stoichiometric relationship atomic structure periodicity energetics

2
1.2 3 Formula 1.4 4.5 Mass and gases in reactions 1.5 2 Solutions 2.1 1 The atom 2.2 1 Mass spectrometer 2.3 2 Electron arrangement 12.1 3 Electron configuration 1.3 1 Equations 1.1 2 The mole concept 5.2 3 Calculation of enthalpy changes 5.3 2 Hess’ law 5.4 2 Bond enthalpies 1.1 1 Particulate nature of matter 1.2 2 The mole concept 1.3 10.5 Reacting masses and volumes 2.1 2 Nucleus 2.2 4 Electron configuration 12.1 Electrons in atoms 2 12.5 13.5 4 6

Upload: vudien

Post on 03-Jan-2017

227 views

Category:

Documents


3 download

TRANSCRIPT

Page 1: Stoichiometric Relationship Atomic structure Periodicity Energetics

1.23Formula

1.44.5Mass and gases in reactions

1.52Solutions

2.11The atom

2.21Mass spectrometer

2.32Electron arrangement

12.13Electron con�guration

1.31Equations

1.12The mole concept

5.23Calculation of enthalpy changes

5.32Hess’ law

5.42Bond enthalpies1.1 1 Particulate nature of matter

1.2 2 The mole concept

1.3 10.5 Reacting masses and volumes

2.1 2 Nucleus

2.2 4 Electron con�guration

12.1 Electrons in atoms2

12.5 13.5

4 6

3.11The periodic table

4.12Ionic bonding

5.11Exothermic and endothermic reactions

8.12Theories of acids and bases

9.12Introduction to oxidation and reduction

9.21Redox equations

9.31Reactivity

9.41Voltaic cells

9.52Electrolytic cells

8.32Strong and weak acids and bases

8.21Properties of acids and bases

8.41The pH scale

6.12Rates of reaction

7.11Dynamic equilibrium

7.21The position of equilibrium

6.23Collision theory

4.26Covalent bonding

4.32Intermolecular forces

4.40.5Metallic bonding

4.52Physical properties

3.22Physical properties

3.33Chemical properties

13.12Trends across period 3

14.11Shapes of molecules and ions

14.22Hybridization

14.32Delocalization of electrons

13.22First-row d-block elements

3.1 1 The periodic table

4.1 2.5 Ionic bonding and structure

4.2 3 Covalent bonding

4.3 4 Covalent structures

4.4 3 Intermolecular forces

4.5 1 Metallic bonding

3.2 5 Periodic trends

13.1 First-row d-block elements2

14.1Covalent bonding and electron domain and molecular geometries

5

14.2 Hybridization2

13.2 Colored complexes2

15.11.5Standard enthalpy changes of reactions

15.22.5Born-Haber cycle

15.31.5Entropy

15.42.5Spontaneity

16.13Rate expression

16.21Reaction mechanism

16.32Activation energy

17.12Liquid-vapor equilibrium

17.22The equilibrium law

6

4

12.5 13.5

5 7

8

8

5 7

7

9

5 4.5

18.14Calculations involving acids and bases

18.22Bu�er solutions

18.31Salt hydrolysis

18.42Acid-base titrations

18.51Indicators

10

6 6

4 4

19.13Standard electrode potentials

19.22Electrolysis

5

3 2

6

4 20.11Introduction

10.14Introduction

10.22Alkanes

10.32Alkenes

10.41Alcohols

11.11Uncertainties and errors in measurements

11.20.5Uncertainties in calculations

11.30.5Graphical techniques

10.52Halogenoalkanes

10.61Reaction pathways

20.22Nucleophilic substitution reactions

20.31Elimination reactions

20.42Condensation reactions

20.51Reaction pathways

20.63Stereoisomerism

10 12

11

6

8

8

12

6 6.5

7

2

102

5.1 4 Measuring energy changes

8.1 1.5 Theories of acids and bases

8.2 1 Properties of acids and bases

8.4 2 Strong and weak acids and bases

8.3 1 The pH scale

8.5 1 Acid deposition

9.1 5 Oxidation and reduction

9.2 3 Electrochemical cells

10.1 4 Fundamentals of organic chemistry

20.1 8 Types of organic reactions

20.2 1 Synthetic routes

20.3 3 Stereoisomerism

19.1 6 Electrochemical cells

11.1 1.5 Uncertainties and errors in measurements and results

11.2 0.5 Graphical techniques

11.3 8 Spectroscopic identi�cation of organic compounds

21.1 2 Spectroscopic identi�cation of organic compounds

10.2 7 Functional group chemistry

5.2 3 Hess’ Law

5.3 2 Bond enthalpies

6.1 7 Collision theory and rates of reaction

7.1 4.5 Equilibrium

15.1 Energy cycles4

16.1 Rate expression and reaction mechanism

4

16.2 Activation energy2

17.1 The equilibrium law4

18.1 Lewis acids and bases1

18.2 Calculations involving acids and bases

4

18.3 pH curves5

15.2 Entropy and spontaneity3

+ mixtures, atom economy

+ applications: ozone

+ applications: PET- instrumentation of MS

- electron arrangement- convergence (to HL)

+ row 3 oxides (from HL)

+ colors, added details

+ graphene, resonances

+ formal charges, ozone application

+ application: ozone

+ enthalpy of solution, hydration

+ application: drugs

+ ?

+ calculations by GDC

+ Q (reaction quotient)

+ ΔG = - R T lnK, relationship with Q

- Lewis acids and bases (to HL)

- pOH, Kw(T)

+ Kw(T)

+ Winkler titration (dissolved O2), many applications

+ fuel cells and many applications

+ ΔG = - n F Eo, cells in series

+ alkyne, aromaticity, IUPAC of esters (but not N-containing FGs)

+ benzene

+ reductions, Markonikov additions, electrophilic substitution

from max 2 steps to max 4 steps

+ E/Z nomenclature

IHD; MS; IR; NMR (only analysis)

NMR multiplicity, X-ray crystallography.

jon.hk

2016

Stoi

chio

met

ric

Rela

tions

hip

Atom

ic st

ruct

ure

Perio

dicit

y

Ener

getic

sKi

netic

sEq

uilib

rium

Redo

x pro

cess

esOr

gani

c che

mist

ryM

easu

rem

ents

Acid

s and

bas

es

Stru

ctur

e and

bon

ding

Page 2: Stoichiometric Relationship Atomic structure Periodicity Energetics

Lab (60)

Core (95)Core (80)

2009 2016

HL (60)

HL (55)

Opt (25)Opt (45)Lab (60)