zeorora h zeorora - 日本ゼオン株式会社 · pdf filezeorora® hta is suit for...

1-6-2 Marunouchi, Chiyoda―ku, Tokyo, 100-8246, JapanTel:+81 -3-3216-0542 Fax:+81-3-3216-1303

http//www.zeon.co.jp/May 2015 0515010(SE)

Printed in Japan

Fluorinated Solvent

Specialty Chemicals Division.

ZEORORA®H ZEORORA®HTASNAP*: The Significant New Alternatives Policy (SNAP) Program is

United States Environmental Protection Agency (EPA)'s program to

evaluate and regulate substitutes for the ozone-depleting chemicals

that are being phased out under the stratospheric ozone protection

provisions of the Clean Air Act (CAA).

FOR MORE INFORMATION

lt is our pleasure to serve customers with high qualityproducts, technologies and the best services possible.

lf you have any questions about ZERORA®H orhave any interest in further information or samples,please contact as follows;

DisclaimersThe information contained herein is believed to be reliable, but no

representations. guarantees or warranties of any kind are made as to its

accuracy, suitability for particular applications or the results to be obtained

therefrom.

The information is based on laboratory work with small-scale equipment and

does not necessarily indicate end product performance.

Because of the variations in methods, conditions and equipment used

commercially in processing these materials, no warranties or guarantees are

made as to the suitability of the products for the application disclosed.

Full-scale testing and end product performance are the responsibility of the

ZEON CORPORATION shall not be liable for and the customer assumes all

risk and liability of any use of handling of any material beyond ZEON

CORPORATION direct control.

The SELLER MAKES NO WARRANTIES, EXPRESS OR IMPLIED INCLUDING,

BUT NOT LIMITED TO, THE IMPLIED WARRANTIES OF MERCHANTABILITY

AND FITNESS FOR APARTICULAR PURPOSE.

Nothing contained herein is to be considered as permission, recommendation,

nor as an inducement to practice any patented invention without permission

of the patent owner.

SNAP* identified ZEORORA-H as “acceptable (to be produced without limitation)” substitute for the ozone-depleting chemical

“ZEORORA®” is “Fluorinated Solvent” developed by Zeon & AIST*. This solvent is inflammable and cause little burden on the environment. “ZEORORA®-H” is used as solvent for many applications, and

“ZEORORA®-HTA” is cleaning solvent.AIST*: National Institute of advanced industrial; science and technology

「ゼオローラHシリーズ」の基本物性Comparison of Environmental Properties

Physical Properties of ZEORORA® H/HTA What is “ZEORORA-H®” ?

F FFFFF

「ZEORORA®H」

● Low volatilizing loss cut down Running cost

● applicable to vapor washing

● easily replaced with other 　fluorinated solvents or bromo 　solvents● easy to control

● Alternative to HCFC-225, nPB● Usable for washing silicone oil and fluorinated oil

● “ZERO” Ozone Depletion Potential● Short atmospheric lifetime and minimal Global Warming Potential

Inflammable

High voilingpoint

Onesolvent

Environmentallyfriendly

Highsolubility

Inflammable

ZEORORA®

Ｈ/HTA

High voilingpoint

Onesolvent

Highsolubility

Specific Gravity [25℃]

Boiling Point (℃）

Viscosity (cP）[25℃]

Surface Tension（mN/m）[25℃]

Specific Heat (cal/g・℃）[25℃]

Vapor Pressure (mmHg) [20℃]

Evaporative Latent Heat (cal/g) [boiling point]

Vapor Density (air=1)

Melting Point(℃）

Flash Point(℃）

Range of Explosion (vol%)[82℃]

Solubility of Water　(g/100g Solvent)

Solubility to Water　(g/100g Water)

Decomposition Test (ARC test)(℃)

KB value

SP value

1.5082.01.4719.2

0.30362.0 36.1 6.65

6.0～10.0None

4.9～12.90.1402

――208.3

1.5882.51.5619.6

0.28962.0 34.5 6.81 20.5NoneNone

0.08060.072

None(under 350℃）148.4

Neat Azeotrope

ZEORORA®ＨTAZEORORA®Ｈ

Category

Formula

Protcol

ODP (CFC-11=1)

HFE-347pc-f

CHF2CF2CH2CF3

HFE-449s1

C4F90CH3

HFC-365mfc

CF3CH2CF2CH3

HFC-43-10mee

CF3CF2CHFCHFCF3

HCFC-225cb

CCIF2CF2CHCIF

Montreal

ZEORORA®H

c-C5F7H3

Features of ZEORORA®-H & ZEORORA®-HTA

Cleaning performance of ZEORORA®-HTA

ZEORORA®-HTA, co-solvent

HCFC-225ZEORORA®HTA

Dissolving machining oil Light Heavy

Other Fluorinated Solvent; HFC, HFE

CleaningPerformonce

Atmosperic Lifetime(year)[IPCC AR5]

GWP 100years [IPCC AR5]

* calculated in accordance with IPCC AR5

ZEORORA® HTA is suit for degreasing engineering oil (light ‒ medium) with “single solvent washing”and supply higher level of cleaning finish in “co-solvent washing”

Applications of ZEORORA®H/HTA

Effect on elastomer & plastic

Washing System of ZEORORA® HTAToxic effects

Toxicity - Fish

Bioaccumulative potential

Acute Toxicity (Inhalation)

Acute Toxicity (Oral)

AMES study

Micronucleus study

Rat inhalation teratology study(1035ppm)

Skin Corrosion/Irritation

Eye damage/irritation

No concentration

LD50 = 14213 ppmV (Rat, 4 hours)

LD50 > 2g/kg (Rat)

Negative

Negative (Mouse)

Negative

No irritation

Washing● Object　;　Precision Metal Parts, Electronic Parts or 　elements, Ceramic Parts, Glass Parts or Lens, ● Purpose ; Degreasing, Removal of Liquid Crystal, 　Flux, Particles, Fluorocarbon Oil, Epoxy Resin (Uncured), Pigment.

Coating Process Solvent● Solute 　; Fluorocarbon Polymers● Purpose ; Water Repellent, Oil Repellent, Anti-fouling, Lubrication Property, Mold Releasability Property.

Admixture of Fluorine type solvent● Purpose ; Improving Cleaning, Non-flammable, Drying performance

Glass epoxy

Acrylic resin

Fluoro rubber

Silicone rubber

0.00.18.40.0-

－0.15.40.4

11.38.7

－0.40

2.5－0.4

Melting0.5

10.71.08.34.5

Test piece

Polyacetal

Polystyrene

Acrylonitrile butadiene styrene

Polycarbonate

Polyvinyl chloride soft

Polyethylene

Polypropylene

Polyvinyl chloride hard

Nylon 66

Polypropylene

0.00.03.40.00.10.5

－0.10.1

－0.30.1

0.30.10.10.2

－3.50.20.0

－1.90.00.3

Rate of dimensional variation(%)

Rate of weight variation(%)

Rate of weight variation(%)Test piece

Size of test piece：50×25×2mmWashing Condition ： Immersion in boiling solvent for 5 min ⇨ in cool bocth （25℃） for 5min ⇨ Vapor washing Measurement condition ： Measure in 5min after washing

Water Separator

Cycle PumpFilterHeater

Ultrasonic

RinsingWashing Vapor Washing～Drying

① ②

Single Solvent Washing with ZEORORA® HTA

Washing Method : ①Hot bath with Ultrasonic vibration remove smear.②Cool bath act as immersion rinsing and cool downing objects for enhancing vapor washing effectiveness.③Vapor Washing～Drying provide fineness finish.

Washing Method :①Hydrocarbon system solvent remove smear②Hot bath with Ultrasonic vibration rinse hydrocarbon system solvent.③Cool bath act as immersion rinsing and cool downing objects for enhancing vapor 　washing effectiveness.④Vapor Washing～Drying provide fineness finish.

Wahing System

Vapor Washing～Drying Rinsing

超音波UltrasonicUltrasonic

Co-solvent washing Ultrasonic washing

Co-solvent Washing ZEORORA® HTA

Co-solventseparator

HeaterH

ZEORORA®HTA

ZEORORA®HTAHydrocarbon system solvent

Water Separator

distillregeneration

Solvent of Reaction, Polymerization, ElectronicsMaterials.● Polymerization Solvent of Fluorocarbon Polymers ● Organic Reaction Solvent, Extract Solvent.● Electrolyte Solvent

Ultrasonic① ② ③

* Co-solvent washing: washing with hydrocarbon system solvent (for example), rinsing and vapor washing with ZEORORA® HTA.

ZEORORA® HTA is suit for degreasing engineering oil (light ‒ medium) with “single solvent washing”and supply higher level of cleaning finish in “co-solvent washing”

Applications of ZEORORA®H/HTA

Effect on elastomer & plastic

Washing System of ZEORORA® HTAToxic effects

Toxicity - Fish

Bioaccumulative potential

Acute Toxicity (Inhalation)

Acute Toxicity (Oral)

AMES study

Micronucleus study

Rat inhalation teratology study(1035ppm)

Skin Corrosion/Irritation

Eye damage/irritation

No concentration

LD50 = 14213 ppmV (Rat, 4 hours)

LD50 > 2g/kg (Rat)

Negative

Negative (Mouse)

Negative

No irritation

Washing● Object　;　Precision Metal Parts, Electronic Parts or 　elements, Ceramic Parts, Glass Parts or Lens, ● Purpose ; Degreasing, Removal of Liquid Crystal, 　Flux, Particles, Fluorocarbon Oil, Epoxy Resin (Uncured), Pigment.

Coating Process Solvent● Solute 　; Fluorocarbon Polymers● Purpose ; Water Repellent, Oil Repellent, Anti-fouling, Lubrication Property, Mold Releasability Property.

Admixture of Fluorine type solvent● Purpose ; Improving Cleaning, Non-flammable, Drying performance

Glass epoxy

Acrylic resin

Fluoro rubber

Silicone rubber

0.00.18.40.0-

－0.15.40.4

11.38.7

－0.40

2.5－0.4

Melting0.5

10.71.08.34.5

Test piece

Polyacetal

Polystyrene

Acrylonitrile butadiene styrene

Polycarbonate

Polyvinyl chloride soft

Polyethylene

Polypropylene

Polyvinyl chloride hard

Nylon 66

Polypropylene

0.00.03.40.00.10.5

－0.10.1

－0.30.1

0.30.10.10.2

－3.50.20.0

－1.90.00.3

Rate of weight variation(%)

Rate of weight variation(%)Test piece

Size of test piece：50×25×2mmWashing Condition ： Immersion in boiling solvent for 5 min ⇨ in cool bocth （25℃） for 5min ⇨ Vapor washing Measurement condition ： Measure in 5min after washing

Water Separator

Cycle PumpFilterHeater

Ultrasonic

RinsingWashing Vapor Washing～Drying

① ②

Single Solvent Washing with ZEORORA® HTA

Washing Method : ①Hot bath with Ultrasonic vibration remove smear.②Cool bath act as immersion rinsing and cool downing objects for enhancing vapor washing effectiveness.③Vapor Washing～Drying provide fineness finish.

Washing Method :①Hydrocarbon system solvent remove smear②Hot bath with Ultrasonic vibration rinse hydrocarbon system solvent.③Cool bath act as immersion rinsing and cool downing objects for enhancing vapor 　washing effectiveness.④Vapor Washing～Drying provide fineness finish.

Wahing System

Vapor Washing～Drying Rinsing

超音波UltrasonicUltrasonic

Co-solvent washing Ultrasonic washing

Co-solvent Washing ZEORORA® HTA

Co-solventseparator

HeaterH

ZEORORA®HTA

ZEORORA®HTAHydrocarbon system solvent

Water Separator

distillregeneration

Solvent of Reaction, Polymerization, ElectronicsMaterials.● Polymerization Solvent of Fluorocarbon Polymers ● Organic Reaction Solvent, Extract Solvent.● Electrolyte Solvent

Ultrasonic① ② ③

* Co-solvent washing: washing with hydrocarbon system solvent (for example), rinsing and vapor washing with ZEORORA® HTA.

Technical Support

Decrease Emission and Cost

Daphne punch oil

G-6050

G-6040

P-1600

Castor oil

Olive oil

25℃1002.83.0×5.9××

1005.26.7×9.3××

40℃1003.33.7×7.2××

25℃1001.92.3×5.8××

1004.45.6×8.6××

40℃1002.73.5×6.8××

25℃1003.52.91004.50.60.2

25℃100100100100100100100

1001001001001006.93.8

40℃1005.43.61005.41.00.7

HFE-449s1＋IPAHFE-449s1ZEORORA®ＨTAHCFC-225Engineering oil

Daphne punch oil G-6050G-6040C-126P-1600Castor oilOlive oil

Products

IDEMITSU KOSAN CO.,LTD.NIHON KOHSAKUYU CO.,LTD.NIHON KOHSAKUYU CO.,LTD.NIHON KOHSAKUYU CO.,LTD.JX NIPPON OIL & ENERGYreagent of KANTO CHEMICAL CO.,INC.reagent of KANTO CHEMICAL CO.,INC.

Blanking oil Blanking oil Blanking oil Cutting fluidsAnti-rust oilVegetable oilVegetable oil

1.063.435.1720

Extreme pressure agent (phosphorus) Oiliness agent, Chlorine compound, Rust prevention additive, Anti-corrosive agent Chlorine compound Semidry, Fatty acid ester

Maker Category Kinetic Viscosity (40℃） Add-in material

AfterBefore

Silicone Grease ： Shin-Etsu G40　Ultrasonic, 50℃ｘ1min

Epoxy resin adhesives applied to a slide was left for 24 hours before washing test（uncured）Ultrasonic, 20℃ｘ10seconds

ZEORORA®HTA

HFE-449s1＋IPA

HFC-43-10mee＋EtOH

n-Decane

HCFC-225

Ethyl acetate

Result

Solved

Not Solved

Solved

JU-R2S(Maker: KOKI)

JU-41P(Maker: KOKI)

JU-100-5(Maker: KOKI)

ZEORORA®HTA HFE-449s1 HCFC-225

ZEORORA®-HTA consumption achive less than 1/3 of HCFC-225. Low consumption rate contribute to “Saving Cost” and “Environmental Conservation”.

Comsumption at reflux condition

Applications

Solubility to oil

Washing of silicon grease

Washing of epoxy resin

Methylene chlorideHFE-569sf2HFE-449s1

HFC43-10meeHCFC-225

ZEORORA®HTA

0 50 100 150 200 350300250

Relative consumption rate

We set up solvent washing laboratory in Zeon R&D center, provide technical support and washing evaluation.

R&D center Solvent washing room

grams of oil dissolve in 100 grams of solvent

“100” means “the oil is compatible to the solvent”

Printer roller BearingLead frame

HD parts Precision metal partsPolygon mirror

boilingpoint

Technical Support

Decrease Emission and Cost

Daphne punch oil

G-6050

G-6040

P-1600

Castor oil

Olive oil

25℃1002.83.0×5.9××

1005.26.7×9.3××

40℃1003.33.7×7.2××

25℃1001.92.3×5.8××

1004.45.6×8.6××

40℃1002.73.5×6.8××

25℃1003.52.91004.50.60.2

25℃100100100100100100100

1001001001001006.93.8

40℃1005.43.61005.41.00.7

HFE-449s1＋IPAHFE-449s1ZEORORA®ＨTAHCFC-225Engineering oil

Daphne punch oil G-6050G-6040C-126P-1600Castor oilOlive oil

Products

IDEMITSU KOSAN CO.,LTD.NIHON KOHSAKUYU CO.,LTD.NIHON KOHSAKUYU CO.,LTD.NIHON KOHSAKUYU CO.,LTD.JX NIPPON OIL & ENERGYreagent of KANTO CHEMICAL CO.,INC.reagent of KANTO CHEMICAL CO.,INC.

Blanking oil Blanking oil Blanking oil Cutting fluidsAnti-rust oilVegetable oilVegetable oil

1.063.435.1720

Extreme pressure agent (phosphorus) Oiliness agent, Chlorine compound, Rust prevention additive, Anti-corrosive agent Chlorine compound Semidry, Fatty acid ester

Maker Category Kinetic Viscosity (40℃） Add-in material

AfterBefore

Silicone Grease ： Shin-Etsu G40　Ultrasonic, 50℃ｘ1min

Epoxy resin adhesives applied to a slide was left for 24 hours before washing test（uncured）Ultrasonic, 20℃ｘ10seconds

ZEORORA®HTA

HFE-449s1＋IPA

HFC-43-10mee＋EtOH

n-Decane

HCFC-225

Ethyl acetate

Result

Solved

Not Solved

Solved

JU-R2S(Maker: KOKI)

JU-41P(Maker: KOKI)

JU-100-5(Maker: KOKI)

ZEORORA®HTA HFE-449s1 HCFC-225

ZEORORA®-HTA consumption achive less than 1/3 of HCFC-225. Low consumption rate contribute to “Saving Cost” and “Environmental Conservation”.

Comsumption at reflux condition

Applications

Solubility to oil

Washing of silicon grease

Washing of epoxy resin

Methylene chlorideHFE-569sf2HFE-449s1

HFC43-10meeHCFC-225

ZEORORA®HTA

0 50 100 150 200 350300250

Relative consumption rate

We set up solvent washing laboratory in Zeon R&D center, provide technical support and washing evaluation.

R&D center Solvent washing room

grams of oil dissolve in 100 grams of solvent

“100” means “the oil is compatible to the solvent”

Printer roller BearingLead frame

HD parts Precision metal partsPolygon mirror

boilingpoint

1-6-2 Marunouchi, Chiyoda―ku, Tokyo, 100-8246, JapanTel:+81 -3-3216-0542 Fax:+81-3-3216-1303

http//www.zeon.co.jp/May 2015 0515010(SE)

Printed in Japan

Fluorinated Solvent

Specialty Chemicals Division.

ZEORORA®H ZEORORA®HTASNAP*: The Significant New Alternatives Policy (SNAP) Program is

United States Environmental Protection Agency (EPA)'s program to

evaluate and regulate substitutes for the ozone-depleting chemicals

that are being phased out under the stratospheric ozone protection

provisions of the Clean Air Act (CAA).

FOR MORE INFORMATION

lt is our pleasure to serve customers with high qualityproducts, technologies and the best services possible.

lf you have any questions about ZERORA®H orhave any interest in further information or samples,please contact as follows;

DisclaimersThe information contained herein is believed to be reliable, but no

representations. guarantees or warranties of any kind are made as to its

accuracy, suitability for particular applications or the results to be obtained

therefrom.

The information is based on laboratory work with small-scale equipment and

does not necessarily indicate end product performance.

Because of the variations in methods, conditions and equipment used

commercially in processing these materials, no warranties or guarantees are

made as to the suitability of the products for the application disclosed.

Full-scale testing and end product performance are the responsibility of the

ZEON CORPORATION shall not be liable for and the customer assumes all

risk and liability of any use of handling of any material beyond ZEON

CORPORATION direct control.

The SELLER MAKES NO WARRANTIES, EXPRESS OR IMPLIED INCLUDING,

BUT NOT LIMITED TO, THE IMPLIED WARRANTIES OF MERCHANTABILITY

AND FITNESS FOR APARTICULAR PURPOSE.

Nothing contained herein is to be considered as permission, recommendation,

nor as an inducement to practice any patented invention without permission

of the patent owner.

SNAP* identified ZEORORA-H as “acceptable (to be produced without limitation)” substitute for the ozone-depleting chemical

zeorora h zeorora - 日本ゼオン株式会社 · pdf filezeorora® hta is suit for...

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