annexure- additional...

ANNEXURES

1 PLANT LAYOUT

2 LIST OF PRODUCTS WITH PRODUCTION CAPACITY AND RAW MATERIALS

3 BRIEF MANUFACTRING PROCESS, CHEMICAL REACTION AND MASS

BALANCE WITH FLOW DIAGRAM

4 WATER CONSUMPTION AND EFFLUENT GENERATION WITH SEGREGATION

OF EFFLUENT STREAMS

5 DETAILS OF PROPOSED EFFLUENT TREATMENT PLANT

6 DETAILS OF HAZARDOUS SOLID WASTE MANAGEMENT AND DISPOSAL

7 DETAILS OF AIR POLLUTION CONTROL MEASURES

8 DETAILS OF HAZARDOUS CHEMICAL STORAGE FACILITY

9 SOCIO - ECONOMIC IMPACTS

10 PROPOSED TERMS OF REFERENCES

11 GIDC WATER SUPPLY LETTER

12 TREATED EFFLUENT DISCHARGE – NCT MEMBER CERTIFICATE

13 BEIL MEMBERSHIP CERTIFICATE

14 GIDC PLOT ALLOTMENT LETTER

15 COPY OF CONSENT TO OPERATE

ANNEXURE: 1

PLANT LAYOUT

ANNEXURE: 2

LIST OF PRODUCTS WITH PRODUCTION CAPACITY

Sr. No.

Existing Production in MT / Month Proposed Production in MT / Month

Products Name Quantity Products Name Total Quantity After Proposed

1 Sulphanilic Acid 40 Manufacturing, Formulation, Drying, Mixing & Packing of OPTICAL WHITENING AGENT/OPTICAL BRIGHTENER

3140

2 Formulation & Packing of OPTICAL WHITENING AGENT/OPTICAL BRIGHTENER Formulation including additives (Marketable Basis)

2500

3 Optical Whitening Agent / Optical Brightener (On 100% Basis)

600

4 -- -- Manufacturing, Formulation, Mixing & Packing of Textile and Leather Chemicals : Binders, Auxiliaries Chemicals for tanning & finishing agents such as textile, dispersions, lacquers, pigments, lepton colours.

1500

5 -- -- Floating agents 60

6 -- -- Spray Drying, formulation and Packing of Water Treatment Chemicals & Paper Dyes ( Sokalan, Magnafloc, Pergasol & Irgalite)

1750

7 -- -- R&D Products on Pilot Plant Scale

2

Total 3100 -- 6452

Product List along with CAS Number. Sr. No.

NAME OF PRODUCTS CAS No.

A Manufacturing, Formulation, Drying, Mixing & Packing of OPTICAL WHITENING AGENT/OPTICAL BRIGHTENER

--

1 Tinopal DMA-X 16090-02-1

Tinopal DMA-X CONC

2 Tinopal BA 4193-55-9

Tinopal BMK

Tinopal UP LIQUID

Tinopal BHT HC LIQUID

Tinopal NP SLURRY

3 Tinopal ABP-X HC 16470-24-9

Tinopal ABP-A LIQUID

Tinopal ABA LIQUID

4 Tinopal 5BM-GX 13863-31-5

5 Tinopal SFP 41098-56-0

Tinopal SPP-Z LIQUID

Tinopal SHP LIQUID

Tinopal AS LIQUID

6 Tinopal ASP LIQUID 67786-25-8

7 Tinopal BOP EXTRA 12224-02-1

B Manufacturing, Formulation, Mixing & Packing of Textile and Leather Chemicals : Binders, Auxiliaries Chemicals for tanning & finishing agents such as textile, dispersions, lacquers, pigments, lepton colours.

--

1 Cyclanon Clear ECO Plus / New

Mictures of 149-44-0 2634-33-5 Cyclanon Wff XC-W New

3 Dekol Wff RSA / SN Mixtures of 112-34-5 110-16-7 55965-84-9

2 Densotan CP Mictures of 111-46-6

Ekoline Easy Care

Fixapret Cat F-M 50-00-0

Fixapret Resin F-ECO

3 Heliz.Binder CFF Mixtures of 136132-73-5 9043-30-5

4 Kieralon Antiper FB-PK Mixtures of 60875-66-1 69011-36-5 67-63-0 157627-86-6 111190-40-0 157627-86-6 126-30-7 2809-21-4 110-16-7

Kieralon Antiper X-CP

Kieralon Desize HP

Kieralon Wash F-ALB

Kieralon Wash F-ALB Plus

Kieralon F-ALB Plus

Kieralon Wash JET-B

Kieralon Wash FB-OL New

Kieralon Wash FB-OLS New

Kieralon Wash FB-XC-J Conc.

Kieralon Wash JET-B / Conc.

Kieralon Wash MFB

5 Lufibrol Extr CP Mixtures of 2399-85-1 5064-31-3 2399-85-1 77-92-9 2809-21-4 55965-84-9

Lufibrol Extr SE

Lufibrol Extr MSD

6 Perapret Add F-PEB Mixtures of 69011-36-5 1310-58-3 69011-36-5 1310-58-3

Perapret Add TX 2517

7 Prestogen Stab D Mixtures of 140-01-2 7664-93-9

Prestogen Stab FB-E

Prestogen Stab FB-PL

8 Primasol Deaer NF Mixtures of 298-07-7 78-42-2 4971-47-5 34590-94-8 166736-08-9 157627-86-6 104-76-7

Primasol Deaer NF New

9 Rongalit Dcharge ST Lq. Mixtures of 149-44-0 7664-41-7

10 Siligen Soft FB-NCE Mixtures of 93-82-3 2634-33-5 112-34-5 69011-36-5 75718-16-0

Siligen Soft SIH

Siligen Soft SIS / YS

Siligen Soft TX HQS 68153-35-5 67-63-0

11 Uniperol Buffer PC Mixtures of 5949-29-1 64-18-6 68603-87-2 55965-84-9 26635-92-7 500-015-7 69011-36-5 9004-96-0

Uniperol Buffer TX P-DP

Uniperol Level RD

Uniperol Level SE

Uniperol Level SF ECO

12 Tamol FB LI Mixture of 91-20-3 7664-93-9 50-00-0 1310-73-2

Tamol M (REF)

Tamol NNOL Mixture of 108-95-2 50-00-0 57-13-6 7664-93-9

Tamol XNL Mixture of 124-04-9 1132-18-5 1310-73-2 50-70-4

13 Relugan D / DI Mixture of 124-04-9 1132-18-5 1310-73-2 50-70-4 50-00-0 7631-90-5

Relugan SLF / DLF Mixture of 50-00-0 1310-73-2 57-13-6 7631-90-5 64-18-6 29405-16-1

14 Basyntan AN Mixture of 108-95-2 1310-73-2 57-13-6 117985-54-3 102980-04-1 50-00-0 7757-82-6 1336-21-6 108-78-1

Basyntan ANF

Basyntan AN Condensate

Basyntan DLE

Basyntan DX

Basyntan FB DI

Basyntan FB. P

Basyntan XA

C Floating agents Mixture of 9003-11-6 64742-47-8 68526-89-6.

D Spray Drying, formulation and Packing of Water Treatment Chemicals & Paper Dyes ( Sokalan, Magnafloc, Pergasol & Irgalite)

--

E R&D Products on Pilot Plant Scale

--

LIST OF RAW MATERIALS:

Sr. No.

Name of the product

Material CAS Number Quantity (MT/Month)

Existing Proposed Total

A. Manufacturing, Formulation, Drying, Mixing & Packing of OPTICAL WHITENING AGENT/OPTICAL BRIGHTENER

1 Tinopal DMA-X

Aniline 62-53-3 21.5 0.0 21.5

Baykanol 1.72 0.0 1.72

Cyanuric Chloride 108-77-0 43.0 0.0 43.0

DASDA 81-11-8 43.645 0.0 43.65

Hyflo 68855-54-9 0.645 0.0 0.65

Morpholine 110-91-8 19.78 0.0 19.78

Sodium Chloride 7647-14-5 24.94 0.0 24.94

Sodium Hydroxide 1310-73-2 58.05 0.0 58.05

OT 70% 63148-62-9 0.065 0.0 0.06

Soda Ash 497-19-8 22.145 0.0 22.15

2 Tinopal DMA-X Conc

Aniline 62-53-3 54.0 0.0 54.0

Baykanol 1.62 0.0 1.62


DASDA 81-11-8 109.62 0.0 109.62

Hyflo 68855-54-9 0.216 0.0 0.22

Morpholine 110-91-8 49.68 0.0 49.68

Sodium Chloride 7647-14-5 38.88 0.0 38.88


OT 70% 63148-62-9 0.162 0.0 0.16

Soda Ash 497-19-8 38.88 0.0 38.88

3 Tinopal BA

Aniline 62-53-3 0.105 0.0 0.11


DASDA 81-11-8 0.224 0.0 0.22

DEA 85% 111-42-2 0.192 0.0 0.19

Hydrochloric Acid 7647-01-0 0.325 0.0 0.33

Hyflo 68855-54-9 0.003 0.0 0.0

Sodium Chloride 7647-14-5 0.211 0.0 0.21


OT 70% 63148-62-9 0.00038 0.0 0.0

Soda Ash 497-19-8 0.068 0.0 0.07

4 Tinopal BMK

Aniline 62-53-3 7.312 0.0 7.31


DASDA 81-11-8 14.848 0.0 14.85

DEA 85% 111-42-2 9.28 0.0 9.28

Hyflo 68855-54-9 0.16 0.0 0.16

Sodium Chloride 7647-14-5 18.32 0.0 18.32


OT 70% 63148-62-9 0.024 0.0 0.02

Soda Ash 497-19-8 5.216 0.0 5.22

STPP 7758-29-5 0.448 0.0 0.45

5 Tinopal UP liquid

Aniline 62-53-3 1.402 0.0 1.4


DASDA 81-11-8 2.981 0.0 2.98

DEA 85% 111-42-2 2.558 0.0 2.56


Hyflo 68855-54-9 0.033 0.0 0.03

Hyflo 68855-54-9 0.999 0.0 1.0

Sodium Chloride 7647-14-5 0.150 0.0 0.15


OT 70% 63148-62-9 0.005 0.0 0.0

Soda Ash 497-19-8 0.899 0.0 0.9

Urea 57-13-6 7.328 0.0 7.33

6 Tinopal BHT HC

Aniline 62-53-3 3.368 0.0 3.37


DASDA 81-11-8 7.16 0.0 7.16

DEA 85% 111-42-2 5.16 0.0 5.16


Hyflo 68855-54-9 0.08 0.0 0.08

Sodium Chloride 7647-14-5 0.4 0.0 0.4


OT 70% 63148-62-9 0.012 0.0 0.01

Soda Ash 497-19-8 2.16 0.0 2.16

TEA 121-44-8 8.0 0.0 8.0

Urea 57-13-6 8.0 0.0 8.0

7 Tinopal NP Slurry

Aniline 62-53-3 2.105 0.0 2.11


DASDA 81-11-8 4.475 0.0 4.48

DEA 85% 111-42-2 3.84 0.0 3.84

Glutaldhyde 111-30-8 0.095 0.0 0.1

Hyflo 68855-54-9 0.05 0.0 0.05

Sodium Chloride 7647-14-5 0.225 0.0 0.23


OT 70% 63148-62-9 0.008 0.0 0.01

Preventol 2634-33-5 0.26 0.0 0.26

Soda Ash 497-19-8 1.35 0.0 1.35

Xanthan gum 11138-66-2 0.095 0.0 0.1

8 Tinopal ABP-X HC


DASDA 81-11-8 6.092 0.0 6.09

DEA 85% 111-42-2 4.352 0.0 4.35

Hyflo 68855-54-9 0.088 0.0 0.09

Sodium Chloride 7647-14-5 8.4 0.0 8.4


OT 70% 63148-62-9 0.009 0.0 0.01

Soda Ash 497-19-8 3.6 0.0 3.6

Sulphanilic acid 121-57-3 5.748 0.0 5.75

9 Tinopal ABP-A


DASDA 81-11-8 21.451 0.0 21.45

DEA 85% 111-42-2 12.901 0.0 12.9

Glutaldhyde 111-30-8 5.4 0.0 5.4

Hyflo 68855-54-9 0.66 0.0 0.66


OT 70% 63148-62-9 0.034 2.0 2.03

Preventol 2634-33-5 0.75 3.0 3.75

Soda Ash 497-19-8 15.676 0.0 15.68


10 Tinopal ABA


DASDA 81-11-8 0.715 0.0 0.72

DEA 85% 111-42-2 0.43 0.0 0.43

Hyflo 68855-54-9 0.022 0.0 0.02


OT 70% 63148-62-9 0.001 0.0 0.0

Soda Ash 497-19-8 0.523 0.0 0.52


11 Tinopal 5BM

Aniline 62-53-3 10.195 0.0 10.19


DASDA 81-11-8 20.696 0.0 20.7

DAXAD 60L 0.408 0.0 0.41

Hyflo 68855-54-9 0.306 0.0 0.31

Sodium Chloride 7647-14-5 16.842 0.0 16.84


N-Methylethanolamine

109-83-1 8.849 0.0 8.85

OT 70% 63148-62-9 0.031 0.0 0.03

Soda Ash 497-19-8 6.117 0.0 6.12

12 Tinopal SFP

2,5 SA 98-44-2 0.555 0.0 0.56

Bay Pure 0.014 0.0 0.01


DASDA 81-11-8 0.376 0.0 0.38

Diethyl amine 109-89-7 0.163 0.0 0.16

Hyflo 68855-54-9 0.006 0.0 0.01

Sodium Chloride 7647-14-5 0.875 0.0 0.88


OT 70% 63148-62-9 0.001 0.0 0.001

Soda Ash 497-19-8 0.146 0.0 0.15

13 Tinopal SPP-Z

2,5 SA 98-44-2 6.66 0.0 6.66


DASDA 81-11-8 4.185 0.0 4.19

Diethyl amine 109-89-7 1.8 0.0 1.8

Hyflo 68855-54-9 0.096 0.0 0.1


OT 70% 63148-62-9 0.007 0.0 0.01

Soda Ash 497-19-8 0.252 0.0 0.25

14 Tinopal SHP

2,5 SA 98-44-2 2.22 0.0 2.22


DASDA 81-11-8 1.502 0.0 1.5

Diethyl amine 109-89-7 0.65 0.0 0.65

Hyflo 68855-54-9 0.022 0.0 0.02

Sodium Chloride 7647-14-5 3.5 0.0 3.5


OT 70% 63148-62-9 0.002 0.0 0.0

PEG 1500 25322-68-3 9.375 0.0 9.38

Soda Ash 497-19-8 0.585 0.0 0.59

15 Tinopal AS

2,5 SA 98-44-2 5.975 0.0 5.98


DASDA 81-11-8 3.755 0.0 3.75

Diethyl amine 109-89-7 1.615 0.0 1.61

Hyflo 68855-54-9 0.086 0.0 0.09


OT 70% 63148-62-9 0.006 0.0 0.01

Soda Ash 497-19-8 1.574 0.0 1.57

TEA 121-44-8 1.023 0.0 1.02

16 Tinopal ASP


DASDA 81-11-8 4.291 0.0 4.29

DDA 3.699 0.0 3.70

Hyflo 68855-54-9 0.067 0.0 0.07


OT 70% 63148-62-9 0.007 0.0 0.01

Soda Ash 497-19-8 3.078 0.0 3.08


17 Tinopal BOP Extra


DASDA 81-11-8 2.874 0.0 2.87

DEA 85% 111-42-2 2.86 0.0 2.86

Metanilic Acid 121-47-1 2.896 0.0 2.9

Sodium Chloride 7647-14-5 15.92 0.0 15.92


OT 70% 63148-62-9 0.005 0.0 0.01

Soda Ash 497-19-8 1.98 0.0 1.98

B. Textile and Leather Chemicals : Binders, Auxiliaries Chemicals for tanning & finishing agents such as textile, dispersions, lacquers, pigments, lepton colours.

1 Cyclanon Clear ECO Plus

- - -

Sodium Formaldehyde Sulfoxylate

149-44-0 0.0 8.0 8.0

2 Cyclanon Wff XC-W New

- - -

Dekol Dis SN 9003-04-7 0.0 2.46 2.46

ACTICIDE MBS Mixture of 2634-33-5 2682-20-4

0.0 0.06 0.06

Cyclanon 66 Mixture of 2682-20-4 7732-18-5

0.0 6.42 6.42

GLUCONIC ACID 526-95-4 0.0 0.72 0.72

DETPMPA (HEPTASODIUM SALT)

Mixture of 22042-96-2 7647-14-5

0.0 0.63 0.63

3 Dekol Wff RSA - - -

BUTYLDIGLYCOL 112-34-5 0.0 0.2 0.2

Luviskol K30 Powder

9003-39-8 0.0 1.0 1.0

Sokalan CP 5 52255-49-9 0.0 1.0 1.0

ACTICIDE MV 55965-84-9 0.0 0.16 0.16

4 Densotan CP 150KG 1H2

- - -


111-46-6 0.0 5.5 5.5

5 Ekoline Easy Care

- - -


111-46-6 0.0 5.4 5.4

6 Fixapret Cat F-M

- - -

AMMONIUM CHLORIDE

12125-02-9 0.0 0.28 0.28

MAGN CHLORO HEX HYD

7786-30-3 0.0 9.72 9.72


7 Fixapret Resin F-ECO

- - -

Glyoxal 172-22-2 0.0 5.84 5.84

Diethylene glycol 111-46-6 0.0 5.18 5.18

Sodium Hydroxide 1310-73-2. 0.0 0.44 0.44

TG Urea 57-13-6 0.0 2.42 2.42

PHOSPHORIC ACID

7664-38-2. 0.0 0.44 0.44

Formaldehyde 50-00-0 0.0 5.68 5.68

8 Heliz.Binder CFF

- - -

Luprintol Emuls PE 136132-73-5 0.0 0.45 0.45

Heliz Binder Tow 111-46-6 0.0 8.3 8.3

TRI ALCHOHOL 3 EO MOLE

068131-40-8 0.0 0.35 0.35

9 Kieralon Antiper FB-PK

- - -

Sodium Carbonate 497-19-8 0.0 0.08 0.08

Sodium Thiosulp Pentahydrate

10102-17-7 0.0 9.02 9.02

10 Kieralon Antiper X-CP

- - -

Sodium Chloride 7647-14-5 0.0 3.8 3.8

OXY-GONE T400 Mixture of 9001-05-2 7647-14-5 61-32-04-3 13472-35-0

0.0 0.9 0.9

PROXEL XL 2 2634-33-5 0.0 0.02 0.02

11 Kieralon Desize HP

- - -

Aquazym Ultra 9000-90-2 0.0 0.8 0.8

Sorbitol solution 50-70-4 0.0 2.0 2.0

Proxel XL. 2634-33-5 0.0 0.02 0.02

12 Kieralon Wash F-ALB

- - -

BUTYLDIGLYCOL 112-34-5 0.0 2.1 2.1

SEQUCEL HD (DEQUEST 2010)

2809-21-4 0.0 1.5 1.5

TRI ALCHOHOL 5 ED MOLE

9043-30-5 0.0 4.5 4.5

TEGO Antifoam 556-67-2 0.0 0.15 0.15

793

Isopropanol 67-63-0 0.0 0.9 0.9

Lutensol Tex XP 50 160875-66-1 0.0 12.0 12.0

13 Kieralon Wash F-ALB Plus

- - -

Amkal NX 27213-90-7 0.0 0.05 0.05

FATTY ALCOHOL 6 EO

68002-97-1. 0.0 1.5 1.5

Lutensol XP 80 160875-66-1 0.0 2.0 2.0

TEGO Antifoam 793

556-67-2 0.0 0.06 0.06

14 Kieralon F-ALB Plus

- - -

Lutensol XP 80 160875-66-1 0.0 1.5 1.5

Lutensol TO 8 69011-36-5 0.0 1.5 1.5

Lutensol TO 6 69011-36-5 0.0 1.0 1.0

Hansa AFC 5060 SP

0.0 0.08 0.08

15 Kieralon Wash JET-B

- - -

TEGO Antifoam 793

0.0 0.06 0.06

Amkal NX 27213-90-7 0.0 0.05 0.05

FATTY ALCOHOL 6 EO

68002-97-1. 0.0 1.5 1.5

Lutensol XP 80 160875-66-1 0.0 2.0 2.0

16 Kieralon Wash FB-OL New

- - -

Amkal NX 25KG 27213-90-7 0.0 0.1 0.1

FATTY ALCOHOL 6 EO

68002-97-1. 0.0 6.5 6.5

17 Kieralon Wash FB-OLS New

- - -

Lutensol TO 6 69011-36-5 0.0 4.5 4.5

Amkal NX 27213-90-7 0.0 0.08 0.08

18 Kieralon Wash FB-XC-J Conc.

- - -

TEGO Antifoam 793

556-67-2 0.0 0.08 0.08

Lutensol Tex XL 160875-66-1 0.0 8.0 8.0

19 Kieralon Wash JET-B Conc.

- - -

Pluriol P 2000 25322-69-4 0.0 1.0 1.0

TEGOSIPON 3062 67674-67-3 0.0 0.2 0.2


9043-30-5 0.0 5.5 5.5

Isopropanol 67-63-0 0.0 0.1 0.1

TRI ALCOHOL 3 EO MOLE

068131-40-8 0.0 2.3 2.3

20 Kieralon Wash MFB

- - -

Plurafac LF 431 168255-97-8 0.0 4.0 4.0

Neol Neopentylglycol Solution 90%_ALT bu

126-30-7 0.0 1.8 1.8

Sokalan CP 12 S 110-16-7 0.0 2.0 2.0

SEQUCEL HD (DEQUEST 2010)

2809-21-4 0.0 1.2 1.2

Lutensol AO 5 64425-86-1 0.0 5.0 5.0

Lutensol AO 7 64425-86-1 0.0 3.8 3.8

21 Lufibrol Extr CP

- - -

Na gluconate (M1154)

527 -07-1 0.0 3.0 3.0

ACTICIDE MV 55965-84-9 0.0 0.04 0.04

Citric Acid 77-92-9 0.0 3.0 3.0

Aquacid 105 Ex 2809-21-4 0.0 3.0 3.0

22 Lufibrol Extr SE

- - -

Sokalan CP 12 S 110-16-7 0.0 1.97 1.97

Potassium Hydroxide

1310-58-3 0.0 0.43 0.43

Trilon M lq. 164462-16-2 0.0 4.99 4.99

23 Lufibrol Extr MSD

- - -

NTA SOLID 97% 139-13-9 0.0 0.6 0.6

NTA TRISOD SALT PDR

5064-31-3 0.0 1.8 1.8

Potassium Hydroxide

1310-58-3 0.0 0.7 0.7

Sokalan CP 12 S 110-16-7 0.0 2.0 2.0

24 Perapret Add F-PEB

- - -

Lutensol TO 8 69011-36-5 0.0 4.69 4.69

SAVOX BW 300 68441-17-8 0.0 13.44 13.44

Potassium Hydroxide

1310-58-3 0.0 0.35 0.35

25 Perapret Add TX 2517

- - -

Wacker Finish CT 54 E

69011-36-5 0.0 0.4 0.4

Lutensol TO 8 69011-36-5 0.0 0.2 0.2

Perapret Add F-PEB

Mixture of 69011-36-5 1310-58-3 7732-18-5

0.0 9.0 9.0

26 Prestogen Stab D

- - -

Trilon C Lq. 140-01-2 0.0 10.7 10.7

Dekol Dis SN 9003-04-7 0.0 10.7 10.7

MAGN CHLORO HEX HYD

7786-30-3 0.0 12.8 12.8

Sulphuric acid 7664-93-9 0.0 2.5 2.5

GLUCONIC ACID 526-95-4 0.0 10.7 10.7


Mixture of 22042-96-2 7647-14-5

0.0 10.3 10.3

27 Prestogen Stab FB-E

- - -

MAGN CHLORO HEX HYD

7786-30-3 0.0 1.34 1.34

Proxel GXL Mixture of 3634-33-5 25265-71-8 7732-18-5

0.0 0.04 0.04

Sulphuric acid 7664-93-9 0.0 0.08 0.08

GLUCONIC ACID 526-95-4 0.0 0.76 0.76


Mixture of 22042-96-2 7647-14-5

0.0 1.9 1.9

28 Prestogen Stab FB-PL

- - -


0.0 0.02 0.02

MAGN CHLORO HEX HYD

7786-30-3 0.0 0.7 0.7

Sulphuric acid 7664-93-9 0.0 0.04 0.04

GLUCONIC ACID 526-95-4 0.0 0.4 0.4


Mixture of 22042-96-2 7647-14-5

0.0 1.0 1.0

29 Primasol Deaer NF

- - -

Primasol NF 100 4971-47-5 0.0 4.51 4.51

Ammonia 1336-21-6 0.0 0.78 0.78

30 Primasol Deaer NF New

- - -

PHOSPHOROUS PENTOXIDE

1314-56-3 0.0 7.07 7.07

PHOSPHORIC ACID TRIS(2-ETHYLHEXYL) ESTER

78-42-2 0.0 2.8 2.8

Lutensol XA 40 166736-08-9 0.0 2.8 2.8

Solvenon DPM 34590-94-8 0.0 4.55 4.55

Lutensol Tex AO 7 157627-86-6 0.0 1.12 1.12

Ammonia 1336-21-6 0.0 8.05 8.05

2-ETHYL-HEXANOL

104-76-7 0.0 19.18 19.18

31 Rongalit Dcharge ST Lq.

- - -

Sodium Formaldehyde Sulfoxylate

149-44-0 0.0 40.0 40.0

Ammonia 1336-21-6 0.0 5.84 5.84

32 Siligen Soft FB-NCE

- - -

Product NF 100 190454-07-0 0.0 3.2 3.2


0.0 0.04 0.04

33 Siligen Soft SIH

- - -

Lutensol TO 8 69011-36-5 0.0 0.8 0.8

Wetsoft NE 820 112-34-5 0.0 3.8 3.8

Wetsoft NE 810 112-34-5 0.0 11.3 11.3


9043-30-5 0.0 2.2 2.2

34 Siligen Soft SIS

- - -

Lutrol E 400 25322-68-3 0.0 0.6 0.6

Lutensol TO 8 69011-36-5 0.0 0.48 0.48

Wacker Finish WR-301 CN

Mixture of 102782-92-3 556-67-2 209-136-7

0.0 2.9 2.9

Acetic acid 64-19-7 0.0 0.06 0.06


9043-30-5 0.0 1.24 1.24

35 Siligen Soft TX HQS

- - -

BUTYLDIGLYCOL 112-34-5 0.0 1.0 1.0

Tegopren 6924 0.0 2.4 2.4

Lutensol TO 8 69011-36-5 0.0 0.2 0.2

Lutensol TO 5 69011-36-5 0.0 0.5 0.5

Acetic acid 64-19-7 0.0 0.02 0.02

36 Uniperol Buffer PC

- - -

Decaltal Pic S 68603-87-2 0.0 0.44 0.44

Citric Acid, monohydrate

5949-29-1 0.0 8.76 8.76

37 Uniperol Buffer TX P-DP

- - -

Formic Acid 64-18-6 0.0 3.0 3.0

Decaltal Pic S 68603-87-2 0.0 0.2 0.2

Citric Acid, monohydrate

5949-29-1 0.0 3.0 3.0

ACTICIDE MV 55965-84-9 0.0 0.04 0.04

38 Uniperol Level RD

- - -

Dekol Dis SN 9003-04-7 0.0 10.0 10.0

Sokalan CP 12 S 110-16-7 0.0 1.5 1.5


Aquacid 1067 EX 22042-96-2 0.0 6.6 6.6

39 Uniperol Level SE

- - -

Formic Acid 64-18-6 0.0 0.01 0.01

Igesol HS-30 0.0 0.1 0.1

KATARANG SD 67762-27-0 0.0 4.8 4.8

NOIGEN 13001-LIQUID

68439-49-6 0.0 5.2 5.2

NOIGEN SA 10 26635-92-7 0.0 5.0 5.0

40 Uniperol Level SF ECO

- - -

DIPROP GLYC (RM)

25265-7-8 0.0 6.0 6.0


9043-30-5 0.0 1.0 1.0

Oleic acid ethoxylated (4,7

9004-96-0 0.0 3.0 3.0

EO)

Castor Oil ethoxylated (47 EO)

8001-79-4 0.0 4.0 4.0

TURKEY RED OIL 70%

8002-33-3 0.0 0.2 0.2

41 Tamol FB LI - - -

Crude Naphthalene 91-20-3 0.0 7.64 7.64

Sulphuric acid 7664-93-9 0.0 8.06 8.06

Formaldehyde 50-00-0 0.0 3.2 3.2


42 Tamol M (REF)

- - -

Refined Naphthalene

91-20-3 0.0 11.46 11.46

Sulphuric acid 7664-93-9 0.0 12.09 12.09

Formaldehyde 50-00-0 0.0 5.7 5.7


43 Tamol NNOL - - -

Phenol 108-95-2 0.0 8.64 8.64

Sulphuric acid 7664-93-9 0.0 10.75 10.75

TG Urea 57-13-6 0.0 5.9 5.9

Formaldehyde 50-00-0 0.0 12.32 12.32


Sulphuric acid 7664-93-9 0.0 1.5 1.5

Metaclaw CL liq 64-02-8 0.0 0.25 0.25

44 Tamol XNL - - -

Decaltal PIC A Micture of 124-04-9 1132-18-5

0.0 2.75 2.75

Acetic acid 64-19-7. 0.0 4.0 4.0


PEG 200 (Pluriol E200)

25322-68-3 0.0 1.84 1.84

Sorbitol solution 50-70-4 0.0 2.74 2.74

Sodium bisulphite 7631-90-5 0.0 0.4 0.4

45 Relugan D / DI - - -


Formaldehyde 50-00-0 0.0 9.8 9.8

Tamol M Mixture of 124-04-9 1132-18-5 1310-73-2 50-70-4

0.0 16.1 16.1

Melamine 108-78-1 0.0 2.45 2.45

TG Urea 57-13-6 0.0 11.55 11.55

Formaldehyde 50-00-0 0.0 9.1 9.1

46 Relugan SLF / DLF

- - -

Formaldehyde 50-00-0 0.0 23.77 23.77


TG Urea 57-13-6 0.0 7.7 7.7


Formic acid 64-18-6 0.0 0.18 0.18


Alkaline DX solution 29405-16-1 0.0 30.24 30.24

Decaltal PIC 68603-87-2 0.0 0.53 0.53

Sodium sulphate 7757-82-6 0.0 2.8 2.8

47 Basyntan AN - - -

Phenol 108-95-2 0.0 3.38 3.38

Sulphuric acid 7664-93-9 0.0 4.12 4.12

TG Urea 57-13-6 0.0 2.16 2.16

Formaldehyde 50-00-0 0.0 3.34 3.34


AN- Condensate 117985-54-3 0.0 14.02 14.02

Formaldehyde 50-00-0 0.0 0.68 0.68

Formic acid 64-18-6 0.0 0.55 0.55

Sodium sulphate 7757-82-6 0.0 0.8 0.8

48 Basyntan ANF - - -

Phenol 108-95-2 0.0 2.12 2.12

Sulphuric acid 7664-93-9 0.0 2.7 2.7

TG Urea 57-13-6 0.0 1.38 1.38

Formaldehyde 50-00-0 0.0 2.1 2.1


Ammonia 1336-21-6 0.0 0.6 0.6



Formaldehyde 50-00-0 0.0 1.83 1.83

Aniline 62-53-3 0.0 0.45 0.45

Melamine 108-78-1 0.0 0.18 0.18

TG Urea 57-13-6 0.0 0.3 0.3

Formaldehyde 50-00-0 0.0 0.92 0.92

Formic acid 64-18-6 0.0 0.05 0.05

Relugan AME 0.0 6.2 6.2

49 Basyntan AN Condensate

- - -

Sodium metabisulphite

007681-57-4 0.0 8.0 8.0

Formaldehyde 50-00-0 0.0 5.77 5.77


Aniline 62-53-3 0.0 1.34 1.34

Melamine 108-78-1 0.0 0.55 0.55

TG Urea 57-13-6 0.0 0.9 0.9

Formaldehyde 50-00-0 0.0 1.58 1.58

50 Basyntan DLE - - -

Phenol 108-95-2 0.0 3.6 3.6

Sulphuric acid 7664-93-9 0.0 4.29 4.29

TG Urea 57-13-6 0.0 2.49 2.49

Formaldehyde 50-00-0 0.0 5.89 5.89


Phenol 108-95-2 0.0 2.39 2.39

Metaclaw CL liq 64-02-8 0.0 0.1 0.1

Formaldehyde 50-00-0 0.0 1.63 1.63



0.0 0.8 0.8

Sulphuric acid 7664-93-9 0.0 0.05 0.05

Sodium hydro sulfite

7775-14-6 0.0 0.01 0.01

51 Basyntan DX - - -

Phenol 108-95-2 0.0 5.18 5.18

Sulphuric acid 7664-93-9 0.0 6.45 6.45

TG Urea 57-13-6 0.0 3.54 3.54

Formaldehyde 50-00-0 0.0 7.39 7.39


Sulphuric acid 7664-93-9 0.0 0.9 0.9

52 Basyntan FB DI

- - -

Phenol 108-95-2 0.0 5.4 5.4

Sulphuric acid 7664-93-9 0.0 6.44 6.44

TG Urea 57-13-6 0.0 3.68 3.68

Formaldehyde 50-00-0 0.0 8.83 8.83


Phenol 108-95-2 0.0 3.6 3.6

Metaclaw CL liq 64-02-8 0.0 0.15 0.15

Formaldehyde 50-00-0 0.0 2.48 2.48



0.0 1.73 1.73

Pthalic anhydride 85-44-9 0.0 0.9 0.9

Formic acid 64-18-6 0.0 0.9 0.9

Sodium sulphate 7757-82-6 0.0 1.95 1.95

FBL 1 0.0 10.8 10.8

53 Basyntan FB. P

- - -

Phenol 108-95-2 0.0 7.5 7.5


Formaldehyde 50-00-0 0.0 7.65 7.65


TG Urea 57-13-6 0.0 1.2 1.2


DLE solution 68603-87-2 0.0 24.0 24.0

Metaclaw CL liq 64-02-8 0.0 0.3 0.3


0.0 1.65 1.65

Sodium sulphate 7757-82-6 0.0 1.5 1.5

Sulphuric acid 7664-93-9 0.0 0.6 0.6

Sodium sulphate 7757-82-6 0.0 3.9 3.9

54 Basyntan XA - - -

Phenol 108-95-2 0.0 5.4 5.4

Sulphuric acid 7664-93-9 0.0 6.44 6.44

TG Urea 57-13-6 0.0 3.73 3.73

Formaldehyde 50-00-0 0.0 8.83 8.83


Phenol 108-95-2 0.0 3.59 3.59

Metaclaw CL liq 64-02-8 0.0 0.15 0.15

Formaldehyde 50-00-0 0.0 2.44 2.44


Sodium hydro sulfite

7775-14-6 0.0 0.02 0.02

C. Floating agents

Pluronic PE-10100 9003-11-6 0.0 28.5 28.5

Escaid 110 64742-47-8 0.0 28.5 28.5

Oxooil 9N 68526-89-6. 0.0 3.0 3.0

D. Spray Drying, formulation and Packing of Water Treatment Chemicals & Paper Dyes (Sokalan, Magnafloc, Pergasol & Irgalite)

Magnafloc LT / Magnafloc LT7991

42751-79-1 0.0 310.0 310.0

ANNEXURE: 3

BRIEF MANUFACTRING PROCESS, CHEMICAL REACTION AND MASS BALANCE WITH FLOW

DIAGRAM

DESCRIPTION OF MANUFACTURING PROCESS (EXISTING)

1. TINOPAL DMA-X

MANUFACTURING PROCESS

• DASDA, Cyanuric Chloride, Caustic Soda Lye, Ice and Water are fed in a reactor for first step

condensation at 0 to 5 degree centigrade. This reaction step is over within 4-6 hours of time.

• Then this material is transferred to another reactor for second step condensation, where aniline

is added for second step reaction temp & pH maintained

• For third step reaction amine is added, caustic soda lye is added to maintain the pH and

temperature.

• Acid isolation is done after third stage reaction and filtration is followed. Mother liquor and

washing water if any is sent to ETP for further processing and disposal.

Chemical Reaction:

Step 1 Condensation

Cyanuric chloride

DASDA free acid

C C N

H

H

N H

H H

H H

S O 3 S

H

S O 3 H

+ Soda Ash

↓

Step 2 Condensation

N

CN

C

NC

Cl

Cl Cl

Cl

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

Cl

Aniline

NH2

+ Caustic soda lye

↓

Step 3 Condensation

Morpholine

+ Caustic soda lye

↓

N

H

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

N

H

O N H

N

H

N N

N

N O

N H

S O 3 N a

N a O 3 S

N H

N N

N N O

N H

MATERIAL BALANCE

TINOPAL DMA-X

Description Qty. in MT Description Qty. in MT

Water 1.500

OT 70% 0.002 CC Suspension

Ice 3.000

Cyanuric Chloride 1.000

Water 0.200 Process Reactor

Water 1.200 Na2Co3 Solution

Soda Ash 0.300 Process Reactor

Water 9.000

DASDA 1.015 DASDA Solution

NaOH ( 48% ) 0.540

hyflo 0.015 Process Reactor Clarification residue 0.015

Water 0.810 NaOH Solution

NaOH ( 48% ) 0.810 Process Reactor

NaCl 0.060 Condensation Step -1

Water 0.100 CO2 0.945

Ice 7.000


Aniline 0.500 Condensation Step -2


Morpholine 0.460 Condensation Step -3


Filtration Wet cake 80% MC+ 2 % NaCl) 10.000

Filtration Press Waste Water 18.552

Water 5.200 Step 4

Wet cake 10.000

NaCl 0.520 Step 5

Soda Ash 0.215

Baykanol 0.040

Drying TINOPAL DMA-X 3.520

Water evaporation during drying 12.455

Total input in MT 45.487 Total Output in MT 45.487

InputReaction / Operation / Equipment

Output

2. TINOPAL DMA-X Conc







temperature.



Chemical Reaction:

Step 1 Condensation

Cyanuric chloride

DASDA free acid

C C N

H

H

N H

H H

H H

S O 3 S

H

S O 3 H

+ Soda Ash

↓

Step 2 Condensation

Aniline NH

2

+ Caustic soda lye ↓

Step 3 Condensation

N

CN

C

NC

Cl

Cl Cl

Cl

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

Cl

N

H

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

N

H

Morpholine


O N H

N

H

N N

N

N O

N H

S O 3 N a

N a O 3 S

N H

N N

N N O

N H

MATERIAL BALANCE

TINOPAL DMA-X CONC


Water 2.250


Ice 4.500





Water 13.500


NaOH ( 48% ) 0.675




0.000


Water 3.000 CO2 1.418

Ice 10.500




Morpholine 0.690 Condensation Step -3


NaCl 0.450 Step 4

Soda Ash 0.075

Filtration Wet cake 75% MC 10.500


Water 3.750 Step 5

Wet cake 10.500

Soda Ash 0.015

Baykanol 0.023

Drying TINOPAL DMA-X CONC 4.065




Output

3. TINOPAL BA







temperature.



Chemical Reaction:

Step 1 Condensation

Cyanuric Chloride

DASDA di-sodium salt

N

HN

H

SO3Na

SO3Na

H

H

+ Soda Ash

↓

Step 2 Condensation

Aniline NH

2

+ Caustic lye solution

↓

N

CN

C

NC

Cl

Cl Cl

Cl

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

Cl

N

H

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

N

H

Step 3 Condensation

Diethanolamine

+ Sodium hydroxide solution

↓

H N

C C OH

H2H2

C C OH

H2 H2

N

H

N

N

N

N(HOH4C2)2

N

HSO3Na

NaO3S

N

H

N

N

NN (C2H4OH)2

NH

MATERIAL BALANCE

TINOPAL BA


Water 1.500


Ice 2.500





Water 8.700


NaOH ( 48% ) 0.450

Process Reactor




Water 0.090 CO2 0.945

Ice 5.000




DEA 85% 0.053

DEA 85% 0.715 Condensation Step -3

Water 0.500 Process Reactor Clarification residue 0.010

hyflo 0.010

HCl 15% 1.300 Isolation Evaporation 0.674

Filtration Waste Water 19.622

Filtration Press Wet cake 6.600

Wet cake 6.600

Water 0.800 Slurry Preparation

NaOH ( 48% ) 0.463

Spray Drying TINOPAL BA crude 2.300

Evaporation 5.563

TINOPAL BA crude 2.300 Formulation & Packing

NaCl 0.800 TINOPAL BA crude 3.100



Output

4. TINOPAL BMK







temperature.



Chemical Reaction:

Step 1 Condensation

Cyanuric Chloride


N

HN

H

SO3Na

SO3Na

H

H

+ Soda Ash

↓

Step 2 Condensation

Aniline NH

2

+ Caustic lye solution

↓

N

CN

C

NC

Cl

Cl Cl

Cl

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

Cl

N

H

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

N

H

Step 3 Condensation

Diethanolamine


↓

H N

C C OH

H2H2

C C OH

H2 H2

N

H

N

N

N

N(HOH4C2)2

N

HSO3Na

NaO3S

N

H

N

N

NN (C2H4OH)2

NH

MATERIAL BALANCE

TINOPAL BMK


Water 1.000


Ice 2.500





Water 8.167


NaOH ( 48% ) 0.405

Process Reactor




Water 0.100 CO2 0.106

Ice 5.000






hyflo 0.010

NaCl 0.850 Isolation



Wet cake 6.500 Drying Crude 2.466

Water evaporation

during drying 4.062

Crude 2.466

NaCl 0.250 Formulation TINOPAL BMK 2.800

Soda Ash 0.056

STPP 0.028



Output

5. TINOPAL UP liquid







temperature.



Chemical Reaction:

Step 1 Condensation

Cyanuric Chloride


N

HN

H

SO3Na

SO3Na

H

H

+ Soda Ash

↓

Step 2 Condensation

Aniline NH

2

+ Caustic lye solution ↓

N

CN

C

NC

Cl

Cl Cl

Cl

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

Cl

N

H

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

N

H

Step 3 Condensation

Diethanolamine


↓

+ Hydrochloric Acid 30% ↓

N

N

N

N

N

H

(C2H

4OH)

2

N

HHO

3S

N

H

SO3H

N

N

N

N

N

H

(C2H

4OH)

2

H N

C C OH

H2H2

C C OH

H2 H2

NH

N

N

N

N(HOH4C2)2

N

HSO3Na

NaO3S

N

H

N

N

NN (C2H4OH)2

NH

MATERIAL BALANCE

TINOPAL UP liquid


Water 1.500


Ice 2.500





Water 8.700


NaOH ( 48% ) 0.450

Process Reactor




Water 0.090 CO2 0.945

Ice 5.000




DEA 85% 0.053



hyflo 0.010


Water 20.000 Filtration Waste Water 39.622


Wet cake 6.600

Water 0.800 Formulation TINOPAL UP liquid 9.900

KOH 0.300

Urea 2.200



Output

6. TINOPAL BHT HC







temperature.



Chemical Reaction:

Step 1 Condensation

Cyanuric Chloride


N

HN

H

SO3Na

SO3Na

H

H

+ Soda Ash

↓

Step 2 Condensation

Aniline NH

2


Step 3 Condensation

N

CN

C

NC

Cl

Cl Cl

Cl

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

Cl

NH

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

NH

Diethanolamine


↓

+ Hydrochloric Acid 30% ↓

N

N

N

N

N

H

(C2H

4OH)

2

N

HHO

3S

N

H

SO3H

N

N

N

N

N

H

(C2H

4OH)

2

H N

C C OH

H2H2

C C OH

H2 H2

NH

N

N

N

N(HOH4C2)2

N

HSO3Na

NaO3S

N

H

N

N

NN (C2H4OH)2

NH

MATERIAL BALANCE

TINOPAL BHT HC


Water 1.500


Ice 2.500





Water 8.650


NaOH ( 48% ) 0.400

Process Reactor




Ice 5.600 CO2 0.945

Water 0.600

Process Reactor



DEA 85% 0.045



hyflo 0.010




Wet cake 6.550 Waste Water 4.000

Water 2.000 Separation Organic Layer 4.550

Organic Layer 4.550 Formulation

Urea 1.000 TINOPAL NP slurry 6.500

TEA 1.000



Output

7. TINOPAL NP Slurry







temperature.



Chemical Reaction:

Step 1 Condensation

Cyanuric Chloride


N

HN

H

SO3Na

SO3Na

H

H

+ Soda Ash

↓

Step 2 Condensation

Aniline NH

2


N

CN

C

NC

Cl

Cl Cl

Cl

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

Cl

NH

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

NH

Step 3 Condensation

Diethanolamine


↓

H N

C C OH

H2H2

C C OH

H2 H2

NH

N

N

N

N(HOH4C2)2

N

HSO3Na

NaO3S

N

H

N

N

NN (C2H4OH)2

NH

MATERIAL BALANCE

TINOPAL NP Slurry


Water 1.500


Ice 2.500





Water 8.700


NaOH ( 48% ) 0.450

Process Reactor




Water 0.090 CO2 0.945

Ice 5.000




DEA 85% 0.053



hyflo 0.010

Separation Waste Water 19.678

Organic Layer 5.918

Organic Layer 5.918 Formulation

Water 4.882 TINOPAL NP slurry 10.890

Glutaldhyde 0.019

Preventol 0.052

Xanthan gum 0.019



Output

8. TINOPAL ABP-X HC


• Sulphanilic acid /Metanilic acid, soda ash. Cyanuric Chloride, Caustic Soda Lye, Ice and Water are

fed in a reactor for first step condensation at 5 to 15 degree centigrade. This reaction step is over

within 4-6 hours of time.

• Then this material is transferred to another reactor for second step condensation, where DASDA,

Caustic soda lye is added for second step reaction temperature & pH maintained.

• For third step reaction, different amines are added for different products in this tetra Sulpho

category caustic soda lye is added to maintain the pH and temperature.

• Then this material is transferred for filtration in Nano filtration Unit.

• The filtrate from Nano filtration unit is sent to ETP for treatment and disposal.

Chemical Reaction:

Step 1 Condensation

Cyanuric chloride

+ Aniline-4-sulfonic acid Sodium salt

SNH

H

O

O

ONa

+ Soda Ash

↓

N

C

CCl

N

CN

Cl

N

H

S O

O

O Na

Step 2 Condensation

+ DAS free acid

CC N

H

H

NH

H H

HSO3H

SO3H

+ Soda Ash

↓

S

O

O

O

Na

S

O

O

O

Na

N

NCl

N

SO

O

O

Na

S OO

O Na

NN H

H

N

NCl

N

N

H

N

H

N

CN

C

NC

Cl

Cl Cl

Step 3 Condensation

+ Diethanolamine

+ Caustic Soda Lye

↓

H N

C C OH

H2H2

C C OH

H2 H2

NaO3S N

H

N

N

N

N(HOH4C2)2

N

HSO3Na

NaO3S

N

H

N

N

NN (C2H4OH)2

NH

SO3Na

MATERIAL BALANCE

TINOPAL ABP-X HC


Water 1.000


Ice 3.500





Water 2.370

Sulphanilic acid 1.187 SA Solution

NaOH ( 48% ) 0.550

Process Reactor

Water 8.315 Dasda Solution

DASDA 1.523 Process Reactor

NaOH ( 48% ) 0.662

Sulphanilic acid 0.250 Condensation Step -1

Ice 1.875 CO2 0.178

Water 0.200

Process Reactor

Water 2.000 Condensation Step -2 CO2 0.178





wet cake 6.250 Condensation Step -3

DEA 85% 1.088 Process Reactor Clarification residue 0.022

Water 5.300

hyflo 0.022

NaOH ( 48% ) 0.662

Drying TINOPAL ABP-XC 5.200




Output

9. TINOPAL ABP-A











Chemical Reaction:

Step 1 Condensation

Cyanuric chloride


SNH

H

O

O

ONa

+ Soda Ash

↓

N

C

CCl

N

CN

Cl

N

H

S O

O

O Na

Step 2 Condensation

+ DASDA free acid

C

C N

H

H

N

H

H H

H S O 3 Na

S O 3 Na

+ Soda Ash

↓

S

O

O

O

Na

S

O

O

O

Na

N

NCl

N

SO

O

O

Na

S OO

O Na

NN H

H

N

NCl

N

N

H

N

H

Step 3 Condensation

N

CN

C

NC

Cl

Cl Cl

+ Diethanolamine

+ Caustic Soda Lye

↓

H N

C C OH

H2H2

C C OH

H2 H2

NaO3S N

H

N

N

N

N(HOH4C2)2

N

HSO3Na

NaO3S

N

H

N

N

NN (C2H4OH)2

NH

SO3Na

MATERIAL BALANCE

TINOPAL ABP-A


Water 2.000


Ice 3.000





Water 3.000


NaOH ( 48% ) 0.450

Process Reactor



NaOH ( 48% ) 0.650


Ice 4.000 CO2 0.215

Water 0.750

Process Reactor



Condensation Step -3

DEA 85% 0.860 Process Reactor

Water 0.750

NaOH ( 48% ) 0.650

Clarification residue 0.022

hyflo 0.022 Clarification


Nano

hyflo 0.022 Formulation & Clarification TINOPAL ABP-A 18.700

Glutaldhyde 0.360 Clarification residue 0.022

Preventol 0.050



Output

10. TINOPAL ABA











Chemical Reaction:

Step 1 Condensation

Cyanuric chloride


SNH

H

O

O

ONa

+ Soda Ash

↓

N

C

CCl

N

CN

Cl

N

H

S O

O

O Na

Step 2 Condensation

+ DASDA free acid

C

C N

H

H

N

H

H H

H S O 3 Na

S O 3 Na

+ Soda Ash

↓

S

O

O

O

Na

S

O

O

O

Na

N

NCl

N

SO

O

O

Na

S OO

O Na

NN H

H

N

NCl

N

N

H

N

H

N

CN

C

NC

Cl

Cl Cl

Step 3 Condensation

+ Diethanolamine

+ Caustic Soda Lye

↓

H N

C C OH

H2H2

C C OH

H2 H2

NaO3S N

H

N

N

N

N(HOH4C2)2

N

HSO3Na

NaO3S

N

H

N

N

NN (C2H4OH)2

NH

SO3Na

MATERIAL BALANCE

TINOPAL ABA


Water 2.000


Ice 3.000





Water 3.000


NaOH ( 48% ) 0.450

Process Reactor



NaOH ( 48% ) 0.650


Ice 4.000 CO2 0.215

Water 0.750

Process Reactor




DEA 85% 0.860 Process Reactor

Water 0.750

NaOH ( 48% ) 0.650




Nano

hyflo 0.022 Formulation & Clarification TINOPAL ABA 23.375




Output

11. TINOPAL 5BM







temperature.



Chemical Reaction:

Step 1 Condensation

Cyanuric chloride

DASDA free acid

C C N

H

H

N H

H H

H H

S O 3 S

H

S O 3 H

+ Soda Ash

↓

Step 2 Condensation

Aniline NH

2


N

CN

C

NC

Cl

Cl Cl

Cl

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

Cl

NH

N

N

N

Cl

N

HSO3Na

NaO3S

N

H

N

N

NCl

NH

Step 3 Condensation

N-Methylethanolamine


O

3 a

N O S

N

H

NH

N

N

N

N

N

HS N

a 3

N

H

N

N

N

N

CH2CH2OH

CH3

HOH2CH2C

CH3

MATERIAL BALANCE

TINOPAL 5BM


Water 1.500


Ice 3.000





Water 9.000


NaOH ( 48% ) 0.450





Water 2.000 CO2 0.945

Ice 6.000




N-Methylethanolamine 0.434 Condensation Step -3


Filtration Wet cake 75% MC 7.000


Water 3.000 Step 5

Wet cake 7.000

NaCl 0.766

DAXAD 60L 0.020

Drying TINOPAL 5BM 3.335




Output

12. TINOPAL SFP


• Aniline 2:5 Di Sulphonic acid, soda ash. Cyanuric Chloride, Caustic Soda Lye, Ice and Water are fed

in a reactor for first step condensation at 5 to 15 degree centigrade. This reaction step is over








Chemical Reaction:

Step 1 Condensation

Cyanuric Chloride

Aniline 2,5 disulphonic acid NH

2

SO3H

HO3S

+ Caustic Soda Lye

+ Soda Ash

↓

N

N

N

ClCl

N H

SO3Na

NaO3S

Step 2 Condensation

DASDA free acid

CH

C

H O3

S

NH2

H

S O3

H

N H2

N

CN

C

NC

C l

C l C l

+ Caustic Soda Lye ↓

SO3Na

NN H

HN

NN

Cl

NN

NCl

NH

N

H

SO3Na

NaO3S

NaO3S

SO3Na

NaO3S

Step 3 Condensation

Morpholine


SO3Na

SO3Na

NN H

HN

NN

NN

N

N

H

N

H

SO3Na

N

ON

O

NaO3S

SO3Na

NaO3S

+ Hydrochloric Acid 30%

O

N

O

N

NN H

HN

NN

NN

N

N

H

N

H NaO3S

SO3H

HO3S

SO3Na

NaO3S

SO3H

O N H

MATERIAL BALANCE

TINOPAL SFP


Water 2.000


Ice 3.000





Water 2.100

2,5 SA 1.720 DSA Solution

NaOH ( 48% ) 0.596

Process Reactor



NaOH ( 48% ) 0.625



2,5 SA 0.500 Condensation Step -1

Ice 4.000 CO2 0.143

Water 1.000

Process Reactor


Process Reactor

Diethyl amine 0.650 Condensation Step -3

Process Reactor

hyflo 0.022 Clarification residue 0.022

Clarification


Filtration wet cake 10.800

Waste Water 23.489

Bay Pure 0.055 Slurry Preparation

Water 8.200

wet cake 10.800

Tinopal SFP 5.700

Spray Drying Evoporation 13.355



Output

13. TINOPAL SPP-Z











Chemical Reaction:

Step 1 Condensation

Cyanuric chloride

Aniline 2,5 disulphonic acid N H

2

S O3

H

H O3

S

+ Caustic Lye

+ Soda Ash

↓

N

N

N

ClCl

N H

SO3Na

NaO3S

Step 2 Condensation

DASDA free acid

CH

C

H O3

S

NH2

H

S O3

H

N H2

N

CN

C

NC

C l

C l C l


SO3Na

NN H

HN

NN

Cl

NN

NCl

NH

N

H

SO3Na

NaO3S

NaO3S

SO3Na

NaO3S

Step 3 Condensation

Diethyl amine

(C2H

5)2NH


SO3Na

NN H

HN

NN

NN

N

NH

N

H

SO3Na

(C2H

5)2N

N(C2H

5)2

NaO3S

NaO3S

NaO3S

SO3Na

MATERIAL BALANCE

TINOPAL SPP-Z


Water 2.000


Ice 3.000





Water 2.100


NaOH ( 48% ) 0.596

Process Reactor



NaOH ( 48% ) 0.625




Ice 4.000 CO2 0.143

Water 1.000

Process Reactor

Condensation Step -2 CO2 0.143

Process Reactor



hyflo 0.010 Clarification Clarification residue 0.010


Nano

Preventol 0.084 Formulation TINOPAL SPP-Z 29.200




Output

14. TINOPAL SHP











Chemical Reaction:

Step 1 Condensation

Cyanuric Chloride

Aniline 2,5 disulphonic acid NH

2

SO3H

HO3S

+ Caustic Soda Lye

+ Soda Ash

↓

N

N

N

ClCl

N H

SO3Na

NaO3S

Step 2 Condensation

DASDA free acid

CH

C

H O3

S

NH2

H

S O3

H

N H2

N

CN

C

NC

C l

C l C l


SO3Na

NN H

HN

NN

Cl

NN

NCl

NH

N

H

SO3Na

NaO3S

NaO3S

SO3Na

NaO3S

Step 3 Condensation

Morpholine


SO3Na

SO3Na

NN H

HN

NN

NN

N

N

H

N

H

SO3Na

N

ON

O

NaO3S

SO3Na

NaO3S

+ Hydrochloric Acid 30%

O

N

O

N

NN H

HN

NN

NN

N

N

H

N

H NaO3S

SO3H

HO3S

SO3Na

NaO3S

SO3H

O N H

MATERIAL BALANCE

TINOPAL SHP


Water 2.000


Ice 3.000





Water 2.100


NaOH ( 48% ) 0.596

Process Reactor



NaOH ( 48% ) 0.625




Ice 4.000 CO2 0.143

Water 1.000

Process Reactor


Process Reactor


Process Reactor




Filtration wet cake 10.800

Waste Water 23.489

PEG 1500 9.375 Formulation

Water 5.825 Tinopal SFP 26.000

wet cake 10.800



Output

15. TINOPAL AS











Chemical Reaction:

Step 1 Condensation

Cyanuric chloride

Aniline 2,5 disulphonic acid N H

2

S O3

H

H O3

S

+ Caustic Lye

+ Soda Ash

↓

N

N

N

ClCl

N H

SO3Na

NaO3S

Step 2 Condensation

DASDA free acid

CH

C

H O3

S

NH2

H

S O3

H

N H2

N

CN

C

NC

C l

C l C l


SO3Na

NN H

HN

NN

Cl

NN

NCl

NH

N

H

SO3Na

NaO3S

NaO3S

SO3Na

NaO3S

Step 3 Condensation

Diethyl amine

(C2H

5)2NH


SO3Na

NN H

HN

NN

NN

N

NH

N

H

SO3Na

(C2H

5)2N

N(C2H

5)2

NaO3S

NaO3S

NaO3S

SO3Na

MATERIAL BALANCE

TINOPAL AS


Water 2.000


Ice 3.000





Water 2.100


NaOH ( 48% ) 0.596

Process Reactor



NaOH ( 48% ) 0.625




Ice 4.000 CO2 0.143

Water 1.000

Process Reactor


Process Reactor






Nano

TEA 0.380 Formulation & Clarification TINOPAL AS 38.000




Output

16. TINOPAL ASP











Chemical Reaction:

Step 1 Condensation

Cyanuric chloride


SNH

H

O

O

ONa

+ Soda Ash

↓

N

C

CCl

N

CN

Cl

N

H

S O

O

O Na

Step 2 Condensation

+ DAS free acid

CC N

H

H

NH

H H

HSO3H

SO3H

+ Soda Ash

↓

S

O

O

O

Na

S

O

O

O

Na

N

NCl

N

SO

O

O

Na

S OO

O Na

NN H

H

N

NCl

N

N

H

N

H

Step 3 Condensation

N

CN

C

NC

Cl

Cl Cl

+ Diisopropanolamine

+ Caustic Soda Lye

↓

NaO3S N

H

N

N

N

N(HOH4C2)2

N

HSO3Na

NaO

O3S

N

H

N

N

NN (C2H4OH)2

NH

SO3Na

MATERIAL BALANCE

TINOPAL ASP


Water 2.000


Ice 3.000





Water 2.700


NaOH ( 48% ) 0.450

Process Reactor



NaOH ( 48% ) 0.650


Ice 4.000 CO2 0.143

Water 0.750

Process Reactor



DDA 1.250 Condensation Step -3


NaOH ( 48% ) 0.650



Water 0.500 Formulation Waste Water from evoporation 3.256

TINOPAL ASP 29.400



Output

17. TINOPAL BOP Extra











Chemical Reaction:

Step 1 Condensation

Cyanuric chloride

+ Aniline-3-sulfonic acid Sodium Salt

NH2

SO

O

O Na

+ Soda Ash

↓

N

HN

N

N

S O

O

C l

C l

O N a

Step 2 Condensation

+ DASDA free acid

CC N

H

H

NH

H H

HSO3H

SO3H

+ Soda Ash

↓

N

CN

C

NC

C l

C l C l

N

N

H

HN

N

N

NN

ClN

N

N

H

H

Cl

NaO3S

SO3Na

SO3Na

NaO3S

Step 2 product: Tetra Na - condensed intermediate

Step 3 Condensation

+ Diethanolamine

+ Caustic Soda Lye

↓

SO3Na

N

N H

H

N

N

N

NNaO

3S

N

N

N

N

N

N

HNaO

3S

(HOH4C

2)2

(C2H

4OH)

2

H

SO3Na

+ Salt

H N

C C OH

H2H2

C C OH

H2 H2

MATERIAL BALANCE

TINOPAL BOP Extra


Water 2.552

Metanilic Acid 1.448 MA Solution


Water 1.500


Ice 3.500





Water 7.800


NaOH ( 48% ) 0.665

Process Reactor

Ice 2.000 Condensation Step -1

Water 0.200 Process Reactor CO2 0.178

Soda Ash 0.500 Condensation Step -2 CO2 0.178




NaOH ( 48% ) 0.700




Wet cake 10.600 Drying Crude 5.000


Crude 5.000

NaCl 3.460 Formulation TINOPAL BOP Extra 8.500

Soda Ash 0.040



Output

HOC -- CHO + H2N --C--NH2

O

+ CH2O +HO--C2H4--O--C2H4--OH

H3PO4

H2C N

C

N

C C

OHOH

O

C2H4

O

C2O4

OH

CH2 O (C2H4--O--C2H4)--OH

DESCRIPTION OF MANUFACTURING PROCESS (PROPOSED)

Fixapret Resin F ECO

A solution of Formaldehyde &Glyoxal charge under stirring in a mixture vessel and adjust pH

by caustic lye up to 7.0 and then urea TG form the intermediate. During the addition of

urea, temperature drops initially below room temperature and then starts rising due to

reaction exotherm. If needed, heat slowly and maintain temperature at ~ 55 deg. C Keep on

adjusting pH to 6.4 – 6.8 by adding Caustic soda lye in small lots. Maintain temperature at ~

55 deg. C there can be a exotherm. pH drops continuously and should be restored with

requisite quantities of Caustic soda lye. Maintain temperature at 550C and pH at 6.4-6.8 for

4 hours. Cool to 500C and addDi Ethylene Glycol and Phosphoric Acid (85%). pH at this stage

settles at 1.5 - 2.0. Maintain temperature @ 500C under stirring for 3 hours. If pH rises

above 2.2 during these 3 hours, then adjust pH to 2 using Sulphuric acid. Finally, cool and

check pH. Adjust pH to 5 with Caustic Lye (25%)

Stir and draw a sample, filter and send to QC lab. Standardize the batch based on QC lab

results and pack through ~ 250 mesh filter.

Chemical Reaction:

MATERIAL BALANCE:


Process Water 0.00 Stage 1

Glyoxal 2.92

Diethylene glycol 2.59

CAUSTIC SODA LYE 0.22

UREA TG 1.21

PHOSPHORIC ACID 0.22

Formaldehyde 2.84

Packing & Storage Fixapret Resin F-ECO 10.000



Output

Heating, Mixing & Cooling

(HO) P

O

(O-CH2-CH-C4H9)

C2H5

O-2 3-A+ NH3 (NH4O)

O-2

- P

O

-3-A

C2H5

(O-CH2-CH-C4H9)

Primasol Deaer NF

A solution of Primasol NF 100 charge under stirring in a process water mixture vessel and

add Liquid Ammonia (25%) under slow stirring.

After addition is over, take sample and send to QC lab to check pH, water/solid content. The

material is then cooled and pH and water content are adjusted if necessary. Filter through ~

120 mesh filter and pack.

Chemical Reaction:

MATERIAL BALANCE:



Primasol NF 100 4.51

AMMONIA SOLUTION 25% 0.78

Packing & Storage Primasol Deaer NF 10.000



Output

Mixing

Primasol Deaer NF (New)

A solution of 2 Ethyl Hexanol, Lutensol AO 7, Phosphoric Pentoxide & 2 Ethyl Hexanol (for

flushing the hopper) , The vessel is sealed & heated to 100 deg. C. Temperature is

maintained for 4 hours.

After this chargeSolvenon DPM,Disframol TO-F, DipropyleneDlycol Monomethyl Ether is

charged &Lutensol XA is charged. The system is flushed with 200 Ltr. process water &

additional process water is added. The reaction mass is mixed for 1 Hour.

After this charge Liquor Ammonia is charged part wise, till PH of 8.00 is achieved. Filter

through ~ 120 mesh filter and pack.

Chemical Reaction:

MATERIAL BALANCE:

P2O5 + HO -- CH2 --CH --C4H9

C2H5

+ NH3 NH4O -- P -- (O -- CH2 -- CH --C4H9)2

C2H5

O



PHOSPHOROUS PENTOXIDE 1.01

PHOSPHORIC ACID TRIS(2-ETHYLHEXYL) ESTER0.40

Lutensol XA 40 190KG 1A1 0.40

Solvenon DPM 0.65

Lutensol Tex AO 7 950KG 31HA1 0.16

AMMONIA SOLUTION 25% 1.15

2-ETHYL-HEXANOL 2.74

Packing & Storage Primasol Deaer NF New 10.000



Output


Tamol FB LI

Take water in a vessel and Charged Naphthalene and add H2SO4. This reaction will be

happened at 140ºC. After that this reaction mass will be reacted with formaldehyde solution

in water.

Slowly start the addition of Sodium Hydroxide solution on the above condensation mass for

Neutralisation. Slurry send for drying then packing.

Chemical Reaction:

MATERIAL BALANCE:


Crude Naphthalene 3.820 Stage 1

Sulphuric acid (98%) 4.030 Suphonation reaction

Process Water 0.900


Formaldehyde 1.600 Condensation

Sodium Hydroxide 4.150 Addition

at 70 - 80°C

Packing & Storage Tamol FB LI 18.100



Output

Basyntan DX

Take water in a vessel and Charged Phenol and add H2SO4. This reaction will be happened

at high temperature about 110ºC. After that this reaction mass will be reacted with

formaldehyde and Urea solution in water.

Slowly start the addition of Sodium Hydroxide solution in to at 70ºC to 80ºC of the above

mass for Neutralisation. Slurry send for drying then packing.

Chemical Reaction:

MATERIAL BALANCE:


Phenol 1.728 Stage 1


Heating ~ up to 100°C

Process water 1.300 Stage 2

Urea 1.179 Condensation

Process water 0.300

Formaldehyde 2.464

Sodium Hydroxide 3.800 Stage 3

Process water 1.100 Netralisation

Sulphuric acid (98%) 0.300

Packing & Storage Basyntan DX 14.321



Output

Relugan SLF / DLF

Formaldehyde and Urea solution in water is react together with present of sodium

bisulphite in an acidic form at temperature approx. 120ºC.

Slowly start the addition of alkaline DX solution at 75ºC. then add filler and then slurry will

send for drying and packing.

Chemical Reaction:

MATERIAL BALANCE:



Formaldehyde 3.396

Sodium Hydroxide 0.010

Urea 1.100

Sodium bisulphite 3.000

Formic acid 0.025 Stage 2

Sodium Hydroxide 0.300 Addition at ~75°C

Alkaline DX solution 4.320

Decaltal PIC 0.075 Stage 3

Sodium sulphate 0.400 Addition at RT

Transfer for Drying

Reacted Mass 17.701 Drying, Packing & Storage Water evaporation during drying 10.201

Relugan SLF/ DLF 7.500



Output

Heating ~120°C

MANUFACTURING PROCESS WITH

Textile, Leather Chemicals: Binders, Auxiliaries Chemicals for tanning & finishing agents

such as textile, dispersions, lacquers & pigments:

The manufacturing process involves batch wise mixing of chemicals in to the reactor with

additives and DM water in different proportion as per the products requirement. Heat the

mass up to ~95˚C and mix it homogenously.

After homogenous mixing, the mass t

quality to be check as per products specification. After QA approval, finish product is

transfer in drums for packing as per customer requirement.

Packed materials transfer to storage facility for dispatch.

Process Flow Diagram:

S WITH FLOW DIAGRAM (PROPOSED)

Chemicals: Binders, Auxiliaries Chemicals for tanning & finishing agents

such as textile, dispersions, lacquers & pigments:



˚C and mix it homogenously.

After homogenous mixing, the mass then cooled up to ambient temperature and product


transfer in drums for packing as per customer requirement.


Chemicals: Binders, Auxiliaries Chemicals for tanning & finishing agents



hen cooled up to ambient temperature and product


Mass Balance:

Prdoduct Name: Cyclanon Clear ECO Plus

Material Balance

Input Reaction / Operation / Equipment

Output

Description

Qty. in

MT Description

Qty. in

MT

Process Water 6.000

Stage 1

Sodium Formaldehyde Sulfoxylate 4.000 Mixing & Clarrification

Packing & Storage Cyclanon Clear ECO Plus 10.000


Prdoduct Name: Kieralon Wash JET-B Conc.

Material Balance



Pluriol P 2000 200KG 1A1 1.00

TEGOSIPON 3062 50kg 1H2 0.20

TRIALCHOHOL 5 ED MOLE 200kg 1H2 5.50 Heating, Mixing & Cooling

Isopropanol 200kg 1A1 0.10TRI ALCOHOL 3 EO MOLE 170kg 1H1 2

Packing & Storage Kieralon Wash JET-B Conc. 10.000



Output

Prdoduct Name: Uniperol Buffer TX P-DP

Material Balance



Formic Acid 85% Cal 100% 35kg 3H1 1.50

Decaltal Pic S 25KG 5H4 0.10

Citric Acid, monohydrate 35kg 5H1 1.50

ACTICIDE MV 25kg 1H2 0.02

Packing & Storage Uniperol Buffer TX P-DP 10.000



Output


Prdoduct Name: Uniperol Level RD

Material Balance



Dekol Dis SN 5.00

Sokalan CP 12 S 250KG 1H1 0.75

CAUSTIC SODA LYE 0.40

Aquacid 1067 EX 3.30

Packing & Storage Uniperol Level RD 10.000



Output


Prdoduct Name: Uniperol Level SE

Material Balance



Formic Acid 85% Cal 100% 35kg 3H1 0.01

Igesol HS-30 100KG 1H1 0.05

KATARANG SD 50kg 1H2 2.40

NOIGEN 13001-LIQUID-60% 200kg 1A2 2.60

NOIGEN SA 10 200kg 1A2 2.50

Packing & Storage Uniperol Level SE 10.000



Output


Prdoduct Name: Uniperol Level SF ECO

Material Balance



DIPROP GLYC (RM) 3.00

TRIALCHOHOL 5 ED MOLE 200kg 1H2 0.50

Oleic acid ethoxylated (4,7 EO) 50KG 1.50

Castor Oil ethoxylated (47 EO) 50KG

1H1 2.00

TURKEY RED OIL 70% 50kg 1H2 0.10

Packing & Storage Uniperol Level SF ECO 10.000



Output


Prdoduct Name: Product Name: Magnafloc LT7991

Material Balance



Magnafloc 6.20

Packing & Storage Magnafloc LT7991 10.000



Output


Prdoduct Name: Irgalite SCM-L / SCI / HCB ap

Material Balance


DM water 4.860 Stage 1

Pigment Violet 3 Dispersion 30.100 Mixing & Clarrification

Acticid MBS 0.042

Packing & Storage Irgalite SCM-L ap 35.002



Output

Prdoduct Name: Irgalite HCR-L / HCR / VMA ap

Material Balance


DM water 1.030 Stage 1

Pigment Violet 44 Dispersion 13.950 Mixing & Clarrification

Acticide MV 0.020

Packing & Storage Irgalite HCR-L ap 15.000



Output

Prdoduct Name: Tamol M (REF)


Refined Naphthalene 3.820 Stage 1


Process Water 0.900


Formaldehyde 1.900 Condensation


Sodium hydro sulfite 0.005 at 70 - 80°C

Transfer for Drying


Tamol M (REF) 8.800



Output

Prdoduct Name: Tamol NNOL




Process Water 0.100


Urea 1.179 Condensation

Formaldehyde 2.464


Process Water 1.100


Sulphuric acid (98%) 0.300 at 70 - 80°C

Metaclaw CL liq 0.050

Transfer for Drying


Tamol NNOL 5.800



Output

Prdoduct Name: Tamol XNL


Process Water 6.205

Decaltal PIC A 1.375

Acetic acid 1.999


PEG 200 (Pluriol E200) 0.920

Sorbitol solution 1.368


Packing & Storage Tamol XNL 16.012



Output

Blending

Prdoduct Name: Relugan D / DI




Formaldehyde 1.400

Tamol M 2.300

Melamine 0.350


Urea 1.650 Addition at 60°C

Formaldehyde 1.300

Transfer for Drying


Relugan D / DI 5.000



Output

Heating ~90°C

Prdoduct Name: Basyntan AN




Process water 0.800 Heating ~ 100°C

Urea 1.078 At ~ 80°C

Process water 0.590

Formaldehyde (37%) 1.670



AN- Condensate 7.010 Condensation


Formic acid 0.275

Sodium sulphate 0.400

Packing & Storage Basyntan AN 18.264



Output

Prdoduct Name: Basyntan ANF




Heating ~ 100°C

Process water 0.770

Urea 0.690



Ammonia 0.300



Sodium bisulphite 1.200 Condensation


Aniline 0.225

Melamine 0.090

Urea 0.150

Formaldehyde 0.460 Heating ~ 90°C

Formic acid 0.025

Relugan AME 3.100 Addition at RT

Process water 0.315

Packing & Storage Basyntan ANF 15.370



Output

Addition at ~ 70°C

Prdoduct Name: Basyntan AN Condensate



Sodium metabisulphite 4.000 Mixing

Heating ~ 70°C

Process water 0.400

Formaldehyde 2.886


Aniline 0.672 Stage 2

Melamine 0.275

Process water 0.200 Addition at ~ 90°C

Urea 0.450

Process water 0.200

Formaldehyde 0.792

Packing & Storage Basyntan AN Condensate 14.025



Output

Prdoduct Name: Basyntan DLE




Heating ~ 100°C


Urea 1.244 1st Condensation


Sodium Hydroxide 0.356 Addition at ~ 80°C


Phenol 1.197 2nd Condensation


Formaldehyde (37%) 0.814 Addition at ~ 60°C


Process water 1.800



Sodium hydro sulfite 0.005

Packing & Storage Basyntan DLE 16.500



Output

Prdoduct Name: Basyntan FB DI




Heating ~ 100°C










Process water 1.800


Pthalic anhydride 0.300

Formic acid 0.300


FBL 1 3.600 Transfer for Drying

Reacted Mass 21.457 Water evaporation during drying 10.857

Basyntan FB DI 10.600



Output

Drying, Packing & Storage

Prdoduct Name: Basyntan FB. P



Phenol 2.500 Addition at ~ 60°C


Formaldehyde (37%) 2.550 Heating up to ~ 90°C

Sodium bisulphite 0.700 Stage 2

Urea 0.400


DLE solution 8.000

Process water 0.500

Metaclaw CL liq 0.100 Mixing at ~ 85°C



Process water 2.000




Basyntan FB DI 10.800



Output


Prdoduct Name: Basyntan XA




Heating ~ 100°C



Process water 0.920








Process water 2.000

Sodium hydro sulfite 0.005

Transfer for Drying


Basyntan XA 7.200



Output


Prdoduct Name: Floating Agent (DPW-EVH-1873


Pluronic PE-10100 9.500

Escaid 110 9.500

Oxooil 9N 1.000

Packing & Storage Floating Agent (DPW-EVH-1873 20.000



Output

Blending

DESCRIPTION OF SPARY DRYING AND PACKING PROCESS:

Spray drying of Pergasol Paper Dyes & Sokalan Paper and Water Treatment Chemicals to

produce dry powder from a liquid or slurry by rapidly drying with a hot air and maintaining

consistent particle size.

After drying, the powder then cooled up to ambient temperature and product quality to be

check as per products specification. After QA approval, powder products are transfer in bags

for packing as per customer requirement.


ANNEXURE: 4

WATER CONSUMPTION AND EFFLUENT GENERATION

WATER CONSUMPTION

Water consumption

QUANTITY (KL/DAY)

EXISTING ADDITIONAL TOTAL

Domestic 44 0 44

Gardening -- 7 7

Industrial Process 132 53 185

Boiler 150 0 150

Cooling 44 0 44

Washing 70 0 70

Total (Industrial) 396 53 449

Total Water Consumption KL/day 440 60 500

WASTEWATER GENERATION

Wastewater Generation

QUANTITY (KL/DAY)

EXISTING ADDITIONAL TOTAL

Domestic 35 0 35

Industrial Process 117 0 117

Boiler 14 0 14

Cooling 10 0 10

Washing 44 0 44

Total (Industrial) 185 0 185

Total Wastewater Generation KL/day 220 0 220

Note:

1) Domestic effluent shall be disposed off through septic tank& soak pit system or

shall be treated along with industrial effluent and discharged into GIDC

underground drainage system and conveyed to FETP (NCT).

2) The industrial effluent is treated & discharged into GIDC underground drainage

pipeline & conveyed to final pumping station, Ankleshwar and then FETP (NCT)

for further treatment. ultimately discharged into deep sea through NCT pipeline.

WATER BALANCE DIAGRAM:

220 KL/Day: After treatment sent to FCETP of M/s

NCT through GIDC Pipe line for final treatment &

disposal in to Deep Sea.

Raw Water: 500 KL/Day from GIDC

Domestic:

44 KL/Day

Process:

185 KL/Day Boiler:

150 KL/Day

Washing:

70 KL/Day Gardening:

7 KL/Day

Septic tank &

Soak Pit:

35 KL/Day

117 KL/Day 14 KL/Day 10 KL/Day

ETP: 220 KL/Day

Cooling

Tower:

44 KL/Day

44 KL/Day

ANNEXURE: 5

Details of Effluent Treatment Scheme

EFFLUENT TREATMENT PLANT PROCESS DESCRIPTION:

The waste water from plant (EM products) is goes by gravity to the plant sump (Cap. 33 KL)

from where its transfer by pump to 2 WWTP-1 vessel where pH of the waste water is

reduced to 2.0 to 3.0 by adding Hydrochloric Acid / Sulphuric acid and then polyelectrolyte

solution to improve the flocculation.

The precipitated & flocculated waste water is passed though filter press to remove

flocculated mass and the filtered waste water coming out from the filter press is sent to ETP

for further treatment.

Another stream of wastewater from production process (EP products) is collect in plant

sump of Cap. 15 KL from where its transfer to WWTP through pump.

The effluent from the production plant comes to collection cum equalization tank. The

collection cum equalization tank is fitted with agitator to keep mass in homogenized

condition. As and when collection tank is filled up pH of the effluent is checked and

corrected to PH 7.0 to 7.5 by caustic.

After neutralization, the wastewater is pass through filter press to remove the suspended

solid. The filtrated waste water coming out from the filter press is collected in MEE feed

tank and solid waste received from filter press is sent to solid waste storage shed for

disposal at TSDF

The wastewater from MEE feed tank is send to Multi Effect Evaporator for further treatment

as per flow chart. The MEE distillate is collect in final effluent storage tank for disposal and

salt received from the MEE is collected in bags & transfer solid waste storage shed for

disposal at TSDF.

a) Primary treatment flow diagram:

Solid Waste to Storage Shed

FP-03

Pump

FP-11

Treated waste water to

WWTP for further

treatment

HCl from Day Tank

Polyelectrolyte SolutionEffluent from Plant

Sump

Vent to Scrubber

WWT- 01

Cap: 20 KL

95

b) FLOW DIAGRAM OF EFFLUENT TREATMENT PLAN:

Lab Sump 10 kl

Primary

Treatment ETP Inlet Tank

75 kl

FP-01

FP-02

MEE Feed Tank 75 kl

MEE Cap. 330 kl/day

Activated Carbon

Bed

TSDF

MEE Waste Belt Filter

Solid waste storage

shed Process Cooling Tower Floor Washing

To FETP through underground

drainage

Filtrate Holding

Tank 140 kl

Holding Tank 90 KL

Condensate Holding Tank 100 kl

Final Discharge

Tank 10 KL

Gate Sump 10 kl

Emergency Tank 460 kl

Concentrate Recycle

Septic Tank

No. 2

FP-03

FP-04

Plant Sump 20 kl

Domestic

Waste Water

Septic Tank

No. 1

Tank No.1 15 kL

Tank No.2 15 kL

96

c) INSTRUMENT & FLOW DIAGRAM OF MEE PLANT:

97

ANNEXURE: 6

DETAILS OF HAZARDOUS SOLID WASTE MANAGEMENT AND DISPOSAL

Sr.

No.

Name of Hazardous

Waste Schedule Catg.

Quantity in MT/Annum Storage / Disposal

Existing Additional Total

1 Process Waste

Sludge/Residue

Containing Acid,

Toxic Metals,

Organic compounds

I 26.1 308 0 308 Organic waste from MEE Conc and Hyflow waste

from process: Disposal by incineration in

common incinerator facility such as

BEIL/GSPL/SEPPL or co-processing by giving to

RSPL

2 Spent carbon I 28.3

5 0 5 Disposal by incineration in common incinerator

facility such as BEIL / GSPL/SEPPL or

co-processing in Cement industries or by

giving to RSPL

3 Off Specification

Products

I 28.4 50 50 100 Disposal by incineration in common incinerator

facility such as BEIL / GSPL/SEPPL or

co-processing in Cement industries or by

giving to RSPL

4 Empty barrels

/containers/liners

Contaminated with

hazardous

chemicals /wastes

I 33.1 40.4 19.6 60 Non-Recyclable Plastic waste & used PPE,

Filter Plates, Cloths, Cartridges, waste insulation

materials, broken glass ware: Disposal by send

to authorized TSDF such as BEIL/SEPPL

5 Empty barrels

/containers/liners

Contaminated with

hazardous

chemicals /wastes

I 33.1 230 220 450 Disposal by send it to authorized

decontamination facility / recycler or reuse or

send back to supplier

6 Chemical sludge

from waste

water treatment

I 35.3 3000 0 3000 MEE Salt: Disposal by selling it to authorized end

user or disposal at TSDF (BEIL/SEPPL).

98

7 Chemical sludge

from waste

water treatment

I 35.3 1800 200 2000 ETP waste disposal by send to authorized TSDF

such as BEIL/SEPPL.

8 Used or Spent Oil I 5.1 10 5 15 Disposal by Reuse in plant & machinery as

lubricant or sell it to authorized re-refiners /

recycler.

9 E-waste -- -- 10 0 10 E-waste disposal by sell it to GPCB authorized

recycler.

10 Spent ion exchange

Resin

I 35.2 0 25 25 Spent ion exchange resin from waster

softening/DM plant: Disposal by sending to TSDF

of M/s. BEIL, Ankleshwar / SEPPL or send back to

supplier.

99

ANNEXURE: 7

DETAILS OF FLUE & PROCESS GAS EMISSION

DETAILS OF AIR POLLUTION CONTROL MEASURES

DETAILS OF FUEL CONSUMPTION: (NO CHANGE)

SR.

NO. NAME OF FUEL

EXISTING

QUANTITY

PROPOSED

QUANTITY TOTAL QUANTITY

1. Diesel 800 lit/day - 800 lit/day

2. LDO 100 lit/day - 100 lit/day

3. Natural Gas 5,000 SM3/ Hrs. - 5,000 SM

3/ Hrs.

4.

LDO /Furness OIL

(FO) *

20 KL / Day - 20 KL / Day

Note: * Required for MEE/Boiler/Spray dryer during emergency (in case non-availability of Natural Gas) only.

DETAILS OF FLUE GAS EMISSION FROM STACK: (NO CHANGE)

SR.

NO.

Stack ID STACK

ATTACHED TO

FUEL STACK HEIGHT

IN METER

PARAMETER PERMISSIBLE

LIMIT

1. 36889 Boiler-1

(Cap. 2.5 T/Hrs.)

Natural Gas /

Diesel/FO 33

SPM

SOX

NOX

150 mg/NM3

100 PPM

50 PPM

Boiler-3

(Cap. 0.8 T/Hrs)

Natural Gas /

Diesel/ FO

2. 68209 Boiler-2

(Cap. 3.0 T/Hrs.)

Natural Gas /

Diesel/ FO 30

3. 8920 DG set- 1

(Cap. 380 KVA) Diesel / LDO 14

4. 36892 DG set- 2


100

5. 68210 DG set- 3


6.

8921 Hot Air

Generator

For Spray Dryer –

1 (Cap. 32.5 Lakh

kcal/Hr.)

Natural Gas /

Diesel/ FO 27

7.

36890 Hot Air

Generator

For Spray Dryer –

2 (Cap. 8 Lakh

kcal/Hr.)

Natural Gas /

Diesel/ FO 27

8.

36891 Hot Air

Generator

For Spray Dryer –

3 (Cap. 8 Lakh

kcal/Hr.)

Natural Gas /

Diesel/ FO 32

9.

95041 Hot Air

Generator

For Spin Flash

Dryer – 1 Cap.

2.25 Lakh

kcal/Hr.

Natural Gas /

Diesel/ FO 27

10.

36898 Multiple Effect

Evaporator –

(Thermic fluid

heater)

Natural Gas /

Diesel /FO 32

101

DETAILS OF PROCESS GAS EMISSION FORM VENT:

SR.

NO.

Stack ID STACK

ATTACHED TO

STACK

HEIGHT IN

METER

AIR

POLLUTION

CONTROL

SYSTEM

PARAMET

ER

PERMISSIBLE

LIMIT

1. 36895 Dust Collector

For Spray Dryer – 1 27

Bag Filters PM PM-150mg/NM3






For Spin Flash Dryer

– 1

27

5. 36894 Vent attached to

process reactors 27 Alkali

Scrubber-1

HCL HCl-20 mg/NM3 6. 36893 Vent attached to

chemical charging

cabin.

27 Alkali

Scrubber-2

7. 68213 Vent attached to HCl

storage Tanks. 9 Alkali

Scrubber-3

8. Proposed Vent attached to

Laboratories fume

hoods & Lab

chemicals storage

cabinets

18

HCL HCl-20 mg/NM3

Note: Stack height is including building height.

102

ANNEXURE: 8

DETAILS HAZARDOUS CHEMICAL STORAGE FACILITY

Storage Details of Hazardous Chemicals

Tank No.

Name of Materials

Type of Hazard

Kind of Storage

Tank MOC

Max. Quantity

to be stored in

(M3)

Tank Dimensions in

(Mtr.) Dyek Dimensions in (Mtr.)

Dia (M)

Height (M)

Length (M)

Width (M)

Height (M)

B-5401 Morpholine Flammable Above Ground

Tank SS304 100 4.0 8.0 10.6 7.74 1.61

B-6610 Idle --- Above Ground

Tank SS304 100 4.0 8.0 10.45 7.7 1.64

B-5403 Aniline Toxic Above Ground

Tank SS304 100 4.0 8.0 10.4 7.75 1.6

B-5404 Diethanolamine Corrosive Above Ground

Tank MS 30 3.188 4.0 5.84 7.78 1.61

B-5405 Aniline Toxic Above Ground

Tank MS 30 3.188 4.0 5.85 7.75 1.57

B-5406 Sodium Hydroxide ~48%

Corrosive Above Ground

Tank MS 30 3.184 4.0 5.78 7.77 1.56

B-5407 Sodium Hydroxide ~ 48%


Tank MS 30 3.184 4.0 5.8 7.7 1.57

B-5408 Hydrochloric acid ~ 32%


Tank PP+FR

P 24 2.8 3.9 5.81 7.78 1.6

B-5409 Hydrochloric acid ~ 32%


Tank PP+FR

P 24 2.8 3.9 5.84 7.75 1.62

Finish Goods Storage Tank Farm Details (Existing)

B-6201 Tinopal Liquid Non

Hazardous Above Ground

Tank MSRL 20 2.75 3.3 6.34 6.62 1.52



Tank MSRL 50 3.5 5.2 6.29 6.63 1.6



Tank MSRL 50 3.5 5.2 6.24 6.6 1.6



Tank MSRL 20 2.75 3.3 6.3 6.55 1.62

103



Tank MSRL 20 2.75 3.3 6.33 6.63 1.57



Tank MSRL 20 2.75 3.3 6.31 6.63 1.57



Tank MSRL 50 3.5 5.2 6.24 6.64 1.63



Tank MSRL 50 3.5 5.2 6.23 6.67 1.57

104

Note: Remaining chemical stored in ware house.

Control measures provided for Raw Material Tank Farm:

1 Flame proof electrical fitting & intrinsically safe instruments are installed.

2 Flame arrestor installed on vent pipe with breather valve.

3 Earth fault relay trip installed for Morpholine tanker unloading pump having interlock with grounding of the tanker to make 100% grounding.

4 Road Tanker grounded before unloading for morpholine.

5 Convenient metallic SS hose pipes provided for tanker unloading for better connectivity.

6 Deep in let pipe provided inner side of the solvent tanks.

7 Check list is followed for loading & unloading.

8 Level indicator provided on the tank.

9 Adequate dyke wall is provided.

10 Leakage collection sump and pumping arrangement provided.

11 Fire (Foam / Powder) extinguisher, Foam monitors is provided.

12 F-30 coating provided for storage tanks.

13 Closed handling system is provided.

14 Acid proof tilelining / coating provided for HCL storage dyke wall.

15 Level switch provided for overfill protection

16 Scrubber system installed for HCL storage tank & used during road tanker unloading.

17 Dedicated pumps are provided and located with its close proximity to the respective tank to avoid unintentional mistake of mixing of chemicals.

18 Leakage / Spillage handling kit provided.

19 To avoid chemical exposure, closed handling system is provided.

20 Fire hydrant system provided.

Control measures provided for Finish liquid Tank Farm:

1 Convenient metallic SS hose pipes provided for tanker unloading for better connectivity.

2 Check list is followed for loading & unloading.

3 Level indicator provided on the tank along with auto on/off valve for high level.

4 Adequate dyke wall is provided.

5 Leakage collection sump and pumping arragment provided.

6 Fire extinguisher is provided.

7 F-30 coating provided for storage tanks.

8 Closed handling system is provided.

9 Dedicated pumps are provided and located with its close proximity to the respective tank to avoid unintentional mistake of wrong packing.

10 Leakage / Spillage handling kit provided.

11 To avoid chemical exposure, closed handling system is provided.

12 Fire hydrant system provided with foam & water monitors.

Control measures provided for Warehouse :

1 Fixed electrical fitting is provided. Lighting is installed between racks above the gangways & away from material storage to avoid heating to storage goods.

2 Electrical fitting tested periodically (i.e. electrical load thermo graphic temperature measurement, mechanical integrity of cables, physical condition of cable & other electrical appliances / installation.)

3 BT reach truck battery charging station is provided in well ventilation area

4 Appropriate passage, gangways provided.

5 Adequate portable fire extinguishers installed at noticeable position & kept easily accessible.

6 Fire hydrant system provided.

105

Fire Alarm System: Automatic fire detection & alarm system consists of Fire Detectors, Addressable Manual Call Points (MCP) & Hooters, somke /heat Detectors (Ware House) are placed at strategic locations and connected by cable to central control panel at ECC (Seurity Office).

7 Emergency exit provided.

8 A warehouse is used exclusively for storage activities. Loose chemical handling not allowed.

9 Chemical segregation is done based on compatibility.

10 In case of maintenance work, Ignition sources controlled by hot work permit system.

11 Natural & Eco ventilator is provided.

12 Proper drainage system is provided for used fire water collection.

13 Lightening arrestor installed and all area of warehouse is fully protected from lightening.

106

ANNEXURE 9

SOCIO - ECONOMIC IMPACTS

1) EMPLOYMENT OPPORTUNITIES

The manpower requirement for the proposed project is expected to generate some permanent

jobs and secondary jobs for the operation and maintenance of plant. This will increase direct /

indirect employment opportunities and ancillary business development to some extent for the

local population. This phase is expected to create a beneficial impact on the local socio-economic

environment.

2) INDUSTRIES

Required raw materials and skilled and unskilled labors will be utilized maximum from the local

area. The increasing industrial activity will boost the commercial and economical status of the

locality, to some extent.

3) PUBLIC HEALTH

The company regularly examines, inspects and tests its emission from sources to make sure that

the emission is below the permissible limit. Hence, there will not be any significant change in the

status of sanitation and the community health of the area, as sufficient measures have been

taken and proposed under the EMP.

4) TRANSPORTATION AND COMMUNICATION

Since the existing factory is having proper linkage for the transport and communication, the

development of this project will not cause any additional impact.

In brief, as a result of the proposed project there will be no adverse impact on sanitation,

communication and community health, as sufficient measures have been proposed to be taken

under the EMP. The proposed project is not expected to make any significant change in the

existing status of the socio - economic environment of this region.

107

ANNEXURE – 10

PROPOSED DRAFT TERMS OF REFERENCE:

1. Project Description

• Justification of project.

• Promoters and their back ground

• Project site location along with site map of 5 km area and site details providing various

industries, surface water bodies, forests etc.

• Project cost

• Project location and Plant layout.

• Water source and utilization including proposed water balance.

• Product spectrum (proposed products along with production capacity) and process

• List of hazardous chemicals.

• Mass balance of each product

• Storage and Transportation of raw materials and products.

2. Description of the Environment and Baseline Data Collection

• Micrometeorological data for wind speed, direction, temperature, humidity and rainfall in 5 km

area.

• Existing environmental status Vis a Vis air, water, noise, soil in 5 km area from the project site.

For SPM, RSPM, SO2, NOx.

• Ground water quality at 5 locations within 5 km.

• Complete water balance

3. Socio Economic Data

• Existing socio-economic status, land use pattern and infrastructure facilities available in the study

area were surveyed.

4. Impacts Identification And Mitigatory Measures

• Identification of impacting activities from the proposed project during construction and

operational phase.

• Impact on air and mitigation measures including green belt

• Impact on water environment and mitigation measures

• Soil pollution source and mitigation measures

• Noise generation and control.

• Solid waste quantification and disposal.

5. Environmental Management Plan

• Details of pollution control measures

• Environment management team

• Proposed schedule for environmental monitoring including post project

108

6. Risk Assessment

• Objectives and methodology of risk assessment

• Details on storage facilities

• Process safety, transportation, fire fighting systems, safety features and emergency capabilities to

be adopted.

• Identification of hazards

• Consequence analysis through occurrence & evaluation of incidents

• Disaster Management Plan.

7. Information for Control of Fugitive Emissions

8. Post Project Monitoring Plan for Air, Water, Soil and Noise.

9. Information on Rain Water Harvesting

10. Green Belt Development plan

109

ANNEXURE -11

GIDC WATER SUPPLY LETTER

110

ANNEXURE -12

TREATED EFFLUENT DISCHARGE – NCT MEMBER CERTIFICATE

111

ANNEXURE -13

BEIL MEMBERSHIP CERTIFICATE

113

ANNEXURE -14

GIDC PLOT ALLOTMENT LETTER

114

ANNEXURE -15

COPY OF CONSENT TO ESTABLISH/ NOC (2005)

117

COPY OF CONSENT TO OPERATE/ CCA (2017)

annexure- additional...

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