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    The School of Chemical and Environmental Engineering

    Hazard analysis

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    Hazard analysis

    Based on hazard identification

    Determines likelihood of accidents to occurDone by one-two people

    Time and effort consuming

    Quantitative and qualitative techniques

    The School of Chemical and Environmental Engineering

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    Quantitative hazard analysis

    FrequencyBased on previous accident

    experience or modeling

    Provides quantifiablelikelihood of accident

    Two processes in parallel

    ConsequencesEffects of likely accident

    Impact on personnel,

    equipment, structures,

    environment

    Based on modeling,

    accident experience or

    judgment

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    Quantitative hazard analysis

    Various risk representations are possible

    Risk to life classified in two groups:

    Individual risk

    Group risk

    Frequencies and consequences of each event

    combine to give a measure of overall risk

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    Equipment Reliability

    P(t) : probability that a component working at

    t=0 has a life equal or less than t

    R(t)= 1-P(t) : reliability of a component

    Failure density function :

    f(t)dt : probability of failure between t and t+dt

    Probability of failure between t1 and t2:

    dt

    tdPtf

    dttfttP t2

    1121

    ,

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    Equipment reliability

    Hazard rate, H

    Test interval, T

    Demand rate, D

    Failure rate, m

    Fractional Dead Time, fdt (= Probability!)

    PPT

    Tfdt u

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    Equipment Reliability

    Assume constant (average) failure rate: tetR mt

    etPm1)(

    tetf mm )(

    t dttftR

    0

    exp m

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    Equipment Reliability

    Therefore, probability of failure between t1

    and t2:

    Mean time to failure (MTF):

    2121

    21 ,tt

    t

    t

    t eedtettP mm

    0

    1

    mdtttfMTF

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    Equipment Reliability

    Tu dttPT0

    T dttPTfdt0

    1

    TeTPtPfdt mm 11

    1)(

    FormT small: and ttP m TPfdt m2

    1

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    Equipment reliability

    Protective system that never fails: H=0

    No protective system: H=D

    Otherwise, hazard occurs during dead time:

    H = D x fdt if D and fdt smallH = m(1-e-DT/2)

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    Equipment reliablity

    H = D x fdt is linearisation

    H = m(1-e-DT/2

    )If DT/2 is small: H = 0.5mDT

    If DT/2 is large : H = m

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    Occurrence estimation

    Example: relief valve (failure remains hidden)

    Test interval, T : 1 year

    Fail-danger fault occurrence, m : 0.01/year

    Demand rate : 1/year

    Fractional dead time fdt = mT

    Hazard rate H = 1 x 0.01 x x 1 = 0.005/year

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    Hazard probability determination

    Two common methods:

    Fault tree analysis (FTA)

    Event tree analysis (ETA)

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    Fault tree analysis (FTA)

    Sequence of events leading to a hazardous

    incident

    Start at fault and trace back all causes

    AND gate: coincident inputs for system failure

    OR gate: system failure occurs by failure of

    any input

    Originates in aerospace industry

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    Fault tree analysis (FTA) Steps in a fault tree analysis

    1. Define the top event PRECISELY (e.g. temperature in

    reactor too high). explosion in process too vague2. Define the existing event. What are the present

    conditions when top event occurs

    3. Define unallowed events (e.g. natural disasters, wiring

    failure,)

    4. Define physical bounds of the process

    5. Define equipment configuration (normal operation state,

    valves open or closed,)

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    Fault tree analysis (FTA) Steps in a fault tree analysis

    6. Define the level of resolution (consider piece of

    equipment or its components)7. Draw fault tree

    8. Use AND and OR gates to define relation of events

    9. Continue developing tree until all branches areterminated by basic, undeveloped or external events

    10.Calculate probability of top event

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    OR

    Tank empty

    Line broken

    Fault tree analysisExample: car fails to start

    Car fails

    to start

    No petrol

    No spark

    Engine not

    turning

    Other

    Pump failed

    Line blocked

    Flat battery

    Faulty distributor

    Dirty plugs

    Starter failed

    Other

    Battery too old

    OR

    OR

    OR

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    Logic rulesGate Input Pairing Output calculation Output Units

    OR PA or PB P = PA + PB - PA xPB Probability

    mA ormB m = mA + mB Frequency 1/time

    PA

    ormB Not permitted

    AND PA and PB P = PA x PB Probability

    mA and mB Convert mB to PB

    PA and mB f = mA x PB Frequency 1/time

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    Two protective systems in parallel

    PA and PB fractional dead times

    Demand rate A = DA = DDemand rate B = DB = PAD

    Fractional dead time of system = 4/3PAPB

    Hazard rate of system =4/3DPAPB

    A

    B

    Demand rate D

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    Occurrence estimationFor n redundant protective systems:r = n-m+1

    With mnumber ofsystems that need

    to work for protection

    !! !1 rnr nr TPnnm

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    Two protective systems in series

    PA and PB fractional dead times

    System is dead if A or B fails

    Fractional dead time of system =

    PA + PB - PAPB

    Demand rate DA B

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    Fault tree analysisExample: reactor overpressure

    Overpressuring

    of reactorAND

    Failure of alarm

    indicator

    Failure of emergency

    shutdown

    Pressure switch 1 failure

    P= 0.13

    Pressure indicator

    light failure P=0.04

    Pressure switch 2 failure

    P=0.13

    Solenoid valve failure

    P=0.34

    OR

    OR

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    Fault tree analysisAdvantages

    Begins with top event (event of interest)

    Enormous insight into path to incidentCan be computerised

    Disadvantages

    Can become enormous

    Uncertainty and subjective structure

    Failure probabilities not always known

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    Event tree analysisStart at an initiating event and look at the

    consequence

    Time sequence of event propagation is embedded

    Each event depends on the precursor event

    Outcomes of precursor event are either binary

    (Yes/No) or multiple

    Commonly used to gauge effect of release of

    material

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    Event tree analysis: Example

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    Event tree analysis:

    Technique description:

    Identify the initiating event (can come from outcome

    of FTA)Identify the safety function/hazard factor and

    determine outcomes

    Construct the event treeClassify the outcome

    Estimate probability of an event tree branch

    Quantify the outcomes

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    Risk of a process

    Risk of a complete

    process assessed by:

    Quantitative Risk

    Analysis (QRA)

    Layer Of Protection

    Analysis (LOPA)

    Chemical Process Safety, D.A. Crowl and J.F. Louvar, 2001

    The School of Chemical and Environmental Engineering

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    Quantitative Risk Analysis

    Major steps

    1.Define potential event sequences and incidents

    2.Evaluate incident consequences (toxic cloud

    dispersion modelling, fire & explosion modelling)

    3.Estimate incident frequencies (ETA, FTA)

    4.Estimate incident impacts on people, environment

    and property

    5.Estimate risk by combining impact and frequencies

    (graph are commonly used)

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    Layer Of Protection Analysis

    Semi-quantitative tool for analysing and

    assessing risk

    Simplified method to characterize

    consequence and estimate risk

    Frequency of undesired consequences arereduced by added layers of protection

    Determination whether sufficient layers of

    protection exist against certain scenarios

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    Layer Of Protection Analysis

    Chemical Process Safety, D.A. Crowl and J.F. Louvar, 2001

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    Layer Of Protection Analysis

    Method:

    Consequences and effects are approximated

    by categories

    Frequencies of consequences and

    effectiveness of protection layers areapproximated

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    Layer Of Protection Analysis

    Major steps

    Identify a single consequence

    Identify accident scenario and associated single causeIdentify initiating event for the scenario and estimate initiating

    event frequency

    Identify protection layers (PL) and their failure probability on

    demandCalculate frequency of consequence

    Estimate risk from consequence frequency and magnitude

    Evaluate acceptability of risk

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    Layer Of Protection Analysis

    Frequency of a consequence endpoint:

    with fiI : initiating event i frequency

    Pij : probability of failure of the jth PL after initiating

    event I

    fic : consequence frequency for initiating event i

    i

    jij

    I

    i

    C

    i Pff1

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    Layer Of Protection Analysis

    Chemical Process Safety, D.A. Crowl and J.F. Louvar, 2001

    The School of Chemical and Environmental Engineering

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    Qualitative Risk Analysis

    The School of Chemical and Environmental Engineering

    Use of experience

    and past data to

    express likelihoodand severity

    Can be made asdetailed as is required

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    Human errors

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    Human errors

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    Acceptable risk

    If property loss and possible number of fatalities can

    be predicted, quantitative assessment can be made:

    Quantitative risk assessment = Incident frequency

    x loss per incident

    Loss per incident can be compared to cost of safetyequipment

    One measure of risk is Fatal Accident Frequency Rate

    (FAFR): # of fatal accidents per 108 working hours = #

    of fatal accidents per 1000 (wo)men in their work life

    The School of Chemical and Environmental Engineering

    Th S h l f Ch i l d E i t l E i i

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    Acceptable risk ?

    If FAFR > 0.4: priority elimination (general rule for

    employees in process industry)

    Hazard generally acceptable if FAFR

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    Non-occupational risks

    Risk/(person year)

    Cancer 280 x 10-5

    Road accidents (UK) 10 x 10-5

    All accidents (UK) 30 x 10-5

    Smoking (20cig/day) 500 x 10-5

    Drinking (1btl wine/day) 75 x 10-5

    All risks man 20yr 100 x 10-5

    Lightning 10-7

    Nuclear release 10-7

    Meteorite 10-11

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    Th S h l f Ch i l d E i t l E i i

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    ALARP

    As Low As Reasonably Practicable

    Comparison of level of risk to cost of lowering the risklevel

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    The School of Chemical and En ironmental Engineering

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    ALARP

    The School of Chemical and Environmental Engineering

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    ALARP

    FAFR Risk/(person year)

    Max tolerable limit

    Employees

    PublicPublic (nuclear)

    50 10-3

    10-4

    10-5

    Legal limit ionizing

    radiation

    75 1.5 x 10-3

    Max tol. risk ionizing

    radiationEmployees 20-25 5x10-3

    Broadly acceptable risk

    (public + employees)

    0.05 10-6

    Negligible risk (public +

    employees)

    0.005 (?) 10-7 (?)

    The School of Chemical and Environmental Engineering

    The School of Chemical and Environmental Engineering

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    Hazard analysis

    The School of Chemical and Environmental Engineering