cheminform abstract: chiral broensted acid directed iron-catalyzed enantioselective friedel—crafts...

ChemInform 2010, 41, issue 22 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Indole derivatives R 0140 DOI: 10.1002/chin.201022094 Chiral Broensted Acid Directed Iron-Catalyzed Enantioselective Friedel—Crafts Alkylation of Indoles with β-Aryl α'-Hydroxy Enones. — A cooperative catalytic system established by the combination of an iron salt and a chiral Broensted acid effec- tively promotes the asymmetric Friedel—Crafts alkylation of indoles. — (YANG, L.; ZHU, Q.; GUO, S.; QIAN, B.; XIA*, C.; HUANG, H.; Chem. Eur. J. 16 (2010) 5, 1638-1645; State Key Lab. Oxo Synth. Sel. Oxid., Lanzhou Inst. Chem. Phys., Chin. Acad. Sci., Lanzhou, Gansu 730000, Peop. Rep. China; Eng.) — Bartels 22- 094

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Page 1: ChemInform Abstract: Chiral Broensted Acid Directed Iron-Catalyzed Enantioselective Friedel—Crafts Alkylation of Indoles with β-Aryl α′-Hydroxy Enones

www.cheminform.wiley-vch.de

201022.fm Page 102 Tuesday, May 4, 2010 2:13 PM

Indole derivativesR 0140 DOI: 10.1002/chin.201022094

Chiral Broensted Acid Directed Iron-Catalyzed Enantioselective Friedel—Crafts Alkylation of Indoles with β-Aryl α'-Hydroxy Enones. — A cooperative catalytic system established by the combination of an iron salt and a chiral Broensted acid effec-tively promotes the asymmetric Friedel—Crafts alkylation of indoles. — (YANG, L.; ZHU, Q.; GUO, S.; QIAN, B.; XIA*, C.; HUANG, H.; Chem. Eur. J. 16 (2010) 5, 1638-1645; State Key Lab. Oxo Synth. Sel. Oxid., Lanzhou Inst. Chem. Phys., Chin. Acad. Sci., Lanzhou, Gansu 730000, Peop. Rep. China; Eng.) — Bartels

22- 094

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