updated form ienvironmentclearance.nic.in/writereaddata/modification/... · 2018. 2. 1. · nectar...

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NECTAR CROP SCIENCES PRIVATE LIMITED PLOT.NO. 54 TO 56, 58 TO 61, PHASE II IDA, PASHAMYLARAM, PATANCHERU MANDAL, SANGAREDDY DISTRICT, TELANGANA UPDATED FORM I Project No. 02181701 TOR Amnd February 2018 Nectar Crop Sciences Private Limited Plot No.s: 54 to 56, 58 to 61, Phase II IDA, Pashamylaram, Patancheru Mandal, Sangareddy District, Telanagana – 502 307 Phone: 08455224340 Fax: 08455224342 Email: [email protected] STUDIES AND DOCUMENTATION BY TEAM Labs and Consultants B115117 & 509, Annapurna Block, Aditya Enclave, Ameerpet, Hyderabad500 038. Phone: 04023748 555/23748616, Telefax: 04023748666 SUBMITTED TO MINISTRY OF ENVIRONMENT, FOREST AND CLIMATE CHANGE GOVERNMENT OF INDIA INDIRA PARYAVARAN BHAWAN, JOR BAGH ROAD, NEW DELHI

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Page 1: UPDATED FORM Ienvironmentclearance.nic.in/writereaddata/modification/... · 2018. 2. 1. · NECTAR CROP SCIENCES PRIVATE LIMITED PLOT.NO. 54 TO 56, 58 TO 61, PHASE II IDA, PASHAMYLARAM,

NECTAR CROP SCIENCES PRIVATE LIMITED PLOT.NO. 54 TO 56, 58 TO 61, PHASE II IDA, PASHAMYLARAM,  PATANCHERU MANDAL, SANGAREDDY DISTRICT, TELANGANA 

  

     

UPDATED FORM I   

    

                    

 

Project No. 0218‐17‐01 TOR Amnd February 2018  

 

Nectar Crop Sciences Private Limited Plot No.s: 54 to 56, 58 to 61, Phase II IDA, Pashamylaram,  Patancheru Mandal, Sangareddy District,  Telanagana – 502 307 Phone: 08455‐224340  Fax: 08455‐224342   E‐mail: [email protected] 

STUDIES AND DOCUMENTATION BY TEAM Labs and Consultants B‐115‐117 & 509, Annapurna Block, Aditya Enclave, Ameerpet,  Hyderabad‐500 038. Phone: 040‐23748 555/23748616, Telefax: 040‐23748666      

 

SUBMITTED TO MINISTRY OF ENVIRONMENT, FOREST AND CLIMATE CHANGE 

GOVERNMENT OF INDIA INDIRA PARYAVARAN BHAWAN, JOR BAGH ROAD, NEW DELHI  

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Form I        Page 1 

APPENDIX – I (See Paragraph – 6) 

FORM I I)  Basic Information S.No.  Item  Details 1  Name of the Project/s  Nectar Crop Sciences Private Limited 2  S. No in the Schedule   5 (b) –A category 3  Proposed capacity/area/length/tonnage to 

be handled/command area/lease area/number of wells to be drilled 

Proposal:  Exemption  of  Public  Hearing  as  the  Unit  is  located  in Notified  Industrial area of Pashamylaram established as Chemical Zone by APIIC, Andhra Pradesh. (Amendment for TOR condition no. 9)  TOR File No. J‐11011/87/2017‐IA.II (I)  dt. 31.05.2017  Area Existing: 5.31 Acres S.No Description Unit  Capacity

Permitted  After Expansion 

1 Agro Chemicals TPD  2.33  9*2 Formulations KLM  16.67  803 R&D and Pilot 

Plant  TPD  ‐‐‐  0.1

* It is proposed to manufacture 5 products at a time on campaign basis out of 20 Products Capital Cost for proposed expansion: Rs. 50 Crores. 

4  New/Expansion/Modernization  Expansion 5  Existing Capacity/Area etc.  Existing Capacity: 2.33 TPD   

Area Existing: 5.31 Acres 6  Category of Project i.e 'A' or 'B'  “A” 7  Does it attract the general condition? If yes, 

please specify Yes. The Unit is Located in Notified Industrial Estate / Area.  Critically Polluted Area of Pattancheru and Bollaram are located at a distance of 6.51 KM’s from the Site. 

8  Does it attract the Specific condition? If yes, please specify. 

No 

9  Location      Plot/Survey/Khasra No.  Plot No.s: 54 to 56, 58 to 61, Phase II IDA, Pashamylaram   Village  Pashamylaram Village   Tehsil  Patancheru Mandal   District  Sangareddy District   State  Telangana 

10  Nearest railway station/airport along with distance in km. 

Railway Station: Lingampally Railway Station– 19.3 Km Airport : Rajiv Gandhi International Airport –  42.3 Km    

11  Nearest Town, City, District Headquarters along with distance in kms. 

Town & District HQ – Sangareddy  ‐  24 KM 

12  Village Panchayats, Zilla Parishad, Municipal Corporation, Local body (complete postal 

Pashamylaram –Village Panchayat 

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Form I        Page 2 

address with telephone nos. to be given) 13  Name of the Applicant  Mr.Sukumar Reddy 14  Registered Address  Nectar Crop Sciences Ltd. 

(formerly known as Hyderabad Chemicals Products Ltd. ) Plot No.s: 54 to 56, 58 to 61, Phase II IDA, Pashamylaram, Patancheru Mandal, Sangareddy District, Telangana 

15  Address for Correspondence:     Name  Mr.Sukumar Reddy   Designation(Owner/Partner/CEO)  Managing Director   Address  Plot No.s: 54 to 56, 58 to 61, Phase II IDA, Pashamylaram, 

Patancheru Mandal, Sangareddy District, Telangana.  Pin Code  502 307   E‐mail  [email protected]    Telephone Number  08455 – 224340   Fax No.  08455 ‐ 224342 

16  Details of alternative Sites examined, if any. Location of these sites should be shown on a topo sheet. 

Not Applicable, as the proposed expansion is within the existing industry. 

17  Interlinked Projects  Not applicable 18  Whether separate application of interlinked 

project has been submitted?  ‐NA‐ 

19  If yes, date of submission   ‐NA‐ 20  If no, reason    21  Whether the proposal involves 

approval/clearance under: if yes, details of the same and their status to be given.                (a) The Forest (Conservation) Act, 1980?           (b) The Wildlife (Protection) Act, 1972?             (c) The C.R.Z Notification, 1991? 

‐NA‐ 

22  Whether there is any Government Order/Policy relevant/relating to the site? 

 No 

23  Forest land involved (hectares)   No 24  Whether there is any location pending 

against the project and /or land in which the project is propose to be set up?                           (a) Name of the Court                                            (b) Case No                                                         (c) Orders/directions of the Court, if any and its relevance with the proposed project. 

 No 

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Form I        Page 3 

(II)  Activity  1.  Construction,  operation  or  decommissioning  of  the  Project  involving  actions,  which  will  cause  physical changes in the locality (topography, land use, changes in water bodies, etc.) S.No.  Information/Checklist confirmation  Yes/No  Details thereof (with approximate quantities /rates, 

wherever possible) with source of information data 1.1  Permanent or temporary change in 

land use, land cover or topography including increase in    intensity of land use (with respect to local     land use plan)   

NO  The proposal is for expansion of existing agrochemicals and formulation unit. 

Existing Site Area: 5.31 acres 

1.2  Clearance  of  existing  land, vegetation and buildings? 

NO  The proposal is for expansion of existing agrochemicals and formulation unit. 

1.3  Creation of new land uses?  NO  Existing – industrial  

1.4  Pre‐construction investigations e.g. bore houses, soil testing? 

YES  Soil  test  done  and  soil  load  bearing  capacity established 

1.5  Construction works?      YES  Construction  activity  involves  creation  of  new production block, additional utilities  like, Chilling Plant etc  and  enhancement  of  Zero  Liquid Discharge  (ZLD) system.   

1.6  Demolition works?  NO  The  proposal  is  for  expansion  of  existing  unit.  The proposed  expansion  activity  involves  creation  of Production Block, Utilities, ZLD system, etc. 

1.7  Temporary  sites  used  for construction  works  or  housing  of construction workers? 

NO  Construction  labor  from  local  villages  shall  be employed. 

1.8  Above  ground  buildings,  structures or  earthworks  including  linear structures, cut and fill or excavations 

YES  Storage  facilities  shall be  constructed.     No major  cut and fill or excavation is anticipated. 

1.9  Underground works including mining or     tunneling? 

NO  No underground works like mining and tunneling.  

1.10  Reclamation works?  NO   1.11  Dredging?   NO   1.12  Offshore structures?  NO   1.13  Production  and  manufacturing 

processes? YES  Enclosed in Annexure – I 

1.14  Facilities for storage of goods or materials? 

NO  Raw  materials  and  solvents  shall  be  stored  with  in factory premises. Materials  in bags and drums will be stored in flame proof ware houses.  

1.15  Facilities for treatment or disposal of solid waste or liquid effluents? 

YES  High  TDS  and  low  TDS  effluents  are  treated  in  ZLD system. Organic  waste  is  sent  to  cement  plants  for  co‐ processing or to TSDF.  Details  of    waste  treatment  facilities    presented  in Annexure II   

1.16  Facilities for long term housing of operational workers? 

NO  Operational workers stay in surrounding villages. 

1.17   New road, rail or sea traffic during  YES  Construction materials shall be transported to the site.  

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Form I        Page 4 

construction or operation?  The  traffic  density  of  the  existing  connecting  road  is negligible. 

1.18   New  road,  rail,  air  waterborne  or other  transport  infrastructure including new or altered  routes  and stations, ports, airports etc? 

NO   

1.19   Closure  or  diversion  of  existing transport  routes  or  infrastructure leading  to  changes  in  traffic movements? 

NO   

1.20  New or diverted  transmission  lines opipelines? 

NO   

1.21  Impoundment, damming,  culverting, realignment or other changes to the hydrology      of  watercourses  or aquifers? 

NO   

1.22  Stream crossings?  NO   1.23  Abstraction  or  transfers  of  water 

form ground or surface waters? YES  Total water required shall increase from 25 KLD to 242 

KLD after expansion out of which 187 KLD shall be met from TSIIC  (Industrial  supply) and  the balance 55 KLD shall be recycled water.   

1.24  Changes in water bodies or the land surface affecting drainage or run‐off?

NO   

1.25  Transport  of  personnel  or materials for  construction,  operation  or decommissioning? 

YES  The  construction material  shall  be  drawn  from  local sources  within  10  km.    There  is  no  transport  of personnel, as the construction workers shall be drawn from local villages. 

1.26  Long‐term dismantling or decommissioning or restoration works? 

NO   

1.27  Ongoing activity during decommissioning which could have an impact on the environment? 

NO   

1.28  Influx of people to an area in either temporarily or permanently? 

YES  The  proposed  expansion  shall  increase  the employment potential. 

1.29  Introduction of alien species?  NO   1.30  Loss of native species or genetic 

diversity? NO  There are no major losses of tree/shrub species. 

1.31  Any other actions?  NO   

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Form I        Page 5 

2.   Use  of Natural  resources  for  construction  or  operation  of  the  Project  (such  as  land, water, materials  or energy, especially any resources which are non‐renewable or in short supply): S.No.  Information/checklist 

confirmation Yes/No  Details thereof (with approximate quantities /rates, 

wherever possible) with source of information data 2.1  Land especially undeveloped or 

agricultural land (ha) YES  Notified Industrial Development Area 

Nectar Crop Sciences Pvt. Ltd. (formerly known as Hyderabad Chemicals Products Ltd. ) Plot No.s: 54 to 56, 58 to 61, Phase II IDA, Pashamylaram, PataMandal, Sangareddy District, Telangana  

2.2   Water (expected source & competing users) unit: KLD 

YES  Total water required shall  increase from 25 KLD to 242 KLD after  expansion  out  of which  187  KLD  shall  be met  from TSIIC  (Industrial  supply)  and  the  balance  55  KLD  shall  be recycled water.   (Water Balance Enclosed in Annexure III) 

2.3  Minerals (MT)  NA   2.4  Construction material – stone, 

aggregates, sand / soil (expected source – MT) 

YES  Shall be sourced from the local villages. 

2.5  Forests and timber (source – MT) 

NO   

2.6  Energy including electricity and fuels (source, competing users) Unit: fuel (T), energy (MW) 

YES  The  required  energy  shall  be drawn  from  TSPDCL.  Existing standby DG sets of 2 X 225 KVA and 1 x 600 KVA.   No  additional  boilers  are  proposed.  It  is  proposed  to establish  Coal  fired  thermic  fluid  heater  of  capacity  6  lac. K.cal/hr and HSD fired thermic fluid heater of capacity 2 lac. K.cal/hr.  

Existing Boilers 1 x 5 TPH Coal Fired Boiler 1 x 3 TPH Coal Fired Boiler (Standby) 1 x 1.5 TPH Coal Fired Boiler  

2.7  Any other natural resources (use appropriate standard units) 

NA   

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Form I        Page 6 

3.   Use,  storage,  transport, handling or production of  substances       or materials, which  could be harmful  to human health or the environment or raise concerns about   actual or perceived risks to human health. S.No.  Information/Checklist confirmation  Yes/No Details thereof (with approximate quantities/rates, 

wherever possible) with source of information data 3.1  Use of substances or materials, which 

are hazardous (as per MSIHC rules) to human health or the environment (flora, fauna, and  water supplies) 

YES  Hazardous chemicals shall be used for manufacturing of  Synthetic  Organic  Chemicals  and  intermediates. MSIHC  rules  shall  be  followed  during  storage, transportation  and  handling  of  raw  materials. Hazardous chemicals and solvent shall be stored and handled in closed systems. 

3.2  Changes in occurrence of disease or affect disease vectors (e.g. insect or water borne diseases). 

NO   

3.3  Affect the welfare of people e.g. by changing living conditions? 

YES  Shall  increase  the  employment  potential  for  locals and affect the living conditions for betterment. 

3.4  Vulnerable groups of people who could be affected by the project e.g. hospital patients, children, the elderly etc., 

NO  No sensitive receptors are present  in the  immediate vicinity  of  the  site.  The  project  shall  not  have  any significant impact on vulnerable groups of people.  

3.5  Any other causes  NO    

4. Production of solid wastes during construction or operation or decommissioning (MT/month) S.No.  Information/Checklist confirmation  Yes/No Details thereof (with approximate quantities/rates, 

wherever possible) with source of information data 4.1  Spoil, overburden or mine wastes  NO   4.2  Municipal waste (domestic and or 

commercial        wastes) NO  Wastes  from  canteen,  other  commercial wastes  like 

paper, empty containers etc.   The canteen wastes and commercial wastes shall be in the range of 10 kg/day 

4.3  Hazardous wastes (as per Hazardous Waste  Management Rules) 

YES  Hazardous waste generation during construction shall be  limited  to waste  oils,  batteries  and  containers  of paints  etc.    The  quantity  of  hazardous  wastes generated  during  operation  contain  salts  from evaporators,  process  residue,  and  solvent  residues, ETP sludge and filtration media etc.   

4.4  Other industrial process wastes  YES  Enclosed at Annexure IV 4.5  Surplus product  NO   4.6  Sewage sludge or other sludge from 

effluent  treatment YES  Sludge from Effluent treatment plant and evaporation 

salts shall be sent to TSDF, Dundigal. 4.7  Construction or demolition wastes  NO  Construction  activities  involve  creation of Production 

Blocks, Utilities and enhancement of ZLD system. 4.8  Redundant machinery or equipment  NO   4.9  Contaminated soils or other materials  NO  All pipe  lines  including pipe  lines of     waste  streams 

are above ground  level  to eliminate  the possibility of any  contamination  due  to  seepage  and  for  ease  of maintenance. 

4.10  Agricultural wastes  NO   4.11  Other solid wastes  YES  Enclosed at Annexure IV 

 

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Form I        Page 7 

5. Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr) S.No.  Information/Checklist confirmation  Yes/No Details thereof (with approximate quantities/rates, 

wherever possible) with source of information data 5.1  Emissions from combustion of fossil 

fuels from stationary or mobile sourcesYES  Emissions details are enclosed in Annexure V 

5.2  Emissions from production processes  YES  Gaseous  emissions  from  process  are  ammonia,  HCl, SO2,  are  scrubbed  in  two  stage  scrubbers  while carbondioxide  and  oxygen  gases  are  let  out  into atmosphere  using  standard  operating  procedure. Hydrogen gas  let out  into atmosphere through water column.   

5.3  Emissions from materials handling including storage or transport 

NO  Material  transfer  takes  place  in  closed  pipeline systems using pumps with mechanical seals. 

5.4  Emissions from construction activities including plant and equipment 

YES  Dust  may  rise  during  transport  of  material  and construction  activity.    The  dust  emissions  shall  be mitigated by water  spraying on  the  roads within  the premises.  

5.5  Dust  or  odors  from  handling  of materials  including  construction materials, sewage and  waste 

NO  Domestic  wastewater  sent  to  zero  liquid  discharge system. 

5.6  Emissions from incineration of waste  NO  Organic waste  streams are sent  to cement plants  for co‐incineration. 

5.7  Emissions from burning of waste in open air (e.g. slash materials, construction debris) 

NO   

5.8  Emissions from any other sources  NO   

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Form I        Page 8 

6. Generation of Noise and Vibration, and Emissions of Light and Heat: S.No.  Information/Checklist confirmation Yes/No  Details thereof (with approximate quantities/rates, 

wherever possible) with source of information data with source of information data 

6.1  From operation of equipment e.g. engines, ventilation plant, crushers 

YES  Material transport and construction equipment shall be source  of  noise,  while  transfer  pumps,  vacuum systems,  DG  sets  are  the  sources  of  noise  during operation.   

6.2  From industrial or similar processes  YES   DG sets controlled by providing Acoustic Enclosures. 6.3  From construction or demolition  YES  Noise during construction shall be due to construction 

equipment and emergency DG sets.    6.4  From blasting or piling  NO   6.5  From construction or operational 

traffic NO  The  increased  traffic  shall  not  have  any  significant 

impact.  6.6  From lighting or cooling systems  NO   6.7  From any other sources  NO   

  7.Risks of contamination of land or water from releases of    pollutants into the ground or into sewers,   surface     waters, groundwater, coastal waters or the sea: S.No.  Information/Checklist confirmation Yes/No  Details thereof (with approximate quantities/rates, 

wherever possible) with source of information data 7.1  From handling, storage, use or 

spillage of hazardous materials NO  All the hazardous materials will be stored in MS drums, 

in  a  covered  shed  and  no  contamination  of  soil  is expected.  Same  philosophy  will  be  followed  for  the after expansion 

7.2  From discharge of sewage or other effluents to water or the land (expected mode and place of discharge) 

NO  All  the  waste  from  domestic  operations  sent  to  ZLD system. 

7.3  By deposition of pollutants emitted to air into the land or into water 

NO  All  the  emissions  from  process  are  controlled  by providing control equipment like scrubbers, Bag filters. 

7.4  From any other sources  NO   7.5  Is there a risk of long term build up 

of pollutants in environment from these     sources? 

NO  

 

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Form I        Page 9 

8.Risk of  accidents during  construction or operation of  the Project, which  could  affect human health or  the environment 

S.No.  Information/Checklist confirmation  Yes/No  Details thereof (with approximate quantities/rates, wherever possible) with source of information data 

8.1  From explosions, spillages, fires etc from storage, handling, use or production of hazardous substances 

YES  All  Inbuilt  Safety  precautions  will  be adopted  and  there  will  not  be  any damage  to  environment  or  human health  

8.2  From any other causes  NA   8.3  Could the project be affected by natural disasters 

causing environmental damage (e.g.     Floods, earthquakes, landslides, cloudburst etc)? 

NO   

 9.Factors which should be considered (such as consequential development) which could lead to environmental effects or the potential for cumulative impacts  with  other existing or planned activities in the locality S. No.  Information/Checklist confirmation  Yes/No  Details thereof (with approximate 

quantities/rates, wherever possible) with source of information data 

9.1  Lead to development of supporting.   facilities, ancillary development or development stimulated by the project which could have impact on the environment e.g.: • Supporting infrastructure (roads, power supply, waste or waste water treatment, etc.) •      housing development •      extractive industries •      supply industries •      other 

YES  The  project  shall  enhance  the  socio economic  status  of  the  area  by increasing  the  demand  for  housing, improving the employment.  

9.2  Lead to after‐use of the site, which could haven impact on the environment 

NO   

9.3  Set a precedent for later developments  NO   

9.4  Have cumulative effects due to proximity to other existing or planned projects with similar    effects 

NO  The  baseline  environmental  status  of the  surrounding  areas  is  within  the prescribed  limits as observed  from the Secondary data. 

 

           

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Form I        Page 10 

(III)  Environmental Sensitivity S.No.  Areas  Name/ 

Identity Aerial  distance  (within  15  km.) Proposed project location boundary 

1   Areas  protected  under  international  conventions,  national  or  local  legislation  for  their  ecological,  landscape, cultural or other related value 

NA   

2  Areas  which  are  important  or  sensitive  for ecological  reasons  ‐  Wetlands,  watercourses  or other  water  bodies,  coastal  zone,  biospheres, mountains, forests 

YES  Nakkavagu Stream ‐8 Km‐E Kotta Cheruvu ‐0.4Km‐N Pedda Cheruvu‐4Km‐NE 

3  Areas  used  by  protected,  important  or  sensitive  species  of  flora  or  fauna  for  breeding,  nesting, foraging, resting, over wintering, migration 

NA     

4   Inland, coastal, marine or underground waters  NO   5   State, National boundaries  NO   6   Routes or facilities used by the public for access to 

recreation or other tourist, pilgrim areas NO   

7   Defense installations  NO   8   Densely populated or built‐up area  YES  Isnapur Village ‐ 3.5 Km. 9   Areas  occupied  by  sensitive man‐made  land  uses  

(hospitals,  schools,  places  of  worship,  community facilities) 

NA  3.5 Km from the site 

10  Areas  containing  important,  high  quality  or  scarce resources  (ground  water  resources,  surface resources,  forestry,  agriculture,  fisheries,  tourism, minerals) 

NO   

11  Areas  already  subjected  to  pollution  or  environmental  damage.  (those where  existing  legal environmental standards     are exceeded) 

NO   

12   Areas  susceptible  to  natural  hazard  which  could  cause  the  project  to  present  environmental problems  (earthquakes,  subsidence,  landslides, erosion,  flooding  or  extreme  or  adverse  climatic conditions) 

NO       

  (IV) Proposed Terms of Reference for EIA studies      Scope of Work of EIA 

The standard terms of reference (page 159‐162) issued by the Ministry of Environment Forest and Climate hange shall  be  followed  for  preparation  of  EIA  report.    Any  additional  study  proposed  by  the  SEAC  shall  also  be completed. 

Ref:  Standard  Terms  of  Reference  (TOR)  for  EIA/EMPO  report  for  projects/activities  requiring  environmental clearance under EIA notification, 2006, MoEFCC, GOI, and April 2015. 

 

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NECTAR CROP SCIENCES PRIVATE LIMITED PLOT.NO. 54 TO 56, 58 TO 61, PHASE II IDA, PASHAMYLARAM,  PATANCHERU MANDAL, SANGAREDDY DISTRICT, TELANGANA 

 

         

ANNEXURES 

        

              

    

SUBMITTED TO MINISTRY OF ENVIRONMENT, FOREST AND CLIMATE CHANGE 

GOVERNMENT OF INDIA INDIRA PARYAVARAN BHAWAN, JOR BAGH ROAD, NEW DELHI 

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                                      Form I Annexures

            Page 1

Fig

A.1

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n M

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f M /

s. N

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es P

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                                      Form I Annexures

            Page 2

Fig

A.2

Lay

out o

f M /

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r Cro

p Sc

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                                      Form I Annexures

            Page 3

ANNEXURE - I

M/s. Nectar Crop Sciences Pvt. Ltd. (formerly known as Hyderabad Chemicals Products

Ltd.) located in Notified Industrial area of Pashamylaram at Plot No. Plot No.s 54 to 56, 58

to 61, Phase II IDA, Pashamylaram, Patancheru Mandal, Sangareddy District, Telangana

obtained consent and authorization (CFO) for manufacturing of 70 TPM of vide Letter No.

TSPCB/RCP/SR-I/11597/CFO/HO/2015-2743 dated 24.02.2016. It is proposed to increase

the manufacturing capacity of agro chemicals from 2.33 TPD to 9 TPD, formulations 16.67

KLM to 80 KLM and proposed R&D and Pilot plant of capacity 100 kg/day in existing site

area of 5.31 acres. Capacity before and after expansion is presented in Table A-1.

Table A-1 Manufacturing Capacity S.No Name of Product CAS No. Capacity (TPD)

Permitted* After Expansion

1 Acephate 30560-19-1 0.83 2.53 2 Imidachlopride 138261-41-3 0.50 0.14 3 Thiomethoxam 153719-23-4 0.50 2.0 4 Acetamiprid 160430-64-8 0.33 0.07 5 Buprofugin 69327-76-0 0.15 2.25 6 Pretilachlor 51218-49-6 0.50 1.5 7 Tricyclazole 41814-78-2 0.28 0.14 8 Hexaconazole 79983-71-4 0.17 0.06 9 Clodinofop 105512-06-9 0.33 0.72 10 Ethion 563-12-2 0.44 0.07 11 Cloquintocet Mexyl 99607-70-2 0.15 0.06 12 Sulfosulfron 141776-32-1 0.10 0.06 13 Fipronil 120068-37-3 0.07 0.01 14 Dimethoate 60-51-5 0.15 0.25 15 Thiodicarb 59669-26-0 0.07 0.03 16 Bispyribac Sodium 125401-92-5 -- 0.06 17 Quizalofop Ethyl 76578-14-8 -- 0.04 18 Pymetrozine 123312-89-0 -- 0.04 19 Azoxystrobin 131860-33-8 -- 0.04 20 Bifenthrin 82657-04-3 -- 0.04

Total Worst Case: 5 Products on campaign basis after expansion

2.33 9

R&D and Pilot Plant Products -- 0.1 Formulations 16.67 KLM 80 KLM

* At any point of time only 4 products are manufactured

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                                      Form I Annexures

            Page 4

List of By – Products S.No Name of Product Name of By-Product Capacity (Kg/day)

Permitted After Expansion 1 Ethion Sodium Bromide 124.08 19.4 2 Acephate Ammonium Sulphate 332.36 1196.5 3 Fipronil Lean HCl 20.33 4.2 4 Pretilachlor Lean HCl (20-25%) 200 600

Process Description of Imidachlopride

Reaction Schemes

M o l .  W t .   2 5 5 . 6 6

NC l

C H 2C l

H N N H

NN O 2

C C M P N I INC l

C H 2 N N H

NN O 2

I m i d a c l o p r id

H C l

M o l .  W t .   3 6 . 5

M o l .  W t .   1 3 0 . 1 1M o l .  W t .   1 6 2 . 0 5

Process Description:

2-chloro-5-chloromethyl pyridine (CCMP) reacts with N-Nitroiminoimidazoline (NII) in

presence of a solvent Dimethylformamide (DMF) to get Imidacloprid. The reaction

medium is neutralized with potassium carbonate. DMF is recovered by distillation and to

the residue water is added and filtered to obtain the product as wet cake. The product is

dried and packed.. The process flow diagram is presented in Fig A.3 and material balance is

presented in Table A.3.

Fig A.3 Process Flow Diagram of Imidachlopride 

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                                      Form I Annexures

            Page 5

Table A-3 Material Balance of Imidachlopride Input Quantity

(Kg/day) Output Quantity

(Kg/day) Remarks

2-chloro-5-chloromethyl pyridine (CCMP)

91.8 Imidacloprid 139 Final Product

N-Nitroimino imidazoline

73.7 DMF

Water 500 DMF Recovered 268 Recovered & reused Dimethyl Formamide (DMF)

275 DMF Loss 0.9 Fugitive Loss

Caustic Lye (48%) 45.3 DMF in Residue 6 Solvent in residue Potassium Carbonate 8.3 CCMP 3.8 Organic Residue N-Nitroimino

imidazoline 3 Organic Residue

Sodium Chloride 31.8 To wastewater Potassium Carbonate 8.3 To wastewater Wastewater 533 To wastewater Total Input 994.1 Total Output 994.1

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                                      Form I Annexures

            Page 6

ANNEXURE – II: Wastewater Treatment Facilities

The main sources of effluent generation from the plant are from process, floor washings,

blowing downs from boiler and cooling tower, and domestic effluents. The effluents

generated in the process, separation techniques and during purification contain organic

residues of raw materials, solvents, and products. Some of the raw materials used in the

process are also inorganic in nature. Hence the effluents contain both organics and in-

organics in various quantities leading to high COD and TDS levels respectively. The

quantity of effluents generated and mode of treatment is presented in Table A-4.

Table A-4 Quantity of Effluent Generated and Mode of Treatment

Description Quantity (KLD) Mode of Treatment Permitted After

Expansion HTDS Effluents

Process 6.1 33.5 Sent to Stripper. Stripper condensate shall dispose to cement industries for co-processing/TSDF. Stripper bottom sent to MEE followed by AFTD. Condensate from MEE shall be sent to biological treatment plant followed by RO. RO rejects sent to MEE and permeate is reused in cooling towers make-up.

Washings 0.28 2 Scrubber Effluent 1 5

Total I 7.38 40.5 LTDS Effluents

Boiler Blow downs 3 3 Sent to Biological Treatment System followed by RO. RO permeate reused for cooling tower makeup. RO rejects sent to MEE.

Cooling Tower Blow downs

8

Domestic 1.5 8 Total II 4.5 19 Grand Total (I+II) 11.88 59.5

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                                      Form I Annexures

            Page 7

ANNEXURE – III: Water Balance

Water is required for process, scrubbers, washing, cooling tower makeup, steam

generation and domestic purposes. The required water shall be drawn from TSIIC

(Industrial Supply) in addition to reuse of treated wastewater. The total water

requirement increased from 25 KLD to 242 KLD after expansion out of which 187 KLD

shall be met from TSIIC (Industrial supply) and the balance 55 KLD shall be recycled

water. Total water balance after expansion is presented in Table A-5.

Table A-5 Total Water Balance – After Expansion Purpose INPUT (KLD) OUTPUT (KLD)

Fresh Water Recycled Water Loss Effluent Process 30 33.5* Washings 2 2 Scrubber 5 5 Boiler Feed 50 47 3 Cooling Tower 75 55 90 8 Domestic 10 2 8 Gardening 15 15 Gross Total 187 55 186 59.5 Total 242 245.5

* Process effluents contain soluble raw materials, byproducts, solvents etc.

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                                      Form I Annexures

            Page 8

ANNEXURE – IV: Solid Waste

Solid wastes are generated from the process shall be sent to TSDF/ Cement Industries for Co-

incineration. The inorganic residue, evaporation salts from MEE and ATFD and ETP Sludge

shall be sent to TSDF. Total solid waste generated and mode of disposal is presented in Table

A-6.

Table A-6 Total Solid Waste Generated and Mode of Disposal

S.No Description Units Quantity Mode of Treatment/Disposal Permitted After

Expansion 1 Ash from Boiler TPD 11 Sold to Brick

manufactures and cement plants

2 Organic residue TPM 5.985 13.42 Sent to TDSF/Cement Plants for Co-incineration

Stripper Distillate KLM 3 3 Solvent Residue TPM 6 12.85 4 Spent Solvents TPM 16.5 41.5 5 Spent Carbon TPM 0.32 Sent to TSDF/Cement

Industries 6 Evaporation salts TPM 5.973 19.25 Sent to TSDF 7 ETP Sludge TPM 2.65 4.3 Sent to TSDF 8 Detoxified

containers & container liners

No.s/ month

80 200 Sold to authorized vendors

9 Waste oil LPM 150 220 Sent to Authorized Recyclers

10 Used batteries No.s/year 20 Sent to Authorized Recyclers

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                                      Form I Annexures

            Page 9

ANNEXURE – V: Stack Emissions Details

The sources of air pollution from the plant are existing 5 TPH and 1.5 TPH Coal fired

boiler and DG set of 2 x 225 KVA, 1 x 600 KVA and 1 x 125 KVA capacity. The required

steam for process and ZLD system shall be met from exisitng 5 TPH and 1.5 TPH coal fired

boiler, while 1 x3 TPH coal fired boiler will be kept as standby. Bag filter is provided for 5

TPH coal fired boiler and multicone cyclone separator for 1.5 TPH coal fired boiler as air

pollution control equipment. It is proposed to establish 6 lac k.cal/hr coal fired and 2 lac

k.cal/hr HSD fired thermic fluid heater for proposed expansion. Muticone cyclone

separators will be provided as APC for coal fired thermic fluid heater. DG set provided

with stack heights based on the CPCB formula for effective stack height.

Stack Emission Details

S. No

Stack Connected to Stack Ht (m)

Dia of stack at top(m)

Temp. of exhaust

gases (0C)

Exit Velocity (m/sec)

Pollutant Emission Rate (g/sec)

PM SO2 NOx Permitted

1 1 x 5 TPH Coal Fired Boiler

30 0.65 146 5.57 0.4 0.52 0.18

2 1 x 3 TPH Coal Fired Boiler*

30 0.83 128 8.5 0.15 0.14 0.21

3 1 x 1.5 TPH Coal Fired Boiler

30 0.6 160 6 0.02 0.03 0.12

4 1 x 600 KVA DG set**

5 0.2 200 6.8 0.002 0.025 0.04

5 2 x 225 KVA DG sets**

4 0.2 150 7 0.001 0.02 0.03

6 1 x 125 KVA DG set 2.5 0.15 320 5 0.001 0.01 0.02 Proposed

1 6 Lac K.cal/hr Coal fired Thermic Fluid Heater

20

0.3 170 8.5 0.07 0.15 0.18

2 2 Lac K.cal/hr HSD fired Thermic Fluid Heater

10 0.25 165 6.2 0.05 0.12 0.14

* Standby Boiler **DG sets will be used during load shut down period.

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STUDIES AND DOCUMENTATION BY TEAM Labs and Consultants QCI: MoE&F OM, List A-1, S.No. 150. (An ISO 9001:2008, ISO 14001:2004 & OHSAS 18001:2007 Certified Organization) B-115, Annapurna Block, Aditya Enclave Ameerpet, Hyderabad-500 038. Phone: 040-23748 555/616, Telefax: 040-23748666 Email: [email protected]