Studies in Surface Science and Catalysis

Advisory Editors: B. Delmon and J.T. Yates

Vol. 135

ZEOLITES AND MESOPOROUS MATERIALS AT THE DAWN OF THE 21STCENTURY Proceedings of the 13th International Zeolite Conference, Montpellier, France, 8-13 July 2001

Edited by

A. Galarneau, F. Di Renzo and F. Fajula Ecole Nationale Superieure de Chimie de Montpellier, 8 Rue de l'Ecole Normale, 34296 Montpellier Cedex 5, France

J. Vedrine University of Liverpool, Leverhulme Centre for Innovative Catalysis, P.O. Box 147, Liverpool L69 3BX, U.K.

2001 ELSEVIER Amsterdam - London - New York - Oxford - Paris - Shannon - Tokyo

SCIENTIFIC PROGRAMME AND CONTENT OF PROCEEDINGS

Plenaries

PL-1- Monday 9h - Ordered mesoporous materials - State of art and prospects F. Schüth 1

PL-2- Tuesday 8h30 - Clinoptilolite-heulandite: applications and basic research T. Armbruster 13

PL-3- Wednesday 8h30 - Evolution of extra-large pore materials M.E. Davis 29

PL-4- Thursday 8h30 - Evolution of refining and petrochemicals. What is the place of zeolites? C. Marcilly 37

PL-5- Friday 8h30 - Is electron microscope an efficient magnifying glass for micro-and meso- porous materials? O. Terasaki andT. Oshuna 61

Note: The Conference has been divided into 32 sessions. Each communication has a code S-M-x with S being the number of the Session, M = K (keynote), O (oral), P (poster) and x the number of the communication.

Keynotes

23-K-Ol- Monday 16h20 - Delaminated zeolites as active catalysts for processing large molecules A. Corma and V. Fornes 73

Ol-K-01- Tuesday 9h50 - Pentasii zeolites from Antartica: from mineralogy to zeolite science and technology A. Alberti, G. Cruciani, E. Galli, S. Merlino, R. Millini, S. Quartiert, G. Vezzalini andS. Zanardi 83

19-K-01- Tuesday 16h20 - Use of 1H NMR imaging to study the diffusion and co-diffusion of gaseous hydrocarbons in HZSM-5 catalysts P. N'Gokoli-Kekele, M.-A. Springuel-Huet, J.-L. Bonardet, J.-M. Dereppe andJ. Fraissard 93

21-K-01- Wednesday 9h50 - Zeolite-based nanocomposites: synthesis, characterization and catalytic applications B. V. Romanovsky 103

03-K-01- Thursday 16h20 - Application of combinatorial tools to the discovery and commercialization of microporous solids: facts and fiction J. Holmgren, D. Bern, M. Bricker, R. Gillepsie, G. Lewis, D. Akporiaye, I. Dahl, A. Karlsson, M. Plassen andR. Wendelbo 113

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30-K-Ol- Friday 9h50 - The local structures of transition metal oxides incorporated in zeolites and their unique photocatalytic properties M. Anpo andS. Higashimoto 123

Note: In the book are only the summaries of the Communications. The text of the Ml papers of oral and poster Communications are in the CD-ROM.

Programme of oral sessions (am 10h30-12h30 and pm 16h30-19h) Summary pages Monday am 12- In-situ spectroscopy and catalysis 133 06- Fundamentals of micelle templating 134 10-Host-guest chemistry 135 17-Principles of adsorption 137 Monday pm 23- Micro- and mesoporous materials in fine chemistry 138 02- Zeolite nucleation and growth 140 11-Post-synthesismodification 141 18- Adsorption and Separation processes 143 Tuesday am 24-New routes to hydrocarbon activation 145 01-Mineralogy of natural zeolites 146 15-Modellingandtheoretical studies A 148 07-New mesoporous molecular sieves 150 Tuesday pm 25-Conversionofaromatics 151 19- Diffusion: fundamental approach 153 16- Modelling and theoretical studies B 155 05- Synthesis of new materials 156 Wednesday am 26- Catalysis for oil refining 158 21- Nanocomposite fundamentals and applications 160 20-Zeolite membranes and films 161 09- Crystal structure determination 163 Thursdaypm 27- Selective oxidation and sulfur resistance 165 03-New methodsof zeolite synthesis 166 22-Advanced materials 168 32- Zeolite minerals and health sciences 170 Friday am 30-Environmental catalysis 171 28- Confinement and physical chemistry for catalysis 173 04- Isomorphous substitutions 175 14-Frameworks, cations, Clusters 176 Friday pm 29- New approaches to catalyst preparation 178 08- Syntheses with non-ionic Surfactants 179 31-Environment-friendly applications of zeolites 181 13- Frameworks and acid sites 182

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Posters should be hanged during the morning coffee break (10h-10h30).

Programme of poster sessions (14h00-16h30) Summarypages Monday 02-Zeolite nucleation and growth 185 06- Fundamentals of micelle templating 198 10- Host-guest chemistry 206 11-Post-synthesismodification 208 12- In-situ spectroscopy and catalysis 217 17-Principlesofadsorption 222 18- Adsorption and Separation processes 226 23- Micro- and mesoporous materials in fine chemistry 230 Tuesday 01-Mineralogy of natural zeolites 240 05- Synthesis of new materials 244 07- New mesoporous molecular sieves 249 15-Modellingandtheoretical studies A 256 16-Modellingandtheoretical studies B 264 19- Diffusion: fundamental approach 269 24- New routes to hydrocarbon activation 271 25- Conversionofaromatics 280 Wednesday 08- Syntheses with non-ionic Surfactants 284 09- Crystal structure determination 288 20-Zeolite membranes and films 291 21- Nanocomposite fundamentals and applications 296 26- Catalysis for oil refining 301 28- Confinement and physical chemistry for catalysis 307 29-New approaches to catalyst preparation 311 30-Environmental catalysis 320 Thursday 03-New methodsof zeolite synthesis 330 04- Isomorphous substitutions 335 13- Frameworks and acid sites 340 14- Frameworks, cations, Clusters 347 22-Advanced materials 359 27- Selective oxidation and sulfur resistance 365 31- Environment-friendly applications of zeolites 369 32- Zeolite minerals and health sciences 373

AUTHOR INDEX 377

SUBJECT INDEX 399