018008
25
49
2
2.04
52
96
01
80
09
21947
2.46
45
96018010
23777
1.89
49
96
01
80
11
11
88
3.16
54
96018012
7944
2.42
52
96018016
8577
2.11
40
96
01
80
17
14
562
1.25
47
96018028
5026
1.
66
5196018029
23279
1.73
52
96018030
1606
3.
84
519
60
18
03
1
5501
3.
42
5596018034
1578
4 1.
90
5196018035
10
23
4
2.21
50
96018036
1403
9 1.
43
6396018037
313
0.58
29
96018044
22
24
4
1.83
44
96018053
5634
1.12
47
96
01
80
54
13
692
1.88
54
96018055
1983
3 1.
26
4696018056
1597
0 1.
51
5496018058
1535
9 1.
32
5796018059
5476
1.05
49
Fra
ctio
ns fr
om c
S
atur
ates
(m
g)
(%)
9.66
24
20.6
41
6.89
22
18.3
38
9.20
31
17.3
37
17.9
37
17.3
31
17.2
42
15.2
33
17.0
34
16.5
34
6.16
20
10.5
22
13.1
28
13.7
29
19.6
44
16.6
35
17.2
37
16.2
34
9.00
19
2.04
7.
09.
01
2513
.2
3015
.2
3310
.3
2517
.2
3318
.5
3415
.0
32
Dlu
mn
chro
mat
oc
Aro
mat
ics
(mg)
(%
)4
.90
12
6.5
9
133.8
2
128.3
7
175.5
2
187.1
2
158.1
3
178.4
6
156.9
8
178.0
6
175.3
8
1 1
6.8
3
142.
92
108.4
4
187.8
9
177
.90
16
5.11
11
4.8
5
109.0
9
197
.34
15
6.3
0
143.5
3
124
.93
14
1 1
.8
278.1
2
188.2
0
2011
.4
2214
.1
2614
.3
30
iraph
y N
SO
(m
g)
(%)
14.8
37
16.4
32
13.4
43
14.5
30
9.8
8
3314
.1
3015
.0
3122.6
41
12.2
30
15.7
34
20.5
41
15.5
32
12.5
41
16.7
35
15.0
32
15.6
33
13.4
30
20.4
43
16.3
35
15.6
33
21.0
45
8.5
6
2912
.9
3610
.3
2414
.1
3114
.7
3615
.3
3015
.2
2813
.1
28
Asp
halte
ne
(mg)
(%
)10
.67.
277.
297.
095.
327.
956.
937.
014.
757.2
67.
619.
548.
71 11.9
10.4
10.7
6.47
6.11
4.4
98.6
010
.215
.29.
138.
518.
568.
087.8
46.
764.6
7
27 14 23 15 18 17 14 13 12 16 15 20 29 25 22 22 15 13 10 18 22 52 25 19 19 20 15 12 10
A6-1
Tabl
e A
6. C
ontin
ued.
Bitu
men
on
Bitu
men
S
at/A
rom
co
lum
nS
ampl
e id
(p
pm-r
ock)
ra
tio
(mg)
9601
8 07
1 12
202
2.51
49
96018072
2688
2.71
30
96
01
80
73
13
227
1.29
51
96018076
1159
4 1.
65
53
96
01
80
79
19
457
1.32
52
96018086
1469
8 1.
39
5196018088
1437
1 1.
55
5096018089
1849
1.
06
45
96018092
5451
2.
63
5196018093
840
1.55
42
9601
8 09
4 61
97
2.9
6
4696019014
2.18
43
96
01
90
15
1.
07
5196
019
016
2.8
4
439
60
19
01
7
1.70
54
Fra
ctio
ns f
rom
col
umn
chro
mat
ocS
atur
ates
(mg)
(%
)10
.6
2510
.2
3714
.6
3012
.9
27
17.6
32
17.3
34
16.2
32
11.3
24
16.3
34
12.1
26
14.1
36
17.8
57
18.0
41
18.8
60
18.7
51
Aro
matic
s
(mg)
(%
)4.2
0
103.
76
1411
.3
237.
82
17
13.4
24
12.5
24
10.4
20
10.7
23
6.1
8
137.
81
174.7
8
128.
14
2616
.8
386.
62
2111
.0
30
iraph
yN
SO
(mg)
(%
)16
.4
388.
41
3115
.1
3115
.8
3312
.2
2213
.8
2716
.7
3316
.1
3418
.5
3914
.1
3115
.9
414
.08
13
7.4
5
173.5
7
114
.67
13
Asp
halte
ne(m
g)
(%)
11.6
4.94
8.35 10
.7
12.0
7.36
7.66
9.39
6.92 12
.04.
221.
291.
802.4
42.
16
27 18 17 23 22 14 15 20 14 26 11 4.1
4.1
7.8
5.9
A6-2
Tabl
e A
7. B
iom
arke
r ra
tios
of D
oman
ik b
itum
en e
xtra
cts.
S
ee p
aram
eter
key
at
end
of ta
ble.
Sam
ple
id
dept
h/st
rat
TRIC
Y
PE
NT
STE
R
C31
HS
R
C29
SR
C
29B
BA
A
T/T+
M
TRIO
CR
C
27S
TER
C
28S
TER
C
29S
TER
9601
8001
9601
8002
9601
8003
9601
8004
9601
8005
9601
8 00
696
018
007
9601
8008
9601
8009
9601
8 01
096
0180
1196
0180
1296
0180
1696
0180
1796
018
028
9601
8029
9601
8 03
096
0180
3196
0180
3596
0180
3696
018
037
9601
8044
9601
8 05
396
0180
5496
018
055
9601
8 05
696
0180
5896
0180
5996
018
063
9601
8066
9601
8067
9601
8070
9601
8071
0.12
0.16
0.20
0.22
0.28
0.32
0.35
0.39
0.42
0.45
0.57
3.90
9.80
9.85
15.2
515
.45
15.7
020
.67
20.3
520
.40
20.7
319
.58
36.5
836
.80
37.1
237
.22
37.5
438
.01
39.5
541
.00
41.2
042
.03
43.4
2
12.8
033
.70
11.7
032
.30
11.8
020
.40
13.6
014
.00
18.9
013
.80
15.1
014
.10
15.1
020
.80
11.4
012
.40
9.50
13.9
014
.00
5.70
4.90
14.9
017
.40
9.00
12.6
010
.70
14.9
011
.40
15.9
014
.70
16.8
015
.40
15.2
0
59.1
030
.90
57.1
030
.00
55.7
047
.20
56.1
054
.30
52.7
056
.80
60.2
057
.00
61.9
055
.80
59.6
058
.00
64.1
055
.90
39.2
042
.90
49.8
056
.10
54.9
069
.70
60.7
069
.20
55.6
066
.10
61.8
057
.80
55.4
054
.10
58.8
0
28.0
035
.40
31.2
037
.80
32.5
032
.40
30.4
031
.60
28.4
029
.40
24.6
029
.00
23.1
023
.40
28.9
029
.60
26.4
030
.20
46.7
051
.40
45.3
029
.00
27.7
021
.30
26.7
020
.10
29.6
022
.60
22.3
027
.50
27.8
030
.50
26.0
0
0.58
0.48
0.57
0.45
0.58
0.54
0.59
0.57
0.56
0.58
0.56
0.58
0.55
0.43
0.52
0.50
0.55
0.58
0.44
0.50
0.54
0.57
0.57
0.56
0.56
0.57
0.57
0.55
0.57
0.58
0.57
0.56
0.57
0.34
0.36
0.33
0.34
0.37
0.36
0.36
0.37
0.36
0.37
0.35
0.37
0.35
0.27
0.26
0.25
0.25
0.37
0.18
0.18
0.23
0.34
0.43
0.43
0.39
0.41
0.43
0.42
0.48
0.42
0.41
0.42
0.42
0.43
0.38
0.43
0.38
0.45
0.41
0.44
0.43
0.42
0.46
0.42
0.40
0.41
0.33
0.36
0.32
0.34
0.40
0.26
0.29
0.28
0.41
0.47
0.45
0.48
0.48
0.46
0.44
0.51
0.48
0.46
0.46
0.47
0.66
0.74
0.57
0.75
0.49
0.71
0.56
0.56
0.69
0.59
0.71
0.57
0.70
0.68
0.52
0.58
0.70
0.64
0.39
0.20
0.30
0.60
0.61
0.61
0.56
0.56
0.61
0.60
0.65
0.63
0.61
0.54
0.66
0.06
0.11
0.07
0.12
0.06
0.10
0.07
0.06
0.09
0.07
0.05
0.04
0.03
0.08
0.03
0.03
0.02
0.05
0.05
0.01
0.03
0.07
0.14
0.12
0.10
0.11
0.17
0.13
0.02
0.10
0.11
0.12
0.08
0.38
0.35
0.25
0.36
0.24
0.34
0.29
0.27
0.32
0.31
0.29
0.32
0.00
0.33
0.29
0.30
0.24
0.27
0.32
0.28
0.32
0.36
0.31
0.29
0.38
0.38
0.33
0.33
0.35
0.36
0.36
0.33
0.26
0.17
0.20
0.13
0.19
0.22
0.19
0.20
0.21
0.19
0.20
0.19
0.19
0.28
0.20
0.19
0.18
0.18
0.20
0.17
0.18
0.16
0.18
0.20
0.20
0.11
0.11
0.19
0.20
0.18
0.18
0.18
0.21
0.20
0.45
0.46
0.62
0.45
0.54
0.46
0.52
0.52
0.49
0.49
0.51
0.49
0.72
0.47
0.52
0.52
0.58
0.53
0.51
0.54
0.52
0.47
0.48
0.50
0.51
0.51
0.48
0.47
0.47
0.46
0.46
0.47
0.54
A7
-1
Tabl
e A
7. C
ontin
ued.
Sam
ple
id
PL
/HO
P
GA
M/H
OP
B
IS/H
OP
D
IA/R
EG
P
RE
G/C
27
TR
I/HO
P
TE
T/T
RI
Ts/
Tm
N
OR
/HO
P
NE
O/N
OR
M
OR
/HO
P96
0180
0196
0180
0296
0180
0396
0180
0496
0180
0596
0180
0696
0180
0796
0180
0896
0180
0996
0180
1096
0180
1196
0180
1296
0180
1696
0180
1796
0180
2896
0180
2996
0180
3096
0180
3196
0180
3596
0180
3696
0180
3796
0180
4496
0180
5396
0180
5496
0180
5596
0180
5696
0180
5896
0180
5996
0180
6396
0180
6696
0180
6796
0180
7096
018
071
0.00
0.01
0.00
0.01
0.01
0.01
0.00
0.00
0.01
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.01
0.01
0.01
0.00
0.00
0.00
0.00
0.00
0.11
0.07
0.07
0.05
0.05
0.10
0.06
0.09
0.09
0.02
0.15
0.11
0.06
0.13
0.26
0.19
0.15
0.09
0.23
0.36
0.41
0.09
0.07
0.09
0.03
0.12
0.04
0.10
0.06
0.06
0.09
0.04
0.06
0.03
0.06
0.02
0.06
0.02
0.02
0.02
0.02
0.03
0.02
0.02
0.03
0.05
0.06
0.07
0.08
0.06
0.02
0.03
0.03
0.02
0.01
0.01
0.04
0.01
0.04
0.01
0.04
0.02
0.02
0.03
0.02
0.01
0.33
0.47
0.46
0.62
0.41
0.47
0.38
0.44
0.46
0.49
0.30
0.35
0.25
0.80
0.26
0.25
0.11
0.28
0.16
0.10
1.42
0.25
0.57
0.37
0.31
0.44
0.33
0.41
0.47
0.27
0.36
0.53
0.39
0.07
0.16
0.16
0.17
0.13
0.12
0.15
0.14
0.15
0.13
0.13
0.10 54
0.17
0.11
0.09
0.08
0.17
0.08
0.03
0.07
0.11
.
0.20
0.17
0.13
0.13
0.20
0.16
0.13
0.14
0.17
0.19
0.22
0.17
0.58
0.16
0.68
0.17
0.29
0.20
0.20
0.25
0.20
0.21
0.19
0.18
0.17
0.13
0.15
0.11
0.21
0.20
0.11
0.06
0.22
0.26
0.19
0.18
0.19
0.21
0.20
0.21
0.19
0.23
0.23
0.22
0.25
0.30
0.27
0.24
0.23
0.29
0.26
0.23
0.27
0.24
0.26
0.24
0.25
0.32
0.27
0.30
0.27
0.25
0.25
0.23
0.42
0.22
0.27
0.25
0.24
0.21
0.29
0.21
0.23
0.22
0.27
0.24
0.24
0.51
0.42
0.50
0.37
0.51
0.37
0.52
0.45
0.44
0.52
0.48
0.38
0.52
0.15
0.45
0.46
0.37
0.43
0.40
0.38
0.23
0.46
0.53
0.65
0.53
0.53
0.58
0.56
0.66
0.60
0.62
0.46
0.65
0.56
0.65
0.61
0.68
0.55
0.64
0.62
0.61
0.61
0.61
0.58
0.56
0.54
0.53
0.54
0.55
0.52
0.56
0.50
0.47
0.07
0.61
0.64
0.62
0.57
0.57
0.61
0.56
0.59
0.57
0.61
0.64
0.58
0.12
0.10
0.18
0.14
0.10
0.15
0.13
0.12
0.12
0.15
0.13
0.11
0.14
0.09
0.15
0.13
0.13
0.15
0.11
0.12
6.78
0.13
0.13
0.24
0.12
0.22
0.14
0.17
0.14
0.15
0.16
0.15
0.16
0.12
0.11
0.10
0.16
0.13
0.13
0.09
0.14
0.11
0.13
0.14
0.13
0.15
0.21
0.16
0.20
0.19
0.12
0.28
0.21
0.24
0.12
0.09
0.15
0.11
0.18
0.08
0.14
0.08
0.09
0.11
0.09
0.09
A7
-2
Tab
le A
7. C
on
tin
ued
.
Sam
ple
id
C32
HS
R
C35
/34
ST
ER
/PE
NT
M
/M+T
T
RIO
CR
1 T
RIO
CR
2 T
RI/M
ON
O
TR
I/ST
ER
9601
8 00
196
018
002
96018003
96018004
96018005
96018006
9601
8 00
796018008
96018009
96018010
96018011
9601
8 01
296018016
96018017
96018028
96018029
96018030
9601
8 03
196018035
96018036
96018037
96
01
80
44
96018053
96018054
96018055
96018056
9601
8 05
896018059
9601
8 06
396018066
96018067
96018070
960
18
07
1
0.5
40.5
30.
550.4
60.5
60.5
20
.57
0.5
30.5
70.
550.5
80.5
60
.54
0.5
20.5
00.5
40.5
20.5
80
.47
0.4
70.5
40.5
40.5
70
.59
0.65
0.5
80.5
80
.59
0.5
40
.56
0.61
0.5
50.6
0
0.09
0.06
0.09
0.0
60.0
70.0
70.0
80.0
80.
070.0
80.0
70.0
80.
080.0
90.0
70.0
70.0
90.0
70.0
90.1
20.0
00.0
70.0
60.0
70.0
80.0
60.0
60.0
50.0
90
.07
0.0
60.0
70.0
6
0.4
71.
150.5
51.
260.5
80.6
90.5
40.5
80.5
40.5
20.
410.
510.3
70.4
20.4
80.
510.
410
.54
1.19
1.20
0.91
0.5
20.5
00.
310
.44
0.2
90.5
30
.34
0.3
60
.47
0.5
00
.56
0.4
4
0.3
40.
260.
430.
250.
510.
290.
440.
440.
310.
410.2
90.
430.
300.3
20.
480.
420.
300.3
60.
610.8
00.
700.4
00.3
90.
390.4
40.4
40.
390.4
00.
350.3
70.
390.4
60.
34
0.0
50
.12
0.0
60.1
40.0
50
.10
0.0
60.0
60
.08
0.0
70.0
50
.04
0.0
30
.09
0.0
30.0
30
.02
0.0
40.0
60.
010.0
30
.07
0.1
50
.10
0.0
90.
110.1
80
.13
0.0
20
.09
0.11
0.1
30
.07
0.07
0.15
0.08
0.17
0.07
0.13
0.08
0.08
0.12
0.0
90.0
70.
050.
030.
100.0
40.
040.
020.
070.
060.0
20.
030.0
90.
200.1
70.1
40.
150.
280.
180.
030.
120.
150.1
70.
11
1.75
2.5
61.
282.8
20.8
32.1
91.
081.
151.
881.
262.
511.
111.
991.
840.8
91.
052.0
91.
680.5
30.2
20.3
71.
431.
451.
321.
221.
180.8
91.
381.
571.
60.
1.36
1.14
1.73
0.19
1.51
0.30
1.60
0.32
1.12
0.43
0.46
1.05
0.52
0.35
0.9
20.
341.
470.
761.
010.
120.3
30.
590.
160.7
90.3
70.8
00.4
90.
42.0
.50
0.3
80.7
20.4
00.3
70.
540.6
90.
38
A7
-3
Tab
le A
7. C
on
tin
ued
.
Sam
ple
id
dep
th/s
trat
T
RIC
Y
PE
NT
S
TE
R
C31
HS
R
C29
SR
C
29B
BA
A
T/T
+M
TR
IOC
R
C27
ST
ER
C
28S
TE
R
C29
ST
ER
96018072
43.5
0
12.8
0 56.1
0
31.1
0 0.5
8
0.4
2
0.61
0.
62
0.09
0.
39
0.18
0.4
39
60
18
07
3
43.5
8 23.8
0
44.3
0
31.9
0
0.51
0
.43
0.
45
0.7
0
0.25
0.
31
0.22
0.4
796018076
9601
8 07
99
60
18
08
696018088
96018089
96
01
80
92
44.7
945.8
348.5
749.6
350
.25
53.4
4
13.3
024.2
016
.50
18.2
08.
8014
.70
55.5
04
3.2
050.4
047.9
051.9
055.3
0
31.2
032
.60
33.1
033
.90
39.3
030.0
0
0.5
80.
550.
550.
550.3
20.4
8
0.41
0.41
0.4
20.3
90
.14
0.3
2
0.46
0.45
0.47
0.4
30.
290.
39
0.59
0.68
0.59
0.6
30.
110.7
7
0.09
0.26
0.15
0.17
0.11
0.1
3
0.26
0.31
0.34
0.26
0.31
0.2
7
0.20
0.20
0.21
0.15
0.16
0.1
8
0.5
40.
480.
460.
590.5
30.5
49
60
18
09
3
54.7
6 3.
50
37.6
0
58.9
0 0.3
0
0.1
2
0.19
0.
13
0.22
0.
26
0.16
0.
599
60
18
09
4
55.1
7 17
.90
54.8
0
27.3
0 0.5
4
0.3
6
0.4
3
0.72
0.
11
0.34
0.
19
0.48
A7
-4
Tab
le A
7. C
ontin
ued.
Sam
ple
id
O
L/H
OP
G
AM
/HO
P
BIS
/HO
P
DIA
/RE
G
PR
EG
/C27
TR
I/H
OP
T
ET
fl-R
I Js
fTm
N
OR
/HO
P
NE
O/N
OR
M
OR
/HO
P96
018
072
96
01
80
73
96
01
80
76
9601
8 07
996
018
086
96018088
96018089
9601
8 09
296
018
093
9601
8 09
4
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.0
50.
090.1
00.0
70.0
60.0
70.1
30.
120.3
60.0
7
0.01
0.02
0.01
0.03
0.01
0.02
0.27
0.02
0.15
0.0
2
0.6
01.
170.
351.
260.6
90.8
30.
180.
590.0
60.
41
0.10
0.32
0.16
0.40
0.12
0.21
0.11
0.26
0.03
0.1
5
0.17
0.3
60.
190.
370.
220.
290.0
40.
240.0
30.2
6
0.27
0.30
0.26
0.22
0.35
0.2
70.
550.2
60.
530.
23
0.61
0.44
0.55
0.4
70.
510.
450.
280.
400.4
70.6
4
0.5
60.
590.5
40.
650.6
00.
650.3
70.
610.1
60.
60
0.14
0.11
0.18
0.14
0.15
0.11
0.27
0.13
0.14
0.2
0
0.09
0.12
0.09
0.10
0.11
0.1
00.
390.
120.
280.1
4
A7
-5
Tabl
e A
7. C
ontin
ued.
Sa
mp
le i
d C
32H
SR
C
35/3
4
ST
ER
/PE
NT
M
/M+
T
TR
IOC
R1
TR
IOC
R2
TR
I/M
ON
O
TR
I/S
TE
R
9601
8 07
29
60
18
07
39
60
18
07
69
60
18
07
99
60
18
086
96
01
80
88
96
01
80
89
96
01
80
92
9601
8 09
396018094
0.57
0.55
0.55
0.55
0.55
0.53
0.28
0.53
0.23
0.56
0.08
0.07
0.0
70.
060.
060.
060.
080.
060.
100.
06
0.55
0.72
0.5
60.
750.
660.
710.
760.
541.
570.
50
0.38
0.30
0.41
0.3
20.
410.
370.
890.
230.
870.2
8
0.08
0.32
0.08
0.33
0.1
60.
180.
170.
110.
230.
09
0.11
0.50
0.12
0.50
0.2
20.
250.
160.
170.
330.1
4
1.47
2.45
1.22
2.43
1.43
1.78
0.14
3.21
0.18
2.40
0.2
91.
920.4
01.
930.9
80.8
60.4
00.
420.1
60.
18
A7
-6
Biomarker Parameters Key for Table A7.
Parameter Name:
TRICY
PENT
Description:
100-^Tricyclic
^ Tricyclic + ^ Pentacyclic + ^ Sterane ]
Where:ZTricydic is the sum of ajj peaks (named and unnamed)in the m/z 191 .1800mass chromatogram from retention time = 0 up to, but not including C27 18a Ts;or up to and including C30 22R Tricyclic (if C27 18a Ts is not present).^Pentacyclic is the sum of ajl peaks (named and unnamed)in the m/z 191.1800mass chromatogram including C27 18a Ts and all peaks eluting after C27 18a Tsin the m/z 191.1800 mass chromatogram.ZSterane is the sum of peaks (named and unnamed)in the m/z 217.1956 masschromatogram including C27 20S Ba Dia and aji peaks (named and unnamed)eluting thereafter (C27 - C^ steranes).
100 2 Pentacyclic
Tricyclic + ^ Pentacyclic + 2_j Sterane^
STEP
Where:^Tricyclic, ^Pentacyclic, and ZSterane are defined as above.
Sterane ________
Tricyclic + ^ Pentacyclic + ^ Sterane^
C31HSR
C29SR
Where:ZTricyclic, ZPentacyclic, and ZSterane are defined as above.
______ 31 22S Hopane______[Csi 22S Hopane + Csi 22R Hopane]
_______C29 2QS aaa Sterane_______ [C29 20S aaa Sterane + C29 20R aaa Sterane]
Where:aaa refers to the 5a(H),14a(H),17a(H) steranes.
C29BBAA_______C29 2QR afip Sterane_______ [C29 20R afifi Sterane + C29 20R aaa Sterane]
Where:aaa refers to the 5a(H),14a(H),17a(H) sterane, and
A7-7
T/T+M
ct|3|3 refers to the 5a(H),14j3(H),17|3(H) sterane.
a
TRIOCR
C27STER
C28STER
C29STER
OL/HOP
GAM/HOP
BIS/HOP
DIA/REG
+a
Where:a = C28 20R Triaromatic Steroid b = C27 20R Triaromatic Steroid c = C29 20R 5a Monoaromatic Steroid d = C28 20R5a+C29 20R5B Monoaromatic Steroi or, if the peaks are resolved, d = C28 20R 5a Monoaromatic Steroid +
C29 20R 5B Monoaromatic Steroid
(C2o Triaromatic Steroid + C2i Triaromatic Steroid)
2^ Triaromatic Steroids
Where:ITriaromatic Steroids is the sum of ail peaks (named and unnamed)in the m/z231.1174 mass chromatogram.
______________ C27 20R aaa Sterane______________ (C2? 20R aaa Sterane + C28 20R aaa Sterane + C29 20R aaa Sterane)
______________C28 20R aaa Sterane______________ (C27 20R aaa Sterane + C28 20R aaa Sterane + C29 20R aaa Sterane)
______________C29 2QR aaa Sterane______________ (C27 20R aaa Sterane + C28 20R aaa Sterane + C29 20R aaa Sterane)
Cso Oleanane Cso Hopane
Cso Gammacerane Cso Hopane
Bisnorhopane Cso Hopane
C27 20S /3a Diasterane C29 20R aaa Sterane
Where:fkx Diasterane refers to the 13(3(H),17a(H) Diasterane(sometimes called "rearranged" sterane)
PREG/C27
TRI/HOP
TET/TRI
Ts/Tm
NOR/HOP
NEO/NOR
MOR/HOP
C32HSR
C35/C34
STER/PENT
TRIOCR2
___ Pregnane ___ C27 20R aaa Sterane
C23 Tricyclic C3o Hopane
C24* Tetracyclic C23 Tricyclic
27 18cE Trisnorhopane (Ts) C27 11 a Trisnorhopane (Tm)
29 Norhopane Cso Hopane
C29 18cE Neonorhopane C29 Norhopane
(C29 lip 21aNormoretane + 30 17/3 2toMoretane)
Norhopane + Cao Hopane)
32 22S Hopane[C32 22S Hopane + Cs2 22R Hopane]
22S Hopane + 35 22R Hopane)
Cn 22S Hopane + Q 22R Hopane)n=34
n=31
Sterane
2_j Pentacyclic
Where:'LSterane and 'LPentacyclic are defined as above.
M/M+T 1-CI7T+M)
TRIOCR1 -,C2o Triaromatic
Triaromatic + Czs 20S Triaromatic + C28 20R Triaromatic)
Triaromatic + C2i Triaromatic)Identified C26 - 28 Triaromatics
A7-9
/. Triaromatic TRI/MONO ^
Monoaromatic
Where:ZTriaromatic is the sum of peaks (named and unnamed)in the m/z 231.1174 mass chromatogram and ZMonoaromatic is the sum of peaks (named and unnamed)in the m/z 253.1956 mass chromatogram.
/. TriaromaticTRI/STER -=~j Sterane
Where:ZTriaromatic and ZSferane are defined as above.
A7-10
Tabl
e A
8. S
atur
ated
hyd
roca
rbon
gas
chr
omat
ogra
phy
data
for
Dom
anik
bitu
men
ext
ract
s.
See
par
amet
er k
ey a
t end
of t
able
.
Sam
ple
id
960
18
00
1
96018002
96018003
96018004
96018005
96018006
96
01
80
07
96018008
96018009
96018010
960
18
01
1
96018012
96018016
96018017
96018028
96018029
96018030
960
18
03
1
96018034
96
01
80
35
96018036
96018037
96018044
9601
8 05
396018054
96018055
96018056
96018058
Com
men
ts
mod
. bi
odeg
rade
d -0
-
mod
. bi
odeg
rade
d-0
-
mod
. bi
odeg
rade
d-0
--0
--0
--0
--0
--0
--0
-
mod
. bi
odeg
rade
d-0
--0
--0
-
min
or b
iode
grad
ed-0
--0
--0
--0
--0
-
seve
re b
iode
grad
atio
nm
od.
biod
egra
ded
seve
re b
iode
grad
atio
nse
vere
bio
degr
adat
ion
seve
re b
iode
grad
atio
nse
vere
bio
degr
adat
ion
Pr/P
h P
r/Ph
area
he
ight
1.07
1.61
1.54
1.59
1.15 1.
5
1.48
1.51
1.63
1.36
1.31
1.31
0.89
1.36
1.42
1.24
0.82
1.19
1.33 1.5
1.3
1.02
0.96
1.34
1.66
1.59 1.
7
1.33
1.62
1.61
1.59
1.62
1.49
1.41
1.41
1.16
1.53
1.43
1.37
0.8
71.
31
1.44
1.61
1.39
1.07
1.38
Pr/1
7 P
r/17
area
he
ight
2.4
8
0.77
1.94
0.7
6
3.3
7
0.9
7
1.04
1.22
0.98
1.29
1.24
1.67
5.8
31.
28
1.25
1.32
3.4
3
2.2
21.
94
1.19
2.9
3
3.6
4
2.4
2.85
0.6
2
1.95 0.6
4.2
7
0.7
6
0.9
4
1.12
0.77
1.13
0.99
1.38
5.2
31.
11
1.05
1.07
3.6
7
2.0
9
1.64
0.9
4
2.71
2.85
3.4
2
Ph
/18
are
a
4.5
8
0.62
1.99
0.62
23..6
4
0.76
1.04
1.18
0.77
1.18
1.07 1.
58.9
7
1.14
1.13
1.12
3.43
1.89
1.59
0.95
3.31
3.68
12.5
7
Ph/
18
heig
ht
3.31
0.44
1.57
0.43
17.2
5
0.54
0.71
0.84
0.56
0.86
0.79
1.11
6.64
0.87
0.83 0.
82.
72
1.63 1.
3
0.6
8
2.18
2.59
4.9
3
CPI
1
CPI
1
area
he
ight
1.01
1.02
1.01
1.15
10.9
31.
05
0.9
70.9
71.
01
1.07
1.09
1.01
0.9
6
0.5
7
1.07
1.01
1.01
1.01
1.05
0.9
7
0.9
71.
27
0.99
0.9
70.
990.9
7
1.01
0.99
1
0.56
1.05
CP
I 2
CP
I 2
are
a
heig
ht
1.02
1.02
1.15
1.01
0.93
0.99
0.96
1.03
1.09 1.1
1.03
0.96
0.52
1.06
1.02
1.02
1.03
0.9
80.9
8
1.14
0.9
4 10.
99
1.03
1
1.01
0.5
3
1.02
CP
I 3
CP
I 3
area
he
ight
1.62
0.
99
1.34
0.94
0.75
10.5
2
0.51
1.02
0.96
1.11
0.97
1.39
0.81
0.96
0.84
1.16
1.29
0.97
0.9
6
0.35
1.36
1.05
1.49
0.
92
1.29 0.9
0.81
0.95
0.8
4
0.69
1.01
0.97
11.
021.
771.
04
0.93
0.84
0.98
1.07
1.03
10.
42
1.33
1.02
CP
U
area 7.61
1.02 1.
90.
99
1.18
1.01
0.9
9
1.01
0.98
1.04
0.97
0.96
2.6
30.
99
0.95
0.97
0.99
0.98
0.91 0.
9
0.69
0.98
1.53
A8-
1
Tabl
e A
8. C
ontin
ued. CP
U
OE
P1
OE
P1
OE
P2
OE
P2
OE
P 3
O
EP
3
Sam
ple
id_
__
he
igh
t ar
ea
heig
ht
area
he
ight
ar
ea
heig
ht
9601
8 96
018
9601
8 96
018
96018
96018
9601
896
018
9601
896
018
9601
896
018
9601
896018
96018
9601
896
018
9601
896
018
9601
896
018
9601
896
018
9601
896
018
9601
896
018
9601
8
001
002
003
004
005
006
007
008
009
010
011
012
016
017
028
029
030
031
034
035
036
037
044
053
054
055
056
058
4.21
0.99
1.63
11. 1. 1. 1. 0. 0. 2. 0. 0. 0. 0. 0. 0.
231
08 041
01 96 95 35 98 98 1 95 95 94 970.58
0. 1.
97 33
4.11
0.
94
1.74
0.
910.
79 0.9
1.03
0.98 0.9
0.97
0.94
0.92
2.62 0.9
0.89 0.9
0.95
0.97
0.83
0.84
0.49
0.85
0.89
2.18
0.92
1.
51
0.93
0.84
0.93
1.13
1.02
0.94
0.96
0.94
0.94
2.01
0.93
0.95
0.98
0.93
0.95
0.88
0.92
0.42
0.84
0.69
1.25
1.03
1.06
0.97
0 0 0 1 1 1 0 1 0 0 0 1 1 0 0 0 1 0
.59
.99
0.5
.52
.01
.03
.08
.94
.15
.81
.92
.87
.12
.24
.99
.99
.34
.26
.84
1.17 1
1.04
0.96
0.65
0.98
0.78
0.71
1.02
0.99 1
1.01
1.48
1.04
0.91
0.88
0.97
1.05
1.04
1.04
0.39
1.24
0.82
0 1 1 1 0
1.2
.98
.11
.64
.05
.81
0.6
0 1 1 1 1 1 0 1
.84
.02
1.3
.25
.34
.59
.55
.57
.42
1.2
0.98
1.11
1.64
1.05
0.81 0.6
0.84
1.02 1.3
1.25
1.34
1.59
1.55
0.57
1.42
A8
-2
Tabl
e A
8. C
ontin
ued.
Sam
ple
id96
018
066
9601
8 06
7
9601
8 07
0
9601
8 07
1
96018072
9601
8 0
73
9601
8 07
6
96018079
9601
8 08
6
9601
8 08
896
018
089
9601
8 09
2
96018093
96018094
Com
men
tsse
vere
bio
degr
adat
ion
seve
re b
iode
grad
atio
n se
vere
bio
degr
adat
ion
seve
re b
iode
grad
atio
n m
od.
biod
egra
ded
seve
re b
iode
grad
atio
nse
vere
bio
degr
adat
ion
mod
. bi
odeg
rade
dm
od.
biod
egra
ded
-0-
min
or b
iode
grad
ed-0
--0
-
min
or b
iode
grad
ed
Pr/P
h P
r/Ph
area
he
ight
1.23 1.
6
1.67
1.58
1.27
1.51
1
1.22
1.31
1.57
1.49 1.
71.
31
1.61
1.06
1.27
Pr/1
7 ar
ea 6.79
3.9
4
53.4
42.1
93.
4
1.01
1.39
5.36
Pr/1
7 P
h/18
P
h/18
he
ight
ar
ea
heig
ht
8.6
8
6.05
38.8
91.
922.6
8
0.8
1.15
5.4
4
9.63
5.64
4.13 1.
73.
06
0.82
2.16
3.09
7.9
4
4.4
53.
011.
252.
380.
61
1.67
2.58
CP1
1 CP
1 1
area
he
ight
0.99 1.
10.
991.
04 0.9
0.9
7
0.95
1.01
0.95
1.03
0.96
0.99
CPI
2
CP
I 2
area
he
ight
0.93
1.14
0.98
1.06
0.91
0.96
0.92
1.03
0.93
1.05
0.9
4 1
CPI
3
CPI
3
area
he
ight
0.88
1.03
0.91
1.26
0.97
1.33
0.89
0.98
0.89
0.97
0.98
0.97 0.9
1.22
0.67
1
CP
U
area 0.85
1.02
1.21
1.06
0.99
0.96
0.97
1.01
A8-3
Tabl
e A
8. C
ontin
ued.
Sam
ple
9601
8
9601
8
9601
8
9601
8
9601
896
018
9601
8
9601
8
9601
8
9601
896
018
9601
8
id 066
067
070
071
072
073
076
079
086
088
089
092
CP
U
heig
ht
0. 0. 1. 0. 0.
86 99 15
1
96 96
OE
P1
area 1.
02
0.93
0.43
1.03
0.87
0.94
OE
P1
heig
ht 0.9
0.9
7
0.45
0.97
0.87
0.95
OE
P2
area 0.7
2
0 0 1, 0. 1,
.96
.69
.21
.92
.29
OE
P2
heig
ht
0.75
0.93
0.75
0.98
0.88
1.21
OE
P3
area 0 1 0. 1,
.85
.24
.96
.49
OE
P3
heig
ht
0.85
1.24
0.96
1.49
9601
8093
0.
97
0.95
0.
86
0.84
0.
72
0.78
0.
7896
018
094
0.97
1
0.97
0.
94
0.99
0.
88
0.88
A8-4
Not
es:
HM
W =
hig
h m
olec
ular
wei
ght
(gre
ater
than
n-C
22)
Pr/P
h =
pris
tane
/phy
tane
P
r/17
= p
rista
ne/n
-C17
P
h/18
= p
hyta
ne/n
-C18
CP
U =
CP
I 2
=
CP
I 3
=
CP
I 4
=
I tial
Inde
x om
inan
ce
1 ( C
n +
25 +
Cv +
Cz9
+C
3i
XI
2 '\C
24 +
C2
6 +
C2
8 +
C3
0 +
C3
2
OE
P =
( C
i +
6C
i +
2 +
Ci
+'^r
{ 4C
.- +
1+
4C
/ +
3 )
C2
5 +
C2
7 +
C2
9 +
C31 +
C 3
3 ^
'C2
4+
C2
6+
C2
8+
C3
0+
C3
2J
^0
1(1
9/9
)
OE
P1
OE
P 2
OC
D
C
1 ^C
X
2
V C
24 +
C26 +
C2
8 +
C3
0 +
C 3
2
+C
27 +
C2
9 +
C31 +
C 3
3 C
25
+ C
27
+ C
29
+ C
31
+ C
33
+C
26
+ C
28
+ C
30
+ C
32
+ C
34
Sca
lan
and
Sm
ith (
1970
)
OE
P 1
= c
ente
red
on n
-C27
(i
= 25
)O
EP
2 =
cen
tere
d on
n-C
29
(i =
27)
OE
P 3
= c
ente
red
on n
-C31
(i
= 29
)
Bra
y an
d E
vans
(19
61)
2x
C29
C28
+ C
30
Phi
lippi
(196
5)
(C23 +
C2
S+
C2
7)+
(C
2S
+C
27
+C
29
)
2 X
(C24 +
C26 +
C28)
base
d on
Mar
zi a
nd o
ther
s (1
993)
A8-
5