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    Chapter 5

    Determination of Rw

    Lecture notes for PET 370

    Spring 2012

    Prepared by: Thomas W. Engler,

    Ph.D., P.E.

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    Determination of Rw

    1. Archies Equation

    a. if water zone is present.

    b. Rwa Approach

    c. Resistivity - Porosity Crossplots

    2. Laboratorya. Direct measurement of representative

    water sample.

    b. Chemical analysis of water sample.

    3. Databasesa. Published regional water catalogs

    b. online:http://octane.nmt.edu/waterquality

    4. SP log

    5. Guess?

    Name Five Methods to determine Rw.

    k

    SSP

    mfeR

    weR 10*

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    Determination of Rw

    Preliminary Concepts

    Total conductivity is influenced by:

    porosity

    water saturation

    salinity

    salt composition

    temperature

    shale content

    metallic minerals; e.g., pyrite

    Water

    conductivity

    metXshXF

    nwSwC

    tC

    Which directly related to water conductivity?

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    Determination of Rw

    Preliminary Concepts

    Temperature Effects

    ionic conductivity - as temp. increases the

    conductivity increases. True or False?

    TrueSalinity Effects

    As salinity increases the conductivity will

    increase. True or False?

    Solution ppm NaCl resistivity,-moil or gas - 1.0 E6

    Potable water 500 10.0Fresh mud filtrate < 5,000 1.0 - 5.0

    Sea water 35,000 0.2Salt mud filtrate 75,000 0.1Saturated salt water 250,000 0.04

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    Determination of Rw

    How to determine formation temperature?

    The formation of interest is at 6500 ft. What is the formationtemperature?

    Tf= 112 F

    What is the geothermal gradient, (gG), in {deg.F/100 ft}?

    gG= 0.80 F/100 ft

    Lea County ,NM

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    Determination of Rw

    How to determine formation temperature?

    Near surface temperature, (To), is given regionally by:

    Gulf Coast 80 deg. F

    Oklahoma 60

    California 60

    Permian Basin 60

    Rocky Mtns. 50Alberta 35

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    Determination of Rw

    Location To, CAnkara, Turkey 6.7Aswan, Egypt 26.7

    Aberdeen, Scotland 8.9

    Bogota, Columbia 14.3

    Bombay, India 27.1

    Calgary, Alberta 5.4

    Caracas, Venezuela 20.5

    Changha, China 18.0

    Gabon, Africa 26.0

    Great Yarmouth, England 8.9

    Location To, CJakarta, Indonesia 26.7Lima, Peru 20.0Mendoza, Argentina 16.0

    Natal, Brazil 23.0

    Perth, Australia 18.0

    Prince George, B.C. 3.6

    Rio De Janeiro, Brazil 23.0Santa Cruz, Bolivia 15.0

    Siberia (west), Russia -4.0

    Trinidad, W.I. 29.7

    How to determine formation temperature?

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    Determination of RwHow to determine resistivity at Tf?

    Courtesy of Schlumberger

    Given a Resistivity = 0.1 ohmm at 75F what is

    The resistivity at 125 ?

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    Determination of Rw

    1. Archies Equation

    a. if water zone is present.

    b. Rwa Approach

    c. Resistivity - Porosity Crossplots

    2. Laboratorya. Direct measurement of representative

    water sample.

    b. Chemical analysis of water sample.

    3. Databasesa. Published regional water catalogs

    b. online:http://octane.nmt.edu/waterquality

    4. SP log

    5. Guess?

    Methods

    F

    oR

    wR

    k

    SSP

    mfeR

    weR 10*

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    Determination of Rw

    How to determine resistivity if a chemical

    composition is available?

    When drilling in evaporite and carbonate formations, the

    following type of problem can occur. A recovered water

    sample is classified as 200,000 ppm of saturated brine;

    i.e., only NaCl ions are present. At a formation

    temperature of 275F what is the Rw?

    Rw= 0.013 ohmm

    Using this Rw in log evaluations indicated the presence

    of oil; however, numerous production tests produced

    only water!

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    Determination of Rw

    How to determine resistivity if a chemical

    composition is available?

    Consider the effect of Mg++and Ca++ions, which are common

    in carbonates, on the computed values of Rw. Assuming a

    concentration of 50,000 ppm of Mg++ and Ca++ ions and

    100,000 ppm of Na Cl what is the Rw?

    Rw= 0.024 ohmm

    What is the increase in water saturation due to this variation in

    Rw?

    Ion Concentration Multiplier Equiv NaCl

    conc.Na+ and Cl- 100,000

    Ca++ 50,000

    Mg++ 50,000

    Total 200,000

    Ion Concentration Multiplier Equiv NaCl

    conc.

    Na+ and Cl- 100,000 1.00 100,000

    Ca++ 50,000 0.35 17,500Mg++ 50,000 -0.50 -25,000

    Total 200,000 92,500

    If n=2 in the Archie saturation equation, then

    2/1

    1

    2*12

    wR

    wR

    wS

    wS

    Therefore for this example Sw2= 1.36*Sw1or a 36% increase in water saturation.

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    Determination of Rw

    How to determine resistivity if a chemical

    composition is available?

    Empirical Ion Multiplier ChartSchlumberger

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    Determination of Rw

    1. Archies Equation

    a. if water zone is present.

    b. Rwa Approach

    c. Resistivity - Porosity Crossplots

    2. Laboratorya. Direct measurement of representative

    water sample.

    b. Chemical analysis of water sample.

    3. Databasesa. Published regional water catalogs

    b. online:http://octane.nmt.edu/waterquality

    4. SP log

    5. Guess?

    Methods

    F

    oR

    wR

    k

    SSP

    mfeR

    weR 10*

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    Determination of Rw

    waRwR

    wS

    :bysaturationwaterDetermine

    )minimum(waRwR:findzones,ofseriesaforCalculate

    FtR=waR

    thusincrease;Rt willbut the

    sametheisiprelationshFthezone,HCainIf

    F

    )

    o

    Ror(

    t

    R

    wR

    then100%),=(SwzonewaterainIf

    FtR

    2wS

    wR

    :EquationsArchie'Rearrange

    Rwa Technique

    Requirements:

    1. Rw is constant

    2. Lithology is constant

    3. A water zone exists and is identifiable

    Procedure:

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    Determination of Rw

    Rwa Technique Example

    = 32.8%

    = 26.4%

    = 28%

    = 30.3%A

    B

    C

    D

    E

    Ct = 2000

    Ct = 3000

    Ct = 3800

    Ct = 2400

    Zone F Ct,millimhos/m

    Rt, ohm-m Rwa,ohm-m Sw, %

    A 30.3 8.82 2000 0.50 0.057 65

    B 30.3 8.82 2000 0.50 0.057 65

    C 26.4 11.62 3000 0.33 0.028 92D 28.0 10.33 3800 0.25 0.024 100

    E 32.8 7.53 2400 0.42 0.056 65

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    Determination of Rw

    1. Archies Equation

    a. if water zone is present.

    b. Rwa Approach

    c. Resistivity - Porosity Crossplots

    2. Laboratorya. Direct measurement of representative

    water sample.

    b. Chemical analysis of water sample.

    3. Databasesa. Published regional water catalogs

    b. online:http://octane.nmt.edu/waterquality

    4. SP log

    5. Guess?

    Methods

    F

    oR

    wR

    k

    SSP

    mfeR

    weR 10*

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    Determination of Rw

    ResistivityPorosity Crossplots

    Pickett Plot

    Rearrange Archies Equation:

    wSlogn)

    waRlog(logm

    tRlog

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    Determination of Rw

    ResistivityPorosity Crossplots

    Pickett Plot Example

    Pickett Plot

    y = 0.3007x-0.5267

    R2= 0.7674

    0.01

    0.10

    1.00

    0.10 1.00 10.00 100.00

    Rt,ohm-m

    Porosit

    aRw=0.10

    Rw=0.12

    m=1/.5267=1.90

    Sw=50%

    Results:

    m = 1.90

    Rw = 0.12 ohm-m

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    Determination of Rw

    ResistivityPorosity Crossplots

    Hingle Plot

    m/1

    waR

    n

    wSm/1

    ]t

    R[

    Rearrange Archies Equation

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    Determination of Rw

    ResistivityPorosity Crossplots

    Hingle Plot Example

    Hingle Plot, m=1.90

    y = 3.4858x

    R2= 0.9836

    0.0

    0.1

    0.2

    0.3

    0.4

    0.5

    0.6

    0.7

    0.00 0.05 0.10 0.15 0.20

    Porosity

    Rt-1/

    Sw = 50%

    At = 10% y = 0.35 Ro = 7.4 ohmmF = 64

    Rw = 0.115 ohmm

    OOIP = 118 Mstb

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    Determination of Rw

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    Determination of Rw

    Bassiouni, Z: Theory, Measurement, and Interpretation ofWell Logs, SPE Textbook Series, Vol. 4, (1994)

    Chapter 4, Sec 4.5-4.6

    Chapter 12, Sec 12.2

    Chapter 13

    Schlumberger, Log Interpretation Chartbook, (1995)

    References

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    Determination of Rw

    How to determine formation temperature?

    During logging operations record the maximum temperature(TTD) at the bottom of the well (DTD).

    Assume a linear geothermal gradient, (gG), {deg.F/100 ft}

    Region of Diurnal andAnnual Variations

    ToTa

    TEMPERATURE

    DEPTH

    100

    gG

    {F/100}

    Tf, Df

    TfD

    )T(TT